201039906 六、發明說明： 【發明所屬之技術領域】 本發明係一種具奈米抗病菌及除臭效果的空氣濾網及其製作方 法，尤指是一種能使空氣濾網表面輻射出α射線、P射線、γ射線或X 射線，_域失去電子的方式，把電子釋_轉巾，哺續釋放 出負離子，且能激發空氣濾網表面上佈植的短纖維分別產生輔助光觸 媒及觸媒作用’以實現對細8、病毒及黴g等有機物的降解者。 【先前技術】 據統計’在大都會中，人們每天約有8G〜9G%的時間生活在室内 環境(包括··住家、辦公室或其他賴_)，室内空氣品質的良窥， 將直接影響人_生活品f及功效率，因此，室岭氣污染物對人 們身體健康的影響’自然受到極大的重視。在密_築物内，如果室 内通氣量从時’污祕容易隨著時間碎積，導致室内空氣品質惡 ❹ t I外請的〉可染物包括：戶外汽機車、工廠排放的廢氣，或因 央空調冷氣系統的進氣口或滤網未定期清理而孳生的微生物等，也 會影響室内空氣的品質。尤其是，台灣地處亞熱帶，屬於長年潮渴高 溫的氣候型態，細菌、症主及徽結六旦兹止 干钥“同 病毋及黴H生’因此，空調通風系統及 重叙清理，即絲必_卜注意且確實執行的 夏要爭項。 綠濾網，主要功能係在滤除 ，、轉懸汁微粒依其粒徑大小對呼吸道會造成不同 '^曰 將粒也小於或等於10_的微粒稱之為吟吸性微粒，因 4 201039906 為該等微粒會隨著呼吸作用進入呼吸系統，並依其粒徑由大至小分別 "L積於冗腔啤吸道及肺泡細胞，而室内環境中呼吸性懸浮微粒的來 源有吸煙、煮、建材中之石缔、人造礦物纖維、植物花粉、動物性 過敏原、微生物之細菌、黴菌及病毒等，依其性質不肖，對人體造成 不同形式之危害’財由於鮮微生歓屬於前賴浮錄中體積最 小者，且各種不同型態的細菌、黴菌及病毒等微生物又普遍存在於自 然界中，對人體造成的危害不僅最快且最為明顯，如：引起過敏、感 ο染、毒性反應，甚至對人體有致命性的殺傷力，然而，現今空調通風 系統中所使用的空氣翻卻對其束手無策，並無法有效發揮遽除空氣 中該等微生物的侧。有此，近年來，空調通風纽的設計及製 造業者，雖已將各式殺菌魏的電子機構(如：具料光㈣功能的電 子機構或能產生光觸媒殺菌功能的電子機構)設計至空調通風*** 中’惟’該等先進的空調通風系統卻因成本較高且佔用較大空間，尚 未普及於-般家敍公共撕，因此，對於獻的使用傳毅舰風 €)系統_戶而言’空氣中的該等微生物對人們身體健康造成的嚴 脅至今仍未獲得有效解決。 此外’近年來’由於電子及電器產品日益普及，都市居住空間過 4集且封閉’都市環境的離子平衡已遭嚴重破壞，因此，許多 =風系統計及製造業者，乃思及以人工方式補充環境中的^離 各式貞離子產生機及其_產品乃應運而生，且·受到人們青 ，然而’添購負離子相品不僅會對人們造成額外的支出負擔， 整個社會亦會因諸多何生性電器產品的使用，而造成電力資源消耗的 5 201039906 沉重負擔，形成了另一種型態的環保問題。 口此’如何⑦相-鋪新的空氣翻，使得該空氣細能被廣 泛地使用在現存的各式空調通風系統中，除能滤除空氣中的雜質、污 垢及灰塵外’尚能賴職貞離子，且在有光絲光驗態下，均能 產生光觸媒及賴伽’以實現對細g、病毒及_等有機物的降解， 產生絕佳的抗菌、滅菌及除臭效果，即成為本發明在此欲探討的一重 要課題。 ^【發明内容】 有鑑於前述舰蝴贼_轉在輯乡醜，剌人經過長 ^力研究與實驗’祕設邮本發_-種具奈米抗病菌及除 果的线_及錄作綠，叫使雜麟_表聽輻射出 γ射、嫩麟，藉临磁電術式，將電子 = 以持續釋放出負離子，且能激發該空錢網表面上佈 G及產生輔助光觸及_翻，以實現對_、病毒 〇及檄滷等有機物的抗菌、滅菌及除臭效果。 本發狀L係錢供—鶴奈餘關嫌纽果的空氣 濾:广濾網織物’該濾網織物均勻分佈有複數個網 -層’該·層係由膠漿乾燥而成，該膠漿内包含至少 礦物粉末，該礦物粉末能輻射出α射線、 13射線、丫射線或X射線，及 的狀1、:= 地被塗佈在該渡網織物表面鄰近該等網孔 的周緣，及禝數個短纖維，該等短纖維係由含氧 米粒子的全延伸紗裁切而成，該』 6 201039906 集地佈植在該膠漿上，且透過鱗漿層，被黏著固定在該濾網織物的 表面上’形成一綿密的過濾層。如此’本發明的空氣濾網除了能濾除 通過網孔的空氣巾的雜質、污垢及灰塵外’由於膠漿層中_物粉末 所輕射出來的α射線、β射線、丫射線或X射線，能以附加或失去電子 Ο201039906 VI. Description of the Invention: [Technical Field] The present invention relates to an air filter having a nanometer antibacterial and deodorizing effect, and a method for fabricating the same, and more particularly to a method for causing a surface of an air filter to emit alpha rays, P-ray, gamma-ray or X-ray, the way in which the _ field loses electrons, releases the electrons into the towel, feeds out the negative ions, and stimulates the short fibers implanted on the surface of the air filter to generate auxiliary photocatalyst and catalyst. 'To achieve the degradation of fine 8, virus and mildew g and other organic matter. [Prior Art] According to statistics, in the metropolis, people live in an indoor environment (including homes, offices, or other _), about 8G to 9G% of the time each day. The good quality of indoor air quality will directly affect people. _Life products f and efficiency, therefore, the impact of chamber gas pollutants on people's health 'naturally received great attention. In the dense building, if the indoor ventilation is from time to time, the dirt will easily accumulate over time, causing the indoor air quality to be irritated. The other things that can be dyed include: outdoor steam locomotives, exhaust emissions from factories, or The air intake of the air conditioning system of the central air conditioner or the microorganisms that are not regularly cleaned and filtered, will also affect the quality of the indoor air. In particular, Taiwan is located in the subtropical zone and belongs to the climatic pattern of long-term thirst and high temperature. The bacteria, the disease master and the emblem are the same as the disease key. That is to say, silk must pay attention to and do the summer competition. Green filter, the main function is to filter out, and the suspended juice particles will cause different airway size according to their particle size. 10_ particles are called sucking particles, because 4 201039906 for these particles will enter the respiratory system with respiration, and according to their particle size from large to small respectively, "L accumulate in the stalk beer channel and alveoli Cells, and the sources of respiratory aerosols in indoor environments are smoking, cooking, stone in building materials, artificial mineral fibers, plant pollen, animal allergens, microbial bacteria, molds and viruses, etc., depending on their nature, The human body causes different forms of harm. Because the fresh oysters belong to the smallest volume in the former floating record, microorganisms such as bacteria, molds and viruses of various types are commonly found in nature, posing a danger to the human body. Not only the fastest and most obvious, such as: causing allergies, sensation, toxicity, and even lethal lethality to the human body. However, the air used in air conditioning and ventilation systems has no way to do it. In addition to the side of such microorganisms in the air, in recent years, the design and manufacturers of air-conditioning and ventilation ventilators have used various types of sterilizing electronic institutions (such as electronic mechanisms with light (four) functions or can produce photocatalysts. The electronic mechanism of sterilizing function is designed to the air conditioning and ventilation system. However, these advanced air conditioning and ventilation systems are not popular in the general public air tearing due to their high cost and occupying a large space. Therefore, for the use of the distribution毅船风€)System_Households' The suspicion of these microorganisms in the air on people's health has not yet been effectively solved. In addition, 'in recent years' due to the increasing popularity of electronic and electrical products, urban living space has exceeded 4 The ion balance of the urban environment has been severely damaged. Therefore, many of the wind systems are considered by the manufacturers, and they are supplemented manually. The various types of helium ion generators and their products are born in the world, and are subject to the people's youth. However, the purchase of negative ion phase products will not only impose additional expenditure burden on people, but also the whole society. The use of raw electrical products, which caused a heavy burden on the consumption of power resources 5 201039906, formed another type of environmental protection problem. This how to '7 phase - paving a new air turn, making the air fine energy widely used in In the existing air-conditioning ventilation systems, in addition to filtering out impurities, dirt and dust in the air, 'there can still be used for sputum ions, and in the presence of light and light, all can produce photocatalyst and Laijia' to achieve The degradation of fine organic substances such as fine g, virus and _, resulting in excellent antibacterial, sterilization and deodorizing effects, has become an important subject for the present invention to be explored. [Inventive content] In view of the aforementioned ship thief _ turn The township is ugly, and the monks have passed the long-term research and experimentation. 'The secret mail is issued _- a line with nano-resistant bacteria and fruit removal _ and recorded as green, called the hybrid _ table to listen to radiation gamma shot, Nen Lin, by magnetic magnetism, Electronic = sustained release negative ions, capable of exciting the surface of the empty cloth mesh money and generating an auxiliary light touch G _ turn, in order to achieve an antibacterial, deodorizing and sterilizing effect _, viruses and other halogen Xi square and organic matter. The hair of the hairline L is the air filter of the crane. The air filter of the crane is: the filter fabric is uniformly distributed with a plurality of mesh-layers. The layer is made of a mortar, and the glue is formed. The slurry contains at least a mineral powder capable of radiating alpha rays, 13 rays, xenon rays or X rays, and the shape 1,: = is applied to the periphery of the mesh fabric adjacent to the periphery of the mesh. And a plurality of short fibers, which are cut from a fully-extending yarn of oxygen-containing rice particles, which is planted on the glue and passed through the scale layer and adhered thereto. A clear filter layer is formed on the surface of the screen fabric. Thus, the air filter of the present invention can filter out the impurities, dirt and dust of the air towel passing through the mesh, and the alpha rays, beta rays, xenon rays or X-rays which are lightly emitted by the powder in the glue layer. Can attach or lose electronic Ο
的方式把1子釋放到空齡’令空氣中的分子形成帶負電的負離子， 而使該礦物粉末成為負離子的發生源，持續釋放貞離子，該等射線尚 曰激發該短纖維上的氧化鋅奈絲子及銀奈絲子細產生輔助光觸 媒及觸媒伽’使氧倾奈米奸絲強氧铺，且使銀奈米粒子更 谷易釋放出帶正電荷的銀離子，實現對細菌、病毒及黴菌等有機物的 降解’產生絕佳的抗g、_及除臭效果。 ^本發明之另-目的’係在提供—種具奈米抗病菌及除臭效果的空 慮網的製作方法’該方法係將氧化鋅奈綠子及銀奈絲子以一預 疋的重1百分比，製成麟母粒(master bateh)，再將塑料母粒以—預 疋的重里百刀比均勾地混人塑化原料中’執行融溶押出及抽紗程序， 以製作出-種含氧化鋅奈絲子及銀奈餘子的全延伸紗，且將該全 ㈤申紗裁切鑛f驗齡’另，觀產生負離子_物粉末(如：二 桃矽(Si〇2)、氧化鋁(Al2〇3)、氧化鈣(Ca〇)、二氧化鈦⑽）、氧化 #C〇〇)' K_(LaC))、氧化鄉eC))或具舖性的金屬氧化物等），以 一預定的重量百分比，均勻混入一膠聚(如：壓克力膠或樹勒中，並 將郷漿均勻地塗絲-劇織物的絲，最後，靜電植毛技術， 將該短纖維密躺佈植在該_織物的表面，倾膠漿乾燥後該短 纖維即能被黏著固定在該細織物的表面上，使得該短纖維上;的 乳化鋅奈米粒子及絲錄子，麵光或無光驗態下，均^現對 7 201039906 細菌、病毒及黴菌等有機物的抗菌及滅菌效果，由於，該空氣濾網不 會產生抗藥性、無毒性、無刺激過敏性、無須光照活化及不^驗= 影響等諸多優點’故具有長效型抗病菌、防霉及除臭等效果，能在定 期清洗後，反覆使用’符合綠色環保的要求。 為便貴審查委員能對本發明的目的、技術特徵及其功效，有更 進一步的認識與瞭解，茲特舉若干實施例，並配合圖式，詳細說明如 下： 【實施方式】 按，「觸媒」是一種催化劑，用以降低化學反應所需的能量，加 快化學反應的速度’但卻不會因化學反應而破壞本身之結構，「光觸 媒」顧名思義是能利用自然界存在的光能，來產生催化作用，以發揮 觸媒的特性。一般言，許多奈米級的光觸媒材料在經過光的激發後， 會使周圍之氧氣及水分子激發成極具氧化力的Hz ·及〇2 ·自由基，該 等自由基可分解所有對人體或環境有害的有機物質及無機物質，不僅 能加速反應，且不會衍生污染。另，由於該等光觸媒材料通常具有一 種半導體結晶的結構，故在被UV光子或其它輻射線(如：α射線、p 射線、γ射線或X射線)撞擊後，半導體結晶中的電子會跳出來，留下 一個具有強大氧化能力的帶正電孔洞，該等電子與電洞在化學上稱為 「電子洞對」’當電子與空氣中的氧分子（〇2)相遇時，即生成反應性 很強的超級氧分子自由基（· 〇2)，當電洞與空氣中的水氣（Η2〇)相 遇時，會透過光化學反應’搶奪水中氫氧基的電子，此時，失去電子 201039906 =二基立刻變成不安定的龍妓^ (•㈣，不安定的氫氧自由 、丨卜來的或附在該等光觸媒材料表面上的有機物時，會藉由 搶奪對方電子的方式，使自己趨於穩定，如此，有機物即^被氧 化，而變成水和二氧化碳，消散在空氣中。 ο 、銀為例’在被奈米化後’由於顆粒變細，導致麵表面積大幅 二加雜變Α ’使得銀奈綠子極轉放絲性銀離子，以吸 ==蛋白上的硫氫基’並與其迅速地結合在一起，使含硫氫基的 =失去活性’導致細g壯，尤其是，帶正電荷驗離子在接觸到 I負電荷_生物細胞後，便會相互赌，且穿舰生物的細胞外壁， 4微生物内部變性’降低生長能力，讓細胞無法代謝及繁殖，直至死 ^故具有絕佳的抗病纽滅菌效果。此外，當_被銀離子殺死後， 離子又會從死去的_上游離出來，持續對活細菌做重複的動作， 舍^有ί菌被消滅為止，因此，銀奈采粒子具有長效型抗病菌、不 ο 等、無毒性、無刺激過敏性、無須光照活化及不受酸鹼值 心曰等諸讀點’更可㈣賴生長，有效達晰腐功能。 以氧化鋅為例，在被奈米化後，由於其晶粒的尺寸與光波相當或 著料其尺寸效絲導致導帶顺帶關_加，使得歧收能力顯 且在光照射下’當一個具有一定能量的光子，或具有超過半 ^體讀能㈣光子’射人氧化鋅奈錄子的半導體電子結構時，一 =子會從價帶激發到導帶’而留下一個空穴，價帶的孔穴把周圍環 =中的減電子搶奪過來，使變成自由基，故能作為強氧化劑， 實現對病菌和病毒等有機物的降解，以殺死病菌和病毒。 一般言’離子是帶錢荷的原子、原子贼分子，是極小的微粒， 9 201039906 ο 離子有兩種’帶正電的稱為「正離子」，帶負電的則是「負離子」。以 (2〇)為例’氫（η)的原子是—個帶正電質子的核被一個帶負電 的Γ子所核繞，若因某種力量的介入使電子離開原處’氫原子因而成 為τ正電的狀態，即離子化的氫（Η+)。對氧⑼而言，原子核中有 8個帶正電㈣子，觸有8健子醜，2個在_，6個在外層， 2層能階可細8個電子，尚有2個空位，因此，氧很容易自他 处奪取電子的原子態，此—過程又稱為「氧化」。因此，級獲取電子 ^原子與擁有1個電子的氫原子，很容易結合而成水分子，若利用 冊卜來症1把水分解’就會使它變成—個帶正電的氫離子钔，及一個 =負電的氫氧根離子⑽> 但在自然觀中，氫氧根離子是以附著 :水（恥+ 〇Η'哪2—)的負離子方式存在，由於，水分子是自 =最容易離子化的分子之一’因此，當環境中有較多負離二 不職中貞離子化的水分子含量十分豐富，含有财貞離子化 離Γ認為會讓生物體感到舒適愉快，故亦將^負離子」 Ο ’、、、I離子」、「凡氣離子」或「空氣中的維他命」。 按，地球上有許多的鑛物，如：二氧化石夕(si02) 氧化鈣(CaO)、二氧化鈦(Ti〇2)、氧化鉻(Cr〇)、氧化 2 3 (SeO^ -¾ B ω. —網(LaO)、氧匕 獅性·屬氧爾，嶋射_線、嶋齡 =線’故能使該等礦物以附加或失去電子的方式，把電子釋放到 二=Γ的水分子形成帶負電的負離子。本發明即利用該 工 '物犯產生負離子的特性’及其轎射出的射線能激發氧化辞夺米粒 子及銀奈米粒子產生觸媒反應的特性，而在本發 厂、 粉末、氧化料_子及銀奈綠子_ ^ ^寺礦物的 τ 叶應用至空氣渡網的製作 201039906 過程，使得所製成的空氣濾網，被安裝至空調通風系統内黑暗的安裝 位置時’除能濾除空氣中的雜質、污垢及灰塵，及持續釋放負離子外， 仍旎使其上的氧化鋅奈米粒子及銀奈米粒子分別產生輔助光觸媒及觸 媒作用’以在無光的狀態下，實現對細菌、病毒及徽菌等有機物的抗 菌及滅菌效果。在本發明巾，為了使空氣濾雛持赫放貞離子，且 在無光驗態下’產生對細g、病毒及黴解有機物的抗菌及滅菌效 果，該空氣濾網必需具備下列結構特性： 〇⑴該等義縣必需能__著在濾喊面，使料礦物能以附 加或失去電子的方式’把電子釋放到空氣中，而使空氣中的水分子 开/成TJT負電的負離子，以持續地釋放出負離子； (2) ^化鋅奈米粒子及銀奈米粒子必需能細地附著在渡網表面，且 〜與通顿氣有較大的翻面積及咖’輯細菌、病毒及 _等有機物’產生較佳的抗菌及滅菌效果；及 ⑶2礦物粉末所輻射出的射線能隨著空氣_方向，激發氧化辞 j粒子及銀奈錄子分別產·助細媒及觸媒作用，使氧化鋅 化劑’且使銀奈米粒子更轉放出帶正電荷的銀 ^ a以貫現對細菌、病毒及黴菌等有機物的降解作用。 發明係一種具奈米抗病菌及除臭效果的空氣據網 包括一祕^ 該賴⑵内膠黎層12’該膠裝層12係由膠裝121乾燥而成， 射線、β射線二至少一種礦物粉末m，該礦物粉末m能輻射出α 線、γ射線或X射線，及產生負離子，該膠装121係被均勻 11 201039906 地塗佈在該翻織物Η表面鄰近鱗網孔ηι的周緣；及複數個短纖 維13，參閲第2圖所示’該等短纖維13係由含氧化鋅奈米粒子⑶ 及銀奈米粒子132的全延伸紗裁切而成，該等短纖維13侧用靜電植 毛技術’被密集地佈植在該膠漿121上，且透過該朦漿層12，被黏著 固疋在該滤網織物U的表面上，形成一絲密的過濾層。在本發明中， 該空氣渡網的製作方法’參閱第2及3圖所示，包括下列步驟·· (21) 將氧化鋅奈米粒子131及絲米粒子132卩一預定的重量百分 0 比’製成塑料母粒(master batch); (22) 將塑料母粒以一預定的重量百分比均勾地混入一塑化原料中； ⑵）對該塑化原料執行融溶押出及抽紗程序，以製作出—種含氧化辞 奈米粒子131及銀奈米粒子132的全延伸紗，且將該全延伸紗裁 切成所需的短纖維13 ; ⑼將能產生負離子的礦物粉末122，以—預定的重量百分比，均句 混入膠漿121中； (25)將該膠漿121均勻地塗佈至濾網織物u的表面； 〇(坤利祕電植毛技術，將該短纖維13密集地佈植在靴網織物u 的表面；及 即症被黏著固定在該濾網織 層，如此，即製成本發明的 (27)俟該膠漿121乾燥後，該短纖維13 物11的表面上，形成一錦密的過濾 空氣濾網10。 在本發日月之一最佳實施例中，該方料將氧化辞奈米粒子⑶及銀 奈米粒子m分取-航的4量百分比，製絲料母粒㈣伽 _)，再將塑料母粒以—預定的重量百分比均勻地混入塑化原料中， 12 201039906 執行融熔押出及抽紗程序，以製作出全延伸紗，嗣，將該全延伸紗裁 切成所需的短纖維13，使得該氧化鋅奈米粒子及銀奈米粒子在各該短 纖維中的含量，分別為0.05%〜5%及0.001%〜1%的重量百分比，且利用 靜電植毛技術，將該等短纖維13密集地佈植在該濾網織物1丨的表面， 形成绵岔的過濾層後，復參閱第2圖所示’該短纖維13内所含的氧化鋅 奈米粒子131及銀奈米粒子132即能與通過網孔ηι的空氣形成極大的 接觸面積及接觸時間，充分發揮其對細菌、病毒及黴菌等有機物的抗 〇菌及滅菌效果。另，在該實施例中，該方法至少使用一種以上的礦物 粉末122 ’該礦物粉末122包括二氧化矽(SiCb)、氧化鋁(ai2〇3)、氧化转 (Ca〇)、二氧化鈦(Ti〇2)、氧化鉻(CrO)、氧化鑭(La〇)、氧化砸(Se〇) 或具輻射性的金屬氧化物等，且以1%〜2〇%的重量百分比，將該礦物 粉末122均勻混入壓克力膠或樹脂等膠衆121中，使得該等礦物粉末 得以穩固地附著在濾網織物11表面，且能以附加或失去電子的方式， 把電子釋放到空氣中，而使通過網孔ln的空氣中的水分子形成帶負電 ❹的負離子’以持續地釋放出負離子，且使所輻射出的α射線、p射線、丫 射線或X射線能隨著空氣流通方向（參閱第2圖所示虛線的箭頭方 向）’激發該等短纖維13内所含的氧化鋅奈米粒子131及銀奈米粒子 132 ’分別產生辅助光觸媒及觸媒作用，使氧化辞奈米粒子成為強氧化 劑，且使銀奈米粒子更易釋放出帶正電荷的銀離子，實現對細菌、病 母及黴等有機物的降解作用。在本發明之前述最佳實施例中，經反 覆實驗證明，氧化鋅奈米粒子131及銀奈米粒子丨％間的重量百分比， 以5d〜60:1能對細菌、病毒及黴菌等有機物產生最佳的抗菌及滅菌效 13 201039906 果。 如此，該空氣濾網10除了能濾除通過該濾網織物u網孔U1的 空氣中的雜質、污垢及灰塵外，由於膠漿層12中的镇物粉末122所韓 射出來的α射線、β射線、γ射線或X射線，能以附加或失去電子的方 式把電子釋放到空氣中，令空氣中的分子形成帶負電的負離子，而使 礦物粉末122成為負離子的發生源，持續釋放負離子，該等射線尚會 激發該短纖維13上的氧化辞奈米粒子131及銀奈米粒子分別產生 辅助光觸媒及觸媒作用，使氧化辞奈来粒子m成為強氧化劑，且使 銀奈米粒子132更易釋放出帶正電荷的銀離子，因此，本發明的空氣 濾網1〇在有光或無光的狀態下，均能實現對細菌、病毒及徽菌等有機 2的抗菌及義效果，由於，該空麟網1()完全不會產生抗藥性、無 毒性、無刺激過敏性、無須光照活化及不受酸驗值影響等諸多優點， 故具有長效型抗病菌、防霉及除臭等效果，且僅需定期清洗後，即能 反覆使用，符合綠色環保的要求。 按’社所述’僅為本發日觸―最佳具體實關，惟本發明的 徵並不紐於此’任域辆微藝者在本魏領軸，可輕易思及 的變化或修飾，皆顧蓋在町本_种料繼圍中。 【圖式簡單說明】 第1圖係本發明的空氣濾網的剖面示意圖；及 第2圖係本發餐空氣濾網的局部剖面示音圖及 第3圖係本發餐製作方法的流程示音圖。 201039906 【主要元件符號說明】 空氣濾網 ..............10 濾網織物 ..............11 網孔 111 膠漿層 ..............12 膠漿 121 礦物粉末 122 短纖維 ..............13 〇氧化鋅奈米粒子 ..............131 銀奈米粒子 132 〇 15The way to release 1 to the age of 'make the molecules in the air form a negatively charged negative ion, and make the mineral powder a source of negative ions, continuously releasing helium ions, which also stimulate the zinc oxide on the short fibers The nano-nose and silver-nose fine-grained auxiliary photocatalyst and the catalyst gamma make the oxygen nano-stained silk and strong oxygen, and make the silver nano-particles more easily release positively charged silver ions, realizing bacteria and viruses. And the degradation of organic matter such as molds produces excellent anti-g, _ and deodorizing effects. ^The other object of the present invention is to provide a method for preparing a hollow net having a nanometer antibacterial and deodorizing effect. The method is to treat zinc oxide green and silver neousons as a pre-dip weight. 1%, made into masterbatch (master bateh), and then the plastic masterbatch is used to perform the melt-dissolving and drawing process in the plasticizing raw material. A fully-extended yarn containing zinc oxidized zinc nuclei and silver naphtha, and the whole (five) shang yarn cuts the minerals to test the age of 'others, and produces an anion powder (such as: two peach 矽 (Si〇2), Alumina (Al2〇3), calcium oxide (Ca〇), titanium dioxide (10)), oxidized #C〇〇)'K_(LaC)), oxidized eC)) or paved metal oxides, etc. The predetermined weight percentage is evenly mixed into a gel (such as: acrylic glue or tree, and the mortar is evenly coated - the silk of the fabric), and finally, the electrostatic flocking technique, the short fiber is densely planted. On the surface of the woven fabric, after the decant is dried, the short fibers can be adhered and fixed on the surface of the fine fabric, so that the emulsified zinc nanoparticles on the short fibers; And silk recording, surface light or no light test, all of the antibacterial and sterilizing effects of 7 201039906 bacteria, viruses and molds, because the air filter will not produce resistance, no toxicity, no stimulation It has all the advantages of allergic, no need for light activation and no effect = effect, so it has long-acting anti-bacteria, anti-mildew and deodorization effects. It can be used repeatedly after regular cleaning to meet the requirements of green environmental protection. The review committee can have a better understanding and understanding of the purpose, technical features and functions of the present invention. A few embodiments will be described in detail with reference to the following drawings: [Embodiment] Press, "catalyst" is a kind Catalysts, which are used to reduce the energy required for chemical reactions and accelerate the speed of chemical reactions, but do not destroy their structures due to chemical reactions. Photocatalysts, as the name implies, can utilize the light energy present in nature to produce catalysis. The characteristics of the catalyst are used. Generally speaking, many nano-scale photocatalyst materials excite the surrounding oxygen and water molecules after being excited by light. Hz · · 〇 2 · Free radicals, which can decompose all organic and inorganic substances harmful to the human body or the environment, not only accelerate the reaction, but also do not degenerate pollution. Also, because these photocatalyst materials are usually Has a structure of semiconductor crystal, so after being hit by UV photons or other radiation (such as: α-ray, p-ray, γ-ray or X-ray), the electrons in the semiconductor crystal will jump out, leaving a strong oxidizing power. With positively charged holes, these electrons and holes are chemically called "electron hole pairs". When electrons meet oxygen molecules in the air (〇2), they generate highly reactive superoxide molecules. (· 〇 2), when the hole meets the water vapor in the air (Η2〇), it will rob the electrons of the hydroxyl group in the water through the photochemical reaction. At this time, the loss of electrons 201039906 = the two bases immediately become unstable.龙妓^ (• (4), when the unstable hydrogen and oxygen free, the organic matter attached to the surface of the photocatalyst material, will stabilize itself by robbing the other party, so, organic I.e. ^ be oxidized, it becomes water and carbon dioxide, dispersed in the air. ο, silver as an example 'after being nano-ized' due to the finer particles, resulting in a large surface area of the surface of the two additions Α 使得 'Let the silver chlorophyll turn to the silvery silver ions, to absorb = = thiohydrogen on the protein The base 'and its rapid combination, so that the sulphur-containing hydrogen group = inactive' leads to fine g-strong, especially, the positively charged test ions will bet on each other after contacting the I negative-charged biological cells, and The outer wall of the ship's organism, 4 microbial internal denaturation 'reducing the growth ability, allowing the cells to be unable to metabolize and multiply until the death has an excellent anti-vaccination effect. In addition, when _ is killed by silver ions, the ions will be released from the dead _, and the repeated action on the living bacteria will continue, and the bacteria will be eliminated. Therefore, the silver granules have a long-lasting type. Anti-pathogenic bacteria, no o, etc., non-toxic, non-irritating allergic, no need to activate light and not subject to pH readings, etc. 'More can (4) Lai growth, effective to achieve rosive function. Taking zinc oxide as an example, after being nano-sized, the size of the crystal grains is equivalent to the light wave or the size effect of the material is caused to cause the conduction band to be turned on and off, so that the disproportion ability is obvious and under the light irradiation. When a photon with a certain energy, or a semiconductor electronic structure with more than half of the read energy (four) photon's shot of zinc oxide, the one will be excited from the valence band to the conduction band' leaving a hole. The pores of the valence band robbed the electrons in the surrounding ring = to become free radicals, so it can be used as a strong oxidant to degrade the organic matter such as germs and viruses to kill germs and viruses. In general, 'ion is an atom with atomic charge, an atomic thief molecule, and it is a very small particle. 9 201039906 ο There are two types of ions that are positively charged as "positive ions" and those with negative electricity are "negative ions". Taking (2〇) as an example, the atom of hydrogen (η) is a nuclear with a positively charged proton, which is surrounded by a negatively charged dice. If a certain force is involved, the electron is removed from the original 'hydrogen atom. It becomes a state of positive τ, that is, ionized hydrogen (Η+). For oxygen (9), there are 8 positively charged (four) sons in the nucleus, 8 healthy ugly, 2 in _, 6 in the outer layer, 2 layers of energy can be 8 electrons, and there are 2 vacancies. Therefore, oxygen is very easy to take the atomic state of electrons from elsewhere, and this process is also called "oxidation." Therefore, the level of the electron atom and the hydrogen atom possessing one electron can be easily combined into a water molecule. If the water is decomposed by the use of the book, it will become a positively charged hydrogen ion. And a negatively charged hydroxide ion (10)> However, in the natural view, the hydroxide ion exists in the form of an anion that adheres to water (shame + 〇Η '2), since water molecules are the easiest One of the ionized molecules' Therefore, when there are more negative ions in the environment, the water molecules in the ionization are very rich, and the ionization ionization is considered to make the organism feel comfortable and happy. ^ Negative ions" Ο ', , I ion", "every gas ion" or "vitamin in the air". Press, there are many minerals on the earth, such as: dioxide dioxide (si02) calcium oxide (CaO), titanium dioxide (Ti〇2), chromium oxide (Cr〇), oxidation 2 3 (SeO^ -3⁄4 B ω. — The net (LaO), Oxygen lion, Oxygen, 嶋 _ 线, 嶋 = = 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线 线Negatively charged negative ions. The present invention utilizes the characteristics of the work to generate negative ions and the radiation emitted by the car to excite the characteristics of the catalytic reaction of the oxidized squaring rice particles and the silver nanoparticles, and in the present plant, the powder The oxidized material _ sub- and the silver granules _ ^ ^ temple mineral τ leaves applied to the production of the air network 201039906 process, so that the air filter produced, when installed in the dark installation position of the air conditioning ventilation system' In addition to filtering out impurities, dirt and dust in the air, and continuously releasing negative ions, the zinc oxide nanoparticles and silver nanoparticles on the surface of the silicon oxide and the silver nanoparticles respectively generate auxiliary photocatalyst and catalyst to act in the absence of light. Under the antibacterial and antibacterial properties of bacteria, viruses and bacteria Sterilization effect. In the towel of the present invention, in order to allow the air filter to hold the ions and to produce an antibacterial and sterilizing effect on the fine g, virus and mildewed organic matter in the absence of light, the air filter must have the following Structural characteristics: 〇 (1) The county must be able to __ in the sifting surface, so that the minerals can release electrons into the air in a way that attaches or loses electrons, and the water molecules in the air are turned on/off into TJT negative Negative ions to continuously release negative ions; (2) ^Zinc nanoparticles and silver nanoparticles must be able to adhere finely to the surface of the network, and ~ and the passage of the gas has a larger area and coffee Bacteria, viruses and organic matter such as _ produce better antibacterial and sterilizing effects; and (3) 2 ray radiation from mineral powder can stimulate the oxidation of j particles and Yinnai recorded separately with the air _ direction and The catalyst acts to make the zinc oxide agent' and the silver nanoparticle particles are more transferred to the positively charged silver to reflect the degradation of bacteria, viruses and molds. The invention is a kind of nano-resistant bacteria and Deodorizing effect of air network package The first secret ^ The Lai (2) the inner rubber layer 12' The glue layer 12 is made of a glued 121, the radiation, the beta beam and at least one mineral powder m, the mineral powder m can radiate the alpha line, the gamma ray or X-rays, and the generation of negative ions, the glue 121 is uniformly coated on the surface of the woven fabric surface adjacent to the scale mesh ηι; and a plurality of short fibers 13, as shown in Fig. 2 The short fibers 13 are cut from a fully extended yarn containing zinc oxide nanoparticles (3) and silver nanoparticles 132, and the short fibers 13 are densely planted on the paste 121 by electrostatic flocking technology. And through the slurry layer 12, adhered to the surface of the screen fabric U to form a dense filter layer. In the present invention, the method for manufacturing the air network is as shown in Figures 2 and 3. The method includes the following steps: (21) preparing zinc oxide nanoparticle 131 and silk rice particles 132 by a predetermined weight percentage of 0 to make a master batch; (22) using a plastic masterbatch The predetermined weight percentage is mixed into a plasticized raw material; (2)) the plasticized raw material is melted and extruded. The drawing process is performed to produce a fully extended yarn containing the oxidized nanoparticle 131 and the silver nanoparticle 132, and the fully extended yarn is cut into the desired short fibers 13; (9) a mineral powder capable of generating negative ions 122, in a predetermined weight percentage, mixed into the glue 121; (25) uniformly apply the glue 121 to the surface of the screen fabric u; 〇 (Kunli secret hair planting technology, the short fiber 13 densely planted on the surface of the boot net fabric u; and the disease is adhered to the filter mesh layer, so that the (27) of the present invention is prepared, and the short fiber 13 is 11 after the glue 121 is dried. On the surface, a filthy filter air filter 10 is formed. In one of the preferred embodiments of the present day and the month, the material is divided into 4 parts by weight of the oxidized Nylon particles (3) and the silver nanoparticles, and the masterbatch (4) gamma _). The plastic masterbatch is evenly mixed into the plasticized material at a predetermined weight percentage, 12 201039906 to perform a melt extrusion and drawing process to produce a fully extended yarn, and the full length yarn is cut into the desired short fibers 13 The content of the zinc oxide nano particles and the silver nanoparticles in each of the short fibers is 0.05% to 5% and 0.001% to 1% by weight, respectively, and the short fibers are used by electrostatic flocking technology. 13 densely planted on the surface of the filter fabric to form a cotton filter layer, and then refer to the zinc oxide nanoparticle 131 and silver nanoparticle contained in the short fiber 13 as shown in Fig. 2 132 can form a great contact area and contact time with the air passing through the mesh η, and fully exert its antibacterial and sterilization effects on organic substances such as bacteria, viruses and molds. In addition, in this embodiment, the method uses at least one or more mineral powders 122'. The mineral powder 122 includes ceria (SiCb), alumina (ai2〇3), oxidized (Ca〇), and titanium dioxide (Ti〇). 2) chromium oxide (CrO), lanthanum oxide (La〇), cerium oxide (Se〇) or a radiation metal oxide, etc., and the mineral powder 122 is uniformed by 1% to 2% by weight. It is mixed into the glue 121 such as acrylic glue or resin, so that the mineral powder can be firmly attached to the surface of the screen fabric 11, and the electrons can be released into the air by means of additional or lost electrons, and the net is passed through the net. The water molecules in the air of the hole ln form a negative ion with a negative electric charge to continuously release the negative ions, and the emitted α rays, p rays, xenon rays or X rays can follow the air flow direction (see Fig. 2). The dotted arrow direction "exciting the zinc oxide nanoparticle 131 and the silver nanoparticle 132' contained in the short fibers 13 respectively generates an auxiliary photocatalyst and a catalytic action, so that the oxidized nanoparticle becomes a strong oxidizing agent. And make silver nanoparticles easier to release With positively charged silver ions, to realize degradation of bacteria, mold and other diseases and mother organics. In the foregoing preferred embodiment of the present invention, it has been proved by repeated experiments that the weight percentage between the zinc oxide nanoparticle 131 and the silver nanoparticles 丨% can be 5d~60:1 to produce organic substances such as bacteria, viruses and molds. The best antibacterial and sterilization effect 13 201039906 fruit. In this way, in addition to the impurities, dirt and dust in the air passing through the screen fabric U1 of the screen fabric, the air filter 10 emits alpha rays, which are emitted by the town powder 122 in the glue layer 12. Beta rays, gamma rays, or X-rays can release electrons into the air in a manner that adds or loses electrons, causing molecules in the air to form negatively charged negative ions, and the mineral powder 122 becomes a source of negative ions, continuously releasing negative ions. The ray also excites the oxidized smectite particles 131 and the silver nanoparticles on the short fibers 13 to generate an auxiliary photocatalyst and a catalyst, respectively, so that the oxidized sinite particles m become strong oxidants, and the silver nanoparticles 132 are made. The positively charged silver ions are more easily released, and therefore, the air filter 1 of the present invention can realize the antibacterial and antibacterial effects on bacteria 2, bacteria and bacteria, etc. in the presence or absence of light, because The empty net 1() has no advantages such as drug resistance, non-toxicity, no irritation, no light activation and no acid value, so it has long-lasting anti-bacteria, mildew and deodorization. Wait Consequences, and requires only regular cleaning, which can be used repeatedly, in line with environmental protection requirements. According to the 'community', it is only the best time to touch the hair of the day. However, the sign of the invention is not in this way. They are all covered in the town of Machimoto. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic cross-sectional view of an air filter according to the present invention; and FIG. 2 is a partial cross-sectional sound map of the present air filter and FIG. 3 is a flow chart showing the method for producing the present meal. Sound map. 201039906 [Explanation of main component symbols] Air filter.............10 Filter fabric..............11 Mesh 111 glue layer. .............12 Glue 121 Mineral powder 122 Short fiber..............13 Zinc oxide zinc nanoparticles....... .......131 Silver Nanoparticles 132 〇15