TW201722399A - Oil-based cosmetic - Google Patents
Oil-based cosmetic Download PDFInfo
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- TW201722399A TW201722399A TW105138602A TW105138602A TW201722399A TW 201722399 A TW201722399 A TW 201722399A TW 105138602 A TW105138602 A TW 105138602A TW 105138602 A TW105138602 A TW 105138602A TW 201722399 A TW201722399 A TW 201722399A
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- component
- mass
- oily cosmetic
- group
- cosmetic according
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 122
- 229920002678 cellulose Polymers 0.000 claims abstract description 48
- 239000001913 cellulose Substances 0.000 claims abstract description 47
- 239000003921 oil Substances 0.000 claims abstract description 30
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 29
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 24
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 23
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 21
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 16
- 239000010696 ester oil Substances 0.000 claims abstract description 16
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 6
- -1 ricinoleate Dodecyl ester Chemical class 0.000 claims description 47
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- QGFAZZMPXMVNQY-UHFFFAOYSA-N 16-methylheptadecanoic acid;tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O QGFAZZMPXMVNQY-UHFFFAOYSA-N 0.000 claims description 2
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
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Abstract
Description
本發明係關於油性化妝料。 The present invention relates to oily cosmetics.
為能獲得漂亮定妝結果及滑順觸感，就口紅等油性化妝料進行有各種研究。例如專利文獻1所記載：由特定醯化纖維素衍生物、酯油及烴油依特定比例組合的油性化妝料，係持續滑順的觸感。又，專利文獻2所記載：含有特定醯化纖維素衍生物、聚矽氧油劑及酯油的油性化妝料，透明感與光澤均優異、且持續滑順的觸感，專利文獻3所記載：含有特定醯化纖維素衍生物、及具非離子性親水基之聚矽氧的油性化妝料，漂亮定妝結果的持續性優異、且持續滑順的觸感。 In order to obtain beautiful makeup results and smooth touch, there are various studies on oily cosmetics such as lipstick. For example, Patent Document 1 discloses that an oily cosmetic which is combined in a specific ratio by a specific deuterated cellulose derivative, an ester oil, and a hydrocarbon oil is a tactile sensation that continues to be smooth. Further, Patent Document 2 discloses that an oil-based cosmetic containing a specific deuterated cellulose derivative, a polyoxosulfuric acid agent, and an ester oil is excellent in both transparency and gloss, and has a smooth touch feeling, and is described in Patent Document 3. An oily cosmetic containing a specific deuterated cellulose derivative and a polyoxyl group having a nonionic hydrophilic group, which is excellent in the durability of a beautiful makeup result and has a smooth and smooth touch.
(專利文獻1)日本專利特開2010-100612號公報 (Patent Document 1) Japanese Patent Laid-Open Publication No. 2010-100612
(專利文獻2)日本專利特開2011-79746號公報 (Patent Document 2) Japanese Patent Laid-Open Publication No. 2011-79746
(專利文獻3)日本專利特開2011-173818號公報 (Patent Document 3) Japanese Patent Laid-Open Publication No. 2011-173818
本發明相關的油性化妝料，係含有下述成分(A)、(B)及(C)： (A)主鏈具有纖維素骨架，總羥基之45~95mol%被-O-M-R基(M係表示CH2或羰基C=O；R係表示碳數3~40之直鏈或分支鏈烷基或烯基)取代的纖維素衍生物1~50質量%；(B)揮發性烴油5~80質量%；(C)25℃下呈液狀之酯油5~50質量%；成分(B)相對於成分(C)的質量比例(B)/(C)係0.7~9，且於25℃下剪切速度為0.1s-1時，塊材整體的剪切黏度在1500Pa．s以下。 The oily cosmetic according to the present invention contains the following components (A), (B) and (C): (A) the main chain has a cellulose skeleton, and 45 to 95 mol% of the total hydroxyl groups are represented by the -OMR group (M system) CH 2 or carbonyl C=O; R represents 1 to 50% by mass of a substituted linear or branched alkyl or alkenyl group; (B) Volatile hydrocarbon oil 5 to 80 % by mass; (C) 5 to 50% by mass of liquid ester oil at 25 ° C; mass ratio of component (B) to component (C) (B) / (C) is 0.7 to 9, and at 25 ° C When the lower shear rate is 0.1s -1 , the overall shear viscosity of the block is 1500Pa. s below.
含有醯化纖維素衍生物的油性化妝料雖滑順的觸感優異，但就移染、保色而言尚有潛在問題。 An oily cosmetic containing a deuterated cellulose derivative is excellent in smooth touch, but has potential problems in terms of transfer dyeing and color retention.
本發明者等發現若將特定醯化纖維素衍生物、揮發性烴油及酯油，依特定比例組合使用，便可獲得滑順觸感優異、且抑制移染、並改善保色的油性化妝料。 The inventors of the present invention have found that when a specific deuterated cellulose derivative, a volatile hydrocarbon oil, and an ester oil are used in combination in a specific ratio, an oily makeup which is excellent in smooth touch and inhibits transfer and improves color retention can be obtained. material.
本發明的油性化妝料在塗佈時不會感受到粗硬、刺痛感等，且嘴唇、皮膚等具滑順，即便於剛塗佈後及經長時間後，仍抑制在杯子等之上之二次附著，抗沾水濕潤亦強。又，從嘴唇、皮膚等之上卸除化妝料時，可乾淨地完全卸除。 The oily cosmetic of the present invention does not feel rough, tingling, and the like at the time of application, and the lips, the skin, and the like are smooth, and are suppressed on the cup or the like even after the application and after a long period of time. The second adhesion, the wet resistance is also strong. Moreover, when the cosmetic is removed from the lips, the skin, etc., it can be completely removed cleanly.
本發明所使用成分(A)的纖維素衍生物，係在主鏈具有纖維素 骨架之前提下，其餘並無限定，作為原料纖維素衍生物係除纖維素之外，較佳係尚可例如：醋酸纖維素、醋酸丁酸纖維素等短鏈醯化纖維素；甲基纖維素、乙基纖維素等短鏈烷基醚化纖維素；經羥烷基、甘油醚基、(單)烷基甘油醚基改質的纖維素。更具體係可舉例如：羥乙基纖維素、羥丙基纖維素、羥丙基甲基纖維素、甘油纖維素、甲基甘油纖維素等。 The cellulose derivative of the component (A) used in the present invention has cellulose in the main chain The skeleton is not mentioned before, and the rest is not limited. As the raw material cellulose derivative, in addition to cellulose, it is preferred to use, for example, short-chain deuterated cellulose such as cellulose acetate or cellulose acetate butyrate; methyl fiber. a short-chain alkyletherified cellulose such as a cellulose or an ethyl cellulose; a cellulose modified with a hydroxyalkyl group, a glyceryl ether group, or a (mono)alkyl glyceryl ether group. More examples include hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, glycerin cellulose, methyl glycerin cellulose, and the like.
又，成分(A)的纖維素衍生物製造原料之纖維素衍生物，較佳係具有以下構成單元。 Further, the cellulose derivative of the raw material of the cellulose derivative of the component (A) preferably has the following structural unit.
(式中，R'係表示碳數2~8之直鏈或分支鏈伸烷基；n係表示每葡萄糖單元的R'O平均加成莫耳數成為0.1~10之數值) (wherein R' represents a linear or branched alkyl group having 2 to 8 carbon atoms; and n represents an average molar addition of R'O per glucose unit of 0.1 to 10)
該構成單元中，R'較佳係直鏈或分支鏈碳數2~4之伸烷基、更佳係伸乙基及伸丙基。又，n較佳係每葡萄糖單元的R'O平均加成莫耳數成為0.3~5之數值、更佳係成為0.5~4.5的數值、特佳係成為1~4的數值。 In the constituent unit, R' is preferably a linear or branched chain alkyl group having 2 to 4 carbon atoms, more preferably an ethyl group and a stretching group. Further, n is preferably such that the R'O average addition molar number per glucose unit is 0.3 to 5, more preferably 0.5 to 4.5, and particularly preferably 1 to 4.
原料纖維素衍生物較佳係可舉例如：羥乙基纖維素、羥丙基纖維素等，更佳係羥丙基纖維素。 The raw material cellulose derivative is preferably hydroxyethyl cellulose or hydroxypropyl cellulose, and more preferably hydroxypropyl cellulose.
再者，原料纖維素衍生物的質量平均分子量(Mw)，就從對油劑的溶解性、及觸感之觀點，較佳係1萬~400萬、更佳係10萬~300萬、特佳係30萬~200萬。 Further, the mass average molecular weight (Mw) of the raw material cellulose derivative is preferably from 10,000 to 4,000,000, more preferably from 100,000 to 3,000,000, from the viewpoint of solubility to the oil agent and touch. The best is 300,000 to 2 million.
成分(A)的纖維素衍生物係就原料纖維素衍生物的羥基取代基之-O-M-R基中，M係表示CH2或羰基C=O，R係表示碳數3~40之直鏈或分支鏈烷基或烯基。 The cellulose derivative of the component (A) is in the -OMR group of the hydroxy substituent of the raw material cellulose derivative, the M system represents CH 2 or a carbonyl group C=O, and the R system represents a linear or branched carbon number of 3 to 40. Alkenyl or alkenyl.
(i)直鏈烷基係可舉例如：丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基、十二烷基、十三烷基、十四烷基、十五烷基、十六烷基、十七烷基、十八烷基、十九烷基、廿烷基、廿一烷基、廿二烷基、廿三烷基、廿四烷基、廿五烷基、廿六烷基、廿七烷基、廿八烷基、廿九烷基、卅烷基、卅一烷基、卅二烷基、卅三烷基、卅四烷基、卅五烷基、卅六烷基、卅七烷基、卅八烷基、卅九烷基及四十烷基。 The (i) linear alkyl group may, for example, be a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a decyl group, a decyl group, an undecyl group, a dodecyl group, a tridecyl group or a tetradecane group. , pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, decyl, decyl, decyl, decyl, decyl , pentacycloalkyl, hexaalkyl, anthracylene, octadecyl, decyl, decyl, decyl, decyl, decyl, decyl, Pentadecyl, hexadecyl, anthracylene, octadecyl, anthracene and tetradecyl.
(ii)分支鏈烷基係可舉例如：甲基戊基、甲基己基、甲基庚基、甲基辛基、甲基壬基、甲基十一烷基、甲基十七烷基、乙基十六烷基、甲基十八烷基、丙基十五烷基、2-十六烷基、2-辛基十二烷基、2-庚基十一烷基、2-癸基十四烷基、2-十二烷基十六烷基、2-十四烷基十八烷基、2-十六烷基廿烷基等。 (ii) a branched alkyl group may, for example, be a methylpentyl group, a methylhexyl group, a methylheptyl group, a methyloctyl group, a methyldecyl group, a methylundecyl group or a methylheptadecyl group. Ethylhexadecyl, methyloctadecyl, propylpentadecyl, 2-hexadecyl, 2-octyldodecyl, 2-heptylundecyl, 2-indenyl Tetradecyl, 2-dodecylhexadecyl, 2-tetradecyloctadecyl, 2-hexadecyldecylalkyl, and the like.
(iii)直鏈烯基係可舉例如：十二碳烯基、十三碳烯基、十四碳烯基、十五碳烯基、十六碳烯基、十七碳烯基、十八碳烯基、十九碳烯基、廿碳稀基、廿一碳稀基、廿二碳烯基、廿三碳烯基、廿四 碳烯基、廿五碳烯基、廿六碳烯基、廿七碳烯基、廿八碳烯基等。 (iii) The linear alkenyl group may, for example, be a dodecenyl group, a thirteen alkenyl group, a tetradecenyl group, a pentadecenyl group, a hexadecenyl group, a heptadecenyl group, or an eighteenth Carbacenyl, nonadecanyl, fluorene, fluorene, quinone, decyl, decyl, decylene A hexenyl group, a pentylene group, a hexacarbon alkenyl group, an anthranylene group, an octadecyl group, and the like.
(iv)分支鏈烯基係可舉例如：異十三碳烯基、異十八碳烯基、異卅碳烯基、2-丁基辛烯基、2-己基癸烯基、2-辛基十二碳烯基、2-癸基十四碳烯基、2-十二烷基十六碳烯基等。 The (iv) branched alkenyl group may, for example, be an isotridecenyl group, an isooctadecenyl group, an isodecenylalkenyl group, a 2-butyloctenyl group, a 2-hexyldecenyl group or a 2-octyl group. A dodecylalkenyl group, a 2-decyltetradecenyl group, a 2-dodecylhexadecenyl group, and the like.
該等之中，就從油性化妝料塗佈時賦予滑順性、以及在嘴唇、皮膚等之上形成均勻被膜的觀點，R較佳係直鏈烷基。又，就從延伸困難度、密接性之良好程度的觀點，較佳係碳數9~21、更佳係碳數11~17、特佳係碳數15。 Among these, R is preferably a linear alkyl group from the viewpoint of imparting smoothness upon application of an oily cosmetic and forming a uniform film on lips, skin, and the like. Further, from the viewpoints of the degree of difficulty in elongation and the degree of adhesion, the carbon number is preferably from 9 to 21, more preferably from 11 to 17 carbon atoms, and particularly preferably from 15 to 17 carbon atoms.
羥基的-O-M-R基取代率，就從提高在油劑中的溶解性、塗佈時不會感受到粗硬、刺痛感的觀點，以及抑制在杯子等之上二次附著的觀點，係45mol%以上、較佳係48mol%以上、更佳係51mol%以上，就從不易起皺、提高耐水性的觀點，係95mol%以下、更佳係94mol%以下、特佳係92mol%以下、最佳係66mol%以下。又，羥基的-O-M-R基取代率係45~95mol%、較佳係48~94mol%、更佳係51~92mol%、特佳係51~66mol%。 The hydroxyl group-OMR group substitution ratio is from the viewpoint of improving the solubility in an oil agent, not feeling rough and tingling when applied, and suppressing secondary adhesion on a cup or the like. % or more, preferably 48 mol% or more, and more preferably 51 mol% or more, from the viewpoint of not easily wrinkling and improving water resistance, 95 mol% or less, more preferably 94 mol% or less, and particularly preferably 92 mol% or less, and most preferably It is 66 mol% or less. Further, the -O-M-R group substitution ratio of the hydroxyl group is 45 to 95 mol%, preferably 48 to 94 mol%, more preferably 51 to 92 mol%, and particularly preferably 51 to 66 mol%.
羥基就從使用感、顏料分散性的觀點，較佳係適度殘留，較佳係5mol%以上、更佳係6mol%以上、特佳係8mol%以上、最佳係34mol%以上，且較佳係55mol%以下、更佳係52mol%以下、特佳係49mol%以下。又，羥基的殘留率較佳係5~55mol%、更佳係6~52mol%、特佳係8~49mol%、最佳係34~49mol%。 The hydroxyl group is preferably suitably present from the viewpoint of the feeling of use and the dispersibility of the pigment, and is preferably 5 mol% or more, more preferably 6 mol% or more, more preferably 8 mol% or more, and most preferably 34 mol% or more, and more preferably 55 mol% or less, more preferably 52 mol% or less, and particularly preferably 49 mol% or less. Further, the residual ratio of the hydroxyl group is preferably 5 to 55 mol%, more preferably 6 to 52 mol%, particularly preferably 8 to 49 mol%, and most preferably 34 to 49 mol%.
成分(A)的纖維素衍生物之質量平均分子量，就從對油成分的 溶解性、持續滑順觸感的觀點，較佳係10萬以上、更佳係20萬以上、特佳係30萬以上、最佳係50萬以上，且較佳係500萬以下、更佳係400萬以下、特佳係300萬以下、最佳係200萬以下。 The mass average molecular weight of the cellulose derivative of the component (A), from the oil component The viewpoint of solubility and smooth sliding feel is preferably 100,000 or more, more preferably 200,000 or more, more preferably 300,000 or more, and most preferably 500,000 or more, and preferably 5,000,000 or less, and more preferably It is 4 million or less, the best is 3 million or less, and the best is 2 million or less.
另外，質量平均分子量(Mw)係利用凝膠滲透色層分析儀(使用氯仿溶劑、以直鏈聚苯乙烯為標準而決定的校正曲線、折射率檢測器)測定而求取。 Further, the mass average molecular weight (Mw) was determined by a gel permeation chromatography analyzer (a calibration curve determined by using a chloroform solvent and linear polystyrene as a standard, and a refractive index detector).
成分(A)的纖維素衍生物係使原料纖維素衍生物、具碳數3~40之直鏈或分支鏈烷基或烯基的酸鹵化物進行反應，藉由取代原料纖維素衍生物總羥基的45~95mol%而製造。 The cellulose derivative of the component (A) is obtained by reacting a raw material cellulose derivative, an acid halide having a linear or branched alkyl group or an alkenyl group having 3 to 40 carbon atoms, by substituting the raw material cellulose derivative. Manufactured from 45 to 95 mol% of a hydroxyl group.
再者，M為CH2者係藉由在鹼存在下，使纖維素衍生物、與對應的烷基鹵化物或甲磺酸烷基酯等磺酸酯進行反應便可製造。主鏈由纖維素骨架構成者係藉由醋酸纖維素的酯交換反應(酸解)亦可獲得。根據該方法，可獲得羥基殘留量極低的纖維素酯衍生物。 Further, those in which M is CH 2 can be produced by reacting a cellulose derivative with a sulfonate such as a corresponding alkyl halide or alkyl methanesulfonate in the presence of a base. The main chain is composed of a cellulose skeleton and can also be obtained by transesterification (acid hydrolysis) of cellulose acetate. According to this method, a cellulose ester derivative having an extremely low residual hydroxyl group can be obtained.
具體係可舉例如：羥乙基纖維素月桂酸酯、羥乙基纖維素肉荳蔻酸酯、羥乙基纖維素棕櫚酸酯、羥乙基纖維素硬脂酸酯、羥乙基纖維素俞樹酸酯；羥丙基纖維素月桂酸酯、羥丙基纖維素肉荳蔻酸酯、羥丙基纖維素棕櫚酸酯、羥丙基纖維素硬脂酸酯、羥丙基纖維素萮樹酸酯；羥乙基甲基纖維素月桂酸酯、羥乙基甲基纖維素肉荳蔻酸酯、羥乙基甲基纖維素棕櫚酸酯、羥乙基甲基纖維素硬脂酸酯、羥乙基甲基纖維素萮樹酸酯；羥丙基甲基纖維素月桂酸酯、羥丙基甲基纖維素肉荳蔻酸酯、羥丙基甲基纖維素棕櫚酸酯、羥丙基甲基纖維素硬脂酸酯、羥丙基甲基纖維素萮樹酸酯等。其中，就從 中在嘴唇、皮膚等之上形成均勻被膜、抑制在杯子等之上二次附著的觀點，較佳係羥丙基纖維素月桂酸酯、羥丙基纖維素肉荳蔻酸酯、羥丙基纖維素棕櫚酸酯、羥丙基纖維素硬脂酸酯、羥丙基纖維素萮樹酸酯，更佳係羥丙基纖維素棕櫚酸酯。 Specifically, for example, hydroxyethyl cellulose laurate, hydroxyethyl cellulose myristate, hydroxyethyl cellulose palmitate, hydroxyethyl cellulose stearate, hydroxyethyl cellulose Sulfate; hydroxypropylcellulose laurate, hydroxypropylcellulose myristate, hydroxypropylcellulose palmitate, hydroxypropylcellulose stearate, hydroxypropylcellulose eucalyptus Ester; hydroxyethyl methylcellulose laurate, hydroxyethyl methylcellulose myristate, hydroxyethyl methylcellulose palmitate, hydroxyethyl methylcellulose stearate, hydroxyethyl Methyl cellulose phthalate; hydroxypropyl methylcellulose laurate, hydroxypropyl methylcellulose myristate, hydroxypropyl methylcellulose palmitate, hydroxypropyl methylcellulose Stearic acid ester, hydroxypropyl methylcellulose phthalate, and the like. Among them, from A viewpoint of forming a uniform film on the lips, the skin, or the like, and suppressing secondary adhesion on a cup or the like, preferably hydroxypropylcellulose laurate, hydroxypropylcellulose myristate, hydroxypropylcellulose Preferably, palmitate, hydroxypropylcellulose stearate, hydroxypropylcellulose phthalate, more preferably hydroxypropylcellulose palmitate.
成分(A)的纖維素衍生物係可使用1種或2種以上，含有量就從在嘴唇、皮膚等之上形成均勻被膜、抑制在杯子等之上二次附著的觀點，在總組成中佔1質量%以上、較佳係1.5質量%以上、更佳係2質量%以上、特佳係3質量%以上，且在50質量%以下、較佳係30質量%以下、更佳係20質量%以下、特佳係15質量%以下、最佳係10質量%以下。又，成分(A)的含有量在總組成中佔1~50質量%、較佳係1.5~30質量%、更佳係2~20質量%、特佳係2~15質量%、最佳係3~10質量%。 In the total composition, the cellulose derivative of the component (A) may be used in one or two or more types, and the content thereof is formed by forming a uniform film on the lips, the skin, or the like, and suppressing secondary adhesion on a cup or the like. 1% by mass or more, preferably 1.5% by mass or more, more preferably 2% by mass or more, more preferably 3% by mass or more, and 50% by mass or less, preferably 30% by mass or less, more preferably 20% by mass. % or less, particularly preferably 15% by mass or less, and most preferably 10% by mass or less. Further, the content of the component (A) is from 1 to 50% by mass, preferably from 1.5 to 30% by mass, more preferably from 2 to 20% by mass, particularly preferably from 2 to 15% by mass, based on the total composition. 3 to 10% by mass.
成分(B)係揮發性烴油。所謂「揮發性」係指具有在35~87℃之引火點。 Ingredient (B) is a volatile hydrocarbon oil. By "volatile" is meant a point of ignition at 35-87 °C.
成分(B)的揮發性烴油就從與成分(A)間之相溶性優異、即便該揮發性烴油揮散後仍不會感受到沾黏、粗硬觸感的觀點，可例如：正癸烷、正十一烷、正十二烷等烷烴系烴油；異癸烷、異十二烷、氫化聚異丁烯等異烷烴系烴油；環癸烷、環十二烷等環狀烷烴烴油。該等之中，較佳係碳數8~16之烴油、更佳係碳數10~16之烴油、特佳係碳數12之烴油。其中，較佳係異烷烴系烴油，更佳係異十二烷、碳數12之氫化聚異丁烯，特佳係異十二烷。 The volatile hydrocarbon oil of the component (B) is excellent in compatibility with the component (A), and does not feel sticky or rough touch even after the volatile hydrocarbon oil is volatilized. For example, Alkane hydrocarbon oils such as alkane, n-undecane and n-dodecane; isoparaffinic hydrocarbon oils such as isodecane, isododecane and hydrogenated polyisobutylene; and cyclic alkane hydrocarbon oils such as cyclodecane and cyclododecane . Among these, a hydrocarbon oil having 8 to 16 carbon atoms, a hydrocarbon oil having 10 to 16 carbon atoms, and a hydrocarbon oil having a carbon number of 12 are preferable. Among them, an isoparaffinic hydrocarbon oil is preferred, and isododecane, a hydrogenated polyisobutylene having a carbon number of 12, and a particularly useful isododecane.
市售物係可舉例如MARUKASOL R(丸善石油化學公司製：引 火點48℃)、PARLEAM® 3(日油公司製：引火點61℃)等。 Commercially available products are, for example, MARUKASOL R (made by Maruzen Petrochemical Co., Ltd.: cited Fire point 48 ° C), PARLEAM® 3 (made by Nippon Oil Co., Ltd.: 61 ° C fire point).
成分(B)係可使用1種或2種以上，含有量就從成分(A)、(C)的相溶性優異，以及經塗佈於嘴唇、皮膚等之上後，即便成分(B)揮發後仍不會有粗硬或沾黏，能在嘴唇等之上形成均勻皮膜，抑制在杯子等之上出現二次附著的觀點，在總組成中佔5質量%以上、較佳係35質量%以上、更佳係40質量%以上、特佳係45質量%以上、最佳係46質量%以上，且在80質量%以下、較佳係75質量%以下、更佳係70質量%以下、特佳係66質量%以下。又，成分(B)的含有量在總組成中佔5~80質量%、較佳係35~75質量%、更佳係40~75質量%、特佳係45~70質量%、最佳係46~66質量%。 The component (B) may be used alone or in combination of two or more kinds, and the content is excellent in compatibility with the components (A) and (C), and after being applied to the lips, the skin, or the like, even if the component (B) is volatilized. After that, there is no rough or sticky, a uniform film can be formed on the lips or the like, and the secondary adhesion on the cup or the like is suppressed, and the total composition accounts for 5% by mass or more, preferably 35% by mass. The above is more preferably 40% by mass or more, more preferably 45% by mass or more, and most preferably 46% by mass or more, and 80% by mass or less, preferably 75% by mass or less, more preferably 70% by mass or less, and more preferably 70% by mass or less. The best quality is 66% by mass or less. Further, the content of the component (B) is 5 to 80% by mass, preferably 35 to 75% by mass, more preferably 40 to 75% by mass, and particularly preferably 45 to 70% by mass, based on the total composition. 46~66% by mass.
本發明所使用成分(C)的酯油係25℃下呈液狀。所謂「25℃下呈液狀」係指具流動性者，亦涵蓋糊狀物。 The ester oil of the component (C) used in the present invention is liquid at 25 °C. The term "liquid at 25 ° C" means fluidity and also covers paste.
作為該酯油係在通常化妝料所使用者的前提下，其餘並無限制，可例如：異壬酸異十三烷基酯、蘋果酸二異硬脂酯、肉荳蔻酸異硬脂酯、蓖麻醇酸辛基十二烷基酯、二癸酸新戊二醇酯、二異硬脂酸雙甘油酯、單異硬脂酸單肉荳蔻酸甘油酯、對甲氧基肉桂酸-2-乙基己酯、醋酸生育酚、單異硬脂酸雙甘油酯等。 The ester oil is not limited in the premise of the user of the general cosmetic, and may, for example, be isotridecyl isononanoate, diisostearyl malate, isostearyl myristate, Octyl dodecyl octanoate, neopentyl glycol dicaprate, diglyceryl diisostearate, glyceryl mono-stearic acid monoglycolate, p-methoxycinnamic acid-2- Ethylhexyl ester, tocopheryl acetate, monoisostearic acid diglyceride, and the like.
該等之中，就從成分(A)的相溶性優異，以及經塗佈於嘴唇、皮膚等之後，即便於成分(B)揮發後仍不會有粗硬或沾黏的觀點，較佳係具分支鏈的酯油，更佳係異壬酸異十三烷基酯、蘋果酸二異硬脂酯、肉荳蔻酸異硬脂酯、蓖麻醇酸辛基十二烷基酯、二異硬脂酸雙甘油酯、單異硬脂酸單肉荳蔻酸甘油酯、對甲氧基肉桂酸-2- 乙基己酯、單異硬脂酸雙甘油酯，特佳係異壬酸異十三烷基酯、蘋果酸二異硬脂酯。 Among these, the compatibility with the component (A) is excellent, and after application to the lips, the skin, and the like, even if the component (B) is volatilized, there is no rough or sticky viewpoint. Branched chain ester oil, more preferably isotridecyl isononanoate, diisostearyl malate, isostearyl myristate, octyl dodecyl ricinoleate, diiso-hard Diglyceride fatty acid, monoisostearic acid monomyristate, p-methoxycinnamic acid-2- Ethylhexyl ester, monoisostearic acid diglyceride, especially isodecyl isononanoate, diisostearyl malate.
成分(C)的酯油係可使用1種或2種以上，含有量就從成分(A)的相溶性優異，以及經塗佈於嘴唇、皮膚等之後，即便於成分(B)揮發後仍不會有粗硬或沾黏，能在嘴唇上等之上形成均勻皮膜，抑制在杯子等之上出現二次附著的觀點，在總組成中佔5質量%以上、較佳係7質量%以上、更佳係10質量%以上、特佳係13質量%以上，且在50質量%以下、較佳係40質量%以下、更佳係35質量%以下、特佳係33質量%以下。又，成分(C)的含有量在總組成中佔5~50質量%、較佳係7~40質量%、更佳係10~35質量%、特佳係13~33質量%。 The ester oil of the component (C) may be used alone or in combination of two or more kinds, and the content is excellent in compatibility with the component (A), and after application to the lips, the skin, etc., even after the component (B) is volatilized. It is not rough or sticky, and it can form a uniform film on the lips and the like, and suppresses secondary adhesion on the cup or the like. The total composition accounts for 5% by mass or more, preferably 7% by mass or more. More preferably, it is 10% by mass or more, and particularly preferably 13% by mass or more, more preferably 50% by mass or less, preferably 40% by mass or less, more preferably 35% by mass or less, and particularly preferably 33% by mass or less. Further, the content of the component (C) is 5 to 50% by mass, preferably 7 to 40% by mass, more preferably 10 to 35% by mass, and particularly preferably 13 to 33% by mass in the total composition.
本發明中，成分(B)相對於成分(C)的質量比例(B)/(C)就從在塗佈時不會感受到粗硬、刺痛感等，且嘴唇、皮膚等滑順，即便剛塗佈後及經長時間後，仍抑制在杯子等之上二次附著，水濕潤亦強的觀點，以及從嘴唇上卸除口紅時仍可乾淨地完全卸除的觀點，係0.7以上、較佳係1.0以上、更佳係1.4以上，且9以下、較佳係7以下、更佳係5以下。又，成分(B)相對於成分(C)的質量比例(B)/(C)係0.7~9、較佳係1.0~7、更佳係1.4~5。 In the present invention, the mass ratio (B)/(C) of the component (B) to the component (C) does not feel rough, tingling, etc. at the time of coating, and the lips, the skin, and the like are smooth. Even after coating and after a long period of time, the viewpoint of suppressing secondary adhesion on a cup or the like, strong water wetting, and the fact that the lipstick can be completely removed when the lipstick is removed from the lips is 0.7 or more. Preferably, it is 1.0 or more, more preferably 1.4 or more, and 9 or less, preferably 7 or less, more preferably 5 or less. Further, the mass ratio (B)/(C) of the component (B) to the component (C) is 0.7 to 9, preferably 1.0 to 7, more preferably 1.4 to 5.
本發明中，成分(A)相對於成分(C)的質量比例(A)/(C)就從在塗佈時不會感受到粗硬、刺痛感等，且嘴唇、皮膚等滑順，即便剛塗佈後及經長時間後，仍抑制在杯子等之上二次附著，水濕潤亦強的 觀點，以及就從嘴唇、皮膚等之上卸除化妝料時亦可乾淨地完全卸除的觀點，較佳係0.10以上、更佳係0.12以上、特佳係0.14以上，且較佳係1.25以下、更佳係1.0以下、特佳係0.65以下。又，成分(A)相對於成分(C)的質量比例(A)/(C)較佳係0.10~1.25、更佳係0.12~1.0、特佳係0.14~0.65。 In the present invention, the mass ratio (A)/(C) of the component (A) to the component (C) does not feel rough, tingling, etc. at the time of coating, and the lips, the skin, and the like are smooth. Even after coating and after a long time, it is suppressed from secondary adhesion on the cup, etc., and the water is wet. The viewpoint and the viewpoint that the cosmetic material can be completely removed when it is removed from the lips, the skin, or the like is preferably 0.10 or more, more preferably 0.12 or more, more preferably 0.14 or more, and preferably 1.25 or less. More preferably, it is 1.0 or less, and the best is 0.65 or less. Further, the mass ratio (A)/(C) of the component (A) to the component (C) is preferably 0.10 to 1.25, more preferably 0.12 to 1.0, and particularly preferably 0.14 to 0.65.
本發明的油性化妝料係可更進一步含有(D)有機聚矽氧樹脂，可使化妝料均勻附著於嘴唇、皮膚等，能提升密接性、提升耐水性。 The oily cosmetic of the present invention may further contain (D) an organic polyoxyxene resin, which allows the cosmetic to be uniformly adhered to the lips, the skin, and the like, thereby improving the adhesion and improving the water resistance.
成分(D)的有機聚矽氧樹脂係在通常化妝料所使用者之前提下，可使用任一者，例如(D-1)三甲基矽烷氧基矽酸、(D-2)氟改質聚矽氧樹脂等。 The organopolyoxyl resin of the component (D) is taken before the user of the usual cosmetic material, and any of them may be used, for example, (D-1) trimethyldecyloxydecanoic acid, (D-2) fluorine. Polyoxygenated resin, etc.
成分(D)中，成分(D-1)三甲基矽烷氧基矽酸係在通常化妝料所使用者之前提下，其餘並無限制，較佳係以矽氧烷構造為主骨架且具交聯構造的化合物，由[(CH3)3SiO1/2]X[SiO2]Y(X係1~3、Y係0.5~8)所示。 In the component (D), the component (D-1) trimethyldecyloxydecanoic acid is taken before the user of the usual cosmetic material, and the rest is not limited, and it is preferred to use a decane structure as a main skeleton and The compound of the crosslinked structure is represented by [(CH 3 ) 3 SiO 1/2 ] X [SiO 2 ] Y (X system 1 to 3, Y system 0.5 to 8).
成分(D-1)三甲基矽烷氧基矽酸就從使用感與化妝持久的觀點，質量平均分子量較佳係1000~10000、較佳係2000~9000、特佳係3000~6000。又，性狀係在25℃下可呈液狀、膠狀、糊狀、固態狀等任一狀態，但就從所獲得之化妝持久的觀點，較佳係固態狀。又，從配合性的觀點，可使用經溶劑稀釋的溶液或分散液、或事先混合獲得的溶液或分散液之狀態。稀釋或分散的溶劑較佳係從二甲基聚矽氧烷、八甲基環四矽氧烷、十甲基環五矽氧烷、異十二烷之中選擇1種或2種以上，更佳係揮發性二甲基聚矽氧烷、 十甲基環五矽氧烷。另外，所謂「揮發性」係指具有35~87℃引火點。 The component (D-1) trimethyldecyloxydecanoic acid has a mass average molecular weight of preferably from 1,000 to 10,000, preferably from 2,000 to 9000, and particularly preferably from 3,000 to 6,000, from the viewpoint of the feeling of use and long-lasting makeup. Further, the trait may be in a liquid state, a gel form, a paste form, or a solid form at 25 ° C, but it is preferably solid in view of the long-lasting makeup obtained. Further, from the viewpoint of compatibility, a solvent-dispersed solution or dispersion or a solution or dispersion obtained by mixing in advance may be used. The solvent to be diluted or dispersed is preferably one or more selected from the group consisting of dimethyl polyoxyalkylene, octamethylcyclotetraoxane, decamethylcyclopentaoxane, and isododecane. Good volatile dimethyl polyoxane, Decamethylcyclopentaoxane. In addition, "volatile" means having a firing point of 35 to 87 °C.
成分(D-1)的市售物係預先溶解於溶劑中，可使用例如：KF-7312J(固形份50%十甲基環五矽氧烷溶液)、KF-9021(50%十甲基環五矽氧烷溶液)、X21-5249(50%十甲基環五矽氧烷溶液)(以上均係信越化學工業公司製)；SS4267(35%二甲基聚矽氧烷溶液)、SR1000(以上均係Momentive Performance Materials．Japan LLC company製)；BY11-018(30%環五矽氧烷溶液)(Toray．Dow Corning ．Silicones公司製)；BELSIL TMS 803(Wacker Chemie AG公司製)等。 A commercially available product of the component (D-1) is previously dissolved in a solvent, and for example, KF-7312J (solid content 50% decamethylcyclopentaoxane solution), KF-9021 (50% decamethylcyclohexane) can be used. Pentaoxane solution), X21-5249 (50% decamethylcyclopentaoxane solution) (all of which are manufactured by Shin-Etsu Chemical Co., Ltd.); SS4267 (35% dimethyl polyoxane solution), SR1000 ( All of the above are manufactured by Momentive Performance Materials. Japan LLC company; BY11-018 (30% cyclopentaoxane solution) (Toray. Dow Corning. manufactured by Silicones, Inc.); BELSIL TMS 803 (manufactured by Wacker Chemie AG).
成分(D)中，成分(D-2)氟改質聚矽氧樹脂較佳係具有一般式(1)：R1 aSiO(4-a)/2 (1) In the component (D), the component (D-2) fluorine-modified polyanthracene resin preferably has a general formula (1): R 1 a SiO (4-a)/2 (1)
(式中，R1係表示從碳數1~8之烴基、苯基、羥基、或一般式-R2-Rf(R2係表示碳數2~6之2價伸烷基；Rf係表示碳數1~8之全氟烷基)、以羥基與一般式-R2-Rf為必須的官能基之中任意選擇，a係平均數1.0≦a≦1.8)所示構造。 (wherein R 1 represents a hydrocarbon group having 1 to 8 carbon atoms, a phenyl group, a hydroxyl group, or a general formula -R 2 -Rf (R 2 represents a divalent alkylene group having 2 to 6 carbon atoms; and Rf represents The perfluoroalkyl group having 1 to 8 carbon atoms and the functional group having a hydroxyl group and a general formula -R 2 -Rf are arbitrarily selected, and the a system has an average number of 1.0 ≦ a ≦ 1.8).
氟改質聚矽氧樹脂就從對皮膚、粉體的附著性觀點，較佳係分子內具有矽醇基，且矽醇基中的OH基比例相對於樹脂質量為0.1~5質量%、更佳係0.5~5質量%。 The fluorine-modified polyoxyl resin preferably has a sterol group in the molecule from the viewpoint of adhesion to skin and powder, and the ratio of the OH group in the decyl group is 0.1 to 5% by mass based on the mass of the resin. Good system 0.5~5 mass%.
成分(D-2)較佳係25℃下呈固態，就從摻合性的觀點，可使用經溶劑稀釋的溶液或分散液，或者使用事先混合而獲得的溶液或分 散液之狀態。稀釋或分散的溶劑較佳係環狀聚矽氧、二甲基聚矽氧烷等。環狀聚矽氧較佳係經溶解於從八甲基環四矽氧烷(D4)及十甲基環五矽氧烷(D5)之中選擇1種以上之後才使用。 The component (D-2) is preferably in a solid state at 25 ° C, and from the viewpoint of blendability, a solvent-diluted solution or dispersion may be used, or a solution or fraction obtained by mixing in advance may be used. The state of the liquid. The solvent to be diluted or dispersed is preferably a cyclic polyfluorene oxide, dimethyl polyoxyalkylene or the like. The cyclic polyfluorene oxide is preferably used after being dissolved in one or more selected from the group consisting of octamethylcyclotetraoxane (D4) and decamethylcyclopentaoxane (D5).
此種氟改質聚矽氧樹脂係可使用INCI命名為「三氟丙基二甲基/三甲基矽烷氧基矽酸酯(Trifluoropropyldimethyl/Trimethylsiloxysilicate)」的XS66-B8226、XS66-C1191、XS66-B8636(以上均係Momentive Performance Materials公司製)等市售物。 Such a fluorine-modified polyoxyl resin can be XS66-B8226, XS66-C1191, XS66- which is named "Trifluoropropyldimethyl/Trimethylsiloxysilicate" by INCI. B8636 (all of which are manufactured by Momentive Performance Materials Co., Ltd.) and the like.
成分(D)的有機聚矽氧樹脂係可使用1種或組合2種以上使用，含有量就從使化妝料均勻附著於嘴唇、皮膚等，及提升密接性的觀點，以及耐水性優異的觀點，佔總組成中較佳係0.01質量%以上、更佳係0.2質量%以上、特佳係0.5質量%以上、最佳係1質量%以上，且較佳係25質量%以下、更佳係20質量%以下、特佳係15質量%以下、最佳係13質量%以下。又，成分(D)的含有量佔總組成中較佳係0.01~25質量%、更佳係0.2~20質量%、特佳係0.5~15質量%、最佳係1~13質量%。 The organic polysiloxane resin of the component (D) may be used singly or in combination of two or more kinds, and the content thereof is such that the cosmetic is uniformly adhered to the lips, the skin, and the like, and the adhesion is improved, and the water resistance is excellent. The total composition is preferably 0.01% by mass or more, more preferably 0.2% by mass or more, more preferably 0.5% by mass or more, more preferably 1% by mass or more, and more preferably 25% by mass or less, more preferably 20%. The mass% or less, the best quality is 15% by mass or less, and the optimum is 13% by mass or less. Further, the content of the component (D) is preferably 0.01 to 25% by mass, more preferably 0.2 to 20% by mass, particularly preferably 0.5 to 15% by mass, and most preferably 1 to 13% by mass based on the total composition.
本發明中，成分(A)相對於成分(D)的質量比例(A)/(D)，就從即便剛塗佈後及經長時間後，仍抑制在杯子等之上二次附著，抗沾水濕潤亦強的觀點，以及就從嘴唇、皮膚等之上卸除化妝料時亦可乾淨地完全卸除的觀點，較佳係0.05以上、更佳係0.2以上、特佳係0.3以上、最佳係0.5以上，且較佳係40以下、更佳係20以下、特佳係12以下、最佳係10以下。又，成分(A)相對於成分(D)的質量 比例(A)/(D)較佳係0.05~40、更佳係0.2~20、特佳係0.3~12、最佳係0.5~10。 In the present invention, the mass ratio (A)/(D) of the component (A) to the component (D) is suppressed from secondary adhesion on a cup or the like even after the application and after a long period of time. The viewpoint that the water is wet and strong, and that the cosmetic material can be completely removed when it is removed from the lips, the skin, or the like is preferably 0.05 or more, more preferably 0.2 or more, and particularly preferably 0.3 or more. The optimum is 0.5 or more, and preferably 40 or less, more preferably 20 or less, particularly preferably 12 or less, and most preferably 10 or less. Also, the quality of the component (A) relative to the component (D) The ratio (A)/(D) is preferably 0.05 to 40, more preferably 0.2 to 20, particularly good for 0.3 to 12, and optimum for 0.5 to 10.
再者，本發明的油性化妝料係可含有25℃下呈固態的蠟。所謂「25℃下呈固態」係指25℃下呈固體的性狀，熔點達61℃以上。 Further, the oily cosmetic of the present invention may contain a wax which is solid at 25 °C. The phrase "solid at 25 ° C" means a solid at 25 ° C and a melting point of 61 ° C or higher.
25℃下呈固態的蠟係在通常之化妝料所使用者之前提下，其餘並無限制，可例如：天然地蠟、地蠟等礦物系蠟；烷烴、微晶蠟等石油系蠟；費歇爾-托晉希蠟(Fischer-Tropsch wax)、聚乙烯蠟等合成烴；棕櫚蠟、堪地里蠟(candelilla wax)、米蠟、木蠟、葵花蠟等植物系蠟；蜜蠟、鯨蠟等動物性蠟；聚矽氧蠟、合成蜜蠟等合成蠟等等。 The wax which is solid at 25 ° C is taken before the user of the usual cosmetic material, and the rest is not limited, and may be, for example, a mineral wax such as a natural wax or a ground wax; a petroleum wax such as an alkane or a microcrystalline wax; Synthetic hydrocarbons such as Fischer-Tropsch wax, polyethylene wax; plant waxes such as palm wax, candelilla wax, rice wax, wood wax, sunflower wax; beeswax, whale Animal wax such as wax; synthetic wax such as polyoxynized wax, synthetic beeswax, and the like.
25℃下呈固態的蠟就從對油性化妝料賦予適度硬度、抑制油滲出、賦予滋潤的觀點，熔點較佳係65℃以上且140℃以下、更佳係70℃以上且90℃以下。又，就從賦予滑順使用感的觀點，最好不要含有熔點超過90℃的蠟。 The wax which is solid at 25 ° C is preferably from 65 ° C to 140 ° C, more preferably from 70 ° C to 90 ° C from the viewpoint of imparting moderate hardness to the oily cosmetic, suppressing oil bleeding, and imparting moisture. Further, from the viewpoint of imparting a smooth feeling of use, it is preferable not to contain a wax having a melting point of more than 90 °C.
再者，25℃下呈固態的蠟就從對油性化妝料賦予適度硬度、抑制油滲出、賦予滋潤的觀點，25℃下的針入度較佳係1以上且150以下、更佳係15以上且110以下。 Further, the wax which is solid at 25 ° C is preferably one or more and 150 or less, more preferably 15 or more, from the viewpoint of imparting moderate hardness to the oily cosmetic, suppressing oil bleeding, and imparting moisture. And 110 or less.
此處，針入度係測定由規定針(針質量25±0.02g、針保持工具的質量47.5±0.02g、錘質量50±0.05g)，在5秒鐘內***於保持25±0.1℃蠟試料中的長度，將該針入距離(mm)乘上10倍的值設為針入度，根據JIS K-2235-5.4(1991年)測定的值。 Here, the penetration degree is measured by a predetermined needle (needle mass 25 ± 0.02 g, needle holding tool mass 47.5 ± 0.02 g, weight mass 50 ± 0.05 g), and inserted in a 25 ± 0.1 ° C wax for 5 seconds. The length in the sample, the value obtained by multiplying the needle insertion distance (mm) by 10 times is the penetration degree, and the value measured according to JIS K-2235-5.4 (1991).
25℃針入度為1以上且150以下的固態蠟係可舉例如礦物系蠟、石油系蠟及合成烴。其中，就從抑制外觀色出現暗斑、以及塗佈膜持續性、滋潤性能較高的觀點，較佳係針入度為15以上且110以下的微晶蠟、烷烴蠟，更佳係針入度為15以上且110以下的微晶蠟。又，較佳係25℃針入度為25以上且80以下的微晶蠟。 Solid-state waxes having a penetration degree of 1 or more and 150 or less at 25 ° C include, for example, mineral waxes, petroleum waxes, and synthetic hydrocarbons. Among them, microcrystalline waxes and alkane waxes having a penetration degree of 15 or more and 110 or less are preferable from the viewpoint of suppressing occurrence of dark spots in the appearance color, and high coating film sustainability and moisturizing performance. A microcrystalline wax having a degree of 15 or more and 110 or less. Further, a microcrystalline wax having a penetration degree of 25 or more and 80 or less at 25 ° C is preferable.
該等蠟係可使用市售物，就微晶蠟係可例如：Multiwax W-445、W-835(以上均係SONNEBORN公司製)；Paracera M(Paramelt公司製)；Hi-Mic-1045、1070、2045(以上均係日本精鑞公司製)；精製微晶蠟(Nikko Rica公司製)；155°微晶蠟(日本石油公司製)等。 Commercially available products can be used as the wax system, and for the microcrystalline wax, for example, Multiwax W-445 and W-835 (all of which are manufactured by SONNEBORN Co., Ltd.); Paracera M (manufactured by Paramelt Co., Ltd.); Hi-Mic-1045, 1070 2045 (all of which are manufactured by Nippon Seiki Co., Ltd.); refined microcrystalline wax (manufactured by Nikko Rica Co., Ltd.); 155° microcrystalline wax (manufactured by Nippon Oil Co., Ltd.).
針入度達15以上的微晶蠟就從滑順使用感、塗佈時賦予光澤的觀點，在25℃下呈固態的蠟中較佳係含有50質量%以上、更佳係含有70質量%以上。 The microcrystalline wax having a penetration degree of 15 or more is preferably 50% by mass or more, and more preferably 70% by mass, in terms of smoothness in application and glossiness at the time of application. the above.
25℃下呈固態的蠟係可使用1種或組合使用2種以上，含有量就從抑制在嘴唇等之上出現化妝料起皺的觀點，佔總組成中較佳係未滿5質量%、更佳係3質量%以下、特佳係1質量%以下、最佳係0.5質量%以下。 The wax system which is solid at 25 ° C may be used alone or in combination of two or more kinds, and the content is preferably less than 5% by mass in terms of suppressing wrinkles of the cosmetic material on the lips or the like. More preferably, it is 3% by mass or less, more preferably 1% by mass or less, and most preferably 0.5% by mass or less.
再者，本發明的油性化妝料係可含有粉體。該粉體係在通常化妝料所使用者之前提下，其餘並無限制，可使用體質顏料、著色顏料、鮮亮性顏料等。 Further, the oily cosmetic of the present invention may contain a powder. The powder system is taken up before the user of the usual cosmetic material, and the rest is not limited, and an extender pigment, a coloring pigment, a bright pigment, or the like can be used.
體質顏料係可例如：矽酸、無水矽酸、矽酸鎂、滑石、絹雲母、 雲母、合成雲母、玻璃碎片、合成金雲母、高嶺土、黏土、膨潤土、氧氯化鉍、氧化鋯、氧化鎂、氧化鋁、硫酸鈣、硫酸鋇、硫酸鎂、碳酸鈣、碳酸鎂等無機顏料、及該等的複合粉體。 The extender pigments can be, for example, tannic acid, anhydrous citric acid, magnesium citrate, talc, sericite, Inorganic pigments such as mica, synthetic mica, glass shards, synthetic phlogopite, kaolin, clay, bentonite, yttrium oxychloride, zirconia, magnesia, alumina, calcium sulfate, barium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, etc. And these composite powders.
著色顏料係可舉例如：氧化鈦、氧化鋅、氧化鐵黃、氧化鐵紅、氧化鐵黑、普魯士藍、群青、氧化鉻、氫氧化鉻等金屬氧化物；錳紫、鈦酸鈷等金屬錯合物；以及碳黑等無機顏料；紅色3號、紅色104號、紅色106號、紅色201號、紅色202號、紅色204號、紅色205號、紅色220號、紅色226號、紅色227號、紅色228號、紅色230號、紅色401號、紅色405號、紅色505號、橙色203號、橙色204號、橙色205號、黃色4號、黃色5號、黃色401號、藍色1號、藍色404號等合成有機顏料；β-胡蘿蔔素、焦糖、甜椒色素等天然有機色素等等。 Examples of the coloring pigment include metal oxides such as titanium oxide, zinc oxide, iron oxide yellow, iron oxide red, iron oxide black, Prussian blue, ultramarine blue, chromium oxide, and chromium hydroxide; and metal oxides such as manganese violet and cobalt titanate. And inorganic pigments such as carbon black; red 3, red 104, red 106, red 201, red 202, red 204, red 205, red 220, red 226, red 227, Red 228, Red 230, Red 401, Red 405, Red 505, Orange 203, Orange 204, Orange 205, Yellow 4, Yellow 5, Yellow 401, Blue 1, Blue Synthetic organic pigments such as color No. 404; natural organic pigments such as β-carotene, caramel, and sweet pepper pigment.
鮮亮性顏料係可使用例如：利用氧化鈦、氧化鐵、氧化矽、普魯士藍、氧化鉻、氧化錫、氫氧化鉻、金、銀、胭脂紅、有機顏料等著色劑，被覆著雲母、合成金雲母、玻璃、二氧化矽、氧化鋁等板狀粉體等的表面者等；以及聚對苯二甲酸乙二酯．聚甲基丙烯酸甲酯積層粉末、聚對苯二甲酸乙二酯．鋁蒸鍍粉末、聚對苯二甲酸乙二酯．金蒸鍍積層粉末等將薄膜原料卷裁剪為任意形狀者等。 The bright pigment can be coated with mica or synthetic gold by using, for example, a coloring agent such as titanium oxide, iron oxide, cerium oxide, Prussian blue, chromium oxide, tin oxide, chromium hydroxide, gold, silver, carmine, or an organic pigment. Surfaces such as mica, glass, cerium oxide, alumina and other plate-like powders; and polyethylene terephthalate. Polymethyl methacrylate laminated powder, polyethylene terephthalate. Aluminum vapor-deposited powder, polyethylene terephthalate. A gold vapor deposited laminated powder or the like is obtained by cutting a film raw material roll into an arbitrary shape or the like.
該等粉體亦可使用經利用尋常方法施行撥水處理、撥水．撥油化處理等各種表面處理者。 These powders can also be treated with water and treated with water. Various surface treatments such as oiling treatment.
粉體係可使用1種或2種以上，含有量佔總組成中較佳係0.01 質量%以上、更佳係0.05質量%以上，且較佳係20質量%以下、更佳係10質量%以下。又，粉體的含有量佔總組成中較佳係0.01~20質量%、更佳係0.05~10質量%。 The powder system may be used in one type or in two or more types, and the content is preferably 0.01 in the total composition. The mass% or more is more preferably 0.05% by mass or more, and more preferably 20% by mass or less, and more preferably 10% by mass or less. Further, the content of the powder is preferably 0.01 to 20% by mass, more preferably 0.05 to 10% by mass, based on the total composition.
再者，本發明的油性化妝料係除上述成分之外，尚可含有尋常化妝料所使用的成分，例如成分(B)與(C)以外的油性成分、界面活性劑、低級醇、多元醇、成分(A)與(D)以外的高分子化合物、紫外線吸收劑、抗氧化劑、染料、香料、色材、防污劑、保濕劑、水等。 Further, the oily cosmetic of the present invention may contain, in addition to the above components, components used in ordinary cosmetic materials, such as oily components other than components (B) and (C), surfactants, lower alcohols, and polyols. A polymer compound other than the components (A) and (D), an ultraviolet absorber, an antioxidant, a dye, a fragrance, a color material, an antifouling agent, a moisturizer, water, or the like.
本發明的油性化妝料係可利用尋常方法製造，劑型係可為固態、半固態、凝膠、液狀等任一形式。 The oily cosmetic of the present invention can be produced by an ordinary method, and the dosage form can be in any form such as a solid, a semi-solid, a gel, or a liquid.
本發明的油性化妝料就從塗佈時的延伸困難度觀點，於25℃剪切速度為0.1s-1時，塊材整體的剪切黏度係1500Pa．s以下、較佳係900Pa．s以下、更佳係500Pa．s以下、特佳係250Pa．s以下、最佳係200Pa．s以下，且較佳係10Pa．s以上、更佳係20Pa．s以上、特佳係30Pa．s以上。又，於25℃剪切速度為0.1s-1時，塊材整體的剪切黏度較佳係10~900Pa．s、更佳係20~500Pa．s、特佳係20~250Pa．s、最佳係30~200Pa．s。 When the oily cosmetic of the present invention extends to difficulty from the viewpoint when applied at a shear rate of 25 deg.] C to 0.1s -1, the overall bulk shear viscosity based 1500Pa. Below s, preferably 900Pa. s below, better 500Pa. s below, especially good 250Pa. s below, the best system is 200Pa. s below, and preferably 10 Pa. Above s, better than 20Pa. Above s, especially good 30Pa. s above. Moreover, when the shear rate is 0.1 s -1 at 25 ° C, the overall shear viscosity of the bulk material is preferably 10 to 900 Pa. s, better system 20~500Pa. s, especially good 20~250Pa. s, the best system is 30~200Pa. s.
剪切黏度係利用流變儀測定。夾具係25mm。讀取測定剪切速度0.1s-1時的剪切黏度。具體而言，利用流變儀(MCR301；Anton Paar公司製)測定經調整過的塊材。夾具係25mm。讀取測定剪切速度0.1s-1時的剪切黏度。 The shear viscosity was measured using a rheometer. Fixture system 25mm. The shear viscosity at a shear rate of 0.1 s -1 was measured. Specifically, the adjusted bulk material was measured using a rheometer (MCR301; manufactured by Anton Paar Co., Ltd.). Fixture system 25mm. Determination of shear viscosity reading at a shear rate of 0.1s -1.
本發明的油性化妝料係以油劑為連續相的化妝料，使用於皮膚、嘴唇、睫毛、指甲、毛髮，較佳係使用於嘴唇。可形成例如：口紅、唇蜜、唇線筆等嘴唇化妝料；睫毛膏、眼線、眼影、腮紅、粉餅、遮瑕膏等彩妝化妝料；乳霜、乳液、美容液、按摩劑、脫臭劑、防曬霜、育髮劑、染髮、髮蠟、髮沐(hair form)等。其中，較佳係成為從口紅、唇蜜、唇線筆之中選擇的嘴唇化妝料。 The oily cosmetic of the present invention is a cosmetic having a continuous phase of an oil agent, and is used for skin, lips, eyelashes, nails, and hair, and is preferably used for the lips. It can form lip makeup such as lipstick, lip gloss, lip liner, mascara, eyeliner, eye shadow, blush, powder, concealer and other make-up cosmetics; cream, lotion, beauty lotion, massage agent, deodorant , sunscreen, hair restorer, hair dye, hair wax, hair form, etc. Among them, it is preferred to be a lip cosmetic selected from the group consisting of lipstick, lip gloss, and lip liner.
本發明的油性化妝料較佳係利用化妝料塗佈工具，使用於例如皮膚、嘴唇、睫毛、指甲、毛髮等適當部位。 The oily cosmetic of the present invention is preferably applied to a suitable portion such as skin, lips, eyelashes, nails, hair or the like using a cosmetic coating tool.
本發明的油性化妝料較佳係呈收納於利用化妝料塗佈工具取出的容器形態，取出的容器更佳係瓶容器、缸式容器、試管容器，其中就從抑制使用時出現液體翻倒的觀點，特佳係瓶容器、試管容器。 The oily cosmetic of the present invention is preferably stored in a form of a container taken out by a cosmetic coating tool, and the container to be taken out is more preferably a bottle container, a cylinder container, or a test tube container, wherein the liquid collapses from the suppression of use. Point of view, special bottle container, test tube container.
將容器中所收納之油性化妝料予以取出的化妝料塗佈工具，係具有供塗佈化妝料用的塗佈面，且前端設有連結該塗佈部的支撐軸。具體係可舉例如：薄片、海綿、粉撲、筆等。其中，就從初期使用時起的塗佈工具取用性、以及在嘴唇、皮膚等處的塗佈困難度之觀點，較佳係具有：供塗佈化妝料用之塗佈面且由錐狀、扁平體構成的塗佈部，以及前端連結該塗佈部的支撐軸之化妝料塗佈工具。 The cosmetic coating tool for taking out the oily cosmetic contained in the container has a coated surface for applying the cosmetic, and a support shaft that connects the coated portion is provided at the distal end. Specifically, for example, a sheet, a sponge, a puff, a pen, or the like can be mentioned. Among them, from the viewpoint of the applicability of the coating tool at the time of initial use and the difficulty in coating on the lips, the skin, and the like, it is preferable to have a coated surface for applying the cosmetic material and have a tapered shape. A coating portion composed of a flat body and a cosmetic coating tool having a front end connecting the support shaft of the coating portion.
本發明的油性化妝料係藉由收納於具備取出用化妝料塗佈工 具的化妝料容器內之形態，使從初期使用時起的塗佈工具的取用性便優異。特別係就從使用後在容器內殘留的化妝料殘餘較少之觀點，更佳係在化妝料塗佈工具上沾濕化妝料的浸漬容器。 The oily cosmetic of the present invention is stored in a cosmetic coating device for taking out In the form of the cosmetic container, the applicability of the coating tool from the initial use is excellent. In particular, from the viewpoint of less residue of the cosmetic material remaining in the container after use, it is more preferable to wet the cosmetic container in the impregnation container.
相關上述實施形態，本發明更進一步揭示以下組成物。 According to the above embodiment, the present invention further discloses the following composition.
<1>一種油性化妝料，係含有下述成分(A)、(B)及(C)：(A)主鏈具有纖維素骨架，總羥基之45~95mol%被-O-M-R基(M係表示CH2或羰基C=O；R係表示碳數3~40之直鏈或分支鏈烷基或烯基)取代的纖維素衍生物1~50質量%；(B)揮發性烴油5~80質量%；及(C)25℃下呈液狀之酯油5~50質量%，其中，於成分(B)相對於成分(C)的質量比例(B)/(C)係0.7~9，且於25℃下剪切速度為0.1s-1時，塊材整體的剪切黏度係1500Pa．s以下。 <1> An oily cosmetic containing the following components (A), (B), and (C): (A) a main chain having a cellulose skeleton, and 45 to 95 mol% of the total hydroxyl group is represented by an -OMR group (M system) CH 2 or carbonyl C=O; R represents 1 to 50% by mass of a substituted linear or branched alkyl or alkenyl group; (B) Volatile hydrocarbon oil 5 to 80 % by mass; and (C) 5 to 50% by mass of the liquid ester oil at 25 ° C, wherein the mass ratio (B) / (C) of the component (B) to the component (C) is 0.7 to 9, When the shear rate is 0.1 s -1 at 25 ° C, the overall shear viscosity of the block is 1500 Pa. s below.
<2>如上述<1>所記載的油性化妝料，其中，成分(A)的纖維素衍生物中，原料纖維素衍生物較佳係具有以下構成單元：
(式中，R'係表示碳數2~8之直鏈或分支鏈伸烷基；n係表示每葡萄糖單元的R'O平均加成莫耳數成為0.1~10之數值) 更佳係羥乙基纖維素、羥丙基纖維素，特佳係羥丙基纖維素。 (wherein R' represents a linear or branched alkyl group having 2 to 8 carbon atoms; and n represents an average molar addition of R'O per glucose unit of 0.1 to 10) More preferred is hydroxyethyl cellulose, hydroxypropyl cellulose, and particularly preferred is hydroxypropyl cellulose.
<3>如上述<1>或<2>所記載的油性化妝料，其中，成分(A)中，原料纖維素衍生物的羥基取代基之-O-M-R基中，R較佳係碳數9~21之直鏈或分支鏈烷基或烯基，更佳係碳數11~17、特佳係碳數15。 <3> The oily cosmetic according to the above <1> or <2>, wherein, in the component (A), in the -OMR group of the hydroxyl substituent of the raw material cellulose derivative, R is preferably a carbon number of 9~ A linear or branched alkyl or alkenyl group of 21, more preferably a carbon number of 11 to 17, and a particularly preferred carbon number of 15.
<4>如上述<1>~<3>中任一項所記載的油性化妝料，其中，成分(A)中，羥基的-O-M-R基取代率較佳係48mol%以上、更佳係51mol%以上，且較佳係94mol%以下、更佳係92mol%以下、特佳係66mol%以下。 The oily cosmetic according to any one of the above-mentioned items, wherein the component (A) has a -OMR group substitution ratio of a hydroxyl group of preferably 48 mol% or more, more preferably 51 mol%. The above is preferably 94 mol% or less, more preferably 92 mol% or less, and particularly preferably 66 mol% or less.
<5>如上述<1>~<4>中任一項所記載的油性化妝料，其中，成分(A)中，羥基殘留率較佳係5mol%以上、更佳係6mol%以上、特佳係8mol%以上、最佳係34mol%以上，且較佳係55mol%以下、更佳係52mol%以下、特佳係49mol%以下。 (5) The oily cosmetic according to any one of the above-mentioned items, wherein the component (A) preferably has a hydroxyl group residual ratio of 5 mol% or more, more preferably 6 mol% or more, and is particularly preferable. It is 8 mol% or more, preferably 34 mol% or more, and is preferably 55 mol% or less, more preferably 52 mol% or less, and particularly preferably 49 mol% or less.
<6>如上述<1>~<5>中任一項所記載的油性化妝料，其中，成分(A)的纖維素衍生物之質量平均分子量較佳係10萬以上、更佳係20萬以上、特佳係30萬以上、最佳係50萬以上，且較佳係500萬以下、更佳係400萬以下、特佳係300萬以下、最佳係200萬以下。 The oily cosmetic according to any one of the above-mentioned items, wherein the cellulose derivative of the component (A) preferably has a mass average molecular weight of 100,000 or more, more preferably 200,000. The above is preferably 300,000 or more, and the best is 500,000 or more, and is preferably 5,000,000 or less, more preferably 4,000,000 or less, more preferably 3,000,000 or less, and the best is 2,000,000 or less.
<7>如上述<1>~<6>中任一項所記載的油性化妝料，其中，成分(A)較佳係羥丙基纖維素月桂酸酯、羥丙基纖維素肉荳蔻酸酯、羥丙基纖維素棕櫚酸酯、羥丙基纖維素硬脂酸酯、羥丙基纖維素萮樹酸酯，更佳係羥丙基纖維素棕櫚酸酯。 The oily cosmetic according to any one of the above-mentioned items, wherein the component (A) is preferably hydroxypropylcellulose laurate or hydroxypropylcellulose myristate. Hydroxypropylcellulose palmitate, hydroxypropylcellulose stearate, hydroxypropylcellulose eucalyptus, more preferably hydroxypropylcellulose palmitate.
<8>如上述<1>~<7>中任一項所記載的油性化妝料，其中，成分(A)的含有量在總組成中較佳係1.5質量%以上、更佳係2質量%以上、特佳係3質量%以上，且較佳係30質量%以下、更佳係20質量%以下、特佳係15質量%以下、最佳係10質量%以下。 The oily cosmetic according to any one of the above-mentioned items, wherein the content of the component (A) is preferably 1.5% by mass or more, more preferably 2% by mass, based on the total composition. The above is particularly preferably 3% by mass or more, more preferably 30% by mass or less, more preferably 20% by mass or less, particularly preferably 15% by mass or less, and most preferably 10% by mass or less.
<9>如上述<1>~<8>中任一項所記載的油性化妝料，其中，成分(B)較佳係具有35~87℃之引火點。 <9> The oily cosmetic according to any one of the above-mentioned items, wherein the component (B) preferably has a firing point of 35 to 87 °C.
<10>如上述<1>~<9>中任一項所記載的油性化妝料，其中，成分(B)較佳係碳數8~16之烴油、更佳係碳數10~16之烴油、特佳係碳數12之烴油。 The oily cosmetic according to any one of the above-mentioned items, wherein the component (B) is preferably a hydrocarbon oil having a carbon number of 8 to 16, more preferably a carbon number of 10 to 16. A hydrocarbon oil, particularly a hydrocarbon oil having a carbon number of 12.
<11>如上述<1>~<10>中任一項所記載的油性化妝料，其中，成分(B)較佳係異烷烴系烴油，更佳係異十二烷、碳數12之氫化聚異丁烯，特佳係異十二烷。 The oily cosmetic according to any one of the above-mentioned items, wherein the component (B) is preferably an isoparaffinic hydrocarbon oil, more preferably isododecane or a carbon number of 12 Hydrogenated polyisobutylene, especially good isododecane.
<12>如上述<1>~<11>中任一項所記載的油性化妝料，其中，成分(B)的含有量在總組成中較佳係35質量%以上、更佳係40質量%以上、特佳係45質量%以上、最佳係46質量%以上，且較佳係75質量%以下、更佳係70質量%以下、特佳係66質量%以下。 The oily cosmetic according to any one of the above-mentioned items, wherein the content of the component (B) is preferably 35 mass% or more, more preferably 40 mass%, of the total composition. The above is particularly preferably 45% by mass or more, and most preferably 46% by mass or more, more preferably 75% by mass or less, more preferably 70% by mass or less, and particularly preferably 66% by mass or less.
<13>如上述<1>~<12>中任一項所記載的油性化妝料，其中，成分(C)的酯油較佳係具有分支鏈的酯油，更佳係異壬酸異十三烷基酯、蘋果酸二異硬脂酯、肉荳蔻酸異硬脂酯、蓖麻醇酸辛基十二烷基酯、二異硬脂酸雙甘油酯、單異硬脂酸單肉荳蔻酸甘油酯、對甲氧基肉桂酸-2-乙基己酯、單異硬脂酸雙甘油酯，特佳係異 壬酸異十三烷基酯、蘋果酸二異硬脂酯。 The oily cosmetic according to any one of the above-mentioned items, wherein the ester oil of the component (C) is preferably an ester oil having a branched chain, and more preferably isocyanuric acid. Trialkyl ester, diisostearyl malate, isostearyl myristate, octyl dodecyl ricinoleate, diglyceryl diisostearate, monoisostearic acid monomyristate Glyceryl ester, p-methoxycinnamic acid 2-ethylhexyl ester, monoisostearic acid diglyceride, especially different Isotridecyl citrate, diisostearyl malate.
<14>如上述<1>~<13>中任一項所記載的油性化妝料，其中，成分(C)的含有量在總組成中較佳係7質量%以上、更佳係10質量%以上、特佳係13質量%以上，且較佳係40質量%以下、更佳係35質量%以下、特佳係33質量%以下。 The oily cosmetic according to any one of the above-mentioned items, wherein the content of the component (C) is preferably 7% by mass or more, more preferably 10% by mass based on the total composition. The above is particularly preferably 13% by mass or more, more preferably 40% by mass or less, more preferably 35% by mass or less, and particularly preferably 33% by mass or less.
<15>如上述<1>~<14>中任一項所記載的油性化妝料，其中，成分(B)相對於成分(C)的質量比例(B)/(C)較佳係1.0以上、更佳係1.4以上，且較佳係7以下、更佳係5以下。 The oily cosmetic according to any one of the above-mentioned items (1) to (14), wherein the mass ratio (B)/(C) of the component (B) to the component (C) is preferably 1.0 or more. More preferably, it is 1.4 or more, and is preferably 7 or less, more preferably 5 or less.
<16>如上述<1>~<15>中任一項所記載的油性化妝料，其中，成分(A)相對於成分(C)的質量比例(A)/(C)較佳係0.10以上、更佳係0.12以上、特佳係0.14以上，且較佳係1.25以下、更佳係1.0以下、特佳係0.65以下。 The oily cosmetic according to any one of the above-mentioned items (1) to (15), wherein the mass ratio (A)/(C) of the component (A) to the component (C) is preferably 0.10 or more. More preferably, it is 0.12 or more, and particularly preferably 0.14 or more, and is preferably 1.25 or less, more preferably 1.0 or less, and particularly preferably 0.65 or less.
<17>如上述<1>~<16>中任一項所記載的油性化妝料，其中，更進一步含有(D)有機聚矽氧樹脂。 The oily cosmetic according to any one of the above-mentioned items, further comprising (D) an organic polyoxynoxy resin.
<18>如上述<17>所記載的油性化妝料，其中，成分(D)較佳係(D-1)三甲基矽烷氧基矽酸，更佳係以矽氧烷構造為主骨架之具交聯構造的化合物，依[(CH3)3SiO1/2]X[SiO2]Y(X係1~3、Y係0.5~8)所示。 <18> The oily cosmetic according to the above <17>, wherein the component (D) is preferably (D-1) trimethyldecyloxydecanoic acid, more preferably a decane structure as a main skeleton. The compound having a crosslinked structure is represented by [(CH 3 ) 3 SiO 1/2 ] X [SiO 2 ] Y (X system 1 to 3, Y system 0.5 to 8).
<19>如上述<18>所記載的油性化妝料，其中，(D-1)三甲基矽烷氧基矽酸的質量平均分子量較佳係1000~10000、更佳係2000~9000、特佳係3000~6000。 <19> The oily cosmetic according to the above <18>, wherein the mass average molecular weight of (D-1) trimethyldecyloxydecanoic acid is preferably from 1,000 to 10,000, more preferably from 2,000 to 9000. It is 3000~6000.
<20>如上述<17>所記載的油性化妝料，其中，成分(D)較佳係(D-2)氟改質聚矽氧樹脂，更佳係具有一般式(1)：R1 aSiO(4-a)/2 (1)(式中，R1係表示從碳數1~8之烴基、苯基、羥基、或一般式-R2-Rf(R2係表示碳數2~6之2價伸烷基；Rf係表示碳數1~8之全氟烷基)、且以羥基與一般式-R2-Rf為必須的官能基之中任意選擇，a係平均數且1.0≦a≦1.8)所示構造者。 <20> The <17> described oily cosmetic, wherein the component (D) is preferably based (D-2) a fluorine modified silicone polyethylene, more preferably having the general formula-based (1): R 1 a SiO (4-a)/2 (1) (wherein R 1 represents a hydrocarbon group having 1 to 8 carbon atoms, a phenyl group, a hydroxyl group, or a general formula -R 2 -Rf (R 2 represents a carbon number 2~) 6 is a valence alkyl group; Rf is a perfluoroalkyl group having a carbon number of 1 to 8, and is selected arbitrarily by a hydroxyl group and a general formula -R 2 -Rf, and a is an average number and 1.0. ≦a≦1.8) The constructor shown.
<21>如上述<20>所記載的油性化妝料，其中，(D-2)氟改質聚矽氧樹脂較佳係分子內具有矽醇基，且矽醇基中的OH基比例相對於樹脂質量係0.1~5質量%、更佳係0.5~5質量%。 <21> The oily cosmetic according to the above <20>, wherein the (D-2) fluorine-modified polyanthracene resin preferably has a sterol group in the molecule, and the ratio of the OH group in the decyl group is relative to The resin quality is 0.1 to 5% by mass, more preferably 0.5 to 5% by mass.
<22>如上述<17>~<21>中任一項所記載的油性化妝料，其中，成分(D)的含有量在總組成中較佳係0.01質量%以上、更佳係0.2質量%以上、特佳係0.5質量%以上、最佳係1質量%以上，且較佳係25質量%以下、更佳係20質量%以下、特佳係15質量%以下、最佳係13質量%以下。 The oily cosmetic according to any one of the above-mentioned items, wherein the content of the component (D) is preferably 0.01% by mass or more, more preferably 0.2% by mass based on the total composition. The above is particularly preferably 0.5% by mass or more, more preferably 1% by mass or more, more preferably 25% by mass or less, more preferably 20% by mass or less, particularly preferably 15% by mass or less, and most preferably 13% by mass or less. .
<23>如上述<17>~<22>中任一項所記載的油性化妝料，其中，成分(A)相對於成分(D)的質量比例(A)/(D)較佳係0.05以上、更佳係0.2以上、特佳係0.3以上、最佳係0.5以上，且較佳係40以下、更佳係20以下、特佳係12以下、最佳係10以下。 The oily cosmetic according to any one of the above-mentioned items, wherein the mass ratio (A)/(D) of the component (A) to the component (D) is preferably 0.05 or more. More preferably, it is 0.2 or more, particularly preferably 0.3 or more, and most preferably 0.5 or more, and more preferably 40 or less, more preferably 20 or less, particularly preferably 12 or less, and most preferably 10 or less.
<24>如上述<1>~<23>中任一項所記載的油性化妝料，其中，更進一步含有25℃下呈固態的蠟，而蠟較佳係熔點65℃以上且140℃以下、更佳係70℃以上且90℃以下。 The oily cosmetic according to any one of the above-mentioned items, further comprising a wax which is solid at 25 ° C, and preferably has a melting point of 65 ° C or more and 140 ° C or less. More preferably, it is 70 ° C or more and 90 ° C or less.
<25>如上述<24>所記載的油性化妝料，其中，25℃下呈固態的蠟較佳係25℃針入度1以上且150以下、更佳係15以上且110以下，特佳係針入度1以上且150以下的微晶蠟、烷烴蠟，最佳係針入度1以上且150以下的微晶蠟。 <25> The oily cosmetic according to the above <24>, wherein the wax which is solid at 25 ° C is preferably a penetration degree of 25 ° C or more and 150 or less, more preferably 15 or more and 110 or less. The microcrystalline wax or the alkane wax having a penetration degree of 1 or more and 150 or less is preferably a microcrystalline wax having a penetration degree of 1 or more and 150 or less.
<26>如上述<24>或<25>所記載的油性化妝料，其中，25℃下呈固態的蠟含有量在總組成中較佳係未滿5質量%、更佳係3質量%以下、特佳係1質量%以下、最佳係0.5質量%以下。 <26> The oil-based cosmetic composition according to the above <24>, wherein the wax content in a solid state at 25 ° C is preferably less than 5% by mass, more preferably less than 3% by mass, based on the total composition. It is more preferably 1% by mass or less, and most preferably 0.5% by mass or less.
<27>如上述<1>~<26>中任一項所記載的油性化妝料，其中，更進一步含有粉體，而粉體較佳係體質顏料、著色顏料、鮮亮性顏料。 The oily cosmetic according to any one of the above-mentioned items, wherein the oily cosmetic further contains a powder, and the powder is preferably a body pigment, a coloring pigment or a bright pigment.
<28>如上述<27>所記載的油性化妝料，其中，粉體含有量在總組成中較佳係0.01質量%以上、更佳係0.05質量%以上、特佳係20質量%以下、最佳係10質量%以下。 <28> The oily cosmetic composition according to the above <27>, wherein the powder content is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, particularly preferably 20% by mass or less, and most preferably the total composition. The best quality is 10% by mass or less.
<29>如上述<1>~<28>中任一項所記載的油性化妝料，其中，25℃剪切速度0.1s-1時，塊材整體的剪切黏度較佳係900Pa．s以下、更佳係500Pa．s以下、特佳係250Pa．s以下、最佳係200Pa．s以下，且較佳係10Pa．s以上、更佳係20Pa．s以上、特佳係30Pa．s以上。 <29> The oily cosmetic according to any one of <1> to <28> wherein, when the shear rate is 0.1 s -1 at 25 ° C, the shear viscosity of the entire block is preferably 900 Pa. s below, better 500Pa. s below, especially good 250Pa. s below, the best system is 200Pa. s below, and preferably 10 Pa. Above s, better than 20Pa. Above s, especially good 30Pa. s above.
<30>如上述<1>~<29>中任一項所記載的油性化妝料，係嘴唇化妝料。 <30> The oily cosmetic according to any one of the above <1> to <29>, which is a lip cosmetic.
<31>一種使用方法，係將上述<1>~<30>中任一項所記載的油性化妝料使應用於嘴唇的使用。 <31> The use of the oily cosmetic according to any one of the above <1> to <30> to the use of the lips.
<32>一種上述<1>~<30>中任一項所記載的油性化妝料之使用，係用於製造油性化妝料。 <32> The use of the oily cosmetic according to any one of the above <1> to <30> for producing an oily cosmetic.
<33>一種使用方法，係將上述<1>~<30>中任一項所記載的油性化妝料，利用化妝料塗佈工具應用於嘴唇。 <33> The oily cosmetic according to any one of the above <1> to <30>, which is applied to the lips by a cosmetic coating tool.
在氮下，於甲苯、甲乙酮混合溶劑中，於50℃下在57.8g(0.165mol)羥丙基纖維素(Celny M；日本曹達公司製)中添加94g(1.01mol)3-甲基吡啶而使溶解。歷時0.5小時滴下85.1g(0.31mol)軟脂醯氯(palmitoyl chloride)。然後，於50℃下進行5小時反應，在乙醇中沉澱而精製，經乾燥，獲得羥丙基纖維素棕櫚酸酯。(質量平均分子量150萬、平均醯基取代度係總羥基的60mol%) Under nitrogen, 94 g (1.01 mol) of 3-methylpyridine was added to 57.8 g (0.165 mol) of hydroxypropylcellulose (Celny M; manufactured by Nippon Soda Co., Ltd.) at 50 ° C in a mixed solvent of toluene and methyl ethyl ketone. Soluble. 85.1 g (0.31 mol) of palmitoyl chloride was added dropwise over 0.5 hours. Then, the reaction was carried out at 50 ° C for 5 hours, and it was purified by precipitation in ethanol, and dried to obtain hydroxypropylcellulose palmitate. (mass average molecular weight 1.5 million, average thiol substitution degree is 60 mol% of total hydroxyl groups)
聚合體的平均分子量(Mw)係使用日立L-6000型高速液相色層分析儀，利用凝膠滲透色層分析儀(GPC)進行測定。洗提液流路泵係使用日立L-6000，檢測器係使用SHODEX RI SE-61微差折射率檢測器，管柱係使用由GMHHR-H呈雙層連接者。樣品係利用洗提液調整為0.5g/100mL濃度並使用20μL。洗提液係使用1mol/L之N,N-二甲基十二烷基胺(FAMIN DM20、花王公司製)的氯仿溶液。依管柱溫度40℃、流速1.0mL/分進行。 The average molecular weight (Mw) of the polymer was measured by a gel permeation chromatography (GPC) using a Hitachi L-6000 high-speed liquid chromatography analyzer. The eluent flow path pump uses the Hitachi L-6000, the detector uses the SHODEX RI SE-61 differential refractive index detector, and the column system uses a double-layered connection by GMHHR-H. The sample was adjusted to a concentration of 0.5 g/100 mL using an eluent and 20 μL was used. The eluent was a solution of 1 mol/L of N,N-dimethyldodecylamine (FAMIN DM20, manufactured by Kao Corporation) in chloroform. The column temperature was 40 ° C and the flow rate was 1.0 mL / min.
H-NMR中，經酯化纖維素的羰基相鄰之次甲基(methine group)的質子係在5ppm附近出現，纖維素的六元環氧相鄰之質子、與纖維素的羥基相鄰之亞甲基的合計係在3.5ppm附近出現。由該積分值計算出。 In H-NMR, the proton system of the methine group adjacent to the carbonyl group of the esterified cellulose appears in the vicinity of 5 ppm, and the proton of the six-membered epoxy adjacent to the cellulose is adjacent to the hydroxyl group of the cellulose. The total of methylene groups appeared in the vicinity of 3.5 ppm. Calculated from the integral value.
在氮下，於甲苯、甲乙酮混合溶劑中，於50℃下在57.8g(0.165mol)羥丙基纖維素(Celny M；日本曹達公司製)中添加231.2g(2.46mol)3-甲基吡啶而使溶解。歷時0.5小時滴下122.5g(0.44mol)軟脂醯氯。然後，於50℃下進行5小時反應，在乙醇中沉澱而精製，且經乾燥後，獲得羥丙基纖維素棕櫚酸酯。(質量平均分子量100萬、平均醯基取代度係總羥基的80mol%) Under nitrogen, 237.8 g (2.46 mol) of 3-methylpyridine was added to 57.8 g (0.165 mol) of hydroxypropylcellulose (Celny M; manufactured by Nippon Soda Co., Ltd.) at 50 ° C in a mixed solvent of toluene and methyl ethyl ketone. And make it dissolve. 122.5 g (0.44 mol) of soft lipid bismuth chloride was added over 0.5 hours. Then, the reaction was carried out at 50 ° C for 5 hours, precipitated in ethanol to be purified, and after drying, hydroxypropylcellulose palmitate was obtained. (mass average molecular weight of 1 million, average thiol substitution degree is 80 mol% of total hydroxyl groups)
在氮下，於甲苯、甲乙酮混合溶劑中，於50℃下在57.8g(0.165mol)羥丙基纖維素(Celny M；日本曹達公司製)中添加232.8g(2.5mol)3-甲基吡啶而使之溶解。歷時0.5小時滴下300.0g(1.09mol)軟脂醯氯。然後，於50℃下進行5小時反應，在乙醇中沉澱而精製，經乾燥，獲得羥丙基纖維素棕櫚酸酯。(質量平均分子量87萬、平均醯基取代度係總羥基的90mol%) Under nitrogen, 232.8 g (2.5 mol) of 3-methylpyridine was added to 57.8 g (0.165 mol) of hydroxypropylcellulose (Celny M; manufactured by Nippon Soda Co., Ltd.) at 50 ° C in a mixed solvent of toluene and methyl ethyl ketone. And make it dissolve. 300.0 g (1.09 mol) of soft lipid bismuth chloride was added over 0.5 hours. Then, the reaction was carried out at 50 ° C for 5 hours, and it was purified by precipitation in ethanol, and dried to obtain hydroxypropylcellulose palmitate. (mass average molecular weight 870,000, average thiol substitution degree is 90 mol% of total hydroxyl groups)
在氮下，氯仿中，於室溫下在5g(8.3×10-6mol)羥丙基纖維素(Celny M；日本曹達公司製)中，添加19.9克(0.21mol)3-甲基吡啶 而使溶解。歷時0.5小時滴下20.6g(0.094mol)月桂醯氯。然後，於50℃下進行15小時反應，在甲醇中沉澱而精製，經乾燥，獲得羥丙基纖維素月桂酸酯。(質量平均分子量80萬、平均醯基取代度係總羥基的90mol%) Under nitrogen, in chloroform, 5 g (8.3 × 10 -6 mol) of hydroxypropylcellulose (Celny M; manufactured by Nippon Soda Co., Ltd.) was added at room temperature, and 19.9 g (0.21 mol) of 3-methylpyridine was added thereto. Soluble. 20.6 g (0.094 mol) of lauryl chloride was added dropwise over 0.5 hours. Then, the reaction was carried out at 50 ° C for 15 hours, and it was purified by precipitation in methanol, and dried to obtain hydroxypropylcellulose laurate. (mass average molecular weight 800,000, average thiol substitution degree is 90 mol% of total hydroxyl groups)
在氮下，於甲苯、甲乙酮混合溶劑中，於50℃下在57.8g(0.165mol)羥丙基纖維素(Celny M；日本曹達公司製)中添加93.8g(1mol)3-甲基吡啶而使之溶解。歷時0.5小時滴下47.6g(0.17mol)軟脂醯氯。然後，於50℃下進行5小時反應，在乙醇中沉澱而精製，經乾燥，獲得羥丙基纖維素棕櫚酸酯。(質量平均分子量75萬、平均醯基取代度係總羥基的30mol%) Under nitrogen, 93.8 g (1 mol) of 3-methylpyridine was added to 57.8 g (0.165 mol) of hydroxypropylcellulose (Celny M; manufactured by Nippon Soda Co., Ltd.) at 50 ° C in a mixed solvent of toluene and methyl ethyl ketone. Dissolve it. 47.6 g (0.17 mol) of soft lipid bismuth chloride was added over 0.5 hours. Then, the reaction was carried out at 50 ° C for 5 hours, and it was purified by precipitation in ethanol, and dried to obtain hydroxypropylcellulose palmitate. (mass average molecular weight of 750,000, average thiol substitution degree is 30 mol% of total hydroxyl groups)
製造表1所示組成的口紅，測定塊材的剪切黏度，且針對剛塗佈後的粗硬度、剛塗佈後的刺痛感、剛塗佈後使嘴唇對搓時的滑順度、剛塗佈後在磁磚上的二次附著性(色差△E)、經塗佈4小時後在磁磚上的二次附著性(色差△E)、剛塗佈後的移染困難度、經塗佈4小時後的移染困難度、經塗佈4小時後的嘴唇上之口紅起皺困難度、剛塗佈後的耐水性、及口紅卸除困難度進行評價。結果合併整理於表1。 The lipstick of the composition shown in Table 1 was produced, and the shear viscosity of the bulk material was measured, and the rough hardness immediately after application, the tingling feeling immediately after application, the smoothness of the lips immediately after application, and the smoothness of the lips immediately after application, Secondary adhesion on the tile immediately after coating (color difference ΔE), secondary adhesion on the tile after 4 hours of coating (color difference ΔE), difficulty in transfer dye immediately after coating, The degree of difficulty in the transfer after 4 hours of application, the difficulty in wrinkling the lipstick on the lips after 4 hours of application, the water resistance immediately after application, and the difficulty in removing the lipstick were evaluated. The results are combined in Table 1.
將色材以外的基劑原料施行加熱溶解而均勻混合，冷卻至40 ℃。在其中添加色材原料，利用分散機施行均勻分散，經脫泡後，流入容器中便獲得口紅。 The base material other than the color material is heated and dissolved, uniformly mixed, and cooled to 40 °C. The color material is added thereto, and uniformly dispersed by a disperser, and after defoaming, a lipstick is obtained by flowing into the container.
針對所調製塊材使用流變儀(MCR301；Anton Paar公司製)，測定25℃剪切黏度。夾具係使用25mm物，讀取剪切速度0.1s-1時的剪切黏度。 A rheometer (MCR301; manufactured by Anton Paar Co., Ltd.) was used for the prepared bulk material, and the shear viscosity at 25 ° C was measured. Fixture system 25 mm, the shear viscosity at a shear rate of 0.1 s -1 was read.
由專業審查人員10位將各口紅塗佈於嘴唇，針對經5分鐘後的粗硬度進行官能評價。結果依評比為良好(沒有粗硬)的審查人員人數表示。 Each lipstick was applied to the lips by 10 professional examiners, and the hardness was evaluated for the hardness after 5 minutes. The results are expressed in terms of the number of reviewers who are good (no rough).
由專業審查人員10位將各口紅塗佈於嘴唇，針對經5分鐘後的刺痛感進行官能評價。結果依評比為良好(沒有刺痛感)的審查人員人數表示。 Each lipstick was applied to the lips by 10 professional examiners, and the tingling feeling after 5 minutes was evaluated for the sensation. The results were expressed by the number of reviewers who rated well (no tingling).
由專業審查人員10位將各口紅塗佈於嘴唇，針對經5分鐘後使嘴唇對搓時的滑順度進行官能評價。結果依評比為良好(有滑順性)的審查人員人數表示。 Each of the lipsticks was applied to the lips by 10 professional examiners, and the smoothness of the lips when the lips were confronted after 5 minutes was evaluated. The results are expressed in terms of the number of reviewers who are good (smooth).
在嘴唇上適量塗佈口紅，經5分鐘後與經4小時後，將口紅轉印於白磁磚，針對顏色附著的部分進行測色。利用下式求取與白磁磚的色差△E。 A proper amount of lipstick was applied to the lips, and after 5 minutes and after 4 hours, the lipstick was transferred to a white tile, and the color-attached portion was subjected to color measurement. The color difference ΔE with the white tile is obtained by the following formula.
△E=(△L2+△a2+△b2)1/2 △E=(△L 2 +Δa 2 +Δb 2 ) 1/2
．白磁磚：住家用陶瓷製磁磚(INAX公司製、10cm×10cm) . White tile: live ceramic tile (made by INAX, 10cm × 10cm)
白磁磚測色值係L=93.7、a=0.86、b=3.95 White tile color measurement values are L=93.7, a=0.86, b=3.95
．測色器：色差計CR-300(Minolta公司製) . Colorimeter: Color Difference Meter CR-300 (manufactured by Minolta Co., Ltd.)
由專業審查人員10位將各口紅塗佈於嘴唇，針對經5分鐘後與經4小時後使嘴唇碰觸杯子時的移染困難度進行官能評價。結果依評比為良好(不易移染)的審查人員人數表示。 Each of the lipsticks was applied to the lips by 10 professional examiners, and the degree of difficulty in the transfer of the lips after 5 minutes and after the lips were touched for 4 hours was evaluated. The results are expressed in terms of the number of reviewers who are good (not easy to transfer).
由專業審查人員10位將各口紅塗佈於嘴唇，針對經4小時後嘴唇上的口紅起皺困難度進行官能評價。結果依評比為良好(不易起皺)的審查人員人數表示。 Each lipstick was applied to the lips by 10 professional examiners, and the sensory evaluation was performed on the difficulty of wrinkling the lipstick on the lips after 4 hours. The results are expressed in terms of the number of reviewers who are good (not easy to wrinkle).
將各口紅塗佈於嘴唇後，針對嘴唇濕潤狀態下的移染度進行評價。 After applying each lipstick to the lips, the degree of transfection in the wet state of the lips was evaluated.
由專業審查人員10位將各口紅塗佈於嘴唇，經5分鐘後舉起裝有20℃水的杯子並喝水，針對杯子上的移染程度進行官能評價。 結果依評比為良好(不易移染)的審查人員人數表示。 Each lipstick was applied to the lips by 10 professional examiners, and after 5 minutes, the cup containing 20 ° C water was lifted and water was given, and the degree of transfer on the cup was evaluated for the function. The results are expressed in terms of the number of reviewers who are good (not easy to transfer).
由專業審查人員10位將各口紅塗佈於嘴唇，經4小時後，彩妝卸除該口紅，針對利用(Biore卸妝用深層卸妝棉富含保濕)卸除時的卸除困難度進行官能評價。結果依評比為良好(可乾淨完全卸除)的審查人員人數表示。 The lipstick was applied to the lips by 10 professional examiners, and after 4 hours, the lipstick was removed from the makeup, and the sensory evaluation was performed for the difficulty in removal when the Biore remover deep cleansing cotton was moisturized. The results are expressed in terms of the number of reviewers who are good (can be cleaned and completely removed).
依照與實施例1~15同樣地製作表2及表3所示組成的口紅，測定塊材的剪切黏度。 Lipsticks of the compositions shown in Tables 2 and 3 were prepared in the same manner as in Examples 1 to 15, and the shear viscosity of the bulk materials was measured.
所獲得口紅均係剛塗佈後沒有粗硬與刺痛感、剛塗佈後使嘴唇對搓時的滑順度、剛塗佈後及經塗佈4小時後抑制在磁磚上的二次附著性、剛塗佈後及經塗佈4小時後不易移染、經塗佈4小時後嘴唇上的口紅不易起皺、剛塗佈後的耐水性優異、且可乾淨地完全卸除口紅。 The obtained lipsticks were not smooth and tingling immediately after application, smoothness when the lips were facing immediately after application, and were suppressed twice on the tile immediately after application and after coating for 4 hours. Adhesiveness, after application, and after 4 hours of application, it is not easy to transfer, and after 4 hours of application, the lipstick on the lips is not easily wrinkled, the water resistance immediately after application is excellent, and the lipstick can be completely removed cleanly.
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| JP2004300093A (en) * | 2003-03-31 | 2004-10-28 | Kose Corp | Lipstick overcoat |
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