TW201215718A - Fiber highly cool to touch - Google Patents

Abstract

It is the object of the invention to provide a fiber excellent in cool contact feeling which is excellent in hand and skin touch and capable of preventing unpleasant feeling in the wet state and a woven fabric, clothing, and underwear excellent in cool contact feeling and obtainable by using the fiber excellent in cool contact feeling. The invention is a fiber excellent in cool contact feeling, which contains a thermoplastic elastomer and an inorganic filler.

Description

201215718 六、發明說明： 【發明所屬之技術領域】 本發明，係關於可防止濕潤時之不適感、且手感及肌 膚觸感優異之具優異接觸涼感之纖維、以及使用該具優異 接觸涼感之纖維所構成之具優異接觸涼感之布料、衣料及 貼身衣物。 【先前技術】 近H作為夏季用之貼身衣物’正研究-種使用在 穿著時可引發涼爽感、且主山 的纖維者。 了賦予一之具優異接觸涼感 製作此種具優異接觸涼感之纖維的方法，以往，係以 提昇纖維之吸水性、戋摇显嫌 ’、 次k昇纖維之熱傳導性的方法等來進 行。 心 使吸水性提昇之纖維，可舉例如，導人縣或經基等 親水性基之樹脂所構成之纖維等。 使熱傳導性提昇之纖維， +例如’混練有熱傳導性 问之填充物之樹脂所構成的纖 之纖料。 的4維、心表㈣有鍍敷處理 然而，使用此種纖維時，雖然理論上確實 侍接觸涼感，但實際對人進 了獲 疋1丁 S月b s式驗時，幾半盥土 者毫無差異，無法實際感到接觸涼感。 、处理201215718 VI. [Technical Field] The present invention relates to a fiber having excellent contact feeling coolness which is excellent in hand feeling and skin touch, which can prevent discomfort during wetness, and a fiber which has excellent contact feeling and cool feeling. It is composed of fabrics, clothing and underwear that have excellent contact with coolness. [Prior Art] Nearly H is a close-fitting clothing for the summer. It is a kind of fiber that is used in the main mountain when it is worn. A method of imparting excellent contact with coolness. The method of producing such a fiber having excellent contact with coolness has been conventionally carried out by a method of improving the water absorption of the fiber, shaking the fiber, and the thermal conductivity of the secondary k-liter fiber. The fiber which enhances the water absorption property of the heart, for example, a fiber composed of a resin of a hydrophilic group such as a human or a base. A fiber which is improved in thermal conductivity, for example, a fiber composed of a resin which is kneaded with a filler having thermal conductivity. The 4D, the heart table (4) has a plating treatment. However, when using this kind of fiber, although it is theoretically true to contact the cool feeling, the actual person has entered the 丁1丁 S month bs test. There is no difference, and you can't actually feel the touch of coolness. ,deal with

於專利文獻1揭示有—種I W 其係將内包有吸水性聚合物之；：:：冰感作用之纖維， 纖維中所構成。該纖維具有 …機粉末粒子保持於 有確實此實際感受之程度的接觸 3 201215718 涼感。然而，為了得到充分的接觸涼感，必須含有大量的 多孔質無機粉末粒子，其結果，會對手感及肌膚觸感造成 不良影響’而無法使用於貼身衣物。 專利文獻1 :日本特開2002-235278號公報。 【發明内容】 本發明之目的在於提供具優異接觸涼感之纖維、以及 使用5亥具優異接觸涼感之纖維所構成之具優異接觸涼感之 布料、衣料及貼身衣物，該具優異接觸涼感之纖維，可在 吕忐等級中實際感受到充分之接觸涼感，且手感及肌膚觸 感優異’非常適合用於貼身衣物等。 本發明，係含有熱可塑性彈性體及無機填充物之纖維。 以下’詳述本發明。 本發明人等，經致力研究之結果發現，當將埶可塑性 彈性體紡紗所得之纖維使用於衣料時，即會具優異接觸涼 感。然而，將含熱可塑性彈性體之纖維使用於衣料時’雖 會具優異接觸涼感，但當因汗等而使其濕潤時，即會變得 黏腻或使肌膚觸感蠻#，胜 β 網Μ 疋使用於貼身衣物等直接接 觸皮膚之衣料時會產生不適感， λ ,, 以而產生新的問題。因此， 專，經進-步致力研究之結果發現· 可塑性彈性體之纖維添加無機填充物，並使用：二… 即可防止滿潤時之不適感，且可 … 感，故特別適用於㈣衣物及肌膚觸 h m * 衣科，藉此完成本發明。 上述熱可塑性彈性體，並無 彈性體及/或聚醋系彈性體為佳。 但以聚酿胺系 201215718 §亥聚酿胺系彈性f， J, ^ , ，並無特別限定，可舉例如聚醚嵌 詨醯胺共聚物、聚醚醯 笪π留描你β t物、聚酯醯胺共聚物等。該 專可早獨使用、亦可併用2種以上。 亥 S玄等聚醯胺系彈性體 T之市售者，可舉例如皮巴券 (Pebax)(阿珂瑪公司製、 見々 古離龍（Gril〇n)ELX、古齙备减 J ^ } ' ^ t, 魯醯胺（Grilamid)ELY (以上為艾 姆斯昭和電工公司製）、 x 戴阿米德（Daiamid)、貝斯達米梓 (Vestamid)(以上為大赛 只啊運木德 脊路-德固賽公司製）等。 該聚酯系彈性體，计& & 並…、特別限定，可舉例如聚醚酯共 聚物、聚醋酷共聚物等。 、 該等可單獨使用、亦可併用2独^ 該等聚酯系彈性體中之市 r . a . ^ 帀。者，可舉例如古利拉克斯 (大日本/由墨化學工辈公引制、 &、 & 菜A司製）、努陪蘭（帝人化成公司 (V/n (Hytrel)(東麗杜邦公司製）、並 ^ ； 9里馬羅尹（Primalloy)(三 菱化學公司製）等。 ”一 該等熱可塑性彈性體中， Γ連式（1)所表示之聚醚嵌 段醯胺共聚物，由於可得到賦予 傻兵接觸涼感之纖維、 紡紗性優異、及可得到比重輕而 月匕表作輕量布料、衣料、 貼身衣物之纖維，故特別佳。該等 号嵌段醯胺共聚物中 之市售者，可舉例如皮巴克斯（阿珂瑪公司们等。 201215718 【化學式1】 〇 Ο HO- II || PA—C—Ο—PE—〇- 式（1)中，ΡΑ表示聚醯胺' ΡΕ表示聚醚。 。。本發明之具優異接觸涼感之纖維所含之樹脂成分，雖 了單獨為該熱可塑性彈性體，但僅含熱可塑性彈性體作為 树月曰成分之纖維，一般而言，會有黏腻感且紡紗難以進行， 故亦可併用該熱可塑性彈性體以外之其他樹脂。 本發明之具優異接觸涼感之纖維，進一步含有無機填 藉由含有該無機填充物，來於纖維表面形成微小凹 凸而使纖維表面改質，故可防止為熱可塑性彈性體特性 之濕潤時㈣«，且可大幅提昇使詩衣料接觸皮膚 之肌膚觸感、或脫衣時之肌膚脫H再者，由於可減低 纖維的黏腻感’因此可改善製作原絲時之紡紗性。 此外，本發明之具優異接觸涼感之纖維，由於並非為 了賦予接觸涼感性，而是以防止濕潤時之黏腻感等為目的 \加無機填充物’因此不需添加大量的無機填充物，即 使使用於衣料等時，亦不會對手感及肌膚觸感產生不良影 。亥無機填充物，並無特別限定，可舉例如輕質碳酸鈣、 重質碳㈣等碳g請、錢鋇、㈣碳酸鎂等碳酸鎮、硫 s夂鈣、硫酸鋇、二氧化鈦、氧化鐵、氧化錫、氧化鈦、氧 201215718 化辞、氧化鎂、肥粒鐵粉末、硫化辞、碳酸鋅、氮化鋁、 氮化矽、锻光白、燒成矽藻土等矽藻土、矽酸鈣、矽酸鋁、 矽酸鎂、不定梨二氧化矽、非晶質合成二氧化矽、膠體二 氧化矽等二氧化矽、膠體氧化鋁、擬水鋁石、氫氧化鋁、 氣氣化鎖、乳化銘、氧化結水和物、辞销白、沸石、加水 埃洛石、黏土、水溶膠、鋁矽酸鹽、滑石（Talc)、葉蠟石 (Pyrophyllite)、皂石（saponite)、鋰膨潤石（Hectorite)、矽鈉 鋅铭石（sauconite)、石夕鎮石（stevensite)、蒙脫石 (Montmorillonite)、貝得石（Beideiiite)、綠高嶺石（nontr〇nite) 等膨潤石（Smectite)、蛭石（Vermiculite)、金雲母、黑雲母、 鐵鋰雲母、白雲母、鈉雲母、綠磷石、海綠石等雲母、柯 綠石（clinochlore)、鮞綠泥石（chamosite)、鎳綠泥石 (nimite)、|孟鋁綠泥石（pennantite)、鋁綠泥石（sud〇ite)、片 矽鋁石（donbassite)、綠脆雲母（ciintonite)、珍珠雲母、錳黝 簾石、葉蛇紋石、晰蛇紋石（Lizardite)、纖蛇紋石、美塞楝、 綠椎石、磁綠泥石（berthierine)、鐵蛇紋石、矽鎂鎳礦、高 嶺石（ka〇linite)、狄克石（dickite)、珍珠石（nacHte)、埃洛石 (halloySlte)等高嶺土、剝層高嶺土、燒成高嶺土、海泡石、 皮、’婁石絲狀銘英石、水铭英石、石夕鐵石、膠石夕結礦、活 性白土、膨潤土、絹雲母等礦物質顏料等。該等可單獨使 用、亦可併用2種以上。 該等之中，以氧化鈦、氧化鋅、硫酸鋇、二氧化 佳。 两 又’該無機填充物之形狀’並無特別限定，可舉例如 201215718 球狀、針狀、板狀等之定型物或非定型物。 該無機填充物之平均粒徑的 ,. , j T仏07权佳下限為0.20μηι、較佳 上限為3.〇〇pm。若未滿〇 ， ^ ^ ^ _ 钔對濕潤時之黏腻感等不 k感的改善效果不充分，而若超過3 〇〇 u 六扭眭^ 弋、义00^^，則會損及作為 衣料時之手感及肌膚觸感、或使纖維強度降低。 泫無機填充物之含量的較佳下限為2 ^量％、較佳上 限為3〇重量％。更佳上限為7重量％。若未滿2重量％， 則對濕潤時之黏腻感等不適感的改善效果不充>，而若超 過30重4%，則會使纖維的強度降低。又，亦會使纺紗性 變差。 本發明之具優異接觸涼感之纖維，可為僅由含上述熱 可塑性樹脂及無機填充物之纖維構成，亦可在不阻礙本發 明目的之範圍心使㈣其它纖維交織者，以改善肌膚觸 感等貼身衣物之必要條件。該其它纖維並無特別限定，可 舉例如尼龍6、尼们2等聚醯胺系樹脂等；聚醋、棉 '人 造絲等。 本發明之具優異接觸涼感之纖維，值之較佳下限 為 0.20J/sec/cm2。若 qmax 值未滿 〇 ，則 即使進行官能試驗，大半數的人皆不會感受到接觸涼感。 更佳下限為0.21J/sec/cm2、再更佳下限為〇22J/sec/ 又’本說明書中’ qmax值，係指於一定面積、一定質 量之熱板中蓄積既定之熱量’將其接觸於試樣表面後，所 蓄積之熱量立即往低溫側之試樣移動之熱流量的峰值。qmax 201215718 max 值，係可考量為模擬穿衣時被試樣奪去之體溫，可 值愈大則穿衣時被奪去之體溫愈大、接觸涼感愈高。 本發明之具優異接觸涼感之纖維，熱傳導率之較佳 限為lxio.3t/W.m2。熱傳導率亦可考 ^ . ^ ^ 亏量為對應接觸涼感 之重要參數之一。若熱傳導率未％ ΐχΐ〇-3。^心則即 使進行官能試驗，大多數的人皆不會感受到接觸涼感。 此外，本說明書中，熱傳導率，係於放置於試樣台上 之試樣上重疊熱板，測定使熱板之溫度穩定至既定溫度後 的熱損失速度，再根據下式（2)算出。 熱傳導率（W / cm / °C ) = w.D / a / △ τ U) W .熱流量（j / sec) D .試樣之厚度（crn) A:熱板面積（cm2) △ A :試樣台與熱板之溫度差（^ ) 本發明之具優異接觸涼感之纖維，濕潤滑動起始角度 之較佳下限為20。，較佳上限為25。。若未滿2〇。，則手感 及肌膚觸感變差，若超過25。，則使用於貼身衣物時肌膚脫 離性會降低。又，該濕潤滑動起始角度，係根據JIS p 8147 以傾斜法測定滑動起始角度，藉此求得。 本發明之具優異接觸涼感之纖維，濕潤抗滑值之較佳 下限為1.2 8CN/cm2、較佳上限為1.5 8 CN/cm2。若未滿 USCN/cm2,則手感及肌膚觸感變差，而若超過158 cn / cm2，則濕潤時之肌膚脫離性會降低。此外，該濕潤抗 201215718 滑值，係濕潤時之靜 斜法測定。靜料阻抗值，可根據爪！>8147以傾 本發明之具優異接觸涼感之纖維 性趙樹脂之勒部所構成，二部21!==彈 下亦稱為芯鞘型複合纖維）。 …/下者（以 樹脂Γ二ΓΓ接觸涼感之纖維，係使用該可染色之 軟性之熱可塑性彈性體，藉此涼感性、具優異柔 性彈性體的優接觸涼感性之熱可塑 的纖維。 …作成具有良好染色性之芯勒構造 ’熱可塑性彈性體’由於不具有用以進行染 斤而之又色位置，或雖具有受色位置但卻非常少，因此 難以使用酸性染料或陽離子染料進行染色。對於此等問 通，日本特開2003_247177號公報中，係有揭示一種使用分 散染料來對聚胺基甲酸自旨等熱可塑性彈性體進行染色的方 ^。又’亦有研究將受色位置導入熱可塑性彈性體系樹脂 來使其可染色之方法、藉由使熱可塑性彈性體系樹脂之 顆粒中3有無機系顏料並以原液染色來著色的方法、藉由 ；為…、可塑〖生彈性體系樹脂之聚醯胺系彈性體樹脂中混 合：醯胺系樹脂以使其可染色的方法等各種方法。然而， 不論藉由任一方法均無法充分解決此種染色之問題。 相對於此，使用該芯鞘型複合纖維進行染色時，染料， 201215718 2過含有熱可塑性彈性體（幾乎不具受色位置）的勒部，而 將3:染性樹脂之芯部染色。藉此，使用該芯稍型複合纖 維進行染色時’即使藉由酸性染料或陽離子染料等之染料 ，可進仃良好的染& ’與單獨使用熱可塑性彈性體的纖維 相比，可進一步發揮優異之染色性。 孩心鞘型硬合纖維’以於芯部含有可染.性樹脂為佳。 作為該可染性樹脂，只要係可染色、可作為纖維使用 :即可，並無特限定’可舉例如尼龍6、尼龍12等聚醯胺 系樹脂、PET、PBT、PTT等聚i㈣脂、其他人造絲、丙 稀醆等，之中’以聚醯胺系樹脂為佳。 用、亦可併用2種以上。 之 旦該芯勒型複合纖維，雖芯部中之該可染性樹脂之含 量’係依所使用之樹脂而不同’但較佳下限為5重量若 未滿5重量。/。，則有時會使染色性降低。 該芯鞘型複合纖維，除了可使芯部含有上述可毕性樹 脂外’亦可視需要使其含有各種添加劑。該添加劑並無特 別限定’可舉例如抗氧化劑、防腐劑、抗靜電劑、安定劑、 乳化防止齊卜消光劑、耐光劑、潤滑劑、香料、可塑劑、 界面活性劑、難燃劑等。 片 該芯勒型複合纖維，以於轉部含有該熱可塑性彈性體 及無機填充物為佳。 該芯鞘型複合纖維中，雖鞘部中 & 利。丨r炙s亥熱可塑性彈性體 之含量，係依所使用之樹脂而不同，但較佳下限為丨5重量 %。若未滿15重量。/。，則有時會使接觸涼感性降低。里 11 201215718 該芯鞘型複合纖維中，除了可使鞘部含有 無性體之外’亦可視需要使其含有各種添加劑。=塑性 並無特別限定’可舉例如抗氧化劑、防腐齊】、抗：觉加劑 安定劑、氧化防止齊卜消光劑、耐光劑、潤滑劑、香：、 可塑劑、界面活性劑 '難燃劑等。 胥抖、 該芯勒型複合纖維之形狀並無特別限定，例士 相對纖維之長邊方向垂直切斷時之截面形狀為圓开;者可： 亦可為橢圓等。又，亦可為具有該芯部與鞘部 ： 圓狀之同心芯勒型構造的纖維、亦可為具有該芯部斑勒:; 對纖維之長邊方向垂直切斷時存在有複數：:部的， 該芯勒型複合纖維中，該鞘部之厚度的較佳上： 2:7。若超過2。_，則在染色時染料難以通過勒部：使 木色性不充分。又，該鞘部之厚度的較佳下限A — 未滿2,，則鞘部過薄’而無法發揮接觸涼感效果。 當該芯朝型複合纖維，具有該芯部與勒部形成為同心 圓狀之同心芯勒型構造時，芯、部直徑與鞘部厚度 一 部/勒部）的較佳下限為5/2〇、較佳上限為Μ。： 未滿5/20,則勒部的比例A ’會使染色性不充分，而： 超過46/ 2，則接觸涼感及柔軟性會降低。 該芯勒型複合纖維，q_值之較佳下限為〇 i7j/sec 八’若w值未滿G m/seeAm2，則與㈣或尼龍 為同等級，即使進行官能試驗，纟半數的人皆不會感受到 接觸涼感。更佳下限為。.18J/sec/W、再更佳下限為 201215718 0 · 1 9 J / s e c / c m2 〇 。該芯2勒型複合纖維，熱傳導率之較佳下限為〇 9χ1〇·3 C(Wm。方熱傳導率未滿0.9xl(T3c>C/W.m2，則即使進 仃g月。式驗，大半數的人皆不會感受到接觸涼感。 f發明之具優異接觸涼感之纖維的製造方法，並無特 限疋例如，可使用藉由在製作含有熱可塑性彈性體及 f機填充物之樹脂顆粒後，使用所製得之樹脂顆粒進行炫 嘁紡紗來加以製作之方法等習知方法。 又，該㈣型複合纖維，例如，可將含有可染性樹脂、 熱可塑性彈性體及益键 、_ …、，真充物之樹脂顆粒投入複合紡紗裝 置，以熔融紡紗之方法等來製造。 n物本發2具優異接觸涼感之纖維，可作為針織物、梭 二不織布等之布料來使用。此種使用本發明之且優異 發明之… #成之具優異接觸涼感的布料，亦為本 優異接觸涼感之布料，可僅由本發明之具 之範圍内，與其它纖維交Γ以：可於不阻礙本發明目的 之必要條件。該其它纖唯並2 膚觸感等貼身衣物 藉由使用本發明之具二 之具優異接觸涼感之布 办感之纖維、或本發明 B* . ’成衣料，而可作杰处B* I*、月 時之不適感、且手感及肌膚 :作成此防止濕潤 觸涼感之衣料亦為本發明之一。優/、之衣料。該具優異接 13 201215718 本發明之具優異接觸涼感之衣料，由於含有熱可塑性 彈性體，因此在穿著時可引起清涼之涼感、而能賦予清涼 感。又’藉由含有無機填充物，而可在濕潤時無黏腻感， 肌膚觸感及手感亦優異，非常適用於貼身衣物。 本發明之具優異接觸涼感之衣料，可為整體皆使用具 優異接觸涼感之纖維者，但特別是雙面織構造之針織物所 構成之涼感優異之衣料’較佳為使用總紗圈數4 30〜70% =優。接觸办感之纖維所構成的紗圈、且具優異接觸涼 士：纖維所構成的紗圈僅配置於肌膚側者（以清 冰感衣料）。 月 本發月之具優異接觸涼感之衣料，係於雙面織構造 :·物所構成之衣料令，藉由使具優異接觸涼感之纖維 、之、/圈數的比例為_定範圍，並將此種具優異接觸 1::、隹所構成之紗圈僅配置於直接接觸肌膚之肌膚側 =可製成對因流汗過多所引起之不適感具有防止效果的 β ’係開發並提出各種作為在夏季或運動等Ζ 者之貼身衣物的高機能衣料，此種機能性衣料，4 出-㈣8旨#疏水性纖維所構成的衣I又 ，水性纖維併用棉以提高透氣性之方法；將二 網狀構诰十 町叩二構造f 、或以平編及經編的變化組織施以鹿皮編織， 號公:Γ性之方法亦探討中，於日本㈣勒-155 中，揭示有一種藉由在構成布之疏 者親水性化與榀妨*文 丨王纖，准表面 干物質來予以改質的布。然而，此種由疏水Patent Document 1 discloses that there is a type I W which is composed of a water-absorbing polymer;::: a fiber having an ice-sensing effect, and is composed of fibers. The fiber has a contact with the powder of the machine powder to maintain the degree of actual feeling 3 201215718 cool feeling. However, in order to obtain a sufficient contact cool feeling, it is necessary to contain a large amount of porous inorganic powder particles, and as a result, it may cause adverse effects on the feeling of the palm and the touch of the skin, and it cannot be used for the close-fitting clothes. Patent Document 1: Japanese Laid-Open Patent Publication No. 2002-235278. SUMMARY OF THE INVENTION An object of the present invention is to provide a fiber having excellent contact with a cool feeling, and a fabric, a clothing material and a close-fitting clothing which are excellent in contact with a cool feeling and which are excellent in contact with a cool feeling. In the Lv忐 grade, you can feel the full contact with the cool feeling, and the feel and the skin feel excellent. It is very suitable for close-fitting clothing. The present invention is a fiber containing a thermoplastic elastomer and an inorganic filler. The present invention is described in detail below. As a result of intensive research, the present inventors have found that when the fiber obtained by spinning the yttrium plastic elastomer is used for clothing, it has excellent contact feeling. However, when the fiber containing the thermoplastic elastomer is used in the clothing, it will have an excellent contact with the cool feeling, but when it is wetted by sweat or the like, it will become sticky or make the skin feel quite sensible. Μ 疋 It can cause discomfort when used in clothing that directly contacts the skin, such as close-fitting clothing, λ , to create new problems. Therefore, it is found that the fiber of the plastic elastomer is added with an inorganic filler, and the use of: two... can prevent discomfort during full run, and can be used for (4) clothing. And the skin touches hm* clothing, thereby completing the present invention. The above thermoplastic elastomer is preferably one having no elastomer and/or a polyester elastomer. However, the polyamine amine system 201215718 § hexameric amine-based elastic f, J, ^ , is not particularly limited, and examples thereof include a polyether-indoleamine copolymer, a polyether 醯笪 π, and a β t substance. Polyester phthalamide copolymer and the like. This product can be used alone or in combination of two or more. For example, the commercial product of the polyamine-based elastomer T of the sho, such as Pebax (made by the company, sees the Gil〇n ELX, the ancient 龅 减 J ^ } ' ^ t, Grilamid ELY (above Ames Showa Denko), x Daiamid, Vestamid (above for the contest only) The polyester-based elastomer, such as a polyetherester copolymer, a polyacetic acid copolymer, etc., may be used alone. It is also possible to use the same in the polyester elastomers of the above-mentioned polyester elastomers, for example, Gullax (Greater Japan / Ink Chemical Industry, &, &; Vegetable A system), Nusong Lan (V/n (Hytrel) (Dongli Dubang company), and ^; 9 Primalloy (Mitsubishi Chemical Co., Ltd.), etc." Among these thermoplastic elastomers, the polyether block phthalamide copolymer represented by the hydrazine type (1) is excellent in spinning properties and is available because it can provide a fiber which gives a cool feeling to the cool soldier. It is particularly preferred because it is light in weight and the moon is used as a fiber for lightweight fabrics, clothing, and body clothing. Commercially available ones of the equivalent block amide copolymers, such as Pibacs (Adama, etc.) 201215718 [Chemical Formula 1] 〇Ο HO- II || PA—C—Ο—PE—〇— In the formula (1), ΡΑ indicates that polyamine “ΡΕ” indicates a polyether. The invention has excellent contact with coolness. Although the resin component contained in the fiber is the thermoplastic elastomer alone, the thermoplastic elastomer alone contains the fiber of the sapphire component, and generally has a sticky feeling and the spinning is difficult to perform. Further, the resin other than the thermoplastic elastomer is used. The fiber having excellent contact cooling property of the present invention further contains an inorganic filler, and the inorganic filler is used to form fine irregularities on the surface of the fiber to modify the surface of the fiber, thereby preventing the fiber from being modified. It is the time when the thermoplastic elastomer is wet (4), and it can greatly improve the touch of the skin that touches the skin of the poetry clothing or the skin when it is undressed, because it can reduce the sticky feeling of the fiber. original In addition, the fiber having excellent contact with the cool feeling of the present invention is not intended to impart a cool feeling to the contact, but is intended to prevent stickiness during wetting, and to add an inorganic filler. Therefore, it is not necessary to add When a large amount of inorganic filler is used for clothing or the like, it does not adversely affect the feeling of the palm and the touch of the skin. The inorganic filler is not particularly limited, and examples thereof include carbon such as light calcium carbonate and heavy carbon (four). g, Qian Qian, (4) Carbonic acid such as magnesium carbonate, sulfur sulphide calcium, barium sulfate, titanium dioxide, iron oxide, tin oxide, titanium oxide, oxygen 201215718, magnesium oxide, ferrite powder, vulcanization, zinc carbonate , aluminum nitride, tantalum nitride, forged white, calcined diatomaceous earth, diatomaceous earth, calcium citrate, aluminum citrate, magnesium citrate, amorphous pear cerium oxide, amorphous synthetic cerium oxide, colloid Cerium dioxide and the like cerium oxide, colloidal alumina, boehmite, aluminum hydroxide, gasification lock, emulsification, oxidized water and matter, resignation white, zeolite, water-filled halloysite, clay, hydrosol , aluminosilicate, talc (Talc), pyrophyllite (Pyrophyllite), saponite, Hectorite, sauconite, stevensite, montmorillonite, beideiiite, green kaolin Non-trendite (Smectite), Vermiculite, phlogopite, biotite, iron-lithium mica, muscovite, sodium mica, chlorite, glauconite, etc. clinochlore ), chlorite (chamosite), nickel chlorite (nimite), montmorillonite (pennantite), aluminite chlorite (sud〇ite), bismuth aluminite (donbassite), green crisp mica ( Ciintonite), pearl mica, manganese zoisite, leaf serpentine, Lizardite, serpentine, meringue, smectite, berhierine, iron serpentine, strontium nickel ore , kaolinite (ka〇linite), dickite (dickite), perlite (nacHte), halloySlte, kaolin, delaminated kaolin, calcined kaolin, sepiolite, skin, 'silver filament Mingyingshi, Shuimingyingshi, Shixia Tieshi, Jiaoshixiding, activated clay, bentonite Mineral pigments such as sericite. These may be used singly or in combination of two or more. Among these, titanium oxide, zinc oxide, barium sulfate, and sulfur dioxide are preferred. The shape of the inorganic filler is not particularly limited, and examples thereof include a shaped object or a non-shaped object such as a 201215718 spherical shape, a needle shape, or a plate shape. The lower limit of the average particle diameter of the inorganic filler, . , j T 仏 07 is 0.20 μηι, and the upper limit is preferably 3. pm. If it is not full, ^ ^ ^ _ 钔 is not sufficient to improve the feeling of stickiness when wet, and if it exceeds 3 〇〇u, six twists, 义, 义 00^^, it will be damaged. The feel of the clothing and the touch of the skin, or the strength of the fiber is lowered. A preferred lower limit of the content of the inorganic filler is 2% by volume, preferably 30% by weight. A more preferable upper limit is 7% by weight. If it is less than 2% by weight, the effect of improving the feeling of discomfort such as stickiness during wetting is not sufficient, and if it exceeds 30% by 4%, the strength of the fiber is lowered. Moreover, the spinning property is also deteriorated. The fiber having excellent contact cooling feeling of the present invention may be composed only of fibers containing the above thermoplastic resin and inorganic filler, or may be used to improve the skin feel without interfering with the purpose of the present invention. Necessary conditions for intimate clothing. The other fibers are not particularly limited, and examples thereof include polyamine-based resins such as nylon 6, Nie 2, and the like; and polyester, cotton, and the like. The lower limit of the value of the fiber having excellent contact cooling feeling of the present invention is 0.20 J/sec/cm2. If the qmax value is not full, even if the fascia test is performed, most people will not feel the contact coolness. A lower limit is 0.21 J/sec/cm2, and a lower limit is 〇22 J/sec/. In the present specification, the term 'qmax' refers to the accumulation of a predetermined amount of heat in a certain area of a certain quality hot plate. Immediately after the surface of the sample, the accumulated heat is immediately transferred to the peak of the heat flux of the sample on the low temperature side. The qmax 201215718 max value can be considered as the temperature of the sample taken away from the sample during the dressing. The larger the value, the larger the body temperature and the higher the contact coolness when the clothes are taken. The fiber of the present invention having excellent contact cooling feeling preferably has a thermal conductivity of lxio.3t/W.m2. The thermal conductivity can also be tested as ^ ^ ^ ^ Deficit is one of the important parameters corresponding to the contact cooling sense. If the thermal conductivity is not % ΐχΐ〇-3. ^Xin, even if the fascia test is carried out, most people will not feel the contact feeling cool. Further, in the present specification, the thermal conductivity is obtained by superimposing a hot plate on a sample placed on a sample stage, and measuring the heat loss rate after the temperature of the hot plate is stabilized to a predetermined temperature, and calculating it according to the following formula (2). Thermal conductivity (W / cm / °C) = wD / a / △ τ U) W. Heat flow rate (j / sec) D. Thickness of sample (crn) A: Hot plate area (cm2) △ A: Sample Temperature difference between the table and the hot plate (^) The preferred lower limit of the wet sliding starting angle of the fiber having excellent contact cooling feeling of the present invention is 20. The upper limit is preferably 25. . If it is less than 2 inches. , the feel and the touch of the skin deteriorate, if it exceeds 25. , when used in close-fitting clothing, the skin dissociation will be reduced. Further, the wet sliding start angle was obtained by measuring the sliding start angle by the tilt method in accordance with JIS p 8147. The fiber of the present invention having a good contact cooling property preferably has a lower limit of wet skid resistance of 1.2 8 CN/cm 2 and a preferred upper limit of 1.5 8 CN/cm 2 . If it is less than USCN/cm2, the feel and skin feel deteriorate, and if it exceeds 158 cn / cm2, the skin detachment will be reduced when wet. In addition, the wetting resistance of 201215718 is measured by the static method when wet. Static material impedance value, according to the claw! > 8147 is composed of a fiber-like resin of the present invention having excellent contact with coolness, and the two parts 21!== are also referred to as core-sheath type composite fibers. .../the lower one (the resin which is contacted with the resin Γ ΓΓ , , , , , , , ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ ΓΓ It is difficult to use acid dyes or cationic dyes for dyeing because it does not have a color position for dyeing, or has a color-receiving position but is very small. Japanese Patent Application Laid-Open No. 2003-247177 discloses a method of dyeing a thermoplastic elastomer such as a polyaminocarboxylic acid using a disperse dye. a method of introducing a thermoplastic elastomer resin into a dyeable method, a method of coloring 3 particles of an inorganic inorganic pigment in a particle of a thermoplastic elastomer resin, and dyeing with a stock solution, by: a plastic elastomer system Various methods such as a method in which a guanamine-based resin is dyed by mixing a polyamine-based elastomer resin of a resin. However, either by any The problem of the dyeing cannot be sufficiently solved by the method. In contrast, when the core-sheath type composite fiber is used for dyeing, the dye, 201215718 2, has a part containing a thermoplastic elastomer (having almost no color receiving position), and 3 : Dyeing of the core of the dyeable resin. By using the core-type conjugate fiber for dyeing, 'even with a dye such as an acid dye or a cationic dye, it is possible to dye good & 'and use thermoplastic elasticity alone. Compared with the fiber of the body, the dyeing property can be further improved. The sheath-type hard fiber of the child is preferably a dyeable resin in the core. As the dyeable resin, it can be dyed as a fiber. Use: Yes, there is no particular limitation, for example, polyamine resin such as nylon 6, nylon 12, poly i (tetra) grease such as PET, PBT, PTT, other rayon, acrylonitrile, etc. The amine-based resin is preferably used in combination of two or more kinds. In the core-type composite fiber, the content of the dyeable resin in the core portion is different depending on the resin to be used, but the lower limit is preferred. 5 weights if less than 5 The weight of the core-sheath type composite fiber may be such that the core-sheath type composite fiber may contain various additives in addition to the above-mentioned bondable resin. The additive is not particularly limited. For example, an antioxidant, a preservative, an antistatic agent, a stabilizer, an emulsification preventing matting agent, a light stabilizer, a lubricant, a fragrance, a plasticizer, a surfactant, a flame retardant, etc. Preferably, the rotating portion contains the thermoplastic elastomer and the inorganic filler. In the core-sheath type composite fiber, the content of the elastomeric elastomer in the sheath portion is used. The resin is different, but the lower limit is preferably 5% by weight. If it is less than 15% by weight, the contact cooling property may be lowered. In the case of the core-sheath type composite fiber, the sheath portion may be removed. In addition to the inclusion of an anamorphic body, it may also contain various additives as needed. = plasticity is not particularly limited 'for example, antioxidants, antiseptic, etc.】, anti-adhesive stabilizers, oxidation-preventing matting agents, light stabilizers, lubricants, fragrances: plasticizers, surfactants Agents, etc. The shape of the core-type composite fiber is not particularly limited, and the cross-sectional shape of the sample when the longitudinal direction of the fiber is perpendicularly cut is rounded; the one may be an ellipse or the like. Further, it may be a fiber having the core portion and the sheath portion: a circular concentric core structure, or may have the core portion: when the longitudinal direction of the fiber is perpendicularly cut, there are plural numbers: In the core-type composite fiber, the thickness of the sheath portion is preferably 2:7. If it exceeds 2. _, the dye is difficult to pass through the dye at the time of dyeing: the wood color is insufficient. Further, the preferred lower limit A of the thickness of the sheath portion is less than 2, and the sheath portion is too thin to provide a contact cooling effect. When the core-oriented composite fiber has a concentric core structure in which the core portion and the portion are formed in a concentric shape, a preferred lower limit of the core portion diameter and the sheath portion thickness portion is 5/2. 〇, the upper limit is Μ. : When the ratio is less than 5/20, the ratio A ' of the portion will be insufficient, and if it exceeds 46/2, the contact feeling and softness will be lowered. The core-type conjugate fiber has a preferred lower limit of q_ value of 〇i7j/sec 八'. If the value of w is less than G m/seeAm2, it is the same grade as (4) or nylon, even if the functional test is performed, half of the people are Will not feel the touch of cool. A better lower limit is. .18J/sec/W, and the lower limit is 201215718 0 · 1 9 J / s e c / c m2 〇 . The preferred lower limit of the thermal conductivity of the core 2 type composite fiber is 〇9χ1〇·3 C (Wm. The square thermal conductivity is less than 0.9xl (T3c> C/W.m2, even if it enters the g month. Most of the people do not feel the feeling of contact with the cool. f The method for manufacturing the fiber with excellent contact and cool feeling is not limited. For example, a resin containing a thermoplastic elastomer and a filler can be used. After the granules, a conventional method such as a method of producing a squeezing spun yarn using the obtained resin granules, and the quaternary composite fiber, for example, may contain a dyeable resin, a thermoplastic elastomer, and a benefit bond. _ ..., the resin particles of the true filling are put into a composite spinning device, and are manufactured by a method of melt spinning, etc. n The object is a fiber having excellent contact with coolness, and can be used as a fabric for knitting, shuttle 2, and the like. The use of the invention and the excellent invention... The fabric having excellent contact coolness is also a fabric which is excellent in contact with coolness, and can be intertwined with other fibers only within the scope of the present invention to: Can not hinder the invention The other conditions are: the other fiber-like and the skin-feeling and the like can be made by using the fabric of the invention having the excellent contact cool feeling, or the B*. Jiejie B* I*, discomfort at the time of the month, and the feeling and skin: the fabric which is made to prevent the moist and cool feeling is also one of the inventions. The fabric of the superior/. The excellent material 13 201215718 The invention has excellent Because it contains a thermoplastic elastomer, it can give a cool and cool feeling when worn, and it can give a cool feeling. In addition, by containing an inorganic filler, it can be moisturized without stickiness, and the skin feels. And the hand feel is also excellent, and it is very suitable for the close-fitting clothing. The fabric having excellent contact with the cool feeling of the present invention can be used as a whole with a fiber having excellent contact feeling of coolness, but in particular, the knitted fabric of the double-woven structure is excellent in cool feeling. The cloth material 'preferably uses the total number of yarn loops 4 30 to 70% = excellent. The yarn loops formed by the fibers of the contact feeling, and the excellent contact with the shims: the yarn loops composed of the fibers are only disposed on the skin side (to clear ice Cloth material. The moon material has excellent contact with the cool feeling of the fabric, which is based on the double-sided weave structure: · The fabric material consists of the material, by making the ratio of the fiber with excellent contact with coolness, / the number of turns is _ Scope, and the yarn loop composed of the excellent contact 1::, 隹 is only placed on the side of the skin that directly contacts the skin = can be made into a β' system for preventing discomfort caused by excessive sweating It also proposes a variety of high-performance clothing materials for the close-fitting clothing of the summer or sports, such as functional fabrics, 4 out-(four)8-purpose #hydrophobic fibers, and water-based fibers to improve the breathability. Method; the two-network structure of the 诰 叩 叩 叩 构造 构造 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , It is revealed that there is a cloth which is modified by the hydrophilicity of the cloth and the material of the surface. However, this is made of hydrophobic

14 201215718 纖維構成之衣料’雖能有效地使所產生之熱發散，但當因 抓汗使肌冑或衣服濕潤時，㊉了因沾濕感所產生之不適感 以外 亦會因布料容易貼附於肌膚而產生難以行動之問 題。 相對於此’ s亥涼感衣料，當為由此種雙面織構造之針 ’我物構成日寺II由將具優異接觸涼感之纖維.所構成之紗圈 數的比例控制於 制於既疋㈣内，而可賦予穿著時之爽涼感覺 Μ月亦1，並可防止流汗時之濕潤感造成之不適感，或防 止肌膚脫離性惡化而使布料貼附於肌膚。又，藉由將具優 〃接觸Λ7、感之纖維所構成之紗圈僅配置於肌膚側，可使具 優異接觸涼感之纖維直接接觸肌膚，而製成具優異清i 感、接觸涼感的衣料。 ^“7、感衣料’具優異接觸涼感之纖維 ::的二佳下限為總紗圈數…較佳上限為 / 30/。則引起清涼感、接觸涼感之效果不 “ 超過70%，則在流汗時 而右 田女_n — s L j 1 U /占濕玖而感到不適，亦合 :布料谷易貼附於肌膚而難以行動。更佳下限為33%、； 佳上限為67%。 勹W/。、更 X，當該清涼感衣料之肌膚側僅由具 纖維所構成的紗圈構成時 、觸尽感之 ^ 慢吳接觸冰感之纖飨所諶士 之V圈比例的較佳下限為總紗圈數之财、冓成 7〇〇/。，而當肌膚側係由具優異 0 ，佳上限為 構成時’且優I接觸、Y 4、I之纖維與疏水性纖維 下限為30%、較佳上限為5〇%。 〜圈比例的較佳 '<〇% 15 20121571814 201215718 The fabric made of fiber's can effectively dissipate the heat generated, but when the tendon or clothes are wetted by sweating, it will be easy to attach due to the discomfort caused by the wet feeling. It is difficult to move on the skin. In contrast to this 's cool sensation material, when the needle is made of such a double-sided fabric, the composition of the Japanese temple II is controlled by the ratio of the number of yarn loops formed by the fiber having excellent contact with the cool feeling. (4) It can give the feeling of coolness when wearing it, and it can also prevent the discomfort caused by the moist feeling when sweating, or prevent the skin from deteriorating and make the cloth adhere to the skin. In addition, by placing the yarn loops made of the fibers that are in contact with the Λ7 and the sensation on the skin side, the fibers with excellent contact with the coolness can be directly contacted with the skin, and the fabric having excellent i-like feeling and cool contact can be obtained. . ^ "7, sensation material" fiber with excellent contact cooling:: The second lower limit is the total number of laps... The upper limit is / 30/. The effect of cooling and contact with cool is not "more than 70%, then When I sweat, I am a woman, _n — s L j 1 U / I feel uncomfortable when I am wet, and it is also suitable: Cloth is easy to stick to the skin and it is difficult to move. A better lower limit is 33%, and a good upper limit is 67%.勹W/. And more X, when the skin side of the cool sensation material is composed only of the yarn loop composed of fibers, the feeling of the touch is slow. The lower limit of the V-ring ratio of the gentleman who touches the ice sensation is the total The number of yarn loops is 〇〇成〇〇7〇〇/. When the skin side is composed of an excellent 0 and a good upper limit, the lower limit of the fiber and the hydrophobic fiber of the excellent I contact, Y 4 , I is 30%, and the upper limit is preferably 5 %. ~ circle ratio is better '<〇% 15 201215718

Qmax 又’該清涼感衣料中 值以 0.07J/m2/sec ，該具優異接觸涼感之纖維 以上為佳。 其 ，涼感衣料’以含有該熱可塑性彈性體及無機填充 ·.，。於該情形下，該含有熱可塑性彈性體之纖維中， 含有硬鏈段為聚醯胺12且軟鏈段為聚乙二醇之聚醢胺系彈 f生體A以及硬鏈段為聚醯胺12且軟鏈段為聚四曱二醇之 聚醯胺系彈性體B的混合樹脂之纖維，由於可賦予:優異 之接觸涼感，且吸放濕特性與擴散特性皆優異，因此較佳、。 又，該含有熱可塑性彈性體之纖維，較佳為聚醚嵌段 醯胺共聚物之皮巴克斯1014SA〇1 (阿托菲納日本公司製） 之含量為60重量％以上之纖維、多孔質化並於表面施有親 水化處理之纖維、於聚酯或尼龍等之合成纖維添加1〜$ 重1 %之氧化鈦等無機物以提高接觸涼感性的纖維等。 該清涼感衣料中，該具優異接觸涼感之纖維，當欲將 布料厚度儘可能作成較薄時，可適當地併用其他纖維。此 時’該具優異接觸涼感之纖維中該熱可·塑性彈性體含量之 較佳下限為5〇重量％。若未滿50重量％，則有時會無法 充分發揮接觸涼感。 該清涼感衣料中，該具優異接觸涼感之纖維所構成之 紗圈，以僅配置於肌膚側為佳。藉由此種配置，穿著該清 涼感衣料時，由於主要是具優異接觸涼感之纖維構成的紗 圈與肌膚接觸，因此可引起接觸涼感及清涼感，而藉由將 後述之疏水性纖維所構成之紗圈配置於外側，可提昇皮膚 所產生之熱及水分之擴散性及蒸散性。 201215718 該清涼感衣料中，該具優異接觸涼感之纖維紗圈以外 之紗圈，以由疏水性纖維構成之紗圈為佳。 清冰感衣料中，如上所述，由於將具該優異接觸涼感 之纖維所構成之紗圈僅配置於肌膚側，因此疏水性纖維所 構成之紗圈，主要係配置於外側。藉此可促進汗的蒸散， 以良好效率使產生之熱發散。 本說明書中，所謂疏水性纖維，係指公定水分率為5 〇% 以下之化學纖維’具體而言，例如有由聚丙烯（公定水分 率.〇%)、聚酯（〇.4%)、丙烯酸樹脂（2.0%)、尼龍（4.5%)、 維尼龍（5.0%)等構成之纖維。該等可翠獨使用、亦 用2種以上。此外，公宏士八办 ^ 疋水刀率，係指於20〇C、65%RH下 之水分率。 視需要，倮其含有具優兵接 涼感之纖維 '疏水性纖維以外之纖維，例如由棉、麻等 成之天然纖維、或人谇蚊 &絲、乙酸酯等的半合成纖維。 圖1，係該清涼咸右# 级衣枓一例之示意圖。此Qmax is also a median value of 0.07 J/m2/sec for the cooling sensation, and it is preferred that the fiber has excellent contact with coolness. It is a cool feeling fabric containing the thermoplastic elastomer and inorganic filler. In this case, the fiber containing the thermoplastic elastomer contains a polyamine amine 12 having a hard segment of polyamine 12 and a soft segment of polyethylene glycol, and a hard segment of polycondensate. The fiber of the mixed resin of the amine 12 and the soft segment of the polyamidene-based elastomer B of the polytetramethylene glycol is preferable because it can provide excellent contact feeling and coolness, and is excellent in both moisture absorption and release properties and diffusion characteristics. . Further, the fiber containing the thermoplastic elastomer is preferably a fiber of a content of 60% by weight or more of Pibbax 1014SA〇1 (manufactured by Atofina Japan Co., Ltd.) of a polyether block phthalamide copolymer, and a porous material. A fiber having a hydrophilization treatment on the surface and an inorganic material such as titanium oxide having a weight of 1% by weight or more are added to a synthetic fiber such as polyester or nylon to improve the fiber which is in contact with coolness. In the cooling sensation material, the fiber having excellent contact with the cool feeling may be used in combination with other fibers when the thickness of the cloth is to be made as thin as possible. At this time, the preferred lower limit of the content of the heat-resistant plastic elastomer in the fiber having excellent contact cooling feeling is 5% by weight. If it is less than 50% by weight, the contact feeling may not be fully exerted. In the cooling sensation material, it is preferable that the yarn ring composed of the fiber having excellent contact with the cool feeling is disposed only on the skin side. With this configuration, when the cool sensation material is worn, the yarn loop composed mainly of fibers having excellent contact with the cool feeling is in contact with the skin, so that the contact feeling of coolness and the coolness can be caused, and the hydrophobic fiber is formed by the latter. The yarn loop is placed on the outside to enhance the heat and moisture diffusion and evapotranspiration of the skin. 201215718 In the cool sensation, it is preferable that the yarn loop other than the fiber loop having excellent cold contact is made of a hydrophobic fiber. In the ice-sensing fabric, as described above, since the yarn loops composed of the fibers having the excellent contact cooling feeling are disposed only on the skin side, the yarn loops composed of the hydrophobic fibers are mainly disposed on the outer side. Thereby, the evapotranspiration of the sweat can be promoted, and the generated heat is dissipated with good efficiency. In the present specification, the term "hydrophobic fiber" refers to a chemical fiber having a predetermined moisture content of 5% by weight or less. Specifically, for example, polypropylene (common moisture content: 〇%), polyester (〇. 4%), A fiber composed of an acrylic resin (2.0%), nylon (4.5%), vinylon (5.0%) or the like. These can be used alone or in combination of two or more. In addition, the Gonghongshi Office has a water rate of 20〇C and 65%RH. If necessary, it contains fibers other than hydrophobic fibers, such as natural fibers made of cotton or hemp, or semi-synthetic fibers such as silkworms and acetates. Fig. 1 is a schematic view showing an example of the cool and salty right-grade clothes. this

係從肌膚側觀看該清泞代少，_ M U 側為上、内側為下時之戴面圖。 ⑻係 如圖1所示，清涼感 ^ 纖維所編成之部分12、鱼’ ’係由具優異接觸涼感 構成，由具優異接觸斥感Γ水性纖維所編成之部分13 且具有互異之矩形部的 係線 感之纖維所編成之邹分12 /外’所5胃由具優異接觸 維構成之紗圈的部分，“係具有由具優異接觸涼感之 由疏水性纖維編成之部分1 3， %， 17 201215718 日u由具優異接觸涼感之纖維構成之紗圈、而 由疏水性纖維構成之紗圈的部分。 又由具優異接觸涼感之纖維編成之部分1 2，係僅两 置於肌㈣（下側），當穿著該清涼感衣料時，係主基 具優異接觸涼感之纖維所編成之部分12肖肌膚接觸之構 ^圖2係4清涼感衣料之另一例，圖2(a)，係由肌膚側 觀看時之俯視圖，圖2(b)，係外側為上 '内侧為下時之截 面圖。 如圖2所示，清涼感衣料21，係由具優異接觸涼感之 纖維所編成之部分22、與由疏水性纖維所編成之部分U所 冓成又由具優異接觸涼感之纖維所編成之部分2 2 ,係 僅配置於肌膚側（下側），當穿著該清涼感衣料時，係主 要為具優異接觸涼感之纖維所編成之部分22與肌膚接觸之 構成。 圖3，係顯示穿著該清涼感衣料時皮膚所散發之熱、水 蒸氣之流動的示意圖。 如圖3所示，皮膚所散發之熱、水蒸氣，首先通過由 具優異接觸涼感之纖維所編成之部分12，此時，藉由具優 異接觸涼感之纖維吸熱 '吸水。然後，無法藉由具優異接 觸涼感之纖維吸熱、吸水之熱及水分，藉由通過由疏水性 纖維所編成之部分13擴散後’散熱、蒸散至外部。又，圖 3中’僅圖示具有具優異接觸涼感之纖維所編成之部分、與 疏水性纖維所編成之部分兩部分之部位，而在僅由疏水性It is seen from the skin side that the 泞 M U side is the upper side and the inner side is the lower side. (8) As shown in Fig. 1, the part of the cooling sensation fiber 12, the fish '' is composed of an excellent contact cold feeling, and is made up of a portion of the hydrophobic fiber with excellent contact repulsion and has a rectangular portion. The line of the sensation of the fiber is made up of the Zoufen 12 / outside 'the 5 parts of the stomach made up of the excellent contact dimension," the part has a part made of hydrophobic fibers with excellent contact coolness. , 17 201215718 The part of the yarn loop composed of fibers with excellent contact with cool and the hydrophobic yarn. The part made of fibers with excellent contact with coolness is only placed in the muscle (4) (Bottom side), when wearing the cool feeling material, the part of the main base with excellent contact with the cool fiber is made up of 12 parts of the skin contact structure. Figure 2 is another example of the 4 cool feeling cloth, Figure 2 (a), The top view when viewed from the skin side, Figure 2(b), is the cross-section of the upper side when the inside is down. As shown in Figure 2, the cool sensation material 21 is made of fibers with excellent contact and coolness. Part 22, with part U made up of hydrophobic fibers The part 2 2 which is made up of fibers with excellent contact with coolness is only placed on the skin side (lower side). When wearing this cool sensation, it is mainly made up of fibers with excellent contact and coolness. Fig. 3 is a schematic view showing the flow of heat and water vapor emitted from the skin when the cooling sensation material is worn. As shown in Fig. 3, the heat and water vapor emitted from the skin are first passed through the device. The part 12 of the fiber which is excellent in contact with the cool feeling. At this time, the fiber absorbs heat by the fiber with excellent contact feeling coolness. Then, it cannot absorb heat, absorb heat and moisture by the fiber with excellent contact feeling coolness, and is passed through the hydrophobic The part 13 of the fiber is diffused and then 'heats and evades to the outside. In addition, in Fig. 3, only the part which is composed of the fiber having excellent contact coolness and the part which is composed of the hydrophobic fiber is shown. And only by hydrophobicity

18 201215718 纖維所編成之部分所構成之部位中，皮膚所散發之熱、水 蒸氣’係擴散後’散熱、蒸散至外部。 該清涼感衣料中，由於具有具優異接觸涼感之纖維所 編成之部分、與疏水性纖維所編成之部分兩部分之部位的 比例係在適當範圍内’因此穿著時可賦予涼爽感覺及清涼 感’並可防止流汗時之濕潤感造成之不適、及防止肌膚脫 離性惡化而使布料貼附於肌膚。 該清涼感衣料，透氣度之較佳下限為200cm3/ cm2/ sec、較佳上限為 500cm3/ cm2/sec。若未滿 200cm3/cm2 / sec，則透氣性差，會阻礙皮膚所發出熱之發散及汗的蒸 散，而若超出500cm3/cm2/sec，則熱或水分之移動，即 會透過衣料而無法充分進行，相反地可能會使外部氣體進 入0 此外’ s亥透氣度，可使用弗拉吉魯（Frazier )型透氣度 試驗機’依據JIS L 1 096 A法規定之方法來予以測定。 該清涼感衣料，目付之較佳下限為90g/ m2、較佳上限 為2〇Og/ m2。若未滿90g/ m2 ’則熱及水分難以移動，清 涼感效果降低，而若超過200g/ m2，則會因重量及熱傳達 阻抗增加，導致涼感性降低。 該雙面織構造之針織物’可使用圓型羅紋針織機，藉 由在編成紗圈時調整織針之量來製造。具體而十， /、 3，例如， 藉由以可編成紗圈（由具優異接觸涼感之纖維構成）之編 針數之30〜7〇%來編成的方法來製得。 本發明之具優異接觸涼感之衣料的製造方法， 並無特 'S- 19 201215718 別限定，例如，可使 進行編織、藉此來製作優異㈣涼感之纖維 τ衣枓之方法等習知方法。 又’該清涼感衣料，例， ^ ^ ^ 仰如可使用對以上述方式制用+ 又面織構造的針織物進行 1付之 丁键製、裁剪等習知方法來制4 使用本發明之且傷氣ia° 棬里拉酿 八優”接觸涼感之纖維、或本發明之且 優異接觸涼感之布料，即 一 接觸冷感優異之貼身六 物。又，本發明之具優異〜 、 又 物使用。 P钓貼身衣 明之 以此方式製得之接觸冷感優異之貼身衣物，亦為本發 〇 本發明之具優異接觸涼感之貼身衣物，由於含有埶可 塑性彈性體’因此在穿著時 > _ 亍』~起π办之沐感、而能賦予 清涼感° X ’藉由含有無機填充物，而可在濕潤時&黏腻 感，肌膚觸感及手感亦優異。本發明之具優異接觸涼感之 貼身衣物，由於係直接接觸肌膚因此可得到特別優異之效 果。 〃 藉由使用本發明之具優異接觸涼感之纖維、或本發明 之具優異接觸涼感之布料，而除了可製造本發明之具優異 接觸涼感之貼身衣物外，亦可製造長筒襪'手套、面罩、 圍巾4。由於§亥等係直接接觸肌膚’因此可得到特別優異 之效果。 根據本發明，可提供一種能防止濕潤時之不適感、且 手感及肌膚觸感優異之具優異接觸涼感之纖維、以及使用 該具優異接觸涼感之纖維構成之具優異接觸涼感之布料、 201215718 衣料及貼身衣物。 【實施方式】 以下’揭示實施例以更詳細說明本發明，但本發明並 不僅限於該等實施例。 (實施例1 ) 對熱可塑性聚醯胺系之聚醚嵌段醯胺共聚物（阿珂瑪 製，「皮巴可斯1041SA01」）98重量％，添加氧化鈦㈠界 化學工業公司製，「D918」，平均㈣0·2—”重量％ 後，進行熔融混合，使用造粒機製作樹脂顆粒。 其次，制製得之樹脂顆纟，以炼融 來製得原絲。 4 使用所得之原絲進行編織，製作布料。 (實施例2 ) 除聚醚嵌段醯胺丘平 /、祆物（阿珂瑪製，「皮巴可血 l〇41SA〇1」）的添加量為％重旦 皮巴T斯 公司製，「_」，平均粒"里。、：化鈦（得化學工業 〇/冰 办舍 二〇,26Pm)的添加量為4重晉 Λ外’與實施例1以同樣方式製作布料，重量 (實施例3 ) 除聚醚嵌段醯胺Α 為6重量 洲識」）的添加量為9：^/珂瑪製，「皮巴可斯 公司製，「D918」，平均物—里。、氧化鈦（蹲化學工業 %外，與實施例丨以同樣::〇’26_)的添加量 (實施例4) #方式製作布料。 對熱可塑性聚酯系彈 ”生體之聚㈣共聚物（東麗杜邦 21 201215718 司製海德雷魯8171」）98重量％，添加氧化欽（得 化學工業公司製，「D918」’平均粒# 〇2—) 2重量％ 後’使用造粒機進行熔融混合以製作樹脂顆粒。 '人使用製得之樹脂顆粒，以熔融紡紗法進行製絲 來製得原絲。 使用所得之原絲進行編織，製作布料。 (實施例5 ) 對熱可塑性聚醯胺系彈性體之聚鱗嵌段醯胺共聚物 瑪製，「皮巴可斯1〇41SA〇1」）Μ重量％，添加硫 業公司製，「㈣狀」，平均粒徑〇.3一 里。/。後’使用造粒機進行熔融混合以製作樹脂顆粒。 來製::絲使用製得之樹脂顆粒，融纺紗法進行製絲 使用所得之原絲進行編織，製作布料。 (實施例6) 對熱可塑性聚醯胺系彈性體之聚喊嵌段醯胺共聚物 (阿珂瑪製，「皮巴可斯1041Sa〇1 化粗/ 4 ) 9 8重量％，添加氧 鋅（壯化學總公司製’ 「微細鋅白 2舌旦 」’平均粒徑〇.3μηι ) 重量％後，使用造粒機進行熔融混合 ^ L 〇 U製作樹脂顆粒。 久’使用製付之樹脂顆粒，以，片_丄 來製得原絲。 “纺紗法進行製絲 使用所得之原絲進行編織，製作布料 (實施例7) 對熱可塑性聚醯胺系彈性體 篮之&越嵌段醯胺共聚物 22 201215718 (阿珂瑪製，「皮巴可斯1041SA01」）98重量％，添加二 虱化石夕粒子（德山公司製，「艾可斜力卡（ExceHca)sH_〇3」， :均粒程〇加）2重量％後’使用造粒機進行炫融混合以 製作樹脂顆粒。 來製彳=絲使用製得之樹脂顆粒’―進行製絲 使用所得之原絲進行編織，製作布料。 (實施例8 ) 對熱可塑性聚醯胺系彈性體之聚峻嵌 =:製：「皮巴可…〜7〇重量％，添加肥 刀 “一）3G重量％後，使用造粒機進 订炫一此合以製作樹脂顆粒。 其次’使用製得之樹脂顆粒， 來製得原絲。 每、紗法進行製絲 使用所得之原絲進行編織，製作布料。 (比較例1 ) 使用熱可塑性聚醯胺系彈性體 (阿河瑪製，「W咖， 段醢胺共聚物 J *7衣 反巴可斯1041SA01 ,)夕贴， 紗法進行製絲而勒〜s 」）之顆粒，以熔融紡 作布料。 彳原絲°使用所得之原絲進行編織，製 (評價） 對貫施例1〜8及比較例丨所製 進行評價。結果示於表卜斤“之布料，以下述方法 (1)濕潤滑動起始角度之測定 ·»·» 23 201215718 以傾斜法依據JIS P 8 147所規定之方法， “1疋滑動起始 秒、法碼： 之法码開始 具體而言，係傾斜台之上升速度：2〇/ 93.3 7g ’使傾斜台傾斜，測定安裝有濕潤試驗片 移動之瞬間的傾斜角度。 (2)濕潤抗滑值之測定 測定滑動起始 以傾斜法依據JIS P 8147所規定之方法， 角度。 具體而言’係傾斜台之上升速度：2。/心 /办、、法碼： 93.3 7g’使傾斜台傾斜，測定安裝有濕潤試 颂：月之法碼開始 移動之瞬間的靜摩擦阻抗值。 (3) qmax值之測定 於溫度設定為20.5〇C之試樣台上放置各布姐 、 I j 以才变 壓0.098N/cm2將加溫至32.5。(：之貯熱板重叠於布料上 後’測定所蓄積之熱量往低溫側試樣移動之熱量的峰值。 其測定之動作’係使用Thermolabo II型精密迅速熱物性測 定裝置（卡德科技公司製）來進行。 (4) 熱傳導率之測定 於溫度設定為20_5°C之試樣台上放置各布料，將熱板 以接觸壓0.059N/cm2重疊於布料上，再將熱板溫度調節成 3 2.5 C並使其穩定。使用Thermolabo II型精密迅速熱物性 測定裝置（卡德科技公司製），測定熱板溫度穩定至既定 溫度時之熱損失速度，並從該值測定熱傳導率。 (5) 紡紗性18 201215718 Among the parts made up of the fibers, the heat and water vapor emitted by the skin are diffused and then dissipated to the outside. In the cooling sensation material, the ratio of the portion prepared by the fiber having excellent contact cooling feeling to the portion of the portion in which the hydrophobic fiber is knitted is within an appropriate range, so that the feeling of cooling and the feeling of coolness can be imparted when worn. It can prevent the discomfort caused by the moist feeling when sweating, and prevent the skin from deteriorating and make the cloth adhere to the skin. The cooling sensitizing material preferably has a lower limit of air permeability of 200 cm 3 /cm 2 /sec and a preferred upper limit of 500 cm 3 /cm 2 /sec. If it is less than 200cm3/cm2 / sec, the gas permeability will be poor, and the heat generated by the skin will be inhibited and the sweat will be evaded. If it exceeds 500cm3/cm2/sec, the movement of heat or moisture will not be sufficient through the cloth. Conversely, the external gas may enter 0. In addition, the 'Shai's air permeability may be measured using the Frazier type air permeability tester according to the method specified in JIS L 1 096 A. The preferred lower limit of the refreshing coating material is 90 g/m2, and the preferred upper limit is 2 〇Og/m2. If it is less than 90g/m2', heat and moisture are difficult to move, and the cooling effect is lowered. If it exceeds 200g/m2, the weight and heat transmission impedance increase, resulting in a decrease in coolness. The knitted fabric of the double-woven structure can be manufactured by adjusting the amount of knitting needles when knitting a knitting ring using a circular rib knitting machine. Specifically, ten, /, 3 are produced, for example, by a method of knitting a yarn loop (composed of fibers having excellent contact cooling) by 30 to 7 %. The method for producing a fabric having an excellent contact with a cool feeling of the present invention is not limited to the above-mentioned method. For example, a conventional method such as a method of producing a fiber τ garment having excellent (four) cool feeling can be obtained by knitting. Further, the cooling sensation material, for example, can be produced by using a conventional method such as one-piece dicing, cutting, or the like for a knitted fabric having the above-described method and a double-woven structure. And the ia ° 棬 棬 酿 ” ” ” ” 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触P fishing body close-fitting clothing which is made in this way and which is excellent in contact with cold feeling, is also the body garment of the present invention which has excellent contact cold feeling, and therefore contains a plastic elastomer, so when worn, >亍 ~ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ The cool-feeled close-fitting clothing is particularly excellent because it is in direct contact with the skin. 除了 By using the fiber of the present invention having excellent contact with coolness, or the fabric of the present invention having excellent contact with coolness, In addition to the close-fitting clothing having excellent contact with the cool feeling of the present invention, it is also possible to manufacture the stockings 'gloves, masks, and scarves 4. Since § hai and the like directly contact the skin', a particularly excellent effect can be obtained. According to the present invention, a kind can be provided. A fiber which is excellent in contact feeling coolness, which is excellent in the feeling of discomfort during moisturization, and which is excellent in texture and touch, and a fabric which is excellent in contact with cool using the fiber having excellent contact with coolness, 201215718 clothing and underwear. The invention is described in more detail below, but the invention is not limited to the examples. (Example 1) Thermoplastic polyamine-based polyether block decylamine copolymer (Adam system) 98% by weight of "Pibakos 1041SA01", added with titanium oxide (1), "D918", and an average of (4) 0.2% by weight, and then melt-mixed, and granulator was used to produce resin pellets. The obtained resin pellets are obtained by smelting to obtain the strands. 4 The obtained strands are woven to produce a fabric. (Example 2) In addition to the polyether block 醯Chupin /, Zoroastrianism was (A Kema system, "Peabody can l〇41SA〇1 blood") to be added once the Peabody weight% T Adams Inc., "_", the average particle " inside. , Titanium (a chemical industry 〇 / 冰 舍 〇 26, 26Pm) was added in the same amount as in the case of Example 1 to make cloth in the same manner as in Example 1, weight (Example 3) except polyether block 醯The amount of amine Α is 6 weights.) The amount of addition is 9:^/ 珂 ,, "Pybaks company, "D918", average - 里. The amount of addition of titanium oxide (the same as in Example :::〇'26_) in the titanium oxide industry (Example 4) #制制制制. 98% by weight of a poly(tetra) copolymer of a thermoplastic polyester elastomer (Dongli Dubang 21 201215718 Sidd Hydra 8171), added Oxidation Chin ("D918"' average grain made by Chemical Industry Co., Ltd. 〇 2 -) 2% by weight after 'melting and mixing using a granulator to prepare resin pellets. 'The human used the obtained resin pellets and made the yarn by the melt spinning method to obtain the raw yarn. The resulting raw yarn is woven to produce a fabric. (Example 5) The polystyrene block amide copolymer of the thermoplastic polyamido-based elastomer was made of "Pibaks 1〇41SA〇1") Μ% by weight, added by the company of sulfur company, "(4) Shape, average particle size 〇.3 mile. /. Thereafter, melt mixing was carried out using a granulator to prepare resin pellets. To make:: Use the obtained resin pellets, and use the melt spinning method to make silk. Use the obtained raw yarn to weave and fabricate the fabric. (Example 6) Polyacrylic polyacrylamide-based elastomer-based poly-blocking phthalamide copolymer (made by Alchema, "Pibacs 1041Sa〇1 coarse/4" 98% by weight, added with zinc oxide (The "fine zinc white 2 tongue" manufactured by Zhuang Chemical Corporation, 'average particle size 〇.3μηι) % by weight, and then melt-mixed with a granulator to produce resin pellets. For a long time, the raw yarn was obtained by using the prepared resin pellets in the form of sheets. "Spinning method is carried out by weaving the raw yarn obtained by the spinning to produce a cloth (Example 7). For the thermoplastic polyamide-based elastomer basket, < Block amide copolymer 22 201215718 (made by Azuma, "Pybaks 1041SA01") 98% by weight, adding bismuth fossil granules (made by Tokuyama Co., Ltd., "Exce Hca sH_〇3", : averaging range) 2% by weight 'Use a granulator to perform a blending process to make resin pellets.彳 彳 = 树脂 使用 使用 使用 使用 丝 丝 丝 丝 丝 丝 丝 丝 ― ― ― ― ― ― ― ― ― ― ― (Example 8) For the thermoplastic polybenzamide-based elastomer, it was prepared by using a granulator and then adding a fertilizer knife to the weight of 3 g by weight. Hyun together to make resin pellets. Next, the obtained resin particles were used to obtain a raw yarn. The yarn is weighed by the yarn method, and the obtained raw yarn is used for weaving to produce a fabric. (Comparative Example 1) Using a thermoplastic polyamine-based elastomer (Ahema, "W-ca, segmental amine copolymer J*7-cloth anti-Baccos 1041SA01,"), the yarn method was used to make the yarn. The particles of ~s") are melt-spun into cloth. The raw silk was weaved using the obtained raw yarn, and the evaluation (manufactured) was carried out in accordance with the examples 1 to 8 and the comparative examples. The result is shown in the table of the cloth, in the following method (1) Determination of the wet sliding starting angle ·»·» 23 201215718 According to the method specified in JIS P 8 147 by the tilt method, "1疋 sliding start second, Method code: The law code starts to be specifically the rising speed of the tilting table: 2〇 / 93.3 7g 'The tilting table is tilted, and the tilt angle at the moment when the wet test piece is moved is measured. (2) Measurement of wet anti-slip value The slip initiation was measured by the tilt method according to the method specified in JIS P 8147, angle. Specifically, the rate of rise of the inclined table is 2. / Heart / Office, and code: 93.3 7g' Tilt the tilting table and measure the static friction resistance value at the moment when the month code starts to move. (3) Determination of qmax value Place each cloth and I j on the sample table with the temperature set at 20.5 °C to increase the pressure to 0.05 N/cm2 and heat to 32.5. (The heat storage plate is superimposed on the fabric, and the peak of the heat of the accumulated heat transferred to the low temperature side sample is measured. The action of the measurement is based on the Thermolabo II type rapid rapid thermal property measuring device (made by CardTech) (4) Measurement of thermal conductivity Place the fabric on the sample table with the temperature set at 20_5 °C, superimpose the hot plate on the fabric with a contact pressure of 0.059 N/cm2, and adjust the temperature of the hot plate to 3 2.5 C and stabilized it. The Thermolabo II type rapid rapid thermal property measuring device (manufactured by Kaide Technology Co., Ltd.) was used to measure the heat loss rate when the temperature of the hot plate was stabilized to a predetermined temperature, and the thermal conductivity was measured from the value. (5) Spinning

24 S 201215718 計算將用於實施例及比較例中所使用之樹脂顆粒財 24小時連續熔融紡紗時之擠壓步驟、延伸步驟、熱固定仃 驟中絲狀纖維的切斷次數，依據以下基準進行評價。疋步 ◎.絲狀纖維之切斷次數為〇次 〇：絲狀纖維之切斷次數為1〜3次 △:絲狀纖維之切斷次數為4次以上 (6)官能試驗 对1 ϋ名被試驗者 丨竹辦间义接觸涼感、 4滑過肌膚時布料之肌膚脫離性的官能試驗，依據 =準進行評價。又’ ◎之情形為3點、〇之情形為2 △之情形為1點、χ之情形A f) 4； j. 將其作為評價點。 點，求出1〇人之合計’ 好◎’冰爽、且乾燥時、濕潤時之布料的脫離性皆為良 〇=爽’但乾燥時、濕潤時之布料的脫離性普通 △.冰爽，但濕潤時之布料的脫離性差 χ :涼爽，但脫離性差24 S 201215718 Calculate the number of times the filamentary fibers are cut in the extrusion step, the stretching step, and the heat-fixing step when the resin pellets used in the examples and the comparative examples are continuously melt-spun for 24 hours, according to the following criteria. Conduct an evaluation.疋步◎. The number of cuts of filamentary fibers is 〇次〇: the number of cuts of filamentary fibers is 1~3 times △: the number of cuts of filamentary fibers is 4 or more (6) Functional test for 1 ϋ The subject's test was carried out by the tester, and the sensory test of the skin detachment of the fabric when sliding over the skin was evaluated according to the standard. The case of ' ◎ is 3 o'clock, the case where 〇 is 2 △ is 1 point, and the case of χ is A f) 4; j. It is used as an evaluation point. Point, find the total of 1 person's 'good ◎' icy, and the detachment of the fabric when it is dry and wet is good 〇 = cool 'but the detachment of the cloth when dry and wet △. , but the detachment of the fabric when wet: poor, but poorly detached

25 201215718 官能試驗 評價點 卜 1—Η CO OJ CD οα 卜 CO CO CO CO 1—^ 各被試驗者之評價 <] < 〇 〇 〇 〇 〇 ◎ <] 〇 ◎ ◎ <1 〇 〇 〇 ◎ 〇 <] 〇 〇 <1 0 <] <] 〇 X < <] ◎ 0 < <] <] ◎ <] ◎ ◎ ◎ 〇 〇 <3 0 〇 <] 〇 〇 〇 〇 〇 〇 〇 ◎ < <] 〇 〇 < <] <] <] 〇 <] <1 〇 ◎ <] <] 〇 〇 〇 < 〇 ◎ ◎ ◎ 〇 〇 〇 ◎ 〇 ◎ ◎ ◎ ◎ 〇 〇 〇 ◎ 〇 紡紗性 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 < 熱傳導率 (W/cm/°Cxl〇·3) —— 1.04 1.01 s P 1.03 1.08 0.99 ! 1.06 qmax 值 (J/s/cm2) °·215 0.210 0.206 0.211 0.203 0.211 0.214 0.220 0.212 濕潤阻抗值 (CN/cm2) __L52^ 1.52 1.40 1.52 00 in 1.52 1.46 1.28 1 | 1.75 滑動起始角度 (度） <N cn CN 〇〇 <N 實施例1 實施例2 實施例3 實施例4 實施例5 實施例6 實施例7 實施例8 比較例1 201215718 戈口表1所示，使用實施例 ^ m r, Λ- - ”丨机π〜方热塑性彈 體及無機填充物之原絲的布料， 古 〜7寸田於qmax值及熱傳導率 因此具優異接觸涼感，且因濕潤滑動阻抗值不會過高， 了知：為衣料使用時，其濕潤時之肌膚脫離性良好。 另方面，使用以比較例丨製造之原絲的布料，由於 Γ值^熱傳導率高’故具優異接觸涼感，但因濕濁滑動阻 ^差^ IB作為衣料使科其濕料之肌膚脫離性 (實施例9 ) 30]4Γ作為G'部用樹脂之聚醯胺樹脂的尼龍12(「UBESTA 、、θ練^于4興產公司製）85重量％、作為鞘部用樹脂之 Ο:有：化敛（「咖」’場化學工業公司製，平均粒徑 ΙίΜίΠο/重量％之聚喊嵌段醯胺共聚物（「皮巴可斯 」，Ρ可珂瑪製）1 5重量％，投入複合紡紗裝置， 以炫融紡紗法推γ制从 絲。 丁製，、，糸，製得直徑為50μηι之芯鞘型複合 面二定IS電子顯微鏡拍攝製得之芯勒型複合絲的截 州疋勒部厚度為2μιη。 使用製付之芯鞘型複合絲進行編織製得布料。 (實施例1 〇 ) 將作為怒25 201215718 Functional test evaluation point 1—Η CO OJ CD οα Bu CO CO CO CO 1—^ Evaluation of each subject<] < 〇〇〇〇〇◎ <] 〇◎ ◎ <1 〇〇 〇 ◎ 〇 <] 〇〇 <1 0 <] <] 〇X <<] ◎ 0 <<]<] ◎ <] ◎ ◎ ◎ 〇〇 <3 0 〇&lt ;] 〇〇〇〇〇〇〇◎ <<]〇〇<<><]<]〇<]<1 〇◎ <] <] 〇〇〇< 〇◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇〇 〇 〇 〇 性 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 < Thermal conductivity (W / cm / ° Cxl 〇 · 3) - 1.04 1.01 s P 1.03 1.08 0.99 ! 1.06 qmax value (J/s/cm2) °·215 0.210 0.206 0.211 0.203 0.211 0.214 0.220 0.212 Wetting resistance value (CN/cm2) __L52^ 1.52 1.40 1.52 00 in 1.52 1.46 1.28 1 | 1.75 Sliding starting angle (degrees <N cn CN 〇〇<N Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Comparative Example 1 201215718 Table 1 shows the use case ^ mr, Λ- - "" π ~ square thermoplastic elastomer and inorganic filler of the original silk fabric, ancient ~ 7 inch field in qmax value and thermal conductivity, therefore has excellent contact cooling, and the wet sliding resistance value will not It is too high, and it is known that when it is used as a clothing material, the skin is well detached when it is wet. On the other hand, the fabric of the original yarn produced by the comparative example is excellent in contact with the coolness due to the high value of the thermal conductivity of the original yarn. Because of the wet sliding resistance, IB is used as a clothing material to make the skin detachable of the wet material (Example 9). 30] 4ΓNylon 12 which is a polyamide resin of G' part resin ("UBESTA, θ练^ 85% by weight of the resin used in the company, and the resin used for the sheath part: There is a condensed block amide copolymer which is made by the "Chemical Industry Co., Ltd., average particle size ΙίΜίΠο/% by weight. ("Piakos", Ρ 珂 制)) 15% by weight, put into the composite spinning device, and push the γ-made yarn from the sleek spinning method. Ding,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The fabric is obtained by weaving using a core-sheath type composite yarn. (Example 1 〇) will be anger

树月曰之聚醢胺樹脂的尼龍12(「UBESTA «ί U 1 4 U」，宝 itR <eb 混練有氧化^ /產公司製）65重量％、作為勒部用樹脂之 〇26叫 「D918」’堺化學工業公司製，平均粒徑 量％之聚醚嵌段醯胺共聚物（「皮巴可斯 27 201215718 投入複合紡紗裝置， 5 0μιη之芯鞘型複合 1041SA01」’阿珂瑪製）35重量％， 以熔融紡紗法進行製絲，製得直徑為 絲0 此外，使用電子顯微鏡拍攝製得之㈣型複合絲的截 面’測定鞘部厚度為5μηι。 使用製得之芯勒型複合絲進行編織而製得布料。 (實施例1 1 ) 將作為芯部用樹脂之聚醯胺樹脂的尼龍12(「刪sta 3〇⑽」’宇部興產公司製）5G重量％、作為料用樹脂之 混練有氧化鈇（「觸」，堺化學工業公司製，平均粒徑 〇·26μιη) 5重量％之聚醚嵌段醯胺共聚物（「皮巴可斯 HMlSAOi」，阿珂瑪製）5〇重量％，投入複合紡紗裝置， 以熔融紡紗法進行製絲，製得直徑為5〇μιη之芯鞘型複合 絲0 此外，使用電子顯微鏡拍攝製得之芯鞘型複合絲的截 面’測定鞘部厚度為7μηι。 使用製得之芯鞘型複合絲進行編織而製得布料。 (實施例12 ) 將作為芯部用樹脂之聚醯胺樹脂的尼龍丨2 (「UBESTA 3014U」，宇部興產公司製）35重量％、作為勒部用樹脂之 混練有氧化鈦（「D918」，堺化學工業公司製，平均粒徑 〇·26 μιη) 5重量％之聚醚嵌段醯胺共聚物（「皮巴可斯 l〇4lSA01」，阿珂瑪製）μ重量％，投入複合紡紗裝置， 以熔融紡紗法進行製絲，製得直徑為5〇μιη之芯鞘型複合Nylon 12 ("UBESTA «ί U 1 4 U", bao itR < eb mixed oxidized product / manufactured by the company) 65% by weight of the glutamine resin of the tree 曰 曰 、 、 〇 26 D918"'s chemical industry company, the average particle size of the polyether block phthalamide copolymer ("Piakos 27 201215718 into the composite spinning device, 50 μιη core sheath type composite 1041SA01" 'Ama 35% by weight, which was produced by a melt spinning method to obtain a wire having a diameter of 0. Further, the cross section of the (four) type composite yarn obtained by using an electron microscope was measured to have a sheath thickness of 5 μm. The fabric is obtained by weaving using the obtained core-shaped composite yarn. (Example 1 1) Nylon 12 ("Sta 3" (10)" manufactured by Ube Industries, Ltd.), which is a polyamine resin for the core resin, was kneaded with 5 g% by weight as a material resin. Touch", 堺Chemical Industries, Inc., average particle size 〇·26μιη) 5% by weight of polyether block guanamine copolymer ("Pibbs HMlSAOi", manufactured by Azuma) 5 〇 wt%, put into composite spinning The yarn device was subjected to a melt spinning method to obtain a core-sheath type composite yarn having a diameter of 5 μm. Further, the cross section of the core-sheath type composite yarn obtained by using an electron microscope was measured to have a sheath thickness of 7 μm. The fabric was obtained by weaving using the obtained core-sheath type composite yarn. (Example 12) 35% by weight of nylon 丨2 ("UBESTA 3014U", manufactured by Ube Industries, Ltd.), which is a polyamide resin for the core resin, and titanium oxide ("D918") , 堺·Chemical Industry Co., Ltd., average particle size 〇·26 μιη) 5% by weight of polyether block decylamine copolymer ("Pibacos l〇4lSA01", manufactured by Azuma) μ% by weight, put into composite spinning Yarn device, which is made by melt spinning, and is made into a core-sheath type composite with a diameter of 5〇μηη.

28 S 201215718 絲。 此外，使用電子顯微鏡 只做硯拍攝製得之芯 面，測定勒部厚度為10_。 子夏。絲的截 使用製得之芯勒型福人絲 稠玉複0絲進行編織而製得布料。 (實施例1 3 )28 S 201215718 Silk. In addition, an electron microscope was used only for the core surface obtained by 砚 shooting, and the thickness of the portion was measured to be 10 mm. Child summer. The cut of the silk is made by using a core-shaped Fussian silk, and a thick jade complex yarn is woven to obtain a fabric. (Embodiment 1 3 )

將作為芯部用樹脂之聚醯胺樹㈣ 3014U」，宇部興產公司製） （刪STA ，'?站士— 垔置/〇、作為鞘部用樹脂之 混練有氧化鈦（「D91 8 , ，μ几姐 」土界化學工業公司製，平均粒徑 _ 5重里％之聚醚嵌段醯胺共聚物（「皮巴可斯 ，阿珂瑪製）95重量％，投入複合纺紗裝置， 以熔融紡紗法進行製絲，製得 丁且佐為50μιη之芯鞘型複人 絲0 〇 此外，使用電子顯微鏡拍攝製得之芯勒型複合絲 面’測定鞘部厚度為20μηι。 使用製得之芯勒型複合絲進行編織而製得布料。 以下，藉由實施例9〜13中製得之芯顆型複合絲所具 有之既定芯勒構造’係可製得染色性優異之布料，為了確 定這點，使用為本發明之具優異接觸涼感之纖維、但不且 有既定之芯勒構造之纖維所構成的布料，將其以實驗例表 不 〇 (貫驗例1 ) 使用混練有氧化鈦（Γ D918」’堺化學工業公司製， 平均粒徑0·26μη〇 5重量％之聚_嵌段醯胺共聚物（「皮巴 可斯1041SA01」，阿河瑪製），以炫融纺紗法進行製絲而 29 201215718 製得原絲。 使用所製得之原絲進行編織，製作布料。 (實驗例2) 將作為芯部用樹脂之聚醯胺樹脂的尼龍丨2 (「UbestA 3014U」，于部興產公司製）5重量〇/。'作為鞘部用樹脂之 混練有氧化鈦（「D918」，堺化學工業公司製，平均粒徑 〇.26μηι ) 5重量％之聚醚嵌段醯胺共聚物（「皮巴可斯 i〇41SA01」’阿珂瑪製）97重量％，投入複合纺紗裝置， 以熔融紡紗法進行製絲’製得直徑為50μηι之芯鞘型複合 此外，使用電子顯微鏡拍攝製得之芯鞠型複合 面，測定鞘部厚度為2〇μιη。 風 吏用製知之心勒型複合絲進行編織來製得布料。 (評價） 使用酸性染料（Nyl〇san，α Q y⑽日本科萊恩公司製）對f # 例9〜13及實驗例丨、2中 對實知 7所製侍之布料進行染色 述方法進行評價。結果示於表2。核订木色並以下 (1)染色性 對進行染色後之布料， 舫A ★站 5名被試驗者之目視蟬枰 較其之鮮明性。綜合 貝比 』网，、、，〇果M下述之4階段進 ◎:鮮明性與均一性非常佳 運仃砰彳貝。 〇：鮮明性佳 △:鮮明性不佳 201215718 (2) qmax值之測定 於溫度設定為20.5。(：之試樣台上放置各布料，以接觸 壓0.098N/cm2將加溫至32 5 t之貯熱板重疊於布料上 後，測定所蓄積之熱量往低溫側試樣移動之熱量的峰值。 其測定之動作，係使用Thermolabo II型精密迅速熱物性測 定裝置（卡德科技公司製）來進行。 (3) 熱傳導率之測定 於溫度設定為20.5°C之試樣台上放置各布料，將熱板 以接觸壓0.059N/ cm2重疊於布料上’再將熱板溫度調節成 32.5 C並使其穩定。使用ThermoUbo II型精密迅速熱物性 測定裝置（卡德科技公司製）’測定熱板溫度穩定至既定 溫度時之熱損失速度’並從該值測定熱傳導率。 【表2】 鞘部之厚度 ㈣ 染色性 Qinax 值 (J/s/cm2) 熱傳導率 (W/cm/°CxlO'3) 實施例9 2 ◎ 0.173 0.91 實施例1 0 5 ◎ 0.180 0.93 實施例1 1 10 ◎ 0.187 0.96 實施例1 2 15 〇 0.192 0.98 實施例1 3 20 〇 0-215 1.11 實驗例1 無芯部 X 0.256 1.29 賁驗例2 25 Δ 0.225 1.08 (實施例14 ) 將含有熱可塑性聚醯胺系彈性體之聚醚嵌段醯胺共聚 物（阿珂瑪製’ 「皮巴可斯1 04 1 S AO 1」）、與無機填充物 之氧化鈦（「D9 1 8」，堺化學工業公司製，平均粒徑〇 26μηι) 之具優異接觸涼感之纖維僅配置於肌膚側，將疏水性纖維 31 201215718 之聚酯纖維（旭化成公司製，鐵克農法因（Technofine))主 要配置於外側，以圓型羅紋針織機依據圖4所示之組織圖1 編織成雙面織構造的針織物，再使用其製造T恤。 所製得之T恤中，具優異接觸涼感之纖維所構成之紗 圈數係占總紗圈數的50%，而由疏水性纖維所構成之紗圈 數係占總紗圈數之5 0 %。又，T恤之外側，疏水性纖維所構 成之紗圈比例為1 00%，而肌膚侧，具優異接觸涼感之纖維 索構成之紗圈比例為1 〇〇%〇再者，所製得Τ恤之目付為丨84g / m2。 此外’所製得T恤之透氣度，係使用弗拉吉魯型透氣 度試驗機（山口科學產業公司製，textile air PERMEABILITY TESTER)，根據 Jis L 1096 A 法所規定之 方法進行測疋，結果為3 2 6 c m3 / c m 2 / s e c。 (實施例1 5 ) 使用含有熱可塑性聚醯胺系彈性體之聚醚嵌段醯胺共 聚物（阿珂瑪製，「皮巴可斯i 〇4丨s A〇丨」）、與無機填充 物之氧化鈦（「D918」，堺化學工業公司製，平均粒徑〇 26μηι) 之具優異接觸涼感之纖維’作為構成肌膚側之紗圈的纖 、准’並使用聚酯纖維（旭化成公司製’鐵克農法因 (Teehnofine))作為構成外側之紗圈的纖維，以圓型羅紋針 織機依據圖5所示之組織圖2編織成雙面織構造的針織 物’再使用其製造T恤。 所製得之T恤中，具優異接觸涼感之纖維構成之紗圈 數係占總紗圈數之33.3%，而由疏水性纖維構成之紗圈數係Polyamide tree (4) 3014U", which is made of a resin for the core, is manufactured by Ube Industries Co., Ltd. (Deleted STA, '? Stations - 垔 〇 / 〇, as a sheath resin, kneaded with titanium oxide ("D91 8 , , μ Sister, made by the soil chemical industry company, the average particle size _ 5 wt% of the polyether block guanamine copolymer ("Pibacos, made by Amadea" 95% by weight, put into the composite spinning device, The yarn was produced by the melt spinning method to obtain a core-sheath type multifilament yarn of 50 μm, and the core-shaped composite silk surface obtained by using an electron microscope was measured to have a sheath thickness of 20 μm. The core-shaped composite yarn is woven to obtain a fabric. Hereinafter, the fabric having excellent dyeability can be obtained by the predetermined core structure of the core-shaped composite yarn obtained in Examples 9 to 13. In order to determine this, a fabric comprising the fiber having excellent contact with the cool feeling of the present invention, but not having a predetermined core structure, is used as an experimental example (test example 1). Titanium oxide (Γ D918"'s chemical industry company, average The poly-block guanamine copolymer ("Pibaks 1041SA01", manufactured by Aheima) having a diameter of 0·26 μη〇5 wt% was produced by the dazzling spinning method and 29 201215718. The obtained raw yarn was woven to produce a fabric. (Experimental Example 2) Nylon 2 ("Ubest A 3014U", manufactured by Tosoh Corporation), which is a polyamide resin of a core resin, was used in an amount of 5 wt%. 'As a sheath resin, a titanium oxide ("D918", manufactured by Nippon Chemical Co., Ltd., average particle size 〇.26μηι) 5% by weight of a polyether block phthalamide copolymer ("Pibacos i〇41SA01" 97% by weight, manufactured by Achema, put into a composite spinning device, and manufactured by a melt spinning method to produce a core-sheath type composite having a diameter of 50 μm, and a core-shell type composite surface obtained by using an electron microscope. The thickness of the sheath portion was measured to be 2 〇 μιη. The fabric was obtained by weaving with a heart-shaped composite yarn of the known type. (Evaluation) Using an acid dye (Nyl〇san, α Q y (10) manufactured by Clariant, Japan) on f # In Examples 9 to 13 and Experimental Examples 2, 2, the fabrics of the servant 7 were made. The results of the dyeing method were evaluated. The results are shown in Table 2. The color of the wood color and the following (1) dyeing of the fabric after dyeing, 舫A ★ station 5 subjects were visually obscured. Babi's net,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The temperature was set to 20.5. (: The cloth was placed on the sample stage, and the heat storage plate heated to 32 5 t was superposed on the fabric at a contact pressure of 0.098 N/cm 2 , and the accumulated heat was measured to the low temperature side. The peak value of the heat of movement of the sample. The measurement was carried out using a Thermolabo II type rapid rapid thermal property measuring device (manufactured by Kaide Technology Co., Ltd.). (3) Measurement of thermal conductivity The fabric was placed on a sample stage set to a temperature of 20.5 ° C, and the hot plate was superposed on the fabric at a contact pressure of 0.059 N/cm 2 . Then the temperature of the hot plate was adjusted to 32.5 C and the temperature was adjusted to 32.5 C. stable. The ThermoUbo II type rapid rapid thermal property measuring apparatus (manufactured by Cardtech Co., Ltd.) was used to measure the heat loss rate when the hot plate temperature was stabilized to a predetermined temperature, and the thermal conductivity was measured from this value. [Table 2] Thickness of sheath portion (4) Dyeing Qinax value (J/s/cm2) Thermal conductivity (W/cm/°CxlO'3) Example 9 2 ◎ 0.173 0.91 Example 1 0 5 ◎ 0.180 0.93 Example 1 1 10 ◎ 0.187 0.96 Example 1 2 15 〇0.192 0.98 Example 1 3 20 〇0-215 1.11 Experimental Example 1 Coreless X 0.256 1.29 贲Test Example 2 25 Δ 0.225 1.08 (Example 14) Containing thermoplasticity Polyether block phthalamide copolymer of amide-based elastomer (Adama's "Pibacs 1 04 1 S AO 1"), and titanium oxide with inorganic filler ("D9 18", 堺Chem The fiber of the hydrophobic fiber 31 201215718 (made by Asahi Kasei Co., Ltd., Technofine) is mainly disposed on the outside. A circular rib knitting machine is woven into a knitted fabric of a double-sided woven structure according to the organization chart 1 shown in Fig. 4, and a T-shirt is manufactured using the same. In the T-shirts produced, the number of yarn loops composed of fibers having excellent contact cooling is 50% of the total number of loops, and the number of loops composed of hydrophobic fibers is 5 0 of the total number of loops. %. In addition, on the outer side of the T-shirt, the ratio of the loop of the hydrophobic fiber is 100%, and on the skin side, the ratio of the loop of the fiber with excellent contact with the coolness is 1 〇〇%. The price of the shirt is 丨84g / m2. In addition, the air permeability of the T-shirt was measured using a Fragil-type air permeability tester (textile air PERMEABILITY TESTER, manufactured by Yamaguchi Scientific Industries Co., Ltd.) according to the method specified in the Jis L 1096 A method. It is 3 2 6 c m3 / cm 2 / sec. (Example 1 5) A polyether block phthalamide copolymer containing a thermoplastic polyamine-based elastomer (manufactured by Alchema, "Pibbs i 〇 4 丨 A 〇丨"), and inorganic filler A titanium fiber ("D918", manufactured by Nippon Chemical Co., Ltd., average particle size 〇26μηι), which has excellent contact with the coolness of the fiber, is used as a fiber and a quasi-structure of the yarn ring on the skin side, and polyester fiber (made by Asahi Kasei Co., Ltd.) 'Teehnofine', as a fiber constituting the outer yarn loop, was knitted into a double-woven fabric knitted fabric by a circular rib knitting machine according to the texture chart 2 shown in Fig. 5, and a T-shirt was produced using the same. In the T-shirts produced, the number of yarn loops composed of fibers having excellent contact coolness is 33.3% of the total number of loops, and the number of loops composed of hydrophobic fibers is

32 201215718 占總紗圈數之66 7%。x，τ l . 又 T恤之外側，由疏水性纖維構成 之紗圈比例為1〇〇%，％ , 、 〇〇/。而肌膚側，由具優異接觸涼感之纖維 構成之/圈比例為5〇%、而由疏水性纖維構成之紗圈比例 為50%。再者，所製得τ恤之目付為mg/， 此外’以與實施例14同樣之方式測定所製得丁恤之透 氣度，其結果為397.6 。 (比較例2 ) 使用市售之表面經親水化的聚酯纖維（可爾麗製，索 菲斯塔）經編織而成網狀的τ恤（美津濃公司製）。 (比較例3 ) 使用以市售之棉以平編織成的T恤。 (評價） 對實施例14、15及比較例2、3所製得之τ恤，依以 下方法進行評價。 (1)人工氣候室之評價 假定為夏季早晨的步行，於28°Cx65%RH環境的人工 氣候室内，穿著實施例丨4及比較例2、3所製得之τ恤， 坐在椅子上安靜15分鐘後，在從正面承受風速為im/sec 的風之狀態下於跑步機步行3〇分鐘，測定其後3〇分鐘， 安靜坐在椅子座位上而恢復時衣服内溫度的變化、衣服内 濕度的變化、及氧攝取量。其結果示於圖6。 此外’測定係對健康之成人男性6名進行，而顯示其 平均值》 由圖6可知，穿著以實施例14所製造之τ恤時，與穿 33 201215718 著以比較例2'3所製造之”血時相較’可抑制衣服内溫度 及溼度的上昇。又’穿著以實施例14製造之τ恤時，與穿 著以比較例2、3製造之了恤時相較，步行中之氧攝取量亦 可抑制於較低。其原因，可考量為以實施例14製造之τ恤， ^以比較例2、3製造之了恤相較可帶來較舒適之衣服内環 境’因此可減輕運動負荷而以較少能量消耗。 (2)官能評價1 2004年7月於京都市内舉辦之家庭步行（京都府步行 協會主辦）活動中，穿著以實施例14及比較例2所製得之 Τ恤進行步行後，以平f穿著之了恤作為基準，以回答問卷 的形式進行官能評價。將該結果示於圖7。又，官能評價， 係對9名成人男性進行，而顯示其平均值。 又，對進行官能評價之2名男性亦進行直腸溫與衣服 内溫度之測定。其結果示於圖7。 匕由圖7可知，以實施例14製造之丁恤，於所有項目中 Π::平常穿…恤高的評價，特別是行動容易度及 ^ 性優異。另一方面，以比較例2製造之τ恤，在 吸汗性、出汗時之肌膚脫離性等各點上為不良評價。 例2^/在穿著以實施例14製造之1恤時，與穿著以比較 低之值造之Τ恤時相較’直腸溫度、衣服内溫度亦顯示較 (3)官能評價1 —於2004年11月，以運動部所屬之男性大學生穿著以 貫施例15及比較例2製得之τ恤進行跑步後，以平常穿著 201215718 之τ恤作為基準， 結果不於圖8。又， 而顯示其平均值。 採回答問卷的形彳％ / 幻办式進行官能評價。將該 官能評價，係對29名£喊士與Λ ώ ”石男性大學生進行， 由圖8可知，A L Μ .. 譽造之T t b …。；王部13項目中，以實施例15 恤…最高成績’其中之U項目，均較以比較 传之？明顯優良。特別是黏腻感、行動容易度、 布料處理、重量感虑 汉肌膚觸感、穿著感覺等項目中，以實 施例15製造之τ恤的評價均較高。 藉由本發明，可提供一種能防止濕潤時之不適感、且 手感及肌膚觸感優異之具優異接觸涼感之纖維、及使用該 具優異接觸涼感之纖維構成之具優異接觸涼感之布料、衣 料及貼身衣物。 【圖式簡單說明】 圖Ua)、（b) ’係顯示本發明之具優異接觸涼感之衣料 一例的示意圖。 圖2(a)、（b) ’係顯示本發明之具優異接觸涼感之衣料 一例的示意圖。 圖3，係顯示穿著清涼感衣料時皮膚所散發之熱、水蒸 氣之流動的示意圖。 圖4，係顯示於實施例丨4所編織成之雙面織構造之針 織物的組織圖。 圖5 ’係顯示於實施例1 5所編織成之雙面織構造之針 織物的組織圖。 圖6 ’係顯示實施例中所進行之人工氣候室中的評價結 35 201215718 果之圖。 圖7，係顯示實施例中所進行之官能評價1的結果之圖 表。 圖8，係顯示實施例中所進行之官能評價2的結果之圖 表。 【主要元件符號說明】 11.21 涼感衣料 12.22 以具優異接觸涼感之纖維編成之部分 13.23 以疏水性纖維編成之部分32 201215718 The total number of laps is 66 7%. x, τ l . On the outer side of the T-shirt, the proportion of the loops composed of hydrophobic fibers is 1%, %, 〇〇/. On the skin side, the ratio of the loop composed of fibers having excellent contact with coolness was 5 %, and the ratio of the loops composed of hydrophobic fibers was 50%. Further, the weight of the t-shirt prepared was mg/, and the air permeability of the obtained t-shirt was measured in the same manner as in Example 14, and as a result, it was 397.6. (Comparative Example 2) A mesh-shaped t-shirt (manufactured by Mizuno Co., Ltd.) was obtained by weaving a commercially available surface-hydrophilized polyester fiber (manufactured by Kelly, Sophosta). (Comparative Example 3) A T-shirt woven with a commercially available cotton was used. (Evaluation) The t-shirts obtained in Examples 14 and 15 and Comparative Examples 2 and 3 were evaluated by the following methods. (1) The evaluation of the artificial climate chamber is assumed to be a walk in the summer morning. In the artificial climate chamber of 28 ° C x 65% RH environment, wearing the t-shirt made in Example 丨 4 and Comparative Examples 2 and 3, sitting in a chair is quiet. After 15 minutes, walk on the treadmill for 3 minutes in the wind with the wind speed of im/sec from the front, measure the next 3 minutes, sit quietly in the chair seat and recover the temperature inside the clothes, inside the clothes. Humidity changes and oxygen uptake. The result is shown in Fig. 6. In addition, the 'measurement system is performed on 6 healthy adult males, and the average value is shown." As can be seen from Fig. 6, when wearing the t-shirt manufactured in the fourteenth embodiment, it is manufactured by the wearer 33 201215718 by the comparative example 2'3. "Blood time comparison" can suppress the increase in temperature and humidity in the clothes. In addition, when wearing the t-shirt manufactured in Example 14, the oxygen intake during walking is compared with when wearing the t-shirts manufactured in Comparative Examples 2 and 3. The amount can also be suppressed to a lower level. The reason for this is that the t-shirt manufactured in the same manner as in Example 14 can be considered, and the shirt made in the comparative examples 2 and 3 can provide a more comfortable environment for the clothes. (2) Functional evaluation 1 In the family walk (hosted by the Kyoto Prefecture Walking Association) held in Kyoto City in July 2004, the sputum produced in Example 14 and Comparative Example 2 was worn. After walking on the shirt, the sensory evaluation was carried out in the form of a questionnaire in the form of a questionnaire, and the results are shown in Fig. 7. Further, the functional evaluation was performed on 9 adult males, and the average value was shown. Also, 2 men who performed a faculty evaluation The temperature of the rectum and the temperature in the clothes were measured. The results are shown in Fig. 7. As can be seen from Fig. 7, the tanning shirt manufactured in the example 14 was used in all the items: the evaluation of the usual wearing, especially the action On the other hand, the t-shirt manufactured in Comparative Example 2 was evaluated for poorness in terms of sweat absorption and skin detachment at the time of sweating. Example 2^/Manufactured in the same manner as in Example 14 In the case of a one-piece shirt, compared with wearing a t-shirt at a relatively low value, 'the temperature of the rectum and the temperature inside the clothes are also compared. (3) Functional evaluation 1 - In November 2004, wearing a male college student to which the sports department belongs After running with the t-shirts of Example 15 and Comparative Example 2, the t-shirts of 201215718 were used as the benchmark, and the results were not as shown in Fig. 8. Again, the average value was displayed. The functional evaluation was carried out in a magical manner, and the evaluation of the faculty was carried out on 29 male students of the 喊 Λ Λ 石 石 , , , , , , 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。. In the Wang 13 project, the U-items of the 15th edition of the ... the highest scores are compared with the comparison. Obviously excellent. In particular, the evaluation of the t-shirt manufactured in the fifteenth embodiment was high in the items such as the feeling of stickiness, the ease of movement, the handling of the fabric, the feeling of the weight of the skin, the feeling of wearing the skin, and the feeling of wearing. According to the present invention, it is possible to provide a fiber having excellent contact feeling and a feeling of discomfort during wetness, which is excellent in texture and touch, and a fabric and a clothing material which are excellent in contact with the cool feeling using the fiber having excellent contact with coolness. Close-fitting clothing. BRIEF DESCRIPTION OF THE DRAWINGS Figs. Ua) and (b)' are schematic views showing an example of a fabric having excellent cold contact feeling of the present invention. Fig. 2 (a) and Fig. 2(b) are schematic views showing an example of a clothing material having excellent cold contact feeling of the present invention. Fig. 3 is a view showing the flow of heat and water vapor generated by the skin when wearing a cool sensation. Fig. 4 is a view showing the structure of a woven fabric of a double-sided woven structure woven in the embodiment 丨4. Fig. 5 is a structural view showing the woven fabric of the double-sided woven structure woven in the fifteenth embodiment. Figure 6 is a diagram showing the evaluation of the artificial climate chamber performed in the examples. Fig. 7 is a graph showing the results of the functional evaluation 1 performed in the examples. Fig. 8 is a graph showing the results of the sensory evaluation 2 performed in the examples. [Explanation of main component symbols] 11.21 Cool sensation material 12.22 Part of fiber made with excellent contact coolness 13.23 Part made of hydrophobic fiber

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Claims (1)

201215718 七、申請專利範圍： 衣料，其係雙面織構造之針 ’具有含熱可塑性彈性體及 之纖維所構成的紗圈，與疏 1. 一種具優異接觸涼感之 織物所構成之涼感優異之衣料 無機填充物之具優異接觸涼感 水性纖維所構成的紗圈， 總紗圈數之 構成的紗圈， 30〜70%係由該具優異接觸 涼感之纖維所 °亥具優異接觸涼感之纖 側，且該疏水性纖維所構成 2.如申請專利範圍第1 其中’該熱可塑性彈性體， 系彈性體。 維所構成的紗圈僅配置於肌膚 的紗圈配置於外側。 項之具優異接觸涼感之衣料， 係聚醯胺系彈性體及/或聚酯 3.如申請專利範圍第1項之具優異接 '、中4熱可塑性彈性體’係聚趟嵌段醯胺共聚物“ 4.如申請專利範圍第1項之具優異接觸涼感之衣料， 其中’無機填充物，係、平均粒徑為㈣〜3GMm。 5·如申研專利範圍第1項之具優異接觸涼感之衣料， 其中’具優異接觸涼感之纖維，係含有無機填充物 重量U 6.如申請專利範圍第i項之具優異接觸涼感之衣料， 其中，具優異接觸涼感之纖維，係、含有熱可塑性彈性 重量％以上。 7. -種具優異接觸涼感之貼身衣物’係使用中請專利範 圍第1項之具優異接觸涼感之衣料所製成。 37201215718 VII. Patent application scope: The clothing material, which is a double-woven structure needle, has a yarn loop composed of a thermoplastic elastomer and a fiber, and is excellent in the cool feeling of a fabric with excellent contact and cool feeling. The yarn ring composed of the inorganic filler of the clothing material has excellent contact with the cool water-based fiber, and the yarn loop composed of the total number of yarn loops, 30 to 70% is composed of the fiber having excellent contact with the cool feeling. And the hydrophobic fiber is composed of 2. In the patent application, the first one is 'the thermoplastic elastomer, which is an elastomer. The loops formed by the dimension are placed only on the outside of the loop of the skin. A fabric having excellent contact with coolness, a polyamine-based elastomer and/or a polyester 3. As in the first aspect of the patent application, it has an excellent connection, a medium-duty thermoplastic elastomer, and a poly-blocking amine. Copolymer "4. According to the first paragraph of the patent application, the fabric having excellent contact with cool feeling, wherein 'inorganic filler, system, average particle size is (4) ~ 3GMm. 5. If the application of the patent scope of the first item has excellent contact The fabric of cool sensation, wherein the fiber having excellent contact with coolness contains the weight of the inorganic filler U. 6. The fabric having excellent contact with coolness as in the scope of claim i, wherein the fiber having excellent contact with coolness, contains heat The plasticity is more than or equal to the weight of the plastic. 7. - The close-fitting clothing with excellent contact and coolness is made of the material with excellent contact and cool feeling in the first item of the patent range.