TW202146078A

TW202146078A - Anti-virus facial mask and the method of forming the same

Info

Publication number: TW202146078A
Application number: TW109118540A
Authority: TW
Inventors: 江國慶
Original assignee: 克米龍有限公司
Priority date: 2020-06-01
Filing date: 2020-06-01
Publication date: 2021-12-16

Abstract

The present invention discloses a substrate for a facial mask, the substrate is formed by Roll to Roll process and to have anti-Virus function. The mask comprises an inner layer, a middle layer and an outer layer, wherein the middle layer or the outer layer comprises a metalloorganic compound for inhibiting the virus.

Description

抑制病毒口罩與其製作方法 Virus-inhibiting mask and its making method

本發明係關於一種口罩，尤其是有關於一種抗病毒口罩與其製程。 The present invention relates to a mask, in particular to an antiviral mask and a manufacturing process thereof.

近年來由於流感橫行，特別是對於孩童而言，影響尤其嚴重。目前所有市面口罩只有過濾粉塵、或細菌功能，無防護抑制、殺死病毒功能，本發明於是生焉。 In recent years, due to the prevalence of influenza, especially for children, the impact has been particularly severe. At present, all the masks on the market only have the function of filtering dust or bacteria, but have no function of protecting and inhibiting or killing viruses, so the present invention is born.

本發明係有關於具有下列特性之口罩。本發明提出一種口罩之製作方法，包含：備置浸染溶液，該浸染溶液包含抗病毒(及/或滅菌酵素)與樹脂成分；以轉軸至轉軸式裝置驅動基材移動，藉由通過具有浸染溶液之浸染槽，使該基材吸附該浸染溶液，形成抗病毒成分於該基材上，其中基材包含不織布，基材包含PP。 The present invention relates to a mask having the following characteristics. The present invention provides a method for making a mask, comprising: preparing a dip solution containing antiviral (and/or sterilizing enzymes) and resin components; driving a substrate to move with a rotary shaft-to-rotary device, and by passing through a process with the dip solution In a dip-dyeing tank, the base material is made to absorb the dip-dye solution to form an antiviral component on the base material, wherein the base material comprises non-woven fabric and the base material comprises PP.

本發明揭露一種口罩，包含：裏層；中層，配置於該裏層之上；及外層，配置於該中層之上，其中製作外層步驟包含：備置浸染溶液，該浸染溶液包含抗病毒(及/或滅菌酵素)與樹脂成分；以轉軸至轉軸式裝置驅動基材移動，藉由通過具有浸染溶液之浸染槽，使該基材吸附該浸染溶液，形成抗病毒成分於該基材上，其中基材包含不織布，基材包含PP。 The present invention discloses a mask, comprising: an inner layer; a middle layer, arranged on the inner layer; and an outer layer, arranged on the middle layer, wherein the step of making the outer layer comprises: preparing a dip solution, the dip solution containing antiviral (and/or or sterilizing enzyme) and resin components; drive the substrate to move with a rotating shaft to a rotating shaft type device, and make the substrate absorb the impregnation solution by passing through the impregnation tank with the impregnation solution to form an antiviral component on the substrate, wherein the base The material contains non-woven fabric, and the base material contains PP.

本發明揭露一種口罩，包含：裏層，其中製作該裏層步驟包含：備置浸染溶液，該浸染溶液包含香味分子；以轉軸至轉軸式裝置驅動基材移動，藉由通過具有浸染溶液之浸染槽，使該基材吸附該香味分子，使該基材具有香氣；中層，配置於該裏層之上；及外層，配置於該中層。本發明揭露一種口罩，包含一種口罩，包含：裏層；中層，配置於該裏層之上，包含過濾層；及外層，配置於該中層之上，其中該外層包含陽離子金屬有機化合物，用於抑制病毒。其中該外層包含紫外線吸收劑、光致變色染料、樹脂或上述之任意組合。其中該外層包含溶菌酵素，其中該中層包含奈米微孔聚四氟乙烯(PTFE)薄膜。 The invention discloses a mask, comprising: an inner layer, wherein the step of making the inner layer comprises: preparing a dip-dyeing solution, the dip-dyeing solution containing fragrance molecules; driving a substrate to move with a rotary shaft-to-rotation-shaft type device, by passing through a dip-dyeing tank with the dip-dyeing solution , so that the base material adsorbs the aroma molecules, so that the base material has aroma; The middle layer is arranged on the inner layer; and the outer layer is arranged on the middle layer. The present invention discloses a mask, comprising a mask, comprising: an inner layer; a middle layer, arranged on the inner layer, including a filter layer; and an outer layer, arranged on the middle layer, wherein the outer layer comprises a cationic metal organic compound, used for Inhibit virus. Wherein the outer layer comprises ultraviolet absorbers, photochromic dyes, resins or any combination thereof. Wherein the outer layer comprises lysozyme, and wherein the middle layer comprises nano-microporous polytetrafluoroethylene (PTFE) film.

本發明揭露一種口罩，包含：裏層；中層，配置於該裏層之上，其中製作該中層步驟包含：備置浸染溶液，該浸染溶液包含抗病毒(及/或滅菌酵素)與樹脂，藉由通過具有浸染溶液之浸染槽，使該中層基材吸附該抗病毒(及/或滅菌酵素)；及外層，配置於該中層之上。 The present invention discloses a mask, comprising: an inner layer; a middle layer, disposed on the inner layer, wherein the step of making the middle layer comprises: preparing an impregnation solution, the impregnation solution comprising antiviral (and/or sterilizing enzymes) and resin, by The middle layer substrate is made to adsorb the antivirus (and/or sterilizing enzyme) through a dyeing tank with a dyeing solution; and the outer layer is disposed on the middle layer.

一種口罩，包含：裏層；中層，配置於該裏層之上，包含超微孔生技濾淨膜(PTFE)；及外層，配置於該中層之上，其中該外層可抗紫外線。其中該外層包含紫外線吸收劑、光致變色染料、樹脂或上述之任意組合。 A mask, comprising: an inner layer; a middle layer, arranged on the inner layer, comprising an ultra-microporous biotechnology filter membrane (PTFE); and an outer layer, arranged on the middle layer, wherein the outer layer can resist ultraviolet rays. Wherein the outer layer comprises ultraviolet absorbers, photochromic dyes, resins or any combination thereof.

一種口罩，包含：裏層，包含香味分子，藉由通過浸染溶液，使該裏層基材吸附該香味分子；中層，配置於該裏層之上，包含超微孔生技濾淨膜(PTFE)；及外層，配置於該中層之上。 A mask, comprising: an inner layer, including fragrance molecules, through which the inner layer base material adsorbs the fragrance molecules by passing through a dyeing solution; a middle layer, disposed on the inner layer, including an ultra-microporous biotechnology filter membrane (PTFE ); and the outer layer, disposed on the middle layer.

一種口罩，包含：裏層；中層，配置於該裏層之上，包含抗菌成份，其中該抗菌成份包含溶菌酵素或抗流感藥劑；及外層，配置於該中層之上，其中該外層可抗紫外線。 A mask, comprising: an inner layer; a middle layer, disposed on the inner layer, containing an antibacterial ingredient, wherein the antibacterial ingredient comprises lysozyme or an anti-influenza agent; and an outer layer, disposed on the middle layer, wherein the outer layer can resist ultraviolet rays .

一種口罩，包含：裏層；中層，配置於該裏層之上；及外層，配置於該中層之上，包含抗菌成份，其中該抗菌成份包含溶菌酵素或抗流感藥劑，其中該中層包含超微孔生技濾淨膜(PTFE)。 A mask, comprising: an inner layer; a middle layer, arranged on the inner layer; and an outer layer, arranged on the middle layer, comprising an antibacterial ingredient, wherein the antibacterial ingredient comprises lysozyme or an anti-influenza agent, wherein the middle layer comprises ultrafine Pore biotechnology filter membrane (PTFE).

一種口罩，包含：裏層；中層，配置於該裏層之上，包含過濾層；及外層，其中至少該裏層或該外層包含抑制病毒活性物，選自以下之一或任意組合(1)表面蛋白破壞有機化合物，藉由化學吸附性改變病毒表面蛋白質；(2)產生羥基金屬化合物，利用自由基反應產生羥基自由基，提取病毒蛋白質中的氫原子，其中該抑制病活性毒物包含有機一無機複合鹽類或陽離子金屬有機化合物。其中該抑制病毒活性物之抑制病毒活性大於標準值為3，較佳為其中該抑制病毒活性物之抑制病毒活性值為3.4。 A mask, comprising: an inner layer; a middle layer, disposed on the inner layer, comprising a filter layer; and an outer layer, wherein at least the inner layer or the outer layer comprises a virus-inhibiting active substance, selected from one of the following or any combination (1) Surface proteins destroy organic compounds and change virus surface proteins by chemisorption; (2) produce Hydroxy metal compounds use free radical reaction to generate hydroxyl radicals to extract hydrogen atoms in virus proteins, wherein the virus-inhibiting active poisons comprise organic-inorganic complex salts or cationic metal-organic compounds. The virus-inhibiting activity of the virus-inhibiting active substance is greater than the standard value of 3, preferably the virus-inhibiting activity value of the virus-inhibiting active substance is 3.4.

一種製造抑制病毒活性層之方法，包含：備置抑制病毒活性物，其中該抑制病毒活性物選自以下之一或任意組合(1)表面蛋白抑制有機化合物，藉由化學吸附性改變病毒表面蛋白質；(2)產生羥基金屬化合物，利用自由基反應產生羥基自由基，提取病毒蛋白質中的氫原子；及混和該抑制病毒活性物與一溶劑，使其披覆、塗佈、於該抑制病毒活性層之至少一表面。其中該抑制病活性毒物包含有機一無機複合鹽類或陽離子金屬有機化合物。其中該抑制病毒活性物之抑制病毒活性大於標準值為，較佳為3.4。 A method of manufacturing a virus-inhibiting active layer, comprising: preparing a virus-inhibiting active substance, wherein the virus-inhibiting active substance is selected from one or any combination of the following (1) a surface protein-inhibiting organic compound, which changes the virus surface protein by chemical adsorption; (2) generating a hydroxyl metal compound, using a free radical reaction to generate hydroxyl radicals, and extracting hydrogen atoms in the virus protein; and mixing the virus-inhibiting active substance and a solvent to coat, coat, and coat the virus-inhibiting active layer at least one surface. The virus-inhibiting active poison comprises organic-inorganic complex salts or cationic metal organic compounds. The virus-inhibiting activity of the virus-inhibiting active substance is greater than the standard value, preferably 3.4.

一種製造抑制病毒活性層之方法，包含：備置抑制病毒活性物，其中該抑制病毒活性物選自以下之一或任意組合(1)表面蛋白抑制有機化合物，藉由化學吸附性改變病毒表面蛋白質；(2)產生羥基金屬化合物，利用自由基反應產生羥基自由基，提取病毒蛋白質中的氫原子；及混和該抑制病毒活性物與一高分子，利用織布或不織布程序使其摻雜於該抑制病毒活性層中。其中該抑制病活性毒物包含有機一無機複合鹽類或陽離子金屬有機化合物。其中該抑制病毒活性物之抑制病毒活性大於標準值為3，較佳為其中該抑制病毒活性物之抑制病毒活性值為3.4。 A method of manufacturing a virus-inhibiting active layer, comprising: preparing a virus-inhibiting active substance, wherein the virus-inhibiting active substance is selected from one or any combination of the following (1) a surface protein-inhibiting organic compound, which changes the virus surface protein by chemical adsorption; (2) generating a hydroxy metal compound, using a free radical reaction to generate a hydroxy radical, and extracting hydrogen atoms in the viral protein; and mixing the virus-inhibiting active substance with a macromolecule, and using a woven or non-woven procedure to mix it with the inhibitor virus active layer. The virus-inhibiting active poison comprises organic-inorganic complex salts or cationic metal organic compounds. The virus-inhibiting activity of the virus-inhibiting active substance is greater than the standard value of 3, preferably the virus-inhibiting activity value of the virus-inhibiting active substance is 3.4.

一種口罩，包含：一裏層；一中層，配置於該裏層之上，包含過濾層；及一外層，其中該過濾層包含靜電以及抑制病毒活性物，選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬。其中該過濾層包含聚丙烯或聚四氟乙烯。在另一實施例中，其中外層包含抑制病毒活性物，選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽。 A mask, comprising: an inner layer; a middle layer, disposed on the inner layer, comprising a filter layer; and an outer layer, wherein the filter layer contains static electricity and anti-virus actives, selected from the following one or any combination of surface proteins Destroy organic compounds, produce hydroxyl metal compounds, organic-inorganic complex salts, highly active metal compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metals, and silver metals. Wherein the filter layer comprises polypropylene or polytetrafluoroethylene. In another embodiment, wherein the outer layer comprises virus-inhibiting active substances selected from one or any combination of the following surface protein-destroying organic compounds, hydroxy metal compounds, organic-inorganic complex salts, highly active metal compounds, organic copper compounds, organic compounds Zinc compounds, organotin compounds, copper metals, silver metals, metal silicates.

一種口罩，包含：一裏層；一中層，配置於該裏層之上，包含過濾層，其中該過濾層包含靜電及第一抑制病毒活性物；及外層，配置於該中層之上，包含第二抑制病毒活性物，其中該第一抑制病毒活性物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽。其中第二抑制病毒活性物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽。 A mask, comprising: an inner layer; a middle layer, disposed on the inner layer, including a filter layer, wherein the filter layer contains static electricity and a first virus-inhibiting active substance; and an outer layer, disposed on the middle layer, including the first Two virus-inhibiting active substances, wherein the first virus-inhibiting active substance is selected from one of the following or any combination of surface protein destroying organic compounds, producing hydroxyl metal compounds, organic-inorganic complex salts, highly active metal compounds, organic copper compounds, organic zinc compounds Compounds Organotin compounds, copper metals, silver metals, metal silicates. Wherein the second virus-inhibiting active substance is selected from the following one or any combination of surface protein destroying organic compounds, producing hydroxyl metal compounds, organic-inorganic complex salts, highly active metal compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metal compounds , silver metal, metal silicate.

一種製造口罩抑制病毒活性層之方法，包含：備置抑制病毒活性物及備置高分子；混和兩者並使形成熔融混合物，熔融溫度大於160度；將熔融混合物擠入高速熱氣流形成纖維，並堆積成網狀結構製作不織布；將該不織布植入靜電。其中抑制病活性毒物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽。在一實施例中，其中外層包含抑制病毒活性層，其中中層包含抑制病毒活性層。高分子包含聚四氟乙烯、聚丙烯或四氟乙烯-全氟丙烯共聚物，聚四氟乙烯以氟取代聚乙烯中所有氫原子的人工合成高分子材料。這種材料具有抗酸抗鹼、抗各種有機溶劑的特點，幾乎不溶於所有的溶劑。同時，聚四氟乙烯具有耐高溫的特點，它的摩擦系數極低。在另一實施例中，一撥水層，配置於中層和外層之間。 A method for manufacturing a virus-inhibiting active layer of a mask, comprising: preparing a virus-inhibiting active substance and preparing a macromolecule; mixing the two to form a molten mixture with a melting temperature greater than 160 degrees; extruding the molten mixture into a high-speed hot air flow to form fibers, and stacking them The non-woven fabric is made into a net-like structure; the non-woven fabric is implanted with static electricity. The virus-inhibiting active poison is selected from the following one or any combination of surface protein-destroying organic compounds, hydroxy metal compounds, organic-inorganic composite salts, highly active metal compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metals, silver Metals, metal silicates. In one embodiment, wherein the outer layer comprises a virus-inhibiting layer, and wherein the middle layer comprises a virus-inhibiting layer. The polymer includes polytetrafluoroethylene, polypropylene or tetrafluoroethylene-perfluoropropylene copolymer. Polytetrafluoroethylene replaces all hydrogen atoms in polyethylene with fluorine. Synthetic polymer materials. This material has the characteristics of acid and alkali resistance and resistance to various organic solvents, and is almost insoluble in all solvents. At the same time, PTFE has the characteristics of high temperature resistance, and its friction coefficient is extremely low. In another embodiment, a water repellent layer is disposed between the middle layer and the outer layer.

一種口罩外層由紡黏不織布組成，中層由氣流形成纖維，並帶有靜電，作為過濾層；內層由針軋或熱固性不織布組成，也可以用紡黏不織布組成，作為與面部接觸的吸水舒適層。若採用聚丙烯作為中層，因為是疏水性材料，其含水量為零，纖維內嵌的電荷不受環境濕度的影響。一種口罩，包含：一裏層；一中層，配置於該裏層之上，包含氣流形成纖維過濾層，其中該過濾層包含靜電及第一抑制病毒活性物；及外層，包含紡黏不織布，配置於該中層之上，其包含第二抑制病毒活性物，其中該第一抑制病毒活性物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬。其中該第二抑制病毒活性物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽。 The outer layer of a mask is composed of spunbond non-woven fabric, the middle layer is composed of airflow-forming fibers, and has static electricity as a filter layer; the inner layer is composed of needle-rolled or thermosetting non-woven fabric, and can also be composed of spunbond non-woven fabric as a water-absorbing comfort layer in contact with the face. . If polypropylene is used as the middle layer, because it is a hydrophobic material, its water content is zero, and the electric charge embedded in the fiber is not affected by the ambient humidity. A mask, comprising: an inner layer; a middle layer, disposed on the inner layer, comprising an air flow to form a fiber filter layer, wherein the filter layer contains static electricity and a first virus-inhibiting active substance; and an outer layer, comprising a spunbond non-woven fabric, configured Above the middle layer, it comprises a second virus-inhibiting active substance, wherein the first virus-inhibiting active substance is selected from the following one or any combination of surface protein destroying organic compounds, producing hydroxy metal compounds, organic-inorganic complex salts, high activity Metal Compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metal, silver metal. Wherein the second virus-inhibiting active substance is selected from the following one or any combination of surface protein destroying organic compounds, producing hydroxyl metal compounds, organic-inorganic composite salts, highly active metal compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper Metal, silver metal, metal silicate.

在另一實施例中，中層可以包含兩層氣流形成纖維不織布，至少其中一層包含靜電，兩者包含抑制病毒活性物。換言之，一種口罩，包含第一層，具有第一抑制病毒活性物之紡黏不織布；第二層，具有第二抑制病毒活性物之氣流形成纖維，配置於該第一層之側，第三層，具有第三抑制病毒活性物之氣流形成纖維，配置於該第二層之側；以及第四層，為親膚層，配置於該第三層之側，其中至少該第二層及該第三層之一包含靜電，其中該第二層及該第三層包含疏水性材質。 In another embodiment, the middle layer may comprise two layers of air-flow-forming fibrous nonwovens, at least one of which comprises static electricity, and both of which comprise virus-inhibiting actives. In other words, a mask comprising a first layer, a spunbond nonwoven fabric with a first virus-inhibiting active substance; a second layer, an airflow-forming fiber with a second virus-inhibiting active substance, arranged on the side of the first layer, and a third layer , the airflow-forming fibers with the third virus-inhibiting active substance are arranged on the side of the second layer; and the fourth layer, which is a skin-friendly layer, is arranged on the side of the third layer, wherein at least the second layer and the first layer are arranged on the side of the second layer. One of the three layers includes static electricity, wherein the second layer and the third layer include hydrophobic material.

一種抑制病毒口罩，包含：第一層，具有第一抑制病毒活性物之紡黏不織布；第二層，具有撥水層，配置於該第一層之側；第三層，具有第三抑制病毒活性物之氣流形成纖維，配置於該第二層之側，其中該第三層包含靜電；以及第四層，配置於該第三層之側。 A virus-inhibiting mask, comprising: a first layer, a spunbond nonwoven fabric with a first virus-inhibiting active substance; a second layer, a water-repellent layer, disposed on the side of the first layer; and a third layer, a third virus-inhibiting layer The airflow of the active material forms fibers, which are arranged on the side of the second layer, wherein the third layer contains static electricity; and the fourth layer is arranged on the side of the third layer.

此結構包含透過外層攔截飛沫，並採用第一層上之第一抑制病毒活性物抑制其上之病毒活性，外層功能在於避免身體間處感染；殘餘透過的飛沫則透過包含第二層(或/及第三層；段視需求採用一層或兩層中層)以物理性攔截、靜電吸附，再採用第二(或/及第三)抑制病毒活性物，功能在於以三合一功能抑制病毒活性。本發明是先將聚丙烯(或聚氟乙烯)的膠粒熔化，之後用空氣將液化的聚丙烯(或聚氟乙烯)，以高速氣流噴成超細的纖維，為紡黏纖維細緻約數十倍至百倍。而粘紡不織布就是熔化壓成布狀，纖維較粗但分佈較平均亦較為堅固，因此可保護易破的過濾層。 This structure includes intercepting droplets through the outer layer, and using the first antiviral active agent on the first layer to inhibit the virus activity on the first layer. The function of the outer layer is to avoid infection between the body; the remaining droplets penetrated through the second layer (or// and the third layer; one or two middle layers are used depending on the needs) to physically intercept and electrostatically adsorb, and then use the second (or/and third) to inhibit virus activity, the function is to inhibit virus activity with a three-in-one function. In the present invention, the colloidal particles of polypropylene (or polyvinyl fluoride) are first melted, and then the liquefied polypropylene (or polyvinyl fluoride) is sprayed into ultra-fine fibers with high-speed air flow with air, which is a finer fraction of the spunbond fibers. Ten to one hundred times. The bonded spun non-woven fabric is melted and pressed into a cloth shape. The fibers are thicker but more evenly distributed and stronger, so it can protect the fragile filter layer.

102:轉軸 102: Spindle

102A:溶液 102A: Solution

104:浸染槽 104: Dyeing tank

106:轉軸至轉軸式裝置 106: Spindle to Spindle Device

108:加熱器 108: Heater

110:基材 110: Substrate

200:外層 200: outer layer

220:中間層 220: middle layer

240:裏層 240: inner layer

400:備置高分子材料以及抗病毒材料 400: Prepare polymer materials and antiviral materials

410:將兩者混合加熱熔融 410: mix the two and heat and melt

420:利用高速氣流噴出纖維製作不織布 420: Using high-speed airflow to eject fibers to make non-woven fabrics

430:對不織布進行靜電駐極處理 430: Electrostatic electret treatment of non-woven fabrics

第一圖為本發明之裝置。 The first figure is the device of the present invention.

第二圖為本發明之製作。 The second figure is the production of the present invention.

第三圖為本發明之口罩。 The third picture is the mask of the present invention.

第四圖與第五圖為通過抗病毒檢測圖。 Figure 4 and Figure 5 are pictures of passing anti-virus detection.

第六圖為本發明製作流程 The sixth figure is the production process of the present invention

一般而言，口罩包含至少三層，包含裡層、中層為過濾層，以及外層。本發明口罩包含利用以下製程製作外層之基材，使其具備紫外線防護或抗病毒功效。 Generally speaking, a mask contains at least three layers, including an inner layer, a middle layer as a filter layer, and an outer layer. The mask of the present invention includes a base material for making an outer layer by the following process, so that it has ultraviolet protection or antiviral effects.

一轉軸至轉軸式(roll to roll)裝置106配置，轉軸至轉軸式(roll to roll)裝置106包含至少三個轉軸102，其中至少一轉軸被至於一浸染槽104內，浸染槽104用於承載染料。得藉由驅動裝置，例如馬達等加以驅動轉軸102，使其依據一轉軸旋轉，而牽動軟質基材移動，例示如第一圖中之旋轉箭頭方向旋轉，使得基材110可由一端捲至另一端。於此過程中將帶動基材110移動，並通過浸染槽104內，於其中將防止外線染料或抗病毒成分附著於基材110上。可控制轉軸102之轉速，利於控制移動速率，進而控制材料厚度。加熱裝置108對應配置於水平移動基材110之下側，可以選擇性開啟加熱裝置，提供乾燥所需熱源。加熱裝置108可以為燈泡、熱風、電磁輻射或是紅外線加熱器。 A roll-to-roll device 106 is configured. The roll-to-roll device 106 includes at least three rotating shafts 102, wherein at least one rotating shaft is placed in a dyeing tank 104, which is used for carrying dye. The rotating shaft 102 must be driven by a driving device, such as a motor, to rotate according to a rotating shaft, thereby driving the soft substrate to move, such as the rotation in the direction of the rotation arrow in the first figure, so that the substrate 110 can be rolled from one end to the other. . During this process, the substrate 110 will be driven to move and pass through the dip tank 104 , where the external dyes or antiviral components will be prevented from adhering to the substrate 110 . The rotation speed of the rotating shaft 102 can be controlled, which is beneficial to control the moving speed and thus the thickness of the material. The heating device 108 is correspondingly disposed on the lower side of the horizontally moving substrate 110 , and the heating device can be selectively turned on to provide a heat source required for drying. The heating device 108 may be a light bulb, hot air, electromagnetic radiation or an infrared heater.

隨著製程進展，基材由未浸染之一端移轉至另一端，此時已完成浸染之基材將被捲至另一端而收取。基於基材具有撓曲性，故可以將其捲曲於另一端。若有必要，則可以開啟加熱裝置提供烘乾所需熱能。隨後可將成捲之基材實施後續加工製作成口罩或其他用品，諸如抗病毒頭套、床單、被套、枕頭套、遮簾、擦拭巾等。 As the process progresses, the substrate is transferred from one end to the other end that has not been impregnated, and the substrate that has been impregnated at this time will be rolled to the other end for collection. Since the base material is flexible, it can be curled at the other end. If necessary, the heating device can be turned on to provide the heat energy required for drying. The rolled substrate can then be processed into masks or other products, such as anti-virus head covers, bed sheets, quilt covers, pillow covers, blinds, wipes, and the like.

利用可撓曲式基材，使得材質得透過本發明之轉軸至轉軸式裝置，可以大量製作薄膜，製程不污染環境。且利用驅動轉軸之速度控制薄膜成長厚度，且可附著於不規則或不平表面。 Using a flexible base material, the material can pass through the rotating shaft of the present invention to the rotating shaft device, A large number of thin films can be produced, and the process does not pollute the environment. And the speed of the driving shaft is used to control the growth thickness of the film, and it can be attached to irregular or uneven surfaces.

實施例參照第二圖，此實施例裝置與第一圖類似，不同者為本實施例採用印刷、塗佈、噴灑或噴墨(inkjet print)，將溶液塗佈於所欲之軟質基板上。備置溶液後，則啟動噴墨、噴灑、印刷或塗佈程序，將材質分佈於軟質基材之上，若利用噴墨列印式則可以將染料圖案直接噴塗於軟質基板上，其餘步驟類似上實施例，包含選擇性加熱。 Embodiment Referring to the second figure, the device of this embodiment is similar to the first figure, except that in this embodiment, printing, coating, spraying or inkjet printing is used to coat the solution on the desired flexible substrate. After preparing the solution, start the process of inkjet, spray, printing or coating to distribute the material on the soft substrate. If the inkjet printing method is used, the dye pattern can be directly sprayed on the soft substrate. The rest of the steps are similar to the above. Examples include selective heating.

抗紫外線口罩可以在其表布上噴塗、浸染或塗佈抗紫外線吸收材質或光致變染料，而達到抗紫外線功能。若噴塗有防紫外線可觀察其變化，而得知防護功能，傳統上口罩並無防護紫外線功能，更遑論觀察其防護效果，實際上，傳統口罩無任何防護功能，因此不利於臉部美容術後保養。美容術後保養，其中最重要一環便是防止紫外線照射，因此本發明對於美容術後保養十分重要，傳統口罩完全無法達到此功效。 Anti-ultraviolet masks can be sprayed, dip-dyed or coated with anti-ultraviolet absorbing materials or photovariable dyes on the surface cloth to achieve anti-ultraviolet function. If it is sprayed with anti-ultraviolet rays, you can observe its changes and know the protective function. Traditionally, masks have no UV protection function, let alone observe their protective effect. In fact, traditional masks do not have any protective function, so it is not conducive to facial cosmetic surgery. maintainance. The most important part of post-beauty maintenance is to prevent ultraviolet radiation, so the present invention is very important for post-beauty maintenance, and traditional masks cannot achieve this effect at all.

本發明將光致變色(Photo-Chromic)染料摻雜於樹脂中，例如水性樹脂，可採用微粉狀、膠囊態、液態，將光致變染料與樹脂混合。例如採用水性樹脂與親水性光致變染料混合，以製作上述之浸染溶液。光致變染料與樹脂混合比例可為1：5-1：20，其中可以利用水稀釋，以調整黏度。光致變染料可吸收陽光或紫外線而改變結構，光致變染料經由陽光或紫外線照射後產生可逆化學變化而導致顏色改變。當不受上述陽光或紫外線照射，可恢復原本顏色。光致變染料並可與光安定劑及UV吸收劑等選擇性一起摻雜輔助吸收紫外線。添加抗氧化劑或/及UV吸收劑於可提升抗光疲乏。 In the present invention, photochromic dyes are doped into resins, such as water-based resins, and the photochromic dyes can be mixed with resins in micropowder, capsule or liquid state. For example, a water-based resin is mixed with a hydrophilic photovariable dye to make the above-mentioned dip dyeing solution. The mixing ratio of photovariable dye and resin can be 1:5-1:20, which can be diluted with water to adjust the viscosity. Photovariable dyes can absorb sunlight or ultraviolet rays to change their structure, and photovariable dyes undergo reversible chemical changes after exposure to sunlight or ultraviolet rays, resulting in color changes. When not exposed to the above-mentioned sunlight or ultraviolet rays, the original color can be restored. Photovariable dyes can be selectively doped with light stabilizers and UV absorbers to assist in absorbing ultraviolet light. Antioxidants or/and UV absorbers can be added to improve resistance to light fatigue.

因此請參看第三圖，其揭示本發明口罩之截面示意圖，其可包含三層或四層以上，本實施例以三層為例子。外層200為一防紫外線層，其實施方式可參看以上各實施方法。中間層則為過濾層220，用以過濾粉塵、細菌等等，裏層240可以為棉布製作，也可以採用親膚性材質，例如冰絲棉材質或TPE等。利用以上之方法，可以在裏層製作香氛基材，其原理為利用香氛、香精、精油、香水原料等添加於裏層基材之製作，如此可以得到香氛裏層，提升效果。外層或是中層則可以添加溶菌或除菌酵素，以消除細菌，其方法可以用噴塗、浸染、塗佈或印刷。傳統只能過濾，無法殺死病毒，故本發明除可過濾外，也可以分解細菌、抑制病毒。此外，外層200或是中層220也可添加抑制流感病毒成分或除菌酵素，以消除細菌、抑制病毒，其方法可以用噴塗、浸染、塗佈或印刷。傳統只能過濾細菌，無法殺死細菌，故本發明除可過濾外，也可以分解細菌、抑制病毒。此外，亦可以利用上述噴塗、浸染、塗佈將抗病毒藥劑附著在外層200或是中層220，以抑制流感病毒或腸病毒等等。上述之制流感病毒成分可以採用陽離子有機化合物，陽離子金屬有機金屬化合物(如有機銅化合物、有機鋅化合物有機錫化合物以及一些其他有機金屬化合物)等。為避免洗滌脫落的話，可以於不織布程序中加入熔融態基材內，隨後再利用不織布程序製作不織布，如此便不易流失。基於口罩乃是一次性使用商品，可以採用上述噴塗、浸染、塗佈或印刷方式製作。本發明上述陽離子有機金屬化合物可以為有機無機複合利用具抗病毒有機配體和具抗病毒無機陽離子形成複合鹽類。 Therefore, please refer to the third figure, which discloses a schematic cross-sectional view of the mask of the present invention, which may include three layers or more than four layers, and three layers are used as an example in this embodiment. The outer layer 200 is an anti-ultraviolet layer, and its implementation can refer to the above implementation methods. The middle layer is a filter layer 220 for filtering dust, bacteria, etc. The inner layer 240 can be made of cotton cloth, or can be made of skin-friendly material, such as ice silk cotton material or TPE. Using the above method, the fragrance base material can be made in the inner layer. The principle is to use fragrance, essence, essential oil, Perfume raw materials, etc. are added to the production of the inner layer substrate, so that the inner layer of the fragrance can be obtained and the effect can be improved. The outer layer or the middle layer can be added with bacteriolytic or sterilizing enzymes to eliminate bacteria. The method can be spraying, dip-dyeing, coating or printing. The traditional method can only filter, but cannot kill viruses, so the present invention can decompose bacteria and inhibit viruses in addition to filtering. In addition, the outer layer 200 or the middle layer 220 can also be added with influenza virus-inhibiting ingredients or sterilizing enzymes to eliminate bacteria and inhibit viruses. The method can be spraying, dipping, coating or printing. Traditionally, only bacteria can be filtered, but bacteria cannot be killed. Therefore, in addition to filtering, the present invention can also decompose bacteria and inhibit viruses. In addition, the above-mentioned spraying, dipping, and coating can also be used to attach the antiviral agent to the outer layer 200 or the middle layer 220 to inhibit influenza virus or enterovirus and the like. The above-mentioned ingredients for preparing influenza virus can be cationic organic compounds, cationic metal-organometallic compounds (such as organic copper compounds, organic zinc compounds, organic tin compounds and some other organic metal compounds) and the like. In order to avoid washing and falling off, it can be added to the molten base material in the non-woven process, and then the non-woven fabric is made by the non-woven process, so that it is not easy to run off. Based on the fact that masks are disposable commodities, they can be made by the above spraying, dip-dyeing, coating or printing methods. The above-mentioned cationic organometallic compounds of the present invention may be organic-inorganic composites using organic ligands with antiviral properties and inorganic cations with antiviral properties to form composite salts.

必須注意的是細菌與病毒完全不同，病毒是由一個核酸分子(DNA或RNA)與蛋白質構成的非細胞形態，為類生物，無法自行表現出生命現象，靠寄生生活的介於生命體及非生命體之間的有機物種，它既不是生物亦不是非生物，是由一個保護性外殼包裏的一段DNA或者RNA，藉由感染的機制，這些簡單的有機體可以利用宿主的細胞系統進行自我複製。細菌一般是單細胞，細胞結構簡單，缺乏細胞核以及膜狀胞器，例如粒線體和葉綠體。基於這些特徵，細菌屬於原核生物。細菌的形狀相當多樣，主要有球狀、桿狀，以及螺旋狀。 It must be noted that bacteria are completely different from viruses. Viruses are non-cellular forms composed of a nucleic acid molecule (DNA or RNA) and proteins. They are biological species and cannot express life phenomena on their own. An organic species between living organisms that is neither living nor non-living, but consists of a piece of DNA or RNA encased in a protective shell, these simple organisms can use the host's cellular system for self-replication through the mechanism of infection . Bacteria are generally unicellular with a simple cell structure, lacking a nucleus and membranous organelles such as mitochondria and chloroplasts. Based on these characteristics, bacteria are classified as prokaryotes. The shape of bacteria is quite diverse, mainly spherical, rod-shaped, and spiral.

過濾層220可以採用超微孔生技濾淨膜(PTFE生技膜)可以過濾0.1-2.5微米以下之微粒，以抑制PM 2.5危害，可防霾、透氣、好呼吸特性。奈米微孔聚四氟乙烯(PTFE)薄膜，奈米微孔膜孔徑小於一般微孔膜，擁有高度疏水疏油性，所以具有極良好的透濕、透氣和防水防油污性。耐超高水壓和超高水汽透汽率的PTFE奈米微孔薄膜是由超高結晶態的聚四氟乙烯材料，在超高壓下擠壓成膜並配合極快的拉伸速度，使薄膜具有奈米微孔超高強度三維結構特徵。孔徑可控制在0.03微米(μm)(30奈米(nm))~15微米(μm)之間，厚度為8 ~50微米(μm)，孔隙率高達80~97%。超微孔生技濾淨膜以高分子薄膜濾材取代傳統不織布濾材層，過濾率高達99.9%以上，可將空氣中病毒、過敏原、細懸浮微粒排除，高透氣且不悶。另外的過濾層可以採用熔噴的高分子材料，例如聚丙烯，在製作過程中，可參閱圖六，首先，備置高分子材料以及抗病毒材料400，將兩者混合加熱熔融410，上述之抗病毒材料可以為本段以上或以下之單一或混合成分。之後利用熔噴機製作熔噴布料420，熔融的高分子藉由押出機擠入高速熱氣流中，以形成超細纖維並吹向收集器堆積成超細纖維網狀結構，其中可以利用單排噴絲孔，熱風由噴絲孔兩側風道高速吹出，對聚合物熔體細流進行拉伸；另一方法利用多排噴絲孔並列排列，噴絲孔與風道呈同心圓。最高溫度：華氏550~580，吐出量：0.2~1.3g/h/min，纖維直徑範圍：0.5-40μm，熔融壓力：300-2000psi。之後對熔噴布進行靜電駐極處理430，因靜電力作用，能提高對粉塵、病毒、細菌捕集率和空氣過濾效率。在10~30kV/cm電場中對纖維進行靜電充電就可以得到駐極體纖維：(1)藉助高壓電場形成的靜電力使卷繞纖維靜電充電；(2)藉助電暈放電作用使纖維靜電充電。靠凡得瓦力(Van der Waals force，指分子間的正負電荷吸引力)，替我們擋到了病毒。因此本發明之過濾層具有三種機制，第一利用超細纖維以物理性阻擋病毒、細菌之機制，其次利用靜電作用，提升捕捉效能，其三利用抗病毒藥劑，抑制捕捉之病毒的活性。外層可攔截飛沫，其上之抑制病毒物可抑制百分之99的病毒活性，若透過之飛沫，可由至少包含一層帶靜電的中層過濾層攔截，使用物理性篩孔配合靜電捕捉，再透過纖維上的抑制病毒物，可抑制百分之99的病毒活性，如此構成三合一效能，非傳統可以比擬。在一實施例中，植入永久靜電荷而不導電的纖維，可因不織布因靜電力作用，大大提高對粉塵捕集率。在10~30kV/cm電場中對纖維進行靜電充電就可得到駐極纖維：藉助高壓電場形成的靜電力使卷繞纖維靜電充電、藉助電暈放電作用使纖維靜電充電、借助摩擦起電法或熱極化法。 The filter layer 220 can use an ultra-microporous biotechnology filter membrane (PTFE biotechnology membrane), which can filter particles below 0.1-2.5 microns to inhibit the damage of PM 2.5, and can prevent haze, breathable, and good breathing characteristics. Nanoporous polytetrafluoroethylene (PTFE) film, the pore size of nanoporous membrane is smaller than that of ordinary microporous membrane, and it has high hydrophobicity and oleophobicity, so it has excellent moisture permeability, air permeability, waterproof and oil resistance. The PTFE nano-microporous film with resistance to ultra-high water pressure and ultra-high water vapor permeability is made of ultra-high crystalline polytetrafluoroethylene material. The film has the characteristics of nano-microporous ultra-high-strength three-dimensional structure. The pore size can be controlled between 0.03 micrometers (μm) (30 nanometers (nm)) to 15 micrometers (μm), the thickness is 8 to 50 micrometers (μm), and the porosity is as high as 80 to 97%. The ultra-microporous biofiltration membrane replaces the traditional non-woven filter material layer with a polymer membrane filter material, and the filtration rate is as high as 99.9% or more, which can exclude viruses, allergens, and fine suspended particles in the air. It is highly breathable and not stuffy. The other filter layer can be made of melt-blown polymer material, such as polypropylene. During the production process, please refer to Figure 6. First, prepare the polymer material and the anti-virus material 400, and mix the two to heat and melt 410. The viral material may be a single or mixed component of the above or below paragraphs. Then, the melt-blown fabric 420 is made by a melt-blown machine, and the melted polymer is extruded into a high-speed hot air flow by an extruder to form ultra-fine fibers and blown to the collector to form a network of ultra-fine fibers, in which a single row can be used. In the spinneret hole, the hot air is blown out at high speed from the air ducts on both sides of the spinneret hole to stretch the thin stream of the polymer melt; the other method uses multiple rows of spinneret holes arranged side by side, and the spinneret holes and the air duct are concentric. Maximum temperature: Fahrenheit 550~580, discharge volume: 0.2~1.3g/h/min, fiber diameter range: 0.5-40 μm , melt pressure: 300-2000psi. Afterwards, electrostatic electret treatment 430 is performed on the melt-blown cloth. Due to the action of electrostatic force, the collection rate of dust, viruses and bacteria and the air filtration efficiency can be improved. Electret fibers can be obtained by electrostatically charging the fibers in an electric field of 10~30kV/cm: (1) electrostatically charge the wound fibers by the electrostatic force formed by the high-voltage electric field; (2) electrostatically charge the fibers by the action of corona discharge . Relying on Van der Waals force (the attraction between positive and negative charges between molecules), the virus was blocked for us. Therefore, the filter layer of the present invention has three mechanisms: firstly, the microfiber is used to physically block viruses and bacteria; secondly, the electrostatic effect is used to improve the capture efficiency; thirdly, the antiviral agent is used to inhibit the activity of the captured virus. The outer layer can intercept droplets, and the virus-inhibiting substances on it can inhibit 99% of the virus activity. If the droplets pass through, they can be intercepted by at least one layer of electrostatically charged middle filter layer, using physical meshes with electrostatic capture, and then through the fiber The anti-viral substances above can inhibit 99% of the virus activity, which constitutes a three-in-one effect, which can be compared with non-traditional methods. In one embodiment, implanting fibers with permanent electrostatic charge and non-conductivity can greatly improve the dust collection rate due to the electrostatic force of the non-woven fabric. Electret fibers can be obtained by electrostatically charging the fibers in an electric field of 10~30kV/cm: electrostatically charging the wound fibers by the electrostatic force formed by the high-voltage electric field, electrostatically charging the fibers by the action of corona discharge, or by the triboelectric method or Thermal polarization.

就本發明製作方法中，首先備置降低病毒活性溶液，例如(1)準備抑制病毒表面蛋白質有機化合物，藉由化學吸附性改變病毒的表面蛋白質，抑制病毒複製；或(2)準備金屬化合物，利用自由基反應產生羥基自由基，提取病毒蛋白質中的氫原子，破壞病毒型態，抑制病毒複製；或(3)利用有機金屬化合物，其包含金屬(包括類金屬)和碳原子鍵結的有機金屬化合物，除傳統金屬元素外，鑭系元素、錒系元素、半金屬、類金屬(如硼、矽、砷、硒)也可以和碳鍵結，形成有機金屬化合物。利用上述物質，可以使病毒表面蛋白質破壞，或破壞核酸，或破壞套膜，而降低病毒活性。舉一例而言，A型流感病毒抑制劑的甲醯胺和異腈類化合物，其包含R基，選自烷基、環烷基、芳香基、雜芳基、氨基酸基及上述基團的取代衍生物。甲醯胺和異腈類化合物是以胺為原料分別通過醯化、脫水等方式製備得到，這些甲醯胺和異腈類化合物及其鹽可用於製備抑制病毒物。另一優選例子是一種基於肽或蛋白質類型化合物，包括一種或多種蛋白質、多肽或者肽、核酸、肽核酸、核酸類似物、核苷、核苷類似物、小的有機分子、聚合物、脂質、留體、脂肪酸、碳水化合物或者以上任意的組合。上述基於肽或蛋白質類型化合物，其為該化合物的主要具有氨基酸構架，其中氨基酸是通過肽鍵連結。一種基於肽或者蛋白質的化合物也可具有附著至該氨基酸構架或骨架的其它化學化合物或基團，包括有助於錨定域的錨定活性的部分。細胞外錨定域或錨定域是指任何能穩定地結合位於或在靶細胞外表面上或者鄰近靶細胞外表面的實體。其次，在另一實施例中，抑制內切酶的高活性金屬化合物團，具有高親和力和結合能力的流感核酸內切酶抑制劑。又如一價銅化合物遇到細菌及病毒時，一價銅離子與氧氣反應後，產生羥基，銅離子和羥基這兩種物質可減少病毒及細菌的數量水分中分離出一價銅離子，一價銅化合物分離出的一價銅離子與二價銅離子相比，具有更易被氧化的特性，因此可產生羥基。羥基具有抑制微生物繁殖的功效，可發揮抗病毒效果。 In the production method of the present invention, a solution for reducing virus activity is first prepared, for example (1) preparing an organic compound that inhibits the surface protein of the virus, changing the surface protein of the virus by chemical adsorption, and inhibiting the replication of the virus; or (2) preparing a metal compound, using The free radical reaction generates hydroxyl radicals, which extract hydrogen atoms from viral proteins, destroy the virus type, and inhibit virus replication; or (3) use organometallic compounds, which contain metals (including metalloids) and carbon atom-bonded organometallics Compounds, in addition to traditional metal elements, Lanthanides, actinides, semimetals, and metalloids (eg, boron, silicon, arsenic, selenium) can also bond with carbon to form organometallic compounds. Using the above substances, the virus surface protein can be destroyed, or the nucleic acid can be destroyed, or the mantle can be destroyed, thereby reducing the virus activity. For example, the formamide and isonitrile compounds of influenza A virus inhibitor, which comprise R group, selected from alkyl, cycloalkyl, aryl, heteroaryl, amino acid group and the substitution of the above groups derivative. Formamide and isonitrile compounds are prepared from amine as raw materials by hydration, dehydration, etc. respectively. These formamide and isonitrile compounds and their salts can be used to prepare virus-inhibiting substances. Another preferred example is a peptide or protein-based compound comprising one or more proteins, polypeptides or peptides, nucleic acids, peptide nucleic acids, nucleic acid analogs, nucleosides, nucleoside analogs, small organic molecules, polymers, lipids, Steroids, fatty acids, carbohydrates or any combination of the above. The above-mentioned compounds are based on peptide or protein type, which mainly have amino acid framework, wherein the amino acids are linked by peptide bonds. A peptide or protein-based compound may also have other chemical compounds or groups attached to the amino acid framework or backbone, including moieties that contribute to the anchoring activity of the anchoring domain. An extracellular anchoring domain or anchoring domain refers to any entity capable of stably binding on or on or adjacent to the outer surface of a target cell. Secondly, in another embodiment, a highly reactive metal compound group that inhibits endonuclease, an influenza endonuclease inhibitor with high affinity and binding ability. Another example is that when the monovalent copper compound encounters bacteria and viruses, the monovalent copper ion reacts with oxygen to produce hydroxyl, and the two substances of copper ion and hydroxyl can reduce the number of viruses and bacteria. The monovalent cupric ion separated from the copper compound has the characteristic of being more easily oxidized than the divalent cupric ion, so it can generate hydroxyl groups. Hydroxyl has the effect of inhibiting the reproduction of microorganisms and can exert an antiviral effect.

本發明之陽離子金屬有機化合物係為金屬陽離子與有機材料二者的化合物，亦即二者係經過化合作用或程序而產生陽離子金屬有機化合物，其屬於有機無機化合抑制病毒劑(材料)。例如，合成酰基吡唑啉酮與Ni ⁺、Cu ²⁺、Co ²⁺或Zn ²⁺的化合物，對大腸桿菌和金黃色葡萄球菌都有一定的抑制作用，化合物的抑菌活性比金屬離子高，說明化合物形成後，過渡金屬離子對配體的抑菌活性起到了增強的效應。又如，合成四縮氨基硫脲和2個縮氨基硫脲與Ni ⁺、Cu ²⁺或Zn ²⁺穩定的螯合物，其抑菌能力遠比配體和單獨之金屬離子都好。因此，本發明之有機無機化合物兼有個別單獨有機、無機抑制病毒的優點，具有有機抗菌劑的高效性、持續性及無機抗菌劑的安全性、耐熱性，所得產品不僅抗菌效果好，不受紫外線的干擾。有機金屬化合物中，金屬和碳的鍵結性質一般會介於離子鍵和共價鍵之間。當金屬的電負度很低(例如鹼金屬元素)或是含碳的配基為穩定的碳負離子時，其鍵結會類似離子鍵。碳負離子可以因為共振或者是因為有吸電子取代基(例如三苯甲基負離子)而穩定。在另一實施例中，本發明外層、中層或內層包含一種鹼金屬或鹼土金屬的結晶型矽鋁酸鹽，它的結構具有很強陽離子交換能力；金屬-矽酸鹽類例如銀或銀和鋅-矽酸鹽類，與生物具有良好親和性。優點尚包含：高安全性、耐久性、有廣譜抗菌性(改變金屬離子的種類，可殺不同菌種)、不易產生抗藥性。填充形式將上述成分與合成纖維混合製作成纖維。由於被混入纖維內部，因而耐洗滌性好，效果時間長。後加工形式在纖維後加工過程中，將上述成分通過化合鍵或氫鍵結合在纖維表面，與病毒接觸面積較大(相同劑量下)。其可於不同需求而採用不同製程。 The cationic metal-organic compound of the present invention is a compound of both metal cations and organic materials, that is, both are produced by chemical action or procedures to produce cationic metal-organic compounds, which belong to organic-inorganic compound virus-inhibiting agents (materials). For example, the synthesis of compounds of acylpyrazolones and Ni ⁺ , Cu ²⁺ , Co ²⁺ or Zn ²⁺ has a certain inhibitory effect on Escherichia coli and Staphylococcus aureus, and the antibacterial activity of the compounds is higher than that of metal ions , indicating that after the compound is formed, the transition metal ion has an enhanced effect on the antibacterial activity of the ligand. For another example, the synthesis of tetrathiosemicarbazone and two thiosemicarbazides stabilized with Ni ⁺ , Cu ²⁺ or Zn ²⁺ chelates have far better bacteriostatic ability than ligands and individual metal ions. Therefore, the organic-inorganic compound of the present invention has both the advantages of individual organic and inorganic inhibition of viruses, and has the high efficiency and sustainability of organic antibacterial agents and the safety and heat resistance of inorganic antibacterial agents. UV interference. In organometallic compounds, the bonding properties of metal and carbon generally fall between ionic and covalent bonds. When the electronegativity of the metal is very low (such as an alkali metal element) or the carbon-containing ligand is a stable carbanion, the bond will resemble an ionic bond. Carbanions can be stabilized by resonance or by electron withdrawing substituents such as trityl anions. In another embodiment, the outer, middle or inner layer of the present invention comprises an alkali metal or alkaline earth metal crystalline aluminosilicate whose structure has a strong cation exchange capacity; metal-silicates such as silver or silver And zinc-silicates, with good affinity with organisms. The advantages still include: high safety, durability, broad-spectrum antibacterial properties (change the type of metal ions, and can kill different bacterial species), and it is not easy to produce drug resistance. Filled form fibers are made by mixing the above ingredients with synthetic fibers. Because it is mixed into the fiber, it has good washing resistance and long effect time. Post-processing form In the post-processing process of the fiber, the above-mentioned components are combined on the surface of the fiber through chemical bonds or hydrogen bonds, and the contact area with the virus is larger (under the same dose). It can use different processes for different needs.

第四圖與第五圖為本發明口罩外層透過SGS檢測，通過ISO 18184標準，證明本發明抗病毒效果良好。請參考第四圖，其中載明抗病毒活性良好的標準值為3，而本發明之抗H3N2病毒活性為3.4，遠高於標準值。請參考第五圖，其中載明抗病毒活性良好的標準值為3，而本發明之抗H1N1病毒活性為3.4以上，遠高於標準值。本發明不僅抑制病菌，且可以消滅病毒，因此，產生質的變化，而有新的功效。由第四圖與第五圖證明本發明抗病毒效果良好(抗H3N2病毒活性為3.4，抗H1N1病毒活性為3.4以上，遠高於標準值)，因此，本案具有量的變化，而有功效顯著的提升，具有不可預期的效果。 Figure 4 and Figure 5 show that the outer layer of the mask of the present invention is detected by SGS, which has passed the ISO 18184 standard, which proves that the anti-virus effect of the present invention is good. Please refer to the fourth figure, which states that the standard value of good antiviral activity is 3, while the anti-H3N2 virus activity of the present invention is 3.4, which is much higher than the standard value. Please refer to the fifth figure, which states that the standard value of good antiviral activity is 3, while the anti-H1N1 virus activity of the present invention is above 3.4, which is much higher than the standard value. The present invention not only inhibits germs, but also can eliminate viruses, therefore, it produces qualitative changes and has new effects. The fourth and fifth figures prove that the present invention has a good antiviral effect (the anti-H3N2 virus activity is 3.4, and the anti-H1N1 virus activity is more than 3.4, which is much higher than the standard value). Therefore, this case has a quantitative change, and has a significant effect. The improvement has unpredictable effects.

對熟悉此領域技藝者，本創作雖以較佳實例闡明如上，然其並非用以限定本創作精神。在不脫離本創作之精神與範圍內所作之修改與類似的配置，均應包含在下述之申請專利範圍內，此範圍應覆蓋所有類似修改與類似結構，且應做最寬廣的詮釋。 For those skilled in the art, although the present creation is illustrated above with preferred examples, it is not intended to limit the spirit of the present creation. Modifications and similar configurations made without departing from the spirit and scope of this creation should be included in the following patent application scope, which should cover all similar modifications and similar structures, and should be interpreted in the broadest possible way.

410:將兩者混合加熱熔融 410: mix the two and heat and melt

Claims

一種抑制病毒口罩，包含： A virus-suppressing mask comprising:

一裏層； one mile;

一中層，配置於該裏層之上，包含過濾層；及 a middle layer disposed above the inner layer, including the filter layer; and

一外層，配置於該過濾層之上，其中該過濾層包含靜電以及抑制病毒活性物，該抑制病毒活性物選自以下之一或任意組合：表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽類。 An outer layer, disposed on the filter layer, wherein the filter layer contains static electricity and virus-inhibiting active substances, and the virus-inhibiting active substances are selected from one or any combination of the following: surface proteins destroy organic compounds, produce hydroxyl metal compounds, organic-inorganic compounds Complex salts, highly active metal compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metals, silver metals, metal silicates.

如申請專利範圍第1項所述之抑制病毒口罩，其中該過濾層包含聚丙烯或聚四氟乙烯。 The virus-inhibiting mask as described in item 1 of the claimed scope, wherein the filter layer comprises polypropylene or polytetrafluoroethylene.

如申請專利範圍第1項所述之抑制病毒口罩，其中該外層包含抑制病毒活性物，選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽類。 The virus-inhibiting mask described in item 1 of the scope of the patent application, wherein the outer layer comprises virus-inhibiting active substances selected from one or any combination of the following surface protein-destroying organic compounds, hydroxy metal compounds, organic-inorganic composite salts, highly active Metal compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metals, silver metals, metal silicates.

一種抑制病毒口罩，包含： A virus-suppressing mask comprising:

一裏層； one mile;

一中層，配置於該裏層之上，包含過濾層，其中該過濾層包含靜電及第一抑制病毒活性物；及 a middle layer, disposed on the inner layer, including a filter layer, wherein the filter layer includes static electricity and a first anti-virus active; and

外層，配置於該中層之上，包含第二抑制病毒活性物，其中該第二抑制病毒活性物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽類。 The outer layer, disposed on the middle layer, contains a second virus-inhibiting active substance, wherein the second virus-inhibiting active substance is selected from the following one or any combination of surface protein destroying organic compounds, producing hydroxy metal compounds, organic-inorganic composite salts, Highly active metal compounds, organic copper compounds, organic zinc compounds Organic tin compounds, copper metals, silver metals, metal silicates.

如申請專利範圍第4項所述之抑制病毒口罩，其中該第一抑制病毒活性物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽類。 The virus-inhibiting mask described in item 4 of the patent application scope, wherein the first virus-inhibiting active substance is selected from the following one or any combination of surface protein-destroying organic compounds, hydroxy metal compounds, organic-inorganic composite salts, highly active metals Compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metals, silver metals, metal silicates.

如申請專利範圍第4項所述之抑制病毒口罩，一撥水層，配置於該中層和該外層之間。 For the virus-inhibiting mask described in item 4 of the scope of the patent application, a water-repellent layer is disposed between the middle layer and the outer layer.

一種抑制病毒口罩，包含： A virus-suppressing mask comprising:

第一層，具有第一抑制病毒活性物之紡黏不織布； The first layer, the spunbond non-woven fabric with the first virus-inhibiting active substance;

第二層，具有撥水層，配置於該第一層之側； The second layer, which has a water repellent layer, is disposed on the side of the first layer;

第三層，具有第三抑制病毒活性物之氣流形成纖維，配置於該第二層之側，其中該第三層包含靜電；以及 The third layer, the airflow-forming fibers with the third virus-inhibiting active substance, are arranged on the side of the second layer, wherein the third layer comprises static electricity; and

第四層，配置於該第三層之側。 The fourth layer is disposed on the side of the third layer.

一種製造口罩抑制病毒活性層之方法，包含： A method for manufacturing a virus-inhibiting active layer of a mask, comprising:

備置抑制病毒活性物及備置高分子； Prepare virus-inhibiting active substances and prepare macromolecules;

混和該抑制病毒活性物及該高分子； mixing the virus-inhibiting active substance and the polymer;

使上述混和之該抑制病毒活性物及該高分子形成熔融混合物，熔融溫度大於160度； The virus-inhibiting active substance and the macromolecule are mixed to form a molten mixture, and the melting temperature is greater than 160 degrees;

將熔融混合物擠入高速熱氣流形成纖維，並堆積成網狀結構製作不織布；將該不織布植入靜電。 The molten mixture is extruded into a high-speed hot air flow to form fibers, and stacked into a network structure to make non-woven fabrics; The non-woven fabric is electrostatically implanted.

如申請專利範圍第8項所述之製造口罩抑制病毒活性層之方法，其中該抑制病活性毒物選自以下之一或任意組合表面蛋白破壞有機化合物、產生羥基金屬化合物、有機無機複合鹽類、高活性金屬化合物、有機銅化合物、有機鋅化合物有機錫化合物、銅金屬、銀金屬、金屬矽酸鹽類。 The method for manufacturing a virus-inhibiting active layer of a mask as described in item 8 of the scope of the patent application, wherein the virus-inhibiting active poison is selected from the following one or any combination of surface protein-destroying organic compounds, production of hydroxy metal compounds, organic-inorganic composite salts, Highly active metal compounds, organic copper compounds, organic zinc compounds, organic tin compounds, copper metals, silver metals, metal silicates.

如申請專利範圍第8項所述之製造口罩抑制病毒活性層之方法，其中該高分子包含聚四氟乙烯、聚丙烯或或四氟乙烯-全氟丙烯共聚物。 The method for manufacturing a virus-inhibiting active layer of a mask as described in item 8 of the patent application scope, wherein the polymer comprises polytetrafluoroethylene, polypropylene or tetrafluoroethylene-perfluoropropylene copolymer.

如申請專利範圍第7項所述之製造口罩抑制病毒活性層之方法，其中該高分子為疏水性。 The method for manufacturing a virus-inhibiting active layer of a mask as described in item 7 of the patent application scope, wherein the polymer is hydrophobic.