TW201225405A - Dual chamber fuel cell power supply - Google Patents

Dual chamber fuel cell power supply Download PDF

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TW201225405A
TW201225405A TW099142498A TW99142498A TW201225405A TW 201225405 A TW201225405 A TW 201225405A TW 099142498 A TW099142498 A TW 099142498A TW 99142498 A TW99142498 A TW 99142498A TW 201225405 A TW201225405 A TW 201225405A
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Taiwan
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hydrogen
fuel cell
water
hydride
power supply
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TW099142498A
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Chinese (zh)
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TWI451621B (en
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Chung-Hsing Chao
Jenn-Jong Shieh
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Ta Hwa Inst Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

An integrated dual chambers hydrogen energy system including a fuel cell for hydrogen control and electricity management applications by a chemical hydrides including magnesium or magnesium hydrides directly reacting with water using a catalysts for examples, stainless steel catalyst, and metal hydride hydrogen stage as a buffer to recycle heat energy to transfer the hydrogen storage and the effectiveness analysis is proposed. In order to achieve this goal, a metal hydride hydrogen storage as a buffer not only recycles the heat energy from fuel cell but also averages the hydrogen supply of chemical hydrides including magnesium or magnesium hydrides reacting directly with water is setup. Experimental results prove that our prototype, the integrated dual chambers hydrogen energy system, can manage the heat energy from fuel cell and average hydrogen supply for chemical hydrides including magnesium or magnesium hydrides reacting directly with water. As a result, the user in on-demand period knows the data on the amount of hydrogen flow rate, the electricity from fuel cell, the fuel cell/reactor/metal hydride hydrogen storage temperature, and recycled heat energy storage capacity information by the system interface.

Description

201225405 六、發明說明: 【發明所屬之技術領域】 本發明係關於一種然料電池供電裝置,特別是一種具 雙氫氣流量供應之然料電池供電裝置。 【先前技術】 水是自然界中最豐富之元素,性質穩定且安全’其組成成 分中之氫原子,更可形成氫氣做為一乾淨之能源供人類使用。 數十年來,業界均在努力尋找一經濟安全有效之方法,來製造 出廉價而方便使用之氫氣做為能源。 目前習知之以電解方式製造氫氣技術,雖然技術可行,但 仍然有許多問題存在阻擾其應用上之普及,例如需耗大量之電 力進行電解,能源轉換效率差、產生不需要之廢棄物造成環境 污染、電極耗損或機器系統體積過大或氫氣供應不及等技術障 礙均屬之。 此外,如以金屬溶解於酸中,或以鹼金屬或鹼土族金屬 (alkali metals or alkali earth metal hydrides),或硼氫化合物 (borohydrides)與水反應等,亦可製造氫氣。然而此類反應技術 多以固體金屬化合物或硼氫化合物加水混合方式進行,除了產 生氮氣以外,尚有固體產品廢棄物及廢液產生殘留於反應系 統,部分甚至附著於未反應原料之表面而阻礙反應之繼續進 行。此外,此種反應速率快,固體反應物之量不易控制,所釋 放大量之熱常與產生之氫氣在含氧之環境卞V劇烈反應而發生 ***’以致造成安全上之疑慮。 曰本特開平8-115733號公報提出有一種令耐熱性電極接 觸於可设置在水中和水進行電熱化學反應的鋁體或鎂體所構 201225405 成的反應金屬體的狀態下,對反應金屬體树熱性電極通電並 進行水中放電’躺上述反應金屬體與水產生的電熱化學反應 產生氫氣的方法。 日本特開平mG8755號公報還提出—種使加熱至廳 以下的水與催化舰觸,把水分解而產生氫氣的方法。 另-方面’燃料電池可藉由水與氫氣之輸人,以提供一乾 淨、輕便、反舰速、安全且穩定之供電祕,為可有效解決 空氣污染及溫室效制題之—供電鶴。雜如鮮所述有許 多不同技術之錢技術可供轉電池之供钱統使用,然而燃 料電池因貞鑛化,例如,簡電池運具在啟動/爬坡/加速、 等速、下坡減速、煞車等不同負載需求均會影響氫氣之流率, 因此無法提供連續穩定供電。 圖1所示為習知燃料電池供電裝置100示意圖,包括 辅助二次電池110、氫氣產生器丨2〇、燃料電池140、水槽 150、電源分配器130和幫浦8〇,冷卻水611與燃料電池 所需氫氣401經燃料電池140轉換成輸出直流電能113。 當燃料電池因負載變化,例如,燃料電池運具在啟動/爬坡 /加速、等速、下坡減速、煞車等不同負載需求時’電源分 配器130啟動輔助二次電池11〇輸出充電/放電輸出電力 113-2’以補償氩氣產生器120產生氫氣所輸出電力113-1 的不足或過剩。習知燃料電池供電裝置1〇〇之燃料電池14〇 所產生之廢熱(未示出)則釋出於空氣中外,另需一補充水 .. . . * · '·. , ·- . - -:; ;, . . _ . 1140給燃料電池140。習知燃料電池無電裝査100之主要 缺點除需要電源分配器130外,因無法將燃料電池產生廢 熱回收’以致整體之效率差。此外,習知燃料電池供電襄 置100仍然需要二次電池。因此仍無法完全有效可解決習知 201225405 二次電池電動車電池壽命有限(二〜三年)且會污染環境、充電時 間過長且能量密度低之缺點。 【發明内容】 為解決上述技術問題,.本發明提供了 一種廉價且可大 量穩定供給氫氣給然料電池,並提升燃料電池供電裝置整 體效率之雙氫氣流量供應之燃料電池供電裝置。雙氫氣流 量供應之燃料電池供電裝置包括··一燃料電池,接收〆燃 料電池輸入水與一燃料電池輸入氫氣以產生一輪出直流 電能、一燃料電池輸出水;一熱交換器,具有一第一熱交 換流與一第二熱交換流;一氫氣緩衝器,内裝一金屬氫化 物合金’該第二熱交換流經該氫氣緩衝器以產生〜第一氛 氣;一反應器,内裝一化學氫化物與一反應器水;該第二 熱交換流經該化學氮化物產生一第二氫氣與一水蒸汽;一 氮水分離器,接受該第一氫氣、該第二氫氣與一水蒸汽並 將該一水蒸汽冷卻為一氫水分離器輸出水,該燃科電池輸 入氫氣由該第一氫氣與該第二氫氣產生;一第一幫浦,經 一水槽使該燃料電池輸入水流串流該第一熱交換流;一第 二幫浦,使該第二熱交換流流經該氫氣緩衝器與該反應 器;一流量控制器,當該一第二氩氣小於該一燃料電池輸 入氫氣命令值時,控制使該第一氫氣與該一第二氫氣同時 供給該燃料電池輸入氩氣;且當該一第二氫氣大於該燃料 電池輸入氩氣命令值時,控制使該第二氫氣肉時供給該燃 料電池輸入氫氣與該一第二氫氣。 本發明藉由回收燃料電池產生廢熱提供氫氣緩衝器 與反應器使用以產生燃料電池所需的氫氣。因此本發明之 201225405 雙氫氣流量供應之燃料電池供電裝置然料電池之供電的 連續性與整體效率可大大提高外,本發明之排放物為水、 能量密度高’並可滿足美國能源部於2010年所定之單位重量 氫氣密度(6wt%)要求(鎂與水反應>7% ;氫化鎂與水反應 >15%)。 【實施方式】 以下將對本發明的實施例做出詳細說明。雖然本發明 將結合實施例進行閣述,但應理解這並非意指將本發明限 定於這些實施例。相反地’本發明意在涵蓋由後附申請專 利範圍所界定的本發明精神和範圍内所定義的各種變 化、修改和均等物。 此外’在以下對本發明的詳細描述中,闡明大量的具 體細節以提供針對本發明的全面理解。然而,本技術領域 中具有通常知識者應理解,沒有這些具體細節,本發明同 樣可以實施。以下結合附圖和具體實施例對本發明的技術 方法進行詳細的描述,以使本發明的特徵和優點更為明 顯0 圖2所示為根據本發明一實施例雙氫氣流量供應之 燃料電池供電裝置200示意圖。如圖2所示,燃料電池供 電裝置200包括氫氣緩衝器(hydrogen gas buffer)10、反應 器(reactor)20、流量控制器(mass f|〇w controller, MFC)30、 燃料電池(full cell)4〇、水槽(切ater tank)50、熱交換器(heat exchanger)60、氫水分離器(hydrogen gas/water separator)70 和幫浦(pump)80與90。 在反應器20内包括來自水槽5〇的水mi與化學氫化 201225405 物1110。幫浦90帶動熱交換器60之熱交換器輸出熱水 602以提供熱源給反應n 2G,使反應|| 2G㈣化學氮化 物mo與水ini反應。在一實施例中,化學氣化物包 括鎂(magnesium)或氫化鎂(magnesiumhydride) 〇 在一實施例 中,水1111與化學氫化物包括鎂或氫化錢111〇在室溫下反 應。在一實施例中,為提高化學氫化物1110之反應速率, 熱交換器60所回收燃料電池4〇廢熱(未示出)可將熱交換器 輸出熱水602以將反應器20之反應溫度提高至4〇〜6〇。c。 φ 水1111與鎂或氫化鎂1110在藉由反應產生氫氣的同時,伴 隨著氫氣的發生同時產生錢氣H為了從反應器 20取出的氣體中區分氫氣和水蒸氣,在反應器2〇與流量 控制器30之間設置氫水分離器7〇,藉由氮水分離器7〇 取出的氫氣且把水蒸氣冷卻為氫水分離器輸出水3〇3並回 收至水槽50以再利用。 氫氣儲存器ίο内褒有金屬氫化物合金1112,可提供或 吸收氫氣。金屬氫化物合金1112,是丨個金屬原子大約與2、 # 3個’甚至更多個氫原子結合成之合金晶體,但仍保持金屬氫 化物合金1112的晶體結構。一旦條件改變,如稍微加熱,氫 原子就會從晶體空隙中跑出來,並以氩氣的形式放出,同時 金屬氫化物合金1112的晶體也會恢復原狀。因此,金屬氫化 物合金1112的貯氫過程是可逆的,有人稱它為「可逆貯氫」。 金屬氫化物合金1112不僅貯氫量大,且可以反覆使用。可以 作為金屬氩化物合金lm材嵙必須滿足下列條件^會先貯 氫量要大;第二,吸氫和放氫都容易,只要稍稍加熱就可以 放氫且速度要快;第三,使用壽命長和價格便宜。目前,有 很多正在研究和開發的金屬氫化物合金1112,但歸納起來主 201225405201225405 VI. Description of the Invention: [Technical Field] The present invention relates to a battery power supply device, and more particularly to a battery power supply device having a dual hydrogen flow supply. [Prior Art] Water is the most abundant element in nature, and its properties are stable and safe. The hydrogen atoms in its constituent components can form hydrogen as a clean energy source for human use. For decades, the industry has struggled to find an economically safe and effective way to make cheap and easy-to-use hydrogen as an energy source. At present, the technology of hydrogen production by electrolysis is known. Although the technology is feasible, there are still many problems that hinder the popularization of its application, such as the need to consume a large amount of electricity for electrolysis, poor energy conversion efficiency, and the generation of unnecessary waste. Technical obstacles such as pollution, electrode wear or excessive volume of the machine system or inability to supply hydrogen are all. Further, hydrogen may be produced by dissolving a metal in an acid, or by reacting alkali metals or alkali earth metal hydrides, or borohydrides with water. However, such reaction techniques are mostly carried out by mixing a solid metal compound or a boron hydride compound with water. In addition to generating nitrogen, solid product waste and waste liquid remain in the reaction system, and some even adhere to the surface of the unreacted raw material to hinder The reaction continues. In addition, such a reaction rate is fast, the amount of the solid reactant is not easily controlled, and a large amount of heat is often released and the hydrogen generated in the oxygen-containing environment 剧烈V reacts violently to cause an explosion, resulting in safety concerns. Japanese Laid-Open Patent Publication No. Hei 8-115733 proposes a reaction metal body in which a heat-resistant electrode is brought into contact with a reaction metal body of 201225405 formed by an aluminum body or a magnesium body which can be disposed in water and water for electrothermal chemical reaction. The tree heat electrode is energized and discharged in water. The method of generating hydrogen gas by the electrothermal chemical reaction between the metal body and the water is described. Japanese Patent Laid-Open Publication No. mG8755 also proposes a method of decomposing water to generate hydrogen gas by heating water below the hall with a catalytic ship. In addition, the fuel cell can be supplied by water and hydrogen to provide a clean, lightweight, anti-ship speed, safe and stable power supply secret, which can effectively solve the problem of air pollution and greenhouse efficiency. There are many different technology money technologies that can be used for the transfer of batteries. However, fuel cells are demineralized due to sputum mineralization, for example, simple battery tools in start/climb/acceleration, constant speed, downhill Different load demands, such as braking, affect the flow rate of hydrogen, so it is impossible to provide continuous and stable power supply. 1 is a schematic diagram of a conventional fuel cell power supply device 100, including an auxiliary secondary battery 110, a hydrogen generator 丨2〇, a fuel cell 140, a water tank 150, a power distributor 130, and a pump 8 〇, cooling water 611 and fuel The hydrogen 401 required for the battery is converted by the fuel cell 140 into an output DC power 113. When the fuel cell changes due to load, for example, when the fuel cell carrier is in different load demands such as start/climb/acceleration, constant speed, downhill deceleration, braking, etc., the power distributor 130 activates the auxiliary secondary battery 11 〇 output charging/discharging The power 113-2' is output to compensate for the shortage or excess of the output power 113-1 of the hydrogen generated by the argon generator 120. The waste heat (not shown) generated by the fuel cell 14 of the conventional fuel cell power supply device is released from the air, and a supplementary water is required. . . . . . . . . . . . :; ; , . . _ . 1140 to the fuel cell 140. The main disadvantage of the conventional fuel cell powerless device 100 is that, in addition to the power distributor 130, the fuel cell cannot be recovered from waste heat, so that the overall efficiency is poor. In addition, the conventional fuel cell power supply unit 100 still requires a secondary battery. Therefore, it is still not fully effective to solve the conventional knowledge. 201225405 Secondary battery electric vehicles have limited battery life (two to three years) and are disadvantageous in polluting the environment, charging time is too long, and energy density is low. SUMMARY OF THE INVENTION In order to solve the above technical problems, the present invention provides a fuel cell power supply device which is inexpensive and can stably supply a hydrogen supply battery and improve the overall efficiency of the fuel cell power supply device. The dual-hydrogen flow supply fuel cell power supply device comprises: a fuel cell, receiving the fuel cell input water and a fuel cell input hydrogen to generate a round of DC power, a fuel cell output water; a heat exchanger having a first a heat exchange stream and a second heat exchange stream; a hydrogen buffer containing a metal hydride alloy; the second heat exchange flows through the hydrogen buffer to produce a first atmosphere; a reactor containing a a chemical hydride and a reactor water; the second heat exchange flows through the chemical nitride to produce a second hydrogen and a water vapor; a nitrogen water separator receives the first hydrogen, the second hydrogen and a water vapor Cooling the water vapor into a hydrogen water separator output water, the fuel cell input hydrogen is generated by the first hydrogen gas and the second hydrogen gas; a first pump, the fuel cell is input into the water flow string through a water tank Flowing the first heat exchange stream; a second pump flowing the second heat exchange stream through the hydrogen buffer and the reactor; a flow controller when the second argon gas is less than the fuel cell input When the gas command value is controlled, the first hydrogen gas and the second hydrogen gas are simultaneously supplied to the fuel cell to input argon gas; and when the second hydrogen gas is greater than the fuel cell input argon gas command value, the second hydrogen gas is controlled The fuel cell is supplied with hydrogen and the second hydrogen gas. The present invention provides a hydrogen sump and a reactor to generate hydrogen gas for use in a fuel cell by recovering waste heat from a fuel cell. Therefore, the continuity and overall efficiency of the power supply of the fuel cell power supply device of the 201225405 dual hydrogen flow supply of the present invention can be greatly improved, and the emission of the present invention is high in water and energy density, and can satisfy the US Department of Energy in 2010. The annual weight per unit weight of hydrogen (6 wt%) is required (magnesium reacts with water >7%; magnesium hydride reacts with water > 15%). [Embodiment] Hereinafter, embodiments of the invention will be described in detail. While the invention will be described in conjunction with the embodiments, it is understood that this invention is not intended to limit the invention. Rather, the invention is intended to cover various modifications, alternatives, and equivalents as defined by the scope of the invention. Further, in the following detailed description of the invention, numerous specific details are set forth However, it will be understood by those of ordinary skill in the art that the present invention may be practiced without these specific details. The technical method of the present invention will be described in detail below with reference to the accompanying drawings and specific embodiments to make the features and advantages of the present invention more obvious. FIG. 2 is a diagram showing a fuel cell power supply device with dual hydrogen flow supply according to an embodiment of the present invention. 200 schematic. As shown in FIG. 2, the fuel cell power supply device 200 includes a hydrogen gas buffer 10, a reactor 20, a flow controller (mass f|〇w controller, MFC) 30, and a fuel cell (full cell). 4, a sink tank 50, a heat exchanger 60, a hydrogen gas/water separator 70, and pumps 80 and 90. Water m from the water tank 5 and chemical hydrogenation 201225405 1110 are included in the reactor 20. The pump 90 drives the heat exchanger of the heat exchanger 60 to output hot water 602 to provide a heat source for the reaction n 2G to react the reaction || 2G(tetra) chemical nitride mo with the water ini. In one embodiment, the chemical vapor comprises magnesium or magnesium hydride. In one embodiment, water 1111 is reacted with a chemical hydride, including magnesium or hydrogenated money, at room temperature. In one embodiment, to increase the reaction rate of the chemical hydride 1110, the waste heat of the fuel cell 4 recovered by the heat exchanger 60 (not shown) may output the hot water 602 to the heat exchanger to increase the reaction temperature of the reactor 20. To 4〇~6〇. c. φ water 1111 and magnesium or magnesium hydride 1110 generate hydrogen gas by reaction, and hydrogen gas is generated simultaneously with the generation of hydrogen gas. In order to distinguish between hydrogen and water vapor in the gas taken out from the reactor 20, the reactor 2 flows and flows. A hydrogen water separator 7 is disposed between the controllers 30, and the hydrogen gas taken out by the nitrogen water separator 7 is cooled and cooled to a hydrogen water separator output water 3〇3 and recovered in the water tank 50 for reuse. The hydrogen reservoir ίο has a metal hydride alloy 1112 that provides or absorbs hydrogen. The metal hydride alloy 1112 is an alloy crystal in which about one metal atom is bonded to about 2, #3 or even more hydrogen atoms, but the crystal structure of the metal hydride alloy 1112 is maintained. Once the conditions change, such as a slight heat, the hydrogen atoms will escape from the crystal voids and be released as argon, while the crystals of the metal hydride alloy 1112 will return to their original state. Therefore, the hydrogen storage process of the metal hydride alloy 1112 is reversible, and it is called "reversible hydrogen storage". The metal hydride alloy 1112 has a large hydrogen storage amount and can be used repeatedly. It can be used as a metal argon alloy lm material. The following conditions must be met. ^The hydrogen storage capacity should be large first. Second, hydrogen absorption and hydrogen release are easy. As long as it is heated slightly, hydrogen can be released and the speed is fast. Third, the service life Long and cheap. At present, there are many metal hydride alloys 1112 being researched and developed, but it is summarized as the main 201225405

要有4大系列。第1個系列是鎂系貯氫合金,如氫化鎂、鎮-錄合金專,第2個系列是稀土系貯氫合金,如鋼-錄合金、混 合稀土鎳·猛合金、混合稀土鎳·鋁合金等·,第3個系列是鈦系 貯氫合金,如氫化鈦、鈦-錳合金等;第4個系列是鍅系貯氫 合金’如銼系貯氫合金應用作鎳-氫電池負極材料。在一實施 例中,金屬氫化物合包括但不限於氫化鋰(LiH)、氫化銅 (CuH2)、氫化鎂(MgH2)、鎂_鎳氫合金(MgNiH4)、氫化鈦 (TiH2)、鈦,鐵氫合金(TiFeH1 5)、鈦-鈷氫合金 (TiCoH1.5) '鈦-錳氫合金(TiMnl.5H2.14)、鈦-鉻氫合金 (Τι02Η2.6)或鑭-鎳氫合金(LaNi5H6)。 幫浦90亦帶動熱交換器輸出熱水6〇2以提供熱源給 氫氣儲存器1〇,使反應器20内的金屬氫化物合金(metal hydride)1112 反應。 β燃料電池所需的冷卻水403由熱交換器輸出冷水6〇1 提供。熱交換器輸出冷水601同時帶走燃料電池4〇所排 放之廢熱(未示出)。氫氣緩衝器10與反應器20所產生的 氫氣經氫水分離器70後送入流量控制器3〇以提供給燃料 電池所需的域備。燃料電池*所排放之燃料電池輸 出水402則回收至水槽50以再利用。理論上水槽5〇不需 水Μ。。然而一補充水1M〇可進-步提供水 槽50利用。 燃料電池供電裝置200啟動時,流量控制器7〇可控制 使燃料電池所需的氫氣賴與由氫氣緩衝器辦 ΙΓΓΓ燃料電池所需的氫氣4Gi與熱交換器輸出 帶錢錢魏U3G,且熱域轉出冷冰 帶走的燃料電池4〇所排放之廢熱(未示出)經熱交換器 201225405 60以提供熱交換器輸出熱水602並經由幫浦90給氫氣緩 衝器10與反應器20。氫氣緩衝器10與反應器20接收熱 交換器輪出熱水602之熱能以產生更多的氫氣給燃料電 池40,直到流量控制器輸出氫氣301與氫氣設定值115〇 相差在一預設定值範圍内。因此,燃料電池40產生廢熱(未 示出)可經由熱交換器60回收使用以產生燃料電池所需之氫 氣401,進而使整體之燃料電池供電裝置具相當高之效 率。 當燃料電池因負載變化,例如,燃料電池運具在啟動 /爬坡/加速、等速、下坡減速、煞車等不同負載需求時, 若反應器20所產生的氫氣不足時,流量控制器7〇可控制 氫氣緩衝器10所產生的氫氣經氫水分離器70直接補充氫 氣給燃料電池40。反之,若反應器20所產生過多的氫氣 時’流量控制器70可控制反應器20使所產生之過多的氮 氣經氫水分離器70可直接送入氫氣緩衝器1〇,以進而將 過多的氫氣儲存起來。如此一來,本發明除不需習知燃料 電池供電裝置之電源分配器外,燃料電所需之氫氣4〇1連 續性可大大提升,進而使燃料電池40可產生穩定的輸出直 流電能1130,以大大提昇整體燃料電池供電裝置之供電 品質。 圖3所示為根據本發明一實施例雙氫氣流量供應之 燃料電池供電電動車300示意圖。在圖3與圖2中標記相 同的元件具有相似的功能,在此將不對這些元件進行詳細 描述。在圖3中,輸出直流電能H3〇可驅動一直流馬達 3010。在一實施例中,直流馬達3〇1〇驅動一電動車(未示出)。 因此,本發明裝置可解決習知二次電池電動車電池壽命有限 201225405 (二〜t年)且會㈣環境、充電時間過長域量贿低之缺點。 之辦根據本發明另""實施例雙氫氣流量供應 :、枓電池供電電動車彻示意圖。在圖4與圖2中標記 目同的7L件具有相似的功能,在此將不對這些元件進行詳 ^描it在圖4中,輸出直流電能113〇可經一反流器 nVerter)4020驅動一交流馬達4_。在一實施例中交直流 馬達4〇10驅動電動車(未示出)^因此,本發明裝置可解決 習知二次電池電動車電池壽命有限(二〜三年)骑污染環境、 充電時間過長且能量密度低之缺點。 上文具體實施方式和附圖僅為本發 例:顯然,脫離權利要求書所界定的二;用神3 魏圍的喊下可以有各種增補、修改和㈣。本領域技 術人員應該理解,本發明在實際制中可根據具體的環境 和工作要求在*背離發明準·前提下在形式、結構、佈 局比例材料、元素、元件及其它方面有所變化。因此, 在此彼露之魏例僅驗說明而非限制,本發明之範圍由 後附權利要求及其合法等同物界定,而不限於此前之描 述。 【圖式簡單說明】 圖1習知燃料電池供電裝置。 圖2本發肖實施例雙氫氣流,量供應之燃料電池供電裳 置示意圖。 圖3根據本發明—實施例雙氫氣流量供應之燃料電池供 電電動車示意圖。 12 201225405 圖4根據本發明另一實施例雙氫氣流量供應之燃料電池 供電電動車示意圖。 【主要元件符號說明】 100:習知燃料電池供電裝置示意圖 110 :輔助二次電池 120 :氫氣產生器 140 :燃料電池 150 :水槽 130 :電源分配器 611 :冷卻水 113-1 :輸出電力 1Π-2充電/放電輸出電力 1140 :補充水 200:本發明一實施例雙氫氣流量供應之燃料電池供電裝置 示意圖 10 :氫氣緩衝器 20 :反應器 30 :流量控制器 40 :燃料電池 50 :水槽 60 :熱交換器 70:氫水分離器 80、90 :幫浦 1110 :化學氫化物、鎂、氫化鎂 1111:水 13 201225405 1112 :金屬氫化物合金 1140 : —補充水 113、mo :輸出直流電能 1150 :氫氣設定值 301 :流量控制器輸出氫氣 303 :氫水分離器輸出水 401 :燃料電池所需的氫氣 402 :燃料電池輸出水 403 :燃料電池所需的冷卻水 602 :熱交換器輸出熱水 300 :本發明一實施例雙氫氣流量供應之燃料電池供電電動 車示意圖 3010 :直流馬達 400 :本發明另一實施例雙氫氣流量供應之燃料電池供電電 動車示意圖 4020 :反流器 4010 ··交流馬達There are 4 series. The first series is magnesium-based hydrogen storage alloys, such as magnesium hydride, town-recorded alloys, and the second series is rare earth-based hydrogen storage alloys, such as steel-recorded alloys, mixed rare earth nickels, alloys, mixed rare earth nickels and aluminums. Alloys, etc., the third series is titanium hydrogen storage alloys, such as titanium hydride, titanium-manganese alloys; the fourth series is lanthanide hydrogen storage alloys such as lanthanide hydrogen storage alloys for nickel-hydrogen battery anode materials . In one embodiment, the metal hydride includes, but is not limited to, lithium hydride (LiH), copper hydride (CuH2), magnesium hydride (MgH2), magnesium-nickel hydride (MgNiH4), titanium hydride (TiH2), titanium, iron. Hydrogen alloy (TiFeH1 5), titanium-cobalt hydrogen alloy (TiCoH1.5) 'Titanium-manganese hydrogen alloy (TiMnl.5H2.14), titanium-chromium hydrogen alloy (Τι02Η2.6) or bismuth-nickel hydrogen alloy (LaNi5H6) . The pump 90 also drives the heat exchanger to output hot water 6 〇 2 to provide a heat source to the hydrogen reservoir 1 〇 to react the metal hydride 1112 in the reactor 20. The cooling water 403 required for the beta fuel cell is supplied by the heat exchanger output cold water 〇1. The heat exchanger outputs cold water 601 while taking away the waste heat (not shown) discharged from the fuel cell 4〇. The hydrogen buffer 10 and the hydrogen produced by the reactor 20 are sent to the flow controller 3 through the hydrogen water separator 70 to provide the required field for the fuel cell. The fuel cell output water 402 discharged from the fuel cell* is recovered to the water tank 50 for reuse. In theory, the water tank does not need water. . However, a supplemental water 1M can be used to provide the water tank 50. When the fuel cell power supply device 200 is started, the flow controller 7 can control the hydrogen required for the fuel cell and the hydrogen gas 4Gi and the heat exchanger output required by the hydrogen buffer to carry the fuel cell, and the heat is transferred to the U3G. The waste heat (not shown) discharged from the field of the fuel cell 4 taken out of the cold ice passes through the heat exchanger 201225405 60 to provide the heat exchanger output hot water 602 and to the hydrogen buffer 10 and the reactor 20 via the pump 90. . The hydrogen buffer 10 and the reactor 20 receive the heat energy of the heat exchanger wheel hot water 602 to generate more hydrogen to the fuel cell 40 until the flow controller output hydrogen 301 differs from the hydrogen set point 115 在一 by a predetermined value. Within the scope. Therefore, the waste heat generated by the fuel cell 40 (not shown) can be recovered via the heat exchanger 60 to produce the hydrogen gas 401 required for the fuel cell, thereby making the overall fuel cell power supply apparatus considerably more efficient. When the fuel cell changes due to load, for example, when the fuel cell carrier is in different load demands such as start/climb/acceleration, constant speed, downhill deceleration, braking, etc., if the hydrogen generated by the reactor 20 is insufficient, the flow controller 7 The hydrogen gas generated by the hydrogen buffer 10 can be controlled to directly supply hydrogen to the fuel cell 40 via the hydrogen water separator 70. On the other hand, if the reactor 20 generates too much hydrogen, the flow controller 70 can control the reactor 20 so that the excess nitrogen generated can be directly sent to the hydrogen buffer 1 through the hydrogen water separator 70, thereby further excessive Hydrogen is stored. In this way, in addition to the conventional power distributor of the fuel cell power supply device, the continuity of the hydrogen gas required for fuel power can be greatly improved, so that the fuel cell 40 can generate stable output DC power 1130. In order to greatly improve the power quality of the overall fuel cell power supply. 3 is a schematic diagram of a fuel cell powered electric vehicle 300 with dual hydrogen flow supply in accordance with an embodiment of the present invention. Elements labeled the same in Figures 3 and 2 have similar functions and will not be described in detail herein. In Fig. 3, the output DC power H3 〇 can drive the DC motor 3010. In one embodiment, the DC motor 3〇1〇 drives an electric vehicle (not shown). Therefore, the device of the present invention can solve the shortcomings of the battery life of the conventional secondary battery electric vehicle, which is limited to 201225405 (two to t years) and will (4) the environment and the charging time is too long. According to the present invention, the "" embodiment of the dual hydrogen flow supply: 枓 battery-powered electric vehicle schematic diagram. The 7L parts labeled in FIG. 4 and FIG. 2 have similar functions, and these elements will not be described in detail herein. In FIG. 4, the output DC power 113〇 can be driven by a inverter nVerter 4020. AC motor 4_. In an embodiment, the AC/DC motor 4〇10 drives an electric vehicle (not shown). Therefore, the device of the present invention can solve the problem that the battery life of the conventional secondary battery electric vehicle is limited (two to three years), riding the environment, and charging time. Long and low energy density. The above detailed description and the accompanying drawings are only the present invention: obviously, the two defined by the claims; and the shouting of God 3 Weiwei can have various additions, modifications and (4). It should be understood by those skilled in the art that the present invention may vary in form, structure, layout material, elements, elements, and the like in the actual system in accordance with the specific environmental and operational requirements. Therefore, the scope of the present invention is defined by the appended claims and their legal equivalents, and is not limited by the foregoing description. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 shows a conventional fuel cell power supply device. Fig. 2 is a schematic view showing the fuel cell power supply of the double hydrogen flow and the quantity supplied in the embodiment of the present invention. Figure 3 is a schematic diagram of a fuel cell powered electric vehicle with dual hydrogen flow supply in accordance with the present invention. 12 201225405 FIG. 4 is a schematic diagram of a fuel cell powered electric vehicle with dual hydrogen flow supply according to another embodiment of the present invention. [Description of main component symbols] 100: Schematic diagram of a conventional fuel cell power supply device 110: Auxiliary secondary battery 120: Hydrogen generator 140: Fuel cell 150: Water tank 130: Power distributor 611: Cooling water 113-1: Output power 1Π- 2 Charging/Discharging Output Power 1140: Supplemental Water 200: A fuel cell power supply apparatus for dual hydrogen flow supply according to an embodiment of the present invention is shown in FIG. 10: Hydrogen buffer 20: Reactor 30: Flow controller 40: Fuel cell 50: Sink 60: Heat exchanger 70: Hydrogen water separator 80, 90: Pump 1110: Chemical hydride, magnesium, magnesium hydride 1111: Water 13 201225405 1112: Metal hydride alloy 1140: - Supplemental water 113, mo: Output DC power 1150: Hydrogen set value 301: Flow controller output hydrogen 303: Hydrogen water separator output water 401: Hydrogen gas required for fuel cell 402: Fuel cell output water 403: Cooling water required for fuel cell 602: Heat exchanger output hot water 300 FIG. 30 is a schematic diagram of a fuel cell-powered electric vehicle with dual hydrogen flow supply according to an embodiment of the present invention. 3010: DC motor 400: Another embodiment of the present invention provides dual-hydrogen flow supply for fuel cell power supply. EMU schematic 4020: 4010 · reflux AC motor

Claims (1)

201225405 七、申請專利範圍: 種雙氫氣流量供應之燃料電池供電裝置,包括: 一燃料電池’接收-燃料電池輸人水與—燃料電池輸 入氫氣以產生一輸出直流電能、一燃料電池輸出水; —熱交換n m熱交換流與―第二熱交換流; 一氫氣緩衝器,内裝一金屬氫化物合金,該第二熱交 換流經該氫氣緩衝器以產生一第一氮氣; 一反應器,内裝一化學氫化物與一反應器水;該第二 • 熱交換流經該化學氫化物產生一第二氫氣與一水蒸 汽; 了氫水分離器,接受該第—氫氣、該第二氫氣與一水 蒸汽並將該一水蒸汽冷卻為一氫水分離器輸出水,該 燃料電池輸入氫氣由該第一氫氣與該第二氫氣產生; 一第一幫浦,經一水槽使該燃料電池輸入水流串流該 第一熱交換流; 一第二幫浦,使該第二熱交換流流經該氫氣緩衝器與 Φ 該反應器; 一流量控制器,當該一第二氫氣小於該一燃料電池輸 入氫氣命令值時’控制使該第一氫氣與該一第二氫氣 同時供給該燃料電池輸入氫氣;且當該一第二氫氣大 於該燃料電池輸入氫氣命令值時,控制使該第二氫氣 同時供給該燃料電池輸入氫氣與該一第二氫氣。 2. 如申睛專利範圍第1項所述的燃料電池供電裝置,其 中,該燃料電池輸出水與該氫水分離器輸出水注入該 水槽。 3. 如申睛專利範圍第1項所述的燃料電池供電裝置,進 15 201225405 一步包括注入該水槽的一補充水。 4. =申凊專利fc圍第!項所述的燃料電池供電裝置其 中化學氫化物為鎂或氫化鎂。 5. 如申明專利範圍第1項所述的燃料電池供電裝置,其 中,其中該金屬氫化物合金為氫化鋰(LiH)、氫化銅 (CuH2)、氫化鎂(MgH2)、鎂-鎳氫合金(MgNiH4)、氫 化鈦(TiH2)、鈦-鐵氫合金(TiFeH1.5)、鈦姑氫合金 (TiCoH1.5)、鈦·錳氩合金(TiMnl.5H2.14)、鈦-鉻氫合 • 金(TiCr2H2.6)或鑭-鎳氫合金(LaNi5H6)。 6. 如申請專利範圍第1項所述的燃料電池供電裴置,其 中,該輸出直流電能驅動一直流馬達。 7. 如申請專利範圍第1項所述的燃料電池供電裝置,其 中,該輸出直流電能經一反流器驅動一交流馬達。201225405 VII. Patent application scope: A fuel cell power supply device for supplying dual hydrogen flow, comprising: a fuel cell 'receiver-fuel cell input water and fuel cell input hydrogen to generate an output DC power, a fuel cell output water; a heat exchange nm heat exchange stream and a "second heat exchange stream; a hydrogen buffer containing a metal hydride alloy, the second heat exchange flowing through the hydrogen buffer to produce a first nitrogen; a reactor, a chemical hydride and a reactor water are installed; the second heat exchange flows through the chemical hydride to generate a second hydrogen and a water vapor; and a hydrogen water separator receives the first hydrogen and the second hydrogen And a water vapor and cooling the water vapor to a hydrogen water separator output water, the fuel cell input hydrogen is generated by the first hydrogen gas and the second hydrogen gas; a first pump, the fuel cell is passed through a water tank The input water stream streams the first heat exchange stream; a second pump causes the second heat exchange stream to flow through the hydrogen buffer and Φ the reactor; a flow controller, when the one When the hydrogen gas is smaller than the input hydrogen command value of the fuel cell, 'controlling that the first hydrogen gas and the second hydrogen gas are simultaneously supplied to the fuel cell input hydrogen; and when the second hydrogen gas is greater than the fuel cell input hydrogen command value, Controlling the second hydrogen to simultaneously supply the fuel cell input hydrogen to the second hydrogen. 2. The fuel cell power supply device according to claim 1, wherein the fuel cell output water and the hydrogen water separator output water are injected into the water tank. 3. For the fuel cell power supply device according to item 1 of the scope of the patent application, the step of 2012 20120405 includes a supplementary water injected into the water tank. 4. = apply for patent fc circumference! The fuel cell power supply device of the invention wherein the chemical hydride is magnesium or magnesium hydride. 5. The fuel cell power supply device according to claim 1, wherein the metal hydride alloy is lithium hydride (LiH), copper hydride (CuH2), magnesium hydride (MgH2), magnesium-nickel hydrogen alloy ( MgNiH4), titanium hydride (TiH2), titanium-iron-hydrogen alloy (TiFeH1.5), titanium hydrogen alloy (TiCoH1.5), titanium-manganese argon alloy (TiMnl.5H2.14), titanium-chromium hydride/gold (TiCr2H2.6) or bismuth-nickel hydride alloy (LaNi5H6). 6. The fuel cell power supply device of claim 1, wherein the output DC power drives the DC motor. 7. The fuel cell power supply device of claim 1, wherein the output DC power is driven by an inverter to an AC motor.
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