TW201132558A - Deoxidizing agent - Google Patents

Deoxidizing agent Download PDF

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Publication number
TW201132558A
TW201132558A TW99109799A TW99109799A TW201132558A TW 201132558 A TW201132558 A TW 201132558A TW 99109799 A TW99109799 A TW 99109799A TW 99109799 A TW99109799 A TW 99109799A TW 201132558 A TW201132558 A TW 201132558A
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Taiwan
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container
hydrogen
rate
control
hydrogen molecule
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TW99109799A
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Chinese (zh)
Inventor
Adrian Carmichael
Andrew Stuart Overend
Mark Rule
Ronald James Valus
Christine Leeming
Steven Burgess Tattum
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Colormatrix Holdings Inc
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Priority to TW99109799A priority Critical patent/TW201132558A/en
Publication of TW201132558A publication Critical patent/TW201132558A/en

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Abstract

The present invention provides a deoxidizing device and a container containing deoxidizing device. The container has a sealing device. The sealing device includes a body comprising a threaded section for connection with a fixed sealing container device, for example, connection with a bottle opening. The interior of threaded section is an inner lining design and includes a hydrogen molecule generator device, in which the inner lining includes a material layer integrated with hydride, which is diffusion mixed with a polymer matrix component. Another side of this material layer is a PET material layer. The material layer can be used as a control layer for controlling the permeation rate of steam from a soft drink in the container and permeated through the hydride-containing material layer, and the formation of hydrogen molecules can be controlled through the hydrogen-molecule generator device. Thus, when in use, steam passes through the material layer, and the material layer is used to contact hydrogen molecules. The hydrogen molecules formed then mix with oxygen molecules, and the resulting mixture enters the container equipped with the sealing device. Subsequently, a reaction between hydrogen molecules and oxygen molecules takes place, and the catalyst performs a catalytic action in the container for performing oxygen-stripping function.

Description

201132558 •六、發明說明： 【發明所屬之技術領域】 本發明係涉及一種脫氧作用，特別是指並非只限於食 物或飲料容器所專用的脫氧功能之劊新設計者。 【先前技術】 按，聚合物如聚合對苯二甲酸乙二醇酯（pET)為廣泛用 於纖維、薄膜和三維結構的材料應用上。聚合物特別重要 的應用就是用於容器上，尤其是食品和飲料用的容器。此 應用在過去20年來大幅成長，而越來越受到歡迎。儘管有 其應用上的成長，聚合物本身有些根本性的限制，而限制 其適用性。其中—個限制是所有聚合物有一定程度上的氧 乳渗透率。&氧氣滲透率可讓氧氣渗透進am容器内， 為本發明的重要特性，女 3 / 尤其疋食物和飲料用的容ϋ會因為 透現而產生降解作用。因為此功能，所謂的滲 …藉由個別聚合物鏈的移動，而渗透穿越過 物質，此現象不同於滲漏，滲漏現象為 大型和小型孔洞上的物質轉移現象。 構上的 ^ 了食物和飫料外，其他產品也會受到氧氣的影麼， :括藥劑和許多的化學物質，甚至是電子產 ‘ =氧氣敏感性的產品，品牌廢商-般常使用 屬匕裝。最近，品牌廠商已開始使用塑料 / 材塑料質混有被動性的氧化防護劑或脫氧劑。一'般^ 疋採用脫氧劑’但過去的脫氧材料則有許 m 3 201132558 多應用上的問題，尤其是脫氧劑目前在氧化固態材質包裝 的應用上。應用的科技包括鐵的氧化（無論是袋裝或容器 側壁上的整合材質應用）、氧化亞硫酸氫鈉的氧化和易氧 化性的聚合物，特別是聚（丁二烯）或間苯二f胺已二胺 )°所有的相關應用科技，在容器裝填時，則有脫氧作用 速率緩慢和不足的問題，造成容器側壁上形成霧狀，或包 裝材質的褪色問題。這些問題則限制脫氧劑的用途，尤其 疋透明塑料包裝材質（如PET) ’或重要的可回收材質應用 上。 專利編號W02008/090354A1則揭露一種容器，此容器使用 有特殊材質，可跟容器中的水份反應，而釋出氫分子。但 所使用的活性物質可快速跟水份反應，或生成具有保護性 的氧化塗層物質❶為解決此問題，WO2008/090354A1编號的發 明’則讓活性物質混合有聚合基質成份，可用於控制緩慢 的氫分子釋出速率。但此方译的限制，就是在三個月的期 間中’會明顯降低氫分子的生成速率。因此，為能夠持續 有效的脫氧作用，此系統的設計，需讓氫分子的生成速率 不得明顯低於氧分子的滲透速率。此功能可藉由讓氫分子 的生成速率遠高於氧分子早期儲存壽命中，所需的脫氧速 率來控制。201132558 • VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a deoxidation effect, and more particularly to a brand new designer that is not limited to the deoxidation function dedicated to food or beverage containers. [Prior Art] Polymers such as polymeric ethylene terephthalate (pET) are widely used in materials for fibers, films and three-dimensional structures. A particularly important application of polymers is in containers, especially for food and beverages. This application has grown tremendously over the past 20 years and is becoming more and more popular. Despite its application growth, the polymer itself has some fundamental limitations that limit its applicability. One of the limitations is that all polymers have a certain degree of oxidative permeability. & Oxygen Permeability allows oxygen to penetrate into the am container. This is an important feature of the invention, and the bulk of the food and beverages can be degraded by the presence of the product. Because of this function, the so-called osmosis ... penetrates through the material by the movement of individual polymer chains, which is different from leakage, which is a phenomenon of mass transfer on large and small pores. In addition to the food and the ingredients, other products will also be affected by oxygen, including: chemicals and many chemical substances, even electronic products '= oxygen sensitive products, brand waste business - commonly used Armored. Recently, brand manufacturers have begun to use plastic/plastic materials mixed with passive oxidative protectants or deoxidizers. A 'deoxygenizer' is used in the past, but in the past, deoxidizing materials have been used. m 3 201132558 Multiple application problems, especially the deoxidizer is currently used in oxidized solid material packaging applications. Applied technologies include the oxidation of iron (whether in the case of bags or integrated materials on the side walls of containers), the oxidation of oxidized sodium bisulfite and the oxidizable polymers, especially poly(butadiene) or meta-phenylene f Amine diamine) All related application techniques, when the container is filled, there is a problem of slow and insufficient deoxidation rate, resulting in fogging on the side wall of the container, or fading of the packaging material. These problems limit the use of deoxidizers, especially in clear plastic packaging materials (such as PET) or important recyclable materials. Patent No. WO2008/090354A1 discloses a container which is made of a special material which reacts with moisture in the container to release hydrogen molecules. However, the active substance used can react rapidly with water or form a protective oxidizing coating substance. To solve this problem, the invention numbered WO2008/090354A1 allows the active substance to be mixed with a polymeric matrix component, which can be used for control. Slow hydrogen molecule release rate. However, the limitation of this translation is that during the three-month period, the rate of hydrogen molecule formation is significantly reduced. Therefore, in order to be able to continue effective deoxygenation, the system is designed so that the rate of formation of hydrogen molecules is not significantly lower than the rate of penetration of oxygen molecules. This function can be controlled by allowing the rate of hydrogen molecule formation to be much higher than the rate of deoxygenation required for the early storage life of the oxygen molecule.

此外’可能難以讓基質成份和活性物質充份混合，因 此’氫分子釋出速率可能因為混合劑物質批次的不同而有 差異。在某些情況下，則難以提供儲存壽命所需的釋出迷 率’即提供容器所需特定的基質成份/活性物質的混合比 ，如使用密閉設計的容器。在此情況下，需使用含大量的U 4 201132558 .活性物質的氫分子生成基質成份 酋古·击㈣/、 ‘ 、妁仰虱刀子生成活性物. 質间達5(U)，而在此情況下，氯分子釋出速率則過高。 疋以，針對上述習知上所存在之問題點，如 一種能夠更具理想實用性之 出 加以田』祈構以實有待相關業界 加以心宗大破之目標及方向者。 灯 有鑑於此，發明人本於多 _ 夕平從事相關產品之製造開發 與没§十經驗，斜射上祝〔夕a j 外對上述之目標，詳加設計與 終得一確具實用性之本發明。 滇砰估後， 【發明内容】 本發明之主要目的，係在提供一種脫氧 氧裝置之容器，依據本發 、置及具有脫 脫氧裝置之容器則含下列裝置： 斤耠供的具有 含一種氫分子促生裝置’， 置 此裝置含活性物質， 份反應生成氫分子。 可跟水 此控制裝置可用於水、 ^ ^ ^ 伤，參透率的控制，可藉由氫分子 促生裝置在無上述控制裝 飞刀子 ，而降低氳分子的生成詈. 订比車乂刀析 制虱分子促生裝置的水份 了控 少·^平，蒼亏由氫分子你 的功能來控制穿透速率 1 生裝置 ’也跟活性物質有關。 土身凤r刀符性 相較於上述反應逮率， W 5，, 了藉由耠供兩個相同容器裝 置而輕易達成，但這兩個容 展 ^ ^ v 器則如上述内容，含一個控制 裝置，而另-個容器則不含控制裝置。 201132558 、若上述控制裝置則藉由氫分子生成裝置，而提供有氫 分子生成速率的控制功能，可調整特定時間下的氩分子生 成速率卩了藉此決定容器館存壽命的性能。例如，為能 夠提供更長的儲存壽命，在相同的基質成份量中，則需有 更大置的活J·生物質，藉由水份對氫分子促生裝置的渗透率 進灯調控制。相反的，在無控制裝置的情況下，更大量的 活性物質’則造成更快的氫分子生成速率，消耗速率快而 降低容器的儲存壽命。 上述控制裝置最好設計有第一個反應速率，此第一個 反應速率定義為： 最初5日期間容器的氫分子反應速率/在最初5曰期 間後’第2段5曰期間到85曰期間中，容器的氫分子反應 速率； 上述反應速率應在4、3或最好是在2下。此反應速 率應在0.5 、0_ 8或最好是在1以上。 上述選定的5日期間應在整體期間的45日、3〇日、15 曰、10日或5日的容器充填期間内，如裝飲料的容器。 上述控制裝置應提供有第二個反應速率，其中的第二 個反應速率定義為： 最初5日期間容器的氫分子反應速率/在最初5日期 間後，第2段5日期到180日期間中，容器的氫分子反應 速率； ^ 上述反應速率應在4、3或最好是在2以下。此反應 迷率應在0· 5 、 0.8或最好是在1以上。 上述控制裝置應提供有第三個反應迷率，其 、〒的弟了 6 201132558 個反應速率定義為： 最初5日期間容器的氣分子反應速率/在最初5曰期 間後’第2段5曰期到27〇曰期間中，容器的氮分子反應 速率； 上述第三個反應速率，應在4、3或最好是在2下。 此反應速率應在0. 5 、〇. 8或最好是在i以上。 也可使用帛j固和第二個反應速率，最好是同時採用 第一個、第二個和第三個反應速率。 ， 在適當情況下’可藉由此控制裝置作為水份滲透接^ 氫分子促生裝置的唯一管道。上述控制裝置為容器中，用 於執行氫分子促生裝置和水份來源的阻隔控制功能。 除非另有說月者’否則本文戶斤指的透濕性，使用 procedure E% Procedure E在38 t和相對濕度9⑽的情況下 ，進行測量。 上述氫分子生成裝置可含有某種基質成份，可跟活性 成伤混合，如使用預先混合或事後攪拌擴散混合的方法。 上述基質成份可含如聚合物成份，其選定則依據聚合物跟 水份的溶解度，以及對活性成份的化學惰性而定。適當的 基質成份的水蒸氣滲透率，應在〇. 2 、〇. 4 、 0.6 、 0.8 或最好是在1. 〇g. mm/ m2. day以上。上述基質成份可為至少兩 種的聚合物混合成份。 水蒸氣的滲透率應在5 、4或最好是在3g. day 上。適當的聚合基質成份包括但不限於乙烯醋酸乙稀、笨 乙烯、乙烯'丁烯（SEBS )共聚物，尼龍6、苯乙烯、笨 乙烯丙烯酸酯共聚物、聚對苯二曱酸乙二醇酯、聚乙烯、 7 201132558 聚丙烯。 上述 率，如控 此，最好 裝置的滲 反應速率 為達 質成份的 0.5以下 上述 蒸氣的渗 基質成份 多種的基 合物中， 氫分子促 有多種的 渗透速率 上述 透速率應 上述 ' LDPE ' 上述 在〇· 01刪 • 5、0.2 不同 控制裝置應適當選定，彳用於控制水蒸氣的渗透 制水蒸氣跟容器中的活性成份接觸反應速率。因 是讓水份在控制裝置中，進入接觸到氫分子促生 透速率，低於敵方進入接觸到氣 氧刀子促生裝置的 (如通過下列所指出的基質成份）。 成如上述内容之功能制裝“的水蒸氣對基 渗透速率（g•病2.day)，應在1、或最好是在 控制裝置所含有的物質，如聚合基質成 透速率（g.刪/m2. day)，應低於氫分子促生 的水蒸氣滲透速率（此聚合基 質成份，其含量應為最大量。）就上述 此控制裝置對此基質成份的水蒸ί滲透 生裝置中的基質成份（此聚合基質成份 基質成份，其含量應為最大量。）中， 應在 1 、0· 75、或 〇· 5g. rnm/m2· day 以下。 控制裝置含一種如聚合物的材質層，其 在 2.0、1.5、0.8 或(Ug，、、以下 控制裝置的聚合物材質| ’其材質選自 PET、EVA、SEBS和尼龍（如尼龍_6) 控制裝置可含一種如聚合物的材質層， 、0. 025咖或最好是在〇. 〇45咖以上，其厚 或0.1刪以下。 裝置設計，可用於執行控制敦置的水份 份，其水 裝置申的 ，若含有 實例的聚 速率，在 量，若含 其水蒸氣 水蒸氣滲 〇 HDPE 、 pp 〇 其厚度應 度應在〇 滲透速率Si 8 201132558 。在一實施例中，上述控制裝置得設計有單一的材質層（ 如片狀的材質層），應位於氫分子促生裝置和容器中=水 份來源間’此單一材質層含上述聚合物材質。此單—材質 層的厚度，應在0· 010舰、0. 〇25卹或最好是在〇 〇45咖以上。 其厚度應在0. 5咖、0. 2mra或〇. 1咖以下。 例如’此控制裝置中的聚合物材質，應提供有氣分子 和水蒸氣的適當滲透速率。且對氫分子生成而進入容器中 的副產物，無需要滲透率。 聚合物的結晶度會影響水份的滲透速率，可藉由下列 的結晶度計算式了解： P/Po = (l-c)/(l+c/2) 其中的P=結晶聚合物的滲透速率，Po=非結晶性聚合 物的滲透速率，c=結晶體積量。 聚合物材質和PET時’聚合物鍊的方向則會影響承透 速率，但就其如聚烯烴他的聚合物而言，其渗透速率則跟 聚合物鍊的向無關。 在另一個實施例中，上述控制裝置可為並列接觸的多 材質層設計，這些材質層可固定或夾層處理，而彼此連結 ，可藉由多材質層的設計，提供有控制裝置的滲透控制功 能。多材質層位於氫分子促生裝置和容器的水份間。通過 單一或多材質層的水蒸氣滲透速率，即應低於氫分子促生 裝置的水蒸氣滲透速率。 多材質層控制裝置的水蒸氣滲透速率，可使用下列的 計算式算出：Furthermore, it may be difficult to adequately mix the matrix component with the active material, so the rate of hydrogen molecule release may vary from batch to batch. In some cases, it is difficult to provide the release rate required for shelf life, i.e., to provide a specific mixing ratio of the matrix component/active material required for the container, such as the use of a closed design container. In this case, it is necessary to use a large amount of U 4 201132558. The hydrogen molecule of the active substance is used to form a matrix component, the Emirates (4)/, ', and the 妁 虱 knife generates an active substance. The mass is up to 5 (U), and here In this case, the rate of release of chlorine molecules is too high. In view of the above problems, such as a problem that can be more ideal and practical, and to be prayed to the target and direction of the relevant industry. In view of this, the inventor has been engaged in the development and development of related products and has no §10 experience, and slanted on the goal of the above-mentioned goals, detailed design and finality of practicality. invention. After the evaluation, the main object of the present invention is to provide a container for a deoxidizing oxygen device, which according to the present invention, and a container having a deoxidizing device, comprises the following device: A molecular growth promoting device', which contains an active substance, and reacts to form hydrogen molecules. The water control device can be used for water, ^ ^ ^ injury, and control of the penetration rate. The hydrogen molecule-promoting device can be used to fly the knife without the above control, thereby reducing the formation of the ruthenium molecule. The molecular weight-promoting device has a low control of moisture, and the loss of the hydrogen molecule is controlled by your function to control the penetration rate. The device is also related to the active substance. Compared with the above reaction rate, W 5 , is easily achieved by 耠 for two identical container devices, but the two capacity devices are as described above, including one The control unit, while the other container does not contain the control unit. 201132558. If the above control device provides a control function for the rate of formation of hydrogen molecules by means of a hydrogen molecule generating device, the rate of generation of argon molecules at a specific time can be adjusted to determine the performance of the shelf life of the container. For example, in order to provide a longer shelf life, in the same amount of matrix component, a larger amount of living J·biomass is required, and the permeability of the hydrogen molecule promoting device is controlled by the water. Conversely, in the absence of a control device, a greater amount of active material' results in a faster rate of hydrogen molecule formation, a faster rate of consumption and a lower shelf life of the container. Preferably, the control device is designed with a first reaction rate, which is defined as: the hydrogen molecule reaction rate of the vessel during the first 5 days / after the first 5 曰 period, the second period 5 曰 period to 85 曰 period The rate of hydrogen molecule reaction of the vessel; the above reaction rate should be 4, 3 or preferably 2. The reaction rate should be 0.5, 0-8 or preferably 1 or more. The selected 5-day period shall be during the container filling period of 45 days, 3 days, 15 days, 10 days or 5 days of the whole period, such as a container for beverages. The above control device shall be provided with a second reaction rate, wherein the second reaction rate is defined as: the hydrogen molecule reaction rate of the container during the first 5 days / after the first 5 days, the second period 5 days to 180 days , the hydrogen molecule reaction rate of the vessel; ^ the above reaction rate should be 4, 3 or preferably 2 or less. The reaction rate should be at 0.5, 0.8 or preferably at least 1. The above control device should provide a third reaction rate, which is the same as the younger brother. 6 201132558 The reaction rate is defined as: the gas molecule reaction rate of the container during the first 5 days / after the first 5曰 period, the second segment 5曰The rate of nitrogen molecular reaction of the vessel during the period of 27 ;; the third reaction rate described above should be 4, 3 or preferably 2. The reaction rate should be at 0.5, 〇. 8 or preferably above i. It is also possible to use 帛j and a second reaction rate, preferably using the first, second and third reaction rates simultaneously. , where appropriate, can be used as the sole conduit for the hydrogen permeation device. The above control device is in the container for performing a hydrogen molecule promoting device and a moisture source blocking control function. Unless otherwise stated, the moisture permeability of the person referred to herein is measured using the procedure E% Procedure E at 38 t and relative humidity 9 (10). The above hydrogen molecule generating device may contain a certain matrix component which can be mixed with the active agent, such as a method of mixing by mixing or mixing after stirring. The above matrix component may contain, for example, a polymer component, which is selected depending on the solubility of the polymer and water, and the chemical inertness of the active component. The water vapor permeability of the appropriate matrix component should be 〇. 2, 〇. 4, 0.6, 0.8 or preferably 1. 〇g. mm/ m2. day or more. The above matrix component may be at least two polymer blend components. The water vapor permeability should be 5, 4 or preferably 3 g. day. Suitable polymeric matrix components include, but are not limited to, ethylene vinyl acetate, stupid ethylene, ethylene 'butene (SEBS) copolymer, nylon 6, styrene, stupid ethylene acrylate copolymer, polyethylene terephthalate , polyethylene, 7 201132558 polypropylene. The above rate, if it is controlled, preferably, the permeation rate of the device is 0.5 or less of the composition of the vapor. The hydrogen molecule promotes a plurality of permeation rates. The permeation rate should be the above-mentioned 'LDPE'. The above-mentioned different control devices should be properly selected to control the rate of contact between the water vapor of the water vapor and the active components in the container. Because the water is in the control device, the contact with hydrogen molecules promotes the rate of penetration, which is lower than the enemy's entry into the gas-oxygen knife-promoting device (as indicated by the matrix components indicated below). The function of the water-based base permeation rate (g•2.day), as described above, should be at 1, or preferably in the control device, such as the rate at which the polymeric matrix is permeable (g. Deletion / m2. day), should be lower than the water vapor permeation rate promoted by hydrogen molecules (the content of this polymeric matrix should be the maximum amount.) In the above-mentioned control device, the water content of the matrix component is vaporized. The matrix component (the content of the matrix component of the polymeric matrix, which should be the maximum amount) should be below 1, 0·75, or 〇·5g. rnm/m2·day. The control device contains a material such as a polymer. Layer, which is 2.0, 1.5, 0.8 or (Ug,,, below, the polymer material of the control device | 'The material is selected from PET, EVA, SEBS and nylon (such as nylon_6). The control device may contain a polymer such as Material layer, 0. 025 coffee or preferably in 〇. 〇45 coffee or more, its thickness or less than 0.1. The device design can be used to control the water content of the control, its water device application, if it contains examples The rate of polymerization, in the amount, if it contains its water vapor vapour percolation HDPE The thickness of pp 〇 should be in the 〇 permeability rate Si 8 201132558. In one embodiment, the above control device is designed with a single material layer (such as a sheet-like material layer), which should be located in the hydrogen molecule promoting device and container. Medium = water source between 'this single material layer contains the above polymer material. The thickness of this single material layer should be 0. 010 ship, 0. 〇 25 shirt or preferably 〇〇 45 coffee or more. Should be at 0. 5 coffee, 0. 2mra or 〇. 1 coffee below. For example, 'the polymer material in this control device should provide the appropriate penetration rate of gas molecules and water vapor. And generate hydrogen molecules into the container. The by-product of the product, no need for permeability. The crystallinity of the polymer affects the permeation rate of water, which can be understood by the following crystallinity calculation formula: P/Po = (lc) / (l + c / 2) P = permeation rate of crystalline polymer, Po = permeation rate of amorphous polymer, c = amount of crystal volume. When polymer material and PET, the direction of the polymer chain affects the rate of penetration, but it is like poly Olefin, in terms of its polymer, its penetration rate is similar to that of the polymer chain. In another embodiment, the above control device can be designed for multiple material layers in parallel contact, and the material layers can be fixed or sandwiched and connected to each other, and can be provided with penetration of the control device by designing multiple material layers. Control function. The multi-layer is located between the hydrogen molecule promoting device and the moisture of the container. The water vapor permeation rate through the single or multi-material layer should be lower than the water vapor permeation rate of the hydrogen molecule promoting device. The water vapor permeation rate of the device can be calculated using the following formula:

Pt = Lt(La/Pa)+(Lb/Pb)+. . . (Ln/Pn) v 9 201132558 其中： Ρτ =總滲透速率 Pw =各材質層的滲透速率 Lt =夾層總厚度 Pa_n =各材質層的厚度 此夕材質層的總厚度，應在〇. _刪、〇. 〇3〇〇mm或〇. 〇45咖 以上在某些情況下，若為壓縮多材質層的設計，其厚度 應在0. lmm、〇· 3mm或〇. 5刪以上。此多材質層設計的厚度，應 在lmra或最好是在〇· 7咖以下。在一實施例中，其中一種壓 縮材質層，其厚度應在〇. 2mm或最好是在〇. 1腦以下。 若控制袈置為多材質層設計時，這些材質層提供有許 多的功能特性。例如’曝露而跟容器瓶頸接觸到的材質層 ，其表面的功能特性可用於調整開啟控制密閉裝置的旋轉 扭矩值。同樣地，控制裝置的材質層得彼此連結。再者， 可使用發泡材質層設計，用於調整控制裝置的壓縮功能。 上述控制裝置中，不管設計是否為單一材質層或失調 材質層，可為水渗透率設計，或使用排水確實設計，如塗 裝有矽質樹脂或氣烴材質，控制裝置應具有水蒸氣、氧分 子和氫分子的滲透率。 氫分子促生襄置的設計，可在長時間的情況下，在容 器中缓慢釋出氫分子。在使用適當的催化劑的情況下，氫 分子會跟容器内部的或容器壁上的氧分子反應。此外，= 初應有較快的氫分子釋出速率，然後在數個月或數年期間 中’則有較緩慢的反應速率。Pt = Lt(La/Pa)+(Lb/Pb)+. . . (Ln/Pn) v 9 201132558 where: Ρτ = total permeation rate Pw = permeation rate of each material layer Lt = total interlayer thickness Pa_n = each material The thickness of the layer shall be in the total thickness of the layer of eve. _Delete, 〇. 〇3〇〇mm or 〇. 〇45 咖以上 In some cases, if it is designed to compress multiple layers, the thickness shall be In 0. lmm, 〇 · 3mm or 〇. 5 delete above. The thickness of this multi-layer design should be in lmra or preferably below 〇·7 coffee. In one embodiment, one of the layers of compression material should have a thickness of 〇. 2 mm or preferably 〇. 1 brain or less. These layers provide a number of features if the control is set to a multi-layer design. For example, the material layer that is exposed to the bottle neck of the container can be used to adjust the rotational torque value of the opening control device. Similarly, the material layers of the control device are connected to each other. Furthermore, a foamed material layer design can be used for adjusting the compression function of the control device. In the above control device, whether the design is a single material layer or a misaligned material layer, it can be designed for water permeability, or it can be designed with drainage. If it is coated with tantalum resin or gas hydrocarbon material, the control device should have water vapor and oxygen. The permeability of molecules and hydrogen molecules. The hydrogen molecule-promoting device is designed to slowly release hydrogen molecules in the container over a long period of time. With the use of a suitable catalyst, the hydrogen molecules react with oxygen molecules inside the vessel or on the walls of the vessel. In addition, = should have a faster release rate of hydrogen molecules at the beginning, and then have a slower reaction rate during months or years.

再者，應在包裝充填時，才會開始出現氫分子的釋电V 10 201132558 反應。最後，物質釋出氫分手的反應，不會造成容器内容 物的品質惡化。 ， 此容器應含有某種催化劑成份，用於催化上述氫分子 和氧分子的反應。因此’在此容器中的氧分子，可較渗透 進入容器壁的氧分子，以水份作為副產物的情況下，進行 脫氧作用。 為達成此揭露功能目的’容器可包覆有任何產品，而 無任何特別設計而用於包裝内部和外部間物質轉移用途的 小型或大型孔洞，此容器可為密閉裝置設計。為達成此揭 露功能目的，其中的某種催化劑’可含任何用催化氫分子 和氧分子反應的成份物質。 此容器可有容器壁的結構設計，含第1種的聚合物樹 脂成份’和第2種的催化劑成份’可催化氫分子和氧分子 間的反應。氫分子促生裝置應位於容器内部，或是靠近容 器内部表面區域上。氫分子促生襞置應位於容器内部，或 採用密閉裝置的設計。 氣分子促生裝置含可跟活性成份混合作用的基質成份 時’活性成份對基質成份的重量百分比值應在〇. 〇1或最好 是在0. 02以上。基質成份應採用聚合物成份，確實跟活性 成伤擴散到混合。一般而言’ 一旦活性成份在聚合物成份 中擴散混合時’氫分子釋出速率則由水份對於聚合物的滲 透速率’或水份對選定基質成份的溶解度來控制。因此， 聚合物物質的選定’則依據水份在聚合物中的滲透速率或 溶解度而定，即可藉此控制活性成份釋出氫分子的速率。 但藉由選定適當的控制裝置，氫分子釋出速率可由上述榜$] 11 201132558 制裝 t%以 〇最 60wt% 份物 為鈉 如金 包括 卸、 狀態 合有 月數 三曱 份和 慮使 屬鹽 氫化 合基 置來控制。 聚合基質成份的活性成份含量應在lwt%或最好是在2w 上。此聚合基質成份的活性成份盡量，應在70wt%以上 好是讓聚合物的基質成份中，其活性成份含量應在1-、2-40wt%或最好是在4_3〇wt%以上。聚合物中的其他成 質’可含大量的上述聚合物成份。 上述的活性成份可含有金屬或氫化物，此金屬成份可 經、舒、鎂、鋅或铭。例如，氫化物可為無機物， 屬氫化物或硼氫化物，或是有機物。 週用於促進氫分子和水Furthermore, the release of hydrogen molecules V 10 201132558 should begin when the package is filled. Finally, the reaction of the substance to release hydrogen breaks up without causing deterioration in the quality of the contents of the container. The vessel should contain a catalyst component that catalyzes the reaction of the above hydrogen molecules with oxygen molecules. Therefore, the oxygen molecules in the container can be deoxidized by infiltrating the oxygen molecules entering the wall of the container and using water as a by-product. To achieve this exposing function, the container can be coated with any product without any specially designed small or large holes for packaging internal and external material transfer applications. This container can be designed for containment. For the purpose of this disclosure, one of the catalysts' may contain any constituent material that reacts with hydrogen molecules and oxygen molecules. The container may have a structural design of the container wall, and the polymer resin component of the first type and the catalyst component of the second type catalyze the reaction between the hydrogen molecule and the oxygen molecule. The hydrogen molecule promoting device should be located inside the container or close to the inner surface area of the container. The hydrogen molecule-promoting device should be located inside the container or be designed with a closed device.至以上。 Preferably, the gas molecule-promoting device contains a matrix component which can be mixed with the active ingredient. The weight percent of the active ingredient to the matrix component should be 〇. 〇1 or preferably 0.02 or more. The matrix component should be a polymer component that does spread to the mixed activity. In general, once the active ingredient is diffused and mixed in the polymer component, the hydrogen molecule release rate is controlled by the rate of penetration of water by the polymer or the solubility of water to the selected matrix component. Thus, the choice of polymeric material will depend on the rate of permeation or solubility of the water in the polymer, thereby controlling the rate at which the active component will liberate hydrogen molecules. However, by selecting the appropriate control device, the hydrogen molecule release rate can be made from the above list of $] 11 201132558, t%, the most 60% by weight, the sodium, such as gold, including the unloading, the state, the number of months, and the consideration. The salt hydrogenation base is placed under control. The active ingredient content of the polymeric matrix component should be at 1 wt% or preferably at 2 w. The active ingredient of the polymeric matrix component should be as high as 70% by weight or more. Therefore, the active ingredient content of the matrix component of the polymer should be from 1 to 2 to 40% by weight or preferably from 4 to 3% by weight. Other qualities in the polymer may contain a large amount of the above polymer components. The above active ingredients may contain a metal or a hydride which may be passed through, sulphur, magnesium, zinc or melamine. For example, the hydride can be inorganic, hydride or borohydride, or organic. Used to promote hydrogen molecules and water

” …-|工乃乂 7刀_ ， UJ T不限於：鈉、鋰、鉀、鈣、氫化鈉、氫化鋰、氫化 虱化鈣、鎂氫化物、硼氫化鈉和硼氫化鋰等。在游離 下，所有的這些物質可快速跟水份反應，但若預先混 聚,物的基質成料，其反應速率的半衰期則以週： 為單位來計算。 其他活性成份可含有機氫化物，如 丁巻二石夕氧燒、 基錫氫化物，以及如鎂、辞和鋁的金屬。 右而 >古性成 水份的反應速率過低時，可添加水解催Μ或特 用的化學劑成份。例如，可使用氫氧或 Κ 4軋離子過渡金 類或貴金屬的催化劑，來提高矽氫化物的水解率 也可考慮讓活性成份含聚合物成份，如 眾合物類的矽 物 poly(methylhydro) sii〇xane 的成份物質， 舫丄 貝可同時提供聚 買成份和活性成份，跟水份接觸時，即 P可釋出氫分子 例如 氫分子促生裝置可含有活性成份 以不同方"...-|工乃乂7刀_, UJ T is not limited to: sodium, lithium, potassium, calcium, sodium hydride, lithium hydride, hydrogenated calcium telluride, magnesium hydride, sodium borohydride and lithium borohydride. All of these substances can react quickly with water, but if pre-polymerized, the matrix of the material is formed, and the half-life of the reaction rate is calculated in weeks: Other active ingredients may contain organic hydrides such as巻 石 夕 氧 、, base tin hydride, and metals such as magnesium, rhenium and aluminum. Right and > ancient reaction to moisture when the reaction rate is too low, you can add hydrolyzed or special chemical ingredients For example, hydrolyzed or ruthenium-exchanged catalysts of ionic transition metals or noble metals may be used to increase the hydrolysis rate of the ruthenium hydride. It is also considered to allow the active component to contain a polymer component such as a steroid poly(methylhydro). a component of sii〇xane, mussels can simultaneously provide a combination of ingredients and active ingredients. When in contact with water, P can release hydrogen molecules such as hydrogen molecules. The bio-promoting device can contain active ingredients in different ways.

12 應。此容器可設計有 將容器密閉。此密閉 除和更換’如使用螺 性的設計，例如，使 後者的情況下，如下 性蓋材質的薄膜。在 計’提供有無菌的容 者可各自裝有氫分子 置和薄臈裝置後，可 子’可藉此提高容器 水份生成氫分子時， 置在含水份的環境下 產生水份的食物和飲 物或内部物質有關。 化’在生成氫分子前 份的接觸情形最小化 輕易使用許多的方法 金屬箔、金屬塑料或 促生裝置或使用類似 可使用聚乙烯袋氫分 在氫分子促生裝置放 包覆。另一個在各密 密閉裝置中，裝有一 例為考量下，容器中 谷器中的食物和飲料 201132558 "在容器中產生反 閉裝置，可方便 體密閉，也可移 移除但非可更換 的薄膜裝置。在 可設計有一個彈 使用薄膜密閉設 的密閉功能，兩 初移除此密閉裝 置，而釋出氫分 活性成份和 分子促生裝置放 大部份即放有會 般跟容器的内容 分子生成量最小 子促生裝置跟水 氧作用一樣，可 括但不限於使用 ，來包覆氫分子 計結構。例如， 換性設計結構， 相關各別的密閉 在儲放前，可在 以最佳實施 份來源，即來自 移動式的元件，如密 裝置可藉此將容器本 紋设計，也可使用可 用貼附在容器本體上 文内容，此密閉裝置 實施例中’此容器可 器封條’可提供合理 促生裝置。在使用最 藉此更換薄膜密閉裝 内容物的儲存壽命。 氫分子的生成只在氫 ’才會發生，如容器 料。氫分子的生成一 為避免或將此時的氫 ，其份量應足以氫分 。不像是氧分子的脫 來進行脫水作用，包 聚烯烴袋的結構設計 的氫分子促生裝置設 子促生裝置包覆的替 置在容器中，先進行 閉裝置的放置方法， 種或多種乾燥劑。 氫分子促生裝置的水 ’也應考量到其他容 m 13 器相關 ，含容 或紫外 電力、 質（如 跟 列標準 的氫分 已知毒 程度。 成份物 和其較 產物（ 因 而分佈 活含性 ，應將 分子生 量最小 容器不 作的容 密閉設 後方位 在 除的薄 201132558 的生成水份來源。此水份生成裝置應有 器内各物或容器在其他刺激、高溫或曝 線輻射、壓力變化、壓力變化，微波輻 磁場和超音波作用，相關的氫分子成份 水合鹽）。 聚合物遇合，其適當活性成份物質選定 而定’包括但不限於每公斤的成本、每 子生成量、活性成份的高溫和氧化穩定 性、反應的副產物，以及聚合物混合前 在提供適當穩定的活性成份中，棚氫化 質，因為可在一般市場容易取得，具有 低的成本，有較低的分子當量，且會生 偏硼酸鈉鹽）。 為氫分子釋出後，即會快速擴散在整個 在整個容器壁上，即容器中氫分子促生 然後基質成份），則非屬重要的考慮。 氫分子促生裝置放置在容器内，才得將 成量最大化，而將脫氧作用所需使用的 化。在容器内部，一般應將氫分子促生 透明的部位上。例如，在一般使用透明 器中，容器中的氫分子促生裝置，其儲 計。一般應將氫分子促生裝置放置在上 置上。 實施例中，氫分子促生裝置可放置在容 膜元件（最好是非更換式的設計）中，12 should be. This container can be designed to seal the container. This sealing and replacement is as follows. For example, in the case of the latter, a film of the following cover material is used. In the case of providing a sterile container, each of which can be equipped with a hydrogen molecule and a thinning device, the food can be used to increase the moisture content of the container to form a hydrogen-containing food when placed in a moisture-containing environment. It is related to drinking or internal substances. Minimization of contact in the formation of hydrogen molecules is easy. Many methods are easily used. Metal foils, metal plastics or growth promoting devices or similar use can be used to encapsulate hydrogen in a hydrogen molecule-promoting device. The other is in a close-packed device, taking into account a case, the food and beverage in the container in the container 201132558 " in the container to produce a closed device, which can be easily closed, removable or non-replaceable Thin film device. In the design, there is a sealing function of a film sealed with a film. The two devices are initially removed, and the hydrogen-distributing active component and the molecular-promoting device are enlarged to have the most content of the content of the container. The kid promoting device is the same as water oxygen, and can be used, but not limited to, to coat the hydrogen molecular meter structure. For example, the reversible design structure, the relevant separate sealing before storage, can be used in the best implementation source, that is, from mobile components, such as dense devices, which can be used to design the container or the like. Attached to the contents of the container body, the 'this container seal' can provide a reasonable growth promoting device in this embodiment of the closure device. The storage life of the film-sealed contents is replaced by the use of the most. The generation of hydrogen molecules occurs only in hydrogen, such as container materials. The formation of hydrogen molecules - in order to avoid or the hydrogen at this time, the amount should be sufficient for hydrogen. Unlike the dehydration of oxygen molecules, the hydrogen molecule-promoting device of the structural design of the polyolefin bag is placed in the container, and the method of placing the device is first, or a variety of Desiccant. Hydrogen molecule-promoting device water should also be considered to be related to other devices, containing or ultraviolet power, quality (such as the standard toxic degree of the standard hydrogen. The components and their products (and thus the distribution) Sexuality, the minimum amount of molecular mass should not be used to seal the post-orientation of the source of moisture in the thinning 201132558. The moisture generating device should have various irritants, high temperature or exposure radiation in the device. Pressure change, pressure change, microwave spoke magnetic field and ultrasonic wave action, related hydrogen molecular composition hydrated salt). The polymer meets and the appropriate active ingredient material is selected, including but not limited to the cost per kilogram, the amount per child, The high temperature and oxidative stability of the active ingredient, by-products of the reaction, and the provision of a suitably stable active ingredient before mixing the polymer, the shed hydrogenation, because it is readily available in the general market, has a low cost, and has a low molecular weight. Equivalent, and will produce sodium metaborate). After the hydrogen molecules are released, they will rapidly diffuse throughout the entire container wall, ie, the hydrogen molecules in the container promote the matrix component, which is not an important consideration. The hydrogen molecule-promoting device is placed in the container to maximize the amount of production required for deoxygenation. Inside the container, hydrogen molecules should generally be promoted to be transparent. For example, in a generally used transparent device, a hydrogen molecule in a container promotes the device, which is stored. The hydrogen molecule promoting device should generally be placed on top. In an embodiment, the hydrogen molecule promoting device can be placed in a membrane element (preferably a non-replaceable design).

向水份含量 露在可見光 射、pH值、 生成條件物 ’則依據下 克活性成份 性、材質的 的處理容易 納是典型的 高溫穩定性 成無害的副 容器内部， 裝置上（如 但一般而言 脫氧用的氫 氫分子生成 裝置放置在 PET材質製 放最好使用 述控制裝置 器一種可移 可接觸到容 f SI 14The moisture content is exposed to visible light, the pH value, and the formation condition is based on the treatment of the active ingredient and the material. It is typical that the high temperature stability is harmless in the interior of the sub-tank, on the device (but generally The hydrogen-hydrogen molecular generating device for deoxidation is placed in a PET material. It is preferably used as a control device for a movable contact with a device.

夾層.設計，其材質層無法讓氧 材質層。此薄膜可含氫分子促 層和容器内容物的間距，應小 容物的間距。薄獏得含有一種 置，其中的控制裝置和容器内 氫分子促生裝置和容器内容物 容器本體上的箔蓋設計。 擴散到整個容器壁上，將任何 最低。再者，氫分子的生成速 ，氫分子生成迷率（如提高容 器中的氫分子增加量維持在最 擴散速率遠高於氧分子的擴散 子里，則無需超過四個體積百 在可燃性的限制值。此外，食 低，因此，在任何時候，容器 谷器的頭部空間中。因此，出 常低。例如，500 ml的pet容 透速率為 〇· 05 cc/package-day ， lcc ，以便讓氫分子的擴散速 此外，氫分子生成速率需約為 夠數量的氫分子，而跟大部份 應。 -的氮分子’即可達成很高的脫 下’容器中氫分子的生成（損 降到最低。因此，此科技可輕 ESJ 201132558 •器中的内容物。此薄獏鍵為 分子滲透，如採用鋁金屬的 生裝置層’氫分子促生農置 於此非滲透薄膜層和容器内 材質層，可裝有上述控制裝 容物材質層的間距，應小於 的間距。此薄膜可為貼附在 因為所生成的氫分子會 時候谷器中的氫分子量降到 率越快’則擴散越快，因此 器的儲放溫度），只會讓容 低°因為氫分子在聚合物的 速率，容器頭部空間的氫分 分比，此數值則低於氫分子 物或飲料中的氫分子溶解度 中大部份的氫分子會出現在 現在容器中的氫分子量則非 器則有30ml的頭部空間，渗 較各器所需的氫分子量低約 率大於氧分子的滲透速率。 2 cc/day ，才得生成足 和所有滲透的氧分子進行反 因為容器中只需有小量 氧效果，而在長時間的情況 失），其膨脹和收縮情形則 15 201132558 易應用在 為促 有許多的 應，包括 金屬碳化 渡金屬鹽 π族金屬 化氮氣和 本沒有副 為能 反應所需 進入到容 劑。相反 好在容器 者作用時 需直接在 質成份中 點，包括 ，讓氫分 量，降到 或回收。 本發1 ，而將所： 到 lOOOppm 0. 5_ 的 3 剛性和彈性容器 進氫分子和氧分 催化劑可用於催 許多的過渡金屬 物（如碳化鈦） 的化合物。其中 中，#巴和翻是首 氧氣反應的效果 產物形成。最好 夠將脫氧作用的 的催化劑量。例 器内部即進行脫 的’若容器中的 内部和附近部位 ’催化劑可放置 食物或飲料散佈 。將催化劑放入 但不限於將食物 子和氧分子反應 最低，讓食物或 有催化劑。已知 置和氧分子的反 如鎳硼化物）、 如氮化欽）和過 特別有效。此VI 毒性和極高的催 的副產物，或根 化劑。 最好算出氧分子 前，需在氧分子 器壁添加有催化 脫氧作用時，最 。最後，若需兩 器壁上。催化劑 化劑放入聚合基 提供有許多的優 化程度降到最低 料所需的催化劑 化劑最容易移除 上。 子的反應，則需 化氫分子促生.裝 、金屬硼化物（ '金屬氮化物（ ，屬VIII族金屬 選’因為具有低 最佳，只有很少 使用氧化還原催 速率達到最高， 如’若需在使用 氧時，則會在容 i 氧分子已出現有 ’放置有催化劑 在谷器内部或容 時’通常需將催 聚合基質成份中 和飲料的品質惡 ’以及食物或飲 飲料容器中的催 t的許多催化#卜 料成極㈣反應速率 γ夕催化劑量降到最 _ °.01_到⑽動、。，传含有❻.01_ 【器相鮮重量百Μ卿到10卿或最好是在Mezzanine. Design, the material layer can not make oxygen layer. The film may contain a spacing between the hydrogen molecular layer and the contents of the container, which should be the spacing of the contents. The thin crucible contains a design in which the control device and the hydrogen molecule promoting device in the container and the foil cover on the container contents container body are designed. Spread to the entire container wall and will be any minimum. Furthermore, the rate of formation of hydrogen molecules and the generation of hydrogen molecules (such as increasing the amount of hydrogen molecules in the container to maintain the maximum diffusion rate much higher than the diffusion of oxygen molecules, then no more than four volumes in flammability Limit value. In addition, the food is low, therefore, at any time, the container bar is in the head space. Therefore, it is often low. For example, the 500 ml pet permeability rate is 〇· 05 cc/package-day , lcc , In order to allow the diffusion rate of hydrogen molecules, in addition, the rate of hydrogen molecule formation needs to be about a sufficient number of hydrogen molecules, and most of the nitrogen molecules can be used to achieve high removal of hydrogen molecules in the container. The damage is reduced to a minimum. Therefore, this technology can light the contents of ESJ 201132558. This thin 貘 key is molecular infiltration, such as the use of aluminum metal bio-device layer 'hydrogen molecule promotes the farmer placed in this non-permeable film layer and container The material layer may be provided with the above-mentioned spacing of the control material layer, which should be less than the pitch. The film may be attached because the hydrogen molecular weight in the bar is reduced as the hydrogen molecule is generated, and the diffusion rate is faster. More Fast, so the storage temperature of the device) will only make the capacitance low because of the hydrogen molecule at the rate of the polymer, the hydrogen fraction of the head space of the container, which is lower than the solubility of hydrogen molecules in hydrogen molecules or beverages. Most of the hydrogen molecules will appear in the current container, and the molecular weight of hydrogen will be 30 ml head space. The lower the molecular weight of hydrogen required for each device is greater than the penetration rate of oxygen molecules. 2 cc/day It is necessary to generate enough oxygen and all infiltrated oxygen molecules because there is only a small amount of oxygen in the container, but in the case of long-term loss, the expansion and contraction situation is 15 201132558 Easy to apply in order to promote many Including metal-metallized metal salt π-group metallized nitrogen and the non-sub-components required to react into the bulk. Conversely, it is better for the container to act directly at the point of the mass component, including, to allow the hydrogen component to be reduced or recycled. The present invention is directed to a rigid and flexible container of 1000 ppm 0. 5_. Hydrogen molecules and oxygen catalysts can be used to promote a large number of transition metal compounds (such as titanium carbide). Among them, #巴和翻 is the first oxygen reaction effect product formation. It is preferred to have a sufficient amount of catalyst to deoxidize. The inside of the case is removed. If the inside and the vicinity of the container are in the vicinity, the catalyst can be placed in a food or beverage. Put the catalyst in, but not limited to, minimize the reaction between food and oxygen molecules, and let the food or catalyst. It is known that it is particularly effective to place oxygen molecules like nickel borides, such as nitriding. This VI is a by-product of toxicity and extremely high catalysis, or a rooting agent. It is best to calculate the oxygen molecule before adding the catalytic deoxidation to the oxygen molecule wall. Finally, if you need two walls. The addition of the catalyst to the polymer base provides a number of optimizations to minimize the amount of catalyst required to remove the catalyst. The reaction of the child requires the hydrogen molecule to promote the loading and the metal boride ('metal nitride (which belongs to the VIII metal selection) because it has a low optimum, and only rarely uses the redox rate to reach the highest, such as 'if When oxygen is used, there will be a presence in the oxygen or the beverage container in the presence of a catalyst placed in the interior of the barn or in the capacity of the catalyst. Many of the catalysts of the catalyzed t 成 成 成 四 四 四 四 四 四 四 四 四 四 四 四 四 四 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 Is at

刀比以上的催化劑（不包括容H 16 201132558 中的任何内容物）。在較適當的實施例中，只需5卿或更 低的催化劑量。除非另有說明者，否則本文所指的"_"單 位，為重量的百萬分之一比值。 使用小量的催化劑，即使使用昂貴的的催化劑成份也 是經濟的。再者，因為用量小即有报好的效果，對其他包 裝特性，如顏色、煙霧和可回收性即會有最低的影經。例 如，使用她作為催化劑時，其濃度約為lppm以下的pd，在 擴散作用上即足以達到所需的脫氧速率。一般而言，所需 的催化劑量，即依據催化劑的原有速率、顆粒尺寸、容器 J厚度1刀子和氧分子反應速率和所需的脫氧程度而定 〇 為達成最大的催效果，最好讓催化劑進行充份的擴散 。催化劑可為同質或異質性。就同質的催化劑，最好是讓 催化劑分子擴散在聚合基質成份中。就異質催化劑而言， 應讓催化劑的平均顆粒尺寸小於i微 是…納米。異質催化劑的顆粒可為單一顆=，= 擴散混合於碳、氧化鋁或其他類似材質中。 催化劑的催化方法不會至_去看 法不疋重要考慮，最好讓催化劑充份 = '催化劑可在導入氫分子原料前t後的期間中，隨時 放入容器中。催化 劑了在生成聚合物’或是聚合物後來的 备解期間中，混合於 溶_ m $ σ Μ成&中。可遇合有喷灑劑或 有催化π、匕劑’用於聚合物顆粒或溶解過程前。可使用 液注射或懸泮物遇合於預溶的聚合物中。也可 再合：？母粒催化劑，然後在注射或押出成型前， 口適备1的母料顆粒與聚合物顆粒。在容器中，貝“】 17 201132558 放有催化劑，此催化劑可跟氫分子促生裝置中的活性基質 成份混合。 在首選實例的體現上，催化劑可混合在容器壁上。最 好至少跟容器壁的某些聚合物成份物質混合。在首選實例 的體現上，催化劑混合成份物質應佔容器壁内部面積的5 0%、 75%或最好是在90%以占。 在首選實例的體現上，可確實進行整個容器内部的擴 散，最好是排除密閉設計的岑慮。 本發明中的容器，可為單層或多層結構。在多層結構 中，最好是使用單層或多層結構的阻隔層。此阻隔層的材 質不限，可為乙烯醇共聚物（EVOH)、聚（羥基乙酸）和聚 (metaxylylenediamine adipamide)材質。其他適當的材質可為一 個或多個含聚g旨（包括但不限於PET 、p〇iyetheresters、聚 酉曰 amides 、聚胺醋（p〇iyurethanes)、聚酰亞胺（poiyimides)、 1 硫（polyureas)、聚醯胺醢亞胺（p〇iyamideimides)、聚苯醚（Knife ratio above the catalyst (not including anything in H 16 201132558). In a more appropriate embodiment, a catalyst amount of 5 sec or less is required. Unless otherwise stated, the "_" unit referred to herein is a ratio of one millionth of the weight. The use of a small amount of catalyst makes it economical to use expensive catalyst components. Moreover, because of the small amount, there is a reported good effect, and the other packaging characteristics, such as color, smoke and recyclability, will have the lowest impact. For example, when using her as a catalyst, a pd having a concentration of about 1 ppm or less is sufficient to achieve a desired deoxidation rate in terms of diffusion. In general, the amount of catalyst required, that is, according to the original rate of the catalyst, the particle size, the thickness of the vessel J, the knives and the oxygen molecule reaction rate, and the degree of deoxidation required, are determined to achieve the maximum stimulating effect. The catalyst is fully diffused. The catalyst can be homogenous or heterogeneous. In the case of a homogeneous catalyst, it is preferred to diffuse the catalyst molecules in the polymeric matrix component. In the case of a heterogeneous catalyst, the average particle size of the catalyst should be less than i micro... nanometers. The particles of the heterogeneous catalyst may be a single one =, = diffused and mixed in carbon, alumina or other similar materials. Catalyst catalyzed methods are not considered to be important considerations. It is best to allow the catalyst to be fully charged. 'The catalyst can be placed in the vessel at any time during the period before the introduction of the hydrogen molecular starting material. The catalyst is mixed in the solution _ m $ σ && during the subsequent preparation of the polymer or polymer. It can be used with a spray or a catalytic π, sputum agent before the polymer particles or the dissolution process. Liquid injection or suspension can be used to meet the pre-dissolved polymer. Can also be reconciled:? The masterbatch catalyst is then prepared with 1 masterbatch particles and polymer particles prior to injection or extrusion molding. In the container, the shell "" 17 201132558 is provided with a catalyst which can be mixed with the active matrix component of the hydrogen molecule promoting device. In a preferred embodiment, the catalyst can be mixed on the vessel wall. Some of the polymer components are mixed. In the preferred embodiment, the catalyst component should account for 50%, 75%, or preferably 90% of the internal area of the container wall. In the preferred embodiment, It is possible to surely carry out the diffusion inside the entire container, and it is preferable to exclude the confinement design. The container in the present invention may be a single layer or a multilayer structure. In the multilayer structure, it is preferable to use a barrier layer of a single layer or a multilayer structure. The material of the barrier layer is not limited, and may be a vinyl alcohol copolymer (EVOH), a poly(glycolic acid), and a metaxylylenediamine adipamide material. Other suitable materials may be one or more containing polyg (including but not Limited to PET, p〇iyetheresters, polyamides, p〇iyurethanes, poiyimides, 1 polyureas, polyamidamide (p〇iyamide) Imides), polyphenylene ether (

Polyphenyleneoxide)、酚氧樹脂、環氧樹脂、聚烯烴（包括但 不限於聚丙烯和聚乙烯）、聚丙烯、聚苯乙烯、聚乙烯（ 包括但不限於聚氯乙烯（PVC))的混合材質。此外，内部的 破璃材質或外部的包覆材質（氧化矽、鋁、氧化鋁或非定 型幻可作為阻隔層使用。所有上述聚合物材f，可作為 此處的混合材質。任何和所有的材質也可用於容器的密閉 裝置上，在某些情況下，則 〜蘇用玻璃材質。 在首選實例的體現上， 此容器壁則使用聚酯材質，如 PET ，最好是使用混有催化如 另惟化劑的PET材質。 此容器的外型、結禮七* 構或應用上，在本發明非屬重要考 18 201132558 慮。一 可為小 20ml 到 度、彈 置包括 裝或其 器中， 例的體 混合式 成型或 上 藉由容 於保護 上 合物材 -day)和 分子的 透所需 藉由控 氫分子 倍以上 最 如最好 _般而言’容器尺寸和外型 於lml或大於1000L容量者 100L，最好是100ml到5L的 性（或剛性）和可能的應 但不限於袋、瓶、罐、托 他類似的容器設計。此外 或在一種容器中，裝有一 現上，此容器可為任何尺 的設計結構），也可能是 熱成型）、多層袋或袋裝 述容器裝置中，可在裝有 器内部的脫氧作用提供防 高敏感性的電子元件或裝 述容器設計有可滲透的容 質’在無氧環境的脫氧速 1X10 cm -cm/ (m2-atin~day)。 般而言，即用於特別調整 最佳的釋出時間，使其類 的儲存壽命。氫分子生成 制裝置或聚合基質成份含 的生成速率，使其等於或 ，因為其整體反應式為2 佳情況下，氫分子促生裝 可長達100日、18〇日、 無限制。例如，容器尺寸 ，容器的最佳容量範圍自 容量。同樣地，容器壁厚 用功能則無限制。容器裝^ 盤、水桶、盆桶、吸塑包 ’容器可放置在另一個容 個或多個容器。在首選實 寸（塑料、玻璃、金屬或 密封盤和多層結構（注塑 結構。 易受侵蝕物質的容器中， 侵餘的功能，此容器可用 置。 器壁’含1種或多種的聚 率約為 6.5xl〇-7cm3-cm/( m2-atm 自氫分子促生裝置釋出氫 似或長於可防止氧分子參 釋出的特定時間長度，可 s來調整。也可特別調整 約為氧分子滲透速率的兩 H2+ 〇2 〜2 HzO。 置則用於長時間的作用， 270日或尤其是365日以Polyphenylene oxide), phenolic resin, epoxy resin, polyolefin (including but not limited to polypropylene and polyethylene), polypropylene, polystyrene, polyethylene (including but not limited to polyvinyl chloride (PVC)). In addition, the internal glass material or the outer cladding material (yttria, aluminum, alumina or amorphous) can be used as a barrier layer. All the above polymer materials f can be used as a mixed material here. Any and all The material can also be used on the sealing device of the container. In some cases, the material is made of glass. In the preferred embodiment, the wall of the container is made of polyester, such as PET, preferably mixed with catalysis. The PET material of the other agent. The appearance of the container, the structure or application of the container, in the invention is not an important test 18 201132558. One can be 20ml to the degree, the elastic device includes the device or its device In the case of the body-mixed molding or the above-mentioned, it is necessary to protect the composite material-day and the molecular permeability required by controlling the hydrogen molecules more than the best, and in general, the container size and appearance are in the lml. Or 100L greater than 1000L capacity, preferably 100ml to 5L (or rigid) and possibly a container design similar to, but not limited to, bags, bottles, cans, and other. In addition or in a container, which may be of any design, which may be of any size, or may be a thermoformed, multi-layer bag or bag container device, deoxidation provided inside the device The high-sensitivity electronic components or the espresso container are designed to have a permeable mass 'deoxygenation rate of 1X10 cm -cm/(m2-atin~day) in an oxygen-free environment. In general, it is used to specifically adjust the optimal release time to make its class storage life. The rate of formation of the hydrogen molecule generating device or the polymeric matrix component is equal to or because the overall reaction formula is 2, and the hydrogen molecule promoting device can be up to 100 days, 18 days, and unlimited. For example, the size of the container, the optimal capacity range of the container is self-capacity. Similarly, the function of the wall thickness of the container is not limited. Container trays, buckets, tubs, blister packs ‘ Containers can be placed in one or more containers. In the preferred size (plastic, glass, metal or sealing disc and multi-layer structure (injection structure. In the container of corrosive substances, the function of the remnant, this container can be used. The wall] contains one or more kinds of polymerization rate 6.5xl〇-7cm3-cm/(m2-atm can be adjusted from the hydrogen molecule-promoting device to release hydrogen or longer than the specific length of time that can prevent the release of oxygen molecules. It can also be adjusted to about oxygen molecules. The permeation rate of the two H2+ 〇2 ~ 2 HzO. The setting is used for long-term effects, 270 days or especially 365 days

iSI 19 201132558 上。上述作用條件為室溫儲存（22 °C )和一般大氣壓力。 也可進行容器、食物或飲料的初步脫氧，因此，可提 间速率提向氫分子的生成速率。在這些實例中，可讓催化 劑位於容器内部或附近部位。 、即考慮提供有許多的氫分子促生裝置，可各自控制氫 刀子生成迷率。藉由提供許多的氫分子促生裝置，在容器 中的氫分子生成速率即可特別調整，以符合特定的需求。 同樣地，不同活性物質也可跟容器作用釋出氫分子。這些 物質可為單一氮分子生成層的隨機混合物質，或放置在不 同材質層中。也可考慮除了提供至少一個的氫分子促生裝 置外可在封裝時，將氫分子促生裝置加到容器内部中。 在更為實施例的體現上，此密閉裝置裝有氫分子促生 裝置，可用於取代現有的容器密閉裝置，而提高容器中的 氣分子生成’或提供容器内部的脫氧作用，或增強脫氧作 用。例如，此類的密閉裝置可用於取代現有未裝有任何的 氫分子促生設計的密閉裝置，為傳統式無相關功能的密閉 裝置。 即可藉此提供消費者，可增強氧化敏感產品的儲存壽 命。另外，此密閉裝置可取代現有含氫分子促生功能，但 功能較差的密閉裝置’可能是因為密閉裝置的年久使用而 老化’或氫分子促生的時間調適。 若所取代的現有密閉裝置，非屬具有氫分子促生裝置 的設計者’此密閉裝置可整合有氫分子促生裝置，以及催 化氫分子和氧分子反應的催化劑的功能。在此情況下，此 密閉裝置可藉由防止水份進入氫分子促生裝置的情況下，「，iSI 19 201132558. The above conditions are room temperature storage (22 ° C) and general atmospheric pressure. Preliminary deoxidation of the container, food or beverage can also be carried out, so that the rate of introduction of hydrogen molecules can be increased. In these examples, the catalyst can be placed inside or near the container. That is, it is considered to provide a plurality of hydrogen molecule promoting devices, each of which can control the hydrogen knife generating rate. By providing a plurality of hydrogen molecule promoting devices, the rate of hydrogen molecule formation in the vessel can be specifically adjusted to meet specific needs. Similarly, different active substances can also act to release hydrogen molecules from the container. These materials can be a random mixture of layers of a single nitrogen molecule or placed in different layers of material. It is also contemplated that in addition to providing at least one hydrogen molecule promoting device, a hydrogen molecule promoting device can be added to the interior of the container during packaging. In a further embodiment, the hermetic device is provided with a hydrogen molecule promoting device, which can be used to replace the existing container sealing device, thereby improving the formation of gas molecules in the container or providing deoxidation inside the container or enhancing deoxidation. . For example, such a hermetic device can be used to replace a conventional hermetic device that is not equipped with any hydrogen molecule-promoting design, and is a conventional hermetic device with no associated function. This provides consumers with enhanced storage life for oxidation-sensitive products. In addition, this sealing device can replace the existing hydrogen-containing molecule promoting function, but the poorly functioning sealing device 'may be aged due to the long-term use of the sealing device' or the time-adjusted hydrogen molecule-promoting time. If the existing sealed device is replaced, it is not a designer having a hydrogen molecule promoting device. This sealing device can integrate a hydrogen molecule promoting device and a catalyst for catalyzing the reaction of hydrogen molecules and oxygen molecules. In this case, the sealing device can prevent the water from entering the hydrogen molecule promoting device, "

W W J 20 201132558 •提供保護。 密閉設計， 更換現 類似的元件 入催化劑， 的情況下， 分子促生強 容器所 可為人們所 依據第 ⑴ 跟水份反 (ϋ) 裝置。 依據第 ’可含有如 和控制裝置 在第一 第二個組合 第二個組合 此組合 此組合 此氫分 雖然在 此裝置可裝有金屬箔片或其他非滲透率材質、 可藉此避免水份跟氫分子促生裝置接觸。的 有的密閉裝i時，應、使用跟原彳移除密閉裝置 。容器壁上有催化劑時，此密閉裝置無需再裝 只需裝有氫分子促生裝置即可。因此，在後者 此方法可更藉由將密閉裝置換新，使用具有氫 化功能的新密閉裝置。 裝有的產品，應最好具有水份來源，這些產品 食用的食物和飲料，尤其是後者。 二個發明内容，為一種脫氧裝置而含有： 一種氫分子促生裝置，此裝置含有基質成份可 應生成氫分子； 一種可控制水份跟氫分子促生裝置接觸的控制 一個發明内容中的氫分子促生裝置和控制裝置 依據第一個發明内容中的任何氫分子促生裝置 的功能。 個組合部位上，可提供有此氫分子促生裝置。 β位彳于提供有此控制裝置，本文中的第一個和 部位，可面對面排列。此組合可為夾層結構。 可為内襯式密閉襄置設計。 可為碟形設計，此組合最好使用圓形斷面設計 子促生裝置得包覆在控制裝置中。W W J 20 201132558 • Provide protection. In the case of a closed design, replacing a similar component into a catalyst, a molecularly-promoting container can be used as a basis for the (1) anti-water (ϋ) device. According to the first 'may contain and control the device in the first second combination, the second combination of the combination of the hydrogen component, although the device can be equipped with metal foil or other non-permeability material, thereby avoiding moisture Contact with a hydrogen molecule promoting device. In some cases, when the air is sealed, use the original device to remove the airtight device. When there is a catalyst on the wall of the vessel, the sealing device does not need to be reinstalled, and only a hydrogen molecule promoting device is required. Therefore, in the latter method, a new closed device having a hydrogenation function can be further used by replacing the hermetic device. The products contained should preferably have a source of moisture, the foods and beverages that these products consume, especially the latter. The invention consists of a deoxidizing device comprising: a hydrogen molecule promoting device comprising a matrix component capable of generating hydrogen molecules; and a control for controlling the contact of water with the hydrogen molecule promoting device The molecular growth promoting device and control device are in accordance with the function of any of the hydrogen molecule promoting devices of the first invention. The hydrogen molecule promoting device can be provided at a combined portion. The β position is provided with this control device, and the first and the parts in this article can be arranged face to face. This combination can be a sandwich structure. It can be designed as a lined closed device. It can be a dish design which is preferably wrapped in a control device using a circular section design.

第二個發明内容中的脫氧裝置，為一種容器騎SI 21 0 201132558 ί 任何或其他功能上的應用。此組 下。這.些介質或環境^ 2其他介質或環境接觸的情況 態或聚合物態。氫空、容器的頭部空間部位、液 為脫氧作用），而為任何原因而釋出（不只是因 物反應過程，而需裝何的化學？質、電化學或生 可為固態的組合，‘：風裝置者。在實施例中’為-種 子。 导化干反應的液態介質，而釋出氫分 依據第三個發明内容， 置 .^ ^ 即棱供有一種容器用的密閉裝 閉裝置則裝有第二個發明内容的组合。 此組合最好採用内襯式密閉裝置設計。 依據第四個發明内完， 耠供有依據第二個發明内容的 、’0方法’此方法含相關的氫分子你哇护罢A批立，壯 此方法最好f有至+ b子促生裝置和控制裝置。 箭八—個加熱裝置，或是上述第一個 風刀子促生裝置或第二個 人 制裝置，而在高溫情況下，整 合有兩個裝置的功能，你丨 ΠΛ。 如溫度在50 ^，或最好是在1 〇〇 C以上。 4取ST疋# 1 最：就兩個控制進行高溫處理，上述第一個和第二個 、置可大出排列而彼此接觸，而祕二、松 而構成第一個和第二個突出 接觸的材質層。 此方法可讓控制裝置包覆氫分子促生裝置。 依據第五個發明内容，則依據第三個發明内容，而提 供有密閉裝置的製法，此方法 在則構成雄閉材質設計的氫分 子促生裝置和控制裝置的組合結構。 密閉材質得採用將容器密閉的裝置設計，例如，密閉 材質可螺紋設計的密閉裝置設計，可確保密閉裝置將容器The deoxidizing device in the second aspect of the invention is a container for riding any of SI 21 0 201132558 ί or other functional applications. Under this group. These media or environments ^ 2 other media or environmental contact conditions or polymer state. Hydrogen air, the head space of the container, the liquid is deoxidized), and released for any reason (not just the chemical reaction process, but also the combination of chemical, electrochemical or raw solids. ':Wind device. In the embodiment 'is-seed. Conducting the dry reaction of the liquid medium, and releasing the hydrogen according to the third invention, the ^ ^ ie, the edge is provided with a closed container for the container The device is equipped with a combination of the second invention. The combination is preferably designed with a liner-type closure. According to the fourth invention, the method of the second invention is provided with a '0 method'. Related hydrogen molecules, you wow to protect the A batch, this method is best to have a + b sub-promoting device and control device. Arrow eight - a heating device, or the first wind knife to promote the device or the first Two personal devices, and in the case of high temperature, integrated with the function of two devices, you 丨ΠΛ. For example, the temperature is 50 ^, or preferably at 1 〇〇 C or more. 4 Take ST疋 # 1 Most: Just two Controls for high temperature processing, the first and second above Large out of arrangement and in contact with each other, and secret two, loose to form the first and second protruding contact material layer. This method allows the control device to coat the hydrogen molecule promoting device. According to the fifth invention, based on According to a third aspect of the invention, there is provided a method of manufacturing a hermetic device, wherein the method comprises a combination of a hydrogen molecule promoting device and a control device which are designed as a male material. The sealing material is designed to seal the container, for example, sealing. The material can be threaded and designed to ensure the closure of the container

i SI 22 201132558 本體包覆。 依據第二個發明内容，#榀担处士 L丄. ^ 敢好如供有上述密閉材質的組 合，此組合t為内襯式密閉护罟初 闭衮置汉计，此方法在密閉裝置 提供有内襯設計，如密閉裝置開^ , j衣1開口處的内襯密閉材質設計 0i SI 22 201132558 Body cladding. According to the second invention, #榀担士士 L丄. ^ Dare to provide a combination of the above-mentioned closed materials, this combination t is a lining type closed guard 罟 initial closing device, this method is provided in the airtight device Lining design, such as airtight device opening ^, j clothing 1 at the opening of the lining closed material design 0

依據第六個發明内容，即槎供佑摅諠 7 L I权供依據第一個發明内容的 谷1§製造方法’此方法裝有氣公名代* 広衣啕虱刀子促生裝置控制裝置，而 成為容器的元件。 在實施例中，上述鱼分j (¾ +壯ae t 刀千促生裝置或控制裝置裝有一 個岔閉裝置，此容器元件可提供右交 死択有令器雄閉和開啟功能的 本體設計。 依據第七個發明内容，提供有控制裝置功能，用於防 ^水份來源（如容器中的水份）跟氫分子促生裝置（如容 器中的元件裝置）接觸，其中的氫分子促生裝置含活性物 質’可跟水份反應生成氫分夺。 依據第八個發明内容，提供有控制裝置功能，用於降 低氣分子促生裝置的氫分子（容器中的氫分子）生成速率 ’其中的氫分子促生裝置含活性物質，跟水份反應生成氫 刀子’而此控制裝置位於水份來源（容器中的水份）和氫 分子促生裝置間。 依據第九個發明内容，提供有水份（容器中的水份） 跟氨分子促生裝置（容器中的元件裝置）的控制方法，此 方法的控制裝置則位於水份和氫分子促生裝置間。 依據第十個發明内容，提供有可降低氫分子促生裝置 (容器_的元件裝置）氫分子生成速率的方法，此方法的According to the sixth invention, the 槎 槎 摅喧 7 LI 权 供 依据 依据 LI LI LI LI LI LI § § § § § § § § § § § § § § § § § § § § § § § § § § § § § And become the component of the container. In an embodiment, the above-mentioned fish sub-j (3⁄4 + Zhuang ae knife-promoting device or control device is equipped with a shut-off device, the container element can provide a body design with a right-handed deadlock and a male closing and opening function According to a seventh aspect of the invention, there is provided a control device function for preventing a source of moisture (such as moisture in a container) from contacting a hydrogen molecule promoting device (such as a component device in a container), wherein the hydrogen molecule promotes The living device contains an active material, which can react with water to form hydrogen. According to the eighth aspect of the invention, a control device function is provided for reducing the hydrogen molecule (hydrogen molecule in the container) generation rate of the gas molecule promoting device' The hydrogen molecule promoting device contains an active material and reacts with water to form a hydrogen knife, and the control device is located between the water source (water in the container) and the hydrogen molecule promoting device. According to the ninth invention, There is a control method for moisture (water in the container) and an ammonia molecule promoting device (component device in the container), and the control device of the method is located between the water and the hydrogen molecule promoting device. SUMMARY ten invention, there is provided a method of molecular hydrogen generation rate of hydrogen molecules can be reduced growth-promoting means (member _ the container means), this method

'：SI 23 201132558 控制裝置則位於水份和氫分子促生裝置間。 依據第十一個發明内宜，接祉女 門谷：如供有可延長容器内產品的 儲存壽命，其中的控制裝晉 置可控制避免容器中的水份跟氫 分子促生裝置接觸，其中的氫分 跟虱 虱刀子促生裝置含活性物皙， 可跟水份反應生成氫分子。 貝 依據第十二個發明内容 ^ 梃供有可延長容器内產口„的 儲存壽命，此方法的控制步 ° 促生裝置間，其中的氫分子仞 風刀于 刀子促生裝置含活性物質， 份反應生成氫分子。 j跟水 依據第十三個發明内容， 促生裝置（容器中的元件：置間可降低氣分子 法的控制裝置位於容器中 =子生成速率，此方 中的氫分子促生裝置含活性物 促=置間，其 子。 只了跟水伤反應生成氫分 依據第十四個發明内容， Μ ( Φ ^ ^ 耠么、有長時間可降低氫分子 促生裝置中的π件裝 认与八〜现刀于生成速率，其中 的風为子促生裝置含活性 兵 ，其中丨，可跟水份接觸生成氫分子 。 °尹的水伤和氫分子促生裝置間 依據本文任何發明内容 跟本文任何其他功能整合。一實施例令的任何的功能，可 【實施方式】 ’惟此等實施例僅二:：：示在明之較佳實施例 在專利申請上並不受此結” I ·» 24 201132558 構之限制.： 如第1圖所揭的功能執行裝置1〇可塑模製成一個如第 2圖所示的容器22，此容器22含一個外殼24，瓶口 28設 計有螺紋瓶頸26，位於螺紋瓶頸26下方則有旋緊螺紋部位 3〇 ’有一個錐形部位32自旋緊螺紋延伸而出，本體部位科 位於錐形部位32下方，而基座36位於容器底部。此容器1〇 適用如第3圖的包裝飲料38。包裝飲料38裝有飲料的内容 物’此飲料可以是蘇打飲料·、啤酒、葡萄酒、果汁、茶= 水。在特定實施例的體現中，此飲料可能是氧分子高敏感 性的飲料成份。在另一個實施例體現中，可為添加維生素 C或果汁的飲料組合，其中至少有丨種飲料含維生素此果 汁成份。在此實施例的體現中，容器22中的飲料，以密閉 裝置40將容器22的瓶口 28密封。 包裝飲料38裝有飲料的内容物，可為碳酸或非碳酸飲 料。適當的飲料内容物可為蘇打飲料、啤酒、葡萄酒 '果 汁、余和水。在特定實施例的體現中，此飲料可能是氧分 子高敏感性的飲料成份。在另一個實施例體現中，可為添 加維生素C或果汁的飲料組合，其中至少有〗種飲料含維 生素果汁成份。在此實施例的體現中，容器22中的飲料， 以密閉裝置40將容器22的瓶口 28密封。':SI 23 201132558 The control unit is located between the water and the hydrogen molecule promoting device. According to the eleventh invention, it is suitable to contact the female door valley: if the storage life of the product in the container can be extended, the control device can be controlled to prevent the water in the container from contacting the hydrogen molecule promoting device, wherein The hydrogen and helium knife-promoting device contains an active substance which reacts with water to form hydrogen molecules. According to the twelfth invention, the present invention provides a storage life for prolonging the production port of the container. The control step of the method promotes the device, wherein the hydrogen molecule hurricane knife contains the active substance in the knife promoting device. The reaction generates hydrogen molecules. j with water according to the thirteenth invention, the growth promoting device (components in the container: the device can be lowered in the chamber to control the gas molecular method in the container = the rate of generation, the hydrogen molecules in this side The growth-promoting device contains the active substance to promote the setting of the hydrogen. According to the fourteenth invention, Μ ( Φ ^ ^ 耠, for a long time can reduce the hydrogen molecule promoting device The π-piece accompaniment and the eight-to-the-knife at the rate of formation, wherein the wind is a sub-promoting device containing active soldiers, wherein helium can be contacted with water to form hydrogen molecules. ° Yin's water injury and hydrogen molecule promoting device Any of the functions of the present invention are integrated with any other functions herein. Any of the functions of an embodiment may be [embodiment] 'only these embodiments are only two::: the preferred embodiment shown in the patent application is not Subject to this结" I ·» 24 201132558 constitutive limitation: The functional actuator 1 as disclosed in Fig. 1 can be molded into a container 22 as shown in Fig. 2, the container 22 comprising a casing 24, the mouth 28 Designed with a threaded neck 26, located below the threaded neck 26, there is a threaded portion 3' having a tapered portion 32 extending from the tightening thread, the body portion being located below the tapered portion 32, and the base 36 being located in the container Bottom. This container 1 is suitable for a packaged beverage 38 as shown in Figure 3. The packaged beverage 38 contains the contents of the beverage 'this beverage can be a soda drink, beer, wine, juice, tea = water. In a particular embodiment In this embodiment, the beverage may be a beverage component with high sensitivity to oxygen molecules. In another embodiment, it may be a beverage combination containing vitamin C or fruit juice, wherein at least one of the beverages contains vitamins and juice components. In this embodiment. In the embodiment, the beverage in the container 22 seals the mouth 28 of the container 22 with a sealing device 40. The packaged beverage 38 contains the contents of the beverage, which may be carbonated or non-carbonated beverages. Suitable beverage contents may be Soda beverage, beer, wine 'juice, rest and water. In a particular embodiment, the beverage may be a highly sensitive beverage component of oxygen molecules. In another embodiment, vitamin C or juice may be added. A beverage combination wherein at least one of the beverages comprises a vitamin juice component. In an embodiment of this embodiment, the beverage in the container 22 seals the mouth 28 of the container 22 with a containment device 40.

參考第4圖内容，圓形斷面的密閉裝置仙，含一個可 將瓶頸26密封的螺紋部位44本體42設計。此部位私的内部 為内襯46設計，裝有氫分子促生裝置，可跟氫化妈整合使 用。此内部的部位44為含氫分子促生裝置的内襯邳，此内 襯46含一個材質層48，氫化物擴散混合於聚合基質成份中-S 25 PET材質層50和52。PET材質 物，為具有控制功能的材質層 蒸氣’避免跟含氫化物的材質 ’此催化劑可在pET的聚合基 成型的聚合基質成份和像是鈀 24和功能執行裝置1〇的結構， 裝有飲料和密閉裝置40，容器 些水蒸氣即會通過材質層5〇， 。因此’氫化物即會生成氫分 24的聚合物基質成份中，藉由 ，跟氧分子混合《催化劑即會 成水份。因此，滲透進入容器 用’保護容器内容物不受到氧 ’即可提供脫氧作用，此功能 化所控制。 材質層的特性或功能，如何藉 成速率。 聚物（Ateva 1070)和9%醋酸乙烯 標準），於93 °C以除濕機強制 低於 lOOppm (Computrac MAX 2000Lmo 棚氫化納（Venpure SF)。 [S】 201132558 。在材質層的另一邊，則為 層50最靠近容器中的内容 ，用於控制容器飲料令的水 層48接觸。 容器外殼24裝有催化劑 質成伤中擴散混合，由射出 化合物的催化劑，構成外殼 然後再吹模製成容器22。 使用時，使用的容器22 頭部空間則充滿水蒸氣。這 跟材質層48中的氫化物接觸 子’而風分子再進入到外殼 容器壁的滲透率進入容器中 催化氫分子和氧分子反應生 中的氧分子即會進行脫氧作 化。只要容器可生成氫分子 則由内襯中的氫化物含量變 下列實例即說明此控制 由材質層48來控制氫分子生 使用材料： EVA - ethylvinylacetate 共 酯，溶流指數 2. 8g/10min(ASTM 除濕約2分鐘，讓水份含量 isture Analyser)。 使用取自Rohm & Hassed的 26 201132558 RLE-005 -擠出型塗層聚8旨薄膜取自—cor Flexibles (0. 01 22mmPET/0. 0508mmLDPE) °. 實例2 (對照比較）： 某片狀材質含三個夹層材質層，各材質層使用如需實 例1中的材質，LDPE和PET使用實例【化合物的擠出片製 成，而在RLE-005的LDPE表面進行夾層處理，而構成3層的 材質層結構。各材質層的厚度如下：實例1的化合物為〇. 686mm、LDPE為0.0508mm和PET為0 〇122mm。3層的擠出材質層 總厚度為〇, 749刪。 實例3 : 片狀材質層為5層式夾層結構，各含有pET 、LDpE、 實例1化合物、LDPE和PET的材質層，使用實例丨化合物 擠出加工製造’再於RLE-005的兩個表面上進行夾層處理， 可讓兩個LDPE材質層，使用實例1的材質，進行片狀夾層 表面的處理。各材質層的厚度如下：實例1的化合物為〇. 686咖、LDPE為〇〇5〇8圆、PET為〇.〇122哪。五個材質層的總厚 度為0. 812刪。 實例4 : 片狀材質層為3層式夾層結構’各含有EVA 、實例1 化。物和EVA化合物的材質層，由實例1化合物共同擠出 加工，進行兩個EVA夾層的製備。各材質層厚度如下：EV A〇· 〇726mm 、實例1化合物為〇. 66〇4mm、EVA為〇. 〇726刪，總厚 度為0. 8128刪。 實例2到4所使用的材質，則評估說明如實例5 。 實例5 : m 27 201132558 矩形條（約5cm χ1·5απ )可自實例2到4 行切割製借，久播太日,，I w 片肤·材質進 ⑽纟樣本則精確稱重到克為單 2位數》各樣本使用滴定管逐漸加入⑽ 數點以下 部，此玻璃瓶的滴宏；^$ 破續瓶的底 此玻璃瓶的滴疋管裝置則倒放在裝滿水的 滿水的滴定管頂端則插有3刪的彈性聚乙稀管、 於樣本下方處，使用接合在聚乙埽管另一…： t, # ^ ^ t -f |：J ^ ^ ^ ^ 、射器將空 間變化上㈣量。収^的水歸㈣，進行時 ^2到4的氫分子變…，在第5圖 早位〇nl/g)的變化情形。其結果清楚顯示 的氫分子促生材質層，可控制氫 層 赃的兩個表面材質層可強化其批Z生成速率，而麵 中的P㈤^制功能。曝露在水蒸氣 中的虱亂釋出速率在5到1〇日間，使用腸阻隔層，則自 2-23降到L74 ml/g.day ’在使用__控制阻隔層時， 降到咖/g.da”但令人驚舒的是，控制阻隔層，在 〇〇曰的水蒸氣曝露期間令，則對氫氣的釋出速率有不良影 響，使用EVA控制阻隔層則自〇47增加到〇52 使用LDP_控制a隔層再增加到〇· 64 的水準。此令 人驚舒的氫氣釋出速率，受到水蒸氣控制阻隔層的軟體2 果，在5-10日期間的平均氫氣釋出速率則高於95-⑽日期 間的速率’例如，p且隔層的影響，則會增加釋出速率。同 樣地，尤其是在實例3中，175，的比值（最後攔位 95-100曰期間的數值則未改變，顯示阻隔層可達成長時門 的儲存壽命延長效果。因此，控制阻隔層可用於將脫氧^ 用最大化’而提供更長氧化產品的儲存壽命。 m 28 201132558 實例 平均 5-10 曰 氫氣釋 出速率 (ml/g. day) 平均 95-100 日 氫氣釋 出速率 (ml/g. d ay) 平均 175-180 曰氫氣 釋出速 率（ml/g .day) 平均 5-10/95-100日氫 氣釋出 速率 (ml/g. day) 平均 5-10/175 -180 曰 氫氣釋 出速率 (ml/g. day) 2 (對照 比較） 2.23 0.47 0.22 4. 75 10.14 4(EVA 阻 隔層） 1.74 0. 52 0.20 3.36 8.70 3(PET 阻 隔層） 0.67 0.64 0.41 1.06 1.63 在内襯46中，可使用許多不同材質作為控制用的材質 層。控制用的材質層應適當選定，讓控制材質層的水份滲 透率低於聚合基質1f7有氫化物成份擴散混合的滲透率。下 列材質可用於控制材質層中，提供適當的聚合基質成份， 而混合有氫化物成份。 m 29 201132558 聚合物 水蒸氣滲透率 (g. ram/ m2. day ) 聚（偏二氯乙烯）-Saran , 0.01(a) 聚（四氟乙烯、乙烯共聚物） HostafIon 0. 02(a) 高密度聚乙稀（（DuPont Sclair 19A) 1 0.13 聚乙烯、丙烯酸共聚物（EAA)BASF L ucalen A2910M(11% 丙浠酸含量） 0.23 低密度聚乙烯-Dow LDPE 722 (MFI 8g/10min@190 °C ) 0.26 乙稀四氟乙稀共聚物-DuPont Tefzel T2 0.3 硬聚氣乙烯（聚氯乙烯） 0.36(a) 聚丙烯（ΡΡ) - BASELL ADSYL 3C37F 0.45(b) 低密度聚乙烯-DOW LDPE 4005(MFI 5.5g/10min@190 °C ) 0. 46(b) 聚（乙浠teraphthalate) 0.39-0.51 聚丁烯（PB) Shell Chemical Duraflex 1600(密度 0.91g/ cm3) 0. 47(b) 乙烯乙烯醇共聚物（EVOH) - Eval E(44 mole %乙烯摩爾含量） 0. 6(b) EVA - Dupony Elvax 3120 ( VA 含量 7.5 % ) 0. 74(b) 聚（曱基丙烯酸曱酯） 0.84 ( a ) 30 201132558 聚（乙烯基縮丁醛） 1.06 ( a ) EVA - DuPont Elvax 3130 ( VA 含量 12 % ) 1.1(b) 苯乙烯丁二烯嵌段共聚物（SBS )-BASF AG Styrolux 656C 1.13(b) 尼龍 6 - BASF Ultramid B4 (無拉伸 性） 1.15)b) 一般用途聚苯乙烯-BASF AG '聚苯 乙烯168N : 1.2(b) EVA - DuPont Elvax 3123 ( VA 含量 15 % ) 1.6(b) 聚（碳酸） 1.83(a) 丙烯腈、甲基丙烯酸酯共聚物B P Chemical BAREX 210 2. 0(b) EVA - DuPont Elvax 3165 ( VA 含量 18 % ) 2.0(b) 聚對苯二曱酸乙二醇酯（PBT ) BASF AG Ultradur B4550 2. 5(b) 乙稀乙稀醇共聚物（EVOH) - Eval L(27mole %乙烯含量） 3. 2(b) 丙烯腈d苯乙烯d丙烯酸酯共聚 物-BASF AG Luran S 776S 3. 5(b) 聚（甲基丙烯酸乙酯） 4.16(a) 聚合物 水蒸氣滲透率 f si 31 201132558 2 (g. mm/ m . day) 丙浠腈、丁二稀、苯乙烯共聚物 -GE 塑料 Cycolac 5. 9(b) 表l-不同種類的同質共聚物水蒸氣滲透率[參考資 料：（a) - Polymer Handbook (4th Ed) table 1， page VI/545) 、 （b)Referring to Figure 4, the circular cross-section of the closure device includes a body 42 of threaded portion 44 that seals the neck 26 . The private interior of this part is designed for the inner lining 46 and is equipped with a hydrogen molecule-promoting device that can be integrated with the hydrogenation mother. The inner portion 44 is a liner of a hydrogen-containing molecular growth promoting device. The liner 46 contains a layer of material 48 which is diffused and mixed with the layers of the S 25 PET material 50 and 52. PET material, which is a control layer of the material layer, 'avoids the material with hydrides'. This catalyst can be formed on the polymerized matrix of pET and the structure of palladium 24 and functional actuators. The beverage and the sealing device 40, the water vapor of the container will pass through the material layer 5〇. Therefore, the hydride will form a polymer matrix component of hydrogen 24, and by mixing with the oxygen molecule, the catalyst will become water. Thus, infiltration into the container provides a deoxygenation effect by 'protecting the contents of the container from oxygen', which is controlled by this functionalization. How the property or function of the material layer is used to derive the rate. Polymer (Ateva 1070) and 9% vinyl acetate standard), forced to less than 100 ppm with a dehumidifier at 93 °C (Computrac MAX 2000 Lmo Venpure SF) [S] 201132558. On the other side of the material layer, The layer 50 is closest to the contents of the container, and is used to control the contact of the water layer 48 of the container beverage. The container shell 24 is filled with a catalyst to form a wound diffusion mixture, which is formed by a catalyst which ejects the compound, and then blow molded into a container. 22. When in use, the head space of the container 22 used is filled with water vapor. This is in contact with the hydride contact in the material layer 48 and the permeability of the wind molecules into the wall of the outer container enters the container to catalyze hydrogen and oxygen molecules. The oxygen molecules in the reaction will be deoxidized. As long as the container can generate hydrogen molecules, the hydride content in the liner will be changed. The following example shows that the control is controlled by the material layer 48 to control the hydrogen molecules. The material used: EVA - ethylvinylacetate Co-ester, solution index 2. 8g/10min (ASTM dehumidification for about 2 minutes, let water content is theist Analyser). Use 26 201132558 RLE-005 from Rohm & Hassed -Extrusion coating Poly 8 film taken from -cor Flexibles (0. 01 22mmPET/0. 0508mmLDPE) °. Example 2 (comparative comparison): A sheet material consists of three layers of interlayer material, each material layer is used For the material in Example 1, LDPE and PET are used as examples of the compound [extruded sheet of the compound, and the LDPE surface of RLE-005 is laminated to form a three-layer material layer structure. The thickness of each material layer is as follows: The compound of Example 1 was 686. 686 mm, LDPE was 0.0508 mm, and PET was 0 〇 122 mm. The total thickness of the extruded layer of the three layers was 〇, 749. Example 3: The sheet material layer was a 5-layer sandwich structure, each Material layer containing pET, LDpE, compound of Example 1, LDPE and PET, using the example 丨 compound extrusion processing to make a sandwich treatment on the two surfaces of RLE-005, allowing two LDPE material layers, using example 1 The material is processed on the surface of the sheet-like interlayer. The thickness of each material layer is as follows: the compound of Example 1 is 〇. 686 coffee, LDPE is 〇〇5〇8 circle, PET is 〇.〇122. Five material layers The total thickness is 0. 812. Example 4: The sheet material layer is a 3-layer interlayer A material layer containing each of EVA, Example 1, and EVA compound was co-extruded from the compound of Example 1 to prepare two EVA interlayers. The thickness of each material layer was as follows: EV A 〇 · 〇 726 mm , Example 1 The compound is 〇. 66〇4mm, EVA is 〇. 〇 726 deleted, the total thickness is 0. 8128 deleted. For the materials used in Examples 2 through 4, the evaluation instructions are as in Example 5. Example 5: m 27 201132558 Rectangular strips (approx. 5cm χ1·5απ ) can be cut from the 2nd to 4th rows of the example, long-time broadcast, I w skin · material into (10) 纟 sample is accurately weighed to gram 2 digits" each sample is gradually added to the burette (10) below the number of points, the drop of the glass bottle; ^$ the bottom of the broken bottle, the drip tube device of the glass bottle is placed on the filled burette filled with water The top is inserted with a 3 cut elastic polyethylene tube, under the sample, using the joint in the polyethylene tube another...: t, # ^ ^ t -f |:J ^ ^ ^ ^, the emitter will change spatially On (four) amount. The water collected is (4), and the hydrogen molecule changes from ^2 to 4, and the change in the early position 〇nl/g in Fig. 5). The result clearly shows that the hydrogen molecule promotes the material layer, and the two surface material layers of the hydrogen layer can be controlled to strengthen the batch Z generation rate, and the P(f) function in the surface. The rate of release from exposure to water vapor is between 5 and 1 day, and from the intestinal barrier, it is reduced from 2-23 to L74 ml/g.day 'When using the __ control barrier, it drops to coffee/ G.da” But it is astounding that the control of the barrier layer during the water vapor exposure of the crucible has an adverse effect on the rate of hydrogen evolution. The use of EVA to control the barrier layer increases from 〇47 to 〇. 52 Use the LDP_ control a compartment to increase to the level of 〇·64. This amazing hydrogen release rate, the soft body of the water vapor barrier layer, the average hydrogen release during 5-10 days The rate is then higher than the rate during the 95-(10) day', for example, p and the effect of the barrier increases the rate of release. Similarly, especially in Example 3, the ratio of 175 (last stop 95-100曰) The value during the period has not changed, indicating that the barrier layer can achieve a longer shelf life of the door when grown. Therefore, the control barrier layer can be used to maximize deoxidation and provide a longer shelf life for the oxidized product. m 28 201132558 Example Average 5-10 Hydrogen evolution rate (ml/g. day) Average 95-100 days hydrogen Release rate (ml/g. d ay) Average 175-180 曰 Hydrogen evolution rate (ml/g .day) Average 5-10/95-100 days hydrogen evolution rate (ml/g. day) Average 5- 10/175 -180 Hydrogen evolution rate (ml/g. day) 2 (Comparative comparison) 2.23 0.47 0.22 4. 75 10.14 4 (EVA barrier layer) 1.74 0. 52 0.20 3.36 8.70 3 (PET barrier layer) 0.67 0.64 0.41 1.06 1.63 In the lining 46, many different materials can be used as the material layer for control. The material layer for control should be appropriately selected so that the moisture permeability of the control material layer is lower than that of the polymer matrix 1f7 with hydride component diffusion mixing. Permeability. The following materials can be used to control the material layer to provide a suitable polymeric matrix component with a hydride component. m 29 201132558 Polymer Water Vapor Permeability (g. ram/ m2. day) Poly(Polychloride) Ethylene)-Saran, 0.01(a) Poly(tetrafluoroethylene, ethylene copolymer) HostafIon 0. 02(a) High Density Polyethylene ((DuPont Sclair 19A) 1 0.13 Polyethylene, Acrylic Copolymer (EAA) BASF L Ucalen A2910M (11% propionic acid content) 0.23 low density polyethylene - Dow LDPE 722 (MFI 8g/10min@190 °C) 0.26 Ethylenetetrafluoroethylene Copolymer - DuPont Tefzel T2 0.3 Hard Polyethylene (Polyvinyl Chloride) 0.36(a) Polypropylene (ΡΡ) - BASELL ADSYL 3C37F 0.45(b) Low Density Polyethylene-DOW LDPE 4005 (MFI 5.5g/10min@190 °C) 0. 46(b) Poly(ethylenephthalazone) 0.39-0.51 Polybutene (PB) Shell Chemical Duraflex 1600 (density 0.91g/cm3) 0 47(b) Ethylene vinyl alcohol copolymer (EVOH) - Eval E (44 mole % ethylene molar content) 0. 6(b) EVA - Dupony Elvax 3120 (VA content 7.5 %) 0. 74(b) Poly (曱) Ethyl acrylate) 0.84 ( a ) 30 201132558 Poly(vinyl butyral) 1.06 ( a ) EVA - DuPont Elvax 3130 (VA content 12 %) 1.1 (b) Styrene butadiene block copolymer (SBS) -BASF AG Styrolux 656C 1.13(b) Nylon 6 - BASF Ultramid B4 (no stretch) 1.15) b) General purpose polystyrene - BASF AG 'Polystyrene 168N : 1.2(b) EVA - DuPont Elvax 3123 ( VA Content 15%) 1.6(b) Poly(carbonic acid) 1.83(a) Acrylonitrile, methacrylate copolymer BP Chemical BAREX 210 2. 0(b) EVA - DuPont Elvax 3165 (VA content 18%) 2.0(b) Polyethylene terephthalate (PBT) BASF AG Ultradur B4550 2. 5(b) Ethylene glycol copolymer (EVOH) - Eval L (27mole % ethylene content) 3 2(b) Acrylonitrile d-styrene d acrylate copolymer-BASF AG Luran S 776S 3. 5(b) Poly(ethyl methacrylate) 4.16(a) Polymer water vapor permeability f si 31 201132558 2 (g. mm/m . day) Propylene nitrile, butyl diene, styrene copolymer - GE plastic Cycolac 5. 9(b) Table 1 - Water vapor permeability of different types of homopolymers [Reference: (a ) - Polymer Handbook (4th Ed) table 1, page VI/545) , (b)

-Permeability Properties of Plastics & Elastomers - A guide to Pac kaging & Barrier Materials, 2nd Edition ， 5 Edited by Lies1 K. M assey ， Published by Plastics Design Library ， 2003]。 本發明内容不限於上述具體說明細節，本發明可延伸 應用於本文中，任何單一或多個新發明的組合（包括任何 附帶的專利聲明、摘要說明和圖面内容），或是任何方法 步驟或過程揭露中，其單一或多個新發明内容的組合。 上述實施例所揭示者係藉以具體說明本發明，且文中 雖透過特定的術語進行說明’當不能以此限定本發明之專 利範圍；熟悉此項技術領域之人士當可在瞭解本發明之精 神與原則後對其進行變更與修改而達到等效之目的，而此 等變更與修改，皆應涵蓋於如后所述之申請專利範圍所界 定範疇中。-Permeability Properties of Plastics & Elastomers - A guide to Pac kaging & Barrier Materials, 2nd Edition, 5 Edited by Lies1 K. Massey, Published by Plastics Design Library, 2003]. The present invention is not limited to the specific details described above, but the invention may be extended to any single or multiple combinations of new inventions (including any accompanying patent claims, abstract and drawings), or any method steps or The process exposes a combination of its single or multiple new inventions. The above embodiments are intended to be illustrative of the present invention, and are intended to be illustrative of the invention. The principles are changed and modified to achieve an equivalent purpose, and such changes and modifications are to be included in the scope defined by the scope of the patent application as described later.

f SI 32 201132558 J【圖式簡單說明】 第 1圖 本發 明 之 設 計 斷 面 圖 0 第 2圖 本發 明 之 瓶 子 的 斷 面 圖 0 第 3圖 本發 明 之 瓶 子 和 密 閉 裝 置 的 斷 面 圖。 第 4圖 本發 明 之 密 閉 裝 置 的 部 份 斷 面 圖 0 第 5圖 本發 明 使 用 不 同 内 概 材 質 氫 分 子生成的變化圖 【主要元件符號說明】 10 裝置 容器 2 2 2 4 2 8 2 6 3 0 3 2 3 4 3 6 3 8 4 0 4 2 4 4 4 6 4 8 5 0、5 2 外殼 瓶口 螺紋瓶頸 螺紋部位 錐形部位 本體部位 基座 包裝飲料 密閉裝置 本體 螺紋部位 内襯 材質層 PET材質層 33f SI 32 201132558 J [Simple diagram of the drawing] Fig. 1 Design of the invention Fig. 0 Fig. 2 Fig. 0 of the bottle of the invention Fig. 3 Fig. 3 is a sectional view of the bottle and the sealing device of the invention. Figure 4 is a partial cross-sectional view of the sealing device of the present invention. Figure 5 is a variation diagram of the hydrogen molecule generated by the different materials in the present invention. [Main component symbol description] 10 Device container 2 2 2 4 2 8 2 6 3 0 3 2 3 4 3 6 3 8 4 0 4 2 4 4 4 6 4 8 5 0,5 2 Shell bottle mouth thread neck threaded part conical part body part base package beverage sealing device body thread part lining material layer PET material Layer 33

Claims (1)

201132558 七、申請專利範圍： 1 、一種具有脫氧裝 一氫分子促生裝 應生成氫分子； 一用於控制容器 制裝置。 2、 依據申請專利範 ，其中該控制裝 速率，其中的第 5曰期間容器中 結束，在85日後 1段期間的反應 3、 依據申請專利範 ，其中該反應速 4、 依據申請專利範 ，其中該控制裝 二個反應速率則 的氫分子反應逮 後的容器中氫分 控制第三個反應 初第1段5日期 5曰期間結束，. ;其中的第二個 而第三個反應速. 置之容器，包括： 置含某種活性物質成份’可跟水份反 中氫分子促生裝置的水份滲透率的控 圍第1頊所述之具有脫氧裝置之容器 置可用於控制第一個發明内容的反應 一個反應速率則定義為：最初第1段 的氫分-f反應速率/第2段5日期間 的容器中氫分子反應速率，其中的第 速率，則大於0.5 ，但小於4。 圍第2項所述之具有脫氧裴置之容器 率則大於0.5但小於2。 ° 置可用於控制第^固反應迷率之= :義為：最初第丨段5曰“容= &quot;第2段5曰期間結束，^中 f反應速率；而其中的控制裝署曰 吏率，此第三個反應速率定’則 a1容器中的氫分子反應速率笛.最 “7“後的容器中氫分c 1應速率，則大於0.5 ，但小二速率 择則大於〇. 5但小於2。 、： 2， 34 201132558 5 、依據申請專利範圍任一項所述之具有脫氧裝置之容器 ，其中該氫分子促生裝置含某種具有活性的基質成份 具有混合作用。 6 、依據申請專利範圍任一項所述之具有脫氧裝置之容器 ，其中該氫分子促生裝置含某種具有活性的基質成份 具有擴散作用。 7、依據申請專利範圍第5或6項所述之具有脫氧裝置之 容器，其中該基質成份的水蒸氣滲透率大於〇. 2g. mm/m2. day ，但小於 5g. mm/m2. day 。 8 、依據申請專利範圍第5至7項所述之具有脫氧裝置之 9 ο r=丄 IX I- * 2 IX 3 -X 4 IX 可 份 成 質 物 性 活 的 t% owt 6 - 11 有 份 成。 質物 基化 該氫 中或 其屬 , 金 器有 容含 器活 容和 之份 置水 裝中 氧器 脫容 有制 具控 之於 述用 所可 項， 一 定 任選 圍置 範裝 矛 f 專控 青亥 =°=° 中 據其 依， 器 容 之 置 裝 氧 脫 有 具 之 述 所 項 一 。任 驟圍 步範 渗專 的請 質申 物據 性依 份依，成依，0.依 氣75具 蒸ο·之 水為述 中值所 .器，比項 容其一 對，任 置率圍 裝透範 制滲利 控氣專 該蒸請 中水申 其的據 成 質 基 應 對 率 透 滲 器 容 之 置 。裝 低氧 更脫 或有 質 基 質 物 性 活。 含下 對以 份或 成75 質ο· 基在所 物應頊 合，一 聚率任 置透圍 裝滲範 制氣利 控蒸專 該水請 中的申 其份據 器 容 之 置 裝 氧 脫 有 具 之 述 其 8g. 在 率 透 滲 氣 蒸 水 其 層 質 材 種 一 含 置。 裝下 /S 伟以 控day -2一 該 中 器歹 容排 之觸 置接 裝面 氧對 脫面 有可 具， 之層 述質 所材 項個 一多 任含 圍置 範裝 矛f 專控 請該 中 據其 器 容 之 置 裝 氧 脫 有 具 之 述 。所 層項 置13 裝第 制圍 控範 的利 一專 單請 成申 構據 ，依 ，率 率透 透滲 滲的 氣置 蒸裝 水生 的促 層子 質分 材氮 個份 一成 少質 至基 對質 氣物 蒸性 水活 該含 中於 其低 ，應 5 3 201132558 ♦ 15、依據申請專利範圍任一項所述之具有脫氧裝置之容器 ，其令該控制裝置含多個材質層’可接觸到使用中的 容器瓶口 ’和一個泡錦亨，可用於調整控制裝置的壓 縮率。 16、 依據申請專利範圍任一頊所述之具有脫氧裝置之容器 ，其中該容器裝置設計有容器壁’其第一個材質成份 是聚合物樹脂，而第二個材質成份含催化劑用於催化 氫分子和氧分子的反應。 17、 依據申請專利範圍任一項所述之具有脫氧裝置之容器 ，其中該氫分子促生裝置吁位於此容器内部或上方。 18、 依據申請專利範圍任一項所述之具有脫氧裝置之容器 ，其中該氫分子促生裝置為容器中’可移除的元件設 計。 19、 依據申請專利範圍任一項所述之具有脫氧裝置之容器 ，其中該氫分子促生裝置為容器中’則設計有薄膜元 件，可移除讓容器的内容物進入，此薄膜裝置含一個 構成控制裝置的材質層。 20、 依據申請專利範圍第19項所述之具有脫氧裝置之容器 ’其中該薄膜貼附在容器本體’而構成容器裝置。 21、 依據申請專利範圍第19項所述之具有脫氧步詈之容考 ，其中該催化劑可整合於容器壁中。 22、 依據申晴專利範圍第19項所述之具有脫氧裝置之容器 ’其中該氫分子促生裝覃可持續生成氫分子促生裝置 至少270日。 23、 一種脫氧裝置，包括： 一氫分子促生裝置，裝有某種活性物質，可跟水份反 應生成氫分子； 一控制裝置用於控制t分子促生裝置的水份滲透率。 [SI 36 201132558 24、 依據申請專利範圍第23項所述之脫氧裝置，其中該氫 分子促生裝置提供有第一個材質層組合，而其中的控 制裝置位於此組合的第二個材質層中，此組合為夹層 設計。 25、 依據申請專利範圍第23或24項所述之脫氧裝置，其中 該設計組合為内襯式密閉裝置設計。 26、 依據申請專利範圍第1至22項所述之具有脫氧裝置之 容器製法，其中此製法即關於氫分子促生裝置和容器 控制裝置相關元件的製作。 m 37201132558 VII, the scope of application for patents: 1, a deoxidizing device, a hydrogen molecule to promote the production of hydrogen molecules; a control device for the container. 2, according to the patent application scope, wherein the control loading rate, wherein the fifth period of the container ends, the reaction during the first period after 85 days 3, according to the patent application, wherein the reaction rate is 4, according to the patent application, wherein The control is equipped with two reaction rates of hydrogen molecules after the reaction of the hydrogen in the vessel is controlled. The third reaction is the first phase of the first phase 5 and the end of the 5th period, the second and third reaction rate. The container includes: a container containing a certain active substance, which can be used with water to inhibit the moisture permeability of the hydrogen molecule-promoting device. The container having the deoxidizing device described in the first aspect can be used to control the first one. SUMMARY OF THE INVENTION A reaction rate is defined as the rate of hydrogen-f reaction in the first stage/the rate of hydrogen molecule reaction in the vessel during the second period of the second period, wherein the first rate is greater than 0.5 but less than 4. The container having deaerator set as described in item 2 is greater than 0.5 but less than 2. ° can be used to control the ^ solid reaction rate = : meaning: the first stage 5 曰 "capacity = &quot; the second paragraph 5 曰 period end, ^ f reaction rate; and the control assembly 曰吏Rate, this third reaction rate is set to 'the hydrogen molecule reaction rate in the a1 container. The hydrogen content of the container after the "7" is the rate of c 1 , which is greater than 0.5, but the rate of the second is greater than 〇. 5 And a container having a deoxidizing device according to any one of the claims, wherein the hydrogen molecule promoting device contains a certain active matrix component to have a mixing effect. A container having a deoxidizing device according to any one of the preceding claims, wherein the hydrogen molecule promoting device comprises a certain active matrix component having a diffusion effect. 7. Deoxygenation according to claim 5 or 6. The container of the device, wherein the matrix component has a water vapor permeability greater than 〇. 2g. mm/m2. day, but less than 5g. mm/m2. day. 8. Deoxygenated according to the scope of claims 5 to 7. 9 of the device ο r=丄IX I- * 2 IX 3 -X 4 IX can be used as a physical property t% owt 6 - 11 has a part. The substance is hydrogenated in the hydrogen or its genus, the gold has a container capacity and a part of the water in the oxygen device Decontamination has the control of the control, and it is optional. It must be selected to install the spear f. The special control Qinghai = ° = ° According to its dependence, the device is equipped with oxygen. If you want to use the product according to the nature, according to the nature, according to the basis, according to the basis, 0. Yiqi 75 steamed ο· water as the median value. The rate is bound to the system, and the gas is controlled by the water. The water is required to be based on the quality of the permeability of the permeation device. It is equipped with low oxygen or more matrix material. Into 75 quality ο· base in the object should be combined, a rate of arbitrage, perforation, venting, gas control, steam control, the water, the application of the water according to the device, the device is equipped with oxygen 8g. In the rate of permeate steamed water, its layer material is contained. Installed /S Wei to control the day -2 one of the Chinese 歹The contact surface of the arranging and arranging oxygen can be used for the noodle, and the layer of the material is more than one of the items containing the arranging spear f. The special control should be installed according to the device. Said. The layer of the item is installed in the 13th system of the control system, please use the basis of the application, according to the rate, the permeability of the gas, the vaporization of the water, the promotion of the layer of minerals, the nitrogen content of the </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; 'Contactable bottle opening in use' and a bubble jerk can be used to adjust the compression ratio of the control unit. A container having a deoxidizing device according to any one of claims, wherein the container device is designed with a container wall whose first material is a polymer resin and the second material contains a catalyst for catalytic hydrogen The reaction of molecules and oxygen molecules. 17. A container having a deoxygenation device according to any of the claims, wherein the hydrogen molecule promoting device is located inside or above the container. 18. A container having a deoxygenation device according to any of the claims, wherein the hydrogen molecule promoting device is a &apos;removable component design in a container. 19. The container having a deoxidizing device according to any one of the claims, wherein the hydrogen molecule promoting device is a container in which a thin film member is designed to be removable, and the contents of the container are removed. The material layer that constitutes the control device. 20. A container device having a deoxidizing device as described in claim 19, wherein the film is attached to the container body to constitute a container device. 21. A test having a deoxygenation step as described in claim 19, wherein the catalyst can be integrated into the vessel wall. 22. The container having a deoxidizing device according to claim 19 of the Shenqing patent scope, wherein the hydrogen molecule promotes the formation of a hydrogen molecule promoting device for at least 270 days. 23. A deoxidizing device comprising: a hydrogen molecule promoting device containing an active material capable of reacting with water to form hydrogen molecules; and a control device for controlling the water permeability of the t molecule promoting device. [SI 36 201132558 24] The deoxidizing device according to claim 23, wherein the hydrogen molecule promoting device is provided with a first material layer combination, wherein the control device is located in the second material layer of the combination. This combination is a sandwich design. 25. The deoxidizing device according to claim 23, wherein the design combination is a liner-type sealing device design. 26. A method of making a container having a deoxidizing device according to claims 1 to 22, wherein the method of making is related to the fabrication of components related to a hydrogen molecule promoting device and a container control device. m 37
TW99109799A 2010-03-31 2010-03-31 Deoxidizing agent TW201132558A (en)

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