TW201142501A - Photosensitive coloring composition and color filter - Google Patents

Photosensitive coloring composition and color filter Download PDF

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TW201142501A
TW201142501A TW100106836A TW100106836A TW201142501A TW 201142501 A TW201142501 A TW 201142501A TW 100106836 A TW100106836 A TW 100106836A TW 100106836 A TW100106836 A TW 100106836A TW 201142501 A TW201142501 A TW 201142501A
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coloring composition
fluorenyl
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TW100106836A
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TWI438570B (en
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Kanako Mizuno
Isao Shigemori
Takatoshi Kubota
Masaki Kanno
Sotai Wada
Naoki Egusa
Kenji Hiki
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Toyo Ink Mfg Co
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Priority claimed from JP2011003524A external-priority patent/JP5673111B2/en
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/031—Organic compounds not covered by group G03F7/029
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/80—[b, c]- or [b, d]-condensed
    • C07D209/82—Carbazoles; Hydrogenated carbazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D498/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/105—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having substances, e.g. indicators, for forming visible images

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Materials For Photolithography (AREA)
  • Polymerisation Methods In General (AREA)
  • Optical Filters (AREA)

Abstract

Provided are a photosensitive coloring composition and a color filter using the same. The photosensitive coloring composition has a high sensitivity and a retention of film thickness even if the composition has high pigment contents or larger film thickness. Further, the photosensitive coloring composition has excellent properties in linearity, pattern shape, resolution, development resistance and chemical resistance. The photosensitive composition of the present invention has a high sensitivity and can form excellent filter segments of each color and a black matrix pattern by using specific compounds as photopolymerization initiators, even if the composition has high pigment contents or the film thickness forming of the color filter segments and the black matrix are larger. Therefore, the photosensitive coloring composition according to the present invention may be used to obtain a color filter having high quality.

Description

201142501 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種感光性著色組合物，尤其係有關對 於液晶顯示裝置或固體攝像元件中使用的滤色器（color filter)中的紅、綠、藍等各色濾波器節（filter segment) 以及黑色矩陣（black matrix)等的形成有用的高感度的感 光性著色組合物。此外，本發明係有關使用該感光性著色 組合物形成的濾色器。 【先前技術】 應色器’是在玻璃等透明基板的表面上將2種以上不 同色相的微細的帶狀（條紋狀）濾波器節平行或交叉配置而 構成的，或者是將微細的濾波器節在縱橫向上以規定排列 進行配置而構成的。濾波器節具有數微米至數百微米的微 細尺寸，並且每個色相以規定的排列整齊配置。 通常，在彩色液晶顯示裝置中，藉由蒸鍍或濺鍍在濾 色器上形成用於驅動液晶的透明電極，並在該透明電極上 進步形成用於使液晶以一定方向取向的取向膜。為了充 分獲得此等透明電極以及取向膜的性能，該等的形成一般 需要在200t以上、較佳為在230X：以上的高溫下進行。 因此，目前作為濾色器的製造方法，使用耐光性、耐 熱性都優異的顏料作為著色材料的所謂顏料分散法的方法 成為主流。 在使用顏料分散法的情況下，將在感光性樹脂溶液中 分散了顏料的感光性著色組合物（顏料抗蝕劑）塗布到玻璃 4 322802 201142501 等透明基板上，藉由乾燥除去馨劑， 顏色的圖案曝光，接著，藉ά 、、、進仃—種濾色器 形成第色關案，==料雜料曝光部分， 對於所有的遽色器顏色依;==熱等處理後， 造濾色器。 複同樣的#作’由此可以製 車導=====置’作為彩色液晶電视、汽 了巨大… 體型筆記本電腦已 桌上’而且作為具有節省能源、節省空間特= 但現 顯==!!示器以及電視機也開始普及。彩= 狀^置作絲代以往eRT的_裝置㈣t目邑夜曰曰 疋液晶顯示裝置的顏色再現特性比CRT差。 因此，在配置了各色濾波器節 現性的要求残提高。 $网顏色再 節：二=τ度’通常在渡色器的各色據波器 來，從产;: 黑色矩陣的形成材料，從近年 Α問題、低反射化以及低成本化的觀點考慮 路费里m中分散有遮光性色素的樹脂製黑色矩陣代替金屬 ^、、色矩陣’正受到關注。然❿’在樹脂製黑色矩陣中， 2屬路製黑色矩陣相比，存在有遮光性（光密度）低的問 了提高遽色11的顏色再現特性以及提高黑色矩陣的 大.，需要增加感光性著色組合物中的顏料含量或者增 降==但是’在增加簡含4的方法存在有感度下 ‘”、衫性和解析度變差等問題。而在增大膜厚的方法令， 322802 5 201142501 存在有曝光光線無法到達膜底部，並且圖案形狀較差等問 題。 為了解決此等問題，需要感光性著色組合物的高感度 化’而通常進行（1)賦予樹脂反應性雙鍵、（2)選擇光聚合 引發劑、增感劑，或進行光聚合引發劑、增感劑的增量、 (3)選擇單體或進行單體的增量等，作為實例，可以列舉專 利文獻1和2。 現有技術文獻 專利文獻 專利文獻1 :日本特開2001-264530號公報 專利文獻2:日本特開2003-156842號公報 【發明内容】 (發明要解決的問題） 然而，若僅賦予樹脂雙鍵，選擇光聚合引發劑、增感 劑和單體’則提高感度的效果有限。特別是在增量光聚合 引發劑時’會因光聚合引發劑特有的顏色而著色，並且導 致耐熱性下降、透光率降低、以及解析度下降等。此外， 在增量單體時，產生發黏等問題。 因此本發明的目的在於提供一種即使顏料含量高或 者膜厚較厚，也具有高感度，並且殘膜率高，而且直線性、 圖案形狀、解析度、耐顯影性、耐藥品性優異的感光性著 色、、且〇物以及使用該感光性著色組合物形成的滤色器。 (解決問題的方法） 本發明的感光性著色組合物，為了具有高感度，並且 6 322802 201142501 知到優異的直線性、圖案形狀、解析度、耐顯影性、耐藥 品性’其特徵在於使用下述通式（1)或（11)所表示的光聚合 • 引發劑。 也就是說，本發明的感光性著色組合物是含有下述式 (1)或（11)所表示的光聚合引發劑（A) ’並且含有樹脂（b)、 光聚合性化合物（C)和顏料（D)的感光性著色組合物。 通式（1)201142501 VI. Description of the Invention: [Technical Field] The present invention relates to a photosensitive coloring composition, and more particularly to red and green in a color filter used in a liquid crystal display device or a solid-state imaging device. A useful high-sensitivity photosensitive coloring composition such as a filter segment or a black matrix such as blue or blue. Further, the present invention relates to a color filter formed using the photosensitive coloring composition. [Prior Art] The color eliminator is configured by arranging two or more fine strip-shaped (striped) filter segments of different hues on the surface of a transparent substrate such as glass in parallel or in a cross, or a fine filter. The nodes are arranged in a predetermined arrangement in the vertical and horizontal directions. The filter section has a fine size of several micrometers to several hundred micrometers, and each hue is arranged neatly in a prescribed arrangement. Generally, in a color liquid crystal display device, a transparent electrode for driving a liquid crystal is formed on a color filter by evaporation or sputtering, and an alignment film for aligning liquid crystal in a certain direction is formed on the transparent electrode. In order to sufficiently obtain the properties of the transparent electrode and the alignment film, the formation of these transparent layers is generally required to be carried out at a high temperature of 200 t or more, preferably 230 X or more. Therefore, as a method for producing a color filter, a method of using a pigment dispersion method in which a pigment excellent in light resistance and heat resistance is used as a coloring material has been mainstream. In the case of using the pigment dispersion method, a photosensitive coloring composition (pigment resist) in which a pigment is dispersed in a photosensitive resin solution is applied onto a transparent substrate such as glass 4 322802 201142501, and the coloring agent is removed by drying. The pattern is exposed, and then, by means of ά, ,, 仃 仃 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤 滤Color. The same #作' can be used to make the car guide ===== set as a color LCD TV, the steam is huge... The laptop is on the table and it has energy saving and space saving = but now = =!! The display and the TV have also become popular. Color = shape ^ set as the wire of the past eRT _ device (four) t-eye 邑 曰曰 疋 liquid crystal display device color reproduction characteristics than CRT. Therefore, the requirement for the performance of each color filter is increased. $Net color re-section: two = τ degrees 'usually in the color filter of the color filter, from the production;: The formation of the black matrix, from the point of view of recent problems, low reflection and low cost A black matrix made of a resin in which a light-shielding pigment is dispersed in m is attracting attention instead of a metal color and a color matrix. Then, in the black matrix of the resin, the light-shielding (optical density) is lower than that of the two-system black matrix, and the color reproduction characteristic of the black color 11 is increased and the black matrix is increased. The content or increase or decrease of the pigment in the coloring composition == but 'there is sensitivity under the method of increasing the inclusion of 4', the problem of poorness of the shirting and resolution, etc., and the method of increasing the film thickness, 322802 5 201142501 There is a problem that the exposure light does not reach the bottom of the film, and the shape of the pattern is poor. In order to solve these problems, the high sensitivity of the photosensitive coloring composition is required, and (1) the resin-reactive double bond is usually given, (2) A photopolymerization initiator, a sensitizer, or a photopolymerization initiator, an increase in the sensitizer, (3) selection of a monomer, or an increase in the amount of the monomer, etc., as examples, Patent Documents 1 and 2 can be cited. CITATION LIST Patent Literature Patent Literature 1: JP-A-2001-264530 (Patent Document 2) Japanese Laid-Open Patent Publication No. 2003-156842 (Summary of the Invention) When the resin double bond is selected, the photopolymerization initiator, the sensitizer, and the monomer are selected, and the effect of improving the sensitivity is limited. Especially in the case of the incremental photopolymerization initiator, the color of the photopolymerization initiator is colored, and the color is caused. The heat resistance is lowered, the light transmittance is lowered, the resolution is lowered, etc. Further, when the monomer is increased, problems such as stickiness are generated. Therefore, an object of the present invention is to provide a film having a high pigment content or a thick film thickness. A color filter having a high sensitivity and a high residual film ratio, and having excellent linearity, pattern shape, resolution, development resistance, and chemical resistance, and a color filter formed of the photosensitive coloring composition. (Means for Solving the Problem) In order to have high sensitivity, the photosensitive coloring composition of the present invention has excellent linearity, pattern shape, resolution, development resistance, and chemical resistance in the case of 6 322 802 201142501. The photopolymerization initiator represented by the above formula (1) or (11). That is, the photosensitive coloring composition of the present invention contains the following formula (1) or (11). Photopolymerization initiator shown (A) 'and containing the resin (b), a photosensitive coloring composition photopolymerizable compound (C) and a pigment (D) of the general formula (1)

(式（1)中，Ri表示取代或未取代的烯基（alkenyi)、取 代或未取代的烧基、取代或未取代的烧氧基、取代或未取 代的芳基、取代或未取代的芳氧基、取代或未取代的雜環 基、取代或未取代的雜環氧基、取代或未取代的烧基硫基 (alkylsulfanyl)、取代或未取代的芳基硫基 (arylsulfanyl)、取代或未取代的烷基亞磺醯基、取代或 未取代的芳基亞續酿基、取代或未取代的烧基續醢基、取 代或未取代的芳基確醯基、取代或未取代的醯基、取代或 未取代的醯氧基、取代或未取代的胺基、取代或未取代的 膦基（phosphinoyl)、取代或未取代的胺基甲醯基 (carbamoyl)、或取代或未取代的胺磺醯基（suifamoyl)。 322802 7 201142501 r2表示取代或未取代的烯基、取代或未取代的烷基、 取代或未取代的烧氧基、取代或未取代的芳基、取代或未 取代的芳氧基、取代或未取代的雜環基、取代或未取代的 雜環氧基、取代或未取代的烷基硫基、取代或未取代的芳 基硫基、取代或未取代的烷基亞磺酿基、取代或未取代的 芳基亞磺醯基、取代或未取代的烷基磺醯基、取代或未取 代的芳基磺醯基、取代或未取代的醯氧基、或取代或未取 代的胺基。 R3至R5各自獨立地表示氫原子、鹵原子、氰基、硝基、 取代或未取代的烯基、取代或未取代的烷基、取代或未取 代的烷氧基、取代或未取代的芳基、取代或未取代的芳氧 基、取代或未取代的雜環基、取代或未取代的雜環氧基、 取代或未取代的烷基硫基、取代或未取代的芳基硫基、取 代或未取代的醯基、或取代或未取代的胺基。 R6至R9各自獨立地表示氫原子、鹵原子、氰基、鹵代 烷基（haloalkyl)、取代或未取代的烧基、取代或未取代的 烷氧基、取代或未取代的芳基、取代或未取代的芳氧基、 取代或未取代的雜環基、取代或未取代的雜環氧基、取代 或未取代的烯基、取代或未取代的烷基硫基、取代或未取 代的芳基硫基、取代或未取代的烷基亞磺醯基、取代或未 取代的芳基亞續酿基、取代或未取代的烧基續醢基、取代 或未取代的芳基4醯基、取代或未取代的絲、或下述通 式（2)的取代基。 通式（2) 322802 8 201142501 R · Ο(In the formula (1), Ri represents a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted one. An aryloxy group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkylsulfanyl group, a substituted or unsubstituted arylsulfanyl group, a substitution Or unsubstituted alkylsulfinyl, substituted or unsubstituted aryl, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted Mercapto, substituted or unsubstituted anthraceneoxy, substituted or unsubstituted amino, substituted or unsubstituted phosphinoyl, substituted or unsubstituted carbamoyl, or substituted or unsubstituted Sulfamoyl. 322802 7 201142501 r2 represents a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or not Substituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or Unsubstituted heterocyclic oxy, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted arylsulfin a substituted, unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted amine group. R3 to R5 each independently represent hydrogen Atom, halogen atom, cyano group, nitro group, substituted or unsubstituted alkenyl group, substituted or unsubstituted alkyl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryl group, substituted or unsubstituted aryl group An oxy group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted fluorenyl group, Or a substituted or unsubstituted amino group. R6 to R9 each independently represent a hydrogen atom, a halogen atom, a cyano group, a haloalkyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituent or Unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or not Heterocyclyl, substituted or unsubstituted heterocyclic oxy, substituted or unsubstituted alkenyl, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted alkane A sulfinyl group, a substituted or unsubstituted aryl fluorinated group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted wire, or the following Substituent of the formula (2). Formula (2) 322802 8 201142501 R · Ο

I2 II 一C—CsN—O-'C—Ri, Ο (式（2)中，Rr和L與Ri和R2同義。） R1〇至Ru各自獨立地表示氣原子、鹵原子、氰基、硝基、 鹵代烷基、取代或未取代的烷基亞磺醯基、取代或未取代 的芳基亞磺酿基、取代或未取代的燒基磺醯基、取代或未 取代的芳基磺醯基、或取代或未取代的醯基，但是心至Ru 不全部同時為氫原子。此外，R10至的至少一個為;G肖基或 下述通式（3)。） 通式（3) 亨18I2 II -C-CsN-O-'C-Ri, Ο (In the formula (2), Rr and L are synonymous with Ri and R2.) R1〇 to Ru each independently represent a gas atom, a halogen atom, a cyano group, a nitrate Alkyl, haloalkyl, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted arylsulfinyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted arylsulfonyl Or a substituted or unsubstituted fluorenyl group, but not all of the core to Ru are hydrogen atoms at the same time. Further, at least one of R10 to is G group or the following formula (3). ) General formula (3) Heng 18

15 〇 (式（3)中，R15至R19各自獨立地表示氫原子、鹵原子、 氰基、硝基、鹵代烧基、取代或未取代的烧基、取代或未 取代的烧氧基、取代或未取代的芳基、取代或未取代的芳 氧基、取代或未取代的雜環基、取代或未取代的雜環氧基、 取代或未取代的烯基、取代或未取代的烷基硫基、取代或 未取代的芳基硫基、取代或未取代的醯基、或取代或未取 代的胺基。）) 通式（11) 9 322802 20114250115 〇 (In the formula (3), R15 to R19 each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, a halogenated alkyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkane a thiol group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted fluorenyl group, or a substituted or unsubstituted amine group.)) Formula (11) 9 322802 201142501

(通式（11)中，RS1表示取代或未取代的烯基、取代或未 取代的院基、取代或未取代的烧氧基、取代或未取代的芳 基、取代或未取代的芳氧基、取代或未取代的雜環基、取 代或未取代的雜環氧基、取代或未取代的烷基硫基、取代 或未取代的芳基硫基、取代或未取代的烷基亞磺醯基、取 代或未取代的芳基亞磺酿基、取代或未取代的烷基磺醯 基、取代或未取代的芳基磺醯基、取代或未取代的醯基、 取代或未取代的醯氧基、取代或未取代的胺基、取代或未 取代的膦基、取代或未取代的胺基甲醯基、或取代或未取 代的胺磺醯基。 R52表示被環烧基取代的碳數為1至20的烧基。 至R55各自獨立地表示氫原子、鹵原子、氰基、硝基、 取代或未取代的烯基、取代絲取代的絲、取代或未取 代的烷氧基、取代或未取代的芳基、取代或未取代的芳氧 基、、取代或未取代的雜環基、取代或未取代的雜環氧基、 取代或未取代的烷基硫基、取代或未取代的芳基硫基、取 代或未取代的醯基、或取代或未取代的胺基。 R56至R58各自獨立地表示氫原子、鹵原子、氰基、硝基、 322802 10 201142501 鹵代烷基、取代或未取代的烧基亞磺醯基、取代或未取代 的芳基亞續醢基、取代或未取代的烷基績醯基、取代或未 取代的芳基磺醯基、或取代或未取代的醯基。 R59至R63各自獨立地表示氫原子、鹵原子、氰基、硝基、 鹵代烷基、取代或未取代的烷基、取代或未取代的烷氧基、 取代或未取代的芳基、取代或未取代的芳氧基、取代或未 取代的雜環基、取代或未取代的雜環氧基、取代或未取代 的烯基、取代或未取代的烷基硫基、取代或未取代的芳基 硫基、取代或未取代的醯基、或取代或未取代的胺基。 R64表示氫原子、鹵原子、氰基、硝基、取代或未取代 的嫦基、取代或未取代的烷基、取代或未取代的烷氧基、 取代或未取代的芳基、取代或未取代的芳氧基、取代或未 取代的雜環基、取代或未取代的雜環氧基、取代或未取代 的烧基硫基、取代或未取代的芳基硫基、取代或未取代的 醯基、或取代或未取代的胺基。） 此外’本發明係有關前述的感光性著色組合物，其特 徵在於進—步含有其它的光聚合引發劑（Y)。 此外’本發明係有關前述的感光性著色組合物，其特 徵在於其它光聚合引發劑⑺包含選自笨乙綱系化合物、膊 系化合物和咪唾系化合物所構成群組中的至少一種以上的 化合物。 此外’本發明係有關前述的感光性著色組合物，其特 徵在於進-步含有多官能硫醇⑺。 此外’本發明係有關一種濾色器，其特徵在於在透明 11 322802 201142501 基板上具有由前述感光性著色組合物所形成的濾波器節和 /或黑色矩陣。 (發明效果） 本發明的感光性著色組合物，藉由使用特定的肟酯 (oxime ester)系化合物作為光聚合引發劑，即使顏料含量 高或者各色濾波器節和黑色矩陣的形成膜厚較厚，也具有 高感度，並且可以形成具有優異的直線性、圖案形狀、解 析度、耐顯影性、财藥品性的各色濾、波器節和黑色矩陣圖 案。 因此，藉由使用本發明的感光性著色組合物，可以得 到高品質的濾色器。 【實施方式】 首先，對本發明的感光性著色組合物進行具體說明。 本發明的感光性著色組合物，含有上述通式（1)或（11) 所表示的光聚合引發劑（A)，並且含有樹脂（B)、光聚合性 化合物（C)和顏料（D)。 包含上述式（1)和（11)所表示的化合物的光聚合引發 劑（A)，可以得到感度高，並特別是高殘膜率的塗膜，因此 可以得到濾色器的生產穩定性優異的感光性著色組合物。 藉由使用含有該光聚合引發劑的感光性著色組合物，可以 形成具有優異的直線性、圖案形狀、解析度、耐顯影性、 耐藥品性的濾波器節和黑色矩陣。 此外，藉由併用其它引發劑，可以得到更良好的耐藥 品性。 12 322802 201142501 〈光聚合弓丨發劑（A)&gt; 本發明的感光性著色組合物中含有的光聚合引發劑 (A) ’為通式（1)或（11)所表示的化合物。 首先，對通式（1)所表示的光聚合引發劑（A)進行說明。 通式（1)(In the formula (11), RS1 represents a substituted or unsubstituted alkenyl group, a substituted or unsubstituted institutional group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group. a substituted, unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted alkyl sulfinic acid Mercapto, substituted or unsubstituted arylsulfinyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted arylsulfonyl, substituted or unsubstituted fluorenyl, substituted or unsubstituted a methoxy group, a substituted or unsubstituted amino group, a substituted or unsubstituted phosphino group, a substituted or unsubstituted aminomethyl fluorenyl group, or a substituted or unsubstituted amine sulfonyl group. R52 represents a group substituted by a cycloalkyl group. a carbon group having 1 to 20 carbon atoms. Each of R55 independently represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkenyl group, a substituted silk substituted silk, a substituted or unsubstituted alkoxy group. , substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted Heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted fluorenyl group, or substituted or unsubstituted amino group R56 to R58 each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, a 322802 10 201142501 haloalkyl group, a substituted or unsubstituted sulfinyl sulfinyl group, a substituted or unsubstituted aryl sulfhydryl group, a substituted or unsubstituted alkyl fluorenyl group, a substituted or unsubstituted aryl sulfonyl group, or a substituted or unsubstituted fluorenyl group. R59 to R63 each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, Haloalkyl, substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted Heterocyclicoxy, substituted or unsubstituted alkenyl, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted fluorenyl, or substituted or unsubstituted amino R64 represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, Alken or unsubstituted fluorenyl, substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic group a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted fluorenyl group, or a substituted or unsubstituted amino group.) The present invention relates to the aforementioned photosensitive coloring composition characterized in that it further contains another photopolymerization initiator (Y). Further, the present invention relates to the photosensitive coloring composition described above, characterized in that the other photopolymerization initiator (7) contains at least one selected from the group consisting of a compound of a genus, a compound, and a stilbene compound. Compound. Further, the present invention relates to the aforementioned photosensitive coloring composition characterized in that it further contains a polyfunctional thiol (7). Further, the present invention relates to a color filter characterized by having a filter section and/or a black matrix formed of the aforementioned photosensitive coloring composition on a substrate of transparent 11 322802 201142501. (Effect of the Invention) The photosensitive coloring composition of the present invention has a high film content or a thick film thickness of each color filter segment and black matrix by using a specific oxime ester compound as a photopolymerization initiator. It also has high sensitivity, and can form various color filters, waver segments, and black matrix patterns having excellent linearity, pattern shape, resolution, development resistance, and chemical properties. Therefore, by using the photosensitive coloring composition of the present invention, a high-quality color filter can be obtained. [Embodiment] First, the photosensitive coloring composition of the present invention will be specifically described. The photosensitive coloring composition of the present invention contains the photopolymerization initiator (A) represented by the above formula (1) or (11), and contains the resin (B), the photopolymerizable compound (C), and the pigment (D). . The photopolymerization initiator (A) containing the compound represented by the above formulas (1) and (11) can provide a coating film having high sensitivity and particularly high residual film ratio, and thus excellent color filter production stability can be obtained. Photosensitive coloring composition. By using a photosensitive coloring composition containing the photopolymerization initiator, a filter segment and a black matrix having excellent linearity, pattern shape, resolution, development resistance, and chemical resistance can be formed. In addition, by using other initiators in combination, better resistance to chemicals can be obtained. 12 322802 201142501 <Photopolymerization hair styling agent (A)&gt; The photopolymerization initiator (A) contained in the photosensitive coloring composition of the present invention is a compound represented by the formula (1) or (11). First, the photopolymerization initiator (A) represented by the formula (1) will be described. General formula (1)

通式（1)中，R,表示取代或未取代的稀基、取代或未取 代的烷基、取代或未取代的烷氧基、取代或未取代的芳基、 取代或未取代的芳氧基、取代或未取代的雜環基、取代或 未取代的雜環氧基、取代或未取代的絲硫基、取代或未 取代的芳基硫基、取代或未取代的坑基亞績醯基、取代或 未取代的芳基亞俩基、取代或未取代眺基伽基、取 代或未取代的芳基料基、取代絲取代㈣基、取代或 未取代㈣氧基、喊絲取代的縣、取傾未取代的 膦基、取代或未取代的絲甲喊、絲代或未取代的胺 磺醯基。 作為匕中的取代或未取代的婦基，可以列舉碳數為^ 至18的直鏈狀、支鏈狀、單環狀或縮合多環㈣基，並且 該等的結構中也可以具有多個碳碳雙鍵，作為具體例，可 322802 13 201142501 以列舉乙烯基、1-丙烯基、烯丙基、2-丁烯基、3-丁烯基、 異丙烯基、異丁烯基、1-戊烯基、2-戊烯基、3-戊烯基、 4- 戊烯基、1-己烯基、2-己烯基、3-己烯基、4-己烯基、 5- 己烯基、環戊烯基、環己烯基、1，3-丁二烯基、環己二 烯基、環戊二烯基等，但並不限定於此等基團。 作為I中的取代或未取代的烷基，可以列舉碳數為1 至18的直鏈狀、支鏈狀、單環狀或縮合多環狀烷基；或者 碳數為2至18，並且根據情況被1個以上的-0-中斷的直 鏈狀、支鏈狀、單環狀或縮合多環狀烷基。作為碳數為1 至18的直鏈狀、支鏈狀、單環狀或縮合多環狀烷基的具體 例，可以列舉曱基、乙基、丙基、丁基、戊基、己基、庚 基、辛基、壬基、癸基、十二烧基（dodecyl)、十八烧基、 異丙基、異丁基、異戊基、第二丁基、第三丁基、第二戊 基、第三戊基、第三辛基、新戊基、環丙基、環丁基、環 戊基、環己基、金剛烷基、降冰片基、冰片基、4-癸基環 己基等，但並不限定於此等基團。此外，作為碳數為2至 18，並且根據情況被1個以上的-0-中斷的直鏈狀、支鏈狀 烧基的具體例，可以列舉-CH2-O-CH3、-CH2-CH2-O-CH2-CH3、 -CH2_CH2_CH2_0_CH2_CH3、-(CH2-CH2_0)n_CH3(此處，π 為 1 至 8)、-(CH2-CH2-CH2-〇VCH3(此處，m 為 1 至 5)、-CH2_CH(CH3) -0-CH2-CH3-、-CH2- CH-(0CH3)2等，但並不限定於此等基團。 作為碳數為2至18，並且根據情況被1個以上的-0-中斷的單環狀或縮合多環狀烷基的具體例，可以列舉以下 基團，但並不限定於此等基團。 14 322802 201142501In the formula (1), R represents a substituted or unsubstituted dilute group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group. a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted thiol group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted pit sulphide a substituted, unsubstituted or unsubstituted fluorenyl aryl group, a substituted or unsubstituted aryl group, a substituted silk substituted (tetra) group, a substituted or unsubstituted (tetra)oxy group, a substituted silk The county is taken from an unsubstituted phosphino group, a substituted or unsubstituted silk, shredded or unsubstituted sulfonyl group. Examples of the substituted or unsubstituted base group in the oxime include a linear, branched, monocyclic or condensed polycyclic (tetra) group having a carbon number of from 1 to 18, and the structure may have a plurality of Carbon-carbon double bond, as a specific example, may be 322802 13 201142501 to list vinyl, 1-propenyl, allyl, 2-butenyl, 3-butenyl, isopropenyl, isobutenyl, 1-pentene , 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, The cyclopentenyl group, the cyclohexenyl group, the 1,3-butadienyl group, the cyclohexadienyl group, the cyclopentadienyl group and the like are not limited to these groups. The substituted or unsubstituted alkyl group in I may, for example, be a linear, branched, monocyclic or condensed polycyclic alkyl group having a carbon number of 1 to 18; or a carbon number of 2 to 18, and The case is a linear, branched, monocyclic or condensed polycyclic alkyl group interrupted by one or more -0-. Specific examples of the linear, branched, monocyclic or condensed polycyclic alkyl group having 1 to 18 carbon atoms include mercapto, ethyl, propyl, butyl, pentyl, hexyl and g. Base, octyl, decyl, decyl, dodecyl, octadecyl, isopropyl, isobutyl, isopentyl, t-butyl, tert-butyl, second pentyl , third amyl, third octyl, neopentyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, adamantyl, norbornyl, borneol, 4-mercaptocyclohexyl, etc., but It is not limited to such groups. Further, specific examples of the linear or branched alkyl group having a carbon number of 2 to 18 and being interrupted by one or more -0- as the case may be -CH2-O-CH3, -CH2-CH2- O-CH2-CH3, -CH2_CH2_CH2_0_CH2_CH3, -(CH2-CH2_0)n_CH3 (here, π is 1 to 8), -(CH2-CH2-CH2-〇VCH3 (here, m is 1 to 5), -CH2_CH (CH3) -0-CH2-CH3-, -CH2-CH-(0CH3)2, etc., but is not limited to such a group. The carbon number is 2 to 18, and depending on the case, one or more - 0 Specific examples of the interrupted monocyclic or condensed polycyclic alkyl group include the following groups, but are not limited thereto. 14 322802 201142501

4乃力j〇 JO 彳3〇 ⑹ &lt;〇 作為R!中的取代或未取代的烷氧基，可以列舉碳數為 1至18的直鏈狀、支鏈狀、單環狀或縮合多環狀烷氧基； 或者碳數為2至18，並且根據情況被1個以上的-0-中斷 的直鏈狀、支鏈狀、單環狀或縮合多環狀烷氧基。作為碳 數為1至18的直鏈狀、支鏈狀、單環狀或縮合多環狀烷氧 基的具體例，可以列舉曱氧基、乙氧基、丙氧基、丁氧基、 戊氧基、己氧基、庚氧基、辛氧基、壬氧基、癸氧基、十 二烷氧基、十八烷氧基、異丙氧基、異丁氧基、異戊氧基、 第二丁氧基、第三丁氧基、第二戊氧基、第三戊氧基、第 三辛氧基、新戊氧基、環丙氧基、環丁氧基、環戊氧基、 環己氧基、金剛烷氧基、降冰片氧基、冰片氧基、4-癸基 環己氧基等，但並不限定於此等基團。此外，作為碳數為 2至18，並且根據情況被1個以上的-0-中斷的直鏈狀、支 鏈狀烷氧基的具體例，可以列舉-0-CH2-0-CH3、-0-CH2-CH2-0-CH2_CH3 ' -0~CH2-CH2-CH2-0-CH2-CH3 ' -〇-(CH2-CH2_0)n-CH3(此處，n 為 1 至 8)、-0-(CH2-CH2-CH2-0%-CH3(此處，m 為 1 至 5)、-0-CH2-CH(CH3)-0-CH2-CH3-、-0-CH2-CH-(0CH3)2 等，但並不限定於此等基團。 作為碳數為2至18，並且根據情況被1個以上的-0- 15 322802 201142501 中斷的單環狀或縮合多環狀院氧基的具額，可以列舉以 下基團，但並不限定於此等基團。4 力力 j〇JO 彳3〇(6) &lt; 〇 as a substituted or unsubstituted alkoxy group in R!, a linear, branched, monocyclic or condensed carbon having a carbon number of 1 to 18 A cyclic alkoxy group; or a linear, branched, monocyclic or condensed polycyclic alkoxy group having a carbon number of 2 to 18 and interrupted by one or more of -0-, as the case may be. Specific examples of the linear, branched, monocyclic or condensed polycyclic alkoxy group having 1 to 18 carbon atoms include a decyloxy group, an ethoxy group, a propoxy group, a butoxy group, and a pentyl group. Oxy, hexyloxy, heptyloxy, octyloxy, decyloxy, decyloxy, dodecyloxy, octadecyloxy, isopropoxy, isobutoxy, isopentyloxy, a second butoxy group, a third butoxy group, a second pentyloxy group, a third pentyloxy group, a third octyloxy group, a neopentyloxy group, a cyclopropoxy group, a cyclobutoxy group, a cyclopentyloxy group, Examples of the cyclohexyloxy group, the adamantyloxy group, the norbornyloxy group, the borneoloxy group, the 4-decylcyclohexyloxy group, and the like are not limited thereto. Further, specific examples of the linear or branched alkoxy group having a carbon number of 2 to 18 and interrupted by one or more -0- as the case may be -0-CH2-0-CH3, -0 -CH2-CH2-0-CH2_CH3 ' -0~CH2-CH2-CH2-0-CH2-CH3 ' -〇-(CH2-CH2_0)n-CH3 (here, n is 1 to 8), -0-( CH2-CH2-CH2-0%-CH3 (here, m is 1 to 5), -0-CH2-CH(CH3)-0-CH2-CH3-, -0-CH2-CH-(0CH3)2, etc. However, it is not limited to such a group. The number of monocyclic or condensed polycyclic alkoxy groups having a carbon number of 2 to 18 and interrupted by one or more -1 - 15 322802 201142501, as the case may be, The following groups are exemplified, but are not limited thereto.

作為R】中的取代或未取代的芳基，可以列舉碳數為6 至24的單環或縮合多環芳基，作為具義，可以列舉笨 基、卜萘基、2-萘基、卜蒽基、9_蒽基、2_菲基、3_菲基、 9-菲基、1-芘基（i-pyrenyi)、5_稠四苯基 (5-naphthacenyl)、1-節基（1_indenyl)、2_奠基 (2-azulenyl)、卜苊基n-acenaphthyl)、2_苐基、9 薙基、 3-茈基、鄰甲苯基、間甲苯基、對甲苯基、2,3_二曱苯基、 2, 5-二曱苯基、2’ 4, 6-三曱苯基“邮）、對異丙苯基 (p-cumenyl)、對十二烷基笨基、對環己基苯基、4_聯苯基、 鄰氟苯基、間氯苯基、對絲基、對減苯基、隨基苯 基、鄰酼基苯基、對氰絲L肖絲基、間疊氮基苯 基等’但並不限定於此等基團β 作為Rl巾的減絲取代料氧基，可㈣舉碳數為 ’作為具體例，可以列舉 9-蒽氧基、9-菲氧基、1-I、2-奠氧基、1-苊氧基、 4至18的單環或縮合多環芳氧基， 笨氧基、1-萘氧基、2-萘氧基、9_ 逆氧基、5-稠四苯氧基、1-茚氧基、 9-第氧基等，但並不限定於此等基團。 作為Ri中的取代或未取代的雜 322802 16 201142501 原子、氧原子、硫原子、磷原子的碳数為4至24的芳香族 或月曰肪族雜環基，其可以列舉2-售吩基（2_thieny 1)、2~ 苯并噻吩基、萘并[2, 3-b]噻吩基、3-噻蒽基 (3-thianthrenyl)、2-嗟蒽基（2_thianthrenyl)、2-。夫喃 基、2-苯并吱痛基、比痛基（pyranyl)、異苯并吱喃基、苯 并0比0南基（chromenyl)、氧雜蒽基（xanthenyl)、啡嗜嗟基 (phenoxathiinyl)、2Η-β比洛基、β比咯基、味嗤基、°比嗤基、 0比咬基、°比卩井基（pyrazinyl)、鳴咬基、塔哄基 (pyridazinyl)、中氮茚基（indolizinyl)、異0引0朵基 (isoindolyl)、3H-吲哚基、2-吲哚基、3-吲哚基、lH-n引 0坐基、嘌吟基（卩111^1171)、411-啥哄基（411-91^11〇11211171)、 異啥淋基、啥琳基、醜哄基（phthalazinyl)、萘咬基 (naphthyridinyl)、啥曙琳基（quinoxalinyl)、喧唾琳基 (quinazolinyl)、增琳基（cinnolinyl)、嗓咬基 (pteridinyl)、4aH-咔唑基、2-咔唑基、3-咔唑基、沒_&gt; 味嚇·基、菲咬基（phenanthridinyl)、2-〇丫唆基、咕咬基 (perimidinyl)、啡淋基（phenanthrolinyl)、井基 (phenazinyl)、啡石申哄基（phenarsazinyl)、異°塞。坐基、啡 噻畊基（phenothiazinyl)、異噚唑啉基、呋咱基 (furazanyl)、3-啡哄基（3-phenoxazinyl)、異笨并二氫0比 喃基（isochromanyl)、苯并二氫吡喃基、吡咯啶基 (pyrrolidinyl)、吡咯啉基、咪唑啶基、咪唑啉基、11比唾 咬基、'1比嗅琳基、锒咬基（口丨口61*丨(1丨1171)、旅啡基 (piperazinyl)、吲哚啉基、異吲哚啉基、奎寧環基 322802 17 201142501 (quinuclidinyl)、嗎啉基（morph〇linyl)、噻吨啊基、 喹啉基、4-異喹啉基、3-啡噻畊基、2-啡卩等n塞基、3_香豆 素基等’但並不限定於這些基圑。 作為Ri中的取代或未取代的雜環氧基，可以列舉人 氮原子、氧原子、硫原子、磷原子的碳數為4至Η ^ 狀或縮合多環狀雜環氧基，作為具體例， 、^ 1可以列舉2_呋喃 氧基、2-嗟吩氧基、2-㈣氧基、3,朵氣基、苯并咬 喃氧基、2-笨并β塞吩氧基、2-咔唾氧基、3—π卡唾氧基4 咔唾氧基、9-吖啶氧基等，但並不限定於此等基團。 作為R,中的取代絲減的絲鶴，^列舉碳數 為1至8的⑽狀、线狀、單環狀錢〇環狀烧基硫 基，作為具體例，可以列舉甲硫基、乙硫基、丙硫基、τ 硫基、戊硫基、己硫基、辛硫基、癸硫基、十二烷硫其、 十八院硫基等，但it不限定於此等基團。 作為RJ的取代或未取代的芳基硫基，可以列舉碳數 為6至18的單環狀或縮合多環狀芳基硫基，作為具體例， 可以列舉苯硫基、卜萘硫基、2-萘硫基、卜蒽硫基、菲 硫基等’但並不限定於此等基團。 作為h中的取代或未取代的烷基亞磺醯基，較佳為碳 數為1至20的烷基亞磺醯基，作為具體例，可以列舉甲芙 亞磺醯基、乙基亞磺醯基、丙基亞磺醯基、異丙基亞磺： 基、丁基亞磺醯基、己基亞磺醯基、環己基亞磺醯基、辛 基亞磺醯基、2-乙基己基亞磺醯基、癸基亞磺醯基、十二 烷基亞磺醯基、十八烷基亞磺醯基、氰基甲基亞磺醯基、 322802 18 201142501 曱氧基曱基亞磺醯基等，但並不限定於此等基團。 作為m中的取代或未取代的芳基亞磺醯基，較佳為碳 數為6至30的芳基亞磺醯基’作為具體例，可以列舉苯基 亞磺醯基、1-萘基亞磺醯基、2_萘基亞磺酿基、2_氣苯基 亞磺醯基、2-甲基苯基亞磺醯基、2_曱氧基苯基亞磺醯基、 2-丁氧基苯基亞磺醯基、3~氣苯基亞磺醯基、3_三氟甲基 苯基亞磺醯基、3-氰基苯基亞磺醯基、3_硝基苯基亞磺醯 基、4-氟苯基亞磺醯基、4-氰基苯基亞磺醯基、4-甲氧基 苯基亞磺醯基、4-曱基硫基笨基亞磺醯基、4-苯基硫基苯 基亞％醯基、4-二甲基胺基苯基亞續酿基等，但並不限定 於此等基團。 作為Ri中的取代或未取代的烷基磺醯基，較佳為碳數 為1至20的烷基磺醢基’作為具體例’可以列舉甲基磺醯 基、乙基磺醯基、丙基磺醯基、異丙基磺醯基、丁基磺醯 基、己基磺醯基、環己基磺醯基、辛基磺醯基、2-乙基己 基磺醯基、癸基磺醯基、十二烷基磺醯基、十八烷基磺醯 基、氰基曱基磺醯基、甲氧基曱基磺醯基等，但並不限定 於此等基團。 作為Ri中的取代或未取代的芳基磺醯基，較佳為碳數 為6至30的芳基磺醯基，作為具體例，可以列舉苯基磺醯 基、1-萘基磺醯基、2-萘基磺醯基、2-氯苯基磺醯基、2-甲基苯基磺醯基、2-甲氧基苯基磺醯基、2-丁氧基苯基磺 酿基、3-亂苯基確醯基、3-三氟甲基苯基續酿基、3-氰基 苯基磺醯基、3-硝基苯基磺醯基、4-氟苯基磺醯基、4-氰 19 322802 201142501 基苯基磺醯基、4-甲氧基苯基磺醯基、4一曱基硫基苯基磺 醢基、4-苯基硫基苯基磺醯基、4-二甲基胺基苯基磺醯基 等，但並不限定於此等基團。 作為Ri中的取代或未取代的醯基’可以列舉：結合了 氫原子或碳數為1至18的直鏈狀、支鏈狀、單環狀或縮合 多環狀的脂肪族的羰基，被碳數為2至20的烷氧基取代的 羰基，結合了碳數為6至18的單環狀或縮合多環狀芳基的 羰基，被碳數為6至18的單環狀或縮合多環狀芳氧基取代 的羰基，結合了含有氮原子、氧原子、硫原子、磷原子的 碳數為4至18的單環狀或縮合多環狀雜環基的羰基；作為 具體例，可以列舉甲醯基、乙醯基、丙醯基、丁醯基、異 丁酿基、戊醯基、異戊醢基、三曱基乙醢基（pivaloyl)、 月桂醯基、肉豆蔻醯基、棕櫚醯基、硬脂醯基、環戊基羰 基、環己基羰基、丙烯醯基、曱基丙烯醯基、巴豆醯基、 異巴豆醯基、油醯基、肉桂醯基苯甲醯基、曱氧基羰基、 乙氧基羰基、丙氧基羰基、丁氧基羰基、己氧基羰基、辛 氧基羰基、癸氧基羰基、十八烷氧基羰基、三氟曱氧基羰 基、苯甲醯基、甲苯曱醯基（toluoyl)、1-萘曱醯基 (Ι-naphthoyl)、2-萘曱醯基、9-蒽羰基、苯氧基羰基、4-甲基苯氧基羰基、3-硝基苯氧基羰基、4-二曱基胺基苯氧 基羰基、2-甲基硫基苯氧基羰基、1-萘甲醯氧基羰基、2-萘曱醯氧基羰基、9,蒽氧基羰基、3-糠醯基（3-furoyl)、 2-嗟吩曱醯基（2-thenoyl)、於驗醯基（nicotinoyl)、異於 鹼醯基等，但並不限定於此等基團。 20 322802 201142501 作為Ri中的取代或未取代的醯氧基，可以列舉破數為 2至20的醯氧基，作為具體例，可以列舉乙醯氧基、丙醯 氧基、丁醯氧基、戊醯氧基、三氟曱基碳醯氧基、苯甲醯 氧基、1-萘羰基氧基、2-萘羰基氧基等。 作為Ri中的取代或未取代的胺基，可以列舉胺基、燒 基私基、一烧基胺基、方基胺基、二芳基胺基、烧基芳基 胺基、苄基胺基、二节基胺基等。 此處’作為烷基胺基，可以列舉曱基胺基、乙基胺基、 丙基胺基、丁基胺基、戊基胺基、己基胺基、庚基胺基、 辛基胺基、壬基胺基、癸基胺基、十二烷基胺基、十八烷 基胺基、異丙基胺基、異丁基胺基、異戊基胺基、第二丁 基胺基、第三丁基胺基、第二戊基胺基、第三戊基胺基、 第三辛基胺基、新戊基胺基、環丙基胺基、環丁基胺基、 環戊基胺基、環己基胺基、環庚基胺基、環辛基胺基、環 十二烷基胺基、1-金剛烷胺基、2-金剛烷胺基等，但並不 限定於此等基團。 作為二烷基胺基，可以列舉二甲基胺基、二乙基胺基、 二丙基胺基、二丁基胺基、二戊基胺基、二己基胺基、二 庚基胺基、二辛基胺基、二壬基胺基、二癸基胺基、二（十 二烷基）胺基、二（十八烷基）胺基、二異丙基胺基、二異丁 基胺基、二異戊基胺基、甲基乙基胺基、甲基丙基胺基、 甲基丁基胺基、甲基異丁基胺基、環丙基胺基、°比咯啶基、 哌啶基、哌啡基等，但並不限定於此等基團。 作為芳基胺基，可以列舉苯胺基、卜萘胺基、2-萘胺 21 322802 201142501 基、鄰曱苯胺基（〇- toluidino)、間曱苯胺基、對曱苯胺 基、2-聯苯胺基、3-聯苯胺基、4-聯苯胺基、1-苐胺基、 2-苐胺基、2-噻唑胺基、對聯三苯胺基等，但並不限定於 此等基團。 作為二芳基胺基，可以列舉二苯基胺基、二曱苯基胺 基、N-苯基-1-萘胺基、N-苯基-2-萘胺基等，但並不限定 於此等基團。 作為烷基芳基胺基，可以列舉N-曱基苯胺基、N-曱基 _2_π比咬基、N_乙基苯胺基、N -丙基苯胺基、N_丁基苯胺基、 N-異丙基、N-戊基苯胺基、N-乙基苯胺基、N-曱基-1-萘胺 基等，但並不限定於此等基團。 作為R!中的取代或未取代的膦基，可以列舉碳數為2 至50的膦基，作為具體例，可以列舉二曱基膦基、二乙基 膦基、二丙基膦基、二苯基膦基、二甲氧基膦基、二乙氧 基膦基、二苯曱醯基膦基、二（2, 4, 6-三曱基苯基）膦基等， 但並不限定於此等基團。 作為R!中的取代或未取代的胺基甲醯基，可以列舉碳 數為1至30的胺基甲醯基，作為具體例，可以列舉N-甲 基胺基曱醯基、N-乙基胺基甲醯基、N-丙基胺基曱醯基、 N-丁基胺基曱醯基、N-己基胺基曱醯基、N-環己基胺基曱 醯基、N-辛基胺基曱醯基、N-癸基胺基曱醯基、N-十八烷 基胺基曱酿基、N-苯基胺基甲酿基、N_2_曱基苯基胺基曱 醯基、N-2-氯苯基胺基甲醯基、N-2-異丙氧基苯基胺基曱 醯基、N-2-(2-乙基己基）苯基胺基曱醯基、N-3-氣苯基胺 22 322802 201142501 基甲醯基、N-3-硝基苯基胺基曱醯基、N_3-氰基笨基胺基 甲醯基、N-4-曱氧基苯基胺基曱醯基、N_4-氰基苯基胺基 曱醯基、N-4-曱基硫基苯基胺基甲醯基、n-4-苯基硫基苯 基胺基曱醢基、N-曱基-N-苯基胺基曱醯基、n, N-二甲基胺 基甲醯基、N，N-二丁基胺基曱醯基、N，N一二笨基胺基甲醯 基等，但並不限定於此等基團。 作為Ri中的取代或未取代的胺續醯基，可以列舉破數 為0至30的胺磺醯基’作為具體例，可以列舉胺磺醯基、 N-烷基胺磺醯基、N-芳基胺績醯基、n，N_二烷基胺績醯基、 N，N-二芳基胺磺醯基、N-烧基-N-芳基胺續醯基等。更具體 來說’可以列舉N-曱基胺磺醯基、卜乙基胺磺醯基、N一丙 基胺磺醢基、N-丁基胺橫酿基、N-己基胺續醢基、N-環己 基胺磺醯基、N-辛基胺磺醯基、N-2-乙基己基胺磺醯基、 N-癸基胺磺醯基、N-十八烷基胺磺醯基、N—苯基胺磺醯基、 N-2-曱基苯基胺續醯基、n-2-氣苯基胺續醯基、n-2-甲氧 基苯基胺磺醯基、N-2-異丙氧基苯基胺基曱醯基、N_3一氣 苯基胺磺醯基、N-3-硝基苯基胺磺醯基、N_3_氰基苯基胺 磺醯基、N-4-甲氧基苯基胺磺醯基、卜4_氰基苯基胺磺醯 基、N-4-二曱基胺基苯基胺磺醯基、N一4_曱基硫基苯基胺 磺醯基、N-4-苯基硫基苯基胺磺醯基、N_甲基_N_苯基胺磺 醯基、N，N-二曱基胺磺醯基、n，N-二丁基胺磺醯基、n，N-二苯基胺磺醯基等，但並不限定於此等基團。 、匕為取代或未取代的烯基、取代或未取代的烷基、取 代或未取代眺氧基、取代或未取代的芳基、取代或未取 322802 23 201142501 代的芳氧基、取代或未取代的雜環基、取代或未取代的雜 環氧基、取代或未取代的烧基硫基、取代或未取代的芳基 硫基、取代或未取代的烧基亞續醢基、取代或未取代的芳 基亞續醢基、取代或未取代的烧基磺醯基、取代或未取代 的芳基磺醯基、取代或未取代的醯氧基、或取代或未取代 的胺基。 作為R2中的取代或未取代的烯基、取代或未取代的烧 基 '取代或未取代的烷氧基、取代或未取代的芳基、取代 或未取代的芳氧基、取代或未取代的雜環基、取代或未取 代的雜環氧基、取代或未取代的烷基硫基、取代或未取代 的芳基硫基、取代或未取代的烷基亞績酿基、取代或未取 代的芳基亞磺醢基、取代或未取代的烷基磺醯基、取代或 未取代的芳基磺醯基、取代或未取代的醯氧基、和取代或 未取代的胺基，與前述R!中的取代或未取代的烯基、取代 或未取代的烷基、取代或未取代的烷氧基、取代或未取代 的芳基、取代或未取代的芳氧基、取代或未取代的雜環基、 取代或未取代的雜環氧基、取代或未取代的烷基硫基、取 代或未取代的芳基硫基、取代或未取代的烷基亞磺醯基、 取代或未取代的芳基亞磺醯基、取代或未取代的烷基磺醯 基、取代或未取代的芳基磺醯基、取代或未取代的醯氧基、 和取代或未取代的胺基同義。 R3至I各自獨立地表示氫原子、鹵原子、氰基、硝基、 取代或未取代的烯基、取代或未取代的烷基、取代或未取 代的烧氧基、取代或未取代的芳基、取代或未取代的芳氧 24 322802 201142501 基、取代或未取代的雜環基、取代或未取代的雜環氧基、 取代或未取代的烷基硫基、取代或未取代的芳基硫基、取 代或未取代的醯基、或取代或未取代的胺基。 作為R3至R5中的鹵原子，可以列舉氟原子、氯原子、 溴原子、碘原子。 作為R3至R5中的取代或未取代的烯基、取代或未取代 的烷基、取代或未取代的烷氧基、取代或未取代的芳基、 取代或未取代的芳氧基、取代或未取代的雜環基、取代或 未取代的雜環氧基、取代或未取代的烷基硫基、取代或未 取代的芳基硫基、取代或未取代的醯基、和取代或未取代 的胺基，與前述Ri中的取代或未取代的烯基、取代或未取 代的烷基、取代或未取代的烷氧基、取代或未取代的芳基、 取代或未取代的芳氧基、取代或未取代的雜環基、取代或 未取代的雜環氧基、取代或未取代的烷基硫基、取代或未 取代的芳基硫基、取代或未取代的醯基、和取代或未取代 的胺基同義。 R6至R9各自獨立地表示氫原子、鹵原子、氰基、鹵代 烧基、取代或未取代的院基、取代或未取代的烧氧基、取 代或未取代的芳基、取代或未取代的芳氧基、取代或未取 代的雜環基、取代或未取代的雜環氧基、取代或未取代的 烯基、取代或未取代的烷基硫基、取代或未取代的芳基硫 基、取代或未取代的烷基亞磺醯基、取代或未取代的芳基 亞磺醯基' 取代或未取代的烷基磺醯基、取代或未取代的 芳基績St基、取代或未取代的胺基、或下述通式（2)的取代 25 322802 201142501 基。 通式（2) ?2， W D. —C—CsN—◦一亡一 Ri (式 R4R9中的函原子，與kR6中的_ 作為RdR9中的自代燒基，可以列舉所 ° 上㈣原子取代的碳數為i至15的院基，作為具::子二 以列舉三氟曱基、二氣甲基、三溴甲基、三碘 乙基、五氯乙基、五溴乙基、五碘乙基、三氟 ：、 三溴二碘乙基、七氟丙基、七氣丙基、+ i 土 基 ^ 氣丙基七廣丙基、九氟丁 、九 十—氟戊基、十―氣戊基、十 溴戊基、十二氟己基、十三氣己基、十五氟庚基、十七 氟辛基、十九氟壬基、二十-氟癸基、二十三敗十―烧基、 二十五氟十二烷基等，但並不限定於此等基團。 作為上述鹵代烧基，從合成方面以及作為著色組合物 的特性方面考慮，更佳為三氟曱基、五氟乙基。 R6至R9中的取代或未取代的烷基、取代或未取代的烷 氧基、取代或未取代的芳基、取代或未取代的芳氧基、取 代或未取代的雜環基、取代或未取代的雜環氧基、取代或 未取代的烯基、取代或未取代的烷基硫基、取代或未取代 的芳基硫基、取代或未取代的烷基亞續醯基、取代或未取 代的芳基亞磺醯基、取代或未取代的烷基磺醯基、取代或 26 322802 201142501 未取代的芳基磺醯基、和取代或未取代的胺基，與前述Ri 中的取代或未取代的烷基、取代或未取代的烷氧基、取代 或未取代的芳基、取代或未取代的芳氧基、取代或未取代 的雜環基、取代或未取代的雜環氧基、取代或未取代的烯 基、取代或未取代的烷基硫基、取代或未取代的芳基硫基、 取代或未取代的烷基亞磺醯基、取代或未取代的芳基亞磺 醯基、取代或未取代的烷基磺醯基、取代或未取代的芳基 磺醯基、和取代或未取代的胺基同義。 R1〇至Ru各自獨立地表示氫原子、鹵原子、氰基、確基、 鹵代烷基、取代或未取代的烷基亞磺醯基、取代或未取代 的芳基亞磺醯基、取代或未取代的烷基磺醯基、取代或未 取代的芳基磺醯基、或取代或未取代的醯基，但是Ri。至心 不全部同時為氳原子。 R1〇至Ru中的自代烷基，與前述匕至Rg中的鹵代烷基 同義，取代或未取代的烷基亞磺醯基、取代或未取代:二 基亞磺醯基、取代或未取代的烷基磺醯基、取代或未取代 的芳基磺醯基、和取代或未取代的醯基，與前述匕中的取 代或未取代的烷基亞磺醯基、取代或未取代的芳基亞磺醯 基、取代或未取代的烷基磺醯基、取代或未取代的芳^磺 醯基、和取代或未取代的酿基同義。 κ R1〇至Ru中的取代基’從合成方面以及作為著色組合物 的特性方面考慮’較佳為㈣基或取代或未取代的醯基^ 況，並更佳為硝基或下述通式（3)的情況。 月 通式（3) 322802 27 201142501 ^18The substituted or unsubstituted aryl group in R] may, for example, be a monocyclic or condensed polycyclic aryl group having a carbon number of from 6 to 24, and examples thereof include a strepto group, a naphthyl group, a 2-naphthyl group, a diphenyl group, and 9 _ fluorenyl, 2 phenanthryl, 3 phenanthrenyl, 9-phenanthryl, i-pyrenyi, 5-cyphthene, 5-arylyl, 2 _Founding (2-azulenyl), 苊基基 n-acenaphthyl), 2_fluorenyl, 9 fluorenyl, 3-fluorenyl, o-tolyl, m-tolyl, p-tolyl, 2,3-diphenyl, 2 , 5-diphenylphenyl, 2' 4,6-triphenylphenyl "postal", p-cumenyl, p-dodecyl, p-cyclohexylphenyl, 4_ Phenyl, o-fluorophenyl, m-chlorophenyl, p-fluorenyl, p-phenylene, hexylphenyl, o-nonylphenyl, p-cyanide L-sixyl, m-azidophenyl, etc. The group β is not limited to the minus-substituted oxy group of the R1, and the number of carbon atoms may be 'four'. Specific examples thereof include a 9-methoxy group, a 9-phenoxy group, and a 1-I, 2 group. - alkoxy, 1-decyloxy, 4 to 18 monocyclic or condensed polycyclic aryloxy, phenyloxy, 1-naphthyloxy, 2-naphthalene a group, a 9-epoxy group, a 5-condensed tetraphenoxy group, a 1-decyloxy group, a 9-oxy group, etc., but is not limited to such a group. As a substituted or unsubstituted heterocyclic 322802 16 in Ri 201142501 An aromatic or erythromylidene heterocyclic group having 4 to 24 carbon atoms of an atom, an oxygen atom, a sulfur atom or a phosphorus atom, and examples thereof include a 2-mercapto group (2_thieny 1) and a 2 to benzothiophenyl group. Naphtho[2,3-b]thienyl, 3-thianthrenyl, 2-thenthrenyl, 2-flavyl, 2-benzopyrene, specific pain base (pyranyl), isobenzopyranyl, benzox 0 to chromenyl, xanthenyl, phenoxathiinyl, 2 Η-β piroxime, beta thiol, Miso base, ° 嗤 、, 0 ratio bite base, ° ratio pyrazine, pyridyl, pyridazinyl, indolizinyl, isoindolyl ), 3H-fluorenyl, 2-mercapto, 3-mercapto, lH-n, 0-spin, sulfhydryl (卩111^1171), 411-mercapto (411-91^11〇) 11211171), isoindolinyl, 啥琳基, phthalazinyl, naphthyri Dinyl), quinoxalinyl, quinazolinyl, cinnolinyl, pteridinyl, 4aH-carbazolyl, 2-oxazolyl, 3-oxazolyl , no _&gt; scented base, phenanthridinyl, 2-mercapto, perimidinyl, phenanthrolinyl, phenazinyl, phenolite Phenarsazinyl), iso-plug. Sitrate, phenothiazinyl, isoxazolinyl, furazanyl, 3-phenoxazinyl, isochromanyl, benzo Dihydropyranyl, pyrrolidinyl, pyrrolinyl, imidazolidinyl, imidazolinyl, 11 to salivary, '1 to olynyl, biting base (mouth mouth 61*丨 (1)丨1171), piperazinyl, porphyrinyl, isoindolyl, quinuclidinyl 322802 17 201142501 (quinuclidinyl), morph〇linyl, thioxanyl, quinolinyl , 4-isoquinolyl, 3-morphothinyl, n-pyrene, etc., such as n-sodium, 3- coumarin, etc. 'but not limited to these bases. As a substituted or unsubstituted in Ri Examples of the heterocyclic oxy group include a human nitrogen atom, an oxygen atom, a sulfur atom, and a phosphorus atom, and the carbon number is 4 to Η^ or a condensed polycyclic heterocyclic oxy group. Specific examples thereof include 2-furan. Oxyl, 2-nonyloxy, 2-(tetra)oxy, 3, anthranyl, benzocarboxyoxy, 2-stupyl-β-phenoxy, 2-decyloxy, 3-π Salivyloxy 4 咔sialoxy, 9-acridinyloxy, etc. However, it is not limited to such a group. As a silk crane in which R is substituted, a (10)-like, linear or monocyclic oxime cyclic thiol group having a carbon number of 1 to 8 is used. Specific examples thereof include a methylthio group, an ethylthio group, a propylthio group, a tauthio group, a pentylthio group, a hexylthio group, an octylthio group, a decylthio group, a dodecyl sulfide group, an 18th compound sulfur group, and the like. However, it is not limited to such a group. Examples of the substituted or unsubstituted arylthio group of RJ include a monocyclic or condensed polycyclic arylthio group having 6 to 18 carbon atoms, and as a specific example, The phenylthio group, the naphthylthio group, the 2-naphthylthio group, the dithizone group, the phenanthryl group, etc. are described as 'but are not limited to these groups. As the substituted or unsubstituted alkyl sulfinium sulfonium in h The alkyl group is preferably an alkylsulfinyl group having 1 to 20 carbon atoms. Specific examples thereof include a sulfasalsulfonyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylidene group. Sulfonic acid: butyl sulfinyl group, hexyl sulfinyl group, cyclohexyl sulfinyl group, octyl sulfinyl group, 2-ethylhexyl sulfinyl group, fluorenyl sulfinyl group, twelve Alkyl sulfinyl, ten An octadecylsulfinyl group, a cyanomethylsulfinyl group, a 322802 18 201142501 anthracene sulfenyl sulfinyl group, etc., but is not limited to such a group. As a substituted or unsubstituted in m The arylsulfinyl group, preferably an arylsulfinyl group having a carbon number of 6 to 30, is exemplified by a phenylsulfinyl group, a 1-naphthylsulfinyl group, a 2-naphthyl group. Sulfinic acid, 2-hydroxyphenylsulfinyl, 2-methylphenylsulfinyl, 2-methoxyphenylsulfinyl, 2-butoxyphenylsulfinyl, 3~ gas phenylsulfinyl, 3-trifluoromethylphenylsulfinyl, 3-cyanophenylsulfinyl, 3-nitrophenylsulfinyl, 4-fluorophenyl Sulfosyl, 4-cyanophenylsulfinyl, 4-methoxyphenylsulfinyl, 4-mercaptothiophenylsulfonyl, 4-phenylthiophenyl % mercapto group, 4-dimethylaminophenyl sulfonyl group, etc., but it is not limited to such a group. The substituted or unsubstituted alkylsulfonyl group in Ri, preferably an alkylsulfonyl group having a carbon number of 1 to 20, as a specific example, may be exemplified by methylsulfonyl, ethylsulfonyl, and c. Sulfosyl, isopropylsulfonyl, butylsulfonyl, hexylsulfonyl, cyclohexylsulfonyl, octylsulfonyl, 2-ethylhexylsulfonyl, decylsulfonyl, The dodecylsulfonyl group, the octadecylsulfonyl group, the cyanosulfonylsulfonyl group, the methoxydecylsulfonyl group, and the like are not limited thereto. The substituted or unsubstituted arylsulfonyl group in Ri is preferably an arylsulfonyl group having a carbon number of 6 to 30, and specific examples thereof include a phenylsulfonyl group and a 1-naphthylsulfonyl group. , 2-naphthylsulfonyl, 2-chlorophenylsulfonyl, 2-methylphenylsulfonyl, 2-methoxyphenylsulfonyl, 2-butoxyphenylsulfonic acid, 3- disordered phenyl sulfhydryl, 3-trifluoromethylphenyl continuation, 3-cyanophenylsulfonyl, 3-nitrophenylsulfonyl, 4-fluorophenylsulfonyl, 4-cyano 19 322802 201142501 phenyl sulfonyl, 4-methoxyphenyl sulfonyl, 4-mercaptothiophenylsulfonyl, 4-phenylthiophenylsulfonyl, 4- The dimethylaminophenylsulfonyl group or the like is not limited to these groups. The substituted or unsubstituted fluorenyl group in Ri may be a linear, branched, monocyclic or condensed polycyclic aliphatic carbonyl group having a hydrogen atom or a carbon number of 1 to 18, An alkoxy-substituted carbonyl group having 2 to 20 carbon atoms, a carbonyl group having a monocyclic or condensed polycyclic aryl group having 6 to 18 carbon atoms, a monocyclic or condensed carbon having 6 to 18 carbon atoms a cyclic aryloxy-substituted carbonyl group having a carbonyl group having a monocyclic or condensed polycyclic heterocyclic group having 4 to 18 carbon atoms and containing a nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom; as a specific example, Listed as methyl thiol, ethyl hydrazino, propyl fluorenyl, butyl sulfhydryl, isobutyl aryl, pentamidine, isovaleryl, pivaloyl, laurel, myristyl, palm carp Base, stearyl sulfhydryl, cyclopentylcarbonyl, cyclohexylcarbonyl, acryl fluorenyl, decyl decyl decyl, crotonyl, isocrotonyl, oleyl, cinnamylbenzhydryl, decyloxy Carbonyl, ethoxycarbonyl, propoxycarbonyl, butoxycarbonyl, hexyloxycarbonyl, octyloxycarbonyl, decyloxycarbonyl, ten Alkoxycarbonyl, trifluoromethoxycarbonyl, benzhydryl, toluoyl, 1-naphthoyl, 2-naphthoquinone, 9-fluorenylcarbonyl, benzene Oxycarbonyl, 4-methylphenoxycarbonyl, 3-nitrophenoxycarbonyl, 4-didecylaminophenoxycarbonyl, 2-methylthiophenoxycarbonyl, 1-naphthoquinone Oxycarbonyl, 2-naphthyloxycarbonyl, 9, decyloxycarbonyl, 3-furoyl, 2-thenoyl, nicotinoyl ), other than an alkali sulfhydryl group, etc., but is not limited to such groups. 20 322802 201142501 Examples of the substituted or unsubstituted fluorenyloxy group in Ri include a decyloxy group having a number of 2 to 20, and specific examples thereof include an ethoxy group, a propenyloxy group, and a butyloxy group. A pentyloxy group, a trifluoromethyl carboxyoxy group, a benzamidineoxy group, a 1-naphthalenecarbonyloxy group, a 2-naphthylcarbonyloxy group, or the like. Examples of the substituted or unsubstituted amino group in Ri include an amine group, a decyl group, a monoalkylamino group, a arylamino group, a diarylamino group, a alkylaryl group, and a benzylamino group. , two base amino groups and so on. Here, 'as the alkylamino group, a mercaptoamine group, an ethylamino group, a propylamino group, a butylamino group, a pentylamino group, a hexylamino group, a heptylamino group, an octylamino group, Mercaptoamine, mercaptoamine, dodecylamino, octadecylamino, isopropylamino, isobutylamino, isoamylamino, second butylamino, Tributylamine, second amylamino, third amylamino, third octylamino, neopentylamino, cyclopropylamino, cyclobutylamino, cyclopentylamino a cyclohexylamino group, a cycloheptylamino group, a cyclooctylamino group, a cyclododecylamino group, a 1-adamantanyl group, a 2-adamantanyl group, or the like, but is not limited thereto. . Examples of the dialkylamino group include a dimethylamino group, a diethylamino group, a dipropylamino group, a dibutylamino group, a dipentylamino group, a dihexylamino group, a diheptylamino group, Dioctylamino, dinonylamino, dimethylamino, di(dodecyl)amino, dioctadecylamino, diisopropylamino, diisobutylamine Base, diisoamylamino group, methyl ethylamino group, methylpropylamino group, methylbutylamino group, methyl isobutylamino group, cyclopropylamino group, pyrrolidinyl group, The piperidinyl group, the piperidinyl group and the like are not limited to these groups. Examples of the arylamine group include an anilino group, a naphthylamino group, a 2-naphthylamine 21 322802 201142501 group, an o-anilino group, a m-anilino group, a p-anilino group, a 2-biphenylamino group. And a 3-benzidine group, a 4-biphenylamino group, a 1-nonylamino group, a 2-nonylamino group, a 2-thiazolylamino group, a conjugated triphenylamine group, etc., but it is not limited to these groups. Examples of the diarylamine group include a diphenylamino group, a diphenylphenylamino group, an N-phenyl-1-naphthylamino group, and an N-phenyl-2-naphthylamino group, but are not limited thereto. These groups. Examples of the alkylarylamine group include N-mercaptoanilide group, N-fluorenyl-2-ππ-bite group, N-ethylanilino group, N-propylanilino group, N-butylanilino group, N- Isopropyl, N-pentylanilino, N-ethylanilino, N-fluorenyl-1-naphthylamine, etc., but are not limited to these groups. The substituted or unsubstituted phosphino group in R! may, for example, be a phosphino group having 2 to 50 carbon atoms, and specific examples thereof include a dimercaptophosphino group, a diethylphosphino group, a dipropylphosphino group, and two. a phenylphosphino group, a dimethoxyphosphino group, a diethoxyphosphino group, a diphenylphosphinoyl group, a bis(2,4,6-tridecylphenyl)phosphino group, etc., but is not limited thereto These groups. Examples of the substituted or unsubstituted aminomethyl fluorenyl group in R! include an aminomethyl fluorenyl group having 1 to 30 carbon atoms. Specific examples thereof include N-methylamino fluorenyl group and N-B. Aminomethylmercapto, N-propylamino fluorenyl, N-butylamino fluorenyl, N-hexylamino fluorenyl, N-cyclohexylamino fluorenyl, N-octyl Amino fluorenyl, N-decylamino fluorenyl, N-octadecylamino aryl, N-phenylaminomethyl, N 2 -nonylphenylamino fluorenyl, N-2-Chlorophenylaminomethylindenyl, N-2-isopropoxyphenylaminoindenyl, N-2-(2-ethylhexyl)phenylaminoindenyl, N- 3-oxophenylamine 22 322802 201142501 methylmercapto, N-3-nitrophenylaminoindenyl, N_3-cyanophenylaminomethyl, N-4-decyloxyphenylamine Base group, N_4-cyanophenylamino fluorenyl group, N-4-mercaptothiophenylaminomethyl fluorenyl group, n-4-phenylthiophenylamino fluorenyl group, N - mercapto-N-phenylaminoindenyl, n,N-dimethylaminomethylindenyl, N,N-dibutylaminoindenyl, N,N-diphenylamino醯基等, but not limited to such base . Examples of the substituted or unsubstituted amine fluorenyl group in Ri include, for example, an amine sulfonyl group having a number of from 0 to 30, and examples thereof include an amine sulfonyl group, an N-alkylamine sulfonyl group, and N- An arylamine fluorenyl group, an n,N-dialkylamine fluorenyl group, an N,N-diarylamine sulfonyl group, an N-alkyl-N-arylamine hydrazino group, and the like. More specifically, 'N-mercaptoamine sulfonyl group, acenamyl sulfonyl group, N-propylamine sulfonyl group, N-butylamine flavonoid, N-hexylamine fluorenyl group, N- Cyclohexylamine sulfonyl, N-octylamine sulfonyl, N-2-ethylhexylamine sulfonyl, N-decylamine sulfonyl, N-octadecylamine sulfonyl, N- Phenylamine sulfonyl, N-2-mercaptophenylamine hydrazino, n-2-phenylphenylamine hydrazino, n-2-methoxyphenylamine sulfonyl, N-2- Isopropoxyphenylaminoindenyl, N_3 monophenylenesulfonyl, N-3-nitrophenylamine sulfonyl, N_3-cyanophenylamine sulfonyl, N-4-methyl Oxyphenylamine sulfonyl, 4-cyanophenylamine sulfonyl, N-4-didecylaminophenylsulfonyl, N-1,4-ylthiophenylamine sulfonate , N-4-phenylthiophenylamine sulfonyl, N-methyl-N-phenylamine sulfonyl, N,N-didecylamine sulfonyl, n,N-dibutyl The aminesulfonyl group, the n,N-diphenylaminesulfonyl group, and the like are not limited thereto. , 匕 is a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted decyloxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryl group, aryl group, 322802 23 201142501 Unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted alkyl group, substituted Or unsubstituted aryl fluorenyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted arylsulfonyl, substituted or unsubstituted decyloxy, or substituted or unsubstituted amino . As a substituted or unsubstituted alkenyl group in R2, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted group. Heterocyclyl, substituted or unsubstituted heterocyclooxy, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted alkyl, substituted or unsubstituted a substituted arylsulfinyl group, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, a substituted or unsubstituted alkoxy group, and a substituted or unsubstituted amine group, and a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substituted or not Substituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted alkylsulfinyl group, substituted or Unsubstituted arylsulfinyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted Substituted arylsulfonyl, substituted or unsubstituted anthracenyl, and synonymous with substituted or unsubstituted amine. R3 to I each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group. Alkyl, substituted or unsubstituted aryloxy 24 322802 201142501 base, substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted aryl group A thio group, a substituted or unsubstituted fluorenyl group, or a substituted or unsubstituted amine group. Examples of the halogen atom in R3 to R5 include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a substitution or a substituent in R3 to R5; Unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted fluorenyl group, and substituted or unsubstituted Amino group, and a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group in the above Ri. , substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted fluorenyl group, and substituted Or an unsubstituted amino group is synonymous. R6 to R9 each independently represent a hydrogen atom, a halogen atom, a cyano group, a halogenated alkyl group, a substituted or unsubstituted institutional group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted group. Aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkenyl group, substituted or unsubstituted alkylthio group, substituted or unsubstituted aryl sulfide Alkyl, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted arylsulfinyl' substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted aryl, substituted or substituted An unsubstituted amine group, or a substituent of the following formula (2) 25 322802 201142501. General formula (2) ?2, W D. -C-CsN - ◦一一一 Ri (the functional atom in the formula R4R9, and _ in the kR6 as the self-generated alkyl group in RdR9, which can be enumerated as the (four) atom Substituting a carbon number of from 1 to 15 as a subunit: to give a trifluoromethyl group, a di-methyl group, a tribromomethyl group, a triiodoethyl group, a pentachloroethyl group, a pentabromoethyl group, Pentaiodoethyl, trifluoro:, tribromodiiodoethyl, heptafluoropropyl, heptapropylpropyl, + i soil base, gas propyl heptapropyl, nonafluorobutyrate, ninety-fluoropentyl, X-air pentyl, decabromopentyl, dodecafluorohexyl, thirteen gas hexyl, fifteen fluoroheptyl, heptafluorooctyl, nineteen fluorodecyl, twenty-fluoroindolyl, twenty-three defeat Although it is not limited to such a group, the above-mentioned halogenated alkyl group is more preferably trifluoro in terms of synthesis and characteristics as a coloring composition. Mercapto, pentafluoroethyl. substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted in R6 to R9 Substituted heterocycle , substituted or unsubstituted heterocyclic oxy, substituted or unsubstituted alkenyl, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted alkyl hydrazine a substituted or unsubstituted arylsulfinyl group, a substituted or unsubstituted alkylsulfonyl group, a substituted or 26 322802 201142501 unsubstituted arylsulfonyl group, and a substituted or unsubstituted amine group, and the foregoing Substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted in Ri Heterocyclicoxy, substituted or unsubstituted alkenyl, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted An arylsulfinyl group, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, and a substituted or unsubstituted amine group. R1〇 to Ru each independently represent a hydrogen atom. , halogen atom, cyano group, exact group, haloalkyl group, substituted or unsubstituted alkane Sulfosyl, substituted or unsubstituted arylsulfinylene, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted arylsulfonyl, or substituted or unsubstituted fluorenyl, but Ri Not all of the same is a ruthenium atom. The self-substituted alkyl group of R1 〇 to Ru is synonymous with the above-mentioned oxime to the haloalkyl group in Rg, substituted or unsubstituted alkylsulfinyl group, substituted or unsubstituted: diyl a sulfinyl group, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, and a substituted or unsubstituted fluorenyl group, and a substituted or unsubstituted alkyl sulfinic acid in the aforementioned hydrazine An fluorenyl, substituted or unsubstituted arylsulfinyl group, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, and a substituted or unsubstituted brewing group are synonymous. κ R1〇 The substituent to the 'Ru' is considered from the viewpoint of synthesis and as a characteristic of the coloring composition, preferably a (tetra) group or a substituted or unsubstituted fluorenyl group, and more preferably a nitro group or a formula (3) Case. Month (3) 322802 27 201142501 ^18

Rl7N^^Rl9Rl7N^^Rl9

r16W R15 〇 (式（3)中’心至Rig各自獨立地表示氫原子、鹵原子、 氰基、硝基、南代烷基、取代或未取代的烷基、取代或未 取代的烧氧基、取代或未取代的芳基、取代或未取代的芳 氧基、取代或未取代的雜環基、取代或未取代的雜環氧基、 取代或未取代的烯基、取代或未取代的烷基硫基、取代或 未取代的芳基硫基、取代或未取代的醯基、或取代或未取 代的胺基。） 匕5至Ru中的鹵代烷基，與前述匕至r9中的鹵代烷基 同義，取代或未取代的烷基、取代或未取代的烷氧基、取 代或未取代的芳基、取代或未取代的芳氧基、取代或未取 代的雜環基、取代或未取代的雜環氧基、取代或未取代的 烯基、取代或未取代的烷基硫基、取代或未取代的芳基硫 基、取代或未取代的酿基、和取代或未取代的胺基，與匕 中的取代或未取代的烷基、取代或未取代的烷氧基、取代 或未取代的芳基、取代或未取代的芳氧基、取代或未取代 的雜環基、取代或未取代_環氧基、取代或未取代的稀 基、取代或未取代的烷基硫基、取代或未取代的芳基硫基、 取代或未取代的酿基、和取代或未取代的胺基同義。 、此處，心至Ru中的硝基或式（3)所表㈣取代基的取 代位置，從合成方面以及作為著色組合物的特性方面考 322802 28 201142501 慮，更佳為在Ri2處取代的情況。 刖述的Ri至Rlg中的取代基的氫原子，可進一步被其它 的取代基取代。 作為其它的取代基，例如，可以列舉；氟原子、氯原 子、演原子、碘原子等鹵素基團；甲氧基、乙氧基、第三 丁氧基專烧氧基；苯氧基、對甲苯氧基等芳氧基；曱氧基 羰基、丁氧基羰基、苯氧基羰基等烷氧基羰基；乙醯氧基、 丙酿氧基、苯曱醯氧基等醯氧基；乙醯基、苯甲醯基、異 丁醯基、丙烯醯基、甲基丙烯醯基、曱氧草醯基（meth〇xalyl) 等醯基；曱基硫基、第三丁基硫基等烷基硫基；苯基硫基、 對甲苯基硫基等芳基硫基；曱基胺基、環己基胺基等烷基 胺基；二曱基胺基、二乙基胺基、嗎啉代基（m〇rph〇Un〇)、 旅π定基專一烧基胺基；苯基胺基、對甲苯基胺基等芳基胺 基；曱基、乙基、第三丁基、十二烷基等烷基；苯基、對 曱本基、二曱苯基、異丙苯基、萘基、蒽基、菲基等芳基； α夫喃基、嗟吩基等雜環基’除此之外，還可以列舉經基、 羧基、曱醯基、酼基、續基（sulfo)、曱續醯基、對甲苯橫 酿基、胺基、石肖基、氰基、三氟曱基、三氯曱基、三甲基 矽烷基（trimethylsilyl)、膦酸亞基（ph〇sphinico)、膦醯 基（phosphono)、三曱基銨基、二甲基鏑基、三苯基苯甲醢 甲基鱗基（triphenylphenacylphosphoniumyl)等。 本發明的感光性著色組合物中含有的通式（1)所表示 的光聚合引發劑（A)，其特徵係在肟酯系光聚合引發劑中， 在N-苯基咔唑骨架的苯基上取代有吸電子性取代基。通常 322802 29 201142501 認為，肟酯系光聚合引發劑係藉由吸收紫外線，使其肟酯 部分分解，生成亞胺基自由基和燒氧基自由基，進一步分 解生成的活性種自由基會引起反應，但本發明的感光性著 色組合物中含有的光聚合引發劑（A)，係藉由具有通式（1) 所表示的結構，而使由紫外線照射所致的分解效率非常 高，能夠以較少的曝光量形成圖案。 本發明的通式（1)所表示的光聚合引發劑（A)比以往的 引發劑具有更高感度，這可能是由於以下所列舉的3個原 因，但其詳細内容尚未明確。 作為第1個原因，本發明的通式（1)所表示的光聚合引 發劑（A)，由於其中通式（1)所表示的結構具有良好的紫外 線吸收性能，因此可以極其良好地吸收所給予的能量線之 能量。此外還可認為，由於所得的能量被有效地用於肟酯 部位的分解，因此藉由能量線照射而迅速分解，並且瞬間 就能夠生成大量的自由基。 作為第2個原因，可以認為本發明的通式（1)所表示的 光聚合引發劑（A )，從吸收紫外線所產生的亞胺基自由基到 活性種自由基的分解，係源自於通式（1)所表示的結構，並 且非常迅速。如果生成的亞胺基自由基為準穩定，則分解 變慢，活性自由基的生成量減少，紫外線吸收部分的化學 結構對此產生了較大的影響。並且可以認為，由於本發明 的通式（1)所表示的光聚合引發劑（A)具有通式（1)所示的 結構，因此藉由光照射進行分解所產生的亞胺基自由基的 分解非常迅速，結果生成了大量的自由基。 30 322802 201142501 此外認為，本發明的通式（1)所表示的光聚合引發劑 (A)，如上所述，由於亞胺基自由基的分解非常迅速，因此 抑制了再結合。在再結合較多的情況下，由分解所產生的 活性種就減少’因此作為自由基聚合引發劑的功能下降。 作為第3個原因，可以列舉上述可發揮良好的紫外線 吸收性能的被吸電子性取代基取代的咔唑的效果與_型辟 酯的效果的協同效果。 接著’對於通式（11)所表示的光聚合引發劑（A)進行說 明0 通式（11)R16W R15 〇 (in the formula (3), 'heart to Rig each independently represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a southern alkyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group. , substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkenyl group, substituted or unsubstituted An alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted fluorenyl group, or a substituted or unsubstituted amine group.) a halogenated alkyl group of 匕5 to Ru, and an alkyl halide of the above hydrazine to r9 Synonymous, substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic, substituted or unsubstituted Heterocyclic oxy, substituted or unsubstituted alkenyl, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted aryl, and substituted or unsubstituted amino And a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group in the oxime, Substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted epoxide group, substituted or unsubstituted dilute group, substituted or unsubstituted alkyl group A thio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted aryl group, and a substituted or unsubstituted amine group are synonymous. Here, the substitution position of the nitro group in the heart to Ru or the substituent in the formula (4) of the formula (3) is considered to be 322802 28 201142501 from the viewpoint of synthesis and the characteristics of the coloring composition, and more preferably substituted at Ri2. Happening. The hydrogen atom of the substituent in Ri to Rlg described above may be further substituted with another substituent. Examples of the other substituent include a halogen group such as a fluorine atom, a chlorine atom, a hydrazine atom, and an iodine atom; a methoxy group, an ethoxy group, a third butoxy group, and an oxy group; An aryloxy group such as a tolyloxy group; an alkoxycarbonyl group such as a fluorenyloxycarbonyl group, a butoxycarbonyl group or a phenoxycarbonyl group; a methoxy group such as an ethoxy group, a propyloxy group or a benzomethoxy group; a thiol group such as a thiol group, an isobutylene group, an acryl fluorenyl group, a methacryl fluorenyl group, a meth〇xalyl group; an alkylthio group such as a mercaptothio group or a t-butylthio group; An arylthio group such as a phenylthio group or a p-tolylthio group; an alkylamino group such as a mercaptoamine group or a cyclohexylamino group; a dinonylamino group, a diethylamino group, and a morpholino group (m) 〇rph〇Un〇), π定基基基基基基基; phenylamine, p-tolylamine and other arylamine groups; alkyl, ethyl, tert-butyl, dodecyl and other alkyl groups ; an aryl group such as a phenyl group, a p-fluorenyl group, a diphenylene group, a cumyl group, a naphthyl group, an anthranyl group or a phenanthryl group; a heterocyclic group such as an α-furyl group or a fluorenyl group; Base Carboxyl, fluorenyl, fluorenyl, sulfo, fluorenyl, p-toluene, amine, schiffyl, cyano, trifluoromethyl, trichlorodecyl, trimethyldecyl Trimethylsilyl), phosphonic acid subunit (ph〇sphinico), phosphonyl (phosphono), trimethylammonium group, dimethyl fluorenyl, triphenylphenacylphosphoniumyl and the like. The photopolymerization initiator (A) represented by the formula (1) contained in the photosensitive coloring composition of the present invention is characterized in that an oxime ester photopolymerization initiator is a benzene group in the N-phenylcarbazole skeleton. Substituted with an electron withdrawing substituent. Usually, 322802 29 201142501 considers that the oxime ester photopolymerization initiator partially decomposes the oxime ester by absorbing ultraviolet rays to form an imino radical and an alkoxy radical, and further decomposition of the active species radical generates a reaction. However, the photopolymerization initiator (A) contained in the photosensitive coloring composition of the present invention has a structure represented by the formula (1), and the decomposition efficiency by ultraviolet irradiation is extremely high, and it is possible to Less exposure forms a pattern. The photopolymerization initiator (A) represented by the formula (1) of the present invention has higher sensitivity than the conventional initiator, which may be due to the following three reasons, but the details thereof are not clear. As a first reason, the photopolymerization initiator (A) represented by the formula (1) of the present invention has excellent ultraviolet absorption properties because of the structure represented by the formula (1), so that it can be absorbed extremely well. The energy of the energy line given. Further, it is considered that since the obtained energy is effectively used for the decomposition of the oxime ester site, it is rapidly decomposed by the irradiation of the energy ray, and a large amount of radicals can be generated instantaneously. For the second reason, it is considered that the photopolymerization initiator (A) represented by the formula (1) of the present invention is derived from the decomposition of an imine radical generated by ultraviolet rays to an active species radical. The structure represented by the general formula (1) is very rapid. If the generated imino radical is quasi-stable, the decomposition becomes slow, the amount of active radicals is reduced, and the chemical structure of the ultraviolet absorbing portion has a large influence. In addition, the photopolymerization initiator (A) represented by the formula (1) of the present invention has a structure represented by the formula (1), and thus the imino radical generated by decomposition by light irradiation is considered. The decomposition is very rapid and results in a large amount of free radicals. In the photopolymerization initiator (A) represented by the formula (1) of the present invention, as described above, since the decomposition of the imino radical is very rapid, recombination is suppressed. In the case where there is a lot of recombination, the active species produced by the decomposition is reduced, and thus the function as a radical polymerization initiator is lowered. The third cause is a synergistic effect between the effect of the above-mentioned carbazole substituted with an electron-withdrawing substituent which exhibits excellent ultraviolet absorbing performance and the effect of the cleavage ester. Next, the photopolymerization initiator (A) represented by the formula (11) is described.

通式（11)中，RS1表示取代或未取代的烯基、取代或未 取代的烷基、取代或未取代的烷氧基、取代或未取代的芳 基、取代或未取代的芳氧基、取代或未取代的雜環基、取 代或未取代的雜環氧基、取代或未取代的烷基硫基、取代 或未取代的芳基硫基、取代或未取代的烷基亞磺醯基、取 代或未取代的芳基亞磺醯基、取代或未取代的烷基磺醯 基、、取代或未取代的芳基磺醯基、取代或未取代的醯基、 取代或未取代的醯氧基、取代或未取代的胺基、取代或未 31 322802 201142501 取代的膦基、取代或未取代的胺基曱醯基、或取代或未取 代的胺磺醯基。 其中，從合成方面以及作為著色組合物的特性方面考 慮，特佳為烷基。 &amp;表示被環烷基取代的碳數為1至20的燒基。 作為環烷基，可以列舉環丙基、環丁基、環戊基、環 己基、環庚基、環辛基、環十八烷基等碳數為3至2〇的環 炫基。 其中’ R52為被環戊基取代的院基的話》從光聚合引發 劑的合成方面以及穩定性方面考慮是有利的。 R53至R55各自獨立地表示氫原子、鹵原子、氰基、硝基、 取代或未取代的烯基、取代或未取代的烷基、取代或未取 代的烷氧基、取代或未取代的芳基、取代或未取代的芳氧 基、取代或未取代的雜環基、取代或未取代的雜環氧基、 取代或未取代的烷基硫基、取代或未取代的芳基硫基、取 代或未取代的酿基、或取代或未取代的胺基。 其中，從合成方面以及作為著色組合物的特性方面考 慮’特佳為氮原子。 ^至R58各自獨立地表示氫原子、鹵原子、氰基、硝基、 i代烧基、取代絲取代的絲亞韻基、取代或未取代 的芳基亞伽基、取代或未取代的⑥基俩基、取代或未 取代的芳基4醯基、或取代或未取代的醯基。 其中，從合成方面以及作為著色組合物的特性方面考 慮’特佳為氮原子。 322802 32 201142501 R59至Rea各自獨立地表示氫原子、鹵原子、氰基、;ε肖基、 鹵代烷基、取代或未取代的烷基、取代或未取代的烷氧基、 取代或未取代的芳基、取代或未取代的芳氧基、取代或未 取代的雜環基、取代或未取代的雜環氧基、取代或未取代 的烯基、取代或未取代的烷基硫基、取代或未取代的芳基 硫基、取代或未取代的醯基、或取代或未取代的胺基。 其中，從合成方面以及作為著色組合物的特性方面考 慮’特佳為氫原子或烧基。 R64表示氳原子、鹵原子、氰基、硝基、取代或未取代 的稀基、取代或未取代的烧基、取代或未取代的燒氧基、 取代或未取代的芳基、取代或未取代的芳氧基、取代或未 取代的雜環基、取代或未取代的雜環氧基、取代或未取代 的烧基硫基、取代或未取代的芳基硫基、取代或未取代的 醯基、或取代或未取代的胺基。 其中’從合成方面以及作為著色組合物的特性方面考 慮，特佳為烷基。 前述的尺“至R64中的取代基的氫原子可以進一步被其 它的取代基取代。 作為其匕的取代基，例如，可以列舉：氟原子、氯原 子、溴原子、碘原子等鹵素基團；甲氧基、乙氧基、第三 丁氧基等烷氧基；笨氧基、對曱苯氧基等芳氧基；甲氧基 羰基、丁氧基羰基、笨氧基羰基等烷氧基羰基；乙醯氧基、 丙醯氧基、苯曱醯氧基等醯氧基；乙醯基、苯甲醯基、異 丁醯基、丙烯醯基、甲基丙烯醯基、曱氧草醯基等醯基； 322802 33 201142501 曱基硫基、第三丁基硫基等烷基硫基；苯基硫基、對曱苯 基硫基等芳基硫基；甲基胺基、環己基胺基等烷基胺基； 二曱基胺基、二乙基胺基、嗎啉代基、哌啶基等二烷基胺 基；苯基胺基、對曱苯基胺基等芳基胺基；曱基、乙基、 第三丁基、十二烷基等烷基；苯基、對曱苯基、二曱苯基、 異丙苯基、萘基、蒽基、菲基等芳基；呋喃基、噻吩基等 雜環基，除此之外，還可以列舉羥基、羧基、曱醯基、巯 基、磺基、曱磺醯基、對曱苯磺醯基、胺基、硝基、氰基、 三氟曱基、三氣曱基、三曱基矽烷基、膦酸亞基、膦醯基、 三曱基銨基、二曱基锍基、三苯基苯曱醯曱基鱗基等。 作為最佳的通式（11)所表示的光聚合引發劑（A)的結 構，可以列舉下述式（12)所表示的化合物。 式（12)In the formula (11), RS1 represents a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group. , substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted alkyl sulfinium sulfonate Alkyl, substituted or unsubstituted arylsulfinyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted arylsulfonyl, substituted or unsubstituted fluorenyl, substituted or unsubstituted Alkoxy, substituted or unsubstituted amino, substituted or unsubstituted 31,322,802 201142501 substituted phosphino, substituted or unsubstituted amino fluorenyl, or substituted or unsubstituted sulfonamide. Among them, an alkyl group is particularly preferred from the viewpoint of synthesis and characteristics as a coloring composition. &amp; represents a burnt group having 1 to 20 carbon atoms substituted by a cycloalkyl group. The cycloalkyl group may, for example, be a cyclohexyl group having a carbon number of 3 to 2 Å such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group or a cyclooctadecyl group. Among them, 'R52 is a group substituted by a cyclopentyl group>> is advantageous in terms of synthesis of a photopolymerization initiator and stability. R53 to R55 each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aromatic group. a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, A substituted or unsubstituted aryl group, or a substituted or unsubstituted amine group. Among them, it is considered to be a nitrogen atom from the viewpoint of synthesis and as a property of the coloring composition. ^ to R58 each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, an i-alkyl group, a substituted silk-substituted silk fluorenyl group, a substituted or unsubstituted aryl ylene group, a substituted or unsubstituted 6 A benzyl, substituted or unsubstituted aryl-4-indenyl group, or a substituted or unsubstituted indenyl group. Among them, it is considered to be a nitrogen atom from the viewpoint of synthesis and as a property of the coloring composition. 322802 32 201142501 R59 to Rea each independently represent a hydrogen atom, a halogen atom, a cyano group, an ε-Schothyl group, a halogenated alkyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group. A substituted or unsubstituted aryloxy group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkylthio group, a substituted or Unsubstituted arylthio, substituted or unsubstituted fluorenyl, or substituted or unsubstituted amine. Among them, it is considered to be a hydrogen atom or a burnt group from the viewpoint of synthesis and characteristics as a coloring composition. R64 represents a halogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted dilute group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or not Substituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted Amidino, or a substituted or unsubstituted amine group. Among them, the alkyl group is particularly preferable in terms of synthesis and characteristics as a coloring composition. The hydrogen atom of the substituent in the above-mentioned "R64" may be further substituted with another substituent. Examples of the substituent of the oxime thereof include a halogen group such as a fluorine atom, a chlorine atom, a bromine atom or an iodine atom; An alkoxy group such as a methoxy group, an ethoxy group or a third butoxy group; an aryloxy group such as an oxyoxy group or a p-phenoxy group; an alkoxy group such as a methoxycarbonyl group, a butoxycarbonyl group or an alkoxycarbonyl group; a carbonyl group; an oxiranyl group such as an ethoxy group, a propenyloxy group or a benzomethoxy group; an ethyl fluorenyl group, a benzamidine group, an isobutyl group, an acryl fluorenyl group, a methacryl fluorenyl group, an anthraquinone group, etc. Sulfhydryl; 322802 33 201142501 alkylthio group such as mercaptothio group or tert-butylthio group; arylthio group such as phenylthio group or p-phenylphenylthio group; methylamino group, cyclohexylamino group, etc. An alkylamino group; a dialkylamino group such as a dimercaptoamine group, a diethylamino group, a morpholino group or a piperidinyl group; an arylamino group such as a phenylamino group or a p-nonylphenylamino group; An alkyl group such as a phenyl group, an ethyl group, a tert-butyl group or a dodecyl group; an aryl group such as a phenyl group, a p-nonylphenyl group, a diphenylene group, a cumyl group, a naphthyl group, an anthranyl group Examples of the heterocyclic group such as a furyl group and a thienyl group include a hydroxyl group, a carboxyl group, a decyl group, a fluorenyl group, a sulfo group, a sulfonyl group, a p-toluenesulfonyl group, an amine group, a nitro group, and a cyanogen group. Base, trifluoromethyl, trimethyl fluorenyl, tridecyl decyl, phosphonic acid subunit, phosphinium, trimethyl ammonium, dimethyl fluorenyl, triphenyl phenyl fluorenyl, etc. The structure of the photopolymerization initiator (A) represented by the formula (11) is preferably a compound represented by the following formula (12).

本發明的感光性著色組合物中含有的通式（11)所表示 的光聚合引發劑（A)，是肟酯系光聚合引發劑。通常認為， 肟酯系光聚合引發劑係藉由吸收紫外線，使其肟酯部分分 解，生成亞胺基自由基和烧氧基自由基，進一步分解生成 的活性種自由基會引起反應，但本發明的感光性著色組合 34 322802 201142501 物中含有的通式（11)所表示的光聚合引發劑（A )，係藉由具 有通式（11)所表示的結構，而使由紫外線照射所致的分解 效率非常高，能夠以較少的曝光量形成圖案。 本發明的通式（11)所表示的光聚合引發劑（A )比以往 的引發劑具有更高感度，可能是由於以下所列舉的2個原 因，但其詳細内容尚未明確。 作為第1個原因，本發明的通式（11)所表示的光聚合 引發劑（A)，由於其中通式（11)所表示的結構具有良好的紫 外線吸收性能，因此可以極其良好地吸收所給予的能量線 之能量。此外還可認為，由於所得的能量被有效地用於肟 酯部位的分解，因此藉由能量線照射而迅速分解，瞬間就 能夠生成大量的自由基。 作為第2個原因，可以認為本發明的通式（11)所表示 的光聚合引發劑（A)，從吸收紫外線所產生的亞胺基自由基 到活性種自由基的分解，係源自於通式（11)所表示的結 構，非常迅速。如果生成的亞胺基自由基為準穩定，則分 解變慢，活性自由基的生成量減少，紫外線吸收部分的化 學結構對此產生了較大的影響。可以認為本發明的光聚合 引發劑（A)係藉由具有通式（11)所示的結構，而使因光照射 進行分解所產生的亞胺基自由基的分解非常迅速，結果生 成了大量的自由基。 此外認為，本發明的通式（11)所表示的光聚合引發劑 (A)，如上所述，由於亞胺基自由基的分解非常迅速，因此 抑制了其再結合。在再結合較多的情況下，由分解所產生 35 322802 201142501 的活性種減少，因此作為自由基聚合引發劑的功能下降。 含有上述通式（1)或（11)所表示的化合物的光聚合引 發劑（A)，考慮其感度和圖案化性，相對於感光性著色組合 物中的顏料（D)10〇重量份，可以以1至200重量份的量， 較佳為以1至150重量份的量使用。 〈其它的光聚合引發劑（γ)&gt; 在本發明的感光性著色組合物中，若將其它的光聚合 引發劑（Υ)和上述式（1)或（U)所表示的化合物併用，即可 以得到更良好的耐藥品性，因此為較佳。 作為其它的光聚合引發劑（Υ)，可以使用：4-苯氧基二 氣苯乙酮、4-第三丁基二氣苯乙酮、二乙氧基苯乙酮、對 一甲基胺基苯乙酮、1-(4-異丙基苯基）-2-經基-2-甲基丙 烷-1-酮、1-羥基環己基苯基酮、2一曱基444-(曱硫基） 本基]~2-嗎嚇·代基丙烧-1 -酿j、2-节基-2-二曱基胺基 (4-嗎啉代基苯基）-丁烷—1 一酮、2一（二甲基胺基）_2_[(4_ 甲基苯基）甲基]-l-[4-(4-嗎啉基）苯基]―卜丁酮等苯乙酮 系化合物；苯偶因、苯偶因甲基醚、苯偶因乙基醚、苯偶 因異丙醚、苯偶醯二曱基縮酮（benzil dimethyi ketal) 等本偶因系化合物，一本甲S同（benzophenone)、苯甲酿苯 曱St、本曱醢本甲酸甲醋、4-苯基二苯甲酮、經基二苯曱 酮、丙烯酸化的二苯曱酮、4-苯甲醯基一4, _甲基二苯硫醚、 3, 3’，4, 4’-四（第三丁基過氧化羰基）二苯甲_等二苯甲酮 系化合物；噻噸酮、2-氣噻噸酮、2-甲基噻噸酮、異丙基 噻噸酮、2, 4-二異丙基噻噸酮、2, 4-二乙基噻噸酮等噻噸 322802 36 201142501 酮系化合物；2, 4, 6-三氣-s-三啡、2-笨基-4, 6-二（三氣曱 基）-s-三畊、2-(對曱氧基苯基）_4,6_二（三氣曱基）_s_三 11井、2-(對甲苯基）-4,6-二（三氯甲基）-s-三畊、2-胡椒基 -4, 6-二（三氣甲基）-s—三哄、2, 4-二（三氯甲基）-6-苯乙烯 基-S-三畊、2-(萘-1-基）_4,6-二（三氯甲基）-s_三畊、 2-(4-曱氧基-萘-1-基）一4, 6-二（三氯曱基）-s-三畊、2, 4-二氣曱基-胡椒基-6-三畊、2, 4-三氯曱基（4,-甲氧基苯乙 烯基）-6-三畊等三哄系化合物；1，2-辛二酮，i-[4-(苯硫基） 苯基-，2-(0-笨曱醯肟）]、〇-(乙醯基tN—d —苯基_2_側氧 基（oxo)-2-(4 -甲氧基-萘基）亞乙基）羥基胺等肟酯系化 合物；二（2, 4, 6-三曱基苯曱醯基）苯基膦氧化物、2, 4, 6-三甲基苯曱醯基-二苯基-膦氧化物等膦系化合物；2, 2，_ 一（鄰乳苯基）-4, 5, 4’，5’-四苯基-1,2’-聯味嗤、2, 2’-二 (鄰曱氧基苯基）-4, 4’，5, 5’ -四苯基聯咪唑、2, 2,-二（鄰氣 笨基）-4, 4，5, 5’ -四（對甲基苯基）聯味嗤等咪唾系化合 物；9, 10-菲醌、樟腦醌、乙基蒽醌等醌系化合物；硼酸酯 系化合物、吟β坐系化合物、二茂鈦（Utan〇cene)系化合物 等。 其中’更佳為包含選自苯乙酮系化合物、膦系化合物 和咪唑系化合物所構成群組中的至少一種以上的光聚合引 發劑（Y)。 此等光聚合引發劑可以使用1種或根據需要以任意比 率將2種以上混合使用。其它的光聚合引發劑（γ)，相對於 感光性著色組合物中的顏料（D)l〇〇重量份，可以以1至2q〇 322802 37 201142501 重量份的量’較佳為以1至150重量份的量使用。 此外，相對於100重量份光聚合引發劑（A),可以以1 至10重量伤的量使用。為了得到更良好的财藥品性，相 對於100 4量份光聚合引發劑（A)，較佳為5至議重量份 的量。 &lt;增感劑（E)&gt; 進步，在本發明的感光性著色組合物中，還可以含 有增感劑⑻。增感劑⑻的含量，相對於感光性著色組合 物中的光聚合引發劑（A) 1 〇〇重量份，可以以1至1 〇〇重量 份的量使用》 作為增感劑（E) ’可以列舉.以查耳酮（cha]_c〇ne)衍生 物和二苄又丙鲖（dibenza lace tone)等為代表的不飽和酮 類、以苯偶醢和樟腦親等為代表的1，2_二酮衍生物、苯偶 因衍生物、第衍生物、萘I昆衍生物、蒽醌衍生物、氧雜蒽 衍生物、嗟噸（thioxanthene)衍生物、氧雜蒽酮衍生物、 噻噸酮（thioxanthone)衍生物、香豆素衍生物、香豆素酮 衍生物、花青（cyanine)衍生物、部花青（merocyanine)衍 生物、氧雜菁（oxonol)衍生物等聚曱快（polymethine)色 素、°丫咬衍生物、。丫哄（azine)衍生物、°塞哄（thiazine) 衍生物、曙哄衍生物、朵嚇·衍生物、奠衍生物、奠鏽 (azulenium)衍生物、方酸内鑌（squarylium)衍生物、卟淋 衍生物、四苯基卟啉衍生物、三芳基甲烷衍生物、四苯并 卟琳衍生物、四°比哄并四氮雜卟琳 (tetrapyrazinoporphyrazine)衍生物、酜菁 38 322802 201142501 (phthalocyanine)衍生物、四氣雜卟琳 (tetraazaporphyrazine)衍生物、四啥噚琳并四氮雜卟淋 衍生物、萘醜菁衍生物、亞献菁（subphthalocyanine)衍生 物、吡喃鑌（pyrylium)衍生物、噻喃鏽衍生物、四葉蘿芙 靈（tetraphylline)衍生物、輪烯（annulene)衍生物、螺0比 喃（spiropyran)衍生物、螺曙哄（spiroxazine)衍生物、硫 代螺n比鳴衍生物、金屬芳烴（metal arene)錯合物、有機釕 錯合物、米其勒酮（Michler’s ketone)衍生物等。 進一步，作為該等的具體例，可以列舉在大河原信等 編“色素手冊”（1986年，講談社）、大河原信等編“機能 性色素之化學”（1981年，CMC)、以及池森忠三朗等編“特 殊機能材料”（1986年，CMC)中記載的增感劑，但是並不 限定於此等。並且，除此之外，還可以含有對於從紫外線 到近紅外線區域的光顯示出吸收的增感劑。 在上述增感劑（E)中，作為可特別適合地對通式（1)和 (11)所表示的化合物進行增感的增感劑，4以列舉嘆嘲_ 衍生物、米其勒酮衍生物、咔唑衍生物。更具體來說’可 以使用2, 4-二乙基噻噸酮、2-氯噻噸酮、2, 4-二氯噻β頓酮、 2-異丙基噻噸酮、4-異丙基噻噸酮、1-氯-4-丙氧基嗟嘲 酮、4, 4’ -二（二甲基胺基）二苯甲酮、4, 4’ -二（二乙基胺基） 二苯曱酮、4, 4’-二（乙基曱基胺基）二苯甲酮、Ν-乙基咔 嗤、3-苯甲醯基-Ν-乙基吟嗤、和3, 6-二苯甲醯基-Ν-乙基 咔唑等。 就增感劑（Ε)而言’也可以以任意比率含有兩種以上的 39 322802 201142501 增感劑。 &lt;樹脂（B)&gt; 本發明的感光性著色組合物中含有的樹脂（B)，較佳是 在可見光區域的400至700nm的整個波長區域中其穿透率 為80%以上，更佳為95%以上的樹脂。樹脂（b)包括熱塑性 樹脂、熱固性樹脂和感光性樹脂，該等可以單獨使用或者 將兩種以上混合使用。 作為熱塑性樹脂，例如，可以列舉縮丁酿（butyra 1) 樹脂、苯乙烯-馬來酸共聚物、氣化聚乙烯、氯化聚丙烯、 聚氣乙烯、氣乙烯-乙酸乙烯酯共聚物、聚乙酸乙嫦酯、聚 胺酯（polyurethane)系樹脂、聚酯樹脂、丙烯酸系樹脂、 醇酸樹脂、聚苯乙烯、聚醯胺樹脂、橡膠系樹脂、環化橡 膠系樹脂、纖維素類、聚乙烯、聚丁二烯、聚醯亞胺樹脂 等。 此外，作為熱固性樹脂，例如，可以列舉環氧樹脂、 笨并胍胺樹脂、松香改性馬來酸樹脂、松香改性富馬酸樹 脂、三聚氰胺樹脂、尿素樹脂、酚醛樹脂等。 作為感光性樹脂，可以使用將具有異氰酸酯基、醛基、 環氧基等反應性取代基的（曱基）丙烯酸系化合物或肉桂酸 與具有羥基、羧基、胺基等反應性取代基的線狀高分子反 應，而在該線狀高分子中導入（曱基）丙烯醯基、苯乙烯基 等光交聯性基團所得的樹脂。此外，還可以使用藉由（甲基） 丙烯酸羥基烷酯等具有羥基的（甲基）丙烯酸系化合物而使 苯乙烯-馬來酸酐共聚物、烯烴_馬來酸酐共聚物等含有 40 322802 201142501 酸針的線狀高分子進行半酯化而得的樹脂。 樹脂（B)，相對於感光性著色組合物中的顏料（d)i⑼ 重量份，可以以20至400重量份，較佳為以5〇至25〇重 量份的量使用。 〈光聚合性化合物（C)&gt; 本發明的感光性著色組合物中含有的光聚合性化合物 (C)，是光聚合性單體或低聚物，例如，可以列舉（曱美） 丙烯酸曱酯、（曱基）丙烯酸乙酯、（甲基）丙烯酸2_羥基i乙 酯、（甲基）丙烯酸2-羥基丙酯、（曱基）丙烯酸環己醋、（甲 基）丙烯酸沒-羧乙酯、聚乙二醇二（甲基）丙烯酸酯、丨6_ 己二醇二（曱基）丙烯酸酯 二乙二醇二（甲基）丙烯酸酯、 二丙二醇二（甲基）丙烯酸酯、三羥甲基丙烷三（甲基）丙烯 酸酯、季戊四醇三（曱基）丙烯酸酯、丨’^己二醇二縮水甘 油醚二（曱基）丙烯酸酯、雙酚A二縮水甘油醚二（甲基）丙 烯酸酯、新戊二醇二縮水甘油醚二（曱基）丙烯酸酯、二季 戊四醇六（曱基）丙烯酸酯、（曱基）丙烯酸三環癸酯、醋基 丙烯酸酯、羥甲基化三聚氰胺的（甲基）丙烯酸酯、環氧基 (曱基）丙烯酸酯、胺酯丙烯酸酯等各種丙稀酸酯和曱基丙 烯酸酯、（甲基）丙烯酸、苯乙烯、乙酸乙烯酯、羥乙基乙 彿基韃、乙二醇二乙稀基醚、季戊四醇三乙烯基趟、（甲基） 丙稀酿胺、N-經甲基（曱基）丙稀醯胺、N-乙埽基甲醯胺、 丙烯腈等。該等可以單獨使用或者將兩種以上混合使用。 光聚合性化合物（C)，相對於感光性著色組合物中的顏 料（D)l〇〇重量份，可以以10至3〇〇重量份，較佳為以1〇 41 322802 201142501 至200重量份的量使用。 在感光I·生著色細合物中，光聚合引發劑⑴的重 與光聚合性化合物⑹的重f [M]的比率[Ia/M]，較佳為 。.〇3至l.oo :並更佳為〇 〇4至〇 95。 進步田感光性著色組合物含有增感劑（E)和其它 光聚合引發劑00時，光聚合引發劑⑴、增_(E)和^ ^聚合引發劑（γ)的合計重量⑹與光聚合性化合物⑹ 〇 〇重5:[:]的比率[Ib/M]，較佳為〇.。4至1· 5。，並更佳為 田為〇. 03以上，[WM]為〇. 04以上時，感度高， 效果良好。此外，當⑽]為1.00以下，[Ib/M]為1·5(Γ以 下時’圖案形狀的直線性和解析度更優異。 〈顏料（D)&gt; 、作為本發明的感光性著色組合物中含有的顏料（D)，可 乂將^機或無機顏料單獨使用或者將兩種以上混合使用。 ^頁料中較佳為顯色性高並且耐熱性高的顏料。通常可 以使用有機顏料。 以下，用顏料索引號（C.I.)來表示在本發明的感光性 著色組合物中可以使用的有機顏料的具體例。 在用於形成紅色濾波器節的紅色感光性著色組合物 中’例如’可以使用C. I.顏料紅7、9、14、41、48 :卜 48 · 2、48 : 3、48 ·· 4、81 : 1、81 : 2、81 : 3、97、122、 123 、 146 、 149 、 168 、 177 、 178 、 179 、 180 、 184 、 185 、 187 、 192 、 200 、 202 、 208 、 210 、 215 、 216 、 217 、 220 、 42 322802 201142501 223 、 224 、 226 、 227 、 228 、 240 、 242 、 246 、 254 、 255 、 264、272、279等紅色顏料。在紅色感光性著色組合物中， 還可以併用黃色顏料、橙色顏料。 作為在紅色感光性著色組合物中可以併用的黃色顏 料，例如，可以使用C. I.顏料黃1、2、3、4、5、6、10、 12、13、14、15、16、17、18、20、24、3卜 32、34、35、 35 :卜 36、36 :卜 37、37 : 1、40、42、43、53、55、60、 6卜 62、63、65、73、74、77、8卜 83、86、93、94、95、 97、98、100、1(U、104、106、108、109、110、113、114、 115 、 116 、 117 、 118 、 119 、 120 、 123 、 125 、 126 、 127 、 128 、 129 、 137 、 138 、 139 、 147 、 148 、 150 、 151 、 152 、 153 、 154 、 155 、 156 、 16卜 162 、 164 、 166 、 167 、 168 、 169 、 170 、 171 、 172 、 173 、 174 、 175 、 176 、 177 、 179 、 180 、 18卜 182 、 185 、 187 、 188 、 193 、 194 、 199 、 213 、 214 等。 此外，在用於形成黃色慮波器節的黃色感光性著色組 合物中，此等黃色顏料可以單獨使用或將兩種以上組合使 用。 作為在紅色感光性著色組合物中可以併用的橙色顏 料，例如，可以使用C. I.顏料撥36、43、51、55、59、61、 71、73等橙色顏料。 此外，在用於形成橙色濾、波器節的橙色感光性著色組 合物中，此等橙色顏料可以單獨使用或將兩種以上組合使 用0 43 322802 201142501 在用於形成綠色濾波器節的綠色感光性著色組合物 中，例如，可以使用C· I·顏料綠7、1〇、36、37和58等 綠色顏料。在綠色感光性著色組合物中，還可以併用上述 黃色顏料。 在用於形成藍色滤波器郎的藍色感光性著色組合物 中，例如，可以使用C· I.顏料藍15、15 : 1、15 : 2、15 : 3、15 : 4、15 ·· 6、16、22、60、64、80 等藍色顏料。在 藍色感光性著色組合物中’還可以併用C. I.顏料紫1、19、 23、27、29、30、32、37、40、42、50 等紫色顏料。 在用於形成青色（cyan)濾波器節的青色感光性著色組 合物中，例如，可以使用C· I.顏料藍15 : 1、15 : 2、15 : 3、15: 4、15: 6、16、80 等藍色顏料。 在用於形成品紅色（magenta)濾波器節的品紅色感光 性著色組合物中，例如’可以使用C. I·顏料紫1、19等紫 色顏料’以及C. I·顏料紅81、144、146、177、169等紅 色顏料。在品紅色感光性著色組合物中，還可以併用黃色 顏料。 在用於形成黑色矩陣的黑色感光性著色組合物中，例 如，可以使用碳黑（carbon black)、苯胺黑、蒽醌系黑色 顏料、茈系黑色顏料’具體來說，可以使用C. I.顏料專j、 6、7、12、20、31等。在黑色感光性著色組合物中，也可 以使用紅色顏料、藍色顏料、綠色顏料的混合物。作為専 色顏料，從價格、遮光性程度的觀點考慮，較佳為碳黑， 並且碳黑也可以用樹脂等進行表面處理。此外，為了調整 322802 44 201142501 =色感—物中，還可藍色顏料 此外，作為無機顏料，可以列舉硫酸鋇 鉛、鉛黃、鋅黃、鐵丹（氧化鐵紅（ιι 、硫酸 魯士藍、氧化鉻綠、鈷綠、 知、，工、群青、普 氧化鈦、四氧化鐵等金屬氧化物粉、丄二化‘成鐵黑、 粉等❶為了獲得彩度和亮度 金屬1化物粉、金屬 性、感度、顯影性等，將I嫉:衡’同時確保良好的塗布 在本發明的感光性^色^^有T料組合使用。 以在不降低耐熱性的範圍内含有穴申‘、、了進仃調色，可 以本發明的感光性著多 ； (100重量％)，朗（D)成分的I 總&quot;^發成分為基準 現性的觀點考慮’較佳為1。重量%以上，顏色再 以上，並最佳為20重量％以上 更佳為丨5重量％ 組合物的获性的觀點考慮，顏從提高感光性著色 90重量％以下，更佳為80重量％以丁 权佳為 里％以下，並最佳為70重量0/ 以下。 发/〇 〈多官能硫醇（F)&gt; 在本發明的感光性著色組合物中，可以含有多官能讲 醇(F)e多官能硫醇(F)是具有2個以上硫醇⑽基的= 物。 多官能硫醇⑻藉由與上述光聚合引發劑⑴一起 用，在光照射後的自由基聚合過程中’發揮作為鍵轉移 的作用，產生不易因氧而受到阻聚的硫自由基 45 幻28〇2 201142501 radical) ’因此所得的感光性著色組合物的感度變高。特 別以SH基與亞甲基（methylene)、伸乙基（ethylene)等月旨 肪族基團結合的多官能脂肪族硫醇為佳。 例如，可以列舉己二硫醇、癸二硫醇、丨，4_丁二醇二 硫代丙酸酯、1，4_丁二醇二硫代乙醇酸酯、乙二醇二硫； 乙醇酸酯、乙二醇二硫代丙酸酯、三羥曱基丙烷三硫代乙 醇酸S曰、二羥甲基丙烷三硫代丙酸酯、三羥甲基乙烷三 酼基丁酸目旨）、絲曱基咕三（3，基旨）、三經 丙烧三（3-Μ基丙酸S旨）、季細H四硫代乙醇酸酯、季^ 四醇四硫代丙酸醋、季戊四肖四（3_疏基丙酸醋）、二季^ 四醇六（3,基丙酸酯）、三疏基丙酸三（2_經乙基）= 酸醋、U 4-二甲基巯基苯、2, 4, 6_三巯基个三哄、2—(ν: 二丁基胺基）-4, 6-二職十三哄等。此等多官能硫醇 單獨使用-種或者將2種以上混合使用。 多官能硫醇⑺的含量，相對於100重量份顏料（D) 較佳至議重量份，並更佳為U至50.0重量伤 &amp;站认由使用〇·05重量份以上的多官能硫醇’可以得到 二無性。在使用硫醇(SH)基為1個的單官能硫 夺無去獲付這種耐顯影性的提高。 〈紫外線吸收劑⑹、阻聚劑⑻〉 收二明的感光性著色組合物中，可以含有紫外線 m 4聚雜)。藉由含有紫外線吸收劑⑹或阻聚 製圖案的形狀和解析度。作為紫外線吸收劑 °以列舉·2-[4-[(2~錄_3_(十三錄和十三烧邊 322802 46 201142501 氧基丙基）氧基]-2-經基笨基]-4, 6 -二（2, 4-二甲基苯基） -1,3, 5-三哄、2-(2-羥基-4-[l-辛氧基羰基乙氧基]苯基） _4, 6-二（4-苯基苯基）-1，3, 5-三哄等羥基苯基三D井系； 2-(5-甲基-2-超基苯基）苯并三β坐、2-(2H-苯并三唾-2-基） -4,6-一（1_曱基_1-本基乙基）苯盼、2-(3-第三丁基-5-曱 基-2-羥基苯基）-5-氯苯并***等苯并***系；2, 4-二羥基 二苯曱酮、2-羥基-4-辛氧基二苯曱酮、2, 2,，4, 4,-四羥基 二苯甲酮等二苯甲酮系；苯基水揚酸酯、對第三丁基苯基 水楊酸酯等水楊酸酯系；乙基-2-氰基-3, 3，-二苯基丙婦酸 酯等氰基丙烯酸酯系；2, 2, 6, 6-四曱基哌啶-1-氡基（三丙 酮-胺-N-氧基）、二（2, 2, 6, 6-四甲基-4-哌啶基）—癸二酸 酯、聚[[6-[(1，1，3,3-四丁基）胺基]-1，3,5-三哄-2,4-二 基][(2, 2, 6, 6-四甲基-4-派咬基）亞胺基]等受阻胺系等， 該等可以單獨使用或混合使用。此外，作為阻聚劑，例如， 可以列舉：曱基氫醌、第三丁基氫醌、2, 5_二第三丁基氫 画昆、4-苯酿、4-曱氧基苯酴、4-甲氧基-1-萘盼、第三丁基 兒茶酚等氫醌衍生物和苯酚化合物；啡隹哄 (phenothiazine)、二（1-二甲基苄基）啡噻哄、3, 7-二辛基 啡噻畊等胺化合物；二丁基二硫代胺基甲酸銅、二乙基二 硫代胺基曱酸銅、二乙基二硫代胺基曱酸錳、二苯基二硫 代胺基曱酸錳等銅和錳鹽化合物；4-亞硝基苯酚、N_亞石肖 基二苯基胺、N-亞硝基環己基經基胺、N-亞硝基苯基羥基 胺等亞硝基化合物及其銨鹽或鋁鹽等，該等可以單獨使用 或混合使用。 47 322802 201142501 紫外線吸收劑和阻聚劑，相對於著色組合物中的顏料 (D)100重量份，可以以0. 01至20重量份，並較佳為以0. 05 至10重量份的量（合計量）使用。 藉由使用0.01重量份以上的紫外線吸收劑或阻聚 劑，可以得到更良好的解析度。 〈儲藏穩定劑（J)&gt; 在本發明的感光性著色組合物中，可以含有儲藏穩定 劑（J)。藉由含有儲藏穩定劑（J)，可以使組合物的經時黏 度穩定化。作為儲藏穩定劑，例如，可以列舉：2, 6-二（1，1-二曱基乙基）-4-曱基苯酚、季戊四醇四[3-(3, 5-二第三丁 基-4-羥基苯基）丙酸酯]、2, 4-二（正辛基硫基）-6-(4-羥基 -3, 5 -二第三丁基苯胺基）1，3，5_三哄等受阻紛系；四乙基 膦、三苯基膦、四苯基膦等有機膦系；二甲基二硫代磷酸 鋅、二丙基二硫代磷酸鋅、二丁基二硫代磷酸鉬等亞磷酸 鹽系；十二烷基硫化物、苯并噻吩等硫系；苄基三曱基氯 化物、二乙基羥基胺等四級銨氣化物；乳酸、草酸等有機 酸及其曱基醚等，該等可以單獨使用或者混合使用。 儲藏穩定劑，相對於著色組合物中的顏料（D)100重量 份，可以以0. 01至20重量份，較佳為以0. 05至10重量 份的量使用。 藉由使用0. 01重量份以上的儲藏穩定劑，可以提高感 光性著色組合物的經時穩定性。 〈溶劑〉 為了能夠很容易地使顏料（D)充分分散在樹脂（B)或光 48 322802 201142501 聚合性化合物（c)等色素載财，並且在玻璃基板等透明基 板上塗布至乾燥臈厚為〇· 2 i lGem，而形成濾波器節和 黑色矩陣，在本發明的感光性著色組合物中，可以含有溶 劑。作為溶劑，例如，可以列舉i，2,3_三氯丙烷、丨，3一丁 烷一醇、1’ 3-丁二醇、1，3-丁二醇二乙酸酯、丨，4_二噚烷、 2-庚酮、2-甲基-1，3-丙烷二醇、3, 5, 5_三甲基_2_環己烯 1酮、3, 3, 5-二甲基環己酮、3_乙氧基丙酸乙酯、3_甲基 -1,3-丁烷二醇、3一甲氧基_3_甲基丁醇、3_甲氧基_3_ 甲基丁基乙酸醋、3-甲氧基丁醇、3_甲氧基丁基乙酸醋、 4-庚酮、間二甲苯、間二乙基苯、間二氣苯、N，N_二甲基 乙醯胺、N’N-二曱基曱醯胺、正丁醇、正丁基苯、正丙基 乙酸酯、N-甲基吼洛咬酮、鄰二甲苯、鄰氯曱苯、鄰二乙 基苯、鄰二氣苯、對氣曱苯、對二乙基苯、第二丁基苯、 第三丁基苯、r-丁内酯、異丁醇、異佛爾酮、乙二醇二乙 基醚、乙二醇二丁基醚、乙二醇單異丙基醚、乙二醇單乙 基醚、乙二醇單乙基醚乙酸酯、乙二醇單第三丁基醚、乙 二醇單丁基趟、乙二醇單丁基韆乙酸s旨、乙二醇單丙基謎、 乙二醇單己基趟、乙二醇單曱基喊、乙二醇單甲基鱗乙酸 酯、二異丁基_、二乙二醇二乙基喊、二乙二醇二甲基謎、 二乙二醇單異丙基醚、二乙二醇單乙基醚乙酸酯、二乙二 醇單丁基趟、二乙二醇單丁躺乙酸醋、二乙二醇單甲基 醚、環己醇、環己醇乙酸醋、環己綱、二丙二醇二甲細土、 二丙二醇甲基醚乙酸酯、二丙二醇單乙基醚、二丙二醇單 丁基醚、二丙二醇單丙基崎、二丙二醇單甲基鱗、 322802 49 201142501 醇、甘油三乙酸g旨（tri ace tin)、三丙二醇單丁基謎、三丙 二醇單曱基醚、丙二醇二乙酸酯、丙二醇苯基醚、丙二醇 單乙基醚、丙二醇單乙基醚乙酸酯、丙二醇單丁基醚、丙 二醇單丙基醚、丙二醇單曱基醚、丙二醇單曱基醚乙酸酯、 丙二醇單甲基醚丙酸酯、苄醇、曱基異丁基酮、曱基環己 醇、乙酸正戊酯、乙酸正丁酯、乙酸異戊酯、乙酸異丁酯、 乙酸丙酯、二元酸酯等，該等可以單獨使用或混合使用。 溶劑，相對於著色組合物中的顏料（D)100重量份，可 以以100至10000重量份，並較佳為以500至5000重量份 的量使用。 〈其它成分〉 在本發明的感光性著色組合物中，為了提高與透明基 板的密合性，可以含有矽烷偶合劑等密合提高劑。 作為矽烷偶合劑，例如，可以列舉：乙烯基三（/5-甲 氧基乙氧基）梦焼·、乙稀基乙氧基碎烧、乙稀基三曱氧基碎 烷等乙烯基矽烷類；曱基丙烯醯氧基丙基三曱氧基矽烷 等（曱基）丙烯酸系矽烷類；/5-(3, 4-環氧基環己基）乙基三 曱氧基矽烷、β-(3, 4-環氧基環己基）曱基三曱氧基矽烷、 召-(3, 4-環氧基環己基）乙基三乙氧基矽烷、-(3, 4-環氧 基環己基）曱基三乙氧基矽烷、T-環氧丙氧基丙基三曱氧 基矽烷、T-環氧丙氧基丙基三乙氧基矽烷等環氧基矽烷 類；Ν-；5 (胺基乙基）r -胺基丙基三甲氧基矽烷、N-/3 (胺 基乙基）7 _胺基丙基三乙氧基梦烧、N-yS (胺基乙基）7 _ 胺基丙基甲基二乙氧基矽烷、T-胺基丙基三乙氧基矽烷、 50 322802 201142501 r -胺基丙基三甲氧基矽烷、N-苯基-7 -胺基丙基三甲氧基 矽烷、N-苯基-r -胺基丙基三乙氧基矽烷等胺基矽烷類； 魏基丙基二甲氧基石夕烧、7_疏基丙基三乙氧基碎院等 硫矽烷類等。 矽烷偶合劑，相對於著色組合物中的顏料（D)100重量 份，可以以0. 01至10重量份，較佳為以0. 05至5重量份 的量使用。 此外，在本發明的感光性著色組合物中，可以含有具 有將溶存之氧予以還原的作用的胺系化合物。 作為這種胺系化合物，可以列舉三乙醇胺、曱基二乙 醇胺、三異丙醇胺、4-二曱基胺基苯曱酸曱酯、4-二曱基 胺基苯甲酸乙酯、4-二甲基胺基苯甲酸異戊酯、苯曱酸2-二甲基胺基乙酯、4-二甲基胺基苯甲酸2-乙基己酯、N，N-二曱基對曱苯胺等。 〈感光性著色組合物的製法〉 本發明的感光性著色組合物，可以藉由下述方法製 造。使用三支式幸昆磨機（triple roll mill)、雙支式親磨 機、砂磨機、捏合機、磨碎機（attritor)等各種分散設備 將顏料（D)微細地分散在樹脂（B)等色素載體和/或溶劑 中，製造顏料分散體，然後，在該顏料分散體中混合光聚 合引發劑（A)、樹脂（B)、光聚合性化合物（C)、根據情況添 加的其它光聚合引發劑（Y)、增感劑（E)、多官能硫醇（F)、 紫外線吸收劑（G)、阻聚劑（H)、儲藏穩定劑（J)、溶劑和其 它成分，並進行授拌，由此而可製造感光性著色組合物。 51 322802 201142501 此外’包含2種以上顏料的感光性著色組合物，可以藉由 將各顏料分別微細地分散在色素载體和/或溶劑中所形成 的各顏料分散體進行混合，再進—步混合光聚合引發劑 (A)、光聚合性化合物⑹等，並騎勝而製造。 在將顏料分散在樹脂（B)和/或溶劑中時，可以適當地 含有樹脂型顏料分散劑、表面活性劑、顏料衍生物等分散 助劑/分散助劑使顏料的分散變得優異，並且防止分散後 的顏料再次凝聚的效果好，因此在使用藉由利用分散助劑 將顏料刀散在樹脂（B)和/或溶劑中而形成的感光性著色組 合物時，可以得到透明性優異的濾色器。 /刀散助劑’相對於100重量份顏料（D)，可以以0. 1至 40重量份’較佳為以〇. 1至30重量份的量使用。 作為樹·脂型顏料分散劑，是包含具有吸附於顏料的性 質的顏料親和性部位、和與色素载體具有相溶性的部位， 並且會發揮_於顏料而使顏料在色素載體中駭分散之 作用的物質。作為樹脂型顏料分散劑，具體來說，可以使 用聚胺S旨' 旨等聚麟S旨、不飽和聚醯胺、聚缓 I聚叛卩分）胺鹽、聚叛酸銨鹽 、聚羧酸烷基胺鹽、 聚夕氧烧長鏈聚鞍基酿胺碳酸鹽、含經基的聚叛酸醋、 該等的改性物、藉由聚（低級伸烧基亞胺）與具有游離叛基 的㈣的反應而形成的醯胺及其鹽等油性分散劑、（甲基） 丙烯I I乙稀共聚物、（甲基）丙稀酸_(甲基）丙稀酸醋共 聚物本乙稀•馬來酸共聚物、聚乙烯醇、聚乙稀吼略咬酉同 等水溶性樹1¾水溶性高分子化合物、聚㈣、改性聚丙 52 322802 201142501 烯酸酯系、環氧乙烧（ethylene oxide)/環氧丙烧 (propylene oxide)加成化合物、填酸酯系等。該等可以單 獨使用或者將2種以上混合使用。 作為市售的樹脂型分散劑，可以列舉畢克化學曰本 (BYK-Chemie Japan)公司製的 Disperbyk-101、103、107、 108、110、1U、116、130、140、154、16卜 162、163、 164 、 165 、 166 、 170 、 171 、 174 、 180 、 181 、 182 、 183 、 184、185、190、2000、2001、2020、2025、2050、2070、 2095、2150、2155，或 Anti-Terra-U、203、204，或 BYK-P104、P104S、220S、6919，或 Lactimon、Lactimon_WS 或Bykumen等，日本路博潤（Japan Lubrizol)公司製的 SOLSPERSE-3000 、 9000 、 13000 、 13240 、 13650 、 13940 、 16000、17000、18000、20000、21000、24000、26000、27000、 28000、31845、32000、32500、32550、33500、32600、34750、 35100、36600、38500、41000、41090、53095、55000、76500 等，汽巴日本（Ciba Japan)公司製的EFKA-46、47、48、 452、4008、4009、4010、4015、4020、4047、4050、4055、 4060、4080、4400、44(U、4402、4403、4406、4408、4300、 4310、4320、4330、4340、450、45卜 453、4540、4550、 4560、4800、5010、5065、5066、5070、7500、7554、11(H、 120、150、1501、1502、1503 等，味之素精細化學（Ajinomoto Fine-Techno)公司製的 Adisper PA1U、PB71 卜 PB82卜 PB822 、 PB824 等。 作為表面活性劑，可以列舉：聚氧乙烯烷基醚 53 322802 201142501 (polyoxyethylene alkyl ether)硫酸鹽、十二烷基苯磺酸 鈉、苯乙烯-丙烯酸共聚物的鹼鹽、烷基萘磺酸鈉、烷基二 苯基醚二磺酸鈉、月桂基硫酸單乙醇胺、月桂基硫酸三乙 醇fee、月桂基硫酸錄，及又力曰H又干U吁收、々更脂吸納、月相 基硫酸納、苯乙稀-丙烯酸共聚物的單乙醇胺、聚氧乙稀爲 基醚磷酸酯等陰離子性表面活性劑；聚氧乙烯油基醚、影 氧乙婦月桂基峻、聚氧乙稀壬基苯基喊、聚氧乙婦烷基幽 磷酸Sa、聚氧乙稀山梨糖醇肝單硬脂酸酯、聚乙二醇單月 桂酸醋㈣離子性表面活性劑；絲讀㈣及該等的缚 氧乙烷加成物等陽離子性表面活性劑.；烷基二甲基胺基乙 酸甜菜驗等燒基甜菜驗、烧基味唾琳等兩性表面活性劑， 該等可以單獨使用或者將2種以上混合使用。 所謂顏料触物，是在有機顏料中導人取代基而得到 的化合物，有機賴也包含—般不被稱作㈣的 贫 酿系等淡黃色的芳㈣多環化合物。作為顏料街生物，- 昭63'3G5m號公報、日本特公昭％ 5620 ^報、日本特公昭59_4()172號公報、 而2號公報、日本特公平5-9彻號公報等中記= 質，該等可以單獨使用或者將2種以上混合使用 本發明的感光性著色組合物，可以以 顯影型著色抗蝕劑材料的形式進 :丨顯衫型或鹼 料，是將顏料(D)分散在入有鹼·°° 。者色抗蝕劑材 化合物⑹、光性樹物、光聚合性 材料。聚°引發劑（Α)和溶劑的組合物中而得到的 322802 54 201142501 感光性著色組合物，較佳為使用離心分離、燒結過滤 器、職器科段，除去其巾以上的粗大粒子，較佳 為除去l/zm以上的粗大粒子，更佳為除去G 5#m以上的 粗大粒子以及混入的塵埃。 〈濾色器〉 接者，對本發明的渡色器進行說明。 一本發明的濾色器，係在透明基板上具有由本發明的感 光性著色組合物形成的濾波器節和/或黑色矩陣，一般的濾 色器具有至少-個紅色濾波器節、至少一個綠色濾波器節 和至少一個藍色濾波器節，或者具有至少一個品紅色濾波 器節、至少一個青色濾波器節和至少一個黃色濾波器節。 作為透明基板，可以使用鈉鈣玻璃、低驗硼石夕酸玻璃、 無鹼鋁硼矽酸玻璃等玻璃板，或者聚碳酸酯、聚甲基丙烯 酸甲酷、聚對苯二甲酸乙二醇酯等樹脂板。此外，為了驅 動面板化後的液晶，可以在玻璃板或樹脂板的表面上形成 由氧化銦、氧化錫等所構成的透明電極。 濾波器節和黑色矩陣的乾燥膜厚，較佳為〇. 2至 10//in，並更佳為0.2至5//in。在乾燥塗膜時，可以使用 減壓乾燥機、對流烘箱、IR烘箱、熱板等。 藉由光刻法（photo 1 i thography)形成各色渡波器節和 黑色矩陣，係按照下述方法進行。亦即，藉由噴塗、旋塗、 狹，塗布或輥塗等塗布方法，將作為溶_影型或驗顯影 型著色抗㈣材料而調製的感光性著色組合物塗布在透明 基板上’使乾燥膜厚為（^至。對於根據需要而乾 322802 55 201142501 燥，的蹲，通過以與該膜接觸或非接觸狀態所設置的具有 預定圖案的遮罩（mask)進行紫外線曝光。 然後，可以將其浸潰在溶劑或鹼顯影液中，或者藉由 噴霧器等喷霧顯影液，除去未固化部分，形成所希望的圖 案，，從而形成濾波器節和黑色矩陣。此外，為了促進藉由 .，属〜所％成的濾波器節和黑色矩陣的聚 要進行㈣。藉由光刻法，可⑽成精度比印刷 濾' 波器節和黑色矩陣。 在顯影時’使用碳酸鈉、氫氧化鈉等的水溶液作為驗 顯影液’也可以使用二甲基节基胺、三乙醇胺等有機驗。 此外在顯影液中還可以添加消泡劑或表面活性劑。 作為顯影處理方法，可以適用噴淋顯影法、喷霧顯影 法、浸潰（dipping)顯影法、攪拌（液盛，paddle)顯影法等。/ 。另外，為了提高紫外線曝光感度，還可以在塗布並乾 燥上述感光性著色組合物後，塗布水溶性或鹼可溶性樹 脂，例如聚乙烯醇或水溶性丙烯酸系樹脂等並乾燥，形成 防止因氧所造成之阻礙聚合的膜，然後進行紫外線曝光。 實施例 以下，依據實施例對本發明進行具體說明，但口要不 超出本發明的要旨，則其並不限定於以下的實施例&quot;7另外， 在實施例和比較例中，“份”是指“重量份”。 此外，丙烯酸系樹脂溶液中的樹脂的分子量，是使用 HLC-8220GPC(東曹股份有限公司製）作為裝置，並將2個 TSK-GEL SUPER ΗΖΜ-Ν連接起來作為管柱使用，且使用丁肝 322802 56 201142501 作為溶劑所測定的聚苯乙烯換算的重均分子量。 首先《周整3有通式⑴所表示的光聚合引發劑（A)的 感光性著色組合物’使用其製韻色^，並評價各種特性 (實施例1至24和比較例1至2)。 感光性著色組合物的調整，係藉由分別合成/製造通式 (1)所表㈣光聚合！|發劑（A)、㈣酸純脂溶液、顏料 分散體’並將該等予以混合等而進行。 在光聚合引發劑（A)的合成中，首先合成中間艘化合 物’接著由該中間體化合物合成前驅體化合物，然後由該 刖驅體化合物合成该光聚合引發劑。對所得的化合物，進 行元素分析（C、Η、N)(珀金埃爾默（PerkinElmer)公司製的 2400 .CHN)和藉由 EI-MS (Thermo 公司製的 p〇iarisQ)進 行質量分析，確認各自的結構。 〈通式（1)所表示的光聚合引發劑（A)的製造方法&gt; [光聚合引發劑（A1)的合成] 將lOO.Og N-二苯甲酮基咔唑溶解在1〇〇〇ml氯仿中， 再添加85· Og氣化鋁，在〇它進行攪拌下，經2小時滴加 已將32. Og丙酿亂溶於5〇〇ml氣仿的溶液。滴加結束後， 在25°C攪拌4小時。將反應液倒入2〇〇〇g冰水中，用2000ml 氯仿進行萃取。用硫酸鎂乾燥有機層，過濾乾燥劑，然後 用虱仿/甲醇對殘留物進行再結晶（recryStai 1 izati〇n)， 由此得到113. 〇g中間體化合物（al)。接著，將loo. 〇g化 合物（al)溶解於i〇〇〇mi四氫呋喃和5〇〇mi濃鹽酸的混合溶 液中’在室溫進行攪拌下，經1小時滴加38 4g亞硝酸第 57 322802 201142501 三丁酯。滴加結束後’在室溫攪拌5小時。將反應液注入 1600ml冰水中，用1600ml氯仿進行萃取。對有機層進行 水洗（500mlx3次），用硫酸鎂乾燥，然後過濾乾燥劑，顧 去溶劑’用正己院洗務殘留物’由此得到99. 8g前驅體化 合物（bl)。接著’在300ml乙酸乙酯中攪拌30· 〇g化合物 (bl) ’加入6· 3g乙酸野、1〇· 6g乙酸納，並加熱回流3小 時。然後，將反應液注入500ml冰水中，用乙酸乙酯萃取 組合物’對有機層進行水洗（3〇〇mlx3次），用硫酸鎂乾燥， 然後過濾乾燥劑，餾去溶劑，用乙酸乙酯-己烷對殘留物進 行再結晶’由此得到31. 4g光聚合引發劑（A1)。 光聚合引發劑（A1)The photopolymerization initiator (A) represented by the formula (11) contained in the photosensitive coloring composition of the present invention is an oxime ester photopolymerization initiator. It is generally considered that the oxime ester photopolymerization initiator partially decomposes the oxime ester by absorbing ultraviolet rays to form an imino radical and an alkoxy radical, and further decomposes the active species radical to cause a reaction, but The photopolymerization initiator (A) represented by the formula (11) contained in the photosensitive coloring composition of the invention, which is represented by the formula (11), is caused by ultraviolet irradiation. The decomposition efficiency is very high and the pattern can be formed with less exposure. The photopolymerization initiator (A) represented by the formula (11) of the present invention has higher sensitivity than the conventional initiator, and may be due to the following two reasons, but the details thereof are not clear. For the first reason, the photopolymerization initiator (A) represented by the formula (11) of the present invention has excellent ultraviolet absorption properties because of the structure represented by the formula (11), so that it can be absorbed extremely well. The energy of the energy line given. Further, it is considered that since the obtained energy is effectively used for the decomposition of the oxime ester site, it is rapidly decomposed by the irradiation of the energy ray, and a large amount of radicals can be generated instantaneously. The second reason is that the photopolymerization initiator (A) represented by the general formula (11) of the present invention is derived from the decomposition of an imido radical generated by ultraviolet ray absorption to an active species radical. The structure represented by the formula (11) is very rapid. If the generated imino radical is quasi-stable, the decomposition becomes slow, the amount of active radicals is reduced, and the chemical structure of the ultraviolet absorbing portion has a large influence. It is considered that the photopolymerization initiator (A) of the present invention has a structure represented by the formula (11), and the decomposition of the imine radical generated by the light irradiation is very rapid, resulting in a large amount of production. Free radicals. Further, as described above, the photopolymerization initiator (A) represented by the formula (11) of the present invention has a very rapid decomposition of the imino radical, and thus recombination thereof is suppressed. In the case where there is a lot of recombination, the active species produced by the decomposition of 35 322802 201142501 is reduced, and thus the function as a radical polymerization initiator is lowered. The photopolymerization initiator (A) containing the compound represented by the above formula (1) or (11) is considered to have a sensitivity and a patterning property, and is 10 parts by weight based on 10 parts by weight of the pigment (D) in the photosensitive coloring composition. It can be used in an amount of from 1 to 200 parts by weight, preferably from 1 to 150 parts by weight. <Other photopolymerization initiator (γ)&gt; In the photosensitive coloring composition of the present invention, when another photopolymerization initiator (Υ) is used together with the compound represented by the above formula (1) or (U), That is, it is possible to obtain more excellent chemical resistance, and therefore it is preferable. As another photopolymerization initiator (Υ), 4-phenoxybisacetophenone, 4-tert-butyldiacetophenone, diethoxyacetophenone, p-monomethylamine can be used. Acetophenone, 1-(4-isopropylphenyl)-2-yl-2-methylpropan-1-one, 1-hydroxycyclohexyl phenyl ketone, 2-mercapto 444-(sulfuric acid Base]~基]~2-吗惊·代基丙烧-1 - Stuffed j, 2-pyryl-2-didecylamino (4-morpholinophenyl)-butane-1 ketone An acetophenone compound such as 2-(dimethylamino)_2_[(4-methylphenyl)methyl]-l-[4-(4-morpholinyl)phenyl]-butanone; benzene Occasionally, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzil dimethyi ketal, etc. Benzophenone), benzoquinone St, benzoic acid methyl vinegar, 4-phenyl benzophenone, transbenzophenone, acrylated dibenzophenone, 4-benzylidene- 4 , _methyldiphenyl sulfide, 3, 3', 4, 4'-tetrakis(t-butylperoxycarbonyl)benzyl- and other benzophenone-based compounds; thioxanthone, 2-gas thioxanthene Ketone, 2 - methylthioxanthone, isopropylthioxanthone, 2,4-diisopropylthioxanthone, 2,4-diethylthioxanthone, etc., thioxantate 322802 36 201142501 ketone compound; 2, 4, 6-tris-s-trisyl, 2-phenyl-4,6-di(tris)-s-three-plow, 2-(p-methoxyphenyl)_4,6-di (three gases)曱基)_s_三11 well, 2-(p-tolyl)-4,6-di(trichloromethyl)-s-three tillage, 2-piperidin-4,6-di(trismethyl) -s-triterpene, 2, 4-di(trichloromethyl)-6-styryl-S-three tillage, 2-(naphthalen-1-yl)_4,6-di(trichloromethyl)- S_three tillage, 2-(4-decyloxy-naphthalen-1-yl)-4,6-di(trichloroindenyl)-s-three tillage, 2, 4-dione fluorenyl-piperonyl- 6-three tillage, 2, 4-trichloroindenyl (4,-methoxystyryl)-6-three tillage and other triterpenoid compounds; 1,2-octanedione, i-[4-(benzene Thio)phenyl-, 2-(0-alum)], 〇-(ethinyl tN-d-phenyl-2-oxo-oxo(oxo)-2-(4-methoxy- An anthracene ester compound such as naphthyl)ethylene)hydroxylamine; bis(2,4,6-trimercaptophenyl)phenylphosphine oxide, 2,4,6-trimethylphenylhydrazine -phosphine systems such as diphenyl-phosphine oxide Compound; 2, 2, _ a (o-lactylphenyl)-4, 5, 4', 5'-tetraphenyl-1,2'-linked miso, 2, 2'-di(o-decyloxy) Phenyl)-4,4',5,5'-tetraphenylbiimidazole, 2,2,-di(o-phenyl)-4,4,5,5'-tetra(p-methylphenyl)唾 唾 嗤 咪 唾 唾; 9 9 9; 9, 10-phenoquinone, camphorquinone, ethyl hydrazine and other lanthanide compounds; borate ester compounds, 吟β squat compounds, titanium (Utan〇cene) compounds Wait. Among them, it is more preferable to contain at least one or more photopolymerization initiators (Y) selected from the group consisting of acetophenone-based compounds, phosphine-based compounds, and imidazole-based compounds. These photopolymerization initiators may be used singly or in combination of two or more kinds at any ratio as needed. The other photopolymerization initiator (γ) may be in an amount of from 1 to 2q 〇 802 322 802 37 201142501 parts by weight, preferably from 1 to 150, per part by weight of the pigment (D) in the photosensitive coloring composition. The amount by weight is used. Further, it can be used in an amount of from 1 to 10 parts by weight based on 100 parts by weight of the photopolymerization initiator (A). In order to obtain a more favorable chemical property, the amount of the photopolymerization initiator (A) is preferably 5 parts by weight relative to 100 parts by weight. &lt;Sensitizer (E)&gt; Further, the photosensitive coloring composition of the present invention may further contain a sensitizer (8). The content of the sensitizer (8) can be used in an amount of 1 to 1 part by weight based on 1 part by weight of the photopolymerization initiator (A) in the photosensitive coloring composition. An unsaturated ketone represented by a chalcone (cha] _c〇ne) derivative and a dibenza lace tone, and a benzophenone and a camphor proton are represented, 1, 2 _ Diketone derivatives, benzoin derivatives, derivatives, naphthalene I, derivatives, anthracene derivatives, xanthene derivatives, thioxanthene derivatives, xanthone derivatives, thioxanthone (thioxanthone) derivatives, coumarin derivatives, coumarin derivatives, cyanine derivatives, melocyanine derivatives, oxonol derivatives, etc. ) Pigment, ° bite derivative,. a azine derivative, a thiazine derivative, an anthracene derivative, a sulphate derivative, a sulphate derivative, an azulenium derivative, a squarylium derivative, Deuterium derivative, tetraphenylporphyrin derivative, triarylmethane derivative, tetrabenzopyrene derivative, tetrapyrazinoporphyrazine derivative, phthalocyanine 38 322802 201142501 (phthalocyanine Derivatives, tetraazaporphyrazine derivatives, tetraterpene and tetraazaindene derivatives, naphthalene phthalocyanine derivatives, subphthalocyanine derivatives, pyrylium derivatives , thiola rust derivative, tetraphylline derivative, annulene derivative, spiropyran derivative, spiroxazine derivative, thiotropium ratio Ming derivatives, metal arene complexes, organic ruthenium complexes, Michler's ketone derivatives, and the like. Further, as a specific example of the above, the "Pigment Handbook" (1986, Kodansha), Dahe Yuanxin, etc., "Chemistry of Functional Pigments" (1981, CMC), and Chisen-Sang Sanlang, etc. The sensitizer described in "Special Functional Materials" (1986, CMC) is not limited thereto. Further, in addition to this, a sensitizer which exhibits absorption of light from the ultraviolet ray to the near-infrared region may be contained. In the above sensitizer (E), as a sensitizer which is particularly suitable for sensitizing the compounds represented by the general formulae (1) and (11), 4 is exemplified by a singly-derivative derivative and a ketoconazole. Derivatives, carbazole derivatives. More specifically, '2,4-diethylthioxanthone, 2-chlorothioxanthone, 2,4-dichlorothiazepine, 2-isopropylthioxanthone, 4-isopropyl group can be used. Thioxanthone, 1-chloro-4-propoxypyridone, 4,4'-bis(dimethylamino)benzophenone, 4,4'-di(diethylamino)diphenyl Anthrone, 4, 4'-bis(ethyldecylamino)benzophenone, anthracene-ethyl anthracene, 3-benzylidene-indole-ethyl anthracene, and 3,6-diphenyl Formamyl-oxime-ethylcarbazole and the like. For the sensitizer (Ε), it is also possible to contain two or more kinds of 39 322802 201142501 sensitizers in any ratio. &lt;Resin (B)&gt; The resin (B) contained in the photosensitive coloring composition of the present invention preferably has a transmittance of 80% or more in the entire wavelength region of 400 to 700 nm in the visible light region, more preferably More than 95% of the resin. The resin (b) includes a thermoplastic resin, a thermosetting resin, and a photosensitive resin, and these may be used singly or in combination of two or more. Examples of the thermoplastic resin include butyra 1 resin, styrene-maleic acid copolymer, vaporized polyethylene, chlorinated polypropylene, polystyrene, ethylene-vinyl acetate copolymer, and polycondensation. Acetyl acetate, polyurethane resin, polyester resin, acrylic resin, alkyd resin, polystyrene, polyamide resin, rubber resin, cyclized rubber resin, cellulose, polyethylene, Polybutadiene, polyimide resin, and the like. Further, examples of the thermosetting resin include an epoxy resin, a decylamine resin, a rosin-modified maleic acid resin, a rosin-modified fumaric acid resin, a melamine resin, a urea resin, a phenol resin, and the like. As the photosensitive resin, a (fluorenyl)acrylic compound having a reactive substituent such as an isocyanate group, an aldehyde group or an epoxy group, or a cinnamic acid and a linear substituent having a reactive substituent such as a hydroxyl group, a carboxyl group or an amine group can be used. A polymer obtained by introducing a photocrosslinkable group such as a fluorenyl group or a styryl group into the linear polymer. Further, a styrene-maleic anhydride copolymer, an olefin-maleic anhydride copolymer or the like may be used to contain 40 322802 201142501 acid by a (meth)acrylic compound having a hydroxyl group such as a hydroxyalkyl (meth)acrylate. A resin obtained by semi-esterifying a linear polymer of a needle. The resin (B) may be used in an amount of 20 to 400 parts by weight, preferably 5 to 25 parts by weight, based on the weight of the pigment (d) i (9) in the photosensitive coloring composition. <Photopolymerizable Compound (C)> The photopolymerizable compound (C) contained in the photosensitive coloring composition of the present invention is a photopolymerizable monomer or oligomer, and examples thereof include, for example, ruthenium acrylate. Ester, ethyl (meth) acrylate, 2-hydroxyethyl ethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, cyclohexyl acrylate (meth) acrylate, non-carboxy (meth) acrylate Ethyl ester, polyethylene glycol di(meth) acrylate, 丨6_ hexanediol di(decyl) acrylate diethylene glycol di(meth) acrylate, dipropylene glycol di(meth) acrylate, three Hydroxymethylpropane tri(meth)acrylate, pentaerythritol tris(decyl)acrylate, 丨'^hexanediol diglycidyl ether di(indenyl)acrylate, bisphenol A diglycidyl ether di(methyl) Acrylate, neopentyl glycol diglycidyl ether bis(indenyl) acrylate, dipentaerythritol hexakisyl acrylate, tricyclodecyl acrylate, acetoxy acrylate, methylolated melamine (meth) acrylate, epoxy (fluorenyl) propyl Various acrylates and mercaptoacrylates such as enoate esters and amine ester acrylates, (meth)acrylic acid, styrene, vinyl acetate, hydroxyethyl bufyl, ethylene glycol diethyl ether, Pentaerythritol trivinyl fluorene, (meth) acrylamide, N-methyl (mercapto) acrylamide, N-acetyl carbamide, acrylonitrile, and the like. These may be used alone or in combination of two or more. The photopolymerizable compound (C) may be 10 to 3 parts by weight, preferably 1 to 41 322802 201142501 to 200 parts by weight, based on the weight of the pigment (D) in the photosensitive coloring composition. The amount used. In the photosensitive I. raw coloring composition, the ratio [Ia/M] of the weight of the photopolymerization initiator (1) to the weight f [M] of the photopolymerizable compound (6) is preferably [Ia/M]. .〇3 to l.oo: and more preferably 〇 〇4 to 〇 95. When the sensitizing coloring composition of the progressive field contains the sensitizer (E) and other photopolymerization initiator 00, the total weight (6) of the photopolymerization initiator (1), the _(E) and the polymerization initiator (γ) and photopolymerization The ratio of the compound (6) 〇〇5:[:] [Ib/M], preferably 〇. 4 to 1.5. More preferably, it is Tian Wei. 03 or more, [WM] is 〇. When 04 or more, the sensitivity is high and the effect is good. In addition, when (10)] is 1.00 or less, [Ib/M] is 1. 5 (when Γ or less, the linearity and resolution of the pattern shape are more excellent. <Pigment (D)&gt;, as a photosensitive coloring combination of the present invention The pigment (D) contained in the product may be used singly or in combination of two or more kinds. It is preferably a pigment having high color rendering property and high heat resistance in the sheet material. Usually, an organic pigment can be used. Hereinafter, a specific example of an organic pigment which can be used in the photosensitive coloring composition of the present invention is indicated by a pigment index number (CI). In the red photosensitive coloring composition for forming a red filter section, for example, 'for example' CI Pigment Red 7, 9, 14, 41, 48 can be used: Bu 48 · 2, 48: 3, 48 · · 4, 81: 1, 81: 2, 81: 3, 97, 122, 123, 146, 149 , 168, 177, 178, 179, 180, 184, 185, 187, 192, 200, 202, 208, 210, 215, 216, 217, 220, 42 322802 201142501 223, 224, 226, 227, 228, 240, Red pigments such as 242, 246, 254, 255, 264, 272, 279 In the red photosensitive coloring composition, a yellow pigment or an orange pigment may be used in combination. As the yellow pigment which can be used in combination in the red photosensitive coloring composition, for example, CI pigment yellow 1, 2, 3, 4, 5 may be used. 6, 10, 12, 13, 14, 15, 16, 17, 18, 20, 24, 3, 32, 34, 35, 35: Bu 36, 36: Bu 37, 37: 1, 40, 42, 43 53, 55, 60, 6 Bu 62, 63, 65, 73, 74, 77, 8 Bu 83, 86, 93, 94, 95, 97, 98, 100, 1 (U, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 155, 156, 16 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 18, 182, 185, 187, 188, 193, 194, 199, 213, 214, etc. Further, in the yellow photosensitive coloring composition for forming a yellow wave filter section, these yellow pigments may be used singly or in combination of two or more. As the orange pigment which can be used in combination in the red photosensitive coloring composition, for example, an orange pigment such as C.I. pigments 36, 43, 51, 55, 59, 61, 71, 73 can be used. Further, in the orange photosensitive coloring composition for forming an orange filter or a waver section, these orange pigments may be used singly or in combination of two or more. 0 43 322802 201142501 Green sensitization for forming a green filter section As the coloring composition, for example, green pigments such as C·I·Pigment Green 7, 1, 36, 36, 37, and 58 can be used. In the green photosensitive coloring composition, the above yellow pigment may also be used in combination. In the blue photosensitive coloring composition for forming a blue filter, for example, C·I. Pigment Blue 15, 15: 1, 15: 2, 15: 3, 15: 4, 15 ·· 6, 16, 22, 60, 64, 80 and other blue pigments. In the blue photosensitive coloring composition, a purple pigment such as C.I. Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 42, 50 may be used in combination. In the cyan photosensitive coloring composition for forming a cyan filter section, for example, C·I. Pigment Blue 15: 1, 15: 2, 15: 3, 15: 4, 15: 6, 16,80 and other blue pigments. In the magenta photosensitive coloring composition for forming a magenta filter section, for example, 'a purple pigment such as C.I. Pigment Violet 1, 19, and C. I·Pigment Red 81, 144 may be used. Red pigments such as 146, 177, and 169. In the magenta photosensitive coloring composition, a yellow pigment may also be used in combination. In the black photosensitive coloring composition for forming a black matrix, for example, carbon black, nigrosine, lanthanum black pigment, lanthanide black pigment can be used. Specifically, CI pigment can be used. 6, 6, 12, 20, 31, etc. A mixture of a red pigment, a blue pigment, and a green pigment may also be used in the black photosensitive coloring composition. The ochre pigment is preferably carbon black from the viewpoint of the price and the degree of light opacity, and the carbon black may be surface-treated with a resin or the like. In addition, in order to adjust 322802 44 201142501 = color sense, it is also possible to use blue pigment. In addition, as inorganic pigment, lead bismuth sulfate, lead yellow, zinc yellow, iron oxide (iron oxide red ( ιι, sulfur sulfate blue) can be cited. , chrome oxide green, cobalt green, know, work, ultramarine, titanium oxide, iron oxide and other metal oxide powder, bismuth 'iron black, powder, etc. in order to obtain chroma and brightness metal powder, The metality, the sensitivity, the developability, and the like, and the use of the photosensitive material of the present invention in combination with the T-materials of the present invention are ensured, and the composition is contained in a range that does not lower the heat resistance. In addition, the color sensitivity of the present invention is large; (100% by weight), and the total I of the rand (D) component is considered to be a reference. In the above, the color is more than 20% by weight, more preferably 5% by weight, more preferably 5% by weight. From the viewpoint of the availability of the composition, the coloring is improved by 90% by weight or less, more preferably 80% by weight. Jiawei is less than %, and the best is 70 weight 0/min. <Polyfunctional thiol (F)&gt; The photosensitive coloring composition of the present invention may contain a polyfunctional alcohol (F) e polyfunctional thiol (F) which is a compound having two or more thiol (10) groups. The polyfunctional thiol (8) is used together with the above photopolymerization initiator (1) to function as a bond transfer during radical polymerization after light irradiation, and to generate a sulfur radical which is not easily inhibited by oxygen. 28〇2 201142501 radical) 'The sensitivity of the photosensitive coloring composition thus obtained becomes high. In particular, a polyfunctional fat in which an SH group is combined with a monthly aliphatic group such as a methylene group or an ethylene group is added. The group thiol is preferred. For example, hexanedithiol, decanedithiol, hydrazine, 4-butanediol dithiopropionate, 1,4-butanediol dithioglycolate, and ethylene may be mentioned. Alcohol disulfide; glycolic acid ester, ethylene glycol dithiopropionate, trishydroxypropyl propane trithioglycolic acid S曰, dimethylolpropane trithiopropionate, trimethylolethane酼 丁 酸 目 、 、 、 、 、 、 、 、 、 、 、 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Alcohol ester, quaternary tetraol tetrathiopropionic acid vinegar, pentaerythritol tetrakis (3_ thioglycolic acid vinegar), diquater ^ tetraol hexa(3,ylpropionate), trispopropionate (2_ via ethyl) = acid vinegar, U 4-dimethyl decyl benzene, 2, 4, 6_ triterpene triterpenoid, 2-(ν: dibutylamino)-4, 6-di Thirteen 哄 and so on. These polyfunctional thiols may be used singly or in combination of two or more. The content of the polyfunctional thiol (7) is preferably from 0.4 parts by weight to more than 100 parts by weight of the pigment (D), and more preferably from U to 50.0 parts by weight. The station recognizes that more than 5% by weight of the polyfunctional thiol is used. 'You can get two asexual. The use of a monofunctional sulfur having one thiol (SH) group does not provide such improvement in developability. <Ultraviolet absorber (6), polymerization inhibitor (8)> The photosensitive coloring composition of the second embodiment may contain ultraviolet rays (m 4 ). The shape and resolution of the pattern are contained by containing the ultraviolet absorber (6) or the polymerization. As the ultraviolet absorber °, for example, 2-[4-[(2~录_3_(13 recordings and thirteen burning edges 322802 46 201142501 oxypropyl)oxy]-2-ylamino]-4 , 6-bis(2,4-dimethylphenyl)-1,3,5-trianthene, 2-(2-hydroxy-4-[l-octyloxycarbonylethoxy]phenyl) _4, 6-bis(4-phenylphenyl)-1,3,5-trianthene and other hydroxyphenyl tri-D wells; 2-(5-methyl-2-superphenyl)benzotriazine 2-(2H-benzotrisin-2-yl)-4,6-mono(1-fluorenyl-1-benzylethyl)benzene, 2-(3-tert-butyl-5-fluorenyl) a benzotriazole system such as 2-hydroxyphenyl)-5-chlorobenzotriazole; 2,4-dihydroxydibenzophenone, 2-hydroxy-4-octyloxybenzophenone, 2, 2 , 4, 4,-tetrahydroxybenzophenone and other benzophenones; phenyl salicylate, p-tert-butylphenyl salicylate and other salicylate; ethyl-2- Cyanoacrylate such as cyano-3,3,-diphenylpropanate; 2, 2, 6, 6-tetradecylpiperidin-1-yl (triacetone-amine-N-oxyl ), bis(2, 2, 6, 6-tetramethyl-4-piperidinyl)-sebacate, poly[[6-[(1,1,3,3-tetrabutyl)amino] -1,3,5-tris-2,4-diyl][(2, 2, 6, 6- A tetramethyl-4-pyrene group, an imine group, or the like, a hindered amine system, etc., which may be used singly or in combination. Further, as the polymerization inhibitor, for example, mercaptohydroquinone or tributyl group may be mentioned. Hydroquinone, 2, 5_di-tert-butylhydrogen, hydroquinone such as 4-benzene, 4-decyloxybenzoquinone, 4-methoxy-1-naphthoquinone, and tert-butylcatechol Derivatives and phenolic compounds; phenothiazine, bis(1-dimethylbenzyl) phenhydrazide, 3,7-dioctylmorphine, etc.; dibutyldithiocarbamic acid Copper and manganese salt compounds such as copper, diethyldithiocarbamate copper citrate, manganese diethyldithiocarbamate, manganese diphenyldithiocarbamate, etc.; 4-nitrosophenol a nitroso compound such as N_ succinyl diphenylamine, N-nitrosocyclohexyltransamine, N-nitrosophenylhydroxylamine, or an ammonium salt or an aluminum salt thereof, which may be used alone or 01至20重量份,优选优选为0. 05至10重量。 The weight of the pigment (D) 100 parts by weight of the pigment in the coloring composition may be from 0.01 to 20 parts by weight, and preferably from 0.05 to 10 weight Amount of By using 0.01 parts by weight or more of the ultraviolet absorber or the polymerization inhibitor, a better resolution can be obtained. <Storage Stabilizer (J)&gt; The photosensitive coloring composition of the present invention may contain Storage Stabilizer (J) By containing a storage stabilizer (J), the viscosity of the composition can be stabilized over time. As the storage stabilizer, for example, 2,6-di(1,1-didecylethyl)-4-nonylphenol, pentaerythritol tetrakis[3-(3, 5-di-tert-butyl-4) -hydroxyphenyl)propionate], 2,4-di(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino) 1,3,5-triazine Occasionally blocked; organic phosphines such as tetraethylphosphine, triphenylphosphine, tetraphenylphosphine; zinc dimethyl dithiophosphate, zinc dipropyl dithiophosphate, molybdenum dibutyl dithiophosphate a phosphite system; a sulfuric acid such as lauryl sulfide or benzothiophene; a quaternary ammonium vapor such as benzyltrimethyl chloride or diethylhydroxylamine; an organic acid such as lactic acid or oxalic acid; Ether, etc., these may be used singly or in combination. The storage stabilizer is used in an amount of from 0.01 to 20 parts by weight, preferably from 0.05 to 10 parts by weight, based on 100 parts by weight of the pigment (D) in the coloring composition. By using a storage stabilizer of 0.01 parts by weight or more, the temporal stability of the photosensitive coloring composition can be improved. <Solvent> In order to allow the pigment (D) to be easily dispersed in the resin (B) or the light 48 322802 201142501, the polymerizable compound (c), etc., is applied to a transparent substrate such as a glass substrate to a dry thickness.滤波器· 2 i lGem, a filter segment and a black matrix are formed, and the photosensitive coloring composition of the present invention may contain a solvent. As the solvent, for example, i, 2, 3-trichloropropane, hydrazine, 3-butane monool, 1' 3-butanediol, 1,3-butanediol diacetate, hydrazine, 4_ may be mentioned. Dioxane, 2-heptanone, 2-methyl-1,3-propanediol, 3, 5, 5-trimethyl-2-cyclohexene 1 ketone, 3, 3, 5-dimethyl ring Hexanone, ethyl 3-ethoxypropionate, 3-methyl-1,3-butanediol, 3-methoxy-3-methylbutanol, 3-methoxy-3-methylbutene Acetic acid vinegar, 3-methoxybutanol, 3-methoxybutyl acetate vinegar, 4-heptanone, m-xylene, m-diethylbenzene, m-benzene, N,N-dimethyl B Indoleamine, N'N-dimercaptodecylamine, n-butanol, n-butylbenzene, n-propyl acetate, N-methylindole, o-xylene, o-chloropyrene, o-di Ethylbenzene, o-diphenyl, p-benzoquinone, p-diethylbenzene, t-butylbenzene, tert-butylbenzene, r-butyrolactone, isobutanol, isophorone, ethylene glycol Diethyl ether, ethylene glycol dibutyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monoethyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol mono-tert-butyl ether Ethylene glycol monobutyl hydrazine, ethylene glycol single Based on acetic acid s, ethylene glycol monopropyl mystery, ethylene glycol monohexyl hydrazine, ethylene glycol monomethyl sulfonate, ethylene glycol monomethyl squarate acetate, diisobutyl _, diethylene glycol Diethyl sulfonate, diethylene glycol dimethyl mystery, diethylene glycol monoisopropyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl hydrazine, diethylene glycol single Ding vinegar acetate, diethylene glycol monomethyl ether, cyclohexanol, cyclohexanol acetate vinegar, cyclohexyl, dipropylene glycol dimethyl fine, dipropylene glycol methyl ether acetate, dipropylene glycol monoethyl ether , dipropylene glycol monobutyl ether, dipropylene glycol monopropyl sulphate, dipropylene glycol monomethyl squaring, 322802 49 201142501 alcohol, glycerol triacetate g (tri ace tin), tripropylene glycol monobutyl mystery, tripropylene glycol monodecyl Ether, propylene glycol diacetate, propylene glycol phenyl ether, propylene glycol monoethyl ether, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether, propylene glycol monopropyl ether, propylene glycol monodecyl ether, propylene glycol monodecyl Ether acetate, propylene glycol monomethyl ether propionate, benzyl alcohol, mercaptoisobutyl ketone, nonylcyclohexanol, n-amyl acetate, N-butyl acetate, isoamyl acetate, isobutyl acetate, propyl acetate, dibasic esters and the like, these may be used alone or in combination. The solvent may be used in an amount of from 100 to 10,000 parts by weight, and preferably from 500 to 5,000 parts by weight, based on 100 parts by weight of the pigment (D) in the coloring composition. <Other components> In the photosensitive coloring composition of the present invention, an adhesion improving agent such as a decane coupling agent may be contained in order to improve the adhesion to the transparent substrate. Examples of the decane coupling agent include vinyl tris(/5-methoxyethoxy) carbene, ethylene ethoxy pulverization, and vinyl decyl oxide such as ethylene trioxalate. Classes; mercapto propylene methoxy propyl tridecyloxy decane, etc. (fluorenyl) acrylic decanes; /5-(3, 4-epoxycyclohexyl)ethyltrimethoxy decane, β-( 3, 4-Epoxycyclohexyl)decyltrimethoxy decane, s-(3,4-epoxycyclohexyl)ethyltriethoxydecane, -(3,4-epoxycyclohexyl) Ethyl decanes such as mercaptotriethoxy decane, T-glycidoxypropyltrimethoxy decane, T-glycidoxypropyltriethoxydecane; Ν-; 5 ( Aminoethyl)r-aminopropyltrimethoxydecane, N-/3 (aminoethyl) 7-aminopropyltriethoxymethane, N-yS (aminoethyl) 7 _ Aminopropylmethyldiethoxydecane, T-Aminopropyltriethoxydecane, 50 322802 201142501 r-Aminopropyltrimethoxydecane, N-phenyl-7-aminopropyltrimethyl Amino decane such as oxydecane or N-phenyl-r-aminopropyltriethoxydecane; Weiylpropyl Dimethoxy zebra, 7-sodium propyl triethoxy sulfonate, etc. The decane coupling agent is used in an amount of from 0.01 to 10 parts by weight, preferably from 0.05 to 5 parts by weight, based on 100 parts by weight of the pigment (D) in the coloring composition. Further, the photosensitive coloring composition of the present invention may contain an amine compound having an action of reducing dissolved oxygen. Examples of such an amine-based compound include triethanolamine, mercaptodiethanolamine, triisopropanolamine, 4-didecylaminobenzoic acid decyl ester, 4-didecylaminobenzoic acid ethyl ester, and 4- Isoamyl dimethylaminobenzoate, 2-dimethylaminoethyl benzoate, 2-ethylhexyl 4-dimethylaminobenzoate, N,N-dimercaptononanilide Wait. <Method for Producing Photosensitive Coloring Composition> The photosensitive coloring composition of the present invention can be produced by the following method. The pigment (D) is finely dispersed in the resin (B) using a three-stage triple roll mill, a double-arm mill, a sand mill, a kneader, an attritor, and the like. a pigment dispersion is prepared in a pigment carrier and/or a solvent, and then the photopolymerization initiator (A), the resin (B), and the photopolymerizable compound (C) are mixed in the pigment dispersion, and other additives are added as the case may be. Photopolymerization initiator (Y), sensitizer (E), polyfunctional thiol (F), ultraviolet absorber (G), polymerization inhibitor (H), storage stabilizer (J), solvent and other components, and By mixing, a photosensitive coloring composition can be manufactured. 51 322802 201142501 Further, a photosensitive coloring composition containing two or more kinds of pigments can be mixed by separately dispersing each pigment in a pigment carrier and/or a solvent to form a respective pigment dispersion. The photopolymerization initiator (A), the photopolymerizable compound (6), and the like are mixed and produced by riding. When the pigment is dispersed in the resin (B) and/or the solvent, a dispersing aid/dispersing aid such as a resin type pigment dispersing agent, a surfactant, or a pigment derivative may be appropriately contained to make the dispersion of the pigment excellent, and Since the effect of preventing the pigment after dispersing from re-agglomeration is good, when a photosensitive coloring composition formed by dispersing a pigment blade in a resin (B) and/or a solvent by a dispersing aid is used, a filter excellent in transparency can be obtained. Color. The sizing agent is used in an amount of from 0.1 to 30 parts by weight, preferably from 0.1 to 30 parts by weight, per 100 parts by weight of the pigment (D). The tree-and-fat pigment dispersant includes a pigment affinity site having a property of adsorbing to a pigment, and a site compatible with a pigment carrier, and exhibits a pigment to disperse the pigment in the pigment carrier. The substance of action. As the resin type pigment dispersant, specifically, a polyamine S can be used, such as a polyamine S, an unsaturated polyamine, a poly-polyamide, an ammonium salt, a polycarboxylate, or a polycarboxylate. Acid alkylamine salt, polyoxo-fired long-chain poly-salt-branched amine carbonate, warp-containing poly-retensive vinegar, modified by these, by poly(lower alkylene) and free An oily dispersant such as guanamine or a salt thereof formed by the reaction of the ruthenium (IV), (meth) propylene II ethylene copolymer, (meth) acrylic acid _ (meth) acrylic acid vinegar copolymer B Rare · Maleic acid copolymer, polyvinyl alcohol, polyethylene, slightly bite, the same water-soluble tree, 13⁄4 water-soluble polymer compound, poly (tetra), modified polypropylene 52 322802 201142501 olefinic acid ester, epoxy ethylene burning (ethylene Oxide) / propylene oxide addition compound, acid ester system, and the like. These may be used singly or in combination of two or more. As a commercially available resin-type dispersing agent, Disperbyk-101, 103, 107, 108, 110, 1U, 116, 130, 140, 154, 16 162 manufactured by BYK-Chemie Japan Co., Ltd. , 163, 164, 165, 166, 170, 171, 174, 180, 181, 182, 183, 184, 185, 190, 2000, 2001, 2020, 2025, 2050, 2070, 2095, 2150, 2155, or Anti- Terra-U, 203, 204, or BYK-P104, P104S, 220S, 6919, or Lactimon, Lactimon_WS or Bykumen, etc., SOLSPERSE-3000, 9000, 13000, 13240, 13650, manufactured by Japan Lubrizol. 13940, 16000, 17000, 18000, 20000, 21000, 24000, 26000, 27000, 28000, 31845, 32000, 32500, 32550, 33500, 32600, 34750, 35100, 36600, 38500, 41000, 41090, 53095, 55000, 76500, etc. EFKA-46, 47, 48, 452, 4008, 4009, 4010, 4015, 4020, 4047, 4050, 4055, 4060, 4080, 4400, 44 (U, 4402, 4403) manufactured by Ciba Japan Co., Ltd. , 4406, 4408, 4300, 4310, 4320, 4330, 4340, 450, 45, 45 3, 4540, 4550, 4560, 4800, 5010, 5065, 5066, 5070, 7500, 7554, 11 (H, 120, 150, 1501, 1502, 1503, etc., Ajinomoto Fine-Techno) Adisper PA1U, PB71, PB82, PB822, PB824, etc. As the surfactant, polyoxyethylene alkyl ether 53 322802 201142501 (polyoxyethylene alkyl ether) sulfate, sodium dodecylbenzenesulfonate, styrene - Alkali salt of acrylic copolymer, sodium alkylnaphthalene sulfonate, sodium alkyl diphenyl ether disulfonate, monoethanolamine lauryl sulfate, triethanol feta lauryl sulfate, lauryl sulfate, and dry and dry U-receiving, anti-lipid absorption, sodium-based sodium sulphate, styrene-acrylic acid copolymer monoethanolamine, polyoxyethylene-based ether phosphate and other anionic surfactants; polyoxyethylene oleyl ether, shadow Oxygen ethoxylate laurel base, polyoxyethylene decyl phenyl sulfonate, polyoxyethylene alkyl phthalate phosphate Sa, polyoxyethylene sorbitol liver monostearate, polyethylene glycol monolaurate (IV) Ionic surfactant; silk reading (4) and these oxygen-containing ethane additions Other cationic surfactants; Alkyl dimethyl aminoethyl group sour food burned mortem inspection beet, burning taste yl saliva Lin et amphoteric surfactants, these may be used alone or in combination of two or more. The pigment touch is a compound obtained by introducing a substituent into an organic pigment, and the organic ray also contains a pale yellow aryl (tetra) polycyclic compound such as a lean system which is not generally referred to as (d). As a pigment street creature, - Zha 63'3G5m, Japan's special public show, 5,620, and Japan's special public, 59_4 (), 172, and No. 2, Japan's special fair, 5-9, etc. These may be used singly or in combination of two or more kinds of the photosensitive coloring compositions of the present invention, and may be used in the form of a development-type colored resist material: a smear type or an alkali material, which is a pigment (D) dispersed. In the presence of alkali · ° °. Resin material Compound (6), photonic material, photopolymerizable material. The 322802 54 201142501 photosensitive coloring composition obtained by combining the composition of the initiator and the solvent is preferably a centrifugal separation, a sintered filter, or a service section, and the coarse particles above the towel are removed. It is preferable to remove coarse particles of l/zm or more, and it is more preferable to remove coarse particles of G 5#m or more and dust mixed therein. <Color filter> The color filter of the present invention will be described. A color filter of the present invention has a filter section and/or a black matrix formed of the photosensitive coloring composition of the present invention on a transparent substrate, and a general color filter has at least one red filter section and at least one green color. The filter section and the at least one blue filter section have either at least one magenta filter section, at least one cyan filter section, and at least one yellow filter section. As the transparent substrate, a glass plate such as soda lime glass, low-borite sorbic acid glass, or alkali-free aluminum boron borosilicate glass, or polycarbonate, polymethyl methacrylate or polyethylene terephthalate can be used. Wait for the resin board. Further, in order to drive the panelized liquid crystal, a transparent electrode made of indium oxide, tin oxide or the like may be formed on the surface of the glass plate or the resin plate. The dry film thickness of the filter section and the black matrix is preferably from 2 to 10//in, and more preferably from 0.2 to 5//in. When drying the coating film, a vacuum dryer, a convection oven, an IR oven, a hot plate, or the like can be used. The formation of the respective color waver segments and the black matrix by photolithography was carried out in the following manner. That is, a photosensitive coloring composition prepared by a coating method such as spray coating, spin coating, coating, or roll coating is applied onto a transparent substrate as a solvent-based or development-developing colored anti-(4) material. The film thickness is (^. For the drying of 322802 55 201142501 as needed, UV exposure is performed by a mask having a predetermined pattern set in contact or non-contact with the film. Then, It is impregnated in a solvent or an alkali developing solution, or a developing solution is sprayed by a sprayer or the like to remove an uncured portion to form a desired pattern, thereby forming a filter segment and a black matrix. Further, in order to promote the use of The filter section and the black matrix of the genus ~ are formed (4). By photolithography, (10) can be made into a precision filter and a black matrix. In the development, 'use sodium carbonate, sodium hydroxide An aqueous solution such as an aqueous solution can also be used as an organic test such as dimethyl benzylamine or triethanolamine. Further, an antifoaming agent or a surfactant can be added to the developer. It can be applied to spray development method, spray development method, dipping development method, stirring (paddle) development method, etc. In addition, in order to improve the ultraviolet exposure sensitivity, it is also possible to apply and dry the above-mentioned photosensitive light. After the coloring composition, a water-soluble or alkali-soluble resin such as polyvinyl alcohol or a water-soluble acrylic resin is applied and dried to form a film that prevents polymerization due to oxygen, and then exposed to ultraviolet light. The present invention is specifically described, but the present invention is not limited to the following examples unless otherwise stated. In the examples and comparative examples, "parts" means "parts by weight". In addition, the molecular weight of the resin in the acrylic resin solution is HLC-8220GPC (manufactured by Tosoh Corporation), and two TSK-GEL SUPER ΗΖΜ-Ν are connected as a column, and used. Liver 322802 56 201142501 Polystyrene-equivalent weight average molecular weight measured as a solvent First, "the whole 3 has a photopolymerization initiation represented by the general formula (1) The photosensitive coloring composition of (A) used the rhyme color thereof and evaluated various characteristics (Examples 1 to 24 and Comparative Examples 1 and 2). The adjustment of the photosensitive coloring composition was carried out by separately synthesizing/manufacturing In the synthesis of the photopolymerization initiator (A), the photopolymerization initiator (A), the photopolymerization agent (A), the (tetra) acid pure fat solution, and the pigment dispersion are mixed and the like. First, an intermediate compound is synthesized, and then a precursor compound is synthesized from the intermediate compound, and then the photopolymerization initiator is synthesized from the oxime compound. Elemental analysis (C, Η, N) is performed on the obtained compound (Perkin The mass analysis was performed by EI-MS (p〇iarisQ manufactured by Thermo Co., Ltd.) by PerkinElmer Co., Ltd., and the respective structures were confirmed. <Method for Producing Photopolymerization Initiator (A) Represented by General Formula (1)&gt; [Synthesis of Photopolymerization Initiator (A1)] Dissolve 100. Og N-benzophenone carbazole in 1 〇〇 In 〇ml chloroform, an additional 85·Og of vaporized aluminum was added, and under stirring, a solution of 32. Og of glycerin was dissolved in 5 〇〇ml of air-formed solution was added dropwise over 2 hours. After the completion of the dropwise addition, the mixture was stirred at 25 ° C for 4 hours. The reaction solution was poured into 2 g of ice water and extracted with 2000 ml of chloroform. The organic layer was dried over magnesium sulfate, and the residue was filtered, and then the residue was recrystallized (recryStai 1 izati〇n) to give 113. 〇g intermediate compound (al). Next, the loo. 〇g compound (al) was dissolved in a mixed solution of i〇〇〇mi tetrahydrofuran and 5 〇〇mi concentrated hydrochloric acid. Under stirring at room temperature, 38 4 g of nitrous acid was added dropwise over 1 hour. 201142501 Tributyl ester. After the completion of the dropwise addition, the mixture was stirred at room temperature for 5 hours. The reaction solution was poured into 1600 ml of ice water, and extracted with 1600 ml of chloroform. The organic layer was washed with water (500 ml x 3 times), dried over magnesium sulfate, and then filtered to remove the solvent. Then, 30 g of the compound (bl) was stirred in 300 ml of ethyl acetate to add 6.3 g of acetic acid, 1 g·6 g of sodium acetate, and heated under reflux for 3 hours. Then, the reaction liquid was poured into 500 ml of ice water, and the composition was extracted with ethyl acetate. The organic layer was washed with water (3 〇〇 ml x 3 times), dried over magnesium sulfate, and then filtered, and the solvent was evaporated. The photopolymerization initiator (A1) was obtained by the recrystallization of the residue by hexane. Photopolymerization initiator (A1)

[光聚合引發劑（A2)的合成] 將lOO.Og N-二笨曱酮基咔唑溶解在1〇〇〇ml氣仿中， 已氣化1呂，在〇°C進行授摔下，經2小時滴加 在25。 g，丁醯氣溶於500ml氣仿的溶液。滴加結束後， C攪拌4小時。將反應液倒入2000g冰水中，用2〇〇〇ml 仃萃取。用硫顏乾燥有機層，職乾燥劑，然後 /甲醇對殘留物進行再結晶，由此得到1〇9 3g中間 322802 58 201142501 體化合物（a2)。接著，將100. 化合物（a2)溶解於1000ml 四氫呋喃和500ml濃鹽酸的混合溶液中，在室溫進行攪拌 下，經1小時滴加43. lg亞硝酸第三丁酯。滴加結束後， 在室溫攪拌5小時。將反應液注入16〇〇ml冰水中，用1600ml 氯仿進行萃取。對有機層進行水洗（500mlx3次），用硫酸 鎂乾燥，然後過濾乾燥劑，餾去溶劑，用正己烷洗滌殘留 物，由此得到89. 3g前驅體化合物（b2)。接著，在300ml 乙酸乙酯中攪拌30. 0g化合物（b2)，加入6· lg乙酸酐、 10. 3g乙酸鈉，並加熱回流3小時》然後，將反應液注入 500ml冰水中，用乙酸乙酯萃取組合物，對有機層進行水 洗（300ml x3次），並用硫酸錢乾燥，然後過遽乾燥劑，館 去溶劑，用乙酸乙酯-己烷對殘留物進行再結晶，由此得到 30. 0g光聚合引發劑（A2)。 光聚合引發劑（A2)[Synthesis of Photopolymerization Initiator (A2)] Dissolve 100.Og N-dipodone carbazole in 1 〇〇〇ml of gas, which has been vaporized by 1 liter and dropped at 〇 °C. Add dropwise at 25 over 2 hours. g, Dingqi gas is dissolved in 500 ml of the simulated solution. After the completion of the dropwise addition, C was stirred for 4 hours. The reaction solution was poured into 2000 g of ice water and extracted with 2 ml of hydrazine. The organic layer was dried with sulfur, and the residue was recrystallized from methanol to give 1 〇 9 3 g of intermediate 322802 58 201142501 compound (a2). Next, 100% of the compound (a2) was dissolved in a mixed solution of 1000 ml of tetrahydrofuran and 500 ml of concentrated hydrochloric acid, and while stirring at room temperature, 43. lg of butyl nitrite was added dropwise over 1 hour. After the completion of the dropwise addition, the mixture was stirred at room temperature for 5 hours. The reaction solution was poured into 16 ml of ice water and extracted with 1600 ml of chloroform. The organic layer was washed with water (500 ml x 3 times), dried with magnesium sulfate, and then filtered, and the solvent was evaporated, and the residue was washed with n-hexane to obtain 89. 3 g of the precursor compound (b2). Next, 30. 0 g of the compound (b2) was stirred in 300 ml of ethyl acetate, 6·g of acetic anhydride, 10.3 g of sodium acetate was added, and the mixture was heated under reflux for 3 hours. Then, the reaction solution was poured into 500 ml of ice water with ethyl acetate. 0克。 The extract is obtained, the organic layer is washed with water (300ml x 3 times), and dried with sulphuric acid, then the drying agent, the solvent is removed, and the residue is recrystallized with ethyl acetate-hexane, thereby obtaining 30. 0g Photopolymerization initiator (A2). Photopolymerization initiator (A2)

o&quot;^ch3o&quot;^ch3

NN

IIII

[光聚合引發劑（A3)的合成] 將lOO.OgN-(對确基苯基）咔唑溶解在1〇〇〇mi氯仿 中，再添加101. 8g氮化紹，在（TC進行攪拌下，經2小時 滴加已將44· 3g 丁醯氯溶於500ml氣仿的溶液。滴加結束 322802 59 201142501 後在25 C搜掉4小時。將反應液倒入2000g冰水中，用 20_氣仿進行萃取。用硫酸鎮乾燥有機層，過滤乾燥劑， 然後用氣仿7曱醇對殘留物進行再結晶，由此得到113.6g 中門體化δ物（剛。接著，將100. Og化合物（a3)溶解於 1000ml 四氫咭。土 ：曲 m k . .. .. 1000ml四氫呋喃和5〇〇ml濃鹽酸的混合溶液中，在室溫進 行攪拌下，經1小時滴加43· lg亞硝酸第三丁酯。滴加結 束後’在室溫攪拌5小時。將反應液注入16〇〇ml冰水中， 用1500ml氣仿進行萃取。對有機層進行水洗（5〇〇mlx3 次）’並用硫酸鎂乾燥，然後過滤乾燥劑，傲去溶劑，用正 己烷洗滌殘留物，由此得到107· 2g前驅體化合物（b3)。接 者’在500ml乙酸乙g旨中擾捧50. 0g化合物（b3)，加入19. 9g 乙酸酐、11. 7g乙酸鈉，並加熱回流3小時。然後，將反 應液注入500ml冰水中’用乙酸乙酯萃取組合物，對有機 層進行水洗（500mlx3次），並用硫酸鎂乾燥，然後過遽乾 燥劑，餾去溶劑，用乙酸乙酯-己烷對殘留物進行再結晶， 由此得到57. 6g光聚合引發劑（A3)。 光聚合引發劑（A3)[Synthesis of photopolymerization initiator (A3)] Dissolve 100. OgN-(p-decylphenyl)carbazole in 1 〇〇〇mi chloroform, and then add 101. 8 g of nitridinium under stirring After 2 hours, add 44.3 g of butyl chloroform dissolved in 500 ml of the simulated solution. After the end of 322802 59 201142501, the mixture was searched for 4 hours at 25 C. The reaction solution was poured into 2000 g of ice water with 20 qi. The mixture was subjected to extraction, and the organic layer was dried with sulphuric acid, and the residue was filtered, and then the residue was recrystallized with a gas-like 7 decyl alcohol, thereby obtaining 113.6 g of a smectified δ substance (just. Next, 100. Og of the compound) (a3) Dissolved in 1000 ml of tetrahydroanthracene. Soil: 曲mk . . . . 1000ml of tetrahydrofuran and 5〇〇ml of concentrated hydrochloric acid in a mixed solution, stirring at room temperature, adding 43·lg nitrous acid over 1 hour The third butyl ester was stirred at room temperature for 5 hours. The reaction solution was poured into 16 ml of ice water and extracted with 1500 ml of air. The organic layer was washed with water (5 〇〇 ml x 3 times) and sulfuric acid was used. The magnesium is dried, then the desiccant is filtered, the solvent is arrogant, and the residue is washed with n-hexane, thereby obtaining 107·2 g before The compound (b3). The carrier was irritated in 500 ml of ethyl acetate to 50. 0 g of the compound (b3), and 19.9 g of acetic anhydride, 11.7 g of sodium acetate was added, and the mixture was heated under reflux for 3 hours. Into 500 ml of ice water, the composition was extracted with ethyl acetate, and the organic layer was washed with water (500 ml×3 times) and dried over magnesium sulfate, and then the solvent was evaporated, and the solvent was evaporated. Crystallization, thereby obtaining 57.6 g of a photopolymerization initiator (A3). Photopolymerization initiator (A3)

Ο [光聚合引發劑U4)的合成] 將100.OgN-二苯甲酮基-1,3-二曱基-咔唑溶解在 60 322802 201142501 1000ml氯仿中，再添加78. 6g氯化鋁，在0°C進行攪拌下， 經2小時滴加已將29. 6g丙醯氯溶於500ml氯仿的溶液。 滴加結束後，在25°C攪拌4小時。將反應液倒入2000g冰 水中，用2000ml氯仿進行萃取。用硫酸鎂乾燥有機層，過 濾乾燥劑，然後用氯仿/曱醇對殘留物進行再結晶，由此得 到111. 8g中間體化合物（a4)。接著，將100. 0g化合物（a4) 溶解於1000ml四氫呋喃和500ml濃鹽酸的混合溶液中，在 室溫進行攪拌下，經1小時滴加35. 7g亞硝酸第三丁酯。 滴加結束後，在室溫擾拌5小時。將反應液注入1600ml冰 水中，用1600ml氯仿進行萃取。對有機層進行水洗 (500mlx3次），並用硫酸鎂乾燥，然後過濾乾燥劑，餾去 溶劑，用正己烷洗滌殘留物，由此得到98. 3g前驅體化合 物（b4)。接著，在300ml乙酸乙酯中攪拌30. 0g化合物 (b4)，加入5. 9g乙酸酐、10. 0g乙酸納，並加熱回流3小 時。然後，將反應液注入500ml冰水中，用乙酸乙酯萃取 組合物，對有機層進行水洗（300mlx3次），並用硫酸鎂乾 燥，然後過濾乾燥劑，餾去溶劑，用乙酸乙酯-己烷對殘留 物進行再結晶，由此得到31. 2g光聚合引發劑（A4)。 光聚合引發劑（A4) 61 322802 201142501。 [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ A solution of 29.6 g of acetonitrile in 500 ml of chloroform was added dropwise over 2 hours while stirring at 0 °C. After the completion of the dropwise addition, the mixture was stirred at 25 ° C for 4 hours. The reaction solution was poured into 2000 g of ice water and extracted with 2000 ml of chloroform. The organic compound was dried over magnesium sulfate, and the residue was purified by chromatography. The butyl nitrite was added dropwise, and the mixture was stirred at room temperature for 3 hours, and 35. 7 g of tributyl nitrite was added dropwise. After the completion of the dropwise addition, the mixture was stirred at room temperature for 5 hours. The reaction solution was poured into 1600 ml of ice water and extracted with 1600 ml of chloroform. The organic layer was washed with water (500 ml x 3 times), and dried over magnesium sulfate, and then filtered, and the solvent was evaporated, and the residue was washed with n-hexane to give 98.3 g of the precursor compound (b4). Next, 30. 0 g of the compound (b4) was stirred in 300 ml of ethyl acetate, and 5. 9 g of acetic anhydride, 1.0 g of sodium acetate was added, and the mixture was heated under reflux for 3 hours. Then, the reaction liquid was poured into 500 ml of ice water, and the composition was extracted with ethyl acetate, and the organic layer was washed with water (300 ml×3 times), and dried over magnesium sulfate, and then filtered, and the solvent was evaporated to ethyl acetate-hexane. The residue was subjected to recrystallization to obtain 31. 2 g of a photopolymerization initiator (A4). Photopolymerization initiator (A4) 61 322802 201142501

〈丙烯酸系樹脂溶液的製造方法〉 [丙稀酸系樹脂溶液的調製] 在反應谷器中加入370份環己嗣，並一邊向容器中注 入氮氣一邊加熱至80°C，在該溫度下經1小時滴加2〇.〇 份曱基丙烯酸、10. 0份曱基丙烯酸曱酯、55· 〇份甲基丙烯 1正丁S曰、15. 0伤甲基丙稀酸2-經基乙醋、和〇份2，2，·~ 偶氮二異丁腈的混合物，進行聚合反應。滴加結束後，再 在80°C下反應3小時，然後添加已將1〇份偶氮二異丁腈 溶於50份環己酮中的溶液，並進一步在8〇ΐ下持續反應ι 小時’得到丙稀酸系樹脂溶液。 冷卻至室溫後’取樣約2g的丙稀酸系樹脂溶液，在 180°C下加熱乾燥20分鐘，測定不揮發成分，並據此在上 述合成的丙烯酸系樹脂溶液中添加環己鲷，使其不揮發成 分為20重量％。所得的丙烯酸系樹脂的重均分子量 40000。 &lt;顏料分散體的製造方法〉 [紅色顏料分散體的調製] 將下述組成的混合合均勻後，使用直徑為_ 322802 62 201142501 的氧化锆珠，並藉由EIGER研磨機（EIGER日本公司製“迷 你型M-250 MKIΓ )分散5小時，然後用5 m的過渡器過 濾，製作紅色顏料分散體P-R。 •二酮基吡咯并吡咯系顏料（C. I.顏料紅254) 6. 82份 (汽巴日本公司製“IRGAPHOR RED B-CF”） •蒽醌系顏料（C. I.顏料紅177) 1.08份 (汽巴日本公司製“CR0M0PHTAL RED A2B”） •鎳偶氮錯合物系顏料（C. I.顏料黃150) (朗盛（LANXESS)公司製 “E4GN”） 0. 88 份 •樹脂型顏料分散劑 (日本路博潤公司製“S0LSPERSE 20000”） 1.74份 •二酮基吡咯并吡咯系顏料衍生物 2. 05份<Method for Producing Acrylic Resin Solution> [Preparation of Acrylic Resin Solution] 370 parts of cyclohexane was placed in a reaction bar, and heated to 80 ° C while injecting nitrogen into the container, at which temperature 1 滴 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 A mixture of vinegar and bismuth 2,2,·~ azobisisobutyronitrile is subjected to polymerization. After the completion of the dropwise addition, the reaction was further carried out at 80 ° C for 3 hours, and then a solution in which 1 part of azobisisobutyronitrile was dissolved in 50 parts of cyclohexanone was added, and the reaction was further continued at 8 Torr for 1 hour. Acrylic resin solution. After cooling to room temperature, a sample of about 2 g of the acrylic resin solution was sampled, and dried by heating at 180 ° C for 20 minutes, and the nonvolatile matter was measured, and cyclohexanone was added to the above-mentioned synthetic acrylic resin solution. Its nonvolatile content is 20% by weight. The obtained acrylic resin had a weight average molecular weight of 40000. &lt;Manufacturing Method of Pigment Dispersion>> [Preparation of Red Pigment Dispersion] After mixing and mixing the following compositions, zirconia beads having a diameter of _322802 62 201142501 were used, and an EIGER mill (manufactured by EIGER Japan Co., Ltd.) “Mini M-250 MKIΓ” was dispersed for 5 hours and then filtered with a 5 m transition to produce a red pigment dispersion PR. • Diketopyrrolopyrrole pigment (CI Pigment Red 254) 6. 82 parts (Ciba "IRGAPHOR RED B-CF" made by the Japanese company) • 蒽醌-based pigment (CI Pigment Red 177) 1.08 parts ("C0M0PHTAL RED A2B" made by Ciba Japan)) Nickel azo complex pigment (CI Pigment Yellow 150 ("E4GN" manufactured by LANXESS) 0. 88 parts Resin-type pigment dispersant ("S0LSPERSE 20000" manufactured by Lubrizol Corporation of Japan) 1.74 parts • Diketopyrrolopyrrole pigment derivative 2. 05 copies

•丙烯酸系樹脂溶液 •環己酮 5.83 份 81.60 份 [綠色顏料分散體的調製] 使用下述組成的混合物，和紅色顏料分散體同樣地製 作綠色顏料分散體P-G。 •鹵化銅敝菁系顏料（C. I.顏料綠36) 63 322802 201142501 (東洋油墨製造公司製“LI0N0LGREEN6YK”）8.93份 •單偶氮系顏料（C. I.顏料黃150) (朗盛公司製“E4GN”） 2. 74 份 •樹脂型顏料分散劑 (日本路博潤公司製“S0LSPERSE 20000”） 2. 80 份 •丙烯酸系樹脂溶液 5. 53 份 •環己酮 80. 00 份 [藍色顏料分散體的調製] 使用下述組成的混合物，和紅色顏料分散體同樣地製 作藍色顏料分散體P-B。 • ε型銅醜菁系顏料（C. I.顏料藍15 : 6) (BASF 製 “Heliogen Blue L-6700F” ） 12· 88 份 •樹脂型顏料分散劑 (日本路博潤公司製“S0LSPERSE 20000”） 5. 62 份 •丙稀酸系樹脂溶液 1. 50 份 •環己酮 80. 00 份 [黑色顏料分散體的調製] 使用下述組成的混合物，和紅色顏料分散體同樣地製 作黑色顏料分散體P-BK。 •碳黑（三菱化學公司製“MA77”） 11.67 份 •樹脂型顏料分散劑 (日本路博潤公司製“SOLSPERSE 20000”） 2. 80 份 •丙稀酸系樹脂溶液 5. 53 份 •環己酮 80. 00 份 64 322802 201142501 [實施例1至24和比較例1至2] (感光性著色組合物的調製） 以表1至4所示的配方比率混合攪拌各材料，用 的過濾器進行過濾，得到各色的感光性著色組合物。 [表1 ] 實施例 1 實施例 2 實施例 3 實施例 4 實施例 5 實施例 6 實施例 7 顏料分散體 P-R P-R P-R P-R P-R P-R P'R 41.92 40. 53 27； 64 47. 91 20. 73 34. 55 35 93 丙烯酸系樹脂溶液 24.85 17. 25 36. 09 19. 60 29. 27 31.70 28. 33 光聚合引發劑（A) A1 A2 A4 A3 A1 A3 A2 0. 52 0. 13 0. 28 0. 25 0. 20 0. 30 0 R7 其他的光聚合引發劑（Y) Y1 Y1 Y1 Y4 Y3 Y1 0. 53 0. 45 0. 50 0. 95 0. 85 〇 1〇 其他的光聚合引發劑（Y) Y2 Y2 0.45 0. 25 增感劑（E) E1 E2 0. 25 0. 05 光聚合性化合物（C) 1. 74 1. 32 2. 81 1. 25 5. 07 2. 96 1 34 多官能硫醇（F) F1 0. 60 紫外線吸收劑（G) G1 〇 28 有機溶劑 30. 97 40. 24 32. 28 29. 99 43. 18 29. 59 33 35 合計 100.00 100.00 100. 00 100.00 100.00 100.00 100.00 322802 65 201142501 [表2] 實施例 8 實施例 9 實施例 10 實施例 11 實施例 12 實施例 13 實施例 14 顏料分散體 P-R P-G P-G P-G P-G P-G P-G 45. 60 38. 96 38. 57 47. 10 47. 78 31. 89 37. 82 丙烯酸系樹脂溶液 11. 77 20. 00 19. 18 2. 54 3. 99 36.40 34. 56 光聚合引發劑（A) A3 A2 A1 A4 A2 A1 A3 1.40 1.45 0. 73 0. 70 0.48 0. 28 0. 09 其他的光聚合引發劑（Y) Y2 Y5 Y2 Y1 Y2 0.43 0. 11 0. 43 0. 38 0. 21 其他的光聚合引發劑（Y) Y3 0. 40 增感劑（E) E2 0. 21 光聚合性化合物（C) 2. 28 1. 54 1.45 2. 34 1. 18 3.34 1. 02 多官能硫醇（F) F2 0. 30 阻聚劑（H) H1 H2 0. 01 0. 01 有機溶劑 38. 73 38. 05 39. 64 47. 21 45. 74 27. 70 26. 00 合計 100.00 100.00 100.00 100.00 100.00 100.00 100. 00 66 322802 201142501 [表3] 實施例 15 實施例 16 實施例 17 實施例 18 實施例 19 實施例 20 實施例 21 顏料分散體 P-G P-B P-B P-B P-B P-B P-K 28.46 23. 13 42. 11 23. 13 25.44 26. 98 42. 79 丙烯酸系樹脂溶液 29. 51 29. 76 0. 00 26. 41 5. 93 4. 41 0. 00 光聚合引發劑（A) A2 A1 A2 A4 A2 A3 A3 0. 12 1. 08 2. 74 3. 31 0. 93 3.44 1.15 其他的光聚合引發劑（Y) Y2 Y3 Y1 Y1 Y4 0. 60 0. 05 0. 24 0. 61 L 41 其他的光聚合引發劑（Y) Y2 0. 17 增感劑（E) E1 E2 E1 1. 03 0. 15 0. 09 光聚合性化合物（C) 2. 03 4. 30 2. 93 6. 62 3. 12 4. 59 2. 40 紫外線吸收劑（G) G2 0. 10 儲存穩定劑（J) J1 J2 0. 03 0. 03 有機溶劑 39. 25 41. 68 51. 19 40. 14 63. 61 60. 55 52. 25 合計 100.00 100. 00 100. 00 100. 00 100. 00 100. 00 100.00 67 322802 201142501 [表4] 實施例 22 實施例 23 實施例 24 比較例 1 比較例 2 顏料分散體 Ρ-Κ Ρ-Κ Ρ-Κ P-R P-R 48. 14 40. 73 45. 26 27. 64 27. 64 丙烯酸系樹脂溶液 3.55 1. 02 0. 00 40. 59 39. 58 光聚合引發劑（Α) Α2 Α4 Α1 Α1 1.62 1.44 0.94 0. 50 其他的光聚合引發劑（Υ) Υ2 Υ5 Υ6 0. 40 0. 24 0. 50 增感劑（Ε) Ε2 0.40’ 光聚合性化合物（C) 2. 68 1. 60 1. 28 1. 65 多官能硫畔（F) F2 F3 0. 74 0. 50 有機溶劑 43.21 54. 47 51. 78 29. 62 32.28 合計 100.00 100.00 100.00 100.00 100.00 表1至4中的略語，如下所述。 光聚合引發劑Y1 : 2-甲基-1-[4-(甲硫基）苯基]-2 一嗎 代基丙-1 -酿| (汽巴日本公司製“IRGACURE 907”） 光聚合引發劑Y2 : 2-(二甲基胺基）-2-[(4-甲基苯基) 甲基]-l-[4-(4-嗎啉基）苯基]_卜丁酮 (汽巴曰本公司製“IRGACURE 379”） 光聚合引發劑Y3 :2,4,6-三甲基苯甲醢基-二苯基膦 氧化物 (BASF 公司製 “Lucirin ΤΡ0”） 光聚合引發劑Y4 : 2,2，-二（鄰氯苯基）-4,5,4’，5，-四 本基~~1，2 -聯味唾 68 322802 201142501 (黑金化成公司製“聯咪唑，，） 光聚合引發劑Y5 :對二甲基胺基苯乙酮 (曰本DAIKI精細化學公司製“dma”） 光聚合引發劑Y6:乙烷-1-酮，i-[9-乙基-6-(2-甲基 苯甲醯基）-9H-咔唑-3-基]，1-(〇一乙醯肟） (汽巴日本公司製“IRGACURE OXE02”） 增感劑E1 . 2, 4-二乙基嗟嘲嗣 (日本化藥公司製“Kayacure DETX-S”） 增感劑E2 : 4, 4’-二（二乙基胺基）二苯甲酮 (保土谷化學工業公司製“EAB-F”） 光聚合性化合物C:二季戊四醇六丙烯酸酯 (東亞合成公司製“ARONIX M-402”） 多官能硫醇F1 :三羥曱基乙烷三（3-巯基丁酸酯） (昭和電工公司製“TEMB”） 多官能硫醇F2 :三羥甲基丙烷三（3-巯基丁酸酯） (昭和電工公司製“TPMB”） 多官能硫醇F3:季戊四醇四（3-酼基丙酸酯） (堺化學工業公司製“PEMP”） 系外線吸收劑G1 : 2_[4_[(2-經基-3-(十二烧基和十 三烧基）氧基丙基）氧基]-2-羥基苯基]-4, 6-二（2, 4-二甲 基苯基）-1，3, 5-三啡 (汽巴日本公司製“TINUVIN400”） 紫外線吸收劑G2 : 2-(2H-苯并***-2-基）-4, 6-二（1-曱基本基乙基）苯盼 69 322802 201142501 (汽巴日本公司製“TINUVIN900”） 阻聚劑HI : N-亞硝基苯基經基胺銘鹽 (和光純藥工業公司製“Q-1301”） 阻聚劑H2 :甲基氫醌 (精工化學公司製“ΜΓ ) 儲藏穩定劑J1 : 2, 6-二（1,1-二甲基乙基）_4_甲基苯 酚 (本州化學工業公司製“BHT”） 儲藏穩定劑J2 :三苯基膦 (北興化學工業公司製“Τρρ”） 有機溶劑··環己酮 對所得的感光性著色組合物，使用下述方法進行評 4貝。結果不於表5和6。 [濾波器節和黑色矩陣的圖案形成] 藉由旋塗法將所得的感光性著色組合物塗布在1〇· l〇cm的玻璃基板上，然後在潔淨烘箱中在肌下加熱 分鐘除去溶劑’得到約的塗膜。接著，將該基板冷卻 至室溫後，使用超高壓水銀燈，並經由1〇〇抑寬（間距為 ㈣和25_寬（間距為5(^m)條紋圖案的光罩進行紫 外線曝光。然後’使用23 C的碳酸鈉水溶液對該基板進行 喷霧顯影，㈣⑽子錢錢行M，風乾，並在潔淨 烘箱中在23(TC下加熱30分鐘。對於各感光性著色組合物 的塗膜，以無顯影殘留並且能夠形成圖案的最短時間進行 喷霧顯影，並將該時間作為適當的顯影時間。 322802 70 201142501 塗膜的膜厚，使用Dektak 3030(日本真空技術公司製） . 進行測定。 '[感度評價] 測定藉由上述方法所形成的濾波器節或黑色矩陣中 l〇0&quot;m光罩部分的圖案膜厚’並對塗布後的膜厚，評價達 刻90%以上的最小曝光量。最小曝光量越小，則形成了感 度越高的良好的感光性著色組合物。 〇：未達50mJ/cm2 △ : 50mJ/cm2 以上且未達 l〇〇mJ/cm2 X : 100mJ/cm2 以上 [直線性評價] 對於藉由上述方法所形成的濾波器節或黑色矩陣中 l〇0/zm光罩部分的圖案’使用光學顯微鏡進行觀察並評 償。評價等級如下所述。 〇：直線性良好 △:部分直線性不良 X :直線性不良 [圖案形狀評價] 對於藉由上述方法所形成的濾波器節或黑色矩陣中 100//m光罩部分的圖案截面，使用電子顯微鏡進行觀察並 評價。圖案截面為正錐形是良好的。評價等級如下所述。 〇·截面為正錐形 X :截面為倒錐形 [解析度評價] 322802 71 201142501 對於藉由上述方法所形成的m節或黑色矩陣中 _光罩部分的圖案’使衫學顯微鏡進行觀察並評價。 :賈A級如下所述。解析度不良，是指鄰接的條紋圖案相 連’或者產生缺損。評價等級如下所述。 ◎ •解析度和直線性良好 〇.在直線性方面稍差，但解析度 △:部分解析度不良 χ :解析度不良 [耐顯影性評價] 噴霧顯時’測定以適當時間的2倍時間進行顯影所 厚成的濾波器節或黑色矩料1QQ_光罩部分的圖案膜 並與以適當顯影時間顯影所形成的圖案膜厚進行比 較。評價等級如下所述。 ◎ 〇 △ χ 膜厚差在20%以内 膜厚差大於20%，並在40%以内 膜厚差大於40% 進行2倍顯影時產生缺損或剝離 [耐樂品性評價] 將藉由上述方法所形成的濾波器節或黑色矩陣在N 一甲 比嘻相中歸30分雜’用離子交換水崎洗務，風 ^並使用光學顯微鏡對100/zm光罩部分的圖案進行 並評價。評料級如下所述。 ” ◎:外觀、顏色未變化而良好 〇：部分產生皺褶等，但顏色未變化而良好 322802 72 201142501 △:產生一些褪色 X :產生剥離或褪色 [經時穩定性評價] 對所得的感光性著色組合物，測定初期和在室溫下1 個月後的黏度’計算相對於初期黏度的黏度增加程度，並 進行評價。評價等級如下所述。 ◎:黏度增加的比例在5%以下而良好 〇：黏度增加的比例大於5%，並在10%以下 X :黏度增加的比例大於10% [表5] 實施例 1 實施例 2 實施例 3 實施例 4 實施例 5 實施例 6 實施例 7 實跑例 8 實施例 9 實施例 10 實牴例 11 實施例 12 實施例 13 感度 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 直線性 〇 〇 〇 〇 0 〇 〇 〇 〇 〇 〇 〇 〇 圊案形狀 〇 〇 〇 〇 〇 〇 〇 0 〇 〇 〇 〇 〇 解析度 〇 〇 〇 〇 〇 〇 ◎ ◎ 〇 〇 〇 〇 ◎ 耐顯彩性 〇 〇 ◎ ◎ ◎ 〇 〇 〇 〇 ◎ 〇 ◎ 〇 耐藥品性 〇 ◎ ◎ ◎ ◎ ◎ ◎ 〇 @ ◎ ◎ ◎ 經時稞定性 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 [表6] 實施例 14 實施例 15 實施例 16 實施例 17 實铯例 18 實施例 19 實施例 20 實施例 21 實施例 22 實施例 23 實施例 24 比枚例 1 比較例 2 感度 〇 〇 〇 〇 〇 〇 〇 0 〇 〇 〇 Δ X 直線性 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 △ X 圈案形狀 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 X 解析度 〇 〇 〇 〇 〇 ◎ 〇 〇 〇 〇 〇 △ X 耐顯影性 ◎ ◎ 〇 〇 〇 ◎ 〇 〇 ◎ ◎ ◎ X X 耐祭品性 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 ◎ △ X 經暗钱定性 〇 ◎ 〇 〇 〇 〇 ◎ 〇 〇 〇 〇 〇 〇 如表5和6所示’使用實施例1至24的感光性著色組 合物所形成的濾波器節和黑色矩陣，其感度、直線性和解 322802 73 201142501 析度良好，此外’將本專利申請案的光聚合引發劑（A)和其 匕的光聚合引發劑（Y)併用的實施例2至7、10至16、18、 19 &gt; 21、22、24，顯示出在耐藥品性方面更優異的特性。 其中’其它的光聚合引發劑（γ)為2一（二曱基胺基）一2_[(4-曱基苯基）曱基]一1-[4-(4-嗎啉基）苯基]-1-丁酮的實施例 3 4 1〇、12、14、15、22，其耐顯影性更加優異。 此外，進一步含有多官能硫醇（F)的實施例5、14、23、 24，其耐顯影性優異。 此外，進一步含有紫外線吸收劑（G)或阻聚劑〇〇的實 施例7、8、13、19，其解析度優異。 此外，進一步含有儲藏穩定劑（J)的實施例15、20， 其經時穩定性優異。 如比較例1至2般使用其它的肟酯系光聚合引發劑的 情況或者不含光聚合性化合物（C)的情況’在圖案特性方面 產生不良無法得到全部特性都良好的結果。 接著，調整含有通式（11)所表示的光聚合引發劑（A) 的感光性著色組合物，使用其製㈣色H，並評價各種特 性（實施例m至124和比較例⑻；⑽）。 感光性著色組合物的調整，係藉由分別製造丙烯酸系 t月曰/谷液和顏料分散體，並與其它成分滿合等而進行。 &lt;丙稀酸系樹脂溶液的製造方法〉 [丙烯酸系樹脂溶液的調製] ，反應容器中加入370份環己酮，姐一邊向容器中注 氮氣邊加熱至80°C，在該溫度下經1小時滴加20. 0 74 322802 201142501 份甲基丙烯酸、10· 0份曱基丙稀酸曱酯、55. 〇份甲基丙稀 酸正丁酯、15· 0份曱基丙烯酸2-羥基乙酯、和4. 〇份2 2, _ 偶氮二異丁腈的混合物，進行聚合反應。滴加結束後，再 在80°C下反應3小時，然後添加已將1·〇份偶氮二異丁猜 溶於50份環己酮中的溶液’並進一步在8(rc下持續反應i 小時，得到丙烯酸系樹脂溶液。 冷卻至室溫後’取樣約2g的丙烯酸系樹脂溶液，在 180°C下加熱乾燥20分鐘’測定不揮發成分，並據此在上 述合成的丙烯酸系樹脂溶液中添加環己綱，使其不揮發成 分為20重量％。所得的丙稀酸系樹脂的重均分子量為 40000。 〈顏料分散體的製造方法〉 [紅色顏料分散體的調製] 將下述組成的混合物攪拌混合均勻後，使用直徑為lmm 的氧化錯珠’並藉由EIGER研磨機（EIGER日本公司製“迷 你型Μ-250 ΜΚΙΓ )分散5小時’然後用5/zm的過濾器過 遽’製作紅色顏料分散體p-R。 •二酮基°比咯并吡咯系顏料（C. I.顏料紅254) 6. 82份 (汽巴日本公司製“IRGAPHOR RED B-CF”） •蒽靦系顏料（C. I.顏料紅177) 1.08份 (汽巴日本公司製“CROMOPHTAL RED A2B”） •錄偶氮錯合物系顏料（C. I.顏料黃150) (朗盛公司製“E4GN”） 0.88份 •樹脂型顏料分散劑 1.74份 75 322802 201142501 (日本路博潤公司製“SOLSPERSE 20000”） •二酮基吡咯并吡咯系顏料衍生物 2. 05份• Acrylic resin solution • Cyclohexanone 5.83 parts 81.60 parts [Preparation of green pigment dispersion] A green pigment dispersion P-G was produced in the same manner as the red pigment dispersion using a mixture of the following composition. • Copper phthalocyanine pigment (CI Pigment Green 36) 63 322802 201142501 ("LI0N0LGREEN6YK" manufactured by Toyo Ink Co., Ltd.) 8.93 parts • Monoazo pigment (CI Pigment Yellow 150) ("E4GN" manufactured by LANXESS) 2 74 parts • Resin-type pigment dispersant (S0LSPERSE 20000, manufactured by Lubrizol Corporation, Japan) 2. 80 parts • Acrylic resin solution 5. 53 parts • Cyclohexanone 80. 00 parts [Modulation of blue pigment dispersion A blue pigment dispersion PB was produced in the same manner as the red pigment dispersion using a mixture of the following composition. • ε-type copper ugly pigment (CI Pigment Blue 15: 6) (Heligen Blue L-6700F by BASF) 12· 88 parts • Resin-type pigment dispersant (“S0LSPERSE 20000” by Lubrizol Corporation of Japan) 5 62 parts • Acrylic resin solution 1. 50 parts • Cyclohexanone 80. 00 parts [Preparation of black pigment dispersion] A black pigment dispersion P was produced in the same manner as the red pigment dispersion using a mixture of the following composition -BK. • Carbon black ("MA77" manufactured by Mitsubishi Chemical Corporation) 11.67 parts • Resin-type pigment dispersant ("SOLSPERSE 20000" manufactured by Lubrizol Corporation of Japan) 2. 80 parts • Acrylic resin solution 5. 53 parts • Ring Ketone 80. 00 parts 64 322802 201142501 [Examples 1 to 24 and Comparative Examples 1 to 2] (Preparation of photosensitive coloring composition) The materials were mixed and stirred at the formulation ratios shown in Tables 1 to 4, using a filter. Filtration was carried out to obtain photosensitive coloring compositions of respective colors. [Table 1] Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Pigment dispersion PR PR PR PR PR PR P'R 41.92 40. 53 27; 64 47. 91 20. 73 34. 55 35 93 Acrylic resin solution 24.85 17. 25 36. 09 19. 60 29. 27 31.70 28. 33 Photopolymerization initiator (A) A1 A2 A4 A3 A1 A3 A2 0. 52 0. 13 0. 28 0 25 0. 20 0. 30 0 R7 Other photopolymerization initiators (Y) Y1 Y1 Y1 Y4 Y3 Y1 0. 53 0. 45 0. 50 0. 95 0. 85 〇1〇 Other photopolymerization initiators ( Y) Y2 Y2 0.45 0. 25 sensitizer (E) E1 E2 0. 25 0. 05 Photopolymerizable compound (C) 1. 74 1. 32 2. 81 1. 25 5. 07 2. 96 1 34 Functional thiol (F) F1 0. 60 UV absorber (G) G1 〇28 Organic solvent 30. 97 40. 24 32. 28 29. 99 43. 18 29. 59 33 35 Total 100.00 100.00 100. 00 100.00 100.00 100.00 100.00 322802 65 201142501 [Table 2] Example 8 Example 9 Example 10 Example 11 Example 12 Example 13 Example 14 Pigment dispersion PR PG PG PG PG PG PG 4 5. 60 38. 96 38. 57 47. 10 47. 78 31. 89 37. 82 Acrylic resin solution 11. 77 20. 00 19. 18 2. 54 3. 99 36.40 34. 56 Photopolymerization initiator (A A3 A2 A1 A4 A2 A1 A3 1.40 1.45 0. 73 0. 70 0.48 0. 28 0. 09 Other photopolymerization initiators (Y) Y2 Y5 Y2 Y1 Y2 0.43 0. 11 0. 43 0. 38 0. 21 Other photopolymerization initiators (Y) Y3 0. 40 Sensitizer (E) E2 0. 21 Photopolymerizable compound (C) 2. 28 1. 54 1.45 2. 34 1. 18 3.34 1. 02 Polyfunctional sulfur Alcohol (F) F2 0. 30 Inhibitor (H) H1 H2 0. 01 0. 01 Organic solvent 38. 73 38. 05 39. 64 47. 21 45. 74 27. 70 26. 00 Total 100.00 100.00 100.00 100.00 100.00 100.00 100. 00 66 322802 201142501 [Table 3] Example 15 Example 16 Example 17 Example 18 Example 19 Example 20 Example 21 Pigment dispersion PG PB PB PB PB PB PK 28.46 23. 13 42. 11 23. 13 25.44 26. 98 42. 79 Acrylic resin solution 29. 51 29. 76 0. 00 26. 41 5. 93 4. 41 0. 00 Photopolymerization initiator (A) A2 A1 A2 A4 A2 A3 A3 0 . 12 1. 0 8 2. 74 3. 31 0. 93 3.44 1.15 Other photopolymerization initiator (Y) Y2 Y3 Y1 Y1 Y4 0. 60 0. 05 0. 24 0. 61 L 41 Other photopolymerization initiator (Y) Y2 0. 17 sensitizer (E) E1 E2 E1 1. 03 0. 15 0. 09 Photopolymerizable compound (C) 2. 03 4. 30 2. 93 6. 62 3. 12 4. 59 2. 40 UV Absorbent (G) G2 0. 10 Storage stabilizer (J) J1 J2 0. 03 0. 03 Organic solvent 39. 25 41. 68 51. 19 40. 14 63. 61 60. 55 52. 25 Total 100.00 100. 00 100. 00 100. 00 100. 00 100. 00 100.00 67 322802 201142501 [Table 4] Example 22 Example 23 Example 24 Comparative Example 1 Comparative Example 2 Pigment dispersion Ρ-Κ Ρ-Κ Ρ-Κ PR PR 48. 14 40. 73 45. 26 27. 64 27. 64 Acrylic resin solution 3.55 1. 02 0. 00 40. 59 39. 58 Photopolymerization initiator (Α) Α2 Α4 Α1 Α1 1.62 1.44 0.94 0. 50 Others Photopolymerization initiator (Υ) Υ2 Υ5 Υ6 0. 40 0. 24 0. 50 sensitizer (Ε) Ε2 0.40' Photopolymerizable compound (C) 2. 68 1. 60 1. 28 1. 65 Multifunctional Sulfur (F) F2 F3 0. 74 0. 50 Organic solvents 43.21 54. 47 51. 78 29. 62 32.28 Total 100.00 100.00 100.00 100.00 100.00 Abbreviations in Tables 1 to 4, as described below. Photopolymerization initiator Y1 : 2-methyl-1-[4-(methylthio)phenyl]-2 mono-n-propylpropan-1 - brewing | ("ICGACURE 907" manufactured by Ciba Japan Co., Ltd.) Photopolymerization initiation Agent Y2: 2-(Dimethylamino)-2-[(4-methylphenyl)methyl]-l-[4-(4-morpholinyl)phenyl]-butanone (Ciba IR"IRGACURE 379" manufactured by the company) Photopolymerization initiator Y3: 2,4,6-trimethylbenzimidyl-diphenylphosphine oxide ("Lucirin ΤΡ0", manufactured by BASF Corporation) Photopolymerization initiator Y4: 2,2,-di(o-chlorophenyl)-4,5,4',5,-tetrabenyl~~1,2-linked flavor saliva 68 322802 201142501 (Black imident company "Biimidazole,") light Polymerization initiator Y5: p-dimethylamino acetophenone ("dma" manufactured by Sakamoto DAIKI Fine Chemical Co., Ltd.) Photopolymerization initiator Y6: ethane-1-ketone, i-[9-ethyl-6-( 2-Methylbenzylidene)-9H-indazol-3-yl], 1-(〇一乙醯肟) ("IRGACURE OXE02" manufactured by Ciba Japan Co., Ltd.) Sensitizer E1. 2, 4-II Ethyl oxime (Kayacure DETX-S, manufactured by Nippon Kayaku Co., Ltd.) Sensitizer E2: 4, 4'-bis(diethylamino)benzophenone (EAB-made by Hodogaya Chemical Industry Co., Ltd.) F ) Photopolymerizable compound C: dipentaerythritol hexaacrylate ("ARONIX M-402", manufactured by Toagosei Co., Ltd.) Polyfunctional thiol F1: trihydroxy decyl ethane tris(3-mercaptobutyrate) (made by Showa Denko Co., Ltd.) "TEMB") Polyfunctional thiol F2: Trimethylolpropane tris(3-mercaptobutyrate) ("TPMB", manufactured by Showa Denko) Polyfunctional thiol F3: Pentaerythritol tetrakis(3-mercaptopropionate) ("PEMP" manufactured by 堺Chemical Industries Co., Ltd.) is an external absorbent G1: 2_[4-[(2-amino-3-(dodecanyl) and decyl)oxypropyl)oxy]-2- Hydroxyphenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5-trimorphine ("TINUVIN400" manufactured by Ciba Japan) UV absorber G2 : 2-(2H- Benzotriazol-2-yl)-4,6-bis(1-indolylethyl)benzene Pan 69 322802 201142501 ("CONUBA900" manufactured by Ciba Japan) Inhibitor HI: N-nitrosobenzene Base amide amine salt ("Q-1301" manufactured by Wako Pure Chemical Industries Co., Ltd.) Inhibitor H2: Methylhydroquinone ("精" by Seiko Chemical Co., Ltd. Storage stabilizer J1 : 2, 6-two (1,1 -Dimethylethyl)_4_methylphenol (Honzhou Chemical Industry Division system "BHT") storage stabilizer J2: triphenylphosphine (Hokko Chemical Industry Co., Ltd. "Τρρ") organic solvent · Cyclohexanone photosensitive coloring composition obtained using the following method Comments 4 dB. The results are not shown in Tables 5 and 6. [Pattern Formation of Filter Section and Black Matrix] The obtained photosensitive coloring composition was applied onto a glass substrate of 1 μm·cm by spin coating, and then the solvent was removed by heating in a clean oven for a minute under the muscle oven' Approximately the coating film was obtained. Next, after the substrate was cooled to room temperature, an ultrahigh pressure mercury lamp was used, and ultraviolet exposure was performed via a reticle with a pitch of (four) and a width of 5 (m) (a pitch of 5 (^m) stripes. Then ' The substrate was spray-developed using a 23 C aqueous sodium carbonate solution, (iv) (10) sub-money M, air-dried, and heated in a clean oven at 23 (TC for 30 minutes. For the coating film of each photosensitive coloring composition, Spray development was carried out in the shortest time period in which no development residue was able to form a pattern, and this time was taken as an appropriate development time. 322802 70 201142501 The film thickness of the coating film was measured using Dektak 3030 (manufactured by Nippon Vacuum Technology Co., Ltd.). Sensitivity Evaluation] The pattern thickness of the filter segment or the black matrix formed by the above method was measured, and the film thickness after coating was evaluated to a minimum exposure amount of 90% or more. The smaller the minimum exposure amount, the better the photosensitive coloring composition having a higher sensitivity. 〇: less than 50 mJ/cm 2 Δ : 50 mJ/cm 2 or more and less than 10 μM/cm 2 X : 100 mJ/cm 2 or more [ Linear evaluation] The pattern of the l〇0/zm mask portion formed by the above method or the black matrix is observed and evaluated using an optical microscope. The evaluation levels are as follows. 〇: Good linearity △: partial straight line Sexual defect X: Linearity defect [Pattern shape evaluation] The pattern section of the 100/m mask portion in the filter segment or the black matrix formed by the above method was observed and evaluated using an electron microscope. The taper is good. The evaluation grade is as follows: 〇·The cross section is a positive taper X: The cross section is a reverse taper [Evaluation of resolution] 322802 71 201142501 For the m-section or black matrix formed by the above method The pattern of the cover portion was observed and evaluated by a shirt microscope. The grade A was as follows. The poor resolution means that the adjacent stripe patterns are connected or defective. The evaluation levels are as follows. ◎ • Resolution and straight line Good in performance. It is slightly inferior in linearity, but resolution Δ: partial resolution is poor χ : poor resolution [evaluation of development resistance] When spraying is measured 'measured at appropriate time The pattern of the thickened filter section or the black matrix 1QQ_mask portion was developed twice in comparison with the pattern thickness formed by development at an appropriate development time. The evaluation level is as follows. ◎ 〇△ χ If the film thickness difference is less than 20% within 20%, and the film thickness difference is more than 40% within 40%, the defect or peeling occurs when the film is developed twice. [Nailability evaluation] The filter formed by the above method The section of the 100/zm reticle portion was evaluated and evaluated by an optical microscope using an ion microscope for the 30-minute miscellaneous in the N-methyl 嘻 phase. The rating level is as follows. ◎: Appearance and color are unchanged and good 〇: Partially wrinkles, etc., but the color does not change and is good 322802 72 201142501 △: Some fading is produced X: Peeling or fading occurs [Evaluation of stability over time] Sensitivity obtained In the coloring composition, the viscosity at the initial stage and the temperature after one month at room temperature was measured and the degree of viscosity increase with respect to the initial viscosity was calculated and evaluated. The evaluation level is as follows. ◎: The ratio of viscosity increase is 5% or less. 〇: the ratio of viscosity increase is more than 5%, and below 10% X: the ratio of viscosity increase is more than 10% [Table 5] Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Example 11 Example 12 Example 13 Sensitivity and linearity 〇〇〇〇0 file Shape 〇〇〇〇〇〇〇0 〇〇〇〇〇resolution 〇〇〇〇〇〇 ◎ ◎ 〇〇〇〇 ◎ resistance to photographic 〇〇 ◎ ◎ ◎ 〇〇〇〇 ◎ 〇 ◎ 〇 耐品 〇 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ ◎ 经 稞 稞 〇〇〇〇〇〇〇〇〇〇〇〇〇 〇〇〇〇〇〇〇〇〇〇〇〇〇 〇〇〇〇〇〇〇〇〇〇〇〇〇 [Table 6] Example 14 Example 15 Example 16 Example 17 Example 18 Example 19 Example 20 Example 21 Example 22 Example 23 Example 24 Specific example 1 Comparative Example 2 Sensitivity 〇〇〇〇〇〇〇0 〇〇〇Δ X Linearity 〇〇〇〇〇〇〇〇 〇〇〇△ X circle shape 〇〇〇〇〇〇〇〇〇〇〇X resolution 〇〇〇〇〇 ◎ 〇〇〇〇〇△ X resistance to development ◎ ◎ 〇〇〇 ◎ 〇〇 ◎ ◎ ◎ XX耐 耐 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 ◎ △ X by dark money qualitative 〇 ◎ ◎ ◎ as shown in Tables 5 and 6 'Use the sensitization of Examples 1 to 24 The filter section and the black matrix formed by the coloring composition have good sensitivity, linearity and resolution 322802 73 201142501, and the photopolymerization initiator (A) of the present patent application and the photopolymerization initiator thereof (Y) and Examples 2 to 7, 10 to 16, 18, 19 &gt; 21, 22, and 24 showed more excellent properties in terms of chemical resistance. Among them, 'other photopolymerization initiators (γ) were 2 ( Example 3 of dinonylamino)- 2-[(4-mercaptophenyl)indenyl]-l-[4-(4-morpholinyl)phenyl]-1-butanone 4 1 〇, 12 14, 15, 15, and 22, which are more excellent in developability. Further, Examples 5, 14, 23, and 24 which further contain a polyfunctional thiol (F) are excellent in developability. Further, Examples 7, 8, 13, and 19, which further contained the ultraviolet absorber (G) or the polymerization inhibitor, were excellent in resolution. Further, Examples 15 and 20 further containing a storage stabilizer (J) were excellent in stability over time. When the other oxime ester-based photopolymerization initiator was used as in Comparative Examples 1 and 2 or the case where the photopolymerizable compound (C) was not contained, the result was poor in pattern characteristics, and all of the properties were not obtained. Then, the photosensitive coloring composition containing the photopolymerization initiator (A) represented by the formula (11) was adjusted, and (4) color H was used, and various characteristics were evaluated (Examples m to 124 and Comparative Examples (8); (10)) . The adjustment of the photosensitive coloring composition is carried out by separately producing an acrylic tau/gluten solution and a pigment dispersion, and mixing them with other components. &lt;Method for Producing Acrylic Resin Solution> [Preparation of Acrylic Resin Solution], 370 parts of cyclohexanone was added to the reaction vessel, and the sister heated to 80 ° C while injecting nitrogen into the vessel, at which temperature 1 hour drop of 20. 0 74 322802 201142501 parts of methacrylic acid, 10·0 parts of decyl acrylate, 55. 〇 part of n-butyl methacrylate, 15.0 parts of 2-hydroxy methacrylate A mixture of ethyl ester and 4. 2 parts of 2, azobisisobutyronitrile is subjected to polymerization. After the completion of the dropwise addition, the reaction was further carried out at 80 ° C for 3 hours, and then a solution in which 1·〇 of azobisisodin was dissolved in 50 parts of cyclohexanone was added and further continued at 8 (rc) The acrylic resin solution was obtained in an hour. After cooling to room temperature, 'sampling about 2 g of the acrylic resin solution and heating and drying at 180 ° C for 20 minutes' was used to measure the nonvolatile matter, and accordingly, in the above-mentioned synthetic acrylic resin solution. The cyclohexene was added so as to have a nonvolatile content of 20% by weight. The weight average molecular weight of the obtained acrylic resin was 40,000. <Method for Producing Pigment Dispersion> [Preparation of Red Pigment Dispersion] The following composition was used. After the mixture was stirred and mixed uniformly, oxidized beads of 1 mm in diameter were used and dispersed by an EIGER mill ("mini Μ-250 ΜΚΙΓ" manufactured by EIGER Japan Co., Ltd. for 5 hours" and then made with a 5/zm filter. Red pigment dispersion pR • Diketopylpyrolopyrrole pigment (CI Pigment Red 254) 6. 82 parts ("IgAPHOR RED B-CF" by Ciba Japan)) Lanthanide pigment (CI Pigment Red) 177) 1.08 copies (Ciba Japan System "CROMOPHTAL RED A2B") • Recorded azo complex pigment (CI Pigment Yellow 150) ("E4GN" manufactured by LANXESS) 0.88 parts • Resin pigment dispersant 1.74 parts 75 322802 201142501 (Lubricol, Japan) Company made "SOLSPERSE 20000") • Diketopyrrolopyrrole pigment derivative 2. 05 parts

•丙浠酸系樹脂溶液 5. 83份 •環己酮 81. 60份 [綠色顏料分散體的調製] 使用下述組成的混合物，和紅色顏料分散體同樣地製 作綠色顏料分散體P-G。 •鹵化銅酿菁系顏料（C. I.顏料綠36) 8. 93份 (東洋油墨製造公司製“LIONOL GREEN 6ΥΓ ) •單偶氮系顏料（C. I.顏料黃150) 2. 74份 (朗盛公司製“E4GN”） •樹脂型顏料分散劑 2. 80份 (日本路博潤公司製“SOLSPERSE 20000”） •丙烯酸系樹脂溶液 5. 53份 •環己酮 80. 00份 [藍色顏料分散體的調製] 使用下述組成的混合物，和紅色顏料分散體同樣地製 作藍色顏料分散體P-B。 • ε型銅醜菁系顏料（C. I.顏料藍15 : 6) 76 322802 201142501 (BASF 製 “Heliogen Blue L-6700F” ） 12. 88 份 •樹脂型顏料分散劑 5. 62 份 (日本路博潤公司製“SOLSPERSE 20000”） •丙烯酸系樹脂溶液 1. 50 份 •環己酮 80. 00 份 [黑色顏料分散體的調製] 使用下述組成的混合物，和紅色顏料分散體同樣地製 作黑色顏料分散體P-BK。 11. 67 份 2. 80 份 5. 53 份 80. 00 份 •碳黑（三菱化學公司製“MA77”） •樹脂型顏料分散劑 (日本路博潤公司製“S0LSPERSE 20000”） •丙烯酸系樹脂溶液 •環己酮 [實施例101至124和比較例101至102] (感光性著色組合物的調製） 以表7至10所示的配方比率混合攪拌各材料，用1 的過濾器進行過濾，得到各色的感光性著色組合物。 77 322802 201142501 [表7] 實施例 101 實施例 102 實施例 103 實施例 104 實施例 105 實施例 106 實施例 107 顏料分散體 P-R P-R P-R P-R P-R P-R P-R 41. 92 40. 53 27. 64 47. 91 20. 73 34. 55 35. 93 丙烯酸系樹脂溶液 24. 85 17. 25 36. 09 19. 60 29. 27 31. 70 28. 33 光聚合引發劑（A) A5 A5 A5 A5 A5 A5 A5 0. 52 0. 13 0. 28 0. 25 0. 20 20. 0 0. 67 其他的光聚合引發劑（Y) Y1 Y1 Y1 Y4 Y3 Y1 0. 53 0. 45 0. 50 0. 95 0. 85 0. 10 其他的光聚合引發劑（Y) Y2 Y2 0. 45 0. 25 增感劑（E) E1 E2 0. 25 0. 05 光聚合性化合物（C) 1. 74 1. 32 2. 81 1. 25 5. 07 2. 96 1.34 多官能硫醇（F) F1 0. 60 紫外線吸收劑（G) G1 0. 28 有機溶劑 30. 97 40. 24 32. 28 29. 99 43. 18 29. 59 33. 35 合計 100.00 100.00 100. 00 100.00 100.00 100. 00 100.00 78 322802 201142501 [表8] 實施例 108 實施例 109 實施例 110 實施例. 111 實施例 112 實施例 113 實施例 114 顏料分散體 P-R P-G P-G P-G P-G P-G P-G 45. 60 38. 96 51. 29 47. 10 47. 78 31. 89 37.82 丙烯酸系樹脂溶液 11. 77 20. 00 14.43 2. 54 3. 99 36.40 34. 56 光聚合引發劑（A) A5 A5 A5 A5 A5 A5 A5 1. 40 1.45 0. 17 0. 70 0. 48 0. 28 0. 09 其他的光聚合引發劑（Y) Y2 Y5 Y2 Y1 Y2 0. 67 0. 11 0.43 0. 38 0. 21 其他的光聚合引發劑（Y) Y3 0.40 增感劑（E) E2 0. 21 光聚合性化合物（C) 2. 28 1. 54 2. 56 2. 34 1.18 3. 34 1. 02 多官能硫醇（F) F2 0. 30 阻聚劑（H) H1 H2 0. 01 0. 01 有機溶劑 38. 73 38. 05 30.88 47.21 45· 74 27. 70 26. 00 合計 100. 00 100.00 100.00 100. 00 100. 00 100. 00 100.00 79 322802 201142501 [表9] 實施例 115 實施例 116 實施例 117 實施例 118 實施例 119 實施例 120 實施例 121 顏料分散體 P-G P-B P-B P-B P-B P-B P-BK 28.46 23. 13 42. 11 23. 13 25.44 26. 98 42. 79 丙烯酸系樹脂溶液 29. 51 29. 76 0. 00 26.41 5. 93 4.41 0. 00 光聚合引發劑（A) A5 A5 A5 A5 A5 A5 A5 0. 12 1. 08 2. 74 3. 31 0. 93 3.44 1.15 其他的光聚合引發劑（Y) Y2 Y3 Y1 Y1 Y4 0. 60 0. 05 0. 24 0. 61 1.41 其他的光聚合引發劑（Y) Y2 0. 17 增感劑（E) E1 E2 E1 1. 03 0. 15 0. 09 光聚合性化合物（C) 2. 03 4. 30 2. 93 6. 62 3. 12 4. 59 2. 40 紫外線吸收劑（G) G2 0. 10 儲藏穩定劑（J) J1 J2 0. 03 0. 03 有機溶劑 39. 25 41. 68 51. 19 40. 14 63. 61 60. 55 52. 25 合計 100.00 100.00 100. 00 100. 00 100. 00 100. 00 100.00 80 322802 201142501 r [表 10] 實施例 122 實施例 123 實施例 124 比較例 101 比較例 102 顏料分散體 Ρ-ΒΚ Ρ-ΒΚ Ρ-ΒΚ P-R P-R 48. 14 40.73 45. 26 27. 64 27. 64 丙烯酸系樹脂溶液 3. 55 1. 02 0. 00 40. 59 39. 58 光聚合引發劑（Α) Α5 Α5 Α5 Α5 1. 62 1. 44 0. 94 0. 50 其他的光聚合引發劑（Υ) Υ2 Υ5 Υ6 0. 40 0. 24 0. 50 增感劑（Ε) Ε2 0.40 光聚合性化合物（C) 2.68 1. 60 1. 28 1. 65 多官能硫醇（F) F2 F3 0. 74 0. 50 有機溶劑 43.21 54. 47 51. 78 29. 62 32. 28 合計 100.00 100.00 100.00 100.00 100. 00 表7至10中的略語，如下所述。 光聚合引發劑A5 :下述式（12)結構的化合物 式（12) Λ• Propionic acid resin solution 5. 83 parts • Cyclohexanone 81. 60 parts [Preparation of green pigment dispersion] A green pigment dispersion P-G was produced in the same manner as the red pigment dispersion using a mixture of the following composition. • Halogenated copper-based pigments (CI Pigment Green 36) 8. 93 parts (LIONOL GREEN 6ΥΓ, manufactured by Toyo Ink Co., Ltd.) • Monoazo pigments (CI Pigment Yellow 150) 2. 74 parts (made by LANXESS) E4GN") • Resin type pigment dispersant 2. 80 parts ("SOLSPERSE 20000" manufactured by Lubrizol Corporation, Japan) • Acrylic resin solution 5. 53 parts • Cyclohexanone 80. 00 parts [Modulation of blue pigment dispersion A blue pigment dispersion PB was produced in the same manner as the red pigment dispersion using a mixture of the following composition: • ε-type copper ugly pigment (CI Pigment Blue 15: 6) 76 322802 201142501 (Heligen Blue L- by BASF) 6700F" ) 12. 88 parts • Resin type pigment dispersing agent 5. 62 parts ("SOLSPERSE 20000" made by Lubrizol Corporation of Japan) • Acrylic resin solution 1. 50 parts • Cyclohexanone 80. 00 parts [Black pigment dispersion Preparation of the body] A black pigment dispersion P-BK was produced in the same manner as the red pigment dispersion using a mixture of the following composition: 11. 67 parts 2. 80 parts 5. 53 parts 80. 00 parts • carbon black (Mitsubishi Chemical Co., Ltd. "MA77") • Resin type pigments Agent (S0LSPERSE 20000, manufactured by Lubrizol Corporation, Japan) • Acrylic resin solution • Cyclohexanone [Examples 101 to 124 and Comparative Examples 101 to 102] (Preparation of photosensitive coloring composition) Tables 7 to 10 The respective formulation ratios were mixed and stirred, and filtered with a filter of 1 to obtain photosensitive coloring compositions of respective colors. 77 322802 201142501 [Table 7] Example 101 Example 102 Example 103 Example 104 Example 105 Example 106 Example 19. Pigment dispersion PR PR PR PR PR PR PR PR 41. 92 40. 53 27. 64 47. 91 20. 73 34. 55 35. 93 Acrylic resin solution 24. 85 17. 25 36. 09 19. 60 29. 27 31. 70 28. 33 Photopolymerization initiator (A) A5 A5 A5 A5 A5 A5 A5 0. 52 0. 13 0. 28 0. 25 0. 20 20. 0 0. 67 Other photopolymerization Agent (Y) Y1 Y1 Y1 Y4 Y3 Y1 0. 53 0. 45 0. 50 0. 95 0. 85 0. 10 Other photopolymerization initiator (Y) Y2 Y2 0. 45 0. 25 Sensitizer (E E1 E2 0. 25 0. 05 Photopolymerizable compound (C) 1. 74 1. 32 2. 81 1. 25 5. 07 2. 96 1.34 Polyfunctional thiol (F) F1 0. 60 UV absorber (G) G1 0. 28 Organic solvent 30. 97 40. 24 32. 28 29. 99 43. 18 29. 59 33. 35 Total 100.00 100.00 100. 00 100.00 100.00 100. 00 100.00 78 322802 201142501 [ Table 8] Example 108 Example 109 Example 110 Example. 111 Example 112 Example 113 Example 114 Pigment dispersion PR PG PG PG PG PG PG 45. 60 38. 96 51. 29 47. 10 47. 78 31. 89 37.82 Acrylic resin solution 11. 77 20. 00 14.43 2. 54 3. 99 36.40 34. 56 Photopolymerization initiator (A) A5 A5 A5 A5 A5 A5 A5 1. 40 1.45 0. 17 0. 70 0 48 0. 28 0. 09 Other photopolymerization initiators (Y) Y2 Y5 Y2 Y1 Y2 0. 67 0. 11 0.43 0. 38 0. 21 Other photopolymerization initiators (Y) Y3 0.40 Sensitizers ( E) E2 0. 21 Photopolymerizable compound (C) 2. 28 1. 54 2. 56 2. 34 1.18 3. 34 1. 02 Polyfunctional thiol (F) F2 0. 30 Inhibitor (H) H1 H2 0. 01 0. 01 Organic solvent 38. 73 38. 05 30.88 47.21 45· 74 27. 70 26. 00 Total 100. 00 100.00 100.00 100. 00 100. 00 100. 00 100.00 79 322802 201142501 [Table 9] Example 115 Example 116 Example 117 Example 118 Example 119 Example 120 Example 121 Pigment dispersion PG PB PB PB PB PB P-BK 28.46 23. 13 42. 11 23 13 25.44 26. 98 42. 79 Acrylic resin solution 29. 51 29. 76 0. 00 26.41 5. 93 4.41 0. 00 Photopolymerization initiator (A) A5 A5 A5 A5 A5 A5 A5 0. 12 1. 08 2. 74 3. 31 0. 93 3.44 1.15 Other photopolymerization initiators (Y) Y2 Y3 Y1 Y1 Y4 0. 60 0. 05 0. 24 0. 61 1.41 Other photopolymerization initiators (Y) Y2 0. 17 Sensitizer (E) E1 E2 E1 1. 03 0. 15 0. 09 Photopolymerizable compound (C) 2. 03 4. 30 2. 93 6. 62 3. 12 4. 59 2. 40 UV absorber (G) G2 0. 10 Storage stabilizer (J) J1 J2 0. 03 0. 03 Organic solvent 39. 25 41. 68 51. 19 40. 14 63. 61 60. 55 52. 25 Total 100.00 100.00 100. 00 100. 00 100. 00 100. 00 100.00 80 322802 201142501 r [Table 10] Example 122 Example 123 Example 124 Comparative Example 101 Comparative Example 102 Pigment dispersion Ρ-ΒΚ Ρ-Β Ρ-ΒΚ PR PR 48. 14 40.73 45. 26 27. 64 27. 64 Acrylic resin solution 3. 55 1. 02 0. 00 40. 59 39. 58 Photopolymerization initiator (Α) Α5 Α5 Α5 Α5 1. 62 1. 44 0. 94 0. 50 Other photopolymerization initiator (Υ) Υ2 Υ5 Υ6 0. 40 0. 24 0. 50 sensitizer (Ε) Ε2 0.40 Photopolymerizable compound (C) 2.68 1. 60 1. 28 1. 65 Polyfunctional thiol (F) F2 F3 0. 74 0. 50 Organic solvent 43.21 54. 47 51. 78 29. 62 32. 28 Total 100.00 100.00 100.00 100.00 100. 00 Tables 7 to 10 Abbreviation, as described below. Photopolymerization initiator A5: a compound of the following formula (12) Formula (12) Λ

光聚合引發劑Υ1 : 2-曱基-1-[4-(〒硫基）苯基]-2-嗎 琳代基丙炫-1-酮 81 322802 201142501 (汽巴日本公司製“IRGACURE 907”） 光聚合引發劑Y2 : 2-(二曱基胺基）-2-[(4-曱基苯基） 曱基]-l-[4-(4-嗎啉基）苯基]-1-丁酮 (汽巴日本公司製“IRGACURE 379”） 光聚合引發劑Y3: 2, 4, 6-三曱基苯曱醯基-二苯基膦 氧化物 (BASF 公司製 “Lucirin ΤΡ0”） 光聚合引發劑Y4: 2, 2’-二（鄰氣苯基）-4, 5, 4’，5’-四 苯基-1，2’-聯咪唑 (黑金化成公司製“聯咪唑”） 光聚合引發劑Y5 :對二曱基胺基苯乙酮 (曰本DAIKI精細化學公司製“DMA”） 光聚合引發劑Y6:乙烷_1-酮，1_[9-乙基-6-(2-甲基 苯曱醯基）-9H-咔唑-3-基]，1-(0-乙醯肟） (汽巴日本公司製“IRGACUREOXE02”） 增感劑E1 : 2, 4-二乙基噻噸酮 (日本化藥公司製“Kayacure DETX-S”） 增感劑E2 : 4, 4’-二（二乙基胺基）二苯曱酮 (保土谷化學工業公司製“EAB-F”） 光聚合性化合物C ··二季戊四醇六丙烯酸酯 (東亞合成公司製“ARONIXM-402”） 多官能硫醇F1 :三羥曱基乙烷三（3-酼基丁酸酯） (昭和電工公司製“TEMB”） 多官能硫醇F2 :三羥曱基丙烷三（3-酼基丁酸酯） 82 322802 201142501 (昭和電工公司製“ΤΡΜΒ”） 多官能硫醇F3 :季戊四醇四（3-M基丙酸酯） (堺化學工業公司製“PEMP”） 紫外線吸收劑Gl : 2-[4-[(2-羥基-3-(十二烷基和十 二烧基）氧基丙基）氧基]-.2-經基苯基]-4, 6 -二（2, 4-二曱 基苯基）-1，3,5-三畊 (汽巴日本公司製“TINUVIN400”） 紫外線吸收劑G2 : 2_(2H-苯并三β坐_2_基）_4，6_二（1_ 甲基-1-苯基乙基）苯酚 (汽巴日本公司製“TINUVIN900”） 阻聚劑HI : Ν-亞硝基苯基羥基胺鋁鹽 (和光純藥工業公司製“Q-1301”） 阻聚劑Η2 :甲基氫醌 (精工化學公司製“ΜΗ”） 儲藏穩定劑J1 : 2, 6-二（1, 1-二甲基乙基）-4-曱基苯 酚 (本州化學工業公司製“BHT”） 儲藏穩定劑J2 :三苯基膦 (北興化學工業公司製“TPP”） 有機溶劑：環己酮 使用所得的感光性著色組合物，藉由以下方法形成濾 波器節和黑色矩陣的圖案，並如前所述，進行感度、直線 性評價、圖案形狀評價、解析度評價、耐顯影性評價、耐 藥品性評價、經時穩定性評價。結果示於表11至12。 83 322802 201142501 [濾波器節和黑色矩陣的圖案形成] 藉由旋塗法將所得的感光性著色組合物塗布在l〇cmx 10cm的玻璃基板上，然後在潔淨烘箱中在7〇〇c下加熱15 分鐘除去溶劑’得到約2em的塗膜。接著，將該基板冷卻 至室溫後，使用超高壓水銀燈，並經由1〇〇/ίΖΙΠ寬（間距為 200/zm)和25/zro寬（間距為5〇/zm)條紋圖案的光罩進行紫 外線曝光。然後，使用23°C的碳酸鈉水溶液對該基板進行 喷霧顯影，然後用離子交換水進行洗務，風乾，並在潔淨 丈共箱中在230 C下加熱30分鐘。對於各感光性著色組合物 的塗膜，以無顯影殘留並且能夠形成圖案的最短時間進行 喷霧顯影，並將該時間作為適當的顯影時間。 塗膜的膜厚，使用Dektak 3030(日本真空技術公司製） 進行測定。 [表 11: 實施例 101 實施例 102 實施例 103 實施例 104 實施例 105 實施例 106 實施例 107 實施例 108 實拖例 109 實施例 110 貧柢例 111 實施例 實施例 _ 感度 直線性 〇 〇 〇 0 〇 〇 〇 〇 〇 0 〇 _2_ 〇 〇 〇 〇 〇— 〇 〇 π 113 一 〇 图索形狀 〇 〇 〇 〇 〇 0 0 〇 〇 〇 〇 〇 〇 解析度 〇 〇 〇 〇 〇 〇 ◎ ◎ 〇 〇 〇 〇 〇 封顯彩性 0 〇 ◎ ◎ ◎ 〇 0 〇 〇 ◎ 〇 ◎ 耐藥品性 〇 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ ◎ 〇 蛆時穩定性 〇 〇 0 〇 0 0 〇 〇 0 〇 〇 〇 ◎ 0 322802 84 201142501 [表 12] 實施例 114 資施例 115 資铯例 116 實施例 117 貧施例 118 實施例 119 實施例 120 實拖例 121 實施例 122 實施例 123 實铯例 124 比較例 101 比較例 102 感度 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 △ 直線性 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 Λ ®索形狀 〇1 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 解析度 〇 〇 〇 〇 〇 ◎ 〇 〇 〇 〇 〇 △ 耐顯彩性 ◎ ◎ 〇 〇 〇 ◎ 〇 0 ◎ ◎ ◎ X 耐藥品性 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 ◎ A 經時穩定性 〇 ◎ 〇 〇 〇 〇 ◎ 〇 〇 〇 〇 〇 〇 如表11和12所示，使用實施例101至124的感光性 著色組合物所形成的濾波器節和黑色矩陣，其感度、直線 性和解析度良好，此外，將本專利申請案的通式（11)所表 示的光聚合引發劑（A)和其它的光聚合引發劑（γ)併用的實 把例 102 至 1〇7、110 至 116、118、119、121、122、124 ’ 顯示出在耐藥品性方面更優異的特性。其中，其它的光聚 合引發劑（Y)為2-(二曱基胺基）-2-[(4-甲基苯基）曱基] -l-[4- (4-嗎啉基）苯基]-卜丁酮的實施例ι〇3、丨〇4、u〇、 112 ' 114 ' 115、122 ’其耐顯影性也優異。 此外，進一步含有多官能硫醇（1?)的實施例丨〇5、114、 123、124 ’其耐顯影性優異。 此外，進一步含有紫外線吸收劑（(?）或阻聚劑（H)的實 施例107、108、Π3、119，其解析度優異。 此外，進一步含有儲藏穩定劑（J)的實施例115、120， 其經時穩定性優異4比較例1G1至1{)2般使用其它的將 酯系光聚合引發劑的情況或者不含光聚合性化合物⑹的 情況，在®案特性方面產生不良，無法得到全部特性都良 322802 85 201142501 好的結果。 接著，即使膜厚較厚，或者顏料含量較高，也心藉 由本發明的感光性著色組合物而得到優異特性的情況，分 別示於實施例201和202。 [實施例201](厚膜的情況） 使用和實施例101相同的感光性著色組合物，並藉由 旋塗法將其塗布在lGonxlG⑽的破縣板上，然後在潔淨 烘箱中在70°C下加# 15分鐘除去溶劑，得到約的塗 膜。接著，將該基板冷卻至室溫後，❹超高壓水銀燈， 並經由lOOym寬（間距為20〇em)和25ym寬（間距為 50 v m)條紋圖案的光罩進行紫外線曝光。然後，使用23。〇 的碳酸鈉水溶液對該基板進行噴霧顯影，然後用離子交換 水進行洗蘇，風乾，並在潔淨供箱中在230°C下加熱30分 鐘。對於各感光性著色組合物的塗膜，以無顯影殘留並且 能夠形成圖案的最短時間進行噴霧顯影，並將該時間作為 適當的顯影時間。 塗膜的膜厚’使用Dektak 3030(日本真空技術公司製） 進行測定。 如前所述進行各評價的結果為，感度：〇、直線性評 價：〇、圖案形狀評價：〇、解析度評價：〇、耐顯影性 評價：〇、耐藥品性評價：〇、經時穩定性評價：q。 [實施例202](提高顏料含有率的情況） 除了將實施例101的感光性著色組合物的顏料分散 從41.92變為60.23，以及將丙烯酸系樹脂溶夜從 ^ 斗* 85 322802 86 201142501 變為6. 54外，和實施例ιοί同樣，藉由旋塗法將其塗布在 lOcmxlOcm的玻璃基板上，然後在潔淨烘箱中在7〇。匸下加 熱15分鐘除去溶劑，得到約2am的塗膜。接著，將該基 板冷卻至室溫後，使用超高壓水銀燈，並經由1〇〇//m寬（間 距為200 /ζιη)和25/ζιη寬（間距為50//m)條紋圖案的光罩進 行紫外線曝光。然後，使用23°C的碳酸鈉水溶液對該基板 進行喷霧顯影，然後用離子交換水進行洗滌，風乾，並在 潔淨烘箱中在23(TC下加熱30分鐘。對於各感光性著色組 合物的塗膜，以無顯影殘留並且能夠形成圖案的最短時間 進行喷霧顯影，並將該時間作為適當的顯影時間。 塗膜的膜厚，使用Dektak 3030(日本真空技術公司製） 進行測定。 如前所述進行各評價的結果為，感度：〇、直線性評 饧.〇、圖案形狀評價：〇、解析度評價：〇、耐顯影性 評價：〇、耐藥品性評價：〇、經時穩定性評價：〇。 接著’表示濾色器的製作例。 [濾色器的製作] 和實施例101同樣地，藉由旋塗法將實施例1〇1的紅 色感光性著色組合物塗布在1〇cmxl〇cni的玻璃基板上，然 後在春淨烘箱中在7(TC下加熱15分鐘除去溶劑，得到約 2/zm的塗膜。接著，將該基板冷卻至室溫後，使用超高壓 水銀燈’並經由1〇〇以m寬（間距為2〇〇 # m)和25 v m寬（間 距為50以m)條紋圖案的光罩進行紫外線曝光。然後，使用 23°C的碳酸鈉水溶液對該基板進行喷霧顯影，然後用離子 87 322802 201142501 交換水進行洗條，風乾，並在潔淨烘箱中在230°C下加熱 30分鐘，得到紅色濾波器節。接著，藉由同樣的操作，使 用實施例109的綠色感光性著色組合物，在紅色濾波器節 旁邊形成綠色遽波器節，製作具有2色遽波器節的遽色器。 結果可以得到一種耐光性、耐熱性優異，並且即使膜 厚較厚或者顏料含有率高，顏色再現特性也提高的高品質 滤色器。 【圖式簡單說明】 無。 【主要元件符號說明】 無。 88 322802Photopolymerization initiator Υ1 : 2-mercapto-1-[4-(indolyl)phenyl]-2-morphinylpropan-1-one 81 322802 201142501 ("GAGACURE 907" manufactured by Ciba Japan Co., Ltd." ) Photopolymerization initiator Y2 : 2-(didecylamino)-2-[(4-mercaptophenyl)indolyl]-l-[4-(4-morpholinyl)phenyl]-1- Butanone ("IRGACURE 379", manufactured by Ciba Japan Co., Ltd.)) Photopolymerization initiator Y3: 2,4,6-trimercaptobenzoyl-diphenylphosphine oxide ("Lucirin ΤΡ0", manufactured by BASF Corporation) Photopolymerization Initiator Y4: 2, 2'-di(o-phenyl)-4, 5, 4', 5'-tetraphenyl-1,2'-biimidazole ("Biimidazole" manufactured by Heijin Chemical Co., Ltd.) Photopolymerization Initiator Y5: p-Dimethylamino acetophenone ("DMA" by DAIKI Fine Chemical Co., Ltd.) Photopolymerization initiator Y6: ethane-1-ketone, 1-[9-ethyl-6-(2- Methyl phenyl hydrazino)-9H-carbazol-3-yl], 1-(0-acetamidine) ("IRGACUREOXE02" manufactured by Ciba Japan Co., Ltd.) Sensitizer E1 : 2, 4-diethyl thiophene Tons of Ketone (Kayacure DETX-S, manufactured by Nippon Kayaku Co., Ltd.) Sensitizer E2: 4, 4'-bis(diethylamino)benzophenone (EAB-F, manufactured by Hodogaya Chemical Industry Co., Ltd.) ) Photopolymerizable compound C · Dipentaerythritol hexaacrylate ("ARONIXM-402", manufactured by Toagosei Co., Ltd.) Polyfunctional thiol F1: Trihydroxy decyl ethane tris(3-mercaptobutyrate) (Showa Denko Co., Ltd.) "TEMB") Polyfunctional thiol F2: Trihydroxy hydroxypropane tris(3-mercaptobutyrate) 82 322802 201142501 ("Show" made by Showa Denko) Polyfunctional thiol F3: Pentaerythritol IV (3-M Propionate) ("PEMP" manufactured by Seiko Chemical Industry Co., Ltd.) UV absorber Gl: 2-[4-[(2-hydroxy-3-(dodecyl and dodecyl)oxypropyl)oxy) Base]-.2-Phenylphenyl]-4,6-bis(2,4-dimercaptophenyl)-1,3,5-three-plowing ("CONUVIN400" manufactured by Ciba Japan Co., Ltd.) UV absorber G2 : 2_(2H-benzotriazine β_2_yl)_4,6_bis(1_methyl-1-phenylethyl)phenol ("TINUVIN900" manufactured by Ciba Japan Co., Ltd.) Inhibitor HI : Ν -Nitrosophenylhydroxylamine aluminum salt ("Q-1301" manufactured by Wako Pure Chemical Industries, Ltd.) Inhibitor Η2: Methylhydroquinone ("ΜΗ" manufactured by Seiko Chemical Co., Ltd.) Storage Stabilizer J1 : 2, 6- Bis(1,1-dimethylethyl)-4-nonylphenol ("BHT" manufactured by Honshu Chemical Industry Co., Ltd.) Storage Stabilizer J2: Triphenylphosphine ("TPP" manufactured by Kitagawa Chemical Co., Ltd.) Organic solvent: A photosensitive coloring composition obtained by using cyclohexanone, and formed by the following method As described above, the pattern of the knot and the black matrix was evaluated for sensitivity, linearity, pattern shape evaluation, resolution evaluation, development resistance evaluation, chemical resistance evaluation, and stability over time. The results are shown in Tables 11 to 12. 83 322802 201142501 [Pattern formation of filter section and black matrix] The obtained photosensitive coloring composition was applied onto a 10 cmx10 cm glass substrate by spin coating, and then heated in a clean oven at 7 °c. The solvent was removed in 15 minutes to obtain a coating film of about 2 cm. Then, after cooling the substrate to room temperature, an ultrahigh pressure mercury lamp was used, and the mask was spread through a stripe pattern of 1 〇〇/ίΖΙΠ width (200/zm pitch) and 25/zro width (5 Å/zm pitch). UV exposure. Then, the substrate was spray-developed using a 23 ° C aqueous solution of sodium carbonate, then washed with ion-exchanged water, air-dried, and heated in a clean room at 230 C for 30 minutes. For the coating film of each photosensitive coloring composition, spray development was carried out in the shortest time without development residue and patterning, and this time was taken as an appropriate development time. The film thickness of the coating film was measured using Dektak 3030 (manufactured by Nippon Vacuum Technology Co., Ltd.). [Table 11: Example 101 Example 102 Example 103 Example 104 Example 105 Example 106 Example 107 Example 108 Example 1 Example 110 Example Example _ Sense linearity 〇〇〇 0 〇〇〇〇〇0 〇_2_ 〇〇〇〇〇— 〇〇π 113 One-dimensional graph shape 〇〇〇〇〇0 0 〇〇〇〇〇〇resolution 〇〇〇〇〇〇◎ ◎ 〇〇 〇〇〇 显 显 ◎ ◎ ◎ 〇 0 〇〇 ◎ 〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇蛆 〇〇 stability 〇〇 0 〇 0 0 〇〇 0 〇〇〇 ◎ 0 322802 84 201142501 [Table 12] Example 114 Capital Example 115 Capital Example 116 Example 117 Lean Example 118 Example 119 Example 120 Real Example 121 Example 122 Example 123 Example 124 Comparative Example 101 Comparative Example 102 Sensitivity 〇〇〇〇〇〇〇〇〇〇〇 △ Linearity 索 ® Cable Shape 〇 1 〇〇〇〇〇〇〇〇〇〇 Resolution 〇〇〇〇〇 ◎ 〇〇〇〇〇 △ Resistance to chromaticity ◎ ◎ 〇〇〇 ◎ 〇 0 ◎ ◎ ◎ X Chemical resistance ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 ◎ A Stability over time 〇 ◎ 〇〇〇〇 ◎ As shown in Tables 11 and 12, the filter sections and black matrix formed using the photosensitive coloring compositions of Examples 101 to 124 have sensitivity, linearity, and resolution. In addition, the photopolymerization initiator (A) represented by the general formula (11) of the present patent application and the other photopolymerization initiator (γ) are used in combination with Examples 102 to 1 to 7, 110 to 116, 118, 119, 121, 122, and 124' show superior characteristics in terms of chemical resistance. Among them, the other photopolymerization initiator (Y) is 2-(didecylamino)-2-[(4-methylphenyl)indenyl]-l-[4-(4-morpholinyl)benzene Examples of the oxime ketones ι〇3, 丨〇4, u〇, 112 '114 '115, 122' were also excellent in developability. Further, Examples 丨〇5, 114, 123, and 124' further containing a polyfunctional thiol (1?) are excellent in developability. Further, Examples 107, 108, and Π3, 119 further containing an ultraviolet absorber ((?) or a polymerization inhibitor (H), which are excellent in resolution. Further, Examples 115 and 120 further containing a storage stabilizer (J) In the case of using an ester-based photopolymerization initiator or a photopolymerizable compound (6) in the same manner as in the case of Comparative Example 1G1 to 1{)2, the product characteristics are poor and cannot be obtained. All features are good 322802 85 201142501 Good results. Next, even if the film thickness is thick or the pigment content is high, the case where excellent characteristics are obtained by the photosensitive coloring composition of the present invention is shown in Examples 201 and 202, respectively. [Example 201] (Case of thick film) The same photosensitive coloring composition as in Example 101 was used, and it was coated on a plate of lGonxlG (10) by spin coating, and then at 70 ° C in a clean oven. The solvent was removed by adding #15 minutes to obtain an approximate coating film. Next, after cooling the substrate to room temperature, an ultrahigh pressure mercury lamp was irradiated and exposed to ultraviolet light through a mask having a width of 100 μm (20 μm pitch) and a width of 25 μm (pitch of 50 μm). Then, use 23. The substrate was spray-developed with a sodium carbonate aqueous solution, then washed with ion-exchanged water, air-dried, and heated at 230 ° C for 30 minutes in a clean supply tank. For the coating film of each photosensitive coloring composition, spray development was carried out in the shortest time without development residue and patterning, and this time was taken as an appropriate development time. The film thickness of the coating film was measured using Dektak 3030 (manufactured by Nippon Vacuum Technology Co., Ltd.). As a result of the evaluation as described above, the sensitivity was: 〇, linear evaluation: 〇, pattern shape evaluation: 〇, resolution evaluation: 〇, development resistance evaluation: 〇, chemical resistance evaluation: 〇, stable over time Sex evaluation: q. [Example 202] (When the pigment content was increased) The pigment dispersion of the photosensitive coloring composition of Example 101 was changed from 41.92 to 60.23, and the nighttime of the acrylic resin was changed from ^*3 322802 86 201142501 6.54, as in the case of Example ι, it was coated on a glass substrate of 10 cm x 10 cm by spin coating, and then at 7 Torr in a clean oven. The solvent was removed by heating under a roll for 15 minutes to obtain a coating film of about 2 am. Next, after cooling the substrate to room temperature, an ultra-high pressure mercury lamp was used, and a mask having a stripe pattern of 1 〇〇//m width (200 Å/m) and 25/ζηη width (50//m pitch) was used. UV exposure. Then, the substrate was spray-developed using a 23 ° C aqueous sodium carbonate solution, then washed with ion-exchanged water, air-dried, and heated in a clean oven at 23 (TC for 30 minutes. For each photosensitive coloring composition) The coating film was spray-developed in the shortest time without development residue and patterning, and this time was taken as an appropriate development time. The film thickness of the coating film was measured using Dektak 3030 (manufactured by Nippon Vacuum Technology Co., Ltd.). The results of the evaluations were as follows: sensitivity: 〇, linear evaluation 〇, pattern shape evaluation: 〇, resolution evaluation: 〇, development resistance evaluation: 〇, chemical resistance evaluation: 〇, stability over time Evaluation: 〇. Next, a production example of a color filter is shown. [Production of Color Filter] In the same manner as in Example 101, the red photosensitive coloring composition of Example 1〇1 was applied to 1 藉 by spin coating. On a glass substrate of cmxl〇cni, the solvent was removed by heating at 7 (TC for 15 minutes) in a spring cleaning oven to obtain a coating film of about 2/zm. Then, after cooling the substrate to room temperature, an ultrahigh pressure mercury lamp was used. And UV exposure was carried out through a mask having a stripe pattern of m width (2 Å #m) and 25 volt width (50 Å pitch). Then, the substrate was treated with a 23 ° C aqueous solution of sodium carbonate. Spray development was carried out, and then the strip was washed with ion 87 802802 201142501, air-dried, and heated in a clean oven at 230 ° C for 30 minutes to obtain a red filter section. Then, using the same operation, the example was used. A green photosensitive coloring composition of 109, a green chopper section is formed beside the red filter section, and a color cleaner having a two-color chopper section is produced. As a result, an excellent light resistance and heat resistance can be obtained, and even a film thickness is obtained. High-quality color filter with thicker or high pigment content and improved color reproduction characteristics. [Simplified illustration] None. [Main component symbol description] None. 88 322802

Claims (1)

201142501 七、申請專利範圍： ’其特徵在於：含有下述通式（1) 弓丨發劑（A)、樹脂（B)、光聚合性 1. 一種感光性著色組合物 或（11)所表示的光聚合 化合物（C)和顏料（D)，201142501 VII. Patent application scope: 'It is characterized by containing the following general formula (1) Bow hair styling agent (A), resin (B), photopolymerization 1. A photosensitive coloring composition or (11) Photopolymerizable compound (C) and pigment (D), 此處，式（1)中，Rl表示取代或未取代的烯基 (alkenyl)、取代或未取代的烷基、取代或未取代的烷 氧基、取代或未取代的芳基、取代或未取代的芳氧基、 取代或未取代的雜環基、取代或未取代的雜環氧基、取 代或未取代的烧基硫基（aikyisuifanyi)、取代或未取 代的芳基硫基（8巧13111{&amp;1^1)、取代或未取代的烷基亞 確醯基、取代或未取代的芳基亞磺醯基、取代或未取代 的烷基磺醞基、取代或未取代的芳基磺醯基、取代或未 取代的醯基、取代或未取代的醯氧基、取代或未取代的 胺基、取代或未取代的膦基（phosphinoyl)、取代或未 取代的胺基曱醯基（carbamoyl)、或取代或未取代的胺 石黃醢基（sulfamoyl)， R2表示取代或未取代的稀基、取代或未取代的燒 1 322802 201142501 基、取代或未取代的烧氧基、取代或未取代的芳基、取 代或未取代的m取代或未取代_縣、ς代或 未取代雜環氧基、取代或未取代的錄硫基、取代或 未取代的芳基硫基、取代或未取代的絲亞伽基、取 代或未取代的芳基亞賴基、取代或未取代的貌基續酿 基、取代或未取代的芳基磺醯基、取代或未取代的醯氧 基、或取代或未取代的胺基， R3至Rs各自獨立地表示氫原子、鹵原子、氰基、硝 基、取代或未取代的烯基、取代或未取代的烷基、取代 或未取代的烧氧基、取代或未取代的芳基、取代或未取 代的芳氧基、取代或未取代的雜環基、取代或未取代的 雜環氧基、取代或未取代的烷基硫基、取代或未取代的 芳基硫基、取代或未取代的醯基、或取代或未取代的胺 基， R6至R9各自獨立地表示氫原子、鹵原子、氰基、鹵 代烷基（haloalkyl)、取代或未取代的烷基、取代或未 取代的烷氧基、取代或未取代的芳基、取代或未取代的 芳氧基、取代或未取代的雜環基、取代或未取代的雜環 氧基、取代或未取代的烯基、取代或未取代的烷基硫 基、取代或未取代的芳基硫基、取代或未取代的烧基亞 磺醯基、取代或未取代的芳基亞磺醯基、取代或未取代 的烷基磺醯基、取代或未取代的芳基磺醯基、取代或未 取代的胺基、或下述通式（2)的取代基’ 通式（2) 2 322802 201142501 ?2. —C—C=N—〇— Ο ο C-Ri &gt; 式（2)中，Ri.和R2’與Ri和R2同義， Ri〇至Ru各自獨立地表示氫原子、鹵原子、氣久 石肖基、齒代燒基、取代或未取代的烧基亞項酿笑、取代 或未取代的芳基亞橫醯基、取代或未取代的燒基#自 基、取代或未取代的芳基續醯基、或取代或未取代的酉篮 基，但是匕〇至Rm不全部同時為氫原子，此外，Ri。 Rh的至少一個為硝基或下述通式（3)， 通式（3)Here, in the formula (1), R1 represents a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or not Substituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group (aikyisuifanyi), substituted or unsubstituted arylthio group 13111{&amp;1^1), substituted or unsubstituted alkylarylene, substituted or unsubstituted arylsulfinylene, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted aromatic A sulfonyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted oxiranyl group, a substituted or unsubstituted amine group, a substituted or unsubstituted phosphinoyl group, a substituted or unsubstituted amine group 曱醯Carbamoyl, or a substituted or unsubstituted sulfamoyl group, R2 represents a substituted or unsubstituted dilute, substituted or unsubstituted burnt 1 322802 201142501 base, substituted or unsubstituted alkoxy group, substituted or Unsubstituted aryl, substituted or unsubstituted m substituted or unsubstituted _ county, ς Alken or unsubstituted heterocyclic oxy, substituted or unsubstituted thiol, substituted or unsubstituted arylthio, substituted or unsubstituted selylene, substituted or unsubstituted aryl ylene, substituted Or an unsubstituted aryl group, a substituted or unsubstituted arylsulfonyl group, a substituted or unsubstituted decyloxy group, or a substituted or unsubstituted amine group, and R3 to Rs each independently represent a hydrogen atom or a halogen Atom, cyano, nitro, substituted or unsubstituted alkenyl, substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted fluorenyl group, or a substituted or Unsubstituted amino group, R6 to R9 each independently represent a hydrogen atom, a halogen atom, a cyano group, a haloalkyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted group. Aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted Heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkenyl group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted alkyl group Sulfhydryl, substituted or unsubstituted arylsulfinylene, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted arylsulfonyl, substituted or unsubstituted amine, or Substituent of formula (2) Formula (2) 2 322802 201142501 ?2. —C—C=N—〇— Ο ο C-Ri &gt; In formula (2), Ri. and R2' and Ri and R2 Synonymous, Ri〇 to Ru each independently represent a hydrogen atom, a halogen atom, a sulphate, a dentate group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryl ylidene group, The substituted or unsubstituted alkyl group is a radical, a substituted or unsubstituted aryl group, or a substituted or unsubstituted sulfhydryl group, but the oxime to Rm are not all hydrogen atoms at the same time, and further, Ri. At least one of Rh is a nitro group or a general formula (3) of the following formula (3) 式（3)中，R1S至Rig各自獨立地表示氫原子、鹵原 子、氰基、硝基、鹵代烷基、取代或未取代的烷基、取 代或未取代的烧氧基、取代或未取代的芳基、取代或未 取代的芳氧基、取代或未取代的雜環基、取代或未取代 的雜環氧基、取代或未取代的烯基、取代或未取代的烷 基硫基、取代或未取代的芳基硫基、取代或未取代的醯 基、或取代或未取代的胺基， 通式（11) 322802 3 201142501In the formula (3), R1S to Rig each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, a halogenated alkyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted group. Aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkenyl group, substituted or unsubstituted alkylthio group, substituted Or an unsubstituted arylthio group, a substituted or unsubstituted fluorenyl group, or a substituted or unsubstituted amine group, the formula (11) 322802 3 201142501 通式（11)中，RS1表示取代或未取代的烯基、取代 或未取代的烷基、取代或未取代的烷氧基、取代或未取 代的芳基、取代或未取代的芳氧基、取代或未取代的雜 %基、取代或未取代的雜環氧基、取代或未取代的烷基 硫基、取代或未取代的芳基硫基、取代或未取代的烧基 亞磺醯基、取代或未取代的芳基亞磺醢基、取代或未取 代的烷基磺醯基、取代或未取代的芳基磺醯基、取代或 未取代的醯基、取代或未取代的醯氧基、取代或未取代 的胺基、取代或未取代的膦基、取代或未取代的胺基曱 醯基、或取代或未取代的胺磺醯基， R52表示被環烷基取代的碳數為i至2〇的烷基， R53至R55各自獨立地表示氫原子、鹵原子、氰基、 硝基、取代或未取代的烯基、取代或未取代的烷基、取 代或未取代的烧氧基、取代或未取代的芳基、取代或未 取代的芳氧基、取代或未取代的雜環基、取代或未取代 的雜環氧基、取代或未取代的烷基硫基、取代或未取代 的芳基硫基、取代或未取代的醯基、或取代或未取代的 胺基， 322802 4 201142501 R56至R58各自獨立地表示氫原子、鹵原子、氰基、 硝基、齒代烷基、取代或未取代的烷基亞磺醯基、取代 或未取代的芳基亞讀醢基、取代或未取代的烧基續酿 基、取代或未取代的芳基磺醯基、或取代或未取代的醯 基， R59至R63各自獨立地表示氫原子、鹵原子、氰基、 硝基、鹵代烷基、取代或未取代的烷基、取代或未取代 的烷氧基、取代或未取代的芳基、取代或未取代的芳氧 基、取代或未取代的雜環基、取代或未取代的雜環氧 基、取代或未取代的烯基、取代或未取代的烷基硫基、 取代或未取代的方基硫基、取代或未取代的酿基、或取 代或未取代的胺基， R64表示氫原子、鹵原子、氰基、硝基、取代或未 取代的烯基、取代或未取代的烷基、取代或未取代的烷 氧基、取代或未取代的芳基、取代或未取代的芳氧基、 取代或未取代的雜環基、取代或未取代的雜環氧基、取 代或未取代的烷基硫基、取代或未取代的芳基硫基、取 代或未取代的醯基、或取代或未取代的胺基。 2. 如申請專利範圍第1項所述的感光性著色組合物，其 中’進一步含有其它的光聚合引發劑（γ)。 3. 如申請專利範圍第2項所述的感光性著色組合物，其 中，其它的光聚合引發劑（Y)包含選自笨乙鋼系化合 物、膦系化合物和咪唑系化合物所構成群組中的至少一 種以上的化合物。 322802 5 201142501 4. 如申請專利範圍第1項至第3項中任一項所述的感光性 -著色組合物，其中，進一步含有多官能硫醇（F)。 5. —種渡色器（color filter)，其特徵在於：在透明基板 上具有由申請專利範圍第1項至第4項中任一項所述的 感光性著色組合物所形成的選自濾波器節（fi iter segment)和黑色矩陣（black matrix)中的至少一種。 6 322802 201142501 四、指定代表圖：本案無圖式。 . (一)本案指定代表圖為：第（ ）圖。 (二)本代表圖之元件符號簡單說明：In the formula (11), RS1 represents a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group. , substituted or unsubstituted hetero-, substituted or unsubstituted heterocyclic oxy, substituted or unsubstituted alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted alkylsulfin Alkyl, substituted or unsubstituted arylsulfinyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted arylsulfonyl, substituted or unsubstituted fluorenyl, substituted or unsubstituted anthracene An oxy group, a substituted or unsubstituted amino group, a substituted or unsubstituted phosphino group, a substituted or unsubstituted amino fluorenyl group, or a substituted or unsubstituted amine sulfonyl group, and R52 represents a carbon substituted by a cycloalkyl group. The alkyl group is i to 2 Å, and R53 to R55 each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted group. Alkoxylated, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or not Substituted heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted fluorenyl group, or substituted or unsubstituted Amine, 322802 4 201142501 R56 to R58 each independently represent a hydrogen atom, a halogen atom, a cyano group, a nitro group, a dentate alkyl group, a substituted or unsubstituted alkylsulfinyl group, a substituted or unsubstituted aryl group. Reading an fluorenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted fluorenyl group, each of R59 to R63 independently represents a hydrogen atom, a halogen atom, or a cyano group. , nitro, haloalkyl, substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted heterocyclic, a substituted or unsubstituted heterocyclic oxy group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted Substituted amine group, R64 represents a hydrogen atom, a halogen atom, a cyanogen , nitro, substituted or unsubstituted alkenyl, substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted Heterocyclic group, substituted or unsubstituted heterocyclic oxy group, substituted or unsubstituted alkylthio group, substituted or unsubstituted arylthio group, substituted or unsubstituted fluorenyl group, or substituted or unsubstituted amine base. 2. The photosensitive coloring composition according to claim 1, wherein the photopolymerization initiator (γ) is further contained. 3. The photosensitive coloring composition according to claim 2, wherein the other photopolymerization initiator (Y) comprises a group selected from the group consisting of a stupid ethylene compound, a phosphine compound, and an imidazole compound. At least one or more compounds. The photosensitive-coloring composition according to any one of the items 1 to 3, further comprising a polyfunctional thiol (F). 5. A color filter comprising a photosensitive coloring composition according to any one of claims 1 to 4 on a transparent substrate, selected from the group consisting of a filter. At least one of a fi iter segment and a black matrix. 6 322802 201142501 IV. Designated representative map: There is no schema in this case. (1) The representative representative of the case is: ( ). (2) A brief description of the symbol of the representative figure: 3 3228023 322802
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KR20110102846A (en) 2011-09-19

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