TW201736540A - Adhesive sheet for conductive member, conductive member laminate, and image display device - Google Patents

Adhesive sheet for conductive member, conductive member laminate, and image display device Download PDF

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TW201736540A
TW201736540A TW105143084A TW105143084A TW201736540A TW 201736540 A TW201736540 A TW 201736540A TW 105143084 A TW105143084 A TW 105143084A TW 105143084 A TW105143084 A TW 105143084A TW 201736540 A TW201736540 A TW 201736540A
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adhesive sheet
meth
conductive member
acrylate
adhesive
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TW105143084A
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Chinese (zh)
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TWI752000B (en
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Ryota Yamamoto
Kahoru Niimi
Hidejiro Yoshikawa
Makoto Inenaga
Takahisa Uchida
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Mitsubishi Chem Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/10—Adhesives in the form of films or foils without carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mathematical Physics (AREA)
  • Optics & Photonics (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Liquid Crystal (AREA)
  • Non-Insulated Conductors (AREA)

Abstract

Provided are: an adhesive sheet for conductive members, which will not corrode a conductive member such as, for example, a transparent conductive layer, and which has forming resistance reliability and fine curing properties; a conductive member laminate; and an image display device. Particularly , the present invention provides an adhesive sheet for conductive members, which is preferable for bonding a conductive member such as a transparent conductive layer in an image display device using an image display panel such as a plasma display (PDP), a liquid crystal display (LCD), an organic EL display (OLED), or the like. The adhesive sheet for conductive members has an adhesive agent layer comprising an adhesive agent composition containing a (meth)acryl-based copolymer and 1,2,3-triazole.

Description

導電構件用黏著片材、導電構件積層體及圖像顯示裝置Adhesive sheet for conductive member, conductive member laminate, and image display device

本發明係關於一種導電構件用黏著片材及使用該黏著片材之導電構件積層體等。本發明尤其關於一種適合於電漿顯示器(PDP)、液晶顯示器(LCD)、有機EL(Electroluminescence，電致發光)顯示器(OLED)、無機EL顯示器、電泳顯示器(EPD)、干擾調變顯示器(IMOD)等使用圖像顯示面板之圖像顯示裝置中貼合透明導電層等導電構件之導電構件用黏著片材等。The present invention relates to an adhesive sheet for a conductive member, a conductive member laminate using the adhesive sheet, and the like. The invention relates in particular to a plasma display (PDP), a liquid crystal display (LCD), an organic EL (Electroluminescence) display (OLED), an inorganic EL display, an electrophoretic display (EPD), an interference modulation display (IMOD). An adhesive sheet for a conductive member in which a conductive member such as a transparent conductive layer is bonded to an image display device using an image display panel.

於個人電腦、行動設備終端(PDA)、遊戲機、電視(TV)、汽車導航系統、觸控面板、手寫板等的圖像顯示裝置、例如電漿顯示器(PDP)、液晶顯示器(LCD)、有機EL顯示器(OLED)、無機EL顯示器、電泳顯示器(EPD)、干擾調變顯示器(IMOD)等平面型或使用具有曲面之圖像顯示面板之圖像顯示裝置中，為了確保視認性或防止破損等，未於各構成構件間設置空隙並利用黏著片材或液狀黏著劑將各構成物材間貼合而一體化。 例如，於具備於液晶模組之視認側與表面保護面板之間***有觸控面板而成之構成之圖像顯示裝置中，於表面保護面板與液晶模組之視認側之間配置黏著片材或液狀黏著劑，將觸控面板與另一構成構件、例如將觸控面板與液晶模組、觸控面板與表面保護面板貼合而一體化。 觸控面板通常具備由摻錫之氧化銦(ITO)、銦-鎵-鋅複合氧化物(IGZO)、摻Ga之氧化鋅(GZO)等金屬氧化物或銀、銅、鉬等金屬材料形成之微細配線或具有由銀奈米線、奈米碳管等形成之透明導電層之上部電極板及下部電極板。又，為了彙集透明導電層所檢測出之手指或觸摸筆等之位置資訊並進行通信，將由金屬材料形成之導體圖案(配線圖案)形成於透明導電層與IC(Integrated Circuit，積體電路)等控制機構之間。該等由各種材料形成之透明導電層或導體圖案通常係以表面與黏著劑相接之方式固定。該透明導電層或導體圖案存在如下顧慮：對腐蝕脆弱，於高溫或濕熱環境下會因黏著材之釋氣或源自溶出成分之酸成分等而腐蝕，視情形會斷線等。 因此，例如於專利文獻1中揭示有含有苯并***及/或其衍生物作為金屬腐蝕防止劑之金屬貼附用黏著片材。 又，例如於專利文獻2中揭示有如下黏著劑組合物：其包含將丙烯酸烷氧基烷基酯及具有可交聯之官能基之丙烯酸系單體作為必需成分而構成之丙烯酸系聚合物及交聯劑，並且丙烯酸系聚合物中實質上不包含含羧基單體。揭示有根據該黏著劑組合物，藉由使用特定量之脂肪族系異氰酸酯交聯劑及含有複數個羥基之胺系化合物而抑制黃變，又，藉由使丙烯酸系聚合物採用交聯結構，即便不包含含羧基單體成分，亦可滿足高溫下之耐發泡、剝落性。 [先前技術文獻] [專利文獻] [專利文獻1]日本專利特開2006-45315號公報 [專利文獻2]日本專利特開2009-079203號公報Image display devices such as a personal computer, a mobile device terminal (PDA), a game machine, a television (TV), a car navigation system, a touch panel, a tablet, etc., such as a plasma display (PDP), a liquid crystal display (LCD), In order to ensure visibility or prevent breakage in an image display device such as an organic EL display (OLED), an inorganic EL display, an electrophoretic display (EPD), an interference modulation display (IMOD), or an image display device having a curved surface display panel For example, voids are not provided between the respective constituent members, and the respective constituent materials are bonded and integrated by an adhesive sheet or a liquid adhesive. For example, in an image display device having a touch panel formed between a viewing side of a liquid crystal module and a surface protection panel, an adhesive sheet is disposed between the surface protection panel and the viewing side of the liquid crystal module. Or a liquid adhesive, the touch panel and the other constituent members, for example, the touch panel and the liquid crystal module, the touch panel and the surface protection panel are integrated and integrated. The touch panel is usually formed of a metal oxide such as tin-doped indium oxide (ITO), indium-gallium-zinc composite oxide (IGZO), Ga-doped zinc oxide (GZO), or a metal material such as silver, copper or molybdenum. The fine wiring or the upper electrode plate and the lower electrode plate of the transparent conductive layer formed of a silver nanowire, a carbon nanotube or the like. In addition, in order to collect and communicate the position information of a finger or a touch pen detected by the transparent conductive layer, a conductor pattern (wiring pattern) formed of a metal material is formed on the transparent conductive layer and an integrated circuit such as an IC (integrated circuit). Between control agencies. The transparent conductive layer or conductor pattern formed of various materials is usually fixed in such a manner that the surface is in contact with the adhesive. The transparent conductive layer or the conductor pattern has the following disadvantages: it is fragile to corrosion, and is corroded by the outgas of the adhesive material or the acid component derived from the eluted component in a high-temperature or moist heat environment, and may be broken as the case may be. For example, Patent Document 1 discloses an adhesive sheet for metal attaching containing benzotriazole and/or a derivative thereof as a metal corrosion preventing agent. Further, for example, Patent Document 2 discloses an adhesive composition comprising an acrylic polymer comprising an alkoxyalkyl acrylate and an acrylic monomer having a crosslinkable functional group as an essential component, and A crosslinking agent, and the acrylic polymer does not substantially contain a carboxyl group-containing monomer. It is disclosed that, according to the adhesive composition, yellowing is inhibited by using a specific amount of an aliphatic isocyanate crosslinking agent and an amine compound containing a plurality of hydroxyl groups, and by using a crosslinked structure of the acrylic polymer, Even if it does not contain a carboxyl group-containing monomer component, it can satisfy foaming and peeling resistance at high temperatures. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Patent Laid-Open Publication No. Hei. No. 2006-45315 (Patent Document 2) Japanese Patent Laid-Open Publication No. 2009-079203

[發明所欲解決之問題] 用於圖像顯示裝置之構成構件包含於高溫或高濕環境下經時產生氣體(亦稱為「釋氣」)之構件，故而於利用黏著片材貼合該等圖像顯示裝置之構成構件之情形時，該黏著片材亦需要具有可充分地對抗釋氣之氣壓之耐發泡可靠性。 上述專利文獻1之含有金屬腐蝕防止劑之兩面黏著片材存在金屬腐蝕防止劑於照射紫外線之耐久性試驗中發泡而使光學特性降低等問題點。 根據上述專利文獻2之黏著劑組合物，即便為不包含丙烯酸等含羧基單體之丙烯酸系聚合物，亦可滿足高溫下之耐發泡、剝落性，但由於無法防止作為腐蝕之因素之水分滲入至黏著劑中，故而就金屬腐蝕防止性之觀點而言，未必滿足。 因此，本發明所欲解決之問題在於提供一種不會腐蝕導電構件且具有耐發泡可靠性及良好之硬化特性之導電構件用黏著片材。更具體而言，提供一種即便與透明導電層之導電層面或由金屬材料形成之導體圖案(配線圖案)直接貼合，亦不會腐蝕該等，又，即便隔著絕緣保護膜(鈍化膜)與透明導電層之導電層面貼合，亦不會腐蝕透明導電層之導電構件用黏著片材。 [解決問題之技術手段] 本發明之主要特徵在於具有包含含有(甲基)丙烯酸系共聚物及1,2,3-***之黏著劑組合物之黏著劑層。 [發明之效果] 本發明之導電構件用黏著片材可具有針對導電構件之耐腐蝕可靠性，並且亦可具有作為黏著片材之耐發泡可靠性及良好之硬化特性。因此，本發明之導電構件用黏著片材可用作適合貼合具有透明導電層及/或由包含銅或者銀之金屬材料形成之導體圖案之導電構件等各種導電構件。尤其可較佳地用作具有觸控面板之圖像顯示裝置用之黏著片材。[Problems to be Solved by the Invention] The constituent members for the image display device include members that generate gas (also referred to as "gassing") over time in a high-temperature or high-humidity environment, and thus are bonded to each other by using an adhesive sheet. In the case of a constituent member of an image display device, the adhesive sheet is also required to have a foaming reliability which is sufficiently resistant to the gas pressure of the outgassing. In the double-sided adhesive sheet containing the metal corrosion preventing agent of the above-mentioned Patent Document 1, there is a problem that the metal corrosion preventing agent is foamed in the durability test against ultraviolet rays to lower the optical characteristics. According to the adhesive composition of the above-mentioned Patent Document 2, even if it is an acrylic polymer which does not contain a carboxyl group-containing monomer such as acrylic acid, it can satisfy the foaming resistance and peeling property at a high temperature, but it cannot prevent moisture as a factor of corrosion. Since it penetrates into an adhesive, it is not necessarily satisfying from the viewpoint of metal corrosion prevention. Therefore, the problem to be solved by the present invention is to provide an adhesive sheet for a conductive member which does not corrode a conductive member and which has foaming reliability and good hardening properties. More specifically, it is provided that even if it is directly bonded to a conductive layer of a transparent conductive layer or a conductor pattern (wiring pattern) formed of a metal material, it does not corrode, and even if an insulating protective film (passivation film) is interposed therebetween Adhesive sheet for conductive members that adheres to the conductive layer of the transparent conductive layer and does not corrode the transparent conductive layer. [Technical means for solving the problem] The main feature of the present invention resides in an adhesive layer comprising an adhesive composition containing a (meth)acrylic copolymer and 1,2,3-triazole. [Effects of the Invention] The adhesive sheet for a conductive member of the present invention can have corrosion resistance reliability with respect to the conductive member, and can also have foaming reliability and good hardening characteristics as an adhesive sheet. Therefore, the adhesive sheet for a conductive member of the present invention can be used as various conductive members suitable for bonding a conductive member having a transparent conductive layer and/or a conductor pattern formed of a metal material containing copper or silver. In particular, it can be preferably used as an adhesive sheet for an image display device having a touch panel.

以下，對本發明之實施形態之一例詳細地進行說明。但是，本發明並不限定於下述實施形態。 ＜導電構件用黏著片材＞ 本發明之實施形態之一例之導電構件用黏著片材(以下，省略後稱為「本黏著片材」)具有包含含有(甲基)丙烯酸系(共)聚合物及1,2,3-***之黏著劑組合物之黏著劑層。 該黏著劑層既可為單層，亦可為多層，又，於為多層之情形時，亦可介存如所謂之基材層之其他層。於黏著劑層為具有其他層之多層構成之情形時，較佳為本黏著片材之表面層為包含上述黏著劑組合物之黏著劑層。 於本黏著片材為多層之情形時，包含上述黏著劑組合物之黏著劑層之厚度並無限定，相對於本黏著片材整體之厚度，較佳為10%以上，更佳為30%以上，進而較佳為50%以上。若包含上述黏著劑組合物之黏著劑層之厚度為上述範圍，則對導電構件之耐腐蝕可靠性、耐發泡可靠性、硬化特性變得良好，故而較佳。 再者，於本發明中，所謂「(共)聚合物」，係包括均聚物及共聚物之意義，所謂「(甲基)丙烯酸酯」係包括丙烯酸酯及甲基丙烯酸酯之意義。 [黏著劑組合物] 本黏著片材所使用之黏著劑組合物(以下，省略後稱為「本組合物」)含有(甲基)丙烯酸系(共)聚合物及1,2,3-***。 本組合物亦可進而含有亞磷酸酯化合物、交聯劑、光聚合起始劑、抗氧化劑、其他成分。 本組合物較佳為光硬化性之組合物。 ((甲基)丙烯酸系(共)聚合物) 作為(甲基)丙烯酸系(共)聚合物，例如除(甲基)丙烯酸烷基酯之均聚物以外，亦可列舉藉由將其與具有共聚性之單體成分進行聚合而獲得之共聚物，更佳為列舉包含自(甲基)丙烯酸烷基酯、可與其共聚合之含羧基單體、含羥基單體、含胺基單體、含環氧基單體、含醯胺基單體及其他乙烯基單體中選擇之一種以上之單體作為結構單元之共聚物。 (甲基)丙烯酸系(共)聚合物可藉由常規方法視需要使用聚合起始劑對以下所例示之單體等進行製造。 於(甲基)丙烯酸系(共)聚合物為包含含羧基單體作為結構單元之共聚物之情形時，就獲得優異之黏著物性之觀點而言，(甲基)丙烯酸系(共)聚合物較佳為含有1.2～15質量%之含羧基單體，其中含有1.5質量%以上或者10質量%以下，其中進而較佳為含有2.0質量%以上或者8質量%以下。 作為更具體之(甲基)丙烯酸系(共)聚合物之一例，可列舉由側鏈之碳數為4～18之直鏈或支鏈(甲基)丙烯酸烷基酯(以下亦稱為「共聚性單體A」)與可與其共聚合之自以下之群中選擇之任一種以上之單體成分構成之共聚物。 ・含羧基單體(以下亦稱為「共聚性單體B」) ・巨單體(以下亦稱為「共聚性單體C」) ・側鏈之碳數為1～3之(甲基)丙烯酸酯(以下亦稱為「共聚性單體D」) ・含羥基單體(以下亦稱為「共聚性單體E」) ・其他乙烯基單體(以下亦稱為「共聚性單體F」) 又，作為(甲基)丙烯酸系(共)聚合物之一例，亦可列舉：(a)由包含共聚性單體A、共聚性單體B及/或共聚性單體C之單體成分構成之共聚物或(b)由包含共聚性單體A、共聚性單體B及/或共聚性單體C、共聚性單體D及/或共聚性單體E之單體成分構成之共聚物作為尤佳之例示。 作為上述側鏈之碳數4～18之直鏈或支鏈(甲基)丙烯酸烷基酯(共聚性單體A)，例如可列舉：(甲基)丙烯酸正丁酯、(甲基)丙烯酸異丁酯、(甲基)丙烯酸第二丁酯、(甲基)丙烯酸第三丁酯、(甲基)丙烯酸戊酯、(甲基)丙烯酸異戊酯、(甲基)丙烯酸新戊酯、(甲基)丙烯酸己酯、(甲基)丙烯酸環己酯、(甲基)丙烯酸庚酯、(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸正辛酯、(甲基)丙烯酸異辛酯、(甲基)丙烯酸壬酯、(甲基)丙烯酸異壬酯、(甲基)丙烯酸第三丁基環己酯、(甲基)丙烯酸癸酯、(甲基)丙烯酸異癸酯、(甲基)丙烯酸十一烷基酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸十三烷基酯、(甲基)丙烯酸十四烷基酯、(甲基)丙烯酸鯨蠟酯、(甲基)丙烯酸硬脂酯、(甲基)丙烯酸異硬脂酯、(甲基)丙烯酸山萮酯、(甲基)丙烯酸異&#158665;基酯、3,5,5-三甲基環己烷(甲基)丙烯酸酯、(甲基)丙烯酸二環戊酯、(甲基)丙烯酸二環戊烯酯、(甲基)丙烯酸二環戊烯氧基乙酯、(甲基)丙烯酸苄酯等。該等可使用1種，或亦可將2種以上組合使用。 上述共聚性單體A於共聚物之總單體成分中，較佳為含有30質量%以上且90質量%以下，其中，進而較佳為於35質量%以上或者88質量%以下之範圍內含有，其中，尤其進而較佳為於40質量%以上或者85質量%以下之範圍內含有。 作為上述含羧基單體(共聚性單體B)，例如可列舉：(甲基)丙烯酸、2-(甲基)丙烯醯氧基乙基六氫鄰苯二甲酸、2-(甲基)丙烯醯氧基丙基六氫鄰苯二甲酸、2-(甲基)丙烯醯氧基乙基鄰苯二甲酸、2-(甲基)丙烯醯氧基丙基鄰苯二甲酸、2-(甲基)丙烯醯氧基乙基順丁烯二酸、2-(甲基)丙烯醯氧基丙基順丁烯二酸、2-(甲基)丙烯醯氧基乙基琥珀酸、2-(甲基)丙烯醯氧基丙基琥珀酸、丁烯酸、反丁烯二酸、順丁烯二酸、伊康酸。該等可使用1種，或亦可將2種以上組合。再者，「(甲基)丙烯酸基」係包括丙烯酸基及甲基丙烯酸基之意義。同樣地，「(甲基)丙烯醯基」係包括丙烯醯基及甲基丙烯醯基之意義。 上述共聚性單體B於共聚物之總單體成分中，較佳為於1.2質量%以上且15質量%以下之範圍內含有，其中，就獲得優異之黏著物性之觀點而言，較佳為於1.5質量%以上或者10質量%以下之範圍內含有，其中，尤佳為於2質量%以上或者8質量%以下之範圍內含有。 上述巨單體(共聚性單體C)係於藉由聚合而成為(甲基)丙烯酸系(共)聚合物時側鏈之碳數成為20以上之單體。藉由使用共聚性單體C，可將(甲基)丙烯酸系(共)聚合物製成接枝共聚物。因此，可根據共聚性單體C與除此以外之單體之選擇或調配比率使接枝共聚物之主鏈與側鏈之特性變化。 作為上述巨單體(共聚性單體C)，較佳為骨架成分係由丙烯酸系聚合物或乙烯系聚合物構成者。作為巨單體之骨架成分，例如可列舉上述共聚性單體A、上述共聚性單體B、下述共聚性單體D、下述共聚性單體E等所例示者，該等可單獨使用，或將2種以上組合使用。 巨單體係具有自由基聚合性基或羥基、異氰酸酯基、環氧基、羧基、胺基、醯胺基、硫醇基等官能基者。作為巨單體，較佳為具有可與其他單體共聚合之自由基聚合性基者。自由基聚合性基可含有一個或者兩個以上，其中，尤佳為一個。於巨單體具有官能基之情形時，官能基亦可含有一個或者兩個以上，其中，尤佳為一個。又，既可含有自由基聚合性基與官能基中之任一者，亦可含有兩者。 共聚性單體C之數量平均分子量較佳為500～2萬，其中，較佳為800以上或者8000以下，其中，較佳為1000以上或者7000以下。 巨單體可適當地使用以一般方式製造而成者(例如東亞合成公司製造之巨單體等)。 上述共聚性單體C於共聚物之總單體成分中，較佳為於5質量%以上且30質量%以下之範圍內含有，其中，較佳為於6質量%以上或者25質量%以下之範圍內含有，其中，尤佳為於8質量%以上或者20質量%以下之範圍內含有。 作為上述側鏈之碳數為1～3之(甲基)丙烯酸酯(共聚性單體D)，可列舉：(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸正丙酯、(甲基)丙烯酸異丙酯等。該等可使用1種，或亦可將2種以上組合。 上述共聚性單體D於共聚物之總單體成分中，較佳為含有0質量%以上且70質量%以下，其中，進而較佳為於3質量%以上或者65質量%以下之範圍內含有，其中，尤其進而較佳為於5質量%以上或者60質量%以下之範圍內含有。 作為上述含羥基單體(共聚性單體E)，可列舉：(甲基)丙烯酸2-羥基乙酯、(甲基)丙烯酸2-羥基丙酯、(甲基)丙烯酸3-羥基丙酯、(甲基)丙烯酸2-羥基丁酯等(甲基)丙烯酸羥基烷基酯類。該等可使用1種，或亦可將2種以上組合。 上述共聚性單體E於共聚物之總單體成分中，較佳為含有0質量%以上且30質量%以下，其中，進而較佳為於0質量%以上或者25質量%以下之範圍內含有，其中，尤其進而較佳為於0質量%以上或者20質量%以下之範圍內含有。 作為上述其他乙烯基單體(共聚性單體F)，除共聚性單體A～E以外，亦可列舉分子內具有乙烯基之化合物。作為此種化合物，可例示：分子內具有醯胺基或烷氧基烷基等官能基之官能性單體類；以及聚伸烷基二醇二(甲基)丙烯酸酯類；以及乙酸乙烯酯、丙酸乙烯酯及月桂酸乙烯酯等乙烯酯單體；以及苯乙烯、氯苯乙烯、氯甲基苯乙烯、α-甲基苯乙烯及其他取代苯乙烯等芳香族乙烯基單體。該等可使用1種，或亦可將2種以上組合。 上述共聚性單體F於共聚物之總單體成分中，較佳為含有0質量%以上且30質量%以下，其中，進而較佳為於0質量%以上或者25質量%以下之範圍內含有，其中，尤其進而較佳為於0質量%以上或者20質量%以下之範圍內含有。 除上述所揭示者以外，亦可視需要適當地使用：順丁烯二酸酐、伊康酸酐等含酸酐基單體；(甲基)丙烯酸縮水甘油酯、α-乙基丙烯酸縮水甘油酯、(甲基)丙烯酸-3,4-環氧基丁酯等含環氧基單體；(甲基)丙烯酸二甲胺基乙酯、(甲基)丙烯酸二乙胺基乙酯等含胺基(甲基)丙烯酸酯系單體；(甲基)丙烯醯胺、N-第三丁基(甲基)丙烯醯胺、N-羥甲基(甲基)丙烯醯胺、N-甲氧基甲基(甲基)丙烯醯胺、N-丁氧基甲基(甲基)丙烯醯胺、雙丙酮(甲基)丙烯醯胺、順丁烯二酸醯胺、順丁烯二醯胺等含有醯胺基或醯亞胺基之單體；乙烯基吡咯啶酮、乙烯基吡啶、乙烯咔唑等雜環系鹼性單體等。 作為(甲基)丙烯酸系(共)聚合物之最典型之例，例如可列舉使(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸辛酯、(甲基)丙烯酸癸酯、(甲基)丙烯酸異硬脂酯、(甲基)丙烯酸丁酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸甲酯等單體成分(a)、具有羧基之(甲基)丙烯酸、2-(甲基)丙烯醯氧基乙基六氫鄰苯二甲酸、2-(甲基)丙烯醯氧基丙基六氫鄰苯二甲酸、2-(甲基)丙烯醯氧基乙基鄰苯二甲酸、2-(甲基)丙烯醯氧基丙基鄰苯二甲酸、2-(甲基)丙烯醯氧基乙基順丁烯二酸、2-(甲基)丙烯醯氧基丙基順丁烯二酸、2-(甲基)丙烯醯氧基乙基琥珀酸、2-(甲基)丙烯醯氧基丙基琥珀酸、丁烯酸、反丁烯二酸、順丁烯二酸、伊康酸等單體成分(b)、及具有有機官能基等之(甲基)丙烯酸羥乙酯、(甲基)丙烯酸羥丙酯、(甲基)丙烯酸羥丁酯、(甲基)丙烯酸甘油酯、順丁烯二酸單甲酯、伊康酸單甲酯、乙酸乙烯酯、(甲基)丙烯酸縮水甘油酯、(甲基)丙烯醯胺、(甲基)丙烯腈、氟化(甲基)丙烯酸酯、聚矽氧(甲基)丙烯酸酯等單體成分(c)共聚合所得之(甲基)丙烯酸酯共聚物。 (甲基)丙烯酸系(共)聚合物之質量平均分子量較佳為10萬以上且150萬以下，其中，較佳為15萬以上或者130萬以下，其中，尤佳為20萬以上或者120萬以下。 於欲獲得凝集力較高之黏著組合物之情形時，就分子量越大，越可藉由分子鏈之交聯而獲得凝集力之觀點而言，(甲基)丙烯酸系(共)聚合物之質量平均分子量較佳為70萬以上且150萬以下，尤佳為80萬以上或者130萬以下。另一方面，於欲獲得流動性或應力緩和性較高之黏著組合物之情形時，質量平均分子量較佳為10萬以上且70萬以下，尤佳為15萬以上或者60萬以下。 另一方面，於使黏著片材等成形時不使用溶劑之情形時，由於不易使用分子量較大之聚合物，故而(甲基)丙烯酸系(共)聚合物之質量平均分子量較佳為10萬以上且70萬以下，尤佳為15萬以上或者60萬以下，其中，尤佳為20萬以上或者50萬以下。 (金屬腐蝕防止劑) 本組合物含有1,2,3-***。 1,2,3-***具有作為對導電構件之導電層之金屬腐蝕防止劑之功能。1,2,3-***由於對銅之耐銅腐蝕可靠性及作為黏著片材之耐發泡可靠性優異，因此含有1,2,3-***之本組合物可較佳地用作具有透明導電層及由包含銅之金屬材料形成之導體圖案(配線圖案)之導電構件。其原因在於推測藉由於由包含銅之金屬材料形成之導體圖案表面形成銅原子與1,2,3-***之分子化學鍵結而成之保護皮膜而防止腐蝕。又，於具有由包含銀之金屬材料形成之導體圖案之導電構件中，亦可同樣地實現利用1,2,3-***所得之保護皮膜之效果。 再者，存在1,2,4-***作為1,2,3-***之異構物。該1,2,4-***係熔點約為120℃之固體，另一方面，1,2,3-***之熔點約為20℃，於室溫下大致為液體狀態。因此，1,2,3-***具有混合於黏著劑組合物中時之分散性優異而可均勻地混合，又，容易母料化等優異之優勢。 於本組合物中，就金屬腐蝕防止劑之滲出或金屬腐蝕防止效果等觀點而言，較佳為以相對於(甲基)丙烯酸系(共)聚合物100質量份為0.01質量份以上且5質量份以下之比率含有1,2,3-***，其中，進一步較佳為以0.1質量份以上或者1質量份以下之比率含有1,2,3-***，其中，進一步較佳為以0.2質量份以上或者0.5質量份以下之比率含有1,2,3-***。 再者，本組合物中亦可將1,2,3-***與1,2,4-***併用。 (亞磷酸酯化合物) 本組合物可進而含有亞磷酸酯化合物。 亞磷酸酯化合物不僅其本身不具有腐蝕性，而且亦可使羧基等酸成分穩定。因此，藉由於包含特定之(甲基)丙烯酸系(共)聚合物之本組合物中調配亞磷酸酯化合物，即便本組合物包含酸成分，亦可防止作為被黏著體之導電構件之氧化劣化，於本組合物不包含酸成分之情形時，當然可防止作為被黏著體之導電構件之氧化劣化。 因此，若由含有亞磷酸酯化合物之本組合物形成黏著片材，則可具有對導電構件(典型而言，具有包含ITO之透明導電層及/或由包含銅或銀之金屬材料形成之導體圖案之導電構件)之耐腐蝕可靠性，並且可防止導電構件之氧化劣化。因此，例如可較佳地用作具有觸控面板之圖像顯示裝置用之黏著片材。 本組合物可含有之亞磷酸酯化合物並無限定。尤其較佳為下述式(1)所示之亞磷酸酯化合物。 式(1)      P[-OR]3 (式中之R為烴，具體而言，可列舉經取代或未經取代芳香族、脂肪環及烷基等；複數個R可彼此相同，亦可不同，相鄰之複數個R可彼此鍵結而形成飽和或不飽和之環結構) 又，亦可為包含2個以上之上述式(1)所表示之結構單元之化合物。 於包含特定之(甲基)丙烯酸系(共)聚合物及1,2,3-***之本組合物中調配上述式(1)所示之各種亞磷酸酯化合物，結果確認到任一亞磷酸酯化合物均顯示出防氧化劣化效果，且確認到尤其是對包含ITO之透明導電層之防氧化劣化效果優異。 作為本組合物所含有之亞磷酸酯化合物，例如可列舉：亞磷酸三苯酯、亞磷酸三(壬基苯基)酯、亞磷酸三甲酚酯、亞磷酸三硬脂酯、亞磷酸三乙酯、亞磷酸三(2-乙基己基)酯、亞磷酸三癸酯、亞磷酸三月桂酯、亞磷酸三(十三烷基)酯、亞磷酸三油酯、亞磷酸二苯酯(2-乙基己基)酯、亞磷酸二苯酯單癸酯、亞磷酸二苯酯單(十三烷基)酯、四苯基二伸丙基二丙二醇二亞磷酸酯、四苯基(四-十三烷基)季戊四醇四亞磷酸酯、四(C12～C15烷基)-4,4-亞異丙基二苯基二亞磷酸酯、亞磷酸三(2,4-二第三丁基苯基)酯、亞磷酸三(4-壬基苯基)酯、3,9-雙(壬基苯氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、3,9-雙(4-壬基苯氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、3,9-雙(癸氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、3,9-雙(十三烷氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、3,9-雙(硬脂氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、3,9-雙(2,6-二第三丁基-4-甲基苯氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、3,9-雙(2,4-二第三丁基苯氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、3,9-雙{2,4-雙(1-甲基-1-苯基乙基)苯氧基}-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、2,2'-亞甲基雙(4,6-二第三丁基-1-苯基)亞磷酸酯、4,4'-亞異丙基二苯酚C12-15醇亞磷酸酯、二硬脂基季戊四醇二亞磷酸酯、2,4,8,10-四(1,1-二甲基乙基)-6-{(2-乙基己基)氧基}-12H-二苯并[d,g][1,3,2]二氧磷雜八環、2,4,8,10-四(1,1-二甲基乙基)-6-(十三烷氧基)-12H-二苯并[d,g][1,3,2]二氧磷雜八環、1,1'-聯苯-4,4'-二基雙[亞磷酸雙(2,4-二第三丁基苯基)酯]、氫化雙酚A-季戊四醇亞磷酸酯聚合物、氫化雙酚A亞磷酸酯聚合物、亞磷酸二乙酯、亞磷酸雙(2-乙基己基)酯、亞磷酸二月桂酯、亞磷酸二油酯、亞磷酸二苯酯等。 其中，作為本組合物所含有之亞磷酸酯化合物，例如若考慮到與本組合物之相溶性，則較佳為脂肪族亞磷酸酯(例如，作為實施例2-2之亞磷酸酯化合物之亞磷酸三癸酯或實施例2-3之3,9-雙(癸氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5.5]十一烷等)。又，若考慮到耐水解性，則較佳為芳香族亞磷酸酯(例如，作為實施例2-1之亞磷酸酯化合物之亞磷酸三(2,4-二第三丁基苯基)酯等)。又，若考慮到溶解性與耐水解性之平衡性，則較佳為亞磷酸二苯酯單(十三烷基)酯等兼具脂肪族酯基與芳香族酯基之亞磷酸酯。 於本組合物中，關於亞磷酸酯化合物之含有比率，就無損黏著性能且可更有效地抑制ITO等之導電構件之氧化劣化之觀點而言，較佳為以相對於(甲基)丙烯酸系(共)聚合物100質量份為0.0001(1×10-4 )質量份以上且2.0質量份以下之比率含有亞磷酸酯化合物，其中，進一步較佳為以0.0005質量份以上或者0.8質量份以下之比率含有亞磷酸酯化合物，其中，進一步較佳為以0.001質量份以上或者0.7質量份以下之比率含有亞磷酸酯化合物，尤其進一步較佳為以0.01質量份以上或者0.6質量份以下之比率含有亞磷酸酯化合物。 (其他金屬腐蝕防止劑) 於本組合物中，除1,2,3-***及亞磷酸酯化合物以外，亦可併用1,2,4-***、苯并***及其衍生物等其他金屬腐蝕防止劑。 (交聯劑) 本組合物亦可視需要包含交聯劑。 例如，作為使上述(甲基)丙烯酸系(共)聚合物進行交聯之方法，可列舉：添加可與導入至(甲基)丙烯酸系(共)聚合物中之羥基或羧基等反應性基化學鍵結之交聯劑，並藉由加熱或熟化使之反應之方法；或添加作為交聯劑之具有2個以上之(甲基)丙烯醯基之多官能(甲基)丙烯酸酯及光聚合起始劑等反應起始劑，並藉由紫外線照射等使之交聯之方法。其中，就不會因反應而消耗本組合物中之羧基等極性官能基而可維持源自極性成分之較高之凝集力或黏著物性之觀點而言，較佳為藉由紫外線等光照射之交聯方法。 作為上述交聯劑，例如可列舉具有選自(甲基)丙烯醯基、環氧基、異氰酸酯基、羧基、羥基、碳二醯亞胺基、㗁唑啉基、氮丙啶基、乙烯基、胺基、亞胺基、醯胺基、N-取代(甲基)丙烯醯胺基、烷氧基矽烷基中之至少1種交聯性官能基之交聯劑，可使用1種，或亦可將2種以上組合使用。再者，交聯性官能基亦可由可脫保護之保護基保護。 其中，就交聯反應之控制之容易性之觀點而言，較佳為多官能(甲基)丙烯酸酯。 作為此種多官能(甲基)丙烯酸酯，例如可列舉：1,4-丁二醇二(甲基)丙烯酸酯、1,6-己二醇二(甲基)丙烯酸酯、1,9-壬二醇二(甲基)丙烯酸酯、聚伸烷基二醇二(甲基)丙烯酸酯、新戊二醇二(甲基)丙烯酸酯、甘油二(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯酸酯、季戊四醇四(甲基)丙烯酸酯、二季戊四醇六(甲基)丙烯酸酯、三季戊四醇五(甲基)丙烯酸酯、三羥甲基丙烷三(甲基)丙烯酸酯、異氰尿酸三(丙烯醯氧基乙基)酯等紫外線硬化型之多官能單體類，以及聚酯(甲基)丙烯酸酯、環氧(甲基)丙烯酸酯、(甲基)丙烯酸胺基甲酸酯、聚醚(甲基)丙烯酸酯等多官能丙烯酸系低聚物類或多官能丙烯醯胺等。 又，作為具有2種以上之交聯性官能基之交聯劑，例如可列舉：(甲基)丙烯酸縮水甘油酯、α-乙基丙烯酸縮水甘油酯、(甲基)丙烯酸-3,4-環氧丁酯、4-羥基丁基(甲基)丙烯酸酯縮水甘油醚等含環氧基單體；(甲基)丙烯酸2-異氰酸酯基乙酯、異氰酸2-(2-(甲基)丙烯醯氧基乙氧基)乙酯、(甲基)丙烯酸2-(0-[1'-甲基亞丙基胺基]羧基胺基)乙酯、(甲基)丙烯酸2-[(3,5-二甲基吡唑基)羰基胺基]乙酯等含異氰酸酯基或封端異氰酸酯基之單體；乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、3-縮水甘油氧基丙基三甲氧基矽烷、3-(甲基)丙烯醯氧基丙基甲基二乙氧基矽烷、3-(甲基)丙烯醯氧基丙基三乙氧基矽烷、N-2-(胺基乙基)-3-胺基丙基甲基二甲氧基矽烷、3-異氰酸酯基丙基三乙氧基矽烷等各種矽烷偶合劑。 具有2種以上之交聯性官能基之交聯劑亦可採用使一官能基與(甲基)丙烯酸系(共)聚合物反應而鍵結於(甲基)丙烯酸系(共)聚合物所成之結構。藉由採用此種結構，可使例如(甲基)丙烯醯基或乙烯基等雙鍵性之交聯性官能基化學鍵結於(甲基)丙烯酸系(共)聚合物。又，藉由使交聯劑鍵結於(甲基)丙烯酸系(共)聚合物，有可抑制交聯劑之滲出或本黏著片材之意外之塑化之傾向。又，藉由使交聯劑鍵結於(甲基)丙烯酸系(共)聚合物而促進光交聯反應之反應效率，因此有可獲得凝集力更高之硬化物之傾向。 本組合物亦可進而含有可與交聯劑之交聯性官能基反應之單官能單體。作為此種單官能單體，例如可列舉：丙烯酸甲酯等(甲基)丙烯酸烷基酯；(甲基)丙烯酸羥乙酯、(甲基)丙烯酸羥丙酯、(甲基)丙烯酸羥丁酯、聚伸烷基二醇(甲基)丙烯酸酯等含羥基(甲基)丙烯酸酯；(甲基)丙烯酸、2-(甲基)丙烯醯氧基乙基六氫鄰苯二甲酸、2-(甲基)丙烯醯氧基丙基六氫鄰苯二甲酸、2-(甲基)丙烯醯氧基乙基鄰苯二甲酸、2-(甲基)丙烯醯氧基乙基順丁烯二酸、2-(甲基)丙烯醯氧基丙基順丁烯二酸、2-(甲基)丙烯醯氧基乙基琥珀酸、2-(甲基)丙烯醯氧基丙基琥珀酸、丁烯酸、反丁烯二酸、順丁烯二酸、伊康酸等含羧基單體；順丁烯二酸酐、伊康酸酐等含酸酐基單體；(甲基)丙烯酸四氫糠酯、甲氧基聚乙二醇(甲基)丙烯酸酯等含醚基(甲基)丙烯酸酯；(甲基)丙烯醯胺、二甲基(甲基)丙烯醯胺、二乙基(甲基)丙烯醯胺、(甲基)丙烯醯基嗎啉、異丙基(甲基)丙烯醯胺、二甲胺基丙基(甲基)丙烯醯胺、苯基(甲基)丙烯醯胺、N-甲氧基甲基(甲基)丙烯醯胺、N-丁氧基甲基(甲基)丙烯醯胺等(甲基)丙烯醯胺系單體等。 其中，就提高對被黏著體之密接性或濕熱白化抑制之效果之觀點而言，較佳為使用含羥基(甲基)丙烯酸酯或(甲基)丙烯醯胺系單體。 關於交聯劑之含量，就使本組合物之柔軟性與凝集力平衡之觀點而言，較佳為以相對於上述(甲基)丙烯酸系(共)聚合物100質量份而為0.01以上且10質量份以下之比率調配，其中，尤佳為0.05質量份以上或者8質量份以下，其中，尤佳為0.1質量份以上或者5質量份以下。 再者，於本黏著片材為多層之情形時，關於構成黏著片材之層中之中間層或成為基材之層，交聯劑之含量亦可超過上述範圍。中間層或成為基材之層中之交聯劑之含量較佳為以相對於上述(甲基)丙烯酸系(共)聚合物100質量份而為0.01以上且40質量份以下之比率調配，其中，尤佳為1質量份以上或者30質量份以下，其中，尤佳為2質量份以上或者25質量份以下。 (光聚合起始劑) 於藉由光照射進行交聯之情形時，較佳為含有光聚合起始劑。 基於光聚合起始劑之自由基產生機構被分為2大類，有將自身之單鍵裂解並分解而產生自由基之α裂解型、及自系統中之化合物中使氫激發而產生自由基之脫氫型。該等之中，較佳為使用脫氫型光交聯起始劑。 其中，於使用具有(甲基)丙烯醯基之有機系交聯劑作為交聯劑之情形時，尤佳為進而添加光聚合起始劑。原因在於藉由光照射產生自由基而成為系統中之聚合反應之起點。 光聚合起始劑可適當使用目前公知者。其中，就交聯反應之控制之容易性之觀點而言，較佳為感應到波長380 nm以下之紫外線之光聚合起始劑。 另一方面，就可獲得較高之光反應性之方面及所感應之光容易到達至本黏著片材之深部之方面而言，較佳為感應到長於波長380 nm之波長之光之光聚合起始劑。 光聚合起始劑根據自由基產生機構而被分成2大類，大致分成可將光聚合起始劑自身之單鍵裂解分解而產生自由基之裂解型光聚合起始劑、及經光激發之起始劑與系統中之氫供與體形成激發錯合物並可使氫供與體之氫轉移之脫氫型光聚合起始劑。 該等中之裂解型光聚合起始劑於藉由光照射產生自由基時會分解而成為另一化合物，一旦被激發，則會失去作為交聯起始劑之功能。因此，不會以活性種之形式殘存於交聯反應結束後之黏著材中，從而不可能使黏著材產生意外之光劣化等，故而較佳。 另一方面，脫氫型光聚合起始劑於藉由紫外線等活性能量線照射產生自由基之反應時，不會產生如裂解型光聚合起始劑之分解物，因此就反應結束後不易成為揮發成分，從而可降低對被黏著體之損傷之方面而言有用。 作為上述裂解型光聚合起始劑，就對光之感應性較高且反應後成為分解物並脫色之方面而言，較佳為雙(2,4,6-三甲基苯甲醯基)-苯基氧化膦、2,4,6-三甲基苯甲醯基二苯基氧化膦、(2,4,6-三甲基苯甲醯基)乙氧基苯基氧化膦、雙(2,6-二甲氧基苯甲醯基)2,4,4-三甲基戊基氧化膦等醯基氧化膦系光聚合起始劑。 作為上述脫氫型光聚合起始劑，例如可列舉：二苯甲酮、4-甲基-二苯甲酮、2,4,6-三甲基二苯甲酮、4-苯基二苯甲酮、3,3'-二甲基-4-甲氧基二苯甲酮、4-(甲基)丙烯醯氧基二苯甲酮、4-[2-((甲基)丙烯醯氧基)乙氧基]二苯甲酮、4-(甲基)丙烯醯氧基-4'-甲氧基二苯甲酮、2-苯甲醯苯甲酸甲酯、苯甲醯甲酸甲酯、二乙二醇雙(2-苯基-2-側氧基乙酸酯)、4-(1,3-丙烯醯基-1,4,7,10,13-五氧雜十三烷基)二苯甲酮、9-氧硫&#134079;□、2-氯-9-氧硫&#134079;□、3-甲基-9-氧硫&#134079;□、2,4-二甲基-9-氧硫&#134079;□蒽醌、2-甲基蒽醌、2-乙基蒽醌、2-第三丁基蒽醌、2-胺基蒽醌、樟腦醌或其衍生物等。 該等之中，較佳為二苯甲酮、4-甲基-二苯甲酮、2,4,6-三甲基二苯甲酮、4-苯基二苯甲酮、3,3'-二甲基-4-甲氧基二苯甲酮、4-(甲基)丙烯醯氧基二苯甲酮、4-[2-((甲基)丙烯醯氧基)乙氧基]二苯甲酮、4-(甲基)丙烯醯氧基-4'-甲氧基二苯甲酮、2-苯甲醯苯甲酸甲基、苯甲醯基甲酸甲基。 再者，上述所列舉之光聚合起始劑既可使用任1種或其衍生物，亦可將該等之2種以上組合使用。 進而，除光聚合起始劑以外，亦可使用增感劑。作為增感劑，並無特別限定，只要為光聚合起始劑所使用之增感劑，則可無問題地使用。例如可列舉：芳香族胺或蒽衍生物、蒽醌衍生物、香豆素衍生物、9-氧硫□衍生物、酞菁衍生物等或二苯甲酮、&#134079;酮、9-氧硫&#134079;□、米其勒酮、9,10-菲醌等芳香族酮及該等之衍生物等。 再者，光聚合起始劑或增感劑亦可以鍵結於(甲基)丙烯酸系(共)聚合物之狀態包含。作為使光聚合起始劑或增感劑鍵結於(甲基)丙烯酸系(共)聚合物之方法，可採用與使上述交聯劑鍵結於(甲基)丙烯酸系(共)聚合物之情形時相同之方法。 光聚合起始劑之含量並無特別限制，典型而言，尤佳為以相對於(甲基)丙烯酸系(共)聚合物100質量份而為0.1以上且10質量份以下之比率調整，其中，尤佳為以0.2質量份以上或者5質量份以下之比率調整，其中，尤佳為以0.5質量份以上或者3質量份以下之比率調整。其中，亦可因與其他要素之平衡性而超出該範圍。 (抗氧化劑) 除上述以外，本組合物亦可視需要含有抗氧化劑。 作為抗氧化劑，例如可列舉：2,2'-亞甲基雙(4-甲基-6-第三丁基苯酚)、己二醇-雙(3,5-二第三丁基-4-羥基氫化肉桂酸酯)、四[亞甲基(3,5-二第三丁基-4-羥基氫化肉桂酸酯)]甲烷、三乙二醇-雙-3-(3-第三丁基-4-羥基-5-甲基苯基)丙酸酯、1,3,5-三甲基-2,4,6-三(3,5-二第三丁基-4-羥基-苄基)苯、3-(4'-羥基-3',5'-二第三丁基苯酚基)丙酸正十八烷基酯、4,4'-亞甲基雙(2,6-二第三丁基苯酚)、4,4'-亞丁基-雙-(6-第三丁基-3-甲基-苯酚)等受阻酚系抗氧化劑或硫系、胺系等各種抗氧化劑。 (其他成分) 進而，本組合物亦可適當含有通常之黏著劑組合物中所調配之公知之成分。例如，可適當含有光穩定劑、紫外線吸收劑、金屬鈍化劑、防銹劑(上述金屬腐蝕防止劑除外)、抗老化劑、抗靜電劑、吸濕劑、發泡劑、消泡劑、無機粒子、黏度調整劑、黏著賦予樹脂、光敏劑、螢光劑等各種添加劑，或反應觸媒(三級胺系化合物、四級銨系化合物、月桂酸錫化合物等)。 (黏著劑組合物之調整) 本黏著片材所使用之黏著劑組合物(本組合物)係藉由將(甲基)丙烯酸系(共)聚合物、1,2,3-***及視需要之其他成分、例如亞磷酸酯化合物、交聯劑等分別以特定量進行混合而獲得。 作為該等之混合方法，並無特別限制，各成分之混合順序亦無特別限定。又，亦可於製造本組合物時添加熱處理步驟，於此情形時，較理想為預先將本組合物之各成分進行混合後進行熱處理。亦可使用將各種混合成分濃縮後母料化而成者。 又，混合時之裝置亦並無特別限制，例如可使用萬能混練機、行星式攪拌機、班布里混合機、捏合機、框式混合機、加壓捏合機、三輥研磨機、雙輥研磨機。亦可視需要使用溶劑進行混合。又，本組合物亦可用作不包含溶劑之無溶劑系。藉由用作無溶劑系，可具備不會殘存溶劑而耐熱性及耐光性增高之優勢。 進而，本組合物亦可以如下方式使用：預先製成包含構成(甲基)丙烯酸系(共)聚合物之單體成分、1,2,3-***、光聚合起始劑及其他任意成分之組合物，於將其用作導電構件用黏著片材時，進行光照射以進行聚合反應而生成(甲基)丙烯酸系(共)聚合物。 ＜導電構件用黏著片材之形態＞ 本黏著片材除可將本組合物直接塗佈於被黏著體並形成為片狀後使用以外，亦可製成於脫模膜上成型為單層或多層之片狀之附脫模膜之黏著片材。 作為該脫模膜之材質，例如可列舉：聚酯膜、聚烯烴膜、聚碳酸酯膜、聚苯乙烯膜、丙烯酸膜、三乙醯纖維素膜、氟樹脂膜等。該等之中，尤佳為聚酯膜及聚烯烴膜。 脫模膜之厚度並無特別限制。其中，例如就加工性及操作性之觀點而言，較佳為25 μm～500 μm，其中，進而較佳為38 μm以上或者250 μm以下，其中，進而較佳為50 μm以上或者200 μm以下。 再者，本黏著片材亦可採用未如上所述般使用被黏著體或脫模膜而將本組合物直接擠出成形之方法或藉由注入至模具中成形之方法。進而，藉由將本組合物直接填充至導電構件等構件間，亦可製成黏著片材之態樣。 ＜導電構件用黏著片材之物性＞ (對導電構件之導電層之防腐效果) 本黏著片材具有對導電構件、尤其是透明導電層或由包含銅之金屬材料形成之導體圖案之防腐性。因此，可將利用以下之(1)～(2)之方法所測得之ITO電阻值之變化率[((Ω/Ω0)－1)×100]設為未達5%，其中，可設為未達3%。又，可將利用以下之(3)～(4)之方法所測得之銅電阻值之變化率[((Ω/Ω0)－1)×100]設為未達20%，其中，可設為未達10%，進而可設為未達5%，尤其可設為未達3%。 (1)將導電構件用黏著劑組合物(本組合物)製膜成厚度150 μm之片狀而製成黏著片材，並將上述黏著片材貼合於包含氧化銦(ITO)之ITO配線形成於玻璃基板上而成之評價用ITO玻璃基板而製作附黏著片材之ITO配線。 (2)預先測定上述附黏著片材之ITO配線中之ITO配線之室溫下之電阻值(Ω0)，並於65℃・90%RH環境下將上述附黏著片材之ITO配線保管500小時，測定上述附黏著片材之ITO配線中之ITO配線之上述保管後之電阻值(Ω)。 (3)將導電構件用黏著劑組合物(本組合物)製膜成厚度150 μm之片狀而製成黏著片材，並將上述黏著片材貼合於銅配線形成於玻璃基板上而成之評價用銅玻璃基板而製作附黏著片材之銅配線。 (4)預先測定上述附黏著片材之銅配線中之銅配線之室溫下之電阻值(Ω0)，並於65℃・90%RH環境下將上述附黏著片材之銅配線保管500小時，測定上述附黏著片材之銅配線中之銅配線之上述保管後之電阻值(Ω)。 (透明性) 本黏著片材較佳為光學透明。即，較佳為透明黏著片材。此處，所謂「光學透明」，意在總光線透過率為80%以上，較佳為85%以上，更佳為90%以上。 (厚度) 本黏著片材之厚度較佳為10 μm以上且500 μm以下，其中，更佳為15 μm以上或者400 μm以下，其中，尤其進而較佳為20 μm以上或者350 μm以下。 ＜導電構件用黏著片材之用途＞ 本黏著片材於例如個人電腦、行動設備終端(PDA)、遊戲機、電視(TV)、汽車導航系統、觸控面板、手寫板等圖像顯示裝置、例如電漿顯示器(PDP)、液晶顯示器(LCD)、有機EL顯示器(OLED)、無機EL顯示器、電泳顯示器(EPD)、干擾調變顯示器(IMOD)等使用圖像顯示面板之圖像顯示裝置中，適合貼合各構成構件、其中導電構件、其中具有透明導電層及/或由包含銅之金屬材料形成之導體圖案之導電構件。又，亦適合貼合包含含有ITO或者IGZO之透明導電層及/或具有由包含銅或銀之金屬材料形成之導體圖案之透明導電層之導電構件。 ＜導電構件積層體＞ 本發明之導電構件積層體(以下，亦省略後稱為「本積層體」)可藉由將本黏著片材與導電構件、例如透明導電層之導電層面貼合而獲得。 本積層體只要具有至少將本黏著片材之任一黏著劑層面與透明導電層之導電層面貼合而成之構成即可。 於本黏著片材為兩面黏著片材之情形時，本積層體亦可具有將本黏著片材之兩黏著劑層面與透明導電層之導電層面貼合而成之構成。 上述透明導電層亦可以覆蓋其導電膜之導電層面之方式形成利用烯烴系聚合物、胺基甲酸酯系聚合物、環氧系聚合物、丙烯酸系聚合物、聚矽氧系聚合物、或者無機玻璃等而形成之絕緣保護膜(鈍化膜)。 於此情形時，本黏著片材並未與透明導電層面直接貼合(並未與透明導電層面直接相接)。本黏著片材即便源自本組合物之成分(尤其是酸成分)浸透而自該絕緣膜到達至透明導電層，亦可藉由1,2,3-***之作用防止透明導電層腐蝕。尤其是由於1,2,3-***之水溶性較高，於本黏著片材於濕熱環境下吸濕時容易移動至透明導電層，故而可實現優異之金屬腐蝕防止效果。 如此，根據本黏著片材，不論有無絕緣保護膜，不僅可實現被黏著體之金屬離子所導致之黏著劑層之變色或變質防止效果，亦可實現針對被黏著體之優異之金屬腐蝕防止效果。 與導電層面貼合所得之本積層體可較佳地用於觸控面板。作為觸控面板，可列舉電阻膜方式、靜電電容方式、電磁感應方式等方式者，較佳為靜電電容方式。 作為上述透明導電層，只要為至少於單面之表層具有導電層者即可，可列舉藉由蒸鍍或濺鍍、塗佈等於透明基材之表層設置有導電物質而成之透明導電層。 透明導電層之導電層所使用之導電物質並無特別限定，具體而言，除氧化銦、銦-鎵-鋅複合氧化物、摻錫之氧化銦(ITO)、氧化鋅、氧化鎵、氧化鈦等金屬氧化物以外，亦可列舉銀、銅、鉬、鋁等金屬材料。其中，可較佳地使用透明性優異之摻錫之氧化銦(ITO)及銦-鎵-鋅複合氧化物(IGZO)。又，就導電性優異之觀點而言，亦可較佳地使用銅或銀。於透明導電層中，作為欲利用導電物質形成圖案之基材，並無特別限定，可列舉玻璃、樹脂膜等。 典型而言，透明導電層至少於單面之表層具有導電層。又，典型而言，於透明導電層以引繞周邊部之方式形成有將銅或銀作為主成分之導體圖案(配線圖案)。1,2,3-***對其中之銅之耐腐蝕可靠性較高，因此包含其之本黏著片材可尤其較佳地用於具備由包含銅之金屬材料形成之導體圖案之導電構件。 作為其他本積層體之具體例，例如可列舉：脫模膜/本黏著片材/觸控面板、脫模膜/本黏著片材/保護面板、脫模膜/本黏著片材/圖像顯示面板、圖像顯示面板/本黏著片材/觸控面板、圖像顯示面板/本黏著片材/保護面板、圖像顯示面板/本黏著片材/觸控面板/本黏著片材/保護面板、偏光膜/本黏著片材/觸控面板、偏光膜/本黏著片材/觸控面板/本黏著片材/保護面板等構成。又，於上述構成中，可列舉於本黏著片材與和其相鄰之觸控面板、保護面板、圖像顯示面板、偏光膜等構件之間介置有上述導電層之所有構成。但是，並不限定於該等積層例。 再者，上述觸控面板亦包含使觸控面板功能內置於保護面板而成之結構體或使觸控面板功能內置於圖像顯示面板而成之結構體。 ＜圖像顯示裝置＞ 本發明之圖像顯示裝置(以下，亦省略後稱為「本裝置」)至少具有本積層體、圖像顯示面板及表面保護面板作為構成構件。 更具體而言，可列舉將本黏著片材與透明導電層之導電層面貼合而得之本積層體***至圖像顯示面板與表面保護面板之間之構成之圖像顯示裝置。此時，於圖像顯示面板側亦使用本黏著片材。 作為表面保護面板之材質，除玻璃以外，亦可為丙烯酸系樹脂、聚碳酸酯系樹脂、環烯烴聚合物等脂環式聚烯烴系樹脂、苯乙烯系樹脂、聚氯乙烯系樹脂、酚系樹脂、三聚氰胺系樹脂、環氧系樹脂等塑膠。 圖像顯示面板係由除偏光膜以外之相位差膜等其他光學膜、液晶材料及背光光源系統構成(通常，本組合物或黏著物品對圖像顯示面板之被接著面成為光學膜)，根據液晶材料之控制方式而存在STN(Super Twisted Nematic，超扭轉向列)方式或VA(Vertical Aligned，垂直配向)方式或IPS(In-Plane Switching，橫向電場效應)方式等，可為任何方式。 作為本圖像顯示裝置，例如可構成液晶顯示器、有機EL顯示器、無機EL顯示器、電子紙、電漿顯示器及微機電系統(MEMS)顯示器等圖像顯示裝置。 ＜語句之說明＞ 於本說明書中，於表述為「X～Y」(X、Y為任意之數字)之情形時，只要未特別說明，則包含「X以上且Y以下」之意義，並且包含「較佳為大於X」或者「較佳為小於Y」之意義。 又，於表述為「X以上」(X為任意之數字)或者「Y以下」(Y為任意之數字)之情形時，包含「較佳為大於X」或者「較佳為未達Y」之意圖。 一般而言，所謂「片材」，於JIS中之定義中，係指較薄、其厚度小於長度與寬度之商且平坦之製品，一般而言，所謂「膜」，係與長度及寬度相比厚度極小且最大厚度被任意地限定之較薄且平坦之製品，通常係指以輥之形供給者(日本工業標準JIS K6900)。然而，片材與膜之交界並不確定，於本發明中，無需於語言上對兩者進行區別，因此，於本發明中，於稱為「膜」之情形時亦包含「片材」，於稱為「片材」之情形時亦包含「膜」。 [實施例] 以下，藉由實施例及比較例進而詳細地進行說明。但是，本發明並不限定於該等實施例。 ＜(甲基)丙烯酸系(共)聚合物＞ (甲基)丙烯酸系(共)聚合物使用以下者。 ・A-1：包含丙烯酸2-乙基己酯76質量份、乙酸乙烯酯20質量份及丙烯酸4質量份之共聚物(質量平均分子量40萬) ・A-2：包含丙烯酸丁酯81質量份、甲基丙烯酸甲酯15質量份及丙烯酸4質量份之共聚物(質量平均分子量20萬) ＜實施例1＞ [實施例1-1] 向(甲基)丙烯酸系(共)聚合物(A-1)1 kg中添加1,2,3-***(大塚化學公司製造)3 g作為金屬腐蝕防止劑、及4-甲基二苯甲酮與2,4,6-三甲基二苯甲酮之混合物(Lamberti公司製造，商品名「Esacure TZT」)15 g作為光聚合起始劑並均勻混合，獲得黏著劑層用樹脂組合物。 將黏著劑層用樹脂組合物夾於經剝離處理之2片聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，商品名「DIAFOIL MRV」，厚度100 μm及三菱樹脂公司製造，商品名「DIAFOIL MRQ」，厚度75 μm)之間，並以黏著片材之厚度成為150 μm之方式賦形成片狀，製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表1。 [實施例1-2] 向(甲基)丙烯酸系(共)聚合物(A-2)1 kg中添加作為金屬腐蝕防止劑之1,2,3-***3 g、作為交聯劑之紫外線硬化樹脂丙氧化季戊四醇三丙烯酸酯(新中村工業股份有限公司，商品名「ATM-4PL」)20 g、作為光聚合起始劑之4-甲基二苯甲酮及2,4,6-三甲基二苯甲酮之混合物(Lamberti公司製造，商品名「Esacure TZT」)15 g，並均勻混合，獲得黏著劑層用樹脂組合物。 繼而，將上述黏著劑層用樹脂組合物以厚度成為150 μm之方式於經剝離處理之聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，商品名「DIAFOIL MRV」，厚度100 μm)上成形為片狀後，被覆經剝離處理之聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，商品名「DIAFOIL MRQ」，厚度75 μm)，製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表1。 [實施例1-3] 使用作為金屬腐蝕防止劑之1,2,3-***5 g，除此以外，以與實施例1-2相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表1。 [比較例1-1] 未添加作為金屬腐蝕防止劑之1,2,3-***，除此以外，以與實施例1-1相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表1。 [比較例1-2] 使用苯并***(城北化學公司製造、商品名「BT120」)5 g代替1,2,3-***作為金屬腐蝕防止劑，除此以外，以與實施例1-1相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表1。 [比較例1-3] 使用甲苯并***(4-甲基苯并***與5-甲基苯并***之混合物)(Shipro Kasei公司製造，商品名「SEETEC TT-R」)5 g代替1,2,3-***作為金屬腐蝕防止劑，除此以外，以與實施例1-1相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表1。 [比較例1-4] 使用2,5-二巰基-1,3,4-噻二唑(TOYOBO公司製造，商品名「MTD」)5 g代替1,2,3-***作為金屬腐蝕防止劑，除此以外，以與實施例1-1相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表1。 ＜各種評價＞ (1)耐腐蝕可靠性 於玻璃基板(60 mm×45 mm)上以線寬70 μm、線長度46 mm、線間隔30 μm並以往返10.5次之方式形成將厚度1300 Å之ITO、厚度3000 Å之銅膜依序積層而成之金屬膜之往返線，並且於該往返線之兩末端形成2 mm見方之正方形而形成銅圖案(長度約97 cm)，製作耐腐蝕可靠性評價用銅玻璃基板(參照圖1(A))。 將上述實施例及比較例中製作之黏著片材積層體(黏著片材厚度150 μm)之單面之剝離膜剝離，並利用手壓輥將聚對苯二甲酸乙二酯(PET)膜(東洋紡織公司製造，商品名「COSMOSHINE A4100」，125 μm)貼附於其露出面。繼而，將上述附PET膜之黏著片材切成52 mm×45 mm後，將剩下之剝離膜剝離，如圖1(B)所示，以將金屬膜之往返線上被覆之方式利用手壓輥將該黏著片材貼附於耐腐蝕可靠性評價用銅玻璃基板，進而，隔著PET膜，以實施例1-1及比較例1-1～1-4之波長365 nm之累計光量成為3000 mJ/cm2 、實施例1-2及1-3之波長365 nm之累計光量成為2000 mJ/cm2 之方式利用高壓水銀燈照射紫外線，使之進行紫外線交聯，製作耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)(參照圖1(D))。 預先測定該耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)中之銅配線之室溫下之電阻值(Ω0)。 另一方面，將該耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)於65℃・90%RH環境下保管500小時，保管後測定耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)中之銅配線之電阻值(Ω)。 並且，算出銅電阻值、即線末端間電阻值之變化率(%)[((Ω/Ω0)－1)×100]，於表1中表示成「電阻值變化」。 關於耐腐蝕可靠性，將電阻值之變化率為20%以上者判定為「×(poor)」，將未達20%者判定為「○(good)」。結果示於表1。 (2)耐發泡可靠性 將實施例及比較例中製作之黏著片材積層體(厚度150 μm)之單面之剝離膜剝離，並利用手動輥貼合於鈉鈣玻璃板(150×200 mm，厚度0.55 mm)。進而，將剩餘之剝離膜剝離，一面使化學強化玻璃板(180×220 mm，厚度0.6 mm)對齊，一面利用手動輥貼合。 繼而，將貼合品於60℃、0.2 MPa環境下進行20分鐘高壓釜處理。使用金屬鹵化物燈照射裝置(牛尾電機公司製造，型號UVC-0516S1，LAMP UVL-8001M3-N)，以每照射1次而波長365 nm下之照射量成為3000 mJ/cm2 之方式調整輸送帶速度、放射照度，針對該樣品照射15次後，觀察外觀之變化。 關於耐發泡可靠性，於對外觀進行觀察時，將與紫外線照射前不存在變化者判定為「○(good)」，將產生氣泡者判定為「×(poor)」。結果示於表1。 (3)紫外線硬化特性 (紫外線硬化前儲存彈性模數G') 紫外線硬化前之儲存彈性模數係藉由如下而求出：將將使實施例及比較例中製作之黏著片材以成為1～2 mm厚度之方式積層而成者沖裁成直徑20 mm之圓狀而成者作為測定試樣，並使用流變儀(英弘精機股份有限公司製造之「MARS」)，以黏著治具：Φ25 mm平行板、應變：0.5%、頻率：1 Hz、溫度：-50～200℃、升溫速度：3℃/min測定-50℃～200℃下之動態儲存彈性模數G'，並讀取125℃下之儲存彈性模數值。結果示於表1。 (紫外線硬化後儲存彈性模數G') 紫外線硬化後之儲存彈性模數係以如下方式進行測定。 利用高壓水銀燈隔著PET膜對實施例及比較例中製作之黏著片材照射紫外線而使之進行紫外線交聯。此時，關於實施例1-1及比較例1-1～1-4，以波長365 nm之累計光量成為3000 mJ/cm2 之方式進行照射，實施例1-2及1-3係以該積層光量成為2000 mJ/cm2 之方式進行照射。將使以如上方式進行紫外線交聯後之黏著片材以成為厚度1～2 mm之方式積層並沖裁成直徑20 mm之圓狀而成者作為測定試樣。 使用流變儀(英弘精機股份有限公司製造，商品名「MARS」)以黏著治具：Φ25 mm平行板、應變：0.5%、頻率：1 Hz、溫度：-50～200℃、升溫速度：3℃/min測定-50℃～200℃下之該測定試樣之動態儲存彈性模數G'，並讀取125℃下之儲存彈性模數值，藉此求出紫外線硬化後之儲存彈性模數。結果示於表1。 關於紫外線硬化特性，對紫外線硬化前儲存彈性模數G'與紫外線硬化後儲存彈性模數G'進行比較，將硬化後之值明顯上升者判定為「○(good)」，將值幾乎未變化者判定為「×(poor)」。結果示於表1。 [表1] (評價結果) 實施例1-1～1-3之黏著片材含有1,2,3-***作為金屬腐蝕防止劑，藉此，銅配線之電阻值之變化較少，且耐腐蝕可靠性優異。又，耐發泡可靠性、紫外線硬化特性亦良好。 另一方面，比較例1-1不包含金屬腐蝕防止劑，而耐腐蝕可靠性較差。 比較例1-2雖包含苯并***作為金屬腐蝕防止劑，但因苯并***之特性而耐發泡可靠性較差。 比較例1-3雖包含甲苯并***作為金屬腐蝕防止劑，但因甲苯并***之特性而耐發泡可靠性較差。 比較例1-4雖包含二巰基噻二唑作為金屬腐蝕防止劑，但由於二巰基噻二唑會吸收紫外線，故而黏著片材之紫外線硬化特性較差。 根據以上之結果可知，1,2,3-***由於熔點約為20℃，且於常溫下幾乎為液體，故而於黏著片材之實際製造步驟中，容易添加至黏著主劑中，又，向黏著主劑之分散性亦優異。 又，亦明確1,2,3-***由於水溶性較高，於黏著片材於濕熱環境下吸濕時，容易移動至金屬層(銅配線)之表面，故而可發揮優異之金屬腐蝕防止效果。 又，亦明確1,2,3-***由於在波長300～400 nm之分光光度下不存在吸收，故而不會阻礙UV(Ultraviolet，紫外線)硬化特性。 如上所述，發現1,2,3-***與先前之金屬腐蝕防止劑相比具有優異之特性，尤其有效地用於導電構件用之黏著片材。 ＜實施例2＞ [實施例2-1] 向(甲基)丙烯酸系(共)聚合物(A-1)1 kg中添加丙氧化季戊四醇聚丙烯酸酯(新中村化學工業公司製造，商品名「ATM-4PL」)200 g作為交聯劑、及4-甲基二苯甲酮與2,4,6-三甲基二苯甲酮之混合物(Lamberti公司製造，商品名「Esacure TZT」)10 g作為光聚合起始劑並均勻混合，獲得中間層用樹脂組合物。 將中間層用樹脂組合物夾於經剝離處理之2片聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，商品名「DIAFOIL MRF」，厚度75 μm及三菱樹脂公司製造，商品名「DIAFOIL MRT」，厚度38 μm)之間，並以黏著片材之厚度成為80 μm之方式賦形成片狀，製作中間層用樹脂片(α)。 向(甲基)丙烯酸系(共)聚合物(A-1)1 kg中添加1,2,3-***1.5 g作為金屬腐蝕防止劑、亞磷酸三(2,4-二第三丁基苯基)酯(BASF公司製造，商品名「Irgafos 168」)5 g作為亞磷酸酯化合物、及4-甲基二苯甲酮與2,4,6-三甲基二苯甲酮之混合物(Lamberti公司製造、商品名「Esacure TZT」)15 g作為光聚合起始劑並均勻混合，獲得黏著劑層用樹脂組合物。 將上述黏著劑層用樹脂組合物夾於經剝離處理之2片聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，商品名「DIAFOIL MRV」，厚度100 μm及三菱樹脂公司製造，商品名「DIAFOIL MRT」，厚度38 μm)之間，並以黏著片材之厚度成為35 μm之方式賦形成片狀，製作黏著劑層用樹脂片(β)。 進而，將上述黏著劑層用樹脂組合物夾於經剝離處理之2片聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，商品名「DIAFOIL MRQ」，厚度75 μm及三菱樹脂公司製造，商品名「DIAFOIL MRT」，厚度38 μm)之間，並以黏著片材之厚度成為35 μm之方式賦形成片狀，製作黏著劑層用樹脂片(β')。 將上述中間層用片材(α)之兩側之PET膜依序剝離去除，並且將黏著劑層用樹脂片(β)及(β')之一側之PET膜剝離，將所露出之黏著面依序貼合於中間層用片材(β)之兩表面，製作包含(β)/(α)/(β')之積層體。 隔著殘留於上述(β)及(β')之表面之PET膜，以波長365 nm之累計光量成為2000 mJ/cm2 之方式利用高壓水銀燈照射紫外線，使(α)、(β)及(β')進行紫外線交聯，製作黏著片材積層體(厚度150 μm)。針對該黏著片材積層體，進行下述各種評價。結果示於表2。 [實施例2-2] 向(甲基)丙烯酸系(共)聚合物(A-2)1 kg中添加1,2,3-***3 g作為金屬腐蝕防止劑、亞磷酸三癸酯(ADEKA公司製造，商品名「Adekastab 3010」)3 g作為亞磷酸酯化合物、季戊四醇三及四丙烯酸酯(東亞合成公司製造，「ARONIXM-306」)20 g作為交聯劑、以及1-羥基-環己基苯基酮(BASF公司製造，Irgacure 184)10 g作為光聚合起始劑並均勻混合，獲得黏著劑層用樹脂組合物。 繼而，將上述黏著劑層用樹脂組合物於經剝離處理之聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，DIAFOIL MRV，厚度100 μm)上以厚度成為150 μm之方式成形為片狀後，被覆經剝離處理之聚對苯二甲酸乙二酯膜(三菱樹脂公司製造，商品名「DIAFOIL MRQ」，厚度75 μm)。隔著經剝離處理之聚對苯二甲酸乙二酯膜，以波長365 nm之累計光量成為1000 mJ/cm2 之方式利用高壓水銀燈照射紫外線使黏著劑層用樹脂組合物進行紫外線交聯，製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表2。 [實施例2-3] 使用3,9-雙(癸氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5.5]十一烷(城北化學公司製造，商品名「JPE-10」)3 g作為亞磷酸酯化合物，除此以外，以與實施例2-2相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表2。 [比較例2-1] 未添加作為金屬腐蝕防止劑之1,2,3-***及作為亞磷酸酯化合物之亞磷酸三(2,4-二第三丁基苯基)酯(BASF公司製造，商品名「Irgafos 168」)，除此以外，以與實施例2-1相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表2。 [比較例2-2] 未添加作為金屬腐蝕防止劑之1,2,3-***，除此以外，以與實施例2-1相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表2。 [比較例2-3] 添加苯并***(城北化學公司製造，商品名「BT120」)1.5 g代替1,2,3-***作為金屬腐蝕防止劑，且未添加亞磷酸酯化合物，除此以外，以與實施例2-1相同之方式製作黏著片材積層體。針對該黏著片材積層體，進行下述各種評價。結果示於表2。 ＜各種評價＞ (1)防氧化劣化性 於玻璃基板(60 mm×45 mm)上以厚度150～200 Å、線寬70 μm、線長度46 mm、線間隔30 μm並以往返10.5次之方式形成氧化銦(ITO)之往返線，並且於該往返線之兩末端形成包含ITO之2 mm見方之正方形而形成ITO圖案(長度約97 cm)，製作防氧化劣化性評價用ITO玻璃基板(參照圖1(A))。 將於上述實施例及比較例中製作之黏著片材積層體(厚度150 μm)之單面之剝離膜剝離，並利用手壓輥將PET膜(東洋紡織公司製造，商品名「COSMOSHINE A4100」，125 μm)貼附於其露出面。繼而，將上述附PET膜之黏著片材切成52 mm×45 mm後，將剩餘之剝離膜剝離，如圖1(B)所示，以將ITO之往返線上被覆之方式利用手壓輥將該黏著片材貼附於防氧化劣化性評價用ITO玻璃基板，製作防氧化劣化性評價用樣品(附黏著片材之ITO配線)(參照圖1(C))。 預先測定該防氧化劣化性評價用樣品(附黏著片材之ITO配線)中之ITO配線之室溫下之電阻值(Ω0)。 另一方面，將該防氧化劣化性評價用樣品(附黏著片材之ITO配線)於65℃・90%RH環境下保管500小時，保管後，測定耐防氧化劣化性評價用樣品(附黏著片材之ITO配線)中之ITO配線之電阻值(Ω)。 並且，算出ITO電阻值、即線末端間電阻值之變化率(%)[((Ω/Ω0)－1)×100]，於表2中表示成「電阻值變化」。 關於防氧化劣化性，將電阻值之變化率為5%以上者判定為「×(poor)」，將未達5%判定為「○(good)」。結果示於表2。 (2)耐腐蝕可靠性 於玻璃基板(60 mm×45 mm)上以線寬70 μm、線長度46 mm、線間隔30 μm並以往返10.5次之方式形成將厚度1300 Å之ITO、厚度3000 Å之銅膜依序積層而成之金屬膜之往返線，並且於該往返線之兩末端形成2 mm見方之正方形而形成銅圖案(長度約97 cm)，製作耐腐蝕可靠性評價用銅玻璃基板(參照圖1(A))。 將於上述實施例及比較例中製作之黏著片材積層體(厚度150 μm)之單面之剝離膜剝離，並利用手壓輥將PET膜(東洋紡織公司製造，商品名「COSMOSHINE A4100」，125 μm)貼附於其露出面。繼而，將上述附PET膜之黏著片材切成52 mm×45 mm後，將剩餘之剝離膜剝離，如圖1(B)所示，以將金屬膜之往返線上被覆之方式利用手壓輥將黏著片材貼附於耐腐蝕可靠性評價用銅玻璃基板，製作耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)(參照圖1(D))。 預先測定該耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)中之銅配線之室溫下之電阻值(Ω0)。 另一方面，將該耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)於65℃・90%RH環境下保管500小時，保管後，測定耐腐蝕可靠性評價用樣品(附黏著片材之銅配線)中之銅配線之電阻值(Ω)。 並且，算出銅電阻值、即線末端間電阻值之變化率(%)[((Ω/Ω0)－1)×100]，於表2中表示成「電阻值變化」。 關於耐腐蝕可靠性，將電阻值之變化率為20%以上者判定為「×(poor)」，將未達20%判定為「○(good)」。結果示於表2。 [表2] (評價結果) 實施例2-1～2-3之黏著片材含有1,2,3-***作為金屬腐蝕防止劑，進而包含亞磷酸酯，藉此ITO配線、銅配線均為電阻值之變化較少且耐腐蝕可靠性及防氧化劣化性優異者。 另一方面，比較例2-1均不包含亞磷酸酯化合物及金屬腐蝕防止劑，而耐腐蝕可靠性及防氧化劣化性較差。 比較例2-2由於不包含金屬腐蝕防止劑，故而銅配線之腐蝕尤其顯著。 比較例2-3不包含亞磷酸酯化合物，而對ITO配線之防氧化劣化性較差。 [產業上之可利用性] 本發明之導電構件用黏著片材可具有對導電構件(典型而言，具有透明導電層及/或由包含銅或者銀之金屬材料形成之導體圖案之導電構件)之耐腐蝕可靠性，並且可具有耐發泡可靠性，因此可用作適合貼合各種導電構件之黏著片材。尤其可較佳地用作具有觸控面板之圖像顯示裝置用之黏著片材。Hereinafter, an example of an embodiment of the present invention will be described in detail. However, the present invention is not limited to the following embodiments. <Adhesive sheet for a conductive member> The adhesive sheet for a conductive member (hereinafter referred to as "the present adhesive sheet" is omitted) has a (meth)acrylic (co)polymer. And an adhesive layer of the 1,2,3-triazole adhesive composition. The adhesive layer may be a single layer or a plurality of layers, and in the case of a plurality of layers, other layers such as a so-called substrate layer may also be present. In the case where the adhesive layer is composed of a plurality of layers of other layers, it is preferred that the surface layer of the adhesive sheet is an adhesive layer containing the above adhesive composition. In the case where the adhesive sheet is a plurality of layers, the thickness of the adhesive layer containing the above adhesive composition is not limited, and is preferably 10% or more, more preferably 30% or more, based on the entire thickness of the adhesive sheet. Further preferably, it is 50% or more. When the thickness of the pressure-sensitive adhesive layer containing the pressure-sensitive adhesive composition is in the above range, corrosion resistance reliability, foaming reliability, and hardening property of the conductive member are improved, which is preferable. In the present invention, the term "(co)polymer" includes the meaning of a homopolymer and a copolymer, and the term "(meth)acrylate" includes the meaning of acrylate and methacrylate. [Adhesive Composition] The adhesive composition used in the present adhesive sheet (hereinafter referred to as "the present composition" is omitted) contains a (meth)acrylic (co)polymer and 1,2,3-three. Oxazole. The composition may further contain a phosphite compound, a crosslinking agent, a photopolymerization initiator, an antioxidant, and other components. The composition is preferably a photocurable composition. ((Meth)acrylic (co)polymer) As the (meth)acrylic (co)polymer, for example, a homopolymer of an alkyl (meth)acrylate may be mentioned by A copolymer obtained by polymerizing a monomer component having copolymerizability, more preferably an alkyl group-containing monomer containing a (meth)acrylic acid alkyl ester, a hydroxyl group-containing monomer, an amine group-containing monomer A copolymer of at least one selected from the group consisting of an epoxy group-containing monomer, a mercapto group-containing monomer, and other vinyl monomers as a structural unit. The (meth)acrylic (co)polymer can be produced by a conventional method using a polymerization initiator as needed for the monomers exemplified below. When the (meth)acrylic (co)polymer is a copolymer containing a carboxyl group-containing monomer as a structural unit, a (meth)acrylic (co)polymer is obtained from the viewpoint of obtaining excellent adhesive properties. It is preferably contained in an amount of 1.2 to 15% by mass based on the carboxyl group-containing monomer, and is contained in an amount of 1.5% by mass or more or 10% by mass or less, and more preferably 2.0% by mass or more or 8% by mass or less. An example of a more specific (meth)acrylic (co)polymer is a linear or branched alkyl (meth)acrylate having a carbon number of 4 to 18 in a side chain (hereinafter also referred to as " The copolymerizable monomer A") is a copolymer composed of any one or more monomer components selected from the group consisting of the following.・Carboxyl group-containing monomer (hereinafter also referred to as "copolymerizable monomer B") ・Giant monomer (hereinafter also referred to as "copolymerizable monomer C") ・The number of carbon atoms in the side chain is 1 to 3 (methyl) Acrylate (hereinafter also referred to as "copolymerizable monomer D") ・Hydroxyl group-containing monomer (hereinafter also referred to as "copolymerizable monomer E") ・Other vinyl monomers (hereinafter also referred to as "copolymerizable monomer F" Further, examples of the (meth)acrylic (co)polymer include (a) a monomer containing a copolymerizable monomer A, a copolymerizable monomer B, and/or a copolymerizable monomer C. a copolymer composed of a component or (b) consisting of a monomer component comprising a copolymerizable monomer A, a copolymerizable monomer B and/or a copolymerizable monomer C, a copolymerizable monomer D, and/or a copolymerizable monomer E. Copolymers are exemplified as being particularly preferred. Examples of the linear or branched alkyl (meth)acrylate (copolymerizable monomer A) having 4 to 18 carbon atoms in the side chain include n-butyl (meth)acrylate and (meth)acrylic acid. Isobutyl ester, second butyl (meth)acrylate, tert-butyl (meth)acrylate, amyl (meth)acrylate, isoamyl (meth)acrylate, neopentyl (meth)acrylate, Hexyl (meth)acrylate, cyclohexyl (meth)acrylate, heptyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl (meth)acrylate, (methyl) Isooctyl acrylate, decyl (meth) acrylate, isodecyl (meth) acrylate, t-butylcyclohexyl (meth) acrylate, decyl (meth) acrylate, isophthalic acid (meth) acrylate Ester, undecyl (meth)acrylate, lauryl (meth)acrylate, tridecyl (meth)acrylate, tetradecyl (meth)acrylate, cetyl (meth)acrylate Ester, stearyl (meth) acrylate, isostearyl (meth) acrylate, behenyl (meth) acrylate, (meth) acrylate, &lt;158665; base ester, 3,5,5-three Methylcyclohexane (meth) acrylate, (meth) propylene , Dicyclopentenyl (meth) acrylate, dicyclopentenyl acrylate, (meth) acrylate, dicyclopentenyloxyethyl acrylate, (meth) acrylate, benzyl and the like. These may be used alone or in combination of two or more. The copolymerizable monomer A is preferably contained in an amount of 30% by mass or more and 90% by mass or less based on the total monomer component of the copolymer, and more preferably in a range of 35% by mass or more and 88% by mass or less. Among them, it is particularly preferably further contained in the range of 40% by mass or more or 85% by mass or less. Examples of the carboxyl group-containing monomer (copolymerizable monomer B) include (meth)acrylic acid, 2-(meth)acryloxyethyl hexahydrophthalic acid, and 2-(methyl)acrylic acid.醯oxypropyl hexahydrophthalic acid, 2-(meth) propylene methoxyethyl phthalate, 2-(methyl) propylene methoxy propyl phthalate, 2-(A Acryloxyethyl maleic acid, 2-(methyl)propenyloxypropyl maleic acid, 2-(methyl)acryloxyethyl succinic acid, 2-( Methyl) propylene methoxy propyl succinic acid, crotonic acid, fumaric acid, maleic acid, and itaconic acid. These may be used alone or in combination of two or more. Further, "(meth)acrylic group" means the meaning of an acryl group and a methacryl group. Similarly, "(meth)acrylonitrile" means the meaning of propylene fluorenyl and methacryl fluorenyl. The copolymerizable monomer B is preferably contained in the range of 1.2% by mass or more and 15% by mass or less based on the total monomer component of the copolymer. From the viewpoint of obtaining excellent adhesive properties, it is preferably It is contained in the range of 1.5 mass % or more or 10 mass % or less, and it is especially preferable to contain in the range of 2 mass % or more or 8 mass % or less. The macromonomer (copolymerizable monomer C) is a monomer having a carbon number of 20 or more in the side chain when the (meth)acrylic (co)polymer is polymerized. The (meth)acrylic (co)polymer can be made into a graft copolymer by using the copolymerizable monomer C. Therefore, the characteristics of the main chain and the side chain of the graft copolymer can be changed depending on the selection or blending ratio of the copolymerizable monomer C and the other monomer. As the macromonomer (copolymerizable monomer C), the skeleton component is preferably composed of an acrylic polymer or a vinyl polymer. Examples of the skeleton component of the macromonomer include the above-mentioned copolymerizable monomer A, the above copolymerizable monomer B, the following copolymerizable monomer D, and the following copolymerizable monomer E, which may be used alone. Or two or more types can be used in combination. The macromonomer system has a radical polymerizable group or a functional group such as a hydroxyl group, an isocyanate group, an epoxy group, a carboxyl group, an amine group, a guanamine group, or a thiol group. As the macromonomer, it is preferred to have a radical polymerizable group which can be copolymerized with other monomers. The radical polymerizable group may contain one or two or more, and particularly preferably one. In the case where the macromonomer has a functional group, the functional group may also contain one or two or more, and particularly preferably one. Further, it may contain either a radical polymerizable group or a functional group, or both. The number average molecular weight of the copolymerizable monomer C is preferably from 500 to 20,000. Among them, it is preferably 800 or more or 8,000 or less, and more preferably 1,000 or more and 7,000 or less. The macromonomer can be suitably used in a general manner (for example, a macromonomer manufactured by Toagosei Co., Ltd., etc.). The copolymerizable monomer C is preferably contained in the range of 5% by mass or more and 30% by mass or less based on the total monomer component of the copolymer, and preferably 6% by mass or more or 25% by mass or less. It is contained in the range, and it is especially preferable to contain it in the range of 8 mass % or more or 20 mass % or less. Examples of the (meth) acrylate (copolymerizable monomer D) having 1 to 3 carbon atoms in the side chain include methyl (meth)acrylate, ethyl (meth)acrylate, and (meth)acrylic acid. N-propyl ester, isopropyl (meth)acrylate, and the like. These may be used alone or in combination of two or more. The copolymerizable monomer D is preferably contained in an amount of from 0% by mass to 70% by mass based on the total monomer component of the copolymer, and more preferably in a range of from 3% by mass to 65% by mass. Among them, it is particularly preferably further contained in a range of 5 mass% or more or 60 mass% or less. Examples of the hydroxyl group-containing monomer (copolymerizable monomer E) include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, and 3-hydroxypropyl (meth)acrylate. A hydroxyalkyl (meth)acrylate such as 2-hydroxybutyl (meth)acrylate. These may be used alone or in combination of two or more. The copolymerizable monomer E is preferably contained in an amount of 0% by mass or more and 30% by mass or less based on the total monomer component of the copolymer, and more preferably in a range of 0% by mass or more or 25% by mass or less. In particular, it is more preferably contained in the range of 0% by mass or more or 20% by mass or less. As the other vinyl monomer (copolymerizable monomer F), in addition to the copolymerizable monomers A to E, a compound having a vinyl group in the molecule may be mentioned. As such a compound, functional monomers having a functional group such as a mercaptoamine group or an alkoxyalkyl group in the molecule; and a polyalkylene glycol di(meth)acrylate; and vinyl acetate can be exemplified. Vinyl ester monomers such as vinyl propionate and vinyl laurate; and aromatic vinyl monomers such as styrene, chlorostyrene, chloromethylstyrene, α-methylstyrene and other substituted styrenes. These may be used alone or in combination of two or more. The copolymerizable monomer F is preferably contained in an amount of from 0% by mass to 30% by mass based on the total monomer component of the copolymer, and more preferably in a range of from 0% by mass to 25% by mass. In particular, it is more preferably contained in the range of 0% by mass or more or 20% by mass or less. In addition to the above, it may be appropriately used as needed: an acid anhydride group-containing monomer such as maleic anhydride or itaconic acid anhydride; glycidyl (meth)acrylate, glycidyl α-ethyl acrylate, (A) An epoxy group-containing monomer such as (meth)acrylic acid-3,4-epoxybutyl acrylate; dimethylaminoethyl (meth)acrylate; diethylaminoethyl (meth)acrylate; Acrylate monomer; (meth) acrylamide, N-tert-butyl (meth) acrylamide, N-methylol (meth) acrylamide, N-methoxymethyl (Methyl) acrylamide, N-butoxymethyl (meth) acrylamide, diacetone (meth) acrylamide, maleic acid amide, maleic amine, etc. a monomer of an amino group or a quinone imine group; a heterocyclic basic monomer such as vinylpyrrolidone, vinyl pyridine or vinyl carbazole; and the like. Typical examples of the (meth)acrylic (co)polymer include 2-ethylhexyl (meth)acrylate, octyl (meth)acrylate, and decyl (meth)acrylate. a monomer component (a) such as isostearyl (meth)acrylate, butyl (meth)acrylate, ethyl (meth)acrylate or methyl (meth)acrylate, or a (meth)acrylic acid having a carboxyl group; 2-(Methyl)propenyloxyethylhexahydrophthalic acid, 2-(methyl)propenyloxypropylhexahydrophthalic acid, 2-(methyl)propenyloxyethyl Phthalic acid, 2-(meth)acryloxypropyl phthalate, 2-(meth) propylene oxiranyl ethyl maleate, 2-(methyl) propylene oxime Propyl maleic acid, 2-(methyl) propylene methoxyethyl succinic acid, 2-(methyl) propylene methoxy propyl succinic acid, crotonic acid, fumaric acid, cis-butane a monomer component (b) such as enedioic acid or itaconic acid, and hydroxyethyl (meth)acrylate having an organic functional group, hydroxypropyl (meth)acrylate, or hydroxybutyl (meth)acrylate, Methyl acrylate glyceride, maleic acid monomethyl ester, itaconic acid monomethyl ester, acetic acid Monomer components such as enester, glycidyl (meth)acrylate, (meth)acrylamide, (meth)acrylonitrile, fluorinated (meth)acrylate, poly(oxy)oxy (meth)acrylate ( c) Copolymerization of the resulting (meth) acrylate copolymer. The mass average molecular weight of the (meth)acrylic (co)polymer is preferably 100,000 or more and 1.5 million or less, and more preferably 150,000 or more or 1.3 million or less, and particularly preferably 200,000 or more or 1.2 million. the following. In the case where an adhesive composition having a high cohesive force is desired, the (m)acrylic (co)polymer is used in view of the fact that the molecular weight is larger and the cohesive force is obtained by crosslinking of molecular chains. The mass average molecular weight is preferably 700,000 or more and 1.5 million or less, and more preferably 800,000 or more or 1.3 million or less. On the other hand, in the case of obtaining an adhesive composition having high fluidity or stress relaxation property, the mass average molecular weight is preferably 100,000 or more and 700,000 or less, and more preferably 150,000 or more or 600,000 or less. On the other hand, when a solvent is not used for molding an adhesive sheet or the like, since the polymer having a large molecular weight is not easily used, the mass average molecular weight of the (meth)acrylic (co)polymer is preferably 100,000. The above is less than 700,000, and particularly preferably 150,000 or more, or 600,000 or less, and particularly preferably 200,000 or more or 500,000 or less. (Metal corrosion inhibitor) The composition contains 1,2,3-triazole. 1,2,3-triazole has a function as a metal corrosion preventing agent for a conductive layer of a conductive member. 1,2,3-triazole is preferably used as a composition containing 1,2,3-triazole because of its copper corrosion resistance to copper and excellent foaming reliability as an adhesive sheet. A conductive member having a transparent conductive layer and a conductor pattern (wiring pattern) formed of a metal material containing copper. The reason for this is that corrosion is prevented by forming a protective film in which copper atoms are chemically bonded to molecules of 1,2,3-triazole by a surface of a conductor pattern formed of a metal material containing copper. Further, in the conductive member having the conductor pattern formed of the metal material containing silver, the effect of the protective film obtained by using 1,2,3-triazole can be similarly achieved. Further, 1,2,4-triazole is present as an isomer of 1,2,3-triazole. The 1,2,4-triazole is a solid having a melting point of about 120 ° C. On the other hand, the melting point of 1,2,3-triazole is about 20 ° C, and it is substantially in a liquid state at room temperature. Therefore, the 1,2,3-triazole has an advantage that it is excellent in dispersibility when mixed in an adhesive composition, can be uniformly mixed, and is excellent in master batching. In the present invention, it is preferably 0.01 parts by mass or more and 5 parts by mass based on 100 parts by mass of the (meth)acrylic (co)polymer, from the viewpoint of the leaching of the metal corrosion preventing agent or the metal corrosion preventing effect. The ratio of the parts by mass or less is 1,2,3-triazole, and it is further preferable to contain 1,2,3-triazole in a ratio of 0.1 part by mass or more or 1 part by mass or less, and further preferably The ratio of 0.2 parts by mass or more or 0.5 parts by mass or less contains 1,2,3-triazole. Further, 1,2,3-triazole may be used in combination with 1,2,4-triazole in the present composition. (Phosphite compound) The composition may further contain a phosphite compound. The phosphite compound is not only not corrosive in itself, but also stabilizes an acid component such as a carboxyl group. Therefore, by formulating the phosphite compound in the present composition containing a specific (meth)acrylic (co)polymer, even if the composition contains an acid component, oxidative degradation of the conductive member as the adherend can be prevented. When the composition does not contain an acid component, it is of course possible to prevent oxidative degradation of the conductive member as the adherend. Therefore, if an adhesive sheet is formed from the present composition containing a phosphite compound, it may have a conductive member (typically, a transparent conductive layer containing ITO and/or a conductor formed of a metal material containing copper or silver) The conductive member of the pattern has corrosion resistance reliability and can prevent oxidative degradation of the conductive member. Therefore, for example, it can be preferably used as an adhesive sheet for an image display device having a touch panel. The phosphite compound which the composition may contain is not limited. Particularly preferred is a phosphite compound represented by the following formula (1). Formula (1) P[-OR] 3 (wherein R is a hydrocarbon, specifically, a substituted or unsubstituted aromatic, an aliphatic ring, an alkyl group, etc.; and a plurality of R may be the same or different Further, a plurality of adjacent R groups may be bonded to each other to form a saturated or unsaturated ring structure. Further, it may be a compound containing two or more structural units represented by the above formula (1). The various phosphite compounds represented by the above formula (1) are blended in the present composition containing a specific (meth)acrylic (co)polymer and 1,2,3-triazole, and as a result, any sub-Asian compound is confirmed. Each of the phosphate compounds exhibited an oxidation preventing deterioration effect, and it was confirmed that the effect of the oxidation preventing deterioration of the transparent conductive layer containing ITO was particularly excellent. Examples of the phosphite compound contained in the composition include triphenyl phosphite, tris(nonylphenyl) phosphite, tricresyl phosphite, tristearyl phosphite, and triethyl phosphite. Ester, tris(2-ethylhexyl) phosphite, tridecyl phosphite, trilauryl phosphite, tris(tridecyl) phosphite, trioleyl phosphite, diphenyl phosphite (2 -ethylhexyl)ester, diphenyl phthalate monodecyl ester, diphenyl phosphite mono(tridecyl)ester, tetraphenyldipropyldipropylene glycol diphosphite, tetraphenyl (tetra- Tridecyl pentaerythritol tetraphosphite, tetrakis(C12-C15 alkyl)-4,4-isopropylidene diphenyl diphosphite, tris(2,4-di-t-butylbenzene) Ester), tris(4-mercaptophenyl) phosphite, 3,9-bis(nonylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphorane [5,5]undecane, 3,9-bis(4-mercaptophenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5] Mono-, 3,9-bis(decyloxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 3,9-bis (ten Trialkoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 3,9-double ( Stearyloxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 3,9-bis(2,6-di-t-butyl -4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 3,9-bis(2,4-di Tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 3,9-bis{2,4-dual ( 1-methyl-1-phenylethyl)phenoxy}-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 2,2' -methylenebis(4,6-di-t-butyl-1-phenyl)phosphite, 4,4'-isopropylidenediphenol C12-15 alcohol phosphite, distearyl pentaerythritol II Phosphite, 2,4,8,10-tetrakis(1,1-dimethylethyl)-6-{(2-ethylhexyl)oxy}-12H-dibenzo[d,g][ 1,3,2]dioxaphosphorane, 2,4,8,10-tetrakis(1,1-dimethylethyl)-6-(tridecyloxy)-12H-dibenzo[ d,g][1,3,2]dioxaphosphorane, 1,1'-biphenyl-4,4'-diyl bis[bisphosphoric acid bis(2,4-di-t-butylphenyl) Ester], hydrogenated bisphenol A-pentaerythritol phosphite polymer, hydrogenated bisphenol A phosphite polymer, diethyl phosphite, bis(2-ethylhexyl) phosphite, dilauryl phosphite, Dioleyl phosphite, diphenyl phosphite, etc. . Among them, the phosphite compound contained in the present composition is preferably an aliphatic phosphite (for example, as the phosphite compound of Example 2-2, in consideration of compatibility with the present composition. Tridecyl phosphite or 3,9-bis(decyloxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane, etc. of Example 2-3 ). Further, in view of hydrolysis resistance, an aromatic phosphite (for example, tris(2,4-di-t-butylphenyl) phosphite as the phosphite compound of Example 2-1 is preferable. Wait). Moreover, in consideration of the balance between solubility and hydrolysis resistance, a phosphite having both an aliphatic ester group and an aromatic ester group such as diphenyl phosphite monotridecyl ester is preferable. In the present composition, the content ratio of the phosphite compound is preferably relative to the (meth)acrylic acid from the viewpoint of not impairing the adhesive property and more effectively suppressing the oxidative degradation of the conductive member such as ITO. 100 parts by mass of the (co)polymer is contained in a ratio of 0.0001 (1 × 10 -4 ) parts by mass or more and 2.0 parts by mass or less, and more preferably 0.0005 parts by mass or more or 0.8 parts by mass or less. The ratio of the phosphite compound is more preferably 0.001 parts by mass or more or 0.7 parts by mass or less, and particularly preferably 0.01 parts by mass or more or 0.6 parts by mass or less. Phosphate compound. (Other metal corrosion inhibitor) In the present composition, in addition to the 1,2,3-triazole and phosphite compounds, 1,2,4-triazole, benzotriazole and its derivatives may be used in combination. Other metal corrosion inhibitors. (Crosslinking Agent) The composition may also contain a crosslinking agent as needed. For example, as a method of crosslinking the (meth)acrylic (co)polymer, a reactive group such as a hydroxyl group or a carboxyl group which is introduced into the (meth)acrylic (co)polymer may be added. a chemically bonded crosslinking agent and a method of reacting it by heating or aging; or adding a polyfunctional (meth) acrylate having two or more (meth) acrylonitrile groups as a crosslinking agent and photopolymerization A reaction initiator such as an initiator, which is crosslinked by ultraviolet irradiation or the like. Among them, from the viewpoint of consuming a polar functional group such as a carboxyl group in the composition by the reaction and maintaining a high cohesive force or adhesive property derived from a polar component, it is preferably irradiated with light such as ultraviolet rays. Cross-linking method. Examples of the crosslinking agent include a (meth)acryl fluorenyl group, an epoxy group, an isocyanate group, a carboxyl group, a hydroxyl group, a carbodiimide group, an oxazoline group, an aziridine group, and a vinyl group. a crosslinking agent capable of using at least one crosslinking functional group of an amine group, an imido group, a guanamine group, an N-substituted (meth) acrylamide group, or an alkoxyalkyl group, or one type thereof, or Two or more types may be used in combination. Furthermore, the crosslinkable functional groups can also be protected by a deprotectable protecting group. Among them, a polyfunctional (meth) acrylate is preferred from the viewpoint of easiness of control of the crosslinking reaction. Examples of such a polyfunctional (meth) acrylate include 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, and 1,9- Decanediol di(meth)acrylate, polyalkylene glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate, glycerol di(meth)acrylate, pentaerythritol tris Acrylate, pentaerythritol tetra(meth)acrylate, dipentaerythritol hexa(meth) acrylate, tripentaerythritol penta(meth) acrylate, trimethylolpropane tri(meth) acrylate, isocyanuric acid UV-curable polyfunctional monomer such as tris(propylene methoxyethyl) ester, and polyester (meth) acrylate, epoxy (meth) acrylate, (meth) acrylate urethane Polyfunctional acryl oligomers such as polyether (meth) acrylate or polyfunctional acrylamide. Further, examples of the crosslinking agent having two or more kinds of crosslinkable functional groups include glycidyl (meth)acrylate, glycidyl α-ethyl acrylate, and (meth)acrylic acid-3,4- Epoxy group-containing monomer such as butyl butyl carbonate or 4-hydroxybutyl (meth) acrylate glycidyl ether; 2-isocyanate ethyl (meth) acrylate and 2-(2-(methyl) isocyanate ) acryloxyethoxy)ethyl ester, 2-(0-[1'-methylpropyleneamino]carboxyamino)ethyl (meth)acrylate, 2-[(())(meth)acrylate a monomer containing an isocyanate group or a blocked isocyanate group such as 3,5-dimethylpyrazolyl)carbonylamino]ethyl ester; vinyl trimethoxy decane, vinyl triethoxy decane, 3-glycidyloxy Propyltrimethoxydecane, 3-(methyl)propenyloxypropylmethyldiethoxydecane, 3-(methyl)propenyloxypropyltriethoxydecane, N-2- Various decane coupling agents such as (aminoethyl)-3-aminopropylmethyldimethoxydecane and 3-isocyanatepropyltriethoxydecane. A crosslinking agent having two or more kinds of crosslinkable functional groups may be bonded to a (meth)acrylic (co)polymer by reacting a monofunctional group with a (meth)acrylic (co)polymer. Into the structure. By adopting such a structure, a double bond crosslinkable functional group such as a (meth) acrylonitrile group or a vinyl group can be chemically bonded to a (meth)acrylic (co)polymer. Further, by binding the crosslinking agent to the (meth)acrylic (co)polymer, there is a tendency to suppress the bleeding of the crosslinking agent or the unexpected plasticization of the present adhesive sheet. Further, since the crosslinking agent is bonded to the (meth)acrylic (co)polymer to promote the reaction efficiency of the photocrosslinking reaction, a cured product having a higher cohesive strength tends to be obtained. The composition may further comprise a monofunctional monomer which is reactive with the crosslinkable functional groups of the crosslinking agent. Examples of such a monofunctional monomer include alkyl (meth)acrylate such as methyl acrylate; hydroxyethyl (meth)acrylate; hydroxypropyl (meth)acrylate; and hydroxybutyl (meth)acrylate. a hydroxyl group-containing (meth) acrylate such as an ester or a polyalkylene glycol (meth) acrylate; (meth)acrylic acid, 2-(meth)acryloxyethyl hexahydrophthalic acid, 2 -(Methyl)acryloxypropylhexahydrophthalic acid, 2-(methyl)propenyloxyethylphthalic acid, 2-(methyl)acryloxyethyloxybutylene Diacid, 2-(methyl) propylene methoxy propyl maleate, 2-(methyl) propylene methoxyethyl succinic acid, 2-(methyl) propylene methoxy propyl succinic acid a carboxyl group-containing monomer such as crotonic acid, fumaric acid, maleic acid or itaconic acid; an acid anhydride group-containing monomer such as maleic anhydride or itaconic acid anhydride; tetrahydroanthracene (meth)acrylate Ether-containing (meth) acrylate such as ester, methoxy polyethylene glycol (meth) acrylate; (meth) acrylamide, dimethyl (meth) acrylamide, diethyl (A) Acrylamide, (meth) propylene decylmorpholine, isopropyl (meth) propylene Indoleamine, dimethylaminopropyl (meth) acrylamide, phenyl (meth) acrylamide, N-methoxymethyl (meth) acrylamide, N-butoxymethyl ( A (meth) acrylamide-based monomer such as methyl acrylamide. Among them, from the viewpoint of improving the adhesion to the adherend or the effect of suppressing the wet heat whitening, it is preferred to use a hydroxyl group-containing (meth) acrylate or a (meth) acrylamide monomer. The content of the crosslinking agent is preferably 0.01 or more with respect to 100 parts by mass of the (meth)acrylic (co)polymer, from the viewpoint of the balance between the flexibility and the cohesive force of the composition. In a ratio of 10 parts by mass or less, it is preferably 0.05 parts by mass or more or 8 parts by mass or less, and particularly preferably 0.1 parts by mass or more or 5 parts by mass or less. Further, in the case where the adhesive sheet is a plurality of layers, the content of the crosslinking agent may be more than the above range with respect to the intermediate layer or the layer serving as the substrate in the layer constituting the adhesive sheet. The content of the crosslinking agent in the intermediate layer or the layer to be the substrate is preferably a ratio of 0.01 or more to 40 parts by mass or less based on 100 parts by mass of the (meth)acrylic (co)polymer. In particular, it is preferably 1 part by mass or more or 30 parts by mass or less, and particularly preferably 2 parts by mass or more or 25 parts by mass or less. (Photopolymerization initiator) In the case of crosslinking by light irradiation, it is preferred to contain a photopolymerization initiator. The radical generating mechanism based on the photopolymerization initiator is classified into two types, an α-cleavage type which cleaves and decomposes one's own single bond to generate a radical, and generates a radical by exciting hydrogen from a compound in the system. Dehydrogenation type. Among these, a dehydrogenation type photocrosslinking initiator is preferably used. In the case where an organic crosslinking agent having a (meth)acryl fluorenyl group is used as the crosslinking agent, it is particularly preferred to further add a photopolymerization initiator. The reason is that the radicals are generated by light irradiation to become the starting point of the polymerization reaction in the system. The photopolymerization initiator can be suitably used by those currently known. Among them, from the viewpoint of easiness of control of the crosslinking reaction, a photopolymerization initiator which induces ultraviolet rays having a wavelength of 380 nm or less is preferred. On the other hand, in terms of obtaining a higher photoreactivity and inducing light to easily reach the deep portion of the adhesive sheet, it is preferred to initiate photopolymerization of light having a wavelength longer than 380 nm. Agent. The photopolymerization initiator is classified into two broad categories according to a radical generating mechanism, and is roughly classified into a cleavage type photopolymerization initiator which can cleave and decompose a single bond of a photopolymerization initiator itself to generate a radical, and is activated by light. The starter and the hydrogen donor in the system form a dehydrogenation type photopolymerization initiator which excites the complex and transfers the hydrogen to the hydrogen of the body. The cleavage type photopolymerization initiator in these forms decomposes into a compound upon generation of a radical by light irradiation, and once excited, loses the function as a crosslinking initiator. Therefore, it does not remain in the form of an active species in the adhesive material after the completion of the crosslinking reaction, and it is not preferable to cause an unexpected light deterioration or the like of the adhesive material. On the other hand, when the dehydrogenation type photopolymerization initiator is subjected to a reaction for generating a radical by irradiation with an active energy ray such as ultraviolet rays, a decomposition product such as a cleavage type photopolymerization initiator does not occur, so that it is difficult to become a reaction after completion of the reaction. The volatile component is useful in reducing the damage to the adherend. The cleavage type photopolymerization initiator is preferably bis(2,4,6-trimethylbenzylidene) in terms of high sensitivity to light and decomposition to decomposed after the reaction. -phenylphosphine oxide, 2,4,6-trimethylbenzimidyldiphenylphosphine oxide, (2,4,6-trimethylbenzylidene)ethoxyphenylphosphine oxide, double ( A fluorenylphosphine-based photopolymerization initiator such as 2,6-dimethoxybenzylidene) 2,4,4-trimethylpentylphosphine oxide. Examples of the above-mentioned dehydrogenation type photopolymerization initiator include benzophenone, 4-methyl-benzophenone, 2,4,6-trimethylbenzophenone, and 4-phenyldiphenyl. Methyl ketone, 3,3'-dimethyl-4-methoxybenzophenone, 4-(methyl) propylene decyl benzophenone, 4-[2-((meth) propylene oxime) Ethyl] benzophenone, 4-(methyl)propenyloxy-4'-methoxybenzophenone, methyl 2-benzimidazole, methyl benzhydrazide, Diethylene glycol bis(2-phenyl-2-oxoacetate), 4-(1,3-propenyl fluorenyl-1,4,7,10,13-pentaoxatridecyl) Benzophenone, 9-oxosulfide &#134079; □, 2-chloro-9-oxosulfide &#134079; □, 3-methyl-9-oxosulfide &#134079; □, 2,4-dimethyl -9-oxosulfur &#134079; 蒽醌, 2-methyl hydrazine, 2-ethyl hydrazine, 2-tert-butyl hydrazine, 2-amino hydrazine, camphorquinone or its derivatives Wait. Among these, benzophenone, 4-methyl-benzophenone, 2,4,6-trimethylbenzophenone, 4-phenylbenzophenone, 3,3' are preferred. - dimethyl-4-methoxybenzophenone, 4-(methyl) propylene decyl benzophenone, 4-[2-((methyl) propylene oxy) ethoxy] Benzophenone, 4-(meth)acryloyloxy-4'-methoxybenzophenone, 2-benzylidenebenzoic acid methyl, benzamidinecarboxylic acid methyl. In addition, any one of the above-mentioned photopolymerization initiators or a derivative thereof may be used, or two or more of them may be used in combination. Further, in addition to the photopolymerization initiator, a sensitizer may also be used. The sensitizer is not particularly limited, and any sensitizer used in the photopolymerization initiator can be used without any problem. For example, an aromatic amine or an anthracene derivative, an anthracene derivative, a coumarin derivative, a 9-oxosulfide derivative, a phthalocyanine derivative, or the like, or benzophenone, &#134079; ketone, 9- Oxygen sulfur &#134079; □, octyl ketone, 9,10-phenanthrenequinone and other aromatic ketones and the like. Further, the photopolymerization initiator or the sensitizer may be contained in a state of being bonded to a (meth)acrylic (co)polymer. As a method of bonding a photopolymerization initiator or a sensitizer to a (meth)acrylic (co)polymer, a crosslinking agent may be used to bond the above-mentioned crosslinking agent to a (meth)acrylic (co)polymer. The same method as in the case. The content of the photopolymerization initiator is not particularly limited, and it is particularly preferably adjusted to a ratio of 0.1 or more and 10 parts by mass or less based on 100 parts by mass of the (meth)acrylic (co)polymer. In particular, it is adjusted at a ratio of 0.2 parts by mass or more or 5 parts by mass or less, and more preferably 0.5 parts by mass or more or 3 parts by mass or less. However, it may be outside the range due to the balance with other elements. (Antioxidant) In addition to the above, the present composition may optionally contain an antioxidant. As the antioxidant, for example, 2,2'-methylenebis(4-methyl-6-tert-butylphenol), hexanediol-bis(3,5-di-t-butyl-4-) Hydroxyhydrocinnamate), tetrakis[methylene (3,5-di-t-butyl-4-hydroxyhydrocinnamate)]methane, triethylene glycol-bis-3-(3-tert-butyl 4-hydroxy-5-methylphenyl)propionate, 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxy-benzyl Benzene, n-octadecyl 3-(4'-hydroxy-3',5'-di-t-butylphenol)propionate, 4,4'-methylenebis(2,6-di A hindered phenol-based antioxidant such as tributylphenol) or 4,4'-butylene-bis-(6-t-butyl-3-methyl-phenol), or various antioxidants such as a sulfur-based or an amine-based antioxidant. (Other components) Further, the composition may suitably contain a known component formulated in a usual adhesive composition. For example, a light stabilizer, an ultraviolet absorber, a metal passivator, a rust preventive agent (excluding the above metal corrosion preventive agent), an anti-aging agent, an antistatic agent, a moisture absorbent, a foaming agent, an antifoaming agent, and an inorganic agent may be appropriately contained. Various additives such as particles, viscosity modifiers, adhesion-imparting resins, photosensitizers, and fluorescent agents, or reaction catalysts (tribasic amine compounds, quaternary ammonium compounds, tin laurate compounds, etc.). (Adjustment of Adhesive Composition) The adhesive composition (present composition) used in the present adhesive sheet is obtained by using (meth)acrylic (co)polymer, 1,2,3-triazole and Other components required, such as a phosphite compound, a crosslinking agent, and the like, are each obtained by mixing in a specific amount. The mixing method of these is not particularly limited, and the order of mixing the components is not particularly limited. Further, a heat treatment step may be added in the production of the composition. In this case, it is preferred to heat-treat each component of the composition in advance. It is also possible to use a mixture of various mixed components and to form a masterbatch. Further, the apparatus for mixing is not particularly limited, and for example, a universal kneader, a planetary mixer, a Banbury mixer, a kneader, a frame mixer, a pressure kneader, a three-roll mill, and a two-roll mill can be used. machine. It can also be mixed using a solvent as needed. Further, the present composition can also be used as a solventless system which does not contain a solvent. By using it as a solventless system, it is possible to provide an advantage that heat resistance and light resistance are not increased without leaving a solvent. Further, the present composition can also be used in the following manner: a monomer component comprising a (meth)acrylic (co)polymer, a 1,2,3-triazole, a photopolymerization initiator, and other optional components are prepared in advance. When the composition is used as an adhesive sheet for a conductive member, it is subjected to light irradiation to carry out a polymerization reaction to produce a (meth)acrylic (co)polymer. <Form of Adhesive Sheet for Conductive Member> The adhesive sheet can be formed into a single layer or a release film by applying the composition directly to the adherend and forming it into a sheet shape. A multi-layered sheet-like adhesive sheet with a release film. Examples of the material of the release film include a polyester film, a polyolefin film, a polycarbonate film, a polystyrene film, an acrylic film, a triacetyl cellulose film, and a fluororesin film. Among these, polyester films and polyolefin films are particularly preferred. The thickness of the release film is not particularly limited. In particular, from the viewpoint of workability and workability, it is preferably 25 μm to 500 μm, more preferably 38 μm or more or 250 μm or less, and further preferably 50 μm or more or 200 μm or less. . Further, the present adhesive sheet may be a method in which the composition is directly extruded by using an adherend or a release film as described above or a method of forming by injection into a mold. Further, by directly filling the composition between members such as a conductive member, it is possible to form an adhesive sheet. <Physical Properties of Adhesive Sheet for Conductive Member> (Anticorrosive Effect on Conductive Layer of Conductive Member) The adhesive sheet has corrosion resistance to a conductive member, particularly a transparent conductive layer or a conductor pattern formed of a metal material containing copper. Therefore, the rate of change of the ITO resistance value measured by the following methods (1) to (2) [((Ω/Ω0)-1)×100] can be set to less than 5%, wherein It is less than 3%. Moreover, the rate of change of the copper resistance value measured by the following methods (3) to (4) [((Ω/Ω0)-1)×100] can be set to less than 20%, wherein If it is less than 10%, it can be set to less than 5%, and especially can be set to less than 3%. (1) The conductive member adhesive composition (the present composition) is formed into a sheet having a thickness of 150 μm to form an adhesive sheet, and the adhesive sheet is bonded to an ITO wiring containing indium oxide (ITO). An ITO glass substrate on which an ITO glass substrate for evaluation was formed on a glass substrate was used to produce an ITO wiring with an adhesive sheet. (2) The resistance value (Ω0) at room temperature of the ITO wiring in the ITO wiring of the adhesive sheet is measured in advance, and the ITO wiring of the above-mentioned adhesive sheet is stored for 500 hours in an environment of 65 ° C. and 90% RH. The resistance value (Ω) of the ITO wiring in the ITO wiring of the adhesive sheet was measured. (3) The conductive member adhesive composition (the present composition) is formed into a sheet having a thickness of 150 μm to form an adhesive sheet, and the adhesive sheet is bonded to a copper wiring to be formed on a glass substrate. The copper wiring with the adhesive sheet was produced by the evaluation of the copper glass substrate. (4) The resistance value (Ω0) at room temperature of the copper wiring in the copper wiring of the adhesive sheet is measured in advance, and the copper wiring of the above-mentioned adhesive sheet is stored for 500 hours in an environment of 65 ° C and 90% RH. The resistance value (Ω) after the storage of the copper wiring in the copper wiring of the adhesive sheet was measured. (Transparency) The adhesive sheet is preferably optically transparent. That is, a transparent adhesive sheet is preferred. Here, "optically transparent" means that the total light transmittance is 80% or more, preferably 85% or more, and more preferably 90% or more. (Thickness) The thickness of the adhesive sheet is preferably 10 μm or more and 500 μm or less, and more preferably 15 μm or more or 400 μm or less, and particularly preferably 20 μm or more or 350 μm or less. <Application of Adhesive Sheet for Conductive Member> The adhesive sheet is used in an image display device such as a personal computer, a mobile device terminal (PDA), a game machine, a television (TV), a car navigation system, a touch panel, a tablet, and the like. For example, a plasma display (PDP), a liquid crystal display (LCD), an organic EL display (OLED), an inorganic EL display, an electrophoretic display (EPD), an interference modulation display (IMOD), or the like, which is used in an image display device using an image display panel Suitable for bonding each constituent member, wherein the conductive member, a conductive member having a transparent conductive layer therein and/or a conductor pattern formed of a metal material containing copper. Further, it is also suitable to bond a conductive member including a transparent conductive layer containing ITO or IGZO and/or a transparent conductive layer having a conductor pattern formed of a metal material containing copper or silver. <Conductive member laminated body> The conductive member laminated body of the present invention (hereinafter, also referred to as "the present laminated body" is omitted) can be obtained by bonding the present adhesive sheet to a conductive layer of a conductive member such as a transparent conductive layer. . The laminate may have a configuration in which at least one of the adhesive layers of the adhesive sheet and the conductive layer of the transparent conductive layer are bonded together. In the case where the adhesive sheet is a double-sided adhesive sheet, the laminated body may have a structure in which the two adhesive layers of the adhesive sheet and the conductive layer of the transparent conductive layer are bonded together. The transparent conductive layer may also cover the conductive layer of the conductive film to form an olefin polymer, an urethane polymer, an epoxy polymer, an acrylic polymer, a polyoxyl polymer, or An insulating protective film (passivation film) formed of inorganic glass or the like. In this case, the adhesive sheet does not directly conform to the transparent conductive layer (not directly connected to the transparent conductive layer). Even if the adhesive sheet is impregnated from the component (especially an acid component) of the composition and reaches the transparent conductive layer from the insulating film, the transparent conductive layer can be prevented from being corroded by the action of 1,2,3-triazole. In particular, since the water solubility of 1,2,3-triazole is high, it is easy to move to the transparent conductive layer when the adhesive sheet absorbs moisture in a moist heat environment, so that an excellent metal corrosion preventing effect can be achieved. Thus, according to the present adhesive sheet, the presence or absence of the insulating protective film can not only achieve discoloration or deterioration prevention effect of the adhesive layer caused by the metal ions of the adherend, but also achieve excellent metal corrosion prevention effect against the adherend. . The laminated body obtained by bonding with the conductive layer can be preferably used for a touch panel. Examples of the touch panel include a resistive film method, a capacitive method, and an electromagnetic induction method, and a capacitive method is preferable. The transparent conductive layer may have a conductive layer on at least one surface layer of the single surface, and a transparent conductive layer in which a conductive material is provided on the surface layer equal to the transparent substrate by vapor deposition or sputtering may be used. The conductive material used for the conductive layer of the transparent conductive layer is not particularly limited, specifically, indium oxide, indium-gallium-zinc composite oxide, tin-doped indium oxide (ITO), zinc oxide, gallium oxide, titanium oxide. Other metal oxides include metal materials such as silver, copper, molybdenum, and aluminum. Among them, tin-doped indium oxide (ITO) and indium-gallium-zinc composite oxide (IGZO) excellent in transparency can be preferably used. Further, copper or silver can be preferably used from the viewpoint of excellent electrical conductivity. In the transparent conductive layer, the substrate to be patterned by the conductive material is not particularly limited, and examples thereof include glass and a resin film. Typically, the transparent conductive layer has a conductive layer at least on the surface of the single side. Further, typically, a conductor pattern (wiring pattern) having copper or silver as a main component is formed on the transparent conductive layer so as to be wound around the peripheral portion. 1,2,3-triazole has high corrosion resistance to copper, and thus the present adhesive sheet comprising the same can be particularly preferably used for a conductive member having a conductor pattern formed of a metal material containing copper. Specific examples of the other laminated body include, for example, a release film/this adhesive sheet/touch panel, a release film/this adhesive sheet/protective panel, a release film/this adhesive sheet/image display Panel, image display panel/this adhesive sheet/touch panel, image display panel/this adhesive sheet/protective panel, image display panel/this adhesive sheet/touch panel/this adhesive sheet/protective panel , polarizing film / this adhesive sheet / touch panel, polarizing film / this adhesive sheet / touch panel / this adhesive sheet / protective panel. Further, in the above configuration, all of the conductive layers may be interposed between the adhesive sheet and a member such as a touch panel, a protective panel, an image display panel, and a polarizing film adjacent thereto. However, it is not limited to these laminated examples. Furthermore, the touch panel further includes a structure in which the touch panel function is built in the protection panel or a structure in which the touch panel function is built in the image display panel. <Image Display Device> The image display device of the present invention (hereinafter, also referred to as "the present device" is omitted) has at least the laminated body, the image display panel, and the surface protective panel as constituent members. More specifically, an image display device in which the present adhesive sheet is bonded to the conductive layer of the transparent conductive layer and the laminated body is inserted between the image display panel and the surface protective panel can be cited. At this time, the adhesive sheet is also used on the image display panel side. The material of the surface protective panel may be an alicyclic polyolefin resin such as an acrylic resin, a polycarbonate resin or a cycloolefin polymer, a styrene resin, a polyvinyl chloride resin, or a phenol system. Plastics such as resins, melamine resins, and epoxy resins. The image display panel is composed of another optical film such as a retardation film other than the polarizing film, a liquid crystal material, and a backlight source system (generally, the composition or the adhesive article is an optical film on the surface of the image display panel), The STN (Super Twisted Nematic) method, the VA (Vertical Aligned) method, or the IPS (In-Plane Switching) method may be used in any manner. The image display device can constitute, for example, an image display device such as a liquid crystal display, an organic EL display, an inorganic EL display, an electronic paper, a plasma display, or a microelectromechanical system (MEMS) display. <Description of Statements> In the present specification, when it is expressed as "X to Y" (where X and Y are arbitrary numbers), the meaning of "X or more and Y or less" is included unless otherwise specified. "It is better to be greater than X" or "preferably less than Y". In the case of "X or above" (X is an arbitrary number) or "Y below" (Y is an arbitrary number), "preferably greater than X" or "preferably not Y" is included. intention. In general, the term "sheet" as used in the definition of JIS refers to a product which is relatively thin and whose thickness is less than the length and width. Generally speaking, the so-called "film" is related to the length and width. A thinner and flat article which is extremely small in thickness and whose maximum thickness is arbitrarily defined is generally referred to as a roll shape supplier (Japanese Industrial Standard JIS K6900). However, the boundary between the sheet and the film is not determined. In the present invention, it is not necessary to distinguish between the two in terms of language. Therefore, in the present invention, the term "film" is also included in the case of "film". "film" is also included in the case of "sheet". [Examples] Hereinafter, the examples and comparative examples will be described in detail. However, the invention is not limited to the embodiments. <(Meth)acrylic (co)polymer> The following (meth)acrylic (co)polymer is used.・A-1: a copolymer containing 76 parts by mass of 2-ethylhexyl acrylate, 20 parts by mass of vinyl acetate, and 4 parts by mass of acrylic acid (mass average molecular weight: 400,000) ・A-2: 81 parts by mass of butyl acrylate Copolymer of 15 parts by mass of methyl methacrylate and 4 parts by mass of acrylic acid (mass average molecular weight: 200,000) <Example 1> [Example 1-1] To (meth)acrylic (co)polymer (A) -1) Add 1 g of 1,2,3-triazole (manufactured by Otsuka Chemical Co., Ltd.) to 3 kg as a metal corrosion inhibitor, and 4-methylbenzophenone and 2,4,6-trimethyldiphenyl 15 g of a mixture of ketone (manufactured by Lamberti Co., Ltd., trade name "Esacure TZT") was used as a photopolymerization initiator and uniformly mixed to obtain a resin composition for an adhesive layer. The resin composition for an adhesive layer was sandwiched between two polyethylene terephthalate films (manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL MRV", thickness 100 μm and manufactured by Mitsubishi Plastics Co., Ltd., trade name" DIAFOIL MRQ", with a thickness of 75 μm), was formed into a sheet shape so that the thickness of the adhesive sheet became 150 μm, and an adhesive sheet laminate was produced. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 1. [Example 1-2] To 1 kg of the (meth)acrylic (co)polymer (A-2), 3 g of 1,2,3-triazole as a metal corrosion preventing agent was added as a crosslinking agent. UV curable resin propenylpentoxide triacrylate (Xin Nakamura Industrial Co., Ltd., trade name "ATM-4PL") 20 g, 4-methylbenzophenone as a photopolymerization initiator and 2,4,6- A mixture of trimethylbenzophenone (manufactured by Lamberti Co., Ltd., trade name "Esacure TZT") 15 g was uniformly mixed to obtain a resin composition for an adhesive layer. Then, the resin composition for an adhesive layer was applied to a polyethylene terephthalate film (manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL MRV", thickness: 100 μm) having a thickness of 150 μm. After forming into a sheet shape, the polyethylene terephthalate film (manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL MRQ", thickness: 75 μm) was subjected to release treatment to prepare an adhesive sheet laminate. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 1. [Example 1-3] An adhesive sheet laminate was produced in the same manner as in Example 1-2 except that 5 g of 1,2,3-triazole as a metal corrosion preventing agent was used. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 1. [Comparative Example 1-1] An adhesive sheet laminate was produced in the same manner as in Example 1-1 except that 1,2,3-triazole as a metal corrosion inhibitor was not added. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 1. [Comparative Example 1-2] 5 g of benzotriazole (manufactured by Seongbuk Chemical Co., Ltd., trade name "BT120") was used instead of 1,2,3-triazole as a metal corrosion inhibitor, and Example 1 was used. The adhesive sheet laminate was produced in the same manner as in -1. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 1. [Comparative Example 1-3] Toluene triazole (a mixture of 4-methylbenzotriazole and 5-methylbenzotriazole) (manufactured by Shipro Kasei Co., Ltd., trade name "SEETEC TT-R") 5 g was used. An adhesive sheet laminate was produced in the same manner as in Example 1-1, except that 1,2,3-triazole was used as the metal corrosion inhibitor. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 1. [Comparative Example 1-4] Using 2,5-dimercapto-1,3,4-thiadiazole (trade name "MTD" manufactured by TOYOBO Co., Ltd.) 5 g instead of 1,2,3-triazole as metal corrosion prevention An adhesive sheet laminate was produced in the same manner as in Example 1-1 except for the above. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 1. <Various evaluations> (1) Corrosion-resistant reliability is formed on a glass substrate (60 mm × 45 mm) with a line width of 70 μm, a line length of 46 mm, a line spacing of 30 μm, and a round trip of 10.5 times to a thickness of 1300 Å. A copper film of ITO and a thickness of 3000 Å is sequentially laminated to form a metal film, and a square of 2 mm square is formed at both ends of the round line to form a copper pattern (about 97 cm in length) to produce corrosion resistance reliability. A copper glass substrate for evaluation (see Fig. 1 (A)). The release film of the adhesive sheet laminate (adhesive sheet thickness 150 μm) produced in the above Examples and Comparative Examples was peeled off, and a polyethylene terephthalate (PET) film was applied by a hand roller ( Manufactured by Toyobo Co., Ltd., the product name "COSMOSHINE A4100", 125 μm) is attached to the exposed surface. Then, after the adhesive sheet with the PET film described above was cut into 52 mm × 45 mm, the remaining release film was peeled off, and as shown in Fig. 1 (B), the metal film was covered by a hand on the line. The adhesive sheet was attached to the copper glass substrate for corrosion resistance evaluation, and further, the integrated light amount at the wavelength of 365 nm of Example 1-1 and Comparative Examples 1-1 to 1-4 was formed through the PET film. 3,000 mJ/cm 2 , and the cumulative light amount at a wavelength of 365 nm of Examples 1-2 and 1-3 was 2000 mJ/cm 2 , and ultraviolet rays were irradiated by a high-pressure mercury lamp to cause ultraviolet crosslinking, thereby producing corrosion resistance reliability evaluation. Sample (copper wiring with adhesive sheet attached) (refer to Figure 1 (D)). The resistance value (Ω0) at room temperature of the copper wiring in the sample for corrosion resistance reliability evaluation (copper wiring with an adhesive sheet) was measured in advance. On the other hand, the sample for corrosion resistance reliability evaluation (copper wiring with adhesive sheet) was stored in an environment of 65° C. and 90% RH for 500 hours, and the sample for corrosion resistance evaluation was measured after storage (adhesive sheet was attached). The resistance value (Ω) of the copper wiring in the copper wiring). Then, the copper resistance value, that is, the rate of change (%) of the resistance value between the end of the line [((Ω/Ω0)-1) × 100]) is shown, and is shown in Table 1 as "change in resistance value". Regarding the corrosion resistance reliability, it is judged as "×(poor)" when the rate of change of the resistance value is 20% or more, and "○ (good)" when it is less than 20%. The results are shown in Table 1. (2) Foaming Resistance The peeling film of one side of the adhesive sheet laminate (thickness: 150 μm) produced in the examples and the comparative examples was peeled off, and bonded to a soda lime glass plate by a hand roller (150×200). Mm, thickness 0.55 mm). Further, the remaining release film was peeled off, and the chemically strengthened glass plate (180 × 220 mm, thickness 0.6 mm) was aligned and bonded by a hand roller. Then, the laminate was subjected to autoclave treatment at 60 ° C and 0.2 MPa for 20 minutes. The metal halide lamp irradiation device (manufactured by Oxtail Electric Co., Ltd., model UVC-0516S1, LAMP UVL-8001M3-N) was used to adjust the conveyor belt in such a manner that the irradiation amount at a wavelength of 365 nm became 3000 mJ/cm 2 per irradiation. The speed and irradiance were observed after 15 times of irradiation on the sample. Regarding the foaming reliability, when the appearance is observed, it is judged as "○ (good)" in the case where there is no change before the ultraviolet irradiation, and "× (poor)" is determined in the bubble generation. The results are shown in Table 1. (3) Ultraviolet curing property (Storage elastic modulus G' before ultraviolet curing) The storage elastic modulus before ultraviolet curing is obtained by: making the adhesive sheet produced in the examples and the comparative examples into 1 In the case of a thickness of ～2 mm, a laminate of 20 mm in diameter was used as a measurement sample, and a rheometer ("MARS" manufactured by Hidehiro Seiki Co., Ltd.) was used to adhere the jig: Φ25 mm parallel plate, strain: 0.5%, frequency: 1 Hz, temperature: -50 to 200 ° C, heating rate: 3 ° C / min, the dynamic storage elastic modulus G' at -50 ° C to 200 ° C is measured, and read Storage elastic modulus values at 125 °C. The results are shown in Table 1. (Storage elastic modulus G' after ultraviolet curing) The storage elastic modulus after ultraviolet curing was measured as follows. The adhesive sheets produced in the examples and the comparative examples were irradiated with ultraviolet rays by a high pressure mercury lamp through a PET film to be subjected to ultraviolet crosslinking. At this time, in Example 1-1 and Comparative Examples 1-1 to 1-4, the integrated light amount at a wavelength of 365 nm was irradiated at 3000 mJ/cm 2 , and Examples 1-2 and 1-3 were used. Irradiation was carried out so that the amount of laminated light became 2000 mJ/cm 2 . The adhesive sheet which was subjected to the ultraviolet crosslinking as described above was laminated to a thickness of 1 to 2 mm and punched into a circular shape having a diameter of 20 mm as a measurement sample. Using a rheometer (manufactured by Yinghong Seiki Co., Ltd., trade name "MARS") to adhere the jig: Φ25 mm parallel plate, strain: 0.5%, frequency: 1 Hz, temperature: -50 to 200 ° C, heating rate: 3 The dynamic storage elastic modulus G' of the measurement sample at -50 ° C to 200 ° C was measured at ° C / min, and the stored elastic modulus value at 125 ° C was read, thereby determining the storage elastic modulus after ultraviolet curing. The results are shown in Table 1. Regarding the ultraviolet curing property, the storage elastic modulus G' before the ultraviolet curing is compared with the storage elastic modulus G' after the ultraviolet curing, and the value after the hardening is significantly increased is judged as "○ (good)", and the value is hardly changed. It is judged as "×(poor)". The results are shown in Table 1. [Table 1] (Evaluation Results) The adhesive sheets of Examples 1-1 to 1-3 contained 1,2,3-triazole as a metal corrosion preventing agent, whereby the resistance value of the copper wiring was less changed, and corrosion resistance reliability was obtained. Excellent. Moreover, the foaming reliability and the ultraviolet curing property are also good. On the other hand, Comparative Example 1-1 did not contain a metal corrosion inhibitor, and corrosion resistance was poor. Although Comparative Example 1-2 contains benzotriazole as a metal corrosion preventing agent, the foaming reliability is inferior due to the characteristics of benzotriazole. In Comparative Example 1-3, toluene triazole was used as the metal corrosion preventing agent, but the foaming reliability was inferior due to the characteristics of tolyltriazole. Although Comparative Example 1-4 contains dimercaptothiadiazole as a metal corrosion preventing agent, since the dimercaptothiadiazole absorbs ultraviolet rays, the ultraviolet curing property of the adhesive sheet is inferior. According to the above results, since 1,2,3-triazole has a melting point of about 20 ° C and is almost liquid at normal temperature, it is easily added to the adhesive main component in the actual manufacturing step of the adhesive sheet, and The dispersibility to the adhesive main agent is also excellent. Further, it is also clear that 1,2,3-triazole is highly water-soluble, and when the adhesive sheet absorbs moisture in a hot and humid environment, it easily moves to the surface of the metal layer (copper wiring), thereby exhibiting excellent metal corrosion prevention. effect. Further, it is also clear that 1,2,3-triazole does not hinder UV (Ultraviolet) hardening characteristics because it does not absorb at a spectrophotometer of a wavelength of 300 to 400 nm. As described above, it has been found that 1,2,3-triazole has excellent characteristics as compared with the prior metal corrosion inhibitor, and is particularly effective for an adhesive sheet for a conductive member. <Example 2> [Example 2-1] To a 1 kg of a (meth)acrylic (co)polymer (A-1), a pentaerythritol polyacrylate (manufactured by Shin-Nakamura Chemical Co., Ltd., trade name "ATM-4PL") 200 g as a crosslinking agent, and a mixture of 4-methylbenzophenone and 2,4,6-trimethylbenzophenone (manufactured by Lamberti Co., Ltd., trade name "Esacure TZT") 10 g was used as a photopolymerization initiator and uniformly mixed to obtain a resin composition for an intermediate layer. The intermediate layer resin composition was sandwiched between two polyethylene terephthalate films (manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL MRF", thickness 75 μm and manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL". The MRT was formed between sheets having a thickness of 38 μm and formed into a sheet shape so that the thickness of the adhesive sheet was 80 μm, and a resin sheet (α) for the intermediate layer was produced. 1.5 g of 1,2,3-triazole was added to 1 kg of (meth)acrylic (co)polymer (A-1) as a metal corrosion inhibitor, and tris(2,4-di-t-butyl phosphite) Phenyl) ester (manufactured by BASF Corporation, trade name "Irgafos 168") 5 g as a phosphite compound, and a mixture of 4-methylbenzophenone and 2,4,6-trimethylbenzophenone ( 15 g, manufactured by Lamberti Co., Ltd., trade name "Esacure TZT", was used as a photopolymerization initiator and uniformly mixed to obtain a resin composition for an adhesive layer. The resin composition for an adhesive layer was sandwiched between two polyethylene terephthalate films (manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL MRV", thickness 100 μm, and manufactured by Mitsubishi Plastics Co., Ltd., trade name. DIAFOIL MRT, a thickness of 38 μm, was formed into a sheet shape so that the thickness of the adhesive sheet was 35 μm, and a resin sheet (β) for an adhesive layer was produced. Further, the resin composition for an adhesive layer was sandwiched between two polyethylene terephthalate films (manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL MRQ", thickness: 75 μm, and manufactured by Mitsubishi Plastics Co., Ltd.). The product name "DIAFOIL MRT" (thickness: 38 μm) was formed into a sheet shape so that the thickness of the adhesive sheet was 35 μm, and a resin sheet (β') for the adhesive layer was produced. The PET film on both sides of the intermediate layer sheet (α) is peeled off in order, and the PET film on one side of the resin sheet (β) and (β') is peeled off from the adhesive layer to adhere the exposed film. The surface was bonded to both surfaces of the intermediate layer sheet (β) in order to produce a laminate including (β)/(α)/(β'). By a PET film remaining on the surfaces of the above (β) and (β'), ultraviolet rays were irradiated by a high-pressure mercury lamp so that the integrated light amount at a wavelength of 365 nm became 2000 mJ/cm 2 , so that (α), (β), and '') UV cross-linking to form an adhesive sheet laminate (thickness 150 μm). The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 2. [Example 2-2] 3 g of 1,2,3-triazole was added to 1 kg of (meth)acrylic (co)polymer (A-2) as a metal corrosion inhibitor, tridecyl phosphite ( 3 g of a phosphite compound, pentaerythritol tri- and tetraacrylate (manufactured by Toagosei Co., Ltd., "ARONIXM-306") 20 g as a crosslinking agent, and a 1-hydroxy-ring, manufactured by ADEKA Co., Ltd., trade name "Adekastab 3010" 10 g of hexyl phenyl ketone (manufactured by BASF Corporation, Irgacure 184) was used as a photopolymerization initiator and uniformly mixed to obtain a resin composition for an adhesive layer. Then, the resin composition for an adhesive layer was formed into a sheet shape so as to have a thickness of 150 μm on a release-treated polyethylene terephthalate film (manufactured by Mitsubishi Plastics Co., Ltd., DIAFOIL MRV, thickness: 100 μm). Thereafter, a polyethylene terephthalate film (manufactured by Mitsubishi Plastics Co., Ltd., trade name "DIAFOIL MRQ", thickness: 75 μm) was subjected to release treatment. The polyethylene terephthalate film which was subjected to the release treatment was irradiated with ultraviolet rays by a high-pressure mercury lamp so that the cumulative light amount at a wavelength of 365 nm became 1000 mJ/cm 2 , and the resin composition for the adhesive layer was subjected to ultraviolet crosslinking to prepare Adhesive sheet laminate. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 2. [Example 2-3] Using 3,9-bis(decyloxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane (manufactured by Chengbei Chemical Co., Ltd.) An adhesive sheet laminate was produced in the same manner as in Example 2-2 except that 3 g of the phosphite compound was used as the phosphite compound. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 2. [Comparative Example 2-1] 1,2,3-triazole as a metal corrosion preventing agent and tris(2,4-di-t-butylphenyl) phosphite as a phosphite compound (BASF Corporation) An adhesive sheet laminate was produced in the same manner as in Example 2-1 except that the product name "Irgafos 168" was produced. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 2. [Comparative Example 2-2] An adhesive sheet laminate was produced in the same manner as in Example 2-1 except that 1,2,3-triazole as a metal corrosion preventing agent was not added. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 2. [Comparative Example 2-3] 1.5 g of benzotriazole (manufactured by Seongbuk Chemical Co., Ltd., trade name "BT120") was added instead of 1,2,3-triazole as a metal corrosion inhibitor, and no phosphite compound was added. Otherwise, an adhesive sheet laminate was produced in the same manner as in Example 2-1. The following various evaluations were performed on the adhesive sheet laminate. The results are shown in Table 2. <Various evaluations> (1) Anti-oxidation deterioration on a glass substrate (60 mm × 45 mm) with a thickness of 150 to 200 Å, a line width of 70 μm, a line length of 46 mm, a line spacing of 30 μm, and a round trip of 10.5 times A bismuth line of indium oxide (ITO) was formed, and a square of 2 mm square of ITO was formed at both ends of the round-trip line to form an ITO pattern (about 97 cm in length), and an ITO glass substrate for evaluation of oxidation deterioration resistance was prepared (see Figure 1 (A)). The release film of the adhesive sheet laminate (thickness 150 μm) produced in the above examples and comparative examples was peeled off, and the PET film (manufactured by Toyobo Co., Ltd., trade name "COSMOSHINE A4100") was peeled off by a hand roller. 125 μm) attached to its exposed surface. Then, after the adhesive sheet with the PET film was cut into 52 mm × 45 mm, the remaining release film was peeled off, as shown in Fig. 1 (B), and the hand roller was used to cover the ITO on the return line. The adhesive sheet was attached to an ITO glass substrate for evaluation of oxidation deterioration resistance, and a sample for evaluation of oxidation deterioration resistance (ITO wiring with an adhesive sheet) was prepared (see FIG. 1(C)). The resistance value (Ω0) at room temperature of the ITO wiring in the sample for evaluation of oxidation resistance deterioration (ITO wiring with an adhesive sheet) was measured in advance. On the other hand, the sample for evaluation of oxidation and deterioration resistance (ITO wiring with an adhesive sheet) was stored in an environment of 65° C. and 90% RH for 500 hours, and after storage, a sample for evaluation of oxidation and deterioration resistance was measured (attached) The resistance value (Ω) of the ITO wiring in the ITO wiring of the sheet. Further, the ITO resistance value, that is, the rate of change (%) of the resistance value between the end of the line [((Ω/Ω0)-1) × 100]) is shown, and is shown in Table 2 as "change in resistance value". Regarding the oxidation degrading resistance, it is judged as "×(poor)" when the rate of change of the resistance value is 5% or more, and "○ (good)" is determined as less than 5%. The results are shown in Table 2. (2) Corrosion resistance The ITO with a thickness of 1300 Å and a thickness of 3000 are formed on a glass substrate (60 mm × 45 mm) with a line width of 70 μm, a line length of 46 mm, a line spacing of 30 μm and a round trip of 10.5 times. The copper film of Å is sequentially laminated to form a metal film, and a square of 2 mm square is formed at both ends of the round line to form a copper pattern (about 97 cm in length), and copper glass for corrosion resistance evaluation is produced. Substrate (see Fig. 1(A)). The release film of the adhesive sheet laminate (thickness 150 μm) produced in the above examples and comparative examples was peeled off, and the PET film (manufactured by Toyobo Co., Ltd., trade name "COSMOSHINE A4100") was peeled off by a hand roller. 125 μm) attached to its exposed surface. Then, after the adhesive sheet with the PET film was cut into 52 mm × 45 mm, the remaining release film was peeled off, and as shown in Fig. 1 (B), the hand roll was used to cover the metal film on the return line. The adhesive sheet was attached to a copper glass substrate for corrosion resistance evaluation, and a sample for corrosion resistance evaluation (copper wiring with an adhesive sheet) was produced (see FIG. 1(D)). The resistance value (Ω0) at room temperature of the copper wiring in the sample for corrosion resistance reliability evaluation (copper wiring with an adhesive sheet) was measured in advance. On the other hand, the sample for corrosion resistance reliability evaluation (copper wiring with an adhesive sheet) was stored in an environment of 65° C. and 90% RH for 500 hours, and after storage, a sample for evaluation of corrosion resistance reliability (adhesive sheet) was measured. The resistance value (Ω) of the copper wiring in the copper wiring of the material. Then, the copper resistance value, that is, the rate of change (%) of the resistance value between the end of the line [((Ω/Ω0)-1) × 100]) is shown, and is shown in Table 2 as "change in resistance value". Regarding the corrosion resistance reliability, it is judged as "×(poor)" when the rate of change of the resistance value is 20% or more, and "○ (good)" is determined as less than 20%. The results are shown in Table 2. [Table 2] (Evaluation Results) The adhesive sheets of Examples 2-1 to 2-3 contain 1,2,3-triazole as a metal corrosion preventing agent, and further contain a phosphite, whereby the ITO wiring and the copper wiring are resistance values. It is less changeable and has excellent corrosion resistance reliability and oxidation deterioration resistance. On the other hand, Comparative Example 2-1 did not contain a phosphite compound and a metal corrosion inhibitor, and was inferior in corrosion resistance reliability and oxidation deterioration resistance. In Comparative Example 2-2, since the metal corrosion preventing agent was not contained, the corrosion of the copper wiring was particularly remarkable. Comparative Example 2-3 did not contain a phosphite compound, but was inferior in oxidation resistance deterioration to the ITO wiring. [Industrial Applicability] The adhesive sheet for a conductive member of the present invention may have a conductive member (typically, a conductive member having a transparent conductive layer and/or a conductor pattern formed of a metal material containing copper or silver) It is corrosion-resistant and has foaming resistance, so it can be used as an adhesive sheet suitable for bonding various conductive members. In particular, it can be preferably used as an adhesive sheet for an image display device having a touch panel.

圖1係用以於下述實施例中對耐腐蝕可靠性之評價試驗方法進行說明之圖，(A)係防氧化劣化性評價用ITO玻璃基板之ITO圖案之俯視圖或耐腐蝕可靠性評價用銅玻璃基板之銅圖案之俯視圖，(B)係表示於防氧化劣化性評價用ITO玻璃基板上被覆有黏著片材之狀態之俯視圖或表示於耐腐蝕可靠性評價用銅玻璃基板上被覆有黏著片材之狀態之俯視圖，(C)係防氧化劣化性評價用樣品之剖視圖，(D)係耐腐蝕可靠性評價用樣品之剖視圖。Fig. 1 is a view for explaining a test method for evaluating corrosion resistance reliability in the following examples, and (A) is a plan view of an ITO pattern for oxidizing and deteriorating evaluation of an ITO glass substrate, or a corrosion resistance reliability evaluation. (B) is a plan view showing a state in which an adhesive sheet is coated on an ITO glass substrate for evaluation of oxidation resistance deterioration, or a coating on a copper glass substrate for evaluation of corrosion resistance reliability. (C) is a cross-sectional view of a sample for evaluation of oxidation resistance deterioration, and (D) is a cross-sectional view of a sample for evaluation of corrosion resistance reliability.

Claims (13)

一種導電構件用黏著片材，其包含黏著劑層，該黏著劑層包含含有(甲基)丙烯酸系共聚物及1,2,3-***之黏著劑組合物。An adhesive sheet for a conductive member, comprising an adhesive layer comprising an adhesive composition containing a (meth)acrylic copolymer and 1,2,3-triazole. 如請求項1之導電構件用黏著片材，其中上述黏著劑組合物含有亞磷酸酯化合物。An adhesive sheet for a conductive member according to claim 1, wherein the above adhesive composition contains a phosphite compound. 如請求項1或2之導電構件用黏著片材，其中上述亞磷酸酯化合物包含選自脂肪族亞磷酸酯、芳香族亞磷酸酯以及具有脂肪族酯基及芳香族酯基之亞磷酸酯之任一種以上。The adhesive sheet for a conductive member according to claim 1 or 2, wherein the phosphite compound comprises an phosphite selected from the group consisting of an aliphatic phosphite, an aromatic phosphite, and a phosphite having an aliphatic ester group and an aromatic ester group. Any one or more. 如請求項1至3中任一項之導電構件用黏著片材，其中上述(甲基)丙烯酸系共聚物包含含羧基單體作為結構單元。The adhesive sheet for a conductive member according to any one of claims 1 to 3, wherein the (meth)acrylic copolymer contains a carboxyl group-containing monomer as a structural unit. 如請求項4之導電構件用黏著片材，其中上述(甲基)丙烯酸系共聚物含有1.2～15質量%之含羧基單體。The adhesive sheet for a conductive member according to claim 4, wherein the (meth)acrylic copolymer contains 1.2 to 15% by mass of a carboxyl group-containing monomer. 如請求項1至5中任一項之導電構件用黏著片材，其中上述黏著劑組合物係具有光硬化性之組合物。The adhesive sheet for a conductive member according to any one of claims 1 to 5, wherein the above-mentioned adhesive composition is a photocurable composition. 如請求項1至6中任一項之導電構件用黏著片材，其中上述黏著劑組合物包含交聯劑。The adhesive sheet for a conductive member according to any one of claims 1 to 6, wherein the above-mentioned adhesive composition contains a crosslinking agent. 如請求項1至7中任一項之導電構件用黏著片材，其中上述導電構件具有透明導電層。The adhesive sheet for a conductive member according to any one of claims 1 to 7, wherein the conductive member has a transparent conductive layer. 如請求項8之導電構件用黏著片材，其中上述透明導電層具有絕緣保護膜。An adhesive sheet for a conductive member according to claim 8, wherein the transparent conductive layer has an insulating protective film. 如請求項1至9中任一項之導電構件用黏著片材，其中上述導電構件具有包含摻錫之氧化銦之透明導電層及/或由包含銅之金屬材料形成之導體圖案。The adhesive sheet for a conductive member according to any one of claims 1 to 9, wherein the conductive member has a transparent conductive layer containing tin-doped indium oxide and/or a conductor pattern formed of a metal material containing copper. 一種導電構件積層體，其具有將如請求項1至10中任一項之導電構件用黏著片材與導電構件貼合而成之構成。A conductive member laminate having a structure in which an adhesive sheet for a conductive member according to any one of claims 1 to 10 is bonded to a conductive member. 一種圖像顯示裝置，其包含如請求項11之導電構件積層體、圖像顯示面板及表面保護面板作為構成構件。An image display device comprising a conductive member laminate as claimed in claim 11 , an image display panel, and a surface protective panel as constituent members. 一種導電構件用黏著劑組合物，其含有(甲基)丙烯酸系共聚物及1,2,3-***。An adhesive composition for a conductive member comprising a (meth)acrylic copolymer and 1,2,3-triazole.
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