TW201343644A - Thiazolylcarboxamide deriviate and methoud using the same - Google Patents

Thiazolylcarboxamide deriviate and methoud using the same Download PDF

Info

Publication number
TW201343644A
TW201343644A TW102110201A TW102110201A TW201343644A TW 201343644 A TW201343644 A TW 201343644A TW 102110201 A TW102110201 A TW 102110201A TW 102110201 A TW102110201 A TW 102110201A TW 201343644 A TW201343644 A TW 201343644A
Authority
TW
Taiwan
Prior art keywords
alkyl
group
alkoxy
same
halogen
Prior art date
Application number
TW102110201A
Other languages
Chinese (zh)
Inventor
Koji Tanaka
Hirokazu Fujihara
Motohiro Hasebe
Atsushi Okada
Original Assignee
Nihon Nohyaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Nohyaku Co Ltd filed Critical Nihon Nohyaku Co Ltd
Publication of TW201343644A publication Critical patent/TW201343644A/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)

Abstract

The object of this invention provides a plant-pest controlling agent which has superior effectiveness, especially a compound useful for a rice blast disease controlling agent which is applied on the water surface, than those in the prior art. In particular, the invention provides a thiazolylcarboxamide derivate represented by the general formula (I): [wherein, R1 represents a hydrogen atom, a halogen atom, an alkyl group or an haloalkyl group; Y represents O, S, SO, SO2, -N(R3)-, or -N=C(R3)- (R3 represents a hydrogen atom, an alkyl group; a formyl group, an alkoxyalkyl group and the like), when Y represents O, S, SO, SO2, -N(R3)-, R2 represents an aminoalkyl group, a monoalkylaminoalkyl group, a dialkylaminoalkyl group, a hydroxyalkyl group, an alkoxyalkyl group, an alkoxyalkoxyalkyl group and the like, and when Y represents -N=C(R3)-, R2 represents an alkyl group, an alkoxy group and the like; R4, R5, R6, R7 and R8 are the same or different, and represent a hydrogen atom, an alkyl group and the like; X1, X2 and X3 are the same or different, and represent a hydrogen atom, a halogen atom, an alkyl group, a haloalkyl group, a cycloalkyl group and the like] or a salt thereof, and a plant-pest controlling agent containing the derivate.

Description

噻唑羧醯胺衍生物及其使用方法 Thiazole carboxamide derivative and method of use thereof

本發明是關於新穎的噻唑羧醯胺衍生物，或其鹽類，及含有該化合物做為有效成分的植物病害防治劑以及其使用方法。 The present invention relates to a novel thiazole carboamide derivative, or a salt thereof, and a plant disease controlling agent containing the compound as an active ingredient and a method of using the same.

向來，已知某種的N-2-(經取代吡唑基)乙基羧醯胺衍生物做為植物病害防治劑(例如，參照專利文獻1，或2。)，或某種噻唑羧醯胺衍生物有用於做為植物病害防治劑(例如，參照專利文獻3。)。但是，其植物病害防治效果並不充分。 Conventionally, a certain N-2-(substituted pyrazolyl)ethylcarboxamide derivative has been known as a plant disease controlling agent (for example, refer to Patent Document 1, or 2), or a certain thiazole carboxamide. The amine derivative is used as a plant disease controlling agent (for example, refer to Patent Document 3). However, its plant disease control effect is not sufficient.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]國際公開第2006/108791號小冊 [Patent Document 1] International Publication No. 2006/108791

[專利文獻2]國際公開第2006/108792號小冊 [Patent Document 2] International Publication No. 2006/108792

[專利文獻3]國際公開第2008/062878號小冊 [Patent Document 3] International Publication No. 2008/062878

農業及園藝等的作物生產上，由於病害等的損害現 在還是很大，對既有藥的抵抗性病害的產生，對地球環境的負荷等的因素而有需要開發以低藥量而有高效果的新穎的植物病害防治劑。又，由於農耕者的老齡化等而對各種省工的施用方法的需求，也對具有適合於這些的施用方法的性質的植物病害防治劑的創造也有需求。本發明是為了滿足這些需求，而提供做為植物病害防治劑有用的噻唑羧醯胺衍生物。 In the production of crops such as agriculture and horticulture, damage due to diseases, etc. In addition, it is necessary to develop a novel plant disease control agent which has a high effect and has a high effect on factors such as the generation of a resistant disease of the existing drug and the load on the earth's environment. In addition, there is a demand for the application of a plant disease control agent having a property suitable for the application method of these methods because of the aging of the farmer and the like. The present invention is to provide a thiazole carboquinone derivative useful as a plant disease controlling agent in order to satisfy these needs.

本發明者等為解決上述課題而精心反覆研究的結果，發現本發明的一般式(I)表示的噻唑羧醯胺或其鹽類做為植物病害防治劑，特別是對稻熱病有優異的水面施用，或箱處理的防治效果，而完成本發明。即，本發明是，關於：[1]一般式(I)表示的噻唑羧醯胺衍生物或其鹽類： The inventors of the present invention have found that the thiazolcarbamide or its salt represented by the general formula (I) of the present invention is a plant disease controlling agent, and particularly has excellent water surface resistance to rice fever, in order to solve the above problems. The present invention is completed by the application or the control effect of the tank treatment. That is, the present invention relates to: [1] a thiazole carboquinone derivative represented by the general formula (I) or a salt thereof:

{式中，R1表示，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；(4a)(C1-C6)烷氧基；或(5a)鹵(C1-C6)烷氧基；(6a)(C3-C6)環烷基，Y表示，O，S，SO，SO2，-N(R3)-，或-N=C(R3)- (式中，R3表示，(1b)氫原子；(2b)(C1-C6)烷基；(3b)(C2-C6)烯基；(4b)(C2-C6)炔基；(5b)鹵(C1-C6)烷基；(6b)鹵(C2-C6)烯基；(7b)鹵(C2-C6)炔基；(8b)甲醯基；(9b)(C1-C6)烷氧(C1-C6)烷基；(10b)鹵(C1-C6)烷氧(C1-C6)烷基；(11b)(C1-C6)烷硫(C1-C6)烷基；(12b)(C1-C6)烷亞磺醯(C1-C6)烷基；(13b)(C1-C6)烷磺醯(C1-C6)烷基；(14b)(C1-C6)烷氧羰基；(15b)(C1-C6)烷氧(C1-C6)烷羰基；(16b)(C1-C6)烷羰基；(17b)鹵(C1-C6)烷羰基；(18b)(C1-C6)烷氧羰(C1-C6)烷基；(19b)(C3-C6)環烷基；或(20b)(C1-C6)烷氧基。)，(1)Y表示，O，S，SO，SO2，或-N(R3)-(R3與前述同。)時，R2表示，(1c)胺(C1-C6)烷基； (2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(4c)(C1-C6)烷羰胺(C1-C6)烷基；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基；(7c)單(C1-C6)烷胺羰基；(8c)二(C1-C6)烷胺羰基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(9c)單(C1-C6)烷胺硫羰基；(10c)二(C1-C6)烷胺硫羰基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(13c)鹵(C1-C6)烷氧(C1-C6)烷基；(14c)(C2-C6)烯氧(C1-C6)烷基；(15c)(C2-C6)炔氧(C1-C6)烷基；(16c)(C3-C6)環烷氧(C1-C6)烷基；(17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同。)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；(19c)(C1-C6)烷羰氧(C1-C6)烷基；(20c)苯(C1-C6)烷氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基； (22c)單(C1-C6)烷胺羰氧(C1-C6)烷基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(28c)(C1-C6)烷氧亞胺(C1-C6)烷基；(29c)N-(C1-C6)烷-N-甲醯胺(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基；(31c)非芳香族雜環基；(32c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基 的經取代非芳香族雜環氧(C1-C6)烷基；(37c)芳香族雜環基；(38c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基；(41c)R2與R3鍵合，並與其所鍵合的氮原子一起，形成5或6員的含氮脂肪族雜環亦可以，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的可以相同或不相同的，1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基， (2)Y表示，-N=C(R3)-(R3與前述同。)時，R2表示，(1d)(C1-C6)烷基；(2d)(C1-C6)烷氧基；(3d)單(C1-C6)烷胺基；或(4d)二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同。)，R4，R5，R6，及R7可以相同或不相同，表示(1e)氫原子；(2e)(C1-C6)烷基；(3e)鹵(C1-C6)烷基；(4e)(C3-C6)環烷基；(5e)(C1-C6)烷羰基；(6e)(C1-C6)烷氧羰基；(7e)(C1-C6)烷氧(C1-C6)烷基；或(8e)R4與R5，R6與R7，R4與R6或R4與R7鍵合，與其鍵合的碳原子一起，形成3至6員的脂肪族環也可以，R8表示，(1f)氫原子；(2f)(C1-C6)烷基；(3f)(C1-C6)烷氧基；(4f)(C3-C6)環烷基；(5f)(C1-C6)烷羰基；(6f)(C3-C6)環烷羰基； (7f)(C1-C6)烷氧羰基；(8f)(C3-C6)環烷氧羰基；或(9f)(C1-C6)烷氧(C1-C6)烷基，X1，X2及X3是可以相同或不相同，表示(1g)氫原子；(2g)鹵原子；(3g)甲醯基；(4g)氰基；(5g)羥亞胺(C1-C6)烷基；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基；(8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基；(10g)(C1-C6)烷硫基；(11g)鹵(C1-C6)烷硫基；(12g)(C1-C6)烷亞磺醯基；(13g)鹵(C1-C6)烷亞磺醯基；(14g)(C1-C6)烷磺醯基；(15g)鹵(C1-C6)烷磺醯基；(16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi)鹵(C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基； (19g)苯(C1-C6)烷基；(20g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代苯(C1-C6)烷基；(21g)(C3-C6)環烷基；(22g)芳香族雜環基；(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基；(24g)芳香族雜環氧基；或(25g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環氧基。}；[2]如上述[1]所述的噻唑羧醯胺衍生物或其鹽類，R1表示，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；(4a)(C1-C6)烷氧基；或(6a)(C3-C6)環烷基，Y表示，O，S，-N(R3)-，或-N=C(R3)- (式中，R3表示，(1b)氫原子；(2b)(C1-C6)烷基；(8b)甲醯基；(9b)(C1-C6)烷氧(C1-C6)烷基；(11b)(C1-C6)烷硫(C1-C6)烷基；(12b)(C1-C6)烷亞磺醯(C1-C6)烷基；(13b)(C1-C6)烷磺醯(C1-C6)烷基；(14b)(C1-C6)烷氧羰基；(15b)(C1-C6)烷氧(C1-C6)烷羰基；(16b)(C1-C6)烷羰基；(17b)鹵(C1-C6)烷羰基；(18b)(C1-C6)烷氧羰(C1-C6)烷基(19b)(C3-C6)環烷基；或(20b)(C1-C6)烷氧基。)，(1)Y表示，O，S，或-N(R3)-(R3與前述同。)時，R2表示，(1c)胺(C1-C6)烷基；(2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(4c)(C1-C6)烷羰胺(C1-C6)烷基；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基； (7c)單(C1-C6)烷胺羰基；(9c)單(C1-C6)烷胺硫羰基；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(13c)鹵(C1-C6)烷氧(C1-C6)烷基；(15c)(C2-C6)炔氧(C1-C6)烷基；(16c)(C3-C6)環烷氧(C1-C6)烷基；(17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同。)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；(19c)(C1-C6)烷羰氧(C1-C6)烷基；(20c)苯(C1-C6)烷氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(28c)(C1-C6)烷氧亞胺(C1-C6)烷基；(29c)N-(C1-C6)烷-N-甲醯胺(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基；(31c)非芳香族雜環基；(32c)在環上有，可以相同或不相同，(i)鹵原子，(ii)氰基，(iii) (C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環氧(C1-C6)烷基；(37c)芳香族雜環基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基；(41c)R2與R3鍵合，並與其所鍵合的氮原子一起，形成5或6員的含氮脂肪族雜環亦可以，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯 基及(viii)氧基(=O)所選擇的可以相同或不相同的，1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基，(2)Y表示，-N=C(R3)-(R3與前述同。)時，R2表示，(2d)(C1-C6)烷氧基；或(4d)二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同。)，R4，R5，R6，及R7可以相同或不相同，表示(1e)氫原子；(2e)(C1-C6)烷基；(3e)鹵(C1-C6)烷基；(7e)(C1-C6)烷氧(C1-C6)烷基；或(8e)R4與R5，R6與R7，R4與R6或R4與R7鍵合，並與其鍵合的碳原子一起，形成3至6員的脂肪族環亦可，R8表示，(1f)氫原子；(3f)(C1-C6)烷氧基；(4f)(C3-C6)環烷基； (5f)(C1-C6)烷羰基；或(7f)(C1-C6)烷氧羰基，X1，X2及X3可以相同或不相同，表示(1g)氫原子；(2g)鹵原子；(4g)氰基；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基；(8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基；(16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi)鹵(C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基；(21g)(C3-C6)環烷基；(22g)芳香族雜環基；(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基；(24g)芳香族雜環氧基；或(25g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6) 烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環氧基；[3]如上述[1]所述的噻唑羧醯胺衍生物或其鹽類，R1表示，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；或(6a)(C3-C6)環烷基，Y表示，O，-N(R3)-，或-N=C(R3)-(式中，R3表示，(1b)氫原子；(2b)(C1-C6)烷基；(8b)甲醯基；(9b)(C1-C6)烷氧(C1-C6)烷基；(11b)(C1-C6)烷硫(C1-C6)烷基；(12b)(C1-C6)烷亞磺醯(C1-C6)烷基；(13b)(C1-C6)烷磺醯(C1-C6)烷基；(14b)(C1-C6)烷氧羰基；(15b)(C1-C6)烷氧(C1-C6)烷羰基；(16b)(C1-C6)烷羰基；(17b)鹵(C1-C6)烷羰基；(18b)(C1-C6)烷氧羰(C1-C6)烷基；(19b)(C3-C6)環烷基；或(20b)(C1-C6)烷氧基。)， (1)Y表示，O，或-N(R3)-(R3與前述同。)時，R2表示，(1c)胺(C1-C6)烷基；(2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基；(7c)單(C1-C6)烷胺羰基；(9c)單(C1-C6)烷胺硫羰基；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同。)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；(19c)(C1-C6)烷羰氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基； (31c)非芳香族雜環基；(32c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環氧(C1-C6)烷基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基；(41c)R2與R3鍵合，並與其所鍵合的氮原子一起，形成5或6員的含氮脂肪族雜環也可以，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵 (C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的可以相同或不相同的，1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基，(2)Y表示，-N=C(R3)-(R3與前述同。)時，R2表示，(2d)(C1-C6)烷氧基；或(4d)二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同。)，R4，R5，R6，及R7可以相同或不相同，表示(1e)氫原子；(2e)(C1-C6)烷基；或(3e)鹵(C1-C6)烷基，R8表示，(1f)氫原子；(3f)(C1-C6)烷氧基；或(4f)(C3-C6)環烷基，X1，X2及X3是可以相同或不相同，表示(1g)氫原子； (2g)鹵原子；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基；(8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基；(16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi)鹵(C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基；(21g)(C3-C6)環烷基；(22g)芳香族雜環基；或(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基；[4]如上述[1]乃至[3]任1項所述的噻唑羧醯胺衍生物或其鹽類，R4表示，(C1-C6)烷基或鹵(C1-C6)烷基，R5，R6，及R7表示氫原子；[5]一種植物病害防治劑，其特徵為：以上述[1]乃至[4]任1項所述的噻唑羧醯胺衍生物或其鹽類做為有效成分；[6]一種植物病害的防治方法，其特徵為：以上述[1]乃至[4]任1項所述的噻唑羧醯胺衍生物或其鹽類的有效量處理對象作物及/或對象作物的種子； [7]一種用途，係將上述[1]乃至[4]任1項所述的噻唑羧醯胺衍生物或其鹽類做為植物病害防治劑：等。 Wherein R 1 represents (1a) a halogen atom; (2a) (C 1 -C 6 )alkyl; (3a) a halogen (C 1 -C 6 )alkyl; (4a) (C 1 -C 6 Alkoxy; or (5a) halo(C 1 -C 6 )alkoxy; (6a)(C 3 -C 6 )cycloalkyl, Y represents O,S,SO,SO 2 ,-N ( R 3 )-, or -N=C(R 3 )- (wherein R 3 represents (1b) a hydrogen atom; (2b) (C 1 -C 6 )alkyl; (3b) (C 2 -C 6 ) alkenyl; (4b) (C 2 -C 6 )alkynyl; (5b) halo(C 1 -C 6 )alkyl; (6b)halo(C 2 -C 6 )alkenyl; (7b)halogen (C 2 -C 6 )alkynyl; (8b)carbazinyl; (9b)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (10b)halo (C 1 -C 6 ) Alkoxy (C 1 -C 6 )alkyl; (11b) (C 1 -C 6 )alkylthio(C 1 -C 6 )alkyl; (12b)(C 1 -C 6 )alkylsulfinium (C) 1 -C 6 )alkyl; (13b)(C 1 -C 6 )alkane (C 1 -C 6 )alkyl; (14b)(C 1 -C 6 )alkoxycarbonyl; (15b)(C 1 -C 6 ) alkoxy (C 1 -C 6 )alkylcarbonyl; (16b)(C 1 -C 6 )alkylcarbonyl; (17b)halo(C 1 -C 6 )alkylcarbonyl; (18b) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (19b) (C 3 -C 6 )cycloalkyl; or (20b)(C 1 -C 6 )alkoxy.), (1 Y represents, when O, S, SO, SO 2 , or -N(R 3 )-(R 3 is the same as defined above), R 2 represents (1c)amine (C 1 -C 6 )alkyl; (2c) mono(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl; (3c)di(C 1 -C 6 )alkylamine (C 1 -C 6 ) The alkyl group of the alkyl (di(C 1 -C 6 )alkylamino group may be the same or different.); (4c) (C 1 -C 6 ) alkylcarbonylamine (C 1 -C 6 )alkyl; (5c (C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (6c) (C 1 -C 6 ) alkanesulfonamide (C 1 -C 6 )alkyl; (7c) (C 1 -C 6 )alkylamine carbonyl; (8c) bis(C 1 -C 6 )alkylaminecarbonyl (alkyl group of di(C 1 -C 6 )alkylamino group may be the same or different.); (9c a mono(C 1 -C 6 )alkylaminethiocarbonyl group; (10c) a di(C 1 -C 6 )alkylaminethiocarbonyl group (the alkyl group of the di(C 1 -C 6 )alkylamino group may be the same or different. (11c) hydroxy(C 1 -C 6 )alkyl; (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (13c)halo(C 1 -C 6 )alkane Oxygen (C 1 -C 6 )alkyl; (14c)(C 2 -C 6 )alkenyloxy(C 1 -C 6 )alkyl; (15c)(C 2 -C 6 )alkyneoxy (C 1 -C 6 ) alkyl; (16c) (C 3 -C 6 )cycloalkoxy (C 1 -C 6 )alkyl; (17c) bis(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl The alkoxy groups of the (di(C 1 -C 6 ) alkoxy group may be the same or different.); (18c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkyl; (19c) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (20c) benzene (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl (21c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkylcarbonyl; (22c)mono(C 1 -C 6 )alkylaminecarbonyloxy(C 1 -C 6 )alkyl; (23c ) di (C 1 -C 6) alkylamino carbonyloxy (C 1 -C 6) alkyl (two (C 1 -C 6) alkylamino alkyl groups may be the same or different);. (24c) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; (25c)(C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; (26c)(C 1 -C 6 Alkanesulfonium (C 1 -C 6 )alkyl; (27c)(C 1 -C 6 )alkoxycarbonyl(C 1 -C 6 )alkyl; (28c)(C 1 -C 6 )alkoxy Amine (C 1 -C 6 )alkyl; (29c) N-(C 1 -C 6 )alkane-N-methylamine (C 1 -C 6 )alkyl; (30c N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (31c) non-aromatic heterocyclic group; (32c) in the ring And may be the same or different from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 ) alkyl group, ( v) (C 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected one or more Substituted substituted non-aromatic heterocyclic group; (33c) non-aromatic heterocyclic (C1-C6) alkyl; (34c) having the same or different in the ring, by (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi) a substituted non-aromatic heterocyclic ring (C 1 -C) having one or more substituents selected from a halogen (C 1 -C 6 ) alkoxy group, (vii) a formazan group and a (viii)oxy group (=O) 6 ) an alkyl group; (35c) a non-aromatic heteroepoxy (C 1 -C 6 )alkyl group; (36c) having the same or different in the ring, from (i) a halogen atom, (ii) a cyano group , (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo (C 1 - C 6 ) alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected a substituted non-aromatic heteroepoxy (C 1 -C 6 )alkyl group having one or more substituents; (37c) an aromatic heterocyclic group; (38c) having the same or different in the ring, i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxylate a group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) a substituted aromatic heterocyclic group having one or more substituents selected from a formazan group; (39c) an aromatic heterocyclic ring ( C 1 -C 6 )alkyl; (40c) may be the same or different on the ring, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, Iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, and (vii)mercapto a substituted aromatic heterocyclic (C 1 -C 6 )alkyl group having one or more substituents selected; (41c) R 2 is bonded to R 3 and together with the nitrogen atom to which it is bonded, forms 5 or 6 The nitrogen-containing aliphatic heterocyclic ring may also be a nitrogen-containing aliphatic heterocyclic ring containing 0 to 1 oxygen atom, 0 to 1 sulfur atom, 1 to 2 nitrogen atoms, and the nitrogen-containing aliphatic hetero The ring is, on the ring, there may be (i) a halogen atom, (ii) a cyano group, (iii) (C 1 - C 6 An alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, (vii) And the one or more substituents which may be the same or different from the methyl group and (viii)oxy group (=O); (42c) formazan (C 1 -C 6 ) alkyl group; (43c) two (methyloxy)(C 1 -C 6 )alkyl; (44c)(C 1 -C 6 )alkylsulfonyloxy(C 1 -C 6 )alkyl; (45c)(C 1 -C 6 ) Alkoxycarbonyloxy(C 1 -C 6 )alkyl; (46c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkoxy(C 1 -C 6 )alkoxy (C 1 -C 6 Or an alkyl group; or (47c) a carboxy(C 1 -C 6 )alkyl group; (2) Y represents -N=C(R 3 )-(R 3 is the same as defined above. And R 2 represents (1d)(C 1 -C 6 )alkyl; (2d)(C 1 -C 6 )alkoxy; (3d)mono(C 1 -C 6 )alkylamino; (4d) a di(C 1 -C 6 )alkylamino group (the alkyl group of the di(C 1 -C 6 )alkylamino group may be the same or different.), R 4 , R 5 , R 6 , and R 7 may be The same or different, representing (1e) a hydrogen atom; (2e) (C 1 -C 6 )alkyl; (3e) halo(C 1 -C 6 )alkyl; (4e)(C 3 -C 6 ) ring (5e)(C 1 -C 6 )alkylcarbonyl; (6e)(C 1 -C 6 )alkoxycarbonyl; (7e)(C 1 -C 6 )alkoxy(C 1 -C 6 ) alkane Or (8e) R 4 and R 5 , R 6 and R 7 , R 4 and R 6 or R 4 and R 7 are bonded to form a 3 to 6 member aliphatic ring together with the carbon atom to which they are bonded Yes, R 8 represents (1f) a hydrogen atom; (2f) (C 1 -C 6 )alkyl; (3f)(C 1 -C 6 )alkoxy; (4f)(C 3 -C 6 ) ring (5f)(C 1 -C 6 )alkylcarbonyl; (6f)(C 3 -C 6 )cycloalkylcarbonyl; (7f)(C 1 -C 6 )alkoxycarbonyl; (8f)(C 3 -C 6 )cycloalkoxycarbonyl; or (9f)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl, X 1 , X 2 and X 3 may be the same or different, indicating (1 g a hydrogen atom; (2 g) a halogen atom; (3 g) a formazan group; (4 g) a cyano group; (5 g) a hydroxyimine (C 1 -C 6 )alkyl group; (6g) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (7g)(C 1 -C 6 )alkyl; (8g)halo(C 1 -C 6 )alkyl (9g)(C 1 -C 6 )alkoxy; (10g)(C 1 -C 6 )alkylthio; (11g)halo(C 1 -C 6 )alkylthio; (12g) (C 1 -C 6 )alkylsulfinyl; (13 g) halo(C 1 -C 6 )alkylsulfinyl; (14 g) (C 1 -C 6 ) alkanesulfonyl; (15 g) halogen (C 1 - C 6 ) alkanesulfonyl; (16 g) (C 1 -C 6 ) alkoxycarbonyl; (17 g) phenyl; (18 g) having the same or different in the ring, (i) a halogen atom, Ii) cyano, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, and (vi) a substituted phenyl group having one or more substituents selected by a halogen (C 1 -C 6 ) alkoxy group; (19 g) phenyl(C 1 -C 6 )alkyl group; (20 g) having the same on the ring Or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy group, (vi) halogen (C 1 -C 6 ) alkoxy group, and (vii) substituted benzene (C 1 -C 6 ) of one or more substituents selected by the formyl group alkyl; (21g) (C 3 -C 6) cycloalkyl; (22g) aromatic heterocyclic group; (23g) has on the ring, may be the same or With, of (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6) alkyl, (v) (C 1 -C 6 ) alkoxy group, (vi) halogen (C 1 -C 6 ) alkoxy group, and (vii) substituted aromatic heterocyclic group having one or more substituents selected from the formyl group; (24 g) aroma a heterocyclic oxy group; or (25g) which may be the same or different from the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) Halogen (C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, and (vii)methyl indenyl selected A substituted aromatic heterocyclic oxy group having one or more substituents. [2] The thiazole carboxamide derivative or a salt thereof according to the above [1], wherein R 1 represents (1a) a halogen atom; (2a) (C 1 - C 6 ) alkyl; (3a) Halogen (C 1 -C 6 )alkyl; (4a)(C 1 -C 6 )alkoxy; or (6a)(C 3 -C 6 )cycloalkyl, Y represents, O,S,-N ( R 3 )-, or -N=C(R 3 )- (wherein R 3 represents (1b) a hydrogen atom; (2b) a (C 1 -C 6 )alkyl group; (8b) a formazan group; 9b) (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (11b) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; (12b) (C 1 - C 6 ) alkyl sulfinium (C 1 -C 6 ) alkyl; (13b) (C 1 -C 6 ) alkanesulfonyl (C 1 -C 6 )alkyl; (14b) (C 1 -C 6 ) Alkoxycarbonyl; (15b) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkylcarbonyl; (16b) (C 1 -C 6 ) alkylcarbonyl; (17b) halogen (C 1 -C 6 ) (18b)(C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl (19b)(C 3 -C 6 )cycloalkyl; or (20b)(C 1 -C 6 ) Alkoxy.), (1) Y represents, O, S, or -N(R 3 )- (R 3 is the same as defined above), and R 2 represents (1c)amine (C 1 -C 6 ) alkane (2c) mono(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl; (3c)di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl (di The alkyl groups of C 1 -C 6 )alkylamino groups may be the same or different.); (4c) (C 1 -C 6 ) alkylcarbonylamine (C 1 -C 6 )alkyl; (5c)(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (6c)(C 1 -C 6 )alkane Sulfonamide (C 1 -C 6 )alkyl; (7c) mono(C 1 -C 6 )alkylaminecarbonyl; (9c)mono(C 1 -C 6 )alkylaminethiocarbonyl; (11c)hydroxyl (C 1 -C 6 )alkyl; (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (13c)halo(C 1 -C 6 )alkoxy (C 1 -C 6 ) (15c)(C 2 -C 6 ) alkynyloxy(C 1 -C 6 )alkyl; (16c)(C 3 -C 6 )cycloalkoxy (C 1 -C 6 )alkyl; (17c The alkoxy group of the di(C 1 -C 6 ) alkoxy(C 1 -C 6 )alkyl group (di(C 1 -C 6 ) alkoxy group may be the same or different.); (18c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (19c) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (20c Benzene (C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (21c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkylcarbonyl; (23c)di(C 1 ) The alkyl group of -C 6 )alkylamine carbonyloxy(C 1 -C 6 )alkyl (di(C 1 -C 6 )alkylamino group may be the same or different. (24c)(C 1 -C 6 )alkylthio(C 1 -C 6 )alkyl; (25c)(C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; (26c (C 1 -C 6 ) alkanesulfonyl (C 1 -C 6 )alkyl; (27c) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (28c) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (29c) N-(C 1 -C 6 )alkane-N-formamide (C 1 -C 6 )alkyl; (30c) N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (31c) non-aromatic heterocyclic group; (32c) on the ring Yes, may be the same or different, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected one or more substitutions a substituted non-aromatic heterocyclic group; (33c) a non-aromatic heterocyclic (C 1 -C 6 )alkyl group; (34c) having the same or different in the ring, and (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi) a substituted non-aromatic heterocyclic ring (C 1 -) having one or more substituents selected from the group consisting of a halogen (C 1 -C 6 ) alkoxy group, (vii) a formazan group and a (viii)oxy group (=O) C 6 )alkyl; (35c) non-aromatic heteroepoxy (C 1 -C 6 )alkyl; (36c), which may be the same or different, on the ring, from (i) a halogen atom, (ii) cyanide a group, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo (C 1 -C 6 ) alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected one or more substituents of substituted non-aromatic heteroepoxy (C 1 -C 6 ) alkane (37c) an aromatic heterocyclic group; (39c) an aromatic heterocyclic (C 1 -C 6 )alkyl group; (40c) having the same or different ring groups, (i) a halogen atom, Ii) cyano, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halogen a (C 1 -C 6 ) alkoxy group, and (vii) a substituted aromatic heterocyclic (C 1 -C 6 )alkyl group having one or more substituents selected from a formazan group; (41c) R 2 and R 3 bonding, together with the nitrogen atom to which it is bonded, may form a 5- or 6-membered nitrogen-containing aliphatic heterocyclic ring containing 0 to 1 oxygen atom, 0 to 1 a sulfur atom, 1 to 2 nitrogen atoms, the nitrogen-containing aliphatic heterocyclic ring may have (i) a halogen atom, (ii) a cyanide on the ring. a group, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo (C 1 -C 6 ) alkoxy, (vii)methyl indenyl and (viii)oxy (=O) may be the same or different, one or more substituents; (42c) formazan (C 1 ) -C 6 )alkyl; (43c) bis(methyloxy)(C 1 -C 6 )alkyl; (44c)(C 1 -C 6 )alkylsulfonyloxy(C 1 -C 6 )alkyl (45c)(C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (46c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkoxy (C 1 - C 6 ) alkoxy (C 1 -C 6 )alkyl; or (47c)carboxy(C 1 -C 6 )alkyl, (2)Y represents, -N=C(R 3 )-(R 3 and the foregoing with. Wherein R 2 represents (2d)(C 1 -C 6 )alkoxy; or (4d)di(C 1 -C 6 )alkylamino (di(C 1 -C 6 )alkylamino alkane The groups may be the same or different.), R 4 , R 5 , R 6 , and R 7 may be the same or different and represent (1e) a hydrogen atom; (2e) (C 1 -C 6 )alkyl; (3e) Halogen (C 1 -C 6 )alkyl; (7e)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; or (8e)R 4 and R 5 , R 6 and R 7 ,R 4 is bonded to R 6 or R 4 and R 7 and together with the carbon atom to which it is bonded, forms an aliphatic ring of 3 to 6 members, and R 8 represents (1f) a hydrogen atom; (3f) (C 1 -C 6 )alkoxy; (4f)(C 3 -C 6 )cycloalkyl; (5f)(C 1 -C 6 )alkylcarbonyl; or (7f)(C 1 -C 6 )alkoxycarbonyl, X 1 , X 2 and X 3 may be the same or different and represent (1 g) a hydrogen atom; (2 g) a halogen atom; (4 g) a cyano group; (6 g) a (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (7g) (C 1 -C 6 )alkyl; (8g) halo(C 1 -C 6 )alkyl; (9g)(C 1 -C 6 )alkoxy; (16g (C 1 -C 6 ) alkoxycarbonyl; (17 g) phenyl; (18 g) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6) alkyl, (v) (C 1 -C 6) alkyl Group, and (vi) halo (C 1 -C 6) alkoxy selected one or more substituents substituted phenyl group; (21g) (C 3 -C 6) cycloalkyl; (22g) Aromatic a heterocyclic group; (23g) having the same or different in the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen ( C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, and (vii)monomethyl a substituted aromatic heterocyclic group of the above substituent; (24 g) an aromatic heterocyclic oxy group; or (25 g) which may be the same or different from the ring, (i) a halogen atom, (ii) a cyano group , (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo (C 1 - C 6 ) alkoxy group, and (vii) a substituted aromatic heterocyclic oxy group having one or more substituents selected from the fluorenyl group; [3] the thiazole carboxamide derivative according to the above [1] Or a salt thereof, R 1 represents (1a) a halogen atom; (2a) (C 1 -C 6 )alkyl; (3a) halo(C 1 -C 6 )alkyl; or (6a)(C 3 - C 6 ) cycloalkyl, Y represents, O, -N(R 3 )-, or -N=C(R 3 )- (wherein R 3 represents (1b) a hydrogen atom; (2b) (C 1 -C 6 )alkyl; (8b a mercapto group; (9b) (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (11b) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; 12b) (C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; (13b)(C 1 -C 6 )alkane (C 1 -C 6 )alkyl; (14b)( C 1 -C 6 ) alkoxycarbonyl; (15b) (C 1 -C 6 ) alkoxy(C 1 -C 6 )alkylcarbonyl; (16b)(C 1 -C 6 )alkylcarbonyl; (17b)halide C 1 -C 6 )alkylcarbonyl; (18b)(C 1 -C 6 ) alkoxycarbonyl(C 1 -C 6 )alkyl; (19b)(C 3 -C 6 )cycloalkyl; or (20b) (C 1 -C 6 ) alkoxy group. (1) Y represents, O, or -N(R 3 )-(R 3 is the same as defined above), R 2 represents (1c)amine (C 1 -C 6 )alkyl; (2c) (C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl; (3c)di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl (di(C 1 -C 6 ) The alkyl groups of the alkylamino group may be the same or different.); (5c) (C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (6c)(C 1 -C 6 )alkane Indoleamine (C 1 -C 6 )alkyl; (7c)mono(C 1 -C 6 )alkylaminecarbonyl; (9c)mono(C 1 -C 6 )alkylaminethiocarbonyl; (11c)hydroxyl (C 1 -C 6 )alkyl; (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (17c)di(C 1 -C 6 )alkoxy(C 1 -C 6 ) alkane The alkoxy groups of the (di(C 1 -C 6 ) alkoxy group may be the same or different.); (18c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 - C 6 )alkyl; (19c) (C 1 -C 6 ) alkoxycarbonyl(C 1 -C 6 )alkyl; (21c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkylcarbonyl (23c) bis(C 1 -C 6 )alkylaminecarbonyloxy(C 1 -C 6 )alkyl (alkyl of di(C 1 -C 6 )alkylamino group may be the same or different.); (24c) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; (25c)(C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; (26c) (C 1 -C 6 ) alkanesulfonyl (C 1 -C 6 )alkyl; (27c) (C 1 -C 6 Alkoxycarbonyl (C 1 -C 6 )alkyl; (30c) N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl (31c) a non-aromatic heterocyclic group; (32c) having the same or different in the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii)methyl fluorenyl And (viii) a substituted non-aromatic heterocyclic group having one or more substituents selected from the group consisting of an oxygen group (=O); (33c) a non-aromatic heterocyclic group (C 1 -C 6 )alkyl group; (34c) On the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 ) alkyl group. , (v) (C 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected 1 a substituted non-aromatic heterocyclic (C 1 -C 6 )alkyl group having more than one substituent; (35c) a non-aromatic heteroepoxy (C 1 -C 6 )alkyl group; (36c) having a ring, May be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) ( C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii) a substituted non-aromatic heteroepoxy (C 1 -C 6 )alkyl group having one or more substituents selected from the group consisting of a fluorenyl group and (viii) anoxy group (=O); (39c) an aromatic heterocyclic ring (C) 1 -C 6 )alkyl; (40c) may be the same or different on the ring, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) a mercapto group selected a substituted aromatic heterocyclic (C 1 -C 6 )alkyl group having one or more substituents; (41c) R 2 is bonded to R 3 and together with the nitrogen atom to which it is bonded, forms 5 or 6 members A nitrogen-containing aliphatic heterocyclic ring may be used. The nitrogen-containing aliphatic heterocyclic ring is an oxygen atom having 0 to 1 ring, 0 to 1 sulfur atom, 1 to 2 nitrogen atoms, and the nitrogen-containing aliphatic heterocyclic ring. Yes, there may be (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 )alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) may be the same or different , one or more substituents; (42c) formazan (C 1 -C 6 )alkyl; (43c) bis(methyloxy)(C 1 -C) 6 ) alkyl; (44c) (C 1 -C 6 ) alkanesulfonyloxy (C 1 -C 6 )alkyl; (45c)(C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 ) Alkyl; (46c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; or (47c)carboxy (C 1 -C 6 )alkyl, (2)Y represents -N=C(R 3 )-(R 3 is the same as defined above. Wherein R 2 represents (2d)(C 1 -C 6 )alkoxy; or (4d)di(C 1 -C 6 )alkylamino (di(C 1 -C 6 )alkylamino alkane The groups may be the same or different.), R 4 , R 5 , R 6 , and R 7 may be the same or different and represent (1e) a hydrogen atom; (2e) (C 1 -C 6 )alkyl; or (3e a halogen (C 1 -C 6 )alkyl group, R 8 represents (1f) a hydrogen atom; (3f) (C 1 -C 6 ) alkoxy group; or (4f) (C 3 -C 6 ) cycloalkyl group , X 1 , X 2 and X 3 may be the same or different and represent (1 g) a hydrogen atom; (2 g) a halogen atom; (6 g) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 ) (7g) (C 1 -C 6 )alkyl; (8g) halo(C 1 -C 6 )alkyl; (9g)(C 1 -C 6 )alkoxy; (16g) (C 1 -C 6 ) alkoxycarbonyl; (17 g) phenyl; (18 g) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 Alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, and (vi)halo(C 1 -C 6 )alkoxy selected a substituted phenyl group having one or more substituents; (21 g) (C 3 -C 6 )cycloalkyl group; (22 g) an aromatic heterocyclic group; or (23 g) having the same or different in the ring, From (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 An alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii a substituted aromatic heterocyclic group of one or more substituents selected from the group consisting of the above-mentioned [1] to [3], or a salt thereof, or a salt thereof. And R 4 represents a (C 1 -C 6 )alkyl group or a halogen (C 1 -C 6 )alkyl group, and R 5 , R 6 , and R 7 represent a hydrogen atom; [5] a plant disease controlling agent, which is characterized The thiazolyl carboxamide derivative according to any one of the above [1] or [4] or a salt thereof as an active ingredient; [6] a method for controlling a plant disease, characterized by the above [1] Or the effective amount of the thiazolcarboxamide derivative or the salt thereof according to any one of the above items, and the seed of the target crop and/or the target crop; [7] one use of the above [1] or even [4] The thiazole carboquinone derivative or a salt thereof according to any one of the items 1 as a plant disease controlling agent: and the like.

本發明是，提供比以往的技術有優異的性能的植物病害防治劑，特別是做為以水面施用或箱處理的稻熱病防治劑而有用的化合物。 The present invention provides a plant disease controlling agent which has superior performance to the prior art, and is particularly useful as a rice fever control agent which is applied by water surface or tank.

在下面說明本發明的一般式(I)噻唑羧醯胺的定義。 The definition of the general formula (I) thiazole carboxamide of the present invention is explained below.

「鹵原子」，「鹵」表示，氟原子，氯原子，溴原子，或碘原子。 "Halogen", "halo" means a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom.

「(C1-C6)烷基」就是，例如，表示甲基，乙基，正丙基，異丙基，正丁基，異丁基，二級丁基，三級丁基，正戊基，新戊基，正己基等的直鏈或支鏈狀的碳原子數1至6個的烷基。 "(C 1 -C 6 )alkyl" means, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, butyl, tert-butyl, n-pentyl A linear or branched alkyl group having 1 to 6 carbon atoms, such as a benzyl group, a neopentyl group or a n-hexyl group.

「(C2-C6)烯基」就是，例如，表示乙烯基，丙烯基，正丁烯基，正戊烯基，正己烯基等的直鏈或支鏈狀的碳原子數2至6個的烯基。 "(C 2 -C 6 )alkenyl" is, for example, a linear or branched carbon atom of 2 to 6 representing a vinyl group, a propenyl group, a n-butenyl group, a n-pentenyl group, a n-hexenyl group or the like. Alkenyl.

「(C2-C6)炔基」就是，例如，表示乙炔基，2-丙炔基，1-甲基-2-丙炔基，1,1-二甲基-2-丙炔基，1-丁炔基，2-丁炔基，3-丁炔基，1-戊炔基，2-戊炔基，3-戊炔基，4-戊炔基，1-甲基-2-丁炔基，1-甲基-3-丁炔基，1,1-二甲基-2-丁炔基，1,1-二甲基-3-丁炔基，1-甲基-3-戊炔基，1-甲基-4-戊炔基等的直鏈或支鏈狀的碳原 子數2至6個的炔基。 "(C 2 -C 6 ) alkynyl" means, for example, ethynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-2-butyl Alkynyl, 1-methyl-3-butynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1-methyl-3-pentyl A linear or branched alkynyl group having 2 to 6 carbon atoms such as an alkynyl group or a 1-methyl-4-pentynyl group.

「鹵(C1-C6)烷基」就是，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數1至6個的烷基，例如，可舉三氟甲基，二氟甲基，氟甲基，全氟乙基，2,2,2-三氟乙基，全氟異丙基，氯甲基，溴甲基，1-溴乙基，2,3-二溴丙基等。 The "halogen (C 1 -C 6 )alkyl group" means a straight or branched alkyl group having 1 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different, for example, , which may, for example, be trifluoromethyl, difluoromethyl, fluoromethyl, perfluoroethyl, 2,2,2-trifluoroethyl, perfluoroisopropyl, chloromethyl, bromomethyl, 1-bromo Ethyl, 2,3-dibromopropyl and the like.

「鹵(C2-C6)烯基」就是，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數2至6個的烯基，例如，可舉2,2-二氯乙烯基，2,2-二溴乙烯基，3-氯丙烯基，3,3-二氟丙烯基，3,3-二氯丙烯基，4-氯-2-丁烯基，4,4,4-三氟-2-丁烯基，4,4,4-三氯-2-丁烯基，5-氯-3-戊烯基，6-氟-2-己烯基等。 The "halo(C 2 -C 6 )alkenyl group" means a linear or branched alkenyl group having 2 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different, for example, 2,2-dichlorovinyl, 2,2-dibromovinyl, 3-chloropropenyl, 3,3-difluoropropenyl, 3,3-dichloropropenyl, 4-chloro-2 -butenyl, 4,4,4-trifluoro-2-butenyl, 4,4,4-trichloro-2-butenyl, 5-chloro-3-pentenyl, 6-fluoro-2 - Hexyl group and the like.

「鹵(C2-C6)炔基」就是，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數2至6個的炔基，例如，可舉2-氟乙炔基，2-溴乙炔基，2-氯乙炔基，2-碘乙炔基，3-氯-1-丙炔基，1-氯-2-丙炔基，3-氯-1-甲基-2-丙炔基，4-氯-1-丁炔基，4-氯-2-丁炔基，4-氯-3-丁炔基，3-氯-1-戊炔基，5,5,5-三氟-3-戊炔基，1-氯-2-丁炔基，4-氯-1-甲基-2-丁炔基，1,1-二甲基-4-氯-2-丁炔基，1-甲基-5-氯-3-戊炔基，1-甲基-5,5,5-三氟-2-戊炔基等。 The "halo(C 2 -C 6 )alkynyl group" means a linear or branched alkynyl group having 2 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different, for example, And 2-fluoroethynyl, 2-bromoethynyl, 2-chloroethynyl, 2-iodoethynyl, 3-chloro-1-propynyl, 1-chloro-2-propynyl, 3-chloro 1-methyl-2-propynyl, 4-chloro-1-butynyl, 4-chloro-2-butynyl, 4-chloro-3-butynyl, 3-chloro-1-pentyne ,5,5,5-trifluoro-3-pentynyl, 1-chloro-2-butynyl, 4-chloro-1-methyl-2-butynyl, 1,1-dimethyl- 4-chloro-2-butynyl, 1-methyl-5-chloro-3-pentynyl, 1-methyl-5,5,5-trifluoro-2-pentynyl and the like.

「(C3-C6)環烷基」就是，例如，表示環丙基，環丁基，環戊基，環己基等的碳原子數3至6個的環烷基。 The "(C 3 -C 6 )cycloalkyl group" is, for example, a cycloalkyl group having 3 to 6 carbon atoms such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group or a cyclohexyl group.

「(C1-C6)烷氧基」就是，例如，表示甲氧基，乙氧基，正丙氧基，異丙氧基，正丁氧基，二級丁氧基，三級丁氧基，正戊氧基，異戊氧基，新戊氧基，正己氧基等的直鏈或支鏈狀的碳 原子數1至6個的烷氧基。 "(C 1 -C 6 ) alkoxy" means, for example, methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, bis-butoxy, tert-butoxy A linear or branched alkoxy group having 1 to 6 carbon atoms, such as a n-pentyloxy group, an isopentyloxy group, a neopentyloxy group, a n-hexyloxy group or the like.

「鹵(C1-C6)烷氧基」就是，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數1至6個的烷氧基，例如可舉三氟甲氧基，二氟甲氧基，全氟乙氧基，2,2,2-三氟乙氧基，全氟異丙氧基，氯甲氧基，溴甲氧基，1-溴乙氧基，2,3-二溴丙氧基等。 The "halogen (C 1 -C 6 ) alkoxy group" means a linear or branched alkoxy group having 1 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different. For example, trifluoromethoxy, difluoromethoxy, perfluoroethoxy, 2,2,2-trifluoroethoxy, perfluoroisopropoxy, chloromethoxy, bromomethoxy , 1-bromoethoxy, 2,3-dibromopropoxy, and the like.

「(C1-C6)烷硫基」就是，例如，表示甲硫基，乙硫基，正丙硫基，異丙硫基，正丁硫基，二級丁硫基，三級丁硫基，正戊硫基，異戊硫基，正己硫基等的直鏈或支鏈狀的碳原子數1至6個的烷硫基。 "(C 1 -C 6 )alkylthio" means, for example, methylthio, ethylthio, n-propylthio, isopropylthio, n-butylthio, dimethylthiocyanate, tertiary butyl sulfide A linear or branched alkylthio group having 1 to 6 carbon atoms such as n-pentylthio, isopentylthio, n-hexylthio or the like.

「(C1-C6)烷亞磺醯基」就是，例如，表示甲亞磺醯基，乙亞磺醯基，正丙亞磺醯基，異丙亞磺醯基，正丁亞磺醯基，二級丁亞磺醯基，三級丁亞磺醯基，正戊亞磺醯基，異戊亞磺醯基，正己亞磺醯基等的直鏈或支鏈狀的碳原子數1至6個的烷亞磺醯基。 "(C 1 -C 6 )alkylsulfinyl) is, for example, a sulfinyl group, an sulfinyl group, a propyl sulfinyl group, an isopropylsulfinyl group, a butyl sulfinium sulfonate. a linear or branched carbon atom number of a base, a secondary butyl sulfinyl group, a tertiary butyl sulfinyl group, a n-pentylene sulfonyl group, an isoamyl sulfinyl group, a hexyl sulfinyl group, or the like Up to 6 alkylsulfinyl groups.

「(C1-C6)烷磺醯基」就是，例如，表示甲磺醯基，乙磺醯基，正丙磺醯基，異丙磺醯基，正丁磺醯基，二級丁磺醯基，三級丁磺醯基，正戊磺醯基，異戊磺醯基，正己磺醯基等的直鏈或支鏈狀的碳原子數1至6個的烷磺醯基。 "(C 1 -C 6 ) alkanesulfonyl" is, for example, a methylsulfonyl group, an ethylsulfonyl group, a n-propylsulfonyl group, an isopropylsulfonyl group, a n-butylsulfonyl group, a secondary butanesulfonate. A linear or branched alkanesulfonyl group having 1 to 6 carbon atoms such as a mercapto group, a tertiary butyl sulfonyl group, a n-pentanesulfonyl group, an isovaleryl group or a hexyl sulfonyl group.

「鹵(C1-C6)烷硫基」就是，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數1至6個的烷硫基，例如，可舉三氟甲硫基，二氟甲硫基，全氟乙硫基，2,2,2-三氟乙硫基，全氟異丙硫基，氯甲硫基，溴甲硫基，1-溴乙硫基，2,3-二溴丙硫基等。 The "halogen (C 1 -C 6 )alkylthio group" means a linear or branched alkylthio group having 1 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different. For example, trifluoromethylthio, difluoromethylthio, perfluoroethylthio, 2,2,2-trifluoroethylthio, perfluoroisopropylthio, chloromethylthio, bromomethylsulfide Base, 1-bromoethylthio, 2,3-dibromopropylthio and the like.

「鹵(C1-C6)烷亞磺醯基」就是，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數1至6個的烷亞磺醯基，例如，可舉三氟甲亞磺醯基，二氟甲亞磺醯基，全氟乙亞磺醯基，2,2,2-三氟乙亞磺醯基，全氟異丙亞磺醯基，氯甲亞磺醯基，溴甲亞磺醯基，1-溴乙亞磺醯基，2,3-二溴丙亞磺醯基等。 The "halogen (C 1 -C 6 ) alkylsulfinyl group" means a linear or branched alkyl group having 1 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different. A sulfinyl group, for example, a trifluoromethanesulfonyl group, a difluoromethanesulfonyl group, a perfluoroethanesulfinyl group, a 2,2,2-trifluoroethanesulfinyl group, a perfluoroiso A sulfinyl group, a chloromethanesulfinyl group, a bromomethylsulfinyl group, a 1-bromoethanesulfinyl group, a 2,3-dibromopropanesulfinyl group, and the like.

「鹵(C1-C6)烷磺醯基」就是，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數1至6個的烷磺醯基，例如，可舉三氟甲磺醯基，二氟甲磺醯基，全氟乙磺醯基，2,2,2-三氟乙磺醯基，全氟異丙磺醯基，氯甲磺醯基，溴甲磺醯基，1-溴乙磺醯基，2,3-二溴丙磺醯基等。 The "halogen (C 1 -C 6 ) alkanesulfonyl group" means a straight or branched chain alkyl group having 1 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different. Sulfhydryl group, for example, trifluoromethanesulfonyl, difluoromethanesulfonyl, perfluoroethanesulfonyl, 2,2,2-trifluoroethanesulfonyl, perfluoroisopropylsulfonyl, chlorine Methanesulfonyl, bromomethylsulfonyl, 1-bromoethanesulfonyl, 2,3-dibromopropylsulfonyl and the like.

「(C1-C6)烷羰基」就是，例如，表示甲羰基(乙醯基)，乙羰基，正丙羰基，異丙羰基，正丁羰基，三級丁羰基等的直鏈或支鏈狀的碳原子數1至6個的烷-羰基。 "(C 1 -C 6 )alkylcarbonyl" is, for example, a straight or branched chain represented by methylcarbonyl (ethinyl), ethylcarbonyl, n-propylcarbonyl, isopropylcarbonyl, n-butylcarbonyl, tert-butylcarbonyl or the like. An alkane-carbonyl group having 1 to 6 carbon atoms.

「鹵(C1-C6)烷羰基」就是，例如，表示被可以相同或不相同的1個以上的鹵原子所取代的直鏈或支鏈狀的碳原子數1至6個的烷-羰基，例如，可舉三氟乙醯基，二氟乙醯基，全氟乙羰基，全氟異丙羰基，2,2,2-三氟乙羰基，氯乙醯基，溴乙醯基，1-溴乙羰基，2,3-二溴丙羰基等。 The "halo(C 1 -C 6 )alkylcarbonyl group" means, for example, a linear or branched alkyl group having 1 to 6 carbon atoms which may be substituted by one or more halogen atoms which may be the same or different. The carbonyl group may, for example, be a trifluoroethenyl group, a difluoroacetinyl group, a perfluoroethylcarbonyl group, a perfluoroisopropylcarbonyl group, a 2,2,2-trifluoroethylcarbonyl group, a chloroethyl group, a bromoethyl group, 1-Bromoethylcarbonyl, 2,3-dibromopropylcarbonyl, and the like.

「(C3-C6)環烷羰基」而言，例如，表示環丙羰基，環丁羰基，環戊羰基，環己羰基等的碳原子數3至6個的環烷-羰基。 The "(C 3 -C 6 )cycloalkanecarbonyl group" is, for example, a cycloalkane-carbonyl group having 3 to 6 carbon atoms such as a cyclopropylcarbonyl group, a cyclobutylcarbonyl group, a cyclopentylcarbonyl group or a cyclohexylcarbonyl group.

「(C1-C6)烷氧羰基」就是，例如，表示甲氧羰基，乙氧羰基，正丙氧羰基，異丙氧羰基，正丁氧羰基，三級丁氧羰基等的直鏈或支鏈狀的碳原子數1至6個的烷氧-羰基。 "(C 1 -C 6 ) alkoxycarbonyl" is, for example, a straight chain representing a methoxycarbonyl group, an ethoxycarbonyl group, a n-propoxycarbonyl group, an isopropoxycarbonyl group, a n-butoxycarbonyl group, a tertiary butoxycarbonyl group or the like. A branched alkoxy-carbonyl group having 1 to 6 carbon atoms.

「(C3-C6)環烷氧羰基」而言，例如，表示環丙氧羰基，環丁氧羰基，環戊氧羰基，環己氧羰基等的碳原子數3至6個的環烷氧-羰基。 The "(C 3 -C 6 )cycloalkoxycarbonyl group" is, for example, a cycloalkane having 3 to 6 carbon atoms such as a cyclopropoxycarbonyl group, a cyclobutoxycarbonyl group, a cyclopentyloxycarbonyl group or a cyclohexyloxycarbonyl group. Oxy-carbonyl.

「單(C1-C6)烷胺基」就是，例如，表示N-甲胺基，N-乙胺基，N-正丙胺基，N-異丙胺基，N-正丁胺基，N-異丁胺基，N-二級丁胺基，N-三級丁胺基，N-正戊胺基，N-新戊胺基，N-正己胺基等的直鏈或支鏈狀的碳原子數1至6個的單烷胺基。 "Single (C 1 -C 6 )alkylamino group" means, for example, N-methylamino, N-ethylamino, N-n-propylamino, N-isopropylamino, N-n-butylamino, N -linear or branched, isobutylamino, N-tert-butylamino, N-tert-butylamino, N-n-pentylamino, N-neopentyl, N-n-hexylamine, etc. A monoalkylamine group having 1 to 6 carbon atoms.

「二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基，可以相同或不相同。)」就是，例如，表示N,N-二甲胺基，N,N-二乙胺基，N,N-二正丙胺基，N,N-二異丙胺基，N,N-二正丁胺基，N,N-二異丁胺基，N,N-二二級丁胺基，N,N-二三級丁胺基，N,N-二正戊胺基，N,N-二新戊胺基，N,N-二正己胺基，N-甲基-N-乙胺基，N-甲基-N-正丙胺基，N-甲基-N-異丙胺基，N-甲基-N-正丁胺基，N-甲基-N-異丁胺基，N-甲基-N-二級丁胺基，N-甲基-N-三級丁胺基，N-甲基-N-正戊胺基，N-甲基-N-新戊胺基，N-甲基-N-正己胺基等的可以相同或不相同的二個(C1-C6)烷基所成的二烷胺基。 "Alkyl group of a di(C 1 -C 6 )alkylamino group (di(C 1 -C 6 )alkylamino group may be the same or different.)" means, for example, an N,N-dimethylamino group, N,N-diethylamino, N,N-di-n-propylamino, N,N-diisopropylamino, N,N-di-n-butylamino, N,N-diisobutylamino, N,N -Secondary butylamino, N,N-di-tert-butylamino, N,N-di-n-pentylamino, N,N-di-p-amylamine, N,N-di-n-hexylamine, N- Methyl-N-ethylamino, N-methyl-N-n-propylamino, N-methyl-N-isopropylamino, N-methyl-N-n-butylamino, N-methyl-N- Isobutylamino, N-methyl-N-second butylamino, N-methyl-N-tertiary butylamino, N-methyl-N-n-pentylamino, N-methyl-N- A dialkylamino group which may be the same or different two (C 1 -C 6 ) alkyl groups such as neopentylamino, N-methyl-N-n-hexylamino and the like.

「單(C1-C6)烷胺羰基」就是，例如，表示N-甲胺羰基，N-乙胺羰基，N-正丙胺羰基，N-異丙胺羰基，N-正丁胺羰基，N-異丁胺羰基，N-二級丁胺羰基，N-三級丁胺羰基，N-正戊胺羰基，N-新戊胺羰基，N-正己胺羰基等的直鏈或支鏈狀的碳原子數1至6個的單烷胺基-羰基。 "mono(C 1 -C 6 )alkylaminecarbonyl" means, for example, N-methylaminecarbonyl, N-ethylaminecarbonyl, N-n-propylaminecarbonyl, N-isopropylaminecarbonyl, N-n-butylaminecarbonyl, N -linear or branched chain of isobutylamine carbonyl, N-second butylamine carbonyl, N-tertiary butylamine carbonyl, N-n-pentylaminecarbonyl, N-neopentylcarbonylcarbonyl, N-n-hexylaminecarbonyl, etc. A monoalkylamino-carbonyl group having 1 to 6 carbon atoms.

「二(C1-C6)烷胺羰基(二(C1-C6)烷胺基的烷基可以相同或不相同。)」就是，例如，表示N,N-二甲胺羰基，N,N-二乙胺羰基，N,N-二正丙胺羰基，N,N-二異丙胺羰基，N,N-二正丁胺羰基， N,N-二異丁胺羰基，N,N-二二級丁胺羰基，N,N-二三級丁胺羰基，N,N-二正戊胺羰基，N,N-二新戊胺羰基，N,N-二正己胺羰基，N-甲基-N-乙胺羰基，N-甲基-N-正丙胺羰基，N-甲基-N-異丙胺羰基，N-甲基-N-正丁胺羰基，N-甲基-N-異丁胺羰基，N-甲基-N-二級丁胺羰基，N-甲基-N-三級丁胺羰基，N-甲基-N-正戊胺羰基，N-甲基-N-新戊胺羰基，N-甲基-N-正己胺羰基等的可以相同或不相同的二個(C1-C6)烷基所成的二烷胺基-羰基。 "Di(C 1 -C 6 )alkylaminecarbonyl (alkyl group of di(C 1 -C 6 )alkylamino group may be the same or different.)", that is, for example, represents N,N-dimethylaminecarbonyl, N , N-diethylamine carbonyl, N,N-di-n-propylamine carbonyl, N,N-diisopropylaminecarbonyl, N,N-di-n-butylaminecarbonyl, N,N-diisobutylaminecarbonyl, N,N- Dibasic butylamine carbonyl, N,N-di-tertiary butylamine carbonyl, N,N-di-n-pentylamine carbonyl, N,N-di-p-amylamine carbonyl, N,N-di-n-hexylamine carbonyl, N-A --N-ethylamine carbonyl, N-methyl-N-n-propylamine carbonyl, N-methyl-N-isopropylaminecarbonyl, N-methyl-N-n-butylaminecarbonyl, N-methyl-N-iso Butylaminecarbonyl, N-methyl-N-secondary butylamine carbonyl, N-methyl-N-tertiary butylamine carbonyl, N-methyl-N-n-pentylaminecarbonyl, N-methyl-N-new a dialkylamino-carbonyl group which may be the same or different two (C 1 -C 6 )alkyl groups such as pentylaminecarbonyl, N-methyl-N-n-hexylaminecarbonyl or the like.

「單(C1-C6)烷胺硫羰基」就是，例如，表示N-甲胺硫羰基，N-乙胺硫羰基，N-正丙胺硫羰基，N-異丙胺硫羰基，N-正丁胺硫羰基，N-異丁胺硫羰基，N-二級丁胺硫羰基，N-三級丁胺硫羰基，N-正戊胺硫羰基，N-新戊胺硫羰基，N-正己胺硫羰基等的直鏈或支鏈狀的碳原子數1至6個的單烷胺基-硫羰基。 "mono(C 1 -C 6 )alkylaminethiocarbonyl" means, for example, N-methylaminethiocarbonyl, N-ethylaminethiocarbonyl, N-n-propylaminethiocarbonyl, N-isopropylaminethiocarbonyl, N-positive Butyl thiocarbonyl, N-isobutylamine thiocarbonyl, N-second butylamine thiocarbonyl, N-tertiary butylamine thiocarbonyl, N-n-pentyl thiocarbonyl, N-neopentyl thiocarbonyl, N-positive A linear or branched monoalkylamino-thiocarbonyl group having 1 to 6 carbon atoms such as an amine thiocarbonyl group.

「二(C1-C6)烷胺硫羰基(二(C1-C6)烷胺基的烷基可以相同或不相同。)」就是，例如，表示N,N-二甲胺硫羰基，N,N-二乙胺硫羰基，N,N-二正丙胺硫羰基，N,N-二異丙胺硫羰基，N,N-二正丁胺硫羰基，N,N-二異丁胺硫羰基，N,N-二二級丁胺硫羰基，N,N-二三級丁胺硫羰基，N,N-二正戊胺硫羰基，N,N-二新戊胺硫羰基，N,N-二正己胺硫羰基，N-甲基-N-乙胺硫羰基，N-甲基-N-正丙胺硫羰基，N-甲基-N-異丙胺硫羰基，N-甲基-N-正丁胺硫羰基，N-甲基-N-異丁胺硫羰基，N-甲基-N-二級丁胺硫羰基，N-甲基-N-三級丁胺硫羰基，N-甲基-N-正戊胺硫羰基，N-甲基-N-新戊胺硫羰基，N-甲基-N-正己胺硫羰基等的可以相同或不相同的二個(C1-C6)烷基所成的二烷胺基-硫羰基。 "Di(C 1 -C 6 )alkylaminethiocarbonyl (alkyl group of di(C 1 -C 6 )alkylamino group may be the same or different.)", for example, represents N,N-dimethylamine thiocarbonyl. ,N,N-diethylaminethiocarbonyl, N,N-di-n-propylamine thiocarbonyl, N,N-diisopropylaminethiocarbonyl, N,N-di-n-butylamine thiocarbonyl, N,N-diisobutylamine Thiocarbonyl, N,N-di-second butylamine thiocarbonyl, N,N-di-tertiary butylamine thiocarbonyl, N,N-di-n-pentylamine thiocarbonyl, N,N-di-p-amylamine thiocarbonyl, N , N-di-n-hexylamine thiocarbonyl, N-methyl-N-ethylamine thiocarbonyl, N-methyl-N-n-propylamine thiocarbonyl, N-methyl-N-isopropylamine thiocarbonyl, N-methyl- N-n-butylamine thiocarbonyl, N-methyl-N-isobutylamine thiocarbonyl, N-methyl-N-second butylamine thiocarbonyl, N-methyl-N-tertiary butylamine thiocarbonyl, N -Methyl-N-n-pentylamine thiocarbonyl, N-methyl-N-nepylamine thiocarbonyl, N-methyl-N-n-hexylamine thiocarbonyl, etc. which may be the same or different (C 1 - C 6 ) Dialkylamino-thiocarbonyl group formed by an alkyl group.

「(C1-C6)烷氧亞胺(C1-C6)烷基」就是，表示直鏈或支 鏈狀的碳原子數1至6個的烷氧亞胺基與(C1-C6)烷基鍵合的基，例如，可舉甲氧基亞胺基甲基，乙氧基亞胺基甲基，正丙氧基亞胺基甲基，異丙氧基亞胺基甲基，1-(甲氧基亞胺基)乙基，1-(乙氧基亞胺基)乙基，1-(正丙氧基亞胺基)甲基，1-(異丙氧基亞胺基)乙基，2-(甲氧基亞胺基)乙基，2-(乙氧基亞胺基)乙基，2-(正丙氧基亞胺基)甲基，2-(異丙氧基亞胺基)乙基等。 "(C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl" means a straight or branched alkoxyimine group having 1 to 6 carbon atoms and (C 1 - C 6 ) alkyl-bonded group, for example, methoxyiminomethyl, ethoxyiminomethyl, n-propoxyiminomethyl, isopropoxyimine , 1-(methoxyimino)ethyl, 1-(ethoxyimino)ethyl, 1-(n-propoxyimino)methyl, 1-(isopropoxy) Amino)ethyl, 2-(methoxyimino)ethyl, 2-(ethoxyimino)ethyl, 2-(n-propoxyimino)methyl, 2-(iso Propoxyimido)ethyl and the like.

「羥亞胺(C1-C6)烷基」就是，表示羥基亞胺基與(C1-C6)烷基鍵合的基，例如，可舉羥基亞胺基甲基，1-(羥基亞胺基)乙基，2-(羥基亞胺基)乙基等。 The "hydroxyiamine (C 1 -C 6 )alkyl group" is a group which represents a hydroxyimino group bonded to a (C 1 -C 6 ) alkyl group, and, for example, a hydroxyiminomethyl group, 1-( Hydroxyimino)ethyl, 2-(hydroxyimino)ethyl and the like.

「羥(C1-C6)烷基」就是，表示羥基與(C1-C6)烷基鍵合的基，例如，可舉羥基甲基，1-羥乙基，2-羥乙基，3-羥丙基，4-羥丁基等。 The "hydroxy(C 1 -C 6 )alkyl group" is a group which represents a hydroxyl group bonded to a (C 1 -C 6 ) alkyl group, and examples thereof include a hydroxymethyl group, a 1-hydroxyethyl group, and a 2-hydroxyethyl group. , 3-hydroxypropyl, 4-hydroxybutyl and the like.

「(C1-C6)烷氧(C1-C6)烷基」就是，表示(C1-C6)烷氧基與(C1-C6)烷基鍵合的基，例如，可舉甲氧甲基，乙氧甲基，正丙氧甲基，異丙氧甲基，正丁氧甲基，二級丁氧甲基，三級丁氧甲基，正戊氧甲基，異戊氧甲基，新戊氧甲基，正己氧甲基，1-甲氧乙基，1-乙氧乙基，1-正丙氧乙基，1-異丙氧乙基，1-正丁氧乙基，1-二級丁氧乙基，1-三級丁氧乙基，1-正戊氧乙基，1-異戊氧乙基，1-新戊氧乙基，1-正己氧乙基，2-甲氧乙基，2-乙氧乙基，2-正丙氧乙基，2-異丙氧乙基，2-正丁氧乙基，2-二級丁氧乙基，2-三級丁氧乙基，2-正戊氧乙基，2-異戊氧乙基，2-新戊氧乙基，2-正己氧乙基，3-甲氧丙基，4-甲氧丁基，1-甲氧基-1-甲基乙基，2-甲氧基-1-甲基乙基，3-甲氧基-1-甲基丙基，4-甲氧基-1-甲基丁基，1-甲氧基-2-甲基乙基，2-甲氧基-2-甲基乙基，3-甲氧基-2-甲 基丙基，4-甲氧基-2-甲基丁基，3-乙氧丙基，4-乙氧丁基等。 "(C 1 -C 6 ) alkoxy(C 1 -C 6 )alkyl" is a group which represents a (C 1 -C 6 ) alkoxy group bonded to a (C 1 -C 6 ) alkyl group, for example, Methoxymethyl, ethoxymethyl, n-propoxymethyl, isopropoxymethyl, n-butoxymethyl, di-butoxymethyl, tert-butoxymethyl, n-pentyloxymethyl, Isovalerylmethyl, neopentyloxymethyl, n-hexyloxymethyl, 1-methoxyethyl, 1-ethoxyethyl, 1-n-propoxyethyl, 1-isopropoxyethyl, 1-positive Butoxyethyl, 1-second butoxyethyl, 1-tert-butoxyethyl, 1-n-pentyloxyethyl, 1-isopentyloxyethyl, 1-neopentyloxyethyl, 1-n-hexane Oxyethyl, 2-methoxyethyl, 2-ethoxyethyl, 2-n-propoxyethyl, 2-isopropoxyethyl, 2-n-butoxyethyl, 2-second butoxyethyl , 2-tertiary butoxyethyl, 2-n-pentyloxyethyl, 2-isopentyloxyethyl, 2-pivaloethoxyethyl, 2-n-hexyloxyethyl, 3-methoxypropyl, 4- Methoxybutyl, 1-methoxy-1-methylethyl, 2-methoxy-1-methylethyl, 3-methoxy-1-methylpropyl, 4-methoxy- 1-methylbutyl, 1-methoxy-2-methylethyl, 2-methoxy-2-methylethyl, 3-methoxy-2-methylpropyl, 4-methoxy-2-methylbutyl, 3-ethoxypropyl, 4-ethoxybutyl and the like.

「鹵(C1-C6)烷氧(C1-C6)烷基」就是，表示鹵(C1-C6)烷氧基與(C1-C6)烷基鍵合的基，例如，可舉三氟甲氧甲基，二氟甲氧甲基，全氟乙氧甲基，2,2,2-三氟乙氧甲基，全氟異丙氧甲基，氯甲氧甲基，溴甲氧甲基，1-溴乙氧甲基，2,3-二溴丙氧甲基，1-三氟甲氧乙基，1-二氟甲氧乙基，1-全氟乙氧乙基，1-(2,2,2-三氟乙氧基)乙基，1-全氟異丙氧乙基，1-氯甲氧乙基，1-溴甲氧乙基，1-(1-溴乙氧基)乙基，1-(2,3-二溴丙氧基)乙基，2-三氟甲氧乙基，2-二氟甲氧乙基，2-全氟乙氧乙基，2-(2,2,2-三氟乙氧基)乙基，2-全氟異丙氧乙基，2-氯甲氧乙基，2-溴甲氧乙基，2-(1-溴乙氧基)乙基，2-(2,3-二溴丙氧基)乙基，3-三氟甲氧丙基，4-三氟甲氧丁基，3-(2,2,2-三氟乙氧基)丙基，4-(2,2,2-三氟乙氧基)丁基等。 "Halo(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl" means a group in which a halogen (C 1 -C 6 )alkoxy group is bonded to a (C 1 -C 6 )alkyl group, For example, trifluoromethoxymethyl, difluoromethoxymethyl, perfluoroethoxymethyl, 2,2,2-trifluoroethoxymethyl, perfluoroisopropyloxymethyl, chloromethoxy Base, bromomethoxymethyl, 1-bromoethoxymethyl, 2,3-dibromopropoxymethyl, 1-trifluoromethoxyethyl, 1-difluoromethoxyethyl, 1-perfluoro Oxyethyl, 1-(2,2,2-trifluoroethoxy)ethyl, 1-perfluoroisopropyloxyethyl, 1-chloromethoxyethyl, 1-bromomethoxyethyl, 1- (1-Bromoethoxy)ethyl, 1-(2,3-dibromopropoxy)ethyl, 2-trifluoromethoxyethyl, 2-difluoromethoxyethyl, 2-perfluoro Oxyethyl, 2-(2,2,2-trifluoroethoxy)ethyl, 2-perfluoroisopropoxyethyl, 2-chloromethoxyethyl, 2-bromomethoxyethyl, 2- (1-Bromoethoxy)ethyl, 2-(2,3-dibromopropoxy)ethyl, 3-trifluoromethoxypropyl, 4-trifluoromethoxybutyl, 3-(2, 2,2-Trifluoroethoxy)propyl, 4-(2,2,2-trifluoroethoxy)butyl and the like.

「(C2-C6)烯氧(C1-C6)烷基」就是，表示(C2-C6)烯氧基與(C1-C6)烷基鍵合的基，例如，可舉乙烯氧甲基，丙烯氧甲基，正丁烯氧甲基，正戊烯氧甲基，正己烯氧甲基，1-乙烯氧乙基，1-丙烯氧乙基，1-正丁烯氧乙基，1-正戊烯氧乙基，1-正己烯氧乙基，2-乙烯氧乙基，2-丙烯氧乙基，2-正丁烯氧乙基，2-正戊烯氧乙基，2-正己烯氧乙基，3-丙烯氧丙基，4-丙烯氧丁基等。 "(C 2 -C 6 ) olefinic oxygen (C 1 -C 6 )alkyl" is a group which represents a (C 2 -C 6 )alkenyloxy group bonded to a (C 1 -C 6 ) alkyl group, for example, Ethyloxymethyl, propyleneoxymethyl, n-butenyloxymethyl, n-pentenyloxymethyl, n-hexenyloxymethyl, 1-vinyloxyethyl, 1-propenyloxyethyl, 1-n-butyl Alkenyloxyethyl, 1-n-pentenyloxyethyl, 1-n-hexenyloxyethyl, 2-vinyloxyethyl, 2-propenyloxyethyl, 2-n-butenyloxyethyl, 2-n-pentene Oxyethyl, 2-n-hexenyloxyethyl, 3-propenyloxypropyl, 4-propoxylated butyl, and the like.

「(C2-C6)炔氧(C1-C6)烷基」就是，表示(C2-C6)炔氧基與(C1-C6)烷基鍵合的基，例如，可舉乙炔氧甲基，2-丙炔氧甲基，(1-甲基-2-丙炔氧基)甲基，(1,1-二甲基-2-丙炔氧基)甲基，1-丁炔氧甲基，2-丁炔氧甲基，3-丁炔氧甲基，1-戊炔氧甲基，2-戊炔氧甲基，3-戊炔氧甲基，4-戊炔氧甲基，(1-甲基-2-丁炔氧基)甲基，(1-甲基-3-丁炔氧基)甲基，(1,1-二甲基-2-丁炔氧基)甲基，(1,1-二 甲基-3-丁炔氧基)甲基，(1-甲基-3-戊炔氧基)甲基，(1-甲基-4-戊炔氧基)甲基，1-(2-丙炔氧基)乙基，1-(1-甲基-2-丙炔氧基)乙基，1-(1,1-二甲基-2-丙炔氧基)乙基，1-(1-丁炔氧基)乙基，1-(2-丁炔氧基)乙基，1-(3-丁炔氧基)乙基，1-(1-戊炔氧基)乙基，1-(2-戊炔氧基)乙基，1-(3-戊炔氧基)乙基，1-(4-戊炔氧基)乙基，1-(1-甲基-2-丁炔氧基)乙基，1-(1-甲基-3-丁炔氧基)乙基，1-(1,1-二甲基-2-丁炔氧基)乙基，1-(1,1-二甲基-3-丁炔氧基)乙基，1-(1-甲基-3-戊炔氧基)乙基，1-(1-甲基-4-戊炔氧基)乙基，2-(2-丙炔氧基)乙基，2-(1-甲基-2-丙炔氧基)乙基，2-(1,1-二甲基-2-丙炔氧基)乙基，2-(1-丁炔氧基)乙基，2-(2-丁炔氧基)乙基，2-(3-丁炔氧基)乙基，2-(1-戊炔氧基)乙基，2-(2-戊炔氧基)乙基，2-(3-戊炔氧基)乙基，2-(4-戊炔氧基)乙基，2-(1-甲基-2-丁炔氧基)乙基，2-(1-甲基-3-丁炔氧基)乙基，2-(1,1-二甲基-2-丁炔氧基)乙基，2-(1,1-二甲基-3-丁炔氧基)乙基，2-(1-甲基-3-戊炔氧基)乙基，2-(1-甲基-4-戊炔氧基)乙基，3-(2-丙炔氧基)丙基，4-(2-丙炔氧基)丁基等。 "(C 2 -C 6 ) alkynyloxy(C 1 -C 6 )alkyl" is a group which represents a (C 2 -C 6 ) alkynyloxy group bonded to a (C 1 -C 6 ) alkyl group, for example, Ethyl acetyloxymethyl, 2-propynyloxymethyl, (1-methyl-2-propynyloxy)methyl, (1,1-dimethyl-2-propynyloxy)methyl, 1-butynyloxymethyl, 2-butynyloxymethyl, 3-butynyloxymethyl, 1-pentynyloxymethyl, 2-pentynyloxymethyl, 3-pentynyloxymethyl, 4- Pentynyloxymethyl, (1-methyl-2-butynyloxy)methyl, (1-methyl-3-butynyloxy)methyl, (1,1-dimethyl-2-butene Alkynyloxy)methyl, (1,1-dimethyl-3-butynyloxy)methyl, (1-methyl-3-pentynyloxy)methyl, (1-methyl-4- Pentynyloxy)methyl, 1-(2-propynyloxy)ethyl, 1-(1-methyl-2-propynyloxy)ethyl, 1-(1,1-dimethyl- 2-propynyloxy)ethyl, 1-(1-butynyloxy)ethyl, 1-(2-butynyloxy)ethyl, 1-(3-butynyloxy)ethyl, 1 -(1-pentynyloxy)ethyl, 1-(2-pentynyloxy)ethyl, 1-(3-pentynyloxy)ethyl, 1-(4-pentynyloxy)ethyl , 1-(1-methyl-2-butynyloxy)ethyl, 1-(1-methyl-3-butynyloxy)ethyl, 1-(1,1-dimethyl-2- Butynyloxy)ethyl, 1-(1 ,1-dimethyl-3-butynyloxy)ethyl, 1-(1-methyl-3-pentynyloxy)ethyl, 1-(1-methyl-4-pentynyloxy) Ethyl, 2-(2-propynyloxy)ethyl, 2-(1-methyl-2-propynyloxy)ethyl, 2-(1,1-dimethyl-2-propynyloxy) Ethyl, 2-(1-butynyloxy)ethyl, 2-(2-butynyloxy)ethyl, 2-(3-butynyloxy)ethyl, 2-(1-pentyl Alkynyloxy)ethyl, 2-(2-pentynyloxy)ethyl, 2-(3-pentynyloxy)ethyl, 2-(4-pentynyloxy)ethyl, 2-(1 -methyl-2-butynyloxy)ethyl, 2-(1-methyl-3-butynyloxy)ethyl, 2-(1,1-dimethyl-2-butynyloxy) Ethyl, 2-(1,1-dimethyl-3-butynyloxy)ethyl, 2-(1-methyl-3-pentynyloxy)ethyl, 2-(1-methyl- 4-pentynyloxy)ethyl, 3-(2-propynyloxy)propyl, 4-(2-propynyloxy)butyl and the like.

「(C3-C6)環烷氧(C1-C6)烷基」就是，表示(C3-C6)環烷氧基與(C1-C6)烷基鍵合的基，例如，可舉環丙氧甲基，環丁氧甲基，環戊氧甲基，環己氧甲基，1-環丙氧乙基，1-環丁氧乙基，1-環戊氧乙基，1-環己氧乙基，2-環丙氧乙基，2-環丁氧乙基，2-環戊氧乙基，2-環己氧乙基，3-環丙氧丙基，4-環丙氧丁基，3-環己氧丙基，4-環己氧丁基等。 "(C 3 -C 6 )cycloalkoxy (C 1 -C 6 )alkyl" means a group which is bonded to a (C 1 -C 6 ) alkyl group (C 3 -C 6 ), For example, cyclopropoxymethyl, cyclobutoxymethyl, cyclopentyloxymethyl, cyclohexyloxymethyl, 1-cyclopropoxyethyl, 1-cyclobutoxyethyl, 1-cyclopentyloxy Base, 1-cyclohexyloxyethyl, 2-cyclopropoxyethyl, 2-cyclobutoxyethyl, 2-cyclopentyloxyethyl, 2-cyclohexyloxyethyl, 3-cyclopropoxypropyl, 4-cyclopropoxybutyl, 3-cyclohexyloxypropyl, 4-cyclohexyloxybutyl and the like.

「二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同。)」就是，表示可以相同或不相同的二個(C1-C6)烷氧基與(C1-C6)烷基鍵合的基，例如，可舉二甲氧甲基，二乙氧 甲基，二正丙氧甲基，二異丙氧甲基，二正丁氧甲基，二異丁氧甲基，二二級丁氧甲基，二三級丁氧甲基，1,1-二甲氧乙基，1,1-二乙氧乙基，1,1-二正丙氧乙基，1,1-二異丙氧乙基，1,1-二正丁氧乙基，1,1-二異丁氧乙基，1,1-二二級丁氧乙基，1,1-二三級丁氧乙基，2,2-二甲氧乙基，2,2-二乙氧乙基，2,2-二正丙氧乙基，2,2-二異丙氧乙基，2,2-二正丁氧乙基，2,2-二異丁氧乙基，2,2-二二級丁氧乙基，2,2-二三級丁氧乙基，1,2-二甲氧乙基，1,2-二乙氧乙基，1,2-二正丙氧乙基，1,2-二異丙氧乙基，1,2-二正丁氧乙基，1,2-二三級丁氧乙基，1-乙氧基-2-甲氧乙基，2-乙氧基-1-甲氧乙基，1,1-二甲氧丙基，1,1-二乙氧丙基，1,1-二正丙氧丙基，1,1-二異丙氧丙基，1,1-二正丁氧丙基，1,1-二三級丁氧丙基，2,2-二甲氧丙基，2,2-二乙氧丙基，2,2-二正丙氧丙基，2,2-二異丙氧丙基，2,2-二正丁氧丙基，2,2-二三級丁氧丙基，3,3-二甲氧丙基，3,3-二乙氧丙基，3,3-二正丙氧丙基，3,3-二異丙氧丙基，3,3-二正丁氧丙基，3,3-二三級丁氧丙基，1,2-二甲氧丙基，1,2-二乙氧丙基，1,2-二正丙氧丙基，1,3-二甲氧丙基，1,3-二乙氧丙基，1,3-二正丙氧丙基，2,3-二甲氧丙基，2,3-二乙氧丙基，2,3-二正丙氧丙基，1-乙氧基-2-甲氧丙基，2-乙氧基-1-甲氧丙基，2-乙氧基-3-甲氧丙基，3-乙氧基-2-甲氧丙基，1-乙氧基-3-甲氧丙基，3-乙氧基-1-甲氧丙基，1,2-二甲氧基-1-甲基乙基，1,1-二甲氧丁基，1,1-二乙氧丁基，1,1-二正丙氧丁基，1,1-二異丙氧丁基，1,1-二正丁氧丁基，1,1-二三級丁氧丁基，2,2-二甲氧丁基，2,2-二乙氧丁基，2,2-二正丙氧丁基，2,2-二異丙氧丁基，2,2-二正丁氧丁基，2,2-二三級丁氧丁基，3,3-二甲氧丁基，3,3-二乙氧丁基，3,3-二正丙氧丁 基，3,3-二異丙氧丁基，3,3-二正丁氧丁基，3,3-二三級丁氧丁基，4,4-二甲氧丁基，4,4-二乙氧丁基，4,4-二正丙氧丁基，4,4-二異丙氧丁基，4,4-二正丁氧丁基，4,4-二三級丁氧丁基，1,2-二甲氧丁基，1,2-二乙氧丁基，1,2-二正丙氧丁基，1,3-二甲氧丁基，1,3-二乙氧丁基，1,3-二正丙氧丁基，1,4-二甲氧丁基，1,4-二乙氧丁基，1,4-二正丙氧丁基，2,3-二甲氧丁基，2,3-二乙氧丁基，2,3-二正丙氧丁基，2,4-二甲氧丁基，2,4-二乙氧丁基，2,4-二正丙氧丁基，3,4-二甲氧丁基，3,4-二乙氧丁基，3,4-二正丙氧丁基，1-乙氧基-2-甲氧丁基，1-乙氧基-3-甲氧丁基，1-乙氧基-4-甲氧丁基，2-乙氧基-1-甲氧丁基，2-乙氧基-3-甲氧丁基，4-乙氧基-3-甲氧丁基，3-乙氧基-2-甲氧丁基，3-乙氧基-4-甲氧丁基，1-乙氧基-2-甲氧基-1-甲基丙基，1-乙氧基-2-甲氧基-2-甲基丙基，1-乙氧基-2-甲氧基-3-甲基丙基等。在這裏，二(C1-C6)烷氧基的烷氧基與烷基的同一個碳原子鍵合也可以，與不同的碳原子鍵合也可以。 "Alkyloxy groups of di(C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl (di(C 1 -C 6 ) alkoxy may be the same or different.)" means that they may be the same or A group in which two (C 1 -C 6 ) alkoxy groups which are different from each other are bonded to a (C 1 -C 6 ) alkyl group, for example, dimethoxymethyl, diethoxymethyl, di-n-propoxy Methyl, diisopropoxymethyl, di-n-butoxymethyl, diisobutoxymethyl, di-2-butoxymethyl, di-tert-butoxymethyl, 1,1-dimethoxyethyl, 1,1-diethoxyethyl, 1,1-di-n-propoxyethyl, 1,1-diisopropoxyethyl, 1,1-di-n-butoxyethyl, 1,1-diisobutyl Oxyethyl, 1,1-di-2-butoxyethyl, 1,1-di-tert-butoxyethyl, 2,2-dimethoxyethyl, 2,2-diethoxyethyl, 2, 2-Di-n-propoxyethyl, 2,2-diisopropoxyethyl, 2,2-di-n-butoxyethyl, 2,2-diisobutoxyethyl, 2,2-di-di-butyl Oxyethyl, 2,2-di-tert-butoxyethyl, 1,2-dimethoxyethyl, 1,2-diethoxyethyl, 1,2-di-n-propoxyethyl, 1,2 -diisopropoxyethyl, 1,2-di-n-butoxyethyl, 1,2-di-tert-butoxyethyl, 1-ethoxy-2-methoxyethyl, 2-ethoxy- 1-methoxyethyl, 1, 1-Dimethoxypropyl, 1,1-diethoxypropyl, 1,1-di-n-propoxypropyl, 1,1-diisopropyloxypropyl, 1,1-di-n-butoxypropyl , 1,1-di-tert-butoxypropyl, 2,2-dimethoxypropyl, 2,2-diethoxypropyl, 2,2-di-n-propoxypropyl, 2,2-diiso Propoxypropyl, 2,2-di-n-butoxypropyl, 2,2-di-tert-butoxypropyl, 3,3-dimethoxypropyl, 3,3-diethoxypropyl, 3, 3-Di-n-propoxypropyl, 3,3-diisopropyloxypropyl, 3,3-di-n-butoxypropyl, 3,3-di-tert-butoxypropyl, 1,2-dimethoxy Propyl, 1,2-diethoxypropyl, 1,2-di-n-propoxypropyl, 1,3-dimethoxypropyl, 1,3-diethoxypropyl, 1,3-di-n-butyl Propoxypropyl, 2,3-dimethoxypropyl, 2,3-diethoxypropyl, 2,3-di-n-propoxypropyl, 1-ethoxy-2-methoxypropyl, 2 -ethoxy-1-methoxypropyl, 2-ethoxy-3-methoxypropyl, 3-ethoxy-2-methoxypropyl, 1-ethoxy-3-methoxypropyl , 3-ethoxy-1-methoxypropyl, 1,2-dimethoxy-1-methylethyl, 1,1-dimethoxybutyl, 1,1-diethoxybutyl, 1,1-di-n-propoxybutyl, 1,1-diisopropoxybutyl, 1,1-di-n-butoxybutyl, 1,1-di-tert-butoxybutyl 2,2-Dimethoxybutyl, 2,2-diethoxybutyl, 2,2-di-n-propoxybutyl, 2,2-diisopropoxybutyl, 2,2-di-n-butoxy Butyl, 2,2-di-tert-butoxybutyl, 3,3-dimethoxybutyl, 3,3-diethoxybutyl, 3,3-di-n-propoxybutyl, 3,3- Diisopropoxybutyl, 3,3-di-n-butoxybutyl, 3,3-di-tert-butoxybutyl, 4,4-dimethoxybutyl, 4,4-diethoxybutyl, 4,4-di-n-propoxybutyl, 4,4-diisopropoxybutyl, 4,4-di-n-butoxybutyl, 4,4-di-tert-butoxybutyl, 1,2-di Methoxybutyl, 1,2-diethoxybutyl, 1,2-di-n-propoxybutyl, 1,3-dimethoxybutyl, 1,3-diethoxybutyl, 1,3- Di-n-propoxybutyl, 1,4-dimethoxybutyl, 1,4-diethoxybutyl, 1,4-di-n-propoxybutyl, 2,3-dimethoxybutyl, 2, 3-diethoxybutyl, 2,3-di-n-propoxybutyl, 2,4-dimethoxybutyl, 2,4-diethoxybutyl, 2,4-di-n-propoxybutyl, 3,4-Dimethoxybutyl, 3,4-diethoxybutyl, 3,4-di-n-propoxybutyl, 1-ethoxy-2-methoxybutyl, 1-ethoxy- 3-methoxybutyl, 1-ethoxy-4-methoxybutyl, 2-ethoxy-1-methoxybutyl, 2-ethoxy-3-methoxybutyl 4-ethoxy-3-methoxybutyl, 3-ethoxy-2-methoxybutyl, 3-ethoxy-4-methoxybutyl, 1-ethoxy-2-methoxy 1-methylpropyl, 1-ethoxy-2-methoxy-2-methylpropyl, 1-ethoxy-2-methoxy-3-methylpropyl, and the like. Here, the alkoxy group of the di(C 1 -C 6 ) alkoxy group may be bonded to the same carbon atom of the alkyl group, and may be bonded to a different carbon atom.

「(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基」就是，表示(C1-C6)烷氧(C1-C6)烷氧基與(C1-C6)烷基鍵合的基，例如，可舉2-(甲氧基)乙氧甲基，2-(乙氧基)乙氧甲基，2-(正丙氧基)乙氧甲基，2-(異丙氧基)乙氧甲基，2-(正丁氧基)乙氧甲基，2-(二級丁氧基)乙氧甲基，2-(三級丁氧基)乙氧甲基，2-(正戊氧基)乙氧甲基，2-(異戊氧基)乙氧甲基，2-(新戊氧基)乙氧甲基，2-(正己氧基)乙氧甲基，1-(甲氧甲氧基)乙基，2-(甲氧甲氧基)乙基，3-(甲氧甲氧基)丙基，4-(甲氧甲氧基)丁基，1-(2-甲氧乙氧基)乙基，2-(2-乙氧乙氧基)乙基，1-(2-正丙氧乙氧基)乙基，1-(2-異丙氧乙氧基)乙基，1-(2-正丁氧乙氧基)乙基，1-(2-二級丁氧乙氧基)乙基，1-(2-三級丁氧乙氧基)乙 基，1-(2-正戊氧乙氧基)乙基，1-(2-異戊氧乙氧基)乙基，1-(2-新戊氧乙氧基)乙基，1-(2-正己氧乙氧基)乙基，2-(2-甲氧乙氧基)乙基，2-(2-正丙氧乙氧基)乙基，2-(2-異丙氧乙氧基)乙基，2-(2-正丁氧乙氧基)乙基，2-(2-二級丁氧乙氧基)乙基，2-(2-三級丁氧乙氧基)乙基，2-(2-正戊氧乙氧基)乙基，2-(2-異戊氧乙氧基)乙基，2-(2-新戊氧乙氧基)乙基，2-(2-正己氧乙氧基)乙基，3-(2-甲氧乙氧基)丙基，4-(2-甲氧乙氧基)丁基等。 "(C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl" means, (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy The group bonded to the (C 1 -C 6 ) alkyl group may, for example, be 2-(methoxy)ethoxymethyl, 2-(ethoxy)ethoxymethyl, 2-(n-propoxy) Ethyloxymethyl, 2-(isopropoxy)ethoxymethyl, 2-(n-butoxy)ethoxymethyl, 2-(2-butoxy)ethoxymethyl, 2-( Tertiary butoxy)ethoxymethyl, 2-(n-pentyloxy)ethoxymethyl, 2-(isopentyloxy)ethoxymethyl, 2-(neopentyloxy)ethoxymethyl, 2-(n-hexyloxy)ethoxymethyl, 1-(methoxymethoxy)ethyl, 2-(methoxymethoxy)ethyl, 3-(methoxymethoxy)propyl, 4- (methoxymethoxy)butyl, 1-(2-methoxyethoxy)ethyl, 2-(2-ethoxyethoxy)ethyl, 1-(2-n-propoxyethoxy) Ethyl, 1-(2-isopropoxyethoxy)ethyl, 1-(2-n-butoxyethoxy)ethyl, 1-(2-di-butoxyethoxy)ethyl, 1 -(2-tertiary butoxyethoxy)ethyl, 1-(2-n-pentyloxyethoxy)ethyl, 1-(2-isopentyloxyethoxy)ethyl, 1-(2- Neopentyloxyethyl)ethyl, 1-(2-n-hexyloxyethoxy)ethyl, 2-(2-methoxyethoxy)ethyl ,2-(2-n-propoxyethoxy)ethyl, 2-(2-isopropoxyethoxy)ethyl, 2-(2-n-butoxyethoxy)ethyl, 2-(2 -Secondary butoxyethoxy)ethyl, 2-(2-tertiary butoxyethoxy)ethyl, 2-(2-n-pentyloxyethoxy)ethyl, 2-(2-iso-amyl) Oxyethoxyethyl)ethyl, 2-(2-pivaloxyethoxy)ethyl, 2-(2-n-hexyloxyethoxy)ethyl, 3-(2-methoxyethoxy)propyl , 4-(2-methoxyethoxy)butyl and the like.

「(C1-C6)烷羰氧(C1-C6)烷基」就是，表示直鏈或支鏈狀的碳原子數1至6個的烷-羰氧基與(C1-C6)烷基鍵合的基，例如，可舉乙醯基氧甲基，乙羰氧甲基，正丙羰氧甲基，異丙羰氧甲基，正丁羰氧甲基，三級丁羰氧甲基，1-乙醯基氧乙基，1-乙羰氧乙基，1-正丙羰氧乙基，1-異丙羰氧乙基，1-正丁羰氧乙基，1-三級丁羰氧乙基，2-乙醯基氧乙基，2-乙羰氧乙基，2-正丙羰氧乙基，2-異丙羰氧乙基，2-正丁羰氧乙基，2-三級丁羰氧乙基，3-乙醯基氧丙基，4-乙醯基氧丁基等。 "(C 1 -C 6 ) alkoxycarbonyl(C 1 -C 6 )alkyl" means an alkane-carbonyloxy group having 1 to 6 carbon atoms in a straight or branched chain and (C 1 -C) 6 ) an alkyl-bonded group, for example, an ethyl ethoxymethyl group, an ethoxycarbonylmethyl group, a n-propyl carbonyloxymethyl group, a isopropyloxycarbonylmethyl group, a n-butoxycarbonylmethyl group, a tertiary butyl group Carbonyloxymethyl, 1-ethenyloxyethyl, 1-ethylcarbonyloxyethyl, 1-n-propylcarbonyloxyethyl, 1-isopropylcarbonyloxyethyl, 1-n-butoxycarbonylethyl, 1 - tertiary butoxide oxyethyl, 2-ethenyloxyethyl, 2-ethylcarbonyloxyethyl, 2-n-propylcarbonyloxyethyl, 2-isopropoxycarbonylethyl, 2-n-butoxycarbonyl Ethyl, 2-tertiary butanocarbonyloxyethyl, 3-ethenyloxypropyl, 4-ethenyloxybutyl and the like.

「苯(C1-C6)烷氧(C1-C6)烷基」就是，表示苯基與上述(C1-C6)烷氧(C1-C6)烷基鍵合的基，例如，可舉苯甲氧甲基，1-苯乙氧甲基，2-苯乙氧甲基，3-苯丙氧甲基，4-苯丁氧甲基，5-苯戊氧甲基，6-苯己氧甲基，1-(苯甲氧基)乙基，1-(1-苯乙氧基)乙基，1-(2-苯乙氧基)乙基，1-(3-苯丙氧基)乙基，1-(4-苯丁氧基)乙基，1-(5-苯戊氧基)乙基，1-(6-苯己氧基)乙基，2-(苯甲氧基)乙基，2-(1-苯乙氧基)乙基，2-(2-苯乙氧基)乙基，2-(3-苯丙氧基)乙基，2-(4-苯丁氧基)乙基，2-(5-苯戊氧基)乙基，2-(6-苯己氧基)乙基，3-(苯甲氧基)丙基，4-(苯甲氧基)丁基，3-(1-苯乙氧基)丙基，4-(1-苯乙氧 基)丁基，3-(2-苯乙氧基)丙基，4-(2-苯乙氧基)丁基等。 "Benzene (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl" means a group in which a phenyl group is bonded to the above (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkyl group. For example, benzyloxymethyl, 1-phenylethoxymethyl, 2-phenylethoxymethyl, 3-phenylpropoxymethyl, 4-phenylbutoxymethyl, 5-phenylpentoxymethyl ,6-phenoxymethyl, 1-(benzyloxy)ethyl, 1-(1-phenylethoxy)ethyl, 1-(2-phenylethoxy)ethyl, 1-(3 -phenylpropoxy)ethyl, 1-(4-phenylbutoxy)ethyl, 1-(5-phenylpentyloxy)ethyl, 1-(6-phenylhexyloxy)ethyl, 2- (Benzyloxy)ethyl, 2-(1-phenylethoxy)ethyl, 2-(2-phenylethoxy)ethyl, 2-(3-phenylpropoxy)ethyl, 2- (4-Phenylbutoxy)ethyl, 2-(5-phenylpentyloxy)ethyl, 2-(6-phenylhexyloxy)ethyl, 3-(benzyloxy)propyl, 4- (Benzyloxy)butyl, 3-(1-phenylethoxy)propyl, 4-(1-phenylethoxy)butyl, 3-(2-phenylethoxy)propyl, 4- (2-Phenylethoxy)butyl and the like.

「苯(C1-C6)烷基」就是，表示苯基與上述(C1-C6)烷基鍵合的基，例如，可舉苯甲(苄基)，1-苯乙基，2-苯乙基，3-苯丙基，4-苯丁基等。 "Benzene (C 1 -C 6 )alkyl" means a group in which a phenyl group is bonded to the above (C 1 -C 6 ) alkyl group, and examples thereof include benzyl (benzyl) and 1-phenylethyl groups. 2-phenethyl, 3-phenylpropyl, 4-phenylbutyl and the like.

「(C1-C6)烷硫(C1-C6)烷基」就是，表示(C1-C6)烷硫基與(C1-C6)烷基鍵合的基，例如，可舉甲硫甲基，乙硫甲基，正丙硫甲基，異丙硫甲基，正丁硫甲基，二級丁硫甲基，三級丁硫甲基，正戊硫甲基，異戊硫甲基，正己硫甲基，1-甲硫乙基，1-乙硫乙基，1-正丙硫乙基，1-異丙硫乙基，1-正丁硫乙基，1-二級丁硫乙基，1-三級丁硫乙基，1-正戊硫乙基，1-異戊硫乙基，1-正己硫乙基，2-甲硫乙基，2-甲硫乙基，2-正丙硫乙基，2-異丙硫乙基，2-正丁硫乙基，2-二級丁硫乙基，2-三級丁硫乙基，2-正戊硫乙基，2-異戊硫乙基，2-正己硫乙基，3-甲硫丙基，4-甲硫丁基，3-乙硫丙基，4-乙硫丁基等。 "(C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl" is a group which represents a (C 1 -C 6 )alkylthio group bonded to a (C 1 -C 6 ) alkyl group, for example, Methylthiomethyl, ethylthiomethyl, n-propylthiomethyl, isopropylthiomethyl, n-butylthiomethyl, dibutylthiomethyl, tert-butylthiomethyl, n-pentylthiomethyl, Isovalerylmethyl, n-hexylthiomethyl, 1-methylthioethyl, 1-ethylthioethyl, 1-n-propylthioethyl, 1-isopropylthioethyl, 1-n-butylthioethyl, 1 - secondary butyl sulfide ethyl, 1-tertiary butylthioethyl, 1-n-pentylthioethyl, 1-isopentylthioethyl, 1-n-hexylthioethyl, 2-methylthioethyl, 2-methyl Thioethyl, 2-n-propylthioethyl, 2-isopropylthioethyl, 2-n-butylthioethyl, 2-second butylthioethyl, 2-tris-butylthioethyl, 2-n-pentyl Thioethyl, 2-isopentylthioethyl, 2-n-hexylthioethyl, 3-methylthiopropyl, 4-methylthiobutyl, 3-ethylthiopropyl, 4-ethylthiobutyl, and the like.

「(C1-C6)烷亞磺醯(C1-C6)烷基」就是，表示(C1-C6)烷亞磺醯基與(C1-C6)烷基鍵合的基，例如，可舉甲亞磺醯甲基，乙亞磺醯甲基，正丙亞磺醯甲基，異丙亞磺醯甲基，正丁亞磺醯甲基，二級丁亞磺醯甲基，三級丁亞磺醯甲基，正戊亞磺醯甲基，異戊亞磺醯甲基，正己亞磺醯甲基，1-甲亞磺醯乙基，1-乙亞磺醯乙基，1-正丙亞磺醯乙基，1-異丙亞磺醯乙基，1-正丁亞磺醯乙基，1-二級丁亞磺醯乙基，1-三級丁亞磺醯乙基，1-正戊亞磺醯乙基，1-異戊亞磺醯乙基，1-正己亞磺醯乙基，2-甲亞磺醯乙基，2-乙亞磺醯乙基，2-正丙亞磺醯乙基，2-異丙亞磺醯乙基，2-正丁亞磺醯乙基，2-二級丁亞磺醯乙基，2-三級丁亞磺醯乙基，2-正戊亞 磺醯乙基，2-異戊亞磺醯乙基，2-正己亞磺醯乙基，3-甲亞磺醯丙基，4-甲亞磺醯丁基，3-乙亞磺醯丙基，4-乙亞磺醯丁基等。 "(C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl" means that (C 1 -C 6 )alkylsulfinyl is bonded to (C 1 -C 6 )alkyl Base, for example, may be sulfinylmethyl, sulfinylmethyl, n-propanesulfinylmethyl, isopropylsulfinylmethyl, n-butylsulfinylmethyl, secondary butylsulfin Methyl, tertiary butylsulfinium methyl, n-pentylenesulfonylmethyl, isoamylsulfinium methyl, n-hexylsulfinylmethyl, 1-methylsulfinylethyl, 1-ethenesulfonium Ethyl, 1-n-propanesulfinyl ethyl, 1-isopropylsulfinyl ethyl, 1-n-butyl sulfinium ethyl, 1-second butyl sulfinyl ethyl, 1-tertiary butyl Sulfonyl ethyl, 1-n-pentylenesulfonium ethyl, 1-isopentylenesulfonium ethyl, 1-n-hexylsulfinyl ethyl, 2-methylsulfinyl ethyl, 2-ethylsulfin Base, 2-n-propanesulfinium ethyl, 2-isopropylsulfinyl ethyl, 2-n-butylsulfinyl ethyl, 2-second butylsulfinyl ethyl, 2-trimethyl sulfin Ethyl ethyl, 2-n-pentylenesulfonium ethyl, 2-isopentylenesulfonium ethyl, 2-n-hexylsulfinyl ethyl, 3-methylsulfinylpropyl, 4-methylsulfinyl butyl , 3-ethylsulfinylpropyl, 4-ethylsulfinylbutyl and the like.

「(C1-C6)烷磺醯(C1-C6)烷基」就是，表示(C1-C6)烷磺醯基與(C1-C6)烷基鍵合的基，例如，可舉甲磺醯甲基，乙磺醯甲基，正丙磺醯甲基，異丙磺醯甲基，正丁磺醯甲基，二級丁磺醯甲基，三級丁磺醯甲基，正戊磺醯甲基，異戊磺醯甲基，正己磺醯甲基，1-甲磺醯乙基，1-乙磺醯乙基，1-正丙磺醯乙基，1-異丙磺醯乙基，1-正丁磺醯乙基，1-二級丁磺醯乙基，1-三級丁磺醯乙基，1-正戊磺醯乙基，1-異戊磺醯乙基，1-正己磺醯乙基，2-甲磺醯乙基，2-乙磺醯乙基，2-正丙磺醯乙基，2-異丙磺醯乙基，2-正丁磺醯乙基，2-二級丁磺醯乙基，2-三級丁磺醯乙基，2-正戊磺醯乙基，2-異戊磺醯乙基，2-正己磺醯乙基，3-甲磺醯丙基，4-甲磺醯丁基，3-乙磺醯丙基，4-乙磺醯丁基等。 "(C 1 -C 6 ) alkanesulfonyl (C 1 -C 6 )alkyl" means a group which is bonded to a (C 1 -C 6 ) alkyl group (C 1 -C 6 ) alkanesulfonyl group, For example, it may be methylsulfonium methyl, ethylsulfonylmethyl, n-propylsulfonylmethyl, isopropylsulfonylmethyl, n-butylsulfonylmethyl, secondary butanesulfonylmethyl, tertiary butanesulfonate Methyl, n-pentanesulfonylmethyl, isopentylsulfonylmethyl, n-hexylsulfonylmethyl, 1-methylsulfonylethyl, 1-ethylsulfonylethyl, 1-n-propanesulfonylethyl, 1- Isopropyl sulfonium ethyl, 1-n-butylsulfonyl ethyl, 1-second butasulfonyl ethyl, 1-tertiary butasulfonyl ethyl, 1-n-pentanesulfonyl ethyl, 1-iso-pentane Ethyl ethyl, 1-n-hexylsulfonyl ethyl, 2-methylsulfonium ethyl, 2-ethanesulfonylethyl, 2-n-propanesulfonylethyl, 2-isopropylsulfonylethyl, 2-n-butyl Sulfonyl ethyl, 2-second butanesulfonyl ethyl, 2-tert-butyl sulfonium ethyl, 2-n-pentanesulfonyl ethyl, 2-isopentylsulfonium ethyl, 2-n-hexylsulfonyl ethyl , 3-methanesulfonylpropyl, 4-methylsulfonylbutyl, 3-ethylsulfonylpropyl, 4-ethylsulfonylbutyl and the like.

「(C1-C6)烷氧(C1-C6)烷羰基」就是，表示上述(C1-C6)烷氧基與(C1-C6)烷羰基鍵合的基，例如，可舉甲氧乙醯基，乙氧乙醯基，正丙氧乙醯基，異丙氧乙醯基，正丁氧乙醯基，二級丁氧乙醯基，三級丁氧乙醯基，正戊氧乙醯基，異戊氧乙醯基，新戊氧乙醯基，正己氧乙醯基，1-(甲氧基)乙羰基，2-(甲氧基)乙羰基，3-(甲氧基)丙羰基，4-(甲氧基)丁羰基，1-(乙氧基)乙羰基，2-(乙氧基)乙羰基，3-(乙氧基)丙羰基，4-(乙氧基)丁羰基等。 "(C 1 -C 6) alkoxy (C 1 -C 6) alkylcarbonyl" is, represents (C 1 -C 6) alkoxy and (C 1 -C 6) alkylcarbonyl groups bonded to the above, e.g. , may be methoxyethyl, ethoxyethyl, n-propoxyethyl, isopropoxyethyl, n-butoxyethyl, 2-butoxyethoxy, tertiary butyrate Base, n-pentyloxycarbonyl, isopentyloxyethyl, neopentyloxy, n-hexyloxy, 1-(methoxy)ethylcarbonyl, 2-(methoxy)ethylcarbonyl, 3 -(methoxy)propenylcarbonyl, 4-(methoxy)butancarbonyl, 1-(ethoxy)ethylcarbonyl, 2-(ethoxy)ethylcarbonyl, 3-(ethoxy)propenylcarbonyl, 4 -(ethoxy)butylcarbonyl and the like.

「(C1-C6)烷氧羰(C1-C6)烷基」就是，表示(C1-C6)烷氧羰基與(C1-C6)烷基鍵合的基，例如，可舉甲氧羰甲基，乙氧羰甲基，正丙氧羰甲基，異丙氧羰甲基，正丁氧羰甲基，三級丁氧羰甲基，1-甲氧羰乙基，1-乙氧羰乙基，1-正丙氧羰乙基，1-異丙氧 羰乙基，1-正丁氧羰乙基，1-三級丁氧羰乙基，2-甲氧羰乙基，2-乙氧羰乙基，2-正丙氧羰乙基，2-異丙氧羰乙基，2-正丁氧羰乙基，2-三級丁氧羰乙基，3-甲氧羰丙基，4-甲氧羰丁基，3-乙氧羰丙基，4-乙氧羰丁基等。 "(C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl" means a group which represents (C 1 -C 6 ) alkoxycarbonyl group bonded to a (C 1 -C 6 ) alkyl group, for example , which may be methoxycarbonylmethyl, ethoxycarbonylmethyl, n-propoxycarbonylmethyl, isopropoxycarbonylmethyl, n-butoxycarbonylmethyl, tert-butoxycarbonylmethyl, 1-methoxycarbonyl Base, 1-ethoxycarbonylethyl, 1-n-propoxycarbonylethyl, 1-isopropyloxycarbonylethyl, 1-n-butoxycarbonylethyl, 1-tertiary butoxycarbonylethyl, 2-methyl Oxycarbonylethyl, 2-ethoxycarbonylethyl, 2-n-propoxycarbonylethyl, 2-isopropoxycarbonylethyl, 2-n-butoxycarbonylethyl, 2-tert-butoxycarbonylethyl, 3-methoxycarbonylpropyl, 4-methoxycarbonylbutyl, 3-ethoxycarbonylpropyl, 4-ethoxycarbonylbutyl and the like.

「胺(C1-C6)烷基」就是，表示胺基與(C1-C6)烷基鍵合的基，例如，可舉胺基甲基，1-胺基乙基，2-胺基乙基，3-胺基丙基，4-胺基丁基等。 The "amine (C 1 -C 6 )alkyl group" means a group in which an amine group is bonded to a (C 1 -C 6 ) alkyl group, and, for example, an aminomethyl group, a 1-aminoethyl group, or a 2- Aminoethyl, 3-aminopropyl, 4-aminobutyl and the like.

「單(C1-C6)烷胺(C1-C6)烷基」就是，表示單(C1-C6)烷胺基與(C1-C6)烷基鍵合的基，例如，可舉N-甲胺基甲基，N-乙胺基甲基，N-正丙胺基甲基，N-異丙胺基甲基，N-正丁胺基甲基，N-異丁胺基甲基，N-二級丁胺基甲基，N-三級丁胺基甲基，N-正戊胺基甲基，N-新戊胺基甲基，N-正己胺基甲基，1-(N-甲胺基)乙基，1-(N-乙胺基)乙基，1-(N-正丙胺基)乙基，1-(N-異丙胺基)乙基，1-(N-正丁胺基)乙基，1-(N-異丁胺基)乙基，1-(N-二級丁胺基)乙基，1-(N-三級丁胺基)乙基，1-(N-正戊胺基)乙基，1-(N-新戊胺基)乙基，1-(N-正己胺基)乙基，2-(N-甲胺基)乙基，2-(N-乙胺基)乙基，2-(N-正丙胺基)乙基，2-(N-異丙胺基)乙基，2-(N-正丁胺基)乙基，2-(N-異丁胺基)乙基，2-(N-二級丁胺基)乙基，2-(N-三級丁胺基)乙基，2-(N-正戊胺基)乙基，2-(N-新戊胺基)乙基，2-(N-正己胺基)乙基，3-(N-甲胺基)丙基，4-(N-甲胺基)丁基，3-(N-乙胺基)丙基，4-(N-乙胺基)丁基等。 "mono(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl" means a group in which a mono(C 1 -C 6 )alkylamine group is bonded to a (C 1 -C 6 )alkyl group, For example, N-methylaminomethyl, N-ethylaminomethyl, N-n-propylaminomethyl, N-isopropylaminomethyl, N-n-butylaminomethyl, N-isobutylamine Methyl, N-second butylaminomethyl, N-tertiary butylaminomethyl, N-n-pentylaminomethyl, N-neopentylaminomethyl, N-n-hexylaminomethyl, 1-(N-methylamino)ethyl, 1-(N-ethylamino)ethyl, 1-(N-n-propylamino)ethyl, 1-(N-isopropylamino)ethyl, 1- (N-n-butylamino)ethyl, 1-(N-isobutylamino)ethyl, 1-(N-di-butylamino)ethyl, 1-(N-tertiary butylamino)ethyl Base, 1-(N-n-pentylamino)ethyl, 1-(N-neopentyl)ethyl, 1-(N-n-hexylamino)ethyl, 2-(N-methylamino)ethyl ,2-(N-ethylamino)ethyl, 2-(N-n-propylamino)ethyl, 2-(N-isopropylamino)ethyl, 2-(N-n-butylamino)ethyl ,2-(N-isobutylamino)ethyl, 2-(N-di-butylamino)ethyl, 2-(N-tertiary butylamino)ethyl, 2-(N-n-pentylamine Ethyl, 2-(N-neopentyl)ethyl, 2-(N-n-hexylamino)ethyl, 3-(N-methylamino)propyl 4- (N- methylamino) butyl, 3- (N- ethylamino) propyl, 4- (N- ethylamino) butyl and the like.

「二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)」就是，表示二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同。)與(C1-C6)烷基鍵合的基，例如，可舉 N,N-二甲胺基甲基，N,N-二乙胺基甲基，N,N-二正丙胺基甲基，N,N-二異丙胺基甲基，N,N-二正丁胺基甲基，N,N-二異丁胺基甲基，N,N-二二級丁胺基甲基，N,N-二三級丁胺基甲基，N,N-二正戊胺基甲基，N,N-二新戊胺基甲基，N,N-二正己胺基甲基，N-甲基-N-乙胺基甲基，N-甲基-N-正丙胺基甲基，N-甲基-N-異丙胺基甲基，N-甲基-N-正丁胺基甲基，N-甲基-N-異丁胺基甲基，N-甲基-N-二級丁胺基甲基，N-甲基-N-三級丁胺基甲基，N-甲基-N-正戊胺基甲基，N-甲基-N-新戊胺基甲基，N-甲基-N-正己胺基甲基，1-(N,N-二甲胺基)乙基，1-(N,N-二乙胺基)乙基，1-(N,N-二正丙胺基)乙基，1-(N,N-二異丙胺基)乙基，1-(N,N-二正丁胺基)乙基，1-(N,N-二異丁胺基)乙基，1-(N,N-二二級丁胺基)乙基，1-(N,N-二三級丁胺基)乙基，1-(N,N-二正戊胺基)乙基，1-(N,N-二新戊胺基)乙基，1-(N,N-二正己胺基)乙基，1-(N-甲基-N-乙胺基)乙基，1-(N-甲基-N-正丙胺基)乙基，1-(N-甲基-N-異丙胺基)乙基，1-(N-甲基-N-正丁胺基)乙基，1-(N-甲基-N-異丁胺基)乙基，1-(N-甲基-N-二級丁胺基)乙基，1-(N-甲基-N-三級丁胺基)乙基，1-(N-甲基-N-正戊胺基)乙基，1-(N-甲基-N-新戊胺基)乙基，1-(N-甲基-N-正己胺基)乙基，2-(N,N-二甲胺基)乙基，2-(N,N-二乙胺基)乙基，2-(N,N-二正丙胺基)乙基，2-(N,N-二異丙胺基)乙基，2-(N,N-二正丁胺基)乙基，2-(N,N-二異丁胺基)乙基，2-(N,N-二二級丁胺基)乙基，2-(N,N-二三級丁胺基)乙基，2-(N,N-二正戊胺基)乙基，2-(N,N-二新戊胺基)乙基，2-(N,N-二正己胺基)乙基，2-(N-甲基-N-乙胺基)乙基，2-(N-甲基-N-正丙胺基)乙基，2-(N-甲基-N-異丙胺基)乙基，2-(N-甲基-N-正丁胺基)乙基，2-(N-甲基-N-異丁胺基)乙基，2-(N-甲基-N- 二級丁胺基)乙基，2-(N-甲基-N-三級丁胺基)乙基，2-(N-甲基-N-正戊胺基)乙基，2-(N-甲基-N-新戊胺基)乙基，2-(N-甲基-N-正己胺基)乙基，3-(N,N-二甲胺基)丙基，4-(N,N-二甲胺基)丁基，3-(N,N-二乙胺基)丙基，4-(N,N-二乙胺基)丁基等。 "Di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl (alkyl of di(C 1 -C 6 )alkylamino group may be the same or different.)", that is, two (C 1 -C 6 ) an alkylamino group (the alkyl group of the di(C 1 -C 6 )alkylamino group may be the same or different.) A group bonded to the (C 1 -C 6 ) alkyl group, for example, N, N-dimethylaminomethyl, N,N-diethylaminomethyl, N,N-di-n-propylaminomethyl, N,N-diisopropylaminomethyl, N,N-di-n-butylamine Methyl, N,N-diisobutylaminomethyl, N,N-di-second-butylaminomethyl, N,N-di-tert-butylaminomethyl, N,N-di-n-pentylamine Methyl, N,N-di-p-amylaminomethyl, N,N-di-n-hexylaminomethyl, N-methyl-N-ethylaminomethyl, N-methyl-N-n-propylamino Methyl, N-methyl-N-isopropylaminomethyl, N-methyl-N-n-butylaminomethyl, N-methyl-N-isobutylaminomethyl, N-methyl-N -Secondary butylaminomethyl, N-methyl-N-tertiary butylaminomethyl, N-methyl-N-n-pentylaminomethyl, N-methyl-N-neopentylamino , N-methyl-N-n-hexylaminomethyl, 1-(N,N-dimethylamino)ethyl, 1-(N,N-diethylamino)ethyl, 1-(N, N-di-n-propylamino)ethyl, 1-(N,N-diisopropylamino)B Base, 1-(N,N-di-n-butylamino)ethyl, 1-(N,N-diisobutylamino)ethyl, 1-(N,N-di-di-butylamino)ethyl , 1-(N,N-di-tertiary butylamino)ethyl, 1-(N,N-di-n-pentylamino)ethyl, 1-(N,N-di-p-amylamino)ethyl, 1-(N,N-Di-n-hexylamino)ethyl, 1-(N-methyl-N-ethylamino)ethyl, 1-(N-methyl-N-n-propylamino)ethyl, 1 -(N-methyl-N-isopropylamino)ethyl, 1-(N-methyl-N-n-butylamino)ethyl, 1-(N-methyl-N-isobutylamino)ethyl Base, 1-(N-methyl-N-di-butylamino)ethyl, 1-(N-methyl-N-tertiary butylamino)ethyl, 1-(N-methyl-N- n-Pentylamino)ethyl, 1-(N-methyl-N-neopentyl)ethyl, 1-(N-methyl-N-n-hexylamino)ethyl, 2-(N,N- Dimethylamino)ethyl, 2-(N,N-diethylamino)ethyl, 2-(N,N-di-n-propylamino)ethyl, 2-(N,N-diisopropylamino) Ethyl, 2-(N,N-di-n-butylamino)ethyl, 2-(N,N-diisobutylamino)ethyl, 2-(N,N-di-di-butylamino)B Base, 2-(N,N-di-tertiary butylamino)ethyl, 2-(N,N-di-n-pentylamino)ethyl, 2-(N,N-di-p-amylamino)ethyl , 2-(N,N-di-n-hexylamino)ethyl, 2-(N-methyl-N-ethylamino)ethyl, 2-(N-methyl-N- Acryl)ethyl, 2-(N-methyl-N-isopropylamino)ethyl, 2-(N-methyl-N-n-butylamino)ethyl, 2-(N-methyl-N -isobutylamino)ethyl, 2-(N-methyl-N-di-butylamino)ethyl, 2-(N-methyl-N-tertiary butylamino)ethyl, 2-( N-methyl-N-n-pentylamino)ethyl, 2-(N-methyl-N-neopentyl)ethyl, 2-(N-methyl-N-n-hexylamino)ethyl, 3-(N,N-dimethylamino)propyl, 4-(N,N-dimethylamino)butyl, 3-(N,N-diethylamino)propyl, 4-(N, N-diethylamino)butyl and the like.

「(C1-C6)烷羰胺(C1-C6)烷基」就是，表示直鏈或支鏈狀的碳原子數1至6個的烷-羰胺基與(C1-C6)烷基鍵合的基，例如，可舉乙醯胺基甲基，乙羰胺基甲基，正丙羰胺基甲基，異丙羰胺基甲基，正丁羰胺基甲基，三級丁羰胺基甲基，1-乙醯胺基乙基，1-乙羰胺基乙基，1-正丙羰胺基乙基，1-異丙羰胺基乙基，1-正丁羰胺基乙基，1-三級丁羰胺基乙基，2-乙醯胺基乙基，2-乙羰胺基乙基，2-正丙羰胺基乙基，2-異丙羰胺基乙基，2-正丁羰胺基乙基，2-三級丁羰胺基乙基，3-乙醯胺基丙基，4-乙醯胺基丁基，3-三級丁羰胺基丙基，4-三級丁羰胺基丁基等。 "(C 1 -C 6 )alkylcarbonylamine (C 1 -C 6 )alkyl" means a straight-chain or branched alkyl-carbonylamino group having 1 to 6 carbon atoms and (C 1 -C) 6 ) an alkyl-bonded group, for example, an acetaminomethyl group, an ethyl carbonylaminomethyl group, a n-propylcarbonylaminomethyl group, an isopropylcarbonylaminomethyl group, a n-butylcarbonylaminomethyl group , tertiary butylaminomethyl, 1-ethylaminoethyl, 1-ethylcarbonylaminoethyl, 1-n-propylcarbonylaminoethyl, 1-isopropylcarbonylaminoethyl, 1- n-Butylaminoethyl, 1-tert-butylbutylaminoethyl, 2-ethylaminoethyl, 2-ethylcarbonylaminoethyl, 2-n-propylcarbonylaminoethyl, 2-iso Propylaminoethyl, 2-n-butylcarbonylaminoethyl, 2-tert-butylbutylaminoethyl, 3-ethylaminopropyl, 4-ethylaminobutyl, 3-tertal Butylated aminopropyl, 4-tert-butylbutylaminobutyl and the like.

「(C1-C6)烷氧羰胺(C1-C6)烷基」就是，表示直鏈或支鏈狀的碳原子數1至6個的烷氧-羰胺基與(C1-C6)烷基鍵合的基，例如，可舉甲氧羰胺基甲基，乙氧羰胺基甲基，正丙氧羰胺基甲基，異丙氧羰胺基甲基，正丁氧羰胺基甲基，三級丁氧羰胺基甲基，1-甲氧羰胺基乙基，1-乙氧羰胺基乙基，1-正丙氧羰胺基乙基，1-異丙氧羰胺基乙基，1-正丁氧羰胺基乙基，1-三級丁氧羰胺基乙基，2-甲氧羰胺基乙基，2-乙氧羰胺基乙基，2-正丙氧羰胺基乙基，2-異丙氧羰胺基乙基，2-正丁氧羰胺基乙基，2-三級丁氧羰胺基乙基，3-甲氧羰胺基丙基，4-甲氧羰胺基丁基，3-乙氧羰胺基丙基，4-乙氧羰胺基丁基，3-三級丁氧羰胺基丙基，4-三級丁氧羰胺基丁基等。 "(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl" means a straight or branched alkoxy-carbonylamino group having 1 to 6 carbon atoms and (C 1 a -C 6 )alkyl-bonded group, for example, methoxycarbonylaminomethyl, ethoxycarbonylaminomethyl, n-propoxycarbonylaminomethyl, isopropoxycarbonylaminomethyl, Butoxycarbonylaminomethyl, tertiary butoxycarbonylaminomethyl, 1-methoxycarbonylaminoethyl, 1-ethoxycarbonylaminoethyl, 1-n-propoxycarbonylaminoethyl, 1 -Isopropoxycarbonylaminoethyl, 1-n-butoxycarbonylaminoethyl, 1-tertiary butoxycarbonylaminoethyl, 2-methoxycarbonylaminoethyl, 2-ethoxycarbonylamino Ethyl, 2-n-propoxycarbonylaminoethyl, 2-isopropoxycarbonylaminoethyl, 2-n-butoxycarbonylaminoethyl, 2-tertiary butoxycarbonylaminoethyl, 3- Methoxycarbonylaminopropyl, 4-methoxycarbonylaminobutyl, 3-ethoxycarbonylaminopropyl, 4-ethoxycarbonylaminobutyl, 3-tert-butoxycarbonylaminopropyl, 4-tertiary butoxycarbonylaminobutyl and the like.

「(C1-C6)烷磺醯胺(C1-C6)烷基」就是，表示直鏈或支鏈狀的碳原子數1至6個的烷-磺醯胺基與(C1-C6)烷基鍵合的基，例如，可舉甲磺醯胺基甲基，乙磺醯胺基甲基，正丙磺醯胺基甲基，異丙磺醯胺基甲基，正丁磺醯胺基甲基，二級丁磺醯胺基甲基，三級丁磺醯胺基甲基，正戊磺醯胺基甲基，異戊磺醯胺基甲基，正己磺醯胺基甲基，1-甲磺醯胺基乙基，1-乙磺醯胺基乙基，1-正丙磺醯胺基乙基，1-異丙磺醯胺基乙基，1-正丁磺醯胺基乙基，1-二級丁磺醯胺基乙基，1-三級丁磺醯胺基乙基，1-正戊磺醯胺基乙基，1-異戊磺醯胺基乙基，1-正己磺醯胺基乙基，2-甲磺醯胺基乙基，2-乙磺醯胺基乙基，2-正丙磺醯胺基乙基，2-異丙磺醯胺基乙基，2-正丁磺醯胺基乙基，2-二級丁磺醯胺基乙基，2-三級丁磺醯胺基乙基，2-正戊磺醯胺基乙基，2-異戊磺醯胺基乙基，2-正己磺醯胺基乙基，3-甲磺醯胺基丙基，4-甲磺醯胺基丁基，3-乙磺醯胺基丙基，4-乙磺醯胺基丁基等。 "(C 1 -C 6 ) alkanesulfonamide (C 1 -C 6 )alkyl" means a straight-chain or branched alkyl-sulfonylamino group having 1 to 6 carbon atoms and (C 1 -C 6 )alkyl-bonded group, for example, methylsulfonylaminomethyl, ethylsulfonylaminomethyl, n-propylsulfonylaminomethyl, isopropylsulfonylaminomethyl, Butasulfonylaminomethyl, 2,5-butylsulfonylaminomethyl, tert-butylsulfonylaminomethyl, n-pentylsulfonylaminomethyl, isovalerylaminomethyl, n-hexylsulfonamide Methyl, 1-methanesulfonylaminoethyl, 1-ethylsulfonylaminoethyl, 1-n-propylsulfonylaminoethyl, 1-isopropylsulfonylaminoethyl, 1-n-butyl Sulfonylethyl, 1-second-butyl sulfonylamino, 1-tert-butylsulfonylamino, 1-n-pentylsulfonylamino, 1-isoamylsulfonylamino Ethyl, 1-n-hexylsulfonylaminoethyl, 2-methylsulfonylaminoethyl, 2-ethylsulfonylaminoethyl, 2-n-propylsulfonylaminoethyl, 2-isopropylsulfonium Aminoethyl, 2-n-butylsulfonylaminoethyl, 2-second-butylsulfonylaminoethyl, 2-tris-butylsulfonylaminoethyl, 2-n-pentanesulfonylaminoethyl , 2-isoamylsulfonylaminoethyl, 2-positive Sulfonylethyl, 3-methanesulfonylaminopropyl, 4-methanesulfonylaminobutyl, 3-ethanesulfonylaminopropyl, 4-ethylsulfonylaminobutyl, and the like.

「單(C1-C6)烷胺羰氧(C1-C6)烷基」就是，表示單(C1-C6)烷胺羰氧基與(C1-C6)烷基鍵合的基，例如，可舉N-甲胺羰氧甲基，N-乙胺羰氧甲基，N-正丙胺羰氧甲基，N-異丙胺羰氧甲基，N-正丁胺羰氧甲基，N-異丁胺羰氧甲基，N-二級丁胺羰氧甲基，N-三級丁胺羰氧甲基，N-正戊胺羰氧甲基，N-新戊胺羰氧甲基，N-正己胺羰氧甲基，1-(N-甲胺羰氧基)乙基，1-(N-乙胺羰氧基)乙基，1-(N-正丙胺羰氧基)乙基，1-(N-異丙胺羰氧基)乙基，1-(N-正丁胺羰氧基)乙基，1-(N-異丁胺羰氧基)乙基，1-(N-二級丁胺羰氧基)乙基，1-(N-三級丁胺羰氧基)乙基，1-(N-正戊胺羰氧基)乙基，1-(N-新戊胺羰氧基)乙基，1-(N-正己胺羰氧基)乙基，2-(N-甲胺羰氧基) 乙基，2-(N-乙胺羰氧基)乙基，2-(N-正丙胺羰氧基)乙基，2-(N-異丙胺羰氧基)乙基，2-(N-正丁胺羰氧基)乙基，2-(N-異丁胺羰氧基)乙基，2-(N-二級丁胺羰氧基)乙基，2-(N-三級丁胺羰氧基)乙基，2-(N-正戊胺羰氧基)乙基，2-(N-新戊胺羰氧基)乙基，2-(N-正己胺羰氧基)乙基，3-(N-甲胺羰氧基)丙基，4-(N-甲胺羰氧基)丁基，3-(N-乙胺羰氧基)丙基，4-(N-乙胺羰氧基)丁基等。 "Single (C 1 -C 6 )alkylamine carbonyloxy(C 1 -C 6 )alkyl" means that a mono(C 1 -C 6 )alkylaminecarbonyloxy group and a (C 1 -C 6 )alkyl bond The group to be bonded is, for example, N-methylaminocarbonyloxymethyl, N-ethylaminecarbonyloxymethyl, N-n-propylaminecarbonyloxymethyl, N-isopropylaminecarbonyloxymethyl, N-n-butylamine carbonyl Oxymethyl, N-isobutylamine carbonyloxymethyl, N-second butylamine carbonyloxymethyl, N-tertiary butylamine carbonyloxymethyl, N-n-pentylamine carbonyloxymethyl, N-neopent Amine carbonyloxymethyl, N-n-hexylamine carbonyloxymethyl, 1-(N-methylaminocarbonyloxy)ethyl, 1-(N-ethylaminecarbonyloxy)ethyl, 1-(N-n-propylamine Carbonyloxy)ethyl, 1-(N-isopropylaminecarbonyloxy)ethyl, 1-(N-n-butylaminocarbonyloxy)ethyl, 1-(N-isobutylaminecarbonyloxy)ethyl , 1-(N-II-butylaminecarbonyloxy)ethyl, 1-(N-tertiary butylaminecarbonyloxy)ethyl, 1-(N-n-pentylaminocarbonyloxy)ethyl, 1- (N-Pentylaminecarbonyloxy)ethyl, 1-(N-n-hexylaminocarbonyloxy)ethyl, 2-(N-methylaminocarbonyloxy)ethyl, 2-(N-ethylamine carbonyloxy) Ethyl, 2-(N-n-propylaminocarbonyloxy)ethyl, 2-(N-isopropylaminecarbonyloxy)ethyl, 2-(N-n-butylaminocarbonyloxy)ethyl, 2- (N-isobutylamine carbonyloxy)ethyl, 2-(N-secondary butyl Carbonyloxy)ethyl, 2-(N-tertiary butylaminocarbonyloxy)ethyl, 2-(N-n-pentylaminocarbonyloxy)ethyl, 2-(N-neopentylcarbonylcarbonyl) Ethyl, 2-(N-n-hexylaminocarbonyloxy)ethyl, 3-(N-methylaminocarbonyloxy)propyl, 4-(N-methylaminocarbonyloxy)butyl, 3-(N- Ethylamine carbonyloxy)propyl, 4-(N-ethylaminecarbonyloxy)butyl and the like.

「二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)」就是，表示二(C1-C6)烷胺羰氧(二(C1-C6)烷胺基的烷基可以相同或不相同。)與(C1-C6)烷基鍵合的基，例如，可舉N,N-二甲胺羰氧甲基，N,N-二乙胺羰氧甲基，N,N-二正丙胺羰氧甲基，N,N-二異丙胺羰氧甲基，N,N-二正丁胺羰氧甲基，N,N-二異丁胺羰氧甲基，N,N-二二級丁胺羰氧甲基，N,N-二三級丁胺羰氧甲基，N,N-二正戊胺羰氧甲基，N,N-二新戊胺羰氧甲基，N,N-二正己胺羰氧甲基，N-甲基-N-乙胺羰氧甲基，N-甲基-N-正丙胺羰氧甲基，N-甲基-N-異丙胺羰氧甲基，N-甲基-N-正丁胺羰氧甲基，N-甲基-N-異丁胺羰氧甲基，N-甲基-N-二級丁胺羰氧甲基，N-甲基-N-三級丁胺羰氧甲基，N-甲基-N-正戊胺羰氧甲基，N-甲基-N-新戊胺羰氧甲基，N-甲基-N-正己胺羰氧甲基，1-(N,N-二甲胺羰氧基)乙基，1-(N,N-二乙胺羰氧基)乙基，1-(N,N-二正丙胺羰氧基)乙基，1-(N,N-二異丙胺羰氧基)乙基，1-(N,N-二正丁胺羰氧基)乙基，1-(N,N-二異丁胺羰氧基)乙基，1-(N,N-二二級丁胺羰氧基)乙基，1-(N,N-二三級丁胺羰氧基)乙基，1-(N,N-二正戊胺羰氧基)乙基，1-(N,N-二新戊胺羰氧基)乙基，1-(N,N-二正己胺羰氧基)乙基，1-(N-甲基-N-乙胺羰氧基)乙基，1-(N-甲基-N-正丙胺羰氧基) 乙基，1-(N-甲基-N-異丙胺羰氧基)乙基，1-(N-甲基-N-正丁胺羰氧基)乙基，1-(N-甲基-N-異丁胺羰氧基)乙基，1-(N-甲基-N-二級丁胺羰氧基)乙基，1-(N-甲基-N-三級丁胺羰氧基)乙基，1-(N-甲基-N-正戊胺羰氧基)乙基，1-(N-甲基-N-新戊胺羰氧基)乙基，1-(N-甲基-N-正己胺羰氧基)乙基，2-(N,N-二甲胺羰氧基)乙基，2-(N,N-二乙胺羰氧基)乙基，2-(N,N-二正丙胺羰氧基)乙基，2-(N,N-二異丙胺羰氧基)乙基，2-(N,N-二正丁胺羰氧基)乙基，2-(N,N-二異丁胺羰氧基)乙基，2-(N,N-二二級丁胺羰氧基)乙基，2-(N,N-二三級丁胺羰氧基)乙基，2-(N,N-二正戊胺羰氧基)乙基，2-(N,N-二新戊胺羰氧基)乙基，2-(N,N-二正己胺羰氧基)乙基，2-(N-甲基-N-乙胺羰氧基)乙基，2-(N-甲基-N-正丙胺羰氧基)乙基，2-(N-甲基-N-異丙胺羰氧基)乙基，2-(N-甲基-N-正丁胺羰氧基)乙基，2-(N-甲基-N-異丁胺羰氧基)乙基，2-(N-甲基-N-二級丁胺羰氧基)乙基，2-(N-甲基-N-三級丁胺羰氧基)乙基，2-(N-甲基-N-正戊胺羰氧基)乙基，2-(N-甲基-N-新戊胺羰氧基)乙基，2-(N-甲基-N-正己胺羰氧基)乙基，3-(N,N-二甲胺羰氧基)丙基，4-(N,N-二甲胺羰氧基)丁基，3-(N,N-二乙胺羰氧基)丙基，4-(N,N-二乙胺羰氧基)丁基等。 "Di(C 1 -C 6 )alkylaminecarbonyloxy(C 1 -C 6 )alkyl (di(C 1 -C 6 )alkylaminoalkyl may be the same or different.)" C 1 -C 6 ) alkylamine carbonyl oxide (alkyl group of di(C 1 -C 6 )alkylamino group may be the same or different.) A group bonded to a (C 1 -C 6 ) alkyl group, for example, N,N-dimethylamine carbonyloxymethyl, N,N-diethylamine carbonyloxymethyl, N,N-di-n-propylamine carbonyloxymethyl, N,N-diisopropylaminecarbonyloxymethyl, N , N-di-n-butylamine carbonyloxymethyl, N,N-diisobutylamine carbonyloxymethyl, N,N-di-second butylamine carbonyloxymethyl, N,N-di-tertiary butylamine carbonyl oxygen Methyl, N,N-di-n-pentylamine carbonyloxymethyl, N,N-di-p-amylamine carbonyloxymethyl, N,N-di-n-hexylamine carbonyloxymethyl, N-methyl-N-ethylamine Carbonyloxymethyl, N-methyl-N-n-propylamine carbonyloxymethyl, N-methyl-N-isopropylaminecarbonyloxymethyl, N-methyl-N-n-butylaminecarbonyloxymethyl, N- Methyl-N-isobutylamine carbonyloxymethyl, N-methyl-N-second butylamine carbonyloxymethyl, N-methyl-N-tertiary butylamine carbonyloxymethyl, N-methyl- N-n-pentylamine carbonyloxymethyl, N-methyl-N-neopentyl carbonyloxymethyl, N-methyl-N-n-hexylamine carbonyloxymethyl, 1-(N,N-dimethylamine carbonyl Oxy)ethyl, 1-(N,N- Ethylamine carbonyloxy)ethyl, 1-(N,N-di-n-propylaminocarbonyloxy)ethyl, 1-(N,N-diisopropylaminecarbonyloxy)ethyl, 1-(N,N- Di-n-butylamine carbonyloxy)ethyl, 1-(N,N-diisobutylaminecarbonyloxy)ethyl, 1-(N,N-di-second-butylaminocarbonyl)ethyl, 1- (N,N-Di-tertiary butylamine carbonyloxy)ethyl, 1-(N,N-di-n-pentylaminocarbonyloxy)ethyl, 1-(N,N-di-p-amylamine carbonyloxy) Ethyl, 1-(N,N-di-n-hexylaminocarbonyloxy)ethyl, 1-(N-methyl-N-ethylaminecarbonyloxy)ethyl, 1-(N-methyl-N-positive Acetone carbonyloxy) ethyl, 1-(N-methyl-N-isopropylaminecarbonyloxy)ethyl, 1-(N-methyl-N-n-butylaminocarbonyloxy)ethyl, 1-( N-methyl-N-isobutylamine carbonyloxy)ethyl, 1-(N-methyl-N-secondary butylamine carbonyloxy)ethyl, 1-(N-methyl-N-third Butylaminecarbonyloxy)ethyl, 1-(N-methyl-N-n-pentylaminecarbonyloxy)ethyl, 1-(N-methyl-N-neopentylcarbonyloxy)ethyl, 1 -(N-methyl-N-n-hexylaminecarbonyloxy)ethyl, 2-(N,N-dimethylaminocarbonyloxy)ethyl, 2-(N,N-diethylaminecarbonyloxy)ethyl Base, 2-(N,N-di-n-propylaminocarbonyloxy)ethyl, 2-(N,N-diisopropylaminecarbonyloxy)ethyl, 2-(N,N-di-n-butylaminecarbonyloxy Ethyl, 2-(N,N-diisobutyl) Carbonyloxy)ethyl, 2-(N,N-di-second-butylaminocarbonyl)ethyl, 2-(N,N-di-tert-butylaminocarbonyl)ethyl, 2-(N, N-di-n-pentylamine carbonyloxy)ethyl, 2-(N,N-di-p-amylamine carbonyloxy)ethyl, 2-(N,N-di-n-hexylaminocarbonyloxy)ethyl, 2- (N-methyl-N-ethylaminecarbonyloxy)ethyl, 2-(N-methyl-N-n-propylaminocarbonyloxy)ethyl, 2-(N-methyl-N-isopropylaminecarbonyloxyl Ethyl, 2-(N-methyl-N-n-butylaminocarbonyloxy)ethyl, 2-(N-methyl-N-isobutylaminecarbonyloxy)ethyl, 2-(N- Methyl-N-second butylamine carbonyloxy)ethyl, 2-(N-methyl-N-tertiary butylamine carbonyloxy)ethyl, 2-(N-methyl-N-n-pentylamine Carbonyloxy)ethyl, 2-(N-methyl-N-neopentylcarbonyloxy)ethyl, 2-(N-methyl-N-n-hexylaminecarbonyloxy)ethyl, 3-(N , N-dimethylaminocarbonyloxy)propyl, 4-(N,N-dimethylaminocarbonylcarbonyl)butyl, 3-(N,N-diethylaminecarbonyloxy)propyl, 4-( N,N-diethylaminecarbonyloxy)butyl and the like.

「N-(C1-C6)烷-N-甲醯胺(C1-C6)烷基」就是，表示N-(C1-C6)烷-N-甲醯胺基與(C1-C6)烷基鍵合的基，例如，可舉N-甲基-N-甲醯胺基甲基，N-乙基-N-甲醯胺基甲基，N-正丙基-N-甲醯胺基甲基，N-異丙基-N-甲醯胺基甲基，N-正丁基-N-甲醯胺基甲基，N-異丁基-N-甲醯胺基甲基，N-二級丁基-N-甲醯胺基甲基，N-三級丁基-N-甲醯胺基甲基，N-正戊基-N-甲醯胺基甲基，N-新戊基-N-甲醯胺基甲基，N-正己基-N-甲醯胺基甲基，1-(N-甲基-N- 甲醯胺基)乙基，1-(N-乙基-N-甲醯胺基)乙基，1-(N-正丙基-N-甲醯胺基)乙基，1-(N-異丙基-N-甲醯胺基)乙基，1-(N-正丁基-N-甲醯胺基)乙基，1-(N-異丁基-N-甲醯胺基)乙基，1-(N-二級丁基-N-甲醯胺基)乙基，1-(N-三級丁基-N-甲醯胺基)乙基，1-(N-正戊基-N-甲醯胺基)乙基，1-(N-新戊基-N-甲醯胺基)乙基，1-(N-正己基-N-甲醯胺基)乙基，2-(N-甲基-N-甲醯胺基)乙基，2-(N-乙基-N-甲醯胺基)乙基，2-(N-正丙基-N-甲醯胺基)乙基，2-(N-異丙基-N-甲醯胺基)乙基，2-(N-正丁基-N-甲醯胺基)乙基，2-(N-異丁基-N-甲醯胺基)乙基，2-(N-二級丁基-N-甲醯胺基)乙基，2-(N-三級丁基-N-甲醯胺基)乙基，2-(N-正戊基-N-甲醯胺基)乙基，2-(N-新戊基-N-甲醯胺基)乙基，2-(N-正己基-N-甲醯胺基)乙基，3-(N-甲基-N-甲醯胺基)丙基，4-(N-甲基-N-甲醯胺基)丁基，3-(N-乙基-N-甲醯胺基)丙基，4-(N-乙基-N-甲醯胺基)丁基等。 "N-(C 1 -C 6 ) alkane-N-formamide (C 1 -C 6 )alkyl" means N-(C 1 -C 6 ) alkane-N-formamido and (C 1 - C 6 ) alkyl-bonded group, for example, N-methyl-N-formamidomethyl, N-ethyl-N-formamidomethyl, N-n-propyl- N-methylaminomethyl, N-isopropyl-N-methylaminomethyl, N-n-butyl-N-methylaminomethyl, N-isobutyl-N-methylamine Methyl, N-tert-butyl-N-methylaminomethyl, N-tertiary butyl-N-methylaminomethyl, N-n-pentyl-N-methylaminomethyl , N-neopentyl-N-methylaminomethyl, N-n-hexyl-N-methylaminomethyl, 1-(N-methyl-N-methylamino)ethyl, 1- (N-ethyl-N-formamido)ethyl, 1-(N-n-propyl-N-methylamino)ethyl, 1-(N-isopropyl-N-carboxamide Ethyl, 1-(N-n-butyl-N-methylamino)ethyl, 1-(N-isobutyl-N-methylamino)ethyl, 1-(N-second-butyl --N-methylamino)ethyl, 1-(N-tris-butyl-N-methylamino)ethyl, 1-(N-n-pentyl-N-methylamino)ethyl , 1-(N-neopentyl-N-methylamino)ethyl, 1-(N-n-hexyl-N-methylamino)ethyl, 2-(N-methyl-N-formamidine Amino)ethyl, 2- (N-ethyl-N-formamido)ethyl, 2-(N-n-propyl-N-methylamino)ethyl, 2-(N-isopropyl-N-carboxamide Ethyl, 2-(N-n-butyl-N-methylamino)ethyl, 2-(N-isobutyl-N-methylamino)ethyl, 2-(N-second dibutyl) --N-methylamino)ethyl, 2-(N-tert-butyl-N-methylamino)ethyl, 2-(N-n-pentyl-N-methylamino)ethyl , 2-(N-neopentyl-N-methylamino)ethyl, 2-(N-n-hexyl-N-methylamino)ethyl, 3-(N-methyl-N-formamidine Amino)propyl, 4-(N-methyl-N-formamido)butyl, 3-(N-ethyl-N-carbamido)propyl, 4-(N-ethyl- N-methylamino)butyl and the like.

「N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基」就是，表示N-(C1-C6)烷-N-(C1-C6)烷氧羰胺基與(C1-C6)烷基鍵合的基，例如，可舉N-甲基-N-甲氧羰胺基甲基，N-甲基-N-乙氧羰胺基甲基，N-甲基-N-正丙氧羰胺基甲基，N-甲基-N-異丙氧羰胺基甲基，N-甲基-N-正丁氧羰胺基甲基，N-甲基-N-三級丁氧羰胺基甲基，1-(N-甲基-N-甲氧羰胺基)乙基，1-(N-甲基-N-乙氧羰胺基)乙基，1-(N-甲基-N-正丙氧羰胺基)乙基，1-(N-甲基-N-異丙氧羰胺基)乙基，1-(N-甲基-N-正丁氧羰胺基)乙基，1-(N-甲基-N-三級丁氧羰胺基)乙基，2-(N-甲基-N-甲氧羰胺基)乙基，2-(N-甲基-N-乙氧羰胺基)乙基，2-(N-甲基-N-正丙氧羰胺基)乙基，2-(N-甲基-N-異丙氧羰胺基)乙基，2-(N-甲基-N-正丁氧羰胺基)乙基，2-(N-甲基-N-三級丁 氧羰胺基)乙基，3-(N-甲基-N-甲氧羰胺基)丙基，4-(N-甲基-N-甲氧羰胺基)丁基，3-(N-甲基-N-乙氧羰胺基)丙基，4-(N-甲基-N-乙氧羰胺基)丁基，3-(N-甲基-N-三級丁氧羰胺基)丙基，4-(N-甲基-N-三級丁氧羰胺基)丁基等。 "N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl" means N-(C 1 -C 6 ) alkane-N - (C 1 -C 6) alkoxycarbonyl group and (C 1 -C 6) alkyl group is bonded, for example, may be cited N- methyl -N- methoxycarbonyl aminomethyl, N- methyl -N-ethoxycarbonylaminomethyl, N-methyl-N-n-propoxycarbonylaminomethyl, N-methyl-N-isopropyloxycarbonylaminomethyl, N-methyl-N - n-Butoxycarbonylaminomethyl, N-methyl-N-tertiary butoxycarbonylaminomethyl, 1-(N-methyl-N-methoxycarbonylamino)ethyl, 1-(N -methyl-N-ethoxycarbonylamino)ethyl, 1-(N-methyl-N-n-propoxycarbonylamino)ethyl, 1-(N-methyl-N-isopropoxycarbonylamine Ethyl, ethyl 1-(N-methyl-N-n-butoxycarbonylamino)ethyl, 1-(N-methyl-N-tertiarybutoxycarbonylamino)ethyl, 2-(N -methyl-N-methoxycarbonylamino)ethyl, 2-(N-methyl-N-ethoxycarbonylamino)ethyl, 2-(N-methyl-N-n-propoxycarbonylamino) Ethyl, 2-(N-methyl-N-isopropoxycarbonylamino)ethyl, 2-(N-methyl-N-n-butoxycarbonylamino)ethyl, 2-(N-A Base-N-tertiary butoxycarbonylamino)ethyl, 3-(N-methyl-N-methoxycarbonylamino)propyl, 4-(N-methyl-N-methoxycarbonylamino) Butyl, 3-(N-methyl-N-ethoxycarbonyl Propyl, 4-(N-methyl-N-ethoxycarbonylamino)butyl, 3-(N-methyl-N-tertiarybutoxycarbonylamino)propyl, 4-(N- Methyl-N-tertiary butoxycarbonylamino)butyl and the like.

「甲醯氧(C1-C6)烷基」就是，表示甲醯氧基與(C1-C6)烷基鍵合的基，例如，甲醯氧甲基，1-甲醯氧乙基，2-甲醯氧乙基，3-甲醯氧丙基等。 "Methoxy-(C 1 -C 6 )alkyl" means a group which is bonded to a (C 1 -C 6 ) alkyl group, for example, methyl methoxymethyl, 1-methyl oxo Base, 2-formyloxyethyl, 3-methyloxypropyl, and the like.

「二甲醯氧(C1-C6)烷基」就是，表示二個甲醯氧基與(C1-C6)烷基鍵合的基，二個甲醯氧基在同一或不同的碳原子上取代也可。例如，可舉二甲醯氧甲基，1,1-二甲醯氧乙基，2,2-二甲醯氧乙基，1,2-二甲醯氧丙基等。 "Dimethyl oxy(C 1 -C 6 )alkyl" means a group in which two methyl methoxy groups are bonded to a (C 1 -C 6 ) alkyl group, and the two methoxy groups are the same or different. Substitution on a carbon atom is also possible. For example, it may be dimethyloxymethyl, 1,1-dimethyloxyethyl, 2,2-dimethyloxyethyl, 1,2-dimethyloxypropyl or the like.

「(C1-C6)烷磺醯氧(C1-C6)烷基」就是，表示直鏈或支鏈狀的碳原子數1至6個的烷磺醯氧基與直鏈或支鏈狀的碳原子數1至6個的烷基鍵合的基，例如，可舉甲磺醯氧甲基，1-甲磺醯氧乙基，2-甲磺醯氧乙基，1-乙磺醯氧乙基，1-乙磺醯氧乙基，1-異丙磺醯氧乙基，2-異丙磺醯氧乙基，3-甲磺醯氧丙基等。 "(C 1 -C 6 ) alkanesulfonyloxy (C 1 -C 6 )alkyl" means a straight or branched alkanesulfonyloxy group having 1 to 6 carbon atoms and a straight chain or a branch A chain-bonded group having 1 to 6 alkyl groups having a carbon number, for example, methylsulfonyloxymethyl, 1-methylsulfonyloxyethyl, 2-methylsulfonyloxyethyl, 1-ethyl Sulfoxyloxyethyl, 1-ethylsulfonyloxyethyl, 1-isopropylsulfonyloxyethyl, 2-isopropylsulfonyloxyethyl, 3-methylsulfonyloxypropyl, and the like.

「(C1-C6)烷氧羰氧(C1-C6)烷基」就是，表示直鏈或支鏈狀的碳原子數1至6個的烷-羰氧基與直鏈或支鏈狀的碳原子數1至6個的烷基鍵合的基，例如，可舉甲氧羰氧甲基，1-甲氧羰氧乙基，2-甲氧羰氧乙基，3-甲氧羰氧丙基等。 "(C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl" means an alkane-carbonyloxy group having a straight or branched chain of 1 to 6 carbon atoms and a straight chain or a branch. The chain-bonded group having 1 to 6 alkyl groups having 1 to 6 carbon atoms, for example, methoxycarbonyloxymethyl, 1-methoxycarbonyloxyethyl, 2-methoxycarbonyloxyethyl, 3-methyl Oxycarbonyloxypropyl and the like.

「(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基」就是，表示前述(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧基與(C1-C6)烷基鍵合的基，例如，2-(2-(2-甲氧乙氧基)乙氧基)乙基等。 "(C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl" means, the aforementioned (C 1 -C 6 ) alkane a group in which an oxygen (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy group is bonded to a (C 1 -C 6 ) alkyl group, for example, 2-(2-(2-methoxyethoxy) Ethoxy)ethyl and the like.

「羧(C1-C6)烷基」就是，表示羧基與直鏈或支鏈狀的 碳原子數1至6個的烷基鍵合的基，例如，可舉羧甲基，1-羧乙基，2-羧乙基等。 The "carboxy(C 1 -C 6 )alkyl group" means a group in which a carboxyl group is bonded to a linear or branched alkyl group having 1 to 6 carbon atoms, and examples thereof include a carboxymethyl group and a 1-carboxy group. Ethyl, 2-carboxyethyl and the like.

「芳香族雜環基」就是，表示有由氧原子，硫原子及氮原子所選擇的1個以上的雜原子的5或6員的芳香族雜環基，例如，可舉呋喃基，噻吩基，吡啶基，嘧啶基，嗒基，吡基，吡咯基，咪唑基，吡唑基，噻唑基，異噻唑基，唑基，異唑基，二唑基，***基，四唑基，三基等的單環式芳香族雜環基；喹啉基，異喹啉基，喹唑啉基，喹啉基，苯并呋喃基，苯并噻吩基，苯并唑基，苯并異唑基，苯并噻唑基，苯并咪唑基，苯并***基，吲哚基，吲唑基，吡咯并吡基，咪唑并吡啶基，咪唑并吡基，吡唑并吡啶基，吡唑并噻吩基，吡唑并三基等的芳族性融合的雜環狀基。 The "aromatic heterocyclic group" is a 5- or 6-membered aromatic heterocyclic group which has one or more hetero atoms selected from an oxygen atom, a sulfur atom and a nitrogen atom, and examples thereof include a furyl group and a thienyl group. , pyridyl, pyrimidinyl, anthracene Base Base, pyrrolyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, Azolyl, different Azolyl, Diazolyl, triazolyl, tetrazolyl, tri Monocyclic aromatic heterocyclic group such as quinolyl, isoquinolyl, quinazolinyl, quin Porphyrin, benzofuranyl, benzothienyl, benzo Azolyl Azyl, benzothiazolyl, benzimidazolyl, benzotriazolyl, fluorenyl, oxazolyl, pyrrolopy Base, imidazopyridyl, imidazopyridine Base, pyrazolopyridyl, pyrazolothiophenyl, pyrazolo An aromatic fused heterocyclic group such as a radical.

「芳香族雜環(C1-C6)烷基」就是，表示上述芳香族雜環基與(C1-C6)烷基鍵合的基，可舉芳香族雜環-甲基，1-芳香族雜環-乙基，2-芳香族雜環-乙基，3-芳香族雜環-丙基，4-芳香族雜環-丁基等。 The "aromatic heterocyclic (C 1 -C 6 ) alkyl group" means a group in which the above aromatic heterocyclic group is bonded to a (C 1 -C 6 ) alkyl group, and examples thereof include an aromatic heterocyclic ring-methyl group. - aromatic heterocyclic-ethyl, 2-aromatic heterocyclic-ethyl, 3-aromatic heterocyclic-propyl, 4-aromatic heterocyclic-butyl and the like.

「芳香族雜環(C1-C6)氧基」就是，表示上述芳香族雜環基與氧原子鍵合的基。 The "aromatic heterocyclic ring (C 1 -C 6 )oxy group" means a group in which the above aromatic heterocyclic group is bonded to an oxygen atom.

「非芳香族雜環基」就是，表示有由氧原子，硫原子及氮原子所選擇的1個以上的雜原子的5或6員的非芳香族雜環基，例如，可舉環氧乙基(oxiranyl)，環硫乙基(thiiranyl)，吖丙啶基(aziridinyl)，氧雜環丁基(oxetanyl)，硫環丁基(thietanyl)，氮環丁基(azetidinyl)，吡咯啶基(pyrrolidinyl)，哌啶基(piperidinyl)，嗎啉基，硫代嗎啉基(thiomorpholinyl)，1-氧化硫代嗎啉基，1,1-二氧 化硫代嗎啉基，哌基(piperazinyl)，六亞甲基亞胺基(hexamethyleniminyl)，唑烷基(oxazoliyl)，噻唑啶基(thiazolidinyl)，咪唑啶基(imidazolidinyl)，唑啉基(oxazolinyl)，四氫唑啉基，2-四氫唑啉基，噻唑啉基(thiazolinyl)，異唑啉基，四氫異唑啉基、咪唑啉基(imidazolinyl)，間二氧雜環戊烯基(dioxolyl)，二戊烷基(dioxolanyl)，二氫二唑基(dihydrooxadiazolyl)，2-側氧基-1,3-噻唑啶-5-基，1,3-二氧雜環丁烷(dioxolan)-2-基，1,3-二氧雜環丁烷-4-基，1,3-二氧雜環戊烷-2-基，1,3-二氧雜環庚(dioxepan)-2-基，四氫-1,2-(oxazin)-2-基，吡喃(pyranyl)，四氫吡喃基，硫代吡喃(thiopyranyl)，四氫硫代吡喃基(tetrahydrothiopyranyl)，1-氧化四氫硫代吡喃基，1,1-二氧化四氫硫代吡喃基，四氫呋喃基，四氫硫代呋喃基，1-氧化四氫硫代呋喃基，1,1-二氧化四氫硫代呋喃基，二烷基(dioxanyl)，吡唑啶基(pyrazolidinyl)，吡唑啉基(pyrazinyl)，四氫嘧啶基，二氫***基，四氫***基等的單環式非芳香族雜環基；二氫吲哚基，二氫異吲哚基，二氫苯并呋喃基，二氫苯并二奧辛(dioxinyl)，二氫苯并二氧環庚三烯基(dihydrobenzodioxepinyl)，四氫苯并呋喃基，苯并哌喃基(chromenyl)，二氫喹啉基，四氫喹啉基，二氫異喹啉基，四氫異喹啉基，二氫酞基等的非芳族縮合雜環基等。 The "non-aromatic heterocyclic group" is a 5- or 6-membered non-aromatic heterocyclic group which has one or more hetero atoms selected from an oxygen atom, a sulfur atom and a nitrogen atom, and examples thereof include epoxy B. Oxiranyl, thiiranyl, aziridinyl, oxetanyl, thietanyl, azetidinyl, pyrrolidinyl Pyrrolidinyl), piperidinyl, morpholinyl, thiomorpholinyl, 1-oxothiomorpholinyl, 1,1-dioxythiomorpholinyl, piperazine Piperazinyl, hexamethyleniminyl, Oxazoliyl, thiazolidinyl, imidazolidinyl, Oxazolinyl, tetrahydrogen Oxazolinyl, 2- Tetrahydrogen Oxazolinyl, thiazolinyl, different Oxazolinyl, tetrahydroiso Oxazolinyl, imidazolinyl, dioxolyl, two Dioxolanyl, dihydrogen Dihydrooxadiazolyl, 2-sided oxy-1,3-thiazolidin-5-yl, 1,3-dioxol-2-yl, 1,3-dioxole Butane-4-yl, 1,3-dioxol-2-yl, 1,3-dioxe-2-yl, tetrahydro-1,2- (oxazin)-2-yl, pyranyl, tetrahydropyranyl, thiopyranyl, tetrahydrothiopyranyl, 1-oxidized tetrahydrothiopyranyl, 1,1-dihydrotetrathiothiopyranyl, tetrahydrofuranyl, tetrahydrothiofuranyl, 1-oxidized tetrahydrothiofuranyl, 1,1-dihydrotetrahydrothiofuranyl, a monocyclic non-aromatic heterocyclic group such as a dioxanyl group, a pyrazolidinyl group, a pyrazinyl group, a tetrahydropyrimidinyl group, a dihydrotriazolyl group or a tetrahydrotriazolyl group; Dihydroindenyl, dihydroisoindolyl, dihydrobenzofuranyl, dioxinyl, dihydrobenzodioxepinyl, tetrahydrobenzo a non-aromatic condensed heterocyclic ring such as furyl, chromenyl, dihydroquinolyl, tetrahydroquinolyl, dihydroisoquinolinyl, tetrahydroisoquinolinyl, indanyl or the like Base.

「非芳香族雜環(C1-C6)烷基」就是，表示上述非芳香族雜環基與(C1-C6)烷基鍵合的基，可舉非芳香族雜環-甲基，1-非芳香族雜環-乙基，2-非芳香族雜環-乙基，3-非芳香族雜環-丙基，4-非芳香族雜環-丁基等。 The "non-aromatic heterocyclic (C 1 -C 6 ) alkyl group" means a group in which the above non-aromatic heterocyclic group is bonded to a (C 1 -C 6 ) alkyl group, and a non-aromatic heterocyclic ring- A group, a 1-non-aromatic heterocyclic-ethyl group, a 2-non-aromatic heterocyclic-ethyl group, a 3-non-aromatic heterocyclic-propyl group, a 4-non-aromatic heterocyclic group-butyl group and the like.

「非芳香族雜環氧(C1-C6)烷基」就是，表示上述非芳香族雜 環氧基與(C1-C6)烷基鍵合的基，可舉非芳香族雜環氧-甲基，1-非芳香族雜環氧-乙基，2-非芳香族雜環氧-乙基，3-非芳香族雜環氧-丙基，4-非芳香族雜環氧-丁基等。 The "non-aromatic heteroepoxy (C 1 -C 6 ) alkyl group" means a group in which the non-aromatic heterocyclic oxy group is bonded to a (C 1 -C 6 ) alkyl group, and a non-aromatic heterocyclic ring is used. Oxy-methyl, 1-non-aromatic heteroepoxy-ethyl, 2-non-aromatic heteroepoxy-ethyl, 3-non-aromatic hetero-epoxy-propyl, 4-non-aromatic hetero-epoxy Butyl and the like.

「含氮脂肪族雜環」就是，表示含有0至1個的氧原子，0至1個的硫原子，1至2個的氮原子的，5或6員的脂肪族雜環基，可舉例如，唑啶(oxazolidine)，噻唑啶(thiazolidine)，異唑啶，異噻唑啶，嗎啉，硫代嗎啉，哌(piperazine)，吡咯啶(pyrrolidine)，哌啶(piperidine)，四氫-1,2-唑啶(oaxadine)，四氫-1,3-唑啶等。 The "nitrogen-containing aliphatic heterocyclic ring" is an aliphatic heterocyclic group which has 0 to 1 oxygen atom, 0 to 1 sulfur atom, 1 to 2 nitrogen atoms, and 5 or 6 members. Such as, Oxazolidine, thiazolidine, different Zolidine, isothiazolidine, morpholine, thiomorpholine, piperazine (piperazine), pyrrolidine, piperididine, tetrahydro-1,2- Oxadine, tetrahydro-1,3- Oxazolidine and the like.

「3至6員的脂肪族環」就是，例如，可舉環丙烷，環丁烷，環戊烷，環己烷等的碳原子數3至6個的環烷烴等。 The "aliphatic ring of 3 to 6 members" is, for example, a cycloalkane having 3 to 6 carbon atoms such as cyclopropane, cyclobutane, cyclopentane or cyclohexane.

又，「(C1-C6)」，「(C2-C6)」，「(C3-C6)」等的表現是表示各種取代基的碳原子數的範圍。 Further, the expression "(C 1 -C 6 )", "(C 2 -C 6 )", "(C 3 -C 6 )" or the like is a range indicating the number of carbon atoms of various substituents.

本發明的一般式(I)表示的噻唑羧醯胺衍生物的鹽類而言，例如可例示鹽酸鹽，硫酸鹽，硝酸鹽，磷酸鹽等的無機酸鹽類，乙酸鹽，富馬酸鹽，馬來酸鹽，草酸鹽，甲磺酸鹽，苯磺酸鹽，對甲苯磺酸鹽等的有機酸鹽類，鈉離子，鉀離子，鈣離子，三甲基銨等的無機或有機的鹼基的鹽類。 The salts of the thiazole carboxamide derivatives represented by the general formula (I) of the present invention may, for example, be inorganic acid salts such as hydrochlorides, sulfates, nitrates, phosphates, etc., acetates, fumaric acids. Salt, maleate, oxalate, methanesulfonate, besylate, p-toluenesulfonate, etc., organic salts, sodium, potassium, calcium, trimethylammonium, etc. Salt of organic bases.

本發明的一般式(I)表示的噻唑羧醯胺衍生物是，其構造式中有時含有1個或多數個的不對稱中心，也有2種以上的光學異構物及非鏡像異構物(Diastereomers)存在的情況，本發明將其各個光學異構物及其以任意比率含有的混合物全部包含在內。 The thiazole carboquinone derivative represented by the general formula (I) of the present invention may have one or a plurality of asymmetric centers in the structural formula, and may have two or more optical isomers and non-image isomers. In the case of (Diastereomers), the present invention includes all of its optical isomers and mixtures thereof contained in any ratio.

又，本發明的一般式(I)表示的噻唑羧醯胺衍生物是，有來源 於其構造式中的碳-碳雙鍵的2種的幾何異構物的存在的情況，本發明將其各個幾何異構物及其以任意比率含有的混合物全部包含在內。 Further, the thiazole carboquinone derivative represented by the general formula (I) of the present invention is a source In the case of the presence of two geometric isomers of a carbon-carbon double bond in the structural formula, the present invention includes all of its geometric isomers and mixtures thereof contained in an arbitrary ratio.

本發明的一般式(I)表示的噻唑羧醯胺衍生物中，R1而言，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；(4a)(C1-C6)烷氧基；或(6a)(C3-C6)環烷基為理想，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；或(6a)(C3-C6)環烷基更理想。 In the thiazole carboxamide derivative represented by the general formula (I) of the present invention, in the case of R 1 , (1a) a halogen atom; (2a) (C 1 - C 6 ) alkyl group; (3a) a halogen (C 1 - C 6 )alkyl; (4a)(C 1 -C 6 )alkoxy; or (6a)(C 3 -C 6 )cycloalkyl is ideal, (1a)halogen; (2a)(C 1 - C 6 )alkyl; (3a) halo(C 1 -C 6 )alkyl; or (6a)(C 3 -C 6 )cycloalkyl is more preferred.

Y而言，O，S，-N(R3)-，或-N=C(R3)-為理想，O，-N(R3)-，或-N=C(R3)-更理想。 For Y, O, S, -N(R 3 )-, or -N=C(R 3 )- is ideal, O, -N(R 3 )-, or -N=C(R 3 )- ideal.

R3而言，(1b)氫原子；(2b)(C1-C6)烷基；(8b)甲醯基；(9b)(C1-C6)烷氧(C1-C6)烷基；(11b)(C1-C6)烷硫(C1-C6)烷基；(12b)(C1-C6)烷亞磺醯(C1-C6)烷基； (13b)(C1-C6)烷磺醯(C1-C6)烷基；(14b)(C1-C6)烷氧羰基；(15b)(C1-C6)烷氧(C1-C6)烷羰基；(16b)(C1-C6)烷羰基；(17b)鹵(C1-C6)烷羰基；(18b)(C1-C6)烷氧羰(C1-C6)烷基(19b)(C3-C6)環烷基；或(20b)(C1-C6)烷氧基為理想。 R 3 , (1b) hydrogen atom; (2b) (C 1 -C 6 ) alkyl; (8b) formazan; (9b) (C 1 - C 6 ) alkoxy (C 1 - C 6 ) (11b)(C 1 -C 6 )alkylthio(C 1 -C 6 )alkyl; (12b)(C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; 13b) (C 1 -C 6) alkyl sulfonic acyl (C 1 -C 6) alkyl; (14b) (C 1 -C 6) alkoxycarbonyl; (15b) (C 1 -C 6) alkoxy (C 1 -C 6 )alkylcarbonyl; (16b)(C 1 -C 6 )alkylcarbonyl; (17b)halo(C 1 -C 6 )alkylcarbonyl; (18b)(C 1 -C 6 )alkoxycarbonyl (C 1 -C 6 )alkyl (19b)(C 3 -C 6 )cycloalkyl; or (20b)(C 1 -C 6 )alkoxy is preferred.

R2的理想的態樣是，Y為，O，S，或-N(R3)-時，(1c)胺(C1-C6)烷基；(2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(4c)(C1-C6)烷羰胺(C1-C6)烷基；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基；(7c)單(C1-C6)烷胺羰基；(9c)單(C1-C6)烷胺硫羰基；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(13c)鹵(C1-C6)烷氧(C1-C6)烷基；(15c)(C2-C6)炔氧(C1-C6)烷基；(16c)(C3-C6)環烷氧(C1-C6)烷基； (17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧的烷氧基可以相同或不相同。)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；(19c)(C1-C6)烷羰氧(C1-C6)烷基；(20c)苯(C1-C6)烷氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(28c)(C1-C6)烷氧亞胺(C1-C6)烷基；(29c)N-(C1-C6)烷-N-甲醯胺(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基；(31c)非芳香族雜環基；(32c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基 的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環氧(C1-C6)烷基；(37c)芳香族雜環基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基；(41c)R2與R3鍵合，與其所鍵合的氮原子一起，形成5或6員的含氮脂肪族雜環也可以，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的可以相同或不相同的，1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基。 The ideal aspect of R 2 is, when Y is, O, S, or -N(R 3 )-, (1c) amine (C 1 -C 6 ) alkyl; (2c) mono (C 1 -C 6 An alkylamine (C 1 -C 6 )alkyl group; (3c) a di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl group (di(C 1 -C 6 )alkylamino group May be the same or different.); (4c) (C 1 -C 6 ) alkylcarbonylamine (C 1 -C 6 )alkyl; (5c)(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 ) alkyl; (6c) (C 1 -C 6 ) alkanesulfonamide (C 1 -C 6 )alkyl; (7c) mono(C 1 -C 6 )alkylaminecarbonyl; (9c)mono(C 1 -C 6 )alkylaminethiocarbonyl; (11c)hydroxy(C 1 -C 6 )alkyl; (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (13c)halide (C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (15c)(C 2 -C 6 )alkynyloxy(C 1 -C 6 )alkyl; (16c)(C 3 -C 6 a cycloalkoxy (C 1 -C 6 )alkyl group; (17c) a di(C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl group (di(C 1 -C 6 ) alkoxy alkoxylate The groups may be the same or different.); (18c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (19c) (C 1 -C 6 ) Alkoxycarbonyl (C 1 -C 6 )alkyl; (20c) benzene (C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (21c)(C 1 -C 6 )alkoxy (C 1 -C 6 )alkylcarbonyl; (23c)di(C 1 -C 6 )alkylaminecarbonyloxy(C 1 -C 6 )alkyl (di(C) The alkyl group of 1 -C 6 )alkylamino group may be the same or different.); (24c)(C 1 -C 6 )alkylthio(C 1 -C 6 )alkyl; (25c)(C 1 -C 6 Alkalazine (C 1 -C 6 )alkyl; (26c)(C 1 -C 6 )alkane (C 1 -C 6 )alkyl; (27c)(C 1 -C 6 )alkoxy (C 1 -C 6 )alkyl; (28c)(C 1 -C 6 )alkoxyimine (C 1 -C 6 )alkyl; (29c)N-(C 1 -C 6 )alkane-N -carbamamine (C 1 -C 6 )alkyl; (30c) N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl (31c) a non-aromatic heterocyclic group; (32c) having the same or different in the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii)methyl fluorenyl And (viii) a substituted non-aromatic heterocyclic group having one or more substituents selected from the group consisting of an oxygen group (=O); (33c) a non-aromatic heterocyclic group (C 1 -C 6 )alkyl group; (34c) On the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 ) alkyl group. , (v) (C 1 -C 6) alkoxy, (vi) halo (C 1 -C 6) alkoxy, (vii) acyl, and a (viii) oxy (= O) 1 selected Above substituted non-aromatic heterocyclic group substituted with (C 1 -C 6) alkyl; (35c) non-aromatic heterocyclic oxy (C 1 -C 6) alkyl; (36c) has on the ring, can be The same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C) 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected one or more substituents Substituted non-aromatic heteroepoxy (C 1 -C 6 )alkyl; (37c)aromatic heterocyclic; (39c)aromatic heterocyclic (C 1 -C 6 )alkyl; (40c) on the ring Yes, may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v a (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) a substituted aromatic heterocyclic ring having one or more substituents selected from a formazan group (C 1 -C 6 )alkyl; (41c) R 2 is bonded to R 3 , together with the nitrogen atom to which it is bonded, a nitrogen-containing aliphatic heterocyclic ring of 5 or 6 members may be formed, and the nitrogen-containing aliphatic group may be used. The heterocyclic ring is an oxygen atom having 0 to 1 ring, 0 to 1 sulfur atom, 1 to 2 nitrogen atoms, and the nitrogen-containing aliphatic group Ring, the ring may have on of (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6) alkyl, (v (C 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) may be the same or not The same, one or more substituents; (42c) formazan (C 1 -C 6 )alkyl; (43c) bis(methyloxy)(C 1 -C 6 )alkyl; (44c)( C 1 -C 6 ) alkanesulfonyloxy (C 1 -C 6 )alkyl; (45c)(C 1 -C 6 )alkoxycarbonyloxy(C 1 -C 6 )alkyl; (46c)(C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy(C 1 -C 6 )alkyl; or (47c)carboxy(C 1 -C 6 )alkyl.

R2的別的理想的態樣是，Y是，O，或-N(R3)-時，(1c)胺(C1-C6)烷基；(2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基；(7c)單(C1-C6)烷胺羰基；(9c)單(C1-C6)烷胺硫羰基；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同。)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；(19c)(C1-C6)烷羰氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同。)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基； (31c)非芳香族雜環基；(32c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環氧(C1-C6)烷基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基；(41c)R2與R3鍵合，與其所鍵合的氮原子一起，形成5或6員的含氮脂肪族雜環也可以，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵 (C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的可以相同或不相同的，1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基。 Another desirable aspect of R 2 is that Y is O, or -N(R 3 )-, (1c)amine (C 1 -C 6 )alkyl; (2c)mono (C 1 -C 6 An alkylamine (C 1 -C 6 )alkyl group; (3c) a di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl group (di(C 1 -C 6 )alkylamino group May be the same or different.); (5c) (C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (6c)(C 1 -C 6 ) alkanesulfonamide (C 1 - C 6 )alkyl; (7c)mono(C 1 -C 6 )alkylaminecarbonyl; (9c)mono(C 1 -C 6 )alkylaminethiocarbonyl; (11c)hydroxy(C 1 -C 6 )alkyl (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (17c)di(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl (di(C 1 ) -C 6 ) alkoxy alkoxy groups may be the same or different.); (18c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (19c) (C 1 -C 6 ) alkoxycarbonyl(C 1 -C 6 )alkyl; (21c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkylcarbonyl; (23c)di C 1 -C 6 ) alkylamine oxycarbonyl (C 1 -C 6 )alkyl (alkyl group of di(C 1 -C 6 )alkylamino group may be the same or different.); (24c) (C 1 -C 6 ) alkanethio (C 1 -C 6 )alkyl; (25c)(C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; (26c)(C 1 -C 6 )alkane acyl (C 1 -C 6) alkyl; (27c) (C 1 -C 6) alkoxy (C 1 -C 6) alkyl; (30c) N- (C 1 -C 6) alkyl -N- (C 1 -C 6) alkoxycarbonyl amine (C 1 -C 6) alkyl; (31c) a non-aromatic heterocyclic group; (32c) having the same or different in the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) Halogen (C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii)carbamyl and (viii) a substituted non-aromatic heterocyclic group having one or more substituents selected from oxy (=O); (33c) a non-aromatic heterocyclic (C 1 -C 6 )alkyl group; (34c) having a ring , which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected one or more substitutions a substituted non-aromatic heterocyclic (C 1 -C 6 )alkyl group; (35c) a non-aromatic heteroepoxy (C 1 -C 6 )alkyl group; (36c) having the same or not on the ring The same, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6) alkoxy, (vi) halo (C 1 -C 6) alkoxy, (vii) acyl methyl non-aromatic heterocyclic-substituted (C 1 -C 6) alkyl (viii) oxy (= O) of the selected one or more substituents; (39c) an aromatic heterocyclic (C 1 -C 6 (40c) may be the same or different on the ring, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C) 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, and (vii) one or more selected for mercapto Substituted substituted aromatic heterocyclic (C 1 -C 6 )alkyl; (41c) R 2 bonded to R 3 , together with the nitrogen atom to which it is bonded, forms a 5 or 6 membered nitrogen-containing aliphatic A heterocyclic ring may also be used. The nitrogen-containing aliphatic heterocyclic ring is an oxygen atom having 0 to 1 ring, 0 to 1 sulfur atom, 1 to 2 nitrogen atoms, and the nitrogen-containing aliphatic heterocyclic ring is on the ring. There may be (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) may be the same or different, one or more a substituent; (42c) a methoxy (C 1 -C 6 ) alkyl group; (43c) a bis(methyl methoxy) (C 1 -C 6 ) alkyl group; (44c) (C 1 -C 6 ) alkanesulfonyloxy (C 1 -C 6 )alkyl; (45c)(C 1 -C 6 )alkoxycarbonyloxy(C 1 -C 6 )alkyl; (46c (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; or (47c)carboxy (C 1 -C 6 ) alkyl.

R2的另一種理想的態樣是，Y是，-N=C(R3)-時，(2d)(C1-C6)烷氧基；或(4d)二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同。)。 Another desirable aspect of R 2 is that Y is, -N=C(R 3 )-, (2d)(C 1 -C 6 )alkoxy; or (4d)di(C 1 -C 6 The alkyl groups of the alkylamino group (di(C 1 -C 6 )alkylamino group may be the same or different.).

R4，R5，R6，及R7可以相同或不相同，表示(1e)氫原子；(2e)(C1-C6)烷基；(3e)鹵(C1-C6)烷基；(7e)(C1-C6)烷氧(C1-C6)烷基；或(8e)R4與R5，R6與R7，R4與R6或R4與R7鍵合，與其鍵合的碳原子一起，形成3至6員的脂肪族環態樣為理想，(1e)氫原子；(2e)(C1-C6)烷基；或(3e)鹵(C1-C6)烷基更理想。 R 4 , R 5 , R 6 , and R 7 may be the same or different and represent (1e) a hydrogen atom; (2e) (C 1 -C 6 )alkyl; (3e) a halogen (C 1 -C 6 ) alkane (7e) (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; or (8e) R 4 and R 5 , R 6 and R 7 , R 4 and R 6 or R 4 and R The 7- bond, together with the carbon atom to which it is bonded, forms an aliphatic ring-like form of 3 to 6 members, (1e) a hydrogen atom; (2e) (C 1 - C 6 ) alkyl; or (3e) a halogen The (C 1 -C 6 )alkyl group is more desirable.

又，R4，R5，R6，及R7的別的理想的態樣是，R4是，(C1-C6)烷基或鹵(C1-C6)烷基，並且，R5，R6，及R7是，氫原子的化合物。 Further, another desirable aspect of R 4 , R 5 , R 6 , and R 7 is that R 4 is (C 1 -C 6 )alkyl or halo(C 1 -C 6 )alkyl, and R 5 , R 6 , and R 7 are compounds of a hydrogen atom.

R8而言，(1f)氫原子；(3f)(C1-C6)烷氧基；(4f)(C3-C6)環烷基；(5f)(C1-C6)烷羰基；或(7f)(C1-C6)烷氧羰基為理想，(1f)氫原子；(3f)(C1-C6)烷氧基；或(4f)(C3-C6)環烷基更理想。 R 8 is (1f) a hydrogen atom; (3f) (C 1 -C 6 ) alkoxy; (4f) (C 3 -C 6 ) cycloalkyl; (5f) (C 1 -C 6 ) alkane Carbonyl; or (7f)(C 1 -C 6 )alkoxycarbonyl is ideal, (1f) hydrogen atom; (3f)(C 1 -C 6 )alkoxy; or (4f)(C 3 -C 6 ) A cycloalkyl group is more desirable.

X1，X2及X3而言，可以相同或不相同，(1g)氫原子；(2g)鹵原子；(4g)氰基；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基；(8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基；(16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi)鹵 (C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基；(21g)(C3-C6)環烷基；(22g)芳香族雜環基；(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基；(24g)芳香族雜環氧基；或(25g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環氧基為理想，(1g)氫原子；(2g)鹵原子；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基；(8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基；(16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi)鹵(C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基；(21g)(C3-C6)環烷基； (22g)芳香族雜環基；或(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基更理想。 X 1 , X 2 and X 3 may be the same or different, (1 g) hydrogen atom; (2 g) halogen atom; (4 g) cyano group; (6 g) (C 1 - C 6 ) alkoxyimine ( C 1 -C 6 )alkyl; (7g) (C 1 -C 6 )alkyl; (8g) halo(C 1 -C 6 )alkyl; (9g)(C 1 -C 6 )alkoxy; (16g) (C 1 -C 6 ) alkoxycarbonyl; (17g) phenyl; (18g) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, and (vi)halo(C 1 -C 6 ) a substituted phenyl group having one or more substituents selected from an alkoxy group; (21 g) (C 3 -C 6 )cycloalkyl group; (22 g) an aromatic heterocyclic group; (23 g) having a ring The same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C) a substituted aromatic heterocyclic group having 1 - C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) one or more substituents selected from a formazan group; 24 g) an aromatic heterocyclic oxy group; or (25 g) which may be the same or different from the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) halo(C 1 -C 6 )alkyl, (v)(C a 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) a substituted aromatic heterocyclic oxy group having one or more substituents selected from a formazan group; Desirable, (1 g) hydrogen atom; (2 g) halogen atom; (6 g) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (7 g) (C 1 -C 6 )alkyl (8g) halo(C 1 -C 6 )alkyl; (9g)(C 1 -C 6 )alkoxy; (16g)(C 1 -C 6 )alkoxycarbonyl; (17g)phenyl; 18g) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 ) a substituted phenyl group having one or more substituents selected from the group consisting of an alkyl group, (v) (C 1 -C 6 ) alkoxy group, and (vi) a halogen (C 1 -C 6 ) alkoxy group; (21 g) (C 3 -C 6 )cycloalkyl; (22 g) an aromatic heterocyclic group; or (23 g) having the same or different in the ring, (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo (C 1 -C 6 ) The alkoxy group and the (vii) substituted aromatic heterocyclic group having one or more substituents selected from the indenyl group are more preferred.

本發明的一般式(I)表示的噻唑羧醯胺衍生物是，例如可依照國際公開第2008/062878號小冊所述的方法製造，或可依照下述的製造方法製造，但並不限定於這些方法。 The thiazole carboquinone derivative represented by the general formula (I) of the present invention can be produced, for example, according to the method described in International Publication No. 2008/062878, or can be produced according to the following production method, but is not limited thereto. In these methods.

製造方法1 Manufacturing method 1

(式中，R1，R2，R4，R5，R6，R7，R8，Y，X1，X2，及X3與前述同。) (wherein R 1 , R 2 , R 4 , R 5 , R 6 , R 7 , R 8 , Y, X 1 , X 2 , and X 3 are the same as defined above.)

一般式(II)→一般式(I)的製造方法 General formula (II) → general formula (I) manufacturing method

將一般式(II)表示的噻唑羧酸與一般式(III)表示的2-(經取代吡唑基)乙基胺衍生物在縮合劑，鹼基及不活性溶媒的存在下，反應而可製造一般式(I)表示的本發明的噻唑羧醯胺衍生物。 The thiazolecarboxylic acid represented by the general formula (II) and the 2-(substituted pyrazolyl)ethylamine derivative represented by the general formula (III) are reacted in the presence of a condensing agent, a base and an inactive solvent. A thiazole carboquinone derivative of the present invention represented by the general formula (I) is produced.

在本反應使用的縮合劑而言，例如，可例示氰磷酸二甲酯(DEPC)，羰基二咪唑(CDI)，1,3-二環己基碳二亞胺(DCC)，氯碳酸酯類，碘化2-氯-1-甲基吡啶鎓等，其使用量是在對一般式(II)表示的噻唑羧酸的0.8倍莫耳乃至1.5倍莫耳的範圍適宜選擇 而使用即可。 The condensing agent used in the present reaction may, for example, be dimethyl cyanophosphate (DEPC), carbonyl diimidazole (CDI), 1,3-dicyclohexylcarbodiimide (DCC), chlorocarbonate, 2-chloro-1-methylpyridinium iodide or the like is used in an amount suitable for a range of 0.8 times moles to 1.5 times moles of the thiazolecarboxylic acid represented by the general formula (II). Just use it.

鹼基而言，例如，可舉氫氧化鈉，氫氧化鉀，碳酸鈉，碳酸鉀，碳酸氫鈉，碳酸氫鉀等的無機鹼基類；乙酸鈉，乙酸鉀等的乙酸鹽類；三級丁基氧化鉀，甲基氧化鈉，乙基氧化鈉等的鹼金屬烷基氧化物類；三乙基胺，二異丙基乙基胺，1,8-二氮雜雙環[5.4.0]十一烷基-7-烯等的第三級胺類；吡啶，二甲胺基吡啶等的含氮芳香族化合物等，其使用量是在對一般式(II)表示的噻唑羧酸的通常0.5倍莫耳至10倍莫耳的範圍而使用。 Examples of the base include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, and potassium hydrogencarbonate; acetates such as sodium acetate and potassium acetate; and tertiary grades; Alkali metal alkyl oxides such as potassium butylate, sodium methyloxide, sodium ethoxide, etc.; triethylamine, diisopropylethylamine, 1,8-diazabicyclo[5.4.0] a tertiary amine such as undecyl-7-ene; a nitrogen-containing aromatic compound such as pyridine or dimethylaminopyridine, used in the usual amount of the thiazolecarboxylic acid represented by the general formula (II) Use from 0.5 times the molar range to 10 times the molar range.

在本反應使用的不活性溶媒而言，只要不會顯著阻礙本反應的進行的溶媒即可，例如可例示苯，甲苯，二甲苯等的芳香族烴類；二氯化甲烷，三氯化甲烷，四氯化碳等的鹵化烴類；氯苯，二氯苯等的鹵化芳香族烴類；二乙基醚，甲基三級丁基醚，二烷(dioxane)，四氫呋喃等的鏈狀或環狀醚類；乙酸乙酯等的酯類；二甲基甲醯胺，二甲基乙醯胺等的醯胺類；丙酮，甲基乙基酮等的酮類；二甲基亞碸，1,3-二甲基-2-咪唑啉等的不活性溶媒，這些不活性溶媒可以單獨或2種以上混合而使用。 The inactive solvent to be used in the reaction may be a solvent which does not significantly inhibit the progress of the reaction, and examples thereof include aromatic hydrocarbons such as benzene, toluene, and xylene; and methane chloride and methane chloride. a halogenated hydrocarbon such as carbon tetrachloride; a halogenated aromatic hydrocarbon such as chlorobenzene or dichlorobenzene; diethyl ether, methyl tertiary butyl ether, a chain or cyclic ether such as dioxane or tetrahydrofuran; an ester such as ethyl acetate; a guanamine such as dimethylformamide or dimethylacetamide; acetone, methyl ethyl ketone An inactive solvent such as a ketone; a dimethyl hydrazine or a 1,3-dimethyl-2-imidazoline; and these inactive solvents may be used alone or in combination of two or more.

本反應是等莫耳反應，是故將各反應劑等莫耳使用即可，但也可以任一種的反應劑過量使用。反應溫度是由室溫至所使用的不活性溶媒的沸點域下進行，反應時間是視反應規模，反應溫度而不一定，但在數分乃至48小時的範圍內進行即可。 This reaction is a molar reaction, and it is only necessary to use each of the reactants, etc., but any of the reactants may be used in excess. The reaction temperature is carried out from room temperature to the boiling point range of the inactive solvent to be used, and the reaction time is depending on the reaction scale, and the reaction temperature is not constant, but may be carried out in the range of several minutes or even 48 hours.

反應終了後，由含有目的物的反應系以常法單離即可，必要時可以再結晶，管柱層析法等精製而製造目的物。 After the completion of the reaction, the reaction system containing the desired product may be isolated by a usual method, and if necessary, it may be recrystallized, purified by column chromatography or the like to produce a desired product.

製造方法2 Manufacturing method 2

(式中，R1，R2，R4，R5，R6，R7，R8，X1，X2，X3，及Y與前述同，hal表示鹵原子。) (wherein R 1 , R 2 , R 4 , R 5 , R 6 , R 7 , R 8 , X 1 , X 2 , X 3 , and Y are the same as defined above, and hal represents a halogen atom.)

一般式(II-1)→一般式(I)的製造方法 General formula (II-1) → general formula (I) manufacturing method

將一般式(II-1)表示的噻唑羧酸鹵化物與一般式(III)表示的2-(經取代吡唑基)乙基胺衍生物在鹼基及不活性溶媒的存在下，反應而可製造一般式(I)表示的本發明的噻唑羧醯胺衍生物。 The thiazolecarboxylic acid halide represented by the general formula (II-1) and the 2-(substituted pyrazolyl)ethylamine derivative represented by the general formula (III) are reacted in the presence of a base and an inactive solvent. The thiazole carboquinone derivative of the present invention represented by the general formula (I) can be produced.

在本反應使用鹼基而言，例如，可舉氫氧化鈉，氫氧化鉀，碳酸鈉，碳酸鉀，碳酸氫鈉，碳酸氫鉀等的無機鹼類；乙酸鈉，乙酸鉀等的乙酸鹽類；三級丁基氧化鉀，甲基氧化鈉，乙基氧化鈉等的鹼金屬烷基氧化物類；三乙基胺，二異丙基乙基胺，1,8-二氮雜雙環[5.4.0]十一烷基-7-烯等的第三級胺類；吡啶，二甲胺基吡啶等的含氮芳香族化合物等，其使用量是對一般式(II-1)表示的噻唑羧酸鹵化物，通常在0.5倍莫耳至10倍莫耳的範圍內使用。 Examples of the base used in the reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, and potassium hydrogencarbonate; and acetates such as sodium acetate and potassium acetate. ; alkali metal alkyl oxides such as potassium butyl oxychloride, sodium methyloxide, sodium ethoxide; triethylamine, diisopropylethylamine, 1,8-diazabicyclo[5.4 .0] a tertiary amine such as undecyl-7-ene; a nitrogen-containing aromatic compound such as pyridine or dimethylaminopyridine, used in the amount of thiazole represented by the general formula (II-1) Carboxylic acid halides are typically used in the range of from 0.5 moles to 10 moles.

在本反應使用的不活性溶媒而言，只要不會顯著阻礙本反應的進行的溶媒即可，例如可例示苯，甲苯，二甲苯等的芳香族烴類；二氯化甲烷，三氯化甲烷，四氯化碳等的鹵化烴類；氯苯，二氯苯等的鹵化芳香族烴類；二乙基醚，甲基三級丁醚，二烷，四氫呋喃等的鏈狀或環狀醚類；乙酸乙酯等的酯類；二甲基甲醯胺，二甲基乙醯胺等的醯胺類；丙酮，甲基乙基酮等的酮類；二甲基亞碸，1,3-二甲基-2-咪唑啉等或水的不活性溶媒， 這些不活性溶媒可單獨或2種以上混合使用。 The inactive solvent to be used in the reaction may be a solvent which does not significantly inhibit the progress of the reaction, and examples thereof include aromatic hydrocarbons such as benzene, toluene, and xylene; and methane chloride and methane chloride. a halogenated hydrocarbon such as carbon tetrachloride; a halogenated aromatic hydrocarbon such as chlorobenzene or dichlorobenzene; diethyl ether, methyl tertiary butyl ether, a chain or a cyclic ether such as an alkane or a tetrahydrofuran; an ester such as ethyl acetate; a guanamine such as dimethylformamide or dimethylacetamide; or a ketone such as acetone or methyl ethyl ketone. An inactive solvent such as dimethyl hydrazine, 1,3-dimethyl-2-imidazoline or the like, and these inactive solvents may be used singly or in combination of two or more kinds.

本反應是等莫耳反應，是故將各反應劑等莫耳使用即可，但也可以任一種的反應劑過量使用。反應溫度是由室溫至所使用的不活性溶媒的沸點域下進行，反應時間是視反應規模，反應溫度而不一定，但在數分乃至48小時的範圍內進行即可。 This reaction is a molar reaction, and it is only necessary to use each of the reactants, etc., but any of the reactants may be used in excess. The reaction temperature is carried out from room temperature to the boiling point range of the inactive solvent to be used, and the reaction time is depending on the reaction scale, and the reaction temperature is not constant, but may be carried out in the range of several minutes or even 48 hours.

反應終了後，由含有目的物的反應系以常法單離即可，必要時可以再結晶，管柱層析法等精製而製造目的物。 After the completion of the reaction, the reaction system containing the desired product may be isolated by a usual method, and if necessary, it may be recrystallized, purified by column chromatography or the like to produce a desired product.

製造方法1及2的原料的一般式(III)表示的2-(經取代吡唑基)乙基胺衍生物是，可依照國際公開第2008/062878號小冊所述的方法而製造。 The 2-(substituted pyrazolyl)ethylamine derivative represented by the general formula (III) of the starting materials of the production methods 1 and 2 can be produced according to the method described in International Publication No. 2008/062878.

製造方法3 Manufacturing method 3

製造方法1的原料的一般式(II)表示的噻唑羧酸及製造方法2的原料的一般式(II-1)表示的噻唑羧酸鹵化物是依照以下的方法可製造。 The thiazolecarboxylic acid halide represented by the general formula (II-1) represented by the general formula (II) and the raw material of the production method 2 of the raw material of the production method 1 can be produced by the following method.

(式中，各代號與前述同。) (In the formula, each code is the same as the above.)

一般式(IV)→一般式(V)的製造方法 Manufacturing method of general formula (IV) → general formula (V)

一般式(V)表示的2-鹵噻唑羧酸乙酯是，將依照國際公開第2009/012482號小冊，或J.Heterocyclic Chem.,22，p1621至1630(1985)所述的方法而製造的一般式(IV)表示的2-胺基噻唑-5-羧酸乙酯，賦之於桑德邁爾反應(Sandmeyer反應)(例如，日本化學會編第4版實驗化學講座(第19卷)有機合成[I]，丸善股份有限公司，1992年11月，p.450-453所述的方法)而可製造。 The ethyl 2-halothiazolecarboxylate represented by the general formula (V) is produced according to the method described in International Publication No. 2009/012482, or J. Heterocyclic Chem., 22 , p1621 to 1630 (1985). The ethyl 2-aminothiazole-5-carboxylate represented by the general formula (IV) is assigned to the Sandmeyer reaction (for example, the Chemical Society of Japan, 4th edition, Experimental Chemistry Lecture (Vol. 19) Organic synthesis [I], Maruzen Co., Ltd., November 1992, method described in p. 450-453).

具體而言，將一般式(IV)表示的2-胺基噻唑-5-羧酸乙酯，在不活性溶媒的存在下，與亞硝酸化合物及鹵化合物反應，而可製造一般式(V)表示的2-鹵噻唑羧酸乙酯。 Specifically, the ethyl 2-aminothiazole-5-carboxylate represented by the general formula (IV) is reacted with a nitrous acid compound and a halogen compound in the presence of an inactive solvent to produce a general formula (V). Ethyl 2-halothiazolecarboxylate represented.

在本反應使用的亞硝酸化合物而言，例如，可舉亞硝酸鈉，亞硝酸鉀等的亞硝酸鹼金屬鹽；亞硝酸乙酯，亞硝酸三級丁酯，亞硝酸戊酯等的有碳數1至6的烷基的亞硝酸烷酯等，其使用量是對一般式(IV)表示的2-胺基噻唑-5-羧酸乙酯，通常是在0.8倍莫耳至1.5倍莫耳的範圍內使用。 The nitrous acid compound used in the present reaction may, for example, be an alkali metal nitrite such as sodium nitrite or potassium nitrite; carbon having ferrous nitrite, butyl nitrite or amyl nitrite; An alkyl nitrite or the like having 1 to 6 alkyl groups, which is used in an amount of 2-aminothiazole-5-carboxylic acid ethyl ester represented by the general formula (IV), usually at 0.8 times mole to 1.5 times Used within the scope of the ear.

在本反應使用的鹵化合物而言，例如，可舉氯化銅(I)，溴化銅(I)，碘化銅(I)等的1價的鹵化銅；氯化銅(II)，溴化銅(II)，碘化銅(II)等的2價的鹵化銅；碘化鈉，溴化鉀，碘化鉀等的鹵化鹼金屬；氯化氫，溴化氫，碘化氫等的鹵化氫等。這種鹵化合物可以分別單獨或2種以上組合而使用。其使用量是對一般式(IV)表示的2-胺基噻唑-5-羧酸甲乙酯，合計在0.5倍莫耳至10倍莫耳的範圍內使用。 The halogen compound used in the reaction may, for example, be a monovalent copper halide such as copper (I) chloride, copper (I) bromide or copper (I) iodide; copper (II) chloride or bromine; Copper (II), a divalent copper halide such as copper (II) iodide; an alkali metal halide such as sodium iodide, potassium bromide or potassium iodide; a hydrogen halide such as hydrogen chloride, hydrogen bromide or hydrogen iodide. These halogen compounds may be used singly or in combination of two or more kinds. The amount used is a methyl 2-aminothiazole-5-carboxylate represented by the general formula (IV), and is used in a total range of from 0.5 to 10 moles.

在本反應使用的不活性溶媒而言，只要不顯著阻礙本反應的進行的不活性溶媒即可，例如可例示苯，甲苯，二甲苯 等的芳香族烴類；二氯化甲烷，三氯化甲烷，四氯化碳等的鹵化烴類；氯苯，二氯苯等的鹵化芳香族烴類；二乙基醚，甲基三級丁醚，二烷，四氫呋喃等的鏈狀或環狀醚類；乙酸乙酯等的酯類；二甲基甲醯胺，二甲基乙醯胺等的醯胺類；丙酮，甲基乙基酮等的酮類；乙腈等的腈類；二甲基亞碸，1,3-二甲基-2-咪唑啉等或水的不活性溶媒，這些不活性溶媒可以單獨或2種以上混合使用。 The inactive solvent to be used in the reaction may be an inactive solvent which does not significantly inhibit the progress of the reaction, and examples thereof include aromatic hydrocarbons such as benzene, toluene and xylene; and methane chloride and trichlorination. Halogenated hydrocarbons such as methane and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; diethyl ether, methyl tertiary butyl ether, a chain or a cyclic ether such as an alkane or a tetrahydrofuran; an ester such as ethyl acetate; a guanamine such as dimethylformamide or dimethylacetamide; or a ketone such as acetone or methyl ethyl ketone. A nitrile such as acetonitrile; an inactive solvent such as dimethyl hydrazine or 1,3-dimethyl-2-imidazoline or water; these inactive solvents may be used singly or in combination of two or more kinds.

本反應是等莫耳反應，是故將各反應劑等莫耳使用即可，但也可以任一種的反應劑過量使用。反應溫度是由室溫至所使用的不活性溶媒的沸點域下進行，反應時間是視反應規模，反應溫度而不一定，但在數分乃至48小時的範圍內進行即可。 This reaction is a molar reaction, and it is only necessary to use each of the reactants, etc., but any of the reactants may be used in excess. The reaction temperature is carried out from room temperature to the boiling point range of the inactive solvent to be used, and the reaction time is depending on the reaction scale, and the reaction temperature is not constant, but may be carried out in the range of several minutes or even 48 hours.

反應終了後，由含有目的物的反應系以常法單離即可，必要時可以再結晶，管柱層析法等精製而製造目的物。 After the completion of the reaction, the reaction system containing the desired product may be isolated by a usual method, and if necessary, it may be recrystallized, purified by column chromatography or the like to produce a desired product.

一般式(V)→一般式(II-2)的製造方法 Manufacturing method of general formula (V) → general formula (II-2)

將一般式(V)表示的2-鹵噻唑-5-羧酸乙酯與一般式(VI)表示的化合物，在鹼基及不活性溶媒的存在下，反應而可製造一般式(II-2)表示的噻唑-5-羧酸乙酯。 The ethyl 2-halothiazole-5-carboxylate represented by the general formula (V) and the compound represented by the general formula (VI) can be reacted in the presence of a base and an inactive solvent to produce a general formula (II-2). ) represents the thiazole-5-carboxylic acid ethyl ester.

一般式(VI)表示的化合物是可以使用市售品，或將其本身依照公知的方法而製造。 The compound represented by the general formula (VI) can be produced by using a commercially available product or by itself according to a known method.

在本反應使用的鹼基而言，例如，可舉氫氧化鈉，氫氧化鉀，碳酸鈉，碳酸鉀，碳酸氫鈉，碳酸氫鉀等的無機鹼基類；乙酸鈉，乙酸鉀等的乙酸鹽類；三級丁基氧化鉀，甲基氧化鈉，乙基氧化鈉等的鹼金屬烷基氧化物類；三乙基胺，二異丙基乙基胺，1,8-二氮雜雙環[5.4.0]十一烷基-7-烯等的第三級胺類；吡 啶，二甲胺基吡啶等的含氮芳香族化合物等，其使用量是一般式(V)表示的2-鹵噻唑-5-羧酸乙酯，通常在0.5倍莫耳至10倍莫耳的範圍內使用。 Examples of the base used in the reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, and potassium hydrogencarbonate; and acetic acid such as sodium acetate or potassium acetate. Salts; alkali metal alkyl oxides such as potassium tributylate, sodium methyloxide, sodium ethyloxide; triethylamine, diisopropylethylamine, 1,8-diazabicyclo [5.4.0] Tertiary amines such as undecyl-7-ene; a nitrogen-containing aromatic compound such as pyridine or dimethylaminopyridine, used in an amount of ethyl 2-halothiazole-5-carboxylate represented by the general formula (V), usually in the range of 0.5 to 10 moles. Used within the scope.

在本反應使用的不活性溶媒而言，只要不顯著阻礙本反應的進行的不活性溶媒即可，例如可例示苯，甲苯，二甲苯等的芳香族烴類；二氯化甲烷，三氯化甲烷，四氯化碳等的鹵化烴類；氯苯，二氯苯等的鹵化芳香族烴類；二乙基醚，甲基三級丁醚，二烷，四氫呋喃等的鏈狀或環狀醚類；乙酸乙酯等的酯類；二甲基甲醯胺，二甲基乙醯胺等的醯胺類；丙酮，甲基乙基酮等的酮類；乙腈等的腈類；二甲基亞碸，1,3-二甲基-2-咪唑啉等或水的不活性溶媒，這些不活性溶媒可以單獨或2種以上混合使用。 The inactive solvent to be used in the reaction may be an inactive solvent which does not significantly inhibit the progress of the reaction, and examples thereof include aromatic hydrocarbons such as benzene, toluene and xylene; and methane chloride and trichlorination. Halogenated hydrocarbons such as methane and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; diethyl ether, methyl tertiary butyl ether, a chain or a cyclic ether such as an alkane or a tetrahydrofuran; an ester such as ethyl acetate; a guanamine such as dimethylformamide or dimethylacetamide; or a ketone such as acetone or methyl ethyl ketone. A nitrile such as acetonitrile; an inactive solvent such as dimethyl hydrazine or 1,3-dimethyl-2-imidazoline or water; these inactive solvents may be used singly or in combination of two or more kinds.

本反應是等莫耳反應，是故將各反應劑等莫耳使用即可，但也可以任一種的反應劑過量使用。反應溫度是由室溫至所使用的不活性溶媒的沸點域下進行，反應時間是視反應規模，反應溫度而不一定，但在數分乃至48小時的範圍內進行即可。 This reaction is a molar reaction, and it is only necessary to use each of the reactants, etc., but any of the reactants may be used in excess. The reaction temperature is carried out from room temperature to the boiling point range of the inactive solvent to be used, and the reaction time is depending on the reaction scale, and the reaction temperature is not constant, but may be carried out in the range of several minutes or even 48 hours.

反應終了後，由含有目的物的反應系以常法單離即可，必要時可以再結晶，管柱層析法等精製而製造目的物。 After the completion of the reaction, the reaction system containing the desired product may be isolated by a usual method, and if necessary, it may be recrystallized, purified by column chromatography or the like to produce a desired product.

一般式(II-2)→一般式(II)的製造方法 General formula (II-2) → general formula (II) manufacturing method

一般式(II)表示的噻唑羧酸是，可將一般式(II-2)表示的噻唑-5-羧酸乙酯，賦之於加水分解反應而製造。 The thiazolecarboxylic acid represented by the general formula (II) can be produced by subjecting a thiazole-5-carboxylic acid ethyl ester represented by the general formula (II-2) to a hydrolysis reaction.

具體而言，將一般式(II-2)表示的噻唑-5-羧酸乙酯，在不活性溶媒的存在下，與鹼基或酸反應，而可製造一般式(II)表示的噻唑羧酸。 Specifically, the thiazole-5-carboxylic acid ethyl ester represented by the general formula (II-2) can be reacted with a base or an acid in the presence of an inactive solvent to produce a thiazole carboxyl group represented by the general formula (II). acid.

在本反應使用的鹼基而言，例如，可舉氫氧化鈉，氫氧化鉀，碳酸鈉，碳酸鉀，碳酸氫鈉，碳酸氫鉀等的無機鹼基類；三級丁基氧化鉀，甲基氧化鈉，乙基氧化鈉等的鹼金屬烷基氧物類等，其使用量是對一般式(II-2)表示的噻唑-5-羧酸乙酯通常是在0.5倍莫耳至10倍莫耳的範圍內使用。 Examples of the base used in the reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, and potassium hydrogencarbonate; and tertiary butyl oxyhydroxide, A An alkali metal alkyl oxide such as sodium oxyhydroxide or ethyl ethoxide, or the like, which is used in an amount of from 0.5 to 10 mol% to the ethyl thiazole-5-carboxylate represented by the general formula (II-2). Used within the range of the Momo.

在本反應使用的酸而言，例如，可舉鹽酸，硫酸，硝酸，磷酸等，其使用量是對一般式(II-2)表示的噻唑-5-羧酸乙酯，通常是在0.5倍莫耳至10倍莫耳的範圍內使用。 The acid to be used in the reaction may, for example, be hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid or the like, and is used in an amount of the thiazole-5-carboxylic acid ethyl ester represented by the general formula (II-2), usually at 0.5 times. Mole is used up to 10 times the range of moles.

在本反應使用的不活性溶媒而言，只要不顯著阻礙本反應的進行的不活性溶媒即可，例如，可例示甲醇，乙醇，異丙醇等的醇類；二乙基醚，甲基三級丁醚，二烷，四氫呋喃等的鏈狀或環狀醚類；二甲基甲醯胺，二甲基乙醯胺等的醯胺類；丙酮，甲基乙基酮等的酮類；乙腈等的腈類；二甲基亞碸，1,3-二甲基-2-咪唑啉等或水的不活性溶媒，這些不活性溶媒可單獨或2種以上混合使用。 The inactive solvent to be used in the reaction may be an inactive solvent which does not significantly inhibit the progress of the reaction, and examples thereof include alcohols such as methanol, ethanol and isopropanol; diethyl ether and methyl three. Dibutyl ether, two a chain or a cyclic ether such as an alkane or a tetrahydrofuran; a guanamine such as dimethylformamide or dimethylacetamide; a ketone such as acetone or methyl ethyl ketone; or a nitrile such as acetonitrile; An inactive solvent such as dimethyl hydrazine, 1,3-dimethyl-2-imidazoline or the like, and these inactive solvents may be used singly or in combination of two or more kinds.

本反應是等莫耳反應，是故將各反應劑等莫耳使用即可，但也可以任一種的反應劑過量使用。反應溫度是由室溫至所使用的不活性溶媒的沸點域下進行，反應時間是視反應規模，反應溫度而不一定，但在數分乃至48小時的範圍內進行即可。 This reaction is a molar reaction, and it is only necessary to use each of the reactants, etc., but any of the reactants may be used in excess. The reaction temperature is carried out from room temperature to the boiling point range of the inactive solvent to be used, and the reaction time is depending on the reaction scale, and the reaction temperature is not constant, but may be carried out in the range of several minutes or even 48 hours.

反應終了後，由含有目的物的反應系以常法單離即可，必要時可以再結晶，管柱層析法等精製而製造目的物。 After the completion of the reaction, the reaction system containing the desired product may be isolated by a usual method, and if necessary, it may be recrystallized, purified by column chromatography or the like to produce a desired product.

一般式(II)→一般式(II-1)的製造方法 General formula (II) → general formula (II-1) manufacturing method

將一般式(II)表示的噻唑羧酸，在鹵化劑及不活性溶媒的存在下反應而可製造一般式(II-1)表示的噻唑羧酸鹵化物。 The thiazolecarboxylic acid halide represented by the general formula (II-1) can be produced by reacting a thiazolecarboxylic acid represented by the general formula (II) in the presence of a halogenating agent and an inactive solvent.

在本反應使用的鹵化劑而言，例如，可舉亞磺醯氯(thionyl chloride)，草醯氯(oxalyl chloride)，磷醯氯(phosphoryl chloride)等，其使用量是對一般式(II)表示的噻唑羧酸通常在0.5倍莫耳至10倍莫耳的範圍內使用。 The halogenating agent used in the present reaction may, for example, be thionyl chloride, oxalyl chloride, phosphoryl chloride or the like, and the amount thereof used is for the general formula (II). The thiazolecarboxylic acid represented is usually used in the range of 0.5 to 10 moles.

在本反應使用的不活性溶媒而言，只要不顯著阻礙本反應的進行的不活性溶媒即可，例如可例示苯，甲苯，二甲苯等的芳香族烴類；二氯化甲烷，三氯化甲烷，四氯化碳等的鹵化烴類；氯苯，二氯苯等的鹵化芳香族烴類；二乙基醚，甲基三級丁醚，二烷，四氫呋喃等的鏈狀或環狀醚類；乙酸乙酯等的酯類；二甲基甲醯胺，二甲基乙醯胺等的醯胺類；丙酮，甲基乙基酮等的酮類；二甲基亞碸，1,3-二甲基-2-咪唑啉等或水的不活性溶媒，這些不活性溶媒可以單獨或2種以上混合使用。 The inactive solvent to be used in the reaction may be an inactive solvent which does not significantly inhibit the progress of the reaction, and examples thereof include aromatic hydrocarbons such as benzene, toluene and xylene; and methane chloride and trichlorination. Halogenated hydrocarbons such as methane and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; diethyl ether, methyl tertiary butyl ether, a chain or a cyclic ether such as an alkane or a tetrahydrofuran; an ester such as ethyl acetate; a guanamine such as dimethylformamide or dimethylacetamide; or a ketone such as acetone or methyl ethyl ketone. An inactive solvent such as dimethyl hydrazine, 1,3-dimethyl-2-imidazoline or the like, and these inactive solvents may be used singly or in combination of two or more kinds.

本反應是等莫耳反應，是故將各反應劑等莫耳使用即可，但也可以任一種的反應劑過量使用。反應溫度是由室溫至所使用的不活性溶媒的沸點域下進行，反應時間是視反應規模，反應溫度而不一定，但在數分乃至48小時的範圍內進行即可。 This reaction is a molar reaction, and it is only necessary to use each of the reactants, etc., but any of the reactants may be used in excess. The reaction temperature is carried out from room temperature to the boiling point range of the inactive solvent to be used, and the reaction time is depending on the reaction scale, and the reaction temperature is not constant, but may be carried out in the range of several minutes or even 48 hours.

反應終了後，由含有目的物的反應系以常法單離即可，必要時可以再結晶，管柱層析法等精製而製造目的物。 After the completion of the reaction, the reaction system containing the desired product may be isolated by a usual method, and if necessary, it may be recrystallized, purified by column chromatography or the like to produce a desired product.

以下將本發明的一般式(I)表示的噻唑羧醯胺衍生物衍生物的代表例在第1表乃至第7表，及第9表中例示，但本發明定並不限定於這些。表中，「Me」表示甲基，「Et」表示乙基，「Pr」表示丙基，「Bu」表示丁基，「Ph」表示苯基，「n-」表示正，「i-」表示異，「c-」表示脂環式烴基。物性是，表示融點(℃)，或折射率nD(測定溫度；℃)。記述為NMR的是，表示在第8表示其NMR 數據。 Representative examples of the thiazole carboquinone derivative derivative represented by the general formula (I) of the present invention are exemplified in Tables 1 to 7 and Table 9, but the present invention is not limited thereto. In the table, "Me" means methyl, "Et" means ethyl, "Pr" means propyl, "Bu" means butyl, "Ph" means phenyl, "n-" means positive, "i-" means The "c-" represents an alicyclic hydrocarbon group. Physical properties are, indicating melting point (°C), or refractive index n D (measuring temperature; °C). The NMR data is shown in Fig. 8 to show the NMR data.

含有本發明的一般式(I)表示的噻唑羧醯胺衍生物或其鹽類做為有效成分的植物病害防治劑是適於加害水稻，果樹，野菜，其他的作物及花卉類的各種農林，園藝，貯穀病害，或衛生病害等的病害防治。 The plant disease controlling agent containing the thiazole carboquinone derivative represented by the general formula (I) of the present invention or a salt thereof as an active ingredient is various agricultural and forestry plants suitable for injuring rice, fruit trees, wild vegetables, other crops and flowers. Disease control such as horticulture, grain storage, or health diseases.

本發明的植物病害防治劑是，不只是對於廣範圍的種類的絲狀菌，例如，屬於藻菌綱(Oomycetes)，子囊菌綱(Ascomycetes)，不完全菌綱(Deuteromycetes)，擔子菌綱(Basidiomycetes)菌有優異的殺菌效果，對植物病原細菌，及植物病毒也有優異的效果。 The plant disease controlling agent of the present invention is not only for a wide range of filamentous fungi, for example, belonging to the genus Oomycetes, Ascomycetes, Deuteromycetes, Basidiomycetes ( Basidiomycetes has excellent bactericidal effects and has excellent effects on phytopathogenic bacteria and plant viruses.

例如，稻病害而言，例如，黄化萎縮病(S.macrospora)，苗立枯病(R.chinensis，T.viride)，稻苗徒長病(G.fujikuroi)，稻熱病(M.grisea,P.oryzae)，紋枯病(R.solani)，胡麻葉枯病(C.miyabeanus)，褐變穂(A.padwiki)，紅變米(E.nigrum)，稻 麴病(C.virens)，稻谷枯細菌病(P.glumae)，葉鞘褐變病(P.fuscovaginae)，褐條病(P.avenae)，苗立枯細菌病(P.plantarii)，白葉枯病(X.oryzae)等；玉米病害而言，例如，胡麻葉枯病(B.maydis,C.heter ostrophus)，大斑病(E.turcicum)，斑點病(P.maydis)，黑穂病(U.maydis)等；煙草病害而言，例如，疫病(P.nicotianae/parasitica)，烟草霜霉病(P.tabacina)，白粉病(E.cichoracearum)，碳疽病(C.tabacum)，赤星病(A.longipes,A.alternata)，媒污病(C.salicinum)，萎黄病(O.brassicae)等；茶病害而言，例如，紅粒癌腫病(N.cinnabarina)，白星病(E.leucospila)，碳疽病(C.theae-sinensis)，輪斑病(P.longiseta,P.theae)，網餅病(E.reticulatum)，餅病(E.vexans)，赤燒病(P.syringae pv.theae)等；十字花科病害而言，例如，十字花科根瘤病(P.brassicae)，十字花科白銹病(A.macrospora)，十字花科烟草霜霉病(P.brassicae)，十字花科菌核病(S.sclerotiorum)，高麗菜根腐病(P.lingam)，高麗菜株腐病(T.cucumeris)，油菜白斑病(C.brassicicola)，白菜白斑病(C.brassicicola)，十字花科黑斑病(A.brassicae)，高麗菜黑腐病(X.campestris pv.campestris)等；草莓病害而言，例如，疫病(P.cactorum,P.nicotianae)，白粉病(S.macularis)，碳疽病(G.cingulata)，黑斑病(A.alternata)，蛇眼病(M.fragariae)等；番茄病害而言，例如，番茄晚疫病(P.infestans)，碳疽病(C.phomoides)，葉霉病(C.fulvum)，斑點病(S.lycopersici)，輪紋病(A. solani)，潰瘍病(C.michiganensis)等；茄科病害而言，例如，菌核病(S.sclerotiorum)，白粉病(S.furiginea)，褐紋病(P.vexans)，媒污霉病(M.nattrassii)，甜椒斑點病(S.lycopersici)，辣椒斑點病(S.lycopersici)，茄科青枯病(P.solanacearum)，茄科青枯病(P.solanacearum)等；瓜科病害而言，例如，瓜類疫病(P.melonis)，胡瓜烟草霜霉病(P.cubensis)，胡瓜白粉病(S.furiginea)，胡瓜藤枯病(M.melonis,D.bryoniae)，西瓜藤枯病(M.melonis,D.bryoniae)，胡瓜菌核病(S.sclerotiorum)，胡瓜碳疽病(C.lagenarium)，胡瓜褐斑病(C.cassiicora)，胡瓜黑星病(C.cucumerinum)，瓜類藤裂病(F.oxysporum f.sp.cucumerinum,F.oxysporum f.sp.meronis)，胡瓜斑點細菌病(P.syringae pv.Lachrymans)等；蔥．洋蔥病害而言，例如，蔥烟草霜霉病(P.destructor)，洋蔥葉枯病(P.herbarum)，洋蔥菌核病(S.sclerotiorum)，洋蔥灰色腐敗病(B.alli)，洋蔥白斑葉枯病(B.byssoidea,B.squamosa)，蔥黑斑病(A.porri)，洋蔥乾腐病(F.oxysporum f.sp.cepae)，蔥銹病(P.allii)等；根菜類病害而言，例如，紅蘿蔔黑葉枯病(A.dauci)，蘿蔔黑斑病(A.brassicicola)等；花卉病害而言，例如，玫瑰疫病(P.megasperma)，玫瑰白粉病(S.pannosa)，玫瑰銹病(K.rosae/japonica)，玫瑰黑星病(D.rosae)，菊褐斑病(S.chrysanthemi-indici)，菊斑點病(C.chrysanthemi)，菊白銹病(P.horiana)，萵苣烟草霜霉病(B.lactucae)，翠菊烟草霜霉病(B.lactucae)，株頭癌腫病(A.tumefaciens)等； 食用作物病害而言，例如，甘薯黑斑病(C.fimbriata)，甘薯青霉病(P.expansum)，甘薯根腐病(T.basicora)，燕麥冠銹病(P.coronata)，桑枝枯病(S.mori)，油椰子基腐病(ganoderma disease(G.boninense))，棗椰子眼點病(S.palmivora)等；小麥病害而言，例如，雪腐病(Pythium sp.,M.nivalis,S.borealis,F.nivale)，雪腐病(T.ishikariensis,T.incarnata)，赤霉病(G.zeae,F.avenaceum,F.graminearum,F.culmorum,M.nivale)，麥角病(C.purpurea)，立枯病(G.graminis)，株腐病(C.gramineum)，紋枯病(sharp eyespot(C.cereale))，白粉病(B.graminis f.sp.Tritici)，穎枯病(L.nodorum,S.nodorum)，赤銹病(P.recondita)，黑銹病(P.graminis)，黄銹病(P.striiformis)，眼紋病(P.herpotrichoides)，葉枯病(S.tritici)，黄斑病(P.tritici-repentis)，條斑病(C.gramineum)，裸黑穂病(U.nuda)，腥黑穂病(T.caries)，散黑穂病(U.agropyri)等；大麥病害而言，例如，雪腐病(Pythium sp.,S.borealis,M.nivalis,F.nivale,T.ishikariensis,T.incarnata)，赤霉病(G.zeae,M.nivale,F.avenaceum,F.graminearum,F.culmorum)，麥角病(C.purpurea)，立枯病(G.graminis,O.graminis)，條斑病(C.gramineum)，白粉病(B.graminis f sp.Hordei)，網斑病(P.teres)，斑葉病(P.graminea)，斑點病(B.sorokiniana,C.sativus)，葉燒病(C.herbarm)，雲形病(R.secaris)，黑銹病(P.graminis)，黄銹病(P.striiformis)，小銹病(P.hordei)，堅黑穂病(U.hordei)等；馬鈴薯病害而言，例如，粉狀粉痂菌(S.subterranea)，粉痂菌(S.scabies)，疫病(P.infestans)，夏疫病(A.solani)，黑痣病(R.solani)，輪腐病(C.michiganensis)，輪腐病(C.michiganensis)等； 甜菜病害而言，例如，黑根病(A.sochlioides)，葉腐病(T.cucumeris)，根腐病(T.cucumeris)，蛇眼病(P.betae)，褐斑病(C.beticora)，斑點病(R.beticora)，銹病菌(U.betae)等；豆類的病害而言，例如，菌核病(S.sclerotiorum)，大豆銹病(P.pachyrhizi)，大豆烟草霜霉病(P.manshurica)，大豆紫斑病(C.kikuchii)，大豆黑點病(D.phaseolorum var,sojae)，大豆黑痘病(E.glycines)，大豆碳腐病(M.phaseolina)，大豆黑根腐病(C.crotalariae)，落花生黑根腐病(C.crotalariae)，落花生黑澀病(M.personatum)，落花生粉痂菌(S.arachidis)，落花生黑霉病(A.niger)，落花生褐斑病(C.arachidicola)，菜豆褐斑病(C.arachidicola)，菜豆碳疽病(C.indemthianum)，菜豆根腐病(F.solani f.sp.phaseoli)，菜豆萎凋細菌病(C.flaccumfasiens)，紅豆角斑病(P.griseola)，豌豆烟草霜霉病(P.pisi)，豌豆白粉病(E.pisi)，蠶豆疫病(P.nicotianae)，蠶豆烟草霜霉病(P.viciae)，蠶豆褐斑病(A.fabae)等；蘋果病害而言，例如，白粉病(P.leucotricha)，腐爛病(V.ceratosperma)，白紋羽病(R.necatrix)，紫紋羽病(H.mompa)，黑星病(V.inaequaris)，斑點落葉病(A.mali)，花腐病(monilia病(M.mali))，碳疽病(G.cingulata)，輪紋病(Botryosphaeria sp.)，黑腐病(B.obtuse,X.campestris pv.campestris)，黑點病(M.pomi)，褐斑病(D.mali)，赤星病(G.yamadae)，蘋果膠鏽病(cedar-apple rust(G.Juniperi-virginianae))，多裂裂褶菌病(S.commune)，銀葉病(C.purpurreum)，株頭癌腫病(A.tumefaciens)，火傷病(E.amylovora)等；梨病害而言，例如，白紋羽病(R.necatrix)，黑星病(V.nashicola)， 黑斑病(A.kikuchiana)，赤星病(G.asiaticum)，白粉病(P.pyri)，輪紋病(P.piricora)，胴枯病(P.fukushii)，心腐病(L.sulphureus)，株頭癌腫病(A.tumefaciens)，火傷病(E.amylovora)等；葡萄病害而言，例如，白紋羽病(R.necatrix)，灰色霉病(B.cinerea)，烟草霜霉病(P.viticola)，白粉病(U.necator)，晚腐病(G.cingulata)，黑痘病(E.ampelina)，褐斑病(P.vitis)，銹病(P.ampelopsidis)，黑腐病(G.bidwellii,X.campestris pv.campestris))，多毛孢屬真菌藤枯病(P.menezesiana)，梨葉緣焦枯病菌病(加州病，X.fastidiosa)，株頭癌腫病(A.vitis)等；桃病害而言，例如，縮葉病(T.deformans)，灰星病(M.fructicola)，黑星病(C.carpophilum)，桃果腐病(Phomopsis sp.)，麴霉病(A.niger)，斑點病(C.beyerinckii)，株頭癌腫病(A.tumefaciens)，穿孔細菌病(X.campestris pv.pruni)等；柑桔病害而言，例如，白紋羽病(R.necatrix)，灰色霉病(B.cinerea)，黑點病(D.citri)，粉痂菌(E.fawcettii)，黑點病(G.citricarpa)，圓星病(P.beltranii)，碳疽病(C.gloeosporioides)，綠霉病(P.digitatum)，青霉病(P.italicum)，類樹舌靈芝病(G.applanatum)，媒污病(C.salicinum)，潰瘍病(X.campestris pv.citri)，頑固病(S.citri)，黃龍病(C.Liberibacter)等；樹木．花木病害而言，例如，木通白粉病(M.akebiae)，赤楊類白粉病(M.penicillata)，荷蘭榆樹病(O.ulmi)，栗胴枯病(E.parasitica)，杏胴枯病(L.persoonii)，榆類圓斑病(G.ulmi)，櫻類黑節疤病(A.morbosa)，松類落葉病(L.pinastri)，落針病(needle cast(R.kalkhoffii))，松針褐斑病(needle blight(R.kalkhoffii))，松類松針 枯病(Diplodia blight(S.sapinea))，櫻類銹病(T.asiatica/prumi-spinosae)，柳類葉銹病(M.arctica)，楊類葉銹病(M.medusae)，牡丹銹病(C.flaccidum)，櫟屬類幹邊材腐朽病(S.hirsutum)，檜根株心腐病(H.annosum)，松根株心腐病(G.lucidum)，楢茸病(A.mellea)，雲芝病(T.versicolor)，松類瘤病(C.quercum)，松類葉銹病(C.asterum)，胡桃類幹心腐病(P.igniarius)，赤松赤斑葉枯病(D.septosporum)，黑松赤斑葉枯病(D.septosporum)，櫻類幹心腐病(F.pinicora)等；草坪．牧草病害而言，例如，草皮赤燒病(P.apahanidermatum)，草坪夏斑病(M.poae)，草坪長蠕孢黴葉枯病(D.poae)，草坪錢斑病(Dollar spot，S.homoeocarpa)，草坪碳疽病(C.graminicora)，彎孢菌葉枯病(C.geniculata)，草坪大褐斑病(R.solani)，褐斑病(R.solani)，雪腐病(Pythium sp.,S.borealis,M.nivalis,F.nivale,T.ishikariensis,T.incarnata)，牧草類黑胡麻病(P.graminis)，苜蓿葉斑病(P.medicaginis)，三葉草葉斑病(P.trifolii)，牧草褐穂病(E.typhina)，苜蓿黄斑病(P.medicaginis)，苜蓿莖枯病(P.medicaginis)；其他果樹病害而言，例如，白紋羽病(R.necatrix)，梅白粉病(P.tridactyla)，梅黑星病(C.carpophilum)，柿圓星落葉病(M.nawae)，柿碳疽病(G.kaki)，柿葉枯病(P.diospyri)，柿角斑落葉病(C.kaki)，柿黑星病(F.levieri)，枇杷碳疽病(C.acutatum)，香蕉葉斑病(Black sigatoka或leaf spot，M.fijiensis/musicola)，香蕉巴拿馬病(Panama disease，F.oxysporum f.sp.cubense)，株頭癌腫病(A.tumefaciens)，芒果碳疽病(C.gloeosporioides)等；多犯性病害而言，例如，各種苗立枯病(P.ultimum，P. apahanidermatum)，各種根腐病(P.cinnamomi)，白紋羽病(R.necatrix)，腐爛病(V.ceratosperma)，半身萎凋病(V.dahlia,V.albo-atrum)，灰色霉病(B.cinerea)，菌核病(S.sclerotiorum)，白絹病(S.rolfsii)，蔬菜類立枯病(R.solani)，紫紋羽病(H.mompa)，軟腐病(E.carotovora,E.aroideae)，株頭癌腫病(A.tumefaciens)等；植物病原細菌病而言，例如，胡瓜斑點細菌病(P.syringae pv.Lachrymans)，稻褐條病(P.avenae)，稻苗立枯細菌病(P.plantarii)，稻谷枯細菌病(P.glumae)，稻葉鞘褐變病(P.fuscovaginae)，茄科青枯病(P.solanacearum)，茶赤燒病(P.syringae pv.theae)，柑桔潰瘍病(X.campestris pv.citri)，高麗菜黑腐病(X.campestris pv.campestris)，桃穿孔細菌病(X.campestris pv.pruni)，稻白葉枯病(X.oryzae)，葡萄黑腐病(X.campestris pv.campestris)，蘋果黑腐病(X.campestris pv.campestris)，蘋果火傷病(E.amylovora)，梨火傷病(E.amylovora)，軟腐病(E.aroideae,E.carotovora)，菜豆萎凋細菌病(C.flaccumfasiens)，株頭癌腫病(A.tumefaciens)，菩萄株頭癌腫病(A.vitis)，馬鈴薯粉痂菌(S.scabies)，柑桔頑固病(S.citri)，番茄潰瘍病(C.michiganensis)，馬鈴薯輪腐病(C.michiganensis)，輪腐病(C.michiganensis)，柑桔黃龍病(C.Liberibacter)等；以植物病毒為原因的病害而言，例如，可舉番茄嵌紋病(煙草嵌紋病毒)，胡瓜綠斑嵌紋病(胡瓜綠斑嵌紋病毒)，煙草莖壞疽病(煙草莖壞疽病毒)，麥類萎縮病(麥類萎縮病毒)，大麥斑葉嵌紋病(麥斑葉嵌紋病毒)，馬鈴薯塊莖褐色輪斑病(馬鈴薯掃頂病毒)，甜菜叢根病(甜菜壞疽性葉脈黄化病毒)，番茄嵌紋病(馬鈴薯病毒X)，蘋果高接病(蘋果莖凹陷病毒(Apple stem grooving virus))，蘋果高接 病(蘋果黃化葉斑病毒(Apple chlorotic leaf spot virus,ACLSV))，番茄嵌紋病(馬鈴薯病毒Y)，梅輪斑病(梅輪斑病毒)，胡瓜嵌紋病(夏南瓜(zucchini)黄斑嵌紋病毒)，蘿蔔嵌紋病(蕪菁嵌紋病毒)，大豆嵌紋病(大豆嵌紋病毒)，大麥縞萎縮病(大麥縞萎縮病毒)，大麥黄萎病(大麥黄萎病毒)，大豆矮化病(大豆矮化病毒)，草莓病毒病(草莓輕型黃邊病毒)，馬鈴薯葉捲病(馬鈴薯葉捲病毒)，稻矮化病(稻矮化病毒)，胡瓜嵌紋病(胡瓜嵌紋病毒)，苜蓿嵌紋病(苜蓿嵌紋病毒)，北地嵌紋病(麥北地嵌紋病)，稻縞葉枯病(稻縞葉枯病毒)，番茄黄化壞疽病(番茄黄化壞疽病毒)，稻萎縮病(稻萎縮病毒)，稻黑條萎縮病(稻黑條萎縮病毒)等。 For example, in the case of rice diseases, for example, S. macrospora, R. chinensis (T. viride), G. fujikuroi, and rice fever (M. grisea, P. oryzae), R. solani, C. miyabeanus, A. padwiki, E. nigrum, rice C. virens, P. glumae, P. fuscovaginae, P. avenae, P. plantarii, Lepidoptera Disease (X. oryzae), etc.; for corn diseases, for example, b. maydis, C. hetero ostrophus, E. turcicum, P. maydis, black smut (U. maydis), etc.; for tobacco diseases, for example, P. nicotianae/parasitica, P. tabacina, E. cichoracearum, C. tabacum, A. longipes (A. alternata), C. salicinum, chlorosis (O. brassicae), etc.; for tea diseases, for example, N. cinnabarina, white star disease ( E. leucospila), C.theae-sinensis, P. longiseta (P.theae), E. reticulatum, E. vexans, red burn ( P.syringae pv.theae), etc.; for cruciferous diseases, for example, P. brassicae, A. macrospora, cruciferous tobacco downy mildew (P. brassicae) ), Cruciferous Sclerotinia (S. sclerotiorum), Korean cabbage root rot (P.ling Am), T. cucumeris, C. brassicicola, C. brassiscola, cruciferous black spot (A. brassicae), Korean cabbage black rot ( X.campestris pv.campestris), etc.; for strawberry diseases, for example, P. cactorum (P. nicotianae), powdery mildew (S. macularis), carbon borer (G. cingulata), black spot (A. Alternata), snake eye disease (M. fragariae), etc.; for tomato diseases, for example, tomato late blight (P. infestans), carbon borer (C. phomoides), leaf mold (C. fulvum), spot disease (S .lycopersici), ring disease (A. Solani), ulcer disease (C. michiganensis), etc.; for Solanaceae diseases, for example, S. sclerotiorum, S. furiginea, P. vexans, Phytoplankton (M.nattrassii), S. lycopersici, S. lycopersici, P. solanacearum, P. solanacearum, etc.; For diseases, for example, P. melonis, P. cubensis, S. furiginea, M. melonis, D. bryoniae, watermelon Fujie blight (M.melonis, D.bryoniae), S. sclerotiiorum, C. lagenarium, C. cassiicora, Courgette black star disease (C. Cucumerinum), F. oxysporum f. sp. cucumerinum, F. oxysporum f. sp. meronis, P. syringae pv. Lachrymans, etc.; For onion diseases, for example, P. destructor, P. herbumum, S. sclerotiorum, onion gray spoilage (B.alli), onion leukoplakia Leaf blight (B.byssoidea, B. squamosa), onion black spot disease (A.porri), onion dry rot (F. oxysporum f.sp. cepae), onion rust (P.allii), etc.; root vegetable diseases For example, carrot black leaf blight (A. dauci), radish black spot (A. braassicicola), etc.; for flower diseases, for example, rose plague (P. megasperma), rose powdery mildew (S. pannosa) ), rose rust (K. rosae/japonica), rose scab (D. rosae), chrysanthemum brown spot disease (S. chrysanthemi-indici), chrysanthemum spot disease (C. chrysanthemi), chrysanthemum rust (P. horiana) ), lettuce tobacco downy mildew (B. lactucae), aster tobacco downy mildew (B. lactucae), head cancer disease (A. tumefaciens), etc.; For food crop diseases, for example, sweet potato black spot (C. fimbriata), sweet potato green mold (P. expansum), sweet potato root rot (T. basicora), oat rust (P. coronata), mulberry Disease (S. mori), ganoderma disease (G. boninense), date palm disease (S. palmivora), etc.; for wheat diseases, for example, snow rot (Pythium sp., M .nivalis, S. borealis, F. nivale), snow rot (T. ishikariensis, T. incarnata), scab (G. zeae, F. avenaceum, F. graminearum, F. culmorum, M. nivale), C. purpurea, G. graminis, C. gramineum, sharp eyespot (C. cereale), powdery mildew (B. graminis f.sp. Tritici), L. nodorum, S. nodorum, P. recondita, P. graminis, P. striiformis, P. herpotrichoides, leaves S. tritici, P. tritici-repentis, C. gramineum, U.nuda, T. caries, black mites Disease (U.agropyri), etc.; for barley diseases, for example, snow rot (Pythium sp., S. borealis, M. nivalis, F. nivale, T. ishikari E., T. incarnata), scab (G. zeae, M. nivale, F. avenaceum, F. graminearum, F. culmorum), ergot disease (C. purpurea), blight (G. graminis, O .graminis), C. gramineum, B. graminis f sp. Hordei, P. teres, P. graminea, B. sorokiniana, C. sativus), C. herbarm, R. secaris, P. graminis, P. striiformis, P. hordei, rickets (U. hordei), etc.; for potato diseases, for example, S. subterranea, S. scabies, P. infestans, A. solani, black R. solani, round rot (C. michiganensis), round rot (C. michiganensis), etc.; For sugar beet diseases, for example, A. sochlioides, T. cucumeris, T. cucumeris, P. betae, C. beticora , R. beticora, rust fungus (U.betae), etc.; for diseases of legumes, for example, S. sclerotiorum, soybean rust (P. pachyrhizi), soybean tobacco downy mildew (P .manshurica), soybean purpura (C. kikichii), soybean black spot disease (D. phaseolorum var, sojae), soybean black pox (E. glycines), soybean carbon rot (M.phaseolina), soybean black root rot Disease (C. crotalariae), C. crotalariae, M. personatum, S. arachidis, A. niger, groundnut brown Spot disease (C.arachidicola), C. arachidola, C. indemthianum, F. solani f. sp. phaseoli, and bean wilting bacterial disease (C. Flaccumfasiens), P. griseola, pea tobacco downy mildew (P. pisi), pea powdery mildew (E. pisi), broad bean disease (P. nicotianae), broad bean tobacco downy mildew (P. viciae) ), broad bean brown spot (A.fabae ); for apple diseases, for example, P. leucotricha, V. ceratosperma, R. necatrix, H. mompa, and scab ( V.inaequaris), A.mali, flower rot (M.mali), G. cingulata, Botryosphaeria sp., black rot (B .obtuse, X.campestris pv.campestris), black spot disease (M.pomi), brown spot disease (D.mali), brown spot disease (G.yamadae), apple rust (cedar-apple rust (G.Juniperi- Virginianae)), S.commune, C. purpurreum, A. tumefaciens, E. amylovora, etc.; for pear disease, for example , R. necatrix, V. nashicola, Black spot disease (A.kikuchiana), brown spot disease (G. asiaticum), powdery mildew (P. pyri), ring disease (P. piricora), blight (P. fukushii), heart rot (L. sulphureus ), A. tumefaciens, fire injury (E. amylovora), etc.; for grape diseases, for example, R. necatrix, B. cinerea, tobacco downy mildew Disease (P. viticola), powdery mildew (U. necator), late rot (G. cingulata), black pox (E.ampelina), brown spot (P. vitis), rust (P. ampelopsidis), black Rot (G. bidwellii, X. campestris pv. campestris)), P. menezesiana, Pear leaf blight (California disease, X. fastidiosa), head cancer (A .vitis), etc.; for peach diseases, for example, T. deformans, M. fructicola, C. carpophilum, Phomopsis sp., Phytophthora Disease (A. niger), spot disease (C. beyerinckii), plant head cancer disease (A. tumefaciens), perforated bacterial disease (X. campestris pv. pruni), etc.; for citrus diseases, for example, white feather disease (R.necatrix), gray mold (B. cinerea), black spot disease (D.citri), whitefly fungus (E.fawcet Tii), G. citricarpa, P. beltranii, C. gloeosporioides, P. digitatum, P. italicum, Phyllostachys G. applanatum, C. salicinum, ulcer disease (X. campestris pv. citri), stubborn disease (S. citri), huanglong disease (C. Liberibacter), etc.; For flowering diseases, for example, M. akebiae, M. penicillata, Dutch eucalyptus (O. ulmi), E. parasitica, dried apricot Disease (L.persoonii), G.ulmi, A. morbosa, L. pinastri, needle drop (R.kalkhoffii) )), needle blight (R. kalkhoffii), pine needles Blight (Diplodia blight (S. sapinea)), Sakura rust (T. asiatica / prumi-spinosae), Willow leaf rust (M. arctica), Poplar leaf rust (M. medusae), Peony rust (C. Flaccidum), S. hirsutum, H. annosum, G. lucidum, A. mellea, Yunzhi Disease (T.versicolor), pine sarcoma (C. quercum), pine leaf rust (C. asterum), walnut heart rot (P. igniarius), red pine leaf spot blight (D. septosporum) , black pine leaf blight (D.septosporum), sakura dry heart rot (F. pinicora), etc.; lawn. For pasture diseases, for example, P. apahanidermatum, M. poae, D. poae, and lawn spot, S .homoeocarpa), C. graminicora, C. geniculata, R. solani, R. solani, snow rot ( Pythium sp., S. borealis, M. nivalis, F. nivale, T. ishikariensis, T. incarnata), forage grass black flax (P. graminis), eucalyptus leaf spot (P. medicaginis), clover leaf spot (P.trifolii), E.typhina, P. medicaginis, P. medicaginis, and other fruit tree diseases, for example, white feather disease (R. Necatrix), P.tridactyla, C. carpophilum, M. nawae, G. kaki, persimmon leaf blight (P. Diospyri), C. kaki, F. levieri, C. acutatum, banana leaf spot (Black sigatoka or leaf spot, M. fijiensis/musicola ), Banana disease, F. oxysporum f.sp.cubense, Head canker (A. tumefaciens), mango anthrax disease (C.gloeosporioides) and the like; trespass diseases, for example, various seedling blight (P.ultimum, P. Apahanidermatum), various root rot (P. cinnamomi), R. necatrix, rot disease (V. ceratosperma), half body wilt (V. dahlia, V. albo-atrum), gray mold ( B. cinerea), S. sclerotiorum, S. rolfsii, R. solani, H. mompa, soft rot (E. carotovora) , E. aroideae), A. tumefaciens, etc.; for plant pathogenic bacterial diseases, for example, P. syringae pv. Lachrymans, P. avenae, rice P. plantarii, P. glumae, P. fuscovaginae, P. solanacearum, and tea brash (P. Syringae pv.theae), citrus canker (X. campestris pv. citri), cabbage black rot (X. campestris pv. campestris), peach perforated bacterial disease (X. campestris pv. pruni), rice bacterial blight (X.oryzae), grape black rot (X. campestris pv. campestris), apple black rot (X. campestris pv. campestris), apple fire injury (E. amylovora), pear fire injury (E. amylovora), Soft rot (E.aroideae, E. carotovora) Bacterial disease (C. flaccumfasiens), A. tumefaciens, A. vitis, S. scabies, S. citri, Tomato ulcer disease (C. michiganensis), potato round rot (C. michiganensis), round rot (C. michiganensis), citrus Huanglong disease (C. Liberibacter), etc.; for diseases caused by plant viruses, for example It can be exemplified by tomato mosaic disease (tobacco mosaic virus), courgette green leaf mosaic disease (coot leaf green mosaic virus), tobacco stem gangrene (tobacco stem gangrene virus), wheat atrophy disease (wheat atrophy virus) , barley leaf mosaic disease (Maize leaf mosaic virus), potato tuber brown round spot disease (potato sweeping virus), beet root disease (beet gangrenous vein yellowing virus), tomato mosaic disease (potato virus) X), apple high disease (Apple stem grooving virus), apple high Disease (Apple chlorotic leaf spot virus (ACLSV)), tomato mosaic disease (potato virus Y), plum round spot disease (melan spot virus), courgette mosaic disease (zucchini) Macular mosaic virus), radish mosaic disease (phthalocyanin mosaic virus), soybean mosaic disease (soy mosaic virus), barley atrophy (barley atrophy virus), barley verticillium (barley yellow wilt virus), Soybean dwarf disease (soybean dwarf virus), strawberry virus disease (strawberry light yellow edge virus), potato leaf curl disease (potato leaf virus), rice dwarf disease (rice dwarf virus), courgette mosaic disease (courgette) Mosaic virus), 苜蓿 苜蓿 苜蓿 (苜蓿 病毒 )), 地 嵌 ( 麦 麦 麦 ( ( ( ( ( ( ( ( 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北 北Yellow gangrene virus, rice atrophy (rice atrophy virus), rice black stripe atrophy (rice black atrophic virus).

又，本發明的植物病害防治劑是，對耐性菌也有優異的殺菌效果。耐性菌而言，可舉對甲基多保淨(thiophanate methyl)，免賴得(benomyl)，貝芬替(Carbendazim)等的苯并咪唑系殺菌劑表現耐性的灰色霉病菌(Botrytis cinerea)及對甜菜褐斑病菌(Cercosporabeticola)，蘋果黑星病菌(Venturia inaequalis)，梨黑星病菌(Venturia nashicola)；對二甲醯亞胺系殺菌劑(例如，免克寧(Vinclozolin)，撲滅寧(procymidone)，依普同(Iprodione))表現耐性的灰色霉病菌(Botrytis cinerea)等。 Further, the plant disease controlling agent of the present invention has an excellent bactericidal effect against resistant bacteria. Examples of the resistant bacteria include Botrytis cinerea which exhibits resistance to a benzimidazole-based fungicide such as thiophanate methyl, benomyl, and Carbendazim. Cercosporabeticola, Venturia inaequalis, Venturia nashicola; dimethylimine-based fungicides (eg, Vinclozolin, procymidone) ), Iprodione, which exhibits tolerance to Botrytis cinerea and the like.

以本發明的一般式(I)表示的噻唑羧醯胺衍生物或其鹽類做為有效成分的植物病害防治劑是，對水田作物，旱田作物，果樹，野菜，其他的作物及花卉等為害的前述病害有顯著的防治效果，可配合預料有病害的發生的時期，在病害的發生前或確認發生時將育苗施設，水田，旱田，果樹，野菜，其他的作物，花卉等的種子，水田水，莖葉或土壤等的栽培載體等處理，則可達 成本發明的植物病害防治劑所期望的效果。其中，尤以處理作物，花卉等的育苗土壤，移植時的植穴土壤，株頭，灌漑水，水稻的箱處理，水耕栽培的栽培水等，經由或不經由土壤而由根吸收本發明化合物，利用所謂浸透移行性的施用為理想使用形態。 The plant disease controlling agent which comprises the thiazole carboamide derivative represented by the general formula (I) of the present invention or a salt thereof as an active ingredient is harmful to paddy crops, dry crops, fruit trees, wild vegetables, other crops and flowers. The above-mentioned diseases have significant control effects, and can be used in conjunction with the expected occurrence of disease, seedlings, paddy fields, dry fields, fruit trees, wild vegetables, other crops, flowers, etc. before the occurrence of the disease or when the occurrence of the disease occurs, paddy fields. Water, stems, leaves, soil, etc. The desired effect of the plant disease control agent of the invention. Among them, in particular, the treatment of crops, flowers, and the like, the planting soil, the plant head, the irrigation water, the rice box treatment, the hydroponic cultivation water, etc., are absorbed by the roots through or without the soil. The compound, which is applied by so-called impregnation and migration, is an ideal use form.

可使用本發明的植物病害防治劑的有用植物並無特別的限定，例如可舉穀類(例如水稻，大麥，小麥，黑麥，燕麥，玉米等)，豆類(大豆，紅豆，蠶豆，豌豆，菜豆，花生，等)；果樹、水果類(蘋果，柑桔類，梨，葡萄，桃，梅，櫻桃，胡桃，栗，杏仁，香蕉，等)，蔬菜類(甘藍菜，番茄，菠菜，青花菜，萵苣，洋蔥，蔥，青椒，茄子，草莓，胡椒，秋葵等)，根菜類(胡蘿蔔，馬鈴薯，甘薯，芋頭，蘿蔔，蕪箐，蓮藕，牛蒡，大蒜等)，加工用作物類(棉，麻，甜菜，啤酒花，甘蔗，甜菜，橄欖，橡膠樹，咖啡，菸草，茶，等)；瓜類(南瓜，胡瓜，西瓜，東方甜瓜，哈蜜瓜，等)，牧草類(果園草，高粱，梯牧草(timothy)，三葉草，苜蓿，等)，草坪類(高麗芝，翦股穎，等)；香料等觀賞作物(薰衣草，迷迭香，千里香，荷蘭芹，胡椒，生薑，等)；花卉類(菊，薔薇，康乃馨，蘭，等)，庭園木(銀杏，櫻類，桃葉珊瑚等)，林木(冷杉類，魚鱗雲杉類，松樹，羅漢柏，杉，檜，尤加利等)等的植物。 Useful plants which can use the plant disease controlling agent of the present invention are not particularly limited, and examples thereof include cereals (for example, rice, barley, wheat, rye, oats, corn, etc.), beans (soybeans, red beans, broad beans, peas, and kidney beans). , peanuts, etc.); fruit trees, fruits (apples, citrus, pears, grapes, peaches, plums, cherries, walnuts, chestnuts, almonds, bananas, etc.), vegetables (cabbage, tomatoes, spinach, broccoli) , lettuce, onion, onion, green pepper, eggplant, strawberry, pepper, okra, etc.), root vegetables (carrots, potatoes, sweet potatoes, taro, radish, alfalfa, lotus root, burdock, garlic, etc.), processed for use (mesh) , hemp, beet, hops, sugar cane, beets, olives, rubber trees, coffee, tobacco, tea, etc.); melons (squash, courgette, watermelon, oriental melon, honeydew melon, etc.), pasture (orchard grass, sorghum) , Timothy, shamrock, sorghum, etc.), turf (Gao Lizhi, 翦 颖, etc.); ornamental crops such as spices (lavender, rosemary, thyme, parsley, pepper, ginger, etc.) ); flowers (daisy, 蔷) , Carnations, orchids, etc.), Garden wood (ginkgo, cherry class, peach coral, etc.), trees (fir class, class scale spruce, pine, cypress, cedar, cypress, eucalyptus, etc.) and other plants.

上述「植物」也包含，將對異唑草酮(isoxaflutole)等的HPPD抑制劑，咪唑乙煙酸(imazethapyr)，噻磺隆(thifensulfuron-methyl)等的ALS抑制劑，嘉磷塞(glyphosate)等的EPSP合成酶抑制劑，固殺草(glufosinate)等的麩醯胺酸合成酶抑制劑，西殺草(sethoxydim)等的乙醯輔酶A羧化酶抑制劑，溴苯腈 (bromoxynil)，汰克草(dicamba)，2,4-D等的除草劑的耐性，以古典育種法，或基因重組技術而賦予耐性的植物。 The above "plants" are also included and will be different HPPD inhibitors such as isoxaflutole, ALS inhibitors such as imazethapyr, thifensulfuron-methyl, and EPSP synthase inhibitors such as glyphosate Brady acid synthase inhibitor such as glufosinate, acetaminophen coenzyme A carboxylase inhibitor such as sethoxydim, bromoxynil, dicamba, 2, 4 Tolerance of herbicides such as -D, plants that confer tolerance by classical breeding methods or genetic recombination techniques.

以古典育種法而賦予耐性的「植物」的例而言，可舉對咪唑乙煙酸等的二氮雜戊烯類(imidazolinone)系ALS抑制型除草劑有耐性的油菜，小麥，向日葵，稻，以「Clear field」(登錄商標)的商品名已經在上市。同樣以古典育種法對噻磺隆等的磺醯脲系ALS抑制型除草劑有耐性的大豆，以「STS大豆」的商品名已經在上市。同樣做為以古典育種法對三酮肟(trione oxime)系，芳氧基苯氧丙酸系除草劑等的乙醯輔酶A羧化酶抑制劑賦予耐性的植物的例有SR玉米等。 In the case of the "plant" which imparts tolerance to the classical breeding method, rapeseed, wheat, sunflower, and rice which are resistant to imidazolinone-based ALS-inhibiting herbicide such as imidazolium acid, etc. The product name of "Clear field" (registered trademark) is already on the market. Soybeans which are resistant to sulfonylurea-based ALS-inhibiting herbicides such as thiasulfuron by classical breeding methods are already on the market under the trade name "STS Soybean". An example of a plant which imparts tolerance to an acetamidine coenzyme A carboxylase inhibitor such as a trione oxime-based or an aryloxyphenoxypropionic acid herbicide by the classical breeding method is SR corn or the like.

又對乙醯輔酶A羧化酶抑制劑賦予耐性的植物在Proceedings of the National Academy of Sciences of the United States of America(Proc.Natl.Acad.Sci.USA)87卷，7175至7179頁(1990年)等有報告。又對乙醯輔酶A羧化酶抑制劑有耐性的變異乙醯輔酶A羧化酶在Weed Science 53卷，728至746頁(2005年)等有報告，將這種變異乙醯輔酶A羧化酶基因以基因重組技術導入於植物或將有關賦予抵抗性的變異導入於植物乙醯輔酶A羧化酶，而可做出對乙醯輔酶A羧化酶抑制劑有耐性的植物，再者，嵌合修復術(chimeraplasty)(Gura T．1999．Repairing the Genome’s Spelling Mistakes．Science 285：316-318．)所代表的將導入鹼基取代變異的核酸導入於植物細胞內而在植物的乙醯輔酶A羧化酶基因或ALS基因等導入部位特異性的胺基酸取代變異，可做出對乙醯輔酶A羧化酶抑制劑或ALS抑制劑等有耐性的植物，對這些植物也可使用本發明的植物病害防治劑。 Plants that confer tolerance to an acetoin A carboxylase inhibitor are described in Proceedings of the National Academy of Sciences of the United States of America (Proc. Natl. Acad. Sci. USA), vol. 87, pp. 7175-7179 (1990) ) and so on. The variant acetamyl-CoA carboxylase which is resistant to the acetaminophen coenzyme A carboxylase inhibitor is reported in Weed Science, Vol. 53, pp. 728-746 (2005), and the variant acetamidine coenzyme A is carboxylated. The enzyme gene is introduced into the plant by genetic recombination technology or introduced into the plant acetamyl coenzyme A carboxylase, and the plant can be made tolerant to the acetaminophen coenzyme A carboxylase inhibitor. Chimeraplasty (Gura T. 1999. Repairing the Genome's Spelling Mistakes. Science 285: 316-318.), which introduces a nucleic acid into which a base substitution mutation is introduced, into a plant cell Amino acid substitution mutation specific for the introduction site of A carboxylase gene or ALS gene can be used to make plants resistant to acetaminophen coenzyme A carboxylase inhibitors or ALS inhibitors, and these plants can also be used. The plant disease control agent of the invention.

再者，在基因重組植物呈現的毒素，可舉來源於仙人掌桿菌(Bacillus cereus)，日本甲蟲芽孢桿菌(Bacillus popilliae)的殺蟲性蛋白；來源於蘇力菌(Bacillus thuringiensis)的Cry1Ab，Cry1Ac，Cry1F，Cry1Fa2，Cry2Ab，Cry3A，Cry3Bb1或Cry9C等的δ-內毒素(endotoxin)，VIP1，VIP2，VIP3或VIP3A等的殺蟲蛋白；來源於線蟲的殺蟲蛋白；蝎子毒素，蜘蛛毒素，蜂毒素或昆蟲特異性的神經毒素等動物所產生的毒素；絲狀菌類毒素；植物凝集素(plant lectin)；凝集素(agglutinin)；胰蛋白酶抑制劑，絲胺酸蛋白酶(serine protease)抑制劑，馬鈴薯儲藏蛋白(patatin)，血清胱蛋白(cystatin)，木瓜蛋白酶抑制劑等的蛋白酶抑制劑；蓖麻毒素(ricin)，玉米核糖體抑制蛋白RIP，雞母珠毒蛋白(abrin)，絲瓜子蛋白(luffin)，肥皂草毒蛋白(saporin)，異株瀉根毒蛋白(bryodin)等的核醣體抑制蛋白(RI)；3-羥基類固醇氧化酶，蛻皮類固醇-UDP-糖基轉移酶(glycosyltransferase)，膽固醇氧化酶等的類固醇代謝酶；蜕皮激素(ecdysone)抑制劑；HMG-乙醯輔酶A還原酶；鈉通道，鈣通道抑制劑等的離子通道抑制劑；保幼激素酯酶(juvenile hormone esterase)；利尿激素受體；芪合成酶(stilbene synthase)；聯苄合成酶；幾丁質分解酶(chitinase)；葡聚糖酶(glucanase)等。 Further, the toxin present in the recombinant plant may be an insecticidal protein derived from Bacillus cereus, Bacillus popilliae, Cry1Ab derived from Bacillus thuringiensis, Cry1Ac, Δ-endotoxin of Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, insecticidal protein of VIP1, VIP2, VIP3 or VIP3A; insecticidal protein derived from nematodes; scorpion toxin, spider toxin, melittin Or toxins produced by animals such as insect-specific neurotoxins; filamentous toxoids; plant lectin; agglutinin; trypsin inhibitors, serine protease inhibitors, potatoes Protease inhibitors such as patatin, cystatin, papain inhibitors; ricin, corn ribosome inhibitor RIP, abrin, and loofah protein Luffin), saporin, ribosome inhibitory protein (RI), etc.; 3-hydroxysteroid oxidase, ecdysteroid UD P-glycosyltransferase, cholesterol oxidase and other steroid metabolism enzymes; ecdysone inhibitor; HMG-acetamide coenzyme A reductase; sodium channel, calcium channel inhibitor and other ion channel inhibitors; Juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; glucanase.

又做為在這種基因重組植物呈現的毒素，也包含Cry1Ab，Cry1Ac，Cry1F，Cry1Fa2，Cry2Ab，Cry3A，Cry3Bb1，Cry9C，Cry34Ab或Cry35Ab等的δ-內毒素蛋白，VIP1，VIP2，VIP3或VIP3A等的殺蟲蛋白的混合毒素，有一部分缺失的毒素，改質的毒素。混合毒素是使用重組技術，將這些蛋白的不同區域重新組合而做出。一部分缺失的毒素而言，已知有缺失胺基酸配 列的一部分的Cry1Ab。改質的毒素是，天然型的毒素的胺基酸中有1個或多數個被取代。 Also used as a toxin present in such genetically recombinant plants, also including δ-endotoxin proteins such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, Cry9C, Cry34Ab or Cry35Ab, VIP1, VIP2, VIP3 or VIP3A, etc. The mixed toxin of the insecticidal protein has a portion of the missing toxin and a modified toxin. Mixed toxins are made using recombinant techniques to recombine different regions of these proteins. For some of the missing toxins, a missing amino acid is known. Part of the column of Cry1Ab. The modified toxin is one or more of the amino acids of the natural toxin.

這些毒素的例及能合成這些毒素的重組植物是，在EP-A-0 374 753，WO 93/07278，WO 95/34656，EP-A-0 427529，EP-A-451 878，WO 03/052073等有說明。 Examples of such toxins and recombinant plants capable of synthesizing these toxins are in EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529, EP-A-451 878, WO 03/ 052073 and so on.

本發明的植物病害防治劑為了要防治各種病害，可用原本的狀態，或以水等適宜稀釋，或懸浮的狀態，將對病害防治有效的量對該病害預料會發生的植物使用即可，例如對在果樹，穀類，野菜等發生的病害則在莖葉部撒佈之外，將種子浸漬於藥劑，種子粉衣，過氧化鈣處理等的種子處理，土壤全層混合，條施(furrow application)，床土混合，育苗盤苗處理，植穴處理，株頭處理，表面施肥，稻苗箱處理，水面施用等，土壤等處理而由根吸收也可以。此外，對在培養液(水耕)栽培的培養液的施用，燻煙或是樹幹注入等的使用也可以。 In order to prevent and control various diseases, the plant disease control agent of the present invention may be used in the original state, or in a state suitable for dilution or suspension in the form of water, and the amount effective for disease control may be used for the plant in which the disease is expected to occur, for example, In the case of diseases such as fruit trees, cereals, wild vegetables, etc., the seeds are immersed in the seeds, the seed powder, the calcium peroxide treatment, etc., and the whole soil layer is mixed, and the furrow application is applied. ), bed soil mixing, seedling seedling treatment, planting point treatment, plant head treatment, surface fertilization, rice seedling box treatment, water surface application, etc., soil treatment, etc. can also be absorbed by roots. In addition, the application of the culture solution cultured in the culture solution (hydroponic cultivation), the use of fumigation or trunk injection may be used.

種子處理的方法而言，例如，可舉將液狀或固體狀的製劑稀釋或不稀釋而以液體狀態浸漬種子使藥劑滲透的方法，固形製劑或液狀製劑與種子混合，粉衣處理而在種子的表面附著的方法，樹脂，聚合物等的附著性的載體混合而在種子上覆蓋的方法，在種植同時在種子附近撒佈的方法等。 The method of seed treatment may, for example, be a method in which a liquid or solid preparation is diluted or not diluted to impregnate a seed in a liquid state to infiltrate the agent, and the solid preparation or the liquid preparation is mixed with the seed, and the powder coating is treated. A method of adhering the surface of the seed, a method of mixing the carrier of adhesion of a resin or a polymer, and coating on the seed, a method of spreading in the vicinity of the seed while planting, or the like.

要做種子處理的「種子」就是，指用於植物的繁殖的栽培初期的植物體，例如，種子之外，可舉球根，塊莖，種薯，株芽，繁殖體(propagule)，鱗莖，或插支栽培用的營養繁殖用的植物體。 The "seed" to be seeded is the plant body at the beginning of cultivation for plant reproduction, for example, seeds, bulbs, tubers, seed potatoes, plant buds, propagules, bulbs, or A plant for vegetative propagation for inoculation cultivation.

實施本發明的使用方法時的植物的「土壤」或「栽培載體」就是，指用於栽培作物的支持物，特別是使其生根的支持物，材 質並無特別的限制，但只要植物能生育的材質即可，所謂土壤，育苗床，水等也可以，具體的素材而言，例如可舉，砂，浮石，蛭石，矽藻土，洋菜，凝膠狀物質，高分子物質，岩綿，玻璃綿，木材碎塊，樹皮等也可以。 The "soil" or "cultivation carrier" of a plant when the method of use of the present invention is carried out means a support for cultivating a crop, in particular, a support for rooting thereof. There is no particular limitation on the quality, but the material that can be grown by the plant can be used. The so-called soil, seedling bed, water, etc. can also be used. For specific materials, for example, sand, pumice, vermiculite, diatomaceous earth, and ocean Vegetables, gelatinous substances, high molecular substances, rock wool, glass wool, wood fragments, bark, etc. can also be used.

對作物莖葉部等的撒佈方法而言，可舉將乳劑，可流動性劑等的液體製劑或水和劑或顆粒水和劑等的固形製劑以水適宜稀釋，而撒佈的方法，或撒佈粉劑的方法等。 For the method of spreading the stems and the like of the crops, a liquid preparation such as an emulsion or a flowable agent, or a solid preparation such as a water and a granule water and a granule, and a solid preparation such as a granule water and a solvent may be appropriately diluted with water, and a method of spreading may be employed. Or a method of spreading powder, etc.

對土壤的施用方法而言，例如，可舉將液體製劑以水稀釋或不稀釋而在植物體的株頭或育苗用苗床等施用的方法，將粒劑在植物體的株頭或用於育苗的苗床等撒佈的方法，在播種前或移植前將粉劑，水和劑，顆粒水和劑，粒劑等撒佈而與土壤全體混合的方法，播種前或植物體種植前在植穴，植溝等將粉劑，水和劑，顆粒水和劑，粒劑等撒佈的方法等。 For the method of applying the soil, for example, a method in which the liquid preparation is applied to the plant head or the nursery seedbed or the like by diluting or not diluting the liquid is used, and the granule is applied to the plant head or used for seedling growth. The method of spreading the seedling bed, etc., before the sowing or before the transplant, the powder, the water and the agent, the granule water and the agent, the granules, etc. are mixed with the whole soil, before planting or before planting, A method of spreading powder, water and agent, granule water and agent, granules, etc., etc., such as planting ditch.

對水稻的育苗箱的施用方法而言，劑型是，例如雖在播種時施用，綠化期施用，移植時施用等的施用時期而有不同的情況，但施用粉劑，顆粒水和劑，粒劑等的劑型即可。與培養土的混合也可適用，培養土與粉劑，顆粒水和劑或粒劑等的混合，例如，可與床土混合，與覆土混合，與培養土全體混合等。只將培養土與各種製劑成層狀而交替施用也可以。 For the method of applying the rice seedling box, the dosage form is different, for example, although it is applied at the time of sowing, application during greening, application at the time of transplantation, etc., but powder, water, agent, granule, etc. are applied. The dosage form is OK. Mixing with the culture soil is also applicable, and mixing of the culture soil with the powder, the granule water and the granules, and the like, for example, it can be mixed with the bed soil, mixed with the soil, and mixed with the entire culture soil. It is also possible to apply the culture soil and the various preparations in layers instead of each other.

在水田的施用方法而言，將投入劑(jumbo formulation)，小包裝劑，粒劑，顆粒水和劑等的固形製劑，可流動性，乳劑等的液體狀製劑，通常是，在滿水狀態的水田撒佈。其他，在插秧時，將適當的製劑直接，或，與肥料混合而在土壤上撒佈、注入也可以。又，也可在水頭或灌漑装置等的水流入於水田的源頭利用乳 劑，可流動性等的藥液，隨供水同時施用而省工。 In the method of applying the paddy field, a solid preparation such as a jumbo formulation, a small package, a granule, a granule water, and the like, a liquid preparation such as a fluidity, an emulsion, or the like, usually, in a state of full water The paddy field is strewn. Others, in the case of transplanting, the appropriate preparation may be directly or mixed with the fertilizer to be spread and injected on the soil. In addition, it is also possible to use water such as a water head or a filling device to flow into the source of the paddy field. The liquid medicine such as the agent and the fluidity can be saved with the simultaneous application of the water supply.

旱田作物時，在播種至育苗期中，可處理種子或接近植物體的栽培載體等。在旱田直接播種的植物時，除了種子的直接處理之外，在栽培中的植物的株頭的處理為合適。可使用粒劑撒佈處理或以水稀釋或不稀釋的藥劑以液狀灌注處理等。將粒劑與播種前的栽培載體混合後播種，也是理想的處理。 In the case of a dry crop, the seed or the cultivation carrier close to the plant body can be treated during the sowing to the seedling stage. In the case of plants directly sown in dry fields, in addition to the direct treatment of the seeds, the treatment of the heads of the plants under cultivation is suitable. A liquid granulation treatment or the like may be used, which is granulated or treated with water diluted or undiluted. It is also an ideal treatment to mix the granules with the cultivation carrier before sowing and to sow.

對要移植的栽培植物的播種，育苗期的處理而言，除了種子的直接處理之外，對育苗用苗床，做成液狀的藥劑的灌注處理或粒劑的撒佈處理為理想。又，定植時將粒劑在植穴處理，與移植場所周圍的栽培載體混合也是理想的處理。 For the seeding of the cultivated plants to be transplanted, in the seedling stage, in addition to the direct treatment of the seeds, it is preferable to perform the infusion treatment of the liquid medicine or the spreading treatment of the granules on the seedling bed for seedlings. Moreover, it is also an ideal treatment to mix the granules at the acupoints during planting and to mix with the cultivation carrier around the transplant site.

本發明的植物病害防治劑是，一般是成為便於以農藥製劑上的常法使用的形狀的製劑而使用。 The plant disease controlling agent of the present invention is generally used as a preparation which is easy to use in a conventional method on a pesticide preparation.

即，本發明的一般式(I)表示的噻唑羧醯胺衍生物或其鹽類是，將其與適當的不活性載體，或必要時與佐劑一起以適當比率配合而溶解，分離，懸浮，混合，含浸，吸附或附著成為適宜的劑型，例如懸浮劑，乳劑，液劑，水和劑，顆粒水和劑，粒劑，粉劑，錠劑，小包裝劑等的製劑而使用即可。 That is, the thiazole carboquinone derivative represented by the general formula (I) of the present invention or a salt thereof is dissolved, separated, suspended in an appropriate ratio with an appropriate inactive carrier or, if necessary, an adjuvant. The mixture, the impregnation, the adsorption or the attachment may be used in a suitable dosage form such as a suspension, an emulsion, a liquid, a water and a granule, a granule water and a granule, a granule, a powder, a tablet, a small package, or the like.

本發明的組成物(植物病害防治劑)是，可含有除了有效成分之外必要時在農藥製劑通常使用的添加成分。這種添加成分而言，可舉固體載體，液體載體等的載體，界面活性劑，分散劑，濕潤劑，結合劑，黏著賦予劑，增黏劑，著色劑，擴展劑，展著劑，抗凍劑，抗結塊劑，崩壞劑，分解防止劑等。其他有必要時，將防腐劑，植物片等做為添加成分而使用也可以。這些添加成分可以單獨使用，或，2種以上組合使用也可以。 The composition (plant disease controlling agent) of the present invention may contain an additive component which is usually used in a pesticide preparation, if necessary in addition to the active ingredient. Examples of such an additive component include a solid carrier, a carrier such as a liquid carrier, a surfactant, a dispersing agent, a wetting agent, a binder, an adhesion-imparting agent, a tackifier, a coloring agent, an extender, a spreading agent, and an anti-drug. Freezing agent, anti-caking agent, breaker, decomposition inhibitor, etc. If necessary, preservatives, plant pieces, etc. may be used as an additive component. These additional components may be used singly or in combination of two or more.

固體載體而言，例如可舉石英，黏土，高嶺石，葉蠟石，絲雲母，滑石，皂土，酸性黏土，鎂鋁海泡石，沸石，矽藻土等的天然礦物類，碳酸鈣，硫酸銨，硫酸鈉，氯化鉀等的無機鹽類，合成矽酸，合成矽酸鹽，澱粉，纖維素，植物粉末(例如，鋸木屑，椰子殼，玉米穗軸，菸草莖等)等的有機固體載體，聚乙烯，聚丙烯，聚氯化亞乙烯等的塑膠載體，尿素，無機空心物體，塑膠空心物體，燻化氧化矽(fumed silica，白碳)等。這些可以單獨使用也可以，或2種以上混合而使用也可以。 Examples of the solid carrier include quartz, clay, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, magnesium aluminum sepiolite, zeolite, diatomaceous earth, and the like, calcium carbonate, Inorganic salts such as ammonium sulfate, sodium sulfate, potassium chloride, etc., synthetic tannic acid, synthetic citrate, starch, cellulose, plant powder (for example, sawdust, coconut shell, corn cob, tobacco stem, etc.) Organic solid carrier, polyethylene, polypropylene, polyvinyl chloride and other plastic carriers, urea, inorganic hollow objects, plastic hollow objects, fumed silica (white carbon). These may be used alone or in combination of two or more.

液體載體而言，例如可舉甲醇，乙醇，丙醇，異丙醇，丁醇等的一價醇類，例如乙二醇，二乙二醇，丙二醇，己二醇，聚乙二醇，聚丙二醇，甘油等多元醇類的醇類，例如丙二醇醚等多醇化合物類，例如丙酮，甲基乙基酮，甲基異丁基酮，二異丁基酮，環己酮等的酮類，例如乙基醚，二烷，乙二醇單乙基醚，二丙基醚，四氫呋喃等的醚類，例如正石蠟，環烷烴，異石蠟，煤油，礦油等的脂肪族烴類，例如苯，甲苯，二甲苯，溶劑石腦油，烷基萘等的芳族烴類，例如二氯甲烷，三氯甲烷，四氯化碳等鹵化烴類，例如乙酸乙酯，酞酸二異丙酯，酞酸二丁酯，酞酸二辛酯，己二酸二甲酯等的酯類，例如γ-丁內酯等的內酯類，例如二甲基甲醯胺，二乙基甲醯胺，二甲基乙醯胺，N-烷基吡咯啶酮等的醯胺類，例如乙腈等的腈類，例如二甲基亞碸等的硫化合物，例如大豆油，菜籽油，棉籽油，蓖麻油等的植物油類，水等。這些單獨使用也可以，或2種以上組合使用也可以。 The liquid carrier may, for example, be a monovalent alcohol such as methanol, ethanol, propanol, isopropanol or butanol, such as ethylene glycol, diethylene glycol, propylene glycol, hexanediol, polyethylene glycol, poly An alcohol of a polyhydric alcohol such as propylene glycol or glycerin, for example, a polyol compound such as propylene glycol ether, for example, a ketone such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone or cyclohexanone. E.g. ethyl ether, two An ether such as an alkane, an ethylene glycol monoethyl ether, a dipropyl ether or a tetrahydrofuran, such as an aliphatic hydrocarbon such as a paraffin wax, a cycloalkane, an isoparaffin, a kerosene or a mineral oil, such as benzene, toluene or xylene. Solvent naphtha, aromatic hydrocarbons such as alkylnaphthalene, such as dichloromethane, chloroform, halogenated hydrocarbons such as carbon tetrachloride, such as ethyl acetate, diisopropyl phthalate, dibutyl phthalate An ester such as dioctyl phthalate or dimethyl adipate, such as a lactone such as γ-butyrolactone, such as dimethylformamide, diethylformamide, dimethylacetamide. A guanamine such as an amine or an N-alkylpyrrolidone, for example, a nitrile such as acetonitrile, or a sulfur compound such as dimethyl hydrazine, such as soybean oil, rapeseed oil, cottonseed oil, or vegetable oil such as castor oil. , water, etc. These may be used alone or in combination of two or more.

做為分散劑或濕展劑使用的界面活性劑而言，例如可舉例如脂肪酸去水山梨醇酯，脂肪酸聚氧乙烯去水山梨醇酯， 脂肪酸蔗糖酯，脂肪酸聚氧乙烯酯類，樹脂酸聚氧乙烯酯類，脂肪酸聚氧乙烯二酯，聚氧乙烯烷基醚，聚氧乙烯烷芳基醚，聚氧乙烯烷苯基醚，聚氧乙烯二烷苯基醚，聚氧乙烯烷苯基醚甲醛縮合物，聚氧乙烯聚氧丙烯崁段共聚物，聚氧苯乙烯聚氧乙烯崁段共聚物，烷聚氧乙烯-聚丙烯崁段共聚物醚，聚氧乙烯烷基胺，聚氧乙烯脂肪酸醯胺，聚氧乙烯脂肪酸雙苯基醚，聚伸烷基苄基苯基醚，聚氧伸烷基苯乙烯基苯基醚，乙炔二醇，聚氧伸烷基附加乙炔二醇，聚氧乙烯醚型矽樹脂，酯型矽樹脂，氟系界面活性劑，聚氧乙烯蓖麻油，聚氧乙烯硬化蓖麻油等的非離子性界面活性劑，烷基硫酸鹽，聚氧乙烯烷基醚硫酸鹽，聚氧乙烯烷基苯基醚硫酸鹽，聚氧乙烯苯乙烯苯基醚硫酸鹽，烷苯基磺酸鹽，烷基芳基磺酸鹽，木質素磺酸鹽，烷基硫代琥珀酸鹽，萘基磺酸鹽，烷基萘基磺酸鹽，萘基磺酸的甲醛縮合物的鹽，烷基萘基磺酸的甲醛縮合物的鹽，脂肪酸鹽，多羧酸鹽，聚丙烯酸鹽，N-甲基-脂肪酸肌胺酸鹽，樹脂酸鹽，聚氧乙烯烷基醚磷酸鹽，聚氧乙烯烷基苯基醚磷酸鹽等的陰離子性界面活性劑，月桂基胺鹽酸鹽，硬脂基胺鹽酸鹽，油基胺鹽酸鹽，硬脂基胺乙酸鹽，硬脂基胺丙胺乙酸鹽，氯化烷基三甲基銨，烷基二甲基氯化苯二甲烴銨等的烷基胺鹽的陽離子性界面活性劑，胺基酸型或甜菜鹼型的兩性界面活性劑等。這些界面活性劑可以單獨或2種以上組合使用。 Examples of the surfactant used as the dispersing agent or the wet spreading agent include, for example, fatty acid sorbitan ester, fatty acid polyoxyethylene sorbitan ester, Fatty acid sucrose esters, fatty acid polyoxyethylene esters, resin acid polyoxyethylene esters, fatty acid polyoxyethylene diesters, polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl phenyl ethers, poly Oxyethylene dialkyl phenyl ether, polyoxyethylene alkyl phenyl ether formaldehyde condensate, polyoxyethylene polyoxypropylene oxime copolymer, polyoxystyrene polyoxyethylene oxime copolymer, alkoxy propylene-polypropylene oxime Segment copolymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid decylamine, polyoxyethylene fatty acid bisphenyl ether, polyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, Non-ionic properties of acetylene glycol, polyoxyalkylene alkyl acetylene glycol, polyoxyethylene ether type oxime resin, ester type oxime resin, fluorine-based surfactant, polyoxyethylene castor oil, polyoxyethylene hardened castor oil, etc. Surfactant, alkyl sulfate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, polyoxyethylene styrene phenyl ether sulfate, alkyl benzene sulfonate, alkyl aromatic Sulfonate, lignosulfonate, alkylthiosuccinate, naphthylsulfonic acid Salt, alkylnaphthylsulfonate, salt of formaldehyde condensate of naphthylsulfonic acid, salt of formaldehyde condensate of alkylnaphthylsulfonic acid, fatty acid salt, polycarboxylate, polyacrylate, N-methyl - anionic surfactants such as fatty acid sarcosinate, resinate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl phenyl ether phosphate, laurylamine hydrochloride, stearylamine salt An alkyl group such as an acid salt, an oleylamine hydrochloride, a stearylamine acetate, a stearylamine propylamine acetate, an alkyltrimethylammonium chloride, an alkyldimethylphosphonium chloride or the like A cationic surfactant of an amine salt, an amphoteric surfactant of an amino acid type or a betaine type, or the like. These surfactants may be used alone or in combination of two or more.

結合劑或黏著賦予劑而言，例如可舉羧基甲基纖維素或其鹽，糊精，水可溶性澱粉，黃原膠，瓜耳樹膠，蔗糖，聚乙烯吡咯酮，***樹膠，聚乙烯醇，聚乙酸乙烯酯，聚丙烯酸鈉，平均分子量6,000至20,000的聚乙二醇，平均分子量10萬至 500萬的聚乙烯氧化物，磷脂質(例如腦磷脂或卵磷脂等)，纖維素粉末，糊精，加工澱粉，聚胺基羧酸鉗合化合物，交聯聚乙烯基吡咯酮，馬來酸與苯乙烯類的共聚物，(甲基)丙烯酸系共聚物，多元醇所成的聚合物與二酸酐的半酯，聚苯乙烯磺酸的水可溶性鹽，石蠟，萜烯，聚醯胺樹脂，聚丙烯酸鹽，聚氧乙烯，白蠟，聚乙烯基烷基醚，烷基酚甲醛縮合物，合成樹脂乳劑等。 The binder or the adhesion-imparting agent may, for example, be carboxymethylcellulose or a salt thereof, dextrin, water-soluble starch, xanthan gum, guar gum, sucrose, polyvinylpyrrolidone, gum arabic, polyvinyl alcohol, Polyvinyl acetate, sodium polyacrylate, polyethylene glycol with an average molecular weight of 6,000 to 20,000, an average molecular weight of 100,000 5 million polyethylene oxides, phospholipids (eg cephalin or lecithin, etc.), cellulose powder, dextrin, processed starch, polyaminocarboxylic acid clamp compound, crosslinked polyvinylpyrrolidone, maleic acid Copolymer with styrene, (meth)acrylic copolymer, half ester of polymer and dianhydride formed by polyol, water soluble salt of polystyrene sulfonic acid, paraffin, terpene, polyamide resin , polyacrylate, polyoxyethylene, white wax, polyvinyl alkyl ether, alkylphenol formaldehyde condensate, synthetic resin emulsion, and the like.

增黏劑而言，例如可舉黃原膠，瓜耳樹膠，迪特膠(diutan gum)，羧甲基纖維素，聚乙烯基吡咯酮，羧乙烯聚合物，丙烯系聚合物，澱粉衍生物，多糖類的水溶性高分子，例如高純度皂土，燻化氧化矽(白碳)等的無機微粉。 Examples of the tackifier include xanthan gum, guar gum, diutan gum, carboxymethyl cellulose, polyvinylpyrrolidone, carboxyvinyl polymer, propylene polymer, and starch derivative. A water-soluble polymer of a polysaccharide such as high-purity bentonite or an inorganic fine powder such as smoked cerium oxide (white carbon).

著色劑而言，例如可舉氧化鐵，氧化鈦，普魯士藍等的無機顏料，例如茜素染料，偶氮染料，以及金屬酞花青染料等的有機染料。 Examples of the colorant include inorganic pigments such as iron oxide, titanium oxide, and Prussian blue, and organic dyes such as halogen dyes, azo dyes, and metal phthalocyanine dyes.

抗凍劑而言，例如，可舉乙二醇，二乙二醇，丙二醇，甘油等的多元醇類等。 Examples of the antifreezing agent include polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, and glycerin.

做為抗結塊或促進崩壞的佐劑而言，例如可舉如澱粉，海藻酸，甘露糖，半乳糖的多糖類，聚乙烯吡咯酮，燻化氧化矽(白碳)，酯膠，石油樹脂，三聚磷酸鈉，六偏磷酸鈉，金屬硬脂酸鹽，纖維素粉末，糊精，甲基丙烯酸酯的共聚物，聚乙烯吡咯酮，聚胺基羧酸鉗合化合物，磺酸化苯乙烯．異丁烯．馬來酸酐共聚物，澱粉．聚丙烯腈接支共聚物等。 As an adjuvant which is anti-caking or promotes collapse, for example, starch, alginic acid, mannose, galactose polysaccharide, polyvinylpyrrolidone, smoked cerium oxide (white carbon), ester gum, Petroleum resin, sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, copolymer of methacrylate, polyvinylpyrrolidone, polyaminocarboxylic acid clamp compound, sulfonation Styrene. Isobutylene. Maleic anhydride copolymer, starch. Polyacrylonitrile graft copolymer and the like.

分解防止劑而言，例如可舉沸石，生石灰及氧化鎂等的乾燥劑，酚化合物，胺化合物，硫化合物，磷酸化合物等的抗氧化劑，水楊酸化合物，二苯甲酮化合物等的紫外光吸收劑等。 Examples of the decomposition preventive agent include ultraviolet rays such as zeolite, a desiccant such as quicklime or magnesia, an antioxidant such as a phenol compound, an amine compound, a sulfur compound or a phosphoric acid compound, a salicylic acid compound, and a benzophenone compound. Absorbent, etc.

防腐劑而言，例如可舉山梨酸鉀，1,2-苯并噻唑啉-3-酮等。 Examples of the preservative include potassium sorbate and 1,2-benzothiazolin-3-one.

再者，必要時，也可使用功能性展著劑，胡椒基丁基氧化物(piperonyl butoxide)等的代謝分解抑制劑等的活性促進劑，丙二醇等的抗凍劑，BHT等的抗氧化劑，紫外光吸收劑等及其他的佐劑。 Further, if necessary, a functional spreading agent, an activity promoter such as a metabolic decomposition inhibitor such as piperonyl butoxide, an antifreezing agent such as propylene glycol, or an antioxidant such as BHT may be used. Ultraviolet light absorbers and other adjuvants.

活性成分的化合物的配合比率可視需要而改變，對本發明的植物病害防治劑100重量份中，由0.01至90重量份的範圍適宜選擇即可，例如，做為粉劑，粒劑，乳劑或水和劑時0.01至50重量份(對植物病害防治劑全重量的0.01至50重量%)為適當。 The compounding ratio of the compound of the active ingredient may be changed as needed, and may be appropriately selected from the range of 0.01 to 90 parts by weight, for example, as a powder, a granule, an emulsion or water, in 100 parts by weight of the plant disease controlling agent of the present invention. From 0.01 to 50 parts by weight (from 0.01 to 50% by weight based on the total weight of the plant disease controlling agent) is suitable.

本發明的植物病害防治劑的使用量是因種種的因子，例如目的，對象病害，作物的生育狀況，病害的發生傾向，天候，環境條件，劑型，施用方法，施用場所，施用時期等而變動，但有效成分化合物在每10公畝0.001g至10kg，理想是0.01g至1kg的範圍視目的如何而適宜選擇即可。 The amount of the plant disease controlling agent used in the present invention varies depending on various factors such as the purpose, the target disease, the growth state of the crop, the tendency of the disease, the weather, the environmental conditions, the dosage form, the application method, the application site, the administration period, and the like. However, the active ingredient compound may be suitably selected in the range of 0.001 g to 10 kg, preferably 0.01 g to 1 kg, per 10 ares depending on the purpose.

本發明的植物病害防治劑更是，為了擴大防治對象病害，防治適期起見，或以減低藥量為目的而與其他的農園藝用殺蟲劑，殺蟎劑，殺線蟲劑，農園藝用殺菌劑，生物農藥等混合使用也是可能，又，視使用場面而與除草劑，植物成長調節劑，肥料等混合使用也是可能。 The plant disease control agent of the present invention is used for the purpose of expanding the disease prevention and control, prevention and control, or other agricultural and horticultural insecticides, acaricides, nematicides, agricultural and horticultural purposes for the purpose of reducing the dose. Mixtures of fungicides, biological pesticides, etc. are also possible, and it is also possible to mix them with herbicides, plant growth regulators, fertilizers, etc. depending on the scene of use.

做為這樣的目的而使用的其他的農園藝殺蟲劑，殺蟎劑，殺線蟲劑，例如，可舉滅克蝨(3,5-xylyl methylcarbamate,XMC)，由蘇力菌逢澤氏亞種(Bacillus thuringienses aizawai)，蘇力菌以色列亞種(Bacillus thuringienses israelensis)，蘇力菌日本亞種 (Bacillus thuringienses japonensis)，蘇力菌庫斯克亞種(Bacillus thuringienses kurstaki)，蘇力菌擬步行蟲亞種(Bacillus thuringienses tenebrionis)，或蘇力菌(Bacillus thuringienses)製造的結晶性蛋白質毒素，BPMC，蘇力菌毒素(Bt toxin)系殺蟲化合物，蟎卵酯(CPCBS，Chlorfenson)，DCIP(二氯二異丙基醚)，D-D(1,3-二氯丙烯)，DDT，NAC，O-4-二甲基胺磺醯基苯基-O,O-二乙基硫代磷酸酯(O-4-dimethylsulfamoylphenyl O,O-diethyl phosphorothioate,DSP)，O-乙基-O-4-硝苯基苯基磷硫酸酯(O-ethyl O-4-nitrophenyl phenylphosphono thioate,EPN)，異三聚氰酸三丙酯(TPIC)，阿納寧(acrinathrin)，印楝素(azadirachtin)，谷速松(azinphos-methyl)，亞醌蟎(acequinocyl)，亞滅培(acetamiprid)，乙醯蟲腈(acetoprole)，毆殺松(acephate)，阿巴汀(abamectin)，阿維菌素B(avermectin-B)，磺胺蟎酯(amidoflumet)，雙甲脒(amitraz)，棉鈴威(alanycarb)，得滅克(aldicarb)，涕滅碸威(aldoxycarb)，阿特靈(aldrin)，安殺番(alpha-endosulfan)，亞滅寧(alpha-cypermethrin)，阿苯達唑(albendazole)，烯丙菊酯(allethrin)，依殺松(isazofos)，isamidofos(商品名)，isoamidofos(商品名)，加福松(isoxathion)，亞芬松(isofenphos)，滅必蝨(isoprocarb：MIPC)，依維菌素(ivermectin)，imicyafos(商品名)，益達胺(imidacloprid)，依普寧(imiprothrin)，因得克(indoxacarb)，益化利(esfenvalerate)，殺蟲丹(ethiofencarb)，愛殺松(ethion)，益斯普(ethiprole)，依殺蟎(etoxazole)，依芬寧(ethofenprox)，普伏松(ethoprophos)，益多松(etrimfos)，因滅汀(emamectin)，因滅汀(emamectin benzoate)，安殺番(endosulfan)，益避寧(empenthrin)，毆殺滅(oxamyl)，滅多松(oxydemeton-methyl)，異亞碸磷(oxydeprofos： ESP)，奧苯達唑(oxibendazole)，奧芬達唑(oxfendazole)，油酸鉀，油酸鈉，加奪松(cadusafos)，培丹(cartap)，加保利(carbaryl)，丁基加保扶(carbosulfan)，加保扶(carbofuran)，伽瑪賽洛寧(gamma-cyhalothrin)，滅爾蝨(xylylcarb)，拜裕松(quinalphos)，烯蟲炔酯(kinoprene)，蟎離丹(chinomethionat)，除線威(cloethocarb)，可尼丁基(clothianidin)，克芬蟎(clofentezine)，可芬諾(chromafenozide)，克安勃(chlorantraniliprole)，氯氧磷(chlorethoxyfos)，殺蟲脒(chlordimeform)，可氯丹(chlordane)，陶斯松(chlorpyrifos)，甲基陶斯松(chlorpyrifos-methyl)，溴蟲清(chlorphenapyr)，蟎卵酯(chlorfenson)，克芬松(chlorfenvinphos)，克福隆(chlorfluazuron)，克氯苯(chlorobenzilate)，氯苯甲酸酯(chlorobanzoate)，大克蟎(dicofol)，殺力松(salithion)，氰乃松(cyanophos：CYAP)，汰芬隆(diafenthiuron)，除線特(diamidafos)，氰蟲醯胺(cyantraniliprole)，反式氯氰菊酯(theta-cypermethrin)，得氯蟎(dienochlor)，唑蟎氰(cyenopyrafen)，殺力松(dioxabenzofos)，二苯丙醚(diofenolan)，高效反式氯氰菊酯(sigma-cypermethrin)，除線磷(dichlofenthion：ECP)，乙氰菊酯(cycloprothrin)，二氯松(dichlorvos：DDVP)，二硫松(disulfoton)，達特南(dinotefuran)，賽洛寧(cyhalothrin)，賽酚寧(cyphenothrin)，賽扶寧(cyfluthrin)，二福隆(diflubenzuron)，賽芬蟎(cyflumetofen)，氟蟎嗪(diflovidazin)，錫蟎丹(cyhexatin)，賽滅寧(cypermethrin)，二甲基毒蟲畏(dimethylvinphos)，大滅松(dimethoate)，四氟甲醚菊酯(dimefluthrin)，矽護芬(silafluofen)，賽滅淨(cyromazine)，賜諾特(spinetoram)，賜諾殺(spinosad)，賜派芬(spirodiclofen)，賜派滅(spirotetramat)，螺甲蟎酯(spiromesifen)，氟蟲胺(sulfluramid)，硫 丙磷(sulprofos)，氟啶蟲胺腈(sulfoxaflor)，傑他賽滅寧(zeta-cypermethrin)，大利松(diazinon)，福化利(tau-fluvalinate)，邁隆(dazomet)，賽果培(thiacloprid)，賽速安(thiamethoxam)，硫敵克(thiodicarb)，硫賜安(thiocyclam)，殺蟲雙(thiosultap)，殺蟲雙-鈉，治線磷(thionazin)，硫滅松(thiometon)，避蚊胺(deet)，地特靈(dieldrin)，殺蟲畏(tetrachlorvinphos)，得脫蟎(tetradifon)，四氟醚菊酯(tetramethylfluthrin)，治滅寧(tetramethrin)，丁基嘧啶磷(tebupirimfos)，得芬諾(tebufenozide)，得芬瑞(tebufenpyrad)，七氟菊酯(tefluthrin)，得福隆(teflubenzuron)，滅賜松(demeton-S-methyl)，亞培松(temephos)，第滅寧(deltamethrin)，托福松(terbufos)，曲洛比利(tralopyril)，泰滅寧(tralomethrin)，拜富寧(transfluthrin)，唑蚜威(triazamate)，唑蚜威(triazuron)，水楊菌胺(trichlamide)，三氯松(trichlorfon：DEP)，三福隆(triflumuron)，脫芬瑞(tolfenpyrad)，乃力松(naled：BRP)，噻蟲醛(nithiazine)，烯啶蟲胺(nitenpyram)，諾伐隆(novaluron)，諾福隆(noviflumuron)，烯蟲乙酯(hydroprene)，vaniliprole(商品名)，繁米松(vamidothion)，巴拉松(parathion)，甲基巴拉松(parathion-methyl)，合芬寧(halfenprox)，氯蟲醯肼(halofenozide)，雙三氟蟲脲(bistrifluron)，殺蟲雙(bisultap)，愛美松(hydramethylnon)，羥丙基澱粉，百蟎克(binapacryl)，必芬蟎(bifenazate)，畢芬寧(bifenthrin)，派滅淨(pymetrozine)，白克松(pyraclofos)，pyrafluprole(商品名)，必芬松(pyridafenthion)，畢達本(pyridaben)，啶蟲丙醚(pyridalyl)，pyrifluquinazon(商品名)，pyriprole(商品名)，百利普芬(pyriproxyfen)，比加普(pirimicarb)，畢汰芬(pyrimidifen)，甲基嘧啶磷(pirimiphos-methyl)，除蟲菊酯 (pyrethrins)，芬普尼(fipronil)，芬殺蟎(fenazaquin)，芬滅松(fenamiphos)，新殺蟎(bromopropylate)，撲滅松(fenitrothion：MEP)，芬諾克(fenoxycarb)，芬硫克(fenothiocarb)，苯醚菊酯(phenothrin)，丁基滅必蝨(fenobucarb)，繁福松(fensulfothion)，芬殺松(fenthion：MPP)，賽達松(phenthoate：PAP)，芬化利(fenvalerate)，芬普蟎(fenpyroximate)，芬普寧(fenpropathrin)，芬苯達唑(fenbendazole)，福賽絕(fosthiazate)，覆滅蟎(formetanate)，脫甲基丁嘧啶磷(butathiofos)，布芬淨(buprofezin)，呋線威(furathiocarb)，丙炔菊酯(prallethrin)，嘧蟎酯(fluacrypyrim)，扶吉胺(fluazinam)，吡蟲隆(fluazuron)，(fluensulfone)，氟環脲(flucycloxuron)，護賽寧(flucythrinate)，福化利(fluvalinate)，吡氟硫磷(flupyrazofos)，嘧啶肟草醚(flufenerim)，氟芬隆(flufenoxuron)，氟蟎嗪(flufenzine)，(flufenoprox)，苄蟎醚(fluproxyfen)，溴氟菊酯(flubrocythrinate)，氟蟲雙醯胺(flubendiamide)，氟氯苯菊酯(flumethrin)，flurimfen(商品名)，普硫松(prothiofos)，protrifenbute(商品名)，氟尼胺(flonicamid)，丙蟲磷(propaphos)，毆蟎多(propargite：BPPS)，佈飛松(profenofos)，丙氟菊酯(profluthrin)，安丹(propoxur：PHC)，新殺蟎(bromopropylate)，貝他賽扶寧(beta-cyfluthrin)，六伏隆(hexaflumuron)，合賽多(hexythiazox)，飛達松(heptenophos)，百滅寧(permethrin)，異噻蟲唑(benclothiaz)，免敵克(bendiocarb)，免速達(bensultap)，西脫蟎(benzoximate)，免扶克(benfuracarb)，辛硫磷(phoxim)，裕必松(phosalone)，福賽絕(fosthiazate)，丁硫環磷(fosthietan)，磷胺(phosphamidon)，磷蟲威(phosphocarb)，益滅松(phosmet：PMP)，瀏陽黴纛(polvnactins)，覆滅蟎(formetanate)，福木松(formothion)，福 瑞松(phorate)，機器油(machine oil)，馬拉松(malathion)，倍脈心(milbemycin)，倍脈心A(milbemycin-A)，密滅汀(milbemectin)，滅加松(mecarbam)，mesulfenfos(商品名)，納乃得(methomyl)，聚乙醛(metaldehyde)，美氟綜(metaflumizone)，達馬松(methamidophos)，二硫代氨基甲酸銨(metam-ammonium)，二硫代氨基甲酸鈉(metam-sodium)，滅賜克(methiocarb)，滅大松(methidathion：DMTP)，異硫氰酸甲酯(methyl isothiocyanate)，甲基新癸醯胺(methylneodecamide)，甲基巴拉松，噁蟲酮(metoxadiazone)，甲氧滴滴涕(methoxychlor)，滅芬諾(methoxyfenozide)，甲氧卞氟菊酯(metofluthrin)，烯蟲丙酯(methoprene)，治滅蝨(metolcarb)，氯氟醚菊酯(meperfluthrin)，美文松(mevinphos)，亞素靈(monocrotophos)，殺蟲單(monosultap)，賽洛寧(lambda-cyhalothrin)，利阿諾定(ryanodine)，祿芬隆(lufenuron)，列滅寧(resmethrin)，雷皮菌素(lepimectin)，魚藤酮(rotenone)，鹽酸左旋咪唑(levamisole hydrochloride)，芬佈賜(fenbutatin oxide)，摩朗得酒石酸鹽(morantel tartrate)，溴化甲烷(methyl bromide)，錫蟎丹(氫氧化三環己基錫，cyhexatin)，氰胺化鈣(calcium cyanamide)，鈣硫合劑(calcium polysulfide)，硫(sulfur)，硫酸煙鹼(nicotine-sulfate)等。 Other agricultural and horticultural insecticides, acaricides, nematicides used for such purposes, for example, 3,5-xylyl methylcarbamate (XMC), from the genus (Bacillus thuringienses aizawai), Bacillus thuringienses israelensis, Suribacter subsp. (Bacillus thuringienses japonensis), Bacillus thuringienses kurstaki, Bacillus thuringienses tenebrionis, or crystalline protein toxin produced by Bacillus thuringienses, BPMC, Bt toxin is an insecticidal compound, eucalyptus ester (CPCBS, Chlorfenson), DCIP (dichlorodiisopropyl ether), DD (1,3-dichloropropene), DDT, NAC, O- 4-4-dimethylsulfamoylphenyl O, O-diethyl phosphorothioate (DSP), O-ethyl-O-4-nitrobenzene O-ethyl O-4-nitrophenyl phenylphosphono thioate (EPN), tripropyl methacrylate (TPIC), acrinathrin, azadirachtin, tamarind ( Azinphos-methyl), acequinocyl, acetamiprid, acetoprole, acephate, abamectin, avermectin-B ), amidoflumet, amitraz, alanycarb, aldicarb, aldoxycarb, Aldrin, alpha-endosulfan, alpha-cypermethrin, albendazole, allethrin, isazofos, isamimidos (trade name) ), isoamidofos (trade name), isoxathion, isofenphos, isoprocarb (MIPC), ivermectin, imicyafos (trade name), imidacloprid , imiprothrin, indoxacarb, esfenvalerate, ethiofencarb, ethion, ethiprole, etoxazole Ethofenprox, ethoprophos, etrimfos, emamectin, emamectin benzoate, endosulfan, empenthrin, 殴Oxalyl, oxydemeton-methyl, oxydeprofos: ESP), oxibendazole, oxfendazole, potassium oleate, sodium oleate, cadusafos, cartap, carbaryl, butyl Carbosulfan, carbofuran, gamma-cyhalothrin, xylylcarb, quinalphos, kinoprene, chinomethionat ), in addition to cloethocarb, clothianidin, clofentezine, chromafenozide, chlorantraniliprole, chlorethoxyfos, chlordimeform ), chlordane, chlorpyrifos, chlorpyrifos-methyl, chlorphenapyr, chlorfenson, chlorfenvinphos, chlorfluazuron , chlorobenzilate, chlorobanzoate, dicofol, salithion, cyanophos (CYAP), diafenthiuron, in addition to (diamidafos), cyantraniliprole, theta-cypermethrin, Dienochlor, cyenopyrafen, dioxabenzofos, diofenolan, sigma-cypermethrin, deichlofenthion (ECP), cyanidia Cycloprothrin, dichlorvos (DDVP), disulfoton, dinotefuran, cyhalothrin, cyphenothrin, cyfluthrin, II Diflubenzuron, cyflumetofen, diflovidazin, cyhexatin, cypermethrin, dimethylvinphos, dimethoate , dimefluthrin, silafluofen, cyromazine, spinetoram, spinosad, spirodiclofen, sent out Spirotetramat), spiromesifen, sulfluramid, sulfur Sulprofos, sulfoxaflor, zeta-cypermethrin, diazinon, tau-fluvalinate, dazome, Sai Pei (thiacloprid), thiamethoxam, thiodicarb, thiocyclam, thiosultap, insecticidal bis-sodium, thionazin, thiometon ), deetamine, dieldrin, tetrachlorvinphos, tetradifon, tetramethylfluthrin, tetramethrin, butyl pyrimidine (tebupirimfos), tebufenozide, tebufenpyrad, tefluthrin, teflubenzuron, demeton-S-methyl, temephos , deltamethrin, terbufos, tramopyril, trolomethrin, transfluthrin, triazamate, triazuron, Tricholfamide, trichlorfon (DEP), triflumuron, tolfenpyrad, naled: BRP Thithiazine, nitenpyram, novaluron, noififlumuron, hydroprene, vaniliprole (trade name), vamidothion, bar Parathion, parathion-methyl, halfenprox, halofenozide, bistrifluron, bisultap, amesone (hydramethylnon), hydroxypropyl starch, binapacryl, bifenazate, bifenthrin, pymetrozine, pyraclofos, pyrafluprole (trade name), bifensone ( Pyridafenthion), pyridaben, pyridalyl, pyrifluquinazon (trade name), pyriprol (trade name), pyriproxyfen, pirimicarb, pyrimidifene ), pirimiphos-methyl, pyrethrin (pyrethrins), fipronil, fenazaquin, fenamiphos, bromopropylate, fenitrothion (MEP), fenoxycarb, fenthiophene (fenothiocarb), phenothrin, fenobucarb, fensulfothion, fenthion (MPP), phenthoate (PAP), fenvalerate ), fenpyroximate, fenpropathrin, fenbendazole, fosthiazate, formetanate, butathiofos, buffing Buprofezin), furathiocarb, prallethrin, fluacrypyrim, fluazinam, fluazuron, fluensulfone, flucycloxuron, Flucythrinate, fluvalinate, flupyrazofos, flufenerim, flufenoxuron, flufenzine, flufenoprox, benzamidine Fluproxyfen, flubrocythrinate, flubendiamide, chlorofluorocarbon Flumethrin, flurimfen (trade name), prothiofos, protrifenbute (trade name), flonicamid, propaphos, propargite (BPPS), cloth Profenofos, profluthrin, propoxur (PHC), bromopropylate, beta-cyfluthrin, hexaflumuron, cycad ( Hexythiazox), heptenophos, permethrin, benclothiaz, bendiocarb, bensultap, benzoximate, benfuracarb ), phoxim, phosalone, fosthiazate, fosthietan, phosphamidon, phosphocarb, phosmet: PMP), polvnactins, formetanate, formothion, blessing Phosphorus, machine oil, malathion, milbemycin, milbemycin-A, milbemectin, mecarbam, mesulfenfos Trade name), methodomyl, metaldehyde, metaflumizone, methamidophos, metaam-ammonium, sodium dithiocarbamate Metam-sodium), metiocarb, methidathion (DMTP), methyl isothiocyanate, methylneodecamide, methylbarlaxone, triammonium (metoxadiazone), methoxychlor, methoxyfenozide, metofluthrin, methoprene, metolcarb, permethrin (meperfluthrin) ), mevinphos, monocrotophos, monosultap, lambda-cyhalothrin, ryanodine, lufenuron, liningin Resmethrin), lepimectin, rotenone, levamisole hydidamine Rochloride), fenbutatin oxide, morantel tartrate, methyl bromide, stanozidine, cyhexatin, calcium cyanamide ), calcium polysulfide, sulfur, nicotine-sulfate, and the like.

同樣的目的使用的農園藝用殺菌劑而言，可例示，金色制霉素(aureofungin)，氧環唑(azaconazole)，氧化福美雙殺菌劑(azithiram)，acypetacs(商品名)，阿拉酸式苯(acibenzolar)，阿拉酸式苯-S-甲基(acibenzolar-S-methyl)，亞托敏(azoxystrobin)，敵菌靈(anilazine)，安美速(amisulbrom)，1-氨基丙基磷酸(ampropylfos)，辛唑嘧菌胺(ametoctradin)，烯丙醇，十二嗎啉(aldimorph)，代森 銨(amobam)，異噻菌胺(isotianil)，(isovaledione)，isopyrazam(商品名)，亞賜圃(isoprothiolane)，種菌唑(ipconazole)，依普同(iprodione)，丙森辛(iprovalicarb)，丙基喜樂松(iprobenfos)，依滅列(imazalil)，克熱淨(iminoctadine)，苯烷磺酸鹽(iminoctadine-albesilate)，克熱淨(iminoctadine triacetate)，易胺座(imibenconazole)，烯效唑(uniconazole)，烯效唑P(uniconazole-P)，氯唑靈(echlomezole)，護粒松(edifenphos)，乙環唑(etaconazole)，噻唑菌胺(ethaboxam)，依瑞莫(ethirimol)，代森硫(etem)，乙氧基奎寧(ethoxyquin)，依得利(etridiazole)，烯肟菌酯(enestroburin)，依普座(epoxiconazole)，噁霜靈(oxadixyl)，嘉保信(oxycarboxin)，8-喹啉銅(copper-8-quinolinolate)，土霉素(oxytetracycline)，8-羥喹啉銅(copper-oxinate)，噁咪唑(oxpoconazole)，噁咪唑-富馬酸鹽，歐索林酸(oxolinic acid)，辛異噻啉酮(octhilinone)，甲呋醯胺(ofurace)，肟醚菌胺(orysastrobin)，斯美地(metam-sodium)等的土壤殺菌劑，嘉賜黴素(kasugamycin)，嗎菌威(carbamorph)，加普胺(carpropamid)，貝芬替(carbendazim)，萎鏽靈(carboxin)，香芹酮(carvone)，醌菌腙(quinazamid)，喹烯酮(quinacetol)，快諾芬(quinoxyfen)，滅蟎猛(quinomethionate)，敵菌丹(captafol)，蓋普丹(captan)，精苯霜靈(kiralaxyl)，quinconazole(商品名)，五氯硝基苯(quintozene)，克熱淨(guazatine)，硫雜靈(cufraneb)，福美銅氯(cuprobam)，果綠啶(glyodin)，微灰黃黴素(griseofulvin)，甘寶素(climbazole)，甲酚(cresol)，克收欣(kresoxim-methyl)，克氯得(chlozolinate)，克黴唑(clotrimazole)，克氯綜(chlobenthiazone)，粉淨胺(chloraniformethan)，四氯對苯醌(chloranil)，四氯喹啉(chlorquinox)，三氯硝甲烷 (chloropicrin)，氯苯咪唑(chlorfenazole)，氯二硝基萘(chlorodinitronaphthalene)，四氯異苯腈(chlorothalonil)，地茂散(chloroneb)，氰菌胺(zarilamid(草案))，柳醯苯胺(salicylilide)，賽座滅(cyazofamid)，焦碳酸二乙酯(diethyl pyrocarbonate)，乙霉威(diethofencarb)，環菌胺(cyclafuramid)，雙氯氰菌胺(diclocymet)，菌核利(dichlozoline)，苄氯***醇(diclobutrazol)，益發靈(dichlofluanid)，放線菌酮(cycloheximide)，達滅淨(diclomezine)，大克爛(dicloran)，雙氯酚(二氯phen)，二氯萘醌(dichlone)，二硫龍(disulfiram)，滅菌磷(ditalimfos)，腈硫醌(dithianon)，烯唑醇(diniconazole)，達克利(diniconazole-M)，鋅乃浦(zineb)，白粉克(dinocap)，敵菌死(dinocton)，硝辛酯殺蟎劑(dinosulfon)，硝丁酯(dinoterbon)，敵蟎通(dinobuton)，硝戊酯(dinopenton)，雙吡硫翁(dipyrithione)，二苯胺(diphenylamine)，待克利(difenoconazole)，環氟菌胺(cyflufenamid)，二氟林(diflumetorim)，環克座(cyproconazole)等的苯基醯胺系化合物，嘧菌環胺(cyprodinil)，酯菌胺(cyprofuram)，氰菌靈(cypendazole)，矽氟唑(simeconazole)，二甲嘧酚(dimethirimol)，達滅芬(dimethomorph)，克絕(cymoxanil)，醚菌胺(dimoxystrobin)，溴化甲烷，福美鋅(ziram)，矽噻菌胺(silthiofam)，鏈黴素(streptomycin)，螺環菌胺(spiroxamine)，戊苯碸(sultropen)，環苯吡菌胺(sedaxane)，苯醯菌胺(zoxamide)，邁隆(dazomet)，噻嗪酮(thiadiazin)，噻醯菌胺(tiadinil)，氟噻亞菌胺(thiadifluor)，噻苯咪唑(thiabendazole)，tioxymid(商品名)，硫氯苯亞胺(thiochlorfenphim)，多保淨(thiophanate)，甲基多保淨(thiophanate-methyl)，噻菌腈(thicyofen)，克殺蟎(thioquinox)，滅蟎猛(chinomethionat)，賽氟滅 (thifluzamide)，得恩地(thiram)，癸磷錫(decafentin)，四氯硝基苯(tecnazene)，克枯爛(tecloftalam)，福美雙聯(tecoram)，四克利(tetraconazole)，咪菌威(debacarb)，去氫乙酸(dehydroacetic acid)，得克利(tebuconazole)，異丁乙氧喹啉(tebufloquin)，多地辛(dodicin)，十二烷胍(dodine)，十二烷基苯磺酸(dodecylbenzenesulphonic acid)，雙乙二胺銅(bisethylenediamine copper(II)(DBEDC))，十二環嗎啉(dodemorph)，敵菌酮(drazoxolon)，三泰隆(triadimenol)，三泰芬(triadimefon)，丁***(triazbutil)，唑菌嗪(triazoxide)，***磷胺(triamiphos)，嘧菌醇(triarimol)，水楊菌胺(trichlamide)，三賽唑(tricyclazole)，滅菌唑(triticonazole)，三得芬(tridemorph)，氧化三丁基錫(tributyltin oxide)，賽福座(triflumizole)，三氟敏(trifloxystrobin)，賽福寧(triforine)，甲基益發靈(tolylfluanid)，脫克松(tolclofos-methyl)，鏈黴菌素(natamycin)，鈉乃浦(nabam)，酞菌酯(nitrothal-isopropyl)，硝基苯乙烯，尼瑞莫(nuarimol)，壬基苯磺酸銅(copper nonylphenol sulfonate)，丙烯酸喹啉酯(halacrinate)，維利黴素(validamycin)，(valifenalate)，超敏蛋白(harpin protein)，bixafen(商品名)，啶氧菌酯(picoxystrobin)，氟啶醯菌胺(picobenzamide(fluopicolid))，硫雙二氯酚(bithionol)，比多農(bitertanol)，噁黴靈(hydroxyisoxazole)，噁黴靈鉀(hydroisoxazole-potassium)，百蟎克(binapacryl)，聯苯(biphenyl)，粉病靈(piperalin)，殺紋寧(hymexazol)，唑菌酯(pyraoxystrobin)，吡拉布隆(pyracarbolid)，百克敏(pyraclostrobin)，白粉松(pyrazophos)，唑胺菌酯(pyrametostrobin)，pyriofenone(商品名)，定菌腈(pyridinitril)，比芬諾(pyrifenox)，pyribencarb(商品名)，嘧霉胺 (pyrimethanil)，吡氯靈(pyroxychlor)，氯吡呋醚(pyroxyfur)，pyroquilon(百快隆)，免克寧(Vinclozolin)，凡殺同(famoxadone)，咪菌腈(fenapanil)，咪唑菌酮(fenamidone)，敵磺鈉(fenaminosulf)，芬瑞莫(fenarimol)，種衣酯(fenitropan)，芬諾尼(fenoxanil)，富米綜(ferimzone)，福美鐵(ferbam)，三苯錫(fentin)，拌種各(fenpiclonil)，胺苯吡菌酮(fenpyrazamine)，芬克座(fenbuconazole)，甲呋醯胺(fenfuram)，苯鏽啶(fenpropidin)，芬普福(fenpropimorph)，環醯菌胺(fenhexamid)，熱必斯(phthalide)，得滅多(buthiobate)，丁胺，布瑞莫(bupirimate)，麥穗寧(fuberidazole)，保米黴素(blasticidin-S)，福拉比(furametpyr)，呋霜靈(furalaxyl)，嘧蟎酯(fluacrypyrim)，扶吉胺(fluazinam)，氟嘧菌酯(fluoxastrobin)，三氟苯唑(fluotrimazole)，氟比來(fluopicolide)，氟吡菌醯胺(fluopyram)，氟醯亞胺(fluoroimide)，二甲呋醯胺(furcarbil)，fluxapyroxad(商品名)，氟喹唑(fluquinconazole)，氟康唑(furconazole)，順氟康唑(furconazole-cis)，咯菌腈(fludioxonil)，護矽得(flusilazole)，氟硫滅(flusulfamide)，氟噻菌淨(flutianil(暫定))，福多寧(flutolanil)，護汰芬(flutriafol)，呋喃甲醛(furfural)，furmecyclox(商品名)，氟醯菌胺(flumetover)，氟嗎啉(flumorph)，丙氧喹啉(proquinazid)，撲克拉(prochloraz)，撲滅寧(procymidone)，硫菌威(prothiocarb)，丙硫菌唑(prothioconazole)，普拔克(propamocarb)，普克利(propiconazole)，甲基鋅乃浦(propineb)，呋甲硫菌靈(furophanate)，撲殺熱(probenazole)，溴克座(bromuconazole)，六氯丁二烯(hexachlorobutadiene)，菲克利(hexaconazole)，hexylthiofos(商品名)，bethoxazin(商品名)，本達樂(benalaxyl)，精苯霜靈(benalaxyl-M)，麥鏽靈(benodanil)，免賴得 (benomyl)，稻瘟酯(pefurazoate)，醌肟腙(benquinox)，平克座(penconazole)，抑菌啉(benzamorf)，賓克隆(pencycuron)，苯基異羥肟酸(benzohydroxamic acid)，百得斯(bentaluron)，佈生(benthiazole)，苯噻菌胺酯(benthiavalicarb-isopropyl)，吡噻菌胺(penthiopyrad)，戊苯吡菌胺(penflufen)，白列克(boscalid)，氯瘟磷(phosdiphen)，福賽得(fosetyl)，福賽得(fosetyl-Al)，保粒黴素(polyoxins)，保粒黴素(丁)(polyoxorim)，代森联福美鋅(polycarbamate)，福爾培(folpet)，甲醛，機器油，錳乃浦(maneb)，代森錳鋅(mancozeb)，曼普胺(mandipropamid)，滅克寧(myclozolin)，邁克尼(myclobutanil)，米多霉素(mildiomycin)，代森環(milneb)，苯并威(mecarbinzid)，滅速克(methasulfocarb)，間氯敵菌酮(metazoxolon)，威百畝(metam)，美地(metam-sodium)，滅達樂(metalaxyl)，右滅達樂(metalaxyl-M)，免得爛(metiram)，異氰酸甲酯，敵蟎普(mepthyldinocap)，滅特座(metconazole)，噻菌胺(metsulfovax(草案))，三甲呋菌胺(methfuroxam)，苯氧菌胺(metominostrobin)，滅芬農(metrafenone)，滅派林(mepanipyrim)，精甲霜靈(mefenoxam)，敵蟎普(meptyldinocap)，滅普寧(mepronil)，鄰醯胺(mebenil)，碘化甲烷(iodomethane)，吡咪唑(rabenzazole)，氯化苄二甲烴銨(benzalkonium chloride)，鹼基性氯化銅(basic copper chloride)，鹼基性硫酸銅(basic copper sulfate)，金屬銀(silver)等的無機殺菌劑，次亞氯酸鈉(sodium hypochlorite)，氫氧化亞銅(cupric hydroxide)，水和硫劑(wettable sulfur)，鈣硫合劑(calcium polysulfide)，碳酸氫鉀(potassium hydrogen carbonate)，碳酸氫鈉(sodium hydrogen carbonate)，無機硫(sulfur)，無水硫酸銅(copper sulfate anhydride)，二甲胺甲硫羥羰酸鎳(nickel dimethyldithiocarbamate)，快得寧(oxine-copper)的銅系化合物硫酸鋅(zinc sulfate)，硫酸銅五水合鹽(copper sulfate)等。 For agricultural and horticultural fungicides used for the same purpose, aureofungin, azaconazole, azimutram, acypetacs (trade name), arlic acid benzene can be exemplified. (acibenzolar), acibenzolar-S-methyl, azoxystrobin, anilazine, amisulbrom, 1-aminopropyl phosphate (ampropylfos) , amezolidin, allyl alcohol, aldimorph, dysen Amoeba, isotianil, isovaledione, isopyrazam (trade name), isoprothiolane, ipconazole, iprodione, iprovalicarb, Iprobenfos, imazalil, iminoctadine, iminoctadine-albesilate, iminoctadine triacetate, imibenconazole, olefinic effect Uniconazole, uniconazole-P, echlomezole, edifenphos, etaconazole, ethaboxam, ethirimol, Etem, ethoxyquin, etridiazole, enestroburin, epoxiconazole, oxadixyl, oxycarboxin , copper-8-quinolinolate, oxytetracycline, copper-oxinate, oxpoconazole, methane imidazole-fumarate, oxolene Oxolinic acid, octhilinone, ofurace, oressastrobin, metam -sodium) soil bactericide, kasugamycin, carbamorph, carpropamid, carbendazim, carboxin, carvone ), quinazamid, quinacetol, quinoxyfen, quinomethionate, captafol, captan, kiralaxyl, quinconazole (trade name), quintozene, guazatine, cufraneb, cuprobam, glyodin, griseofulvin , climbazole, cresol, kresoxim-methyl, chlozolinate, clottrimazole, chlobenthiazone, chloraniformethan, four Chloranil, chlorquinox, trichloromethane (chloropicrin), chlorfenazole, chlorodinitronaphthalene, chlorothalonil, chloroneb, cyanamide (draft), sulphur aniline Salicylilide), cyazofamid, diethyl pyrocarbonate, diethofencarb, cyclafuramid, diclocymet, dichlozoline, Benzlobutrazol, dichlofluanid, cycloheximide, diclomezine, dicloran, dichlorophenol (dichlorophen), dichloronaphthylquinone (diclofenac) Dichlone), disulfiram, ditalimfos, dithianon, diniconazole, diniconazole-M, zineb, dinocap , dinocton, dinosulfon, dinoterbon, dinobuton, dinopenton, dipyrithione, diphenylamine Diphenylamine), difenoconazole, cyflufenamid, diflumetorim A phenylguanamine compound such as cyproconazole, cyprodinil, cyprofuram, cypendazole, simeconazole, dimethirimol ), dimethomorph, cymoxanil, dimoxystrobin, methyl bromide, ziram, silthiofam, streptomycin, spirobacteria Spiroxamine, sultropen, sedaxane, zoxamide, dazome, thiadiazin, tiadinil, Thiadifluor, thiabendazole, tioxymid (trade name), thiochlorfenphim, thiophanate, thiophanate-methyl, thiophene Nitric acid (thicyofen), thioquinox, chinomethionat, cyproterone (thifluzamide), thiram, decafentin, tecnazene, tecloftalam, tetoram, tetraconazole, imiprozil Debacarb), dehydroacetic acid, tebuconazole, tebufloquin, dodicin, dodine, dodecylbenzenesulfonic acid (dobaconazole) Dodecylbenzenesulphonic acid), bisethylenediamine copper (II) (DBEDC), dodemorph, drazoxolon, triadimenol, triadimefon, diced Triazbutil, triazoxide, triamiphos, triarimol, tricholamide, tricyclazole, triticonazole, three Tridemorph, tributyltin oxide, triflumizole, trifloxystrobin, triforine, tolylfluanid, tolclofos-methyl ), natamycin, nabam, nitrothal-isopropyl Nitrostyrene, nuarimol, copper nonylphenol sulfonate, halacrinate, validamycin, valifenalate, harpin protein ), bixafen (trade name), picoxystrobin, picobenzamide (fluopicolid), thiobisdichlorophenol (bithionol), bitertanol, hydroxyisoxazole , hydroisoxazole-potassium, binapacryl, biphenyl, piperalin, hymexazol, pyraoxystrobin, pyrabron ( Pyracarbolid), pyraclostrobin, pyrazophos, pyrametostrobin, pyriofenone (trade name), pyridinitril, pyrifenox, pyribencarb (trade name), pyrimidine Mycomycin (pyrimethanil), pyroxychlor, pyroxyfur, pyroquilon, Vinclozolin, famoxadone, fenapanil, imidacloprid (fenamidone), fenaminosulf, fenarimol, fenitropan, fenoxanil, ferimzone, ferbam, triphenyltin (fentin) ), seed dressing (fenpiclonil), fenpyrazamine, fenbuconazole, fenfuram, fenpropidin, fenpropimorph, cyclosporine Amine (fenhexamid), phthalide, buthiobate, butylamine, bupirimate, fuberidazole, blasticidin-S, and furametpyr ), furalaxyl, fluacrypyrim, fluazinam, fluoxastrobin, fluotrimazole, fluopicolide, flupirtine Fluopyram, fluoroimide, furfurbil, fluxapyroxad (trade name), fluquinconazole, Furconazole, furconazole-cis, fludioxonil, flusilazole, flusulfamide, fluothiform (tentative), Fodor Flutolanil, flutriafol, furfural, furmecyclox (trade name), flumetover, flumorph, proquinazid, poker pull ( Prochloraz), procymidone, prothiocarb, prothioconazole, propamocarb, propiconazole, propineb, furfuryl Furophanate, probenazole, bromuconazole, hexachlorobutadiene, hexaconazole, hexylthiofos (trade name), bethoxazin (trade name), bentaxyl (benalaxyl) ), Benalaxyl-M, benodanil, free (benomyl), pefurazoate, benquinox, penconazole, benzmorf, pencycuron, benzohydroxamic acid, hundred Bentaluron, benthiazole, benthiavalicarb-isopropyl, penthiopyrad, penflufen, boscalid, proguanidin (phosdiphen), fosetyl, fosetyl-Al, polyoxins, polyoxorim, polycarbamate, fore Folpet, formaldehyde, machine oil, maneb, mancozeb, mandipropamid, myclozolin, myclobutanil, midodrine Mildiomycin), milneb, mecarbinzid, methasulfocarb, metazoxolon, metam, metam-sodium, chlorpyrifos Metalaxyl, metalaxyl-M, free of metiram, methyl isocyanate, mepthyldinocap, metconazole, thiabicide (me Tsulfovax (draft)), methfuroxam, metominostrobin, metrafenone, mepanipyrim, mefenoxam, meptyldinocap , mepronil, mebenil, iodomethane, rabenzazole, benzalkonium chloride, basic copper chloride , inorganic copper sulphate, inorganic bactericide such as silver, sodium hypochlorite, cupric hydroxide, water and sulfur (wettable sulfur) , calcium polysulfide, potassium hydrogen carbonate, sodium hydrogen carbonate, inorganic sulfur, copper sulfate anhydride, dimethylamine methylthioglycolic acid Nickel Dimethyldithiocarbamate), an oxine-copper copper compound zinc sulfate, copper sulfate pentahydrate, and the like.

同樣做為除草劑例如，可例示1-萘基乙醯胺，2,4-PA，2,3,6-TBA，2,4,5-T，2,4,5-TB，2,4-D，2,4-DB，2,4-DEB，2,4-DEP，3,4-DA，3,4-DB，3,4-DP，4-CPA，4-CPB，4-CPP，MCP，MCPA，脫禾草(MCPA-thioethyl)，MCPB，碘苯腈(ioxinil)，苯草醚(aclonifen)，草芬定(azafenidin)，亞喜芬(acifluorfen)，滅蘇民(aziprotryne)，四唑嘧磺隆(azimsulfuron)，亞速爛(asulam)，乙草胺(acetochlor)，草脫淨(atrazine)，阿特拉通(atraton)，(anisuron)，莎稗磷(anilofos)，艾維激素(aviglycine)，離層酸(abscisic acid)，氨唑草酮(amicarbazone)，嘧磺隆(amidosulfuron)，氨基***(amitrole)，胺環吡克(aminocyclopyrachlor)，氯氨基吡啶酸(aminopyralid)，胺嗪草酮(amibuzin)，甲基胺草磷(amiprophos-methl)，噁唑烷酮(ametridione)，草殺淨(ametryn)，拉草(alachlor)，二丙烯草胺(allidochlor)，亞汰草(alloxydim)，(alorac)，愛速隆(isouron)，丁脒胺(isocarbamid)，異噁氯草酮(isoxachlortole)，異噁草醚(isoxapyrifop)，異噁唑草酮(isoxaflutole)，異噁醯草胺(isoxaben)，丙溴定(isocil)，異草完隆(isonoruron)，異丙隆(isoproturon)，異丙樂靈(isopropalin)，(isopolinate)，異丁胺嗪(isomethiozin)，抗倒胺(inabenfide)，草怕津(ipazine)，***醯草胺(ipfencarbazone)，iprymidam(商品名)，咪唑喹啉酸(imazaquin)，咪唑甲煙酸(imazapic)，依滅草(imazapyr)，甲基咪草煙(imazamethapyr)，咪草酯(imazamethabenz)，甲基咪草酯(imazamethabenz-methyl)，甲氧咪草煙(imazamox)，咪唑乙煙酸(imazethapyr)，依速隆(imazosulfuron)，三嗪茚草胺(indaziflam)，茚 草酮(indanofan)，吲哚丁酸(indolebutyric acid)，烯效唑鉀鹽(uniconazole-P)，甘草津(eglinazine)，戊草丹(esprocarb)，胺苯黃隆(ethametsulfuron)，甲基胺苯黃隆(ethametsulfuron-methyl)，乙丁烯氟靈(ethalfluralin)，硫草敵(ethiolate)，乙基熟酯(ethychlozate ethyl)，磺噻隆(ethidimuron)，賽芬蟎(etinofen)，益收生長素(ethephon)，亞速隆(ethoxysulfuron)，氯氟草醚(ethoxyfen)，etnipromid(商品名)，乙呋草黄(ethofumesate)，乙氧苯草胺(etobenzanid)，***磺(epronaz)，抑草蓬(erbon)，內氧草索(endothal)，樂滅草(oxadiazon)，丙炔噁草酮(oxadiargyl)，噁嗪草酮(oxaziclomefone)，環氧嘧磺隆(oxasulfuron)，草噠松(oxapyrazon)，復祿芬(oxyfluorfen)，氨磺樂靈(oryzalin)，嘧苯胺磺隆(orthosulfamuron)，坪草丹(orbencarb)，唑草胺(cafenstrole)，cambendichlor(商品名)，除草隆(carbasulam)，克繁草(carfentrazone)，乙基克繁草(carfentrazone-ethyl)，卡草靈(karbutilate)，雙醯草胺(carbetamide)，異惡甲草威(carboxazole)，快伏草(quizalofop)，快伏草(quizalofop-P)，快伏草(quizalofop-ethyl)，二甲苯草胺(xylachlor)，靈藻醌(quinoclamine)，醌萍胺(quinonamid)，快克草(quinclorac)，氯甲喹啉酸(quinmerac)，苄草隆(cumyluron)，氯吡啶酯(cliodinate)，嘉磷塞(glyphosate)，固殺草(glufosinate)，拆分草銨膦(glufosinate-P)，醚草敏(credazine)，剋草同(clethodim)，番茄美素(cloxyfonac)，炔草酯(clodinafop)，炔草酯(clodinafop propargyl)，綠麥隆(chlorotoluron)，二氯吡啶酸(clopyralid)，cloproxydim(商品名)，調果酸(cloprop)，氯溴隆(chlorbromuron)，(clofop)，可滅蹤(clomazone)，甲氧基護谷(chlomethoxynil)，甲氧基護谷(chlomethoxyfen)，克普草(clomeprop)，(chlorazifop)，可樂津(chlorazine)，氯酯磺草胺 (cloransulam)，丁醯草胺(chloranocryl)，克爛本(chloramben)，氯酯胺磺隆(cloransulam-methyl)，氯草敏(chloridazon)，氯嘧磺隆(酸)(chlorimuron)，氯嘧磺隆(chlorimuron-ethyl)，氯磺隆(chlorsulfuron)，大克草(chlorthal)，草克樂(chlorthiamid)，綠麥隆(chlortoluron)，全滅草(chlornitrofen)，伐草克(chlorfenac)，燕麥酯(chlorfenprop)，氯炔草靈(chlorbufam)，氟味殺(chlorflurazole)，氯芴素(chlorflurenol)，chlorprocarb(商品名)，氯苯胺靈(chlorpropham)，克美素(chlormequat)，(chloreturon)，羥敵草腈(chloroxynil)，枯草隆(chloroxuron)，三氯丙酸(chloropon)，嘧啶肟草醚(saflufenacil)，氰乃淨(cyanazine)，氰草淨(cyanatryn)，二醛酯(di-allate)，達有龍(diuron)，(diethamquat)，麥草畏(dicamba)，環莠隆(cycluron)，環草特(cycloate)，環殺草(cycloxydim)，雙氯磺草胺(diclosulam)，環磺隆(cyclosulfamuron)，2,4-滴丙酸(dichlorprop)，2,4-滴丙酸(dichlorprop-P)，二氯苯安(dichlobenil)，禾草靈(diclofop)，禾草靈(diclofop-methyl)，苄胺靈(dichlormate)，雙(三氯乙醛基)脲(dichloralurea)，大刈特(diquat)，咯草隆(cisanilide)，disul(商品名)，環草隆(siduron)，汰硫草(dithiopyr)，撻乃安(dinitramine)，環醯草酯(cinidon ethyl)，戊硝酚(dinosam)，西速隆(cinosulfuron)，達諾殺(dinoseb)，硝丁酯(dinoterb)，dinofenate(商品名)，硝丙酚(dinoprop)，丁基賽伏草(cyhalofop-butyl)，雙苯醯草胺(diphenamid)，枯莠隆(difenoxuron)，戊味禾草靈(difenopenten)，雙苯唑快(difenzoquat)，洒布淨(cybutryne)，環丙津(cyprazine)，三環塞草胺(cyprazole)，吡氟醯草胺(diflufenican)，氟吡草腙(diflufenzopyr)，異丙淨(dipropetryn)，環醯草胺(cypromid)，賽伯刈(cyperquat)，激勃素 (gibberellin)，草滅淨(simazine)，草滅散(dimexo)，二甲草胺(dimethachlor)，草噠酮(dimidazon)，異戊乙淨(dimethametryn)，汰草滅(dimethenamid)，西草淨(simetryn)，西瑪通(simeton)，哌草丹(dimepiperate)，丁噁隆(dimefuron)，環庚草醚(cinmethylin)，滅草靈(swep)，磺胺酸(sulglycapin=sulfamic acid)，磺草酮(sulcotrione)，菜草畏(sulfallate)，甲磺草胺(sulfentrazone)，磺醯磺隆(sulfosulfuron)，甲嘧磺隆(sulfometuron)，甲嘧磺隆-甲酯(sulfometuron-methyl)，密草通(secbumeton)，西殺草(sethoxydim)，另丁津(sebuthylazine)，特草定(terbacil)，香草隆(daimuron)，邁隆(dazomet)，得拉本(dalapon)，噻氟隆(thiazafluron)，噻草啶(Thiazopyr)，噻酮磺隆(thiencarbazone)，噻酮磺隆(thiencarbazone-methyl)，仲草丹(tiocarbazil)，(tioclorim)，殺丹(thiobencarb)，噻二唑草胺(thidiazimin)，噻苯隆(thidiazuron)，噻吩磺隆(thifensulfuron)，噻吩磺隆(thifensulfuron-methyl)，甜菜安(desmedipham)，敵草淨(desmetryn)，四氟隆(tetrafluron)，噻吩草胺(thenylchlor))，牧草胺(tebutam)，特丁噻草隆(tebuthiuron)，特丁通(terbumeton)，得殺草(tepraloxydim)，特糠酯酮(tefuryltrione)，環磺酮(tembotrione)，異丁草胺(delachlor)，特草定(terbacil)，特草靈(terbucarb)，特丁草胺(terbuchlor)，特丁津(terbuthylazine)，特丁淨(terbutryn)，苯吡唑草酮(topramezone)，三甲苯草酮(tralkoxydim)，三嗪氟草胺(triaziflam)，醚苯磺隆(triasulfuron)，燕麥畏(tri-allate)，草達津(trietazine)，殺草畏(tricamba)，綠草定(triclopyr)，滅草環(tridiphane)，草達克(tritac)，三氟甲磺隆(tritosulfuron)，氟胺磺隆(triflusulfuron)，氟胺磺隆(triflusulfuron-methyl)，三福林(trifluralin)，三氟啶磺隆鈉鹽(trifloxysulfuron)，(tRIPropindan)，苯磺隆 (tribenuron-methyl)，苯磺隆(tribenuron)，(trifop)，三氟禾草肟(trifopsime)，異草隆(trimeturon)，鈉得爛(naptalam)，萘丙胺(naproanilide)，滅落脫(napropamide)，煙嘧磺隆(nicosulfuron)，滅殺草(nitralin)，除草醚(nitrofen)，三氟甲草醚(nitrofluorfen)，氟氯草胺(nipyraclofen)，草不隆(neburon)，滅草靈(norflurazon)，草完隆(noruron)，燕麥靈(barban)，巴克素(paclobutrazol)，巴拉刈(paraquat)，對氟隆(parafluron)，氟啶草(haloxydine)，氟吡甲禾靈(haloxyfop)，氟吡甲禾靈(haloxyfop-P)，氟吡甲禾靈(haloxyfop-methyl)，halosafen(商品名)，合速隆(halosulfuron)，合速隆(halosulfuron-methyl)，畢克爛(picloram)，氟吡醯草胺(picolinafen)，bicyclopyrone(商品名)，雙草醚(bispyribac)，雙草醚(bispyribac-sodium)，商品名(pydanon)，唑啉草酯(pinoxaden)，必芬諾(bifenox)，哌草磷(piperophos)，殺紋寧(hymexazol)，雙唑草腈(pyraclonil)，磺醯草吡唑(pyrasulfotole)，苄草唑(pyrazoxyfen)，百速隆(pyrazosulfuron)，百速隆(pyrazosulfuron-ethyl)，吡唑特(pyrazolate)，畢拉草(bilanafos)，派芬草(pyraflufen-ethyl)，三氯吡啶醇(pyriclor)，噠草醇(pyridafol)，嘧草硫醚(pyrithiobac)，嘧草硫醚(pyrithiobac-sodium)，必汰草(pyridate)，環酯草醚(pyriftalid)，稗草丹(pyributicarb)，嘧啶肟草醚(pyribenzoxim)，pyrimisulfan(商品名)，氟嘧磺隆(primisulfuron)，嘧草醚(pyriminobac-methyl)，派羅克殺草碸(pyroxasulfone)，甲氧磺草胺(pyroxsulam)，fenasulam(商品名)，棉胺寧(phenisopham)，非草隆(fenuron)，(fenoxasulfone)，芬殺草(fenoxaprop)，芬殺草(fenoxaprop-P)，芬殺草(fenoxaprop-ethyl)，脫禾草(phenothiol)，2,4,5-涕丙酸(fenoprop)，草隆(phenobenzuron)，塞唑禾草靈(fenthiaprop)， (fenteracol)，四唑醯草胺(fentrazamide)，甜菜寧(phenmedipham)，甜菜寧(phenmedipham-ethyl)，丁基拉草(butachlor)，布芬草(butafenacil)，抑草磷(butamifos)，得匍隆(tebuthiuron)，丁硫咪唑酮(buthidazole)，拔敵草(butylate)，播土隆(buturon)，丁烯草胺(butenachlor)，丁氧環酮(butroxydim)，比達寧(butralin)，伏速隆(flazasulfuron)，麥草氟(flamprop)，氧草醚(furyloxyfen)，拔地草(prynachlor)，氟嘧磺隆(primisulfuron-methyl)，伏寄普(fluazifop)，伏寄普(fluazifop-P)，伏寄普(fluazifop-butyl)，異丙吡草酯(fluazolate)，氟氯比(fluroxypyr)，氟硫隆(fluothiuron)，氟草隆(fluometuron)，乙羧氟草醚(fluoroglycofen)，氟咯草酮(flurochloridone)，福泰芬(fluorodifen)，氟除草醚(fluoronitrofen)，氟尿嘧啶核苷(fluorouridine)，氟唑磺隆(flucarbazone)，氟唑磺隆(flucarbazone-sodium)，貝殺寧(fluchloralin)，氟吡磺隆(flucetosulfuron)，嗪草酸(fluthiacet)，嗪草酸甲酯(fluthiacet-methyl)，氟啶嘧磺隆(flupyrsulfuron)，氟噻草胺(flufenacet)，三吡氟草胺(flufenican)，噠嗪氟草酯(flufenpyr)，氟單丙嘧草酯(flupropacil)，氟丙酸(flupropanate)，氟胺草唑(flupoxam)，丙炔氟草胺(flumioxazin)，氟烯草酸(flumiclorac)，氟烯草酸戊酯(flumiclorac-pentyl)，炔草胺(flumipropyn)，(flumezin)，可奪草(fluometuron)，唑嘧磺草胺(flumetsulam)，氟啶酮(fluridone)，呋草酮(flurtamone)，氟氯比(fluroxypyr)，普拉草(pretilachlor)，異丙基黄原酸(proxan)，甘撲津(proglinazine)，環丙腈津(procyazine)，氨基氟樂靈(prodiamine)，甲硫磺樂靈(prosulfalin)，三氟丙磺隆(prosulfuron)，苄草丹(prosulfocarb)，普拔草(propaquizafop)，雷蒙得(propachlor)，普拔根(propazine)，除草靈(propanil)，炔苯草胺 propyzamide，異丙草胺(propisochlor)，茉莉酸丙酯(prohydrojasmon)，嗪咪唑嘧磺隆(propyrisulfuron)，苯胺靈(propham)，氟唑草胺(profluazol)，環丙氟(profluralin)，調環酸鈣鹽(prohexadione-calcium)，丙苯磺隆(propoxycarbazone)，丙苯磺隆鈉(propoxycarbazone-sodium)，環苯草酮(profoxydim)，克草(bromacil)，溴莠敏(brompyrazon)，佈滅淨(prometryn)，撲滅通(prometon)，溴苯腈(bromoxynil)，溴酚肟(bromofenoxim)，溴丁草胺(bromobutide(草案))，除草溴(bromobonil)，雙氟磺草胺(florasulam)，六氯丙酮(hexachloroacetone)，菲殺淨(hexazinone)，烯草胺(pethoxamid)，草除靈(benazolin)，平速爛(penoxsulam)，克草敵(pebulate)，氟丁醯草胺(beflubutamid)，萬隆(vernolate)，佈福松(perfluidone)，bencarbazone(商品名)，苯草多克死(benzadox)，苄草胺(benzipram)，苄寧激素(benzylaminopurine)，苯噻隆(benzthiazuron)，雙苯嘧草酮(benzfendizone)，地散磷(bensulide)，免速隆(bensulfuron-methyl)，新燕靈(benzoylprop)，苯並雙環隆(benzobicyclon)，吡草酮(benzofenap)，氟草黄(benzofluor)，本達隆(bentazone)，甲氯草胺(pentanochlor)，殺丹(benthiocarb)，施得圃(pendimethalin)，環戊惡草酮(pentoxazone)，倍尼芬(benfluralin)，呋草黄(benfuresate)，殺木膦(fosamine)，氟磺胺草醚(fomesafen)，雙氟磺草胺(foramsulfuron)，福芬素(forchlorfenuron)，順丁烯二醯胼(maleic hydrazide)，2甲4丙酸(mecocrop)，高2甲4丙酸(mecocrop-P)，地樂施(medinoterb)，二磺隆(mesosulfuron)，甲基二磺隆(mesosulfuron-methyl)，甲基磺草酮(mesotrione)，滅莠津(mesoprazine)，格草淨(methoprotryne)，滅草胺(metazachlor)，滅殺唑(methazole)，雙醚氯吡嘧磺隆(Metazosulfuron)，甲基苯噻隆 (methabenzthiazuron)，苯嗪草酮(metamitron)，惡唑醯草胺(metamifop)，斯美地(metam)，(methalpropalin)，甲草隆(methiuron)，異惡噻草醚(methiozolin)，methiobencarb(商品名)，甲基殺草隆(methyldymron)，甲氧隆(metoxuron)，磺草唑胺(metosulam)，甲磺隆(metsulfuron)，甲磺隆(metsulfuron-methyl)，二甲噻草伏(metflurazon)，撲奪草(metobromuron)，甲氧苯草隆(metobenzuron)，醚草通(methometon)，莫多草(metolachlor)，滅必淨(metribuzin)，甲哌啶(mepiquat chloride)，滅芬草(mefenacet)，美福泰(mefluidide)，庚草胺(monalide)，單甲異惡隆(monisouron)，靈草隆(monuron)，一氯乙酸(monochloroacetic acid)，綠谷隆(monolinuron)，稻得壯(molinate)，伐草快(morfamquat)，碘磺隆(iodosulfuron)，碘甲磺隆鈉鹽(iodosulfuron-methyl-sodium)，(iodobonil)，碘化甲烷，乳氟禾草靈(lactofen)，理有龍(linuron)，玉嘧磺隆(rimsulfuron)，環草定(lenacil)，硫氰苯胺(rhodethanil)，過氧化鈣，溴化甲烷等。 Also as herbicides, for example, 1-naphthylacetamide, 2,4-PA, 2,3,6-TBA, 2,4,5-T, 2,4,5-TB, 2,4 can be exemplified. -D,2,4-DB,2,4-DEB,2,4-DEP,3,4-DA,3,4-DB,3,4-DP,4-CPA,4-CPB,4-CPP , MCP, MCPA, MCPA-thioethyl, MCPB, ioxinil, aclonifen, azafenidin, acifluorfen, aziprotryne , azimusulfuron, asulam, acetochlor, atrazine, atraton, anisuron, anilofos, Aviglycine, abscisic acid, amizcarbazone, amidosulfuron, aminotrile, aminocyclopyrachlor, chloroaminopyridine acid ( Aminopyralid), amibuzin, amiprophos-methl, ametridione, ametryn, alachlor, allidochlor , alloxydim, (alorac), isouron, isobaramid, isoxachlortole, heterosexual Isoxapyrifop, isoxaflutole, isoxaben, isocil, isororuron, isoproturon, dipyridamole (isoxapyrifop) Isopropalin), (isopolinate), isomethiozin, inabenfide, ipazine, ipfencarbazone, iprymidam (trade name), imidazoquinoic acid (imazaquin) ), Imazacic acid, imazapyr, imazamethapyr, imazamethabenz, imazamethabenz-methyl, imazamox Imazamox), imimazeapyr, imazosulfuron, indaziflam, indole Indanofan, indolebutyric acid, uniconazole-P, eglinazine, esprocarb, ethametsulfuron, methylamine Ethametsulfuron-methyl, ethalfluralin, ethiolate, ethychlozate ethyl, ethidimuron, etinofen, benefit Ethephon, ethoxysulfuron, ethoxyfen, etnipromid (trade name), ethofumesate, etobenzanid, epronaz , erbon, endothal, oxadiazon, oxadiargyl, oxaziclomefone, oxasulfuron, grass Oxapyrazon, oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, cafenstrole, cambendichlor (trade name), weeding Carbosulam, carfentrazone, carfentrazone-ethyl, karbutilate, double Carbamide, carboxazole, quizalofop, quizalofop-P, quizalofop-ethyl, xylachlor, lingual algae Quinoclamine, quinonamid, quinclorac, quinmerac, cumyluron, cliodinate, glyphosate, solid Glufosinate, resolution of glufosinate-P, cedazine, clethodim, cloxyfonac, clodinafop, clodinafop Propargyl), chlorotoluron, clopyralid, cloproxydim (trade name), cloprop, chlorbromuron, clofop, clomazone, A Chlomethoxynil, chlomethoxyfen, clomeprop, chlorazifop, chlorazine, chlorsulfuron (cloransulam), chloranocryl, chloramben, cloransulam-methyl, chloridazon, chlorimuron, chloropyrimidine Chlorimuron-ethyl, chlorsulfuron, chlorthal, chlorthiamid, chlortoluron, chlornitrofen, chlorfenac, oatmeal Chlorfenprop, chlorbufam, chlorflurazole, chlorflurenol, chlorprocarb (trade name), chlorpropham, chlormequat, (chloreturon), Chloroxynil, chloroxuron, chloropon, saflufenacil, cyanazine, cyanatryn, dialdehyde ester (di- Allate), diuron, (diethamquat), dicamba, cycluron, cycloate, cycloxydim, diclosulam, Cyclosulfamuron, 2,4-dipropionic acid, 2,4-dipropionic acid (dichlorprop-P), dichlorobenzone (dichlob) Enil), diclofop, diclofop-methyl, dichlormate, dichloralurea, diquat, oxaloquinone (diil) Cisanilide), disul (trade name), siduron, dithiopyr, dinitramine, cinidon ethyl, dinosam, sagitar Cinosulfuron), dinoseb, dinoterb, dinofenate (trade name), dinoprop, cyhalofop-butyl, diphenamid, Difenoxuron, difenopenten, difenzoquat, cybutryne, cyprazine, cyprazole, pyridoxine Diflufenican, diflufenzopyr, dipropetryn, cypromid, cyperquat, activin (gibberellin), simazine, dimetox, dimethachlor, dimidazon, dimethametryn, dimethenamid, western grass Simetryn, simeton, dimepiperate, dimefuron, cinmethylin, swep, sulglycapin=sulfamic acid, Sulcotrione, sulfallate, sulfentrazone, sulfosulfuron, sulfometuron, sulfometuron-methyl , secbumeton, sethoxydim, sebuthylazine, terbacil, daimuron, dazomet, dalapon, thifluoro Thiazafluron, Thiazopyr, thiencarbazone, thiencarbazone-methyl, tiocarbazil, (tioclorim), thiobencarb, thiadiazole Thidiazimin, thidiazuron, thifensulfuron, thifensulfuron-methyl, beet (desm) Edipham), desmetryn, tetrafluron, thenyl chloride, tebutam, tebuthiuron, terbumeton, killing grass (tepraloxydim), tefuryltrione, tembotrione, delachlor, terbacil, terbucarb, terbuchlor, special Terbuthylazine, terbutryn, topramezone, tralkoxydim, triaziflam, triasulfuron, oatmeal Tri-allate), trietazine, tricamba, triclopyr, tridiphane, tritac, tritosulfuron, fluoride Triflusulfuron, triflusulfuron-methyl, trifluralin, trifloxysulfuron, (tRIPropindan), tribenuron (tribenuron-methyl), tribenuron, (trifop), trifopsime (trifopsime), trimeturon, naptalam, naproanilide, annihilation ( Napropamide), nicosulfuron, nitralin, nitrofen, nitrofluorfen, nipyraclofen, neburon, herbicide Norflurazon, noruron, barban, paclobutrazol, paraquat, parafluron, haloxydine, flupirtine (haloxyfop), haloxyfop-P, haloxyfop-methyl, halosafen (trade name), halosulfuron, halosulfuron-methyl, bic. Picloram, picolinafen, bicyclopyrone (trade name), bispyribac, bispyribac-sodium, trade name (pydanon), pinoxaden, Bifenox, piperophos, hymexazol, pyraclonil, pyrosulfotole, benzoxazol (pyrazoxyfen), pyrazosulfuron, pyrazoosulfuron-ethyl, pyrazolate, bilanafos, pyraflufen-ethyl, pyridinol , pyripafol, pyrithiobac, pyrithiobac-sodium, pyridate, pyrifalid, pyributicarb, pyrimidine Pyriprazole (pyribenzoxim), pyrimisulfan (trade name), primisulfuron, pyriminobac-methyl, pyroxasulfone, pyroxulam, fenasulam Trade name), phenisopham, fenuron, fenoxasulfone, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, defoliation (phenothiol), 2,4,5-propionic acid (fenoprop), phenobenzuron, fenthiaprop, (fenteracol), fentrazamide, phenmedipham, phenmedipham-ethyl, butachlor, butafenacil, butamifos Tebuthiuron, buthidazole, butarate, buturon, butenachlor, butroxydim, butralin , flazasulfuron, flamprop, furyloxyfen, prynachlor, primisulfuron-methyl, fluazifop, fluazifop -P), fluazifop-butyl, fluazolate, fluroxypyr, fluothiuron, fluometuron, fluoroglycofen ), flurochloridone, fluorodifen, fluoronitrofen, fluorouridine, flucarbazone, flucarbazone-sodium, shellfish Fluchloralin, flucetosulfuron, fluthiacet, methyl thiazide Et-methyl), flupyrsulfuron, flufenacet, flufenican, flufenpyr, flupropacil, Flupropanate, flupoxam, flumioxazin, flumiclorac, flumiclorac-pentyl, flumipropyn, Flumezin), fluometuron, flumetsulam, fluridone, flurtamone, fluroxypyr, pretilachlor, isopropyl Proxan, proglinazine, procyazine, prodiamine, prosulfalin, prosulfuron, benzathine (prosulfocarb), propaquizafop, propachlor, propazine, propanil, amphetamine Propyzamide, propisochlor, prohydrojasmon, propyrisulfuron, propham, profluazol, profluralin, circulatory Prohexadione-calcium, propoxycarbazone, propoxycarbazone-sodium, profoxydim, bromacil, brompyrazon, cloth Prometry, prometon, bromoxynil, bromofenoxim, bromobutide (bromobutide), bromobonil, diflufenacil (florasulam) ), hexachloroacetone, hexazinone, pethoxamid, benazolin, penoxsulam, pebulate, flubendiamide Beflubutamid), vernolate, perfluidone, bencarbazone (trade name), benzadox, benzpilamine, benzylaminopurine, benzthiazuron , benzfendizone, bensulide, free speed (bensulfu Ron-methyl), benzoylprop, benzobicyclon, benzofenap, benzofluor, bentazone, pentanochlor, kill Benthiocarb, pendimethalin, pentoxazone, benfluralin, benfuresate, fosamine, fomesafen, difluoro Foramsulfuron, forchlorfenuron, maleic hydrazide, mecocrop, mecocrop-P, dextro Medioterb), mesosulfuron, mesosulfuron-methyl, mesotrione, mesoprazine, methoprotryne, metazachlor , methazole, diether chloropyrazine (Metazosulfuron), methamphetamine (methabenzthiazuron), metaamitron, metamifop, metam, (methalpropalin), methiuron, methiozolin, metiobencarb (methiobencarb) Trade name), methyldymron, metoxuron, metosulam, metsulfuron, metsulfuron-methyl, methicillin Metflurazon), metobromuron, metobenzuron, metometon, metolachlor, metribuzin, mepiquat chloride, fenfen Mefenacet, mefluidide, monalide, monisouron, monuron, monochloroacetic acid, monolinuron, Molding, morfamquat, iodosulfuron, iodosulfuron-methyl-sodium, iodobonil, methane iodide, lactofen ), linuron, rimsulfuron, lenacil, rhodetanil, calcium peroxide , brominated methane, etc.

又，與做為生物農藥，例如，與核型多角體病毒(Nuclear polyhedrosis virus,(NPV))，顆粒體病毒(Granulosis virus,(GV))，細胞質多面體病病毒(cytoplasmic polyhedrosis virus,(CPV))，昆蟲痘病毒(Entomopox virus,(EPV))等的病毒製劑，瘤捕單頂孢菌(Monacrosporium phymatophagum)，蟲生線蟲(Steinernema carpocapsae)，蟲生線蟲(Steinernema kushidai)，穿透巴斯德芽孢菌(Pasteuria penetrans)等，做為殺蟲劑或殺線蟲劑利用的微生物農藥，例如木素木霉(Trichoderma lignorum)，農桿菌(Agrobacterium radiobacter)，非病原性的伊文氏桿菌(Erwinia carotovora)，枯草芽孢桿菌(Bacillus subtilis)等做為殺菌劑使用的微生物農藥，黃原桿 菌(Xanthomonas campestris)等的做為殺草劑使用的生物農藥，混合利用，而可期望同樣的效果。 Also, as a biological pesticide, for example, with nuclear polyhedrosis virus (NPV), Granulosis virus (GV), cytoplasmic polyhedrosis virus (CPV) ), a virus preparation such as Entomopox virus (EPV), Monacrosporium phymatophagum, Steinernema carpocapsae, Steinernema kushidai, penetrating Pasteur A microbial pesticide used as an insecticide or nematicide such as Pasteuria penetrans, such as Trichoderma lignorum, Agrobacterium radiobacter, non-pathogenic Erwinia carotovora , microbial pesticides used as fungicides such as Bacillus subtilis, Huangyuan rod A bio-pesticide used as a herbicide such as Xanthomonas campestris is used in combination, and the same effect can be expected.

再者，與做為生物農藥，例如，寄生蜂豔小蜂(Encarsia formosa)，小繭蜂屬寄生蜂(Aphidius colemani)，食蚜瘿蚊(Aphidoletes aphidimyza)，寄生蜂潛蠅姬小蜂(diglyphus isaea)，寄生性蟎離顎繭蜂(Dacnusa sibirica)，捕食性蟎智利捕植蟍(Phytoseiulus persimilis)，捕食性蟎胡瓜捕植蟎(Amblyseius cucumeris)，捕食性蟲曹氏小黑花椿象(Orius sauteri)，等的天敵生物，白殭菌(Beauveria brongniartii)等的微生物農藥，乙酸(Z)-10-十四烯酯，乙酸(Z,E)-12-十四烷二烯酯((E,Z)-9,12-tetradecadienyl acetate)，乙酸(Z)-8-十二烯酯((Z)-8-dodecenyl acetate)，乙酸(Z)-11-十四烯酯((Z)-11-tetradecenyl acetate)，(Z)-13-二十烯-10-酮((Z)-13-eicosen-10-one)，14-甲基-1-十八烯(14-methyl-1-octadecene)等的費洛蒙劑併用，也是可能的。 Furthermore, as a biological pesticide, for example, Encarsia formosa, Aphidius colemani, Aphidoletes aphidimyza, diglyphus Isaea), parasitic genus Dacnusa sibirica, predatory 螨 Phytoseiulus persimilis, predatory cucurbit cucurbit (Amblyseius cucumeris), predatory worm Cao's small black bud (Orius) Sauteri), natural enemies, such as microbial pesticides such as Beauveria brongniartii, acetic acid (Z)-10-tetradecyl ester, acetic acid (Z, E)-12-tetradecadienyl ester (E ,Z)-9,12-tetradecadienyl acetate), (Z)-8-dodecenyl acetate, (Z)-11-tetradecenyl acetate ((Z)- 11-tetradecenyl acetate), (Z)-13-eicosene-10-one ((Z)-13-eicosen-10-one), 14-methyl-1-octadecene (14-methyl-1- It is also possible to use pheromones such as octadecene).

以下示本發明的化合物的代表的製造法的實施例，但本發明並不受這些實施例所限定。 The examples of the production methods of the compounds of the present invention are shown below, but the present invention is not limited by these examples.

[實施例] [Examples]

參考例1 2-氯-4-三氟甲基-1,3-噻唑基-5-羧酸乙酯的製造 Reference Example 1 Production of ethyl 2-chloro-4-trifluoromethyl-1,3-thiazolyl-5-carboxylate

將依照國際公開第2009-012482號小冊，或J.Heterocyclic Chem.,22，1621至1630(1985)所述的方法製造的2-胺 基-4-三氟甲基-1,3-噻唑基-5-羧酸乙酯(6.0g)溶解於乙腈(50ml)，加氯化亞銅(4.0g)，在冰冷卻下，緩緩費10分鐘滴入亞硝酸三級丁酯(3.09g)。除去冰浴後，加熱迴流下攪拌2小時。放冷後，在反應溶液加乙酸乙酯，以10%鹽酸水溶液清洗，加飽和食鹽水而分液。將有機層以無水硫酸鈉乾燥，減壓濃縮所得的殘渣以氧化矽凝膠管柱層析法精製，得2-氯-4-三氟甲基-1,3-噻唑基-5-羧酸乙酯(4.50g)(產率69%)。 2-Amino-4-trifluoromethyl-1,3-thiazole prepared according to the method described in International Publication No. 2009-012482, or J. Heterocyclic Chem., 22 , 1621 to 1630 (1985) Ethyl 5-carboxylic acid ethyl ester (6.0 g) was dissolved in acetonitrile (50 ml), and cuprous chloride (4.0 g) was added. Under ice cooling, tributyl nitrite (3.09 g) was added dropwise over 10 minutes. ). After removing the ice bath, the mixture was stirred under heating and reflux for 2 hours. After allowing to cool, ethyl acetate was added to the reaction solution, and the mixture was washed with a 10% aqueous hydrochloric acid solution, and brine was added thereto. The organic layer was dried over anhydrous sodium sulfate, and the residue was evaporated to dryness m. Ethyl ester (4.50 g) (yield 69%).

參考例2 2-(2-甲氧乙胺基)-4-三氟甲基-1,3-噻唑基-5-羧酸乙酯的製造 Reference Example 2 Production of ethyl 2-(2-methoxyethylamino)-4-trifluoromethyl-1,3-thiazolyl-5-carboxylate

將在前述反應所得的2-氯-4-三氟甲基-1,3-噻唑基-5-羧酸乙酯(3.30g)溶解於乙腈(30ml)，依序加2-甲氧乙基胺(1.14g)，碳酸鉀(1.76g)，加熱迴流下攪拌2小時。其後，在反應溶液加水，乙酸乙酯而將有機物抽出，加飽和食鹽水而分液。將有機層以無水硫酸鈉乾燥，減壓濃縮所得的殘渣以氧化矽凝膠管柱層析法精製，得2-(2-甲氧乙胺基)-4-三氟甲基-1,3-噻唑基-5-羧酸乙酯(3.75g)(產率99%)。 Ethyl 2-chloro-4-trifluoromethyl-1,3-thiazolyl-5-carboxylate (3.30 g) obtained in the above reaction was dissolved in acetonitrile (30 ml), followed by 2-methoxyethyl Amine (1.14 g) and potassium carbonate (1.76 g) were stirred under reflux for 2 hr. Thereafter, water was added to the reaction solution, and ethyl acetate was taken to extract the organic matter, and saturated brine was added thereto to separate the liquid. The organic layer was dried over anhydrous sodium sulfate, and the residue was evaporated to m. Ethyl thiazolyl-5-carboxylate (3.75 g) (yield 99%).

參考例3 2-(2-甲氧乙胺基)-4-三氟甲基-1,3-噻唑基-5-羧酸的製造 Reference Example 3 Production of 2-(2-methoxyethylamino)-4-trifluoromethyl-1,3-thiazolyl-5-carboxylic acid

將在前述反應所得的2-(2-甲氧乙胺基)-4-三氟甲基-1,3-噻唑基-5-羧酸乙酯(2.40g)溶解於乙醇(20ml)，加氫氧化鉀(1.05g)的水(20ml)溶液，加熱迴流下攪拌2小時。放冷後，在反應溶液減壓濃縮所得的殘渣加水，以甲基三級丁基醚清洗。在水層加10%鹽酸水溶液成為酸性後，將有機物以乙酸乙酯抽出，加飽和食鹽水而分液。將有機層以無水硫酸鈉乾燥，減壓濃縮而得目的物(2.40g)(產率71%)。 Ethyl 2-(2-methoxyethylamino)-4-trifluoromethyl-1,3-thiazolyl-5-carboxylate (2.40 g) obtained in the above reaction was dissolved in ethanol (20 ml). A solution of potassium hydroxide (1.05 g) in water (20 ml) was stirred under reflux for 2 hr. After allowing to cool, the resulting residue was concentrated under reduced pressure of water and water was washed and washed with methyltriethyl ether. After adding a 10% hydrochloric acid aqueous solution to the aqueous layer to make it acidic, the organic substance was extracted with ethyl acetate, and saturated brine was added thereto to separate the liquid. The organic layer was dried over anhydrous sodium sulfate and evaporated.

實施例1 (S)-N-[2-(3,4,5-三氯吡唑-1-基)-1-甲基乙基]-2-(2-甲氧乙胺基)-4-三氟甲基-1,3-噻唑基-5-羧酸醯胺的製造(化合物編號3-11) Example 1 (S)-N-[2-(3,4,5-Trichloropyrazol-1-yl)-1-methylethyl]-2-(2-methoxyethylamino)-4 -Production of trifluoromethyl-1,3-thiazolyl-5-carboxylic acid decylamine (Compound No. 3-11)

將依照國際公開第2008-062878號小冊所述的方法製造的(S)-2-(3,4,5-三氯吡唑-1-基)-1-甲基乙基胺(0.20g)與四氫呋喃(10ml)混合，依序加三乙基胺(0.27g)，2-(2-甲氧乙胺基)-4-三氟甲基-1,3-噻唑-5-羧酸(0.24g)，2-氯-1-甲基吡啶鎓碘(0.27g)，攪拌2小時。在反應溶液加水，乙酸乙酯而抽出有機物，以飽和食鹽水分液，以無水硫酸鈉乾燥。將減壓濃縮所得的殘渣以氧化矽凝膠管柱層析法精製，得目的物(0.42g)。 (S)-2-(3,4,5-Trichloropyrazol-1-yl)-1-methylethylamine (0.20 g) manufactured according to the method described in International Publication No. 2008-062878 ) mixed with tetrahydrofuran (10 ml), followed by the addition of triethylamine (0.27 g), 2-(2-methoxyethylamino)-4-trifluoromethyl-1,3-thiazole-5-carboxylic acid ( 0.24 g), 2-chloro-1-methylpyridinium iodide (0.27 g), stirred for 2 hours. Water was added to the reaction solution, and the organic layer was extracted with ethyl acetate. The residue obtained by concentration under reduced pressure was purified by silica gel column chromatography to give the object (0.42 g).

產率：99% Yield: 99%

物性：116至121℃ Physical properties: 116 to 121 ° C

實施例2 (S)-N-[2-(3,4,5-三氯吡唑-1-基)-1-甲基乙基胺]-2-(2-甲氧乙基甲醯胺)-4-三氟甲基-1,3-噻唑基-5-羧酸醯胺的製造(化合物編號3-74) Example 2 (S)-N-[2-(3,4,5-Trichloropyrazol-1-yl)-1-methylethylamine]-2-(2-methoxyethylformamide Manufacture of -4-trifluoromethyl-1,3-thiazolyl-5-carboxylic acid decylamine (Compound No. 3-74)

將在實施例1所得的(S)-N-[2-(3,4,5-三氯吡唑-1-基)-1-甲基乙基]-2-(2-甲氧乙胺基)-4-三氟甲基-1,3-噻唑基-5-羧酸醯胺(0.40g)溶解於甲酸(5ml)，加熱迴流下攪拌2小時。將減壓濃縮所得的殘渣以氧化矽凝膠管柱層析法精製，得目的物(0.31g)。 (S)-N-[2-(3,4,5-Trichloropyrazol-1-yl)-1-methylethyl]-2-(2-methoxyethylamine) obtained in Example 1 The decyl-4-methyltrifluoromethyl-1,3-thiazolyl-5-carboxylic acid decylamine (0.40 g) was dissolved in formic acid (5 ml) and stirred under reflux for 2 hr. The residue obtained by concentration under reduced pressure was purified by silica gel column chromatography to give the object (0.31 g).

產率：73% Yield: 73%

物性：128至129℃ Physical properties: 128 to 129 ° C

以下表示本發明的代表性的製劑例及試驗例，但本發明並不限定於這些例子。這裏，製劑例中所稱的“份”是表示“重量份”。 Representative formulation examples and test examples of the present invention are shown below, but the present invention is not limited to these examples. Here, the "part" referred to in the formulation examples means "parts by weight".

將以上均勻混合溶解成為乳劑。 The above is uniformly mixed and dissolved into an emulsion.

將以上均勻混合粉碎成為粉劑。 The above is uniformly mixed and pulverized into a powder.

將以上均勻混合，加適量的水捏揉，造粒，乾燥成為粒劑。 The above is uniformly mixed, and an appropriate amount of water is kneaded, granulated, and dried to be a granule.

以上均勻混合粉碎成為水和劑。 The above is uniformly mixed and pulverized into water and an agent.

以下表示本發明的化合物的植物病害防治效果的試驗例，但本發明並不受這些試驗例所限定。 The test examples of the plant disease control effect of the compound of the present invention are shown below, but the present invention is not limited by these test examples.

試驗例1，稻熱病防治效果試驗(水面施用處理) Test Example 1, rice fever control effect test (surface application treatment)

在盆育成的5葉期的稻(品種：金南風)將本申請案之發明化合物以製劑例1同樣調製的乳劑以水稀釋成為所定量而做灌注處理。處理6日後將V8培養基培養而得的稻稻熱病菌(Magnaporthe grisea)的胞子懸浮液噴霧接種，保持於20℃多濕條件下。接種7 日後依試驗例1的判定基準判定防治效果。 In the rice of the 5-leaf stage of the pot culture (variety: Jinnanfeng), the emulsion of the inventive compound of the present application prepared in the same manner as in Formulation Example 1 was diluted with water to be quantified and perfused. After 6 days of treatment, the cell suspension of Magnaporthe grisea cultured in V8 medium was spray-inoculated and kept at 20 ° C under humid conditions. Vaccination 7 The control effect was determined in accordance with the criteria of Test Example 1 in the future.

判定基準 Benchmark

E：防治價0至39% E: Prevention price 0 to 39%

D：防治價40至59% D: Prevention price 40 to 59%

C：防治價60至79% C: Prevention price 60 to 79%

B：防治價80至89% B: Prevention price 80 to 89%

A：防治價90至100% A: Prevention price 90 to 100%

上述的試驗的結果，本發明化合物在處理藥量200gai/10a時表現優異的防治效果，特別是化合物No.1-5，3-1，3-7，3-11，3-12，3-13，3-14，3-15，3-16，3-17，3-18，3-19，3-23，3-24，3-28，3-29，3-32，3-33，3-34，3-40，3-41，3-42，3-43，3-44，3-45，3-58，3-59，3-60，3-62，3-64，3-66，3-68，3-70，3-72，3-74，3-75，3-76，3-77，3-79，3-81，3-83，3-85，3-87，3-89，3-93，3-97，3-101，3-102，3-104，3-105，3-115，3-119，3-121，3-123，3-125，3-127，3-129，3-137，3-151，3-163，3-165，3-167，3-169，3-170，3-171，3-172，3-173，3-174，3-176，3-179，3-180，3-181，3-182，3-188，3-189，3-190，3-191，3-195，3-196，3-197，3-198，3-200，3-201，3-202，3-203，3-204，3-205，3-206，3-208，3-209，3-210，3-211，3-212，3-213，3-215，3-216，3-217，3-218，3-219，3-220，3-221，3-222，3-223，3-224，3-225，3-226，3-227，3-228，3-229， 3-230，3-231，3-232，3-233，3-234，3-237，3-238，3-239，3-242，3-243，3-245，4-3，4-5，4-7，4-9，4-15，4-23，4-25，4-43，4-53，4-55，4-57，4-69，4-70，4-72，4-73，4-74，4-75，4-76，4-77，4-79，5-1，5-3，5-4，6-1，6-2，6-3，6-4，6-6，6-8，6-9，6-11，6-12，6-13，6-21，6-22，6-23，6-34，6-45，6-49，6-50，6-51，6-52，6-54，6-55，6-56，9-1，9-2，9-3，9-4表現判定基準B以上的高活性。另一方面做為比較化合物的，國際公開第2008/062878號小冊所述的化合物II-20，II-62，II-63，II-88，及II-102是，在本試驗中是E。 As a result of the above test, the compound of the present invention exhibited excellent control effects when the treatment amount was 200 gai/10a, particularly Compound No. 1-5, 3-1,3-7, 3-11,3-12, 3- 13,3-14,3-15,3-16,3-17,3-18,3-19,3-23,3-24,3-28,3-29,3-32,3-33, 3-34,3-40,3-43-41,3-42,3-43,3-44,3-45,3-58,3-59,3-60,3-62,3-64,3- 66,3-68,3-70,3-72,3-74,3-75,3-76,3-77,3-79,3-81,3-83,3-85,3-87, 3-89,3-93,3-97,3-101,3-102,3-104,3-105,3-115,3-119,3-121,3-123,3-125,3- 127, 3-129, 3-137, 3-151,3-163, 3-165, 3-167, 3-169, 3-170, 3-171,3-172, 3-173, 3-174, 3-176, 3-179, 3-180, 3-181,3-182, 3-188, 3-189, 3-190, 3-191,3-195, 3-196, 3-197, 3- 198,3-200,3-201,3-202,3-203,3-204,3-205,3-206,3-208,3-209,3-210,3-211,3-212, 3-213,3-215,3-216,3-217,3-218,3-219,3-220,3-221,3-222,3-223,3-224,3-225,3- 226,3-227,3-228,3-229, 3-230,3-231,3-232,3-233,3-234,3-237,3-238,3-239,3-242,3-243,3-245,4-3,4- 5,4-7,4-9,4-15,4-23,4-25,4-43,4-53,4-55,4-57,4-69,4-70,4-72, 4-73,4-74,4-75,4-76,4-77,4-79,5-1,5-3,5-4,6-1,6-2,6-3,6- 4,6-6,6-8,6-9,6-11,6-12,6-13,6-21,6-22,6-23,6-34,6-45,6-49, 6-50, 6-51, 6-52, 6-54, 6-55, 6-56, 9-1, 9-2, 9-3, 9-4 exhibit high activity above the criterion B. On the other hand, as a comparative compound, the compounds II-20, II-62, II-63, II-88, and II-102 described in the International Publication No. 2008/062878 are, in this test, E. .

[產業上的利用可能性] [Industry use possibility]

本發明的噻唑羧醯胺衍生物或其鹽是，比以往的技術有優異的性能，特別是做為在水面施用或箱處理的稻熱病防治劑有用的化合物。 The thiazole carboquinone derivative of the present invention or a salt thereof is superior in performance to the prior art, and is particularly useful as a compound for rice fever control agent which is applied to a surface or a tank.

本申請案是，以在日本提出申請的特願第2012-068171號做為基礎，其內容全部包含在本申請書中。 The present application is based on Japanese Patent Application No. 2012-068171, the entire disclosure of which is incorporated herein.

Claims (7)

一般式(I)表示的噻唑羧醯胺衍生物或其鹽類： {式中，R1表示，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；(4a)(C1-C6)烷氧基；或(5a)鹵(C1-C6)烷氧基；(6a)(C3-C6)環烷基，Y表示，O，S，SO，SO2，-N(R3)-，或-N=C(R3)-(式中，R3表示，(1b)氫原子；(2b)(C1-C6)烷基；(3b)(C2-C6)烯基；(4b)(C2-C6)炔基；(5b)鹵(C1-C6)烷基；(6b)鹵(C2-C6)烯基；(7b)鹵(C2-C6)炔基；(8b)甲醯基；(9b)(C1-C6)烷氧(C1-C6)烷基；(10b)鹵(C1-C6)烷氧(C1-C6)烷基； (11b)(C1-C6)烷硫(C1-C6)烷基；(12b)(C1-C6)烷亞磺醯(C1-C6)烷基；(13b)(C1-C6)烷磺醯(C1-C6)烷基；(14b)(C1-C6)烷氧羰基；(15b)(C1-C6)烷氧(C1-C6)烷羰基；(16b)(C1-C6)烷羰基；(17b)鹵(C1-C6)烷羰基；(18b)(C1-C6)烷氧羰(C1-C6)烷基；(19b)(C3-C6)環烷基；或(20b)(C1-C6)烷氧基)，(1)Y表示，O，S，SO，SO2，或-N(R3)-(R3與前述同)時，R2表示，(1c)胺(C1-C6)烷基；(2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同)；(4c)(C1-C6)烷羰胺(C1-C6)烷基；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基；(7c)單(C1-C6)烷胺羰基；(8c)二(C1-C6)烷胺羰基(二(C1-C6)烷胺基的烷基可以相同或不相同)；(9c)單(C1-C6)烷胺硫羰基；(10c)二(C1-C6)烷胺硫羰基(二(C1-C6)烷胺基的烷基可以相同或 不相同)；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(13c)鹵(C1-C6)烷氧(C1-C6)烷基；(14c)(C2-C6)烯氧(C1-C6)烷基；(15c)(C2-C6)炔氧(C1-C6)烷基；(16c)(C3-C6)環烷氧(C1-C6)烷基；(17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；(19c)(C1-C6)烷羰氧(C1-C6)烷基；(20c)苯(C1-C6)烷氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基；(22c)單(C1-C6)烷胺羰氧(C1-C6)烷基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(28c)(C1-C6)烷氧亞胺(C1-C6)烷基；(29c)N-(C1-C6)烷-N-甲醯胺(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基；(31c)非芳香族雜環基； (32c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環氧(C1-C6)烷基；(37c)芳香族雜環基；(38c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基； (41c)R2與R3鍵合，與其所鍵合的氮原子一起，形成5或6員的含氮脂肪族雜環也可以，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的可以相同或不相同的1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基，(2)Y表示，-N=C(R3)-(R3與前述同)時，R2表示，(1d)(C1-C6)烷基；(2d)(C1-C6)烷氧基；(3d)單(C1-C6)烷胺基；或(4d)二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同)，R4，R5，R6，及R7可以相同或不相同，表示(1e)氫原子；(2e)(C1-C6)烷基；(3e)鹵(C1-C6)烷基； (4e)(C3-C6)環烷基；(5e)(C1-C6)烷羰基；(6e)(C1-C6)烷氧羰基；(7e)(C1-C6)烷氧(C1-C6)烷基；或(8e)R4與R5，R6與R7，R4與R6或R4與R7鍵合，並與其鍵合的碳原子一起形成3至6員的脂肪族環亦可，R8表示，(1f)氫原子；(2f)(C1-C6)烷基；(3f)(C1-C6)烷氧基；(4f)(C3-C6)環烷基；(5f)(C1-C6)烷羰基；(6f)(C3-C6)環烷羰基；(7f)(C1-C6)烷氧羰基；(8f)(C3-C6)環烷氧羰基；或(9f)(C1-C6)烷氧(C1-C6)烷基，X1，X2及X3是可以相同或不相同，表示(1g)氫原子；(2g)鹵原子；(3g)甲醯基；(4g)氰基；(5g)羥亞胺(C1-C6)烷基；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基； (8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基；(10g)(C1-C6)烷硫基；(11g)鹵(C1-C6)烷硫基；(12g)(C1-C6)烷亞磺醯基；(13g)鹵(C1-C6)烷亞磺醯基；(14g)(C1-C6)烷磺醯基；(15g)鹵(C1-C6)烷磺醯基；(16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi)鹵(C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基；(19g)苯(C1-C6)烷基；(20g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代苯(C1-C6)烷基；(21g)(C3-C6)環烷基；(22g)芳香族雜環基；(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基； (24g)芳香族雜環氧基；或(25g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環氧基}。 A thiazole carboquinone derivative represented by the general formula (I) or a salt thereof: Wherein R 1 represents (1a) a halogen atom; (2a) (C 1 -C 6 )alkyl; (3a) a halogen (C 1 -C 6 )alkyl; (4a) (C 1 -C 6 Alkoxy; or (5a) halo(C 1 -C 6 )alkoxy; (6a)(C 3 -C 6 )cycloalkyl, Y represents O,S,SO,SO 2 ,-N ( R 3) -, or -N = C (R 3) - ( wherein, R 3 represents, (1b) a hydrogen atom; (2b) (C 1 -C 6) alkyl; (3b) (C 2 -C 6 ) alkenyl; (4b) (C 2 -C 6 )alkynyl; (5b) halo(C 1 -C 6 )alkyl; (6b)halo(C 2 -C 6 )alkenyl; (7b)halogen (C 2 -C 6 )alkynyl; (8b)carbazinyl; (9b)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (10b)halo (C 1 -C 6 ) Alkoxy (C 1 -C 6 )alkyl; (11b) (C 1 -C 6 )alkylthio(C 1 -C 6 )alkyl; (12b)(C 1 -C 6 )alkylsulfinium (C) 1 -C 6 )alkyl; (13b)(C 1 -C 6 )alkane (C 1 -C 6 )alkyl; (14b)(C 1 -C 6 )alkoxycarbonyl; (15b)(C 1 -C 6 ) alkoxy (C 1 -C 6 )alkylcarbonyl; (16b)(C 1 -C 6 )alkylcarbonyl; (17b)halo(C 1 -C 6 )alkylcarbonyl; (18b) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (19b) (C 3 -C 6 )cycloalkyl; or (20b)(C 1 -C 6 )alkoxy), (1) Y represents, when O, S, SO, SO 2 , or -N(R 3 )-(R 3 is the same as the above), R 2 represents (1c)amine (C 1 -C 6 (2c) mono(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl; (3c)di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl ( The alkyl group of the di(C 1 -C 6 )alkylamino group may be the same or different); (4c) (C 1 -C 6 ) alkylcarbonylamine (C 1 -C 6 )alkyl; (5c) (C 1 -C 6) alkoxycarbonyl amine (C 1 -C 6) alkyl; (6c) (C 1 -C 6) alkylsulfonyl Amides (C 1 -C 6) alkyl; (7C) mono (C 1 - C 6 ) alkylamine carbonyl; (8c) di(C 1 -C 6 )alkylaminecarbonyl (alkyl of di(C 1 -C 6 )alkylamino group may be the same or different); (9c) mono (C 1 -C 6 ) alkylamine thiocarbonyl; (10c) bis(C 1 -C 6 )alkylamine thiocarbonyl (alkyl of bis(C 1 -C 6 )alkylamino group may be the same or different); (11c) hydroxy (C 1 -C 6 )alkyl; (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (13c)halo(C 1 -C 6 )alkoxy (C 1 -C 6 ) an alkyl group; (14c) (C 2 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (15c) (C 2 -C 6 ) alkyne (C 1 -C 6 )alkyl; 16c) (C 3 -C 6 )cycloalkoxy (C 1 -C 6 )alkyl; (17c) bis(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl (di(C 1 - C 6 ) alkoxy alkoxy groups may be the same or different); (18c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (19c (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl (20c) benzene (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (21c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkylcarbonyl; (22c) (C 1 -C 6 )alkylaminecarbonyloxy(C 1 -C 6 )alkyl; (23c)di(C 1 -C 6 )alkylaminecarbonyloxy(C 1 -C 6 )alkyl (di(C 1 ) -C 6) alkylamino alkyl groups may be the same or different); (24c) (C 1 -C 6) alkylthio (C 1 -C 6) alkyl; (25c) (C 1 -C 6) alkyl Sulfos(C 1 -C 6 )alkyl; (26c)(C 1 -C 6 )alkane (C 1 -C 6 )alkyl; (27c)(C 1 -C 6 )alkoxycarbonyl C 1 -C 6 )alkyl; (28c)(C 1 -C 6 )alkoxyimine (C 1 -C 6 )alkyl; (29c)N-(C 1 -C 6 )alkane-N-A Guanidine (C 1 -C 6 )alkyl; (30c) N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; 31c) a non-aromatic heterocyclic group; (32c) having the same or different in the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, Iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii)mercapto and Viii) a substituted non-aromatic heterocyclic group of one or more substituents selected from the group consisting of oxy (=O); (33c) a non-aromatic heterocyclic (C 1 -C 6 )alkyl group; (34c) in the ring On, can be the same or The same, of (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6) alkyl, (v) (C 1 -C 6 ) substituted alkyl of (a) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected one or more substituents An aromatic heterocyclic (C 1 -C 6 )alkyl group; (35c) a non-aromatic heteroepoxy (C 1 -C 6 )alkyl group; (36c) having the same or different in the ring, by (i ) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6) alkyl, (v) (C 1 -C 6) alkoxy , (vi) a halogen-substituted (C 1 -C 6 ) alkoxy group, (vii) a mercapto group and (viii) an oxygen group (=O), a substituted non-aromatic heteroepoxy group having one or more substituents selected (C 1 -C 6 )alkyl; (37c)aromatic heterocyclic; (38c), which may be the same or different, on the ring, from (i) a halogen atom, (ii) a cyano group, (iii) ( C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy And (vii) a substituted aromatic heterocyclic group of one or more substituents selected by a formazan group; (39c) an aromatic heterocyclic ring (C 1 -C 6 )alkyl group; (40c) on the ring Yes, they can be the same or different Of (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6) alkyl, (v) (C 1 -C 6) Alkoxy group, (vi) halogen (C 1 -C 6 ) alkoxy group, and (vii) substituted aromatic heterocyclic (C 1 -C 6 ) alkane having one or more substituents selected from the formyl group (41c) R 2 and R 3 are bonded to form a 5- or 6-membered nitrogen-containing aliphatic heterocyclic ring together with the nitrogen atom to which they are bonded, and the nitrogen-containing aliphatic heterocyclic ring is 0 to 1 Oxygen atom, 0 to 1 sulfur atom, 1 to 2 nitrogen atoms, the nitrogen-containing aliphatic heterocyclic ring may have (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkane (a) an alkyl group or a (viii)oxy group (=O) may be the same or different one or more substituents selected; (42c) a formazan (C 1 -C 6 ) alkyl group; ; (43c) bis (methyl acyl group) (C 1 -C 6) alkyl; (44c) (C 1 -C 6) alkoxy sulfonylurea oxo (C 1 -C 6) alkyl; (45c) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (46c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkoxy(C 1 -C 6 )alkoxy ( C 1 -C 6 )alkyl; or (47c)carboxy (C 1 -C 6 Alkyl, (2) Y represents, -N=C(R 3 )-(R 3 is the same as the above), R 2 represents (1d)(C 1 -C 6 )alkyl; (2d)(C 1 -C 6 ) alkoxy; (3d) mono(C 1 -C 6 )alkylamino; or (4d) di(C 1 -C 6 )alkylamino (di(C 1 -C 6 )alkylamine The alkyl groups may be the same or different, and R 4 , R 5 , R 6 , and R 7 may be the same or different, and represent (1e) a hydrogen atom; (2e) (C 1 -C 6 )alkyl; 3e) halo(C 1 -C 6 )alkyl; (4e)(C 3 -C 6 )cycloalkyl; (5e)(C 1 -C 6 )alkylcarbonyl; (6e)(C 1 -C 6 ) Alkoxycarbonyl; (7e)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; or (8e)R 4 and R 5 , R 6 and R 7 , R 4 and R 6 or R 4 Bonding to R 7 and forming a 3 to 6 membered aliphatic ring together with the carbon atom to which it is bonded, R 8 represents (1f) a hydrogen atom; (2f) (C 1 -C 6 )alkyl; 3f) (C 1 -C 6 )alkoxy; (4f)(C 3 -C 6 )cycloalkyl; (5f)(C 1 -C 6 )alkylcarbonyl; (6f)(C 3 -C 6 ) cycloalkyl-carbonyl group; (7f) (C 1 -C 6) alkoxycarbonyl; (8f) (C 3 -C 6) cycloalkyl alkoxycarbonyl group; or (9f) (C 1 -C 6 ) alkoxy (C 1 - C 6 )alkyl, X 1 , X 2 and X 3 may be the same or different and represent (1 g) a hydrogen atom; (2 g) a halogen atom; (3 g) a formazan group; g) cyano; (5g) hydroxyimine (C 1 -C 6 )alkyl; (6g) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (7g) (C 1 -C 6 )alkyl; (8g) halo(C 1 -C 6 )alkyl; (9g)(C 1 -C 6 )alkoxy; (10g)(C 1 -C 6 )alkylthio; (11g) halo(C 1 -C 6 )alkylthio; (12g) (C 1 -C 6 )alkylsulfinyl; (13g) halo(C 1 -C 6 )alkylsulfinyl; (14g (C 1 -C 6 ) alkanesulfonyl; (15 g) halogen (C 1 -C 6 ) alkanesulfonyl; (16 g) (C 1 -C 6 ) alkoxycarbonyl; (17 g) phenyl; 18g) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 ) a substituted phenyl group having one or more substituents selected from the group consisting of an alkyl group, (v) (C 1 -C 6 ) alkoxy group, and (vi) a halogen (C 1 -C 6 ) alkoxy group; (19 g) Benzene (C 1 -C 6 )alkyl; (20g) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, and (vii)formamidine group selected by one or more substituents substituted phenyl (C 1 -C 6) alkyl; (21g) (C 3 -C 6) cycloalkyl; (22g) aromatic heterocyclic ; (23g) has on the ring, may be the same or different, of (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6 ) an alkyl group, (v) (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) one or more substituents selected from a formazan group a substituted aromatic heterocyclic group; (24g) an aromatic heterocyclic oxy group; or (25g) which may be the same or different from the ring, (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkane An oxy group, and (vii) a substituted aromatic heterocyclic oxy group of one or more substituents selected by a fluorenyl group. 如申請專利範圍第1項所述的噻唑羧醯胺衍生物或其鹽類，其中，R1表示，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；(4a)(C1-C6)烷氧基；或(6a)(C3-C6)環烷基，Y表示，O，S，-N(R3)-，或-N=C(R3)-(式中，R3表示，(1b)氫原子；(2b)(C1-C6)烷基；(8b)甲醯基；(9b)(C1-C6)烷氧(C1-C6)烷基；(11b)(C1-C6)烷硫(C1-C6)烷基；(12b)(C1-C6)烷亞磺醯(C1-C6)烷基；(13b)(C1-C6)烷磺醯(C1-C6)烷基；(14b)(C1-C6)烷氧羰基；(15b)(C1-C6)烷氧(C1-C6)烷羰基； (16b)(C1-C6)烷羰基；(17b)鹵(C1-C6)烷羰基；(18b)(C1-C6)烷氧羰(C1-C6)烷基(19b)(C3-C6)環烷基；或(20b)(C1-C6)烷氧基)，(1)Y表示，O，S，或-N(R3)-(R3與前述同)時，R2表示，(1c)胺(C1-C6)烷基；(2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同)；(4c)(C1-C6)烷羰胺(C1-C6)烷基；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基；(7c)單(C1-C6)烷胺羰基；(9c)單(C1-C6)烷胺硫羰基；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(13c)鹵(C1-C6)烷氧(C1-C6)烷基；(15c)(C2-C6)炔氧(C1-C6)烷基；(16c)(C3-C6)環烷氧(C1-C6)烷基；(17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基； (19c)(C1-C6)烷羰氧(C1-C6)烷基；(20c)苯(C1-C6)烷氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(28c)(C1-C6)烷氧亞胺(C1-C6)烷基；(29c)N-(C1-C6)烷-N-甲醯胺(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基；(31c)非芳香族雜環基；(32c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基， (iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環氧(C1-C6)烷基；(37c)芳香族雜環基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基；(41c)R2與R3鍵合，並與其所鍵合的氮原子一起形成5或6員的含氮脂肪族雜環亦可，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的可以相同或不相同的1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基，(2)Y表示，-N=C(R3)-(R3與前述同)時，R2表示， (2d)(C1-C6)烷氧基；或(4d)二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同)，R4，R5，R6，及R7可以相同或不相同，表示(1e)氫原子；(2e)(C1-C6)烷基；(3e)鹵(C1-C6)烷基；(7e)(C1-C6)烷氧(C1-C6)烷基；或(8e)R4與R5，R6與R7，R4與R6或R4與R7鍵合，並與其鍵合的碳原子一起，形成3至6員的脂肪族環亦可，R8表示，(1f)氫原子；(3f)(C1-C6)烷氧基；(4f)(C3-C6)環烷基；(5f)(C1-C6)烷羰基；或(7f)(C1-C6)烷氧羰基，X1，X2及X3是可以相同或不相同，表示(1g)氫原子；(2g)鹵原子；(4g)氰基；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基；(8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基； (16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi)鹵(C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基；(21g)(C3-C6)環烷基；(22g)芳香族雜環基；(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基；(24g)芳香族雜環氧基；或(25g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環氧基。 The thiazole carboquinone derivative or a salt thereof according to the first aspect of the invention, wherein R 1 represents (1a) a halogen atom; (2a) (C 1 - C 6 ) alkyl; (3a) halogen (C 1 -C 6 )alkyl; (4a)(C 1 -C 6 )alkoxy; or (6a)(C 3 -C 6 )cycloalkyl, Y represents, O,S,-N(R 3 )-, or -N=C(R 3 )- (wherein R 3 represents (1b) a hydrogen atom; (2b) a (C 1 -C 6 ) alkyl group; (8b) a formazan group; (9b (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (11b) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; (12b) (C 1 -C 6 ) alkylene sulfonium (C 1 -C 6 )alkyl; (13b) (C 1 -C 6 ) alkanesulfonyl (C 1 -C 6 )alkyl; (14b) (C 1 -C 6 ) alkane Oxycarbonyl; (15b) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkylcarbonyl; (16b) (C 1 -C 6 ) alkylcarbonyl; (17b) halo(C 1 -C 6 ) alkane a carbonyl group; (18b) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl (19b)(C 3 -C 6 )cycloalkyl; or (20b)(C 1 -C 6 )alkane Oxy), (1) Y represents, O, S, or -N(R 3 )- (R 3 is the same as defined above), R 2 represents (1c)amine (C 1 -C 6 )alkyl; 2c) mono(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl; (3c)di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl (di(C 1 - C 6 ) alkylaminoalkyl groups may be the same or different); (4 c) (C 1 -C 6 )alkylcarbonylamine (C 1 -C 6 )alkyl; (5c)(C 1 -C 6 )alkoxycarbonylamine(C 1 -C 6 )alkyl; (6c)( C 1 -C 6 ) alkanesulfonamide (C 1 -C 6 )alkyl; (7c)mono(C 1 -C 6 )alkylaminecarbonyl; (9c)mono(C 1 -C 6 )alkylaminethiocarbonyl (11c) hydroxy(C 1 -C 6 )alkyl; (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (13c)halo(C 1 -C 6 )alkoxy (C 1 -C 6 )alkyl; (15c)(C 2 -C 6 )alkynyloxy(C 1 -C 6 )alkyl; (16c)(C 3 -C 6 )cycloalkoxy (C 1 -C 6 ) an alkyl group; (17c) a di(C 1 -C 6 ) alkoxy(C 1 -C 6 )alkyl group (the alkoxy group of the di(C 1 -C 6 ) alkoxy group may be the same or different); (18c) (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (19c) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 (20c) phenyl (C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (21c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkylcarbonyl; 23c) two (C 1 -C 6) alkylamino carbonyloxy (C 1 -C 6) alkyl (two (C 1 -C 6) alkylamino alkyl groups may be the same or different); (24c) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; (25c)(C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; (26c)(C 1 -C 6 Alkanesulfonyl (C 1 -C 6 )alkyl; (27c)(C 1 -C 6 )alkoxycarbonyl(C 1 -C 6 )alkyl; (28 c) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (29c) N-(C 1 -C 6 ) alkane-N-formamide (C 1 -C 6 ) alkane (30c) N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (31c) non-aromatic heterocyclic group; 32c) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 ) Alkyl, (v) (C 1 -C 6 ) alkoxy, (vi) halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) selected a substituted non-aromatic heterocyclic group having one or more substituents; (33c) a non-aromatic heterocyclic (C 1 -C 6 )alkyl group; (34c) having the same or different in the ring, (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkane Substituted non-aromatic hybrids of one or more substituents selected from the group consisting of an oxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, (vii) a formazan group and a (viii)oxy group (=O) cycloalkyl (C 1 -C 6) alkyl; (35c) non-aromatic heterocyclic oxy (C 1 -C 6) alkyl; (36c) has on the ring, may be the same or different, of (i) a halogen atom , (ii) cyano, (iii) (C 1 -C 6 )alkyl, (iv) halogen (C 1 -C 6 ) alkane a group selected from the group consisting of (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii)methyl indenyl and (viii)oxy (=O) a substituted non-aromatic heteroepoxy (C 1 -C 6 )alkyl group having one or more substituents; (37c) an aromatic heterocyclic group; (39c) an aromatic heterocyclic ring (C 1 -C 6 )alkyl group (40c) may be the same or different on the ring, consisting of (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C) 6 ) an alkyl group, (v) (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) one or more substituents selected from a formazan group Substituted aromatic heterocyclic (C 1 -C 6 )alkyl; (41c) R 2 is bonded to R 3 and forms a 5 or 6 membered nitrogen-containing aliphatic heterocyclic ring together with the nitrogen atom to which it is bonded The nitrogen-containing aliphatic heterocyclic ring may have 0 to 1 oxygen atom, 0 to 1 sulfur atom, 1 to 2 nitrogen atoms, and the nitrogen-containing aliphatic heterocyclic ring may have (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkane One of the same or different ones selected from the group consisting of an oxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, (vii) a formazan group and a (viii)oxy group (=O). The above substituent; (42c) formazan (C 1 -C 6 )alkyl; (43c) bis(methyloxy)(C 1 -C 6 )alkyl; (44c)(C 1 -C 6 ) alkoxy sulfonylurea oxo (C 1 -C 6) alkyl; (45c) (C 1 -C 6) alkoxycarbonyl oxo (C 1 -C 6) alkyl; (46c) (C 1 -C 6) alkyl Oxygen (C 1 -C 6 ) alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; or (47c)carboxy(C 1 -C 6 )alkyl, (2)Y, -N=C(R 3 )-(R 3 is the same as the above), R 2 represents (2d)(C 1 -C 6 )alkoxy; or (4d)di(C 1 -C 6 )alkylamine The alkyl group of the di(C 1 -C 6 )alkylamino group may be the same or different, and R 4 , R 5 , R 6 , and R 7 may be the same or different, and represent a (1e) hydrogen atom; (2e) (C 1 -C 6 )alkyl; (3e) halo(C 1 -C 6 )alkyl; (7e)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; or (8e R 4 and R 5 , R 6 and R 7 , R 4 and R 6 or R 4 are bonded to R 7 and, together with the carbon atom to which they are bonded, form an aliphatic ring of 3 to 6 members, R 8 And (1f) a hydrogen atom; (3f) (C 1 -C 6 ) alkoxy; (4f) (C 3 -C 6 ) cycloalkyl; (5f) (C 1 -C 6 ) alkylcarbonyl; (7f) (C 1 -C 6 ) alkoxycarbonyl, X 1 , X 2 and X 3 may be the same or different and represent (1 g) a hydrogen atom; (2 g) a halogen (4g) cyano; (6g) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (7g) (C 1 -C 6 )alkyl; (8g) halide C 1 -C 6 )alkyl; (9 g)(C 1 -C 6 )alkoxy; (16 g)(C 1 -C 6 )alkoxycarbonyl; (17 g)phenyl; (18 g) It may be the same or different, of (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo (C 1 -C 6) alkyl, (v) (C 1 -C 6 ) alkoxy group, and (vi) substituted phenyl group of one or more substituents selected by halogen (C 1 -C 6 ) alkoxy group; (21 g) (C 3 -C 6 a cycloalkyl group; (22 g) an aromatic heterocyclic group; (23 g) may be the same or different on the ring, from (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 An alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii a substituted aromatic heterocyclic group of one or more substituents selected by a formazan group; (24 g) an aromatic heterocyclic oxy group; or (25 g) which may be the same or different on the ring, and (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 )alkyl group, (iv) a halogen (C 1 -C 6 )alkyl group, (v) a (C 1 -C 6 ) alkoxy group , (vi) halo (C 1 -C 6) alkoxy, and (vii) acyl selected A By one or more of the substituent of the substituted aromatic heterocyclic group. 如申請專利範圍第1項所述的噻唑羧醯胺衍生物或其鹽類，其中，R1表示，(1a)鹵原子；(2a)(C1-C6)烷基；(3a)鹵(C1-C6)烷基；或(6a)(C3-C6)環烷基，Y表示，O，-N(R3)-，或-N=C(R3)- (式中，R3表示，(1b)氫原子；(2b)(C1-C6)烷基；(8b)甲醯基；(9b)(C1-C6)烷氧(C1-C6)烷基；(11b)(C1-C6)烷硫(C1-C6)烷基；(12b)(C1-C6)烷亞磺醯(C1-C6)烷基；(13b)(C1-C6)烷磺醯(C1-C6)烷基；(14b)(C1-C6)烷氧羰基；(15b)(C1-C6)烷氧(C1-C6)烷羰基；(16b)(C1-C6)烷羰基；(17b)鹵(C1-C6)烷羰基；(18b)(C1-C6)烷氧羰(C1-C6)烷基；(19b)(C3-C6)環烷基；或(20b)(C1-C6)烷氧基)，(1)Y表示，O，或-N(R3)-(R3與前述同)時，R2表示，(1c)胺(C1-C6)烷基；(2c)單(C1-C6)烷胺(C1-C6)烷基；(3c)二(C1-C6)烷胺(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同)；(5c)(C1-C6)烷氧羰胺(C1-C6)烷基；(6c)(C1-C6)烷磺醯胺(C1-C6)烷基；(7c)單(C1-C6)烷胺羰基； (9c)單(C1-C6)烷胺硫羰基；(11c)羥(C1-C6)烷基；(12c)(C1-C6)烷氧(C1-C6)烷基；(17c)二(C1-C6)烷氧(C1-C6)烷基(二(C1-C6)烷氧基的烷氧基可以相同或不相同)；(18c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；(19c)(C1-C6)烷羰氧(C1-C6)烷基；(21c)(C1-C6)烷氧(C1-C6)烷羰基；(23c)二(C1-C6)烷胺羰氧(C1-C6)烷基(二(C1-C6)烷胺基的烷基可以相同或不相同)；(24c)(C1-C6)烷硫(C1-C6)烷基；(25c)(C1-C6)烷亞磺醯(C1-C6)烷基；(26c)(C1-C6)烷磺醯(C1-C6)烷基；(27c)(C1-C6)烷氧羰(C1-C6)烷基；(30c)N-(C1-C6)烷-N-(C1-C6)烷氧羰胺(C1-C6)烷基；(31c)非芳香族雜環基；(32c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環基；(33c)非芳香族雜環(C1-C6)烷基；(34c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以 上的取代基的經取代非芳香族雜環(C1-C6)烷基；(35c)非芳香族雜環氧(C1-C6)烷基；(36c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的1個以上的取代基的經取代非芳香族雜環氧(C1-C6)烷基；(39c)芳香族雜環(C1-C6)烷基；(40c)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環(C1-C6)烷基；(41c)R2與R3鍵合，並與其所鍵合的氮原子一起，形成5或6員的含氮脂肪族雜環亦可，該含氮脂肪族雜環是含0至1個的氧原子，0至1個的硫原子，1至2個的氮原子，該含氮脂肪族雜環是，在環上可以有由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，(vii)甲醯基及(viii)氧基(=O)所選擇的可以相同或不相同的1個以上的取代基；(42c)甲醯氧(C1-C6)烷基；(43c)二(甲醯氧基)(C1-C6)烷基；(44c)(C1-C6)烷磺醯氧(C1-C6)烷基；(45c)(C1-C6)烷氧羰氧(C1-C6)烷基；(46c)(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷氧(C1-C6)烷基；或(47c)羧(C1-C6)烷基， (2)Y表示，-N=C(R3)-(R3與前述同)時，R2表示，(2d)(C1-C6)烷氧基；或(4d)二(C1-C6)烷胺基(二(C1-C6)烷胺基的烷基可以相同或不相同)，R4，R5，R6，及R7可以相同或不相同，表示(1e)氫原子；(2e)(C1-C6)烷基；或(3e)鹵(C1-C6)烷基，R8表示，(1f)氫原子；(3f)(C1-C6)烷氧基；或(4f)(C3-C6)環烷基，X1，X2及X3是可以相同或不相同，表示(1g)氫原子；(2g)鹵原子；(6g)(C1-C6)烷氧亞胺(C1-C6)烷基；(7g)(C1-C6)烷基；(8g)鹵(C1-C6)烷基；(9g)(C1-C6)烷氧基；(16g)(C1-C6)烷氧羰基；(17g)苯基；(18g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，及(vi) 鹵(C1-C6)烷氧基所選擇的1個以上的取代基的經取代苯基；(21g)(C3-C6)環烷基；(22g)芳香族雜環基；或(23g)在環上有，可以相同或不相同，由(i)鹵原子，(ii)氰基，(iii)(C1-C6)烷基，(iv)鹵(C1-C6)烷基，(v)(C1-C6)烷氧基，(vi)鹵(C1-C6)烷氧基，及(vii)甲醯基所選擇的1個以上的取代基的經取代芳香族雜環基。 The thiazole carboquinone derivative or a salt thereof according to the first aspect of the invention, wherein R 1 represents (1a) a halogen atom; (2a) (C 1 - C 6 ) alkyl; (3a) halogen (C 1 -C 6 )alkyl; or (6a)(C 3 -C 6 )cycloalkyl, Y represents, O,-N(R 3 )-, or -N=C(R 3 )- in, R 3 represents, (1b) a hydrogen atom; (2b) (C 1 -C 6) alkyl; (8B) methyl acyl; (9b) (C 1 -C 6) alkoxy (C 1 -C 6 (11b) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; (12b) (C 1 -C 6 )alkylsulfinium (C 1 -C 6 )alkyl; (13b) (C 1 -C 6 ) alkyl sulfonic acyl (C 1 -C 6) alkyl; (14b) (C 1 -C 6) alkoxycarbonyl; (15b) (C 1 -C 6) alkoxy ( C 1 -C 6 )alkylcarbonyl; (16b)(C 1 -C 6 )alkylcarbonyl; (17b)halo(C 1 -C 6 )alkylcarbonyl; (18b)(C 1 -C 6 )alkoxycarbonyl ( C 1 -C 6 )alkyl; (19b)(C 3 -C 6 )cycloalkyl; or (20b)(C 1 -C 6 )alkoxy), (1)Y represents O, or -N When (R 3 )-(R 3 is the same as the above), R 2 represents (1c) an amine (C 1 -C 6 )alkyl group; (2c) a mono(C 1 -C 6 )alkylamine (C 1 -C) 6 ) an alkyl group; (3c) a di(C 1 -C 6 )alkylamine (C 1 -C 6 )alkyl group (the alkyl group of the di(C 1 -C 6 )alkylamino group may be the same or different); 5c) (C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 ) alkyl; (6c) (C 1 -C 6 ) alkanesulfonamide (C 1 -C 6 )alkyl; (7c) mono(C 1 -C 6 )alkylaminecarbonyl; (9c)mono(C 1 -C 6 )alkylaminethiocarbonyl; (11c)hydroxy(C 1 -C 6 )alkyl; (12c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkyl; (17c) (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl (alkoxy of di(C 1 -C 6 ) alkoxy may be the same or different); (18c) (C 1 -C 6 Alkoxy (C 1 -C 6 ) alkoxy (C 1 -C 6 )alkyl; (19c) (C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (21c) (C 1 -C 6) alkoxy (C 1 -C 6) alkylcarbonyl; (23c) two (C 1 -C 6) alkylamino carbonyloxy (C 1 -C 6) alkyl (two (C 1 -C 6) The alkyl group of the alkylamino group may be the same or different); (24c) (C 1 -C 6 )alkylthio (C 1 -C 6 )alkyl; (25c)(C 1 -C 6 )alkylsulfinium ( C 1 -C 6 )alkyl; (26c)(C 1 -C 6 )alkane (C 1 -C 6 )alkyl; (27c)(C 1 -C 6 )alkoxycarbonyl (C 1 -C 6 ) an alkyl group; (30c) N-(C 1 -C 6 ) alkane-N-(C 1 -C 6 ) alkoxycarbonylamine (C 1 -C 6 )alkyl; (31c) non-aromatic heterocyclic ring (32c) on the ring, which may be the same or different, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 - C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi) a substituted non-aromatic heterocyclic group having one or more substituents selected from a halogen (C 1 -C 6 ) alkoxy group, (vii) a formazan group and (viii) anoxy group (=O); (33c) a non-aromatic heterocyclic (C 1 -C 6 )alkyl group; (34c) may be the same or different on the ring, from (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C) 6 ) alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii a substituted non-aromatic heterocyclic (C 1 -C 6 ) alkyl group having one or more substituents selected from the group consisting of a methyl group and (viii) anoxy group (=O); (35c) a non-aromatic heteroepoxy group (C 1 -C 6) alkyl; (36c) has on the ring, may be the same or different, of (i) a halogen atom, (ii) cyano, (iii) (C 1 -C 6) alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halo(C 1 -C 6 )alkoxy, (vii)mercapto and (viii) a substituted non-aromatic heteroepoxy (C 1 -C 6 )alkyl group having one or more substituents selected from the group consisting of an oxygen group (=O); (39c) an aromatic heterocyclic ring (C 1 -C 6 ) (40c) may be the same or different on the ring, from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C) 1 -C 6 )alkyl, (v) a (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) a substituted aromatic heterocyclic ring having one or more substituents selected from a formazan group ( C 1 -C 6 )alkyl; (41c) R 2 is bonded to R 3 and together with the nitrogen atom to which it is bonded, a 5- or 6-membered nitrogen-containing aliphatic heterocyclic ring may be formed, the nitrogen-containing aliphatic group The heterocyclic ring is an oxygen atom having 0 to 1 ring, 0 to 1 sulfur atom, and 1 to 2 nitrogen atoms, and the nitrogen-containing aliphatic heterocyclic ring may have (i) a halogen atom on the ring, Ii) cyano, (iii) (C 1 -C 6 )alkyl, (iv) halo(C 1 -C 6 )alkyl, (v)(C 1 -C 6 )alkoxy, (vi)halogen (C 1 -C 6 ) alkoxy, (vii)methyl indenyl and (viii)oxy (=O) may be the same or different one or more substituents selected; (42c) formazan ( C 1 -C 6 )alkyl; (43c) bis(methyloxy)(C 1 -C 6 )alkyl; (44c)(C 1 -C 6 )alkaneoxy (C 1 -C 6 ) (45c)(C 1 -C 6 ) alkoxycarbonyl (C 1 -C 6 )alkyl; (46c)(C 1 -C 6 )alkoxy(C 1 -C 6 )alkoxy (C 1 -C 6) alkoxy (C 1 -C 6) alkyl; or (47c) carboxymethylcellulose (C 1 -C 6) alkyl, (2) Y represents, -N = C (R 3) - (R 3 When the same as the above, R 2 represents (2d) (C 1 -C 6 ) alkane An oxy group; or (4d) a di(C 1 -C 6 )alkylamino group (the alkyl group of the di(C 1 -C 6 )alkylamino group may be the same or different), R 4 , R 5 , R 6 , and R 7 may be the same or different and represents (1e) a hydrogen atom; (2e) (C 1 -C 6 )alkyl; or (3e) a halogen (C 1 -C 6 )alkyl group, R 8 represents, (1f) a hydrogen atom; (3f)(C 1 -C 6 )alkoxy; or (4f)(C 3 -C 6 )cycloalkyl, X 1 , X 2 and X 3 may be the same or different, indicating (1 g a hydrogen atom; (2 g) a halogen atom; (6 g) (C 1 -C 6 ) alkoxyimine (C 1 -C 6 )alkyl; (7 g) (C 1 -C 6 )alkyl; (8 g) Halogen (C 1 -C 6 )alkyl; (9 g)(C 1 -C 6 )alkoxy; (16 g)(C 1 -C 6 )alkoxycarbonyl; (17 g)phenyl; (18 g) in the ring And may be the same or different from (i) a halogen atom, (ii) a cyano group, (iii) a (C 1 -C 6 ) alkyl group, (iv) a halogen (C 1 -C 6 ) alkyl group, ( v) (C 1 -C 6 ) alkoxy group, and (vi) a substituted phenyl group having one or more substituents selected by a halogen (C 1 -C 6 ) alkoxy group; (21 g) (C 3 - C 6 ) cycloalkyl; (22 g) aromatic heterocyclic group; or (23 g) having the same or different in the ring, from (i) a halogen atom, (ii) a cyano group, (iii) (C 1 -C 6 )alkyl, (iv)halo(C 1 -C 6 )alkyl, (v a (C 1 -C 6 ) alkoxy group, (vi) a halogen (C 1 -C 6 ) alkoxy group, and (vii) a substituted aromatic heterocyclic ring having one or more substituents selected from a formazan group base. 如申請專利範圍第1項至第3項中任一項所述的噻唑羧醯胺衍生物或其鹽類，其中，R4表示，(C1-C6)烷基或鹵(C1-C6)烷基，R5，R6，及R7表示，氫原子。 The thiazole carboquinone derivative or a salt thereof according to any one of claims 1 to 3, wherein R 4 represents a (C 1 -C 6 )alkyl group or a halogen (C 1 - C 6 )alkyl, R 5 , R 6 , and R 7 represent a hydrogen atom. 一種植物病害防治劑，其特徵為：以申請專利範圍第1項至第4項中任一項所述的噻唑羧醯胺衍生物或其鹽類做為有效成分。 A phytochemical inhibitor according to any one of claims 1 to 4, wherein the thiazolcarbamide derivative or a salt thereof is used as an active ingredient. 一種植物病害的防治方法，其特徵為：以申請專利範圍第1項至第4項中任一項所述的噻唑羧醯胺衍生物或其鹽類的有效量處理對象作物及/或對象作物的種子。 A method for controlling a plant disease, which comprises treating an object crop and/or a target crop with an effective amount of the thiazolcarbamide derivative or a salt thereof according to any one of claims 1 to 4 Seed. 一種申請專利範圍第1項至第4項中任一項所述的噻唑羧醯胺衍生物或其鹽類的用途，係將噻唑羧醯胺衍生物或其鹽類做為植物病害防治劑。 The use of the thiazole carboquinone derivative or a salt thereof according to any one of claims 1 to 4, wherein the thiazolcarbamide derivative or a salt thereof is used as a plant disease controlling agent.
TW102110201A 2012-03-23 2013-03-22 Thiazolylcarboxamide deriviate and methoud using the same TW201343644A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2012068171 2012-03-23

Publications (1)

Publication Number Publication Date
TW201343644A true TW201343644A (en) 2013-11-01

Family

ID=49222810

Family Applications (1)

Application Number Title Priority Date Filing Date
TW102110201A TW201343644A (en) 2012-03-23 2013-03-22 Thiazolylcarboxamide deriviate and methoud using the same

Country Status (6)

Country Link
JP (1) JPWO2013141362A1 (en)
KR (1) KR20140138931A (en)
CN (1) CN104302644A (en)
CO (1) CO7101252A2 (en)
TW (1) TW201343644A (en)
WO (1) WO2013141362A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3121202A1 (en) 2018-11-30 2020-06-04 Nuvation Bio Inc. Pyrrole and pyrazole compounds and methods of use thereof
CN111763663B (en) * 2020-07-09 2022-04-15 昆明理工大学 Gastrodia elata glucosyltransferase gene and application thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL374970A1 (en) * 2002-08-02 2005-11-14 Argenta Discovery Limited Substituted thienyl-hydroxamic acids as histone deacetylase inhibitors
EP1710237A1 (en) * 2005-04-08 2006-10-11 Bayer CropScience S.A. New heterocyclylethylbenzamide derivatives
EP2518065A1 (en) * 2005-04-08 2012-10-31 Bayer CropScience AG N-(furanylethyl)-heterocyclylcarboxamide derivatives as fungicides
TWI435863B (en) * 2006-03-20 2014-05-01 Nihon Nohyaku Co Ltd N-2-(hetero) arylethylcarboxamide derivative and pest controlling
JP5205274B2 (en) * 2006-11-22 2013-06-05 日本農薬株式会社 Novel pyrazole derivatives, pest control agents and methods of use thereof
AR078793A1 (en) * 2009-10-27 2011-12-07 Orion Corp DERIVATIVES OF NON-STEROID CARBOXAMIDS AND ACIL HYDRAZONE MODULATORS OF ANDROGENIC RECEPTORS OF SELECTIVE FABRIC (SARM), PHARMACEUTICAL COMPOSITIONS CONTAINING THEM AND USE OF THE SAME IN THE TREATMENT OF PROSTATE CANCER BETWEEN OTHERS
JP2012092033A (en) * 2010-10-26 2012-05-17 Nippon Nohyaku Co Ltd 2-aminothiazole carboxamide derivative and method for using the same

Also Published As

Publication number Publication date
JPWO2013141362A1 (en) 2015-08-03
CO7101252A2 (en) 2014-10-31
KR20140138931A (en) 2014-12-04
CN104302644A (en) 2015-01-21
WO2013141362A1 (en) 2013-09-26

Similar Documents

Publication Publication Date Title
TWI696612B (en) Condensed heterocyclic compound having a cycloalkylpyridyl group or a salt thereof, agricultural and horticultural insecticide containing the compound, and method of using the same
WO2017061497A1 (en) Condensed heterocyclic compound or salts thereof, agricultural and horticultural insecticide containing said compound, and method for using same
CN105051045A (en) Fused heterocyclic compound or salt thereof, agricultural and horticultural insecticide containing fused heterocyclic compound, and method for using agricultural and horticultural insecticide
ES2902667T3 (en) Fused heterocyclic compound having oxime group or salts thereof, agricultural/horticultural insecticide containing these compounds, and method of using this insecticide
KR102579996B1 (en) Anthranilic acid ester compounds or salts thereof and agricultural and horticultural fungicides containing the compounds and methods of using the same
KR102216655B1 (en) 1H-pyrrolopyridine compound, or its N-oxide, or its salts, and agricultural and horticultural insecticides containing the compound and method of use thereof
CN105722822A (en) Amide compound or salt thereof, agricultural/horticultural insecticide/bactericide containing said compound, and method for using same
JP7165681B2 (en) Oxadiazole compound or salt thereof, agricultural and horticultural fungicide containing said compound, and method of using the same
WO2018084142A1 (en) Quinoline compound having oxime group, n-oxide or salt thereof, agricultural and horticultural insecticide comprising same and method for use thereof
JP2018123056A (en) Bactericide composition and method for use thereof
JP7485667B2 (en) Oxadiazole compounds or salts thereof, agricultural and horticultural fungicides containing said compounds, and methods of using the same
WO2016060230A1 (en) Horticultural fungicide and method of using same
TW201343644A (en) Thiazolylcarboxamide deriviate and methoud using the same
JP7407114B2 (en) Oxadiazoline compounds or salts thereof, agricultural and horticultural fungicides containing the compounds, and methods for using the same
WO2021090865A1 (en) Oxadiazoline compound or salts thereof, agricultural and horticultural bactericide containing said compound, and method for using same
JP2017226638A (en) Substituted benzanilide compound or salts thereof, agricultural antibacterial agent containing the compound and use method thereof
UA128104C2 (en) Agricultural and horticultural insecticide or animal ecto- or endo-parasite controlling agent which contains imidazopyridazine compound having substituted cyclopropane oxadiazole group or salts thereof as active ingredient, and usage method of same
WO2015159913A1 (en) Plant disease control method
WO2022138017A1 (en) Oxadiazole compound or salt thereof, and agricultural/horticultural microbicide containing said compound, and method for using same
JP2021127303A (en) Oxadiazoline compound or salt thereof, agricultural and horticultural antimicrobial agents containing that compound, and method of use thereof
TW202342432A (en) Aryltetrahydropyridazine derivative or salt thereof and insecticidal agent containing the compound and method for using the same
WO2013111885A1 (en) Benzyloxypyrimidine oxide derivative, pesticide for agricultural and horticultural use containing benzyloxypyrimidine oxide derivative, and use of same
KR20220045681A (en) Novel Compound for Crop Protection
JP2017141196A (en) Thiazole carboxamide derivative and method for use thereof