201042090 六、發明說明： 【發明所屬之技術領域】 本發明涉及一種電解***，更具體地說，涉及一種用於製備次氣酸 水的電解系統，將鹽酸予以電解生成氣氣，用水來混合所生成的氯氣， 以生成含有次氯酸的次氣酸水。 【先前技術】 次氣酸水為酸性電解水，含有次氯酸分子（HC1〇)，是一種pH為 5. 0〜6_ 5、有效氣濃度為10-3〇mg/L的水’這種次氣酸水具有較强的氧化 能力和快速殺滅微生物的作用。現有製備次氣酸水的電解系統包括電解 槽、自來水供應管路以及次氣酸水排出管路，自來水供應管路向電解槽 内供應添加了食鹽Nacl的自來水，電解槽内設有的陰、陽兩極電解片， 並設有離子隔膜，由離子隔膜將電解槽的陽極侧和陰極侧分開，其製備 原理是：將添加了食鹽Nacl的自來水，通過該帶有離子隔膜的電解槽電 解而成’由於離隔膜將電解槽的陽極侧和陰極侧分開，陽由氣離子C1_ 生成氣氣，然後進一步與H20反應生成鹽酸和次氯酸HC1〇，使從陽極槽 得到的水含10-50mg/L有效氣，然後再通過次氣酸水排出管路排入次氣 酸水容器。 然而，現有用於製備次氯酸水的電解系統主要存在下述問題：（1) 採用添加了食鹽Nacl的自來水為原料，需要利用帶有離子隔膜的電解槽 生成次氯酸水’錢離子隔朗價格昂貴，電解過程中容易堵塞，影響 電$效率；並且’現有的双槽隔膜式電解方式在生產過程中，陽極槽得 到-人氣酸水’陰極槽就得到等量的碱性水，而碱性水的利用價值低；（2) 電解過程中，高電流會通過電解片而產生熱量，熱量會增加電解片的阻 抗’使得電流流量減低，影魏氣的產生量，進而影響次氣酸水的生成 $率’（3)氣氣與水在電解槽中混合，但會存在少量的氣氣没有與水混 合’影響魏酸水的錢效率；⑷水流量、電解液流量 及次氣酸水的 有得财效_ ’使得所生成次紐水不符合押值的要求因 而有必要對現有_於製備次氯酸水的電解祕進行改進。 201042090 【發明内容】 電解’針對上述現有用於製備次氯酸水的 電=統，採用添加了食版1的自來水為原料，次氣酸水的生成率不 =的缺點’提供-種麟製備次氣酸水的電解祕，驗與自來: 為原料，能够有效提高次氯酸水的生成率。 本發明解决其技姻題所_的技财案是··提供—種驗製備·欠 氯酸水的電解系統’包括：電解槽、自來水供鮮路、次績水排出管 路、鹽酸供應管路以及與電解槽電性連接智能控制器；201042090 VI. Description of the Invention: [Technical Field] The present invention relates to an electrolysis system, and more particularly to an electrolysis system for preparing hypo-acid water, which is electrolyzed to form gas and gas, and mixed with water. The generated chlorine gas is generated to produce hypoqi acid water containing hypochlorous acid. [Prior Art] The secondary gas acid water is acidic electrolyzed water containing hypochlorous acid molecules (HC1〇), which is a water having a pH of 5.0 to 6_5 and an effective gas concentration of 10-3 〇mg/L. The secondary acid water has a strong oxidizing power and a fast killing effect on microorganisms. The existing electrolysis system for preparing hypo-acid water includes an electrolysis tank, a tap water supply line and a sub-gas acid water discharge line, and the tap water supply line supplies tap water to which the salt NaCl is added, and the cation and the yang provided in the electrolyzer The bipolar electrolyte sheet is provided with an ion membrane, and the anode side and the cathode side of the electrolysis tank are separated by an ion membrane. The preparation principle is: tap water added with salt NaCl is electrolyzed through the electrolysis cell with ion separator. Since the anode side and the cathode side of the electrolytic cell are separated from the separator, the gas is generated by the gas ion C1_, and then further reacted with H20 to form hydrochloric acid and hypochlorous acid HC1, so that the water obtained from the anode tank contains 10-50 mg/L. The effective gas is then discharged into the secondary acid water container through the secondary acid water discharge line. However, the existing electrolysis system for preparing hypochlorous acid water mainly has the following problems: (1) tap water supplemented with salt NaCl is used as a raw material, and it is necessary to generate hypochlorous acid water by using an electrolytic cell with an ion membrane. Lang is expensive, it is easy to block during electrolysis, affecting electricity efficiency; and 'the existing double-slot diaphragm type electrolysis method in the production process, the anode tank gets - the popular acid water' cathode tank gets the same amount of alkaline water, and The utilization value of alkaline water is low; (2) During the electrolysis process, high current will generate heat through the electrolyte sheet, and heat will increase the impedance of the electrolyte sheet, so that the current flow rate is reduced, and the amount of Wei gas is generated, thereby affecting the sub-gas acid. The water generation rate is '(3) gas and water are mixed in the electrolytic cell, but there will be a small amount of gas mixed with water', which affects the money efficiency of the acid water; (4) water flow, electrolyte flow rate and hypogasification The water has a financial effect _ 'making the secondary water produced does not meet the requirements of the deduction value and it is therefore necessary to improve the electrolysis of the existing _ in the preparation of hypochlorous acid water. 201042090 [Summary of the Invention] Electrolysis 'In view of the above-mentioned electric system for preparing hypochlorous acid water, the tap water added with the food plate 1 is used as a raw material, and the generation rate of the sub-acid acid water is not = the disadvantage of providing - seed preparation The electrolysis of the secondary acid water, the test and the self: as raw materials, can effectively increase the production rate of hypochlorous acid water. The technical solution for solving the technical problem of the present invention is to provide an electrolysis system for the preparation and preparation of hypochloric acid water, including: electrolysis tank, tap water supply fresh road, sub-performance water discharge pipeline, hydrochloric acid supply pipe The road and the intelligent controller electrically connected to the electrolytic cell;
Ο 所述電解槽内分隔形成有用於容納鹽酸電解液的内槽及用於流通自 來水的外槽’所述内槽内設有陰、陽兩極電解片，其下端開設有用於引 入鹽酸電解_電解液流人孔，上賴設有齡槽相連通的氣氣排出 口，所述外槽的下觸設有用於流人自來水的進水孔，其上側開設有用 於流出次氯酸水的出水孔； 所述自來水供應管路的一端設有入水口用於連接入水管，另一端連 接所述進水孔； 所述鹽酸供應管路的一端連接用於儲存鹽酸的鹽酸容器，另一端連 接所述電解液流入孔； 所述次氯酸水排出管路的一端連接所述出水孔，另一端設有出水口 用於連接次氣酸水容器或直接使用。 在本發明所述的用於製備次氣酸水的電解系統中，所述自來水供應 管路沿水流方向順序設有調壓閥、水壓表、過濾閥、兩通閥'限流器、 流量计以及單向閥，所述智能控制器與兩通閥及流量計電性連接，以對 水流流量進行實時監控。 在本發明所述的用於製備次氣酸水的電解系統中，所述鹽酸供應管 路上設有液體泵，所述智能控制器與液體泵電性連接，以對電解液流量 進行實時監控。 在本發明所述的用於製備次氯酸水的電解系統中，所述次氣酸水排 出管路上設酸碱感應器，所述智能控制器與酸域感應器電性連接，以對 201042090 次氣酸水的酸妨進行實時監控。 在本發明所述的用於製備次氯酸水的電解系統中，所述次氣酸水排 : 出管路上進一步設有混合器，所述混合器設於電解槽的出水孔和酸域感 • 應器之間’混合器包括内管及套設内管上的套管，所述内管的上方設有 梳板’所述梳板上開設有數個導孔。 在本發明所述的用於製備次氯酸水的電解系統中，所述氣氣排出口 靠近出水孔設於内槽的上端。 在本發明所述的用於製備次氯酸水的電解系統中，所述氯氣排出口 的設置南度〶於所述出水孔的設置高度。 Ο 。在本發明所述的用於製備次氯酸水的電解***中’所述内槽傾斜2〇 40放置’其中部設有_央電解片’所述中央電解片將内槽分隔為a 區、B區及C區，A區為電解液缓衝區，b區和c區為電解區，所述電解 液流入孔設於A區’所述陰、陽兩極電解片分别位於c區和B區。 在本發明所述的用於製備次氯酸水的電解系統中，所述中央電解片 的下方開設有2〜4mm的流通孑匕。 本發明的用於製備次氣酸水的電解系統的有益效果：（1)採用無隔 膜的電解系統，以來源廣泛、價格低廉的自來水和鹽酸為原料，由於没 有隔膜，操作簡便、生產效率高，且生產過程中，不產生喊性水，可以 〇 大量節約原料；（2)電解系統的電解槽分隔為内槽、外槽，内槽設於外 槽的内部並與外槽密封隔離，内槽容納鹽酸電解液，外槽流通自來水， 鹽酸電解液被電解後生成氣氣從氯氣排出口排出與外槽的自來水相結合 生成次氯酸（HC10) ’且外槽流通的自來水還能够冷却内槽的電解片，^ 够降低電解片的熱量，從而減低電解片的阻抗，避免影響氣氣的生成量。 (3)電解過程中，電解槽傾斜20。〜40°放置，避免電解液的流通不暢。 ⑷氣氣排出口靠近出水孔設置’氣氣排出口的設置高度高於出水孔的 設置高度’氣氣在混合區與自來水混合生成次氣酸，避免了鹽酸電解液 被自來水稀釋，且能穩定氣氣的排出量。（5)採用智能控制器，以電解 力、電解液流量和水流流量作為智能控制器的控制回路參數，來控制電 201042090 解槽的氣氣生產量，製得最有效的次氯酸水。（7)通過在自來水供應管 路上設置調壓閥、水壓表、過濾閥、兩通閥及限流器可以控制水流的壓 、 力和水流量；設置流量計用於量度水流量並向智能控制器反饋；設置單 向閥用於防止生成的次氯酸水回流。（8)通過在次氣酸水排出管路上設 置混合器，能够增加氣氣與水的混合量，提供次氯酸水的生成效率，通 過設置酸碱感應器，用於測定次氣酸水的PH值並向智能控制器反饋。綜 上所述’本發明的用於製備次氣酸水的電解系統的結構簡單，且能够有 效提高次氣酸水的生成率，所製得的次氣酸水具有殺菌和消毒的環保功 效0 〇 【實施方式】 如第一圖所示，第一圖是本發明優選實施例的用於製備次氣酸水的 電解系統的結構示意圖，第二圖是第一圖中電解槽的結構示意圖；本發 明的用於製備次氣酸水的電解系統，包括：電解槽1、自來水供應管路2、 次氣酸水排出管路3、鹽酸供應管路4以及智能控制器5。 參閱第二圖，第二圖所示是第一圖中電解槽的結構示意圖；所述電 解槽1内分隔形成有用於容納鹽酸電解液的内槽U及用於流通自來水的 外槽12，所述内槽u内設有陰、陽兩極電解片18、19，其下端開設有 用於引入幾酸電解液的電驗流入孔111，上端開設有與外槽12相連通 〇 ❾減排4 σ 112 ;所料槽12釘鋼鮮麟狀自來賴進水孔 121其上側開設有用於流出次氣酸水的出水孔122❶ 一自来水供應管路2的一端設有入水π 21，用於連接入水管（未圖 不）’另-端連接外槽12的進水孔121，用於向電解槽i的外槽12通入 自來水。鹽酸供應管路4的—端連接用於儲存鹽酸電解液的鹽酸容器 41，另—端連接内槽11的電解液流入孔111，用於向電解槽1的内槽11 通^酸。次氣酸水排出管路3的一端連接外槽12的出水孔122，另一 端设有出水口 33連接收納次氣酸水容器（未圖示），用於向次氯酸水容 器中排放次氣酸水。智能控制器5内設有電源概及控繼塊，所述電 源模塊與陰、陽兩極電解片18、19電性連接，提供陰、_極電解片 201042090 18、19直流電壓。 本發明的次氯酸水的生成原理是：以鹽酸電解液（HC1)及自來水 (H20)為原料，電解槽丨的内槽u通過鹽酸供應管路4引入鹽酸電解 液（HC1)，陰、陽兩極電解片18、19接通直流電壓，將鹽酸電解液（HC1) ，解生成氫氣（H2)和氣氣（C12)，電解槽1的外槽12通過自來水供應 管路2引入自來水（H2〇)與氣氣（C12)結合生成鹽酸（HC1)和次氣酸 (HC10) ’通過該電解系統能够製得具有殺菌、環保效果的次氣酸水，可 以作為食物添加劑，或作成消毒液。 參閱第一圖至第八圖’以下就電解系統的各部分結構進行詳述： 參閲第一圖’自來水供應管路2沿水流方向順序設有調壓閥22、水 壓表23、過濾閥24、兩通閥25、限流器26、流量計27以及單向閥28。 所述調壓閥22、水壓表23驗調節水翻壓力；所述過細24用於過 濾自來水中的雜質，所述兩通閥25、限流器26及流量計27用於控制水 流量，其中，兩通閥25及流量計27與智能控制器5電性連接，所述兩 通閥25為電磁閥，通過開啟或關閉控制水流的流通，所述流量計27用 於量度水流量並向智能控彻5反饋;職單_ 28麟防止生成的次 氣酸水從進水孔121處倒流回自來水供應管路2，上述元件可通過現有 技術實現。 鹽酸供應管路4上設有液體泵42，液體泵42與智能控制器5電性 連接，用於向電解槽1的内槽12内泵入鹽酸。 次氣酸水排出管路3上設有酸趟應^ 32，酸碱應^ 32與智能 控制器5電性連接’用於測定次氣酸水的pH值並向智能控制器反饋；值 得一提的疋，如第七圖所示，是第一圖中混合器的結構示意圖，次氣酸 水排出管路3上設魏合n 31 ’齡a 31設於電觸丨的丨水孔122 和酸域感應器32之間，所述混合器31包括内管311及套設内管311上 的套管312，所述内管311内部設有細管315，其上方設有梳板313，所 述梳板313上開設有數個導孔314’經過電解槽i的内槽u電解出的氣 氣在與外槽12巾的水結合後生產次氣酸水，然而，其中少量的氣氣並没 201042090 有混合在水中，通過增加混合器31，氣氣32和水可以在細管315中進 ' 一步的混合’並從導孔314中流出，能够提高次氯酸水的生成效率。 、 參㈣一圖及第人圖，第人®所枝本發明_於製備次氣酸水的 電解裝置的控制原理圖，所述智能控制器5與電解槽j電性連接以對 電解槽1的電解力進行實時控制，智能控制器5與兩通閱25及流量計 27電性連接’以對水流流量進行實時監控，智能控制器5與液體泵犯 電性連接’以電解液流量進行實時監控；智能控制器5與酸碱号犯 電性連接，以對次氣酸水的酸减度進行實時監控，電解力電解‘液流量 和水流流量作為智能控制器的控制回路參數，例如：當入水上、下1動 ¢) 時’智能控制器就對應地增加或減少電解力’來保證次氣酸水中次氣酸 分子（HC1G)的有效#，又如’自來水的軟硬度會影響次驗水生成的 酸喊度’智驗繼賴的增域減少祕餘量或電㈣，來控制電 解出魏氣的量來平衡祕生成的次級水驗雜，_通過智能控 制器5可以控制稿槽生麟需PH_次級水，製得最有效的次氣^ 水，該智能控制器可通過現有技術實現。 本發明的改進之處還在於如何穩定次氣酸水的生成所涉及的電解槽 的具體結構上的改進： θ 一、電解槽的冷却結構’用於冷却電解片。 〇 參閱第二圖及第三圖，如第三圖所示是本發明的用於製備次氯酸水 的電解系統的冷却結構原理圖；所述内槽丨丨的中部形成有用於容納鹽酸 電解液的内部空間，所述陰、陽兩極電解片18、19位於内槽11的兩側。 2述外槽12設于内槽11的外圍，外槽12内形成用於容納自來水的外部 空間’其下側開設有用於流入自來水（Η2〇)的進水孔121，其上侧開設 有用於流出次氣酸水（HC10)的出水孔122，所述進水孔121、出水孔 122與外部空間相連通。 電解過程中，高電流通過電解片而產生熱量，使得電解片的温度上 升’阻抗增加，電流流量減低’影響氯氣的產生量，採用上述結構，將 自來水從外槽12的進水孔121引入外部空間，由於自來水引入到内槽 09 201042090 11的外圍’因而能够有效冷却内槽11中的電解片，降低電解片的阻抗， • 避免影響到氣氣的生成量。 714 • 二、電解槽的生成結構，用於穩定生成次氯酸水。 參閱第二圖、第四圖及第五圖，第四圖是本發明的用於製傷欠氯酸 水的電解系統的生成結構原理圖；所述電解液流入孔111、氣氣排出口 112與内槽11的内部空間相連通，用於排出次氯酸水的出水孔122要接 近氣氣排出口 112，避免因電解槽1内壓力不穩定，而改變氣氣的排出 量，影響自來水和氯氣的混合比例，在本實施例中，所述氣氣排出口 ID 靠近出水孔122設於内槽11的上端，在氣氣排出口 112處為氯氣（C12) Ο 和自來水（H20)的混合區115，氯氣（C12)在混合區115與自來水混 合生成鹽酸（HC1)和次氣酸（HC10)，得到次氯酸水，從出水孔122流 出。 另外’值得一提的是’在正常運作時，鹽酸電解液不會被自來水稀 释’參閱第五圖是本發明的用於製備次氣酸水的電解系統的另一生成結 構原理圖；所述氣氣排出口 112的設高度高於所述出水孔122的設置高 度’圖示中示出了停止自來水供應後，外槽12的水位會降至氣氣排出口 112的平面高度以下’這樣就避免自來水進入内槽^，稀釋電解液。因 而’採用上述結構避免了鹽酸電解液被自來水稀釋》 〇 三、電解槽的結構及放置形式，用於穩定供應鹽酸電解液。 參閱第六圖’第六圖示出了優選實施施例的電解槽的内槽的結構米 意圖。在上述結構的基礎上，本實用新型的内槽U採用多槽式内槽’所 述内槽11的中部設有中央電解片23，所述中央電解片23將内槽11分 隔为A區13、B區14及C區15，A區13為電解液緩衝區，B區14和C 區15為電解區，電解液流入孔Hi設於a區，陰、陽兩極電解片18、 19分别設于C區和B區。中央電解片23的設置可以缓衝鹽酸電解浪 (HC1) ’優化電解效果。在本實施例中，電解槽1傾斜2〇。„40°放爹’ 以使内槽11也傾斜20。〜40。，或者内槽π直接傾斜2〇。〜40。設置。所述 中央電解片23的下方開設有2〜4mm的流通孔231。在電解過程中，電解 201042090 快，祕液他區13進人B區14，然後由B區 ▲m區15 ’ _雜進人b區14 _不足辄道被堵塞， ϋ解液就會從a區13進入c區15，再通過流通孔231對流到b 區14，電解_流通控锻為方便，避免***的電解液多於預算量， 使得次氣酸水較為穩定。Ο The electrolytic cell is formed with an inner tank for accommodating hydrochloric acid electrolyte and an outer tank for circulating tap water. The inner tank is provided with an anode and a cathode electrode plate, and the lower end is opened for introducing hydrochloric acid electrolysis_electrolysis The liquid flow manhole is provided with an air gas discharge port which is connected with the age groove, the lower groove of the outer groove is provided with a water inlet hole for flowing tap water, and the upper side is provided with a water outlet hole for discharging hypochlorous acid water. One end of the tap water supply pipe is provided with a water inlet for connecting the water inlet pipe, and the other end is connected with the water inlet hole; one end of the hydrochloric acid supply pipe is connected with a hydrochloric acid container for storing hydrochloric acid, and the other end is connected with the water supply container; The electrolyte is flowing into the hole; one end of the hypochlorous acid water discharge pipe is connected to the water outlet hole, and the other end is provided with a water outlet for connecting the secondary gas acid water container or directly used. In the electrolysis system for preparing hypoqi acid water according to the present invention, the tap water supply line is sequentially provided with a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve 'current limiter, and a flow rate along the water flow direction. And the check valve, the intelligent controller is electrically connected with the two-way valve and the flow meter to monitor the flow of water in real time. In the electrolysis system for preparing hypoqi acid water according to the present invention, a liquid pump is disposed on the hydrochloric acid supply pipe, and the intelligent controller is electrically connected with the liquid pump to monitor the electrolyte flow rate in real time. In the electrolysis system for preparing hypochlorous acid water according to the present invention, an acid-base sensor is disposed on the sub-gas acid water discharge line, and the intelligent controller is electrically connected with the acid domain sensor to the pair 201042090 The sour acid water can be monitored in real time. In the electrolysis system for preparing hypochlorous acid water according to the present invention, the sub-gas acid water drainage: the pipeline is further provided with a mixer, and the mixer is disposed in the water outlet hole and the acid domain of the electrolysis tank. • The mixer includes an inner tube and a sleeve on the inner tube, and a comb plate is disposed above the inner tube. The comb plate has a plurality of guide holes. In the electrolysis system for producing hypochlorous acid water according to the present invention, the gas discharge port is provided near the outlet hole at the upper end of the inner tank. In the electrolysis system for preparing hypochlorous acid water according to the present invention, the arrangement of the chlorine gas discharge port is set to a southerly than the set height of the water outlet hole. Oh. In the electrolysis system for preparing hypochlorous acid water according to the present invention, 'the inner tank is inclined 2〇40, and the central electrolytic sheet is disposed in the central portion to divide the inner tank into the area a, Zone B and Zone C, Zone A is the electrolyte buffer zone, Zones b and C are the electrolysis zones, and the electrolyte inflow holes are located in Zone A. The cathode and anode electrode plates are located in Zones C and B, respectively. . In the electrolysis system for producing hypochlorous acid water according to the present invention, a flow enthalpy of 2 to 4 mm is opened under the central electrolytic sheet. The beneficial effects of the electrolysis system for preparing hypoqi acid water of the invention are as follows: (1) using a diaphragm-free electrolysis system, using tap water and hydrochloric acid with wide sources and low prices as raw materials, and having simple operation and high production efficiency because there is no diaphragm. In the production process, no shouting water is generated, and a large amount of raw materials can be saved; (2) the electrolytic cell of the electrolysis system is divided into an inner tank and an outer tank, and the inner tank is disposed inside the outer tank and is sealed and isolated from the outer tank. The tank contains the hydrochloric acid electrolyte, the outer tank circulates the tap water, and the hydrochloric acid electrolyte is electrolyzed to generate gas. The chlorine gas is discharged from the chlorine gas discharge port and combined with the tap water of the outer tank to form hypochlorous acid (HC10)', and the tap water circulating in the outer tank can be cooled. The electrolytic sheet of the tank can reduce the heat of the electrolytic sheet, thereby reducing the impedance of the electrolytic sheet and avoiding the influence on the amount of gas generated. (3) During the electrolysis process, the electrolysis cell is tilted by 20. Place at ~40° to avoid poor electrolyte flow. (4) The gas discharge port is close to the water outlet hole. The setting height of the gas discharge port is higher than the set height of the water outlet hole. The gas is mixed with the tap water in the mixing zone to generate the sub-gas acid, which avoids the hydrochloric acid electrolyte being diluted by the tap water and stable. The amount of gas released. (5) Using the intelligent controller, the electrolysis force, the electrolyte flow rate and the water flow rate are used as the control loop parameters of the intelligent controller to control the gas production of the 201042090 solution tank to obtain the most effective hypochlorous acid water. (7) By setting a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve and a flow restrictor on the tap water supply line, the pressure, force and water flow of the water flow can be controlled; the flow meter is set for measuring the water flow and is intelligent Controller feedback; a check valve is provided to prevent the generated hypochlorous acid water from flowing back. (8) By providing a mixer on the secondary gas acid water discharge line, the mixing amount of gas and water can be increased, the production efficiency of hypochlorous acid water can be provided, and the acid-base sensor can be used for measuring the acidity of the secondary gas. PH value and feedback to the smart controller. In summary, the electrolysis system for preparing hypoqi acid water of the present invention has a simple structure and can effectively increase the generation rate of sub-acid acid water, and the produced sub-acid acid water has the environmental protection effect of sterilization and disinfection.实施 [Embodiment] As shown in the first figure, the first figure is a schematic structural view of an electrolysis system for preparing hypo-acid water according to a preferred embodiment of the present invention, and the second figure is a schematic structural view of the electrolysis cell in the first figure; The electrolysis system for preparing hypoqi acid water of the present invention comprises: an electrolysis cell 1, a tap water supply line 2, a secondary gas acid water discharge line 3, a hydrochloric acid supply line 4, and an intelligent controller 5. Referring to the second drawing, the second figure is a schematic structural view of the electrolytic cell in the first figure; the electrolytic cell 1 is internally formed with an inner tank U for accommodating hydrochloric acid electrolyte and an outer tank 12 for circulating tap water. The inner tank u is provided with the anode and cathode electropolar sheets 18 and 19, and the lower end is provided with a piezoelectric inflow hole 111 for introducing a few acid electrolyte, and the upper end is open to communicate with the outer tank 12, and the emission reduction is 4 σ 112 The trough 12 of the fresh steel ribbed water inlet 121 has a water outlet hole 122 for discharging the sub-acid acid water on the upper side thereof. One end of the tap water supply line 2 is provided with water π 21 for connecting the water inlet pipe (not The water inlet hole 121 of the outer tank 12 is connected to the other end to supply tap water to the outer tank 12 of the electrolytic cell i. The hydrochloric acid supply line 4 is connected at the end to the hydrochloric acid container 41 for storing the hydrochloric acid electrolyte, and the other end is connected to the electrolyte inflow port 111 of the inner tank 11 for supplying acid to the inner tank 11 of the electrolytic cell 1. One end of the secondary acid water discharge pipe 3 is connected to the water outlet hole 122 of the outer tank 12, and the other end is provided with a water outlet 33 connected to the secondary gas acid water container (not shown) for discharging to the hypochlorous acid water container. Gas acid water. The intelligent controller 5 is provided with a power supply and control block. The power module is electrically connected to the anode and cathode electrolysis sheets 18 and 19, and provides a DC voltage of 201042090 18, 19. The principle of the hypochlorite water of the present invention is: using hydrochloric acid electrolyte (HC1) and tap water (H20) as raw materials, the inner tank u of the electrolytic cell is introduced into the hydrochloric acid electrolyte (HC1) through the hydrochloric acid supply line 4, The anode electrolysis sheets 18 and 19 are connected to a direct current voltage, and the hydrochloric acid electrolyte (HC1) is decomposed to generate hydrogen gas (H2) and gas (C12). The outer tank 12 of the electrolytic cell 1 is introduced into the tap water through the tap water supply line 2 (H2〇). ) Combined with gas (C12) to form hydrochloric acid (HC1) and hypo-acid (HC10) 'The electro-chemical system can produce secondary acid water with bactericidal and environmental protection effects, which can be used as a food additive or as a disinfectant. Referring to the first to eighth figures, the following is a detailed description of the structure of each part of the electrolysis system: Referring to the first figure, the tap water supply line 2 is provided with a pressure regulating valve 22, a water pressure gauge 23, and a filter valve in the direction of the water flow. 24. Two-way valve 25, flow restrictor 26, flow meter 27, and check valve 28. The pressure regulating valve 22 and the water pressure gauge 23 adjust the water turning pressure; the excessively fine 24 is used for filtering impurities in the tap water, and the two-way valve 25, the restrictor 26 and the flow meter 27 are used for controlling the water flow rate. The two-way valve 25 and the flow meter 27 are electrically connected to the intelligent controller 5, and the two-way valve 25 is a solenoid valve for controlling the flow of water by opening or closing. The flow meter 27 is used for measuring water flow and Intelligent control 5 feedback; job list _ 28 Lin prevents the generated secondary acid water from flowing back from the water inlet hole 121 back to the tap water supply line 2, the above components can be realized by the prior art. A liquid pump 42 is provided on the hydrochloric acid supply line 4, and the liquid pump 42 is electrically connected to the intelligent controller 5 for pumping hydrochloric acid into the inner tank 12 of the electrolytic cell 1. The acid gas water discharge line 3 is provided with acid 趟 ^ 32, and the acid and alkali should be electrically connected with the intelligent controller 5 'for determining the pH value of the secondary acid water and feeding back to the intelligent controller; The rafter, as shown in the seventh figure, is a schematic view of the structure of the mixer in the first figure. The secondary gas acid water discharge pipe 3 is provided with Weihe n 31 'a 31 a 31 set in the water hole 122 of the electric contact 丨Between the acid field sensor 32 and the acid field sensor 32, the mixer 31 includes an inner tube 311 and a sleeve 312 on the inner tube 311. The inner tube 311 is internally provided with a thin tube 315, and a comb plate 313 is disposed thereon. The comb plate 313 is provided with a plurality of guide holes 314'. The gas which is electrolyzed through the inner tank u of the electrolytic cell i is combined with the water of the outer tank 12 to produce hypoqi acid water. However, a small amount of gas is not present. 201042090 In the case of mixing in water, by adding the mixer 31, the gas 32 and water can be mixed in one step in the thin tube 315 and flow out from the pilot hole 314, thereby improving the production efficiency of hypochlorous acid water. , (4) a figure and a figure of the person, the first person, the invention, the control principle diagram of the electrolysis device for preparing the hypo-acid water, the intelligent controller 5 is electrically connected with the electrolytic cell j to the electrolytic cell 1 The electrolysis force is controlled in real time, and the intelligent controller 5 is electrically connected with the two through 25 and the flow meter 27 to monitor the flow of the water in real time, and the intelligent controller 5 is electrically connected with the liquid pump. Monitoring; the intelligent controller 5 is electrically connected with the acid-base number to monitor the acid reduction of the sub-acid acid water in real time, and the electrolysis force electrolysis 'liquid flow rate and water flow rate are used as control loop parameters of the intelligent controller, for example: when When entering the water, the next one, the 'intelligent controller will increase or decrease the electrolysis force correspondingly' to ensure the effectiveness of the sub-gas acid molecule (HC1G) in the sub-acid acid water, and the hardness of the tap water will affect the time. The acidity of the water generated by the water test's increase in the domain to reduce the amount of secrets or electricity (four), to control the amount of Wei gas to balance the secret generation of secondary water, _ through the intelligent controller 5 can control Draft slotted with PH_secondary water, made Ci ^ effective water gas, the smart controller may be realized by the prior art. The improvement of the present invention is also in how to stabilize the specific structural improvement of the electrolytic cell involved in the formation of the sub-acid water: θ I. The cooling structure of the electrolytic cell is used for cooling the electrolytic sheet. Referring to the second and third figures, as shown in the third figure, a schematic diagram of the cooling structure of the electrolysis system for preparing hypochlorous acid water of the present invention; the middle portion of the inner tank is formed to accommodate hydrochloric acid electrolysis The inner space of the liquid, the negative and negative electrode sheets 18, 19 are located on both sides of the inner tank 11. 2, the outer tank 12 is provided at the outer periphery of the inner tank 11, and the outer space 12 is formed with an outer space for accommodating tap water. The lower side thereof is provided with a water inlet hole 121 for flowing tap water, and the upper side is opened for the upper side. The water outlet hole 122 of the sub-acid acid water (HC10) flows out, and the water inlet hole 121 and the water outlet hole 122 communicate with the external space. During the electrolysis process, a high current generates heat through the electrolytic sheet, so that the temperature rise of the electrolytic sheet increases, the impedance increases, and the current flow rate decreases, which affects the amount of chlorine gas generated. With the above structure, tap water is introduced from the water inlet hole 121 of the outer tank 12 to the outside. The space is introduced into the outer periphery of the inner tank 09 201042090 11 by the tap water', thereby effectively cooling the electrolytic sheet in the inner tank 11, reducing the impedance of the electrolytic sheet, and avoiding the amount of gas generated. 714 • Second, the formation of the electrolytic cell, used to stabilize the production of hypochlorous acid water. Referring to the second, fourth and fifth figures, the fourth drawing is a schematic diagram of the generation structure of the electrolysis system for injuring hypochlorous acid water of the present invention; the electrolyte inflow hole 111 and the gas discharge port 112. In communication with the inner space of the inner tank 11, the water outlet hole 122 for discharging the hypochlorous acid water is close to the gas discharge port 112, thereby avoiding the change of the gas output due to the unstable pressure in the electrolytic cell 1, affecting the tap water and In the present embodiment, the gas discharge port ID is disposed near the outlet hole 122 at the upper end of the inner tank 11, and at the gas discharge port 112 is a mixture of chlorine gas (C12) Ο and tap water (H20). In the region 115, chlorine gas (C12) is mixed with tap water in the mixing zone 115 to form hydrochloric acid (HC1) and hypogas acid (HC10) to obtain hypochlorous acid water, which flows out from the water outlet hole 122. In addition, it is worth mentioning that 'the hydrochloric acid electrolyte is not diluted by tap water during normal operation'. FIG. 5 is a schematic diagram of another generation structure of the electrolysis system for preparing hypoqi acid water of the present invention; The set height of the gas discharge port 112 is higher than the set height of the water outlet hole 122. The figure shows that after the tap water supply is stopped, the water level of the outer tank 12 is lowered below the plane height of the gas discharge port 112. Avoid running tap water into the inner tank and dilute the electrolyte. Therefore, the above structure is used to avoid dilution of the hydrochloric acid electrolyte by tap water. 〇 Third, the structure and placement of the electrolytic cell are used for stably supplying the hydrochloric acid electrolyte. Referring to the sixth drawing, the sixth figure shows the structural design of the inner tank of the electrolytic cell of the preferred embodiment. On the basis of the above structure, the inner tank U of the present invention adopts a multi-tank inner tank. The central portion of the inner tank 11 is provided with a central electrolytic sheet 23, and the central electrolytic sheet 23 divides the inner tank 11 into an A zone 13 , Zone B 14 and Zone C 15 , Zone A 13 is the electrolyte buffer zone, Zone B 14 and Zone C 15 are the electrolysis zone, electrolyte inflow hole Hi is set in zone a, and the anode and cathode electrode plates 18 and 19 are respectively set. In Areas C and B. The central electrolytic sheet 23 is arranged to buffer the hydrochloric acid electrolysis wave (HC1)' to optimize the electrolysis effect. In the present embodiment, the electrolytic cell 1 is inclined by 2 turns. „40°放爹' so that the inner groove 11 is also inclined by 20 to 40., or the inner groove π is directly inclined by 2〇.~40. The central electrolytic sheet 23 is provided with a flow hole 231 of 2 to 4 mm below. In the electrolysis process, the electrolysis 201042090 is fast, the secret liquid in the area 13 enters the B area 14, and then the B area ▲m area 15 ' _ miscellaneous into the b area 14 _ insufficient sputum is blocked, the sputum will be from The a zone 13 enters the c zone 15, and then convects to the b zone 14 through the circulation hole 231. The electrolysis_circulation control forging is convenient, and the injecting electrolyte is prevented from being more than the budget amount, so that the secondary gas acid water is relatively stable.
s本發明_於製備次氣酸水的電解祕具有下述特點：⑴採用無 釀的電解祕’以麵廣泛、價格低廉的自來和舰為原料由於没 有隔膜’操作簡便、生產效率高，且生產過程中，不產生.水，可以 大量節約原料；⑵電解系統的電解槽分隔為内槽、外槽，内槽設於外 槽的内部並與外槽密封_，内槽容納紐電解液，外槽流通自來水， 鹽酸電解液被冑麟生成氣氣從減排Λ ϋ翻斜獅自來水相结合 生成次氣酸（HC10)，且外槽流通的自來水還能够冷却内槽的電解片，能 够降低電解片的熱量，從而減低電解片的阻抗，避免影響氣氣的生成量。 (3) 電解過程中，電解槽傾斜2〇。〜4〇。放置，避免電解液的流通不暢。 (4) 氯氣排出口靠近出水孔設置，氣氣排出口的設置高度高於出水孔的 設置南度’氣氣在混合區與自來水混合生成次氯酸，避免了鹽酸電解液 被自來水稀釋’且能穩定氣氣的排出量。（5)採用智能控制器，以電解 力、電解液流量和水流流量作為智能控制器的控制回路參數，來控制電 解槽的氣氣生產量’製得最有效的次氯酸水。（7)通過在自來水供應管 路上設置調壓閥、水壓表、過濾閥、兩通閥及限流器可以控制水流的麗 力和水流量；設置流量計用於量度水流量並向智能控制器反餽；設置單 向閥用於防止生成的次氯酸水回流。（8)通過在次氣酸水排出管路上設 置混合器’能够增加氣氣與水的混合量，提供次氣酸水的生成效率，通 過設置酸碱感應器，用於測定次氣酸水的ΡΗ值並向智能控制器反饋。综 上所述，本發明的用於製備次氣酸水的電解系統的結構簡單，且能够有 效提高次氣酸水的生成率，所製得的次氯酸水具有殺菌和消毒的環保功 效0 以上所述，僅為本發明較佳的具體實施方式’但本發明的保護範圍 11 201042090 並不局限於此，任何熟悉本技術領域的技術人員在本發明揭露的技術範 圍内，可輕易想到的變化或替換，都應涵蓋在本發明的保護範圍之内。 因此，本發明的保護範圍應該以權利要求的保護範圍為準。 【圖式簡單說明】 第一圖是本發明的用於製備次氣酸水的電解系統的示意圖； 第二圖是第一圖中電解槽的結構示意圖； 第三圖是第二圖所示的電解槽的冷却結構原理圖； 第四圖是第二圖所示的電解槽的生成結構原理圖；The invention has the following characteristics: (1) using a non-brewed electrolysis secret to use a wide-ranging, low-cost self-contained ship and a ship as a raw material, because there is no diaphragm, the operation is simple, and the production efficiency is high. In the production process, water is not produced, and the raw materials can be saved in a large amount; (2) the electrolytic cell of the electrolysis system is divided into an inner tank and an outer tank, and the inner tank is disposed inside the outer tank and sealed with the outer tank _, the inner tank accommodates the new electrolyte The tap water is circulated in the outer tank, and the hydrochloric acid electrolyte is produced by the unicorn gas from the emission reduction ϋ ϋ 斜 自 自 tap water to produce the sub-gas acid (HC10), and the tap water circulating in the outer tank can also cool the inner pot of the electrolytic sheet, Reduce the heat of the electrolytic sheet, thereby reducing the impedance of the electrolytic sheet and avoid affecting the amount of gas generated. (3) During electrolysis, the cell is tilted 2 〇. ~4〇. Place to avoid poor circulation of electrolyte. (4) The chlorine gas discharge port is arranged close to the water outlet hole, and the set height of the gas gas discharge port is higher than the setting of the water outlet hole. The gas is mixed with tap water in the mixed zone to generate hypochlorous acid, which avoids the hydrochloric acid electrolyte being diluted by tap water. It can stabilize the discharge of gas. (5) Using the intelligent controller, the electrolysis force, the electrolyte flow rate and the water flow rate are used as the control loop parameters of the intelligent controller to control the gas production volume of the electrolysis tank to produce the most effective hypochlorous acid water. (7) The pressure and water flow of the water flow can be controlled by providing a pressure regulating valve, a water pressure gauge, a filter valve, a two-way valve and a flow restrictor on the tap water supply line; the flow meter is set for measuring the water flow and is intelligently controlled. Feedback; set a check valve to prevent the formation of hypochlorous acid water backflow. (8) By providing a mixer on the sub-gas acid water discharge line, the mixing amount of gas and water can be increased, the generation efficiency of the sub-gas acid water can be provided, and the acid-base sensor can be used for the determination of the sub-acid water. Depreciate and feed back to the intelligent controller. In summary, the electrolysis system for preparing hypoqi acid water of the invention has a simple structure and can effectively increase the generation rate of the sub-acid acid water, and the produced hypochlorous acid water has the environmental protection effect of sterilization and disinfection. The above description is only a preferred embodiment of the present invention. However, the protection scope 11 201042090 of the present invention is not limited thereto, and any person skilled in the art can easily think of it within the technical scope disclosed by the present invention. Variations or substitutions are intended to be covered by the scope of the invention. Therefore, the scope of protection of the present invention should be determined by the scope of the claims. BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a schematic view of an electrolysis system for preparing hypo-acid water according to the present invention; the second figure is a schematic structural view of the electrolysis cell in the first figure; Schematic diagram of the cooling structure of the electrolytic cell; the fourth drawing is a schematic diagram of the generating structure of the electrolytic cell shown in the second figure;
第五圖是第二圖所示的電解槽的另一生成結構原理圖； 第六圖是第二圖所示的内槽的優選實施例的結構示意圖； 第七圖是第一圖中混合器的結構示意圖； 第八圖是本發明的用於製備次氣酸水的電解系統的控制原理圖。 【主要元件符號說明】 1 電解槽 11 内槽 111流入孑L 112排出口 115混合區 12 外槽 121進水孔 122 出水孔 13 A區 14 B區 15 C區 2 電解片 21 陰極電解片 22 陽極電解片 23 中央電解片 231流通孔 12Figure 5 is a schematic view showing another structure of the electrolytic cell shown in the second figure; Figure 6 is a schematic structural view of a preferred embodiment of the inner groove shown in the second figure; Schematic diagram of the structure; Figure 8 is a schematic diagram of the control of the electrolysis system for preparing hypoqi acid water of the present invention. [Main component symbol description] 1 Electrolytic tank 11 Inner tank 111 flows into 孑L 112 Discharge port 115 Mixing zone 12 Outer tank 121 Inlet hole 122 Outlet hole 13 A zone 14 B zone 15 C zone 2 Electrolytic sheet 21 Cathode electrolytic sheet 22 Anode Electrolytic sheet 23 central electrolytic sheet 231 through hole 12