TW201332445A - Pest control composition - Google Patents
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- TW201332445A TW201332445A TW101149487A TW101149487A TW201332445A TW 201332445 A TW201332445 A TW 201332445A TW 101149487 A TW101149487 A TW 101149487A TW 101149487 A TW101149487 A TW 101149487A TW 201332445 A TW201332445 A TW 201332445A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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Abstract
Description
本發明是關於一種有害生物防除組成物及一種有害生物控制方法。 The present invention relates to a pest control composition and a pest control method.
一種下述式(1)表示的酯化合物已知具有對有害節足動物有防除效果(例如，參照專利文獻1)： An ester compound represented by the following formula (1) is known to have a control effect against harmful arthropods (for example, refer to Patent Document 1):
專利文獻1：JP-A-2004-2363 Patent Document 1: JP-A-2004-2363
本發明之目的是提供一種有害生物防除組成物及防除有害動物的方法，該組成物對有害動物有優異的防除功效。 SUMMARY OF THE INVENTION An object of the present invention is to provide a pest control composition and a method for controlling a harmful animal which have excellent control effects against harmful animals.
本發明者為了要找出具有優異的防除功效的組成物而已精心地研究，發現一種含有以下述式(1)表示的酯化合物及以下述式(2)表示的檸檬酸三酯的組成物對有害動物具有優異的防除功效，因此已完成本發明。 The present inventors have intensively studied in order to find a composition having excellent control effect, and found a composition pair containing an ester compound represented by the following formula (1) and a citrate triester represented by the following formula (2). The pests have excellent control effects, and thus the present invention has been completed.
具體而言，本發明包括下述發明： In particular, the invention includes the following inventions:
[1]一種有害生物防除組成物，係包括式(1)表示的酯化合物及式(2)表示的檸檬酸三酯。 [1] A pest control composition comprising an ester compound represented by the formula (1) and a citric acid triester represented by the formula (2).
[2]如[1]項所述的蟲害防除組成物，其中式(1)表示的酯化合物與式(2)表示的檸檬酸三酯的重量比是4：1至1：300。 [2] The pest control composition according to [1], wherein the weight ratio of the ester compound represented by the formula (1) to the citrate triester represented by the formula (2) is from 4:1 to 1:300.
[3]如[1]項所述的蟲害防除組成物，其中式(I)表示的酯化合物與式(2)表示的檸檬酸三酯的重量比是1：1至1：100。 [3] The pest control composition according to [1], wherein the weight ratio of the ester compound represented by the formula (I) to the citrate triester represented by the formula (2) is from 1:1 to 1:100.
[4]如[1]至[3]任一項所述的蟲害防除組成物，其中檸檬酸三酯是檸檬酸三乙酯。 [4] The pest control composition according to any one of [1] to [3] wherein the citrate triester is triethyl citrate.
[5]一種防除有害生物的方法，係包括將如[1]至[4]任一項所述的蟲害防除組成物施用於有害生物或其棲息場所。 [5] A method for controlling pests, which comprises applying the pest control composition according to any one of [1] to [4] to a pest or a habitat thereof.
本發明的有害生物防除組成物有優異的防除有害生物的功效。 The pest control composition of the present invention has an excellent pest control effect.
本發明的有害生物防除組成物含有式(1)表示的酯化合物(以下稱為「本案酯化合物」)及式(2)表示的檸檬酸三酯(以下稱為「本案檸檬酸三酯」)。 The pest control composition of the present invention contains an ester compound represented by the formula (1) (hereinafter referred to as "the ester compound of the present invention") and a citrate triester represented by the formula (2) (hereinafter referred to as "citrate triester"). .
本案酯化合物可以，例如，以JP-A20032363等所述方法製造。 The ester compound of the present invention can be produced, for example, by the method described in JP-A 20032363 or the like.
本案酯化合物有基於在環丙烷環上的兩個不對稱碳原子及基於環丙烷環上取代基的雙鍵的異構物。在本發明中，以任何比率含有活性異構物的酯化合物都可使用。 The ester compound of the present invention has an isomer based on two asymmetric carbon atoms on a cyclopropane ring and a double bond based on a substituent on a cyclopropane ring. In the present invention, an ester compound containing an active isomer in any ratio can be used.
本案酯化合物可舉例如：[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲基(1R)-3-(2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸酯，[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲基(1R)-反-3-(2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸酯，[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲基(1R)-順-3-(2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸酯，[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲基(1R)-反-3-((E)-2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸酯，及[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲基(1R)-順-3-((Z)-2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸酯。 The ester compound of the present invention may, for example, be: [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl(1R)-3-(2-cyano-1-propenyl) -2,2-dimethylcyclopropanecarboxylate, [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl(1R)-trans-3-(2 -Cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylate, [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ( 1R)-cis-3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylate, [2,3,5,6-tetrafluoro-4-(methoxy Methyl)phenyl]methyl(1R)-trans-3-((E)-2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylate, and [2,3 ,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl(1R)-cis-3-((Z)-2-cyano-1-propenyl)-2,2- Dimethylcyclopropanecarboxylate.
作為本案檸檬酸三酯，可使用市上可買到的商品或可用已知方法製造的化合物。 As the citric acid triester in the present case, a commercially available product or a compound which can be produced by a known method can be used.
式(2)的「C2至C4烷基」的例包括乙基、丙基、異丙基、丁基、異丁基及三級丁基。 Examples of the "C2 to C4 alkyl group" of the formula (2) include an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, and a tertiary butyl group.
本案檸檬酸三酯包括檸檬酸三乙酯、檸檬酸三丙酯、檸檬酸三異丙酯、檸檬酸三丁酯、檸檬酸三異丁酯，及檸檬酸三級丁酯；而檸檬酸三乙酯特別較佳。 The citrate triester in the present case includes triethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate, triisobutyl citrate, and butyl citrate; and citric acid three Ethyl ester is particularly preferred.
在本發明的有害生物防除組成物中所含的本案檸檬酸三酯可以是1種或2種以上。 The citrate triester of the present invention contained in the pest control composition of the present invention may be one type or two or more types.
本發明的有害生物防除組成物表現防除功效(殺蟲功效、擊斃功效、驅除功效等)的有害生物包括有害節足動物例如有害昆蟲及有害蟎。具體的例包括下列。 The pest controlling composition of the present invention exhibits control effects (insecticidal efficacy, killing effect, repellent effect, etc.) of harmful organisms including harmful arthropods such as harmful insects and harmful cockroaches. Specific examples include the following.
麟翅目(Lepidoptera)有害生物：螟蛾科例如二化螟蟲(Chilo suppressalis)、稻縱捲葉野螟(Cnaphalocrocis medinalis)，及印度穀螟蛾(Plodia interpunctella)：夜蛾科(Noctuidae)例如斜紋夜蛾(Spodoptera litura)、黏夜蛾(Pseudaletia separate)，及甘藍夜蛾(Mamestra brassicae)；粉蝶科(Pieridae)，例如白粉蝶(Pieis rapae)；捲蛾科(Tortricidae)，例如茶姬捲葉蛾(Adoxophyes orana)；蛀果蛾科(Carposinidae)；萊氏蛾科(Lyonetiidae)毒蛾科(Lymantriidae)；加拿大夜蛾(Autographa)；夜蛾科(Agrotis spp.)屬，例如：蕪菁夜蛾(Agrotis segetum)及球菜夜蛾(Agrotis ipsilon)；番茄夜蛾屬(Helicoverpa spp)；玉米穗蟲屬(Heliothis spp)；小菜蛾(Plutella xylostella)；稻弄蝶(Parnara guttata)；袋穀蛾(Tinea pellionella)；衣蛾(Tineolabis selliella)；等。 Lepidoptera pests: the genus Corydalis such as Chilo suppressalis, Cnaphalocrocis medinalis, and Plodia interpunctella: Noctuidae such as twill Spodoptera litura, Pseudaletia separate, and Mamestra brassicae; Pieridae, such as Pieris rapae; Tortricidae, such as Chaga leaf moth ( Adoxophyes orana); Carposinidae; Lyonetiidae Lymantriidae; Autographa; Agrotis spp., for example: Agrotis segetum And Agrotis ipsilon; Helicoverpa spp; Heliothis spp; Plutella xylostella; Parnara guttata; Tinea pellionella ); Tineolabis selliella; and so on.
雙翅目(Diptera)有害生物：家蚊屬(Culex spp.)例如尖音庫蚊淡色亞種(Culex pipiens pallens)及三斑家蚊(Culex tritaeniorhynchus)；斑蚊屬(Aedes spp)例如埃及斑蚊(Aedes aegypti)及白線斑蚊(Aedes albopictus)；瘧蚊屬(Anopheles spp.)例如中華瘧蚊(Anopheles sinensis)；搖蚊科(Chironomidae)；蠅科(Muscidae)例如家蠅(Musca domestica)，廄腐蠅(Muscina stabulans)及黃腹廁蠅(Fannia canicularis)；麗蠅科(Calliphoridae)；肉蠅科(Sarcophagidae)；花蠅科(Anthomyiidae)例如灰地種蠅(Delia platura)及蔥地種蠅(Delia antique)；果實蠅科(Tephritidae)；潛蠅科(Agromyzidae)；果蠅科(Drosophilidae)；蛾蚋科(Psychodidae)；蚤蠅科(Phoridae)；虻科(Tabanidae)；蚋科(Simuliidae)；庫蠓屬(Culicoides)；蠓科(Ceratopogonidae)；等。 Diptera pests: Culex spp., such as Culex pipiens pallens and Culex pipiens Trideeniorhynchus); Aedes spp such as Aedes aegypti and Aedes albopictus; Anopheles spp. such as Anopheles sinensis; Chironomidae Muscidae such as Musca domestica, Muscina stabulans and Fannia canicularis; Calliphoridae; Sarcophagidae; Anthemyiidae For example, Delia platura and Delia antique; Tephritidae; Agromyzidae; Drosophilidae; Psychodidae; Phoridae; Tabanidae; Simuliidae; Culicoides; Ceratopogonidae; et al.
脈紅螢屬(Dictyoptera)有害生物：德國蜚蠊(Blattella germanica)，黑褐家蠊(Periplaneta fuliginosa)，美洲蜚蠊(Periplaneta americana)，棕色家蠊(Periplaneta brunnea)，東方蠊(Blatta orientalis)，等。 Dictyoptera pests: Blattella germanica, Periplaneta fuliginosa, Periplaneta americana, Periplaneta brunnea, Blatta orientalis, Wait.
膜翅目(Hymenoptera)有害生物：蟻科(Formicidae)，胡蜂科(Vespidae)，蟻形蜂科(Bethylidae)，葉蜂科(Tenthredinidae)例如紅角菜葉蜂(Athalia rosae ruficorns)，等。 Hymenoptera pests: Formicidae, Vespidae, Bethylidae, Tenthredinidae, such as Athalia rosae ruficorns, and the like.
蚤目(Siphonaptera)有害生物：狗蚤(Ctenocephalides canis)，貓蚤(Ctenocephalides felis)，人蚤(Pulex irritans)，等。 Siphonaptera pests: Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, etc.
蝨目(Anoplura)有害生物：蝨子(Pediculus humanus)，陰蝨(Pthius pubis)，頭蝨(Pediculus humanus capitis)體蝨(Pediculus humans corporis)，等。 Anoplura pests: Pediculus humanus, Pthius pubis, Pediculus humanus capitis (Pediculus humans corporis), et al.
等翅目(Isoptera)有害生物：大和白蟻(Reticulitermies speratus)，有翅型家白蟻(Coptotermes formosanus)，等。 Isoptera pests: Reticulitermies speratus, Coptotermes formosanus, etc.
半翅目(Hemiptera)有害生物：稻蝨科(Delphacidae)例如斑飛蝨(Laodelphax triatellus)，褐飛蝨(Nilaparvata lugens)，及白背飛蝨(Sogatella furcifera)；角頂葉蟬科(Deltocephalidae)例如偽黑尾葉蟬(Nephotettix cincticeps)及台灣黑尾葉蟬(Nephotettix virescens)；常蚜科(Aphididae)；蝽科(Pentatomidae)；粉蝨科(Aleyrodidae)；介殼蟲總科(Coccoidea)；臭蟲科(Cimicidae)例如臭蟲(Cimex lectularius)；網蝽科(Tingidae)；木蝨科(Psyllidae)，等。 Hemiptera pests: Delphacidae such as Laodelphax triatellus, Nilaparvata lugens, and Sogatella furcifera; Deltocephalidae such as pseudo Nephotettix cincticeps and Nephotettix virescens; Aphididae; Pentatomidae; Aleyrodidae; Coccoidea; Bugidae Cimicidae) such as bed bug (Cimex lectularius); Tingidae; Psyllidae, et al.
鞘翅目(Coleoptera)有害生物：毛皮蠹(Attagenus japonicas)；紅斑皮蠹(Anthrenus verbasci)；玉米根蟲(Diabrotica spp)例如西部玉米食蟲(Diabrotica virgifera virgifera)及十一星黃瓜葉甲(Diabrotica undecimpunctata howardi)；金龜子科(Scarabaeidae)例如金銅金龜(Anomala cuprea)及大豆赤金龜(Anomala rufocuprea)；象鼻蟲科(Curculionidae)例如玉米象(Sitophilus zeamais)，水稻水象鼻蟲(Lissorhoptrus oryzophilus)，棉鈴象鼻蟲(Anthonomus grandis)，及綠豆象(Callosobruchus chinensis)；擬步行科(Tenebrionidae)例如麵包蟲(Tenebrio molitor)及擬穀盜(Tribolium castaneum)；金花蟲科(Chrysomelidae)例如稻負泥蟲(Oulema oryzae)，黃條葉蚤(Phyllotreta Striolata)，及黃守瓜(Aulacophora femoralis)；標本甲科(Anobiidae)；瓢蟲屬(Epilachna spp)例如茄二十八星瓢蟲(Epilachna vigintioctopunctata)；粉蠹科(Lyctidae)；長蠹蟲科(Bostrychidae)；天牛科(Cerambycidae)；蟻型隱翅蟲(Paederus fuscipes)；等。 Coleoptera pests: Attagenus japonicas; Anthrenus verbasci; Diabrotica spp such as Diabrotica virgifera virgifera and Diabrotica undecimpunctata Howardi); Scarabaeidae such as Anomala cuprea and Anomala rufocuprea; Curculionidae such as Sitophilus zeamais, Rice water weevil (Lissorhoptrus oryzophilus), cotton boll Wetvil (Anthonomus grandis), and mung bean (Callosobruchus chinensis); Tenebrionidae (Tenebrio molitor) and Tribolium castaneum; Chrysomelidae (Chrysomelidae) such as rice worm (Oulema oryzae), Phyllotreta Striolata, and Aulacophora femoralis; Anobiidae; Epilachna spp, such as Epilachna vigintioctopunctata; Lyctidae; Bostrychidae; Cerambycidae; Paederus fuscipes );Wait.
纓翅目(Thysanoptera)有害生物：南黃薊馬(Thrips palmi)，西方花薊馬(Frankliniella occidental)，花薊馬(Thrips hawaiiens)，等。 Thysanoptera pests: Thrips palmi, Frankliniella occidental, Thrips hawaiiens, etc.
直翅目(Orthoptera)有害生物：螻蛄科(Gryllotalpidae)，蝗科(Acrididae)，等。 Orthoptera pest: Gryllotalpidae, Acrididae, et al.
蟎目(Acarina)有害生物：皮刺蟎科(Dermanyssidae)例如美洲室塵蟎(Dermatophagoides farinae)及歐洲室塵蟎(Dermatophagoides pteronyssinus)；粉蟎科(Acaridae)例如腐食酪蟎(Tyrophagus putrescentiae)及橢圓食粉蟎(Aleuroglyphus ovatuus)；食甜蟎科(Glycyphagidae)例如隱秘甘蟎(Glycyphagus privatus)，家食甜蟎(Glycyphagus domesticus)，及長鬚粉蹣(Glycyphagus destructor)；肉食蟎科(Cheyletidae)例如馬六甲肉食蟎(Cheyletus malaccensis)及肉食蟎屬(Cheyletus fortis)；細蟎科(Tarsonemidae)；嗜草蟎屬屬(Cortoglyphus spp.)；禽刺蟎科(Haplochthoniidae)；葉蟎科(Tetranychidae)例如二點葉蟎(Tetranychus urticae)，神澤氏葉蟎(Tetranychus kanzawai)，柑桔葉蟎(Panonychus citri)，及歐洲紅葉蟎(Panonychus ulmi)；硬蜱科(Ixodidae)例如長角血蜱(Haemaphysalis longicornis)；皮刺蟎科(Dermanyssidae)例如巨刺蟎科(Ornithonyssus sylviarum)及家禽蝨子(Dermanyssus gallinae)。 Acarina pests: Dermanyssidae such as Dermatophagoides farinae and Dermatophagoides pteronyssinus; Acaridae such as Tyrophagus putrescentiae and ellipse Aleuroglyphus ovatuus; Glycyphagidae such as Glycyphagus privatus, Glycyphagus domesticus, and Glycyphagus destructor; Cheyletidae, for example Cheyletus malaccensis and Cheyletus fortis; Tarsonemidae; Cortoglyphus spp.; Haplochthoniidae; Tetranychidae Tetranychus urticae, Tetranychus kanzawai, Panonychus citri, and Panonychus ulmi; Ixodidae such as Haemaphysalis longicornis ); Dermanyssidae such as Ornithonyssus sylviarum and Dermanyssus gallinae.
特別是，本發明的有害生物防除組成物對雙翅目有害生物、脈紅螢屬有害生物及半翅目有害生物有優異的防除功效。 In particular, the pest control composition of the present invention has excellent control effects against dipteran pests, genus Rhodopsin, and hemipteran pests.
在本發明的有害生物防除組成物中，本案酯化合物與本案檸檬酸三酯的含量比率是通常以重量比自4：1至1：300，較佳是自1：1至1：100，及更較佳是自1：2至1：20。本發明的有害生物防除組成物如含有2種或更多種的本案檸檬酸三酯時，本案酯化合物與本案檸檬酸三酯的總重量的含量比率是如上述的本案酯化合物對本案檸檬酸三酯的含量比率。 In the pest control composition of the present invention, the content ratio of the ester compound of the present invention to the citrate triester of the present invention is usually from 4:1 to 1:300 by weight, preferably from 1:1 to 1:100, and More preferably, it is from 1:2 to 1:20. When the pest control composition of the present invention contains two or more kinds of citrate triesters, the ratio of the total weight of the ester compound of the present invention to the citrate triester of the present invention is as described above for the ester compound of the present invention. The ratio of the content of the triester.
在本發明的有害生物房治組成物中，可使用原有的本案酯化合物及本案檸檬酸三酯的混合物。然而，通常是以下述的調配物使用。調配物的例子包括溶液，油性溶液，乳溶液，可濕性粉劑，可流動性劑(水性懸浮液，水性乳液，等)，微膠囊劑，粉末劑，顆粒劑，錠劑，氣霧劑，二氧化碳調配物，加熱蒸散調配物(殺蟲香棒，電殺蟲盤，吸液芯型熱蒸發型殺蟲劑等)，壓力型殺蟲調配物，加熱燻蒸劑(自燃型燻蒸劑，化學反應型燻蒸劑，多孔性陶瓷板燻蒸劑，等)，不加熱蒸散調配物(樹脂蒸散調配物，紙蒸散調配物，不織布蒸散調配物，針織物蒸散調配物，可昇華的錠劑，等)，燻煙調配物(生霧，等)，直接接觸調配物(薄片狀接觸調配物，帶狀接觸調配物，網狀接觸調配物，等)，超低容量懸浮(ULV)調配物，及毒餌。 In the pesticidal composition of the present invention, a mixture of the original ester compound of the present invention and the citrate triester of the present invention can be used. However, it is usually used in the formulation described below. Examples of the formulation include a solution, an oily solution, a milk solution, a wettable powder, a flowable agent (aqueous suspension, aqueous emulsion, etc.), a microcapsule, a powder, a granule, a lozenge, an aerosol, Carbon dioxide preparation, heating and evapotranspiration (insecticide stick, electric insecticidal tray, wicking type thermal evaporation type insecticide, etc.), pressure type insecticide preparation, heating fumigant (self-ignition type fumigant, chemical reaction Type fumigant, porous ceramic plate fumigant, etc.), non-heated evapotranspiration (resin evapotranspiration, paper evapotranspiration, non-woven evapotranspiration, knit evapotranspiration, sublimable lozenges, etc.) Smoked formula (fog, etc.), direct contact with the formulation (flaky contact formulation, ribbon contact formulation, mesh contact formulation, etc.), ultra low volume suspension (ULV) formulation, and bait.
調配物的方法而言，可舉例如下述的方法。 The method of the preparation may, for example, be the following method.
(1)將本案酯化合物及本案檸檬酸三酯與固體承載物、液體承載物、氣體承載物、誘餌等混合，並如有需要，添加界面活性劑及/或調配物之其他補助劑，再處理而得混合物的方法。 (1) mixing the ester compound of the present invention and the citrate triester of the present invention with a solid carrier, a liquid carrier, a gas carrier, a bait, etc., and if necessary, adding a surfactant and/or other auxiliary agent of the formulation, and then A method of treating a mixture.
(2)將不含活性成分的基材浸泡本案酯化合物及本案檸檬酸三酯的混合物的方法。 (2) A method of immersing a substrate containing no active ingredient in a mixture of the ester compound of the present invention and the citrate triester of the present invention.
(3)將本案酯化合物，本案檸檬酸三酯及基材混合而接著模製的方法。 (3) A method in which the ester compound of the present invention, the citric acid triester of the present invention and the substrate are mixed and then molded.
這些調配物通常含有總量0.001至98重量%之本案酯化合物及本案檸檬酸三酯。 These formulations usually contain a total amount of from 0.001 to 98% by weight of the ester compound of the present invention and the citrate triester of the present invention.
調配物所使用的固體承載物包括細粉劑及顆粒黏土(高嶺黏土，矽藻土，膨潤土，文挾黏土，酸性白土，等)，合成 合水氧化矽，滑石，陶瓷，其他無機礦物(絲雲母，石英，硫，活性碳，碳酸鈣，合水氧化矽，等)及化學肥料(硫酸銨，磷酸銨，硝酸銨，氯化銨，尿素等)；固體物質在常溫下(2,4,6-三異丙基-1,3,5-三烷，萘，對-二氯苯，樟腦，金剛烷，等)；及毛毯，纖維，布，針織物，薄片，紙，紗，泡沫體，多孔性體及包括下列者之多絲纖維：1種或2種或更多種的毛料、絲、棉、麻，紙漿，合成樹脂(例如，聚乙烯系樹脂如低密度聚乙烯；直鏈低-密度聚乙烯樹脂，及高密度聚烯樹脂，乙烯-乙烯酯共聚物例如乙烯-乙烯乙酸酯共聚物；乙烯-丙烯酸酯共聚物例如乙烯-甲基丙烯酸甲酯共聚物及乙烯-甲基丙烯酸乙酯共聚物；乙烯-丙烯酸酯類共聚物例如乙烯-丙烯酸甲酯共聚物及乙烯-丙烯酸乙酯共聚物；乙烯-乙烯羧酸共聚物例如乙烯-丙烯酸共聚物；乙烯-四環十二烯共聚物；聚丙烯系樹脂例如丙烯均聚物及丙烯-乙烯共聚物；聚-4-甲基戊烯-1，聚丁烯-1，聚丁二烯，及聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯系彈性物例如丙烯腈-丁二烯-苯乙烯樹脂，苯乙烯-共軛化二烯崁段共聚物，及苯乙烯共軛化之二烯崁段共聚物氫化產物；氟樹脂；丙烯樹脂例如聚甲基丙烯酸甲酯；聚醯胺系樹脂例如尼龍6及尼龍66；聚酯系樹脂例如聚乙烯對苯二甲酸酯，聚乙烯萘酸酯，聚丁烯對苯二甲酸酯，及聚對苯二甲酸環己烯二亞甲酯；及多孔性樹脂例如聚碳酸配，聚縮醛，聚丙烯碸，聚丙烯酸酯，羥苯甲酸聚酯；聚醚亞醯胺，聚酯碳酸配，聚伸苯基醚樹脂；聚氯乙烯，聚氯亞乙烯，聚胺基甲酸酯，發泡聚胺基甲酸酯，發泡聚丙烯，及發泡乙烯)，玻璃，金屬，陶 瓷，等。 The solid supports used in the formulation include fine powder and granular clay (kaolin clay, diatomaceous earth, bentonite, sorghum clay, acid clay, etc.), synthetic hydrous cerium oxide, talc, ceramics, other inorganic minerals (mica, Quartz, sulfur, activated carbon, calcium carbonate, hydrazine oxide, etc.) and chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, ammonium chloride, urea, etc.); solid matter at room temperature (2, 4, 6- Triisopropyl-1,3,5-three Alkanes, naphthalenes, p-dichlorobenzene, camphor, adamantane, etc.; and felts, fibers, cloths, knits, flakes, paper, yarns, foams, porous bodies and multifilament fibers including: 1 Or two or more kinds of wool, silk, cotton, hemp, pulp, synthetic resin (for example, polyethylene resin such as low density polyethylene; linear low-density polyethylene resin, and high-density polyolefin resin, Ethylene-vinyl ester copolymers such as ethylene-ethylene acetate copolymers; ethylene-acrylate copolymers such as ethylene-methyl methacrylate copolymers and ethylene-ethyl methacrylate copolymers; ethylene-acrylate copolymers For example, ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; ethylene-ethylene carboxylic acid copolymer such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin such as propylene homopolymer And propylene-ethylene copolymer; poly-4-methylpentene-1, polybutene-1, polybutadiene, and polystyrene; acrylonitrile-styrene resin; styrene elastomer such as acrylonitrile- Butadiene-styrene resin, styrene-conjugated diene a segment copolymer, and a hydrogenated product of a styrene-conjugated diene-rhodium segment copolymer; a fluororesin; an acrylic resin such as polymethyl methacrylate; a polyamide resin such as nylon 6 and nylon 66; a polyester resin such as Polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, and polyhexamethylene terephthalate; and porous resin such as polycarbonate, polycondensation Aldehyde, polypropylene oxime, polyacrylate, hydroxybenzoic acid polyester; polyether amide, polyester carbonate, polyphenylene ether resin; polyvinyl chloride, polyvinyl chloride, polyurethane, Foamed polyurethane, expanded polypropylene, and foamed ethylene), glass, metal, ceramic, and the like.
液體承載物的例包括芳香族或脂肪族烴類(二甲苯，甲苯，烷基萘，苯基二甲苯基乙烷，煤油，輕油，己烷，環己烷，等)、(鹵化烴類(氯苯，二氯甲烷，二氯乙烷，三氯乙烷，等)，醇類(甲醇，乙醇，異丙基醇，丁醇，己醇，苄醇，乙二醇，等)，醚(二***，乙二醇二甲基醚，二乙二醇單甲基醚，二乙二醇單乙基醚，丙二醇單甲基醚，四氫呋喃，二烷，等)，酯類(乙酸乙酯及乙酸丁酯)，酮類(丙酮，甲基乙基酮，甲基異丁基酮，環己酮，等)，植物油類(黃豆油，棉子油，等)，植物精油類(橘子油，牛膝草油，檸檬油，等)，及水。 Examples of the liquid carrier include aromatic or aliphatic hydrocarbons (xylene, toluene, alkylnaphthalene, phenyldimethylphenylethane, kerosene, light oil, hexane, cyclohexane, etc.), (halogenated hydrocarbons) (chlorobenzene, methylene chloride, dichloroethane, trichloroethane, etc.), alcohols (methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, etc.), ethers (diethyl ether, ethylene glycol dimethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, tetrahydrofuran, two Alkanes, etc.), esters (ethyl acetate and butyl acetate), ketones (acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.), vegetable oils (yellow soybean oil, cottonseeds) Oil, etc.), plant essential oils (orange oil, hyssop oil, lemon oil, etc.), and water.
氣體承載物之例包括丁烷氣，氯氟碳氣，液化石油氣(LPG)，二甲基醚，氮，及二氧化碳氣體。 Examples of gas carriers include butane gas, chlorofluorocarbon gas, liquefied petroleum gas (LPG), dimethyl ether, nitrogen, and carbon dioxide gas.
界面活性劑之例包括硫酸烷酯，磺酸烷酯，磺酸烷芳酯，烷芳基醚，聚氧乙烯化烷芳基醚，山梨糖醇酐脂肪酸酯，聚氧乙烯山梨糖醇酐脂肪酸酯，聚乙二醇醚，多元醇酯，及糖醇衍生物。 Examples of the surfactant include alkyl sulfate, alkyl sulfonate, alkyl aryl sulfonate, alkyl aryl ether, polyoxyethylated alkyl aryl ether, sorbitan fatty acid ester, polyoxyethylene sorbitan anhydride. Fatty acid esters, polyethylene glycol ethers, polyol esters, and sugar alcohol derivatives.
調配物的其他補助劑之例包括黏著劑，分散劑，及安定劑，等。其具體例包括酪蛋白，明膠，多糖類(澱粉，***樹膠，纖維素衍生物，海藻酸，等)，木質素衍生物，膨潤石，醣類，合成水溶性聚合物(聚乙烯醇，聚乙烯吡咯酮，聚丙烯酸，等)，BHT(2,6-二-三級丁基-4-甲基酚)，及BHA(2-三級丁基-4甲氧基酚及3-三級丁基-4-甲基酚的混合物)。 Examples of other adjuvants for the formulation include adhesives, dispersing agents, and stabilizers, and the like. Specific examples thereof include casein, gelatin, polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonites, sugars, synthetic water-soluble polymers (polyvinyl alcohol, poly Vinylpyrrolidone, polyacrylic acid, etc.), BHT (2,6-di-tert-butyl-4-methylphenol), and BHA (2-tert-butyl-4-methoxyphenol and 3- to 3-stage) a mixture of butyl-4-methylphenol).
殺蟲香棒的基材之例包括植物粉末混合物例如木屑及除蟲菊粉末及黏著劑例如椨粉，澱粉，及麵筋。 Examples of the substrate of the insecticidal incense stick include plant powder mixtures such as wood chips and pyrethrum powders and adhesives such as lotus root starch, starch, and gluten.
電殺蟲盤的基材之例包括盤形棉絨(plate-shaped cotton linter)及紙漿混合物所成的盤形纖絲。 Examples of the substrate of the electric insecticidal disc include a disc-shaped filament formed of a plate-shaped cotton linter and a pulp mixture.
自燃型燻蒸劑之基材例包括可燃性放熱劑例如硝酸鹽，亞硝酸鹽，胍鹽，氯酸鉀，硝化纖維素，乙基纖維素，及木屑粉末；熱解促進劑例如鹼金屬鹽，鹼土金屬鹽，二鉻酸鹽，及鉻酸鹽。氧供應劑例如硝酸鉀；助燃劑例如三聚氰胺及小麥澱粉；增量劑例如矽藻土；及黏著劑例如合成膠合劑。 Examples of the substrate of the self-igniting fumigant include flammable exothermic agents such as nitrates, nitrites, strontium salts, potassium chlorate, nitrocellulose, ethyl cellulose, and wood chip powders; pyrolysis accelerators such as alkali metal salts, alkaline earth metals Salt, dichromate, and chromate. Oxygen supply agents such as potassium nitrate; combustion improvers such as melamine and wheat starch; extenders such as diatomaceous earth; and adhesives such as synthetic cements.
化學反應型燻蒸劑的基材之例包括放熱劑例如硫化物，聚硫化物，及鹼金屬的硫氫化物，及氧化鈣；觸媒例如含碳物質，碳化鐵，及活化白黏土；有機發泡劑例如偶氮雙甲醯胺，苯硫醯肼，二硝基五亞甲基四胺，聚苯乙烯及聚胺基甲酸酯；及填充例如天然纖維片及合成纖維片。 Examples of the substrate of the chemical reaction type fumigant include an exothermic agent such as sulfide, polysulfide, and an alkali metal hydrosulfide, and calcium oxide; a catalyst such as a carbonaceous substance, iron carbide, and activated white clay; Foaming agents such as azobisformamide, phenylthioindole, dinitropentamethylenetetramine, polystyrene and polyurethane; and filling, for example, natural fiber sheets and synthetic fiber sheets.
作為樹脂蒸散調配物的基材用的樹脂之例包括聚乙烯系樹脂例如低密度聚乙烯樹脂，直鏈低密度聚乙烯樹脂，及高密度聚乙烯樹脂；乙烯-乙烯酯共聚物例如乙烯-乙烯乙酸酯共聚物；乙烯-丙烯酸酯共聚物例如乙烯-甲基丙烯酸甲酯共聚物及乙烯-甲基丙烯酸乙酯共聚物；乙烯-丙烯酸酯類共聚物例如乙烯-丙烯酸甲酯共聚物及乙烯-丙烯酸乙酯共聚物；乙烯-乙烯羧酸共聚物如乙烯-丙烯酸共聚物；乙烯-四環十二烯共聚物；聚丙烯系樹脂例如丙烯均聚合物及丙烯-乙烯共聚物；聚-4-甲基戊烯-1，聚丁烯-1，聚丁二烯，及聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯系彈性物例如丙烯腈-丁二烯-苯乙烯樹脂，苯乙烯共軛化之二烯崁段共聚物，及苯乙烯共軛化之二烯崁段共聚物氫化產物；氟樹脂；丙烯酸樹脂例如聚甲基丙烯酸甲酯；醯胺系樹脂例如尼龍6及尼 龍66；聚酯系樹脂例如聚乙烯對苯二甲酸酯，聚乙烯萘酸酯，聚丁烯對苯二甲酸酯，及聚環己烯二亞甲基對苯二甲酸酯；及多孔性樹脂例如聚碳酸酯，聚縮醛，聚丙烯碸，聚丙烯酸酯，羥苯甲酸聚酯，聚醚亞醯胺，聚酯碳酸酯，聚伸苯基醚樹脂，聚氯乙烯，聚二氯亞乙烯，及聚胺基甲酸酯。這些基材可以單獨使用或2種以上之組合使用，且如有必要，在這些基材中可添加可塑劑例如酞酸酯(酞酸二甲酯，酞酸二辛酯，等)，己二酸酯，及硬脂酸。樹脂蒸散調配物可藉由將本案酯化合物及本案檸檬酸三酯捏揉於基材中而得，繼而以注入成形，押出成形，加壓成形等而成形。所得的樹脂調配物也可再經過成形及切割等的步驟，如有必要，成為板狀，膜狀，帶狀，網這些樹脂調配物可加工成為，例如，動物項圈，動物耳標，薄片調配物，導繩(guide string)，及園藝支架(horticultural supports)。 Examples of the resin used as the substrate for the resin evaporation formulation include a polyethylene resin such as a low density polyethylene resin, a linear low density polyethylene resin, and a high density polyethylene resin; and an ethylene-vinyl ester copolymer such as ethylene-ethylene Acetate copolymer; ethylene-acrylate copolymer such as ethylene-methyl methacrylate copolymer and ethylene-ethyl methacrylate copolymer; ethylene-acrylate copolymer such as ethylene-methyl acrylate copolymer and ethylene - ethyl acrylate copolymer; ethylene-ethylene carboxylic acid copolymer such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin such as propylene homopolymer and propylene-ethylene copolymer; poly-4 -methylpentene-1, polybutene-1, polybutadiene, and polystyrene; acrylonitrile-styrene resin; styrene elastomer such as acrylonitrile-butadiene-styrene resin, styrene Conjugated diene oxime copolymer, and styrene conjugated diene oxime copolymer hydrogenated product; fluororesin; acrylic resin such as polymethyl methacrylate; guanamine resin such as nylon 6 and nitrite Long 66; polyester resin such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, and polycyclohexene dimethylene terephthalate; Porous resin such as polycarbonate, polyacetal, polypropylene hydrazine, polyacrylate, hydroxybenzoic acid polyester, polyether amide, polyester carbonate, polyphenylene ether resin, polyvinyl chloride, poly Chloroethylene, and polyurethane. These substrates may be used singly or in combination of two or more kinds, and if necessary, a plasticizer such as phthalic acid ester (dimethyl phthalate, dioctyl phthalate, etc.) may be added to these substrates. Acid esters, and stearic acid. The resin evapotranspiration preparation can be obtained by kneading the ester compound of the present invention and the citric acid triester of the present invention on a substrate, followed by injection molding, extrusion molding, press molding, and the like. The obtained resin formulation can also be subjected to steps such as forming and cutting, and if necessary, into a plate shape, a film shape, a belt shape, and a mesh. These resin formulations can be processed into, for example, animal collars, animal ear tags, and sheet blending. Objects, guide strings, and horticultural supports.
毒餌的基材之例包括誘餌成分例如穀粉，植物油，糖，及結晶性纖維素；抗氧化劑例如二丁基羥甲苯及去甲二氫愈創木酸(nordihydroguaiaretic acid)；防腐劑例如去氫乙酸；兒童及寵物防誤食劑例如辣椒粉；及有害生物引誘香味例如乳酪香味，洋蔥香味及花生油。 Examples of the substrate of the bait include bait components such as cereal flour, vegetable oil, sugar, and crystalline cellulose; antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid; preservatives such as dehydroacetic acid Children and pet anti-ingestion agents such as paprika; and harmful organisms such as cheese flavor, onion flavor and peanut oil.
在本發明有害生物防除組成物中，除了本案酯化合物及本案檸檬酸三酯之外，可以混合或併用有害生物防除劑，驅除劑，增效劑等。 In the pest control composition of the present invention, in addition to the ester compound of the present invention and the citrate triester of the present invention, a pest control agent, a repellent, a synergist or the like may be mixed or used in combination.
可混合或併用的其他有害生物防除劑的活性成分之例包括下列成分。 Examples of the active ingredients of other pest control agents which may be mixed or used include the following ingredients.
(1)合成除蟲菊類化合物 (1) Synthesis of pyrethrum compounds
阿納寧(acrinathrin)，丙烯除蟲菊酯(allethrin)，他賽扶寧(beta-cyfluthrin)，畢芬寧(bifenthrin)，乙氰菊酯(cycloprothrin)，氟氯氰菊酯(cyfluthrin)，賽洛寧(cyhalothrin)，亞滅寧(cypermethrin)，烯炔菊酯(empenthrin)，溴氰菊酯(deltamethrin)，高氰戊菊酯(esfenvalerate)，醚菊酯(ethofenprox)，芬普寧(fenpropathrin)，芬化利(fenvalerate)，護賽寧(flucythrinate)，福芬諾氟(flufenoprox)，氟氯苯菊酯(flumethrin)，福化利(fluvalinate)，合芬寧(halfenprox)，依普寧(imiprothrin)，百滅寧(permethrin)，普亞列寧(prallethrin)，除蟲菊酯(pyrethrins)，列滅寧(resmethrin)，賽滅寧(sigma-cypermethrin)，矽護芬(silafluofen)，七氟菊酯(tefluthrin)(草案)，泰滅寧(tralomethrin)，拜富寧(transfluthrin)，治滅寧(tetramethrin)，酚丁滅寧(phenothrin)，賽酚寧(cyphenothrin)，亞滅寧(alpha-cypermethrin)，傑他賽滅寧(zeta-cypermethrin)，賽洛寧(lambda-cyhalothrin)，伽瑪賽洛寧(gamma-cyhalothrin)，炔呋菊酯(furamethrin)，福化利(tau-Fluvalinate)，2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯，2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-甲基苯基]甲酯，2,2-二甲基-3-(2-甲基-1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧甲基)苯基]甲酯，2,2,3,3-四甲基環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯，等； Acrinathrin, allethrin, beta-cyfluthrin, bifenthrin, cycloprothrin, cyfluthrin, cyhalothrin , cypermethrin, ementhrin, deltamethrin, esfenvalerate, ethofenprox, fenpropathrin, fenproline Fenvalerate), flucythrinate, flufenoprox, flumethrin, fluvalinate, halfenprox, imiprothrin, baifenning (permethrin), prallethrin, pyrethrins, resmethrin, sigma-cypermethrin, silafluofen, tefluthrin (tefluthrin) Draft), tralmethrin, transfluthrin, tetramethrin, phenothrin, cyphenothrin, alpha-cypermethrin, Jade Zeta-cypermethrin, lambda-cyhalothrin, gamma-cynin Yhalothrin), furamethrin, tau-Fluvalinate, 2,2-dimethyl-3-(1-propenyl)cyclopropanecarboxylic acid [2,3,5,6-four Fluoro-4-(methoxymethyl)phenyl]methyl ester, 2,2-dimethyl-3-(1-propenyl)cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4 -methylphenyl]methyl ester, 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(A Oxymethyl)phenyl]methyl ester, 2,2,3,3-tetramethylcyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]- Ester, etc.
(2)有機磷化合物 (2) Organic phosphorus compounds
毆殺松(acephate)，磷化鋁，脫甲基丁嘧啶磷(butathiofos)，加奪松(cadusafos)，氯氧磷(chlorethoxyfos)，氯芬松(chlorfenvinphos)，陶斯松(chlorpyrifos)，甲基陶斯松(chlorpyrifos methyl)，氰乃松(cyanophos)，CYAP，大利松(diazinon)，DCIP二氯二異丙基醚，除線磷(dichlofenthion)，ECP，二氯松(dichlorvos)；DDVP，大滅松(dimethoate)，甲基毒蟲畏(dimethylvinphos)，二硫松(disulfoton)，EPN，愛殺松(ethion)，普伏松(ethoprophos)，益多松(etrimfos)，芬殺松(fenthion)；MPP，撲滅松(fenitrothion)：MEP，福賽絕(fosthiazate)，福木松(formothion)，磷化氫；亞芬松(isofenphos)，加福松(isoxathion)，馬拉松(malathion)，倍硫磷亞碸(mesulfenfos)，滅大松(methidathion)，DMTP，亞素靈(monocrotophos)，乃力松(naled)，BRP，異亞碸磷(oxydeprofos)；ESP，巴拉松(parathion)，裕必松(phosalone)，益滅松(phosmet)，PMP，亞特松(pirimiphos-methyl)，必芬松(pyridafenthion)，拜裕松(quinalphos)，賽達松(phenthoate)，PAP，佈飛松(profenofos)，加護松(propaphos)，普硫松(prothiofos)，白克松(pyraclofos)，殺力松(salithion)，硫丙磷(sulprofos)，丁基嘧啶磷(tebupirimfos)，亞培松(temephos)，殺蟲畏(tetrachlorvinphos)，託福松(terbufos)，硫滅松(thiometon)，三氯松(trichlorfon)，DEP，繁米松(vamidothion)，福瑞松(Phorate)，等； Acephate, aluminum phosphide, butathiofos, cadusafos, chlorethoxyfos, chlorfenvinphos, chlorpyrifos, methyl tausson (chlorpyrifos Methyl), cyanophos, CYAP, diazinon, DCIP dichlorodiisopropyl ether, deichlofenthion, ECP, dichlorvos; DDVP, dimethoate ), dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, etrimfos, fenthion; MPP, Fenitrothion: MEP, fosthiazate, formothion, phosphine; isofenphos, isoxathion, malathion, fenthion Mesulfenfos), methidathion, DMTP, monocrotophos, naled, BRP, oxydeprofos; ESP, parathion, phosalone , phosmet, PMP, pirimiphos-methyl, pyridafenthion, quinalphos, phenthoate, PAP, profenofos, plus pine (propaphos), prothiofos, pyraclofos, salithion, sulprofos, butyl pyrimidine (tebu) Pirimfos), temephos, tetrachlorvinphos, terbufos, thiometon, trichlorfon, DEP, vamidothion, Phorate ,Wait;
(3)胺基甲酸酯(Carbamate)化合物 (3) Carbamate compounds
棉鈴威(alanycarb)，免敵克(bendiocarb)，免扶克(benfuracarb)，BPMC，加保利(carbaryl)，加保扶(carbofuran)，丁基加保扶(carbosulfan)，除線威(cloethocarb)，愛芬克(ethiofencarb)，丁基滅必蝨(fenobucarb)，芬硫克(fenothiocarb)，芬諾克(fenoxycarb)，呋線威(furathiocarb)，滅必蝨(isoprocarb)，MIPC，治滅蝨(metolcarb)，納乃得(methomyl)，滅賜克(methiocarb)，NAC，毆殺滅(oxamyl)，比加普(pirimicarb)，安丹(propoxur)：PHC，XMC，硫 敵克(thiodicarb)，滅爾蝨(xylylcarb)，得滅克(aldicarb)，等。 Alanycarb, bendiocarb, benfuracarb, BPMC, carbaryl, carbofuran, carbosulfan, cloethocarb , ethiofencarb, fenobucarb, fenothiocarb, fenoxycarb, furathiocarb, isoprocarb, MIPC, sputum (metolcarb), methomyl, methiocarb, NAC, oxamyl, pirimicarb, propoxur: PHC, XMC, sulphur Thiodicarb, xylylcarb, aldicarb, etc.
(4)沙蠶毒素(nereistoxia)化合物 (4) Nereistoxia compound
培丹(cartap)，免速達(bensultap)，硫賜安(thiocyclam)，殺蟲單(monosultap)，殺蟲雙(bisultap)，等。 Cartap, bensultap, thiocyclam, monosultap, bisultap, etc.
(5)類尼古丁(neonicotinoid)化合物 (5) Nicotine-like compounds
益達胺(imidacloprid)，烯啶蟲胺(nitenpyram)，亞滅培(acetamiprid)，賽速安(thiamethoxam)，賽果培(thiacloprid)，達特南(dinotefuran)，可尼丁(clothianidin)等； Imidacloprid, nitenpyram, acetamiprid, thiamethoxam, thiacloprid, dinotefuran, clothianidin, etc. ;
(6)苯甲醯脲化合物 (6) Benzamidine urea compound
克福隆(chlorfluazuron)，雙三氟蟲脲(bistrifluron)，汰芬隆(diafenthiuron)，二福隆(diflubenzuron)，吡蟲隆(fluazuron)，氟環脲(flucycloxuron)，氟芬隆(flufenoxuron)，六伏隆(hexaflumuron)，祿芬隆(lufenuron)，諾伐隆(novaluron)，諾福隆(noviflumuron)，得福隆(teflubenzuron)，三福隆(triflumuron)，唑呀威(triazuron)，等； Chlorfluazuron, bistrifluron, diafenthiuron, diflubenzuron, flulazuron, flucycloxuron, flufenoxuron , hexaflumuron, lufenuron, novaluron, noiflunumuron, teflubenzuron, triflumuron, triazuron, Wait;
(7)苯基吡唑化合物 (7) Phenylpyrazole compound
乙醯蟲腈(acetoprole)，乙蟲腈(ethiprole)，芬普尼(fipronil)，甲烯氟蟲腈(vaniliprole)，吡啶氟蟲腈(pyriprole)，吡嗪氟蟲腈(pyrafluprole)等； Acetyl nitrile (acetoprole), ethiprole (ethiprole), fipronil, vaniliprole, pyriprazole, pyrafluprole, etc.;
(8)Bt毒素殺蟲劑 (8) Bt toxin insecticide
自蘇力菌(bacillus thuringiensis)衍生的活孢子及由其產生的結晶毒素及其混合物； Living spores derived from bacillus thuringiensis and crystalline toxins produced therefrom and mixtures thereof;
(9)聯氨化合物 (9) hydrazine compounds
可芬諾(chromafenozide)，合芬隆(halofenozide)，滅芬諾(methoxyfenozide)，得芬諾(tebufenozide)，等； Chromofozide, halofenozide, methoxyfenozide, tebufenozide, etc.;
(10)有機氯化合 (10) Organic chlorination
阿特靈(aldrin)，地特靈(dieldrin)，得氯蟎(dienochlor)，安殺番(endosulfan)，氯化甲醇(methoxychlor)，等； Aldrin, dieldrin, dienochlor, endosulfan, methoxychlor, etc.
(11)天然殺蟲劑 (11) Natural insecticides
機械油，硫酸尼古丁； Mechanical oil, nicotine sulfate;
(12)其他殺蟲劑 (12) Other pesticides
阿維菌素-B(avermectin-B)，新殺蟎(bromopropylate)，布芬淨(buprofezin)，克凡派(chlorfenapyr)，賽滅淨(cyromazine)，D-D(1,3二氯丙烯)，因滅汀(emamectin-benzoate)，芬殺蟎(fenazaquin)，吡氟硫磷(flupyrazofos)，烯蟲乙酯(hydroprene)，烯蟲丙酯(methoprene)，因得克(indoxacarb)，噁蟲酮(metoxadiazone)，倍脈心(milbemycin A)，滅淨(pymetrozine)，啶蟲丙醚(pyridalyl)，百利普芬(pyriproxyfen)，賜諾殺(spinosad)，氟蟲胺(sulfluramid)(草案)，芬瑞(tolfenpyrad)，唑蚜威(triazamate)，氟大滅(flubendiamide)，雷皮菌素(lepimectin)，砷酸，異噻蟲唑(暫定)(benclothiaz)，氰氨基化鈣，多硫化鈣，氯丹(chlordane)，DDT，DSP，嘧蟲胺(flufenerim)，氟尼胺(flonicamid)，(flurimfen)，覆滅蟎(Formetanate)，安百畝((metam-ammonium)，威百畝(metam sodium)，溴甲烷，油酸鉀，丙苯烴菊酯(protrifenbute)，螺甲蟎酯(spiromesifen)，硫黃，美氟綜(metaflumizone)，螺蟲乙酯(spirotetramat)，派利氟喹拿松(pyrifluquinazon)，賜諾特(spinetoram)，氯蟲苯甲醯胺(chlorantraniliprole)，曲洛比利(tralopyril)，等。 avermectin-B, new bromopropylate, buprofezin, chlorfenapyr, cyromazine, DD (1,3 dichloropropene), Emmectin-benzoate, fenazaquin, flupyrazofos, hydroprene, methoprene, indoxacarb, oxafluridone (metoxadiazone), milbemycin A, pymetrozine, pyridalyl, pyriproxyfen, spinosad, sulfluramid (draft) , tolfernpyrad, triazamate, flubendiamide, lepimectin, arsenic acid, isothiazolidine (tentatively) (benclothiaz), calcium cyanamide, polysulfide Calcium, chlordane, DDT, DSP, flufenerim, flonicamid, flurimfen, Formetanate, metam-ammonium, Weibaimu Metam sodium), methyl bromide, potassium oleate, protrifenbute, spiromesifen, sulfur, metaflumizone, spirotetr Amat), pyrifluquinazon, spinetoram, chlorantraniliprole, tramopyril, etc.
其他驅除劑的活性成分的例包括N,N-二乙基-間-甲苯醯胺，檸檬烯，沉香醇(linalool)，香茅醛，薄荷醇，薄荷酮， 日本扁柏油，香葉醇，桉油醇，因得克(indoxacarb)，蒈烷-3,4-二醇，MGK-R-326，MGK-R-874，及BAY-KBR-3023。 Examples of active ingredients of other repellents include N,N-diethyl-m-toluidine, limonene, linalool, citronellal, menthol, menthone, Japanese tar pitch, geraniol, eucalyptol, indoxacarb, decane-3,4-diol, MGK-R-326, MGK-R-874, and BAY-KBR-3023.
增效劑的例包括5-[2-{2-丁氧基乙氧基}乙氧基甲基]-6-丙基-1,3-苯並二噁茂，N-{2-乙基己基}雙環[2,2,1]庚-5-烯-2,3-二羧亞醯胺，八氯二丙基醚，硫氰乙酸異莰酯，及N-{2-乙基己基}-1-異丙基-4-甲基雙環[2,2,2]辛-5-烯-2,3-二羧亞醯胺。 Examples of synergists include 5-[2-{2-butoxyethoxy}ethoxymethyl]-6-propyl-1,3-benzodioxan, N-{2-ethyl Hexyl}bicyclo[2,2,1]hept-5-ene-2,3-dicarboxyliminiumamine, octachlorodipropyl ether, isodecyl thiocyanate, and N-{2-ethylhexyl} 1-Isopropyl-4-methylbicyclo[2,2,2]oct-5-ene-2,3-dicarboxyaryleneamine.
本發明的防除有害生物的方法是將本發明的有害生物防除組成物施用於有害生物或有害生物的棲息場所(植物體，土壤，屋內，動物體，等)而實施。 The method for controlling pests of the present invention is carried out by applying the pest control composition of the present invention to a habitat (plant body, soil, house, animal body, etc.) of a pest or a pest.
具體而言，本發明的有害生物防除組成物的施用方法可舉例如下，且這些方法可視本發明的有害生物防除組成物的形態，施用場所等而適宜選擇。 Specifically, the application method of the pest control composition of the present invention can be exemplified as follows, and these methods can be appropriately selected depending on the form of the pest control composition of the present invention, the application site, and the like.
(1)將本發明的有害生物防除組成物以原本的形態施用於有害生物或有害生物的棲息場所的方法。 (1) A method of applying the pest control composition of the present invention to a habitat of a pest or a pest in its original form.
(2)將本發明的組成物以例如水的溶媒稀釋後噴施於有害生物或有害生物的棲息場所的方法。 (2) A method in which the composition of the present invention is diluted with a solvent such as water and then sprayed on a habitat of a pest or a pest.
在這種情況時，將本發明的有害生物防除組成物製成乳液調配物，可濕性粉劑，可流動性調配物，微膠囊劑等，通常稀釋以使本案酯化合物及本案檸檬酸三酯的總濃度成為0.01至1,000 ppm。 In this case, the pest control composition of the present invention is formulated into an emulsion formulation, a wettable powder, a flowable formulation, a microcapsule, etc., and is usually diluted to make the ester compound of the present invention and the citrate triester of the present invention. The total concentration is from 0.01 to 1,000 ppm.
(3)將本發明的有害生物防除組成物在有害生物的棲息場所加熱，使其活性成分蒸發的方法。 (3) A method in which the pest control composition of the present invention is heated in a habitat of a pest to evaporate the active ingredient.
在這種情況時，本案酯化合物及本案檸檬酸三酯的施用量及濃度是，可視本發明的組成物的形態，施用間隔，施用 場所，施用方法，有害生物種類，為害程度等而適宜決定。 In this case, the application amount and concentration of the ester compound of the present invention and the citrate triester of the present invention are, depending on the form of the composition of the present invention, the application interval, and the application. The site, the method of application, the type of pest, the degree of damage, etc. are appropriately determined.
當本發明的有害生物防除組成物是用於防止蟲害時，其施用量是本案酯化合物及本案檸檬酸三酯的總量對施用空間通常是0.0001至1000 mg/m3，對施用平面是0.0001至1000 mg/m2。視調配物形態而定，而選用殺蟲香棒，電殺蟲盤等加熱而使活性成分蒸發。將樹脂蒸散調配物，紙蒸散調配物，不織布蒸散調配物，針織物蒸散調配物，可昇華的錠劑等，例如，以原本的形態放在要施用的空間，或放在有吹氣的狀態使用。 When the pest control composition of the present invention is used for preventing pests, the application amount thereof is that the total amount of the ester compound and the citrate triester in the present case is usually 0.0001 to 1000 mg/m 3 for the application space, and 0.0001 to the application plane. Up to 1000 mg/m 2 . Depending on the form of the formulation, the insecticidal incense stick is used, and the active ingredient is evaporated by heating. The resin evapotranspiration preparation, the paper evapotranspiration preparation, the non-woven evapotranspiration preparation, the knitted fabric evapotranspiration preparation, the sublimable tablet, etc., for example, placed in the original application form in a space to be applied, or placed in an air blowing state use.
施用本發明的有害生物防除組成物要防止蟲害的空間的例包括廚櫃，衣櫃，日式衣櫃，碗櫃，廁所，浴室，儲藏室，客廳，餐廳，倉庫，汽車內部等。再者，該組成物也可在戶外曠地施用。 Examples of the space in which the pest control composition of the present invention is applied to prevent pests include kitchen cabinets, wardrobes, Japanese wardrobes, cupboards, toilets, bathrooms, storage rooms, living rooms, restaurants, warehouses, automobile interiors, and the like. Furthermore, the composition can also be applied outdoors.
當將本發明的有害生物防除組成物用於家畜上的體外寄生蟲的防除，例如牛、馬、豬、羊、山羊及雞，以及小動物，例如，例如狗、貓、大鼠及小鼠時，對這些動物可使用已知的獸醫學方法施用。具體的施用方法而言，意欲要有全身性的防除時，組成物是以錠劑，與飼料混合，以栓劑，或以注射(肌肉內，皮下，靜脈，腹膜內，等)之方式施用。另一方面，當不作全身性的防除時，該組成物是以油性溶液或水溶液噴施，澆灌或點施處理，將動物以洗毛調配物清洗，套上以樹脂蒸散調配物製成的項圈或耳標，等。當對動物體施用時，本案酯化合物及本案檸檬酸三酯的總量通常在0.01至1000mg/1kg動物體重的範圍內。 When the pest control composition of the present invention is used for the control of ectoparasites on livestock, such as cattle, horses, pigs, sheep, goats, and chickens, and small animals such as, for example, dogs, cats, rats, and mice. These animals can be administered using known veterinary methods. For the specific application method, when it is intended to have systemic control, the composition is administered as a tablet, mixed with a feed, as a suppository, or as an injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.). On the other hand, when not for systemic control, the composition is sprayed with an oily solution or an aqueous solution, watered or applied, the animal is washed with a scouring formulation, and a collar made of a resin evapotranspiration is applied. Or ear tags, etc. When administered to an animal, the total amount of the ester compound of the present invention and the citrate triester of the present invention is usually in the range of 0.01 to 1000 mg / 1 kg of animal body weight.
以下，將更詳細以調配物例及試驗例說明本發明， 但本發明並不只限定於下列諸例。在下述例中，如無特別註明，「份」表示「重量份」。 Hereinafter, the present invention will be described in more detail with reference to examples and test examples. However, the invention is not limited to the following examples. In the following examples, "parts" means "parts by weight" unless otherwise specified.
首先，將說明本發明的有害生物防除組成物的調配物例。這裏，「份」表示「重量份」。 First, an example of the formulation of the pest control composition of the present invention will be explained. Here, "parts" means "parts by weight".
在氣霧劑容器中，加入0.02份的本案酯化合物，0.18份的任何式(2)表示的檸檬酸三酯化合物，及59.8份的Isopar M(異烷烴系烷烴，埃克森美孚公司(Exxon Mobil Co.)製)。在該氣霧劑容器附上開關閥，並經過該閥加入40份的驅除劑(液化石油氣)而得氣霧劑。在這裏，[2,3,5,,6-四氟-4-(甲氧甲基)苯基]甲基(1R)-反-3-(2-氰基-1-丙烯基[E/Z=1/9])-2,2-二甲基環丙烷羧酸酯(以下，簡稱為本案酯化合物A)作為本案酯化合物而使用。 In an aerosol container, 0.02 parts of the ester compound of the present invention, 0.18 parts of any citrate triester compound represented by the formula (2), and 59.8 parts of Isopar M (isoalkane alkane, Exxon Mobil Corporation) were added. Mobil Co.). An on-off valve was attached to the aerosol container, and 40 parts of a repellent (liquefied petroleum gas) was added through the valve to obtain an aerosol. Here, [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl(1R)-trans-3-(2-cyano-1-propenyl[E/ Z=1/9])-2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as the ester compound A in the present invention) is used as the ester compound of the present invention.
在氣霧劑容器中，加入0.01份的本案酯化合物A，0.09份的任何式(2)表示的檸檬酸三酯化合物，及39.9部的Isopar M(異烷烴系烷烴，埃克森美孚公司製。在該氣霧劑容器附上閥部分，並經過該閥部分加入60份的驅除劑(液化石油氣)而得氣霧劑。 In the aerosol container, 0.01 part of the ester compound A of the present invention, 0.09 part of any citrate triester compound represented by the formula (2), and 39.9 parts of Isopar M (isoalkane alkane, manufactured by Exxon Mobil Corporation) were added. An aerosol portion is attached to the aerosol container, and 60 parts of a repellent (liquefied petroleum gas) is added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加0.02份的本案酯化合物A，0.06份的任何式(2)表示的任意的檸檬酸三酯化合物，及59.92份的Isopar M(異烷烴系烷烴，埃克森美孚公司製)。在該氣霧劑容器附上閥部分，並經過該閥部分加入40份的驅除劑(液化石油氣)而得氣霧劑。 In the aerosol container, 0.02 parts of the ester compound A of the present invention, 0.06 part of any citrate triester compound represented by the formula (2), and 59.92 parts of Isopar M (isoalkane alkane, Exxon Mobil) are added. Company system). An aerosol portion was attached to the aerosol container, and 40 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加0.1份的本案酯化合物A，0.9份的任何式(2)表示的檸檬酸三酯化合物，3份的肉豆蔻酸異丙酯，及56份的Isopar M(異烷烴系烷烴，埃克森美孚公司製)。在該氣霧劑容器附上閥部分，並經過該閥部分加入40份的驅除劑(液化石油氣)而得氣霧劑。 In an aerosol container, 0.1 part of the ester compound A of the present invention, 0.9 part of any citrate triester compound represented by the formula (2), 3 parts of isopropyl myristate, and 56 parts of Isopar M (iso) are added. Alkane-based alkane, manufactured by Exxon Mobil Corporation). An aerosol portion was attached to the aerosol container, and 40 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入混合並溶解0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物，8.8份的Isopar M(異烷烴系烷烴，埃克森美孚公司製)，0.8份的RHEODOL MO-60(油酸二醇酯/丙烯二醇，花王公司製)及0.2份的RHEODOL TW-0120(聚山梨醇酯80，花王公司製)，及50份的水所成的溶液。在該氣霧劑容器附上閥部分，並經過該閥部分加入40份的驅除劑(液化石油氣)而得氣霧劑。 In an aerosol container, 0.02 parts of the ester compound A, 0.18 parts of any citrate triester compound represented by the formula (2), and 8.8 parts of Isopar M (isoalkane alkane, Exxon Mobil) are added and dissolved. Company), 0.8 parts of RHEODOL MO-60 (diol oleate / propylene glycol, manufactured by Kao Corporation) and 0.2 parts of RHEODOL TW-0120 (polysorbate 80, manufactured by Kao Corporation), and 50 parts A solution of water. An aerosol portion was attached to the aerosol container, and 40 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入混合並溶解0.02份的本案酯化合物A，0.06份的任何式(2)表示的檸檬酸三酯化合物，8.92份的Isopar M(異烷烴系烷烴，埃克森美孚公司製)，0.8份的RHEODOL MO-60(油酸二醇酯/丙烯二醇，花王公司製)及0.2份的RHEODOL TW-0120(聚山梨醇酯80，花王公司製)，及50份的水所成的溶液。在該氣霧劑容器附上閥部分，並經過該閥部分加入40份的驅除劑(液化石油氣)而得氣霧劑。 In an aerosol container, 0.02 parts of the ester compound A, 0.06 parts of any citrate triester compound represented by the formula (2), and 8.92 parts of Isopar M (isoalkane alkane, Exxon Mobil) were added and dissolved. Company), 0.8 parts of RHEODOL MO-60 (diol oleate / propylene glycol, manufactured by Kao Corporation) and 0.2 parts of RHEODOL TW-0120 (polysorbate 80, manufactured by Kao Corporation), and 50 parts A solution of water. An aerosol portion was attached to the aerosol container, and 40 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入0.02份的本案酯化合物A， 0.18份的任何式(2)表示的檸檬酸三酯化合物，及49.8份的NEO-CHIOZOL(液態石蠟，中央化成公司製)。在該氣霧劑容器附上開關閥，並經過該閥部分加入50份的驅除劑(二甲基醚/液化石油氣1/1混合物)而得氣霧劑。 In the aerosol container, 0.02 parts of the ester compound A of the present invention is added, 0.18 parts of any citrate triester compound represented by the formula (2), and 49.8 parts of NEO-CHIOZOL (liquid paraffin, manufactured by Central Chemicals Co., Ltd.). An on-off valve was attached to the aerosol container, and 50 parts of a repellent (dimethyl ether/liquefied petroleum gas 1/1 mixture) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入0.02份的本案酯化合物A，0.06份的任何式(2)表示的檸檬酸三酯化合物，及49.92份的NEO-CHIOZOL(液態石蠟，中央化成公司製)。在該氣霧劑容器附上閥部分，並經過該閥部分加入50份的驅除劑(二甲基醚/液化石油氣1/1混合物)而得氣霧劑。 In the aerosol container, 0.02 parts of the ester compound A of the present invention, 0.06 part of any citrate triester compound represented by the formula (2), and 49.92 parts of NEO-CHIOZOL (liquid paraffin, manufactured by Central Chemicals Co., Ltd.) were added. A valve portion was attached to the aerosol container, and 50 parts of a repellent (dimethyl ether/liquefied petroleum gas 1/1 mixture) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入0.1份的本案酯化合物A，0.9份的任何式(2)表示的檸檬酸三酯化合物，6份的肉豆蔻酸異丙酯及23份的NEO-CHIOZOL(液態石蠟，中央化成公司製)。在該氣霧劑容器附上閥部分，並經過該閥部分加入70份的驅除劑(二甲基醚/液化石油氣1/1混合物)而得氣霧劑。 In the aerosol container, 0.1 part of the ester compound A of the present invention, 0.9 part of any citrate triester compound represented by the formula (2), 6 parts of isopropyl myristate and 23 parts of NEO-CHIOZOL (liquid state) were added. Paraffin wax, centralized into a company system). An aerosol portion was attached to the aerosol container, and 70 parts of a repellent (dimethyl ether/liquefied petroleum gas 1/1 mixture) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入混合並溶解0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物，5.8份的NEO-CHIOZOL(液態石蠟，中央化成公司製)，3份的肉豆蔻酸異丙酯，0.8份的RHEODOL MO-60(油酸二醇酯/丙二醇，花王公司製)及0.2份的RHEODOL TW-0120(聚山梨醇酯80，花王公司製)，及40份的水所成的溶液。在該氣霧劑容器附上閥部分，並經過該閥部分加入50份的驅除劑(二甲基醚/液化石油氣1/1混合 物)而得氣霧劑。 In the aerosol container, 0.02 parts of the ester compound A of the present invention, 0.18 parts of any citrate triester compound represented by the formula (2), and 5.8 parts of NEO-CHIOZOL (liquid paraffin, manufactured by Central Chemicals Co., Ltd.) were added and dissolved. 3 parts of isopropyl myristate, 0.8 parts of RHEODOL MO-60 (diol oleate/propylene glycol, manufactured by Kao Corporation) and 0.2 parts of RHEODOL TW-0120 (polysorbate 80, manufactured by Kao Corporation) And 40 parts of water solution. A valve portion is attached to the aerosol container, and 50 parts of the repellent (dimethyl ether/liquefied petroleum gas 1/1 mixed) is added through the valve portion. An aerosol is obtained.
在氣霧劑容器中，加入混合並溶解0.02份的本案酯化合物A，0.06份的任何式(2)表示的檸檬酸三酯化合物，5.92份的NEO-CHIOZOL(液態石蠟，中央化成公司製)，3份的肉豆蔻酸異丙酯，0.8份的RHEODOL MO-60(油酸二醇酯/丙二醇，花王公司製)及0.2份的RHEODOL TW-0120(聚山梨醇酯80，花王公司製)，及40份的水所成的溶液。在該氣霧劑容器附上閥部分，並經過該閥部分加入50份的驅除劑(二甲基醚/液化石油氣1/1混合物)而得氣霧劑。 In the aerosol container, 0.02 parts of the ester compound A of the present invention, 0.06 parts of any citrate triester compound represented by the formula (2), and 5.92 parts of NEO-CHIOZOL (liquid paraffin, manufactured by Central Chemicals Co., Ltd.) were added and dissolved. 3 parts of isopropyl myristate, 0.8 parts of RHEODOL MO-60 (diol oleate/propylene glycol, manufactured by Kao Corporation) and 0.2 parts of RHEODOL TW-0120 (polysorbate 80, manufactured by Kao Corporation) And 40 parts of water solution. A valve portion was attached to the aerosol container, and 50 parts of a repellent (dimethyl ether/liquefied petroleum gas 1/1 mixture) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入混合並溶解0.01份的本案酯化合物A，0.9份的任何式(2)表示的檸檬酸三酯化合物，8份的Isopar M(異烷烴系烷烴，埃克森美孚公司製)，0.9份的RHEODOL SP-010(油酸山梨醇酯，花王公司製)及0.1份的RHEODOL TW-0120(聚山梨醇酯80，花王公司製)所成的溶液，及混合並溶解69.86份的水及0.14份的苯甲酸鈉所成的溶液。在該氣霧劑容器附上閥部分，並經過該閥部分加入20份的驅除劑(液化石油氣)而得氣霧劑。 In an aerosol container, 0.01 part of the ester compound A is mixed and dissolved, 0.9 part of any citrate triester compound represented by the formula (2), and 8 parts of Isopar M (isoalkane alkane, Exxon Mobil) Company made), 0.9 parts of RHEODOL SP-010 (sorbitol oleate, manufactured by Kao Corporation) and 0.1 part of RHEODOL TW-0120 (polysorbate 80, manufactured by Kao Corporation), mixed and dissolved A solution of 69.86 parts of water and 0.14 parts of sodium benzoate. An aerosol portion was attached to the aerosol container, and 20 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
將28份的乙烯-甲基丙烯酸甲酯共聚物(甲基丙烯酸甲酯在共聚物中的比率：25重量%，商品名：Acryft WK307，住友化學公司製)，2.5份的本案酯化合物A，2.5份的任何式(2)表示的檸檬酸三酯化合物熔化並使用密封式加壓捏揉機(森山公司製) 捏揉。將捏揉產物由擠製機擠製時熱切成片。將33份的該及67份的直鏈低密度聚乙烯(乙烯均聚物)混合並捏揉而得樹脂捏揉物。然後，將該樹脂捏揉物經由網模成形用非均質模具(heterogenous dies for net molding)押出並伸展，而得直徑約7 cm圓筒形模製物，係由一邊約5 mm的菱形的網所成(其中纖絲的直徑約為0.83 mm，網之直徑為82%)。將模製物割切為20 cm長度，以得有害生物防除組成物。 28 parts of ethylene-methyl methacrylate copolymer (methyl methacrylate in copolymer: 25 wt%, trade name: Acryft WK307, manufactured by Sumitomo Chemical Co., Ltd.), 2.5 parts of the ester compound A, 2.5 parts of any citrate triester compound represented by the formula (2) was melted and a sealed press kneader (manufactured by Moriyama Co., Ltd.) was used. Pinch. The kneaded product is hot cut into pieces as it is extruded from the extruder. 33 parts of this and 67 parts of linear low-density polyethylene (ethylene homopolymer) were mixed and kneaded to obtain a resin kneaded product. Then, the resin kneaded material was extruded and stretched by a heterogenous dies for net molding to obtain a cylindrical molding having a diameter of about 7 cm, which was a diamond-shaped net having a side of about 5 mm. Made (where the diameter of the filament is about 0.83 mm and the diameter of the web is 82%). The molded article was cut to a length of 20 cm to obtain a pest control composition.
將20份的本案酯化合物A，5份的任何式(2)表示的檸檬酸三酯化合物，3份的Newkalgen PS-P(萘磺酸甲醛縮合物之鈉鹽)，1份的Newkalgen EX-70(二辛磺基琥珀酸鈉鹽/苯甲酸鈉))，3份的Newkalgen SX-C(十二烷基苯磺酸鈉鹽/硫酸鈉十合水物)(Newkalgen系列：竹本油脂公司製)，及68份的精製白砂糖(三井製糖公司製)磨碎並混合，以獲得毒餌水溶液用的粉狀組成物。 20 parts of the ester compound A of the present invention, 5 parts of any citrate triester compound represented by the formula (2), 3 parts of Newkalgen PS-P (sodium salt of a naphthalenesulfonic acid formaldehyde condensate), and 1 part of Newkalgen EX- 70 (dioctylsulfosuccinate sodium salt/sodium benzoate), 3 parts of Newkalgen SX-C (sodium dodecylbenzenesulfonate/sodium sulfate) (Newkalgen series: manufactured by Takemoto Oil Co., Ltd.) And 68 parts of refined white granulated sugar (manufactured by Mitsui Sugar Co., Ltd.) were ground and mixed to obtain a powdery composition for an aqueous bait solution.
在24.8份的異丙醇中加0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物而混合。將該混合物注入於氣霧劑容器，再將30.0份的苯甲酸銨-銨緩衝劑(在苯甲酸銨1.0% w/w溶液中加29%氨水，且調整混合物至pH 8.5)注入於該氣霧劑容器而製成氣霧劑母液。然後，在該氣霧劑容器附上閥，並經過該閥加壓加入45.0份的二甲基醚而得氣霧劑。 To 24.8 parts of isopropyl alcohol, 0.02 parts of the ester compound A of the present invention and 0.18 parts of any citrate triester compound represented by the formula (2) were added and mixed. The mixture was injected into an aerosol container, and 30.0 parts of an ammonium-ammonium benzoate-ammonium buffer (29% aqueous ammonia in a 1.0% w/w solution of ammonium benzoate was added, and the mixture was adjusted to pH 8.5) was injected into the gas. The aerosol container is made into an aerosol mother liquor. Then, a valve was attached to the aerosol container, and 45.0 parts of dimethyl ether was added under pressure through the valve to obtain an aerosol.
在24.92份的異丙醇中加0.02份本案酯化合物A，0.06份的任何式(2)表示的檸檬酸三酯化合物而混合。將該混合物 注入於氣霧劑容器，再將30.0份的苯甲酸銨-銨緩衝劑(在苯甲酸銨1.0% w/w溶液加29%氨水，且調整混合物至pH 8.5)注入於該氣霧劑容器而製成氣霧劑母液。然後，在該氣霧劑容器附上閥，並經過該閥加壓加入45.0份的甲基醚而得氣霧劑。 To 24.92 parts of isopropyl alcohol, 0.02 parts of the ester compound A of the present invention, 0.06 part of any citrate triester compound represented by the formula (2) was added and mixed. The mixture Inject into the aerosol container, and then inject 30.0 parts of ammonium benzoate-ammonium buffer (in ammonium acetate benzoate 1.0% w/w solution with 29% ammonia water, and adjust the mixture to pH 8.5) into the aerosol container. Made into an aerosol mother liquor. Then, a valve was attached to the aerosol container, and 45.0 parts of methyl ether was added under pressure through the valve to obtain an aerosol.
將20份的本案酯化合物A，70份的任何式(2)表示的檸檬酸三酯化合物，及10份的2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯混合而得溶液。 20 parts of the ester compound A of the present invention, 70 parts of any citrate triester compound represented by the formula (2), and 10 parts of 2,2-dimethyl-3-(1-propenyl)cyclopropanecarboxylic acid [ A solution was obtained by mixing 2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester.
在氣霧劑容器中，加0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物，0.02份的2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯，3份的肉豆蔻酸異丙酯，及56.78份的Isopar M(異石蠟系烴類，埃克森美孚公司製)。在該氣霧劑容器附上閥部分，並經過該閥部分加入40份的驅除劑(液化石油氣)而得氣霧劑。 In the aerosol container, 0.02 parts of the ester compound A of the present invention, 0.18 parts of any citrate triester compound represented by the formula (2), and 0.02 parts of 2,2-dimethyl-3-(1-propenyl group) were added. Cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, 3 parts of isopropyl myristate, and 56.78 parts of Isopar M (different) Paraffinic hydrocarbons, manufactured by Exxon Mobil Corporation). An aerosol portion was attached to the aerosol container, and 40 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物，0.02份的2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯，6份的肉豆蔻酸異丙酯，及23.78份的NEO-CHIOZOL(液態石蠟，中央化成公司製)。在該氣霧劑容器附上閥部分，並經過該閥部分加入70部的驅除劑(二甲基醚/液化石油氣的1/1混合物)而得氣霧劑。 In the aerosol container, 0.02 parts of the ester compound A of the present invention, 0.18 parts of any citrate triester compound represented by the formula (2), and 0.02 parts of 2,2-dimethyl-3-(1-propenyl group) were added. Cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, 6 parts of isopropyl myristate, and 23.78 parts of NEO-CHIOZOL ( Liquid paraffin, centralized into a company). An aerosol portion was attached to the aerosol container, and 70 parts of a repellent (1/1 mixture of dimethyl ether/liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入混合並溶解0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物，0.02份的2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯，8.78份的Isopar M(異石蠟系烴類，埃克森美孚公司製)，0.8份的RHEODOL MO-60(油酸二醇酯/丙二醇，花王公司製)及0.2份的RHEODOL TW-0120(聚山梨醇酯80，花王公司製)，及40份的水所成的溶液。在該氣霧劑容器附上閥部分，並經過該閥部分加入50份的驅除劑(液化石油氣)而得氣霧劑。 In an aerosol container, 0.02 parts of the ester compound A of the present invention, 0.18 parts of any citrate triester compound represented by the formula (2), and 0.02 parts of 2,2-dimethyl-3-(1) were added and dissolved. -propenyl)cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, 8.78 parts of Isopar M (isoparaffinic hydrocarbons, Exxon Mobil Corporation), 0.8 parts of RHEODOL MO-60 (diol oleate / propylene glycol, manufactured by Kao Corporation) and 0.2 parts of RHEODOL TW-0120 (polysorbate 80, manufactured by Kao Corporation), and 40 parts of water The resulting solution. An aerosol portion was attached to the aerosol container, and 50 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在氣霧劑容器中，加入混合並溶解0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物，0.02份的2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯，8.78份的Isopar M(異石蠟系烴類，埃克森美孚公司製)，0.9份的RHEODOL SP-010(油酸山梨醇酯，花王公司製)及0.1份的RHEODOL TW-0120(聚山梨醇酯80，花王公司製)所成的溶液，及混合並溶解69.86份的水及0.14份的苯甲酸鈉所成的溶液。在該氣霧劑容器附上閥部分，並經過該閥部分加入20份的驅除劑(液化石油氣)而得氣霧劑。 In an aerosol container, 0.02 parts of the ester compound A of the present invention, 0.18 parts of any citrate triester compound represented by the formula (2), and 0.02 parts of 2,2-dimethyl-3-(1) were added and dissolved. -propenyl)cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, 8.78 parts of Isopar M (isoparaffinic hydrocarbons, Exxon a solution of 0.9 parts of RHEODOL SP-010 (sorbitol oleate, manufactured by Kao Corporation) and 0.1 part of RHEODOL TW-0120 (polysorbate 80, manufactured by Kao Corporation), and mixed A solution of 69.86 parts of water and 0.14 parts of sodium benzoate was dissolved. An aerosol portion was attached to the aerosol container, and 20 parts of a repellent (liquefied petroleum gas) was added through the valve portion to obtain an aerosol.
在24.78份的異丙醇中，添加0.02份的本案酯化合物A，0.18份的任何式(2)表示的檸檬酸三酯化合物，及0.02份的2,2-二甲基-3-(1-丙烯基)環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯，然後混合。將該混合物注入於氣霧劑容器，再將30.0份的苯甲酸銨-銨緩衝劑(在苯甲酸銨1.0% w/w溶液加29%氨水， 且調整混合物至pH 8.5)注入於該氣霧劑容器而製成氣霧劑母液。然後在該氣霧劑容器附上閥，並經過該閥加壓加入45.0份的二甲基醚而得氣霧劑。 In 24.78 parts of isopropyl alcohol, 0.02 parts of the ester compound A of the present invention, 0.18 parts of any citrate triester compound represented by the formula (2), and 0.02 parts of 2,2-dimethyl-3-(1) were added. - Propenyl)cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, then mixed. The mixture was injected into an aerosol container, and 30.0 parts of ammonium benzoate-ammonium buffer (in a solution of ammonium benzoate 1.0% w/w plus 29% aqueous ammonia, The mixture was adjusted to pH 8.5) and injected into the aerosol container to form an aerosol mother liquor. Then, a valve was attached to the aerosol container, and 45.0 parts of dimethyl ether was added under pressure through the valve to obtain an aerosol.
其次，下列的試驗例顯示本發明的有害生物防除組成物對有害生物有優異的防除功效。 Next, the following test examples show that the pest control composition of the present invention has an excellent control effect against harmful organisms.
在試驗例中所用的本發明的有害生物防除組成物示於第1表。 The pest control composition of the present invention used in the test examples is shown in Table 1.
其次，用於比較的有害生物防除組成物示於第2表 Second, the pest control composition for comparison is shown in Table 2.
將本案組成物(1)及(2)及比較組成物(3)及(4)的預定 量分別以除臭煤油(Isopar M，埃克森美孚公司(Exxon Mobil Co.)製)稀釋而製成100份的含有0.00625%(wt/v)的本案酯化合物A的液體組成物。 The composition of the case (1) and (2) and the comparison of the composition (3) and (4) The amount was diluted with deodorized kerosene (Isopar M, manufactured by Exxon Mobil Co.) to prepare 100 parts of a liquid composition containing 0.00625% (wt/v) of the ester compound A of the present invention.
將10隻家蠅(5雄蟲及5雌蟲)成蟲釋放於聚乙烯杯(低部直徑：10.6cm，高部直徑：12cm，高：7cm)，並將杯以16網目尼龍網蓋住。將杯放在試驗室的底部(底面積：46cmx46cm，高：70 cm)。自杯的上部高30 cm的地方，將0.5 ml的液體組成物以噴槍噴灑(噴灑壓力：0.9 kg/cm2)。噴灑後即時將杯自試驗箱取出，且在特定的時間後，計數被擊斃的蟲數，並計算擊斃率(二回合的平均值)。結果示於第3表。 Ten houseflies (5 males and 5 females) adults were released into a polyethylene cup (lower diameter: 10.6 cm, high diameter: 12 cm, height: 7 cm), and the cup was covered with a 16 mesh nylon mesh. Place the cup on the bottom of the test chamber (bottom area: 46 cm x 46 cm, height: 70 cm). From the upper part of the cup 30 cm high, 0.5 ml of the liquid composition was sprayed with a spray gun (spraying pressure: 0.9 kg/cm 2 ). Immediately after spraying, the cup was taken out of the test chamber, and after a certain time, the number of killed insects was counted, and the killing rate (average of two rounds) was calculated. The results are shown in Table 3.
將本案組成物(1)及(2)及比較組成物(3)及(5)的規定量各以除臭煤油(Isopar M，埃克森美孚公司(Exxon Mobil Co.)製)稀釋而製成100份的含有0.00625%(wt/v)的本案酯化合物A的液體組成物。 The predetermined amounts of the compositions (1) and (2) and the comparative compositions (3) and (5) of the present invention were each diluted with deodorized kerosene (Isopar M, manufactured by Exxon Mobil Co.). 100 parts of a liquid composition containing 0.00625% (wt/v) of the ester compound A of the present invention.
將10隻德國蜚蠊(5雄蟲及5雌蟲)成蟲釋放於試驗容器(直徑：8.75 cm，高：7.5 cm，底面：16網目的索網)，容器內壁塗以奶油。將該容器放在試驗箱的底部(底面積： 46cmx46cm，高：70 cm)。自容器上部高60 cm的地方，將1.5 ml的液體組成物以噴槍噴灑(噴灑壓力：0.42 kg/cm2)。噴灑30秒後，計數被擊斃的蟲數並計算擊斃率(二回合的平均值)。結果示於第4表。 Ten adult German cockroaches (5 males and 5 females) were released into the test container (diameter: 8.75 cm, height: 7.5 cm, bottom: 16 mesh nets), and the inner wall of the container was creamed. The container was placed at the bottom of the test chamber (bottom area: 46 cm x 46 cm, height: 70 cm). From the upper part of the container 60 cm high, 1.5 ml of the liquid composition was sprayed with a spray gun (spraying pressure: 0.42 kg/cm 2 ). After spraying for 30 seconds, the number of insects killed was counted and the killing rate (average of two rounds) was calculated. The results are shown in Table 4.
將本案組成物(1)及(3)及比較組成物(2)的預定量各以10部的二氯甲烷稀釋並溶解，再加除臭煤油(Isopar M，埃克森美孚公司(Exxon Mobil Co.)製)而製成100份的含有0.00625%(wt/v)的本案酯化合物A的液體組成物。 The predetermined amounts of the compositions (1) and (3) and the comparative composition (2) of the present invention were each diluted and dissolved in 10 portions of dichloromethane, and deodorized kerosene was added (Isopar M, Exxon Mobil). Co.) was made into 100 parts of a liquid composition containing 0.00625% (wt/v) of the ester compound A of the present invention.
將10隻家蠅(5雄蟲及5雌蟲)成蟲釋放於聚乙烯杯(低部直徑：10.6cm，高部直徑：12cm，高：7cm)，並將杯以16網目尼龍網蓋住。將杯放在試驗箱的底部(底面積：46cmx46cm，高：70 cm)。自杯的上部高30 cm的地方，將0.5 ml的液體組成物以噴槍噴灑(噴灑壓力：0.9 kg/cm2)。噴灑後即時將杯自試驗箱取出，在特定的時間後，計數被擊斃的蟲數並計算擊斃率(二回合的平均值)。結果示於第5表。 Ten houseflies (5 males and 5 females) adults were released into a polyethylene cup (lower diameter: 10.6 cm, high diameter: 12 cm, height: 7 cm), and the cup was covered with a 16 mesh nylon mesh. Place the cup on the bottom of the test chamber (bottom area: 46 cm x 46 cm, height: 70 cm). From the upper part of the cup 30 cm high, 0.5 ml of the liquid composition was sprayed with a spray gun (spraying pressure: 0.9 kg/cm 2 ). Immediately after spraying, the cup was taken out of the test chamber, and after a certain time, the number of insects killed was counted and the killing rate (average of two rounds) was calculated. The results are shown in Table 5.
將本組成物(1)及(3)及比較組成物(1)及(2)的規定量各以10份的二氯甲烷稀釋並溶解，再加入除臭煤油(Isopar M，埃克森美孚公司製)稀釋而製成100份的含有0.00625%(wt/v)的本案酯化合物A的液體組成物。 The predetermined amounts of the compositions (1) and (3) and the comparative compositions (1) and (2) were each diluted with 10 parts of dichloromethane and dissolved, and then deodorized kerosene (Isopar M, Exxon Mobil) was added. The company was diluted to prepare 100 parts of a liquid composition containing 0.00625% (wt/v) of the ester compound A of the present invention.
將10隻德國蜚蠊(5雄蟲及5雌蟲)成蟲釋放於試驗容器(直徑：8.75 cm，高：7.5 cm，底面：16網目的索網)，容器內壁塗以奶油。將該容器放在試驗箱的底部(底面積：46cm×46 cm，高：70 cm)。自容器上部高60 cm的地方，將1.5 ml的液體組成物以噴槍噴灑(噴灑壓力：0.9 kg/cm2)。噴灑30秒後，計數被擊斃的蟲數並計算擊斃率(二回合的平均值)。結果示於第6表。 Ten adult German cockroaches (5 males and 5 females) were released into the test container (diameter: 8.75 cm, height: 7.5 cm, bottom: 16 mesh nets), and the inner wall of the container was creamed. The container was placed at the bottom of the test chamber (bottom area: 46 cm x 46 cm, height: 70 cm). From the upper part of the container 60 cm high, 1.5 ml of the liquid composition was sprayed with a spray gun (spraying pressure: 0.9 kg/cm 2 ). After spraying for 30 seconds, the number of insects killed was counted and the killing rate (average of two rounds) was calculated. The results are shown in Table 6.
本發明的有害生物防除組成物對有害生物有優異的防除功效，且是有用的。 The pest control composition of the present invention has an excellent control effect against harmful organisms and is useful.
Claims (5)
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| JP6754197B2 (en) * | 2015-12-28 | 2020-09-09 | 大日本除蟲菊株式会社 | Pest control aerosol |
| JP6910728B2 (en) * | 2017-10-05 | 2021-07-28 | 大日本除蟲菊株式会社 | Ester compounds and their uses |
| JP7144024B2 (en) * | 2018-03-29 | 2022-09-29 | 住化エンバイロメンタルサイエンス株式会社 | Pest control composition, aerosol product, and control method |
| TWI790635B (en) * | 2021-06-08 | 2023-01-21 | 誌懋股份有限公司 | Uses of Australian Cypress Extract for Cockroach Repellent |
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| JPS5428818A (en) * | 1977-08-05 | 1979-03-03 | Fumakilla Ltd | Method of enhancing effect of pesticide smoked in short time |
| US5591727A (en) * | 1990-09-12 | 1997-01-07 | Perycut-Chemie Ag | Insecticidal composition |
| US6638621B2 (en) * | 2000-08-16 | 2003-10-28 | Lyotropic Therapeutics, Inc. | Coated particles, methods of making and using |
| EP1210877A1 (en) * | 2000-12-01 | 2002-06-05 | Aventis CropScience GmbH | Oil-in-water emulsion formulation of insecticides |
| JP2003160418A (en) * | 2001-11-26 | 2003-06-03 | Sumitomo Chem Co Ltd | Method for preparation of insecticidal aerosol |
| JP4285045B2 (en) * | 2002-04-12 | 2009-06-24 | 住友化学株式会社 | Ester compounds and uses thereof |
| ES2211358B1 (en) * | 2002-04-12 | 2005-10-01 | Sumitomo Chemical Company, Limited | ESTER COMPOUND AND ITS USE. |
| JP4340761B2 (en) * | 2002-11-18 | 2009-10-07 | 住友化学株式会社 | Insect repellent |
| JP4857680B2 (en) * | 2005-09-14 | 2012-01-18 | 住友化学株式会社 | How to store pest control agents |
| US8173702B2 (en) * | 2007-03-30 | 2012-05-08 | Sumitomo Chemical Company, Limited | Pesticidal composition and method for controlling harmful insects |
| JP5326320B2 (en) * | 2007-03-30 | 2013-10-30 | 住友化学株式会社 | Pest control composition and pest control method |
| JP2008255039A (en) * | 2007-04-03 | 2008-10-23 | Sumitomo Chemical Co Ltd | Heat transpirator for pest controlling use |
| JP5356754B2 (en) * | 2007-09-20 | 2013-12-04 | 住友化学株式会社 | Aqueous aerosol composition and pest control method using the same |
| AR082963A1 (en) * | 2010-09-17 | 2013-01-23 | Sumitomo Chemical Co | COMPOSITION FOR PEST CONTROL AEROSOL |
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