TW201603706A - Heat evaporation type insect pest-controlling tool - Google Patents

Abstract

The purpose of the present invention is to provide an insect pest-controlling tool which is capable of suppressing the transpiration of an insecticide contained in an insecticide-holding member, said transpiration of the insecticide being caused by unnecessary heat generation by a heat source when used either indoor or outdoor within a short period of time, which is repeatedly usable and which is capable of transpiring the insecticide while preventing the insecticide-holding member from being taken out by babies or infants. To achieve this purpose, provided is a heat evaporation type insect pest-controlling tool comprising a container (1), a heat source (2) that is housed in the container (1) and provided with a heating element (21) generating heat when exposed to oxygen, and an insecticide-holding part (3) that is formed on the outer surface of the heat source (2) and contains an insecticide, wherein the container (1) is provided with ventilation holes (111) communicating the inside and outside of the container (1) and a lid (12) capable of freely opening and closing the ventilation holes (111).

Description

加熱蒸散型害蟲驅除具 Heated evapotranspiration pest repellent

本發明係關於在屋外活動時，不使用電或氣體而利用化學反應熱使殺蟲性成分蒸發以驅除害蟲之害蟲驅除具。 The present invention relates to a pest repellent for repelling insecticidal components by chemical reaction heat without using electricity or gas when living outdoors.

過去，已知有各種不使用電或氣體等之需要燃料之能源，而在屋外活動時，用以保護身體免受蚊、蠅、虻、蜂等害蟲叮咬之驅除具。 In the past, there have been known various types of repellents that do not use electricity, gas, or the like, and that are used to protect the body from pests such as mosquitoes, flies, cockroaches, and bees.

例如，專利文獻1揭示在具有通氣孔6之收納容器5內部中具備經化學反應而發出熱之發熱體組成物3、及設置於其外側之藥劑含浸體8，使用發熱體組成物之化學反應熱使含浸於藥劑含浸體8中之殺蟲成分蒸發而使用之殺蟲器具及殺蟲方法。 For example, Patent Document 1 discloses that a heat generating body composition 3 which is chemically reacted to generate heat and a chemical impregnated body 8 provided outside the storage container 5 having the vent hole 6 are used, and a chemical reaction using the heat generating body composition is disclosed. An insecticidal device and an insecticidal method for evaporating the insecticidal component impregnated in the chemical impregnated body 8 by heat.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本特開2001-316203號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2001-316203

然而，專利文獻1所記載之發明係在收納容器之本體與蓋部設置許多通氣孔，但未設置用以封閉該等之手段。因此，例如僅在短時間於庭院之家庭菜園中作業時，於作業結束後仍持續發熱直至發熱體組成物之化學反應結束為止，而有自藥劑含浸體揮散必要以上之殺蟲成分而造成浪費之情況。此外，若為了防止浪費而取出藥劑含浸體，可抑制殺蟲成分之揮散，但由於至少仍無法抑制發熱體組成物之化學反應，故仍使發熱體組成物持續不必要之化學反應。 However, the invention described in Patent Document 1 is provided with a plurality of vent holes in the main body and the lid portion of the storage container, but means for closing the same is not provided. Therefore, for example, when working in a home garden in a garden for a short period of time, heat is continued after the end of the work until the chemical reaction of the composition of the heat generating body is completed, and the insecticidal component of the chemical impregnated body is dissipated to cause waste. The situation. Further, if the chemical impregnated body is taken out in order to prevent waste, the scattering of the insecticidal component can be suppressed, but at least the chemical reaction of the heat generating body composition cannot be suppressed, so that the heating element composition continues the unnecessary chemical reaction.

另外，專利文獻1所記載之發明由於在收容容器之本體上設置蓋部，故有嬰幼兒誤取下蓋部，使手接觸到內部之藥劑含浸體之可能性。由於嬰幼兒有將手所接觸之物品放入口中之習性，故有誤吸入殺蟲成分之虞。 Further, in the invention described in Patent Document 1, since the lid portion is provided on the main body of the storage container, there is a possibility that the infant accidentally removes the lower lid portion and brings the hand into contact with the internal drug impregnated body. Since infants and young children have the habit of putting the items in contact with the hands in the mouth, they inadvertently inhale the insecticidal ingredients.

因此，本發明之目的係提供一種即使在屋外或屋內僅短時間使用時，仍可抑制必要以上之熱源發熱，抑制保持藥劑之構件中所含藥劑揮散，不僅可使用1次而可使用複數次，再者，使嬰幼兒無法取出保持藥劑之構件而仍可使藥劑揮散之害蟲驅除具。 Accordingly, it is an object of the present invention to provide a heat source that suppresses heat generation more than necessary when used outdoors or indoors, and suppresses volatilization of a drug contained in a member for holding a drug, and can be used not only once but also plural. Secondly, in addition, the infant is unable to remove the pest repellent which retains the components of the medicament while still allowing the medicament to be volatilized.

[1]亦即，本發明係一種加熱蒸散型害蟲驅除具，其特徵係具備收容容器、收納於前述收容容器之內 部，具有藉由氧而發熱之發熱體之熱源、與設置於前述熱源之外表面，具有害蟲驅除劑之藥劑保持部，前述收容容器具備連通前述收容容器之內外之通氣孔、與自由開閉前述通氣孔之蓋部。 [1] That is, the present invention relates to a heated evapotranspiration pest repellent, characterized in that it is provided with a storage container and is housed in the storage container. a heat source having a heat generating body that generates heat by oxygen, and a drug holding portion provided with a pest repellent on a surface provided on the outer surface of the heat source, wherein the storage container includes a vent hole that communicates with the inside and the outside of the storage container, and is freely opened and closed The cover of the vent.

[2]如[1]所記載之加熱蒸散型害蟲驅除具，其中前述害蟲驅除劑具備揮發性，且係擬除蟲菊酯(pyrethroid)系化合物或天然精油成分之至少一者。 [2] The heated evapotranspiration type pest repellent according to [1], wherein the pest repellent is volatile and is at least one of a pyrethroid compound or a natural essential oil component.

[3]如前述[1]或前述[2]所記載之加熱蒸散型害蟲驅除具，其中前述藥劑保持部係由含浸前述害蟲驅除劑之藥劑含浸層、支撐並抵接前述藥劑含浸層之支撐層、及接著於前述熱源之外表面之黏著層之複數層所成。 [3] The heated evapotranspiration type pest repellent according to the above [1], wherein the drug retaining portion is supported by a chemical impregnated layer impregnated with the pest repellent, and supported and abutted against the chemical impregnated layer. The layer and the plurality of layers of the adhesive layer on the outer surface of the heat source are formed.

[4]如前述[1]至前述[3]中任一項所記載之加熱蒸散型害蟲驅除具，其中前述收容容器及蓋部具有遮光性。 [4] The heat-dissipating type pest repellent according to any one of the above [1], wherein the storage container and the lid portion have a light-shielding property.

[5]如前述[1]至前述[4]中任一項所記載之加熱蒸散型害蟲驅除具，其中前述收容容器及蓋部被施以由藉由金屬或氧化金屬化合物蒸鍍、混練紫外線吸收劑、經著色選出之至少一種加工。 The above-described storage container and the lid portion are subjected to vapor deposition by a metal or an oxidized metal compound, and the ultraviolet rays are kneaded by the method of the above-mentioned [1] to [4]. The absorbent is at least one processed by coloring.

[6]如前述[1]至前述[5]中任一項所記載之加熱蒸散型害蟲驅除具，其中前述藥劑保持部之外表面具備光折射率與周圍不同之標幟部，依據前述害蟲驅除劑之減少使設置於前述標幟部之由文字、圖型、記號選出之1或2種以上浮起。 [6] The heated evapotranspiration type pest repellent according to any one of the above [1], wherein the outer surface of the drug holding portion has a label portion having a refractive index different from that of the periphery, according to the pest The reduction of the repellent causes one or more types selected from the character, the pattern, and the mark provided in the marker portion to float.

依據本發明，即使在屋外或屋內僅短時間使用時，仍可抑制必要以上之熱源發熱，抑制保持藥劑之構件中所含藥劑揮散，可不僅使用1次而可使用複數次，且一方面使嬰幼兒無法取出保持藥劑之構件，一方面仍可使藥劑揮散。 According to the present invention, even when it is used outdoors or indoors for a short period of time, it is possible to suppress the heat generation of the heat source more than necessary, and to suppress the volatilization of the medicine contained in the member for holding the drug, and it can be used not only once but also plural times, and on the one hand It is impossible for the infant to take out the components for holding the medicament, and on the other hand, the medicament can be volatilized.

1‧‧‧收容容器 1‧‧‧ containment container

11‧‧‧蓋住開口之構件 11‧‧‧ Covering the opening

111‧‧‧通氣孔 111‧‧‧Ventinel

12‧‧‧蓋部 12‧‧‧ 盖部

2‧‧‧熱源 2‧‧‧heat source

21‧‧‧發熱體 21‧‧‧heating body

22‧‧‧包裝體 22‧‧‧Package

3‧‧‧藥劑保持部 3‧‧‧Pharmaceutical Maintenance Department

31‧‧‧藥劑含浸層 31‧‧‧Drug layer

32‧‧‧支撐層 32‧‧‧Support layer

33‧‧‧黏著層 33‧‧‧Adhesive layer

4‧‧‧標識部 4‧‧‧ Identification Department

圖1為本發明一實施形態之立體圖。 Fig. 1 is a perspective view showing an embodiment of the present invention.

圖2為本發明一實施形態之A-A線剖面圖。 Fig. 2 is a cross-sectional view taken along line A-A of the embodiment of the present invention.

圖3為關於本發明一實施形態之熱源(部分剖斷)與藥劑保持部之分解立體圖。 Fig. 3 is an exploded perspective view showing a heat source (partially cut) and a drug holding portion according to an embodiment of the present invention.

圖4為本發明一實施形態之B-B線剖面圖。 Figure 4 is a cross-sectional view taken along line B-B of an embodiment of the present invention.

以下，針對與本發明之加熱蒸散型害蟲驅除具之實施形態加以詳細說明。又，說明中有表示範圍之記述時，係包含上限與下限者。 Hereinafter, embodiments of the heated evapotranspiration pest repellent of the present invention will be described in detail. In addition, in the description, when the description of the range is included, the upper limit and the lower limit are included.

本發明一實施形態之加熱蒸散型害蟲驅除具係如圖1及圖2所示，於收容容器1之內部收容熱源2與藥劑保持部3者。而且，藥劑保持部3貼合於熱源2上，熱源2與藥劑保持部3密著。 As shown in FIGS. 1 and 2, the heating-evaporable pest repellent according to the embodiment of the present invention accommodates the heat source 2 and the drug holding portion 3 inside the storage container 1. Further, the drug holding unit 3 is bonded to the heat source 2, and the heat source 2 is adhered to the drug holding unit 3.

收容容器1為將熱源2與藥劑保持部3密封 之袋狀容器。本實施形態中，收容容器1雖為袋狀但在其他實施形態中亦可為箱狀等。 The storage container 1 is for sealing the heat source 2 and the medicine holding portion 3 Bag-shaped container. In the present embodiment, the storage container 1 has a bag shape, but in another embodiment, it may be a box shape or the like.

而且，於收容容器1之一側面上設置開口，於蓋住其開口之構件11上穿孔有貫穿收容容器1內外之複數個通氣孔111。藥劑保持部中所含之害蟲驅除劑由該通氣孔111擴散到收容容器1之外部。據此，由於具有藉由收容容器1、蓋住收容容器1之開口之構件11，而不會自外部直接接觸含害蟲驅除劑之藥劑保持部3之構造，故可防範嬰幼兒將藥劑保持部3放入口中而誤飲害蟲驅除劑。又，本實施形態中，通氣孔111係以直徑數mm至數cm左右之圓形孔加以圖示，但只要能使害蟲驅除劑擴散至收容容器1之外部即可，其他實施形態中亦可為利用複數條纖維編織而成之網眼狀。 Further, an opening is provided on one side of the storage container 1, and a plurality of vent holes 111 penetrating the inside and the outside of the storage container 1 are pierced in the member 11 covering the opening. The pest repellent contained in the drug holding portion is diffused to the outside of the storage container 1 by the vent hole 111. According to this configuration, since the member 11 for covering the opening of the storage container 1 is housed in the container 1, the structure of the drug holding portion 3 containing the pest repellent is not directly contacted from the outside, so that the infant holding the drug holding portion can be prevented. 3 Put in the mouth and accidentally drink the pest repellent. Further, in the present embodiment, the vent hole 111 is illustrated as a circular hole having a diameter of several mm to several cm, but the pest repellent may be diffused to the outside of the storage container 1, and other embodiments may be used. It is a mesh shape woven with a plurality of fibers.

而且，設置密封於收容容器1之一側面之開口部之蓋部12，蓋部12為蓋住通氣孔111且可開放之構件。蓋部12之背面，亦即與收容容器1抵接之面中之與收容容器1抵接之部位設置黏著劑，可使通氣孔111自由開閉。藉由使蓋部12密著於收容容器1，對通氣孔111加蓋，可防止害蟲驅除劑自收容容器1擴散至外部，且同時防止空氣中之氧流入到收容容器1之內部。因此，於不使用本發明時，若以蓋部12封閉通氣孔111，由於可抑制因熱源2中因氧化之發熱，故可不消耗必要以上之熱源2，而且，由於不藉由熱源2加熱故可防止害蟲驅除劑自藥劑保持部3不必要之揮發。且，即使蟲驅除劑揮發，仍 可侷限在收容容器1內部，可防止擴散到收容容器1之外部。另一方面，蓋部12可自收容容器1完全剝離以使收容容器1之內外連通之方式使所有通氣孔111開放，且亦可自收容容器1剝離一半左右使通氣孔111之一半左右同樣開放。如此，藉由蓋部12之開閉，可於複數次持續使用直到熱源2中不再因氧化而發熱為止，或直到藥劑保持部3中所含之害蟲驅除劑用完為止。又，本實施形態中，蓋部12係以可與收容容器1分離之個別體圖示，但蓋部12只要能使通氣孔111自由開閉即可，另一實施形態中蓋部12亦可與收容容器1成為一體而設置。 Further, a lid portion 12 that is sealed to an opening portion of one side of the storage container 1 is provided, and the lid portion 12 is a member that covers the vent hole 111 and is openable. The back surface of the lid portion 12, that is, the portion on the surface abutting on the storage container 1 that is in contact with the storage container 1 is provided with an adhesive, and the vent hole 111 can be opened and closed freely. By attaching the lid portion 12 to the storage container 1 and covering the vent hole 111, the pest repellent can be prevented from diffusing from the storage container 1 to the outside, and at the same time, oxygen in the air can be prevented from flowing into the inside of the storage container 1. Therefore, when the vent hole 111 is closed by the lid portion 12, the heat generation due to oxidation in the heat source 2 can be suppressed, so that the heat source 2 or more is not required to be consumed, and since it is not heated by the heat source 2, It is possible to prevent the pest repellent from being volatilized unnecessarily from the drug holding portion 3. And even if the insect repellent is volatilized, It can be confined inside the storage container 1 and can be prevented from diffusing to the outside of the storage container 1. On the other hand, the lid portion 12 can be completely peeled off from the storage container 1 so that all the vent holes 111 are opened in such a manner that the inside and the outside of the storage container 1 are communicated, and one half of the vent hole 111 can be peeled off from the storage container 1 so that one half of the vent hole 111 is also opened. . As described above, the opening and closing of the lid portion 12 can be continued for a plurality of times until the heat source 2 is no longer heated by oxidation, or until the pest repellent contained in the medicine holding portion 3 is used up. Further, in the present embodiment, the lid portion 12 is illustrated as an individual body that can be separated from the storage container 1. However, the lid portion 12 may be configured to open and close the vent hole 111. In another embodiment, the lid portion 12 may be The storage container 1 is provided integrally.

而且，收容容器1與蓋部12之材料較好係由聚乙烯、尼龍、聚胺基甲酸酯等之熱可塑性樹脂之薄膜構成。而且，該等收容容器1與蓋部12之材料更好為於熱可塑性樹脂上施以選自如下之至少一種加工：蒸鍍鋁、二氧化矽、氧化鋁等金屬、氧化金屬化合物；混練苯并***系化合物、二苯甲酮系化合物、水楊酸系化合物、氰基丙烯酸酯系化合物、鎳系化合物、三嗪系化合物等紫外線吸收劑；及以白色、藍色、綠色之顏料或染料予以著色。收容容器1與蓋部12之材料藉由施以上述加工，而具有遮光性。亦即，可防止或減低太陽光等中所含之紫外線等透過至收容容器1與蓋部12之內部，故可抑制藥劑保持部3中所含之害蟲驅除劑之分解等。此外，蒸鍍金屬、氧化金屬化合物時，由於亦一併具有遮光性以及氣體阻隔性，故可防止氧自收容容器1與蓋部12之外部透過到內部， 且可抑制熱源2之因氧化而發熱。 Further, the material of the storage container 1 and the lid portion 12 is preferably made of a film of a thermoplastic resin such as polyethylene, nylon or polyurethane. Moreover, the material of the storage container 1 and the lid portion 12 is preferably such that at least one of the following processes is applied to the thermoplastic resin: metal such as vapor deposition of aluminum, ceria, alumina, or oxidized metal compound; a UV absorber such as a triazole compound, a benzophenone compound, a salicylic acid compound, a cyanoacrylate compound, a nickel compound or a triazine compound; and a white, blue, green pigment or The dye is colored. The material of the storage container 1 and the lid portion 12 is light-shielding by the above-described processing. In other words, it is possible to prevent or reduce the penetration of ultraviolet rays or the like contained in sunlight or the like into the inside of the storage container 1 and the lid portion 12, so that decomposition of the pest repellent contained in the drug holding portion 3 can be suppressed. Further, when the metal or the metal oxide compound is vapor-deposited, since light shielding property and gas barrier property are also provided, oxygen can be prevented from being transmitted from the outside of the storage container 1 and the lid portion 12 to the inside. Moreover, heat generation due to oxidation of the heat source 2 can be suppressed.

熱源2為具有利用氧而發熱之發熱體21與具有通氣性之包裝體22者。發熱體21為利用因氧之氧化反應而生成之反應熱而發熱之粉末狀或粒狀之物質。具體而言，係由能氧化反應之鐵粉、吸附空氣之活性碳、水分、吸水性化合物等所成之複合物。鐵粉等金屬會與空氣中之氧反應而發熱。而且，藉由調整該等之調配量，可某種程度地控制發熱時之溫度及發熱之時間。 The heat source 2 is a heat generating body 21 that generates heat by using oxygen and a package body 22 having air permeability. The heating element 21 is a powdery or granular material that generates heat by the reaction heat generated by the oxidation reaction of oxygen. Specifically, it is a composite of iron powder capable of oxidizing reaction, activated carbon adsorbing air, water, and a water-absorbing compound. Metals such as iron powder react with oxygen in the air to generate heat. Moreover, by adjusting the amount of these adjustments, the temperature at the time of heat generation and the time of heat generation can be controlled to some extent.

包裝體22為具有使氧透過之通氣性，且為袋狀者。於其內部收容發熱體21。至於包裝體22，可使用具有通氣性但不使發熱體21洩漏之不織布等。使用時，接受發熱體21之發熱使包裝體22加熱，再使其熱傳遞至密著於包裝體22中之藥劑保持部3。 The package 22 has a gas permeability to allow oxygen to permeate and has a bag shape. The heating element 21 is housed inside. As the package 22, a non-woven fabric or the like which has air permeability but does not leak the heat generating body 21 can be used. At the time of use, the package body 22 is heated by the heat generated by the heating element 21, and the heat is transferred to the drug holding portion 3 which is adhered to the package 22.

本發明中使用之熱源2較好為市售之拋棄式加熱包。且，發熱體21發熱時之熱源2之外表面之溫度較好為40至70℃，且發熱持續時間較好為8至24小時左右。 The heat source 2 used in the present invention is preferably a commercially available disposable heating pack. Further, the temperature of the outer surface of the heat source 2 when the heating element 21 generates heat is preferably 40 to 70 ° C, and the heat generation duration is preferably about 8 to 24 hours.

藥劑保持部3具有包含含浸害蟲驅除劑之藥劑含浸層31、支撐藥劑含浸層31之支撐層32、及固定於熱源2之外表面上之黏著層33等之多層構造，其一例如圖4所示，具有藥劑含浸層31與黏著層33位在最外層，其間隔著支撐層32之3層構造。 The drug holding unit 3 has a multilayer structure including a chemical impregnated layer 31 containing a pest repellent, a support layer 32 supporting the chemical impregnated layer 31, and an adhesive layer 33 fixed to the outer surface of the heat source 2, and an example thereof is shown in FIG. It is shown that the chemical impregnated layer 31 and the adhesive layer 33 are located at the outermost layer, and are separated by a three-layer structure of the support layer 32.

藥劑含浸層31係具有內部有間隙之網眼構造，於其間隙中藉表面張力等保持害蟲驅除劑之構件。藥 劑含浸層31之材質較好由聚烯烴纖維、芳醯胺纖維、聚酯纖維、維尼綸(vinylon)纖維、尼龍纖維、縲縈纖維等選出之1種或2種以上。且，藥劑含浸層31中之網眼可具有規則性亦可為不規則。另外，藥劑含浸層31之大小可根據欲含浸之害蟲驅除劑之量進行各種變更。 The chemical impregnated layer 31 has a mesh structure having a gap inside, and a member for holding the pest repellent by surface tension or the like in the gap. medicine The material of the impregnation layer 31 is preferably one or more selected from the group consisting of polyolefin fibers, linaloamide fibers, polyester fibers, vinylon fibers, nylon fibers, and rayon fibers. Moreover, the mesh in the chemical impregnation layer 31 may have regularity or irregularity. Further, the size of the chemical impregnated layer 31 can be variously changed depending on the amount of the pest repellent to be impregnated.

而且，藥劑含浸層31中含浸之害蟲驅除劑具備揮發性，較好為擬除蟲菊酯(pyrethroid)系化合物或天然精油成分之至少一者。若為該等成份，則對於蚊、蠅、虻、蜂等害蟲具有殺蟲效果或忌避效果，同時亦容易藉由來自熱源2之熱自袋狀容器1擴散故較佳。 Further, the pest repellent impregnated in the chemical impregnated layer 31 has a volatility, and is preferably at least one of a pyrethroid compound or a natural essential oil component. If it is such a component, it has an insecticidal effect or a repellent effect on pests such as mosquitoes, flies, cockroaches, bees, and the like, and is also easily diffused from the bag-like container 1 by heat from the heat source 2, which is preferable.

作為擬除蟲菊酯系化合物，天然擬除蟲菊酯較好為除蟲菊素(pyrethrin)I〈(1R,3R)-2,2-二甲基-3-(2-甲基-1-丙烯基)環丙烷羧酸(1S)-2-甲基-4-氧代-3-(2Z)-2,4-戊二烯基-2-環戊烯-1-基酯〉、除蟲菊素II〈(1R,3R)-3-[(1E)-3-甲氧基-2-甲基-3-氧代-1-丙烯基]-2,2-二甲基環丙烷羧酸(1S)-2-甲基-4-氧代-3-(2Z)-2,4-戊二烯基-2-環戊烯-1-基酯〉、瓜菊酯(cinerin)I〈(1R,3R)-2,2-二甲基-3-(2-甲基-1-丙烯基)環丙烷羧酸(1S)-3-(2Z)-(2-丁烯基)-2-甲基-4-氧代-2-環戊烯-1-基酯〉、瓜菊酯(cinerin)II〈(1R,3R)-3-[(1E)-3-甲氧基-2-甲基-3-氧代-1-丙烯基)-2,2-二甲基環丙烷羧酸(1S)-3-(2Z)-(2-丁烯基)-2-甲基-4-氧代-2-環戊烯-1-基酯〉、茉酮菊素(jasmolin)I〈(1R,3R)-2,2-二甲基-3-(2-甲基-1-丙烯基)環丙烷羧酸(1S)-2-甲基-4-氧代-3-(2Z)-2-戊烯基-2-環戊烯-1-基酯〉、茉酮菊素II〈(1R,3R)-3-[(1E)- 3-甲氧基-2-甲基-3-氧代-1-丙烯基]-2,2-二甲基環丙烷羧酸(1S)-2-甲基-4-氧代-3-(2Z)-2-戊烯基-2-環戊烯-1-基酯〉，合成擬除蟲菊酯較好為丙烯除蟲菊酯(allethrin)I〈2,2-二甲基-3-(2-甲基-1-丙烯基)環丙烷羧酸2-甲基-4-氧代-3-(2-丙烯基)-2-環戊烯-1-基酯〉、丙烯除蟲菊酯II〈3-(3-甲氧基-2-甲基-3-氧代-1-丙烯基)-2,2-二甲基環丙烷羧酸2-甲基-4-氧代-3-(2-丙烯基)-2-環戊烯-1-基酯〉、胺菊酯(phthalthrin)(別名：D-似蟲菊(tetramethrin))〈(1,3-二氧代-4,5,6,7-四氫吲哚啉-2-基)甲基=2,2-二甲基-3-(2-甲基丙-1-烯-1-基)環丙烷-1-羧酸酯〉、滅蟲菊(resmethrin)〈5-苄基-3-呋喃基〉甲基=2,2-二甲基-3-(2-甲基丙-1-烯-1-基)環丙烷羧酸酯〉、苯醚菊酯(phenothrin)〈3-苯氧基苄基=2-二甲基-3-(甲基丙烯基)環丙烷羧酸酯〉、百滅寧(permethrin)〈3-苯氧基芾基=3-(2,2-二氯乙烯基)-2,2-二甲基環丙烷羧酸酯〉、塞吩寧(cyphenothrin)〈氰基(3-苯氧基苯基)甲基=2,2-二甲基-3-(2-甲基丙-1-烯-1-基)環丙烷羧酸酯〉、醚菊酯(ethofenprox)〈4-(4-乙氧基苯基)-4-甲基-1-(3-苯氧基苯基)-2-氧雜戊烷〉、美特寧(metofluthrin)〈2,2-二甲基-3-(2-甲基丙-1-烯-1-基)環丙烷羧酸=2,3,5,6-四氟-4-(甲氧基甲基)苄基酯〉、四氟苯菊酯(transfluthrin)〈(1R,3S)-3-[(E)-2,2-二氯乙烯基]-2,2-二甲基環丙烷羧酸=2,3,5,6-四氟苄基酯〉、賽扶寧(cyfluthrin)〈氰基(4-氟-3-苯氧基苯基)甲基=3-(2,2-二氯乙烯基)-2,2-二甲基環丙烷-1-羧酸酯〉等。而且，上述中以百滅寧、苯醚菊酯、丙 烯除蟲菊酯、胺菊酯、滅蟲菊、美特寧、四氟苯菊酯最佳。又，上述之擬除蟲菊酯系化合物可僅使用1種，或組合2種以上使用。 As a pyrethroid compound, the natural pyrethroid is preferably pyrethrin I<(1R,3R)-2,2-dimethyl-3-(2-methyl-1) -propenyl)cyclopropanecarboxylic acid (1S)-2-methyl-4-oxo-3-(2Z)-2,4-pentadienyl-2-cyclopenten-1-yl ester Insectin II <(1R,3R)-3-[(1E)-3-methoxy-2-methyl-3-oxo-1-propenyl]-2,2-dimethylcyclopropanecarboxylate Acid (1S)-2-methyl-4-oxo-3-(2Z)-2,4-pentadienyl-2-cyclopenten-1-yl ester>, cinerin I < (1R,3R)-2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid (1S)-3-(2Z)-(2-butenyl)-2 -Methyl-4-oxo-2-cyclopenten-1-yl ester>, cinerin II <(1R,3R)-3-[(1E)-3-methoxy-2- Methyl-3-oxo-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid (1S)-3-(2Z)-(2-butenyl)-2-methyl-4- Oxo-2-cyclopenten-1-yl ester>, jasmolin I <(1R,3R)-2,2-dimethyl-3-(2-methyl-1-propenyl) Cyclopropanecarboxylic acid (1S)-2-methyl-4-oxo-3-(2Z)-2-pentenyl-2-cyclopenten-1-yl ester>, jasperin II < 1R,3R)-3-[(1E)- 3-methoxy-2-methyl-3-oxo-1-propenyl]-2,2-dimethylcyclopropanecarboxylic acid (1S)-2-methyl-4-oxo-3-( 2Z)-2-pentenyl-2-cyclopenten-1-yl ester>, synthetic pyrethroid is preferably propylene pyrethroid (allethrin) I<2,2-dimethyl-3- (2-methyl-1-propenyl)cyclopropanecarboxylic acid 2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl ester>, propylene pyrethrum Ester II <3-(3-methoxy-2-methyl-3-oxo-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid 2-methyl-4-oxo-3 -(2-propenyl)-2-cyclopenten-1-yl ester, phthalthrin (alias: D-like tetramethrin) <(1,3-dioxo-4, 5,6,7-tetrahydroporphyrin-2-yl)methyl=2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropane-1-carboxylate Acid esters>, pyrethrum (resmethrin) <5-benzyl-3-furanyl>methyl=2,2-dimethyl-3-(2-methylprop-1-en-1-yl) ring Propane carboxylate>, phenothrin <3-phenoxybenzyl=2-dimethyl-3-(methacryl)cyclopropanecarboxylate>, permethrin< 3-phenoxymercapto = 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate>, cyphenothrin Cyano (3-phenoxyphenyl)methyl=2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylate>, ethyl pyrethroid Ethofenprox) <4-(4-ethoxyphenyl)-4-methyl-1-(3-phenoxyphenyl)-2-oxapentane>, metofluthrin <2,2 -Dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylic acid = 2,3,5,6-tetrafluoro-4-(methoxymethyl)benzyl ester 〉, transfluthrin <(1R,3S)-3-[(E)-2,2-dichlorovinyl]-2,2-dimethylcyclopropanecarboxylic acid = 2,3, 5,6-tetrafluorobenzyl ester>, cyfluthrin <cyano(4-fluoro-3-phenoxyphenyl)methyl=3-(2,2-dichlorovinyl)-2 , 2-dimethylcyclopropane-1-carboxylate, and the like. Moreover, the above-mentioned baifening, fenthrin, and propyl The pyrethroid, methrin, pyrethrum, meteline, and tetrafluthrin are the best. In addition, the pyrethroid compound may be used alone or in combination of two or more.

天然精油係由植物之枝葉、根莖、木皮、果實、花、花蕾、樹脂等而得之揮發性之油狀物，可藉水蒸氣蒸餾法、壓榨法、萃取法等自植物之各部位分離、純化而得。 The natural essential oil is a volatile oil obtained from the foliage, roots, veneer, fruit, flower, flower bud, resin, etc. of the plant, and can be separated from various parts of the plant by steam distillation, pressing, extraction, etc. Purified.

精油之原材料舉例有各種，較佳為葡萄柚、天竺葵、迷迭香、茴芹、艾嵩油、依蘭、橙、香水榭、德國洋甘菊、白荳蔻、玉樹、快樂鼠尾草、丁香、香菜、西洋柏、檀香、杉木、香茅醛、刺柏、薑、留蘭香、藥用鼠尾草、千層樹、肉桂、橙花、松針、羅勒、廣藿香、馬丁香、小茴香、黑胡椒、苦橙葉、香根草、胡椒薄荷、香檸檬、墨角蘭、柑橘、檸檬尤加利、萊姆、薰衣草、檸檬、檸檬草、紫檀、月桃葉油、桂皮油、薄荷油。由該等原材料獲得之精油對害蟲具有有用之忌避效果。 Examples of raw materials for essential oils are grapefruit, geranium, rosemary, anise, amaranth, ylang-ylang, orange, perfume, German chamomile, white cardamom, eucalyptus, clary sage, clove, coriander , cypress, sandalwood, Chinese fir, citronellal, juniper, ginger, spearmint, medicinal sage, Melaleuca, cinnamon, orange blossom, pine needle, basil, patchouli, horse clove, cumin, Black pepper, bitter orange leaf, vetiver, peppermint, bergamot, marjoram, citrus, lemon eucalyptus, lime, lavender, lemon, lemon grass, red sandalwood, moon peach oil, cinnamon oil, peppermint oil. The essential oils obtained from these raw materials have a useful repellent effect on pests.

由上述原材料獲得之精油中含有具有揮發性之各種化合物。葡萄柚中含有d-檸烯、香葉烯、α-蒎烯等。天竺葵含有香茅醇、香葉醇、芳樟醇等。迷迭香含有α-蒎烯、樟腦、1,8-桉葉油醇等。茴芹含有(E)-茴香腦、檸烯、茴香醛等。艾嵩油含有1,8-桉葉油醇、側柏酮、龍腦、樟腦、蒎烯、青嵩素(倍半萜．內酯)芳樟醇、橙花醇等。依蘭含有芳樟醇、β-石竹烯、大根香葉烯D等。橙含有檸烯、香葉烯、β-沒藥烯等。香水榭含有石竹烯、乙酸 香葉酯、松油醇等。德國洋甘菊含有麝子油烯、母菊蘭烯、α-沒藥醇氧化物B等。白荳蔻含有1,8-桉葉油醇、α-乙酸萜品酯、檸烯等。玉樹含有1,8-桉葉油醇、α-松油醇、對異丙基苯等。快樂鼠尾草含有芳樟醇乙酸酯、芳樟醇、大根香葉烯D等。丁香含有丁香油酚、β-石竹烯、乙酸丁香酚酯等。香菜含有d-芳樟醇、樟腦、α-蒎烯等。西洋柏含有α-蒎烯、δ-3-蒈烯(carene)等。檀香含有順式-α-檀香醇、順式-β-檀香醇、表-β-檀香醇等。杉木含有羅漢柏烯、α-雪松烯、雪松醇等。香茅醛含有香葉醇、檸烯、香茅醇等。刺柏含有α-蒎烯、香葉烯、β-麝子油烯等。薑含有ar-薑黃烯、α-薑烯、β-倍半水芹烯等。留蘭香含有(-)-香芹酮、二氫香芹酮、1,8-桉葉油醇等。藥用鼠尾草含有α-側柏酮、β-側柏酮、樟腦等。千層樹含有萜烯-4-醇、γ-萜烯、α-萜烯等。肉桂含有α-萜烯、檜萜、β-萜烯等。橙花含有芳樟醇、檸烯、β-蒎烯等。松針含有α-蒎烯、β-蒎烯、香葉烯等。羅勒含有芳樟醇、甲基草松腦、β-石竹烯等。廣藿香含有廣藿香醇、α-綠葉烯、β-石竹烯等。馬丁香中含有香葉醇、乙酸香葉酯、芳樟醇等。小茴香中含有(E)-茴香腦、檸烯、甲基草松腦等。黑胡椒中含有β-3-石竹烯、δ-3-蒈烯、檸烯等。苦橙葉中含有乙酸沉香酯、芳樟醇、α-萜烯醇等。香根草中含有香根醇、香根草(vetiven)、α-香根草醇(vetivol)等。香檸檬中含有檸烯、乙酸沉香酯、芳樟醇等。墨角蘭中含有萜烯-4-醇、順式-水和檜烯、對-傘花烴等。柑橘中含有檸烯、γ-萜 烯、β-蒎烯等。檸檬尤加利中含有香茅醛、香茅醇、檸檬醛等。萊姆中含有檸烯、γ-萜烯、β-蒎烯等。薰衣草中含有乙酸芳樟酯、芳樟醇、(Z)-β-羅勒烯等。檸檬中含有檸烯、β-蒎烯、γ-萜烯等。檸檬草中含有檸檬醛、橙花醛、欖香醇等。紫檀中含有芳樟醇、α-萜烯醇、順式-芳樟醇氧化物等。胡椒薄荷中含有1-薄荷醇、1-薄荷酮、薄荷呋喃等。桂皮油中含有肉桂醛、t-2-甲氧基肉桂醛、香豆素等。月桃葉油中含有1,8-桉葉油醇、萜烯-4-醇、對-異丙基甲苯等。薄荷油中含有1-薄荷醇、1-薄荷酮、薄荷呋喃等。 The essential oil obtained from the above raw materials contains various compounds having a volatility. Grapefruit contains d-limonene, geranyl, α-pinene and the like. Geranium contains citronellol, geraniol, linalool, and the like. Rosemary contains α-pinene, camphor, 1,8-eucalyptus alcohol, and the like. Anise contains (E)-fennel, limonene, anisaldehyde and the like. Aimu oil contains 1,8-eucalyptol, thuja ketone, borneol, camphor, decene, quercetin (sesquiterpene lactone) linalool, nerol and the like. Ylang-Ylang contains linalool, β-caryophyllene, radixene D and the like. Orange contains limonene, geranyl, β-myristene and the like. Perfume contains carnation, acetic acid Geranyl ester, terpineol, and the like. German chamomile contains scorpion oleyl, mother chrysanthemum, α-bucotol oxide B and the like. White soybean meal contains 1,8-eucalyptol, α-acetic acid ester, limonene and the like. Yushu contains 1,8-eucalyptol, α-terpineol, p-isopropylbenzene and the like. Happy sage contains linalool acetate, linalool, geranyl D and the like. Clove contains eugenol, β-caryophyllene, eugenol acetate, and the like. Coriander contains d-linalool, camphor, alpha-pinene and the like. Sabina vulgaris contains α-pinene, δ-3-decene (carene) and the like. Sandalwood contains cis-α-santalol, cis-β-santalol, epi-β-santalol and the like. Chinese fir contains rohan albicene, alpha-cedarene, cedarol and the like. Citronellal contains geraniol, limonene, citronellol, and the like. The juniper contains α-pinene, geranyl, β-glutonene and the like. Ginger contains ar-curcumene, α-gingene, β-sesquisene and the like. Spearmint contains (-)-carvone, dihydrocarvone, 1,8-eucalyptol, and the like. Medicinal sage contains alpha-terbinone, beta-columnone, camphor, and the like. The Melaleuca tree contains terpene-4-ol, γ-pinene, α-pinene and the like. Cinnamon contains α-pinene, anthracene, β-pinene and the like. Orange blossom contains linalool, limonene, β-pinene and the like. Pine needles contain α-pinene, β-pinene, geranene and the like. Basil contains linalool, methyl cedar, β-caryophyllen and the like. Patchouli contains patchouli alcohol, α-green leafene, β-caryophyllen and the like. Horse cloves contain geraniol, geranyl acetate, linalool and the like. The cumin contains (E)-fennel, limonene, methyl grass pine and the like. Black pepper contains β-3-carvedene, δ-3-decene, limonene and the like. The bitter orange leaf contains agaric acid ester, linalool, α-nonenol and the like. Vetiver contains geranol, vetiven, v-vetivol, and the like. The bergamot contains limonene, acetic acid, linalool, and the like. Marjoram contains terpene-4-ol, cis-water and decene, p-cymene, and the like. Citrus contains limene, γ-萜 Alkene, β-pinene, and the like. Lemon eucalyptus contains citronellal, citronellol, citral and the like. Lyme contains limonene, γ-pinene, β-pinene and the like. Lavender contains linalyl acetate, linalool, (Z)-β-ocimene and the like. Lemon contains limonene, β-pinene, γ-pinene and the like. Lemongrass contains citral, nerol, and elem. The red sandalwood contains linalool, α-nonenol, cis-linalool oxide and the like. Peppermint contains 1-menthol, 1-menthone, menthyl furan and the like. Cinnamon oil contains cinnamaldehyde, t-2-methoxycinnamaldehyde, coumarin and the like. Moon peach oil contains 1,8-eucalyptol, terpene-4-ol, p-isopropyltoluene and the like. The peppermint oil contains 1-menthol, 1-menthone, peppermint, and the like.

且，上述擬除蟲菊酯系化合物亦可併用天然精油成分使用。 Further, the pyrethroid compound may be used in combination with a natural essential oil component.

支撐層32為支撐藥劑含浸層31，且保持藥劑保持部3之形狀之構件。支撐層32之材質為了輕量化較好由聚乙烯、聚丙烯、聚酯等之合成樹脂所成，但亦可使用熱傳導良好之金屬板。厚度為了一方面保持藥劑保持部3之形狀一方面使自熱源2發出之熱傳遞到藥劑含浸層31，故較好為0.01~10mm。 The support layer 32 is a member that supports the chemical impregnated layer 31 and holds the shape of the drug holding portion 3. The material of the support layer 32 is preferably made of a synthetic resin such as polyethylene, polypropylene or polyester for weight reduction, but a metal plate having good heat conduction can also be used. The thickness is such that the shape of the drug holding portion 3 is maintained on the one hand, and the heat generated from the heat source 2 is transferred to the drug-containing layer 31 on the one hand, so that it is preferably 0.01 to 10 mm.

黏著層33係將藥劑保持部3對於熱源2可剝離地固定之構件。黏著層33之材質較好為丙烯酸酯共聚物等之丙烯酸系黏著劑、胺基甲酸酯樹脂等之胺基甲酸酯系黏著劑。 The adhesive layer 33 is a member that the drug holding portion 3 is detachably fixed to the heat source 2 . The material of the adhesive layer 33 is preferably an acryl-based adhesive such as an acrylate copolymer or a urethane-based adhesive such as a urethane resin.

標識部4係以接著劑等固定設置於藥劑保持部3之藥劑含浸層31之外表面，且以使用者能辨識藥劑 含浸層31中含浸之害蟲驅除劑大致揮散之方式表示之標識。標識部4係以二氧化矽(折射率1.45)、沸石(折射率1.48)、高嶺土(折射率1.56)、滑石(折射率1.57)、碳酸鈣(折射率1.58)、聚苯乙烯(折射率1.6)、聚乙烯(折射率1.53)、甲基丙烯酸甲酯樹脂(折射率1.49)等白色或透明等之微粒子構成。如圖3所示以「END」之文字描述。標識部4其他之例可使用「用完」等之文字，「×」等之記號，又亦可複數的組合該等文字、圖形、記號而構成。 The indicator portion 4 is fixed to the outer surface of the drug-impregnated layer 31 of the drug holding portion 3 by an adhesive or the like, and the user can recognize the drug. The identifier of the pest repellent impregnated in the impregnated layer 31 is expressed in a manner of substantially volatilization. The marking portion 4 is made of cerium oxide (refractive index of 1.45), zeolite (refractive index of 1.48), kaolin (refractive index of 1.56), talc (refractive index of 1.57), calcium carbonate (refractive index of 1.58), and polystyrene (refractive index of 1.6). It is composed of white or transparent fine particles such as polyethylene (refractive index: 1.53) and methyl methacrylate resin (refractive index of 1.49). It is described by the text "END" as shown in Figure 3. Other examples of the marking unit 4 may be characters such as "run out", symbols such as "x", or a combination of the characters, figures, and symbols.

藥劑含浸層31中含浸充分之害蟲驅除劑時，由於害蟲驅除劑之折射率為1.4~1.6與構成標識部4之微粒子之折射率為相同之值，故構成標識部4之微粒子藉由與害蟲驅除劑接觸而潤濕，使害蟲驅除劑與標識部4同化，而令使用者難以辨識標識部4。另一方面，藥劑含浸層31中幾乎未含浸害蟲驅除劑時，構成標識部4之微粒子不與害蟲驅除劑接觸而與周圍之空氣(折射率1.0)接觸，由於構成標識部4之微粒子與空氣之折射率之差較大，故使用者容易辨識標識部4。且，較好以容易辨識標識部4之方式，使標識部4之微粒子顏色與藥劑含浸層31之顏色不同。 When the chemical repellent layer 31 is impregnated with a sufficient pest repellent, since the refractive index of the pest repellent is 1.4 to 1.6 and the refractive index of the microparticles constituting the labeling portion 4 is the same, the microparticles constituting the labeling portion 4 are treated with pests. The repellent is wetted by contact, and the pest repellent is assimilated to the marking portion 4, making it difficult for the user to recognize the marking portion 4. On the other hand, when the pest repellent layer is hardly impregnated with the pest repellent layer 31, the microparticles constituting the labeling portion 4 are not in contact with the pest repellent agent and are in contact with the surrounding air (refractive index of 1.0) due to the microparticles and air constituting the labeling portion 4. Since the difference in refractive index is large, the user can easily recognize the marker portion 4. Further, it is preferable that the color of the fine particles of the marking portion 4 is different from the color of the chemical impregnation layer 31 in such a manner that the marking portion 4 is easily recognized.

1‧‧‧收容容器 1‧‧‧ containment container

11‧‧‧蓋住開口之構件 11‧‧‧ Covering the opening

111‧‧‧通氣孔 111‧‧‧Ventinel

12‧‧‧蓋部 12‧‧‧ 盖部

Claims (6)

一種加熱蒸散型害蟲驅除具，其特徵係具備收容容器、收納於前述收容容器之內部，具有藉由氧而發熱之發熱體之熱源，與設置於前述熱源之外表面，具有害蟲驅除劑之藥劑保持部，前述收容容器具備連通前述收容容器之內外之通氣孔、與自由開閉前述通氣孔之蓋部。 A heated evapotranspiration pest repellent characterized by comprising a storage container, a heat source stored in the storage container, and having a heat source that generates heat by oxygen, and a medicament having a pest repellent disposed on an outer surface of the heat source In the holding portion, the storage container includes a vent hole that communicates with the inside and the outside of the storage container, and a lid portion that opens and closes the vent hole. 如請求項1之加熱蒸散型害蟲驅除具，其中前述害蟲驅除劑具備揮發性，且係擬除蟲菊酯(pyrethroid)系化合物或天然精油成分之至少一者。 The heat-evaporable pest repellent of claim 1, wherein the pest repellent is volatile and is at least one of a pyrethroid compound or a natural essential oil component. 如請求項1或2之加熱蒸散型害蟲驅除具，其中前述藥劑保持部係由含浸前述害蟲驅除劑之藥劑含浸層、支撐並抵接前述藥劑含浸層之支撐層、及接著於前述熱源之外表面之黏著層之複數層所成。 The heated evapotranspiration pest repellent of claim 1 or 2, wherein the drug retaining portion is a chemical impregnated layer impregnated with the pest repellent, a support layer supporting and abutting the chemical impregnated layer, and then being external to the heat source The layers of the adhesive layer of the surface are formed by a plurality of layers. 如請求項1至3中任一項之加熱蒸散型害蟲驅除具，其中前述收容容器及蓋部具有遮光性。 The heating-evaporable pest repellent according to any one of claims 1 to 3, wherein the storage container and the lid portion have a light-shielding property. 如請求項1至4中任一項之加熱蒸散型害蟲驅除具，其中前述收容容器及蓋部被施以由藉由金屬或氧化金屬化合物蒸鍍、混練紫外線吸收劑、經著色選出之至少一種加工。 The heating-evaporable pest repellent according to any one of claims 1 to 4, wherein the storage container and the lid portion are subjected to at least one selected from the group consisting of vapor deposition by a metal or an oxidized metal compound, kneading of an ultraviolet absorber, and coloring. machining. 如請求項1至5中任一項之加熱蒸散型害蟲驅除具，其中前述藥劑保持部之外表面具備光折射率與周圍不 同之標幟部，依據前述害蟲驅除劑之減少使設置於前述標幟部之由文字、圖型、記號選出之1或2種以上浮起。 The heated evapotranspiration pest repellent according to any one of claims 1 to 5, wherein the outer surface of the drug retaining portion has a refractive index of light and a surrounding In the same part, the one or two or more types selected from the characters, patterns, and symbols provided in the marker portion are floated in accordance with the reduction of the pest repellent.