201204398 六、發明說明： 【發明所屬之技術領域】 本發明係關於包含油之組合物。 【先前技術】 在濩髮領域内需要包含油之經改良護髮洗髮精組合物。 尤其尋求關於產品穩定性（特別是在升高之溫度下）之改 良。 【發明内容】 本發明額外地具有另一優點是不需要聚合懸浮劑，因此 可降低調配物成本。 同在申請中之專利申請案第Ερ 〇9163568號描述一種護 髮洗髮組合物，其包含1重量％至26重量％清潔相、護髮膠 網狀物（油分散於其中）、聚合懸浮劑及陽離子性沈積聚合 物。 因此，本發明提供護髮洗髮精組合物，其包含： 0 清潔相， ii) 護髮膠網狀物，其包含脂肪物質、陰離子性界面活性 劑及陽離子性界面活性劑； 其中該護髮膠網狀物不具有總體電荷或為陰離子 的； iii) 油；及 iv) 疏水性經改質陽離子性沈積聚合物； 其中陽離子性沈積聚合物及該凝膠網狀物之兮 、 咏陰離子性界 面活性劑含有彼此差距4個碳以内的烧基。 1 155670.doc 201204398 【實施方式】 本說明書中所提及之所有黏度均為在30°C下用布氏黏度 計（Brookfield viscometer)在軸RV5及20 rpm下所量測之黏 度。 較佳為組合物具有在30°C下所量測之2000 cPs至7000 cPs的黏度量測值。 護髮膠網狀物 護髮膠網狀物包含： (a) 脂肪物質； (b )凝膠網狀物陰離子性界面活性劑，其包含呈有1 6至3 〇 個碳之烷基； (c) 陽離子性界面活性劑； 其中護髮膠網狀物不具有總體電荷或為陰離子性的。 陽離子性界面活性劑提供脂肪物質/陰離子性界面活性 劑凝膠網狀物之改良耐變性，從而自亦包含非陽離子性清 潔相之組合物獲得改良之護髮益處。清潔相中陰離子性界 面活性劑與護髮膠中陰離子性界面活性劑之間的碳鍵長度 差可顯著改善護髮膠網狀物之穩定性且維持其在洗髮精組 合物中的完整性。 較佳地’凝膠網狀物中之陰離子性界面活性劑及陽離子 性界面活性劑彼此差距4個碳以内，較佳彼此差距2個碳且 最佳含有相同數目個碳。更佳為其包含彼此差距4個碳以 内，更佳2個碳以内且最佳為相同長度之單一烷基。此可 輔助維持凝膠網狀物之穩定性。 155670.doc 201204398 凝膝網狀物陽離子性界面活性劑中之碳較佳存在於單一 烷基中。更佳為凝膠網狀物陽離子性界面活性劑具有16至 30個碳。 較佳為陽離子性界面活性劑具有式， 其中R1、R2、R3及R4獨立地為（C丨6至Go)烷基或苯曱基。 較佳為R、R2、R3及R4中之一者、兩者或三者獨立地為 (<：16至<：30)烧基’且其他Ri、、以及〆基團為（Ci_C6)烷 基或苯曱基》 烧基可視情況包含烧基鏈内之一或多個酯（_〇C〇_或_ COO-)及/或醚（_〇_)鍵。烷基可視情況藉由一或多個羥基取 代。烷基可為直鏈或分支鏈，且對於具有3個或3個以上碳 原子之烷基，其可為環狀。烷基可為飽和的或可含有一或 多個碳-碳雙鍵（例如，油烯基）。烷基視情況在烷基鏈上經 一或多個乙烯氧基加以乙氧基化。 用於本發明護髮精組合物中之合適的陽離子性界面活性 劑包括氯化十六烧基三▼基敍、氣化二十二烧基三甲基 銨、氣化十六烷基吡錠、四甲基氣化銨、四乙基氣化銨、 氯化十八烷醯二曱基笨甲基銨、氣化可可三甲基銨、pEG_ 2/由基甲基氣化敍及其相應氫氧化物。其他合適的陽離子 性界面活性劑包括具有CTFA名稱四級銨鹽_5、四級銨鹽_ 31及四級銨鹽_18之物質。前述物質中之任一者之混合物 亦可為合適的。用於本發明護髮精中之尤其有用的陽離子 性界面活性劑為氯化十六烷基三甲基銨，其可為市售的， 例如作為 GENAMIN CTAC，ex H〇echst Celanese。用於本 155670.doc 201204398 發明錢精巾之另-尤其有料陽離子性界面活性劑為氣 化二十二烷基三曱基銨，#可為市售的，例如作為 GENAMIN KDMP > ex Clariant ° 用於本發明中之合適的陽離子性界面活性劑之類別之另 -實例(單獨或與一或多種其他陽離子性調節界面活性劑 混雜）為以下⑴與（ii)之組合： ⑴對應於通式（I)之醯胺基胺：201204398 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a composition comprising an oil. [Prior Art] An improved hair care shampoo composition containing oil is required in the field of hair burst. In particular, seek improvements in product stability (especially at elevated temperatures). SUMMARY OF THE INVENTION The present invention additionally has the additional advantage that a polymeric suspending agent is not required, thereby reducing the cost of the formulation. A hair care shampoo composition comprising from 1% to 26% by weight of a cleansing phase, a hair gel network (oil dispersed therein), a polymeric suspending agent is described in the patent application No. PCT No. 9163568. And cationic deposition polymers. Accordingly, the present invention provides a hair care shampoo composition comprising: a cleansing phase, ii) a hair care gel network comprising a fatty material, an anionic surfactant, and a cationic surfactant; wherein the hair care The gel network does not have an overall charge or is anionic; iii) an oil; and iv) a hydrophobic modified cationic deposition polymer; wherein the cationic deposition polymer and the gel network are ruthenium and anion The surfactant contains a burn group within 4 carbons of each other. 1 155670.doc 201204398 [Embodiment] All the viscosities mentioned in the present specification are the viscosities measured at 30 ° C using a Brookfield viscometer at shafts RV 5 and 20 rpm. Preferably, the composition has a viscosity measurement of from 2000 cPs to 7000 cPs measured at 30 °C. A hair care gel mesh hair care gel mesh comprising: (a) a fatty material; (b) a gel network anionic surfactant comprising an alkyl group having from 16 to 3 carbons; c) a cationic surfactant; wherein the hair gel network does not have an overall charge or is anionic. The cationic surfactant provides improved resistance to denaturation of the fatty material/anionic surfactant gel network to provide improved hair care benefits from compositions that also include a non-cationic cleansing phase. The difference in carbon bond length between the anionic surfactant in the cleansing phase and the anionic surfactant in the hair conditioner can significantly improve the stability of the hair gel network and maintain its integrity in the shampoo composition. . Preferably, the anionic surfactant and the cationic surfactant in the gel network are within 4 carbons of each other, preferably 2 carbons apart from each other and preferably contain the same number of carbons. More preferably, it comprises a single alkyl group within 4 carbons of each other, more preferably within 2 carbons and optimally of the same length. This assists in maintaining the stability of the gel network. 155670.doc 201204398 The carbon in the knee-net cationic surfactant is preferably present in a single alkyl group. More preferably, the gel network cationic surfactant has from 16 to 30 carbons. Preferably, the cationic surfactant has the formula wherein R1, R2, R3 and R4 are independently (C丨6 to Go) alkyl or phenyl fluorenyl. Preferably, one, two or three of R, R2, R3 and R4 are independently (<:16 to <:30) alkyl groups and the other Ri, and oxime groups are (Ci_C6) The alkyl or benzoinyl group may optionally comprise one or more esters (_〇C〇_ or _COO-) and/or ether (_〇_) linkages in the alkyl group. The alkyl group may optionally be replaced by one or more hydroxyl groups. The alkyl group may be a straight chain or a branched chain, and may be cyclic for an alkyl group having 3 or more carbon atoms. The alkyl group can be saturated or can contain one or more carbon-carbon double bonds (e.g., oleyl). The alkyl group is optionally ethoxylated on the alkyl chain via one or more ethyleneoxy groups. Suitable cationic surfactants for use in the hair conditioning compositions of the present invention include hexadecyl trimethyl sulfonate, gasified teflon trimethylammonium, gasified cetyl pyridinium , tetramethylammonium hydride, tetraethylammonium hydride, octadecylphosphonium dimercaptomethylammonium chloride, vaporized cocotrimethylammonium, pEG_ 2/methyl radicalization and corresponding hydroxide. Other suitable cationic surfactants include those having the CTFA designation quaternary ammonium salt _5, quaternary ammonium salt _31 and quaternary ammonium salt -18. Mixtures of any of the foregoing may also be suitable. A particularly useful cationic surfactant for use in the hair conditioner of the present invention is cetyltrimethylammonium chloride, which is commercially available, for example, as GENAMIN CTAC, ex H〇echst Celanese. For use in the invention of the 155670.doc 201204398 invention, in particular, the cationic surfactant is gasified behenyltridecyl ammonium, #commercially available, for example as GENAMIN KDMP > ex Clariant ° Another example of a class of suitable cationic surfactants for use in the present invention (alone or in combination with one or more other cationically modulating surfactants) is a combination of the following (1) and (ii): (1) corresponding to the formula (I) Amidinoamine:
R^ONHC^mNR^ONHC^mN
R3 其中R1為具有10個或1〇個以上碳原子之烴基鏈， R2及R3係獨立地選自H0個碳原子之烴基鏈，且 m為整數1至約及 (ii)酸。 如本文中所用，術語烴基鏈意謂烷基或烯基鏈。 較佳醯胺基胺化合物為對應於式⑴之化合物，其中 R1為具有約11至約24個碳原子之烴基殘基，…及尺3各自 獨立地為具有i至約4個碳原子之烴基殘基，較佳為烧基， 且m為整數1至約4。 R2及R3較佳為甲基或乙基。 m較佳為2或3，亦即，伸乙基或伸丙基。 本文中有用的較佳醯胺基胺包括硬脂醯胺·丙基二甲基 胺、硬脂醯胺丙基：乙基胺、硬脂醯胺乙基二乙基胺、硬 脂醯胺乙基：甲基胺、棕龍胺丙基三甲基胺、棕櫚醯胺 155670.doc 201204398 丙基二乙基胺、棕櫚醯胺乙基二乙基胺、棕櫚醯胺乙基二 曱基胺、山蝓醆醯胺丙基二甲基胺、山蝓酸醢胺丙基二乙 基胺、山蝓酸醯胺乙基二乙基胺、山蝓酸醯胺乙基二甲基 胺、花生醯胺丙基二甲基胺、花生醯胺丙基二乙基胺、花 生醯胺乙基二乙基胺、花生醯胺乙基二甲基胺及其混合 物。 本文中有用的尤其較佳醯胺基胺為硬脂醯胺丙基二甲基 胺、硬脂醯胺乙基二乙基胺及其混合物。 本文中有用的市售醯胺基胺包括：可自Inolex (Philadelphia Pennsylvania， USA)賭得之商品名為 LEXAMINE S-13及可自 Nikko(Tokyo，Japan)購得之商品名 為AMIDOAMINE MSP的硬脂醯胺丙基二甲基胺；可自 Nikko購得之商品名為AMIDOAMINE S之硬脂醯胺乙基二 乙基胺；可自 Croda(North Humberside，England)購得之商 品名為INCROMINE BB的山蝓酸醯胺丙基二甲基胺；及可 自 Scher(Clifton New Jersey, USA)購得之商品名為 SCHERCODINE系列的各種醢胺基胺。 酸（ii)可為能夠質子化毛髮處理組合物中之醯胺基胺的 任何有機酸或礦物酸。本文中有用的合適酸包括鹽酸、乙 酸、酒石酸、反丁烯二酸、乳酸、蘋果酸、丁二酸及其混 合物。酸較佳係選自由乙酸、酒石酸、鹽酸、反丁烯二酸 及其混合物組成之群。 酸之主要作用為質子化毛髮處理組合物中之醯胺基胺， 由此在毛髮處理組合物中原位形成三級胺鹽（TAS)。TAS實 155670.doc 201204398 際上為非永久性四級銨或偽四級銨陽離子性界面活性劑。 0適地，以足以質子化所存在之所有醯胺基胺的量包括 酉文，亦即，與組合物中所存在之醯胺基胺量至少等莫耳之 含量。 基於組合物之總重量以陽離子性界面活性劑之總重量 汁，陽離子性界面活性劑含量一般在〇 〇1%至1〇%，更佳 為0.02%至7.5%，最佳為0.05%至5%範圍内。 凝膠網狀物之陰離子性界面活性劑包含丨6至3 〇個碳，較 佳16至22個碳之烷基鏈。 陰離子性界面活性劑較佳為硫酸鹽或磺酸鹽，更佳為硫 酸鹽，最佳為十六烷基十八烷醯基硫酸鈉。 凝膠網狀物陰離子性界面活性劑中之碳較佳存在於單一 烷基中。 凝膠網狀物包含陰離子性界面活性劑，以詩使凝膠網 狀物具有總體陰離子電荷或使凝膠網狀物無總體電荷。 凝膠網狀物内陰離子性界面活性劑（13)對凝膠網狀物内 陽離子性界面活性劑（c)之比率較佳具有6:1至2〇:1，最佳 為9:1至13:1的比率》 凝膠網狀物包含陰離子性界面活性劑，以用於使凝膠網 狀物具有總體陰離子電荷或使凝膠網狀物無總體電荷。 凝膠網狀物陰離子性界面活性劑以總體組合物之〇ι重 量％至5重量％且更佳〇.5重量％至2〇重量％存在。 脂肪物質較佳係選自脂肪酸、脂肪酿胺、脂肪醇、脂肪 酯及其混合物。尤其較佳為脂肪醇。 155670.doc 201204398 脂肪物質較佳包含具有14至30個凌原子，更佳16至22個 碳原子的脂肪基。合適的脂肪醇之實例包括十六醇、硬脂 醇及其混合物。合適的脂肪酯之實例為單硬脂酸甘油酯。 以總體組合物之重量計，本發明組合物中脂肪物質的含 量便利地為0.01%至10%，較佳為0 1%至5%。 較佳為凝膠網狀物内脂肪醇（a)與凝膠網狀物内陰離子性 界面活性劑（b)之間的比率為〇.1:1至1〇〇:1，較佳為1 2」至 5〇:1 ’更佳為1.5:1至10:1且最佳為約2:1。 較佳為凝膠網狀物之陰離子性及脂肪物質含有彼此差距 4個碳以内，較佳彼此差距2個碳且最佳具有相同數目個碳 之烷基。更佳為其包含彼此差距4個碳以内，更佳2個碳以 内且最佳為相同長度之單一烷基。此可輔助維持凝膠網狀 物之穩定性。 疏水性陽離子性沈積聚合物 本發明組合物包含疏水性經改質陽離子性沈積聚合物。 疏水性經改質陽離子性沈積聚合物較佳地含有具有丨4至 30個碳之碳鏈。碳鏈較佳為單一烷基鏈，更佳地是未分支 的。 合適的疏水性陽離子性沈積輔助聚合物可為經陽離子性 取代之均聚物或可由兩種或兩種以上類型之單體形成。聚 合物之重量平均（Mw)分子量一般為1，000至6百萬道爾頓， 更佳為100,000至2百萬道爾頓。聚合物具有陽離子性含氮 基團’諸如四級銨或質子化胺基，或其混合物。若聚合物 之分子量過低，則護髮作用較弱。若分子量過高，則可能 155670.doc -10- 201204398 存在高拉伸黏度問題，從而導致傾倒組 物之絲黏性。 ^座生組合 陽離子度3氮基團—般係以陽離子性聚合物之總單體 =部分上的取代基形式存在。因此，當聚合物並非均聚 、其可3有間隔非陽離子性單體單元。此等聚合物描 -^CTFA Cosmetic Ingredient Directory, ^ t 〇 it# 陽離子性單體單㈣非陽離子性㈣單元之比率，以產生 具有所需範圍（―般為0·1 meq/gm至5 meq/gm，更佳為〇2 ―现至^ meq/gm)内之陽離子電荷密度的聚合物。經 ，如美國藥典（US Pharmacopoeia)中關於氮測定之化學測 式斤治述之飢氏方法（Kjeldahi meth〇d)合適地測定聚合物 之陽離子電荷密度。 一視特定物質及組合物之pH而定，陽離子胺可為一級胺、 -級胺或三級胺。一般而言’較佳為二級胺及三級胺，尤 其為三級胺。 可以胺形式聚合經胺取代之乙烯單體及胺，且接著藉由 四級銨化轉化為銨。 疏水性經改質陽離子性聚合物可包含自經胺及/或四級 錄取代之單體及/或相容間隔單體獲得之單體單元的混合 物0 可自疏水性經改質沈積聚合物獲得用於本發明中之疏水 r生陽離子性沈積聚合物’該等疏水性經改質沈積聚合物係 來自由瓜爾膠、槐豆、μ雲豆膠、皂莢、桂皮、胡蘆巴及 鳳凰木組成之群。其他有用之聚合物可包括三仙膠、潔冷 155670.doc 11 201204398 膠（gellan gum)、文萊膠、拉姆生膠（rharnsan gum)、筠 篛、甘露聚糖、***膠、大豆多醣、低聚果糖膠、多聚 葡萄糖（澱粉）及羅望子膠。 疏水性經改質陽離子性沈積聚合物及凝膠網狀物之陰離 子性界面活性劑含有彼此差距4個碳以内，較佳彼此差距2 個碳且最佳具有相同數目個碳之烷基。更佳為其包含彼此 差距4個碳以内，更佳2個碳以内且最佳為相同長度之單一 烷基。此辅助維持凝膠網狀物之穩定性且減少對懸浮劑之 需要。 類似地，疏水性經改質陽離子性沈積聚合物及凝膠網狀 物之脂肪物質含有彼此差距4個碳以内，較佳彼此差距2個 碳且最佳具有相同數目個碳之烷基。更佳為其包含彼此差 距4個碳以内’更佳2個碳以内且最佳為相同長度之單一烧 基。此可辅助維持凝膠網狀物之穩定性且減少對懸浮劑之 需要。 基於組合物之總重量以陽離子性聚合物之總重量計，陽 離子性聚合物一般以0.01%、至5%，較佳0.05%至2%，更佳 〇_〇7%至1.2%之含量存在於本發明洗髮精組合物中。 油 油可為通常用於個人護理產品中之任何油，例如聚稀煙 油、S旨油、三酸甘油酯油、烴油及其混合物。油較佳為輕 油。 較佳油包括選自以下各者之油： • 具有在3〇°C下所量測之〇. 1厘泊至500厘泊之點度量測 155670.doc -12- 201204398 值的油。 • 具有5〇〇厘泊以上（500 cps至500000 cps)黏度之油，其 含有至多20%的較低黏度部分（小於5〇〇 cps)。 油可分散於凝膠網狀物内或作為清潔相之部分。 若油處於凝膠網狀物内，則獲得改良之穩定性。 若油處於清潔相中，則產品可易於加工。 聚α-稀煙油 油較佳為聚(X-烯烴油。與聚石夕氧油類似，此等材料可增 強所發現之本發明組合物的護髮益處。合適的聚α-烯烴油 包括自具有6至16個碳，較佳6至12個碳之1_烧稀（1-alkalene)單體所獲得之聚α_烯烴油。材料之非限制實例包 括1-己烯、1-辛烯、^癸烯、十二烯、丨十四烯、丨-十六 烯、分支異構體（諸如，4-甲基-1-戊烯）及其混合物。 較佳聚α-稀烴包括可自Mobil購得之商品名為puresyn 6(數里平均分子量為約5〇〇)、pUreSyn (分子量為約 3000)及Puresyn 300(分子量為約6〇〇〇)之聚癸烯。 聚α_浠烴較佳以總體組合物重量之0.05%至1〇%，尤其 〇.2%至5%且尤其〇.5%至3%之量存在。 三酸甘油輯油 合適的三酸甘油酯油包括油脂，包括天然油脂，諸如荷 荷芭、大豆、向日葵籽油、米糠、鱷梨、杏仁、橄欖、芝 麻蓖麻椰子、椰子樹油、向日葵油、紹油；可可脂； 牛脂、豬脂；藉由氫化上述油所獲得之硬化油；及合成 單、一及二酸甘油酯，諸如肉豆蔻酸甘油酯及2_乙基己酸 155670.doc 13 201204398 甘油醋。 較佳為三酸甘油醋油.以組合物之重量之0.05。/。至1 〇%， 尤其0.2%至5%且尤其0.5%至3°/。的量存在。 合適的烴油具有至少12個碳原子，且包括石蠟油、聚烯 烴油、鑛物油、飽和及不飽和十二烧、飽和及不飽和十三 烧、飽和及不飽和十四烷、飽和及不飽和十五烷、飽和及 不飽和十六烧’及其混合物。亦可使用此等化合物之分支 键異構體以及較尚鏈長度烴。C2.6婦基單體之聚合烴（諸 如，聚異丁烯）亦為合適的。 烴油較佳以組合物之重量之〇 05%至丨〇%，尤其〇 2%至 5%且尤其0.5%至3%的量存在。 合適的醋油具有至少10個碳原子，1包括自脂肪酸或醇 所獲得之具有烴基鏈的酯。典型酯油為式r,c〇〇r，其中 UR獨立地表示烧基或縣，且R•及R中碳原子之總數為 至少10個，較佳至少20個。亦可使用羧酸之二烷基及三烷 基及稀基@旨。 酉旨油較佳以總體組合物重量之0 05%至10%，尤其m 至5%且尤其〇·5%至3%的量存在。 面活性劑，其包含具有 組合物較佳包含清潔陰離子性界 10至14個碳之烷基。 清潔相 本發明組合物包含清潔相 較佳含量為總體組合物之1 155670.doc •14· 201204398 重量％至26重量％ » 清潔相包含清潔界面活性劑。清潔相陰離子性界面活性 劑具有8至14個碳，更佳10至12個且最佳12個碳。更佳為 此等碳存在於單一烷基中。 較佳陰離子性清潔界面活性劑包括烷基鹼金屬硫酸鹽， 更佳為烧㈣硫酸鹽。尤其較佳陰離子性清潔界面活性劑 包括十二烷基醚硫酸鈉。 清潔界面活性劑之含量為總體組合物之5重量％至26重 量％。 其他組分 本發明水性洗髮精組合物可進—步包含懸浮劑，然而較 佳為組合物包含小於G.li4%懸浮劑，較佳不含懸浮劑。 本發明毛髮5蔓理組合物較佳為水性，亦即，其具有水或 水性溶液或向液性液晶相作為其主要組分。 合適地，組合物包含以組合物之總重量計1〇重量。、至卯 重量％，較佳30重量％至95重量％的水。 本發明組合物較佳包含聚矽氧。 尤其較佳聚石夕氧調冑劑為聚石夕氧乳&，諸如由諸如聚二 有機基梦氧烧（尤其為具有CTFA名稱二f聚石夕氧院之聚二 甲基矽氧烷、具有CTFA名稱二甲聚矽氧醇的具有羥基端 基之聚二甲基⑦氧院及具有CTFA名稱胺基封端二甲基聚 石夕氧炫之胺基官能性聚二甲基石夕氧烧）之聚石夕氧所形成的 聚矽氧乳液》 本發明組合物中乳液液滴通常具有〇.〇1微米至20微米， 155670.doc -15- 201204398 更佳0.2微米至1 Ok米|e(圍内之梭德平均液滴直徑（§auter mean droplet diameter)(D3,2)。 用於量測梭德平均液滴直徑（D3,2)之合適方法為使用諸 如Malvern Mastersizer之器具藉由雷射光散射來量測。 用於本發明組合物中的合適之聚矽氧乳液可自諸如D〇w Corning及GE Silicones之聚矽氧供應商獲得。使用此等預 成形聚>5夕氧乳液之優點為易於處理及控制聚石夕氧粒控。此 專預成形聚碎氧乳液通常另外包含合適的乳化劑，諸如陰 離子性或非離子性乳化劑或其混合物，且可藉由化學乳化 過程（諸如，乳液聚合）或使用高剪切混合器藉由機械乳化 來製備。一般梭德平均液滴直徑⑴3,2)小於〇15微米之預成 形聚矽氧乳液稱為微乳液。 合適的預成形聚矽氧乳液之實例包括乳液DC2-1766、 DC2 1784、DC-1785、DC-1786、DC-1788 及微乳液 DC2· 1865及〇02-1870，其均可自〇〇\¥(：〇1：11111§獲得。〇07051 為 較佳聚矽氧。此等均為二甲聚矽氧醇之乳液/微乳液。諸 如 DC2-8177及 DC939(來自 Dow Corning)以及 SME25 3(來自 GE SiliC0nes)之胺基封端二甲基聚矽氧烷乳液亦為合適 的。 某些類型之高分子量表面活性嵌段共聚物與聚矽氧乳液 液滴心&之聚石夕氧乳液亦為合適的，如例如WO03/094874 中所描述。在此等物質中，聚矽氧乳液液滴較佳由聚二有 機基矽氧烷（諸如，上文所描述之聚二有機基矽氧烷）形 成。表面活性嵌段共聚物之一種較佳形式為下式： 155670.doc 201204398R3 wherein R1 is a hydrocarbyl chain having 10 or more carbon atoms, R2 and R3 are independently selected from a hydrocarbyl chain of H0 carbon atoms, and m is an integer from 1 to about and (ii) an acid. The term hydrocarbyl chain, as used herein, means an alkyl or alkenyl chain. Preferably, the guanamine amine compound is a compound corresponding to formula (1) wherein R1 is a hydrocarbyl residue having from about 11 to about 24 carbon atoms, and each of the ruthenium 3 is independently a hydrocarbyl group having from i to about 4 carbon atoms. The residue is preferably an alkyl group, and m is an integer from 1 to about 4. R2 and R3 are preferably a methyl group or an ethyl group. m is preferably 2 or 3, that is, an ethyl group or a propyl group. Preferred guanamine amines useful herein include stearylamine propyldimethylamine, stearylamine propyl: ethylamine, stearylamine ethyldiethylamine, stearylamine B Base: methylamine, melamine propyl trimethylamine, palm amide 155670.doc 201204398 propyldiethylamine, palmitosylethyldiethylamine, palmitosylethyldidecylamine, Anthurium propyl dimethylamine, decyl propyl propyl sulphate, decyl ammonium ethyl ethoxide, decyl ammonium dimethyl amide, peanut 醯Aminopropyldimethylamine, peanut melamine propyldiethylamine, peanut decylamine ethyldiethylamine, peanut decylamine ethyl dimethylamine, and mixtures thereof. Particularly preferred guanamine amines useful herein are stearylamine dimethylamine, stearylamine ethyldiethylamine, and mixtures thereof. Commercially available guanamine amines useful herein include: the trade name LEXAMINE S-13 available from Inolex (Philadelphia Pennsylvania, USA) and the trade name AMIDOAMINE MSP available from Nikko (Tokyo, Japan). Lipoamidamine dimethylamine; stearylamine ethyldiethylamine available from Nikko under the trade name AMIDOAMINE S; available under the trade name INCROMINE BB from Croda (North Humberside, England) Ammonium dimethylamine amine behenate; and various guanamine amines available from Scher (Clifton New Jersey, USA) under the tradename SCHERCODINE series. The acid (ii) can be any organic or mineral acid capable of protonating the guanamine amine in the hair treatment composition. Suitable acids useful herein include hydrochloric acid, acetic acid, tartaric acid, fumaric acid, lactic acid, malic acid, succinic acid, and mixtures thereof. Preferably, the acid is selected from the group consisting of acetic acid, tartaric acid, hydrochloric acid, fumaric acid, and mixtures thereof. The primary action of the acid is the proguanamine in the protonated hair treatment composition whereby the tertiary amine salt (TAS) is formed in situ in the hair treatment composition. TAS 155670.doc 201204398 is a non-permanent quaternary ammonium or pseudo quaternary ammonium cationic surfactant. Suitably, the amount of all of the amide amines present in sufficient protonation comprises hydrazine, i.e., at least the molar amount of the guanamine amine present in the composition. The cationic surfactant content is generally from %1% to 1%, more preferably from 0.02% to 7.5%, most preferably from 0.05% to 5, based on the total weight of the composition of the total weight of the cationic surfactant. Within the range of %. The anionic surfactant of the gel network comprises from 6 to 3 carbon atoms, preferably from 16 to 22 carbon alkyl chains. The anionic surfactant is preferably a sulfate or a sulfonate, more preferably a sulfate, most preferably sodium cetylstearyl sulfate. The carbon in the gel network anionic surfactant is preferably present in a single alkyl group. The gel network contains an anionic surfactant to give the gel network a total anionic charge or to make the gel network uncharged. The ratio of the anionic surfactant (13) in the gel network to the cationic surfactant (c) in the gel network preferably has a ratio of 6:1 to 2〇:1, preferably 9:1 to Ratio of 13:1 The gel network contains an anionic surfactant for the gel network to have an overall anionic charge or to make the gel network uncharged. The gel network anionic surfactant is present in an amount from 5% by weight to 5% by weight and more preferably from 5% by weight to 2% by weight of the total composition. Preferably, the fatty material is selected from the group consisting of fatty acids, fatty amines, fatty alcohols, fatty esters, and mixtures thereof. Particularly preferred is a fatty alcohol. 155670.doc 201204398 The fatty substance preferably comprises a fatty group having 14 to 30 fused atoms, more preferably 16 to 22 carbon atoms. Examples of suitable fatty alcohols include cetyl alcohol, stearyl alcohol, and mixtures thereof. An example of a suitable fatty ester is glyceryl monostearate. The content of the fatty substance in the composition of the present invention is conveniently from 0.01% to 10%, preferably from 0% to 5% by weight of the total composition. Preferably, the ratio between the fatty alcohol (a) in the gel network and the anionic surfactant (b) in the gel network is 1:1.1:1 to 1〇〇:1, preferably 1 2" to 5": 1' is preferably 1.5:1 to 10:1 and most preferably about 2:1. Preferably, the anionic and fatty materials of the gel network contain alkyl groups within 4 carbons of each other, preferably 2 carbons apart from one another and most preferably having the same number of carbons. More preferably, it comprises a single alkyl group within 4 carbons of each other, more preferably within 2 carbons and optimally of the same length. This assists in maintaining the stability of the gel network. Hydrophobic Cationic Deposition Polymer The compositions of the present invention comprise a hydrophobic modified cationic deposition polymer. The hydrophobic modified cationic deposition polymer preferably contains a carbon chain having from 4 to 30 carbons. The carbon chain is preferably a single alkyl chain, more preferably unbranched. Suitable hydrophobic cationic deposition auxiliary polymers may be cationically substituted homopolymers or may be formed from two or more types of monomers. The weight average (Mw) molecular weight of the polymer is generally from 1,000 to 6 million Daltons, more preferably from 100,000 to 2 million Daltons. The polymer has a cationic nitrogen-containing group such as a quaternary ammonium or protonated amine group, or a mixture thereof. If the molecular weight of the polymer is too low, the hair care effect is weak. If the molecular weight is too high, it may be 155670.doc -10- 201204398 There is a problem of high tensile viscosity, which leads to the stickiness of the poured group. ^Seat combination The cationic 3 nitrogen group is generally present as a substituent on the total monomer of the cationic polymer. Thus, when the polymer is not homopolymerized, it may have a spacer non-cationic monomer unit. These polymers are described as ^CTFA Cosmetic Ingredient Directory, ^ t 〇it# cationic monomer single (iv) non-cationic (four) unit ratio to produce the desired range ("typically 0·1 meq/gm to 5 meq /gm, more preferably a polymer of cationic charge density within 〇2 - now to ^ meq/gm). The cationic charge density of the polymer is suitably determined by, for example, the chemical test for nitrogen determination in the US Pharmacopoeia (Kjeldahi meth〇d). The cationic amine may be a primary amine, a -grade amine or a tertiary amine, depending on the pH of the particular material and composition. Generally, it is preferred to be a secondary amine and a tertiary amine, especially a tertiary amine. The amine-substituted ethylene monomer and amine can be polymerized in the amine form and then converted to ammonium by quaternization. The hydrophobic modified cationic polymer may comprise a mixture of monomer units obtained from an amine and/or a quaternary substituted monomer and/or a compatible spacer monomer. 0 may be self-hydrophobic modified deposition polymer Obtaining a hydrophobic r-cationic deposition polymer for use in the present invention. These hydrophobic modified deposition polymers are derived from guar gum, cowpea, yoghurt, acacia, cinnamon, fenugreek and phoenix. A group of wood. Other useful polymers may include Sanxianjiao, Jieliang 155670.doc 11 201204398 gellan gum, Brunei gum, rharnsan gum, alfalfa, mannan, gum arabic, soy polysaccharide, Oligo-fructose gum, polydextrose (starch) and tamarind gum. The hydrophobic modified cationic deposition polymer and the anionic surfactant of the gel network contain alkyl groups within 4 carbons of each other, preferably 2 carbons apart from one another and most preferably having the same number of carbons. More preferably, it comprises a single alkyl group having a difference of 4 carbons or less, more preferably 2 carbons or less, and preferably the same length. This assists in maintaining the stability of the gel network and reduces the need for suspending agents. Similarly, the hydrophobic modified cationic deposition polymer and the fatty material of the gel network contain alkyl groups within 4 carbons of each other, preferably 2 carbons apart from one another and most preferably having the same number of carbons. More preferably, it comprises a single alkyl group which is within 4 carbons of each other and is preferably within 2 carbons and preferably of the same length. This assists in maintaining the stability of the gel network and reduces the need for suspending agents. The cationic polymer is generally present in an amount of 0.01%, to 5%, preferably 0.05% to 2%, more preferably 〇_〇7% to 1.2%, based on the total weight of the composition based on the total weight of the cationic polymer. In the shampoo compositions of the present invention. The oil may be any of the oils commonly used in personal care products, such as polystyrene, S-oil, triglyceride oil, hydrocarbon oils, and mixtures thereof. The oil is preferably a light oil. Preferred oils include those selected from the group consisting of: • Oils having a value measured at 3 ° C. 1 centipoise to 500 centipoise. 155670.doc -12- 201204398 value oil. • Oil with a viscosity of more than 5 centipoise (500 cps to 500,000 cps) containing up to 20% lower viscosity (less than 5 〇〇 cps). The oil can be dispersed in the gel network or as part of the cleansing phase. Improved stability is obtained if the oil is in the gel network. If the oil is in a clean phase, the product can be easily processed. The polyalpha-lean tobacco oil is preferably a poly(X-olefin oil. Similar to the polyoxime oil, these materials enhance the hair care benefits of the compositions of the present invention found. Suitable polyalphaolefin oils include a polyalphaolefin oil obtained from a 1-alkalene monomer having 6 to 16 carbons, preferably 6 to 12 carbons. Non-limiting examples of materials include 1-hexene, 1-octyl Alkene, terpene, dodecene, pyrenetetradecene, decene-hexadecene, branched isomers (such as 4-methyl-1-pentene), and mixtures thereof. Preferred poly--dilute hydrocarbons include Commercially available from Mobil under the tradename puresyn 6 (average molecular weight of about 5 angstroms), pUreSyn (molecular weight of about 3000), and Puresyn 300 (molecular weight of about 6 angstroms) of polydecene. The terpene hydrocarbon is preferably present in an amount of from 0.05% to 1% by weight of the total composition, especially from 2% to 5% and especially from 5% to 3%. Triglyceride oil Suitable triglyceride oil Including oils and fats, including natural oils such as jojoba, soy, sunflower seed oil, rice bran, avocado, almonds, olives, sesame nettle coconut, coconut tree oil, sunflower oil, oil; cocoa butter; tallow , lard fat; hardened oil obtained by hydrogenating the above oil; and synthetic mono-, mono- and diglycerides, such as glyceryl myristate and 2-ethylhexanoic acid 155670.doc 13 201204398 glycerin vinegar. The triglyceride oil is present in an amount of from 0.05% to 1% by weight, especially from 0.2% to 5% and especially from 0.5% to 3% by weight of the composition. Suitable hydrocarbon oils have at least 12 carbon atoms. And include paraffin oil, polyolefin oil, mineral oil, saturated and unsaturated 12 burning, saturated and unsaturated thirteen burning, saturated and unsaturated tetradecane, saturated and unsaturated pentadecane, saturated and unsaturated Six burns and their mixtures. Branching isomers of these compounds as well as longer chain length hydrocarbons may also be used. Polymeric hydrocarbons of C2.6 base monomers, such as polyisobutylene, are also suitable. Preferably, the weight of the composition is from 05% to 丨〇%, especially from 2% to 5% and especially from 0.5% to 3%. Suitable vinegar oils have at least 10 carbon atoms, and 1 includes from fatty acids or alcohols. The obtained ester having a hydrocarbyl chain. A typical ester oil is of the formula r, c〇〇r, wherein UR independently represents a burnt group In the county, the total number of carbon atoms in R• and R is at least 10, preferably at least 20. It is also possible to use a dialkyl group of a carboxylic acid and a trialkyl group and a dilute base. The present invention is present in an amount of from 0 to 10% by weight, especially from m to 5% and especially from about 5% to 3%. A surfactant, comprising a composition preferably comprising from 10 to 14 carbons of a clean anionic boundary. Alkyl. Cleansing Phase The composition of the present invention comprises a cleansing phase preferably in an amount of 1 155670.doc • 14· 201204398 wt% to 26 wt% » The cleansing phase comprises a cleansing surfactant. The cleansing phase anionic surfactant has from 8 to 14 carbons, more preferably from 10 to 12 and most preferably from 12 carbons. More preferably, these carbons are present in a single alkyl group. Preferred anionic cleansing surfactants include alkyl alkali metal sulfates, more preferably burnt (tetra) sulfates. Particularly preferred anionic cleansing surfactants include sodium lauryl ether sulfate. The level of cleaning surfactant is from 5% to 26% by weight of the total composition. Other Components The aqueous shampoo compositions of the present invention may further comprise a suspending agent, however, preferably the compositions comprise less than G.li 4% suspending agent, preferably no suspending agent. The hair 5 vine composition of the present invention is preferably aqueous, that is, it has a water or aqueous solution or a liquid crystal phase as its main component. Suitably, the composition comprises 1 weight based on the total weight of the composition. By weight, preferably 30% by weight to 95% by weight of water. The compositions of the present invention preferably comprise polyfluorene oxide. It is particularly preferred that the polyglycol oxime agent is a polyoxo oxy-milk &amp; for example, by polydiorgano oxymethane (especially polydimethyl methoxy oxane having the CTFA name a polydimethyl 7-oxo having a hydroxyl end group having a CTFA name dimercaptooxyl and an amine-based polydimethyl sulphate having a CTFA name amine-terminated dimethyl polyoxo Oxidized Emulsions Formed by Oxygen) The emulsion droplets in the compositions of the present invention typically have from 微米1 μm to 20 μm, 155670.doc -15- 201204398 more preferably from 0.2 μm to 1 Ok. |e (the auter mean droplet diameter (D3, 2). A suitable method for measuring the average droplet diameter (D3, 2) is to use an instrument such as the Malvern Mastersizer. Measured by laser light scattering. Suitable polyoxynized emulsions for use in the compositions of the present invention are available from polyoxyxylene suppliers such as D〇w Corning and GE Silicones. Use of such preformed poly>5 The advantage of the oxime emulsion is that it is easy to handle and control the poly-stone granule control. Further suitable emulsifiers, such as anionic or nonionic emulsifiers or mixtures thereof, are included and can be prepared by mechanical emulsification processes such as emulsion polymerization or by mechanical emulsification using a high shear mixer. A preformed polyfluorene oxide emulsion having an average droplet diameter (1) 3, 2) of less than 〇 15 μm is referred to as a microemulsion. Examples of suitable preformed polyoxo-emulsions include emulsions DC2-1766, DC2 1784, DC-1785, DC-1786, DC-1788, and microemulsions DC2·1865 and 〇02-1870, all of which are self-contained\¥ (: 〇1:11111§ Obtained. 〇07051 is a preferred polyoxyl. These are all emulsions/microemulsions of dimethylpolyoxyl. Such as DC2-8177 and DC939 (from Dow Corning) and SME25 3 (from Amine-terminated dimethylpolyoxane emulsions of GE SiliC0nes) are also suitable. Certain types of high molecular weight surface-active block copolymers and polyoxo-emulsion emulsions are also known as Suitable, as described, for example, in WO 03/094874. Among such materials, the polyoxymethanol emulsion droplets are preferably composed of a polydiorganomethoxy alkane such as the polydiorganotoxime described above. Formed. A preferred form of the surface active block copolymer is of the formula: 155670.doc 201204398
H0(CH2CH20)x(CH(CH3)CH20)y(CH2CH20)xH 其中x之平均值為4或4以上，且y之平均值為乃或乃以上。 表面活性嵌段共聚物之另一種較佳形式為下式： (H0(CH2CH20)a(CH(CH3)CH20)b)2-N-CH2-CH2- N((0CH2CH(CH3))b(0CH2CH2)a0H)2 其中a之平均值為2或2以上，且b之平均值為6或6以上。 亦可使用上述聚矽氧乳液中之任一者的混合物。 基於組合物之總重量以聚矽氧之總重量計’上述聚矽氧 乳液一般以0.05%至15。/。，較佳〇.5%至12%之含量存在於本 發明組合物中。 聚矽氧較佳以0.5重量％至15重量％，更佳！重量％至12重 量％存在。 本發明組合物可視情況含有如下文所描述之其他成分以 增強效能及/或消費者接受性。組合物可包括共界面活性 劑，以幫助賦予組合物美觀、物理或清潔性質。 共界面活性劑之實例為非離子性界面活性劑，基於組合 物之總重量，其可占〇.5重量％至1〇重量％，較佳〇 7重量％ 至6重量％之量。 舉例而言，本發明洗髮精組合物中可包括之代表性非離 子性界面活性劑包括脂族（C8_Ci8) 一級或二級直鏈或分支 鏈醇或酚與環氧烷（通常為環氧乙烷且一般具有6至3〇個氧 化乙烯基團）之縮合產物。 其他代表性非離子性界面活性劑包括單或二烷基烷醇醯 胺。只例包括可可單或二乙醇醯胺及可可單異丙醇醯胺。 155670.doc 17 201204398 可可單乙醇醯胺。 中的其他非離子性界面活 尤其較佳非離子性界面活性劑為 可包括於本發明洗髮精組合物 性劑為烷基多糖苷（APG)。诵骨，Λ ^ _ J通㊉.，apg為包含連接（視情況 經由橋聯基團）至一或多個播其夕七饥^ 〆W裾基之嵌段的烷基之非離子性 界面活性劑。較佳APG係由下式定義· R〇 ' (G)n 其中R為飽和或不飽和分支鏈或直㈣基，且g為醜基。 R可表示自約C5至約C2。之平均烷基鏈長度。較佳r表示 自約C8至約Cl2之平均烷基鏈長度。最佳為尺之值介於約 9.5與約1().5之間。〇可係選自醣殘基，且較佳為 糖普。G可係選自包含葡萄糖、木糖、乳糖、果糖、甘露 糖及其衍生物之群。G較佳為葡萄糖。 聚合度η之值可為約1至約1〇或1〇以上。n之值較佳介於 約1.1至約2之間。η之值最佳介於約i 3至約15之間。. 用於本發明中之合適的烷基多糖苷可為市售的，且包括 例如名為：Oramix NS1〇 ex Seppic ; p丨 anUren 12〇〇 及 Plantaren 2000 ex Henkel之物質。 可包括於本發明組合物中之其他糖衍生的非離子性界面 活性劑包括C1()-C18 N-烷基（CrC6)聚羥基脂肪酸醯胺，諸 如匸12-(：18>1-甲基葡糖醯胺（如例如|〇 92 06154及1185194 639中所描述）；及冰烷氧基聚羥基脂肪酸醯胺，諸如Ci〇_ CuN-(3 -曱氧基丙基）葡糖酿胺。 共界面活性劑之較佳實例為兩性或兩性離子界面活性 劑，其可占基於總體組合物之總重量〇.5重量％至約1〇重量 155670.doc -18· 201204398 %，較佳1重量。/〇至6重量％範圍内之量。 兩性或兩性離子界面活性劑之實例包括烷基胺氧化物、 院基甜菜鹼、烷基醯胺基丙基甜菜鹼、烷基磺基甜菜驗 (石黃基甜菜鹼）、甘胺酸烷基酯、羧基甘胺酸烷基酯、兩性 乙酸烧基酯、兩性丙酸烧基酯、兩性甘胺酸院基醋、院基 醯胺基丙基羥基磺基甜菜鹼、牛磺酸醯基酯及麩胺酸醯基 酯’其中烷基及醯基具有8至19個碳原子。用於本發明洗 髮精中的典型兩性及兩性離子界面活性劑包括月桂胺氧化 物' 可可二甲基磺基丙基甜菜鹼、十二烷基甜菜鹼、可可 醢胺基丙基甜菜臉及可可兩性乙酸鈉。 尤其較佳兩性或兩性離子界面活性劑為可可醮胺基丙基 甜菜鹼。 前述兩性或兩性離子界面活性劑中之任一者的混合物亦 可為合適的。較佳混合物為可可醯胺基丙基甜菜鹼與如上 文所描述之其他兩性或兩性離子界面活性劑的混合物。較 佳的其他兩性或兩性離子界面活性劑為可可兩性乙酸鈉。 本心明組合物可含有其他成分以用於增強效能及/或消 費者接受性。此等成分包括芳香劑、染料及顏料、值調 節劑 '珠光劑或乳白劑、黏度調節劑，及防腐劑或抗徼生 物劑。此等成分令每-者係以有效實現其目的之量存在。 一般而言，以總體組合物之至多5重量％之含量個別地包 括此等視情.況選用的成分。 本發明將由以下非限制性實例進_步說明，除非另有規 疋’否則其中所弓丨用之所有百分比均為基於總重量之重量 155670.doc -19. 201204398 百分比β 實例 组分 %ad 1 2 3 4 A 月桂醇醚硫酸鈉 70 17.14 17.14 17.14 17.14 17.14 可可醯胺基丙基甜菜 驗 30 5.33 5.33 - 5.33 可可醯胺ΜΕΑ 85 - - 1.0 1.0 • 乙二醇二硬脂酸酯 35 4.0 4.0 4.0 4.0 4.0 二甲聚矽氧醇 50 4.0 4.0 4.0 4.0 4.0 十六燒基十八烧醯基 硫酸鈉 100 0.6 0.6 0.6 0.6 0.6 +六醇十八醇混合物 100 1.0 1.0 1.0 1.0 1.0 氯化十六烧基三曱基 銨 29 - 0.17 _ 0.17 - 氣化二十二烷基三甲 基錄 77.5 0.06 - 0.06 - 0.06 礦物油 100 0.5 0.5 0.5 0.5 0.5 疏水性經改質瓜爾膠 經丙基三甲基氣化錄 100 0.2 0.2 0.2 0.2 - 瓜爾膠羥丙基三曱基 氣化敍 100 - - - - 0.2 香水 100% 0.8 0.8 0.8 0.8 0.8 DMDM乙内醯脲及胺 基甲酸3-碘-2-丙炔基 丁酯 50% 0.2 0.2 0.2 0.2 0.2 氯化鈉 100% 黏度 黏度 黏度 黏度 黏度 Aqua 適量至 100 適量至 100 適量至 100 適量至 100 適量至 100 實例A 30 U下所量測之布洛克菲爾德黏度(viscosity Brookfield)=7.6 Pa.s 鬆弛時間=0,03 s 在45°C下儲存3個月後洗髮精瓶底出現15 mm透明層 實例1至4 3〇 C下所量測之布洛克菲爾德黏度=22.0 Pa.s 鬆弛時間=0.055 s 在45°C下儲存3個月後洗髮精瓶底出現至多0.5 mm透明層 155670.doc 20 ·H0(CH2CH20)x(CH(CH3)CH20)y(CH2CH20)xH wherein the average value of x is 4 or more, and the average value of y is either or more. Another preferred form of the surface active block copolymer is of the formula: (H0(CH2CH20)a(CH(CH3)CH20)b)2-N-CH2-CH2-N((0CH2CH(CH3))b(0CH2CH2 a0H)2 wherein the average value of a is 2 or more, and the average value of b is 6 or more. Mixtures of any of the above polyoxyl emulsions can also be used. The above polyoxyxide emulsion is generally from 0.05% to 15 based on the total weight of the composition based on the total weight of the composition. /. Preferably, the content of 5% to 12% is present in the composition of the present invention. The polyoxygen is preferably from 0.5% by weight to 15% by weight, more preferably! From weight to 12% by weight. The compositions of the present invention may optionally contain other ingredients as described below to enhance potency and/or consumer acceptance. The composition can include a co-surfactant to help impart aesthetic, physical or cleansing properties to the composition. An example of a co-surfactant is a nonionic surfactant which may comprise from 5% by weight to 1% by weight, based on the total weight of the composition, preferably from 7% by weight to 6% by weight. By way of example, representative nonionic surfactants which may be included in the shampoo compositions of the present invention include aliphatic (C8-Ci8) primary or secondary linear or branched alcohols or phenols and alkylene oxides (usually epoxy). The condensation product of ethane and generally having 6 to 3 oxirane groups. Other representative nonionic surfactants include mono or dialkyl alkanolamines. Examples include cocoa mono- or diethanolamine and cocoa monoisopropanolamine. 155670.doc 17 201204398 Cocoa monoethanolamine. Other nonionic interfacial activities are particularly preferred. The nonionic surfactant is an alkyl polyglycoside (APG) which may be included in the shampoo composition of the present invention.诵骨,Λ ^ _ J通十., apg is a nonionic interface containing an alkyl group of a link (optionally via a bridging group) to one or more blocks of a stagnation Active agent. Preferably, the APG is defined by the formula: R 〇 ' (G)n wherein R is a saturated or unsaturated branched or straight (tetra) group, and g is a ugly group. R can be expressed from about C5 to about C2. The average alkyl chain length. Preferably, r represents the average alkyl chain length from about C8 to about Cl2. The optimum value is between about 9.5 and about 1 (). The oxime may be selected from a sugar residue, and is preferably saccharide. G may be selected from the group consisting of glucose, xylose, lactose, fructose, mannose and derivatives thereof. G is preferably glucose. The degree of polymerization η may range from about 1 to about 1 Torr or more. The value of n is preferably between about 1.1 and about 2. The value of η is optimally between about i 3 and about 15. Suitable alkyl polyglycosides for use in the present invention are commercially available and include, for example, the materials named: Oramix NS1〇 ex Seppic; p丨 anUren 12〇〇 and Plantaren 2000 ex Henkel. Other sugar-derived nonionic surfactants which may be included in the compositions of the present invention include C1()-C18 N-alkyl (CrC6) polyhydroxy fatty acid decylamines such as 匸12-(:18>1-methyl Glucosamine (as described, for example, in |〇92 06154 and 1185194 639); and an ice alkoxy polyhydroxy fatty acid guanamine such as Ci〇_CuN-(3-methoxypropyl) glucosamine. A preferred example of the co-surfactant is an amphoteric or zwitterionic surfactant which may comprise from 5% by weight to about 1% by weight based on the total weight of the total composition of 155670.doc -18.201204398%, preferably 1 weight. /〇 to an amount in the range of 6% by weight. Examples of amphoteric or zwitterionic surfactants include alkylamine oxides, hospital betaines, alkylguanidinopropyl betaines, alkylsulfobels ( Alkaloid betaine, alkyl glycinate, alkyl carboxyglycolate, amphoteric acetate, amphoteric propionate, amphoteric glycosyl vinegar, amphoteric propyl propyl Hydroxysulfobetaine, decyl taurate and glutamic acid glutamic acid ester wherein the alkyl and thiol groups have from 8 to 19 carbon atoms Typical amphoteric and zwitterionic surfactants useful in the shampoos of the present invention include laurylamine oxide 'cocodyl dimethyl sulfopropyl betaine, lauryl betaine, cocoa propyl propyl beet face and Sodium cocoamphoacetate. Particularly preferred amphoteric or zwitterionic surfactant is cocoApropyl propyl betaine. Mixtures of any of the foregoing amphoteric or zwitterionic surfactants may also be suitable. Mixture of cocoApropyl propyl betaine with other amphoteric or zwitterionic surfactants as described above. Preferred other amphoteric or zwitterionic surfactants are sodium cocoamphoacetate. The present compositions may contain other Ingredients for enhancing efficacy and/or consumer acceptance. These ingredients include fragrances, dyes and pigments, value modifiers [pearl or opacifiers, viscosity modifiers, and preservatives or anti-caries agents. The ingredients are present in an amount effective to achieve their purpose. In general, these conditions are individually included in the amount of up to 5% by weight of the total composition. The invention will be described by the following non-limiting examples, unless otherwise stated, otherwise all percentages used in the invention are based on the total weight of the weight 155670.doc -19. 201204398 percentage β example component %ad 1 2 3 4 A Sodium lauryl ether 70 17.14 17.14 17.14 17.14 17.14 Cocoa propyl propyl beet test 30 5.33 5.33 - 5.33 Cocoaamine ΜΕΑ 85 - - 1.0 1.0 • Ethylene glycol distearate 35 4.0 4.0 4.0 4.0 4.0 Dimethylpolyoxyl 50 4.0 4.0 4.0 4.0 4.0 Hexadecyl octadecyl sulfonate 100 0.6 0.6 0.6 0.6 0.6 + hexacocosanol mixture 100 1.0 1.0 1.0 1.0 1.0 Chlorinated ten Hexacarbyltrimethylammonium 29 - 0.17 _ 0.17 - gasified behenyltrimethylamine 77.5 0.06 - 0.06 - 0.06 Mineral oil 100 0.5 0.5 0.5 0.5 0.5 Hydrophobic modified guar gum with propyl three Methyl gasification record 100 0.2 0.2 0.2 0.2 - guar hydroxypropyl tridecyl vaporization 100 - - - - 0.2 Perfume 100% 0.8 0.8 0.8 0.8 0.8 DMDM carbendazim and carbamic acid 3-iodo - 2-propynyl butyl ester 50% 0.2 0.2 0.2 0.2 0.2 sodium chloride 100% Viscosity Viscosity Viscosity Aqua Amount to 100 Appropriate amount to 100 Appropriate amount to 100 Appropriate amount to 100 Appropriate amount to 100 Example B Brookfield viscosity measured under 30 U (viscosity Brookfield) = 7.6 Pa.s Relaxation time = 0,03 s After storage for 3 months at 45 ° C, 15 mm transparent layer appeared at the bottom of the shampoo bottle. Example 1 to 4 3 〇C measured Brockfield viscosity = 22.0 Pa.s Relaxation time = 0.055 s at 45 ° C After storage for 3 months, the bottom of the shampoo bottle appears at most 0.5 mm transparent layer 155670.doc 20 ·