TW201224064A

TW201224064A - Basic colorant, color composition, color filter and display element

Info

Publication number: TW201224064A
Application number: TW100132172A
Authority: TW
Inventors: Eiji Yoneda; Satoshi Ebata; Shingo Naruse
Original assignee: Jsr Corp
Priority date: 2010-09-15
Filing date: 2011-09-07
Publication date: 2012-06-16
Also published as: CN102408753A; KR20120028815A; TWI561586B

Abstract

The subject of the present invention provides a basic colorant having a superior heat resistance than in the prior art. The solution of the present invention is a basic colorant having an anion represented by the following formula (1): R(-SO3-)n (1) [in formula(I), R represents a n-valent organic group composed of 1 to 16 atoms (excluding a hydrogen atom), and n represents an integer of 2 to 4].

Description

201224064 六、發明說明：【發明所屬之技術領域】本發明關於一種鹼性著色劑、著色組成物、彩色濾光片及顯示元件’更詳細而言，關於一種驗性著色劑，其適合使用於透過型或反射型的彩色液晶顯示元件、固體攝影元件、有機el顯示元件、電子紙等的彩色濾光片 ;含有該著色劑之著色組成物；一種彩色濾光片，其具備含有該著色劑的著色層；及具備該彩色濾光片之顯示元件。【先前技術】已知在使用放射線感應性著色組成物製造彩色濾光片時，藉由在基板上塗布顏料分散型的放射線感應性著色組成物並使其乾燥之後，對乾燥塗膜照射放射線（以下稱為「曝光」）而顯像成所希望的圖案形狀，而得到各色晝素的方法（專利文獻1〜2) ^另外還已知利用分散有碳黑的光聚合性組成物而形成黑色矩陣的方法（專利文獻 3)。甚至還已知藉由使用顏料分散型的著色樹脂組成物進行喷墨的方式而得到各色晝素的方法（專利文獻4)。附帶一提地’對於實現顯示元件的高輝度化與高色純度化、或固體攝影元件的高精細化而言，已知使用染料作為著色劑是有效的。例如在專利文獻5中提出了一種特定構造之三芳香基甲烷系染料之使用。 [先前技術文獻] [專利文獻] [專利文獻1]日本特開平2_1445〇2號公報 [專利文獻2]日本特開平3_532〇1號公報 201224064 [專利文獻3]曰本特開平6_351 88號公報 [專利文獻4]日本特開2〇〇〇_3 1〇7〇6號公報 [專利文獻5]日本特開2〇〇8_3〇4766號公報【發明内容】 [發明所欲解決之課題] 然而，專利文獻5所提出以三芳香基甲烷系染料為首的鹼性著色劑，其耐熱性不足，若經過超過2〇〇<；c這樣的曝光-顯像後的加熱（後烘烤）步驟，則失去對於顏料在色度特性上的優勢性。在以上所述般的背景之下，非常需要開發出耐熱性優異的鹼性著色劑。所以本發明的課題在於提供一種耐熱性優異的鹼性著色劑及著色組成物。甚至，本發明之課題在於進一步提供一種彩色濾光片，其具備含有該著色劑的著色層而成；及一種顯示元件，其具備該彩色濾光片。 [用於解決課題之手段] 本發明人等潛心檢討的結果，發現具有特定的多官能磺酸根作為陰離子部之鹼性著色劑可解決上述課題。亦即，本發明提供一種鹼性著色劑（以下亦稱為「本著色劑」）’其係具有下述式（1)所表示之陰離子。 R(—S03-)n ⑴ [式（1)之卡，R表示1〜16個原子（但是氫原子除外）所構成之η價有機基，η表示2〜4之整數。j 另外，本發明提供一種著色組成物其係含有著色劑、（Β)黏結劑樹脂及（C)交聯劑之著色組成物，其含有本著色劑作為（Α)著色劑；一種彩色濾光片，其具備 201224064 含有本著色劑的著色層而成；以及一種顯示元件… 備該彩色據光片。在此處，「著色層」意指使用於彩色濾光片的各色畫素、黑色矩陣 '累色間隔物等。 [發明之效果] ^本著色劑的耐熱性優異。只要使用含有本著色劑的著色、、且成物，則即使經過高溫的加熱步驟，依然可形成保持優異的色度特性的著色層。 --:本著色劑可極適合使用於製作以彩色液晶顯不儿件用彩色濾光片、固體 u媸攝衫兀件之色分解用彩色濾光片、有機E L顯示元件用奢咨凃止 Η Ά ^ ^ 心色濾先片、電子紙用彩色濾尤月馮言的各種彩声瀹本 #用Μ㈣另外’本著色劑還可適合使用於』膠成型物之著色、碳粉用的著色劑、電、永顯…墨欠用的者色劑、彩色【實施方式】凡件用的著色劑等。 [用於實施發明之形態j 以下針對本發明作詳細說明本著色劑本者色劑為一種以陽雜三劣而且具有上述式⑴所表亍之’I色團的鹼性著色劑’ 可推測本著色劑藉由導為陰離子部。亦即而使陽離子集中累積，“Π1 “艮作為陰離子部，著色劑可列舉例如：#色劑的耐熱性提高。本 ώ十丨 —香基甲烷系著色劑、-Α田w ^ 色劑、偶氮系著色劑、二 ^ -人甲基系著系著色劑、蒽醌系著g… f烷系著色劑、醌亞胺色劑。者色劑、駄青素系著色劑…星系著首先說明式⑴中記號的定義。 201224064 & R表示由卜16個原子（但是氫原子除外）所構成 4貝有機基，而氫原子除外，原子數以2〜子除外，構成R的原子數若超過16個，則會有本 ^原著色力降低的顧慮。色4之例如R只要滿^上述條件則並未受到特別限定，而可列舉 ”經取代或非經取代之非芳香族煙基「特性基（rl)」）、兀知為 2) 經取代或非經取代之複數個非芳香族炉雜原子的2價連結基所連結之基(以了亦稱為「；二: 」）、土、） 3) 經取代或非經取代之芳香族性基⑼」）杳…(以下亦稱為「特 4) 經取代或非經取代之2個芳香族烴子的2價連結基或2價非芳香 3雜原201224064 VI. Description of the Invention: [Technical Field] The present invention relates to an alkaline coloring agent, a coloring composition, a color filter, and a display element. More specifically, regarding an anionic coloring agent, it is suitable for use in a color filter of a transmissive or reflective type color liquid crystal display element, a solid-state imaging element, an organic EL display element, an electronic paper, or the like; a colored composition containing the coloring agent; and a color filter having the coloring agent a coloring layer; and a display element having the color filter. [Prior Art] When a color filter is manufactured using a radiation-sensitive coloring composition, it is known that a pigment-dispersed radiation-sensitive coloring composition is applied onto a substrate and dried, and then the dried coating film is irradiated with radiation ( In the following, a method of obtaining a desired pattern shape to obtain a desired color is obtained (Patent Documents 1 to 2). Further, it is also known to form a black color by using a photopolymerizable composition in which carbon black is dispersed. Method of matrix (Patent Document 3). Further, a method of obtaining a coloring matter by a method of performing inkjet using a pigment-dispersed colored resin composition is known (Patent Document 4). Incidentally, it is known that it is effective to use a dye as a colorant in order to achieve high luminance and high color purity of a display element or high definition of a solid-state imaging element. For example, Patent Document 5 proposes the use of a triarylmethane dye of a specific configuration. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 5] Japanese Patent Laid-Open Publication No. JP-A No. Hei. No. Hei. No. Hei. Patent Document 5 proposes an alkaline coloring agent including a triarylmethane dye, which is insufficient in heat resistance, and if subjected to an exposure-development heating (post-baking) step of more than 2 〇〇<;c, Then the advantage of the pigment in terms of chromaticity is lost. Under the above-described background, it is highly desirable to develop an alkaline coloring agent excellent in heat resistance. Therefore, an object of the present invention is to provide an alkaline coloring agent and a coloring composition which are excellent in heat resistance. Further, another object of the present invention is to provide a color filter comprising a coloring layer containing the coloring agent, and a display element comprising the color filter. [Means for Solving the Problems] As a result of intensive review by the present inventors, it has been found that the above-mentioned problem can be solved by having a specific polyfunctional sulfonate as an alkali coloring agent of an anion portion. In other words, the present invention provides an alkaline coloring agent (hereinafter also referred to as "the present coloring agent") which has an anion represented by the following formula (1). R(-S03-)n (1) [Card of the formula (1), R represents an η-valent organic group composed of 1 to 16 atoms (except for a hydrogen atom), and η represents an integer of 2 to 4. Further, the present invention provides a coloring composition comprising a coloring agent, a (Β) binder resin, and a coloring composition of (C) a crosslinking agent, which comprises the coloring agent as a coloring agent; a color filter A sheet having 201224064 a coloring layer containing the coloring agent; and a display element... the color light sheet is prepared. Here, "colored layer" means each color pixel used for a color filter, a black matrix 'relenty spacer, and the like. [Effects of the Invention] The present colorant is excellent in heat resistance. When a coloring or the like containing the coloring agent is used, a coloring layer which maintains excellent chromaticity characteristics can be formed even after a high-temperature heating step. --: This coloring agent is extremely suitable for use in the production of color filters for color liquid crystal display, color filter for color decomposition of solid u-shirts, and coating of organic EL display elements. Η Ά ^ ^ Heart color filter, electronic paper color filter, special features of the moon, Feng Yan, 彩 Μ (4) In addition, 'this colorant can also be used for the coloring of the plastic molding, the coloring of the toner Agent, electricity, permanent display... Ink toner, color [Embodiment] Coloring agent for all parts. [Formula j for carrying out the invention] The present invention will be described in detail below with reference to the present invention. The coloring agent is a basic coloring agent which has a 'I color group which is expressed by the above formula (1). The colorant is introduced as an anion portion. That is, the cations are concentrated and accumulated, and "Π1" is used as the anion portion, and the colorant may, for example, be improved in heat resistance of the #色剂. ώ 丨丨香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香香Anthraquinone toner. Colorant, anthraquinone coloring agent... Galaxy First, the definition of the symbol in the formula (1) will be explained. 201224064 & R represents a 4-shell organic group consisting of 16 atoms (except for hydrogen atoms), except for a hydrogen atom, except for the number of atoms 2 to 2, and if the number of atoms constituting R exceeds 16, ^ The original color loss concerns. The color 4 is, for example, R as long as the above conditions are not particularly limited, and may be exemplified by a "substituted or unsubstituted non-aromatic smoke group "characteristic group (rl)"), which is known as 2) substituted or a group of non-aromatic non-aromatic furnace heteroatoms linked by a divalent linking group (also referred to as "; two:"), earth, and 3) substituted or unsubstituted aromatic groups (9)") 杳... (hereinafter also referred to as "special 4") A divalent linking group or a divalent non-aromatic 3 impurity of two substituted or unsubstituted aromatic hydrocarbons

Hk丞所連結之基（稱為「特性基（r4)」）、（乂下亦 5) 經取代或非經取代之雜揮| 雜缞基（以下亦稱為「特性其 (r5)」）等。 ~付！生基上述特性基⑴)中的非芳香族烴基只要族烴基則不受特別限定，可列無，、有方香夕J舉例如由脂肪族烴除. 〜4個氣原子之基、由脂環式經除去2〜4個氣原由脂肪族煙與脂環式烴連結的煙除去2〜4個氣原子:其。脂肪族烴之具體例可列舉烷土烯、炔等；脂環式帜夕具體例可列舉環烷、環烯、飨八夕衣式垤之坤麵合多環烴、架橋環庐、烴、環狀搭烯烴等。特性基（Γ1) 展4螺 ’ Τ的取代基可列舉γ丨石占素基、羥基、烷氧基、側氧基、 ^ 胺基等而在提高本著 201224064 色劑之耐熱性這點上，佳，以經氟基取代為特表例，可列舉例如下述 x在較罪近_S〇3_的碳經_素基為佳。R為特性基（rl)的陰離子之代式所表示之陰離子。The base to which Hk丞 is connected (referred to as "characteristic base (r4)"), (乂下5) substituted or unsubstituted miscellaneous | heteropoly group (hereinafter also referred to as "characteristic (r5)") Wait. ~ pay! The non-aromatic hydrocarbon group in the above-mentioned characteristic group (1)) is not particularly limited as long as it is a group of a hydrocarbon group, and may be listed as a group of aliphatic hydrocarbons, for example, by a group of aliphatic hydrocarbons. The ring type removes 2 to 4 gas atoms and removes 2 to 4 gas atoms from the smoke of the aliphatic smoke and the alicyclic hydrocarbon: it. Specific examples of the aliphatic hydrocarbons include alkane olefins and alkyne; and specific examples of the alicyclic hydrocarbons include naphthenes, cycloolefins, octopus-type quinones, quinone-crossing polycyclic hydrocarbons, bridging rings, hydrocarbons, and hydrocarbons. Cyclic olefins and the like. The substituent of the characteristic group (Γ1) exhibits 4 snail' Τ 可丨丨占占、、、、、、、、、、丨丨 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 The fluorine-based substitution is a specific example, and for example, the following x is preferable to the carbon-based group of the sin 3_. R is an anion represented by the anion of the characteristic group (rl).

-〇3S 八^\^SCV-〇3S 八^\^SCV

FF

SO-SO-

〇3s FF 3 ^FX S〇3- OsS^VSOa 另外，上述特性基(r2)中的非芳香族烴Y::… 香族烴基：則不受特別限定’可列舉例如由脂肪族二去卜5個氩原子之基、由脂環式煙除去卜5個氮工除基、由脂肪族烴與脂環式烴連結的烴除去卜5個氫之之基等。脂肪族煙及脂環式煙之具體例可列舉與：：： (⑴中的脂肪族烴及脂環式煙同樣的化合物。特基中的取代基可列舉與特性基(rl)中的取代基同樣的= 。特性基0：2)中的含雜原子的2價連結基可列舉例如、2.co-、·。。。·、_c刪…NHCQNH、nr1r2 R互相獨立’表示氫原子或經取代或非經取代之、-S-、-SO-、s〇2_、_s各、2價雜環基等。另外，；土）性基⑼中可存在複數個含雜原子的2價連結基特性基（r2)的陰離子之代表例可列舉例如下述 .=特陰離子。丨衣不之 201224064 o3s^^s" SO3 〇3s- N- so3- 〇3SK_y-\〇3s FF 3 ^FX S〇3- OsS^VSOa Further, the non-aromatic hydrocarbon Y in the above-mentioned characteristic group (r2)::... An aromatic hydrocarbon group: is not particularly limited, and may be exemplified by, for example, aliphatic The base of five argon atoms, five nitrogen-removing groups removed from the alicyclic tobacco, and the hydrocarbons linked by the aliphatic hydrocarbon and the alicyclic hydrocarbon are removed from the five hydrogen groups. Specific examples of the aliphatic cigarette and the alicyclic cigarette include:: (1) an aliphatic hydrocarbon and an alicyclic cigarette. The substituent in the specific group may be exemplified by the substitution in the characteristic group (rl). The same is true. The hetero atom-containing divalent linking group in the characteristic group 0: 2) may, for example, be 2.co-, . . . ·, _c deleted...NHCQNH, nr1r2 R are independent of each other' represents a hydrogen atom or a substituted or unsubstituted, -S-, -SO-, s〇2_, _s each, a divalent heterocyclic group or the like. Further, a representative example of the anion having a plurality of hetero atom-containing divalent linking group (r2) in the soil-based group (9) is exemplified by the following: a specific anion.丨衣不之 201224064 o3s^^s" SO3 〇3s- N- so3- 〇3SK_y-\

o3s,O3s,

另外，上述特性基（r3)中的芳香族烴基並未受到特別限定，而可列舉例如由苯、聯笨、萘、罪' g '拓等除去2〜4個氫原子之基。特性基（r3)中的取代基可列舉例如鹵素基、羥基、烷氧基、胺基、烷基等^ R為特性基（r3) 的陰離子之代表例可列舉例如T述式所表示之陰離子。Further, the aromatic hydrocarbon group in the above-mentioned characteristic group (r3) is not particularly limited, and examples thereof include a group in which 2 to 4 hydrogen atoms are removed by benzene, hydrazine, naphthalene, s'g' extension or the like. Examples of the substituent in the functional group (r3) include a halogen group, a hydroxyl group, an alkoxy group, an amine group, an alkyl group, and the like, and a representative example of the anion having the characteristic group (r3) is, for example, an anion represented by the formula .

S〇3* SO, α: so3* so3- SO,·S〇3* SO, α: so3* so3-SO,·

SO,·SO,·

201224064 —另外，上述特性基（r4)中的芳香族烴基，可列舉例如由本除去1〜5個氫原子之基等。特性基“句中的取代基可列舉與上述特性基(r3)中的取代基同樣的基團。特性基 (r4)中的含雜原子的2價連結基可列舉與上述特性基(r2) 原子的2價連結基同樣的基團。特性基㈣中的2 仏非方香族烴基可列舉例如亞，基、伸烷 ^^Oso, -〇3S〇-^s〇3； Ά於等=肪族烴基，特性綱的陰離子之代= 了歹丨舉例如下述式所表示之陰離子 >S03·In addition, the aromatic hydrocarbon group in the above-mentioned characteristic group (r4) may, for example, be a group in which 1 to 5 hydrogen atoms are removed. The substituent in the phrase "the substituent in the sentence may be the same as the substituent in the above-mentioned characteristic group (r3). The hetero atom-containing divalent linking group in the characteristic group (r4) may be exemplified by the above-mentioned characteristic group (r2) The same group as the divalent linking group of the atom. The 2 仏 non-fragrance hydrocarbon group in the characteristic group (IV) may, for example, be a sub group, a hydrazine, an alkyl group, an anthracene group, an anthracene group, an anthracene group, an anthracene group, An aliphatic hydrocarbon group, an anion of a characteristic class = an anion represented by the following formula: > S03·

S03.S03.

另，而可雜環系作為構之基、合物除為構成基、由系化合構成環吡啶、啶等。外 …叫έ〇3.，h2 列舉";ΓΛ性基⑹中的雜環基並未受到特別限定幻舉例如由僅具有氮原子作化合物除去2〜4個氫原子之基，由：具=子之 :環的雜原子之雜環系化合物除去2二個 ; 堇具有硫原子作為構成環的雜原二 Γ:4個氫原子之基、由具有氮原子與氧；二 =:子之雜環系化合物除去— 具有氮原子與硫原子作為飞原子之物除去2〜4個氫原子之基:的雜原子之雜環的雜原子之雜環系化合物有氣原子作為，。朵、異十朵、啥琳1嗜琳體例可列舉°比略、僅具有氧原子作為構成咔唑、啡啶”丫的雜原子之雜環系化合 201224064 物之具體例可列舉口夫喃、 …等。僅具有硫原子作為構成南、異t完稀化合物之具體例可列：為的雜原子之雜環系原子作為構成環的雜々子二°塞葱等。具有氮原子與氧舉…等。具環系化合物之具體例可列之雜環系化合物之1體^原子作為構成環的雜原子性綱中的取代基可列舉與：二：：其…等。特基同樣的基團。R為特性A " 土（r3)中的取代例如下述式所表示::離基子(⑽Further, the heterocyclic ring-based compound may be used as a structural group, and the compound may be a compound or a pyridine or a pyridine. Exo...called έ〇3., h2 enumerates "; the heterocyclic group in the oxime group (6) is not subject to a special definition, for example, a group having 2 to 4 hydrogen atoms removed by having only a nitrogen atom as a compound, = 子子: A heterocyclic compound of a hetero atom of a ring is removed by two or two; 堇 has a sulfur atom as a hetero atom of a ring comprising two: a group of four hydrogen atoms, having a nitrogen atom and oxygen; and two =: Heterocyclic Compound Removal - A heterocyclic compound having a hetero atom of a hetero atom of a hetero atom having a nitrogen atom and a sulfur atom as a radical atom is used as a base of 2 to 4 hydrogen atoms. Examples of the heterologous compound of 201224064 which are heteroatoms which have an oxygen atom and which have a hetero atom which is an oxazole or a quinone fluorene can be exemplified by a specific example. A specific example in which only a sulfur atom is present as a constituent compound of a south or an iso-n-throat can be listed as a hetero atom of a hetero atom as a heterocyclic scorpion constituting a ring, etc. Specific examples of the ring-based compound include a monocyclic atom of the heterocyclic compound, and examples of the substituent in the hetero atomic group constituting the ring include: two:: R. is the characteristic A " The substitution in soil (r3) is represented by the following formula:: from the base ((10)

S〇3 * ?〇3* ΜS〇3 * ?〇3* Μ

S〇3- 另一方面，本著色劑所性發色團，亦即與上述式⑴所：的陽離子只要是陽離子性著色劑之陽離子，則並未=示之陰離子-起形成驗如三芳香基甲烧系發二未：：：別限定’而可列舉例色團、二芳香基甲燒系發色：糸發色團、偶氮系發系發色團、醜青素系發色團團：酿亞胺系發色團'葱酿三芳香基曱烧系發色團^ 佳。另外，在下述式(2)所：：：下述式⑺所表示者為振結構。在本說明書之中，各：離子中存在有各種共振結構的情況，則定為與該式；：表7^之陽離子存在共、所表不之陽離子同等者。 -10- 201224064S〇3- On the other hand, the chromophore of the coloring agent, that is, the cation of the above formula (1), as long as it is a cation of a cationic coloring agent, does not indicate an anion-forming formation as a three-fragrance The base of the base is not the second::: not limited to 'exemplified by the chromophore, the two aromatic ketones hair color: 糸 chromophore, azo hairline chromophore, ugly green color ensemble : Stuffed imine chromophore's onion-brewed three-aromatic enamel chromophore ^ good. Further, in the following formula (2)::: The vibrational structure is represented by the following formula (7). In the present specification, in the case where each of the ions has various resonance structures, it is determined that the cations of Table 7^ are identical to the cations of the above. -10- 201224064

[式（2)之中，[in the formula (2),

Ar表示芳烴環， R3及R4互相獨立，表示氫原子、碳數1〜8之烷基、碳數3〜8之環烷基、苯基或具有乙烯性不飽和鍵之基， R5及R6互相獨立，表示氫原子、碳數1〜8之烷基、碳數3〜8之環烷基、苯基或具有乙烯性不飽和鍵之基， R7表示氫原子、碳數1〜8之烷基、-COOR’（R’表示氫原子或碳數1〜8之烷基）或氣原子， R8及Rn互相獨立，表示氫原子或碳數1〜8之烷基、或R8與R11合在一起而表示氧原子， R9及R10互相獨立，表示氫原子、碳數1〜8之烷基或氣原子， Y表示氫原子或下述式（3)所表示之基。]Ar represents an aromatic hydrocarbon ring, and R3 and R4 are independent of each other, and represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, a cycloalkyl group having 3 to 8 carbon atoms, a phenyl group or a group having an ethylenically unsaturated bond, and R5 and R6 are mutually Independently, it represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, a cycloalkyl group having 3 to 8 carbon atoms, a phenyl group or a group having an ethylenically unsaturated bond, and R7 represents a hydrogen atom and an alkyl group having 1 to 8 carbon atoms. , -COOR' (R' represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms) or a gas atom, and R8 and Rn are independent of each other, and represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, or R8 and R11 are combined. Further, it represents an oxygen atom, and R9 and R10 are independent of each other, and represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms or a gas atom, and Y represents a hydrogen atom or a group represented by the following formula (3). ]

[式（3)之中，R12及R13互相獨立，表示氫原子、碳數1〜8 -11 - 201224064 之烷基、碳數3〜8之環烷基鍵之基。] 苯基或具有乙稀性不飽和In the formula (3), R12 and R13 are each independently, and represent a hydrogen atom, an alkyl group having 1 to 8 -11 to 201224064, and a cycloalkyl bond having 3 to 8 carbon atoms. Phenyl or having ethylenic unsaturation

Ar中的芳烴環係以碳數6〜2〇(較佳芳烴環為佳，具體而言可列舉苯環、萃；兔數6〜⑼之環。『'衣、聯笨環、蒽上述式⑺所關連之R3〜Rll(包 R，)以及上述式(3)所關連之…及r13中的一的基可列舉例如甲基 '乙基、丙基、異丙義炭數1〜8之烧丁基、第三丁基、異丁基：其丁基、第二基、辛基、異辛基、第_去^?第―戍基、己基、庚、〒丞第二辛基、2-乙基己基等。上述式（2)所關連之r3〜尺6以 R12及R13中的碳之環…列舉:;:(3)所關連之丁其、m & &基叮歹J舉例如環丙基、環丁基3裱戊基、環己基、環庚基等。 R R、R及R13中的具有乙烯性不飽和鍵之基並未受到特別限定，而可列舉例如CH2=CH COO_R14_、 CH2 = C(CH3)-C00-R^- 、 CH2 = CH-Ph-R-.、 CH2 = C(CH3)-Ph_R"_及CH2 = ch_c〇 (r14表* 碳數卜斗之烧二基，Ph表示伸苯基）等。 R中的碳數1〜4之烷二基可列舉例如亞甲基、伸乙基、乙烷-1，1-二基、丙烷—二基、丙烷_丨，2_二基、丙烷-1，3-二基、丙烷_2,2_二基'丁烷-12•二基、丁烷二基、丁烷-1，4_二基等。從提升輝度及色純度的觀點看來，在本發明之中的上述式（2)所表示之陽離子之中，尤其以下述式（4)所表示之陽離子為佳。 -12- 201224064 R5\ R6The aromatic hydrocarbon ring in Ar is preferably a carbon number of 6 to 2 Torr (preferably an aromatic hydrocarbon ring, specifically, a benzene ring, a extraction; a ring of 6 to 9 in rabbits). (7) The related R3 to Rll (package R) and the group of one of the above-mentioned formula (3) and r13 may, for example, be a methyl 'ethyl group, a propyl group, or an isopropyl carbon number 1 to 8. Butyl, tert-butyl, isobutyl: butyl, second, octyl, isooctyl, hexyl, hexyl, hexyl, decyl, decyl, 2 -ethylhexyl, etc. The r3~6 of the above formula (2) is a ring of carbon in R12 and R13... Listed by: (3) the related Ding, m && For example, a cyclopropyl group, a cyclobutyl 3 pentyl group, a cyclohexyl group, a cycloheptyl group, etc. The group having an ethylenically unsaturated bond in RR, R and R13 is not particularly limited, and examples thereof include CH2=CH. COO_R14_, CH2 = C(CH3)-C00-R^-, CH2 = CH-Ph-R-., CH2 = C(CH3)-Ph_R"_ and CH2 = ch_c〇 (r14 table * carbon number fighting The dibasic group, Ph represents a phenylene group, etc. The alkyl group having 1 to 4 carbon atoms in R may, for example, be a methylene group or a stretching group. Ethyl, ethane-1,1-diyl, propane-diyl, propane-oxime, 2-diyl, propane-1,3-diyl, propane-2,2-diyl-butane-12 Dibasic, butanediyl, butane-1,4-diyl, etc. Among the cations represented by the above formula (2) in the present invention, in particular, from the viewpoint of enhancing the luminance and color purity, The cation represented by the formula (4) is preferred. -12- 201224064 R5\ R6

R 13R 13

NN

Wn+/R3 R4 [式（4)之中，R3、R4、R5、R6、R12及 R13與上述式（2)及（3) 中的 R3、R4、R5、R6、R12及 R13 同義。] 上述式（4)之中，R3、R4、R12及R13係以碳數1〜8(較佳為碳數1〜6)之烷基或苯基為佳，另外，R5係以碳數1 〜8 (較佳為碳數1〜6)之烷基、環己基或苯基為佳，再者，R6係以碳數1〜8(較佳為碳數1〜6)之烷基、環己基、苯基或氫原子為佳。上述式（2)所表示之陽離子之代表例可列舉例如下述式所表示之陽離子。 -13- 201224064Wn+/R3 R4 [In the formula (4), R3, R4, R5, R6, R12 and R13 have the same meanings as R3, R4, R5, R6, R12 and R13 in the above formulas (2) and (3). In the above formula (4), R3, R4, R12 and R13 are preferably an alkyl group having 1 to 8 carbon atoms (preferably 1 to 6 carbon atoms) or a phenyl group, and R5 is a carbon number of 1 Preferably, R6 is an alkyl group having a carbon number of 1 to 8 (preferably having a carbon number of 1 to 6), and a ring is preferably an alkyl group having a carbon number of 1 to 6 (preferably a carbon number of 1 to 6). A hexyl group, a phenyl group or a hydrogen atom is preferred. Representative examples of the cation represented by the above formula (2) include a cation represented by the following formula. -13- 201224064

-14- 201224064-14- 201224064

另外，次甲基系發色團係以下述式（5-1)〜（5-3)所表示者為佳。 -15- 201224064Further, the methine chromophore is preferably represented by the following formulae (5-1) to (5-3). -15- 201224064

[式（5-1)〜（5·3)之中， R15表示氫原子或齒素原子， R16、R17、R18及R19互相獨立’表示碳數i〜6之烷基’ R20表示經取代或非經取代之碳數1〜6之烷基， G 表示-CH = CH_、_CH = CH-NR21-、_CH = N-NR21_ 或 -N = N-NR _(R 表示鼠原子或碳數1〜6之烧基），[In the formulae (5-1) to (5·3), R15 represents a hydrogen atom or a dentate atom, and R16, R17, R18 and R19 are independent of each other 'is an alkyl group having a carbon number of i to 6'. R20 represents a substituted or Unsubstituted alkyl having 1 to 6 carbon atoms, G representing -CH = CH_, _CH = CH-NR21-, _CH = N-NR21_ or -N = N-NR _ (R represents a rat atom or carbon number 1~ 6 burnt base),

Ra表示經取代或非經取代之芳香族烴基或經取代或非經取代之雜環基。]Ra represents a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted heterocyclic group. ]

Ra係以下述式（5a)〜（5g)所表示之基為佳。The Ra system is preferably a group represented by the following formulas (5a) to (5g).

[式（5a)〜（5g)之中， R22及R29互相獨立’表示碳數1〜6之烧基， R23表示經取代或非經取代之碳數1〜6之烷基， R24、R26、R27及R28互相獨立，表示氫原子、碳數1 〜6之烧基或碳數1〜6之院氧基， -16 - 201224064 R25及R3Q互相獨立，表示氫原子、鹵素原子、碳數1 〜6之烷氧基、經取代或非經取代之碳數1〜6之烷基、硝基、羥基或氰基。] 上述烷基之取代基可列舉||素原子、氰基、羥基等〇上述式（5-1)〜（5-3)所表示之陽離子之代表例可列舉例如下述式所表示之陽離子。[In the formulae (5a) to (5g), R22 and R29 are each independently' represent a carbon group having 1 to 6 carbon atoms, and R23 represents a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, R24, R26, R27 and R28 are independent of each other and represent a hydrogen atom, a carbon number of 1 to 6 or an alkoxy group having a carbon number of 1 to 6, -16 - 201224064 R25 and R3Q are independent of each other, and represent a hydrogen atom, a halogen atom, and a carbon number of 1 to An alkoxy group of 6 or a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a nitro group, a hydroxyl group or a cyano group. Examples of the substituent of the above-mentioned alkyl group include a cation represented by the following formula, and a cation represented by the above formula (5-1) to (5-3). .

偶氮系發色團係以下述式（6-1)〜（6-6)所表示者為佳。 -17- 201224064The azo-based chromophore is preferably represented by the following formulas (6-1) to (6-6). -17- 201224064

N RbN Rb

RbRb

R 38- (6-5)R 38- (6-5)

N==N—Rb [式（6-1)〜（6-6)之中，N==N—Rb [in the formula (6-1) to (6-6),

Rjl、R32、R33、R34、R35及R37互相獨立，表示經取代或非經取代之碳數1〜6之烷基， R36及R4G互相獨立，表示氫原子、鹵素原子、碳數1 〜6之烧基、碳數1〜6之烧氧基、琐基、經基或氰基， R38表示碳數1〜6之烧基， R39表示形成4級銨之基，.Rjl, R32, R33, R34, R35 and R37 are each independently and represent a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, and R36 and R4G are independent of each other, and represent a hydrogen atom, a halogen atom, and a carbon number of 1 to 6. An alkyl group having 1 to 6 carbon atoms, a tribasic group, a thiol group or a cyano group, R38 represents a carbon group having 1 to 6 carbon atoms, and R39 represents a group forming a 4-stage ammonium group.

Rb表示經取代或非經取代之芳香族烴基或經取代或非經取代之雜環基。] 上述 R39係以-NR41CmH2mN+ R42R43R44(m表示 1 〜5 之整數，R41表示氫原子或碳數1〜6之烷基，R42、R43及R44 互相獨立，表示碳數1〜6之烷基）、-COCmH2mN+ R42R43 R44-(m、R42、R43及 R44與前述同義）、-CmH2mN + (NH2)R45 -18 201224064 R (m與前述同義’ r45及r46互相獨立，表示碳數烷基）、或下述式（6_〇或（6_π)所表示之基為佳。一㈣一 coCmH2 6之Rb represents a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted heterocyclic group. The above R39 is -NR41CmH2mN+ R42R43R44 (m represents an integer of 1 to 5, R41 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and R42, R43 and R44 are each independently, and represents an alkyl group having 1 to 6 carbon atoms), -COCmH2mN+ R42R43 R44-(m, R42, R43 and R44 are synonymous with the above), -CmH2mN + (NH2)R45 -18 201224064 R (m is synonymous with the above 'r45 and r46 are independent of each other, meaning a C number alkyl group), or The base represented by the formula (6_〇 or (6_π) is preferred. One (four)-coCmH2 6

(6-i) (6-ii) [式（6·0及（b6-ii)之中，R41及m與前述同義。] 經取代或上述Rb係以下述式（6a)〜（6e)所表示之基非經取代之笨基為佳。(6-i) (6-ii) [In the formulas (6·0 and (b6-ii), R41 and m are synonymous with the above.] Substituted or the above Rb is represented by the following formulas (6a) to (6e) It is preferred that the base is not replaced by a stupid base.

[式（6a)〜（6d)之中 r47表示氫原子、碳數1〜6之烷基、苯基或节基， R表示氫原子、經取代或非經取代之碳數1〜6之烧基、苯基或罕基， R5G表示氫原子、碳數1〜6之烷基或笨基， R51及H52互相獨立，表示氫原子或碳數1〜6之烧基， R49、R53、R54及R55互相獨立，表示氫原子、鹵素原子、碳數1〜6之烷基、碳數1〜6之烷氧基、硝基、羥基或氰基。] -19- 201224064 上述烷基之取代基可列舉鹵素原子、羥基、氰基、 _CONH2基等。上述苯基之取代基可列舉鹵素原子、碳數 1〜6之烧基、碳數1〜6之燒氧基、經基、氰基、确基等〇上述式（6-1)〜（6-6)所表示之陽離子之代表例可列舉例如下述式所表示之陽離子。[In the formulae (6a) to (6d), r47 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a phenyl group or a benzyl group, and R represents a hydrogen atom, a substituted or unsubstituted carbon number of 1 to 6; a group, a phenyl group or a rare group, R5G represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a stupid group, and R51 and H52 are independent of each other, and represent a hydrogen atom or a carbon group having 1 to 6 carbon atoms, R49, R53, R54 and R55 is independent of each other and represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a nitro group, a hydroxyl group or a cyano group. -19-201224064 The substituent of the above alkyl group may, for example, be a halogen atom, a hydroxyl group, a cyano group or a _CONH2 group. Examples of the substituent of the above phenyl group include a halogen atom, a carbon group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a trans group, a cyano group, an exact group, etc., and the above formula (6-1) to (6). -6) Representative examples of the cation represented by the following formula include a cation represented by the following formula.

-20- 201224064-20- 201224064

(H3C)3*NH2CCC {H3C)3+NH2CC〇-^^-f(H3C)3*NH2CCC {H3C)3+NH2CC〇-^^-f

ClCl

y-NHC2H4CNy-NHC2H4CN

/-nhc2h4cn (H3C)3+NHzCCO-^^-N=N- (h3c)3+nh2cc( c2h4cn P2H5 M 'c2h5 p2^5 'c2H4N+(CH3)3/-nhc2h4cn (H3C)3+NHzCCO-^^-N=N- (h3c)3+nh2cc( c2h4cn P2H5 M 'c2h5 p2^5 'c2H4N+(CH3)3

〇2〇2

二芳香基曱烷系發色團係以下述式（7-1)或（7-2)所表示者為佳 R 56 R1 60The diaryl decane chromophore is preferably represented by the following formula (7-1) or (7-2). R 56 R1 60

R59R59

R58 I R61 r62/R58 I R61 r62/

r63 Νί 64 [式（7-1)及（7-2)之中 R56、R57 R58、R59R63 Νί 64 [Formula (7-1) and (7-2) R56, R57 R58, R59

R61、R 62 t> 63 -a 〇 64 RW及互相獨立表示碳數1〜6之烷基 -21 - 201224064 R6Q、R65及R66互相獨立，表示氫原子或碳數1〜6之烷基。] 上述式（7-1)〜（7-2)所表示之陽離子之代表例可列舉例如下述式所表示之陽離子。R61, R 62 t> 63 - a 〇 64 RW and each independently represent an alkyl group having a carbon number of 1 to 6 -21 - 201224064 R6Q, R65 and R66 are each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. Representative examples of the cation represented by the above formulas (7-1) to (7-2) may be exemplified by the cation represented by the following formula.

nh2 醌亞胺系發色團係以下述式（8-1)〜（8-3)所表示者為佳。The nh2 quinone imine chromophore is preferably represented by the following formulas (8-1) to (8-3).

[式（8-1)〜（8-3)之中，[in the formula (8-1) to (8-3),

R67、R68、R69、R70、R71、R 、R8G、R81 ' R82、R83及R84互相獨立，表示氫原子、經取代或非經取代之碳數1〜6之烷基、碳數1〜6之烷氧基、苯基或苄基， R73及R79互相獨立，表示碳數1〜6之烷基或碳數6〜 20之芳香基， R78表示-NR85R86(R85及R86互相獨立，表示經取代或非經取代之碳數1〜6之烷基）、羥基、硝基或氰基， Q表示氧原子或硫原子。] -22- 201224064 氰基等上述烷基之取代基可列舉_素原子、羥基、上述式（8 -1)〜（8 - 3 Ί所皂- 列 )I )所表不之陽離子之代矣& 舉例如下述式所表示之陽離子。 '表例可R67, R68, R69, R70, R71, R, R8G, R81' R82, R83 and R84 are each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, and a carbon number of 1 to 6 Alkoxy, phenyl or benzyl, R73 and R79 are each independently, and represent an alkyl group having 1 to 6 carbon atoms or an aromatic group having 6 to 20 carbon atoms, and R78 represents -NR85R86 (R85 and R86 are independent of each other and represent substituted or An unsubstituted alkyl group having 1 to 6 carbon atoms, a hydroxyl group, a nitro group or a cyano group, and Q represents an oxygen atom or a sulfur atom. -22-201224064 The substituent of the above alkyl group such as a cyano group may, for example, be a cation of a sulfonyl group, a hydroxy group, or a cation represented by the above formula (8-1) to (8 - 3 hydrazine-column) I). & An example is a cation represented by the following formula. 'Table can be

C2H4CNC2H4CN

h3coH3co

ncc2h，'Ncc2h,'

C2H%Xr^：H5 佳蒽l系發色團係以下述式(91)或(9 2)所表示者為C2H%Xr^: H5 Good 蒽l chromophore is represented by the following formula (91) or (9 2)

O NHR92O NHR92

[式（9-1)及（9-2)之中， R87、R92及R93互相獨立，表示氫原子、經取代或非經取代之碳數1〜6之烷基、或經取代或非經取代之苯基、 -23- 201224064 R88及R94互相獨立’表示經取代或非經取代之烷二基， R89、R9G、Rm、Rm、尺”及^?互相獨立，表示碳數 1〜6之院基。] 上述烷基及苯基之取代基可列舉碳數1〜6之烧基、齒素原子、羥基、氰基等。另外，上述烷二基可列舉與前述烷二基同樣者，另外，取代基可列舉羥基、氰基或硝基等。上述式（9-1)或（9-2)所表示之陽離子之代表例可列舉例如下述式所表示之陽離子。[In the formulae (9-1) and (9-2), R87, R92 and R93 are mutually independent, and represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, or a substituted or non-substituted Substituted phenyl, -23- 201224064 R88 and R94 are independent of each other' represents a substituted or unsubstituted alkanediyl group, and R89, R9G, Rm, Rm, 尺" and ^? are independent of each other, and represent a carbon number of 1 to 6. The substituent of the alkyl group and the phenyl group may, for example, be a carbon group having 1 to 6 carbon atoms, a dentate atom, a hydroxyl group or a cyano group. The alkanediyl group may be the same as the alkanediyl group. In addition, examples of the substituent include a hydroxyl group, a cyano group, a nitro group, and the like. Examples of the cation represented by the above formula (9-1) or (9-2) include a cation represented by the following formula.

酞青素系發色團係以下述式（10)所表示者為佳。 CuPC-T (1〇) [式（10)之中，The anthracycline-based chromophore is preferably represented by the following formula (10). CuPC-T (1〇) [in the formula (10),

CuPc表示銅敝青素殘基， T表示下述式（l〇a)或（10b)所表示之基。1 R98 -(cmH2mjN+CmH2mN+R100R101R102)CuPc represents a copper cordatinin residue, and T represents a group represented by the following formula (10a) or (10b). 1 R98 -(cmH2mjN+CmH2mN+R100R101R102)

~(S〇2NHCmH2mN+Rl〇3R1〇4Rl〇5 (10a) d〇b) -24- 201224064 [式（10a)及（10b)之中， R98、R99、Rl〇0、Rl01、Rl02、r103、r1〇4&r105 互相獨立，表示氫原子、碳數1〜6之烧基或笨基， p互相獨立，表示2〜8之整數， m與前述同義。] 上述式（1 0)所表示之陽離子之代表例可列舉例如下~(S〇2NHCmH2mN+Rl〇3R1〇4Rl〇5 (10a) d〇b) -24- 201224064 [In the formulas (10a) and (10b), R98, R99, Rl〇0, Rl01, Rl02, r103, R1〇4&r105 are independent of each other and represent a hydrogen atom, a carbon number of 1 to 6 or a stupid group, p is independent of each other, and represents an integer of 2 to 8, and m is synonymous with the foregoing. Representative examples of the cation represented by the above formula (10) include, for example,

CuPC-["S02NH+C3H6N+(CH3}3 jp，P，C1· p'=2-3 述式所表示之陽離子。〇h3 CuPC-{ CH2N+C3H6N+(CH3)3 ] 2 2C1-ch3 。山唱系發色團係以下述式（11)所表示者為佳。'CuPC-["S02NH+C3H6N+(CH3}3 jp,P,C1·p'=2-3 The cation represented by the above formula. 〇h3 CuPC-{ CH2N+C3H6N+(CH3)3 ] 2 2C1-ch3. It is preferable that the chorus chromophore is represented by the following formula (11).

R106、R1G7 '汉1()8及r1Q9互相獨立表示氫原子、rU3 [式（11)之中，R106, R1G7 'Han 1 () 8 and r1Q9 independently of each other represent a hydrogen atom, rU3 [in the formula (11),

或碳數6〜10之芳香族烴基。但是該芳香族烴基所含的氫原子可經 il 素原子、-R113、_0R113、_sc>3h、_S〇3M 、-C02H、-C〇2R"3、_s〇3R113、_s〇2NHr114 或 -so2nr114r115取代。 R 及R 互相獨立，表示氫原子或碳數丨〜8之烷基 -25- 201224064 R 表示-S〇3h、-S03M、-C02H、-c〇2r113、.s〇3R113 、-S02NHR114 或 _S〇2NRii4Rll5。 r表不〇〜5之整數，在1>為2以上的整數的情況，複數個R112可相同或相異。Or an aromatic hydrocarbon group having 6 to 10 carbon atoms. However, the hydrogen atom contained in the aromatic hydrocarbon group may be replaced by an il atom, -R113,_0R113, _sc>3h, _S〇3M, -C02H, -C〇2R"3, _s〇3R113, _s〇2NHr114 or -so2nr114r115. . R and R are independent of each other and represent a hydrogen atom or an alkyl group having a carbon number of 丨~8-25- 201224064 R represents -S〇3h, -S03M, -C02H, -c〇2r113, .s〇3R113, -S02NHR114 or _S 〇 2NRii4Rll5. The r table is not an integer of ～5. When 1> is an integer of 2 or more, the plurality of R112s may be the same or different.

Rl13表示碳數1〜10之飽和烴基。但是該飽和烴基所含的氫原子可經齒素原子取代，另外飽和烴基所含的亞甲基可經氧原子、羰基取代。 R及R 互相獨立’表示碳數1〜1〇之鏈狀烧基、碳數3〜30之環烷基或_z、或表示Ru4及Rl B互相鍵結形成的呶數1〜1〇之雜環基。但是該烷基及環烷基所含的氫原子可經羥基、鹵素原子、_Z、-CH = CH^ _CH = CHRl 13 取代，另外，該烷基及環烷基所含的亞曱基可經氧原子、羰基或-NR113-取代，該雜環基所含的氫原子可經_Rll3 、-OH或-Z取代。 Μ表示鈉原子或卸原子。 Ζ表示碳數6〜10之芳香族烴基或碳數5〜1〇之芳香族雜環基。但是該芳香族烴基及芳香族雜環基所含的氫或鹵素原子取代，。] R113中的飽和烴基只要碳數為i〜10，則為直鏈狀、支鏈狀及環狀任一皆可，亦可具有架橋構造。具體而言除了可列舉與上述式（2)中的R3同樣的烷基，其他還有壬基力基、J衣戊基、J衣己基環庚基、環辛基、三環癸基。飽和烴基所含的亞甲基經氧原子取代之基可列舉例如R13 represents a saturated hydrocarbon group having 1 to 10 carbon atoms. However, the hydrogen atom contained in the saturated hydrocarbon group may be substituted by a fang atom, and the methylene group contained in the saturated hydrocarbon group may be substituted with an oxygen atom or a carbonyl group. R and R are independent of each other', and represent a chain-like alkyl group having a carbon number of 1 to 1 Å, a cycloalkyl group having 3 to 30 carbon atoms or _z, or a number of turns of 1 to 1 formed by bonding of Ru4 and R1B to each other. Heterocyclic group. However, the hydrogen atom contained in the alkyl group and the cycloalkyl group may be substituted by a hydroxyl group, a halogen atom, _Z, -CH=CH^_CH=CHRl 13 , and the alkylene group contained in the alkyl group and the cycloalkyl group may be An oxygen atom, a carbonyl group or a -NR113--substituted hydrogen atom contained in the heterocyclic group may be substituted by _Rll3, -OH or -Z. Μ denotes a sodium atom or an unloading atom. Ζ represents an aromatic hydrocarbon group having 6 to 10 carbon atoms or an aromatic heterocyclic group having 5 to 1 carbon atoms. However, the aromatic hydrocarbon group and the aromatic heterocyclic group are replaced by hydrogen or a halogen atom. The saturated hydrocarbon group in R113 may be any of a linear chain, a branched chain, and a ring, as long as the carbon number is i10, and may have a bridging structure. Specifically, the alkyl group similar to R3 in the above formula (2) may be mentioned, and other examples include a mercapto group, a J-pentyl group, a J-hexylcycloheptyl group, a cyclooctyl group, and a tricyclodecyl group. The group in which the methylene group contained in the saturated hydrocarbon group is substituted with an oxygen atom can be enumerated, for example.

曱氧基丙基、乙氧基丙基、2-乙基已氧基丙基、甲氧基己基等。 A -26- 201224064 R114及R115互相鍵結而形成的碳數ι〜狀列舉與前述特性基叫中的雜環基同樣者，另外;；： :數5〜1〇之方香族雜環基可列舉吱喃基、售吩基、。比咬 :、…、十坐基、異十坐基、，哇基、異嗟唾基、咪唑基、吡唑基、嘧咬基等。Alkoxypropyl, ethoxypropyl, 2-ethylhexyloxypropyl, methoxyhexyl and the like. A -26- 201224064 The number of carbon atoms formed by bonding R114 and R115 to each other is the same as the heterocyclic group in the above-mentioned characteristic group, and;;: : 5 to 1 方 square aromatic heterocyclic group Examples thereof include a fluorenyl group and a phenyl group. Than bite :, ..., ten sitting base, different ten sitting base, wow base, isoindolyl, imidazolyl, pyrazolyl, pyrimidine base and so on.

Rl〇6、r107、r108 及Z中的方香族烴基如苯基、萘基等。例、r1〇7、r1()8 K及R中的-S〇3R113可列舉曱烧料基、乙mu基、己料喊、癸μ醯基等。另外，-C02R"3可列舉曱氧基羰基、乙氧基羰基、丙氧基羰基、異丙氧基羰基'丁氧基羰基、環己氧基羰基、曱氧基丙氧基羰基等。再者，_s〇2NHr114、_s〇2Nr114r115 中的R 、Rl15係以碳數6〜8之支鏈狀烷基、碳數5〜7 之脂裱式烴基、烯丙基、碳數8〜1〇之芳烷基、碳數2〜8 之含羥基的烷基、碳數2〜8之含烷氧基的烷基、芳香基為佳。式（Π)所表示之陽離子之具體例可列舉下述式所表示之陽離子。 -27- 201224064The sulphuric hydrocarbon group in Rl 〇 6, r107, r108 and Z is a phenyl group, a naphthyl group or the like. Examples, r1〇7, r1()8 K and -S〇3R113 in R may be exemplified by a crucible base, an ethyl group, a compound, a 癸μ醯 group or the like. Further, -C02R"3 may, for example, be an oxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, an isopropoxycarbonyl 'butoxycarbonyl group, a cyclohexyloxycarbonyl group or a nonoxyloxycarbonyl group. Further, R and Rl15 in _s〇2NHr114 and _s〇2Nr114r115 are a branched alkyl group having 6 to 8 carbon atoms, a lipid sulfonyl group having 5 to 7 carbon atoms, an allyl group, and a carbon number of 8 to 1 Å. The aralkyl group, the hydroxyl group-containing alkyl group having 2 to 8 carbon atoms, the alkoxy group-containing alkyl group having 2 to 8 carbon atoms, and the aromatic group are preferred. Specific examples of the cation represented by the formula (?) include a cation represented by the following formula. -27- 201224064

so2nhrcSo2nhrc

Rc=2-ethylhexyl rchno2sRc=2-ethylhexyl rchno2s

so2nhrc so2nhrSo2nhrc so2nhr

其他陽離子性發色團可列舉例如下述式所表示之陽離子Examples of the other cationic chromophore include cations represented by the following formulas.

l-C3H6N+(CH3)3l-C3H6N+(CH3)3

本著色劑可藉由周知的方法製造，而可列舉例如與曰本特開2003-20641 5號公報或日本特表2〇〇7_5〇3477號 -28- 201224064 公報的實施例同樣的方法劑可溶於以乳酸乙0旨為為二以這種方式所得到的本著色有優異的耐熱性。的各種有機溶劑，另外還具著色組成物以下針對本發明之著 -(A)著色劑_ 色組成物之構成成分作說明。本發明之著色組成物人〇太益A h 3有本者色劑作為（A)著色劑。本者色劑可單獨使用或 ^ ^ ^ * x 了合2種以上使用。右使本者色劑溶於有莊i留相^ /± ’機溶劑’則呈藍至紅色，因此The coloring agent can be produced by a known method, and for example, the same method as that of the embodiment of the Japanese Patent Publication No. 2003-20641 5 or the Japanese Patent Laid-Open Publication No. Hei. No. Hei. The present coloring obtained by dissolving in the form of lactic acid B in this manner has excellent heat resistance. Various organic solvents, and a coloring composition are also described below. The constituents of the coloring agent-color composition of the present invention will be described. The coloring composition of the present invention, 〇太益 A h 3 , has a coloring agent as the (A) coloring agent. The toner can be used alone or in combination of ^ ^ ^ * x or more. The right toner is dissolved in the Zhuang i phase, ^ / ± 'machine solvent' is blue to red, so

糟由早獨使用本著色劑或 # U P ― 其他著色劑適當地混合使用，即可適用於例如用以形 ^ β 成1色畫素、紅色畫素、零、色者色層的著色組成物。 …本著色劑以外之著色劑可因應用途而適當地選擇色 ’或材質I體而5，顏料、染料及天然色素任一者皆可使用作為本著色劑以外之著色劑，而從構成彩色渡光片的著色層需要高色純度、輝度、對比、遮光性等的觀點看來’以使用顏料及/或染料為佳。上述顏料為有機顏料及無機顏料之任一皆可，有機顏料可列舉例如顏色索引（c J ; The s〇ciety of DyersandIt is suitable to use the coloring agent or #UP--other coloring agents as appropriate, and it can be applied to, for example, a coloring composition for forming a color pixel, a red pixel, a zero color, and a color layer. . The coloring agent other than the coloring agent can be appropriately selected depending on the application, or the material I can be used. 5, any of the pigment, the dye, and the natural coloring matter can be used as a coloring agent other than the coloring agent. The coloring layer of the light sheet needs high color purity, brightness, contrast, light blocking, etc., and it is preferable to use a pigment and/or a dye. The above pigments may be any of an organic pigment and an inorganic pigment, and examples of the organic pigment include a color index (c J ; The s〇ciety of Dyersand)

Colourists公司發行）之中’分類於色素的化合物。具體而言可列舉如下述般以顏色索引（C I )名稱來記載之物。 C.I. Pigment Yellow 12、C.I. Pigment Yellow 13、C.I. Pigment Yellow 14、C.I. Pigment Yellow 17、C.I. PigmentAmong the pigmentists, the compound classified as a pigment. Specifically, the article described by the color index (C I ) name as described below can be cited. C.I. Pigment Yellow 12, C.I. Pigment Yellow 13, C.I. Pigment Yellow 14, C.I. Pigment Yellow 17, C.I. Pigment

Yellow 20 ' C.I. Pigment Yellow 24 ' C.I. Pigment Yellow 31、C.I· Pigment Yellow 55、C.I. Pigment Yellow 83、 -29- 201224064 C.I. Pigment Yellow 93、C.I. Pigment Yellow 109、C.I. Pigment Yellow 110、C.I. Pigment Yellow 138、C.I.Yellow 20 ' C.I. Pigment Yellow 24 ' C.I. Pigment Yellow 55, C.I. Pigment Yellow 55, C.I. Pigment Yellow 83, -29- 201224064 C.I. Pigment Yellow 93, C.I. Pigment Yellow 109, C.I. Pigment Yellow 110, C.I. Pigment Yellow 138, C.I.

Pigment Yellow 139、C.I. Pigment Yellow 150、C.I.Pigment Yellow 139, C.I. Pigment Yellow 150, C.I.

Pigment Yellow 153、C.I. Pigment Yellow 154、C.I.Pigment Yellow 153, C.I. Pigment Yellow 154, C.I.

Pigment Yellow 155 ' C.I. Pigment Yellow 166 ' C.I.Pigment Yellow 155 ' C.I. Pigment Yellow 166 ' C.I.

Pigment Yellow 168、C.I· Pigment Yellow 180、C.I.Pigment Yellow 168, C.I· Pigment Yellow 180, C.I.

Pigment Yellow 211 ; C.I. Pigment Orange 5 ' C.I. Pigment Orange 13 ' C.I. Pigment Orange 14、C.I. Pigment Orange 24、C.I. Pigment Orange 34、C.I. Pigment Orange 36、C.I· Pigment Orange 38、C.I. Pigment Orange 40、C.I. Pigment Orange 43、 C.I. Pigment Orange 46、C.I. Pigment Orange 49、C.I_ Pigment Orange 61、C.I. Pigment Orange 64、C.I. Pigment Orange 68 ' C.I. Pigment Orange 70 ' C.I. Pigment Orange 71、C.I. Pigment Orange 72、C.I· Pigment Orange 73、 C.I. Pigment Orange 74 ; C.I. Pigment Red 1 ' C.I. Pigment Red 2' C.I. Pigment Red 5、C.I· Pigment Red 17、C.I· Pigment Red 31、C.I· Pigment Red 32 ' C.I. Pigment Red 41 ' C.I. Pigment Red 122 ' C.I. Pigment Red 123、C.I· Pigment Red 144、C.I. Pigment Red 149 ' C.I. Pigment Red 166 ' C.I. Pigment Red 168 ' C.I. Pigment Red 170、C.I. Pigment Red 171、C.I· Pigment Red 175 ' C.I. Pigment Red 176 ' C.I. Pigment Red 177 ' C.I. Pigment Red 178' C.I. Pigment Red 179' C.I. Pigment Red 180、C.I. Pigment Red 185、C.I. Pigment Red 187、0-1- •30- 201224064Pigment Yellow 211 ; CI Pigment Orange 5 ' CI Pigment Orange 13 ' CI Pigment Orange 14, CI Pigment Orange 24, CI Pigment Orange 34, CI Pigment Orange 36, CI Pigment Orange 38, CI Pigment Orange 40, CI Pigment Orange 43, CI Pigment Orange 46, CI Pigment Orange 49, C.I_ Pigment Orange 61, CI Pigment Orange 64, CI Pigment Orange 68 'CI Pigment Orange 70 ' CI Pigment Orange 71, CI Pigment Orange 72, CI· Pigment Orange 73, CI Pigment CI Pigment Red 1 ' CI Pigment Red 2' CI Pigment Red 5, CI· Pigment Red 17, CI· Pigment Red 31, CI· Pigment Red 32 ' CI Pigment Red 41 ' CI Pigment Red 122 ' CI Pigment Red 123 CI Pigment Red 144 'CI Pigment Red 166 ' CI Pigment Red 168 ' CI Pigment Red 170, CI Pigment Red 171, CI· Pigment Red 175 ' CI Pigment Red 176 ' CI Pigment Red 177 ' CI Pigment Red 178' CI Pigment Red 179' CI Pigment Red 180, CI Pigment Red 185, CI Pigment Red 187, 0-1-- 30-201224064

Pigment Red 202' C.I. Pigment Red 206' C.I. Pigment Red 207 ' C.I. Pigment Red 209 ' C.I. Pigment Red 214 > C.I. Pigment Red 220' C.I. Pigment Red 221' C.I. Pigment Red 224 ' C.I. Pigment Red 242 ' C.I. Pigment Red 243 ' C.I. Pigment Red 254' C.I. Pigment Red 255 ' C.I. Pigment Red 262、C.I. Pigment Red 264 ' C.I. Pigment Red 272 ; C.I. Pigment Violet 1 ' C.I. Pigment Violet 19 ' C.I. Pigment Violet 23、C.I. Pigment Violet 29、C.I· Pigment Violet 32' C.I. Pigment Violet 36' C.I. Pigment Violet 38 C.I· Pigment Blue 1、C.I. Pigment Blue 15、C.I. Pigment Blue 15 : 3、C.I. Pigment Blue 15 : 4、C.I. Pigment Blue 15 : 6、C.I· Pigment Blue 60、C.I· Pigment Blue 80 ; C.I. Pigment Green 7、C.I. Pigment Green 36、C,I.Pigment Red 202' CI Pigment Red 206' CI Pigment Red 207 ' CI Pigment Red 209 ' CI Pigment Red 214 > CI Pigment Red 220' CI Pigment Red 221' CI Pigment Red 224 ' CI Pigment Red 242 ' CI Pigment Red 243 ' CI Pigment Red 254 ' CI Pigment Red 255 ' CI Pigment Red 262, CI Pigment Red 264 ' CI Pigment Red 272 ; CI Pigment Violet 1 ' CI Pigment Violet 19 ' CI Pigment Violet 23, CI Pigment Violet 29, CI · Pigment Violet 32 ' CI Pigment Violet 36' CI Pigment Violet 38 CI· Pigment Blue 1, CI Pigment Blue 15, CI Pigment Blue 15 : 3, CI Pigment Blue 15 : 4, CI Pigment Blue 15 : 6, CI· Pigment Blue 60, CI· Pigment Blue 80 ; CI Pigment Green 7, CI Pigment Green 36, C, I.

Pigment Green 58 ； C.I. Pigment Brown 23、C.I. Pigment Brown 25 ; C_I. Pigment Black 1、C.I. Pigment Black 7。另外’上述無機顏料可列舉例如氧化鈦、硫酸鋇、破酸約、辞華、硫酸錯、黃色錯、鋅黃、鐵红（红色氧化鐵（111 ))、鎘紅、群青、紺青、氧化鉻綠、鈷綠、棕土、鈦黑、合成鐵黑、碳黑等。在本發明之中’亦可將顏料藉由再結晶法、再沉爽法、溶劑洗淨法、昇華法、真空加熱法或該等的組合而精製然後使用。另外，顏料亦可依照需要，以樹脂對於其粒子表面進行改質然後使用。對顏料的粒子表面進行 -31 - 201224064 改質的樹脂可列舉例如日本特開200 1 - 1088 1 7號公報所記載之展色劑（Vehicle)樹脂、或市售的各種顏料分散用的樹脂。碳黑表面的樹脂被覆方法，可採用例如日本特開平9-7 1733號公報、日本特開平9-95625號公報、日本特開平9-1 24969號公報等所記載之方法。另外，有機顏料係以藉由所謂的鹽磨處理（s a 11 m i 11 i n g)使初級粒子微細化而使用為佳。鹽磨的方法可採用例如日本特開平 08-1 79 1 1 1號公報所揭示的方法。另外，上述染料可由各種油溶性染料、直接染料、酸性染料、金屬錯合物染料等的中適當地選擇，可列舉例如下述般以顏色索引（C.I.)名稱來記載之物。 C.I. Solvent Yellow 4 ' C.I. Solvent Yellow 14 ' C.I. Solvent Yellow 1 5、C.I. Solvent Yellow 24 ' C.I. Solvent Yellow 82、C.I· Solvent Yellow 88、C.I. Solvent Yellow 94、C.I. Solvent Yellow 9 8、C.I. Sol vent Yellow 162、 C.I. Solvent Yellow 179 ； C.I· Solvent Red 45、C.I. Solvent Red 49 ; C.I. Solvent Orange 2、C.I. Solvent Orange 7、C.I. Solvent Orange 1 1、C.I. Solvent Orange 1 5、C.I. Solvent Orange 26、C.I. Solvent Orange 56 ; C.I. Solvent Blue 35、C.I. Solvent Blue 37、C.I. Solvent Blue 59 ' C.I. Solvent Blue 67 ； C.I. Acid Yellow 17、C.I. Acid Yellow 29、C.I. AcidPigment Green 58; C.I. Pigment Brown 23, C.I. Pigment Brown 25; C_I. Pigment Black 1, C.I. Pigment Black 7. Further, the above inorganic pigment may, for example, be titanium oxide, barium sulfate, acid-cracking, rhodium, sulfuric acid, yellow, zinc yellow, iron red (red iron oxide (111)), cadmium red, ultramarine blue, indigo, chromium oxide. Green, cobalt green, brown earth, titanium black, synthetic iron black, carbon black, etc. In the present invention, the pigment may be purified by a recrystallization method, a re-sinking method, a solvent washing method, a sublimation method, a vacuum heating method, or the like, and then used. Further, the pigment may be modified with a resin for its particle surface as needed and then used. The surface of the particle of the pigment is -31 - 201224064. For the resin to be modified, for example, a vehicle resin described in JP-A No. 200 1 - 1088 1 7 or a commercially available resin for dispersing various pigments. For the method of coating the surface of the carbon black, for example, the method described in JP-A-9-7 1733, JP-A-9-95625, and JP-A-9-1 24969. Further, the organic pigment is preferably used by refining the primary particles by a so-called salt milling treatment (s a 11 m i 11 i n g). The method of salt milling can be carried out, for example, by the method disclosed in Japanese Laid-Open Patent Publication No. 08-1 79 1 1 1 . In addition, the dye may be appropriately selected from various oil-soluble dyes, direct dyes, acid dyes, metal complex dyes, and the like, and examples thereof include those described by the color index (C.I.). CI Solvent Yellow 4 ' CI Solvent Yellow 14 ' CI Solvent Yellow 1 5, CI Solvent Yellow 24 ' CI Solvent Yellow 82, CI · Solvent Yellow 88, CI Solvent Yellow 94, CI Solvent Yellow 9 8, CI Sol vent Yellow 162, CI Solvent Yellow 179 ; CI Solvent Red 45, CI Solvent Red 49 ; CI Solvent Orange 2, CI Solvent Orange 7, CI Solvent Orange 1 1, CI Solvent Orange 1 5, CI Solvent Orange 26, CI Solvent Orange 56 ; CI Solvent Blue 35, CI Solvent Blue 37, CI Solvent Blue 59 ' CI Solvent Blue 67 ; CI Acid Yellow 17, CI Acid Yellow 29, CI Acid

Yellow 40 ' C.I. Acid Yellow 76 ； C.I· Acid Red 91、C.I. Acid Red 92、C.I. Acid Red 97、 -32- 201224064 C.I. Acid Red 1 14、C.I. Acid Red 13 8、C.I_ Acid Red 151 C.I· Acid Orange 51、C.I· Acid Orange 63 ; C.I· Acid Blue 80、C.I. Acid Blue 83、C.I· Acid Blue 90 C.I. Acid Green 9、C.I. Acid Green 16、C.I. Acid Green 25、C.I. Acid Green 27。在本發明之中，其他著色劑可單獨使用或可混合2 種以上使用。從形成輝度高且色純度優異的晝素、或遮光性優異的黑色矩陣的觀點看來，（A)著色劑的含有比例通常在著色組成物的固體含量中占5〜70質量％，宜為5〜60質量％。此處所謂的固體含量是指後述溶劑以外之成分。在本發明之中使用顏料作為其他著色劑的情況下，可依照需要與分散劑、分散助劑一起使用。上述分散劑可使用例如陽離子系、陰離子系、非離子系等適當的分散劑’而以聚合物分散劑為佳。具體而言可列舉胺曱酸乙醋系分散劑、聚乙烯亞胺系分散劑、聚氧乙烯烷醚系分散劑、聚氧乙烯烷基苯醚系分散劑、聚乙二醇二酯系分散劑、去水山梨醇脂肪酸酯系分散劑、聚酯系分散劑、丙烯酸系分散劑等。這樣的分散劑能夠以商業方式取得，例如丙烯酸系分散劑可列舉 Disperbyk-2000、Disperbyk-200 1、 BYK-LPN6919、BYK-LPN21116、BYK-LPN21 324(以上為Byk-Chemie(BYK)公司製）等；胺甲酸乙酯系分散劑可 -33- 201224064 列舉 Disperbyk-161 、 Disperbyk-162 、 Disperbyk-165 、 Disperbyk-167 、 Disperbyk-170 、 Disperbyk-182(以上， Byk-Chemie(BYK)公司製）、Solsperse 76500(Lubrizol股份有限公司製）等；聚乙烯亞胺系分散劑可列舉Solsperse 24000(Lubrizol股份有限公司製）等；聚酯系分散劑可列舉 Ajisper PB821、Ajisper PB822、Ajisper PB880、Ajisper PB881(味之素FINE TECHNO股份有限公司製）等。另外’上述分散助劑可列舉例如顏料衍生物，具體而s可列舉銅耿青素、二酮基D比洛并D比咯、啥醜綱的續酸衍生物等。此外，分散劑及分散助劑的含量可在不妨礙本發明目的之範圍内適當地決定。 -(B)黏結劑樹脂- 本發明之著色組成物中的黏結劑樹脂並未受到特別限定，而以具有羧基、酚性羥基等的酸性官能基的樹脂為佳。其中以具有羧基的聚合物（以下稱為「含羧基的聚合物」）為佳’可列舉例如具有丨個以上羧基的乙烯性不飽和單體（以下稱為「不飽和單體（bl)」）與其他可共聚合的乙烯性不飽和單體（以下稱為「不飽和單體（b2)」）之共聚物。 ^ 上述不飽和單體（bl)可列舉例如（甲基）丙烯酸、馬來酸、馬來酸酐、琥珀酸單[2_(甲基）丙烯醯氧基乙酯]、0 -羧基聚己内酯單（甲基）丙稀酸酯、對乙烯基安息香酸等〇該等不飽和單體（bl)可單獨使用或混合2種以上使 -34- 201224064 1外，上述不飽和單體（b2)可列舉例如N_苯基馬來丄亞胺+ N-%己基馬來醯亞胺般經位取代的馬來醯亞月女’如苯^烯、α _曱基苯乙稀、對經基苯乙稀、對經基 ^曱基苯乙烯、對乙烯基节基縮水甘油醚、苊烯般的务香族乙稀基化合物； >(曱基）丙烯酸甲醋、（甲基）丙烯酸正丁醋、（甲基）丙烯酉欠^乙基己酯、（曱基）丙烯酸2_羥乙酯、（甲基）丙烯酸烯丙鼬、（曱基）丙烯酸苄酯、聚乙二醇（聚合度2〜1〇)曱醚（ :基）丙烯酸酯、聚丙二醇（聚合度2〜1〇)曱醚（曱基）丙烯酸酯、聚乙二醇（聚合度2〜1〇)單（甲基）丙烯酸酯、聚丙二=(聚合度2〜10)單（甲基）丙烯酸酯、（甲基）丙烯酸環己酯、（甲基）.丙烯酸異莰酯、三環[5 2丨〇2.6]癸_8_基（甲基）丙烯酸酯、二環戊烯基（曱基）丙烯酸酯、甘油單（甲基 )丙烯酸酯、（甲基）丙烯酸4_羥苯酯、對異丙基苯酚之環氧乙烷變性（甲基）丙烯酸酯、（甲基）丙烯酸縮水甘油酯、 (甲基）丙烯酸3,4·環氧環己基曱酯、3_[(甲基）丙烯醯氧基甲基]氧雜環丁烧、3-[(曱基）丙浠醯氧基曱基]_3_乙基氧雜環丁烷般的（甲基）丙烯酸酯；如環己基乙烯基_1、異获基乙稀基趟、三環[5.2 1 〇2.6] 癸-8-基乙烯基趟、五環十五烧基乙稀基趟、(乙稀氧某甲基）-3-乙基氧雜環丁烷般的乙烯基醚；如聚苯乙歸、聚 (甲基）丙烯酸甲酯、聚（曱基）丙烯酸正丁酯、聚石夕氧烧般在聚合物分子鍵的末端具有卓（曱基）丙稀酿基的巨單體等。該等的不飽和單體（b2)可單獨使用或可混合2種以上使用。 -35- 201224064 在不飽和單體（bl)與不飽和單體（b2)的共聚物之中，該共聚物中的不飽和單體（bl)之共聚合比例宜為5〜70 質量％、更佳為1 0〜60質量。藉由在這樣的範圍内使不飽和單體（b 1)共聚合’可得到鹼顯像性及保存安定性優異的著色組成物。不飽和單體（bl)與不飽和單體（b2)之共聚物之具體例，可列舉例如日本特開平7_14〇654號公報、日本特開平8-259876號公報、日本特開平1〇_313〇8號公報、曰本特開平10-300922號公報、日本特開平n_174224號公報、曰本特開平1 1-25841 5號公報、日本特開2000-561 1 8號公報、日本特開2002-296778號公報、日本特開 2004-101728號公報等所揭示的共聚物。另外’在本發明之中亦可使用例如曰本特開平 5-1 9467號公報、曰本特開平6_23〇212號公報、日本特開平7-207211唬公報、日本特開平〇9_325494號公報、曰本特開平1 1-140144號公報、日本特開2〇〇8_181〇95號公報等所揭示般的在側鏈具有（甲基）丙烯醯基等聚合性不飽和鍵之含羧基的聚合物作為黏結劑樹脂。本發明中之黏結劑樹脂以Gpc(溶出溶劑：四氫呋喃 )測得的聚苯乙烯換算之重量平均分子量（Mw)通常為 1，000〜100，刪，宜為3,〇〇〇〜5()，()()(）。若]^過小則會有所得到的被膜之殘膜率等降低、損及圖案形狀、耐熱性等、以及電氣特性惡化的顧慮’另一方面，若為過大，則會有解像度降低、損及圖案形狀、以及在藉由狹縫喷嘴的方式it行塗布㈣易產生乾燥異㈣顧慮。 •36- 201224064 另外，本發明中之黏結劑樹脂之重量平均分子量與以GPC(溶出溶劑：四氫呋喃）測得的聚笨乙浠換算之數量平均分子量（Μη)之比（Mw/Mn)宜為1_〇〜5·〇，較佳為1〇〜3 · 0 〇本發明中之黏結劑樹脂可藉由周知方法製造，而亦可藉由例如日本特開2003-2227 17號公報、日本特開 2006-259680號公報、國際公開第07/02987 1號小冊子等所揭示的方法’控制其構造或Mw、Mw/Mn。在本發明之中，黏結劑樹脂可單獨使用或混合2種以上使用。在本發明之中，黏結劑樹脂的含量相對於（A)著色劑 100質量份而言’通常為10〜1，000質量份，宜為2〇〜5〇〇質量份。若黏結劑樹脂的含量太少則會有例如鹼顯像性降低、所得到的著色組成物之保存安定性降低的顧慮，另一方面，若太多則相對而言著色劑濃度降低，因此會有難以達成以作為薄膜為目的之色濃度的顧慮。 -(C)交聯劑- 在本發明之中（C)交聯劑是指具有2個以上可聚合之基的化合物。可聚合之基可列舉例如乙烯性不飽和基、環氧乙烧基、氧雜環丁減、N_烧氧基甲基胺基等。在本發明之中，(C)交聯劑係以具有2個以上的（甲基)丙烯醯基的化合物或具有2個以上的比烷氧基甲基胺基的化合物為佳’尤其以將具有2個以上的(甲基)丙烯醯基的化合物與具有2個以上的N_按童其曰]JN況乳暴甲基胺基的化合物組合使用為佳。 -37- 201224064 上述具有2個以上的（曱基）丙烯醯基的化合物之具體例，可列舉使脂肪族多羥基化合物與（甲基）丙烯醆反應所得到的多官能（曱基）丙烯酸酯、經己内酯變性的多官能（甲基）丙烯酸酯、經環氧烷變性的多官能（甲基）丙稀酸醋、使具有羥基的（甲基）丙烯酸酯與多官能異氰酸酯反應所得到的多官能胺甲酸乙酯（甲基）丙烯酸酯 '使具有經基的（甲基）丙烯酸酯與酸酐反應所得到的具有鲮基的多官能（曱基）丙烯酸酯等。在此處，上述脂肪族多羥基化合物可列舉例如乙二醇、丙二醇、聚乙二醇、聚丙二醇般的2價脂肪族多羥基化合物，如甘油、二經曱基丙烧、新戊四醇、二新戊四醇般的3價以上的脂肪族多羥基化合物。上述具有羥基的 (甲基）丙稀酸酯可列舉例如（曱基）丙烯酸2_羥乙酯、三羥甲基丙烷二（甲基）丙烯酸酯、新戊四醇三（曱基）丙烯酸酯、二新戍四醇五（曱基）丙烯酸酯、甘油二甲基丙烯酸酯等。上述多官能異氰酸酯可列舉例如甲苯二異氰酸酯、 /、亞甲基二異氰酸酯、二苯亞甲基二異氰酸酯、異佛酮二異氰酸酯等。酸酐可列舉例如琥珀酸酐、馬來酸酐、戊二酸酐、伊康酸酐、苯二甲酸酐、六氫苯二曱酸酐般的二元酸酐、如焦蜜石酸酐、聯苯四羧酸二酐、二苯酮四缓酸二針般的四元酸二肝。另外，上述經己内醋變性的多官能（甲基）丙烯酸酯可列舉例如日本特開平n_44955號公報的第[〇〇15]〜 [0018]段落所記載的化合物。上述經環氧燒變性的多官能（曱基）丙烯酸酷可列舉雙酚A之環氧乙烷及/或環氧丙 -38- .201224064 烧變性二（甲其_、π & _ @ 、T暴）丙烯酸S曰、異氰尿酸之環氧乙烷及/或严氧丙烧變性；r f田#、Λ m ^ —(甲基）丙烯酸酯、三羥曱基丙烷之環氧乙烷及/或環氧丙烷變性三（曱基）丙烯酸酯、新戊四醇之環氧2烷及/或環氧丙烷變性三（曱基）丙烯酸酯、新戊四醇之衣氧乙烷及/或環氧丙烷變性四（曱基）丙烯酸酯、二靳戊四醇之％氧乙烷及/或環氧丙烷變性五（甲基）丙烯酸酯一新戊四醇之環氧乙烷及/或環氧丙烷變性六（曱基烯酸酯等。 π 另外，上述具有2個以上的Ν烷氧基曱基胺基的化入物可列舉例如具有三聚氰胺構造、苯并胍胺構造、尿；構1的化合物等。此外’三聚氰胺構造、苯并胍胺構造心八有1個以上的三听環或經苯基取代的三哜環作為基本：木的化學構造，概念也包括三聚氰胺、苯并胍胺或X等的縮。物。具有2個以上的Ν_烧氧基甲基胺基的化合物之具體例可列舉Ν，Ν，Ν’，Ν，，Ν，，，Ν.._六（炫氧基甲基）二聚氰胺、Ν，Ν，Ν，，ν，_四（烧氧基曱基）苯并脈胺、 ν，ν，Ν·，ν=四（燒氧基甲基）甘脲等。在 < 等的夕g能性單體之中，使3價以上的脂肪族多經基化合物與（甲萁、=& & 土）丙’烯酸反應所得到的多官能（曱基） ::s: S曰、經己内酯變性的多官能(甲基)丙烯酸酯、多吕倉b胺甲酸乙酉旨（甲其、 (曱基烯曰、具有羧基的多官能（甲基=稀=、N，Nf 以 Μ Μ Μ ，，，四（烷氧基甲基）苯并胍胺為佳。在著色 > 的強度高、著色層表面平滑性優異，且在未曝== 上及遮光層上難以發生材質污損、殘膜== -39- 201224064 價以上的脂肪族多羥基化合物與（曱基）丙烯酸反應所得到的多官能（曱基）丙婦酸醋之中’以三羥曱基丙烧三丙烯酸酯、新戊四醇三丙烯酸醋、二新戊四醇五丙烯酸酯、二新戊四醇六丙烯酸醋為特佳；而在具有羧基的多官能（甲基）丙稀酸醋之中’以使新戊四醇三丙烯酸酿與號 ί白酸針反應所得到的化合物 '使二新戊四醇五丙稀酸酯與琥珀酸酐反應所得到的化合物為特佳。在本發明之中，（C)交聯劑可單獨使用或混合2種以上使用。本發明中之（C)交聯劑的冬旦Λ ,, ;P Μ的3量相對於（A)著色劑1〇〇質量份而言，以⑺〜^⑼質量份為佳以2〇〜5〇〇質量份為特佳。此情況下，若多官能性單體的含量太少，則會有無法得到充足硬化性的从夕— J顆愿另一方面，右多官能性單體的含量太多，則在斟於士政。 + J在對於本發明之著色組成物賦予鹼顯像性的情況下，會右趴 s有驗顯像性降低、在未曝光部之基板上或遮光層上容易路4从 _ 约發生材質3損、殘膜等的傾向。 -(D)光聚合起始劑_ 在本發明之著色4、&丄 — 、'成物中可含有（D)光聚合起始劑。措此可對著色組成物賦予放射線感應性。本發明所使用的（D)光聚合起始劑 ^ U承產生活性物種的化合物，可藉由可見光、紫外線、遠势k a L ^ 系外線、電子束、X射線等的放射線之曝光而使上述（Ck⑽ 1 )父聯劑的聚合起始。這樣的·光聚合起仏h o Q背1丨可列舉例如噻噸酮系化合物、本乙酮系化合物、聯畔 /人本唾系化合物、三啩系化合物、〇_ 醯基肟糸化合物、鑌略氧系化合物、安息香系化合物、二 -40- 201224064 笨酮系化合物、α -二酮系化合物、多核醌系化合物、二偶氮系化合物、醯亞胺磺酸鹽系化合物、鏽鹽系化合物等。在本發明之中，光聚合起始劑可單獨使用或混合2 種以上使用。光聚合起始劑係以選自噻噸酮系化合物、苯乙酮系化合物、聯咪唑系化合物、三畊系化合物、0-醯基肟系化合物之群中至少1種為佳。在本發明之中所合適的光聚合起始劑之中，噻噸酮系化合物之具體例可列舉噻噸酮、2-氣噻噸酮、2-曱基噻噸酮、2 -異丙基噻噸酮、4 -異丙基噻噸酮、2，4 -二氣噻噸酮、2,4-二曱基噻噸酮、2,4-二乙基噻噸酮、2,4-二異丙基。塞°頓顧）等。另外，上述苯乙酮系化合物之具體例可列舉2-曱基甲基硫代）苯基]-2-味淋基丙-1-1同、2-节基-2-二甲基胺基-1_ (4 -味嚇基苯基）丁-1-嗣、2-(4-甲基节基）-2-(二曱基胺基）-1-(4-咪啉基苯基）丁-1-酮等。另外，上述聯咪唑系化合物之具體例可列舉2,2'-雙 (2-氣苯基）-4,4’，5,5'-四苯基-1,2’-聯咪唑、2,2'-雙（2,4-二氯苯基）-4,4|，5,5'-四苯基-1,2'-聯咪唑、2,2’-雙（2,4,6-三氣苯基）-4,4’，5,5’-四苯基-1，2'-聯咪唑等。此外，在使用聯D米峻系化合物作為光聚合起始劑的情況下，在可改良感度這點上以併用氫供予體為佳。此處所謂的「氫供予體」意指藉由曝光而可對由聯咪唑系化合物產生的自由基供予氫原子之化合物。氫供予體可列舉例如2-巯基苯并噻唑、2-巯基苯并嘮唑等的硫醇系 -41 - 201224064 氫供予體、4,4’-雙（二曱基胺基）二苯酮、4,4'-雙（二乙基胺基）二苯酮等的胺系氫供予體。在本發明之中，氫供予體可單獨使用或混合2種以上使用，而在可進一步改良感度這點上，以組合使用1種以上的硫醇系氫供予體與1種以上的胺系氫供予體為佳。另外，上述三啩系化合物之具體例可列舉2,4,6-參（三氣甲基）-s-三啩、2-曱基-4,6-雙（三氯曱基）-s-三啡、 2-[2-(5 -甲基呋喃-2-基）乙烯基]-4,6-雙（三氣甲基）-s-三畊、2-[2-(呋喃-2-基）乙烯基]-4,6-雙（三氣甲基）-s-三啩、 2-[2-(4-二乙基胺基-2-曱基苯基）乙烯基]-4,6-雙（三氣甲基）-s-三啩、2-[2-(3,4-二曱氧基苯基）乙烯基]-4,6-雙（三氣曱基）-s-三啩、2-(4-甲氧基苯基）-4,6-雙（三氯曱基）-s-三畊、2-(4-乙氧基苯乙烯基）-4,6-雙（三氯曱基）-s-三啩、 2-(4-正丁氧基苯基）-4,6-雙（三氯曱基）-s-三啩等具有鹵甲基的三畊系化合物。另外，0-醯基肟系化合物之具體例可列舉1,2-辛二酮，1-[4-(苯基硫代）苯基]-，2-(0-苯曱醯基肟）、乙酮，1-[9-乙基-6-(2-曱基苯曱醯基）-9H-咔唑-3-基]-，1-(0-乙醯基月亏）、乙嗣，1-[9 -乙基-6-(2 -曱基-4 -四鼠α夫喃基曱氧基苯曱醯基）-9Η -咔唑-3-基]-,1-(0 -乙醯基肟）、乙酮，1-[9 -乙基 -6-{2-曱基-4-(2,2-二曱基-1,3-二氧戊環基）甲氧基苯甲醯基}-9Η-咔唑-3-基]-，1-(0-乙醯基肟）等。在本發明之中，在使用苯乙酮系化合物等的聯咪唑系化合物以外的光聚合起始劑的情況下，亦可併用增感劑。這種增感劑可列舉例如4,4’-雙（二曱基胺基）二苯酮 -42- 201224064 、4,4，-雙（二乙 —曱基胺基兩曱基胺基安牵、苄基）環己_]、香豆素、在本發明劑100質量份質量份為特佳少，則會有由若太多’則所洛的傾向。 -(E)溶劑_ 本發明之意加入的其他物。上述溶劑刀或其他成分有適度揮發性這樣的溶乙二醇單曱醚醇單正丁醚、二醇單正丙醚三乙二醇單乙醇單正丙醚、二醇單乙趟、 1基胺基）二苯酮、4-二乙基胺基苯乙酮v4_ 醯笨、4-二甲基胺基安息香酸乙酯、4_二香酸2-乙基己基、2,5_雙（4_二乙基胺基亞 7-二乙基胺基-3-(4-二乙基胺基笨甲醯基）乙基胺基）查耳酮等。之中，光聚合起始劑的含量相對於（c)交聯 Ϊ言，係以0.01〜120質量份為佳，以1〇〇。在此情況下，若光聚合起始劑的含量太曝光產生的硬化不足的顧慮’另一方面，形成的著色層在顯像時會有容易由基板脫著色組成物含有上述（A)〜成分、及任成分，而通常摻合溶劑而調製成液狀組成只要能夠使構成著色組成物的（A)〜（c)成分散或溶解，並且不與該等成分反應，具 ’即可適當地選擇使用。劑可列舉例如：、乙二醇單***、乙二醇單正丙醚、乙二二乙二醇單曱醚、二乙二醇單***、二乙、二乙二醇單正丁醚、三乙二醇單曱醚、醚、丙二醇單甲醚、丙二醇單***、丙二丙一醇單正丁醚、二丙二醇單曱醚、二丙一丙一醇單正丙醚、二丙二、 -43- 201224064 三丙二醇單甲醚、三丙二醇單***等的（聚）烯烴基二醇單烷醚類；乳酸甲酯、乳酸乙酯等的乳酸烷酯類；曱醇、乙醇、丙醇、丁醇、異丙醇、異丁醇、第三丁醇、辛醇、2-乙基己醇、環己醇等的（環）烷基醇類；二丙酮醇等的酮醇類； . 乙二醇單曱醚醋酸酯、乙二醇單***醋酸酯、二乙二醇單曱醚醋酸酯 > 二乙二醇單***醋酸酯、丙二醇單曱醚醋酸酯、丙二醇單***醋酸酯、二丙二醇單曱醚醋酸酯、3 -曱氧基丁基醋酸酯、3 -甲基-3 -甲氧基丁基醋酸酯等的（聚）烯烴基二醇單烷基醚醋酸酯類；二乙二醇二曱醚、二乙二醇甲基乙基醚、二乙二醇二乙醚、四氫吱喃等的其他醚類；曱基乙基酮、環己酮、2-庚酮、3-庚酮等的酮類；丙二醇二醋酸酯、1，3 - 丁二醇二醋酸酯、1，6 -己二醇二醋酸酯等的二醋酸酯類； 3 -曱氧基丙酸曱酯、3 -曱氧基丙酸乙酯、3 -乙氧基丙酸曱酯、3-乙氧基丙酸乙酯、乙氧基醋酸乙酯、3-曱基-3-甲氧基丁基丙酸酯等的烷氧基羧酸酯類；醋酸乙酯、醋酸正丙酯、醋酸異丙酯、醋酸正丁酯、醋酸異丁酯、蟻酸正戊酯、醋酸異戊酯、丙酸正丁酯、酪酸乙酯、酪酸正丙酯、酪酸異丙酯、酪酸正丁酯、丙酮酸甲酯、丙酮酸乙酯、丙酮酸正丙酯、乙醯醋酸甲酯、乙醯醋酸乙酯、2-氧代丁酸乙酯等的其他酯類；甲苯、二甲苯等的芳香族烴類； -44- 201224064 基吡咯烷看來，該、乙二醇單乙峻醋、二乙二丁二醇二氧基丙酸 3-甲基-3-'蟻酸正酪酸異丙以上使用 N，?-二甲基甲醯胺、甲基乙醯胺、…甲酮等的醯胺或内醯胺類等。 :溶解性、顏料分散性、塗布性等的觀點 f 中係以丙二醇單甲醚、丙二醇單*** 早甲醚醋酸酯、丙二醇單甲醚醋酸酷、丙二醇酸醋、3·甲氧基丁基醋酸醋 '二乙二醇二甲鍵 %甲基乙基醚、環己酮、2·庚酮、3·庚酮、^ 酉曰酸酉曰1,6-己二醇二醋酸酯、乳酸乙酯、甲乙醋、3·乙氧基丙酸甲冑、3_乙氧基丙酸乙醋、甲氧基丁基丙酸醋、醋酸正丁醋、醋酸異丁能士醋、醋酸異戊酿、丙酸正丁醋、酪酸乙醋、酉曰、酪酸正丁酯、丙酮酸乙酯等為佳。在本發明之中，溶劑可單獨使用或混合2種〇溶劑的含量並未受到特別限定，從所得到的著色组成物之塗布性、安定性等的觀點看來，溶劑的: 著色：成物中除了溶劑以外的各成分合計濃度成為5: 5〇質量％為佳’以成為10〜4〇質量％為特佳。 -添加劑- 本發明之著色組成物亦可因應必要而含有各種劑。 ’、、添加劑可列舉例如玻璃、氧化鋁等的填充劑；聚乙烯醇、聚（氟烷基丙烯酸酯）類等的高分子化合物；款系界面活性劑、矽系界面活性劑等的界面活性劑；乙稀基二甲氧基矽炫、乙烯基三乙氧基矽烷、乙烯基參（2_甲氧 -45- 201224064 基乙氧基）矽烷、N-(2-胺乙基）7 胺丙基甲某-田兰烧、N-(2 -胺乙基）-3 -胺丙基三取氧基妙〒氧基石夕院、3_险^_ 乙氧基石夕烧、3 -縮水甘油鱗義％ | 丙基三水…基丙基甲基二甲氧：：：三甲氧基石夕燒、1 缩乙基三曱氧基矽烷、3-氣丙基甲=2-(3,4-%氧環已基）二甲4其丙基三甲氧基石找、3.甲基丙烯酸氧基丙^三甲元氧=氯烧、3,丙基三甲氧基我等的密著促進劑; (4-曱基-6-第三丁基酚）、2,6-二筮-u 硫代雙第一丁基紛等的技氧儿μ ;2-(3-第三丁基-5-甲基-2-羥笨其" 乳化劑敌本基）_5·氯笨并***、ρ窗基二苯酮類等的紫外線吸收劑；聚丙烯酸納等的凝：：制劑；丙二酸、己二酸、伊康酸、檸康酸、富馬酸^ 康酸、2-胺基乙醇、3-胺基I丙醇、5_胺基I戊醇、h 胺基-1，2-丙二醇、2-胺基^3-丙二醇、4胺基]2_ 丁二醇等的殘潰改善劑；琥站酸單[2_(曱基）丙烯醯氧美乙基] 、苯二甲酸單[2-(甲基）丙烯醯氧基乙基]、羧基聚i己内醋單（曱基）丙烯酸酯等的顯像性改善劑；日本=開 2008-242078號公報等所揭示的具有反應性官能基的矽氧烷寡聚物等。本發明之著色組成物可藉由適合的方法調製，其調製方法可列舉例如日本特開200 8-5 8 642號公報、日本特開2010-132874號公報專所揭示的方法。在將本著色劑血顏料這兩者使用作為著色劑的情況，可採用如日本特開 20 10-132874號公報所揭示般的方法，其係藉由使含有本著色劑的染料溶液通過第1過濾器之後，將通過第1過濾器的染料溶液與另外調製的顏料分散液等混合，使所得 -46- 201224064 到的著色組成物通過第2過濾器而調製。另外還可採月由使含有本著色劑的染料與上述（B)〜（C)成分以及g 必要含有上述（D)成分及添加劑成分溶解於（E)溶劑，所付到的溶液通過第丨過濾器之後，將通過第丨過濾器溶液與另外調製的顏料分散液混合，使所得到的著色成物通過第2過濾器而調製的方法。此外亦可採用藉由含有本著色劑的染料溶液通過第】過濾器之後，將通過 1過濾器的染料溶液與上述（B)〜（c)成分以及因應必上述（D)〜（E)成分及添加劑成分混合、溶解，使所得的溶液通過第2過濾器，進一步將通過第2過濾器的溶與另外調製的顏料分散液混合，使所得到的著色組成通過第3過遽器而調製的方法。彩色濾光片及其製造方法本發明之彩色濾光片具備含有本著色劑的著色層製造衫色濾光片的方法，第一可列舉下述方法。先，在基板的表面上，因應必要以區晝出形成晝素的分的方式形成遮光層（黑色矩陣）^接下來，在此基板塗布例如含有本著色劑的藍色放射線感應性組成物之狀組成物之後，進行預烘烤以使溶劑蒸發，而形成塗。接下來’隔著光罩對於此塗獏曝光之後，使用鹼顯液使其顯像’將塗膜的未曝光部溶解除去。然後，藉後：t、烤形成以既定排列方式配置藍色晝素圖案的晝陣列。接下來，使用綠色或紅色的各放射線感應性著色成物，並以與上述同樣的方式，進行各放射線感應怕丨藉丨應使的 Μ 使第要到液物首部上液膜像由素組著 -47- 201224064 色組成物之塗布、預烘烤、曝光、顯像及後烘烤序使綠色晝素陣列及紅色畫素陣列形成在相同基藉此可得到於基板上配置有紅色、綠色及藍色之晝素陣列的彩色濾光片。但是在本發明之中，形晝素的順序並不受上述所限定。另外’黑色矩陣可藉由利用光蝕刻法將由濺鍍所成膜的鉻等的金屬薄膜製成所希望的圖案而而在使用分散有黑色著色劑的放射線感應性著色 ’亦能夠以與上述晝素形成的情況同樣的方式形發明之著色組成物亦可適合使用於該黑色矩陣的形成彩色濾光片時所使用的基板可列舉例如石夕、聚碳酸酯、聚酯、芳香族聚醯胺、聚醯胺酿聚醯亞胺等。另外’在S玄等的基板中’亦可依照需要而實矽烧偶合劑等進行的藥品處理、電漿處理、離子鍍、氣相反應法、真空蒸鍍等適當的前處理。將放射線感應性著色組成物塗布在基板時，喷霧法、輥式塗布法、旋轉塗布法、狹缝模具塗棒式塗布法等適當的塗布法，而尤其以採用旋：、狹縫模具塗布法為佳。預烘烤通常將減壓乾燥與加熱乾燥加以組。減壓乾燥通常進行至50〜200pa。另外，加熱件通常在70〜11〇t進行分鐘左右。… 塗布厚度以乾燥後的膜厚而計，通常為〇石 ’宜為 1.2 〜5 . 〇 y m。，而依板上。三原色成各色鍍或蒸形成，組成物成。本形成。玻璃、亞胺、施藉由鍍、濺可採用布法、塗布法而進行燥的條 8.0 μ m -48- 201224064 升> 成晝素及/或黑色矩陣時所使用的放射線光源，可列舉例如氙燈、鹵素燈、鎢燈、高壓水銀燈、超高壓水銀燈 '金屬函素燈、中壓水銀燈、低壓水銀燈等的燈光源或氬離子雷射、YAG雷射、XeC1準分子雷射、氮雷射專的雷射光源等’而以波長在19〇〜450nm範圍的放射線為佳。放射線之曝光量一般而言以1〇〜l〇,〇〇〇j/m2為佳。另外’上述鹼顯像液係以例如碳酸鈉、氫氧化鈉、氫氧化鉀、四曱基氫氧化銨、膽鹼、丨，8_二氮雜雙環 -[5.4.0]_7_十一烯、1，5_二氮雜雙環-[4 3 〇]_5_壬烯等的水溶液為佳。在上述鹼顯像液中’亦可適量添加例如甲醇、乙醇等的水溶性有機溶劑或界面活性劑等。此外，在驗顯像後通常進行水洗。貝務顯像法顯像處理法可適合使用淋浴顯像法浸潰（dip)顯像法、覆液（paddle)(顯影）顯像法等。顯像終件係以在常溫，5〜300秒鐘為佳。本後烘烤的條件通常是在120〜280 °C進行1〇〜八於左右，而從本著色劑之耐熱性的觀點看來，後供烤的^ 度宜為240°C以下，特佳為230°C以下。以這種方式形成的晝素的膜厚通常為05〜ςΛ • ).◦ β m ，宜為 1.0〜3.0 M m ° 另外，製造♦色遽光片的第二方法，可接田 •i ?木用日本特開平7-3 1 87 23號公報、日本特開2000-3 1〇706號公報* 揭示的、藉由喷墨的方式得到各色晝素的方法等所。此方法 -49- 201224064 之中’首先在基板表面±，形成兼具遮光機能的隔件接下來，在所形成的隔件内，例如藉由噴墨裝置將人本著色劑的藍色著色組成物之液狀組成物噴^之後^ 行預烘烤使溶劑蒸發。接下來’因應必要對此塗之後，藉由後烘烤使其硬化，而形成藍色畫素圖案接下來，使用綠色或紅色的各著色組成物，以與述同樣的方式依序在相同基板上形成綠色晝素圖案及^ 色畫素圖案。藉此可得到在基板上配置有紅色、綠色藍色的三原色畫素圖案的彩色濾光片。但是在本發明中’形成各色晝素的順序並不受上述所限定。此外’上述隔件不僅具有遮光機能，還可發揮用防止喷在區畫之内的各色著色組成物混色的機能，因與上述第一方法所使用的黑色矩陣相比，膜厚較厚。以，隔件通常是使用黑色放射線感應性組成物而形成形成彩色濾光片時所使用的基板或放射線之光源以及預烘烤或後烘烤的方法或條件，係與上述第一方為同樣的。以這種方式，藉由喷墨的方式所形成的書 ’其膜厚與隔件的高度相同程度。在以這種方式所得到的畫素圖案上，因應必要形保護膜之後’藉由濺鍍形成透明導電膜。形成透明導膜之後’亦可進一步形成間隔物，而製成彩色濾光片間隔物通常是使用放射線感應性組成物而形成，然而可製成具有遮光性的間隔物（黑色間隔物）。在此情況疋使用分散有黑色著色劑的放射線感應性著色組成物而本發明之著色組成物亦可適合使用於該黑色間隔物形成。有進光上紅及之於此所法素成電 0 亦下的 -50- 201224064 以這種方式所及色純度極高，因元件、顏色感測器為有用。得到的本發明之彩此在彩色液晶顯示、有機EL顯示元件色遽光片，其輝度元件、彩色攝像管、電子紙等方面極顯示元件，本發明之顯示元件具備本發明之彩色濾光片。顯示兀件可列舉衫色液晶顯示元件、有機EL顯示元件、電子具備本發明之彩色濾光片的彩色液晶顯示元件，可為透過型或反射型，可採取適合的構造。例如可採取使彩色濾光片形成在與配置有薄膜電晶體（TFT)的驅動用基板不同的另一個基板上，而使驅動用基板與形成彩色濾光片的基板隔著液晶層呈對向的構造，進一步還可採取使在配置有薄膜電晶體（TFT)的驅動用基板表面上形成彩色濾光片的基板與形成ITO(摻錫的氧化銦）電極的基板隔著液晶層呈對向的構造。後者的構造具有可更加提升開口率’可得到明亮而高精細的液晶顯示元件這樣的優點。具備本發明之彩色濾光片的彩色液晶顯示元件，除了冷陰極螢光管（CCFL : Cold Cathode Fluorescent Lamp) 之外，還可具備以白色LED為光源的背光單元。白色LED 可列舉例如藉由組合紅色LED、綠色LED與藍色LED而混色以得到白色光的白色LED ;藉由組合藍色LED、紅色 LED與綠色螢光體而混色以得到白色光的白色led ;藉由組合藍色LED、紅色發光螢光體與綠色發光螢光體而混 -51- 201224064 色以得到白色光的白色LED ;藉由藍色LED、YAG系螢光體的混色以得到白色光的白色LED ;藉由組合藍色LED 、橘色發光螢光體與綠色發光螢光體而混色以得到白色光的白色LED ;藉由組合紫外線LED、紅色發光螢光體、綠色發光螢光體與藍色發光螢光體而混色以得到白色光的白色LED等。具備本發明之彩色濾光片的彩色液晶顯示元件可適合使用 TN(Twisted Nematic)型 ' STN(Super Twisted Nematic)型、IPS(In-Planes Switching)型 ' VA(VerticalYellow 40 ' CI Acid Yellow 76 ; CI· Acid Red 91, CI Acid Red 92, CI Acid Red 97, -32- 201224064 CI Acid Red 1 14, CI Acid Red 13 8, C.I_ Acid Red 151 CI· Acid Orange 51, CI·Acid Orange 63; CI·Acid Blue 80, CI Acid Blue 83, CI·Acid Blue 90 CI Acid Green 9, CI Acid Green 16, CI Acid Green 25, CI Acid Green 27. In the present invention, other colorants may be used singly or in combination of two or more. The content ratio of the (A) colorant is usually from 5 to 70% by mass in the solid content of the coloring composition, from the viewpoint of forming a halogen having a high luminance and excellent color purity or a black matrix having excellent light shielding properties. 5 to 60% by mass. The solid content referred to herein means a component other than the solvent described below. In the case where a pigment is used as the other colorant in the present invention, it may be used together with a dispersing agent or a dispersing aid as needed. As the dispersant, for example, a suitable dispersant such as a cationic system, an anionic system or a nonionic surfactant can be used, and a polymer dispersant is preferred. Specific examples thereof include an amine acetoacetate dispersant, a polyethyleneimine dispersant, a polyoxyethylene alkyl ether dispersant, a polyoxyethylene alkyl phenyl ether dispersant, and a polyethylene glycol diester dispersion. Agent, sorbitan fatty acid ester dispersant, polyester dispersant, acrylic dispersant, and the like. Such a dispersing agent can be obtained commercially, and examples of the acrylic dispersing agent include Disperbyk-2000, Disperbyk-200 1, BYK-LPN6919, BYK-LPN21116, and BYK-LPN21 324 (above, Byk-Chemie (BYK)) Ethyl urethane dispersant can be -33- 201224064 List Disperbyk-161, Disperbyk-162, Disperbyk-165, Disperbyk-167, Disperbyk-170, Disperbyk-182 (above, Byk-Chemie (BYK)) Solsperse 76500 (manufactured by Lubrizol Co., Ltd.); and polyethyleneimine-based dispersant: Solsperse 24000 (manufactured by Lubrizol Co., Ltd.); and polyester-based dispersants: Ajisper PB821, Ajisper PB822, Ajisper PB880, Ajisper PB881 (Ajinomoto FINE TECHNO Co., Ltd.) and the like. Further, the above-mentioned dispersing aid may, for example, be a pigment derivative, and specific examples thereof include a copper anthraquinone, a diketone D, a piroxicam, a ruthenium derivative, and the like. Further, the content of the dispersing agent and the dispersing aid can be appropriately determined within the range which does not impair the object of the present invention. - (B) Adhesive Resin - The binder resin in the coloring composition of the present invention is not particularly limited, and a resin having an acidic functional group such as a carboxyl group or a phenolic hydroxyl group is preferred. In particular, a polymer having a carboxyl group (hereinafter referred to as "carboxyl group-containing polymer") is preferable, and examples thereof include an ethylenically unsaturated monomer having one or more carboxyl groups (hereinafter referred to as "unsaturated monomer (bl)". Copolymer with other copolymerizable ethylenically unsaturated monomer (hereinafter referred to as "unsaturated monomer (b2)"). ^ The above unsaturated monomer (bl) may, for example, be (meth)acrylic acid, maleic acid, maleic anhydride, succinic acid mono [2-(methyl)propenyloxyethyl ester], 0-carboxypolycaprolactone Monos(meth) acrylate, p-vinyl benzoic acid, etc. These unsaturated monomers (bl) may be used singly or in combination of two or more kinds to be -34-201224064 1 , the above unsaturated monomer (b2) For example, N-phenylmaleimide + N-% hexylmaleimine-like substituted maleated mais, such as benzophenone, α-mercaptostyrene, and thiol Phenylethylene, p-carbyl styrene, p-vinyl glycidyl ether, terpene-like sulphur-based ethylene compound; >(mercapto)acrylic acid methyl vinegar, (meth)acrylic acid Butane vinegar, (meth) propylene oxime ^ ethylhexyl ester, (mercapto) acrylic acid 2-hydroxyethyl ester, (meth) acrylonitrile, (benzyl) benzyl acrylate, polyethylene glycol (polymerization Degree 2~1〇) oxime ether (:) acrylate, polypropylene glycol (degree of polymerization 2~1〇) oxime ether (mercapto) acrylate, polyethylene glycol (degree of polymerization 2~1〇) single (methyl ) Polyester, polypropylene = (degree of polymerization 2 to 10) mono (meth) acrylate, cyclohexyl (meth) acrylate, (meth) isopropyl decyl acrylate, tricyclo [5 2 丨〇 2.6]癸_8_yl (meth) acrylate, dicyclopentenyl (mercapto) acrylate, glycerol mono (meth) acrylate, 4-hydroxyphenyl (meth) acrylate, p-isopropyl phenol Ethylene oxide denatured (meth) acrylate, glycidyl (meth) acrylate, 3,4 epoxycyclohexyl decyl (meth) acrylate, 3_[(meth) propylene methoxymethyl] Oxetane, 3-[(indenyl)propenyloxyindenyl]_3_ethyloxetane-like (meth) acrylate; such as cyclohexylvinyl-1, isomeric Ethylene-based fluorene, tricyclo[5.2 1 〇2.6] 癸-8-ylvinyl anthracene, pentacyclic fifteen alkylene fluorene, (ethylene oxide methyl)-3-ethyl oxetane An alkane-like vinyl ether; such as polystyrene, poly(methyl) acrylate, poly(decyl) n-butyl acrylate, polyoxo-oxygen at the end of the polymer molecular bond ) Giant monomers such as propylene. These unsaturated monomers (b2) may be used singly or in combination of two or more. -35- 201224064 Among the copolymers of the unsaturated monomer (bl) and the unsaturated monomer (b2), the copolymerization ratio of the unsaturated monomer (b1) in the copolymer is preferably from 5 to 70% by mass, More preferably 1 0 to 60 mass. By the copolymerization of the unsaturated monomer (b 1 ) in such a range, a coloring composition excellent in alkali developability and storage stability can be obtained. Specific examples of the copolymer of the unsaturated monomer (b1) and the unsaturated monomer (b2) include, for example, Japanese Laid-Open Patent Publication No. Hei 7-14-654, Japanese Patent Publication No. Hei 8-259876, and Japanese Patent Laid-Open No. Hei. 〇〇〇〇 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ A copolymer disclosed in, for example, Japanese Laid-Open Patent Publication No. 296778, No. 2004-101728. In addition, in the present invention, for example, the Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A carboxyl group-containing polymer having a polymerizable unsaturated bond such as a (meth) acrylonitrile group in a side chain as disclosed in Japanese Unexamined Patent Publication No. Hei No. Hei. No. Hei. Adhesive resin. The weight average molecular weight (Mw) in terms of polystyrene measured by Gpc (dissolving solvent: tetrahydrofuran) in the present invention is usually 1,000 to 100, and is preferably 3, 〇〇〇~5 (). , () () (). If the thickness is too small, the residual film ratio of the film may be reduced, the pattern shape, heat resistance, and the like may be deteriorated. On the other hand, if the film size is too large, the resolution may be lowered or deteriorated. The pattern shape and the coating by the slit nozzle (4) are prone to dryness (four). 36-201224064 In addition, the ratio of the weight average molecular weight of the binder resin in the present invention to the number average molecular weight (?η) in terms of polystyrene oxime measured by GPC (dissolving solvent: tetrahydrofuran) is preferably (Mw/Mn). 1_〇~5·〇, preferably 1〇~3 · 0 黏 The binder resin in the present invention can be produced by a known method, and can also be produced by, for example, JP-A-2003-2227 17 The method disclosed in the publication No. 2006-259680, International Publication No. 07/02987, and the like, 'controls its structure or Mw, Mw/Mn. In the present invention, the binder resin may be used singly or in combination of two or more. In the present invention, the content of the binder resin is usually 10 to 1,000 parts by mass, preferably 2 to 5 parts by mass, per 100 parts by mass of the (A) colorant. When the content of the binder resin is too small, for example, the alkali developability is lowered, and the storage stability of the obtained colored composition is lowered. On the other hand, if too much, the concentration of the colorant is relatively lowered, so that There is a concern that it is difficult to achieve a color density for the purpose of a film. - (C) Crosslinking Agent - In the present invention, the (C) crosslinking agent means a compound having two or more polymerizable groups. Examples of the polymerizable group include an ethylenically unsaturated group, an ethylene oxide group, an oxetan group, and an N-alkyloxymethylamino group. In the present invention, the (C) crosslinking agent is preferably a compound having two or more (meth)acryl fluorenyl groups or a compound having two or more alkoxymethylamino groups. A compound having two or more (meth) acryloyl fluorenyl groups is preferably used in combination with a compound having two or more N-methyl thiophene methylamine groups. -37-201224064 Specific examples of the compound having two or more (fluorenyl) acrylonitrile groups include polyfunctional (fluorenyl) acrylates obtained by reacting an aliphatic polyhydroxy compound with (meth) acrylonitrile. a polyfunctional (meth) acrylate denatured by caprolactone, a polyfunctional (meth) acrylate vinegar denatured with an alkylene oxide, a reaction of a (meth) acrylate having a hydroxyl group with a polyfunctional isocyanate The polyfunctional urethane (meth) acrylate 'a polyfunctional (fluorenyl) acrylate having a mercapto group obtained by reacting a trans-group (meth) acrylate with an acid anhydride. Here, examples of the aliphatic polyhydroxy compound include divalent aliphatic polyhydroxy compounds such as ethylene glycol, propylene glycol, polyethylene glycol, and polypropylene glycol, such as glycerin, dimercaptopropylpropene, and neopentyl alcohol. An aliphatic polyhydroxy compound having a trivalent or higher valence of dipentaerythritol. The (meth) acrylate having a hydroxyl group may, for example, be 2-hydroxyethyl (meth)acrylate, trimethylolpropane di(meth)acrylate, or neopentyltris(tris) acrylate. , diterpene tetrakis(pentyl) acrylate, glycerin dimethacrylate, and the like. The polyfunctional isocyanate may, for example, be toluene diisocyanate, /, methylene diisocyanate, diphenylmethylene diisocyanate or isophorone diisocyanate. Examples of the acid anhydride include a dianhydride such as succinic anhydride, maleic anhydride, glutaric anhydride, itaconic anhydride, phthalic anhydride, and hexahydrophthalic anhydride, such as pyroic acid anhydride and biphenyltetracarboxylic dianhydride. Diphenyl ketone four acid-lowering four-acid quaternary acid liver. In addition, the polyfunctional (meth) acrylate which has been denatured by the vinegar is exemplified by the compound described in paragraphs [15] to [0018] of JP-A-44955. The above-mentioned epoxidized polyfunctional (fluorenyl) acrylate may be exemplified by bisphenol A ethylene oxide and/or propylene-38-201224064 sinter denatured two (meth), π & _ @, T storm) acrylic acid S 曰, isocyanuric acid ethylene oxide and / or anaerobic propylene burning denaturation; rf field #, Λ m ^ - (meth) acrylate, trihydroxy hydrazine propane ethylene oxide and / or propylene oxide denatured tris(mercapto) acrylate, neopentyl alcohol epoxy 2 alkane and / or propylene oxide denatured tris(mercapto) acrylate, neopentyl alcohol oxyethylene and / or Epoxypropane-denatured tetra(indenyl) acrylate, diamylpentaerythritol oxyethylene and/or propylene oxide-denatured penta(meth)acrylate-neopentyl alcohol ethylene oxide and/or ring Oxypropane denatured hexaenoic acid ester or the like. π Further, the above-mentioned compound having two or more decyloxyguanidinoamine groups may, for example, have a melamine structure, a benzoguanamine structure, or a urine; Compounds, etc. In addition, the 'melamine structure, benzoguanamine structure heart eight has more than one triple hearing ring or phenyl substituted triterpene ring as the basic The chemical structure of wood, the concept also includes a condensation of melamine, benzoguanamine or X. Specific examples of the compound having two or more oxime-methoxymethylamino groups may be Ν, Ν, Ν', Ν,,Ν,,,Ν.._六(Hypodooxymethyl) melamine, hydrazine, hydrazine, hydrazine, ν, _tetrakis(oxomethoxy)benzamide, ν,ν , Ν·, ν=tetrakis (alkoxymethyl) glycoluril, etc. <Multi-functional (fluorenyl) obtained by reacting a trivalent or higher aliphatic poly-based compound with (meth), = && ::s: S曰, polycaprol (meth) acrylate denatured by caprolactone, polybromo bromide formic acid (methyl ketone, thiol olefin, polyfunctional with carboxyl group (methyl = rare =, N, Nf is preferably Μ Μ , , , , tetra (alkoxymethyl) benzoguanamine. The strength of the coloring > is high, the surface smoothness of the colored layer is excellent, and it is not exposed. It is difficult to cause material fouling on the light-shielding layer, and residual film == -39- 201224064 The aliphatic polyhydroxy compound having a valence or higher is reacted with (mercapto)acrylic acid to obtain a polyfunctional (indenyl) acetoacetate Hydroxymercaptopropane triacrylate, neopentyl alcohol triacrylate acrylate, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate vinegar is particularly preferred; and polyfunctional (meth) propyl group having a carboxyl group In the dilute vinegar, 'a compound obtained by reacting neopentyl alcohol triacrylate with a white acid needle' to make dipentaerythritol pentaacrylate In the present invention, the (C) crosslinking agent may be used singly or in combination of two or more kinds. In the present invention, (C) a crosslinking agent of the winter dan, The amount of P Μ is preferably in the range of (7) to (9) parts by mass in terms of (1) to (9) parts by mass, and particularly preferably in the range of 2 Å to 5 Å by mass. If the content of the monomer is too small, there will be a situation in which it is not possible to obtain sufficient hardening properties. On the other hand, if the content of the right polyfunctional monomer is too large, it is inconsistent with the ethics. When the coloring composition of the invention imparts alkali developability, the right 趴 s has a decrease in developability, and on the substrate of the unexposed portion or on the light-shielding layer, the material 4 is damaged, the residual film, etc. - (D) Photopolymerization Initiator _ In the coloring 4, & 丄-, 'forms of the present invention, (D) a photopolymerization initiator may be contained, thereby imparting radiation sensitivity to the coloring composition. The (D) photopolymerization initiator used in the present invention can produce a compound of an active species, which can be obtained by visible light, ultraviolet light, and potential. Ka L ^ The exposure of the above-mentioned (Ck(10) 1 ) parent-linking agent is exposed by radiation such as an external beam, an electron beam or an X-ray. Such a photopolymerization is exemplified by, for example, a thioxanthone system. a compound, an ethyl ketone-based compound, a lycopene/human salivary compound, a triterpenoid compound, a ruthenium ruthenium compound, an anthraquinone-based compound, a benzoin-based compound, a di--40-201224064 ketone-based compound, An α-diketone compound, a polynuclear oxime compound, a diazo compound, a quinone sulfonate compound, a rust salt compound, etc. In the present invention, the photopolymerization initiator may be used alone or in combination 2 More than one kind. The photopolymerization initiator is preferably at least one selected from the group consisting of a thioxanthone-based compound, an acetophenone-based compound, a biimidazole-based compound, a tri-grain-based compound, and a 0-fluorenyl-based compound. Among the photopolymerization initiators suitable for the present invention, specific examples of the thioxanthone-based compound include thioxanthone, 2-oxethione, 2-mercaptothioxanthone, and 2-isopropyl group. Thioxanthone, 4-isopropylthioxanthone, 2,4-dithioxanthone, 2,4-dimercaptothioxanthone, 2,4-diethylthioxanthone, 2,4-di Isopropyl. Say ° ° Gu Gu) and so on. Further, specific examples of the above acetophenone-based compound include 2-mercaptomethylthio)phenyl]-2-propanylpropyl-1-1, 2-benzyl-2-dimethylamino group. -1_ (4-flavorylphenyl) butan-1-indole, 2-(4-methylbenzyl)-2-(didecylamino)-1-(4-morpholinylphenyl) -1-ketone and the like. Further, specific examples of the biimidazole-based compound include 2,2'-bis(2-phenylphenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2, 2'-bis(2,4-dichlorophenyl)-4,4|,5,5'-tetraphenyl-1,2'-biimidazole, 2,2'-bis(2,4,6- Tris-phenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole and the like. Further, in the case of using a D-Mimi compound as a photopolymerization initiator, it is preferred to use a hydrogen donor in combination with the improvement of sensitivity. The "hydrogen donor" as used herein means a compound which can supply a hydrogen atom to a radical generated by a biimidazole compound by exposure. Examples of the hydrogen donor include a mercaptan-41-201224064 hydrogen donor, 4,4'-bis(didecylamino)diphenyl such as 2-mercaptobenzothiazole or 2-mercaptobenzoxazole. An amine-based hydrogen donor such as a ketone or 4,4'-bis(diethylamino)benzophenone. In the present invention, the hydrogen donor may be used singly or in combination of two or more kinds, and one or more thiol-based hydrogen donors and one or more amines may be used in combination in order to further improve the sensitivity. Hydrogen donors are preferred. Further, specific examples of the above triterpenoid compound include 2,4,6-paran (trimethylmethyl)-s-triterpene, 2-mercapto-4,6-bis(trichloroindenyl)-s- Trimorphine, 2-[2-(5-methylfuran-2-yl)vinyl]-4,6-bis(trimethylmethyl)-s-trin, 2-[2-(furan-2- Vinyl]-4,6-bis(trimethylmethyl)-s-triterpene, 2-[2-(4-diethylamino-2-mercaptophenyl)vinyl]-4, 6-bis(trismethyl)-s-triterpene, 2-[2-(3,4-dimethoxyphenyl)ethenyl]-4,6-bis(tris)-s- Triterpenoid, 2-(4-methoxyphenyl)-4,6-bis(trichloroindenyl)-s-trin, 2-(4-ethoxystyryl)-4,6-double Three-tillage system with halomethyl group, such as (trichloroindenyl)-s-triterpene, 2-(4-n-butoxyphenyl)-4,6-bis(trichloroindenyl)-s-triterpene Compound. Further, specific examples of the 0-fluorenyl fluorene-based compound include 1,2-octanedione, 1-[4-(phenylthio)phenyl]-, 2-(0-benzofluorenyl), Ethyl ketone, 1-[9-ethyl-6-(2-mercaptobenzoyl)-9H-indazol-3-yl]-, 1-(0-ethenyl group), acetamidine, 1-[9-ethyl-6-(2-indolyl-4-tetramolysyl-α-pyranyloxyphenylhydrazino)-9Η-carbazol-3-yl]-, 1-(0-B Ethyl ketone, ethyl ketone, 1-[9-ethyl-6-{2-mercapto-4-(2,2-dimercapto-1,3-dioxolanyl)methoxybenzoate Mercapto}-9Η-carbazol-3-yl]-, 1-(0-ethenylhydrazine) and the like. In the case of using a photopolymerization initiator other than the biimidazole compound such as an acetophenone-based compound, a sensitizer may be used in combination. Such a sensitizer may, for example, be 4,4'-bis(didecylamino)benzophenone-42-201224064 or 4,4,-bis(diethyl-decylamino fluorenylamine). Benzyl)cyclohexyl]], coumarin, and 100 parts by mass of the agent of the present invention are particularly preferably small, and there is a tendency that it is too much. - (E) Solvent - Others to which the present invention is intended. The above solvent knife or other component has a moderate volatility such as ethylene glycol monoterpene ether mono-n-butyl ether, glycol mono-n-propyl ether, triethylene glycol monoethanol mono-n-propyl ether, diol monoethyl hydrazine, 1 base Amino)benzophenone, 4-diethylaminoacetophenone v4_indole, ethyl 4-dimethylaminobenzoate, 4-ethylhexyl 2-ethylhexyl, 2,5-bis ( 4-_Diethylamino 7-diethylamino-3-(4-diethylamino)carbamoyl)ethylamino)chalcone and the like. Among them, the content of the photopolymerization initiator is preferably 0.01 to 120 parts by mass, based on (c) crosslinking, of 1 Å. In this case, if the content of the photopolymerization initiator is too much to cause insufficient hardening due to exposure, on the other hand, the formed coloring layer may be easily decolored by the substrate during the development of the composition containing the above (A) to the component. And a component which is usually mixed with a solvent to prepare a liquid composition, as long as (A) to (c) constituting the colored composition can be dispersed or dissolved, and does not react with the components, Choose to use. The agent may, for example, be: ethylene glycol monoethyl ether, ethylene glycol mono-n-propyl ether, ethylene diethylene glycol monoterpene ether, diethylene glycol monoethyl ether, diethylene glycol, diethylene glycol mono-n-butyl ether, three Ethylene glycol monoterpene ether, ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-n-butyl ether, dipropylene glycol monoterpene ether, dipropylene monopropanol mono-n-propyl ether, dipropylene, - 43- 201224064 (poly) olefinic diol monoalkyl ethers such as tripropylene glycol monomethyl ether and tripropylene glycol monoethyl ether; alkyl lactate such as methyl lactate or ethyl lactate; decyl alcohol, ethanol, propanol and butyl a (cyclo)alkyl alcohol such as an alcohol, isopropanol, isobutanol, tert-butanol, octanol, 2-ethylhexanol or cyclohexanol; a keto alcohol such as diacetone alcohol; Alcohol monodecyl ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monoterpene ether acetate > diethylene glycol monoethyl ether acetate, propylene glycol monoterpene ether acetate, propylene glycol monoethyl ether acetate, dipropylene glycol (poly)olefin diols such as monoterpene ether acetate, 3-methoxyoxybutyl acetate, 3-methyl-3-methoxybutyl acetate Other ethers such as diethylene glycol dioxime ether, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether, tetrahydrofuran, etc.; mercapto ethyl ketone, cyclohexanone a ketone such as 2-heptanone or 3-heptanone; a diacetate such as propylene glycol diacetate, 1,3-butanediol diacetate or 1,6-hexanediol diacetate; Ethyl methoxypropionate, ethyl 3-methoxyoxypropionate, decyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl ethoxyacetate, 3-mercapto- Alkoxycarboxylates such as 3-methoxybutylpropionate; ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl formate, acetic acid Isoamyl ester, n-butyl propionate, ethyl butyrate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate, methyl pyruvate, ethyl pyruvate, n-propyl pyruvate, methyl acetate , other esters such as ethyl acetate, ethyl 2-oxobutanoate; aromatic hydrocarbons such as toluene and xylene; -44- 201224064 Vinegar, diethylene dibutanediol Oxypropionate 3-methyl-3-'-antimonic acid n-butyric acid isopropyl Amidoxime or an indoleamine such as N,?-dimethylformamide, methylacetamide or methyl ketone is used. : From the viewpoints of solubility, pigment dispersibility, and coatability, propylene glycol monomethyl ether, propylene glycol monoethyl ether early methyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol vinegar, and 3 methoxybutyl acetate are used. Vinegar 'diethylene glycol dimethyl bond% methyl ethyl ether, cyclohexanone, 2 · heptanone, 3 · heptanone, 酉曰酉曰酉曰 1,6-hexanediol diacetate, ethyl lactate , methyl ethyl vinegar, 3 · ethoxy propionate formazan, 3 - ethoxy propionate ethyl vinegar, methoxy butyl propionate vinegar, acetic acid n-butyl vinegar, acetic acid isobutyl vinegar, acetic acid isoflavone, C Preferably, n-butyl vinegar, ethyl acetonate, strontium, n-butyl butyrate, ethyl pyruvate, and the like. In the present invention, the solvent may be used alone or in combination. The content of the two kinds of hydrazine solvents is not particularly limited, and from the viewpoints of coatability and stability of the obtained coloring composition, the solvent: coloring: The total concentration of each component other than the solvent is 5: 5 〇 mass% is preferable, and it is particularly preferable to be 10 to 4 〇 mass%. - Additive - The colored composition of the present invention may contain various agents as necessary. ', the additive may, for example, be a filler such as glass or alumina; a polymer compound such as polyvinyl alcohol or poly(fluoroalkyl acrylate); interfacial activity of a surfactant such as a surfactant or a lanthanide surfactant; Ethyl dimethoxy oxime, vinyl triethoxy decane, vinyl ginseng (2-methoxy-45-201224064 ethoxy) decane, N-(2-aminoethyl) 7 amine Propyl A-Talan, N-(2-Aminoethyl)-3-Aminopropyl Trioxetyloxy Oxime, 3_Insurance^_ Ethoxylate, 3-Glycidol鳞义% | propyl trihydrate... propyl propyl dimethyl oxy::: trimethoxy sulphur, 1 condensed ethyl tridecyloxy decane, 3-vapor propyl group = 2 (3, 4- % oxocyclohexyl) dimethyl 4 propyl trimethoxy stone, 3. methacrylic acid oxy propyl trimethoxide = chlorination, 3, propyl trimethoxy, etc. adhesion promoter; (4 - mercapto-6-tert-butylphenol), 2,6-dioxin-u thiobis-first butyl sulfonate; 2-(3-tert-butyl-5-methyl -2-hydroxy stupid " emulsifier enemy base) _5 · chloro benzotriazole, ρ window benzophenone and other purple External absorbent; coagulation of polyacrylic acid; etc.: preparation; malonic acid, adipic acid, itaconic acid, citraconic acid, fumaric acid, potassium, 2-aminoethanol, 3-aminopropanol , a residual improver such as 5-amino-I-pentanol, h-amino-1,2-propanediol, 2-amino-3-propanediol, 4-amino]2-butanediol; alkaloid acid [2_( Imaging improvement agent such as fluorenyl propylene oxime oxime ethyl ester, phthalic acid mono [2-(methyl) propylene oxiranyl ethyl], carboxy polyi-ene vinegar mono(indenyl) acrylate A pyrithione oligomer having a reactive functional group disclosed in, for example, JP-A-2008-242078. The coloring composition of the present invention can be prepared by a suitable method, and the method disclosed in Japanese Laid-Open Patent Publication No. Hei. No. 2010-132874, and JP-A-2010-132874. In the case where both of the coloring agent blood pigments are used as the coloring agent, a method as disclosed in Japanese Laid-Open Patent Publication No. 20 10-132874, which is incorporated by the first After the filter, the dye solution of the first filter is mixed with a separately prepared pigment dispersion or the like, and the resulting colored composition of -46 to 201224064 is prepared by a second filter. Further, the dye containing the coloring agent and the components (B) to (C) and the component (D) and the additive component may be dissolved in the solvent (E), and the solution obtained may be passed through the third layer. After the filter, a method in which the second filter solution is mixed with the separately prepared pigment dispersion and the obtained colored product is passed through the second filter is prepared. In addition, after passing the first filter through the dye solution containing the coloring agent, the dye solution passing through the 1 filter and the above components (B) to (c) and the components (D) to (E) above may be used. The additive component is mixed and dissolved, and the obtained solution is passed through a second filter, and the solution obtained by the second filter is further mixed with the separately prepared pigment dispersion liquid, and the obtained coloring composition is prepared by the third filter. method. Color filter and method for producing the same The color filter of the present invention comprises a coloring layer containing the coloring agent. A method for producing a shirt color filter, and the first method is as follows. First, on the surface of the substrate, a light-shielding layer (black matrix) is formed in such a manner as to form a fraction of the halogen element. Next, a blue radiation-sensitive composition containing the present colorant is applied to the substrate. After the composition, prebaking is carried out to evaporate the solvent to form a coating. Next, after exposure to the coating was carried out through a photomask, the alkali exposure liquid was used to develop the image to remove the unexposed portion of the coating film. Then, after borrowing: t, roasting forms an array of enamels in which the blue halogen pattern is arranged in a predetermined arrangement. Next, each of the green or red radiation-sensitive coloring objects is used, and in the same manner as described above, each of the radiation-sensing stimuli is caused by the Μ Μ 第第第第第第第第第第第第第-47- 201224064 Coating, prebaking, exposing, developing and post-baking of the color composition, the green halogen array and the red pixel array are formed on the same basis, thereby obtaining red, green on the substrate And a color filter of the blue halogen array. However, in the present invention, the order of the morphogens is not limited to the above. Further, the 'black matrix can be formed by using a metal film such as chromium formed by sputtering by a photolithography method to form a desired pattern, and using radiation-sensitive coloring in which a black colorant is dispersed. In the same manner as the formation of the element, the colored composition of the invention can also be suitably used for the substrate used for forming the color filter of the black matrix, for example, Shixia, polycarbonate, polyester, aromatic polyamine. Polyamide can be used to brew polyimine. Further, in the substrate of S-Xuan et al., an appropriate pretreatment such as drug treatment, plasma treatment, ion plating, gas phase reaction method, or vacuum vapor deposition may be carried out as needed. When the radiation-sensitive coloring composition is applied to a substrate, an appropriate coating method such as a spray method, a roll coating method, a spin coating method, or a slit die coating method is used, and in particular, spin coating: slit die coating is employed. The law is better. The prebaking is usually carried out by drying under reduced pressure and heating and drying. Drying under reduced pressure is usually carried out to 50 to 200 Pa. In addition, the heating element is usually carried out at about 70 to 11 Torr for about a minute. The coating thickness is usually from 1.2 to 5. 〇 y m, based on the film thickness after drying. And on the board. The three primary colors are formed by plating or steaming in various colors, and the composition is formed. This form. Glass, imine, or a ray that can be dried by plating or sputtering by a coating method or a coating method. 8.0 μm -48 - 201224064 liters> The radiation source used in the formation of a halogen and/or a black matrix can be enumerated. For example, xenon lamp, halogen lamp, tungsten lamp, high pressure mercury lamp, ultra high pressure mercury lamp 'metal element lamp, medium pressure mercury lamp, low pressure mercury lamp, etc. or argon ion laser, YAG laser, XeC1 excimer laser, nitrogen laser A dedicated laser source or the like is preferred, and radiation having a wavelength in the range of 19 〇 to 450 nm is preferred. The exposure amount of the radiation is generally 1 〇 to l 〇, and 〇〇〇 j / m 2 is preferred. Further, the above-mentioned alkali imaging liquid is, for example, sodium carbonate, sodium hydroxide, potassium hydroxide, tetradecylammonium hydroxide, choline, anthracene, 8-diazabicyclo-[5.4.0]-7-undecene. An aqueous solution of 1,5-diazabicyclo-[4 3 〇]_5_pinene or the like is preferred. In the above-mentioned alkali developing solution, a water-soluble organic solvent such as methanol or ethanol or a surfactant may be added in an appropriate amount. In addition, water washing is usually performed after the image is visualized. Baye imaging method The imaging method can be applied to shower imaging, dip imaging, paddle (development) imaging, and the like. The image forming end is preferably at room temperature for 5 to 300 seconds. The conditions for the post-baking are usually from about 1 to about eight at 120 to 280 ° C. From the viewpoint of the heat resistance of the coloring agent, the degree of post-bake is preferably 240 ° C or less. It is below 230 °C. The film thickness of the alizarin formed in this way is usually 05~ςΛ•).◦β m , preferably 1.0~3.0 M m ° In addition, the second method of manufacturing the ♦ color enamel sheet can be connected to the field • i? A method of obtaining various color halogens by inkjet method disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. In the method -49-201224064, firstly, a spacer having a shading function is formed on the surface of the substrate. Next, in the formed spacer, the blue color of the human coloring agent is composed, for example, by an inkjet device. After the liquid composition of the object is sprayed, it is prebaked to evaporate the solvent. Next, 'after the coating is necessary, it is hardened by post-baking to form a blue pixel pattern. Next, each of the green or red colored compositions is used in the same manner as described above on the same substrate. A green alizarin pattern and a ^-color pixel pattern are formed on the surface. Thereby, a color filter in which three primary color pixel patterns of red and green blue are arranged on the substrate can be obtained. However, the order in which the various color elements are formed in the present invention is not limited to the above. Further, the spacers not only have a light-shielding function, but also function to prevent color mixing of the coloring compositions sprayed in the zone, and the film thickness is thicker than that of the black matrix used in the first method. The spacer is usually a light source or a light source for forming a color filter using a black radiation-sensitive composition, and a method or a condition for prebaking or post-baking, which is the same as the first aspect described above. of. In this manner, the book formed by the ink jet method has a film thickness equal to the height of the spacer. On the pixel pattern obtained in this manner, a transparent conductive film is formed by sputtering after the protective film is formed. After the transparent conductive film is formed, spacers may be further formed, and the color filter spacers are usually formed by using a radiation-sensitive composition, but spacers (black spacers) having light-shielding properties can be formed. In this case, a radiation-sensitive coloring composition in which a black colorant is dispersed is used, and the coloring composition of the present invention can also be suitably used for the formation of the black spacer. There is a red light on the light and a -50- 201224064 under the law. In this way, the color purity is extremely high, which is useful for components and color sensors. The color of the present invention is obtained by a color liquid crystal display, an organic EL display element color light-emitting sheet, a luminance element, a color image tube, an electronic paper, etc., and the display element of the present invention is provided with the color filter of the present invention. . The display member may be a shirt color liquid crystal display element, an organic EL display element, or a color liquid crystal display element having the color filter of the present invention, and may be of a transmissive type or a reflective type, and may have a suitable structure. For example, the color filter may be formed on another substrate different from the driving substrate on which the thin film transistor (TFT) is disposed, and the substrate for driving and the substrate on which the color filter is formed may be opposed to each other via the liquid crystal layer. Further, a substrate in which a color filter is formed on a surface of a driving substrate on which a thin film transistor (TFT) is disposed and a substrate on which an ITO (tin-doped indium oxide) electrode is formed may be opposed to each other via a liquid crystal layer. Construction. The latter structure has an advantage that the aperture ratio can be further improved, and a bright and high-definition liquid crystal display element can be obtained. The color liquid crystal display element having the color filter of the present invention may further include a backlight unit using a white LED as a light source in addition to a cold cathode fluorescent lamp (CCFL: Cold Cathode Fluorescent Lamp). The white LED may, for example, be a white LED that is mixed by a combination of a red LED, a green LED, and a blue LED to obtain white light; a white LED that is mixed by a combination of a blue LED, a red LED, and a green phosphor to obtain white light. By combining a blue LED, a red illuminating phosphor and a green illuminating phosphor, a color of -51-201224064 is mixed to obtain a white LED of white light; a color mixture of a blue LED and a YAG-based phosphor is used to obtain a white color. Light white LED; a white LED that combines blue LED, orange illuminating phosphor and green illuminating phosphor to obtain white light; by combining ultraviolet LED, red luminescent phosphor, green luminescent fluorescent A white LED or the like that is mixed with a blue luminescent phosphor to obtain white light. The color liquid crystal display element having the color filter of the present invention can be suitably used as a TN (Twisted Nematic) type 'STN (Super Twisted Nematic) type, IPS (In-Planes Switching) type 'VA (Vertical)

Alignment)型、 OCB(OpticaUy Compensated Birefringence)型等適當的液晶模式。另外’具備本發明之彩色濾光片的有機EL顯示元件可採用適當的構造’可列舉例如日本特開平Η-307242號公報所揭示的構造。另外，具備本發明之彩色濾光片的電子紙可採用適當的構造’可列舉例如日本特開2007-41 169號公報所揭示的構造。 [實施例] 以下列舉實施例而進一步對本發明之實施形態作具體說明。但是本發明不受下述實施例所限定。 <本著色劑之合成及評估> 1 ·本著色劑之合成實施例1 -52- 201224064Suitable liquid crystal modes such as Alignment type and OCB (OpticaUy Compensated Birefringence) type. Further, the organic EL display element having the color filter of the present invention may have a suitable structure. For example, a structure disclosed in Japanese Laid-Open Patent Publication No. Hei-307242 can be cited. In addition, the electronic paper having the color filter of the present invention can adopt an appropriate structure. For example, the structure disclosed in Japanese Laid-Open Patent Publication No. 2007-41169 can be cited. [Examples] Hereinafter, embodiments of the present invention will be specifically described by way of examples. However, the invention is not limited by the following examples. <Synthesis and Evaluation of the Present Colorant> 1·Synthesis of the Present Colorant Example 1 -52- 201224064

在投入有攪拌子的附螺蓋管中，加入C.I.BasicBlue 7 1 _4g(2-72mmol)、間苯二磺酸二鉀（和光純藥公司製 )0.3 84g(1.36mmol)、氣仿2〇mL及水10mL，並在室溫授拌 7小時0 藉由將水層分離除去後，將有機層水洗2次，在減壓下進行濃縮，進一步使所得到的固體減壓乾燥，而得到藍黑色固體1.36g(產率84.0%)。將其定為化合物A。化合物A的1H-NMR(溶劑：重氫氣仿）光譜如以下所述，可確認為目標之化合物。 'H-NMR ： δ 9.05(brs, 1H), 8.73(s, 1H), 8.70(d, 1H), 8.01(d, 1H), 7.01-7.45(m, 9H), 6.67(d, 4H), 6.59(d, 1H), 3.65(q, 2H), 3.5〇(q, 8H), 2.42(brs, 1H), 1.41(t, 3H), 1.24(t, 12H) 實施例2 實施例1之中’除了使用3，3'-二硫代雙（1 -丙石黃酸）二 -53- 201224064 鈉（和光純藥公司製）代替間苯二磺酸二鉀以外，係以與實施例1同樣的方式合成出著色劑，藉由j-NMR(溶劑：重氫氯仿）測定，確認為目標之化合物。將其定為化合物 B。化合物B的1 Η - N M R光譜如以下所述。 ^-NMR： δ 8.81(brs, 1H), 8.61(d, 1H), 7.09-7.56(m, 7H), 6.69(d, 4H), 6.62(d, 1H), 3.69(q, 2H), 3.52(q, 8H), 2.97(t, 4H), 2, 81(t, 4H), 2.24(q, 4H), 1.42(t, 3H), 1.24(t, 12H) 實施例3 實施例1之中，除了使用C_I. Basic Blue 11(下述式所表示之三芳香基甲烧系染料）代替C.I_ Basic Blue 7以外’係以與實施例1同樣的方式合成出著色劑，藉由 i-NMR(溶劑：重氫氣仿）測定，確認為目標之化合物。CIBasicBlue 7 1 _4g (2-72 mmol), dipotassium meta-benzene disulfonate (manufactured by Wako Pure Chemical Industries, Ltd.) 0.3 84 g (1.36 mmol), and 2 mL of gas were added to the capped tube to which the stirrer was placed. 10 mL of water and 10 hours of stirring at room temperature. After separating and removing the aqueous layer, the organic layer was washed twice with water, concentrated under reduced pressure, and the obtained solid was dried under reduced pressure to give blue-black. 1.36 g of solid (yield 84.0%). This was designated as Compound A. The 1 H-NMR (solvent: heavy hydrogen) spectrum of the compound A can be confirmed as described below. 'H-NMR: δ 9.05 (brs, 1H), 8.73 (s, 1H), 8.70 (d, 1H), 8.01 (d, 1H), 7.01-7.45 (m, 9H), 6.67 (d, 4H), 6.59(d, 1H), 3.65(q, 2H), 3.5〇(q, 8H), 2.42(brs, 1H), 1.41(t, 3H), 1.24(t, 12H) Example 2 In Example 1 'In the same manner as in Example 1, except that 3,3'-dithiobis(1-propifluoric acid) bis-53-201224064 sodium (manufactured by Wako Pure Chemical Industries, Ltd.) was used instead of dipotassium isophthalate. In the manner of the coloring agent, the target compound was confirmed by j-NMR (solvent: heavy hydrogen chloroform). This was designated as Compound B. The 1 Η - N M R spectrum of Compound B is as follows. ^-NMR: δ 8.81 (brs, 1H), 8.61 (d, 1H), 7.09-7.56 (m, 7H), 6.69 (d, 4H), 6.62 (d, 1H), 3.69 (q, 2H), 3.52 (q, 8H), 2.97(t, 4H), 2, 81(t, 4H), 2.24(q, 4H), 1.42(t, 3H), 1.24(t, 12H) Example 3 In Example 1 In addition to the use of C_I. Basic Blue 11 (triaryl ketone dye represented by the following formula) instead of C.I_Basic Blue 7, a colorant was synthesized in the same manner as in Example 1, by i- The compound was confirmed to be the target compound by NMR (solvent: heavy hydrogen).

實施例4 實施例1之中’除了使用1，1，2,2,3,3-六氟丙烷-1，3-一續酸一鐘鹽（三菱材料公司製）代替間苯二磺酸二鉀以外’係以與實施例1同樣的方式合成出著色劑’藉由 H-NMR(溶劑：重氫氣仿）測定確認為目標之化合物。將其疋為化合物C。化合物C的1 H-NMR光譜如以下所述。 -54- 201224064 'H-NMR： δ 8.18(d, 2H), 7.89(brs, 4H), 7.15-7, 51(m, 16H), 6.90(d, 8H), 6.79(d, 2H), 3.62(q, 16H), 3.56(qs 4H), 1.43(t, 6H), 1.29(t, 24H) 實施例5 實施例1之中，除了使用C.I. BasicViolet 16(下述式所表示之次曱基系染料）代替C · I. B a s i c B1 u e 7以外’係以與實施例1同樣的方式合成出著色劑，藉由k-NMR) 溶劑：重氫氯仿）測定’確認為目標之化合物。Example 4 In Example 1, 'in addition to 1,1,2,2,3,3-hexafluoropropane-1,3-monosutraic acid salt (manufactured by Mitsubishi Materials Corporation) was used instead of m-benzenedisulfonic acid In addition to the potassium, a coloring agent was synthesized in the same manner as in Example 1 to confirm the target compound by H-NMR (solvent: heavy hydrogen imitation) measurement. It is decomposed into compound C. The 1 H-NMR spectrum of Compound C is as follows. -54- 201224064 'H-NMR: δ 8.18 (d, 2H), 7.89 (brs, 4H), 7.15-7, 51 (m, 16H), 6.90 (d, 8H), 6.79 (d, 2H), 3.62 (q, 16H), 3.56 (qs 4H), 1.43 (t, 6H), 1.29 (t, 24H) Example 5 In Example 1, except that CI BasicViolet 16 (the sub-base system represented by the following formula) was used. In the same manner as in Example 1, except that C.I.B asic B1 ue 7 was used, a coloring agent was synthesized in the same manner as in Example 1, and a compound identified as a target was determined by k-NMR solvent: dihydrochloroform.

實施例6 實施例1之中，除了使用C.I· Basic Blue 41 (下述式所表示之偶氮系染料）代替C. I. B a s i c B1 u e 7以外’係以與實施例1同樣的方式合成出著色劑，藉由W-NMR(溶劑 :重氫氣仿）測定’確認為目標之化合物。[Example 6] A coloring agent was synthesized in the same manner as in Example 1 except that CI·Basic Blue 41 (an azo dye represented by the following formula) was used instead of CI B asic B1 ue 7 in Example 1. The compound identified as the target was determined by W-NMR (solvent: heavy hydrogen imitation).

CH3 CH3OSO3 實施例7 . 實施例1之中，除了使用C.I. Basic Blue 3(下述式所表示之醌亞胺系染料）代替C.I. Basic Blue 7以外，係以與實施例1同樣的方式合成出著色劑，藉由1Η - N M R (溶劑 :重氫氣仿）測定，確認為目標之化合物。 -55- 201224064 <h5c2)2nCH3 CH3OSO3 Example 7 In Example 1, except that CI Basic Blue 3 (an imine dye represented by the following formula) was used instead of CI Basic Blue 7, coloration was synthesized in the same manner as in Example 1. The compound was confirmed to be the target compound by 1 Η-NMR (solvent: heavy hydrogen). -55- 201224064 <h5c2)2n

n(c2h5)2 實施例8 實施例1之中，除了使用C.I. Basic Blue 22(下述式所表示之蒽醌系染料）代替C.I. Basic Blue 7以外，係以與實施例1同樣的方式合成出著色劑，藉由1H-NMR(溶劑 :重氫氣仿）測定，確認為目標之化合物。 H\ /CH3 Ο Νn (c2h5) 2 Example 8 In Example 1, except that CI Basic Blue 22 (an anthraquinone dye represented by the following formula) was used instead of CI Basic Blue 7, it was synthesized in the same manner as in Example 1. The coloring agent was confirmed to be the target compound by 1H-NMR (solvent: heavy hydrogen imitation). H\ /CH3 Ο Ν

Η N(CH2)3N(CH3)3 Χ· 實施例9 實施例1之中，除了使用C.I. Basic Red 1 (下述式所表示之。山嗟系染料）代替C.I· Basic Blue 7、使用 1，1,2,2,3,3-六氟丙烷-1，3-二磺酸二鋰鹽代替間苯二磺酸二鉀以外，係以與實施例1同樣的方式合成出著色劑、藉由1 H-NMR(溶劑：重氫氣仿）測定，確認為目標之化合物。將其定為化合物D。Η N(CH2)3N(CH3)3 Χ· Example 9 In Example 1, except CI Basic Red 1 (the hawthorn dye represented by the following formula) was used instead of CI·Basic Blue 7, and 1, A coloring agent was synthesized in the same manner as in Example 1 except that 1,2,2,3,3-hexafluoropropane-1,3-disulfonic acid dilithium salt was used instead of dipotassium isophthalate. The target compound was confirmed by 1 H-NMR (solvent: heavy hydrogen imitation). This was designated as Compound D.

H5C2uk, λ ",,,λ2Η5 -56- 201224064 實施例1 ο 實施例1之中，除了使用C.I. Basic Yellow 21(下述式所表示之次曱基系染料）代替C.I. Basic Blue 7、使用 1,1,2,2,3,3-六氟丙烷-1,3-二磺酸二鋰鹽代替間苯二磺酸二鉀以外，係以與實施例1同樣的方式合成出著色劑、藉由1H-NMR(溶劑：重氫氣仿）測定，確認為目標之化合物。將其定為化合物E。H5C2uk, λ ",,, λ2Η5 -56- 201224064 Example 1 ο In Example 1, except that CI Basic Yellow 21 (the sub-base dye represented by the following formula) was used instead of CI Basic Blue 7, 1 was used. In the same manner as in Example 1, except that 1,2,2,3,3-hexafluoropropane-1,3-disulfonic acid dilithium salt was used instead of dipotassium isophthalate, a coloring agent was synthesized in the same manner as in Example 1. The target compound was confirmed by 1H-NMR (solvent: heavy hydrogen imitation). This was designated as Compound E.

比較合成例1 實施例1之中，除了使用對甲苯磺酸鈉（和光純藥公司製）代替間苯二磺酸二鉀以外，係以與實施例1同樣的方式合成出著色劑，藉由]Η-ΝΜΙΙ(溶劑：重氫氣仿）測定，確認為目標之化合物（上述化合物b之對曱苯磺酸鹽）。將其定為化合物F。比較合成例2 實施例1之中，除了使用深啡琳（bathophenanthroline) 二磺酸二鈉鹽（和光純藥公司製）代替間苯二續酸二鉀以外，係以與實施例1同樣的方式合成出著色劑，藉由 W-NMR(溶劑：重氫氣仿）測定，確認為下述式所表示之化合物。將其定為化合物G。 -57- 201224064Comparative Synthesis Example 1 In Example 1, a coloring agent was synthesized in the same manner as in Example 1 except that sodium p-toluenesulfonate (manufactured by Wako Pure Chemical Industries, Ltd.) was used instead of dipotassium isophthalate. Η-ΝΜΙΙ (solvent: heavy hydrogen imitation) was determined and identified as the target compound (p-toluenesulfonate of the above compound b). This was designated as Compound F. Comparative Synthesis Example 2 In the same manner as in Example 1, except that the use of bathophenanthroline disodium disulfonate (manufactured by Wako Pure Chemical Industries, Ltd.) was used in place of the dipotassium isophthalate. The coloring agent was synthesized, and it was confirmed by W-NMR (solvent: heavy hydrogen imitation) that it was a compound represented by the following formula. This was designated as Compound G. -57- 201224064

實施例1所得到的化合物A會溶於乳酸乙酯至1 〇質量 %以上’而此溶液呈藍色。實施例2〜1 〇所得到的著色劑任一者皆溶於乳酸乙酯至1 〇質量％以上。另外，實施例1〜1 0所得到的著色劑基於熱重量-示差熱同時測定分析測得的5 %質量減少溫度，任一者皆為 230 C 以上。另一方面，C.I. Basic Blue 7及 C.I. Basic Blue 1 1基於熱重量-示差熱同時測定分析測得的5%質量減少溫度’任一者皆未滿2〇〇°C。 <顏料分散液之調製> 調製例1 使用作為著色劑的C.I. Pigment Blue 15: 6 15質量份、作為分散劑的 BYK-LPN21116(Byk-Chemie(BYK)公司製）12.5質量份（固體含量濃度=40質量％)、作為溶劑的丙二醇單曱醚醋酸酯72.5質量份，藉由珠磨機處理，而調製出顏料分散液（A-1)。調製例2 除了使用 C_I. Pigment Violet 23 代替 C.I. Pigment Blue 1 5 : 6作為著色劑以外，係以與調製例丨同樣的方式調製出顏料分散液（A-2)。 -58- 201224064 調製例3 除了使用 C.I. Pigment Red 254 代替 C.I. Pigment Blue 1 5 : 6作為著色劑以外，係以與調製例i同樣的方式調製出顏料分散液（A-3)。調製例4 除了使用 C.I· Pigment Green 58 代替 C.I. Pigment Blue 1 5 : 6作為著色劑以外，係以與調製例1同樣的方式調製出顏料分散液（A-4)。調製例5 除了使用 C.I. Pigment Red 177 代替 C.I· Pigment Blue 1 5 : 6作為著色劑以外，係以與調製例1同樣的方式調製出顏料分散液（A-5)。調製例6 除了使用 C.I· Pigment Yellow 150 代替 C.I. PigmentThe compound A obtained in Example 1 was dissolved in ethyl lactate to 1% by mass or more and the solution was blue. In the examples 2 to 1, the obtained coloring agent was dissolved in ethyl lactate to 1% by mass or more. Further, the coloring agents obtained in Examples 1 to 10 were subjected to simultaneous measurement and analysis of the 5% mass reduction temperature by thermogravimetry-differential heat, and were either 230 C or more. On the other hand, C.I. Basic Blue 7 and C.I. Basic Blue 1 1 are based on the thermogravimetric-differential heat simultaneous measurement and analysis of the 5% mass reduction temperature' either of which is less than 2 °C. <Preparation of Pigment Dispersion> Preparation Example 1 CI Pigment Blue 15 as a colorant 15: 6 15 parts by mass, BYK-LPN21116 (manufactured by Byk-Chemie (BYK) Co., Ltd.) as a dispersing agent, 12.5 parts by mass (solid content) In the concentration = 40% by mass), 72.5 parts by mass of propylene glycol monoterpene ether acetate as a solvent was treated by a bead mill to prepare a pigment dispersion liquid (A-1). Preparation Example 2 A pigment dispersion liquid (A-2) was prepared in the same manner as in the preparation example except that C_I. Pigment Violet 23 was used instead of C.I. Pigment Blue 1 5:6 as a coloring agent. -58-201224064 Modulation Example 3 A pigment dispersion liquid (A-3) was prepared in the same manner as in Preparation Example i except that C.I. Pigment Red 254 was used instead of C.I. Pigment Blue 1 5:6 as a colorant. Preparation Example 4 A pigment dispersion liquid (A-4) was prepared in the same manner as in Preparation Example 1, except that C.I. Pigment Green 58 was used instead of C.I. Pigment Blue 1 5:6 as a colorant. Preparation Example 5 A pigment dispersion liquid (A-5) was prepared in the same manner as in Preparation Example 1, except that C.I. Pigment Red 177 was used instead of C.I. Pigment Blue 1 5:6 as a colorant. Modification Example 6 except C.I· Pigment Yellow 150 instead of C.I. Pigment

Blue 1 5 : 6作為著色劑以外，係以與調製例i同樣的方式調製出顏料分散液（A_6)。 <染料溶液之調製> 調製例7In the same manner as in Preparation Example i, Blue 1 5 : 6 was used as a coloring agent to prepare a pigment dispersion liquid (A_6). <Modulation of Dye Solution> Modulation Example 7

將作為著色劑的化合物A 5質量份、作為溶劑的丙二醇單甲鍵醋酸酯95質量份加以混合，而調製出染料溶液A 調製例85 parts by mass of the compound A as a coloring agent and 95 parts by mass of propylene glycol monomethyl acetate as a solvent were mixed to prepare a dye solution A.

將作.為著色劑的化合物B 5質量份、作為溶劑的丙二醇單甲鍵醋酸酯9 5質量份加以混合，而調製出染料溶液B -59- 201224064 調製例9 將作為著色劑的化合物C 5質量份、作為溶劑的乳酸乙S旨9 5質量份加以混合，而調製出染料溶液C。調製例1 0 將作為著色劑的化合物D 5質量份、作為溶劑的乳酸乙酯9 5質量份加以混合，而調製出染料溶液D。調製例1 1 將作為著色劑的化合物E 5質量份、作為溶劑的乳酸乙醋9 5質量份加以混合，而調製出染料溶液E。調製例1 2 將作為著色劑的化合物F 5質量份、作為溶劑的丙二醇單甲醚9 5質量份加以混合，而調製出染料溶液F。調製例1 3 將作為著色劑的化合物G 5質量份、作為溶劑的丙二醇單甲醚9 5質量份加以混合，而調製出染料溶液G。調製例1 4 將作為著色劑的C.I. Basic Blue 7 5質量份、作為溶劑的丙二醇單曱醚9 5質量份加以混合，而調製出染料溶液Η。 <黏結劑樹脂之合成> 在具備冷凝卻管與攪拌機的燒瓶中，裝入丙二醇單曱醚醋酸S旨1 0 0質量份，並且進行氮氣置換。加熱至8 0 °C，並在同溫度，花費1小時滴入丙二醇單曱醚醋酸酯100 質量份、曱基丙烯酸20質量份、苯乙烯10質量份、曱基丙烯酸苄酯5質量份、甲基丙烯酸2-羥乙酯1 5質量份、甲 -60- 201224064 基丙稀酸2-乙基己酯23質量份、N-苯基馬來醯亞胺12質量份、琥珀酸單（2-丙烯醯氧基乙基）15質量份及2,2，_偶氮雙（2,4-二甲基戊腈）6質量份之混合溶液，保持在此溫度5 parts by mass of the compound B as a coloring agent and 95 parts by mass of propylene glycol monomethyl carboxylate acetate as a solvent were mixed to prepare a dye solution B - 59 - 201224064. Preparation Example 9 Compound C 5 as a coloring agent The mass fraction and the lactic acid B as a solvent were mixed in a ratio of 95 parts by mass to prepare a dye solution C. Preparation Example 10 A dye solution D was prepared by mixing 5 parts by mass of the compound D as a colorant and 95 parts by mass of ethyl lactate as a solvent. Preparation Example 1 1 The dye solution E was prepared by mixing 5 parts by mass of the compound E as a colorant and 95 parts by mass of lactic acid ethyl acetate as a solvent. Preparation Example 1 2 The dye solution F was prepared by mixing 5 parts by mass of the compound F as a colorant and 95 parts by mass of propylene glycol monomethyl ether as a solvent. Preparation Example 1 3 A mass of the compound G as a colorant and 95 parts by mass of propylene glycol monomethyl ether as a solvent were mixed to prepare a dye solution G. Preparation Example 14 4 parts by mass of C.I. Basic Blue as a coloring agent and 95 parts by mass of propylene glycol monoterpene ether as a solvent were mixed to prepare a dye solution enthalpy. <Synthesis of a binder resin> In a flask equipped with a condenser and a stirrer, propylene glycol monoterpene ether acetate S was charged in an amount of 100 parts by mass, and nitrogen substitution was carried out. The mixture was heated to 80 ° C, and 100 parts by mass of propylene glycol monoterpene ether acetate, 20 parts by mass of methacrylic acid, 10 parts by mass of styrene, and 5 parts by mass of benzyl methacrylate were added dropwise at the same temperature for one hour. 15 parts by mass of 2-hydroxyethyl acrylate, 23 parts by mass of methyl 2-60-201224064 2-ethylhexyl acrylate, 12 parts by mass of N-phenylmaleimide, and succinic acid mono-(2- 15 parts by mass of propylene methoxyethyl) and 6 parts by mass of 2,2,-azobis(2,4-dimethylvaleronitrile), kept at this temperature

聚合2小時。然後，藉由使反應溶液的溫度昇溫至100°C ，進一步聚合1小時，而得到黏結劑樹脂溶液（固體含量濃度=33質量％)。所得到的黏結劑樹脂為M w = 1 2,2 0 0、Μ η = 6，5 0 0。將此黏結劑樹脂定為「黏結劑樹脂（Β丨）」。 <著色组成物之調製及評估> 實施例1 1 將顏料分散液（八_1)12.6質量份、染料溶液a 25 3質里份、作為黏結劑樹脂的黏結劑樹脂丨）溶液丨6」質量份、作為交聯劑的東亞合成股份有限公司製M_4〇2(二新戊四醇六丙烯酸酯與二新戊四醇五丙烯酸酯之混合物 )5.5豸里伤與二和化學股份有限公司製mw_3〇(n,n,n，， ni，n'’，n’|-六（甲氧基甲基）三聚氰胺為主成分、重量平均聚合度1.3)2.4質量份、作為光聚合起始劑的2_苄基_2_二甲基胺基-1-(4-味啉基笨基）丁小酮（〇如SpeciaUy Chemicals公司製，商品名IRGACURE369)2 2質量份、及作為溶劑的丙二醇單曱醚醋酸酯加以混合，而調製出固體3里濃度為20質量％之著色組成物（CR1)。使用旋轉塗布機將著色組成物（CR1)塗布在玻璃基板上之後，以80。(：的熱板進行〗〇分鐘預烘烤，而形成塗膜。藉由改變旋轉塗布機的轉速進行同樣的操作，形成膜厚相異的3牧塗膜。 -61 - 201224064 接下來，將該等基板冷卻至室溫之後，使用高壓水銀燈，不隔著光罩，以2,〇〇〇J/m2的曝光量對於各塗膜實施含有365nm、405nm及436nm各波長的放射線曝光。然後，藉由以顯像壓力1 kgf/cm2(噴嘴口徑1 mm)對該等基板喷灑由23 C的0.04質量。/0氫氧化鉀水溶液所構成的顯像液，進行90秒鐘淋浴顯像。然後在將此基板以超純水洗淨、風乾之後，進一步藉由在23(rc的無塵烘箱内進行後烘烤3 0分鐘，而形成評估用硬化膜。對於所得到的3牧硬化膜，使用色彩分析儀（大塚電子股份有限公司製MCPD2000)，以C光源、2度視野，測定CIE表色系中的色度座標值（x，y)及刺激值（γ卜另外，使用KLA-Tencor製的Alpha-Step IQ測定所得到的硬化膜之膜厚。由測定結果，求得在色度座標值y=0.0 8 0的色度座標值X、刺激值（γ)及膜厚。將評估結果揭示於表丨。刺激值（Y)愈大，表示光透過率（輝度）愈高，而膜厚愈薄，表示著色力愈高。將形成有硬化膜的之基板以兩枚偏光板夾住，以螢光燈（波長範圍380〜780nm)由背面側照射，同時使前面側的偏光板旋轉’藉由輝度計LS_100(Minolta股份有限公司製）’測定透過的光線強度的最大值與最小值。然後，將各個硬化膜的最大值除以最小值所得到的值定為對比。由測定結果，求得在色度座標值y = 〇〇8〇的對比。將評估結果揭示於表1。實施例1 2 將顏料分散液（Α-1)18·5質量份、染料溶液b 22 3質 -62- 201224064 量份、作為黏結劑樹脂的黏結劑樹脂（B1)溶液16」質量份、作為交聯劑的東亞合成股份有限公司製M_4〇2 5.5 量份與三和化學股份有限公司製MW 3〇 2.4質量份、作為光聚合^始劑的2_节基_2_二甲基胺基小（4_味琳基苯基）丁 1酮2.2貝$份、及作為溶劑的丙二醇單曱醚醋酸酯加以混合’而調製出固體含量濃度2〇質量％之 (CR2)。除了使用著色組成物（CR2)代替著色組成物（cri)以外係以與實施例i !同樣的方式進行評估。將評估結果揭示於表1。實施例1 3 旦將顏料分散液（Α-1)18·5質量份、染料溶液c 21 4質莖份、作為黏結劑樹脂的黏結劑樹脂(bi)溶液Μ」質量份m聯劑的東亞合成股份有限公司製m•術5 5質量份與三和化學股份有限公司tMW_3〇2 光聚合起始劑的2_节基_2_ -甲其脸I ^ 一甲基胺基-1-(4-咪啉基苯基）丁 -1-酮2.2質量份、及作為溶劑的乳酸乙醋加以混合，而調製出固體含量濃度2G質量％之著色組成物（CR3)。 / 了使用著色組成物（CR3)代替著色組成物（cri)以 :’係以與實施例U同樣的方式進行評估。將評估結果揭示於表1。實施例1 4 旦將顏料分散液（A-3)17.6質量份、染料溶液D比了質里份 '作為黏結劑樹脂的黏結劑樹脂（bi)溶&ΐ6ι質量份、作為交聯劑的東亞合成股份有限公司製—5.5質 •63- 201224064 量份與三和化學股份有限公司製Mw_3〇 2 4質量份、作為光聚合起始劑的2-节基-2·二曱基胺基_1(4咪啉基苯基）丁 -1-酮（Chiba Specialty (：“18公司製，商品名 IRGACURE3 69)2.2質量份、及作為溶劑的乳酸乙酯加以混合，而調製出固體含量濃度2〇質量％之著色組成物 (CR4)。除了使用著色組成物（CR4)代替著色組成物（CR1)以外，係以與實施例U同樣的方式進行評估。但是還求得此時在色度座私值x = 〇.650的色度座標值y、刺激值（γ)、膜厚及對比。將評估結果揭示於表1。實施例1 5 將顏料分散液（八-4)11_7質量份'染料溶液£ 46 9質里份、作為黏結劑樹脂的黏結劑樹脂（B丨）溶液丨6,丨質量份、作為交聯劑的東亞合成股份有限公司製M_4〇2 5 5質量份與三和化學股份有限公司製MW-30 2.4質量份 '作為光聚合起始劑的2-苄基-2-二曱基胺基_ι_(4_咮啉基苯基）丁 -1-酮（Chiba Specialty Chemicals 公司製，商品名 IKGACURE369)2.2質量份、及作為溶劑的乳酸乙酯加以混合，而調製出固體含量濃度20質量％之著色組成物 (CR5)。除了使用著色組成物（CR5)代替著色組成物（CR1)以外’係以與實施例1 1同樣的方式進行評估。但是還求得此時在色度座標值y = 0.590的色度座標值X、刺激值（γ)、膜厚及對比。將評估結果揭示於表1。 -64- 201224064 比較例1 將顏料分散液（A-DiS.i質量份、顏料分散液（A 2) 4· 5質里份、作為黏結劑樹脂的黏結劑樹脂（b 1)溶液1 6.1 質量份、作為交聯劑的東亞合成股份有限公司製m_4〇2 5·5質量份與三和化學股份有限公司製Mw_3〇 2 4質量份、作為光聚合起始劑的2_节基_2_二甲基胺基_1(4_咮啉基笨基)丁-1-酮2.2質量个分、及作為溶劑的丙二醇單曱醚醋醆酯加以混合’而調製出固體含量濃度2〇質量％之著色組成物（CR6)。除了使用著色組成物（CR6)代替著色組成物（cri)以外’係以與實施例U同樣的方式進行評估。將評估結果揭示於表1。比較例2 將顏料分散液（A -1) 1 8 1質晉曰 , ; 貞里份、染料溶液Η 24.2質量份、作為黏結劑樹脂的黏結劑树脂（Β1)溶液16.1質量份、作為交聯劑的東亞合成般份古 t 珉股伤有限公司製M-402 5.5質量伤與二和化學股份有限公司製 φ ^ ^ ^ „ · ^MW~3〇 2.4質量份、作為光聚合起始劑的2-苄基_2_二甲基】哲旦α '"胺基_1-(4-味啉基苯基）丁 -1 -¾ 2.2負量份、及作為溶劑 w入二神制，内—醇單甲醚醋酸醋加以，昆& ，而调I出固體含量濃 (eR7>。 20貝量0/〇之著色組成物除了使用著色組成物 ’係以與實施例1 1同樣示於表1。外揭 (CR7)代替著色組成物（CR1)以的方 A進行評估。將評估結果 -65- 201224064 比較例3 將顏料分散液（A_1)17 5質量份、染料溶液F 21 4質量伤、作為黏結劑樹脂的黏結劑樹脂（B1)溶液16.1質量份、作為交聯劑的東亞合成股份有限公司製M-402 5.5質罝份與二和化學股份有限公司製MW-30 2.4質量份、作為光聚合起始劑的2_苄基-2-二甲基胺基-1-(4-咪啉基苯基）丁 -1 -酮2.2質量份、及作為溶劑的丙二醇單甲醚醋酸酯加以混合’而調製出固體含量濃度20質量％之著色組成物 (CR8) 〇除了使用著色組成物（CR8)代替著色組成物（CR1)以外’係以與實施例1 1同樣的方式進行評估。將評估結果揭示於表1。比較例4 將顏料分散液（A-1)1 6.5質量份、染料溶液G 22.5質量伤、作為黏結劑樹脂的黏結劑樹脂（B丨）溶液i 6丨質量份、作為交聯劑的東亞合成股份有限公司製M_4〇2 5.5質量份與三和化學股份有限公司製MW-30 2.4質量份、作為光聚合起始劑的2_苄基-2-二甲基胺基-1-(4-咮啉基笨基）丁 -1-輞2.2質量份、及作為溶劑的丙二醇單甲醚醋酸酯加以混合，而調製出固體含量濃度2〇質量％之著色組成物 (CR9)。除了使用著色組成物（CR9)代替著色組成物（CR1)以外’係以與實施例11同樣的方式進行評估。將評估結果揭不於表1。 •66- 201224064 比較例5 將顏料分散液（A-3)15.6質量份、顏料分散液（A-5) 3.9質量份、作為黏結劑樹脂的黏結劑樹脂（B1)溶液丨6.1 質量份、作為交聯劑的東亞合成股份有限公司製M-402 5.5質量份與三和化學股份有限公司製mw-30 2.4質量份、作為光聚合起始劑的2-苄基-2-二甲基胺基-1 -(4·咮啉基苯基）丁 -1-酮（Chiba Specialty Chemicals公司製商品名 IRGACURE369)2.2質量份、及作為溶劑的丙二醇單甲鍵醋酸酯加以混合’而調製出固體含量濃度2〇質量％之著色組成物（CR10)。除了使用著色組成物（CR10)代替著色組成物（CR4) 以外’係以與實施例14同樣的方式進行評估。將評估結果揭不於表1。比較例6 將顏料分散液（Α-4)11·7質量份、顏料分散液（A-6) 7.8質量份、作為黏結劑樹脂的黏結劑樹脂（Β丨）溶液1 6· i 質量份、作為交聯劑的東亞合成股份有限公司製M-402 5.5質量份與三和化學股份有限公司製1^冒_3〇 24質量份、作為光聚合起始劑的2-苄基-2-二甲基胺基_M4_咮啉基苯基）丁-1-酮（ChibaSpecialtyChemicals公司製，商品名 IRGACURE369)2.2質量份、及作為溶劑的丙二醇單曱醚醋酸酯加以混合，而調製出固體含量濃度2〇質量％之著色組成物（CR1 1)。除了使用著色組成物（CRU)代替著色組成物（CR5) 以外，係以與實施例15同樣的方式進行評估。將評估結果揭不於表1。 -67- 201224064 [表l] 著色組成物著色劑 X y Y 膜厚 (μΐΏ) 對比實施例11 CR1 B 15:6/化合物A 0.140 0.080 9.45 2.0 15200 實施例12 CR2 B 15:6/化合物B 0.140 0.080 9.25 2.0 14400 實施例13 CR3 B15:6/化合物C 0.140 0.080 9.33 20 15800 實施例14 CR4 R254/化合物D 0.650 0.330 20.25 2.0 9500 實施例15 CR5 G58/化合物E 0.300 0.590 63.23 2.0 15200 比較例1 CR6 B15:6/V23 0.140 0.080 8.34 2.1 8900 比較例2 CR7 B15:6/BB-7 成為褪色而薄的焦褐色硬化月莫。比較例3 CR8 B 15:6/化合物F 0.140 0.080 7.54 2.0 14500 比較例4 CR9 B 15:6/化合物G 0.140 0.080 8.85 2.3 13200 比較例5 CR10 R254/R177 0.650 0.330 20.02 2.1 8900 比較例6 CR11 G58/Y150 0.300 0.590 60.21 2.1 8900 在表 1 之中，「B15: 6」意指 C.I. Pigment Blue 15 :6、「R2 54」意指 C.I. Pigment Red 254、「G5 8」意指 C.I. Pigment Green 58、「V23」意指 C.I. Pigment Violet 23、「BB-7」意指 C.I. Basic Blue 7、「R177」意指 C.I·Polymerization for 2 hours. Then, the temperature of the reaction solution was raised to 100 ° C, and further polymerization was carried out for 1 hour to obtain a binder resin solution (solid content concentration = 33% by mass). The resulting binder resin was M w = 1 2, 2 0 0, Μ η = 6, 5 0 0. This binder resin was defined as "adhesive resin (Β丨)". <Preparation and evaluation of coloring composition> Example 1 1 A pigment dispersion (8-1) 12.6 parts by mass, a dye solution a 25 3 parts by mass, a binder resin as a binder resin 丨) solution 丨 6 M_4〇2 (a mixture of dipentaerythritol hexaacrylate and dipentaerythritol pentaacrylate) manufactured by Toagosei Co., Ltd. as a crosslinking agent. 5.5豸里伤和二和化工股份有限公司Mw_3〇(n,n,n,,ni,n'',n'|-hexa(methoxymethyl)melamine as a main component, weight average degree of polymerization 1.3) 2.4 parts by mass, as a photopolymerization initiator 2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)butanone (for example, manufactured by Specia Uy Chemicals Co., Ltd., trade name IRGACURE 369) 2 parts by mass, and propylene glycol as a solvent The monoterpene ether acetate was mixed to prepare a coloring composition (CR1) having a solid concentration of 20% by mass. After the colored composition (CR1) was coated on the glass substrate using a spin coater, it was 80. (: The hot plate is pre-baked for a minute to form a coating film. The same operation is performed by changing the rotation speed of the spin coater to form a three-grain coating film having a different film thickness. -61 - 201224064 Next, After the substrate was cooled to room temperature, a high-pressure mercury lamp was used, and radiation exposures of respective wavelengths of 365 nm, 405 nm, and 436 nm were applied to the respective coating films at a exposure amount of 2, 〇〇〇J/m 2 without interposing a photomask. A developing solution composed of a 23 C 0.04 mass% aqueous solution of potassium hydroxide was sprayed on the substrates at a developing pressure of 1 kgf/cm 2 (nozzle diameter: 1 mm), and subjected to a shower for 90 seconds. After the substrate was washed with ultrapure water and air-dried, it was further post-baked in a 23 (rc dust-free oven for 30 minutes to form a cured film for evaluation. For the obtained 3 cured film, Using a color analyzer (MCPD2000 manufactured by Otsuka Electronics Co., Ltd.), the chromaticity coordinate value (x, y) and the stimulus value (γ) in the CIE color system were measured by C light source and 2 degree field of view. In addition, KLA-Tencor was used. The film thickness of the obtained cured film was measured by Alpha-Step IQ. As a result of the measurement, the chromaticity coordinate value X, the stimulation value (γ), and the film thickness at the chromaticity coordinate value y=0.0 8 0 were obtained. The evaluation results were revealed in the table. The larger the stimulation value (Y), the light transmission. The higher the ratio (luminance), the thinner the film thickness, and the higher the coloring power. The substrate on which the cured film is formed is sandwiched by two polarizing plates, and is irradiated by the back side with a fluorescent lamp (wavelength range 380 to 780 nm). At the same time, the polarizing plate on the front side is rotated 'by the luminance meter LS_100 (manufactured by Minolta Co., Ltd.)' to measure the maximum and minimum values of the transmitted light intensity. Then, the maximum value of each cured film is divided by the minimum value. The value was determined as a comparison. From the measurement results, a comparison was made between the chromaticity coordinate values y = 〇〇 8 。. The evaluation results are disclosed in Table 1. Example 1 2 Pigment Dispersion (Α-1) 18·5 Parts by mass, dye solution b 22 3 -62- 201224064 parts by weight, 16 parts by mass of a binder resin (B1) solution as a binder resin, and M_4〇2 5.5 parts by East Asia Synthetic Co., Ltd. as a crosslinking agent And MW 3 〇 2.4 parts by mass of Sanhe Chemical Co., Ltd. For the photopolymerization agent, 2_block base 2_dimethylamino small (4-terenyl phenyl) butanone 2.2 parts per liter, and propylene glycol monoterpene ether acetate as a solvent are mixed' Further, (CR2) having a solid content concentration of 2% by mass was prepared. The evaluation was carried out in the same manner as in Example i except that the coloring composition (CR2) was used instead of the coloring composition (cri). 1. Example 1 3: pigment dispersion (Α-1) 18·5 parts by mass, dye solution c 21 4 stem fraction, binder resin (bi) solution as binder resin 质量 mass part m Of the East Asia Synthetic Co., Ltd. m•5 5 parts by mass and Sanhe Chemical Co., Ltd. tMW_3〇2 photopolymerization initiator 2_segment base_2_-甲其脸 I ^-methylamino-1- 2.2 parts by mass of (4- morpholinylphenyl) butan-1-one and ethyl lactic acid as a solvent were mixed to prepare a colored composition (CR3) having a solid content concentration of 2 G% by mass. / The coloring composition (CR3) was used instead of the coloring composition (cri) to evaluate in the same manner as in Example U. The results of the evaluation are disclosed in Table 1. Example 1 4: 17.6 parts by mass of the pigment dispersion (A-3), and the dye solution D was dissolved as a binder resin (bi) as a binder resin, and 6 parts by mass as a crosslinking agent. Made in East Asia Synthetic Co., Ltd. - 5.5 Quality • 63 - 201224064 Parts and Mw_3〇2 4 parts by mass of Sanhe Chemical Co., Ltd., 2-mercapto-2·didecylamino group as photopolymerization initiator 1 (4 morpholinylphenyl) butan-1-one (Chiba Specialty ("18", trade name: IRGACURE 3 69) 2.2 parts by mass, and ethyl lactate as a solvent were mixed to prepare a solid content concentration of 2著% by mass of the coloring composition (CR4). The coloring composition (CR4) was used in the same manner as in Example U except that the coloring composition (CR1) was used instead of the coloring composition (CR1). Private value x = chromaticity coordinate value y, stimulating value (γ), film thickness and contrast of 〇.650. The evaluation results are disclosed in Table 1. Example 1 5 Pigment Dispersion (8-4) 11-7 parts by mass Dye solution £ 46 9 parts, as a binder resin, binder resin (B丨) solution 丨6, enamel M_4〇25 5 parts by mass of East Asia Synthetic Co., Ltd. as a crosslinking agent, and MW-30, 2.4 parts by mass of Sanwa Chemical Co., Ltd. as a photopolymerization initiator 2-benzyl-2- 2.2 parts by mass of dimercaptoamino group_ι_(4_ porphyrinylphenyl)butan-1-one (manufactured by Chiba Specialty Chemicals Co., Ltd., trade name: IKKACURE 369), and ethyl lactate as a solvent are mixed to prepare a solid. The coloring composition (CR5) having a content concentration of 20% by mass was evaluated in the same manner as in Example 1 except that the coloring composition (CR5) was used instead of the coloring composition (CR1). The chromaticity coordinate value X, the stimulus value (γ), the film thickness and the contrast of the chromaticity coordinate value y = 0.590. The evaluation results are disclosed in Table 1. -64- 201224064 Comparative Example 1 Pigment Dispersion (A-DiS.i Parts by mass, pigment dispersion (A 2) 4·5 parts by mass, binder resin (b 1) solution as binder resin 1 6.1 parts by mass, m_4〇2 5 manufactured by Toagosei Co., Ltd. as a crosslinking agent · 5 parts by mass and Mw_3〇2 4 parts by weight of Sanwa Chemical Co., Ltd. Polymerization initiator 2 - benzyl 2 - dimethylamino-1 (4 oxalinyl) butan-1-one 2.2 parts by mass, and as a solvent, propylene glycol monoterpene ether oxime ester The coloring composition (CR6) having a solid content concentration of 2% by mass was prepared by mixing. The evaluation was carried out in the same manner as in Example U except that the coloring composition (CR6) was used instead of the coloring composition (cri). The results of the evaluation are disclosed in Table 1. Comparative Example 2 A pigment dispersion liquid (A -1) was used as a cross-linking agent, and a dye solution (B2) was used as a binder resin (6.11) as a binder resin. East Asia Synthetic Co., Ltd. M-402 5.5 Quality Injury and Erhe Chemical Co., Ltd. φ ^ ^ ^ „ · ^MW~3〇 2.4 parts by mass, as a photopolymerization initiator 2-benzyl-2-dimethyl] Zhedan α '"Amino-1-(4-morpholinylphenyl)butane-1 -3⁄4 2.2 negative parts, and as a solvent w into the divine system, The inner-alcohol monomethyl ether acetate vinegar was added, and the solid content was concentrated (eR7>. The coloring composition of 20 ounces 0/〇 was used in the same manner as in Example 1). In Table 1, the external exposure (CR7) was evaluated in place of the coloring composition (CR1) by the square A. The evaluation result was -65-201224064 Comparative Example 3 The pigment dispersion liquid (A_1) 17 5 parts by mass, the dye solution F 21 4 Mass damage, 16.1 parts by mass of a binder resin (B1) solution as a binder resin, and M-402 5.5 as a crosslinking agent 2.4 parts by mass of MW-30, manufactured by Erhe Chemical Co., Ltd., as a photopolymerization initiator, 2-benzyl-2-dimethylamino-1-(4- morpholinylphenyl) butyl-1 - 2.2 parts by mass of a ketone and a propylene glycol monomethyl ether acetate as a solvent were mixed to prepare a coloring composition (CR8) having a solid content concentration of 20% by mass. In addition to using a coloring composition (CR8) instead of a coloring composition (CR1) The evaluation was carried out in the same manner as in Example 11. The evaluation results are disclosed in Table 1. Comparative Example 4 The pigment dispersion (A-1) was 6.5 parts by mass, and the dye solution G 22.5 was damaged as a bond. a binder resin (B丨) solution i 6 parts by mass of a resin, M_4〇2 5.5 parts by mass of East Asia Synthetic Co., Ltd. as a crosslinking agent, and 2.4 parts by mass of MW-30 manufactured by Sanwa Chemical Co., Ltd. 2.2 parts by mass of 2-benzyl-2-dimethylamino-1-(4-carbolinylphenyl)butan-1-one of the photopolymerization initiator, and propylene glycol monomethyl ether acetate as a solvent Mixing, and preparing a coloring composition (CR9) having a solid content concentration of 2% by mass. In addition to using a coloring composition The object (CR9) was evaluated in the same manner as in Example 11 except for the coloring composition (CR1). The evaluation results are not shown in Table 1. • 66-201224064 Comparative Example 5 Pigment Dispersion (A-3) 15.6 parts by mass, pigment dispersion (A-5) 3.9 parts by mass, a binder resin (B1) solution as a binder resin, 6.1 parts by mass, M-402, 5.5 parts by mass of East Asia Synthetic Co., Ltd. as a crosslinking agent 2.4 parts by mass of mw-30 manufactured by Sanwa Chemical Co., Ltd., 2-benzyl-2-dimethylamino-1 -(4.porphyrinylphenyl)butene-1- as photoinitiator 2.2 parts by mass of ketone (trade name: IRGACURE 369, manufactured by Chiba Specialty Chemicals Co., Ltd.) and propylene glycol monomethyl acetate as a solvent were mixed to prepare a coloring composition (CR10) having a solid content concentration of 2% by mass. The evaluation was carried out in the same manner as in Example 14 except that the coloring composition (CR10) was used instead of the coloring composition (CR4). The results of the evaluation will not be revealed in Table 1. Comparative Example 6 117 parts by mass of a pigment dispersion liquid (Α-4), 7.8 parts by mass of a pigment dispersion liquid (A-6), and a binder resin (Β丨) solution as a binder resin, 16 parts by mass, 5.5 parts by mass of M-402 manufactured by Toagosei Co., Ltd. as a crosslinking agent, and 24 parts by mass of Sanwa Chemical Co., Ltd., as a photopolymerization initiator, 2-benzyl-2-di 2.2 parts by mass of methylamino-M4_ porphyrinylphenyl)butan-1-one (trade name: IRGACURE 369, manufactured by Chiba Specialty Chemicals Co., Ltd.), and propylene glycol monoterpene ether acetate as a solvent were mixed to prepare a solid content concentration. 2% by mass of the colored composition (CR1 1). Evaluation was performed in the same manner as in Example 15 except that the coloring composition (CRU) was used instead of the coloring composition (CR5). The results of the evaluation will not be revealed in Table 1. -67- 201224064 [Table 1] Coloring composition colorant X y Y Film thickness (μΐΏ) Comparative Example 11 CR1 B 15:6/Compound A 0.140 0.080 9.45 2.0 15200 Example 12 CR2 B 15:6/Compound B 0.140 0.080 9.25 2.0 14400 Example 13 CR3 B15:6/Compound C 0.140 0.080 9.33 20 15800 Example 14 CR4 R254/Compound D 0.650 0.330 20.25 2.0 9500 Example 15 CR5 G58/Compound E 0.300 0.590 63.23 2.0 15200 Comparative Example 1 CR6 B15 :6/V23 0.140 0.080 8.34 2.1 8900 Comparative Example 2 CR7 B15:6/BB-7 becomes a faded and thin brownish hardened moon. Comparative Example 3 CR8 B 15:6/Compound F 0.140 0.080 7.54 2.0 14500 Comparative Example 4 CR9 B 15:6/Compound G 0.140 0.080 8.85 2.3 13200 Comparative Example 5 CR10 R254/R177 0.650 0.330 20.02 2.1 8900 Comparative Example 6 CR11 G58/ Y150 0.300 0.590 60.21 2.1 8900 In Table 1, “B15: 6” means CI Pigment Blue 15 :6, “R2 54” means CI Pigment Red 254, “G5 8” means CI Pigment Green 58, “V23 Means CI Pigment Violet 23, "BB-7" means CI Basic Blue 7, "R177" means CI·

Pigment Red 177、「Y150」意指 C.I. Pigment Yellow 150 o 【圖式簡單說明】無。【主要元件符號說明】無。 -68-Pigment Red 177, "Y150" means C.I. Pigment Yellow 150 o [Simplified illustration] None. [Main component symbol description] None. -68-

Claims

201224064 七、申請專利範圍： 1.一種鹼性著色劑’其係具有下述式（1)所表示之陰離子 R(-S〇3·)"⑴ [式U)之中，R表示1〜16個原子（但是氫原子除外）所構成之η價有機基，η表示2〜4之整數]。 2_如申請專利範圍第i項之鹼性著色劑，其中前述r為經取代或非經取代之非芳香族烴基、經取代或非經取代之複數個非芳香族烴基經由含雜原子的2價連結基所連結之基、經取代或非經取代之芳香族烴基、經取代或非經取代之2個芳香族烴基經由含雜原子的2價連結基或2價非芳香族烴基所連結之基、或經取代或非經取代之雜環基。 3.如申請專利範圍第1項之鹼性著色劑，其為三芳香基甲燒系著色劑、次甲基系著色劑、偶氮系著色劑、二芳香基甲烷系著色劑、醌亞胺系著色劑、蒽醌系著色劑、醜青素系著色劑或。山嗤（X a n t h e n e)系著色劑。 4 如申請專利範圍第2項之鹼性著色劑，其為三芳香基甲烧系著色劑、次曱基系著色劑、偶氮系著色劑、二芳香基曱烷系著色劑、醌亞胺系著色劑、蒽醌系著色劑、駄青素系著色劑或。山嗟系著色劑。 5·一種著色組成物，其係含有（A)著色劑、黏結劑樹脂及（C)交聯劑之著色組成物，其含有如申請專利範圍第1〜4項中任一項之著色劑作為（A)著色劑》 -69- 201224064 6. 如申請專利範圍第5項之著色組成物，其進一步含有 (D)光聚合起始劑。 7. —種彩色濾光片，其係具備含有如申請專利範圍第1〜 4項中任一項之鹼性著色劑的著色層而成。 8. —種顯示元件，其係具備如申請專利範圍第7項之彩色濾光片。 -70- 201224064 四、指定代表圖： (一）本案指定代表圖為：無。 (二）本代表圖之元件符號簡單說明: 無。五、本案若有化學式時，請揭示最能顯示發明特徵的化學式:201224064 VII. Patent application scope: 1. An alkaline coloring agent which has an anion R(-S〇3·)" (1) [Formula U) represented by the following formula (1), and R represents 1~ 16 atoms (except for hydrogen atoms) constitute an η-valent organic group, and η represents an integer of 2 to 4]. 2 - a basic colorant according to item i of the patent application, wherein the aforementioned r is a substituted or unsubstituted non-aromatic hydrocarbon group, a substituted or unsubstituted plural non-aromatic hydrocarbon group via a hetero atom-containing 2 a substituted, unsubstituted or substituted aromatic hydrocarbon group, a substituted or unsubstituted 2 aromatic hydrocarbon group bonded via a hetero atom-containing divalent linking group or a divalent non-aromatic hydrocarbon group a heterocyclic group, or a substituted or unsubstituted heterocyclic group. 3. The alkaline coloring agent according to claim 1, which is a triaryl carbaryl coloring agent, a methine coloring agent, an azo coloring agent, a diaryl methane coloring agent, a quinone imine A coloring agent, an anthraquinone coloring agent, an ugly pigment coloring agent or a coloring agent. Hawthorn (X a n t h e n e) is a coloring agent. 4 as an alkaline coloring agent of claim 2, which is a triaryl carbaryl coloring agent, a fluorene based coloring agent, an azo coloring agent, a diaryl decane coloring agent, a quinone imine A coloring agent, an anthraquinone coloring agent, an anthraquinone coloring agent or a coloring agent. Hawthorn coloring agent. A coloring composition comprising (A) a coloring agent, a binder resin, and (C) a coloring composition of a crosslinking agent, comprising the coloring agent according to any one of claims 1 to 4; (A) Colorant - 69-201224064 6. The colored composition of claim 5, which further contains (D) a photopolymerization initiator. A color filter comprising a colored layer containing an alkaline colorant according to any one of claims 1 to 4. 8. A display element comprising a color filter as in claim 7 of the patent application. -70- 201224064 IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the component symbols of this representative figure: None. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: