201113233 六、發明說明： 【發明所屬之技術領域】 尤 本發明係一種在玻璃器皿内塗佈貴金屬奈米粒子的方法， 指是-種能使貴金屬(如：金或銀)奈米粒子被燒結固定在一玻璃 =皿(如：酒杯、酒碗或酒壺等)的内側表面上，均勻地形成一層 貴金屬奈米粒子膜，以使該玻璃器皿的内側表面具備 曰 效果的製作方法。 【先前技術】 I奈^科技⑽廣泛地應用至許多產業，從民生消費性產業乃 至尖端高概產業，均可見其縱跡，已被公認為二十—世纪最重 =產。尤其是，近年來’許多生產日常生活用品的傳統 ”本紐術無法突破及遭遇外來辭壓力的情形下 境，故’如何將奈米技術製成的各式奈米材料應 專統的日常生活用品，以改善該轉統日常生活用品的缺 的2效“料傳統日常生活用品的機能，進而解決傳統產業 1、’〔困&’即成為目前許多傳統產業所專注研發的方向。” 金屬t目别市面上常見的奈米材料’主要係利用奈米技術將貴 氧屬=.金、銀、纪、翻、錢及釕等），或其它金屬氧化物(如： ' L四氧化三鱗），製作成奈米粒子。 擇性^子為例’金奈綠子具有很高的催化活性，能作為選 气氧⑽2_丨’财地將—氧化碳氧化成二氧化碳，或將 ^匕物财，也能催化不同類型的加氫反應，如：一氧化碳的 風’和—丁二烯的加氫反應、，也能將酸及醇迅速地催化成醋 201113233 類，以有效減少酒精飲品(如：白酒、威士忌及葡萄酒等）中有毒 醇類的含量，且增加酯類的含量，使酒精飲品更為香醇。再以銀 奈米粒子為例，由於顆粒變細，導致整體表面積大幅增加，活性 變大，使得所釋放出的銀離子，不僅具有顯著的殺菌效果，更能 抑制黴菌生長，有效達到防腐功能，現已被廣泛地應用至各式曰 常生活用品_，如：含銀奈米粒子的抗菌香皂、抗菌濾網及抗菌 塗料等，另外，銀奈米粒子亦能催化出茶汁中的茶胺酸及兒茶素 # 等成份’且能降低咖啡因及丹寧等物質，使茶的營養及風味更佳。 有鑑於前述金或銀等貴金屬奈米粒子所具備的抗菌、防霉及 催化等功能，發明人乃思及將貴金屬奈米粒子應用至盛裝酒精飲 品的玻璃器皿上。按，酒精飲品(如：白酒、威士忌及葡萄酒等） 已存在數千年的歷史，無論古今中外，無論販夫走卒或王卿貴 族，無論休間餘暇或婚喪應酬，飲酒文化幾乎已成為人們日常生 活的-部份，贿飲品麵Μ，但大致均係賴食及水果發酵 釀製而成’其中白酒(或威士忌)係以糧食釀造的蒸館酒，也是中 籲 目北方及川貴地區(或北美及中北歐各國)最常喝的酒，酒精濃度 較高，-般均達30%以上，由於其氣味較為辛辣刺鼻，故—般^ 較不易由狀味辨識真偽’導致衫人因喝到假酒，喊生喂吐 =亭4至’嚴重地導致雙目失明或死亡的情事，_酒則係以 葡萄經去梗且略為破碎後’連汁帶皮整個放細射發酵，以使 酒精吸取果皮中的色素及丹料物質，且在發酵7至ω天 酵母菌將糖分解為酒精’且經壓榨及過親，再放置到酒桶中儲 存，由於’葡萄酒含高量的丹寧，而丹寧是天然防腐劑，夏 作用，故使》萄酒得以長久保存，—般言，葡_的酒精含量約 201113233 為百刀之八到十五，優質的葡萄酒因 A 一 時間的發轉製，才能航味變 3邊^必需經長 酒的酸溫味將會使人感到不適。順且豐潤’否則’葡萄 查，現今人們在曰常生活中最 、 :酒壺等)’均係由透明的坡細二 者為了能透過_器皿光錢明的材料特性，欣 =心酉 二=忌、紅葡萄酒及白葡萄酒等)的美麗色二-方面二 口為玻璃材料光滑密實的表面， 、]疋 性，具有不易沾染污物及異味的特 喊飲酒者真正品嚐出杯中物 = 的是白酒及咸士忌等㈣，紅惟’ 内盛裝 中^的㈣辛航味紐雜味，仍會令料人懼怕， 輕易嚐試。 因此，如何利用貴金屬奈米粒子的前述特性，設計出一種玻 璃器二的製作方法，以使責金屬奈綠子能被均勻地燒結固定在 玻璃器皿的_表面，形成—層永不脫落的貴金屬奈練子膜， ^藉由貴金屬奈米粒子騎產生的極大喊面積，發揮長效型抗 囷^防霉等效果，確_側表面不易沾染污物及異味，且能保持 光潔透明的特性’同時’尚能催化玻璃器皿内的酒精飲品，使其 中的酸類及_貞齡祕轉化為g旨類，財效減少麟飲品内 有毒的醇類及丹寧含量，且增加酯類的含量，使酒精飲品變得更 為香醇，即為本發明在此欲探討及解決的一重要課題。 【發明内容】 201113233 有鑑於前述傳統飲酒文化中存在的問題，發明人經過長久努 力研究與實驗，終於開發設抑本發_—種纽翻皿=塗佈 貴金屬奈棘子的方法，以期能在鱗玻璃器皿光潔透明特性的 條件下，使玻皿_側表面上形成—層永不脫落的貴金屬奈 米粒子膜，以透過其所產生_大比表面積，發揮長效 二 防霉及催化等效果。 本發明的-目的，係在-玻璃器皿(如：酒杯、酒碗或酒壺等） 的内側表面，均勻地塗佈-層混合溶液，該混合溶液係由水、水 溶性壓克力粉末、界面添加劑、水雜黏·、#金屬(如：金及 銀)奈米粒子及二氧化硬奈米粒子等成份，依預定的重量百分比， 均勻混合而成，該水溶性壓克力米蛛係一水溶性分散劑，並作用 係在溶解财愤’驗貴金屬奈料好及二氧切奈餘子均 勻且分散《浮纽合溶射，該界面添加_—去除表面張力 的水溶劑，其侧係在去除混合溶液絲_力，使得混合溶液 被塗佈至該玻璃器皿_側表面後，能均勻地分佈在内側表面 上，以確保混合溶液的塗佈厚度能均勻—致，該水雜黏著劑係 包覆在貴金屬奈餘子及二氧化料絲子職面；嗣，經快速 供乾處理’使混合溶液巾的水份迅速揮發，貴金屬奈絲子及二 軋化石夕奈錄子即麟由水雜黏賴，著在該玻璃器 皿的内側表面，而在該玻璃器皿的内側表面形成一厚度均勻薄 臈；最後’城溫燒結處理後，其溫度為二氧化料米粒子的溶 ^皿度該薄膜令的二氧化石夕奈米粒子連同其上附著的貴金屬奈 =粒子即職朗定在該玻璃器皿的_表面，而在該玻璃器皿 的内側表面上均勾地形成一層貴金屬奈米粒子膜，由於貴金屬奈 201113233 米粒子膜中無數個分佈均勻的貴金屬奈米粒子能產生極大的比 表面積，故使得該貴金屬奈綠子财有極佳的長效型催化效 果’能用以催化玻璃器皿内的酒精飲品，使酒精飲品中的酸類及 醇類^份被迅速催化為_員’以有效減少酒精飲品内有毒的醇類 及丹于3里’進而降低酒精飲品的辛辣或酸溫氣味，且增加醋類 含量，使酒精飲品變得更為香醇順口。 、 本發明的另—目的，混合溶_由水、水溶性壓克力粉末、 界面添加劑、水溶性黏著劑、二氧切奈絲子、水溶性的碳酸 鹽^溶性的貴金屬(如··金及銀)鹽及還原劑等成份，依預定的 重量百分比’均妓合喊’該水雜壓克力粉末係—水溶g分 散劑，其作用係在溶解於水中後，能使礙酸鹽、貴金屬鹽及 化石夕奈米粒子均自且分躲祕在混合驗巾，由於碳^鹽且有 在水溶液帽_根離子的·，故能在混合溶液中與二氧 化=奈米粒子結合成水溶性的♦酸鹽，又，由於貴金屬鹽具有在 ，溶液中解離出貴金雜子的特性，且貴金屬離子具有親氧的特 t故極轉概壯魏產生物，而在該混合溶液的調 衣過秋中’均勻且麵地附著在频鹽的表面，該還原劑係葡萄 糖，其作關在將貴金麟子緩慢地還原成為責金屬奈米粒子， 該界面添加舰-去除表錄力的水_，其作㈣在去除混人 溶液的表面張力，使得混合溶液被塗佈至該玻璃器皿的内側表= 後’能均勻地分佈在_表面上，以雜混合溶朗塗佈厚 均勾-致，該水雜黏著劑能在該混合溶液的調製過程中^覆 f石夕酸鹽的表面；騎，經快速烘乾處理，使混合溶液中的水份迅 逮揮發，石夕酸鹽即能藉由水溶性黏著劑，均勾地附著在該玻璃器 201113233 皿的内側表面，而在該玻璃器皿的内側表面形成一厚度均勻的薄 膜；最後，經高溫燒結處理後，溫度為矽酸鹽的熔融溫度，該薄 膜中的矽酸鹽連同其上附著的貴金屬奈米粒子即被燒結固定在 該玻璃器皿的内側表面’而在該玻璃器皿的内侧表面上均勻地形 成一層貴金屬奈米粒子膜。 本發明的又一目的，該水溶性壓克力粉末係一聚丙烯酸衍生 物(Polyacrylic add derivative) ’用以使混合溶液中的各成份能均勻 ^ 地分散在混合溶液，而不致發生沉澱或淤積結塊的現象，如此， 二氧化矽奈米粒子(或矽酸鹽)及貴金屬奈米粒子始能被均勻地塗 佈至該玻璃器皿的内側表面上。 本發明的又另一目的，該界面添加劑係一以聚醚改質的具有 壓克力（丙烯醛基聚合物）功能的二曱基矽氧烷（p〇tyether modified acryl fimctkmal potydimethylsil〇xane)，用以去除混合溶液 的表面張力，以在被塗佈至該玻璃器服的内側表面上後，能均勻 地分佈在内側表面上，以確保混合溶液的塗佈厚度能均勻一致， # 且在高溫麟後，能舰融的二氧化轉錄子或魏鹽能均句 地附著在玻璃11盟的_表面，而使玻璃器皿的内側表面能保持 光潔密實的雜，而不致產生凹凸不平的粗链面。 本發明的又另-目的，該水溶性黏著劑係包含聚尿醋樹脂 (Urethane Pdymer)、Ν·甲基比咯酮杯^%1 pyiT〇iid_)及三乙 胺(Triethyiamine)等成份，用以使二氧化石夕奈米粒子(或石夕酸鹽)及 貴金屬奈米粒子能均勻地附著在玻璃器皿的内側表面，以在高溫 燒結後，能在玻璃器皿的_表面上均勻地形成—層貴金屬奈米 粒子膜’以Μ發揮其應有的、防霉及催化作用。 201113233 女s 1貞番查委貞能對本發明的目的、技術特徵及盆功效 有更進一步的認識與睁 ^ 細說明如下：、瞭解_舉右干實施例，並配合圖式，詳 【實施方式] 間第係—種在玻璃11皿内塗佈貴金屬奈米粒子的方法，參 閱第1圖所示，該方法包括下列步驟： _將一含貴金屬奈米粒子的混合溶液倒入—玻璃器皿(如：酒 杯、酒碗或酒壺等），且均勻搖動該玻璃器皿後，將混合溶 液倒出，且將該玻璃器皿倒置擺放，以在該玻璃器皿^内 側表面，均勾地塗佈-層含貴金屬奈米粒子的混合溶液； (101)以攝氏50〜％度’對該玻璃器皿進行快速烘乾處理，以迅 速去除混合溶液中的水份；及 _以攝氏350〜度，即混合溶液十二氧化料米粒子或石夕 酸鹽的溶融溫度，對該玻璃器皿進行高溫燒結處理，以使 二氧切奈錄子或碰鹽，連同其上附著的貴金屬奈米 粒子，燒結固定在該玻璃器皿的内側表面上，以均勾地形 成一層永不脫落的貴金屬奈米粒子膜。 在本發明中，為了確保貴金屬奈米粒子膜不易沾染污物及異 味，維持該玻璃器皿光潔透明的特性，且能催化玻璃器皿内的酒 精飲品’使酒精飲品中的酸類及醇類成份被迅速催化為酯類，以 有效減少麟飲品内有毒的醇類及丹寧含量，進而降低酒精飲品 的辛辣或酸蜮味，且增域_含量’使酒精飲品變得更為香 醇’該混合溶液的成份必需具備下列四大特性： 201113233 ⑴必需能使二氧化石夕奈米粒子或石夕酸鹽，均勻地分散在混合 溶液中，而不致發生沉澱或淤積結塊的現象，如此，該等 一氧化矽奈米粒子或矽酸鹽始能被均勻地塗佈至破璃器皿 的内侧表面上； °° (2) 此合溶液的表面張力必需能被去除，使得混合溶液被塗佈 至玻璃器皿的内側表面後，能均勻地分佈在内側表面上， 以確保混合溶液的塗佈厚度能均勻一致，且使得高溫燒結 走/成的貝金屬奈米粒子膜，能令玻璃器皿的内側表面始 終保持光潔密實’不致產生凹凸不平的祕面，且不易沾 染污物及異味； (3) 必而硓在南溫燒結形成貴金屬奈米粒子膜後，仍能使該玻 璃器里維持光潔透明的特性；及 、、舄此在元成咼溫燒結後，使二氧化石夕奈米粒子或石夕酸鹽 句勻刀佈且附著在該玻璃器皿的内側表面，以使其上附著 的責金屬奈米粒子能產生長效型抗g、防霉及催化效果。 太、，在本發明之一最佳實施例中，該混合溶液係由水、二氧化矽 不子貝金屬奈米粒子、水溶性壓克力粉末、界面添加劑及 水洛性黏著料成份，依下觸重量百分比，均自混合而成： ⑴水·其重量百分比為40%〜70% ; ㈠:氧化>5夕奈米粒子：其重量百分比為丨5%〜7 ，在該實 j中係先將一氧化石夕研磨成奈米(nanometer)大小的粒 ’ 1奈米等於十億分之1米(10-9 meter)，或奈米級大小的 子即約為1〜1〇〇奈米，介於分子和次微米間的奈米粒 子； 11 201113233 (3) 貝金屬奈米粒子：係金或銀的奈米粒子，或金及銀奈米粒 子的混合，其重量百分比為0.01%〜1〇〇/0 ; (4) 水溶性壓克力粉末：其重量百分比為2%〜3〇%，其中該水 溶性壓克力粉末係一水溶性分散劑，其作用係在溶解於水 中後，能使二氧化矽奈米粒子及貴金屬奈米粒子均勻且分 散地懸浮在混合溶液中，在該實施例中，該水溶性壓克力 粉末係一聚丙烯酸衍生物(p〇lyacrylicacidderivative)，能使 二氧化石夕奈米粒子及貴金屬奈米粒子均勻分散在混合溶液 中，而不致發生沉澱或淤積結塊的現象，如此，該等二氧 鲁 化矽奈米粒子及貴金屬奈米粒子始能隨混合溶液被均勻地 塗佈至該玻璃器皿的内側表面上； ⑶界面添加劑：其重量百分比為〇 〇5%〜5%，該界面添加劑係 一去除表面張力的水溶劑，其作用係在去除混合溶液的表 面張力，使得混合溶液被塗佈至該玻璃器盟的内側表面 後，能均勻地分佈在該玻璃器皿的内側表面上，以確保混 合溶液的塗佈厚度能均勻一致’在該實施例中，該界面添 加劑係-以聚峨質的具有壓克力（丙烯搭基聚合物)功能· 的一甲基石夕氧烧（Polyether modified aeryl ftinetioiial polydimethylsiloxane) ’能去除混合溶液的表面張力，使混 合溶液具備均勻的分佈性’以在被塗佈至該玻璃器皿的内 側表面上後，能確保混合溶液的塗佈厚度能均勻一致，以 在高溫燒結後，能使該玻璃器皿的内側表面始終保持光潔 密實，不致產生凹凸不平的粗糙面，且不易沾染污物及異 味；及 ~ 12 201113233 (6)水溶性黏著劑：其重量百分比為〇2%〜1〇%，該水溶性黏著 劑係在該混合溶液的調製過程中，能包覆在混合溶液中均 勾且分散的二氧化矽奈米粒子及貴金屬奈米粒子的表面， 在該實施财，該水溶性黏著劑係包含聚尿醋樹脂 (Urethane P〇lymer)、N_曱基比咯酮pyrr〇Ud〇㈣及201113233 VI. Description of the invention: [Technical field to which the invention pertains] The present invention is a method for coating precious metal nanoparticles in a glassware, which means that a precious metal (e.g., gold or silver) nanoparticle can be sintered. It is fixed on the inner side surface of a glass = dish (such as a wine glass, a wine bowl or a jug) to form a layer of a noble metal nanoparticle film uniformly, so that the inner surface of the glassware can be provided with a enamel effect. [Prior Art] I Nai Technology (10) is widely used in many industries. From the consumer industry of the people's livelihood to the high-end industries, it can be seen as a trace. It has been recognized as the most important in the 20th century. In particular, in recent years, 'many traditions of producing daily necessities' cannot break through and encounter the pressure of foreign words, so 'how to make various kinds of nano materials made of nanotechnology should be used in daily life. Supplies, in order to improve the lack of daily necessities of the transfer of the two-effect "materials of traditional daily necessities, and then to solve the traditional industry 1, 'sleepy & 'that has become the focus of research and development in many traditional industries. "Metal t-materials commonly found on the market are mainly made of nanotechnology using nanotechnology = gold, silver, ki, turn, money and bismuth, etc.), or other metal oxides (eg: 'L tetraoxide Three scales, made into nano particles. Selective ^ as an example 'Jinai green has a high catalytic activity, can be used as a selective oxygen (10) 2 _ 丨 ' 财 — oxidized carbon oxidized to carbon dioxide, or ^ Treasures can also catalyze different types of hydrogenation reactions, such as carbon monoxide wind and butadiene hydrogenation, and can also quickly catalyze the acid and alcohol into vinegar 201113233 to effectively reduce alcoholic beverages. (such as: liquor, whiskey and wine), the content of toxic alcohols, and increase the content of esters, so that alcoholic beverages are more mellow. In the case of silver nanoparticles, the overall surface area is greatly increased due to the finer particles. The activity becomes large, so that the released silver ions not only have remarkable bactericidal effect, but also inhibit mold growth and effectively achieve anti-corrosion function, and have been widely applied to various kinds of daily necessities _, such as: silver Nanoparticle Insulin soap, antibacterial filter and antibacterial coating, etc. In addition, silver nanoparticles can also catalyze the components of tea acid and catechin in tea juice, and can reduce caffeine and tannins, etc. The nutrition and flavor are better. In view of the antibacterial, anti-mildew and catalysis functions of the precious metal nanoparticles such as gold or silver, the inventors thought about applying precious metal nanoparticles to glassware for alcoholic beverages. Alcoholic beverages (such as liquor, whiskey and wine) have existed for thousands of years. No matter the ancient and modern Chinese and foreign, whether it is a pawn or a royal aristocrat, whether it is a rest or a wedding or a funeral, the drinking culture has become a daily life. Partially, bribes and drinks are not bad, but they are mainly made by fermenting food and fruit. 'Liquor (or whiskey) is a steamed wine made from grain. It is also in the north and Chuangui areas (or North America). And the most commonly consumed wines in the countries of Central and Northern Europe, the alcohol concentration is higher, generally more than 30%, because its smell is more spicy and pungent, so it is not easy to identify the authenticity by the taste. Fake wine, shouting to feed spit = pavilion 4 to 'severely cause blindness or death of the eyes, _ wine is stalked with grapes and slightly broken, then the whole juice is sprayed and fermented to make alcohol Absorb the pigments and dendritic substances in the peel, and decompose the sugar into alcohol during the fermentation of 7 to ω days, and press and pass the pro, and then store it in the barrel, because the wine contains high amounts of tannins. Tannin is a natural preservative and has a summer effect, so that the wine can be preserved for a long time. As a general rule, the alcohol content of Portuguese _ is about 201113233, which is eight to fifteen, and the quality wine is transformed by A. In order to change the taste of the air to 3 sides, it is necessary to have the acid temperature of the long wine to make people feel uncomfortable. Smooth and rich 'other 'grass check, nowadays people in the most common life: jug, etc.) The transparent slope is designed to be able to pass through the material properties of the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Sexually, it has a special shouting that is not easily contaminated with dirt and odor. The drinker really tastes the contents of the cup = the white wine and the salty jealousy (4), and the red (in) the inner (4) Xin Hang tastes the new taste, will still make the people fear, easy to try. Therefore, how to use the aforementioned characteristics of the noble metal nanoparticles to design a method for manufacturing the glassware 2, so that the metal natriures can be uniformly sintered and fixed on the surface of the glassware to form a precious metal that never falls off. Naizheng membrane, ^ by the precious shouting area produced by the precious metal nanoparticle ride, play a long-lasting effect of anti-mite and anti-mildew, so that the side surface is not easily contaminated with dirt and odor, and can maintain a smooth and transparent characteristics' At the same time, 'can still catalyze the alcoholic beverages in glassware, so that the acid and _ 贞 秘 秘 转化 转化 旨 旨 , , , , , , , , , , , , , , , , , , 麟 麟 麟 麟 麟 麟 麟 麟 麟 麟 麟 麟 麟 麟The alcoholic beverage becomes more mellow, which is an important subject for the invention to be discussed and solved here. [Summary of the Invention] 201113233 In view of the problems in the traditional drinking culture mentioned above, after long-term efforts and experiments, the inventors finally developed a method for suppressing the hair of the present invention, which is intended to be coated with precious metals. Under the condition of smooth and transparent characteristics of the squash glassware, the noble metal nanoparticle film which is formed on the side surface of the glass dish will not be detached, and the long-acting two-proof mildew and catalysis effect can be exerted through the large specific surface area generated by the glassware_side surface. . The object of the present invention is to uniformly apply a layer-mixing solution on the inner side surface of a glassware (such as a wine glass, a wine bowl or a jug, etc.), the mixed solution is composed of water, water-soluble acrylic powder, Interface additive, water miscellaneous, #metal (such as: gold and silver) nanoparticles and hardened nanoparticles, etc., are uniformly mixed according to a predetermined weight percentage, the water-soluble acrylic spider A water-soluble dispersing agent, and the action is in the dissolution of the anger "the precious metal is good and the dioxetine is even and dispersed" "fooyant spray, the interface added _ - the surface solvent to remove the surface tension, the side system After the mixed solution wire_force is removed, so that the mixed solution is applied to the side surface of the glassware, it can be evenly distributed on the inner side surface to ensure uniform coating thickness of the mixed solution, and the water-hybrid adhesive It is coated on the precious metal naphtha and the dioxide wire surface; 嗣, after rapid drying treatment, the water of the mixed solution towel is quickly volatilized, and the precious metal nectar and the second-rolled fossil yin na Miscellaneous water, in the glass The inner side surface of the dish, and a uniform thin layer of tantalum is formed on the inner side surface of the glassware; finally, after the urban temperature sintering treatment, the temperature is the solubility of the rice dioxide particles, and the film makes the magnet dioxide The rice particles together with the noble metal attached thereto are ready to be placed on the surface of the glassware, and a precious metal nanoparticle film is formed on the inner surface of the glassware, due to the noble metal 201113233 meter particle film. Numerous uniformly distributed precious metal nanoparticles can produce a large specific surface area, so that the precious metal natriuretic acid has an excellent long-acting catalytic effect, which can be used to catalyze alcoholic beverages in glassware and make alcoholic beverages. The acids and alcohols are quickly catalyzed to be effective in reducing the toxic alcohols and alcohols in alcoholic beverages, thereby reducing the spicy or sour taste of alcoholic beverages, and increasing the vinegar content to make alcoholic beverages. Become more mellow. Another object of the present invention is a mixed solution of water, water-soluble acrylic powder, interfacial additive, water-soluble adhesive, dioxane, water-soluble carbonate, soluble precious metal (such as ··Gold And silver) salt and reducing agent and other ingredients, according to the predetermined weight percentage 'all screams' the water-based acrylic powder system - water-soluble g dispersing agent, its function is dissolved in water, can hinder the acid salt, The precious metal salt and the fossil granules are self-contained and mixed in the test towel. Because of the carbon salt and the water in the aqueous solution cap, it can be combined with the oxidized nanoparticle in the mixed solution to form a water-soluble solution. Acidic acid salt, in addition, because the precious metal salt has the property of dissociating the precious gold miscellaneous in the solution, and the noble metal ion has a polyoxygenate characteristic, and the polar acid is produced in the mixed solution. The clothing is evenly and surface-attached to the surface of the frequency salt. The reducing agent is glucose, which is used to slowly reduce the precious gold linings into metal nanoparticles, which adds the ship-removing force. Water_, its work (4) on the surface of the mixed solution The tension is such that the mixed solution is applied to the inner side of the glassware. The back surface can be uniformly distributed on the surface of the glass, and the mixed coating is thick and uniform, and the water-based adhesive can be in the mixed solution. During the preparation process, the surface of the coating is covered; the ride is quickly dried to make the water in the mixed solution quickly volatilize, and the acid salt can be attached by water-soluble adhesive. On the inner side surface of the glassware 201113233, a uniform thickness film is formed on the inner side surface of the glassware; finally, after the high temperature sintering treatment, the temperature is the melting temperature of the niobate, and the niobate in the film together The noble metal nanoparticles adhered thereto are sintered and fixed on the inner side surface of the glassware, and a noble metal nanoparticle film is uniformly formed on the inner side surface of the glassware. According to still another object of the present invention, the water-soluble acrylic powder is a polyacrylic acid derivative (polyacrylic add derivative) for uniformly dispersing the components in the mixed solution in the mixed solution without causing precipitation or siltation. The phenomenon of agglomeration, such that the cerium oxide nanoparticle (or cerium silicate) and the noble metal nanoparticles can be uniformly applied to the inner side surface of the glassware. According to still another object of the present invention, the interfacial additive is a polyether modified acryl fimctkmal potydimethylsil xane having an acrylic (acrolein-based polymer) function. The surface tension of the mixed solution is removed to be evenly distributed on the inner side surface after being applied to the inner side surface of the glass garment to ensure uniform coating thickness of the mixed solution, and at a high temperature After Lin, the oxidized transcript or Wei salt of the ship can be attached to the surface of the glass, so that the inner surface of the glassware can be kept clean and dense without causing uneven rough surface. . According to still another aspect of the present invention, the water-soluble adhesive comprises Urethane Pdymer, Ν·methylpyrrolidone cup ^%1 pyiT〇iid_), and triethyiamine. So that the cerium oxide nanoparticles (or sulphate) and the noble metal nanoparticles can be uniformly attached to the inner surface of the glassware to be uniformly formed on the surface of the glassware after sintering at a high temperature. The layer of noble metal nanoparticle film 'has its proper, anti-mildew and catalytic effect. 201113233 The female s 1 贞 查 查 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 贞 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有The inter-system is a method for coating precious metal nanoparticles in a glass dish. Referring to Figure 1, the method comprises the following steps: _ pouring a mixed solution containing noble metal nanoparticles into a glassware ( Such as: wine glasses, wine bowls or jugs, etc., and after shaking the glassware evenly, the mixed solution is poured out, and the glassware is placed upside down to be coated on the inner surface of the glassware ^ a layer containing a mixed solution of precious metal nanoparticles; (101) rapidly drying the glassware at a temperature of 50% to 5% to rapidly remove water in the mixed solution; and _ at 350 degrees Celsius, ie, mixing The melting temperature of the solution dodecaxide rice particles or the oxalate salt, the high temperature sintering treatment of the glassware, so that the dicepnet or the salt of the salt, together with the noble metal nanoparticles attached thereto, are sintered and fixed. The glass On the inner surface of the vessel, in order to have the noble metal nanoparticles hook topographic layer never fall off the film. In the present invention, in order to ensure that the noble metal nanoparticle film is less likely to be contaminated with dirt and odor, the glassware is kept clean and transparent, and can catalyze alcoholic beverages in the glassware, so that the acid and alcohol components in the alcoholic beverage are rapidly formed. Catalyzed as an ester to effectively reduce the toxic alcohol and tannin content in the lining drink, thereby reducing the spicy or sour taste of the alcoholic beverage, and increasing the _ content 'to make the alcoholic beverage more mellow' The composition must have the following four characteristics: 201113233 (1) It is necessary to uniformly disperse the cerium oxide nanoparticles or the cerium salt in the mixed solution without causing precipitation or siltation and agglomeration. The cerium oxide nanoparticles or ceric acid salt can be uniformly applied to the inner surface of the glassware; °° (2) The surface tension of the combined solution must be removed so that the mixed solution is applied to the glassware After the inner side surface, it can be evenly distributed on the inner side surface to ensure that the coating thickness of the mixed solution can be uniform and uniform, and the high-temperature sintering of the shell-shaped nano-nano The particle film can keep the inner surface of the glassware smooth and compact. It does not cause uneven surface and is not easy to be contaminated with dirt and odor. (3) After the sintering at the south temperature to form the noble metal nanoparticle film, It can maintain the smooth and transparent characteristics of the glassware; and, after sintering in the temperature of the elementary temperature, the cerium dioxide particles or the cerevisiae are uniformly attached to the inner side of the glassware. The surface, so that the metal nanoparticles attached to it can produce long-lasting anti-g, anti-mildew and catalytic effects. In a preferred embodiment of the present invention, the mixed solution is composed of water, ceria non-butterfly metal nanoparticles, water-soluble acrylic powder, interfacial additive, and water-borne adhesive component. The percentage of weight under the touch is self-mixed: (1) water · its weight percentage is 40%~70%; (a): oxidation > 5 glutinous nanoparticles: its weight percentage is 丨5%~7, in the real j The first is to grind the oxidized stone to a nanometer-sized granule '1 nm equals 1 part per billion (10-9 meter), or the nanometer-sized sub- ton is about 1~1 〇〇 Nano, nanoparticles between molecules and submicron; 11 201113233 (3) Shell metal nanoparticles: gold or silver nanoparticles, or a mixture of gold and silver nanoparticles, the weight percentage is 0.01 %〜1〇〇/0 ; (4) Water-soluble acrylic powder: 2%~3〇% by weight, wherein the water-soluble acrylic powder is a water-soluble dispersant, and its action is dissolved in After the water, the cerium oxide nano particles and the noble metal nanoparticles can be uniformly and dispersedly suspended in the mixed solution. The water-soluble acrylic powder is a polyacrylic acid derivative (p〇lyacrylic acid derivative), which can uniformly disperse the cerium oxide nanoparticles and the noble metal nanoparticles in the mixed solution without causing precipitation or siltation and agglomeration. The phenomenon, in this way, the bismuth oxide nanoparticles and the noble metal nanoparticles can be uniformly applied to the inner surface of the glassware with the mixed solution; (3) interface additive: the weight percentage is 〇〇5 % to 5%, the interface additive is a water solvent for removing surface tension, and the effect is to remove the surface tension of the mixed solution, so that the mixed solution is uniformly applied to the inner surface of the glass unit. On the inner side surface of the glassware, to ensure that the coating thickness of the mixed solution can be uniform. In this embodiment, the interface additive is a one having an acrylic (acrylic polymer) function. Polyether modified aeryl ftinetioiial polydimethylsiloxane can remove the surface tension of the mixed solution and make the mixed solution uniform. The cloth property can ensure uniform coating thickness of the mixed solution after being applied to the inner side surface of the glassware, so that after sintering at a high temperature, the inner surface of the glassware can be kept smooth and firm at all times. Produces rugged rough surface and is not easily contaminated with dirt and odor; and ~ 12 201113233 (6) Water-soluble adhesive: the weight percentage is 〇2%~1〇%, and the water-soluble adhesive is in the mixed solution In the preparation process, the surface of the cerium dioxide nanoparticles and the noble metal nanoparticles which are dispersed in the mixed solution can be coated, and the water-soluble adhesive comprises a polyurethane resin (Urethane P〇). Lymer), N_nonylpyrrolidone pyrr〇Ud〇 (4) and
二乙胺(Tnethylamine)等成份，能在混合溶液被塗佈至該玻 璃器皿的内側表面時，使二氧化石夕奈米粒子及貴金屬奈米 粒子能附著在該玻璃器皿的内側表面上，如此，經高^燒 結後’除能使該玻璃器皿的内側表面仍保辨光潔密實，不 致產生凹凸不平的粗#面外，亦能使炫融的二氧化石夕奈米 粒子與皿_絲面結合，而_貴金屬奈米粒 子’-起被燒結固定在該玻璃器皿的内側表面上，均勾地 形成一層貴金屬奈考粒子膜。 在本發明之另一最佳實施例中，該混合溶液係由水、二氧化 =奈米粒子、水溶性的碳酸鹽、水溶性的貴金屬鹽、還原劑 祕堡克力妹、界面添加做水溶,_著_成份，依下列的 重量百分比，均勻混合而成： (1)水：其重量百分比為25%〜60%; ⑶ 二氧化梦奈米粒子··其重量百分比為15%〜7 5%; 水溶性的碳酸鹽：其重量百公 為磁萨滅τ m 刀比為3/0〜15%，該碳酸鹽可 為厌夂_柳3)等’由於碳_具有 液’並在水溶液令解離出碳酸根離子的特性，故H 溶液中依下列化學式，與二氧切奈練子結 2 (Na203Si，俗稱為水玻璃）： " 13 201113233A component such as Tnethylamine can adhere the SiO2 nanoparticles and the noble metal nanoparticles to the inner surface of the glassware when the mixed solution is applied to the inner surface of the glassware. After the high-sintering, the inner surface of the glassware can be kept clear and compact, and the uneven surface of the glass can be prevented from being roughened, and the smear of the cerium dioxide particles and the dish can be made. In combination, the _ precious metal nanoparticles are sintered and fixed on the inner side surface of the glassware to form a layer of noble metal ruthenium particle film. In another preferred embodiment of the present invention, the mixed solution is made of water, dioxide = nano particles, water-soluble carbonate, water-soluble precious metal salt, reducing agent, secret oil, and water-soluble at the interface. , _ _ ingredients, according to the following weight percentage, evenly mixed: (1) water: its weight percentage is 25% ~ 60%; (3) oxidized Mengnai particles · · weight percentage of 15% ~ 7 5 %; water-soluble carbonate: its weight is 100% for magneto-salt τ m, the ratio is 3/0~15%, the carbonate can be 夂__3), etc. 'Because carbon_ has liquid' and is in aqueous solution To dissociate the characteristics of carbonate ions, so in the H solution according to the following chemical formula, and dioxodine to practice knot 2 (Na203Si, commonly known as water glass): " 13 201113233
Si〇2 + Na2C〇3 -> Na203Si + C02 (4)水/合的貝金屬鹽：其重量百分比為請〇乂〜跳，該貴金 屬孤可為氣化金(AuCU.^O)、醋酸金((cH3C〇〇)刺、確 I夂銀(AgN〇3)等’由於各該貴金屬鹽具有可完全溶解於水溶 液’亚在核射赫出貴金屬離子的雜，且貴金屬離 子又具魏氧畤ϋ，故極賴魏納上的氧產生物理吸 附而在該犯合〉谷液的調製過程中，均句且穩固地附著在 矽酸鈉的表面； (5)還原W •其重里百分比為ο·〕％] 5%，該還原劑可為葡萄 糖’其作用係在該混合溶液的調製過程中，將附著在石夕酸 鈉^的貴金屬離子緩慢_原成為貴金屬奈米粒子，且 ，貴金屬奈米粒子能穩固地附著在石夕酸鈉表面，如此，經 :溫燒結後，熔融的矽酸鈉能與破璃器皿的内側表面結 σ且連同貴金屬奈米粒子’一起被燒、结固定在該玻璃器 亚的内側表面上’而在該玻璃器皿的内側表面上均勻地形 成層分佈均勻且永不脫落的貴金屬奈米粒子膜； ⑹水溶_克力粉末：其重量百分比為2%〜3〇%，其作用係 在’谷解於水中後，忐使一氧化♦奈米粒子、碳酸鹽及貴金^ 屬鹽均勻且分散地懸浮在混合溶液中，而不致發生沉殺或 淤積結塊的現象，如此，始能使矽酸鈉表面均勻地形成貴 金屬奈米粒子，且使矽酸鈉被均勻地塗佈至該該玻璃器皿 的内側表面上； ° ⑺界面添加劑：其重量百分比為〇·〇5%〜5%，其作用係在去除 混合溶液的表面張力，使得混合溶液被塗佈至該玻璃器皿 201113233Si〇2 + Na2C〇3 -> Na203Si + C02 (4) Water/combined shellfish salt: its weight percentage is 〇乂~jump, the precious metal can be gasified gold (AuCU.^O), acetic acid Gold ((cH3C〇〇) thorn, indeed I 夂 silver (AgN〇3), etc. 'Because each of the precious metal salts has a solubility that can be completely dissolved in the aqueous solution, the noble metal ions in the nucleus, and the noble metal ions畤ϋ 故 故 故 故 故 故 故 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏ο·]%] 5%, the reducing agent can be glucose's action in the preparation process of the mixed solution, the noble metal ions attached to the sodium sulphate slowly become raw metal nanoparticles, and the precious metal The nano particles can be firmly attached to the surface of the sodium sulphate so that after the temperature sintering, the molten sodium citrate can be sintered and fixed together with the inner surface of the glassware and together with the noble metal nanoparticles. On the inside surface of the glass sub-' and on the inside surface of the glassware Forming a precious metal nanoparticle film with uniform distribution and never falling off; (6) Water-soluble gram powder: its weight percentage is 2%~3〇%, and its effect is after the solution of the solution in water, The rice particles, carbonates and precious metals are uniformly and dispersedly suspended in the mixed solution without causing the phenomenon of smothering or silting and agglomeration, so that the surface of the sodium citrate can be uniformly formed into the noble metal nanoparticles. And sodium citrate is uniformly applied to the inner surface of the glassware; ° (7) interface additive: its weight percentage is 〇·〇 5%~5%, the effect is to remove the surface tension of the mixed solution, so that The mixed solution was applied to the glassware 201113233
的内侧表面上後，能均勻地分佈在該玻璃器皿的内側表面 上，以確保混合溶液的塗佈厚度能均勻一致，且在高溫燒 結後，能使該玻璃器皿的内側表面始終保持光潔密實，不 致產生凹凸不平的粗糙面，且不易沾染污物及異味；及 (8)水,谷性黏著劑··其重量百分比為〇 〜，該水溶性黏著 劑係在該混合溶液的調製過程中，能包覆在混合溶液中均 勻分散的石夕酸鈉表面，以在混合溶液被塗佈至該玻璃器皿 的内側表面上後’能使石夕酸納均勻地附著在該玻璃器皿的 内側表面上，如此，經尚溫燒結後，溶融的石夕酸納即會與 該玻續器皿的内側表面結合，而連同貴金屬奈米粒子，二 起被燒結固定在該玻璃器皿的内側表面上 層貴金屬奈米粒子膜。 敗 實蝴巾’由於二氧切奈餘子或魏躺材料特 玻翻皿相容，故經高溫燒結處理後，餘的二氧化石夕夺 嫌結蚊在該麵11皿的_表面上，永久 氧^太作子=附者的貴金屬奈米粒子自然能隨著炫融的二 ===1= __皿軸表面永久結合 膜，不僅具有顯著的抑菌及抑 裡長对的不* 酒器内的騎飲品，使酒件σ 2生長的魏’並能催化玻璃 為_，以有效減少類成份被迅速催化 低酒精飲品的辛辣她氣味，且;二=含量’進而降 變得更為香醇順口。 -日頒的含罝，使酒精飲品 本發明在實際施作時 係將前述實施例應用至一酒壺，在該 201113233 酒亞，内側表面上均勻地燒結形成—層貴金屬奈米粒子膜，並將 该/酉亞委由台灣檢驗科技股份公司的超微量工業安全檢驗室，依 據USEPA5021的標準檢驗，使用氣相層析質譜儀，對該酒壺 的催化功能進行檢測，其檢測方式係將酒精濃度高達觀的金門 高，酒20毫升(mL)倒入該酒壺内，搖動該酒壺後取出Μ微升㈣ 的南梁酒’作為實驗組，空白組則為15微升(uL)未經處理的高梁 /酉並對一者中的乙醇、正丙醇、乙酸乙醋、異丁醇、異戊醇及 乳酸乙醋等六種成份含量，進行檢測，獲得如第2 _示的測試 結果(其編縣UG/2_B_641)，清楚顯示依本剌方法製成 的該酒壺，確實能催化赫内高梁酒，使高魏巾_類及醇類 成份被迅速催化為酯類，其中乳酸乙酯的增加量高達13 4%，且 能有效減少高梁_有毒及具辛辣感轉類，其巾正丙醇及異戍 醇的減少量亦分別高達5〇.7%及12%，進岐贿低了高梁酒的 毒性及強烈辛辣氣味，且因為大幅增加了酯類含量，而使得高梁 酒變得更為香醇且順口。 按，以上所述，僅為本發明的一最佳具體實施例，惟本發明 的特徵並不侷限於此，任何熟悉該項技藝者在本發明領域内，可 輕易思及的變化或修飾，皆應涵蓋在以下本發明的申請專利範圍 t。 【圖式簡單說明】 第1圖係本發明的製程示意圖；及 第2圖係針對本發明製作的酒壺’委由台灣檢驗科技股份公司的超 微量工業安全檢驗室檢測的結果示意圖。 16 201113233 【主要元件符號說明】After being disposed on the inner side surface, it can be evenly distributed on the inner side surface of the glassware to ensure uniform coating thickness of the mixed solution, and the inner surface of the glassware can be kept smooth and compact after high-temperature sintering. It does not cause uneven surface and is not easily contaminated with dirt and odor; and (8) water, gluten-based adhesive is 〇~, the water-soluble adhesive is in the preparation process of the mixed solution, The surface of the sodium sulphate which is uniformly dispersed in the mixed solution can be coated to uniformly adhere the sulphate to the inner side surface of the glassware after the mixed solution is applied to the inner surface of the glassware Thus, after sintering at room temperature, the molten sodium sulphate will be combined with the inner surface of the glass vessel, and together with the noble metal nanoparticles, the two layers of the precious metal nanoparticle are sintered and fixed on the inner surface of the glassware. Particle film. The succulent butterfly 'because of the compatibility of the dioxetine or the Wei lie material special glass dish, after the high temperature sintering treatment, the remaining sulphur dioxide is suspected of mosquitoes on the surface of the 11 dishes. Permanent Oxygen ^Taizizi = The precious metal nanoparticles of the attached person can naturally bind to the surface of the plate with the ===1= __ plate surface, which not only has significant antibacterial effect, but also does not affect the length of the pair. The drink in the wineware makes the wine σ 2 grow in the 'W' and can catalyze the glass as _, in order to effectively reduce the spicy odor of the low-alcoholic beverages that are quickly catalyzed by the class, and the second content is further reduced It is mellow. - 日 的 罝 罝 罝 罝 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精 酒精The 酉亚亚委 is tested by the ultra-micro industrial safety inspection room of Taiwan Inspection Technology Co., Ltd. according to the standard of USEPA5021, using the gas chromatography mass spectrometer to detect the catalytic function of the hip flask. The concentration of Jinmen is high, 20 ml (mL) of wine is poured into the jug. After shaking the jug, the Nanliang wine of the microliter (4) is taken as the experimental group, and the blank group is 15 μl (uL). Treated sorghum/酉 and test the contents of six components such as ethanol, n-propanol, ethyl acetate, isobutanol, isoamyl alcohol and lactic acid in one, and obtain the test as shown in the second The result (its county UG/2_B_641) clearly shows that the hip flask made according to the method of the present invention can indeed catalyze the sorghum wine, so that the high-wei towel and alcohol components are rapidly catalyzed into esters, of which lactic acid The increase in ethyl ester is as high as 13 4% and can be effective Shaogaoliang _ toxic and spicy, the reduction of n-propanol and isodecyl alcohol was as high as 5〇.7% and 12% respectively, and the bribes were low in the toxicity and strong spicy smell of sorghum wine, and Because of the substantial increase in the ester content, the sorghum wine becomes more mellow and smooth. The above description is only a preferred embodiment of the present invention, but the features of the present invention are not limited thereto, and any changes or modifications that can be easily conceived in the field of the present invention are known to those skilled in the art. The scope of patent application t of the present invention is to be covered as follows. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the process of the present invention; and Fig. 2 is a schematic diagram showing the results of testing by the ultra-micro industrial safety inspection room of Taiwan Inspection Technology Co., Ltd. for the jug produced by the present invention. 16 201113233 [Explanation of main component symbols]