TW202237752A

TW202237752A - Anti-biological adhesion inorganic material layered structure and paint therefore

Info

Publication number: TW202237752A
Application number: TW110109642A
Authority: TW
Inventors: 林蔓華; 施宏道; 沈弘濱
Original assignee: 匯聚精密科技股份有限公司
Priority date: 2021-03-17
Filing date: 2021-03-17
Publication date: 2022-10-01

Abstract

The present invention provides a layered structure of anti-biological adhesion inorganic material, which is applied to a carrier and can inhibit the adhesion of an organism to the carrier in an operating environment where the pH is not neutral (PH=7) and resist biological adhesion to an inorganic material layer. The layered structure includes an anti-rust primer layer and an inorganic protective layer. The anti-rust primer layer is arranged on the surface of the carrier to isolate at least one of an acid and an alkaline substance in the operating environment. The inorganic protective layer is arranged on one side of the anti-rust primer layer. The inorganic protective layer at least contains a resin and a calcium (Ca). Among them, calcium occupies at least 0.8~50% by weight of the inorganic protective layer, and the particle size of calcium (Ca) is nanometer level. The present invention also provides an anti-biological adhesion inorganic material paint.

Description

抗生物附著無機材料層狀結構及其塗料Layered structure of anti-biological adhesion inorganic material and its coating

本發明係關於一種抗生物附著的技術領域，尤指一種具有耐腐蝕、抗菌之抗生物附著無機材料層狀結構及其塗料。The invention relates to the technical field of anti-biological adhesion, in particular to a layered structure of an anti-biological adhesion inorganic material with corrosion resistance and antibacterial properties and a coating thereof.

在液體或是空氣中充滿各式的物質，包含生物性(例如微生物等)與非生物性的物質(例如灰塵等)，物質會附著在載體上，進而影響原有載體的效率。The liquid or air is filled with various substances, including biological (such as microorganisms, etc.) and non-biological substances (such as dust, etc.), and the substances will be attached to the carrier, thereby affecting the efficiency of the original carrier.

以船舶或軍艦為例說明，當船舶或軍艦受到生物性物質的附著之後，對於船舶、軍艦、海洋存在不小的影響，例如 (1) 增加船舶或軍艦之航行的阻力，導致於航行速度將低，且加快燃料的消耗； (2)改變金屬材料表面特性，加速腐蝕； (3)危害管道系統，影響設備正常工作；(4)增加船舶維修次數，造成航率降低、使用壽命縮短等重大損失；以及(5) 海洋生物污染造成的損失難以精確計算。在前述(1)中，因為生物性物質的附著，將導致船舶或軍艦之速度下降 10% ，為了彌補阻力所導致速度的下降的問題，船舶或軍艦需要多耗費 40% 的油料方才能達到原有的續航力。美國海軍對生物性物質與油耗進行了研究，結果表明一艘輕型排水量之船舶或軍艦在附著有生物性物質的情況下，在正常巡航速度下，會額外增加15%的油耗，若是在一艘重度排水量之船舶或軍艦附著有生物性物質的情況下，在正常巡航速度下，會額外增加200%至300%的油耗。此外，附著在船底的生物性物質(例如貝類、藤壺等)在生長中會分泌各種腐蝕性的液體，例如貝類釋放出的***物就是帶酸性的氧化物質，船舶或軍艦之船底在長期氧化物質的作用下更快鏽蝕。Taking ships or warships as an example, when a ship or warship is attached by biological substances, it will have a considerable impact on the ship, warship, and ocean, such as (1) increasing the resistance of the ship or warship's navigation, resulting in a decrease in the speed of navigation. (2) Change the surface characteristics of metal materials and accelerate corrosion; (3) Harm the pipeline system and affect the normal operation of equipment; (4) Increase the number of ship maintenance, resulting in a reduction in voyage rate and shortened service life. losses; and (5) losses due to marine biofouling are difficult to accurately measure. In the aforementioned (1), due to the adhesion of biological substances, the speed of the ship or warship will drop by 10%. In order to compensate for the speed drop caused by resistance, the ship or warship needs to consume 40% more fuel to achieve the original speed. Some endurance. The U.S. Navy has conducted research on biological substances and fuel consumption, and the results show that a light displacement ship or warship will increase fuel consumption by an additional 15% at normal cruising speed if biological substances are attached to it. When biological substances are attached to heavy displacement ships or warships, the fuel consumption will increase by 200% to 300% at normal cruising speed. In addition, the biological substances attached to the bottom of the ship (such as shellfish, barnacles, etc.) will secrete various corrosive liquids during their growth. For example, the excrement released by shellfish is an acidic oxidizing substance. Rust faster under the action of substances.

因此，傳統上，為了解決效率降低的問題，會在船舶或軍艦的底部塗覆船底漆，以避免海洋中生物性物質的附著。船底漆主要是塗覆在船舶或軍艦水線以下長期浸沒的部分，船底漆由防鏽漆和防污漆兩種性質不同的塗料配套組成。船底防鏽漆是防污漆的底層塗料，它直接塗裝在鋼板上，能防止鋼板的鏽蝕和防止防污漆中毒料對鋼板的腐蝕，以及防污漆是防止船舶或軍艦不受海洋微生物(生物性物質)的附著，在一定時間內能保持船底的光滑與清潔，以此提高航速並節約燃料；然而，傳統的防污漆，是藉由漆膜與具有毒性的防污劑結合，以一定的滲出速度逐步向外滲出毒液(例如氧化亞銅(Cu2O)、石灰(Lime)、砷(Arsenic)等)，以避免海洋微生物的附著，雖然毒液雖可以避免海洋微生物的附著，但是也會汙染海洋。Therefore, conventionally, in order to solve the problem of reduced efficiency, a bottom paint is applied to the bottom of ships or warships to avoid adhesion of biological substances in the sea. The ship bottom paint is mainly applied to the long-term immersion part of the ship or warship below the waterline. The ship bottom paint is composed of two kinds of paints with different properties, anti-rust paint and anti-fouling paint. The bottom antirust paint is the bottom coating of antifouling paint. It is directly coated on the steel plate, which can prevent the corrosion of the steel plate and prevent the corrosion of the steel plate by the poisonous material of the antifouling paint. The attachment of (biological substances) can keep the bottom of the ship smooth and clean for a certain period of time, thereby increasing the speed of the ship and saving fuel; however, the traditional antifouling paint is based on the combination of the paint film and the toxic antifouling agent. Gradually exude venom (such as cuprous oxide (Cu2O), lime (Lime), arsenic (Arsenic), etc.) at a certain oozing speed to avoid the attachment of marine microorganisms. Although the venom can avoid the attachment of marine microorganisms, it is also will pollute the ocean.

因此，如何能改善前述問題，實為一個值得研究之課題。Therefore, how to improve the aforementioned problems is really a topic worthy of research.

本發明之第一目的係提供一種抗生物附著無機材料層狀結構，係應用於載體，以達到抑制生物附著於載體的目的。The first object of the present invention is to provide a layered structure of an anti-biological adhesion inorganic material, which is applied to a carrier to achieve the purpose of inhibiting biological adhesion to the carrier.

本發明之第二目的係根據上述抗生物附著無機材料層狀結構，提供無機防護層，以達到無毒環保與避免污染環境的目的。The second object of the present invention is to provide an inorganic protective layer according to the layered structure of the above-mentioned anti-biological adhesion inorganic material, so as to achieve the purpose of non-toxic environmental protection and avoiding environmental pollution.

本發明之第三目的係根據上述抗生物附著無機材料層狀結構，具有抑菌與抗菌的效果。The third object of the present invention is to have antibacterial and antibacterial effects according to the layered structure of the above-mentioned anti-biological adhesion inorganic material.

本發明之第四目的係根據上述抗生物附著無機材料層狀結構，具有高硬度、耐燃度、耐高溫、高硬度等特性。The fourth object of the present invention is to have properties such as high hardness, flame resistance, high temperature resistance, and high hardness according to the layered structure of the above-mentioned anti-biological adhesion inorganic material.

本發明之第五目的係提供一種抗生物附著無機材料塗料，能夠應用於載體，以達到抑制生物附著於載體的目的。The fifth object of the present invention is to provide an anti-biological adhesion inorganic material coating, which can be applied to the carrier to achieve the purpose of inhibiting the biological adhesion to the carrier.

為達上述目的，本發明提出一種抗生物附著無機材料層狀結構，係應用於一載體且在酸鹼度不為中性(PH=7)的操作環境中能夠供抑制一生物附著於載體，抗生物附著無機材料層狀結構包括一防鏽底漆層與一無機防護層。防鏽底漆層係設置於載體的表面，以能夠隔離操作環境的一酸性與一鹼性物質之至少一者。無機防護層設置在防鏽底漆層之一側。無機防護層至少包含一樹脂與一鈣(Ca)。其中，鈣佔有無機防護層至少0.8~50%以上的重量比，且鈣(Ca)的顆粒尺寸為包含但不限於微米等級與奈米等級。In order to achieve the above-mentioned purpose, the present invention proposes a layered structure of an anti-biological adhesion inorganic material, which is applied to a carrier and can be used to inhibit a biological adhesion to the carrier in an operating environment where the pH is not neutral (PH=7). The layered structure of the attached inorganic material includes an antirust primer layer and an inorganic protective layer. The antirust primer layer is arranged on the surface of the carrier to isolate at least one of an acidic substance and an alkaline substance in the operating environment. The inorganic protective layer is arranged on one side of the antirust primer layer. The inorganic protective layer at least includes a resin and a calcium (Ca). Wherein, calcium accounts for at least 0.8-50% by weight of the inorganic protective layer, and the particle size of calcium (Ca) includes but is not limited to micron and nanometer levels.

為達上述目的，本發明提出一種抗生物附著無機塗料，係應用於載體且在酸鹼度不為中性(PH=7)的操作環境中能夠供抑制生物附著於載體。抗生物附著無機塗料包含一防鏽底漆層與一無機防護層。其中，無機防護層係將各原料成分混合，其特徵在於原料成分為：樹脂與鈣。於其他實施例中，樹脂的重量百分比可為20~70%與鈣的重量百分比可為0.8~50%。此外，除了樹脂與鈣之外，還可以包含例如鋅、鈉、鎂、鉀與鐵等的化學元素。In order to achieve the above purpose, the present invention proposes an anti-biological adhesion inorganic coating, which is applied to the carrier and can inhibit the biological adhesion to the carrier in an operating environment where the pH is not neutral (PH=7). The anti-biological adhesion inorganic paint comprises an anti-rust primer layer and an inorganic protective layer. Wherein, the inorganic protective layer is made by mixing various raw material components, which is characterized in that the raw material components are: resin and calcium. In other embodiments, the weight percentage of resin may be 20-70% and the weight percentage of calcium may be 0.8-50%. In addition, other than resin and calcium, chemical elements such as zinc, sodium, magnesium, potassium, and iron may be included.

相較於習知技術，本發明的抗生物附著無機材料層狀結構包含無毒的鈣(Ca)(於另一實施例中，還可以包含其他化學元素，例如鋅(Zn)、鈉(Na)、鎂(Mg)、鉀(K)與鐵(Fe))，且其中主要的成分是鈣，鈣的熔點可高達842 °C，可以耐高溫，可以適用於高溫的烘烤固化。Compared with the prior art, the anti-biological adhesion inorganic material layered structure of the present invention comprises non-toxic calcium (Ca) (in another embodiment, can also comprise other chemical elements, such as zinc (Zn), sodium (Na) , magnesium (Mg), potassium (K) and iron (Fe)), and the main component is calcium, the melting point of calcium can be as high as 842 °C, it can withstand high temperature, and can be suitable for high temperature baking and curing.

由於各種態樣與實施例僅為例示性且非限制性，故在閱讀本說明書後，具有通常知識者在不偏離本發明之範疇下，亦可能有其他態樣與實施例。根據下述之詳細說明與申請專利範圍，將可使該等實施例之特徵及優點更加彰顯。Since the various aspects and embodiments are only illustrative and non-restrictive, after reading this specification, those with ordinary knowledge may also have other aspects and embodiments without departing from the scope of the present invention. According to the following detailed description and scope of patent application, the features and advantages of these embodiments will be more evident.

於本文中，係使用「一」或「一個」來描述本文所述的元件和組件。此舉只是為了方便說明，並且對本發明之範疇提供一般性的意義。因此，除非很明顯地另指他意，否則此種描述應理解為包括一個或至少一個，且單數也同時包括複數。Herein, "a" or "an" is used to describe the elements and components described herein. This is done for convenience of description only and to provide a general sense of the scope of the invention. Accordingly, such description should be read to include one or at least one and the singular also includes the plural unless it is obvious that it is otherwise meant.

於本文中，用語「第一」或「第二」等類似序數詞主要是用以區分或指涉相同或類似的元件或結構，且不必然隱含此等元件或結構在空間或時間上的順序。應了解的是，在某些情形或組態下，序數詞可以交換使用而不影響本創作之實施。In this article, the terms "first" or "second" and similar ordinal numbers are mainly used to distinguish or refer to the same or similar elements or structures, and do not necessarily imply that these elements or structures are separated in space or time. order. It should be understood that in certain situations or configurations, ordinal numbers may be used interchangeably without affecting the practice of the invention.

於本文中，用語「包括」、「具有」或其他任何類似用語意欲涵蓋非排他性之包括物。舉例而言，含有複數要件的元件或結構不僅限於本文所列出之此等要件而已，而是可以包括未明確列出但卻是該元件或結構通常固有之其他要件。As used herein, the term "includes", "has" or any other similar term is intended to cover a non-exclusive inclusion. For example, an element or structure containing a plurality of elements is not limited to the elements listed herein, but may include other elements not explicitly listed but generally inherent to the element or structure.

參考圖1，係本發明之第一實施例的抗生物附著無機材料層狀結構的結構示意圖。在圖1中，抗生物附著無機材料層狀結構10係應用於一載體2在酸鹼度不為中性(PH=7)的操作環境4中能夠供抑制一生物6附著於載體2，一併參考圖2，係說明本發明圖1之抗生物附著無機材料層狀結構應用於船舶的示意圖。其中，載體2例如可為船舶、軍艦、遊艇、鑽油平台等和操作環境4例如可為海洋、湖泊等。於本實施例中，載體2係以船舶為例說明。Referring to FIG. 1 , it is a schematic structural view of the layered structure of the anti-fouling inorganic material according to the first embodiment of the present invention. In Fig. 1, the anti-bioadhesion inorganic material layered structure 10 is applied to a carrier 2 in an operating environment 4 where the pH is not neutral (PH=7) and can be used to inhibit a biological 6 from attaching to the carrier 2, for reference Fig. 2 is a schematic diagram illustrating the application of the layered structure of the anti-fouling inorganic material in Fig. 1 of the present invention to a ship. Wherein, the carrier 2 may be, for example, a ship, a warship, a yacht, an oil drilling platform, etc., and the operating environment 4 may, for example, be an ocean, a lake, or the like. In this embodiment, the carrier 2 is described by taking a ship as an example.

抗生物附著無機材料層狀結構10包括一防鏽底漆層12與一無機防護層14。於本實施例中，抗生物附著無機材料層狀結構10是設置在載體2(即是船舶)經常浸潤在海洋的操作環境4且容易發生腐蝕的船底位置。前述，抗生物附著無機材料層狀結構10設置於載體2的方式可透過噴塗、滾塗、浸泡、烘烤等工藝。The anti-biological adhesion inorganic material layered structure 10 includes an antirust primer layer 12 and an inorganic protective layer 14 . In this embodiment, the anti-fouling inorganic material layered structure 10 is arranged on the bottom of the carrier 2 (that is, the ship) where the operating environment 4 is often infiltrated in the ocean and is prone to corrosion. As mentioned above, the method of disposing the anti-fouling inorganic material layered structure 10 on the carrier 2 can be through spraying, rolling, soaking, baking and other processes.

防鏽底漆層12係設置於載體2的表面22，以能夠隔離操作環境4的一酸性(或一鹼性物質)，例如防鏽底漆層12可為伐銹底漆(Wash Primer)、有機鋅粉底漆(Organic zinc rich primer)、環氧無鋅底漆(Non-zinc primer)、無機鋅粉底漆(Inorganic zinc rich primer)、油性樹脂漆(Oleoresinous paint)、氯化橡膠漆(Chlorinated rubber paint)、聚氯乙烯樹脂漆(Vinyl resin paint)、環氧樹脂漆(Epoxy resin paint)、瀝青環氧樹脂漆(Tar-epoxy resin paint)、聚氨脂樹脂漆(Polyurethane resin paint)等。The antirust primer layer 12 is arranged on the surface 22 of the carrier 2, so as to isolate an acidic (or an alkaline substance) of the operating environment 4. For example, the antirust primer layer 12 can be a rust-resistant primer (Wash Primer), Organic zinc rich primer, epoxy zinc-free primer (Non-zinc primer), inorganic zinc powder primer (Inorganic zinc rich primer), oleoresinous paint, chlorinated rubber paint paint), polyvinyl chloride resin paint (Vinyl resin paint), epoxy resin paint (Epoxy resin paint), asphalt epoxy resin paint (Tar-epoxy resin paint), polyurethane resin paint (Polyurethane resin paint), etc.

無機防護層14設置在防鏽底漆層12之一側。其中，無機防護層14包含樹脂142、鈣(Ca)144與化學元素146。其中，鈣144佔有無機防護層14至少20%以上的重量比，且鈣(Ca)的顆粒尺寸為奈米等級。值得注意的是，鈣144是由以生物性方式或化學性方式所產生。舉例而言，生物性方式的鈣144可以取自於自然環境的生物，亦即把大自然中存在的含鈣物質，經過研磨或煅燒等方法製成粉末，例如動物骨骼、化石(例如骨骼化石)等；以及，化學性方式的鈣144係可以透過化學分離方式解析例如碳酸鈣、氯化鈣、磷酸鈣、葡萄糖酸鈣、檸檬酸鈣等。於本實施例中，無機防護層14可以透過烘烤固化的方式形成在防鏽底漆層12之一側，烘烤固化的溫度範圍可以控制在180度至200度之間，且烘烤固化的時間範圍可以控制在10分鐘至20分鐘之間。於另外一實施例中，無機防護層14也可以透過自然固化的方式形成在防鏽底漆層12之一側，例如自然固化的時間範圍係24小時至48小時之間。The inorganic protective layer 14 is provided on one side of the antirust primer layer 12 . Wherein, the inorganic protective layer 14 includes a resin 142 , calcium (Ca) 144 and chemical elements 146 . Wherein, calcium 144 accounts for at least 20% by weight of the inorganic protective layer 14 , and the particle size of calcium (Ca) is nanometer level. It should be noted that calcium 144 is produced biologically or chemically. For example, calcium 144 in a biological way can be obtained from organisms in the natural environment, that is, calcium-containing substances existing in nature are ground or calcined to make powder, such as animal bones, fossils (such as bone fossils ), etc.; and, the chemical calcium 144 system can be analyzed by chemical separation methods such as calcium carbonate, calcium chloride, calcium phosphate, calcium gluconate, calcium citrate, etc. In this embodiment, the inorganic protective layer 14 can be formed on one side of the anti-rust primer layer 12 by baking and curing. The time range can be controlled between 10 minutes and 20 minutes. In another embodiment, the inorganic protective layer 14 may also be formed on one side of the antirust primer layer 12 through natural curing, for example, the natural curing time ranges from 24 hours to 48 hours.

於另一實施例中，前述樹脂142更包含添加料(Additive)、顏料(Pigment)、溶劑(Solvent)之至少一者。其中，添加料可依用途不同而添加，以提高漆膜性能，例如乾燥劑、止流劑、防泡劑等；顏料可表現塗料的顏色與補強油漆性能，例如鈦白、黑鉛、鋅黃、鉛丹、銀粉等；以及，溶劑可增加塗料流展性，以利塗抹。In another embodiment, the aforementioned resin 142 further includes at least one of additives, pigments, and solvents. Among them, additives can be added according to different purposes to improve the performance of the paint film, such as desiccant, anti-flow agent, anti-foaming agent, etc.; pigments can express the color of the paint and enhance the performance of the paint, such as titanium dioxide, black lead, zinc yellow , red lead, silver powder, etc.; and, the solvent can increase the fluidity of the paint to facilitate smearing.

於一實施例中，前述化學元素146可以為鋅(Zn)、鈉(Na)、鎂(Mg)、鉀(K)與鐵(Fe)，例如在無機防護層10的鈣、鈉、鎂、鉀與鐵的重量比分別地為37%、0.5%、0.26%、0.012%與0.34%。In one embodiment, the aforementioned chemical elements 146 can be zinc (Zn), sodium (Na), magnesium (Mg), potassium (K) and iron (Fe), such as calcium, sodium, magnesium, The weight ratios of potassium to iron are 37%, 0.5%, 0.26%, 0.012% and 0.34%, respectively.

又於另一實施例中，無機防護層係將各原料成分混合，其特徵在於各原料成分及其重量百分數為：樹脂為20~70%；鈣為0.8~50%；鈉為0.1~10%；鎂為0.1~5%；鉀為0.001~0.1%；以及，鐵為0.1~0.5%。In yet another embodiment, the inorganic protective layer is a mixture of various raw material components, which is characterized in that each raw material component and its weight percentage are: 20-70% for resin; 0.8-50% for calcium; 0.1-10% for sodium ; magnesium is 0.1~5%; potassium is 0.001~0.1%; and iron is 0.1~0.5%.

於另一實施例中，無機防護層14可以是一種抗生物附著無機塗料，係應用於載體且在酸鹼度不為中性(PH=7)的操作環境中能夠供抑制生物附著於該載體，該抗生物附著無機塗料包含防鏽底漆層與無機防護層，其中該無機防護層係將原料成分混合，其特徵在於原料成分至少包含樹脂與鈣。In another embodiment, the inorganic protective layer 14 can be a kind of anti-biological adhesion inorganic coating, which is applied to the carrier and can inhibit the biological adhesion to the carrier in the operating environment where the pH is not neutral (PH=7). The anti-biological adhesion inorganic paint comprises an anti-rust primer layer and an inorganic protective layer, wherein the inorganic protective layer is a mixture of raw material components, and the feature is that the raw material components at least contain resin and calcium.

參考圖3，係本發明之第二實施例的抗生物附著無機材料層狀結構的結構示意圖。在圖3中，抗生物附著無機材料層狀結構10’除包含第一實施例的防鏽底漆層12與無機防護層14之外，更包含中間塗層16。Referring to FIG. 3 , it is a schematic structural diagram of the layered structure of the anti-fouling inorganic material according to the second embodiment of the present invention. In FIG. 3 , the anti-fouling inorganic material layered structure 10' further includes an intermediate coating 16 in addition to the anti-rust primer layer 12 and the inorganic protective layer 14 of the first embodiment.

防鏽底漆層12與無機防護層14的說明如前所述，於此不贅述。The descriptions of the anti-rust primer layer 12 and the inorganic protective layer 14 are as mentioned above, and will not be repeated here.

中間塗層16設置於防鏽底漆層12與無機防護層14之間，以提高防鏽底漆層12與無機防護層14之間的附著力，例如中間塗層16的材料可為環氧樹脂、鱗片狀雲母氧化鐵、聚醯亞胺等。Intermediate coating 16 is arranged between antirust primer layer 12 and inorganic protection layer 14, to improve the adhesion between antirust primer layer 12 and inorganic protection layer 14, for example the material of intermediate coating 16 can be epoxy Resin, flaky mica iron oxide, polyimide, etc.

以上實施方式本質上僅為輔助說明，且並不欲用以限制申請標的之實施例或該等實施例的應用或用途。此外，儘管已於前述實施方式中提出至少一例示性實施例，但應瞭解本發明仍可存在大量的變化。同樣應瞭解的是，本文所述之實施例並不欲用以透過任何方式限制所請求之申請標的之範圍、用途或組態。相反的，前述實施方式將可提供本領域具有通常知識者一種簡便的指引以實施所述之一或多種實施例。再者，可對元件之功能與排列進行各種變化而不脫離申請專利範圍所界定的範疇，且申請專利範圍包括已知的均等物及在本專利申請案提出申請時的所有可預見均等物。The above-mentioned embodiments are only auxiliary descriptions in nature, and are not intended to limit the embodiments of the subject matter of the application or the applications or uses of these embodiments. Furthermore, while at least one exemplary embodiment has been presented in the foregoing description, it should be appreciated that a wide variety of variations are possible. It should also be appreciated that the embodiments described herein are not intended to limit the scope, use, or configuration of claimed subject matter in any way. Rather, the foregoing description will provide those skilled in the art with a convenient guide for implementing one or more of the described embodiments. Furthermore, various changes may be made in the function and arrangement of elements without departing from the scope defined by the claims, which include known equivalents and all foreseeable equivalents at the time of filing this patent application.

2:載體 22:表面 4:操作環境 10、10’:抗生物附著無機材料層狀結構 12:防鏽底漆層 14:無機防護層 142:樹脂 144:鈣 146:化學元素 16:中間塗層 2: carrier 22: surface 4: Operating environment 10, 10': Anti-bioadhesion inorganic material layered structure 12: Anti-rust primer layer 14: Inorganic protective layer 142: Resin 144: Calcium 146: Chemical elements 16: Intermediate coating

圖1係本發明之第一實施例的抗生物附著無機材料層狀結構的結構示意圖。圖2係說明本發明圖1之抗生物附著無機材料層狀結構應用於船舶的示意圖。圖3係本發明之第二實施例的抗生物附著無機材料層狀結構的結構示意圖。 Fig. 1 is a schematic structural view of the layered structure of the anti-bioadhesion inorganic material according to the first embodiment of the present invention. Figure 2 is a schematic diagram illustrating the application of the layered structure of the anti-fouling inorganic material in Figure 1 of the present invention to a ship. Fig. 3 is a schematic structural view of the layered structure of the anti-fouling inorganic material according to the second embodiment of the present invention.

2:載體 2: carrier

22:表面 22: surface

10:抗生物附著無機材料層狀結構 10: Anti-fouling inorganic material layered structure

12:防鏽底漆層 12: Anti-rust primer layer

14:無機防護層 14: Inorganic protective layer

142:樹脂 142: Resin

144:鈣 144: Calcium

146:化學元素 146: Chemical elements

Claims

一種抗生物附著無機材料層狀結構，係應用於載體且在酸鹼度不為中性(PH=7)的操作環境中能夠供抑制生物附著於該載體，該抗生物附著無機材料層狀結構包括：防鏽底漆層，係設置於該載體的表面，以供隔離該操作環境的酸性與鹼性物質之至少一者；以及無機防護層，係設置在該防鏽底漆層之一側，該無機防護層至少包含樹脂與鈣(Ca)。 A layered structure of an anti-bioadhesion inorganic material, which is applied to a carrier and can be used to inhibit organisms from adhering to the carrier in an operating environment where the pH is not neutral (PH=7). The layered structure of an anti-bioadhesion inorganic material includes: An anti-rust primer layer is provided on the surface of the carrier to isolate at least one of acidic and alkaline substances in the operating environment; and The inorganic protective layer is arranged on one side of the antirust primer layer, and the inorganic protective layer at least contains resin and calcium (Ca).

如請求項1所述之抗生物附著無機材料層狀結構，其中該鈣以生物性方式與化學性方式之至少一者產生，該鈣佔有該無機防護層至少0.8~50%以上的重量比。The layered structure of anti-fouling inorganic materials according to claim 1, wherein the calcium is produced by at least one of biological and chemical methods, and the calcium accounts for at least 0.8-50% by weight of the inorganic protective layer.

如請求項1所述之抗生物附著無機材料層狀結構，其中該鈣(Ca)的顆粒尺寸為奈米等級或微米等級。The layered structure of anti-bioadhesion inorganic material as claimed in claim 1, wherein the particle size of the calcium (Ca) is nanoscale or micron scale.

如請求項1所述之抗生物附著無機材料層狀結構，其中該無機防護層更包含化學元素，該化學元素至少為鋅(Zn)、鈉(Na)、鎂(Mg)、鉀(K)與鐵(Fe)之至少一者。The anti-biological adhesion inorganic material layered structure as described in Claim 1, wherein the inorganic protective layer further comprises chemical elements, and the chemical elements are at least zinc (Zn), sodium (Na), magnesium (Mg), and potassium (K) and at least one of iron (Fe).

如請求項1所述之抗生物附著無機材料層狀結構，其中該樹脂更包含添加料(Additive)、顏料(Pigment)與溶劑(Solvent)之至少一者。The layered structure of anti-biological adhesion inorganic material according to claim 1, wherein the resin further includes at least one of additives, pigments and solvents.

如請求項1所述之抗生物附著無機材料層狀結構，更包含中間塗層，係設置於該防鏽底漆層與該無機防護層之間。The layered structure of anti-fouling inorganic materials as described in claim 1 further includes an intermediate coating, which is arranged between the anti-rust primer layer and the inorganic protective layer.

如請求項1所述之抗生物附著無機材料層狀結構，其中該無機防護層烘烤固化的溫度範圍係180度至200度之間。The anti-bioadhesion inorganic material layered structure as described in Claim 1, wherein the baking and curing temperature range of the inorganic protective layer is between 180°C and 200°C.

如請求項7所述之抗生物附著無機材料層狀結構，其中該無機防護層烘烤固化的時間範圍係10分鐘至20分鐘之間，或該無機防護層自然固化的時間範圍係24小時至48小時之間。The anti-bioadhesion inorganic material layered structure as described in claim 7, wherein the time range for baking and curing of the inorganic protective layer is between 10 minutes and 20 minutes, or the time range for natural curing of the inorganic protective layer is 24 hours to between 48 hours.

如請求項1所述之抗生物附著無機材料層狀結構，其中該無機防護層係透過噴塗、滾塗、烘烤與浸泡之至少一者工藝設置在該防鏽底漆層之一側。The anti-fouling inorganic material layered structure as described in claim 1, wherein the inorganic protective layer is provided on one side of the anti-rust primer layer by at least one of spraying, rolling, baking and soaking.

一種抗生物附著無機塗料，係應用於載體且在酸鹼度不為中性(PH=7)的操作環境中能夠供抑制生物附著於該載體，該抗生物附著無機塗料包含防鏽底漆層與無機防護層，其中該無機防護層係將各原料成分混合，其特徵在於各原料成分：樹脂；以及鈣。 An anti-biological adhesion inorganic coating is applied to a carrier and can be used to inhibit biological adhesion to the carrier in an operating environment where the pH is not neutral (PH=7). The anti-biological adhesion inorganic coating includes an anti-rust primer layer and an inorganic A protective layer, wherein the inorganic protective layer is a mixture of raw material components, characterized in that each raw material component: resin; and calcium.