200923868 九、發明說明： 【發明所屬之技術領域】 本發明是有關於一種模内貼標的標籤，特別是指—種 成型良率高、重覆利用性佳且耐高溫及耐磨並具有特殊的 圖案設計效果的模内貼標的標籤。 【先前技術】 一般模内貼標（in-mold labe„ing)的製程是將一聚合物材 質的標籤置於-模具内，並以吹出成型（bl〇wing耐⑴㈣或 射出成型（injection molding)或真空成型（vaccum _脑幻的 方式於該模具内成型一聚合物材質的物品，使得成型後的 物品能與聚合物材質的標籤相結合。 如圖1所示，是台灣專利公告第575223號（第 912 216 0 6射請案）專㈣所揭露的—種用於模内貼標之標 籤，標籤1是置於一模具101巾，並且在模具1〇1中成型 聚合物件102後，使得標籤丨結合於聚合物件1〇2上。標 戴1包含-結合於聚合物件1Q2上且為聚合物材質的基材 11、一形成影像的塗層12、一膠黏層13及一護膜14，塗層 12疋形成於基材Π的正面，而護膜14是藉由耐熱、無溶 劑的膠黏層13貼於基材u的正面並蓋覆於塗層12上，藉 由濩臈14的配置，能保護成型在聚合物件1〇2上的標籤1 避免因摩擦而產生刮傷或磨損等問題。 然而，由於基材1丨正面未經過特殊的表面處理過程， 故塗層12附著於基材u上的附著力不佳，因此在成型過程 中易因壓力與高溫的影響，或者是在溫度差距變化大的環 200923868 境因素下，使得塗層12產生剝離的現象，造成標籤丨成型 的良率不佳且缺乏重覆利用性。再者，聚合物件1〇2在使 用過程中，也會因塗層12易剝離的因素而導致使用上安全 性的顧慮。 【發明内容】 本發明之一目的，在於提供一種成型良率高、重覆利 用性佳且耐高溫及耐磨的模内貼標的標籤。 本發明之另一目的，在於提供一種使用安全性佳的具 有標籤的物品。 本發明的其他目的和優點可以從本發明所揭露的技術 特徵中得到進一步的了解。 為達上述之-或部份或全部目的或是其他目的，本發 明之實施例所揭露之模内貼標的標籤，包含一第一基材、 -表面處理層、一印刷層、一第一膠黏層及—護膜。 :一基材具有一正面及一背面，表面處理層形成於第 —基材的正面，印刷層具有影像，並形成於第—基材的正 =:於= 處Γ層上’第一膠黏層形成於印刷層上，護 膘以第一膠黏層貼覆於印刷層上。 於本發明之一實施例中，標籤還 择^哲^ 鈿紙還包括—形成於該印刷 Θ /、該第一膝黏層間的冷燙膜。 於本發明之一實施例中，標籤 層靼兮A„ 疋I括一形成於該印刷 層與該冷烫膜間的第二膠黏層 固化勝I占劑或電子㈣勝黏層是以紫外線 部蚋-飞罨子束固化膠黏劑或溶 膠黏劑或熱固性勝_㈣成。 膠_或熱塑性 200923868 :本發明之—實施射，該表 或火焰處理或凹 、处理層可為電暈處理 式或網版塗佈方式。 > S版塗佈方式或柔版塗佈方 於本發明之一實施例中，該印 版印刷或凸版印刷或柔版印刷或網版印刷=版印刷或凹 位印刷所形成。 或喷墨印刷或數 於本發明之一實施例中，該第— 化膠黏劑或電子束固化膠黏劑或溶劑型紫外線固 黏劑或熱固性膠黏劑所形成。 膠黏劑或熱塑性膝 於本發明之一實施例中，該 两烯或延伸型聚丙烯或雙軸延伸聚丙乙烯或聚 岑平#締膜或氣化聚丙稀膜 乙_二^乙一知或K型聚對笨二甲酸乙二醋或乙稀- =聚物或尼龍或㈣或聚氯乙烯或聚氯亞乙稀或聚 延伸性聚苯乙稀或聚乳酸或發泡隔熱材或聚酯薄 臈或壓克力或紙材質。 於本發明之-實施例中，該護膜為一光撕膜，該光拇 膜可為聚丙稀或聚對苯二甲酸乙二醋或聚氣乙浠或聚氯亞 乙烯或聚苯乙稀或聚碳酸酯或壓克力材質。 於本發明之一實施例中，護膜可為聚乙烯或聚丙烯或 延伸型聚丙稀或雙軸延伸聚丙烯膜或氯化聚丙稀膜或聚對 苯二甲酸乙二酯或κ型聚對苯二曱酸乙二醋或乙稀一乙稀醇 共聚物或尼《I或紹箱或聚氯乙烯或聚氯亞乙稀或聚碳酸酯 或延伸性聚苯乙烯或聚乳酸或發泡隔熱材或聚酯薄膜或壓 克力或紙材質。 200923868 發明之實施例中的模内貼標 層形成於第一基材的τ & 曰田表面處理 "材的正面’增添印刷層與第-基材之間的 古’使仔標籤在模内貼標的成型過程中，不易因壓力 或尚溫的影響而造成印刷層剝離的現象。此 距變化大的環境因去丁 , 在，皿度差 α 、，也不易因高溫而造成印刷層的剝 精11此提升標籤成型的良率、财高溫性及重覆利用 性’同時搭配制的配置，缺升_性。 【實施方式】 、有關本發明之前述及其他技術内容、特點與功效，在 以下配合參考圖式之六個較佳實施例的詳細說明中，將可 清楚的呈現。以下實施例中所提到的方向用語，例如:’上 '下、左、右、前或後等’僅是參考附加圖式的方向。因 此’使用的方向用語是用來說明並非用來限制本發明。 在本發明被詳細描述之前，要注意的是，在以下的說 明内谷中，類似的元件是以相同的編號來表示。 i如圖2及圖3所示，是本發明模内貼標的標籤的第— 較佳實施例’該標冑是以模内貼標的方式形成於一物 品3上’在本實施例中，物品3是以一容器為例作說明， 但也可為任何需要以標冑2GG標示且為聚合物材質的物件 上。 標藏200包括一第一基材21、一表面處理層μ、一印 刷層23、一第一膠黏層24及一護膜25。第—基材η具有 一正面2Η及一背面212，第—基材21可為^乙稀（ρΕ、）、 聚丙烯㈣、延伸型聚丙烯（0ΡΡ)、雙軸延伸聚丙稀膜 200923868 (BOPP)、氯化聚丙烯膜（CPP)、聚對苯二甲酸乙二酯（ρΕτ) 、Κ型聚對苯二甲酸乙二酯（ΚΡΕΤ)、乙烯—乙稀醇共聚物 (EVOH)、尼龍（NYLON)、鋁箱、聚氯乙婦（pvc)、聚氯亞 乙烯（PVDC)、聚碳酸酯（PC)、延伸性聚苯乙烯（〇ps)、聚乳 酸（PLA)、發泡隔熱材、聚酯薄膜（Mylar)、壓克力或紙材質 ，其中發泡隔熱材為聚氨基曱酸酯（PU)，當然，發泡隔熱材 也可聚乙稀（PE)材質。表面處理層22形成於第一基材21的 正面211，其主要用以增加印刷層23與第一基材Μ之間的 附著力，使得具有文字或圖案等圖像的印刷層23形成於第 一基材21的正面211且位於表面處理層22上，其中，表面 處理層22可為電暈處理、火焰處理、凹版塗佈方式、凸版 塗佈方式、柔版塗佈方式或網版塗佈方式所形成，而印刷 層23可由平版印刷、凹版印刷、凸版印刷、柔版印刷、網 版印刷、喷墨印刷或數位印刷所形成。 >第-膠黏層24形成於印刷層23 i，其主要是用以使 :臈25能貼覆於印刷層23，第-膠黏層24為透明材質且 此保持良好的透光性’其為一耐高溫之紫外線固化膠黏劑 、電子束固化膠黏劑、溶劑型⑽vent Type)膠黏劑、熱塑 性膠黏劑或熱固性膠黏劑所形成，藉由第-膠黏層24耐高 溫的純，使得«扇在模内貼標的過程中不會因高溫 2生氣'包。濩膜25是透過第一膠黏層24貼覆於印刷層 上其主要用以保護印刷層23，使印刷層Μ所呈現的 :案或文字等影像能避免因摩擦或外力的因素，而產生刮 或磨損等問題，護膜25可為聚乙稀（pE)或聚丙稀(pp)或 200923868 延伸型聚丙烯（OPP)或雙軸延伸聚丙烯膜（BOPP)或氣化聚丙 烯膜（CPP)或聚對苯二曱酸乙二酯（PET)或κ型聚對苯二甲 酸乙二酯（KPET)或乙烯-乙烯醇共聚物（EVOH)或尼龍 (NYLON)或鋁箔或聚氯乙烯（pvC)或聚氯亞乙烯（pvD〇或聚 碳酸酯（PC)或延伸性聚笨乙烯（0PS)或聚乳酸（pLA)或發泡隔 熱材或聚酯薄膜（Mylar)或壓克力或紙材質’其中發泡隔熱 材為聚氨基甲酸酯（PU)，護膜25的表面可為光滑且具有光 澤的亮面或者是霧面。 另外’在模内貼標的過程中’標籤2〇〇是先置於模具4 内，並以吹出成型（bl〇wing m〇lding)、射出成型（inj.ecti〇n molding)或真空成型（vaccum m〇lding)的方式於模具4内成 Ϊ本體3 1 ’彳示籤2〇〇形成在物品3的本體31上的方向有二 種，一種是如圖2所示，護膜25未形成有第一膠黏層24 的面疋與核具4接觸，而第一基材21的背面212是形成 於本體3 1的-外表面3 i i，因此在成型後，標蕺是以 第基材21的月面212形成於本體31的外表面311上。當 標籤200在設計上是以第—基材21的背面212形成於本體 31的外表面311上時，則護膜25可設計成—能呈現出立體 圖像的光柵膜，藉此以增加物品3的美觀性並使物品3呈 現出特殊圖案或文字的視覺效果。 另一種是如圖3所示，護膜25未形成有第一勝黏層24 的一面是曰與本體31的外表面311接觸，而第一基材21的背 疋/、模具4接觸，因此在成型後，標籤2〇〇是以護 瞑25形成於本體31的外表面3ιι上，換言之，與圖2相較 10 200923868 下’標籤是整個翻轉後成型於本體31的外表面311， 藉此，钱在成型時，其各層間方向性的設計上較有 彈性。 藉由表面處理層22 @配置，増添印刷層23與第一基 材21之間的附著力’使得標籤細在模⑽標的成型過程 中，不易因壓力或高溫的影響而造成印刷層23剝離的現象 。此外，在溫度差距變化大的環境因素下(如高溫蒸煮物品 3)’也不易因高溫而造成印刷層23的制離，使物品3在使 用上無女全性的顧慮。藉此，能提升標籤_成型的良率 、耐高溫性及重覆利用性，同時搭配護臈25的配置，能提 升標籤200的耐磨性。 如圖4所^:，是本發明模内貼標的標藏之第二較佳實 ㈣J，該標籤2U)《成型方式與第一較佳實施例相同，但 標籤210的組成構件與第一較佳實施例有所不同。 標籤210還包括一形成於印刷層23與第一膠黏層μ 間的冷燙膜26,冷烫膜26藉由轉印的方式形成於印刷層 23上，藉此，能使標籤21〇呈現出多樣化的金屬顏色。此 外，標籤210形成在本體31上的方向也可有二種，—種是 以第一基材21的背面212成型於本體31的外表面311上， 另一種是以護膜25成型於本體31的外表面311上，其中， 標籤210以第一基材21的背面212成型於本體31的外表 面311時，護膜25可設計成一能呈現出立體圖像的光柵膜 如圖5所示’是本發明模内貼標的標籤之第三較佳實 200923868 施例，該標籤220之成型方式與第二較佳實施例相同，但 標籤220的組成構件與第二較佳實施例有所不同。 標籤220還包括一形成於印刷層23與冷燙膜26間的 第二膠黏層27,第二膠黏層27是以紫外線固化膠黏劑、電 子束固化膠黏劑、溶劑型（Solvent Type)膠黏劑、熱塑性膠 黏劑或熱固性膠黏劑所形成，第二膠黏層27除了增加冷燙 膜26貼覆於印刷層23 ±的接著力夕卜更能使冷烫膜更 平整地貼覆於印刷層23上，且藉由冷燙膜26的配置，使 得標籤220能呈現出特殊圖案或文字的設計效果。 如圖6所示，是本發明模内貼標的標籤之第四較佳實 施例，該標籤230之成型方式與第一較佳實施例相同，但 標籤230的組成構件與第一較佳實施例有所不同。 標籤230還包括一形成於第一基材21的背面212的第 三膠黏層28，及一以第三膠黏層28貼覆於第一基材21的 背面212的第二基材29，第二基材29未形成有第三膠黏層 28的一面是形成於本體31的外表面311，在本實施例中第 一基材21為鋁箔或發泡隔熱材材質，其中發泡隔熱材為聚 氨基甲酸酯（PU)，第二基材29可為聚乙烯（PE)、聚丙烯 (PP)、延伸型聚丙烯（OPP)、雙軸延伸聚丙烯膜（B〇pp)、氯 化聚丙烯膜（cpp)、聚對苯二甲酸乙二酯（ρΕΤ) 、κ型聚對 苯一甲酸乙二酯（ΚΡΕΤ)、乙烯—乙烯醇共聚物（EV〇H)、 尼龍（NYLON)、鋁箔或聚氯乙烯（pvc)、聚氯亞乙烯 (PVDC)、聚碳酸酯（ρ〇 、延伸性聚苯乙烯（〇ps)、聚乳 酸（PLA)、發泡隔熱材、聚酯薄膜、壓克力或紙材 12 200923868 貝/、中發/包隔熱材為聚氨基甲酸醋（pu)，第三膠 μ 是以紫外線固化膠黏劑、電子 ⑴ 电卞果固化膠黏劑、溶劑型 (Solvent Type)膠黏劑、熱塑性膠黏劑或熱固性膠黏劑所形 成。 由於第-基材21為鋁箔或發泡隔熱材材質的設計，使 得標鐵230形成於本體31上時，本體^能達到保溫的功 效藉此，標籤230能應用在食用的容器上，當然，標 咖整個包覆於本體31的外表面31"夺，能達到最佳的保 溫效果。另外，標籤230形成在本體31上的方向也可有二 種，-種是以第二基材29未形成有第三膠料Μ之面形 成於本體的外表面311，另一種是以護膜25形成於本體 31的外表面31卜其中’標籤23〇以第二基材”未形成有 第二膠黏層28之面形成於本體31的外表面3ιι日寺，護膜 25可設計成-能呈現出立體圖像的光栅膜，藉此使標籤 23〇呈現出特殊圖案或文字的設計效果。 〃如圖7所示，是本發明模内貼標的標籤之第五較佳實 T例，該標籤240之成型方式與第四較佳實施例相同，作 標籤240的組成構件與第四較佳實施例有所不同。 標藏240還包括一形成於印刷層23與第一膠黏層μ ^的冷Μ 26’冷费膜26藉由轉印的方式形成於印刷層 U上，藉此，能使標籤240里現出多樣化的金屬顏色此 外’因第-基材21為㈣或發泡隔熱材材質的設計，使本 體31能達到保溫的功效。 如圖8所示，是本發明模内貼標的標籤之第六較佳實 13 200923868 施例，該標籤250之成型方式與第四較佳實施例相同，曰 標籤250的組成構件與第五較佳實施例有所不同。 標籤250還包括一形成於印刷層23與冷燙臈間％ 第二膠黏層27,第二膠黏層27是以紫外線固化勝黏劑、: 子束固化膠黏劑、溶劑型（S〇lvent Type)膠黏劑、熱塑性膜 黏劑或熱固性膠黏劑所形成，第二膠黏層27除了增加冷^ 膜26貼覆於印刷層23上的接著力外，更能使冷烫膜％ = 平整地貼覆於印刷層23上。此外，因第一基材21為㈣ 或發泡隔熱材材質的設計，使本體31能達到保溫的功效： 歸納上述，藉由表面處理層22形成於第一基材21的 正面叫’增添印刷層23與第一基材21之間的附著力，使 得標藏2〇0、210、220、23〇、24〇、25〇在模内貼標的成型 過程中’不易因壓力或〶溫的影響而造成印刷層Μ剝離的 現象。此外’在溫度差距變化大的環境因素下，也不易因 高溫而造成印刷層23的剝離，藉此，能提升標籤、21〇 220 230 ' 240 ' 250成型的良率、耐高溫性及重覆利用 性’同時搭配護膜25的配置’能提升耐純，故確實能達 到本發明所訴求之目的。 惟以上所述者，僅為本發明之較佳實施例而已，當不 能以此限定本發明實施之範圍’即大凡依本發明中請專利 $巳圍及發明說明内容所作之簡單的等效變化與修飾，皆仍 屬本發明專利涵蓋之範圍内。另外本發明的任一實施例或 申月專利範圍不須達成本發明所揭露之全部目的或優點或 ’此外摘要部分和標題僅是用來辅助專利文件搜尋 14 200923868 之用’並非用來限制本發明之權利範圍。 【圖式簡單說明】 圖1是一般用於模内貼標之標 識*的—剖視示意圖； 疋本發明模内貼標的樟沾银 AlJ 加扪铋叙的第一較佳實施例的一 :表:圖’說明標籤是以第-基材的背面是形成於本體 叫二3圖是本發明模内貼標的標鐵的第-較佳實施例的-指=圖，說明標籤是以護膜形成於本體的外表面； 圖4疋本發明模内貼標的標 剖視示意圖； 螂的第-較佳實施例的- 圖5是本發明模内貼標的 剖視示意I ^第二㈣實施例的- 圖6是本發明模内貼標的標 剖視示意圖； 冑的卓四較佳實施例的- 圖7是本發明模内貼標的標 剖視示意圖，1 冑的第五較佳實施例的- 圖S是本發明模内貼標的標 剖視示意圖。 ）弟/、較佳實施例的一 15 200923868 【主要元件符號說明】 200、210"標籤 25···.· …·護膜 220、230··標籤 26··.·· •…冷烫膜 240、250··標籤 27••… …·第二膠黏層 21.........第一基材 28·.·.· …·第三膠黏層 211 .......正面 29·.·· •…第二基材 212.......背面 3…… • 物σ口 22.........表面處理層 31 •…· …·本體 23.........印刷層 311… •…外表面 24.........第一膠黏層 4…… …·模具 16200923868 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD The present invention relates to an in-mold labeling, in particular to a high molding yield, good reusability, high temperature resistance and wear resistance, and special In-mold labelled label for graphic design effects. [Prior Art] In-mold labing is a process in which a polymer material label is placed in a mold and blow molded (bl〇wing resistance (1) (four) or injection molding (injection molding). Or vacuum forming (vaccum _ brain magic method to form a polymer material in the mold, so that the molded article can be combined with the polymer material label. As shown in Figure 1, is Taiwan Patent Notice No. 575223 (No. 912 216 0 6) The label disclosed in (4) for in-mold labeling, the label 1 is placed in a mold 101, and after molding the polymer member 102 in the mold 1〇1, The label 丨 is bonded to the polymer member 1〇2. The label 1 comprises a substrate 11 bonded to the polymer member 1Q2 and being a polymer material, an image forming coating 12, an adhesive layer 13 and a protective film 14 The coating 12 is formed on the front surface of the substrate, and the protective film 14 is adhered to the front surface of the substrate u by a heat-resistant, solvent-free adhesive layer 13 and covered on the coating layer 12 by means of 濩臈14 Configuration that protects the label 1 formed on the polymer part 1〇2 from friction Problems such as scratching or abrasion. However, since the surface of the substrate 1 is not subjected to a special surface treatment process, the adhesion of the coating 12 to the substrate u is poor, so that it is easy to be subjected to pressure and high temperature during the molding process. The effect, or the environmental factors of the ring with a large temperature difference, caused the coating 12 to peel off, resulting in poor yield of the label 丨 and lack of reusability. Furthermore, the polymer part 1〇2 In the course of use, there is also a concern about the safety of use due to the factor of easy peeling of the coating layer 12. SUMMARY OF THE INVENTION An object of the present invention is to provide a molding yield with high recyclability and high temperature resistance. And a wear-resistant in-mold labelled label. Another object of the present invention is to provide an article with a label that is safe to use. Other objects and advantages of the present invention can be further derived from the technical features disclosed in the present invention. In order to achieve the above-mentioned or some or all of the objectives or other purposes, the in-mold labeling label disclosed in the embodiments of the present invention comprises a first substrate, a surface a processing layer, a printing layer, a first adhesive layer and a protective film. A substrate has a front surface and a back surface, and a surface treatment layer is formed on the front surface of the first substrate, and the printed layer has an image and is formed on the surface - positive = of the substrate = on the layer of the layer - the first adhesive layer is formed on the printed layer, and the enamel is applied to the printed layer with the first adhesive layer. In one embodiment of the invention, the label Further, the method further comprises: forming a cold foil film between the first knee layer and the first knee layer. In an embodiment of the invention, the label layer 靼兮A 疋I is formed in the printing The second adhesive layer between the layer and the cold-melting film is cured by the agent or the electron (four) winning layer is formed by the ultraviolet ray-flying scorpion bundle curing adhesive or the sol adhesive or the thermosetting property. Glue_ or thermoplastic 200923868: In the present invention, the surface or flame treated or concave, treated layer may be corona treated or screen coated. > S-plate coating or flexographic coating In one embodiment of the invention, the printing or relief printing or flexographic printing or screen printing = printing or recess printing is formed. Alternatively, ink jet printing or a number of embodiments of the present invention may be formed by the first adhesive or electron beam curable adhesive or the solvent type ultraviolet adhesive or thermosetting adhesive. Adhesive or thermoplastic knee in one embodiment of the invention, the two-olefin or extended polypropylene or biaxially stretched polypropylene or polyfluorene #膜膜 or vaporized polypropylene film B_二^乙一知 or K Poly(p-ethylidene) or ethylene---polymer or nylon or (d) or polyvinyl chloride or polyvinyl chloride or poly-stretch polystyrene or polylactic acid or foam insulation or polyester Thin or acrylic or paper. In the embodiment of the present invention, the protective film is a light tearing film, and the light film may be polypropylene or polyethylene terephthalate or polyethylene oxide or polyvinyl chloride or polystyrene. Or polycarbonate or acrylic. In an embodiment of the present invention, the protective film may be polyethylene or polypropylene or extended polypropylene or biaxially oriented polypropylene film or chlorinated polypropylene film or polyethylene terephthalate or kappa type poly pair. Ethylene phthalate or ethylene ethoxide copolymer or nylon "I or slag or polyvinyl chloride or polyvinyl chloride or polycarbonate or extended polystyrene or polylactic acid or foaming partition Hot or polyester film or acrylic or paper. 200923868 The in-mold labeling layer in the embodiment of the invention is formed on the first substrate by τ &曰田面处理" the front side of the material adds the ancient layer between the printed layer and the first substrate. During the molding process of the internal labeling, it is not easy to cause the peeling of the printed layer due to the influence of pressure or temperature. The environment with a large change in distance is due to the difference in the degree of the dish, and it is not easy to cause the stripping of the printed layer due to the high temperature. 11 This improves the yield of the label, the high temperature and the reusability of the label. Configuration, lack of _ sex. The above and other technical contents, features and effects of the present invention will be apparent from the following detailed description of the preferred embodiments of the accompanying drawings. The directional terms mentioned in the following embodiments, for example: 'upper down, left, right, front or back, etc.' are merely directions referring to the additional drawings. Therefore, the terminology used is used to describe that it is not intended to limit the invention. Before the present invention is described in detail, it is noted that in the following description, similar elements are denoted by the same reference numerals. As shown in FIG. 2 and FIG. 3, it is a first preferred embodiment of the label for in-mold labeling of the present invention. The label is formed on an article 3 by in-mold labeling. In this embodiment, the article 3 is a description of a container, but can also be any object that needs to be marked with the standard 2GG and is a polymer material. The label 200 includes a first substrate 21, a surface treatment layer μ, a printing layer 23, a first adhesive layer 24, and a protective film 25. The first substrate η has a front surface 2 Η and a back surface 212, and the first substrate 21 can be ethylene (rh), polypropylene (four), extended polypropylene (0 ΡΡ), biaxially oriented polypropylene film 200923868 (BOPP ), chlorinated polypropylene film (CPP), polyethylene terephthalate (ρΕτ), bismuth-type polyethylene terephthalate (ΚΡΕΤ), ethylene-ethylene glycol copolymer (EVOH), nylon ( NYLON), aluminum box, polyvinyl chloride (pvc), polyvinyl chloride (PVDC), polycarbonate (PC), extensible polystyrene (〇ps), polylactic acid (PLA), foam insulation Polyester film (Mylar), acrylic or paper material, wherein the foam insulation material is polyaminophthalate (PU), of course, the foam insulation material can also be made of polyethylene (PE) material. The surface treatment layer 22 is formed on the front surface 211 of the first substrate 21, and is mainly used to increase the adhesion between the printing layer 23 and the first substrate ,, so that the printing layer 23 having an image such as a character or a pattern is formed on the first surface. A front surface 211 of a substrate 21 is located on the surface treatment layer 22, wherein the surface treatment layer 22 can be corona treatment, flame treatment, gravure coating method, relief coating method, flexographic coating method or screen coating The manner is formed, and the printed layer 23 can be formed by lithography, gravure, letterpress, flexographic, screen printing, inkjet printing or digital printing. > The first adhesive layer 24 is formed on the printed layer 23 i, which is mainly used to enable the 臈 25 to be applied to the printed layer 23, and the first adhesive layer 24 is made of a transparent material and this maintains good light transmittance. It is formed by a high temperature resistant UV curable adhesive, electron beam curing adhesive, solvent type (10) vent type adhesive, thermoplastic adhesive or thermosetting adhesive, and is resistant to high temperature by the first adhesive layer 24. The purity makes the «fans in the process of labeling in the mold will not be angry with the high temperature 2 package. The enamel film 25 is attached to the printed layer through the first adhesive layer 24, and is mainly used to protect the printed layer 23, so that the image of the printed layer can be prevented from being caused by friction or external force. For problems such as scratching or abrasion, the film 25 may be polyethylene (pE) or polypropylene (pp) or 200923868 extended polypropylene (OPP) or biaxially oriented polypropylene film (BOPP) or vaporized polypropylene film (CPP). Or polyethylene terephthalate (PET) or κ-type polyethylene terephthalate (KPET) or ethylene-vinyl alcohol copolymer (EVOH) or nylon (NYLON) or aluminum foil or polyvinyl chloride ( PvC) or polyvinyl chloride (pvD〇 or polycarbonate (PC) or extended polystyrene (0PS) or polylactic acid (pLA) or foamed insulation or Mylar) or acrylic or The paper material 'where the foaming heat insulation material is polyurethane (PU), the surface of the film 25 can be a smooth and shiny bright surface or a matte surface. In addition, 'in the process of labeling in the mold' label 2 The crucible is placed first in the mold 4 and is formed by blow molding, injection molding (inj.ecti〇n molding) or vacuum molding (vacc The manner of um m〇lding) is formed in the mold 4 by the body 3 1 'the sign 2 is formed on the body 31 of the article 3 in two directions, one is as shown in FIG. 2, the film 25 is not formed. The face of the first adhesive layer 24 is in contact with the core 4, and the back surface 212 of the first substrate 21 is formed on the outer surface 3 ii of the body 31. Therefore, after molding, the mark is the first substrate. The lunar surface 212 of 21 is formed on the outer surface 311 of the body 31. When the label 200 is designed to be formed on the outer surface 311 of the body 31 with the back surface 212 of the first substrate 21, the protective film 25 can be designed as - A lenticular film capable of presenting a stereoscopic image, thereby increasing the aesthetics of the article 3 and presenting the article 3 with a special pattern or textual visual effect. Alternatively, as shown in FIG. 3, the protective film 25 is not formed with the first One side of the winning adhesive layer 24 is that the crucible is in contact with the outer surface 311 of the body 31, and the backing//the mold 4 of the first substrate 21 is in contact, so that after the molding, the label 2 is formed on the body 31 by the guard 25 The outer surface of the outer surface is 3 ιι, in other words, compared with FIG. 2, 200923868. The lower label is formed on the outer surface 311 of the body 31 after being inverted. Therefore, when the money is formed, the directionality of each layer is designed to be more flexible. By the surface treatment layer 22 @configuration, the adhesion between the printed layer 23 and the first substrate 21 is made to make the label finely modulo (10) During the molding process, the printing layer 23 is not easily peeled off due to the influence of pressure or high temperature. In addition, under the environmental factors (such as high-temperature cooking articles 3) where the temperature difference greatly changes, it is not easy to cause the printing layer 23 due to high temperature. The separation of the articles makes the item 3 have no female full concern in its use. Thereby, the label_forming yield, high temperature resistance, and reusability can be improved, and the wear resistance of the label 200 can be improved by the configuration of the shin guard 25. As shown in FIG. 4, it is the second preferred embodiment (4) J of the in-mold labeling of the present invention. The labeling method is the same as the first preferred embodiment, but the constituent members of the label 210 are the same as the first one. The preferred embodiment is different. The label 210 further includes a cold foil film 26 formed between the printing layer 23 and the first adhesive layer μ, and the cold foil film 26 is formed on the printing layer 23 by transfer, whereby the label 21 can be made diverse. Metallic color. In addition, the label 210 may be formed on the body 31 in two directions, such that the back surface 212 of the first substrate 21 is formed on the outer surface 311 of the body 31, and the other is formed on the body 31 by the protective film 25. On the outer surface 311, wherein the label 210 is formed on the outer surface 311 of the body 31 with the back surface 212 of the first substrate 21, the protective film 25 can be designed as a grating film capable of presenting a stereoscopic image as shown in FIG. It is a third preferred embodiment of the in-mold labeling of the present invention. The label 220 is formed in the same manner as the second preferred embodiment, but the components of the label 220 are different from the second preferred embodiment. The label 220 further includes a second adhesive layer 27 formed between the printed layer 23 and the cold foil film 26. The second adhesive layer 27 is an ultraviolet curing adhesive, an electron beam curing adhesive, and a solvent type (Solvent Type). Formed by an adhesive, a thermoplastic adhesive or a thermosetting adhesive, the second adhesive layer 27 can be more evenly applied to the cold adhesive film 26 in addition to the adhesion of the cold-melting film 26 to the printed layer 23 ± On the printed layer 23, and by the configuration of the cold foil film 26, the label 220 can exhibit a special pattern or text design effect. As shown in FIG. 6, which is a fourth preferred embodiment of the in-mold labeling of the present invention, the label 230 is formed in the same manner as the first preferred embodiment, but the constituent members of the label 230 and the first preferred embodiment It is different. The label 230 further includes a third adhesive layer 28 formed on the back surface 212 of the first substrate 21, and a second substrate 29 adhered to the back surface 212 of the first substrate 21 by a third adhesive layer 28, One side of the second substrate 29 on which the third adhesive layer 28 is not formed is formed on the outer surface 311 of the body 31. In the embodiment, the first substrate 21 is made of aluminum foil or foamed heat insulation material, wherein the foamed partition is formed. The hot material is polyurethane (PU), and the second substrate 29 may be polyethylene (PE), polypropylene (PP), extended polypropylene (OPP), biaxially oriented polypropylene film (B〇pp). , chlorinated polypropylene film (cpp), polyethylene terephthalate (ρΕΤ), κ-type polyethylene terephthalate (ΚΡΕΤ), ethylene-vinyl alcohol copolymer (EV〇H), nylon ( NYLON), aluminum foil or polyvinyl chloride (PVC), polyvinyl chloride (PVDC), polycarbonate (ρ〇, extensible polystyrene (〇ps), polylactic acid (PLA), foam insulation, poly Ester film, acrylic or paper 12 200923868 shell /, medium / package insulation is polyurethane urethane (pu), third glue μ is UV curing adhesive, electronic (1) electric capsule curing glue An adhesive, a solvent-type (Solvent Type) adhesive, a thermoplastic adhesive or a thermosetting adhesive is formed. Since the first substrate 21 is made of an aluminum foil or a foamed heat insulating material, the target 230 is formed on the body. When the 31 is on, the body can achieve the effect of heat preservation, whereby the label 230 can be applied to the edible container. Of course, the label coffee is entirely coated on the outer surface 31 of the body 31 to achieve the best heat preservation effect. The label 230 may be formed on the main body 31 in two directions, such that the second substrate 29 is formed on the outer surface 311 of the body without the surface of the third rubber material, and the other is the protective film 25. The outer surface 31 of the body 31 is formed on the outer surface of the body 31, and the surface of the second adhesive layer 28 is formed on the outer surface of the body 31. The protective film 25 can be designed to A grating film exhibiting a stereoscopic image, thereby causing the label 23 to exhibit a special pattern or a character design effect. As shown in FIG. 7, it is a fifth preferred example of the label of the in-mold label of the present invention. The label 240 is formed in the same manner as the fourth preferred embodiment as the label 240. The component member is different from the fourth preferred embodiment. The label 240 further includes a cold Μ 26' cold film 26 formed on the printing layer 23 and the first adhesive layer μ ^ formed by printing by transfer On the layer U, the diversified metal color can be produced in the label 240. In addition, the design of the first substrate 21 is (4) or the material of the foamed heat insulating material, so that the body 31 can achieve the heat preservation effect. 8 is a sixth preferred embodiment of the in-mold labeling of the present invention. The label 250 is formed in the same manner as the fourth preferred embodiment. The constituent members of the 曰 label 250 and the fifth preferred embodiment are shown. The examples are different. The label 250 further includes a second adhesive layer 27 formed between the printed layer 23 and the cold enamel, and the second adhesive layer 27 is an ultraviolet curing adhesive, a sub-bundle curing adhesive, and a solvent type (S〇lvent Type) an adhesive, a thermoplastic film adhesive or a thermosetting adhesive. The second adhesive layer 27, in addition to increasing the adhesion of the cold film 26 to the printed layer 23, enables the cold film to be flattened. The ground layer is attached to the printed layer 23. In addition, because the first base material 21 is (4) or the material of the foamed heat insulating material, the body 31 can achieve the effect of heat preservation: As summarized above, the front surface of the first substrate 21 formed by the surface treatment layer 22 is called 'additional The adhesion between the printed layer 23 and the first substrate 21 is such that the labels 2〇0, 210, 220, 23〇, 24〇, 25〇 are not easily damaged by pressure or temperature during the molding process of the in-mold labeling. A phenomenon that causes the print layer to peel off. In addition, under the environmental factors with large temperature difference, it is not easy to peel off the printed layer 23 due to high temperature, thereby improving the yield, high temperature resistance and repetition of the label, 21〇220 230 '240 '250 molding. The usability 'simultaneously matching the configuration of the protective film 25' can improve the purity resistance, so that the object of the present invention can be achieved. However, the above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the practice of the present invention, i.e., the simple equivalent change of the patent application and the description of the invention in the present invention. And modifications are still within the scope of the invention patent. In addition, any of the embodiments of the present invention or the scope of the patents of the present invention are not required to achieve all of the objects or advantages disclosed in the present invention or 'the abstract portions and the headings are only used to assist the patent document search 14 200923868'. Scope of the invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view of a generally used in-mold labeling*; a first embodiment of the first preferred embodiment of the in-mold labeling of the present invention. Table: The description of the label is based on the first substrate of the first substrate is formed on the body, and the second embodiment is the first preferred embodiment of the standard labeling of the inventor of the present invention. Figure 4 is a schematic cross-sectional view of the in-mold labeling of the present invention; Figure 5 is a cross-sectional view of the in-mold labeling of the present invention. Figure 6 is a schematic cross-sectional view of the in-mold labeling of the present invention; Figure 7 is a schematic cross-sectional view of the in-mold labeling of the present invention, and a fifth preferred embodiment of the first embodiment - Figure S is a schematic cross-sectional view of the in-mold labeling of the present invention. ) /, a 15 of the preferred embodiment 2009 23868 [Description of main component symbols] 200, 210 " label 25·······protective film 220, 230··label 26······... Cold film 240 250·· Label 27••...·Second Adhesive Layer 21.........First Substrate 28······· Third Adhesive Layer 211...... . Front surface 29····•...second substrate 212....back surface 3... • object σ port 22......surface treatment layer 31 •...··· body 23 .........print layer 311... •...outer surface 24.........first adhesive layer 4...··mold 16