TW201005035A - Emulsion composition, methods of softening fibrous structures using the same, and fibrous substrate treated therewith - Google Patents

Emulsion composition, methods of softening fibrous structures using the same, and fibrous substrate treated therewith Download PDF

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TW201005035A
TW201005035A TW97127820A TW97127820A TW201005035A TW 201005035 A TW201005035 A TW 201005035A TW 97127820 A TW97127820 A TW 97127820A TW 97127820 A TW97127820 A TW 97127820A TW 201005035 A TW201005035 A TW 201005035A
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emulsion composition
extract
emulsion
water
group
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TW97127820A
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TWI421305B (en
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Fu-Ming Huang
jun-jie Shen
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Dow Corning Shanghai Co Ltd
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Abstract

An emulsion composition comprising: (A) 0.01 to less than 25.0 parts by weight of a diorganopolysiloxane; (B) [0.01 to less than 20.0 parts by weight of] a softening agent; (C) [8.0 to 60.0 parts by weight of] water; and (D) [20.0 to 90.0 parts by weight of] water-soluble monovalent or polyvalent alcohols Wherein the continuous phase of said emulsion composition is an aqueous solution consisting of said (C) water and said (D) water-soluble monovalent or polyvalent alcohols in the ratio of from 1: 0.5 to 1: 10, and total content of said component (C) and (D) is in the rage of 30.0 and 98.0 parts by weight of said emulsion composition.

Description

201005035 九、發明說明： 【發明所屬之技術領域】 本發明係關於新穎的乳劑組合物，其具有由水及水溶性 醇組成之水溶液之連續相。該新穎乳劑組合物之特徵進一 步在於包含呈乳化於該水溶液中之乳劑粒子形式之二有機 聚矽氧烷及軟化劑。該乳劑組合物在儲存過程中保持良好 的時間穩定性及均質外觀長達數月。201005035 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a novel emulsion composition having a continuous phase of an aqueous solution composed of water and a water-soluble alcohol. The novel emulsion composition is further characterized by comprising a diorganopolysiloxane and a softening agent in the form of emulsion particles emulsified in the aqueous solution. The emulsion composition maintains good time stability and a homogeneous appearance for several months during storage.

本發明亦關於新穎的用於纖維基材（尤其薄紙）之軟化乳 劑組合物。該軟化乳劑組合物向經其處理之纖維基材提供 對人類皮膚之柔軟感以及極佳的光滑性、保濕/滋润感及 舒適氣軟ι±。另外，纖維基材之特定吸水性在經軟化乳劑 組合物處理後得以維持。 、本發明亦關於-種使用該乳劑組合物軟化纖維結構之方 法’經其處理之纖維基材，且詳言之，係關於薄紙製品。 經本發明乳劑組合物處理之薄紙藉由併人有效量之軟化劑 有機聚⑪減及水溶性醇（尤其甘油）而具有增強之對人 員皮膚之柔軟性、光滑性、保濕/滋调感及鬆軟性，該二 减及該等水溶性醇係在無乾燥製程之情況下塗 吸水。所製備之薄紙製品保持纖維紙結構之特定 r而不會由處理製程造成任何破壞。 【先前技術】 在；化溥紙製品’向薄紙製品塗覆-些官能性聚矽氧。 亦向薄紙製品塗t_#軟化劑及一些二 133159.doc 201005035 舉例而言，PCT專利公開案WO 1996/024719 ["SOFT TISSUE PAPER CONTAINING AN OIL AND A POLYHYDROXY COMPOUND" (the procter & gamble corporation)]揭示藉由併 入有效量之塗覆於濕薄紙網之多羥基化合物及油而具有增 強之鬆散及觸摸柔軟性的薄紙。該薄紙的多羥基化合物及 .油之添加率以乾纖維重量計均為0.01 %-5%。該多羥基化合 .物及油分別包括甘油及聚矽氧烷基油。 曰本專利公開案 H(heisei)07-145596 ["COMPOSITION FOR TREATING WIPING PAPER" (Dow Corning Toray silicone Co·，Ltd.)]描述用於濕巾之處理組合物，其係由特 定二有機矽氧烷及多元醇組成且可最合適地用於賦予薄紙 可撓性、光滑性及柔軟觸感。該專利公開案亦提及用界面 活性劑乳化組分以製備具有超過50重量％水之乳劑。用乾 燥製程向乾薄紙塗覆處理組合物，且該組合物之塗覆量之 範圍為0.2-5.0重量％。 @ 該等軟化組合物及軟化方法應用於許多薄紙製品以改良 柔軟性及觸感。然而，出於經其處理之薄紙製品之柔軟性 尚不足以使人類皮膚在每日使用中感覺良好且所製備之薄 紙所提供之觸感主要涉及其柔軟性之原因，該等現有技術 不一定令人滿意。 此外，關於該等軟化組合物及軟化方法，除所製備之薄 紙製品觸感不夠外，本發明發明者發現另一問題。該問題 在於使用現有軟化組合物（如水包油乳劑或添加甘油方 法），一些如纖維紙結構之天然吸水性之性質會被軟化處 133159.doc 201005035 在現有技術中， 壞以換取向基材 理或乾燥製程破壞。亦即，發明者發現， 纖維基材之一些天然且有利的性質會經損 提供一定的柔軟性。 f發明内容】The invention also relates to novel softening emulsion compositions for fibrous substrates, especially thin paper. The softened emulsion composition provides softness to human skin as well as excellent smoothness, moisturizing/moisturizing feeling and comfortable softness to the fiber substrate treated therewith. In addition, the specific water absorption of the fibrous substrate is maintained after treatment with the softened emulsion composition. The present invention is also directed to a fibrous substrate which has been treated by the method of softening the structure of the fiber using the emulsion composition, and in particular, relates to a tissue product. The tissue treated by the emulsion composition of the present invention has enhanced softness, smoothness, moisturizing/taste and softness to human skin by combining an effective amount of softener organic poly 11 with water-soluble alcohol (especially glycerin). The second, minus the water-soluble alcohols are coated with water without a drying process. The prepared tissue paper product maintains the specific r of the fibrous paper structure without causing any damage by the processing process. [Prior Art] In the paper product, a thin paper product is coated with some functional polyoxyl. Also applied to thin paper products t_#softeners and some two 133159.doc 201005035 For example, PCT Patent Publication WO 1996/024719 ["SOFT TISSUE PAPER CONTAINING AN OIL AND A POLYHYDROXY COMPOUND" (the procter & gamble corporation) A tissue that has enhanced looseness and touch softness by incorporating an effective amount of a polyhydroxy compound and oil applied to a wet tissue web. The addition ratio of the polyhydroxy compound and the oil of the tissue is 0.01% to 5% by weight of the dry fiber. The polyhydroxy compound and oil include glycerin and polyoxyalkylene oil, respectively. H(heisei) 07-145596 ["COMPOSITION FOR TREATING WIPING PAPER" (Dow Corning Toray silicone Co., Ltd.)] describes a treatment composition for a wet wipe, which is composed of a specific diorganoindole The oxane and polyol are composed and can be most suitably used to impart flexibility, smoothness and soft touch to the tissue. The patent publication also mentions emulsifying components with surfactants to prepare emulsions having more than 50% by weight water. The treatment composition is applied to the dry tissue paper by a drying process, and the coating amount of the composition ranges from 0.2 to 5.0% by weight. @ These softening compositions and softening methods are applied to many tissue products to improve softness and feel. However, the softness of the tissue paper treated therewith is not sufficient to make the human skin feel good in daily use and the tactile sensation provided by the prepared tissue mainly relates to the softness thereof, and the prior art is not necessarily Satisfactory. Further, with regard to such softening compositions and softening methods, the inventors of the present invention have found another problem in addition to the insufficient feel of the prepared tissue paper. The problem lies in the use of existing softening compositions (such as oil-in-water emulsions or the addition of glycerin), some of which are inherently water-absorbent, such as fibrous paper structures, which are softened. 133159.doc 201005035 In the prior art, bad to change the orientation of the substrate Or the drying process is destroyed. That is, the inventors have discovered that some of the natural and advantageous properties of the fibrous substrate provide some flexibility through damage. f invention content]

探求本發明以解決以上所述的問題4發明者研發出新 穎的乳劑組合物，纟包含⑷二有機聚石夕氧貌，爾化 劑，⑹水及⑼水溶性一元醇或多元醇，其中該乳劑組合 物之連續相為由該（c)水與該（D)水溶性—元醇或多元醇以 至1.10之比率組成之水溶液，且該組分（C)及該組分 (D)之總含量在該乳劑組合物之3〇 〇至98 〇重量份範圍内。 發明者亦研發出包含其之新穎的軟化乳劑組合物，及使用 該乳J、、且0物軟化纖維結構之方法，經其處理之纖維基材 及尤其經其處理之薄紙製品。 詳言之，本發明係關於一種乳劑組合物，其包含： (A) [0_01至25.0以下重量份]二有機聚矽氧烷； (B) [0.01至20.0以下重量份]軟化劑； (C) [8.0至60.0重量份]水·，及 (D) [20.0至9〇.〇重量份]水溶性一元醇或多元醇， 其中該乳劑組合物之連續相為由該（c)水與該（D)水溶性一 元醇或多元醇以1 :〇,5至1: 1〇之比率組成之水溶液，且該組 分（C)及該組分（D)之總含量在該乳劑組合物之30.0至98,0 重量份範圍内。 該乳劑組合物在儲存過程中保持良好的時間穩定性及均 質外觀長達數月。此外，該乳劑組合物向經其處理之纖維 133159.doc 201005035 基材提供柔軟感以及極佳光滑性、保濕/滋潤感及舒適鬆 軟性。如吸水性之天然且有利的性質在經其處理纖維基材 後得以維持。 另外，對於製造經其處理之薄紙製品而言可省略另一乾 燥製程及添加甘油製程，因為該乳劑組合物之連續相基本 - 上由水性醇溶液、較佳甘油溶液組成。藉由使用該乳劑組 . 合物，將二有機聚矽氧烷及醇塗覆於乾薄紙網而無需乾燥 製程。 【實施方式】 以上所述之目標可如下實現。 {1} 一種乳劑組合物，其包含： (A) [0.01至25.0以下重量份]二有機聚矽氧烷； (B) [0.01至20·0以下重量份]軟化劑； (C) [8.0至60.0重量份]水；及 (D) [20.0至90.0重量份]水溶性一元醇或多元醇， 參 其中該乳劑組合物之連續相為由該（C)水與該（D)水溶性 • :元醇或多元醇以⑷至1:10之比率組成之水溶液，且 • 且刀（C)及該組分（D)之總含量在該乳劑組合物之3〇.〇 至98.0重量份範圍内。 {2}如{1}之乳劑組合物，其中該乳劑組合物之該連續相 具有30至90重量份之甘油含量。 {}如{1}或{2}之乳劑組合物，其中包含該組分⑷之乳 劑粒子具有5〇至10，_奈米之平均粒度。 {4}如{1}至{3}中任一項之乳劑組合物其中包含該組分 133159.doc 201005035 (A)之乳劑粒子具有5〇至3〇〇奈米之平 (5}如⑴至⑷中任-項之乳劑組合：度。 (A)之乳劑粒子為分子中具有至小 ，其中包含該組分 基、聚氧伸烧基L旨官能基:個j自由胺基官能 基團的二有機聚矽氧烷。 g此基組成之群之 {6}如⑴至{5}中任一項之乳劑組合物其 勺八 ({;)}[〇.:: 2°.°以下重量份W濕劑及視情況(Ο防腐劑广3 用於纖維基材之軟化乳劑組 至{6}中任一項之乳劑組合物。 其匕3如{1} {8}如{7}之用於纖維基材教 之軟化孔劑組合物，其中該纖 基材係選自由濕巾、織物、紡織品及紙組成之群。 ⑼—種軟化纖維結構之方法，其係藉由用如⑴至w中 任一項之乳劑組合物處理具有纖維結構之基材。 U0}-種纖維基材，其係經如請求項⑴至⑻中任一項之 乳劑組合物處理。 ❹ (1U如{1〇}之纖維基材’該纖維基材為薄紙製品。 下文詳細解釋本發明之組分、其他可選組分、乳劑組合 物本身及其製備。The present invention has been explored to solve the above-mentioned problems. 4 The inventors have developed a novel emulsion composition comprising (4) a diorganopolyoxan, an alkalizing agent, (6) water and (9) a water-soluble monohydric or polyhydric alcohol, wherein The continuous phase of the emulsion composition is an aqueous solution consisting of the (c) water and the (D) water-soluble alcohol or polyol to a ratio of 1.10, and the total of the component (C) and the component (D) The content is in the range of from 3 to 98 parts by weight of the emulsion composition. The inventors have also developed a novel softening emulsion composition comprising the same, a method of using the milk J, and a method of softening the fiber structure, a fibrous substrate treated therewith and a tissue paper product treated therewith. In particular, the present invention relates to an emulsion composition comprising: (A) [0_01 to 25.0 parts by weight or less] diorganopolyoxyalkylene; (B) [0.01 to 20.0 parts by weight or less] softener; [8.0 to 60.0 parts by weight] water·, and (D) [20.0 to 9〇.〇 parts by weight] a water-soluble monohydric or polyhydric alcohol, wherein the continuous phase of the emulsion composition is composed of the (c) water and the (D) an aqueous solution of a water-soluble monohydric or polyhydric alcohol in a ratio of 1: 〇, 5 to 1:1, and the total content of the component (C) and the component (D) is in the emulsion composition 30.0 to 98,0 parts by weight. The emulsion composition maintains good time stability and a uniform appearance for several months during storage. In addition, the emulsion composition provides softness and excellent smoothness, moisturizing/moisturizing feeling and comfort softness to the treated fiber 133159.doc 201005035 substrate. Natural and advantageous properties such as water absorption are maintained after the fibrous substrate has been treated therewith. Alternatively, another drying process and a glycerin addition process may be omitted for the manufacture of the treated tissue paper product because the continuous phase of the emulsion composition consists essentially of an aqueous alcohol solution, preferably a glycerin solution. By using the emulsion composition, the diorganopolysiloxane and the alcohol are applied to the dry tissue web without a drying process. [Embodiment] The above described objects can be achieved as follows. {1} An emulsion composition comprising: (A) [0.01 to 25.0 parts by weight or less] diorganopolyoxyalkylene; (B) [0.01 to 20,000 parts by weight or less] softener; (C) [8.0 To 60.0 parts by weight of water; and (D) [20.0 to 90.0 parts by weight] of a water-soluble monohydric or polyhydric alcohol, wherein the continuous phase of the emulsion composition is derived from the (C) water and the (D) water-soluble An aqueous solution of a polyol or a polyol in a ratio of (4) to 1:10, and wherein the total content of the knife (C) and the component (D) is in the range of from 3 〇 to 98.0 parts by weight of the emulsion composition. Inside. {2} The emulsion composition of {1}, wherein the continuous phase of the emulsion composition has a glycerin content of from 30 to 90 parts by weight. An emulsion composition such as {1} or {2}, wherein the emulsion particles comprising the component (4) have an average particle size of from 5 Å to 10 Å. [4] The emulsion composition of any one of {1} to {3} which comprises the component 133159.doc 201005035 (A) of the emulsion particles having a level of 5 to 3 nanometers (5) such as (1) The emulsion composition of any one of (4): degree. The emulsion particles of (A) are small to the molecule, and include the component group, polyoxyalkylene group L, functional group: a j free amine functional group The diorganopolyoxane of the group {6} of the group of the composition of the group of (1) to {5}, the spoon composition of eight ({;)} [〇.:: 2°.° or less The emulsion composition of any one of the wet agent of the fiber base and the softening emulsion group of the fiber substrate of any one of the following [6], such as {1} {8} such as {7} A softening agent composition for use in a fibrous substrate, wherein the fibrous substrate is selected from the group consisting of wet wipes, fabrics, textiles, and paper. (9) A method of softening a fibrous structure by using (1) to The emulsion composition according to any one of w is used to treat a substrate having a fibrous structure. The U0}-fiber substrate is treated with the emulsion composition according to any one of claims (1) to (8). ❹ (1U such as {1纤维} fibrous substrate 'the fiber Material is a tissue products. Explained in detail below components of the present invention, other optional components, and preparing an emulsion composition itself.

【组分（A)J 組分（A)為二有機聚矽氧烷，包括胺基官能性聚矽氧 烷、環氧官能性聚矽氧烷、磺酸酯官能性聚矽氧烷及聚氧 伸烷基官能性聚矽氧烷。不同官能基在向聚矽氧烷結構本 身提供增強之軟化性質方面發揮重要作用，且聚矽氧烷主 鏈提供超光滑性。此外，舒適的鬆軟性由乳劑狀態之組分 Ι 33159.doc ΙΟ 201005035 (A)與組分（D)之間的組合實現。 結構式（1) 0) 其中R1為未經取代、經氟取代 叭‘烷氧基取代或經羥基取[Component (A) J Component (A) is a diorganopolysiloxane, including an amine functional polyoxyalkylene, an epoxy functional polyoxyalkylene, a sulfonate functional polyoxyalkylene, and a poly Oxyalkylene-functional polyoxyalkylene. Different functional groups play an important role in providing enhanced softening properties to the polyoxyalkylene structure itself, and the polyoxyalkylene backbone provides ultra-smoothness. In addition, the comfort softness is achieved by the combination of the components of the emulsion state Ι 33159.doc ΙΟ 201005035 (A) and component (D). Structural formula (1) 0) wherein R1 is unsubstituted, substituted by fluorine, or substituted by hydroxyl group

更確切而言，二有機聚矽氧烷係由以下平均 表不：More specifically, the diorganopolyoxyalkylene is represented by the following average:

代之單價烴基。未經取代之單價烴基例如為甲基、乙基、 丙基或類似院基；苯基、曱苯基、二曱苯基或類似芳基； 或芳烷基。經氟取代之單價烴基例如為3,3,3_三氟丙^、 3,3,4,4,4-五氟丁基或類似的全氟烷基。在以上各者中，… 較佳為未經取代之單價烴基，較佳烷基或芳基且尤其甲基 或苯基。與矽原子鍵結之由Ri表示之基團中有一部分、= 其在分子末端 < 由R丨表示之基團中有一部> 可經羥基或烷 氧基（諸如甲氧基、乙氧基或丙氧基）置換。 R2為除R1以外之官能基且在向聚矽氧烷結構本身提供增 強之軟化性質方面發揮重要作用，且聚矽氧烷主鏈提供^ 光滑性。該官能基例如為由下式（2)表示之聚氧伸烷 基：_R3-0-(C2H40)a(C3H60)bR4[其中 R3 為具有 2至 3〇個碳 原子之伸烷基，R4為選自氫原子、具有1至3〇個碳原子之 烷基或具有下式-(OC)-R5(其中R5為具有！至3〇個碳原子之 烧基）之有機基團之基團’ 1 $a+b$3 0];曱氧基羰基丙 基、乙氧基羰基丙基或類似烷氧基羰基烷基；乙醯氧基丙 133159.doc 201005035 基、丙醯氧基丙基或類似烷基羰氧基烷基；3-胺基丙基、 3-(胺基乙基）胺基丙基、乙二胺基_2_甲基丙基-或烷基胺基 羰基烷基-、烷基羰基胺基烷基·、以〇H封端之胺基乙基胺 基異丁基曱基-[例如，-CH2CH(CH3)CH2-N(CH2CH(OH)CH2 OH)-CH2-NH(CH2CH(OH)CH2〇H)]或類似胺基官能基；環 ' 氧基；羧基；甘油基；聚甘油基；醣基；多醣基；巯基； . 曱醇基；磺酸酯基及醯胺基。詳言之，較佳二有機聚矽氧 Φ 烷為具有胺基官能基、聚氧伸烷基、磺酸酯官能基或環氧 官能基之甲基聚矽氧烷。其中最佳基團為由下式表示之胺 基官能基：-(CH2)d-(NHCH2CH2)e-NH-R4 或-CdH2d-(NHCH (OH)CH(OH))e-NH-CH(OH)CH(OH)(d在 1 至 1〇範圍内；6在 0至10範圍内）。 在上式中’ ”m”及"n"較佳滿足以下條件：且 OSm+n各5000 ;但當n=〇時，至少一個"Air2。"m"較佳 在5至2000範圍内且"η”較佳在〇至1〇〇範圍内。 ❹ 關於組分（Α)之黏度不存在特定限制；然而，自製備具 • 有改良之時間穩定性之乳劑的角度來看，推薦25。(：下組分 • (Α)之黏度較佳在25。〇下5至1，〇〇〇,〇〇〇111以3範圍内。 視情況可使（Α)二有機聚矽氧烷與其他二甲基聚矽氧烷 組合。該二甲基聚石夕氧炫可例如為直鏈二甲基聚石夕氧炫、 支鏈甲基聚石夕氧燒、揮發性環狀二甲基聚石夕氧炫；分子兩 端經三甲基石夕貌氧基封端之二甲基聚石夕氧燒、分子兩端經 三甲基石夕院氧基封端之甲基苯基聚石夕氧燒、分子兩端經石夕 烧醇（〇Η)基封端之二甲基聚石夕氧燒，其在坑下具有 133J59.doc -12· 201005035 至10,000 mm2/s範圍内之黏度。該等二甲基聚矽 知軟化劑且可包括在以下組分（B)中。 [组分（B)】 組分（B)為軟化劑。如本文中所使用，術語"軟化劑"係指 改良持有特定紙製品並用其在皮膚上摩擦之消費者所感知 ' 之觸感（人類皮膚之感覺）的任何化學成分。雖然柔軟性在 . $種程度上為毛巾製品所需’但柔軟性對面紙及衛生紙製 φ ’口而言亦為尤其重要之性質。該觸覺可感知柔軟性之特徵 可在於（但不限於）摩擦、可撓性及光滑性以及主觀描述 (subjective deScriptor)，諸如如潤滑、絲絨、絲或法蘭絨 之感覺。合適物質包括彼等賦予薄紙潤滑感之物質。 該、且刀例如為上述二甲基聚矽氧院、基礎蠘（諸如石蠟 及蜂蝶）及油類（諸如礦物油），以及凡士林及更複雜之潤滑 劑及四級銨化合物、碳氟化合物、經取代c 1 烷烴、 經取代C10-C22烯烴，尤其脂肪醇與脂肪酸之酯衍生物（諸 9 如脂肪酸醯胺、脂肪酸縮合物及脂肪醇縮合物）、糖衍生 • 物（諸如醚類及酯類）及其混合物。 -在本發明中，較佳軟化劑為四級銨化合物；單、二或三 西曰四級銨化合物；二（酯化四級銨）化合物或其 混合物。四 級銨化合物可具有（C10-C22)長烷基鏈。該四級銨化合物 可為咪唑啉鏽（imidaz〇Hnium)化合物，諸如咪唑啉鏽鹽或 其混合物。 合適四級銨化合物之實例可選自具有以下通式之化合 物： 133159.doc 13 201005035 (R,)4-b-N+-(R2)b X- 其中R1為Cl至C6烷基，R2為C10至C22烷基，l至3之整 數。其他類似化合物可包括簡單四級銨鹽之單酯、二酯、 單醯胺及二醯胺衍生物。X可為任何四㈣相容性陰離 . 子，例如在本發明中亦可使用乙酸根、氣離子、溴離^、 * 〒基硫酸根、甲酸根、硫酸根、硝酸根及其類似離子。 φ 纟他四級鍵化合物包括熟知之二燒基二甲基録鹽（例 如’氣化二動物脂二甲基銨、甲基硫酸二動物脂二甲基 銨、氣化二（氫化動物脂）二甲基銨等）及三烷基甲基銨鹽 (例如，氣化三動物脂甲基銨、甲基硫酸三動物脂曱= 銨、氣化三（氫化動物脂）甲基銨等）。 該等四級銨化合物之實例包括氣化烷基三曱基銨、氣化 硬脂醢基三甲基敍、氣化月桂基三甲基錢、氣化十六絲 三甲基錄、氣化牛脂烧基三甲基録、氣化二十二院基三甲 ❿ &銨、氫氧化辛基三甲基録、氫氧化十二絲三甲基錄、 • 溴化硬脂醯基三甲基銨、溴化二十二烷基三曱基銨、氣化 _ 二硬脂醯基二甲基銨、氯化二椰油醯基二甲基銨、氣化二 辛基一甲基銨、氣化二（POE)油基甲基銨（2E〇)、氣化苯甲 烴銨（benzalkonium chloride)、氣化烷基苯曱烴銨、氣化烷 基二甲基苯甲烴錢、节索氯銨（benzethonium chloride)、氣 化硬脂醯基二曱基苯曱基銨、羊毛脂衍生四級銨鹽、硬脂 酸二乙基胺基乙基醯胺、硬脂酸二甲基胺基丙基醯胺、二 十二烷酸醯胺、氯化丙基二甲基羥基丙基銨、西吡氯銨 I33159.doc •14- 201005035 (eetyiPyridinium chl〇Hde)、氣化松油院基苯甲基經乙基味 唾啉鑌或苯甲基銨鹽。 【组分（C)] 组分(C)為纟。水不應含有對人類有害之組分且應為乾 淨的水可例如為自來水、純水及礦質水。Instead of a monovalent hydrocarbon group. The unsubstituted monovalent hydrocarbon group is, for example, a methyl group, an ethyl group, a propyl group or the like; a phenyl group, a fluorenylphenyl group, a diphenylene group or the like aryl group; or an aralkyl group. The monovalent hydrocarbon group substituted by fluorine is, for example, 3,3,3-trifluoropropane, 3,3,4,4,4-pentafluorobutyl or the like perfluoroalkyl group. In each of the above, ... is preferably an unsubstituted monovalent hydrocarbon group, preferably an alkyl group or an aryl group and especially a methyl group or a phenyl group. a part of the group represented by Ri bonded to a ruthenium atom, = at the end of the molecule < a group represented by R & > may be via a hydroxyl group or an alkoxy group (such as methoxy, ethoxy) Substituted or propoxy). R2 is a functional group other than R1 and plays an important role in providing an enhanced softening property to the polyoxyalkylene structure itself, and the polyoxyalkylene main chain provides smoothness. The functional group is, for example, a polyoxyalkylene group represented by the following formula (2): _R3-0-(C2H40)a(C3H60)bR4 [wherein R3 is an alkylene group having 2 to 3 carbon atoms, and R4 is a group selected from a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, or an organic group having the following formula -(OC)-R5 (wherein R5 is a burn group having ! to 3 carbon atoms) 1 $a+b$3 0]; oxime oxycarbonylpropyl, ethoxycarbonylpropyl or similar alkoxycarbonylalkyl; ethoxylated propyl 133159.doc 201005035 propyl, propyloxypropyl or the like Alkylcarbonyloxyalkyl; 3-aminopropyl, 3-(aminoethyl)aminopropyl, ethylenediamine-2-methylpropyl- or alkylaminocarbonylalkyl-, Alkylcarbonylaminoalkyl·Aminoethylaminoisobutylphosphonium- terminated with 〇H-[eg, -CH2CH(CH3)CH2-N(CH2CH(OH)CH2OH)-CH2-NH (CH2CH(OH)CH2〇H)] or similar amine functional group; cyclic 'oxy group; carboxyl group; glyceryl group; polyglyceryl group; sugar group; polysaccharide group; fluorenyl group; sterol group; sulfonate group and oxime Amine. In particular, preferred diorganopolyoxy Φ alkane is a methyl polyoxyalkylene having an amine functional group, a polyoxyalkylene group, a sulfonate functional group or an epoxy functional group. The most preferred group is an amino functional group represented by the formula: -(CH2)d-(NHCH2CH2)e-NH-R4 or -CdH2d-(NHCH(OH)CH(OH))e-NH-CH( OH)CH(OH) (d is in the range of 1 to 1 ;; 6 is in the range of 0 to 10). In the above formula, ' ”m” and "n" preferably satisfy the following conditions: and OSm+n is 5000 each; but when n=〇, at least one "Air2. "m" is preferably in the range of 5 to 2000 and "η" is preferably in the range of 〇 to 1〇〇. 不 There is no specific limitation on the viscosity of the component (Α); however, since the preparation has improved For the time stability of the emulsion, it is recommended to 25. (The viscosity of the lower component • (Α) is preferably 25. The lower 5 to 1, the 〇〇〇, the 〇〇〇 111 to 3. It is possible to combine (Α) diorganopolysiloxane with other dimethyl polyoxane. The dimethyl polyoxo can be, for example, a linear dimethyl polyoxo, a branched methyl group. Oxygen-oxygen, volatile cyclic dimethyl polysulfide; both ends of the molecule are blocked by trimethyl sulphate oxy-terminated dimethyl polyoxan, and both ends of the molecule are passed through trimethyl sylvestre The methyl terminated polyoxylate of the base end, the dimethyl agglomeration of the two ends of the molecule which is terminated by the sulphuric acid (〇Η) group, which has 133J59.doc -12 under the pit. Viscosity in the range of 201005035 to 10,000 mm2/s. These dimethyl polyanthracene softeners may be included in the following component (B) [Component (B)] Component (B) is a softener. In this article As used, the term "softener" refers to any chemical composition that improves the touch (the feeling of human skin) perceived by a consumer holding a particular paper product and rubbing it on the skin. Although softness is at. To a certain extent, it is required for the towel product, but the softness is also of particular importance for the φ' mouth of the toilet paper and the toilet paper. The tactile perceived softness may be characterized by, but not limited to, friction, flexibility and Smoothness and subjective descriptor, such as the feeling of lubrication, velvet, silk or flannel. Suitable substances include those that impart a lubricious feeling to the tissue. The knife is, for example, the above-mentioned dimethyl polyoxane , basic hydrazines (such as paraffin and beeswax) and oils (such as mineral oil), as well as petrolatum and more complex lubricants and quaternary ammonium compounds, fluorocarbons, substituted c 1 alkanes, substituted C10-C22 olefins, In particular, ester derivatives of fatty alcohols and fatty acids (such as fatty acid decylamines, fatty acid condensates and fatty alcohol condensates), sugar derivatives (such as ethers and esters) and mixtures thereof Preferably, in the present invention, the preferred softening agent is a quaternary ammonium compound; a mono-, di- or tri-sulfonium quaternary ammonium compound; a di- (esterified quaternary ammonium) compound or a mixture thereof. The quaternary ammonium compound may have ( C10-C22) a long alkyl chain. The quaternary ammonium compound may be an imidaz 〇Hnium compound such as an imidazoline rust salt or a mixture thereof. Examples of suitable quaternary ammonium compounds may be selected from the group consisting of the following formula Compound: 133159.doc 13 201005035 (R,) 4-b-N+-(R2)b X- wherein R1 is a C1 to C6 alkyl group, and R2 is a C10 to C22 alkyl group, an integer from 1 to 3. Other similar compounds may include monoesters, diesters, monodecylamines and diamine derivatives of simple quaternary ammonium salts. X may be any four (four) compatible anion. For example, in the present invention, acetate, gas ion, bromine, * sulfhydryl sulfate, formate, sulfate, nitrate and the like may also be used. . The φ 纟 四 quaternary bond compound includes the well-known dialkyl dimethyl salt (for example, 'gasified di animal fat dimethyl ammonium, methyl di sulphate dimethyl ammonium, gasified two (hydrogenated animal fat) Dimethylammonium or the like) and a trialkylmethylammonium salt (for example, vaporized tri-animal methyl ammonium, methyl sulphate tri-alkali = ammonium, gasified tris (hydrogenated tallow) methyl ammonium, etc.). Examples of such quaternary ammonium compounds include vaporized alkyltrimethylammonium, vaporized stearyl sulphate trimethyl sulphate, gasified lauryl trimethyl ketone, gasified hexadecitrien trimethyl record, gasification Tallow-burning trimethyl record, gasification twenty-two hospital base trimethoprim & ammonium, octyltrimethyl hydroxide, twelfth trimethylamine hydroxide, • bromolyl trimethyl bromide Ammonium, behenyltrimethylammonium bromide, gasification _ distearyl dimethyl ammonium, dicocoyl dimethyl ammonium chloride, gasified dioctyl monomethyl ammonium, gas Chemically modified (POE) oleyl methyl ammonium (2E 〇), gasified benzalkonium chloride, vaporized alkyl benzoquinone ammonium, vaporized alkyl dimethyl benzoic acid, sulphonated chlorine Ammonium (benzethonium chloride), gasified stearyl decyl benzoyl benzyl ammonium, lanolin derived quaternary ammonium salt, stearic acid diethylaminoethyl decylamine, stearic acid dimethylaminopropyl Base amide, decyl behenate, propyl dimethyl hydroxypropyl ammonium chloride, cetylpyridinium chloride I33159.doc •14- 201005035 (eetyiPyridinium chl〇Hde), gasified pine oil Ethyl ether Parathionium or benzylammonium salt. [Component (C)] Component (C) is hydrazine. Water should not contain components harmful to humans and should be clean water such as tap water, pure water and mineral water.

[组分（D)J 刀（〇)水冷性一元醇或多元醇為以在室溫下與水之極[Component (D) J knife (〇) water-cooled monohydric alcohol or polyol for the extreme temperature and water at room temperature

佳相容性為特徵的液體。該組分向纖維基材提供保濕/滋 潤感且藉由在乳劑狀態中與⑷二有機聚⑦氧烧組合來提 供舒適鬆軟性。 該組刀（D)可為一種醇或水溶性一元醇或多元醇之混合 物較佳水溶性醇為具有2至8個碳原子之一元醇或多元 7此外，較佳組分⑼為低過敏性醇或其混合物，當其 h留在薄紙製品表面時對人類皮膚不引起刺激或引起極小 s刀（D)之特定實例包括乙醇、正丙醇、異丙醇、正 丁醇或類似-元低級醇；1，3_丁二醇、乙二酵、丙二醇或 .一 <兀醇’聚乙二醇、二丙二醇、聚丙二醇或類似聚烷 二醇· · 、、由 ，，田、二甘油、三羥甲基丙烷、異戊四酵、山梨糠 ，、由式ho-ch2(ch(oh)4_c〇〇^示之葡萄糖酸或類似 多元醇。 Θ .、,、用於溥紙處理之軟化乳劑’最佳組分(D)為甘油或 量^ °物’且錢劑組合物中之較佳甘油含量為至9〇重 133159.doc 15 201005035 [乳劑之連續相j 本發明乳劑組合物之特徵在於該乳劑組合物之連續相為 由（C)水及（D)水溶性一元醇或多元醇以i :〇 5至丨：1〇之比率 組成之水溶液，且該組分（c)及該組分⑺）之總含量在該乳 劑組合物之30.0至98.0重量份範圍内。 . 雖然本發明乳劑組合物與水包油乳劑具有類似乳化狀 • 態，但包含二有機聚矽氧烷之乳劑粒子乳化於以（D)水 ❹ 溶性一元醇或多元醇為主之水溶液中。 視（B)軟化劑於水溶液中之溶解性而定，其可分散於水 /谷液中（具有親水性之連續相）、分散於乳劑粒子中（具有疏 水性之油性粒子相）或作為界面活性劑分散於其乳劑界面 令。總之，本發明之乳化狀態極穩定以致該乳劑組合物在 儲存過程中保持良好的時間穩定性及均質外觀長達數月。 (A)二有機聚矽氧烷、（B)軟化劑及（D)水溶性一元醇或多 元醇各自之軟化作用在該特定乳化狀態中進一步得到改 • 良，且在經其處理之纖維基材中獲得對人類皮膚之柔軟感 • 以及極佳光滑性、保濕/滋潤感及舒適鬆軟性。另外，高 • 含置之加速（C)水蒸發之（D)水溶性一元醇或多元醇使得薄 紙處理製程無需乾燥製程。出於此原因，纖維基材之特定 吸水性在經該乳劑組合物處理後得以維持。 作為軟化乳劑組合物，該乳劑組合物之最佳連續相具有 以孔劑組合物之總重量份計30至9〇重量份之甘油含量。隨 後’可使甘油與其他低過敏性醇或其混合物組合。 作為軟化乳劑組合物，該乳劑之連續相中（c)水與⑴）水 I33I59.doc •16· 201005035 溶性一元醇或多元醇的較佳比率為1:0 75至丨：8，更佳比率 為 1:1 至 1:5。 另外，若軟化組合物含有大量組分（D)水溶性醇（尤其乙A fluid characterized by good compatibility. This component provides a moisturizing/moisturizing sensation to the fibrous substrate and provides comfort softness by combining with (4) diorganopolyoxygenate in the emulsion state. The set of knives (D) may be an alcohol or a mixture of water-soluble monohydric or polyhydric alcohols. Preferably, the water-soluble alcohol is a monohydric alcohol or a polyhydric alcohol having 2 to 8 carbon atoms. Further, the preferred component (9) is hypoallergenic. A specific example of an alcohol or a mixture thereof which does not cause irritation to human skin when it remains on the surface of a tissue paper or causes a very small s knife (D) includes ethanol, n-propanol, isopropanol, n-butanol or the like. Alcohol; 1,3_butanediol, ethylene diacetate, propylene glycol or a <sterol' polyethylene glycol, dipropylene glycol, polypropylene glycol or similar polyalkylene glycol · ·, ,,,,,,,,, , trimethylolpropane, isovaric acid, sorbitan, gluconic acid or similar polyol represented by the formula ho-ch2(ch(oh)4_c〇〇. Θ ., , for crepe paper processing The softening emulsion 'the best component (D) is glycerin or the amount ', and the preferred glycerin content in the money composition is up to 9 〇 133159.doc 15 201005035 [Continuous phase of the emulsion j emulsion composition of the invention Characterized in that the continuous phase of the emulsion composition is composed of (C) water and (D) water-soluble monohydric or polyhydric alcohol with i: 〇5 to 丨:1 The ratio of hydrazine is an aqueous solution of the composition, and the total content of the component (c) and the component (7)) is in the range of 30.0 to 98.0 parts by weight of the emulsion composition. Although the emulsion composition of the present invention has an emulsion-like state similar to that of the oil-in-water emulsion, the emulsion particles containing the diorganopolysiloxane are emulsified in an aqueous solution mainly composed of (D) water-soluble monohydric alcohol or polyol. Depending on the solubility of the (B) softener in an aqueous solution, it may be dispersed in water/gluten (a continuous phase having hydrophilicity), dispersed in emulsion particles (oily particle phase having hydrophobicity) or as an interface The active agent is dispersed in its emulsion interface. In summary, the emulsified state of the present invention is extremely stable so that the emulsion composition maintains good time stability and a homogeneous appearance for several months during storage. The softening action of each of (A) diorganopolyoxyalkylene, (B) softener and (D) water-soluble monohydric or polyhydric alcohol is further improved in this particular emulsified state, and the fiber base treated therewith The material is soft to the human skin • It also has excellent smoothness, moisturizing/moisturizing and comfortable softness. In addition, the high (including) accelerated (C) water evaporation (D) water-soluble monohydric alcohol or polyol allows the tissue processing process to eliminate the need for a drying process. For this reason, the specific water absorption of the fibrous substrate is maintained after being treated by the emulsion composition. As a softening emulsion composition, the optimum continuous phase of the emulsion composition has a glycerin content of from 30 to 9 parts by weight based on the total weight of the pore former composition. The glycerin can then be combined with other hypoallergenic alcohols or mixtures thereof. As a softening emulsion composition, a preferred ratio of (c) water to (1) water I33I59.doc •16·201005035 in the continuous phase of the emulsion is 1:0 75 to 丨:8, a better ratio It is 1:1 to 1:5. In addition, if the softening composition contains a large amount of component (D) water-soluble alcohol (especially B

醇、甘油或類似低級醇），則該組合物將因該等醇而高度 易燃。 B 然而，在該軟化乳劑組合物中，含有（c)水之水溶液在 ' 製造、儲存及運輸期間降低可燃性且提供較高安全性 該 ❹ f低可燃性使得本發明乳劑組合物尤㈣處理薄紙製品而 言為易於使用且安全之軟化組合物。 此外，可預先將諸如水溶性離子型界面活性劑、水性香 -水性顏料或潤膚劑（如水生植物提取物）之水溶性組分 分散於（C)水中，隨後與用於製備本發明乳劑組合物之組 合物混合。 另方面，由於（C)水與（D)水溶性醇之水溶液具有比水 本身低侍多的冰點，因此該乳劑組合物在寒冷地區之冬季 © ㈣冷;東且提供良好的冷來/料穩定性。 、 [乳制粒子] 〇乳劑、.且口物之乳劑粒子包含該（Α)二有機聚矽氧烷及 &(A)1機聚碎氧燒相容之其他疏水性組分。當部分或 斤有該（B)軟化劑為疏水性軟化劑時，該⑻軟化劑可包含 在礼劑粒子中或作為界面活性劑包含在乳劑界面上。 雖…、關於礼劑粒度不存在特定限制，但較佳當製備本發 月乳劑組°物作為用於纖維基材之軟化乳劑組合物時，其 〜八有*由田射繞射/分散法或庫侖特計數器法（Coulter 133159.doc 201005035The alcohol will be highly flammable due to the alcohol, glycerol or similar lower alcohol. B However, in the softened emulsion composition, the aqueous solution containing (c) water reduces flammability during manufacture, storage and transportation and provides higher safety. The low flammability of the emulsion makes the emulsion composition of the present invention (IV) In the case of tissue paper products, it is an easy to use and safe softening composition. Further, a water-soluble component such as a water-soluble ionic surfactant, an aqueous fragrant-aqueous pigment or an emollient (such as an aquatic plant extract) may be previously dispersed in (C) water, followed by use in the preparation of the emulsion of the present invention. The composition of the composition is mixed. On the other hand, since the aqueous solution of (C) water and (D) water-soluble alcohol has a lower freezing point than water itself, the emulsion composition is cold in the cold region © (4) cold; and provides good cold/feeding stability. [Milk particles] 〇 emulsion, and the emulsion particles of the mouth material comprise the (Α) diorganopolyoxy siloxane and the other hydrophobic component compatible with the & (A) 1 machine. When the (B) softener is partially or hydrophobic, the (8) softener may be included in the granule particles or included as a surfactant at the emulsion interface. Although there is no particular limitation on the particle size of the granule, it is preferred to prepare the emulsifiable emulsion composition as a softening emulsion composition for a fibrous substrate, which is arbitrarily diffracted by a field diffraction/dispersion method or Coulomb counter method (Coulter 133159.doc 201005035

Counter Method)量測時不龆讲〗 吁不超過10.0 μιη之平均乳劑粒子。 為保持時間穩定性長達數月而無相分離，平均粒 奈米與10.0微米(亦即，10，_奈米)之間的範圍内， 此外，當製備本發明乳劑組合物作為用於薄紙製品之軟 化乳劑組合物時’較佳平均乳劑粒子當由雷射繞射/分散 法或庫侖特計數器法量測時+ 二射/刀散 小於0.3—00奈米）。]於〇.5叫500奈米）且尤其 ❹ 參 最佳乳劑組合物為粒度為5〇至3〇〇奈米、尤其約BO奈米 之微乳劑。該較佳微乳劑組合物具有混濁透明 存餘中料其㈣“狀― 使《準㈣機械㈣設備或操作進行乳化 而言，可使用任何合適的剪切源進行該混合及乳化，】 切源諸如高速攪拌器、均質 '•剪 署.聲”日顯不儀、微流化床裝 羅換罐式混合機（TureU〇changecanmixer)、羅 斯/吧u機（R〇ss mjx )、艾盤 、、 mnn、去心 ）乂盤巴奇膝體磨（Eppenbachconoid m山）、連續式分散機（hom〇mic line m 鐘IS?般·+、曰人W 勒I'混合機、旋 機、雙螺桿_機及類似裝置。製造階段可 之機械剪切裝置，且可採用不同乳化程序之 兩個或兩個以上步驟以製 適當時，亦可採用人工混合。α度之㈣組合物。 關於乳切序1造㈣衫在以 據以下步驟製備包含以上袓分”如了根 分⑼之本發明乳劑組合物。⑷、組分⑻、組分⑹及組 I33I59.doc 201005035 二見:預定量之㈧二有機聚碎氧燒、預定量之⑻軟化 齊丨及視情況預定量之⑼其他界面活性劑置放於高速授拌 /£ δ機中且藉由授摔混合預定時間。 ⑺將預定量之（C)水、視情況（Ε)保濕劑、㈣腐劑、 (H) pH值調節劑置放於高速搜掉混合機中且藉由授摔一起 混合預定時間。在該步财，可在各階段中逐步添加預定 量之（C)水且藉由擾拌與其混合。Counter Method) When measuring, do not talk about the average emulsion particles of no more than 10.0 μιη. In order to maintain time stability for several months without phase separation, between average grain nanometers and 10.0 micrometers (ie, 10, nanometers), in addition, when preparing the emulsion composition of the present invention as a tissue paper product When softening the emulsion composition, it is preferred that the average emulsion particles are less than 0.3-00 nm when measured by a laser diffraction/dispersion method or a Coulomb counter method. ] 〇. 5 is 500 nm) and especially ❹ The optimum emulsion composition is a microemulsion having a particle size of 5 〇 to 3 〇〇 nanometers, especially about BO nanometers. The preferred microemulsion composition has a turbid transparent residue material. (4) "Shape" In order to emulsify the equipment or operation of the quasi-(four) machine (4), the mixing and emulsification can be carried out using any suitable shear source. Such as high-speed agitator, homogenized '• shearing. Sound', the micro-fluidized bed-type tank change mixer (TureU〇changecanmixer), Ross/bar machine (R〇ss mjx), Aipan, , mnn, go to heart) 乂 巴 巴 巴 巴 ( (Eppenbachconoid m mountain), continuous disperser (hom〇mic line m clock IS? +, 曰人 W 勒 I' mixer, rotary machine, twin screw Machines and similar devices. Mechanical shearing devices can be used in the manufacturing stage, and two or more steps of different emulsification procedures can be used to make them suitable, or artificial mixing can be used. The (4) composition of the α degree. The first embodiment of the invention is prepared by the following steps: preparing the emulsion composition of the invention comprising the above-mentioned components, such as roots (9). (4), component (8), component (6) and group I33I59.doc 201005035 See also: predetermined amount (eight) two Organic poly-calcination, predetermined amount (8) softening and pre-conditioning (9) Other surfactants are placed in a high-speed mixing machine and mixed by a drop-off for a predetermined time. (7) A predetermined amount of (C) water, as the case (Ε) humectant, (4) humic agent, ( H) The pH adjusting agent is placed in a high-speed search mixer and mixed by a drop for a predetermined time. In this step, a predetermined amount of (C) water can be gradually added in each stage and disturbed by mixing.

(3)將預定量之⑼水溶性一元醇或多元醇置放於高速授 拌混合機中且藉由麟-起混合預定時間直至所有組分分 散且乳化成均質狀態。 此處所使用之高速攪拌混合機例如為均質混合機、槳式 混合機、漢壽爾混合機（Hensehel mixer)、均f分散機、膠 體磨、用於真线合之㈣混合機、雙螺桿㈣機等。然 而，關於混合機之類型不存在特定限制，只要其具有優越 的乳化能力且產生穩定乳劑即可。 在任何步驟（2)或（3)中，可用某種水混合物或由組分（c) 及組分（D)組成之水溶液替換（C)水。實務上，可對特定設 備或製造方法作出回應而採用組分之該種預混合。(3) A predetermined amount of the (9) water-soluble monohydric alcohol or polyhydric alcohol is placed in a high-speed mixing mixer and mixed by a predetermined time until all the components are dispersed and emulsified into a homogeneous state. The high-speed agitating mixer used herein is, for example, a homomixer, a paddle mixer, a Hensehel mixer, a homodisperser, a colloid mill, a mixer for a true wire, a twin screw (four). Machine and so on. However, there is no particular limitation as to the type of the mixer as long as it has superior emulsifying ability and produces a stable emulsion. In any of the steps (2) or (3), the water may be replaced with a certain water mixture or an aqueous solution consisting of the components (c) and (D). In practice, this type of premixing of components can be used in response to a particular device or manufacturing method.

[組分（G):界面活性劑J 在本發明中，部分組分（B)亦充當界面活性劑之一部分 以將組分（A)及與其相容之其他疏水性組分乳化於組分（〇) 及組分（D)之水溶液中。亦即，某部分組分（B)具有軟化劑 與界面活性劑之間的重疊功能》 然而，當組分（B)具有不良乳化能力及/或存在改良乳劑 I33159.doc •19- 201005035 時間穩定性之意向時，本發明乳劑組合物可進一步含有 (G)界面活性劑。（G)界面活性劑之較佳量為該（a)二有機聚 矽氧烷之0·5至20.0重量份。當（G)界面活性劑包含非離子 界面活性劑時，（G)界面活性劑之更佳量為該（Α)二有機聚 矽氧烷之1.0至10.0重量份。 . 關於一或多種類型之上述（G)界面活性劑不存在特定限 • 制。該界面活性劑之實例包括離子界面活性劑、非離子界 φ 面'舌性劑或兩者之組合。自改良乳劑組合物時間穩定性之 角度來看，較佳使用一或多種類型之（G1)非離子界面活性 劑。 當製備乳劑組合物時，通常，首先可向組分及與其 相容之其他疏水性組分之預形成混合物中添加低親水親油 平衡（HLB)非離子界面活性劑。隨後製備含有高hlb界面 活性劑之水溶液’向其中混入上述混合物。混合所組合之 組分以形成粗乳劑，隨後使粗乳劑乳化以完成乳劑組合 ❹ 物。 - 更詳言之’ 一或多種類型之非離子界面活性劑（G1)之實 例例如為聚氧伸烷基醚、聚氧伸烷基烷基醚、聚氧伸院基 脂肪酸酯、聚氧伸烷基脂肪酸二酯、聚氧伸烷基樹脂酸 醋、聚氧伸烷基（氫化）蓖麻油、聚氧伸烷基烷基酚、聚氧 伸烷基烷基苯基醚、聚氧伸烷基苯基苯基醚、聚氧伸烷基 烷基酯、脫水山梨糖醇脂肪酸酯、聚氧伸烷基脫水山梨糖 醇烧基醋、聚氧伸烷基脫水山梨糖醇脂肪酸酯、聚氧伸燒 基山梨糖醇脂肪酸酯、聚氧伸烷基甘油脂肪酸酯、聚甘油 133159.doc •20· 201005035 烧基醚、聚甘油脂肪酸酯、蔗糖脂肪酸酯、脂肪酸烷醇醯 胺、烷基糖苷、聚氧伸烷基脂肪酸雙苯基醚、聚丙二醇、 全氟聚醚型界面活性劑、聚氧化乙烯-聚氧化丙烯嵌段共 聚物及烧基聚氧化乙烯-聚氧化丙烯嵌段共聚物醚。 一或多種類型之離子界面活性劑（G2)之實例包括陰離子 界面活性劑、陽離子界面活性劑或兩性界面活性劑。陰離 子界面活性劑之實例包括飽和或不飽和脂肪酸鹽（例如， 月桂酸鈉、硬脂酸鈉、油酸鈉及亞油酸鈉等長鏈烷基 硫酸鹽；烷基苯續酸（例如，己基苯續酸、辛基苯磺酸及 十二烷基苯磺酸等）及其鹽；聚氧伸烷基烷基醚硫酸鹽； 聚氧伸烷基烯基醚硫酸鹽；聚氧化乙烯烷基硫酸酯鹽；績 酸基丁二酸烷基酯鹽；聚氧伸烷基續酸基丁二酸鹽；聚氧 伸烷基磺酸基丁二酸酯鹽；聚氧伸烷基改質二甲基聚碎氧 烷之磺酸基丁二酸酯之鹼金屬鹽；聚氧伸烷基烷基苯基喊 硫酸鹽；長鏈烷烴磺酸鹽；長鏈烷基磺酸鹽；聚氧化乙稀 烧基本基乙基硫酸鹽，聚氧伸烧基烧基喊乙酸鹽；長鏈院 基磷酸鹽；聚氧伸炫基烧基醚填酸鹽；酿基麵胺酸鹽；醯 基磺酸鹽；長鏈烧基續酸鹽；院基稀丙基續酸鹽；長鍵α_ 烯烴磺酸鹽；烷基萘磺酸鹽；長鏈烷烴磺酸鹽；長鏈烧基 或稀基績酸鹽；長鏈烧基醯胺績酸鹽；長鍵烧基或稀基碟 酸鹽；烷基醯胺磷酸鹽；烷醯基烷基牛磺酸鹽；Ν_酿基胺 基酸鹽；磺酸基丁二酸鹽；烷基烷基醚羧酸鹽；醯胺喊緩 酸鹽；α-磺酸基脂肪酸酯鹽；丙胺酸衍生物；甘胺酸衍生 物或精胺酸衍生物。上述各物之實例包括鈉鹽、钾鹽或類 133159.doc 21 201005035 似驗金屬鹽；三乙醇胺鹽或類似烷醇胺鹽以及銨鹽，但鈉 鹽較佳。 兩性界面活性劑（G3)之實例包括磷脂，諸如卵磷脂、磷 脂醯乙醇胺、麟脂酸、碟脂酿肌醇、鱗脂酿絲胺酸、填脂 酿膽驗、填月旨醯甘；由、„月旨、心填脂或上述化合物之氯 化物。氫化大豆印碟脂、蛋黃印填脂、油菜印碗脂或類似 • 氫化天然卵磷脂最佳。 ^ 【(E)保濕添加劑] 為改良經本發明㈣組合物處理之纖維基材之光滑性及 保/,.、、/滋/閏感，本發明乳劑組合物較佳包含一或多種類型 之⑻保濕添加劑。在特定情況下，該等組分可稱為"潤膚 劑"。 保濕添加劑具有自大氣中吸引水蒸汽（水份）且將其帶至 經處理基材表面之能力，此產生光滑性及保濕/滋润感且 緩解乾燥。 Φ 該組分⑻之實例包括腺、乳酸鈉、多酿、異構酷、山 • 梨糖醇、腺、料㈣㈣納（SGdium pCA)、植物提取物 及其他類似生物活性劑。較佳組分⑻為乳酸鈉、天鈇植 物提取物、海草提取物及草藥。其中’蘆蒼提取物及㈣ 鈉尤其較佳。 其他植物提取物及其他生物活性劑之實例如下：明日葉 (Angelica keiskei)提取物、鱷梨（av〇cad〇)提取物、粗齒八 仙（Hydrangea serrata)提取物、蜀葵屬植物（An)提取 物、山金車屬植物（Arnica)提取物、蘆薈⑷〇e)提取物、杏 133159.doc -22- 201005035 (apricot)提取物、杏仁（apricot kernel)提取物、銀杏 (Gingko biloba)提取物、茴香（Fennei)果提取物、薑黃 (Turmeric)根提取物、烏龍茶（〇〇i〇ng tea)提取物、薔薇 (Rosa multiflora)提取物、紫錐菊（Echinacea angustifolia) 葉提取物、黃答（Scutellaria baicalensis)根提取物、黃禁 (Phellodendron amurense)提取物、黃連（Coptis rhizome)提 取物、大麥（Hordeum vulgare)籽提取物、貫葉連翹 (Hypericum perforatum)提取物、野芝麻（Lamium album)提 取物、豆瓣菜（Nasturtium officinale)提取物、橙提取物、 乾海產物水溶液（dried sea water solution)、海草提取物、 水解彈性蛋白、水解小麥粉末、水解絲、甘菊 (Chamomile)提取物、胡蘿蔔提取物、茵陳蒿（Artemisia capillaris)花提取物、甘草（Licorice)提取物、玫瑰茄 (Karkade)提取物、火棘（Pyraeantha fortuneana)提取物、摘 猴桃（kiwi)提取物、金雞納樹（Cinchona)提取物、黃瓜提取 物、鳥苷、振子（Gardenia florida)提取物、絲葉（Sasa veitchii)提取物、苦參（Sophora angustifolia)提取物、胡桃 提取物、葡萄柚提取物、鐵線蓮（Clematis vitalba)葉提取 物、小球議（chlorella)提取物、桑樹（Morus alba)根提取 物、黃龍膽（Gentiana lutea)提取物、紅茶提取物、酵母提 取物、牛蒡提取物、醱酵米糠提取物、米胚芽油、康福利 草（Comfrey)提取物、膠原、越桔（Vaccinum vitis idaea)提 取物、細辛（Asiasarum)根提取物、柴胡（Bupleurum falcatum)提取物、臍帶提取物、鼠尾草（Salvia)提取物、 133159.doc -23- 201005035 肥皂草（Soapwort)提取物、竹筍（Sasa bamboo grass)提取 物、野山楂（Crataegus cuneata)果提取物、秦椒（Zanthoxylum piperitum)提取物、香兹（Shiitake)提取物、地黃（Rehmannia) 根提取物、紫草（Lithospermum erythrorhizone)根提取物、 紫蘇（Perilla ocymoide)提取物、心葉椴（Tilia cordata)花提 取物、榆绩線菊（Spiraea ulmaria)提取物、芍藥（Paeonia albiflora)提取物、菖蒲（Acorns calamus)根提取物、白樺 (Betula alba)提取物、問荆（Equisetum arvense)提取物、常 春藤（Hedera helix)提取物、英國山楂（Crataegus oxyacantha) 提取物、歐洲接骨木（Sambucus nigra)提取物、蓍草 (Achillea millefolium)提取物、歐薄荷（Mentha piperita)葉 提取物、鼠尾草（Sage)提取物、錦葵（Malva sylvestris)提 取物、東川芎（Cnidium officinale)根提取物、日本揮牙菜 (Swertia japonica)提取物、大豆（Soybean)提取物、酸棗 (Zizyphus jujuba)果提取物、百里香（thyme)提取物、茶提 取物、丁香（Eugenia caryophyllus)花提取物、白茅（imperata cylindrica)提取物、溫州蜜柑（Citrus unshiu Marc)提取 物、當歸（Angelica)根提取物、金盞菊（Calendula officinalis) 提取物、桃（Prunus persica)核提取物、酸撥（citrus aurantium)皮提取物、魚腥草（Houttuynia cordata)提取物、 蕃茄提取物、納豆提取物、胡蘿蔔提取物、大蒜提取物、 玫瑰（Rosa canina)果提取物、木槿（Hibiscus)提取物、沿階 草屬植物（Ophiopogon)提取物、荷花（Nelumbo nucifera)提 取物、香芹提取物、蜂蜜、金縷梅（Witch hazel)提取物、 133159.doc •24- 201005035 牆草（Parietaria officinalis)提取物、毛果香茶菜（Isodon trichocarpus)提取物、沒藥醇（bisabolol)、枇杷（Eriobotrya japonica)提取物、款冬（Coltsfoot)花提取物、蜂鬥菜（Petasites japonicus)提取物、茯荟（Poria cocos)提取物、假葉樹 (Butcher's broom)提取物、葡萄提取物、蜂膠、絲瓜（Luffa * cylindrica)果實提取物、紅花（Safflower)花提取物、胡椒 . 薄荷（peppermint)提取物、南京椴（Tillia miquellana)提取 物、牡丹（Paeonia suffruticosa)根提取物、乾蛇麻（hops)提 ❹ 取物、長白松（Pinus sylvestris)松果提取物、七葉樹（horse chestnut)提取物、日本臭兹（Japanese skunk-cabbage)提取 物、無患子（Sapindus mukurossi)皮提取物、蜜蜂花 (Melissa)提取物、桃提取物、矢車菊（C：entaurea cyanus)花 提取物、桉樹（Eucalyptus)提取物、虎耳草（Saxifraga sarementosa)提取物、香橙（Citrus junos)提取物、薏苡仁 (Coix seed)提取物、艾草（Artemisia princeps)提取物、黨 φ 衣草（lavender)提取物、蘋果提取物、萵苣提取物、檸檬 • k取物、紫雲英（Astragalus sinicus)提取物、玫瑰提取 物、迷迭香（rosemary)提取物、羅馬洋甘菊（R〇man chamomile)提取物及蜂王漿提取物。 [(F)防腐劑】 組分（F)為防腐劑，其通常添加至乳劑組合物中且可添 加至本發明乳劑中’其例如為（F1)消毒劑之群，包括對經 基苯甲酸院基醋、苯甲酸、苯甲酸鈉、山梨酸、山梨酸 鉀、苯氧乙醇；及(F2)抗菌劑之群，包括苯甲酸、水揚 133159.doc •25· 201005035 酸、石炭酸、山梨酸、對羥基笨甲酸烷基酯、對氣甲基甲 紛（p-chlormethaeresol)、六氣芬（hexachi〇r〇phene)、氯化 本甲經敍、氣化氣己定（chlorhexidine chloride)、三氣碳酿 苯胺（trichlorocarbanilide)、三氯生（trichi〇san)、光敏成 分、苯氧乙醇、甲基異。塞唑琳酮等。 ' 該等化合物應以足以阻止乳劑組合物腐爛之量使用。 , [可選組分】 ❹ 乳劑組合物可進一步含有（Η) pH值調節劑、（J)芳香劑、 (K)抗氧化劑、（L)水溶性聚合物或其他如下所述之（M)生 物學活性組分，或不對其性質有害之極限内之該等試劑的 至少一種類型。 (H) pH值調節劑，其通常添加至乳劑中且可添加至本發 明乳劑組合物中，其例如為乳酸、檸檬酸、乙醇酸、丁二 酸、酒石酸、dl-蘋果酸、碳酸钟、碳酸氣鈉、碳酸氯錄 等。 © (J)方香劑，其通常添加至曰常使用纖維基材中且可添加 . 1本發明乳劑組合物巾，其係用於Μ經處理之基材某種 彡f、香味或用於掩蔽令人不悦的氣味。關於芳香劑類型 並無，定，制，其限制條件在於其為通常添加至薄紙製品 中S夫芳香劑，且該組分之實例包括多種以上展示作為 ±物學活性組分之提取物；多種植物之花、籽、葉及根提 取物丄自海草提取之芳香劑；自動物多個部位或分泌腺提 芳香Μ (例如，麝香及錄油）；或人工合成芳香劑（例 如，薄荷腦、麝香、乙酸乙酯或香草精）。 133159.doc -26· 201005035 (κ)抗氧化劑，其诵堂，天‘ s r 再通常添加至乳冑中且1添加 乳劑組合物中，例如為生育紛、丁基化經基月 丁基經基甲苯、植酸、類胡蘿㈣、類黃綱 ： ㈣—、木脂素(lig叫或息角皆。該試劑應以 護 乳劑中之組分免於氧化之量添加。 護[Component (G): Surfactant J In the present invention, part of the component (B) also functions as a part of the surfactant to emulsify the component (A) and other hydrophobic components compatible therewith with the component. (〇) and in the aqueous solution of component (D). That is, a part of the component (B) has an overlapping function between the softener and the surfactant. However, when the component (B) has poor emulsifying ability and/or the presence of a modified emulsion I33159.doc • 19-201005035 time stable In the intention of sex, the emulsion composition of the present invention may further contain (G) a surfactant. The preferred amount of the (G) surfactant is from 0.5 to 20.0 parts by weight of the (a) diorganopolyoxyalkylene. When the (G) surfactant contains a nonionic surfactant, a more preferred amount of the (G) surfactant is from 1.0 to 10.0 parts by weight of the (Α) diorganopolyoxyalkylene. There are no specific restrictions on one or more of the above (G) surfactants. Examples of the surfactant include an ionic surfactant, a nonionic boundary φ face lingual agent, or a combination of both. From the standpoint of the time stability of the modified emulsion composition, one or more types of (G1) nonionic surfactants are preferably used. When preparing emulsion compositions, in general, a low hydrophilic-lipophilic balance (HLB) nonionic surfactant can first be added to the preformed mixture of the components and other hydrophobic components compatible therewith. Subsequently, an aqueous solution containing a high-hlb surfactant is prepared, into which the above mixture is mixed. The combined components are combined to form a coarse emulsion, which is then emulsified to complete the emulsion composition. - More specifically - Examples of one or more types of nonionic surfactant (G1) are, for example, polyoxyalkylene ethers, polyoxyalkylene alkyl ethers, polyoxyalkylene fatty acid esters, polyoxygen Alkyl fatty acid diester, polyoxyalkylene resin vinegar, polyoxyalkylene (hydrogenated) castor oil, polyoxyalkylene alkyl phenol, polyoxyalkylene alkyl phenyl ether, polyoxygen extension Alkyl phenyl phenyl ether, polyoxyalkylene alkyl ester, sorbitan fatty acid ester, polyoxyalkylene sorbitan sulphuric acid vinegar, polyoxyalkylene sorbitan fatty acid ester , polyoxyalkylene sorbitan fatty acid ester, polyoxyalkylene glycol fatty acid ester, polyglycerol 133159.doc •20· 201005035 alkyl ether, polyglycerin fatty acid ester, sucrose fatty acid ester, fatty acid alkanol Indoleamine, alkyl glycoside, polyoxyalkylene fatty acid bisphenyl ether, polypropylene glycol, perfluoropolyether surfactant, polyoxyethylene-polyoxypropylene block copolymer and alkyl-polyoxyethylene-polyoxidation Propylene block copolymer ether. Examples of one or more types of ionic surfactant (G2) include an anionic surfactant, a cationic surfactant or an amphoteric surfactant. Examples of anionic surfactants include saturated or unsaturated fatty acid salts (for example, long-chain alkyl sulfates such as sodium laurate, sodium stearate, sodium oleate, and sodium oleate; alkylbenzene acids (eg, hexyl) Benzoic acid, octylbenzenesulfonic acid, dodecylbenzenesulfonic acid, etc.) and salts thereof; polyoxyalkylene alkyl ether sulfate; polyoxyalkylene ether sulfate; polyoxyethylene alkyl Sulfate salt; alkyl acid succinate; polyoxyalkylene acid succinate; polyoxyalkyl sulfosuccinate; polyoxyalkylene modified Alkali metal salt of sulfonic acid succinate of methyl polyoxyalkylene; polyoxyalkylene alkyl phenyl sulfate; long chain alkane sulfonate; long chain alkyl sulfonate; Dilute base ethyl sulphate, polyoxyalkylene sulphonate; long chain polybasic phosphate; polyoxy hydrazinyl etherate; flavonoid; sulfhydryl sulfonate Salt; long-chain alkyl sulphate; fenyl-propyl propylate; long-chain α_ olefin sulfonate; alkylnaphthalene sulfonate; long-chain alkane sulfonate; long-chain alkyl or dilute Acid salt; long chain alkyl amide salt; long bond or base disk; alkyl guanamine phosphate; alkyl alkyl alkyl taurate; Sulfosyl succinate; alkyl alkyl ether carboxylate; decyl sulfonate; α-sulfonate fatty acid ester; alanine derivative; glycine derivative or arginine derivative Examples of the above substances include sodium salt, potassium salt or the like 133159.doc 21 201005035 like metal salt; triethanolamine salt or similar alkanolamine salt and ammonium salt, but the sodium salt is preferred. Amphoteric surfactant (G3) Examples include phospholipids, such as lecithin, phospholipids, ethanolamine, linoleic acid, fat-filled inositol, squamous sucrose, fat-filled sputum test, filling the moon, and filling the moon; Lipid or chloride of the above compound. Hydrogenated soybean ink, egg yolk, rapeseed or similar • Hydrogenated natural lecithin. ^ [(E) Moisturizing additive] For improvement of the composition of the invention (4) The smoothness of the fibrous substrate and the /,., / / 滋 / 闰 feeling, the emulsion composition of the present invention preferably comprises one or more types (8) Moisturizing additive. In certain cases, these components may be referred to as "emollient". Moisturizing additive has the ability to attract water vapor (moisture) from the atmosphere and bring it to the surface of the treated substrate. This produces smoothness and moisturizing/moisturizing sensation and relieves dryness. Φ Examples of this component (8) include gland, sodium lactate, multi-brewed, isomerized cool, mountain • sorbitol, gland, material (four) (four) nat (SGdium pCA), plants Extracts and other similar bioactive agents. The preferred component (8) is sodium lactate, scorpion plant extract, seaweed extract and herbs. Among them, 'Aconite extract and (4) sodium are especially preferred. Other plant extracts and other biological activities Examples of the agent are as follows: Angelica keiskei extract, avocado (av〇cad〇) extract, Hydrangea serrata extract, hollyhock (An) extract, arnica ( Arnica extract, aloe vera (4) 〇e) extract, apricot 133159.doc -22- 201005035 (apricot) extract, apricot kernel extract, ginkgo biloba extract, fennel (Fennei) fruit extract ,ginger Extract of Turmeric root extract, 乌i〇ng tea extract, Rosa multiflora extract, Echinacea angustifolia leaf extract, Scutellaria baicalensis root extract, and yellow ban ( Phellodendron amurense extract, Coptis rhizome extract, Hordeum vulgare seed extract, Hypericum perforatum extract, Lamium album extract, Nasturtium officinale extract , orange extract, dried sea water solution, seaweed extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, Chamomile extract, carrot extract, Artemisia capillaris Flower extract, Licorice extract, Karkade extract, Pyraeantha fortuneana extract, kiwi extract, Cinchona extract, cucumber extract, Guanosine, Gardenia florida extract, Sasa veitchii extract, Sophora angustifolia Extract, walnut extract, grapefruit extract, clematis vitalba leaf extract, chlorella extract, mulberry (Morus alba) root extract, gentian (Gentiana lutea) extract, Black tea extract, yeast extract, burdock extract, fermented rice bran extract, rice germ oil, Comfrey extract, collagen, Vaccinum vitis idaea extract, Asiasarum root extract Bupleurum falcatum extract, umbilical cord extract, Salvia extract, 133159.doc -23- 201005035 Soapwort extract, Sasa bamboo grass extract, wild hawthorn (Crataegus cuneata) fruit extract, Zanthoxylum piperitum extract, Shiitake extract, Rehmannia root extract, Lithospermum erythrorhizone root extract, Perilla ocymoide extract Extract, Tilia cordata flower extract, Spiraea ulmaria extract, Paeonia albiflora extract, Acorns calamus Root extract, Betula alba extract, Equisetum arvense extract, Hedera helix extract, Crataegus oxyacantha extract, Sambucus nigra extract, alfalfa Achillea millefolium extract, Mentha piperita leaf extract, Sage extract, Malva sylvestris extract, Cnidium officinale root extract, Japanese seaweed (Swertia japonica) extract, Soybean extract, Zizyphus jujuba fruit extract, thyme extract, tea extract, Eugenia caryophyllus flower extract, imperata cylindrica extract , Citrus unshiu Marc extract, Angelica root extract, Calendula officinalis extract, Prunus persica nuclear extract, citrus aurantium extract, fish gill Grass (Houttuynia cordata) extract, tomato extract, natto extract, carrot extract, garlic extract, rose (Rosa Canina) fruit extract, Hibiscus extract, Ophiopogon extract, lotus flower (Nelumbo nucifera extract), parsley extract, honey, Witch hazel extract, 133159 .doc •24- 201005035 Parietaria officinalis extract, Isodon trichocarpus extract, bisabolol, Eriobotrya japonica extract, Coltsfoot flower extract, Petasites japonicus extract, Poria cocos extract, Butcher's broom extract, grape extract, propolis, loofah * cylindrica fruit extract, safflower flower Extract, pepper, peppermint extract, Tillia miquellana extract, peony (Paeonia suffruticosa) root extract, hops hop extract, Pinus sylvestris pine fruit extract , chestnutnut extract, Japanese skunk-cabbage extract, Sapindus mukurossi skin extract, honeybee (Melissa) extract, peach extract, cornflower (C: entaurea cyanus) flower extract, Eucalyptus extract, Saxifraga sarementosa extract, Citrus junos extract, coix seed ( Coix seed) extract, Artemisia princeps extract, lavender extract, apple extract, lettuce extract, lemon extract, extract of Astragalus sinicus, rose extract Rosemary extract, R〇man chamomile extract and royal jelly extract. [(F) Preservative] Component (F) is a preservative which is usually added to the emulsion composition and can be added to the emulsion of the present invention, which is, for example, a group of (F1) disinfectants, including p-benzoic acid Group of vinegar, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol; and (F2) antibacterial agent group, including benzoic acid, water 133159.doc •25· 201005035 acid, carbolic acid, sorbic acid, P-chlormethaeresol, hexachi〇r〇phene, chlorinated chlorhexidine chloride, chlorhexidine chloride, trigas Trichlorocarbanilide, trichisan, photosensitive component, phenoxyethanol, methyl isoform. Sezolinone and the like. 'The compounds should be used in an amount sufficient to prevent the emulsion composition from decaying. [Optional component] ❹ The emulsion composition may further contain (Η) a pH adjuster, (J) a fragrance, (K) an antioxidant, (L) a water-soluble polymer or other (M) as described below At least one type of such agent within the limits of the biologically active component or which is not detrimental to its properties. (H) a pH adjusting agent, which is usually added to an emulsion and may be added to the emulsion composition of the present invention, such as lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, carbonic acid clock, Sodium carbonate, carbon chloride, etc. © (J) a perfuming agent, which is usually added to a fibrous substrate and can be added. 1 The emulsion composition towel of the present invention is used for the treatment of a substrate, a fragrance, or a Masking an unpleasant smell. Regarding the type of fragrance, it is not limited, it is a limitation that it is a Sf fragrance which is usually added to a tissue paper product, and examples of the component include a plurality of extracts which are exhibited as ±physical active components; Plant flowers, seeds, leaves and root extracts are extracted from seaweed; aromatic substances are extracted from various parts of the body or secreted by the glands (for example, musk and oil); or synthetic fragrances (for example, menthol, Musk, ethyl acetate or vanilla extract). 133159.doc -26· 201005035 (κ) antioxidant, its scorpion, day 'sr is usually added to the chyle and added to the emulsion composition, for example, fertility, butylated basal butyl group Toluene, phytic acid, carotenoids (four), genus Huang Gang: (4) - lignans (ligor or horn). The reagent should be added in an amount to protect the components of the emulsion from oxidation.

Ο ⑹水溶性高分子聚合物及水可膨脹性礦物黏土 於增加黏度，&良時間敎性及增強經其處理之纖維基材 之使用感覺。較佳將水溶性聚合物及水可膨脹性礦物黏土 溶解或分散於水中以製備均一水溶液或分散液，隨後將所 製備之溶液或分散液與其他組分混合。水溶性聚合物可為 兩性型、陽離子型、陰離子型或非離子型。可一起使用水 溶性聚合物及水可膨脹性礦物黏土，或可組合❹兩種或 兩種以上水溶性聚合物。 (M)其他生物學活性組分之實例如下：脫氧核糖核酸、 黏多醣、玻尿酸鈉、軟骨素硫酸鈉、膠原、彈性蛋白、甲 殼素、殼聚糖、水解蛋殼臈及其他生物聚合物等；甘胺 酸、顯胺酸、白胺酸、以胺酸、絲胺酸、蘇胺酸、苯丙 胺酸、精胺酸、離胺酸、天冬胺酸、麩胺酸、胱胺酸、半 胱胺酸、甲硫胺酸、色胺酸及其他胺基酸；***、乙烯 基***及其他激素；鞘脂、神經醯胺、膽固醇、膽固醇 衍生物、磷脂及其他油性成分；卜胺基己酸、甘草酸 (glycyrrhizinic acid)、溶菌酶氣化物、瓜甘菊奠（guaiazuiene)、 氫化可的松（hydrocortisone)、尿囊素、胺甲環酸（tranexamie acid)、甘菊奠（azulene)及其他消炎劑；維生素a、B2、 133159.doc •27- 201005035 B6、C、D及E、泛酸鈣、生物素、菸鹼酸醢胺、維生素c 醋及其他維生素。 [各組分之較佳份數】 乳劑組合物較佳包含0.01至25.〇以下重量份該（A)二有機 聚矽氧烷；0.01至20.0以下重量份該（B)軟化劑；8〇至6〇〇 ' 重量份該（C)水；及20.0至9〇·〇重量份該（D)水溶性一元醇 • 或多元醇。此外，該乳劑組合物之連續相為由該（C)水及 φ 該（D)水溶性一元醇或多元醇以1:0.5至i:i〇之比率組成之 水溶液，且該組分（C)及該組分（D)之總含量在該乳劑組合 物之30.0至98,0重量份範圍内。 作為軟化乳劑組合物，該乳劑組合物之最佳連續相具有 以乳劑組合物之總重量份計30至9〇重量份之甘油含量。隨 後，可使甘油與其他低過敏性醇或其混合物組合。 較佳地，上述組分（A)之含量範圍為4_1〇重量份，上述 組分（B)之含量範圍為0.5_10重量份，上述組分（c)之含量 Ο 範圍為10·40重量份，上述組分（D)之含量範圍為35_85重量 • 份，上述組分（E)之含量範圍為9_2〇重量份，上述組分 之含量範圍為0.05-0.10重量份，上述組分（G)之含量範圍 為0.2-2.5重量份，且上述組分（H)之含量範圍為〇〇ι〇3重 量份。Ο (6) Water-soluble polymer and water-swellable mineral clay for increasing the viscosity, & good time and enhancing the feeling of use of the treated fibrous substrate. Preferably, the water-soluble polymer and the water-swellable mineral clay are dissolved or dispersed in water to prepare a uniform aqueous solution or dispersion, and then the prepared solution or dispersion is mixed with other components. The water soluble polymer may be amphoteric, cationic, anionic or nonionic. A water-soluble polymer and a water-swellable mineral clay may be used together, or two or more water-soluble polymers may be combined. (M) Examples of other biologically active components are as follows: deoxyribonucleic acid, mucopolysaccharide, sodium hyaluronate, sodium chondroitin, collagen, elastin, chitin, chitosan, hydrolyzed eggshell and other biopolymers, etc. Glycine, leucine, leucine, aminic acid, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, half Cystamine, methionine, tryptophan and other amino acids; estradiol, vinyl estradiol and other hormones; sphingolipids, nervous amines, cholesterol, cholesterol derivatives, phospholipids and other oily ingredients; Glycosylhexanoic acid, glycyrrhizinic acid, lysozyme gasification, guaiazuiene, hydrocortisone, allantoin, tranexamie acid, azulene and Other anti-inflammatory agents; vitamins a, B2, 133159.doc • 27- 201005035 B6, C, D and E, calcium pantothenate, biotin, niacinamide, vitamin c vinegar and other vitamins. [Preferred parts of each component] The emulsion composition preferably comprises 0.01 to 25.5% by weight of the (A) diorganopolyoxyalkylene; 0.01 to 20.0 parts by weight of the (B) softener; To (6) parts by weight of the (C) water; and 20.0 to 9 parts by weight of the (D) water-soluble monohydric alcohol or polyol. Further, the continuous phase of the emulsion composition is an aqueous solution composed of the (C) water and φ the (D) water-soluble monohydric alcohol or polyol in a ratio of 1:0.5 to i:i, and the component (C) And the total content of the component (D) is in the range of from 30.0 to 98,0 parts by weight of the emulsion composition. As a softening emulsion composition, the optimum continuous phase of the emulsion composition has a glycerin content of from 30 to 9 parts by weight based on the total weight of the emulsion composition. The glycerin can then be combined with other hypoallergenic alcohols or mixtures thereof. Preferably, the content of the above component (A) is in the range of 4 to 1 part by weight, the content of the above component (B) is in the range of 0.5 to 10 parts by weight, and the content of the above component (c) is in the range of 10 to 40 parts by weight. The content of the above component (D) is in the range of 35 to 85 parts by weight, the content of the above component (E) is in the range of 9 to 2 parts by weight, and the content of the above components is in the range of 0.05 to 0.10 parts by weight, and the above component (G) The content is in the range of 0.2 to 2.5 parts by weight, and the content of the above component (H) is in the range of 3 parts by weight.

[纖維基材I 本發明乳劑組合物可用作用於纖維基材之軟化乳劑組合 物且可塗覆於其纖維結構。經其處理之本發明纖維基材在 曰常使用中提供柔軟感及舒適感。 133159.doc -28· 201005035 如本文中所使用，”纖維結構"意謂包含一或多個纖維之 結構，且如本文中所使用纖維"意謂表觀長度大大超過 其表觀寬度（亦即，長度直徑比至少約1 0)之伸長顆粒。 如本文中所使用，"纖維基材"意謂具有纖維結構之基 材，且例如為代表性纖維基材之群，包括濕巾、織物、纺 J 織品及紙。詳言之，較佳基材為薄紙製品用紙，且較佳纖 ， 維為造紙纖維。 Φ 本發明涵蓋使用多種纖維，諸如天然纖維或合成纖維或 任何其他合適纖維及其任何組合。適用於本發明中之天然 纖維包括動物纖維、礦物纖維、植物纖維及其混合物。動 物纖維可（例如）選自由羊毛、絲及其混合物組成之群。合 成纖維可（例如）包含纖維素（通常稱為"嫘縈（rayon)");纖 維素衍生物’諸如酿、鍵或含氮衍生物；聚稀烴（包括聚 乙稀及聚丙稀）；聚醋（包括聚對苯二甲酸乙二酿）；聚酿胺 (通常稱為”耐綸”）；丙婦I系物；非纖維素聚合碳水化合 ❹ 物(諸如澱粉、甲殼素及甲殼素衍生物，諸如殼聚糖）；及 . 其混合物。 植物纖維可(例如)源自選自由以下各物組成之群之植 木材、棉花、棉絨、亞麻、緩麻、馬尼拉麻、***、 龍舌蘭屬植物（heSperaIoe)、黃麻、竹子、薦渣 玉 米、尚粱、葫蘆、龍舌蘭、絲瓜及其混合物。 通常稱為木漿之木質纖堆自 纖維匕括化學紙漿，諸如牛皮（硫 息、、及亞硫酸鹽紙漿以及機械紙漿及半化學紙浆， 匕括(例如)磨木漿、熱機械紙漿、化學機械紙漿(chemi- I33159.doc -29· 201005035 mechanical pulp ’ CMP)、化學·熱機械紙漿（chemi_therm〇mechanicai pulp ’ CTMP)、中性半化學亞硫酸鹽紙漿（neutrai semichemical sulfite pulp ， NSCS) 〇 木漿纖維可為短纖維（典型為硬木纖維）或長纖維（典型為 軟木纖維）》短纖維之非限制性實例包括源自選自由以下 各物組成之群之纖維源的纖維：相思樹（Acacia)、按樹 (Eucalyptus)、楓樹（Maple)、橡樹（Oak)、白揚木（Aspen)、 樺樹（Birch)、寬葉白楊（Cottonwood)、赤楊木（Alder)、白 蟓樹（Ash)、樓桃（Cherry) '榆樹（Elm)、山核桃樹 (Hickory)、白揚（popiar)、橡膠樹（Gum)、胡桃（Walnm)、 刺槐（Locust)、美國梧桐（Sycamore)、山毛櫸（Beech)、梓 樹（Catalpa)、檫樹（Sassafras)、石梓（Gmelina)、合歡樹 (Albizia)、黃樑木（Anthocephalus)及木蘭（Magnolia)。 此外，本發明為源自再循環紙之纖維，其可含有任何或 所有上述種類以及其他用於幫助原始造紙之非纖維材料， 諸如填充劑及黏著劑。 關於薄紙製品，纖維基材之製造方法可包括已知濕式布 展造紙法及空氣布展造紙法。該等方法通常包括以下步 驟：製備濕或乾纖維組合物，該纖維組合物在濕式布展法 中通常稱為纖維漿；隨後將複數個纖維沈積於成形線或成 A帶上以便形成胚胎纖維結構（亦即，胚胎纖維網）；乾燥 纖維及/或將其黏合在一起以便形成纖維結構；及/或進一 步加工纖維結構以便形成成品纖維結構。 該等薄紙之較佳實例習知地包括壓製及/或氈壓薄紙； 133159.doc -30- 201005035 圖案沈積薄紙；高鬆散未壓實薄紙；起皺薄紙及 紙。該等薄紙可具有均質及/或單層或多層構造；且由其 製備之薄紙製品可具有單層或多層構造。 〃 [軟化方法及製造程序】 在製造程序中可使用將本發明乳劑組合物 材之任何已知方法。舉例而言，該塗覆方法包括喷= 縫擠出及凹板印刷。其他方法包括使乳劑組合物沈積於成 形線或織物或帶上，隨後用胚胎纖維網及/或乾纖維結構 及/或薄紙製品接觸該成形線或織物或帶。此外，在纖維 結構之形成製程中，可將本發明乳劑組合物添加至給造紙 機器提供原料之漿料桶中。 將本發明乳劑組合物塗覆於纖維結構之合適方法之較佳 實例包括在纖維結構繞成卷紙之前喷塗於纖維結構上、擠 出於纖維結構上及印刷於纖維結構及/或薄紙製品上。可 將本發明乳劑組合物塗覆於胚胎纖維網及/或乾纖維結構 及/或薄紙製品上。 可當本發明乳劑組合物在造紙機器上製備時或製備之後 將其塗覆於胚胎纖維網及/或纖維結構及/或薄紙製品。亦 即，可當乳劑濕（亦即，最後乾燥之前）或乾（亦即，最後乾 燥之後）時塗覆乳劑。 本發明IL劑組合物較佳可在已形成胚胎纖維網之後塗 覆在典型方法中，形成胚胎纖維網，隨後在塗覆陽離子 聚矽氧聚合物之前脫水以降低因游離水排出所致之（A)二 有機聚矽氧烷或其混合物之損失。 133159.doc 201005035 本文中所述之用於本發明乳劑組合物之塗覆法可用、 或濕胚胎纖維網及/或纖維結構及/或薄紙製品。其中於乾 種最簡單的塗覆法例如為將乾薄紙製品浸潰於本發 組合物中達幾分鐘。 劑 [工業實用性j ' 本發明乳劑組合物適用於製造纖維製品，從而向經其處 • s之製品提供柔軟感及舒適感。本發明乳劑組合物尤： ❹ 用於製對人類皮膚具有極佳柔軟性、光滑性、保濕 潤感、舒適鬆軟性且具有吸水性之薄紙製品、衛生纖維製 品(亦即’衛生濕巾及衛生紙)、清潔濕巾、醫學及/或化妝 ，氏巾化妝棉、女性衛生用品、紙尿褲、拋棄式尿片、内 衣、細亞麻衣、餐巾紙。 本發明纖維基材亦可用作衣物、織物物品、封裝材料、 醫學材料、厨房材料、嬰兒相關產品、老人護理產品、寵 物二產口口、体具、建築及/或内部材料、文具用品及化妝 籲 纟抑之其他材料。當本發明纖維基材用於上述領域中時， ·&/㈣物對該等產品感到柔軟且舒適之觸感，且在日 常使用中發現極佳功能性質。 實例 >考實用實例及比較實例更詳細地進—步描述本發 明’但應瞭解該等實例不應解釋為限制本發明之範缚。 [乳劑粒子之平均粒度] 乳劑粒子之平均私由 米級粒子之亞微乎？ 於用於由雷射繞射法量測亞微 微水粒子分析器（Malvern Instruments c〇. I33159.doc 32- 201005035[Fiber Substrate I The emulsion composition of the present invention can be used as a softening emulsion composition for a fibrous substrate and can be applied to its fibrous structure. The fibrous substrate of the present invention treated there provides softness and comfort in the usual use. 133159.doc -28· 201005035 As used herein, "fibrous structure" means a structure comprising one or more fibers, and as used herein, means that the apparent length greatly exceeds its apparent width ( That is, elongate particles having a length to diameter ratio of at least about 10. As used herein, "fibrous substrate" means a substrate having a fibrous structure, and is, for example, a group of representative fibrous substrates, including wet Towels, fabrics, spun fabrics and papers. In particular, preferred substrates are paper for tissue paper products, and preferably fibers, which are papermaking fibers. Φ The invention encompasses the use of a variety of fibers, such as natural or synthetic fibers or any other Suitable fibers and any combination thereof. Natural fibers suitable for use in the present invention include animal fibers, mineral fibers, plant fibers, and mixtures thereof. The animal fibers can, for example, be selected from the group consisting of wool, silk, and mixtures thereof. For example) contains cellulose (commonly known as "rayon"); cellulose derivatives such as brewed, bonded or nitrogen-containing derivatives; and poly-hydrocarbons (including polyethylene and polypropylene) Dilute); polyacetate (including polyethylene terephthalate); polyamine (commonly known as "Nylon"); C-I system; non-cellulosic polymeric carbohydrates (such as starch, chitin) And a chitin derivative, such as chitosan; and a mixture thereof. The plant fiber may, for example, be derived from a plant selected from the group consisting of: wood, cotton, cotton, cotton, linen, manila, manila Hemp, agave (heSperaIoe), jute, bamboo, slag corn, sorghum, gourd, agave, loofah and mixtures thereof. Wood pulp piles commonly known as wood pulp, including chemical pulp, Such as cowhide (sulfur, and sulfite pulp and mechanical pulp and semi-chemical pulp, including (for example) ground wood pulp, thermomechanical pulp, chemical mechanical pulp (chemi- I33159.doc -29· 201005035 mechanical pulp ' CMP), chemical/thermo-mechanical pulp (chemi_therm〇mechanicai pulp 'CTMP), neutral semi-chemical sulfite pulp (NSCS) eucalyptus pulp fiber can be short fiber (typically hardwood fiber) or long fiber Non-limiting examples of dimensional (typically softwood fibers) short fibers include fibers derived from a fiber source selected from the group consisting of: Acacia, Eucalyptus, Maple, Oak, Aspen, Birch, Cottonwood, Alder, Ash, Cherry, Elm, Hickory, popiar, Gum, Walnm, Locust, Sycamore, Beech, Catalpa, Sassafras Gmelina, Albizia, Anthocephalus and Magnolia. Moreover, the present invention is a fiber derived from recycled paper which may contain any or all of the above categories as well as other non-fibrous materials, such as fillers and adhesives, which are used to aid in the original papermaking. Regarding the tissue product, the method of producing the fibrous substrate may include a known wet spreading papermaking method and an air spreading papermaking method. The methods generally comprise the steps of preparing a wet or dry fiber composition, which is commonly referred to as a fiber slurry in a wet spreading process; subsequently depositing a plurality of fibers on a forming line or into an A-belt to form an embryonic fiber. Structure (i.e., embryonic fiber web); drying the fibers and/or bonding them together to form a fibrous structure; and/or further processing the fibrous structure to form a finished fibrous structure. Preferred examples of such tissue papers conventionally include pressed and/or felted tissue paper; 133159.doc -30-201005035 Pattern deposited tissue paper; high loose uncompacted tissue paper; creped tissue paper and paper. The tissue may have a homogeneous and/or single layer or multi-layer construction; and the tissue paper product prepared therefrom may have a single layer or multiple layer construction. 〃 [Softening method and manufacturing procedure] Any known method of using the emulsion composition of the present invention can be used in the production process. For example, the coating method includes spray extrusion and gravure printing. Other methods include depositing the emulsion composition onto a shaped line or fabric or belt, followed by contacting the forming line or fabric or belt with an embryonic web and/or dry fibrous structure and/or tissue article. Further, in the formation process of the fibrous structure, the emulsion composition of the present invention can be added to a slurry tank which supplies raw materials to a paper making machine. Preferred examples of suitable methods of applying the emulsion compositions of the present invention to fibrous structures include spraying onto the fibrous structure, extruding onto the fibrous structure, and printing on the fibrous structure and/or tissue product prior to winding the fibrous structure into a web of paper. on. The emulsion compositions of the present invention can be applied to embryonic webs and/or dry fibrous structures and/or tissue products. The emulsion compositions of the present invention can be applied to an embryonic fibrous web and/or fibrous structure and/or tissue paper product when it is prepared on or after preparation on a papermaking machine. That is, the emulsion can be applied when the emulsion is wet (i.e., before final drying) or dry (i.e., after final drying). Preferably, the IL agent composition of the present invention can be applied in a typical process after the embryonic fiber web has been formed to form an embryonic fiber web, followed by dehydration prior to application of the cationic polyoxyl polymer to reduce discharge due to free water ( A) Loss of diorganopolyoxyalkylene or mixtures thereof. 133159.doc 201005035 The coating methods described herein for use in the emulsion compositions of the present invention may be used, or wet embryo webs and/or fibrous structures and/or tissue products. The simplest coating method for dry seeding is, for example, the dipping of a dry tissue product into the hair composition for a few minutes. Agent [Industrial Applicability j' The emulsion composition of the present invention is suitable for the manufacture of a fibrous product, thereby providing a soft feeling and a comfortable feeling to the article passing through it. The emulsion composition of the invention is particularly useful for making thin paper products and sanitary fiber products (ie, sanitary wipes and toilet paper) which have excellent softness, smoothness, moisturization, comfort and softness and water absorption to human skin. ), cleaning wipes, medicine and / or makeup, towel cotton, feminine hygiene products, diapers, disposable diapers, underwear, fine linen, napkins. The fiber substrate of the invention can also be used as clothing, fabric articles, packaging materials, medical materials, kitchen materials, baby related products, elderly care products, pets, mouthpieces, body tools, construction and / or interior materials, stationery and Makeup calls for other materials. When the fibrous substrate of the present invention is used in the above-mentioned field, &/(4) feels soft and comfortable to the like, and excellent functional properties are found in daily use. The present invention is described in more detail in the detailed description of the present invention, and is not to be construed as limiting the scope of the invention. [Average particle size of emulsion particles] Average private weight of emulsion particles Used to measure submicron water particle analyzer by laser diffraction method (Malvern Instruments c〇. I33159.doc 32- 201005035

Ltd.之產品；Mastersizer 2000)量測。 [有機聚矽氧烷之黏度] 有機聚石夕氧貌之黏度藉助於Br〇〇kfieldLtd. product; Mastersizer 2000) measurement. [Viscosity of Organic Polyoxane] Viscosity of Organic Polyurethane Oxygen Appearance by Br〇〇kfield

Lab〇m〇ries之旋轉式黏度計（商標：Br〇〇kfieid M m ultra型）量測；量測溫度：25t。 " [乳劑組合物之外觀] • 乳劑組合物之外觀由目測評估。使用以下標準。 ^ ◎完全透明 9 ◦具有-定濁度的透明(亦即，半透明或稍許混濁） △有點不均勻且有點乳白色混濁 [時間穩定性] 在室溫及啊下將乳劑組合物在怪溫器中保持在靜止狀 態，隨後在製備後及在恆溫器中儲存一個月後立即觀察乳 劑外觀。評估標準展示如下。 ◎未觀察到油相分離超過1年 〇 〇觀察到油相輕度分離 . △明顯觀察到油相分離 [經乳劑處理之薄紙之手感小組測試] ‘重繞製程期間或切割摺疊製程（⑽_fGld prGeess)之前， 藉由塗佈機或噴塗機用薄紙軟化劑乳劑塗佈或喷塗空白薄 紙。 手感小組由10位為製品感官評估專家且經良好培訓之雇 員（不限於女性）組成。 小組測試法為對所呈現樣品之強度等級(柔軟性、滋潤 I33l59.doc -33- 201005035 感及鬆軟性等）同時進行分級之分級測試。小組成員感覺 感g差異且將其在各組中分級，各組中分入4個或3個樣 品。較高評分意謂較佳效能。當經處理薄紙達到最佳效能 時，老化2週後有必要進行小組測試。 [小組測試方法] 在給小組成員（10位）之問卷中呈現3個樣品。要求小組 成員將其按柔軟性、滋潤感及鬆軟性之效能分級，苴中 ’，極佳"為（標記4)，”良好"為（標記3)，"—般"為（標記2)及 ’’差”為_)。隨後，吾人將所有評估之平均等級記錄為 表1.1至1.3中之”手感”結果。 :人之研究實例及比較實例之—系列”手感,,結果展示於 下表1.H.3中。該等結果展示，與彼等經比較實例之乳 劑處理之纖維基材相比，吾人 理之输雜實例之乳劑向經其處 及舒適鬆軟性。 杞月性、保濕/滋淵感 作為參考’於下表中展示三 感及鬆軟性之效能的原始小組測==軟性、滋潤 ⑴為經吾人本發明乳劑（與吾& "表中，薄紙 薄紙製品，薄紙⑺為商業薄紙製品（作九實例^價）處理之 (3)為未經任何乳劑處理之原 ’:目橾參考)’薄紙 々紙基材（作為空白）。 133】 59.doc 34- 201005035 表：薄紙（1)至（3)之"柔軟性"之手感效能 小組成員編號 ⑴* 薄紙 (2) (3) 1 4 2 1 2 4 2 1 3 4 2 1 4 4 3 1 5 3 2 1 6 3 2 1 7 3 2 1 8 4 2 1 9 4 2 1 10 3 2 1 總分 36 21 10 平均記錄 4 2 1 "柔軟性” 極佳 一般 差Lab〇m〇ries rotary viscometer (trademark: Br〇〇kfieid M m ultra type) measurement; measuring temperature: 25t. " [Appearance of Emulsion Composition] • The appearance of the emulsion composition was evaluated by visual inspection. Use the following criteria. ^ ◎ completely transparent 9 透明 has a certain turbidity of transparency (that is, translucent or slightly turbid) △ a little uneven and a little milky white turbidity [time stability] at room temperature and under the emulsion composition in the strange temperature The medium was kept at rest, and then the appearance of the emulsion was observed immediately after preparation and after storage for one month in a thermostat. The evaluation criteria are shown below. ◎ No oil phase separation was observed for more than 1 year. A slight separation of the oil phase was observed. △ Oil phase separation was clearly observed [Hand-feel group test of emulsion-treated tissue paper] 'Rewinding process or cutting and folding process ((10)_fGld prGeess Prior to this, a thin tissue paper was coated or sprayed with a tissue softener emulsion by a coater or sprayer. The Feel group consists of 10 highly trained employees (not limited to women) who are experts in sensory evaluation. The group test method is a grading test for grading the strength level (softness, moisturizing, and moisturizing, etc.) of the sample to be presented. The panelists felt g-differentiation and ranked them in each group, with 4 or 3 samples divided into groups. A higher rating means better performance. When the treated tissue is optimally sized, it is necessary to perform a group test after 2 weeks of aging. [Group test method] Three samples were presented in a questionnaire for the panelist (10 people). Ask the team members to grade their effectiveness according to softness, moisturization and softness, in the ', excellent' (mark 4), "good" (mark 3), "-like" Mark 2) and ''poor') are _). Subsequently, we recorded the average rating of all assessments as the “feel” results in Tables 1.1 to 1.3. : The human case study and the comparative example - series "feel", the results are shown in Table 1.H.3 below. These results show that compared with their comparative examples of emulsion treated fiber substrates, we The emulsion of the example of the miscellaneous example is comfortable and soft. The lunar month, moisturizing/nourishing sensation is used as a reference. The original group test showing the efficacy of the three senses and the softness in the table below == softness, moisturization (1) According to the invention of the present invention (in the &" table, thin paper tissue products, thin paper (7) for commercial tissue paper products (for nine examples) price (3) is the original without any emulsion treatment:: ) 'Thin paper base paper (as a blank). 133] 59.doc 34- 201005035 Table: Thin paper (1) to (3) "softness" Handling effectiveness team member number (1)* Thin paper (2) ( 3) 1 4 2 1 2 4 2 1 3 4 2 1 4 4 3 1 5 3 2 1 6 3 2 1 7 3 2 1 8 4 2 1 9 4 2 1 10 3 2 1 Total score 36 21 10 Average record 4 2 1 "softness" Excellent overall poor

*與吾人之研究實例7等價。 表：薄紙（1)至（3)之”滋潤感"之手感效能 小組成員編號 ⑴* 薄紙 (2) (3) 1 4 2 1 2 4 2 1 3 4 2 1 4 2 3 1 5 3 4 1 6 4 2 1 7 3 2 1 8 4 1 2 9 3 3 1 10 4 2 1 總分 35 23 11 平均記錄 "滋潤感” 4 極佳 2 一般 1 差 *與吾人之研究實例7等價。 -35- 133159.doc 201005035 表··薄紙（1)至（3)之"鬆軟性”之手感效能 小組成員編號* Equivalent to our research example 7. Table: Thin Paper (1) to (3) "Moisture Sensing" Handling Efficacy Team Member Number (1)* Thin Paper (2) (3) 1 4 2 1 2 4 2 1 3 4 2 1 4 2 3 1 5 3 4 1 6 4 2 1 7 3 2 1 8 4 1 2 9 3 3 1 10 4 2 1 Total score 35 23 11 Average record "moisturizing feeling" 4 Excellent 2 Normal 1 Poor* Equivalent to our research example 7. -35- 133159.doc 201005035 Table · Thin paper (1) to (3) "softness" Handling efficacy Team member number

(1Y ❹ 1 2 3 4 5 6 7 8 9 10 總分 平均記錄 "滋潤感” 4 2 3 4 4 3 3 2 3 3 31 3 良好 薄紙(2) (3) 3 4 4 2 2 2 2 4 2 2 1 1 1 1 1 1 1 1 27 10 3 良好 1 差 *與吾人之研究實例7等價 [吸水性] 經除含有以下二有機聚矽氧烷（A2)之調配物以外的所有 調配物處理之紙之吸水性高度或毛細管上升通過gb(國標 (Chinese standard)，GB/T 20808-2006)。按照克列姆法 (Klemm method)，測試薄紙上之吸水性高度或毛細管上升 在100秒内應穿過水面以上3〇 min。 吾人具有其他吸水性測試法，即將一滴〇 〇丨ml體積之水 自移液管置放於經處理薄紙之表面且記錄自起始至水滴為 薄紙所吸收之時間。無以下二有機聚矽氧烷（A2)之調配物 之時間無顯著不同。 [(A)二有機聚矽氧烷] 一有機聚矽氧烷（Al) : DiMe矽氧烷，以〇H封端之胺基 133159.doc • 36 - 201005035 乙基胺基異丁基甲基（-CH2CH(CH3)CH2-N(CH2CH(OH)CH2OH)-CH2-NH(CH2CH(OH)CH2OH))二甲氧基矽烷，C13-15 醇及 縮水甘油，在25°c下具有3,000 mPas» 二有機聚矽氧烷（A2):以（乙二胺基-2-甲基丙基）甲氧基 甲基矽烷基）氧基及以C13-15烷氧基封端之二甲基矽氧 -烷，在25°C 下具有 2,000 mPas。 -二有機聚矽氧烷（A3):以3-胺基丙基乙氧基曱基矽烷氧 基封端之二甲基/甲基（3-胺基丙基）矽氧烷，在25°C下具有 9 1，500 mPas。 二有機聚矽氧烷（A4):以三甲基矽烷氧基封端之二甲基/ 甲基（丙基（聚（EO)(PO))羥基）矽氧烷，在25°C下具有2,000 mPas。 '[(B)軟化劑] 軟化劑SA 200 (B1):脂肪酸/與動物脂醯胺基胺形成之 咪唑啶化合物（四級咪唑啉化合物） φ 軟化劑N100 (B2):聚醯胺樹脂與聚（氧化乙稀）單硬脂酸 • S旨（Ci2H25(〇CH2CH2)23〇H)之混合物，20重量份水溶液。 [(E)保濕劑] 蘆薈提取物（E1):來自蘆薈植物之水性提取物。 乳酸鈉（E2):乳酸鈉水溶液（60重量份）。 [(F)防腐劑](1Y ❹ 1 2 3 4 5 6 7 8 9 10 Total score average record "moisturizing feeling" 4 2 3 4 4 3 3 2 3 3 31 3 Good thin paper (2) (3) 3 4 4 2 2 2 2 4 2 2 1 1 1 1 1 1 1 1 27 10 3 Good 1 Poor* and our research example 7 Equivalent [Water absorption] All formulations except those containing the following two organopolyoxane (A2) The water absorption height or capillary rise of the treated paper passes gb (Chinese standard, GB/T 20808-2006). According to the Klemm method, the water absorption height or capillary rise on the test paper is 100 seconds. The inside should pass 3 〇 min above the water surface. We have other water absorption test method, that is, a drop of 〇〇丨ml volume of water is placed on the surface of the treated tissue paper and recorded from the beginning to the water droplets absorbed by the thin paper. The time of the formulation without the following two organopolyoxane (A2) is not significantly different. [(A) Diorganopolyoxyalkylene] An organopolyoxane (Al): DiMe oxane, 〇H-terminated amine 133159.doc • 36 - 201005035 ethylaminoisobutylmethyl (-CH2CH(CH3)CH2-N(CH2CH(OH)CH2OH)-CH2-NH(CH2CH(OH)CH2O H)) Dimethoxydecane, C13-15 alcohol and glycidol, having 3,000 mPas at 25 ° C » diorganopolyoxyalkylene (A2): (ethylenediamine-2-methylpropyl) a methoxymethyl fluorenyl)oxy group and a dimethyl oxo-alkane terminated with a C13-15 alkoxy group having 2,000 mPas at 25 ° C. - a diorganopolyoxy siloxane (A3): 3-Aminopropylethoxy decyl decyloxy-terminated dimethyl/methyl(3-aminopropyl) decane having 9 1,500 mPas at 25 ° C. Alkane (A4): a dimethyl/methyl (propyl (poly(EO)(PO)) hydroxy) decyloxy group terminated with a trimethyl decyloxy group having 2,000 mPas at 25 °C. '[(B) Softener] Softener SA 200 (B1): fatty acid / imidazolium compound formed with animal fatty amine amine (quaternary imidazoline compound) φ softener N100 (B2): polyamide resin and Poly(ethylene oxide) monostearic acid • S (Ci2H25 (〇CH2CH2) 23〇H) mixture, 20 parts by weight of water solution [(E)Humectant] Aloe extract (E1): water from aloe plants Extract: Sodium lactate (E2): aqueous sodium lactate solution (60 parts by weight). [(F)preservative]

Kathon® LX (F) . 5-氣-2-甲基-3(2H)-異嗟峻 _之1.5。/〇水 溶液（曱基異噻唑酮型防腐劑） [(G)界面活性劑] 133159.doc •37· 201005035 非離子界面活性劑（Gl) : C12H25(〇CH2CH2)23OH 非離子界面活性劑（G2) : C〗2H25(〇CH2CH2)4OH 非離子界面活性劑（G3) : C12H25(〇CH2CH2)3OH 非離子界面活性劑（G4) : 0KC12-C14第二烷基）ω-羥基聚（EO) [(H) pH值調節劑] 實例中使用乙酸（H1)、檸檬酸（H2)及磷酸（H3)。 - [研究實例及比較實例之製備程序] 參 將（B)軟化劑與少量水混入釜中，且用高剪切混合機分 散直至均質。隨後，將（A)二有機聚矽氧烷、（G)界面活性 劑及（H) pH值調節劑裝入上述系統中且用高剪切混合機分 散直至均質。逐步將轉換水（inversi〇n water)裝入上述系統 中且混合該系統直至發生相轉換（乳化）。將稀釋水及甘油 (D)裝入上述系統中’隨後用高剪切混合機分散直至均 質。視情況將Kathon® LX (F)及（E)保濕劑裝入系統中並混 合直至變成均質乳劑組合物。 # 所有實例之上述組分之比例展示於表1.1至1.3中。 .各乳劑之平均粒度、外觀及時間穩定性展示於相同表 中。 經各乳劑處理之薄紙之手感小組測試結果展示於相同表 中。 與比較實例1至1 3相比，吾人之研究實例1至8之乳劑組 合物在儲存過程中保持良好的時間穩定性及均質外觀長達 數月。此外，研究實例之乳劑組合物向經其處理之纖維基材 提供柔軟感以及極佳光滑性、保濕/滋潤感及舒適鬆軟性。 133I59.doc -38- 201005035 表1.1 :研究實例Kathon® LX (F) . 5-Gas-2-methyl-3(2H)- 嗟 嗟 _ 1.5. /〇 aqueous solution (mercaptoisothiazolone type preservative) [(G) surfactant] 133159.doc •37· 201005035 Nonionic surfactant (Gl) : C12H25(〇CH2CH2)23OH Nonionic surfactant (G2 ) : C〗 2H25(〇CH2CH2)4OH Nonionic surfactant (G3) : C12H25(〇CH2CH2)3OH Nonionic surfactant (G4) : 0KC12-C14 second alkyl)ω-hydroxy poly(EO) [ (H) pH adjuster] In the examples, acetic acid (H1), citric acid (H2), and phosphoric acid (H3) were used. - [Preparation procedure of research examples and comparative examples] Reference (B) The softener was mixed with a small amount of water into a kettle and dispersed by a high shear mixer until homogeneous. Subsequently, (A) diorganopolyoxyalkylene oxide, (G) surfactant and (H) pH adjuster were charged into the above system and dispersed by a high shear mixer until homogenization. The inversi〇n water was gradually charged into the above system and the system was mixed until phase inversion (emulsification) occurred. The dilution water and glycerin (D) were charged into the above system' and then dispersed by a high shear mixer until homogeneous. Kathon® LX (F) and (E) humectants are optionally loaded into the system and mixed until they become a homogeneous emulsion composition. # The ratio of the above components of all examples is shown in Tables 1.1 to 1.3. The average particle size, appearance and time stability of each emulsion are shown in the same table. The results of the hand-feel test of the tissue treated with each emulsion are shown in the same table. Compared with Comparative Examples 1 to 13, the emulsion compositions of Examples 1 to 8 of ours maintained good time stability and a homogeneous appearance for several months during storage. Further, the emulsion composition of the study example provides a soft feeling to the fiber substrate treated therewith as well as excellent smoothness, moisturizing/moisturizing feeling and comfort softness. 133I59.doc -38- 201005035 Table 1.1: Research examples

研究實例 *重量份 1 2 3 4 5 6 7 8 二有機聚矽 氧院(A1) 4.37 5 4.10 4.38 4.37 4.37 4.37 (A2) 9.10 (A3) (A4) 1.28 1.28 1.28 1.28 SA200 (B1) 0.57 10 1.07 1.07 0.57 0.57 0.57 0.57 N100 (B2) 5.95 非離子界面 活性劑(G1) 1.6 2.08 0.75 1.60 1.60 1.60 1.60 (G2) 0.32 0.78 0.28 0.32 0.32 0.32 0.32 (G3) (G4) 2 水 31.43 40 14.27 10.46 31.42 31.44 21.44 12.26 甘油(D1) 60.31 42.75 66.52 83.28 60.32 38.97 50.31 50.31 蘆薈提取物 (E1) 20 20 乳酸鈉(E2) 21.34 9.18 Kathon® LX (FI) 0.10 0.10 0.05 0.10 0.10 0.10 0.10 乙酸(HI) 檸檬酸(H2) 磷酸(H3) 0.02 0.25 0.13 0.01 0.01 0.01 0.01 0.01 乳劑性質 粒度(nm) 143 135 145 423 127 136 142 140 外觀 ◎ ◎ ◎ 〇 ◎ ◎ ◎ ◎ 時間穩定性 ◎ ◎ ◎ 〇 ◎ 〇 ◎ 〇 手感 柔軟性 4 4 4 4 4 4 4 4 滋潤感 3 2 3 4 3 4 4 4 鬆軟性 3 2 3 3 3 3 3 3 133I59.doc -39- 201005035Study Example * Parts by weight 1 2 3 4 5 6 7 8 Diorganopolyoxyl (A1) 4.37 5 4.10 4.38 4.37 4.37 4.37 (A2) 9.10 (A3) (A4) 1.28 1.28 1.28 1.28 SA200 (B1) 0.57 10 1.07 1.07 0.57 0.57 0.57 0.57 N100 (B2) 5.95 Nonionic surfactant (G1) 1.6 2.08 0.75 1.60 1.60 1.60 1.60 (G2) 0.32 0.78 0.28 0.32 0.32 0.32 0.32 (G3) (G4) 2 Water 31.43 40 14.27 10.46 31.42 31.44 21.44 12.26 Glycerin (D1) 60.31 42.75 66.52 83.28 60.32 38.97 50.31 50.31 Aloe extract (E1) 20 20 Sodium lactate (E2) 21.34 9.18 Kathon® LX (FI) 0.10 0.10 0.05 0.10 0.10 0.10 0.10 acetic acid (HI) citric acid (H2) phosphoric acid (H3) 0.02 0.25 0.13 0.01 0.01 0.01 0.01 0.01 Emulsion Properties Particle Size (nm) 143 135 145 423 127 136 142 140 Appearance ◎ ◎ ◎ 〇 ◎ ◎ ◎ ◎ Time stability ◎ ◎ ◎ 〇 ◎ 〇 ◎ 〇 Softness 4 4 4 4 4 4 4 4 Moisturizing feeling 3 2 3 4 3 4 4 4 Softness 3 2 3 3 3 3 3 3 133I59.doc -39- 201005035

表1·2 :比較實例（1) 比較實例 *重量份 1 2 3 4 5 6 7 二有機聚矽 氧烷(A1) (A2) 13.59 6.82 16.94 12.45 12.45 6.22 (A3) 13.64 (A4) 6.82 SA200(B1) 4.67 N100 (B2) 13.59 13.64 13.64 16.94 12.45 8.71 18.67 非離子界面 活性劑(G1) 5.65 (G2) (G3) 3.39 (G4) 水 63.43 54.55 54.55 56.48 66.37 65.44 66.38 甘油(D1) 9.06 18.18 18.18 8.30 8.30 8.30 蘆薈提取物 (E1) 乳酸鈉(E2) Kathon® LX (F) 乙酸(HI) 檸檬酸(H2) 磷酸(H3) 0.32 0.60 0.44 0.43 0.43 乳劑性質 粒度(nm) 1950 2100 2510 1200 4500 1220 546 外觀 Δ Δ Δ Δ Δ Δ 〇 時間穩定性 Δ Δ Δ Δ Δ Δ ◎ 手感 柔軟性 4 4 4 4 4 4 4 滋满感 1 2 2 1 1 1 1 鬆軟性 4 4 3 3 3 2 3 133159.doc -40· 201005035 表1.3 :比較實例（2) 比較實例 *重量份 8 9 10 11 12 13 二有機聚矽 氧烷(A1) 7.66 7.86 6.66 4.15 4.00 (A2) 6.22 (A3) (A4) SA200(B1) 10.09 10.00 N100 (B2) 18.67 15.33 15.73 66.58 非離子界面 活性劑(G1) 7.66 5.24 1.11 (G2) (G3) (G4) 2.02 2 水 66.38 61.30 62.91 15.54 77.44 77.65 甘油(D1) 8.30 7.66 7.86 9.99 6.05 6.00 蘆薈提取物 (E1) 乳酸鈉(E2)Table 1·2: Comparative Example (1) Comparative Example * Parts by Weight 1 2 3 4 5 6 7 Diorganopolyoxyalkylene (A1) (A2) 13.59 6.82 16.94 12.45 12.45 6.22 (A3) 13.64 (A4) 6.82 SA200 ( B1) 4.67 N100 (B2) 13.59 13.64 13.64 16.94 12.45 8.71 18.67 Nonionic surfactant (G1) 5.65 (G2) (G3) 3.39 (G4) Water 63.43 54.55 54.55 56.48 66.37 65.44 66.38 Glycerin (D1) 9.06 18.18 18.18 8.30 8.30 8.30 Aloe extract (E1) Sodium lactate (E2) Kathon® LX (F) Acetic acid (HI) Citric acid (H2) Phosphoric acid (H3) 0.32 0.60 0.44 0.43 0.43 Emulsion Properties Particle size (nm) 1950 2100 2510 1200 4500 1220 546 Appearance Δ Δ Δ Δ Δ Δ 〇 time stability Δ Δ Δ Δ Δ Δ ◎ feel softness 4 4 4 4 4 4 4 fullness 1 2 2 1 1 1 1 softness 4 4 3 3 3 2 3 133159.doc -40 · 201005035 Table 1.3: Comparative Example (2) Comparative Example * Parts by Weight 8 9 10 11 12 13 Diorganopolyoxyalkylene (A1) 7.66 7.86 6.66 4.15 4.00 (A2) 6.22 (A3) (A4) SA200(B1) 10.09 10.00 N100 ( B2) 18.67 15.33 15.73 66.58 Nonionic surfactant (G1) 7.66 5.24 1.11 (G2) (G3) (G4) 2.02 2 Water 66.38 61.30 62.91 15.54 77.44 77.65 Glycerin (D1) 8.30 7.66 7.86 9.99 6.05 6.00 Aloe extract (E1 Sodium lactate (E2)

Kathon® LX (F) 乙酸(H1) 檸檬酸(H2) 磷酸(H3) 0.43 0.38 0.39 0.13 0.25 0.25 乳劑性質 粒度(nm) 2700 211 229 133 133 132 外觀 Δ 〇 〇 〇 ◎ ◎ 時間穩定性 Δ ◎ ◎ ◎ ◎ ◎ 手感 柔軟性 4 4 4 4 4 4 滋潤感 1 1 1 1 1 1 鬆軟性 3 3 3 3 1 1 133159.doc -41Kathon® LX (F) Acetic acid (H1) Citric acid (H2) Phosphoric acid (H3) 0.43 0.38 0.39 0.13 0.25 0.25 Emulsion Properties Particle size (nm) 2700 211 229 133 133 132 Appearance Δ 〇〇〇 ◎ ◎ Time stability Δ ◎ ◎ ◎ ◎ ◎ Soft touch 4 4 4 4 4 4 Moisturizing feeling 1 1 1 1 1 1 Softness 3 3 3 3 1 1 133159.doc -41

Claims (1)

磉stone plinth 201005035 十、申請專利範圍·· 1 · 一種乳劑組合物，其包含： (A) 以下重量份之二有 (B) [〇.〇〗至20.0以下重量份]之軟化劑； (c) [8.0至60.0重量份]之水；及 ⑼⑽超㈣重量份】之水溶性—元醇或多元醇， 其中該乳劑組合物之連續相為由該（c)水與該⑼水溶性 一元醇或多元醇以1:0.5至1:1()之比率組成之水溶液，且 该組分（C)及該組分⑼之總含量係在該乳劑組合物之 30.0至98.0重量份之範圍内。 2.如請求们之乳劑組合物，其中該乳劑組合物之該連續 相具有30至90重量份之甘油含量。 3·如請求項1或2之乳劑組合物’其中包含該組分（A)之乳劑 粒子具有50至1〇,〇〇〇奈米之平均粒度。 4·如明求項3之乳劑組合物，其中包含該組分（A)之乳劑粒 子具有50至300奈米之平均粒度。 5. 如印求項1或2之乳劑組合物，其進一步包含（E) [0,01至 20.0以下重量份]之保濕劑及視情況（F)防腐劑。 6. 如明求項1或2之乳劑組合物，其中包含該組分（a)之乳劑 粒子為分子中具有至少一個選自由胺基官能基、聚氧伸 烧基、續酸酯官能基及環氧官能基組成之群之基團的二 有機聚矽氧烷。 一種用於纖維基材之軟化乳劑組合物，其包含如請求項 1至6中任一項之乳劑組合物。 133159.doc 201005035 8.如明求項7之用於纖維基材之軟化乳劑組合物， 中言 纖维基材係選自由濕中、織物、紡織品及紙組成 9. 一種軟化纖維結構之方法，其係藉由用如請求項:：。 任一項之乳劑組合物處理具有纖維結構之基材 6 10. —種纖維基材，其係經如請求項丨至6 土 。 合物處理。 一項之乳劑組 Π.如請求項1G之纖維基材，該纖維基材為薄紙製品。201005035 X. Patent Application Range·· 1 · An emulsion composition comprising: (A) the following parts by weight (B) [〇.〇 to 20.0 parts by weight or less] softener; (c) [8.0 Up to 60.0 parts by weight of water; and (9) (10) super (four) parts by weight of a water-soluble alcohol or polyol, wherein the continuous phase of the emulsion composition is from (c) water and the (9) water-soluble monohydric or polyhydric alcohol An aqueous solution consisting of a ratio of 1:0.5 to 1:1 (), and the total content of the component (C) and the component (9) is in the range of 30.0 to 98.0 parts by weight of the emulsion composition. 2. An emulsion composition as claimed, wherein the continuous phase of the emulsion composition has a glycerin content of from 30 to 90 parts by weight. 3. The emulsion composition of claim 1 or 2 wherein the emulsion particles comprising the component (A) have an average particle size of from 50 to 1 Torr. 4. The emulsion composition of claim 3, wherein the emulsion particles comprising the component (A) have an average particle size of from 50 to 300 nm. 5. The emulsion composition of claim 1 or 2, further comprising (E) [0,01 to 20.0 parts by weight] of a humectant and optionally (F) a preservative. 6. The emulsion composition according to claim 1 or 2, wherein the emulsion particles comprising the component (a) have at least one member selected from the group consisting of an amino functional group, a polyoxyalkylene group, a phthalate functional group, and a diorganopolyoxyalkylene group of groups of epoxy functional groups. A softening emulsion composition for a fibrous substrate comprising the emulsion composition of any one of claims 1 to 6. 133159.doc 201005035 8. The softening emulsion composition for a fibrous substrate according to claim 7, wherein the fibrous substrate is selected from the group consisting of wet, woven, textile, and paper. 9. A method of softening a fibrous structure. By using the request item::. Any of the emulsion compositions for treating a substrate having a fibrous structure 6 10. A fibrous substrate which is subjected to the requirements of 丨 to 6 soil. Compound treatment. An emulsion group 如. The fibrous substrate of claim 1G, which is a tissue paper product. 133159.doc •2. 201005035 七、指定代表囷： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明： ❹ 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式：133159.doc •2. 201005035 VII. Designated representative: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: ❹ VIII. If there is a chemical formula in this case, please reveal the best Chemical formula showing the characteristics of the invention: 133159.doc133159.doc
TW97127820A 2008-07-22 2008-07-22 Emulsion composition, methods of softening fibrous structures using the same, and fibrous substrate treated therewith TWI421305B (en)

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TWI706069B (en) * 2017-11-30 2020-10-01 日商三吉油脂股份有限公司 Paper treatment agent and paper treating method

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US5575891A (en) * 1995-01-31 1996-11-19 The Procter & Gamble Company Soft tissue paper containing an oil and a polyhydroxy compound

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI706069B (en) * 2017-11-30 2020-10-01 日商三吉油脂股份有限公司 Paper treatment agent and paper treating method

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