TW201111763A - Measuring device for water suspended solid concentration by laser optical imaging technology and measuring method therefor - Google Patents
Measuring device for water suspended solid concentration by laser optical imaging technology and measuring method therefor Download PDFInfo
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201111763 六、發明說明: 【發明所屬之技術領域】 本案係關於-種水中懸浮顆粒(suspended s〇lid, 产 裝置及其制方法’尤其是關於—㈣射鮮影像切懸浮顆粒 濃度量測裝置及其量财法,以即時非減式光學影像技術量測 固定水體或動態水體的水t懸浮顆粒濃度,增加懸浮顆粒量測的 【先前技術】 水質為永續_水資_重要指標之…透過廢水處理系統 的自動化、最佳化及即時監測可有效提升廢水處理之穩定性'效 率及效益。-般水質量測項目包含懸浮顆粒(ss)濃度、水溫、酸驗 心導電度、氧化反應電位、化學需氧量、生物需氧量、有機物 貝,數、無機物質參數、溶氧量及濁度等。 -般的SS濃度制乡制細式ss濃度制設備,告 ί量測設備設惡劣環㈣造成量測設職應H損壞、二則品 貝不穩疋、清洗不易、雜訊干擾嚴重,而無法提供即時、準 水體SS濃紐據,而且f定難正增加餅維護成本。 在非接觸式的水質量财面,可湘水體電雜射模式監測 ^質,由於感測到的輻射量與水體污染物濃度、環境對光線吸收 專因素有關’並無法降低環境因子縣影響。此外,亦 :光譜分析建立水質量測綠,但其受水體馳散射出的 擾,降低水質量測的準確性。 丁 ',本案申請人鑑於f知技術中的不足,經過悉心試驗與研究, 二精神:終構思出本案「雷射光學影像水中懸浮 辰又里d裝置及其1測方法」’以非接觸式的懸浮顆粒濃度量 201111763 測^置、量測方法及設計出的演算法根據擷取的影像,可精準的、 ^時的1測水體的SS濃度,進而即時、有效、精確地監測水質, 能夠克服先前技術的不足,以下為本案之簡要說明。 、 【發明内容】 ,為了克服珂述的水質量測缺點,本發明以非接觸式的雷射光 子衫像水中SS濃度量測裳置、量測方法及演算法,量測水中懸浮 顆粒濃度,、而且該制裝置的建置成本減、可在不同場所&位 ❿置進订ss遭度量測,可即時、有效、精確地監測水質。 本發明提出一種量測液體的懸浮顆粒濃度的方法,該方法包 括下列步驟:(a)虛擬性地分割液體為複數個長方體;(b)射入第一 光束至複數個長謂的其巾之_,使複數個長方體散射出第二光 束;⑷由Μ個不_位魏取第二光束以形成M個影像,m為 大於或等於1的正整數;⑹計算河個影像的參數以得知吸光度; 及(e)由吸光度量測液體的懸浮顆粒濃度。 根據上述構想,液體為水體,複數個長方體還包括複數個正 ^ 方體。 根據上述構想’第二光束包括散誠,*散射光包括反射光、 折射光、繞射光、穿透光。 根據上述構想’參數包括穿透率、散解、折射率及其組合。 根據上述構想,步驟⑼的第一光束的射入方向相同或相異於 步驟(c)的擷取影像的方向。 根據上述構想,複數個長方體數目為N,N為正整數,N值 相同或相異於Μ值。 、本發明另提出一種液體中懸浮顆粒濃度的量測裝置,該液體 被虛擬丨生地力縣複數個長方體,該制裝置包括··影像掘取足 2〇i111763 置,其具有鏡頭,鏡軸向液體;及光源,將第_光束射入 數個長方體的其巾之…使複數錄謂賴㈣二歧。 像擷取裝置#貞取第二光束以形成M個影像,M為大於或等於/201111763 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a suspended particle (suspended s〇lid, a production device and a method for preparing the same), in particular, Its quantitative method, measuring the concentration of water suspended particles in fixed water or dynamic water by instant non-subtractive optical imaging technology, increasing the measurement of suspended particles [previous technique] water quality is perpetual _ water _ important indicators... through wastewater The automation, optimization and immediate monitoring of the treatment system can effectively improve the stability of the wastewater treatment 'efficiency and efficiency. The general water quality measurement project includes suspended particle (ss) concentration, water temperature, acid test core conductivity, oxidation reaction potential , chemical oxygen demand, biological oxygen demand, organic matter, number, inorganic material parameters, dissolved oxygen and turbidity, etc. - General SS concentration system for the production of fine ss concentration equipment, telling the measurement equipment is bad Ring (4) causes the measurement to be damaged by the H, the second is not stable, the cleaning is not easy, the noise is serious, and it is impossible to provide the instantaneous and quasi-water body SS, and it is difficult to increase The maintenance cost of the cake. In the non-contact water quality financial situation, the water quality of the Xiangshui body can be monitored, because the sensed amount of radiation is related to the concentration of water pollutants and the environment to the specific factors of light absorption. Factor county influence. In addition, spectral analysis establishes water quality measurement green, but it is disturbed by water body scattering, reducing the accuracy of water quality measurement. Ding', the applicant in this case in view of the shortcomings of the technology, after careful Experiments and research, the second spirit: I finally conceived the case "Laser optical image suspended in the water and the d device and its 1 measurement method" 'measured by non-contact suspended particle concentration 201111763 measurement method, measurement method and design The algorithm can accurately, accurately measure the water quality of the water body according to the captured image, and then monitor the water quality instantly, effectively and accurately, which can overcome the shortcomings of the prior art. The following is a brief description of the case. Contents] In order to overcome the shortcomings of water quality measurement, the present invention uses a non-contact laser photonic shirt image to measure the concentration, measurement method and algorithm of SS concentration in water. The concentration of the suspended particles in the medium, and the cost of the installation of the device is reduced, and the measurement can be measured at different places & positions, and the water quality can be monitored immediately, effectively and accurately. The invention proposes a measuring liquid The method for suspending particle concentration, the method comprising the steps of: (a) virtually dividing the liquid into a plurality of cuboids; (b) injecting the first beam into a plurality of lengths of the stalks thereof, scattering the plurality of cuboids a second beam; (4) taking a second beam from a non-bit to form M images, m being a positive integer greater than or equal to 1; (6) calculating parameters of the river image to know the absorbance; and (e) The absorbance measures the suspended particle concentration of the liquid. According to the above concept, the liquid is a water body, and the plurality of rectangular parallelepipeds further includes a plurality of square cubes. According to the above concept, the second light beam includes scattered light, and the scattered light includes reflected light, refracted light, Diffracted light and penetrated light. According to the above concept, the parameters include transmittance, dispersion, refractive index, and combinations thereof. According to the above concept, the incident direction of the first light beam of the step (9) is the same or different from the direction of the image captured by the step (c). According to the above concept, the number of plural cuboids is N, N is a positive integer, and the N values are the same or different from the Μ value. The present invention further provides a measuring device for the concentration of suspended particles in a liquid, which is virtualized to produce a plurality of rectangular parallelepipes, and the device comprises: an image capturing foot 2〇i111763, which has a lens, a mirror axis a liquid; and a light source, which injects the _beam into a plurality of cuboids of the cuffs thereof; Like the capture device #, the second light beam is taken to form M images, and M is greater than or equal to /
玉整數’並計算Μ娜像的參數崎知液體的料度,由吸 量測液體的懸浮顆粒濃度。 X ,據^述構想,液縣水體,而水料均質水體或非均質水 體’光源為雷射光源。 ' 執’量職置還包括散錄置,散絲置包括散 熱風扇及政熱片,用以維持量測裝置為恆溫。 根據上述構想,量測裝置還包括水平調整裳置 置包括水平儀、_輪及三杨親,用韓持量職置為水= 根據上述構想,影像擷取裝置連接至影像處理裝置。 根據上述構想,影像類取裝置朝向液體的方向與第一光束射 入液體的方向為同向或相異向。 根據上述構想,影像擷取裝置朝向液體的方向垂直於第一光 束射入液體的方向。 本發明另提出-種量職體_浮職濃度的方法,包括下 列步驟:⑻虛擬性地分割液體為複數個長方體;_人第一光束 至複數個長方體的其中之…使複數個長方體散射出第二光束;⑹ 由Μ個不同的位置擷取第二光束以形成M個影像,μ為大於或 專於1的正整數;(d)計算Μ個影像的強度;⑻計算Μ個影像的 強度中’第2強度與第丨強度相比之第i穿透率、第3強度與第2 ,度相比之第2穿透率及第M強度與第心強度相比之第 穿透率;ω由第1穿透率、帛2穿透率至第m ?透率計算穿透 率平句值’(g)以穿透率平均值及朗伯比爾定律計算吸光度;及⑻ 以吸光度量測液體的懸浮顆粒濃度。 201111763 根據上述構想’步驟(c)還包括步驟(Cl)轉化並計算影像為灰产 度,步驟⑹還包括步驟(dl)計算Μ個影像中第二光束的散射率^ 而步驟(h)還包括步驟(hi)以該吸光度計算該液體的濁度。 【實施方式】 本案所提出之「雷射光學影像水中懸浮顆粒濃度量測裝置及 其量測方法」將可由以下的實施例說明而得到充分瞭解,使^得熟 習本技藝之人士可以據以完成之,然而本案之實施並非可由列' # ^施例而被限制其實施型態,熟習本技藝之人士仍可依據除既揭 露之實施例的精神推演出其他實施例,該等實施例皆當 明之範圍。 田、货 φ 攝影機及光源數量並不限宗於一個 5 cti ^ 4S. SJ, ..The jade integer 'and calculates the parameter of the Μ娜 image to know the liquid content of the liquid, and absorbs the suspended particle concentration of the liquid. X. According to the concept, the water body of the liquid county, and the homogeneous water body or the heterogeneous water body of the water source is a laser light source. The 'exercise' position also includes the scatter recording, which includes a heat sink fan and a political heat sheet to maintain the measuring device at a constant temperature. According to the above concept, the measuring device further comprises a horizontal adjustment skirt, including a level, a _ wheel and a Sanyang pro, and a Han holding capacity is used for water. According to the above concept, the image capturing device is connected to the image processing device. According to the above concept, the direction of the image pickup device toward the liquid is in the same direction or in the opposite direction to the direction in which the first light beam enters the liquid. According to the above concept, the direction of the image capturing device toward the liquid is perpendicular to the direction in which the first beam of light is incident on the liquid. The invention further proposes a method for measuring the concentration of the occupational body, including the following steps: (8) virtually dividing the liquid into a plurality of cuboids; _ a first beam of the human to a plurality of cuboids ... scattering a plurality of cuboids a second beam; (6) drawing a second beam from a different position to form M images, μ being a positive integer greater than or specific to 1; (d) calculating the intensity of the image; (8) calculating the intensity of the image The first transmittance of the second intensity and the third strength, the second transmittance and the second transmittance, and the first penetration ratio of the Mth intensity and the first core strength; ω is calculated from the first transmittance, the 帛2 penetration rate to the m-th permeability, and the penetration rate is a flat sentence value '(g) is calculated as the average of the penetration rate and the Lambert Beer's law; and (8) is measured by absorbance The suspended particle concentration of the liquid. According to the above concept, step (c) further includes the step (Cl) converting and calculating the image as the gray production degree, and the step (6) further comprising the step (dl) of calculating the scattering rate of the second light beam in the two images, and the step (h) is further A step (hi) is included to calculate the turbidity of the liquid with the absorbance. [Embodiment] The "laser optical image suspended particle concentration measuring device and its measuring method" proposed in the present application will be fully understood by the following examples, so that those skilled in the art can complete it. However, the implementation of the present invention is not limited by the embodiment of the present invention. Those skilled in the art can still implement other embodiments in accordance with the spirit of the disclosed embodiments. The scope of the Ming. The number of cameras and light sources is not limited to a 5 cti ^ 4S. SJ, ..
及散熱片’用以維持量測裝置為恆溫, =參,第1 ffi ’為本發明實施例丨的雷射光學影像水中懸浮 顆粒濃度量測裝置(簡稱量測裝置)示意圖。在f】圖中,量測^置 主要由數位攝影機u (簡稱攝影機)及雷射光源 ^疋在—平台13顺成。攝影機11的鏡頭in及光源12朝向同 一侧’攝影機11將所擷取的影像傳送至電腦(未顯示)進行處理。 201111763 以降低溫度對篁測ss濃度的影響,而水平調整裝置包括水平儀、 調節輪及三轴加速規等,使每一次量測於同一基準面量測,降低 量測誤差。 請參閱第2圖,為本發明實施例丨的兩組量測裝置拍攝水體 影像的配置圖。在第2圖中,量測裝置1〇a、1〇b彼此垂直設置於 透明槽體14 (本實施例為玻璃材質,46 cm X 30 cm x 5〇 cm)上方及 侧面’數位攝影機11a的鏡頭111a及雷射光源12a朝向水體15 的水面,鏡頭111a擷取光源由水體射出的影像。攝影機仙的鏡 頭111b及光源12b朝向槽體14的側面,鏡頭mb擷取光源由槽 體側面射出的影像。在下述的實驗例中,將以第2圖的配置方^ 進行水中SS濃度量測。 然而’量測裝置數量可為-組或多組。t數量為—組時,量 測裝置設置於題周11之位置不限定於上域側面;當數量為多 組時,量測裝置的相對位置亦不限定於相互垂直。若量測裝置並 非水平設置於水體上方,或並非垂錢置於槽體侧面,所屬技術 領域中具有通常知識者可㈣修正量雕置的傾斜肢進行實驗 參數之修正。當槽财非長謂或立讀時,亦可依據實 設置量測裝置的位置及數量。 Μ 實驗=1垂直拍攝水平雷射光源入射水體的水中ss濃度量測 请參閱第3 ®,為本發明實施例i啦直減水平雷射光源 入射倾的水㈣浮難濃度量測示意圖。為了量測水中SS濃 度’操作者將水·紐齡割為複數個長方體。在第3圖中, 二數=方體為_大小的矩形單元1〜4。光束lQ水平射入水 士攝影機於水體上方娜光束丨。散射出水_影像。由於水體 擬性地分縣矩形單元1〜4,因此由矩形單元1〜4上方拍攝 、衫像之單几強度分別表示為a、b、c、d,電腦處理Rgb陣列 201111763 像素並計算影像灰階度(式i), ^+g+b r—=g 以微軟Excel軟體儲存資料。And the heat sink ′ is used to maintain the measuring device as a constant temperature, and the first ffi ′ is a schematic diagram of the laser optical image suspended particle concentration measuring device (abbreviated as measuring device) in the embodiment of the present invention. In the figure of f], the measurement is mainly made up of a digital camera u (referred to as a camera) and a laser light source. The lens in and the light source 12 of the camera 11 are directed toward the same side. The camera 11 transmits the captured image to a computer (not shown) for processing. 201111763 to reduce the influence of temperature on the measured ss concentration, and the level adjustment device includes a level, an adjustment wheel and a three-axis acceleration gauge, so that each measurement is measured on the same reference plane, reducing the measurement error. Referring to Fig. 2, there is shown a configuration diagram of photographing a water body image by two sets of measuring devices according to an embodiment of the present invention. In Fig. 2, the measuring devices 1a, 1b are arranged perpendicularly to each other in the transparent tank 14 (in this embodiment, glass material, 46 cm X 30 cm x 5 〇 cm) and on the side 'digital camera 11a'. The lens 111a and the laser light source 12a face the water surface of the water body 15, and the lens 111a captures an image of the light source emitted from the water body. The camera head 111b and the light source 12b face the side surface of the trough body 14, and the lens mb extracts an image of the light source emitted from the side surface of the trough. In the experimental example described below, the SS concentration measurement in water was performed in the arrangement of Fig. 2 . However, the number of measuring devices can be -group or groups. When the number of t is a group, the position of the measuring device at the week 11 is not limited to the side of the upper field; when the number is a plurality of groups, the relative positions of the measuring devices are not limited to be perpendicular to each other. If the measuring device is not horizontally placed above the water body, or if the money is not placed on the side of the tank body, those skilled in the art may (4) correct the amount of the inclined limb to correct the experimental parameters. When the slot is not long-term or vertical reading, the position and number of the measuring device can also be set according to the actual setting. Μ Experiment=1 Vertical measurement of the concentration of ss in the water incident on the horizontal laser source. Please refer to Section 3®, which is a schematic diagram of the direct exposure of the horizontal laser source to the incident tilted water (IV). In order to measure the SS concentration in water, the operator cuts the water·New Age into a plurality of cuboids. In Fig. 3, the binary number = rectangular unit 1 to 4 whose square body is _ size. The beam lQ is horizontally injected into the water camera above the water body. Scattered water_image. Since the water body is pseudo-divided into rectangular units 1 to 4 of the county, the single intensity of the shirt image is taken as a, b, c, and d, respectively, and the computer processes the Rgb array 201111763 pixels and calculates the image gray. The gradation (formula i), ^+g+br-=g stores data in Microsoft Excel software.
式I 而,直拍攝水平雷射光源的單位穿透率之計算方法為: ⑻第1單元強度=1()><單位散射率χ單位穿透率、& ;(b)第2單元強度=單位穿透率χΙ〇χ單位散射率^立穿透率2 = ·(〇第3單元強度,咖率2χΙ〇χ單位散射率χ單位穿3 C ?For the formula I, the unit penetration rate of the direct-shooting horizontal laser source is calculated as: (8) Unit 1 intensity = 1 () >< unit scattering rate χ unit transmittance, & (b) 2 Unit strength = unit penetration rate χΙ〇χ unit scattering rate ^ vertical penetration rate 2 = · (〇 3rd unit strength, coffee rate 2 χΙ〇χ unit scattering rate χ unit wear 3 C?
• (d)第4單it強度=單位穿透率3xIqX單位散射率χ單位穿透率4 (e) 單位穿透率=b/a=c/b=d/c ; (f) 計算所有穿透率平均值;及 (g)利用朗伯比爾 的吸光度A: 定律公式(式II),將平均穿透率代入計算水體• (d) 4th single it intensity = unit penetration rate 3xIqX unit scattering rate χ unit penetration rate 4 (e) unit penetration rate = b / a = c / b = d / c; (f) calculate all wear Average value of permeability; and (g) Substituting the average penetration rate into the calculation water body using Lambert Beer's Absorbance A: Law of Formula (Formula II)
式II A=l〇g1〇n Tave為平均穿透率。 之後,建立吸光度與SS濃度關係式,將此關係式寫入 NlL.abView圖控式程式語調程序巾,即可進行㈣材%濃度 的監測。若矩形單元數目為N時,第N單元強度為「單位穿^ N klox單位散射率X單位穿透率n = n」,其單位穿透率為·^。 實驗例1之實驗1 貫驗1的水體為固定水位高度且為人工配置的不同濃度高靡 土溶液,高駐溶液成分穩定且為均f,做為標準水f的鮮品。 水平雷射光源射入向嶺土溶液,攝影機在距離水面不同高度之處 垂直拍攝水體影像,量測吸光度與SS濃度。結果如第4圖所示, 201111763 當與水面距離固定時,高嶺土溶液濃度與吸光度呈正相關,若以 特定咼嶺土溶液濃度為觀察標的,其吸光度隨著距水面距離增加 而呈非線性衰減,因此可藉由吸光度與距水面距離之關係計算出 實際水體水位變化時之ss濃度變化趨勢。 實驗例1之實驗2 實驗2亦是以高嶺土溶液為水體,以垂直拍攝水平雷射光源 入射水體方式量測ss濃度,其結果如第5圖所示,吸光度與ss 濃度成正相關,可反應實際水質變化的狀況,並根據實際水質變 化提供即時資訊,達到自動控制及即時監測之目的。此外,實驗2 的量測方式也可計算出水體濁度(turbidity),請參閱第6圖,其為 影像測定吸光度與濁度的關係圖,由結果可以證實吸光度與濁度 成正相關,其線性函數為尸〇〇〇〇1又+〇〇〇79,相關係數R2 = 0.9363。實驗例1之眚驗3 實驗3則以廢水處理廠的連續流循序批分式活性污泥系統 (continuous-flow sequential batch reactor, CFSBR)放流水為水體,並 調整單位公分光徑長度(即矩形單元的寬度),以垂直拍攝水平雷射 光源入射水體方式量測SS濃度’根據雷射光源與ss作用所造成 的雷射散射光強度計算雷射光束每—單位公分光徑強度的穿透率 與吸光度’其結果如第7 ®所示。在同—濃度下,單位公分光徑 長度與吸光度成正比,證實吸光度之計算符合朗伯比爾定律,而 該定律成為量測SS濃度之理論依據。 請參閱第8圖,為本發明實驗例i實驗3的CFSBR實廠放流 水SS濃度與6公分光徑長度吸光度關係圖,第8圖以第^圖的^ 公分光徑長度為實驗數據,在第8圖中,各縱線的頂端與底端分 別代表水質量測誤差範圍的高值與低值,各縱線的中點^水所二 測的平均值,實心三角形符號(▲)為SS誤差範圍的吸光度而 201111763 符號表示水質量測平均值。由第8圖可知相當低SS濃度的放流水 具有良好的敏感度’吸光度隨SS濃度逐漸增加。因此,實施例i 的i測方式不只可應用於均質、穩定水體(如高嶺土溶液),'也可應 用於非均質水體(如廢水處理廠放流水)。 實驗例2垂直拍攝垂直雷射光源入射水體的水中ss濃度量測 請參閱第9圖,為本發明實驗例2之垂直拍攝垂直雷射光源 入射水體之水中懸浮顆粒量測示意圖。同樣地,水體被^擬性;也 分割為複數個長方體,成為相同大小的矩形單元丨〜4。光束〗〇水 籲平射人水_矩形單元1’攝影機於水體上方娜光束&散射出水 體的影像。由於水體被虛擬性地分割為矩形單元丨〜彳,因此於矩 形單元2〜4上方拍攝到的影像之單元強度分別表示為&、b、:, 像被計算為影像灰階度,而垂直拍攝垂直雷射 穿透率之計算方法為: ⑻,2單元強度=單位散射率xIqX單位散射率=a ; 〇>)第3單域度=單位散射率xIqX單位穿透率、單位散射率Formula II A = l〇g1〇n Tave is the average penetration. Then, establish the relationship between absorbance and SS concentration, and write this relationship into the NlL.abView graphical program tone program towel to monitor the concentration of (IV) material. When the number of rectangular units is N, the strength of the Nth unit is "unit wear ^ N klox unit scattering rate X unit transmittance n = n", and the unit transmittance is · ^. Experiment 1 of Experimental Example 1 The water body of the test 1 is a fixed water level height and is an artificially disposed high concentration of high-soil solution, and the high-resistance solution component is stable and is f, as a fresh product of the standard water f. The horizontal laser source is injected into the ridge solution, and the camera shoots the water image vertically at different heights from the water surface to measure the absorbance and SS concentration. The results are shown in Fig. 4. 201111763 When the distance from the water surface is fixed, the kaolin solution concentration is positively correlated with the absorbance. If the concentration of the specific kaolin solution is taken as the target, the absorbance decreases nonlinearly with increasing distance from the water surface. Therefore, the relationship between the ss concentration and the concentration of the actual water body can be calculated by the relationship between the absorbance and the distance from the water surface. Experiment 2 of Experiment 1 Experiment 2 also uses a kaolin solution as a water body to measure the ss concentration by vertically shooting a horizontal laser light source into the water. The result is shown in Fig. 5, and the absorbance is positively correlated with the ss concentration, which can reflect the actual The status of water quality changes, and provide real-time information based on actual water quality changes, to achieve automatic control and immediate monitoring purposes. In addition, the measurement method of Experiment 2 can also calculate the turbidity of water. Please refer to Figure 6, which is a graph showing the relationship between absorbance and turbidity. The results show that the absorbance is positively correlated with turbidity. The function is corpse 1 and +〇〇〇79, and the correlation coefficient is R2 = 0.9363. Experiment 1 of Experiment 1 3 Experiment 3 uses a continuous-flow sequential batch reactor (CFSBR) discharge water as a water body in a wastewater treatment plant, and adjusts the length of the unit centimeters (ie, a rectangle) The width of the unit), the vertical concentration of the horizontal laser light source is measured by the water source. The transmittance of the laser beam is calculated according to the intensity of the laser scattered light caused by the laser source and ss. With absorbance' the results are shown in Figure 7®. At the same concentration, the length of the unit centimeter is proportional to the absorbance. It is confirmed that the calculation of the absorbance is in accordance with Lambert Beer's law, and the law becomes the theoretical basis for measuring the SS concentration. Please refer to FIG. 8 , which is a graph showing the relationship between the SS concentration of the CFSBR real discharge water and the absorbance of the 6 cm optical path length of Experiment 3 of the experimental example i of the present invention, and FIG. 8 is the experimental data of the ^ cm diameter of the second figure. In Fig. 8, the top and bottom ends of each vertical line represent the high and low values of the water quality measurement error range, the average value of the midpoint of each vertical line, and the solid triangle symbol (▲) is SS. The absorbance of the error range and the 201111763 symbol indicates the average of the water quality. It can be seen from Fig. 8 that the discharge water having a relatively low SS concentration has a good sensitivity. The absorbance gradually increases with the SS concentration. Therefore, the i measurement method of the example i can be applied not only to homogeneous and stable water bodies (such as kaolin solution), but also to heterogeneous water bodies (such as wastewater treatment plant discharge water). Experimental Example 2 Measurement of ss concentration in water perpendicular to a vertical laser source incident on a water body Referring to Fig. 9, a schematic diagram of measurement of suspended particles in water incident on a vertical water source of a vertical laser light source in Experimental Example 2 of the present invention. Similarly, the water body is mimicked; it is also divided into a plurality of rectangular parallelepipeds to become rectangular units of the same size 丨~4. Beam 〗 〇 Water 平 射 人 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Since the water body is virtually divided into rectangular elements 丨~彳, the unit intensities of the images captured above the rectangular elements 2 to 4 are respectively represented as &, b, :, and the image is calculated as image gray scale, and vertical The calculation method for shooting vertical laser penetration rate is: (8), 2 unit intensity = unit scattering rate xIqX unit scattering rate = a; 〇 >) 3rd single domain degree = unit scattering rate xIqX unit transmittance, unit scattering rate
(c) 第4單元強度=單位散射率如單位穿鱗\單位散射率 (d) 單位穿透率=b/a=c/b ; (6)冲算所有穿透率平均值;及 的吸!^朗伯比収律公狱n),將平均穿透率代入計算水體 序中之s濃度關係士將此關係式寫入軟體程 n】:,強度為「單位散射率·單位穿透率'單位散L 一…,其單位穿透率為 早位散射率 11 201111763 實驗例2之實驗1 由於實驗例2主要是拍攝雷射光源的機制式散射光影像,因 此以非線性關係建立吸光度與ss濃度關係式。請參閱第1〇圖, f本發明貫驗例2實驗1的高嶺土絲ss濃度無光度關細。 第ίο圖之非線性函數相關係數為0989986,證實可利用垂直雷射 光源的政射光衰減強度比率計算穿透率及吸光度,當高嶺土溶液 濃度增加’吸紐雜之增加。料,亦可計算出水體濁度,請 參考第11圖’其為高嶺土溶液濁度與吸光度關細,證實吸光度 與濁度成正相關’其非祕函數為y = _G G⑻刪χ2+議G482x + 0.000648,相關係數 r2 = 0.982297。 鲁 此外,並分析不同濃度的高嶺土溶液與吸光度之關係,其結 果如第12圖所示。根據標準水質檢測方法,ss濃度量測誤差百 分比在25 mg/L以下為20%,以上為1〇% ,將誤差範圍繪製為水 貝分析的上限及下限,樣本中心線為水質分析結果,方塊頂端與 底端為可能的誤絲圍,而以實驗例2實驗i推估的濃度為距中 心線兩端崎®成的方塊’方塊頂端與底齡別為高估及低估實 際水質i析’實^圓點⑽)為影像分析的結果。由第12圖得知由 不同濃度的高嶺土溶液樣柄量測的ss濃度皆能反應實際水質· 的變化。 實盤例_^實驗2 貫驗2採用CFSBR模廠所馴養的活性污泥為研究對象。 CFSBR板薇將進流廢水經過厭氧相、好氧相、缺氧相、再曝氣相、 沈殿排,相等程序的處理,成為符合排放標準的放流水。一般而 言,厭氧相程序在沈殿排水相程序之後,經過一段時間才能將活 性污泥均勻授拌’厭氧相的SS濃度介於3000〜漏mg/L ;而好 氧相經過攪拌及曝氣等過程,使沈澱在底部之較大活性污泥揚 12 201111763 ,,好氧相的SS濃度介於5000〜8000 mg/L ;缺氧相程序則在好 乳,程序之後,由於沈澱污泥已被揚起,並缺少曝氣過程,為較 穩定之性質’缺氧相的SS濃度介於5000〜7000 mg/L。 ^在實驗2中,量測裝置架設於CFSBR模廠上方,厭氧相、好 氧相缺氧相的水體均經過5次循環,垂直拍攝垂直雷射光源入 射巧水的厭氧相、好氧相、缺氧相ss濃度量測,其結果如第13 圖⑻至第13圖(_示,吸光度與ss濃度絲性隱。並根據各 相建立的關係式作為CFSBR模廠每一循環的每一操作相之沾濃 #度"平估,而母個循環約為10小時,量測各項吸光度與SS濃度(結 果未示出)二而估計之SS濃度皆在人工分析的1〇%誤差範圍^了 厭氧相、好氧相、缺氧相之平均誤差分別為9.21%、8.06%、7.43%。 因此實驗例2實驗2之量測水體SS濃度不但可行並且正確。活性 污泥性質越穩定時’以本發明量财法獲得的量職果與人工分 析結果誤差越小。 此外,將上述CFSBR模廠處理後之放流水導入透明槽體(容 積為30 cm X 2〇cm X 20cm),以650 mn雷射光源水平入射槽體, 並垂直拍攝水平雷射光源之散射光強度影像,計算穿透率^ 度(量測方法如實驗例!所示)’其結果如第14圖所示,由^進流 廢水經厭氧相、好氧相、缺氧相等程序處理成為合乎排放標準的 放流水,此放流水SS濃度較低,處理後的ss性質昱於未妹 的SS性質’以人工分析處理後之ss易產生誤差(以標準方=測 的誤差範圍為2G%),因此第14圖所示的相關係數請6312比高 SS漠度的放流水低。細,對放流水而言,帛14 _之結果亦磴 實吸光度與放流水SS濃度成正相關。 '° e 實驗例3水平拍攝垂直雷射光源入射水想的水中ss濃度量測 請參閱第15圖,為本發明實驗例3之水平拍攝垂直雷射光源 13 201111763 顧崎啦意0。囉地,倾被虛擬性地 刀。'J為複數個長方體’成為相同大小的矩形單元!〜4。 J由 水體上方垂直射人水體,攝影機於水體側面擷取光束W射出0水 體的影像。祕水體被虛雜地分割為矩科元卜彳,因此於矩 形單元1〜4側_攝_影像之單元強度分職示為ab、c、d, 彩色影像輯算為影像麵度,財平補垂直雷射光源的 穿透率之計算方法為·· (a) 分層分析垂直雷射光散射光衰減強度的影像; (b) 依據水平入射雷射光影像分析方法(如實驗例 層穿透率; (c)計算每一分層吸光度; (Φ利用朗伯比爾定律公式(式π),將平均穿透率代入計算水體 的吸光度A;及 (e)建立吸光度與SS濃度關係式,將此關係式寫入軟體程序 中’即可進行即時水中SS濃度的監測。 本發明的實施例雖然是在槽體(水體)上方及側面分別設置量 測裝置,分別以(1)垂直拍攝水平入射的雷射光束、(2)垂直拍攝垂 直入射的雷射光束,及(3)水平拍攝垂直入射的雷射光束的散射/折 射光學影像,以量測水體SS濃度,但本領域的技術人員可藉由前 述實驗例1〜3的說明進行(4)水平拍攝水平入射的雷射光束之散 射/折射光學影像(即在第2圖中,攝影機ub的鏡頭nib拍攝雷 射光源12b散射/折射的光學影像),以量測水體ss濃度。或者, 可將二組量測裝置分別設置於槽體(水體)相鄰或相對的側面,或 者,將1測裝置分別設置於槽體(水體)側面或下方,或者將兩纟且量 測裝置設置於槽體(水體)上方及下方,依實際需要由不同角度拍攝 雷射光源射入水體後的光學影像,以量測水體SS濃度。 201111763 藉由前述實__述,本剌_置除了可量 本發明實雜能的鑛發明,深具產業價值,援依法提 請。此外,本發明可以由本躺技術人貞做任何做,但不脫離 如所附權利要求所要保護的範圍。 【圖式簡單說明】(c) Unit 4 strength = unit scattering rate such as unit penetration scale / unit scattering rate (d) unit penetration rate = b / a = c / b; (6) calculation of the average of all penetration rates; and suction !^ Lambert than the law prison j), the average penetration rate is substituted into the calculation of the water concentration in the s concentration relationship, this relationship is written into the software process n]:, the intensity is "unit scattering rate · unit penetration rate 'Unit dispersion L a..., its unit penetration rate is the early scattering rate 11 201111763 Experiment 1 of the experimental example 2 Since the experimental example 2 is mainly a mechanical scattered light image of a laser light source, the absorbance is established in a nonlinear relationship. Ss concentration relationship. Please refer to the first diagram, f. The kaolin ss concentration of experiment 1 of experiment 1 has no luminosity correlation. The nonlinear function correlation coefficient of the ίο diagram is 0989986, which proves that the vertical laser source can be utilized. The ratio of the attenuation of the political light to the transmittance and the absorbance are calculated. When the concentration of the kaolin solution increases, the turbidity of the water can be calculated. Please refer to Figure 11 for the turbidity and absorbance of the kaolin solution. Fine, confirming that the absorbance is positively correlated with turbidity' For y = _G G(8), delete χ 议 G482x + 0.000648, correlation coefficient r2 = 0.982297. Lu also, and analyze the relationship between different concentrations of kaolin solution and absorbance, the results are shown in Figure 12. According to the standard water quality test method, ss concentration The percentage of measurement error is 20% below 25 mg/L, and the above is 1〇%. The error range is plotted as the upper and lower limits of the water shell analysis. The sample center line is the water quality analysis result, and the top and bottom of the block are possible mis-wires. The concentration estimated by experiment i in experiment example 2 is the square of the square line from the two ends of the center line. The top and bottom ages of the square are overestimated and underestimated. The actual water quality is analyzed by the actual image (10). Results. It can be seen from Fig. 12 that the ss concentration measured by different concentrations of kaolin solution can reflect the change of actual water quality. The actual example _^Experiment 2 The inspection 2 uses the activated sludge domesticated by the CFSBR mold factory. For the research object, CFSBR will pass the influent wastewater through the anaerobic phase, aerobic phase, anoxic phase, re-exposure phase, and shoal, and process it into a discharge water that meets the discharge standard. Generally speaking, it is boring. Oxygen phase procedure After the Shen Dian drainage phase program, the activated sludge can be uniformly mixed after a period of time. The SS concentration of the anaerobic phase is between 3000 and leaking mg/L. The aerobic phase is subjected to agitation and aeration to make the precipitate at the bottom. Large activated sludge Yang 12 201111763 , the aerobic phase SS concentration is between 5000~8000 mg / L; the anoxic phase program is in good milk, after the procedure, because the sedimentation sludge has been raised, and lack of aeration The process, for the more stable nature, the SS concentration of the anoxic phase is between 5000 and 7000 mg/L. ^ In Experiment 2, the measuring device is erected above the CFSBR mold factory, the anaerobic phase, the aerobic phase and the anoxic phase. The water body was subjected to 5 cycles, and the anaerobic phase, the aerobic phase, and the anoxic phase ss concentration of the vertical laser source were vertically photographed. The results are shown in Fig. 13 (8) to Fig. 13 (_, absorbance and The ss concentration is silky. According to the relationship established by each phase, as the CFSBR mold factory, each operation phase of each cycle is condensed, and the mother cycle is about 10 hours. The absorbance and SS concentration are measured. The estimated SS concentrations are all in the 1%% error range of the manual analysis. The average errors of the anaerobic phase, the aerobic phase, and the anoxic phase are 9.21%, 8.06%, and 7.43%, respectively. Therefore, the measurement of the water SS concentration in Experiment 2 of Experimental Example 2 is not only feasible but correct. The more stable the nature of the activated sludge, the smaller the error in the results obtained by the method of the present invention and the results of the manual analysis. In addition, the discharged water treated by the above CFSBR mold factory is introduced into a transparent tank body (volume 30 cm X 2〇cm X 20 cm), and the tank body is horizontally incident with a 650 mn laser light source, and the scattered light of the horizontal laser light source is vertically photographed. Intensity image, calculate the penetration rate ^ (measurement method as shown in the experimental example!)' The results are shown in Figure 14, which is treated by the anaerobic phase, aerobic phase, and anoxic equalization process. The discharged water conforming to the discharge standard, the SS concentration of the discharged water is low, and the ss property after treatment is in the nature of the SS of the sister. The ss after the manual analysis is prone to error (standard range = error range of 2G%) Therefore, the correlation coefficient shown in Figure 14 is 6312 lower than the discharge water with high SS inversion. Fine, for the discharge water, the result of 帛14 _ is also positively correlated with the SS concentration of the discharged water. '° e Experimental Example 3 Horizontal shooting vertical laser light source incident water ss concentration measurement in water. Please refer to Fig. 15, which is a horizontal shooting vertical laser light source of the experimental example 3 of the present invention 13 201111763 Gu Qiyiyi 0. Daddy, dumped by a virtual knife. 'J is a plural cuboid' to become a rectangular unit of the same size! ~4. J shoots the water body vertically from above the water body, and the camera draws a beam of light from the side of the water body to emit an image of the water body. The secret water body is divided into the moments of the syllabary, so the unit intensity of the rectangular unit 1~4 side is shown as ab, c, d, and the color image is calculated as the image face, Caiping The calculation method of the transmittance of the complementary vertical laser source is: (a) stratified analysis of the attenuation intensity of the vertical laser light scattering light; (b) analysis method based on the horizontal incident laser light image (such as the experimental layer penetration rate) (c) Calculate the absorbance of each layer; (Φ use the Lambert Beer's law formula (formula π), substitute the average penetration rate into the absorbance A of the water body; and (e) establish the relationship between the absorbance and the SS concentration, In the relational writing software program, the monitoring of the SS concentration in the instant water can be performed. Although the measuring device is disposed above and on the side of the tank body (water body), respectively, (1) vertical shooting is horizontally incident. a laser beam, (2) a vertical shot of a vertically incident laser beam, and (3) a horizontally photographed scattering/refracting optical image of a vertically incident laser beam to measure a water body SS concentration, but those skilled in the art can borrow According to the description of the above Experimental Examples 1 to 3 (4) The scattering/refracting optical image of the horizontally incident laser beam is photographed horizontally (ie, in Fig. 2, the lens nib of the camera ub takes an optical image of the scattering/refraction of the laser light source 12b) to measure the water ss concentration. The two sets of measuring devices are respectively disposed on the adjacent or opposite sides of the tank body (water body), or the measuring devices are respectively disposed on the side or the bottom of the tank body (water body), or two measuring devices are disposed in the tank Above and below the body (water body), the optical image of the laser light source is injected into the water body from different angles according to actual needs to measure the water body SS concentration. 201111763 By the above-mentioned actual __ description, this 剌 _ 置 可 可 可The present invention is invented by the technical staff of the present invention, and can be carried out by the present invention without departing from the scope as claimed in the appended claims.
第1圖為本發明實施例1的雷射絲影像水中懸浮顆粒濃产 量測裝置示意圖。 X 第2圖為本發明實施例i的兩組量測裝置拍攝水體影像的配 置圖。 第3圖為本發明實施例1的垂直拍攝水平雷射光源入射水體 之水中懸浮顆粒濃度量測示意圖。 第4圖為本發明實驗例1實驗1的不同高嶺土溶液濃度的吸 光度與距水面距離關係圖。 第5圖為本發明實驗例1實驗2的高屬土溶液吸光度與%濃 度關係圖。 第6圖為本發明實驗例1實驗2之影像測定吸光度與濁度的 關係圖。 第7圖為本發明實驗例1實驗3的不同SS濃度濃度單位公分 光徑長度與吸光度關係圖。 第8圖為本發明實驗例1實驗3的CFSBR實廠放流水SS濃 度與6公分光徑長度吸光度關係圖。 第9圖為本發明實驗例2的垂直拍攝垂直雷射光源入射水體 之水中懸浮顆粒濃度量測示意圖。 15 201111763 第10圖為本發明實驗例2實驗1的*… 光度關侧。 ⑷的㈣土麵%濃度與吸 Γ1圖為本發明實驗例2實驗1的高嶺土溶液濁度與吸光度 關係圖。Fig. 1 is a schematic view showing the apparatus for measuring the concentration of suspended particles in a laser image in the first embodiment of the present invention. X Fig. 2 is a configuration diagram of photographing a water body image by the two sets of measuring devices of the embodiment i of the present invention. Fig. 3 is a schematic view showing the measurement of the concentration of suspended particles in water incident on a water body of a vertical shooting horizontal laser light source according to Embodiment 1 of the present invention. Fig. 4 is a graph showing the relationship between the absorbance of different kaolin solution concentrations and the distance from the water surface in Experiment 1 of Experimental Example 1 of the present invention. Fig. 5 is a graph showing the relationship between the absorbance of the high terrane solution and the % concentration of Experiment 2 of Experimental Example 1 of the present invention. Fig. 6 is a graph showing the relationship between the absorbance and the turbidity of the image of Experiment 2 of Experimental Example 1 of the present invention. Fig. 7 is a graph showing the relationship between the unit length of the SS concentration and the absorbance of the different SS concentration concentrations in Experiment 3 of Experimental Example 1 of the present invention. Fig. 8 is a graph showing the relationship between the SS concentration of the CFSBR plant discharge water and the absorbance of the 6 cm path length in Experiment 3 of Experimental Example 1 of the present invention. Fig. 9 is a view showing the measurement of the concentration of suspended particles in water incident on a vertical water source of a vertical laser light source according to Experimental Example 2 of the present invention. 15 201111763 Fig. 10 is the luminosity side of the experiment 1 of Experimental Example 2 of the present invention. (4) (4) Soil surface concentration and absorption 1 is a graph showing the relationship between the turbidity and absorbance of the kaolin solution of Experiment 1 of Experimental Example 2 of the present invention.
關係_本發明實驗例2實驗1㈣像推估與水質分析SS 第π圖⑻至第U圖(C)分別為本發明實驗例2實驗2之 CFSBR模廠進流廢水的⑻厭氧相、(b)好氧相及⑹缺氧相吸光度與 SS》辰度關係圖。Relationship _ Experimental Example 2 of the present invention Experiment 1 (4) Image estimation and water quality analysis SS π (8) to U (C) are the anaerobic phases of the inflow wastewater of the CFSBR mold factory of Experiment 2 of Experimental Example 2, respectively. b) aerobic phase and (6) relationship between absorbance of anoxic phase and SS.
第14圖為本發明實驗例2實驗2的放流水吸光度與ss濃度 關係圖。 第15圖為本發明實驗例3的水平拍攝垂直雷射光源入射水體 之水中懸浮顆粒濃度量測示意圖。 【主要元件符號說明】 第1圖 10 量測裝置Fig. 14 is a graph showing the relationship between the absorbance of the discharged water and the concentration of ss in Experiment 2 of Experimental Example 2 of the present invention. Fig. 15 is a view showing the measurement of the concentration of suspended particles in water of the horizontally-shot vertical laser light source incident in the experimental example 3 of the present invention. [Description of main component symbols] Figure 1 10 Measuring device
11 數位攝影機 111 鏡頭 12 雷射光源 13 平台 第2圖 10a、10b 量測裝置 11a、lib 數位攝影機 111a、111b 鏡頭 12a、12b 雷射光源 16 201111763 14 透明槽體 15 水體 第3圖、第9圖、第15圖 1〇 光束 卜2、3、4 單位長方體之矩形單元 a、b、c、d 影像之單元強度11 Digital camera 111 Lens 12 Laser light source 13 Platform 2D 10a, 10b Measuring device 11a, lib Digital camera 111a, 111b Lens 12a, 12b Laser light source 16 201111763 14 Transparent tank 15 Water body 3rd and 9th , Figure 15 Figure 1 单元 Beam, 2, 3, 4 unit rectangular rectangular unit a, b, c, d unit strength of the image
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US8941827B2 (en) | 2011-12-29 | 2015-01-27 | National Central University | Changed optical path measuring device for component concentration of water and measuring method thereof |
US9057608B2 (en) | 2012-08-27 | 2015-06-16 | 3Dfamily Technology Co., Ltd. | Simple type dual axes optoelectronic level |
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US9157849B2 (en) | 2011-12-29 | 2015-10-13 | National Central University | Changed optical path measuring device for component concentration of water and measuring method thereof |
TWI456185B (en) * | 2012-01-13 | 2014-10-11 | Oriental Inst Technology | Water turbidity detection system and the method thereof |
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