200917985 九、發明說明： 【發明所屬之技術領域】 本發明係-_醜鞋製作之縣誠材，為一種直 接將丟棄或壞損的舊鞋具，可隨新鞋步回收，_ 製成具適當大小的顆粒原料，再經高溫脱臭、乾燥處理， 以適當關齡妓或錢轉轉，私熟添加劑 與活化用促進劑等材料混合，經機具麟混合均句成一具 適當物性的粗粒原材料’再、經壓片處理製成原材料片，方 便鞋底的越製作’再以勸加溫加壓熟滅型處理，即 可製成完整的鞋底材’確保鞋底材料的取得及製作，達到 無公害的魏使用，依鞋底使恥性做適當的材料比例組 合之變換’可達到產製成本降低之實用功效及目的。 【先前技術】 由於工業化資源消耗及浪費情形極其嚴重，加上地球 上天然資源再生不易及有限’使得因為各式工業生產所需 的天然資源不足的情形愈來愈明顯，而各式產品的產製成 本相對日益增南’加上環境的破壞，導致整個生態及大氣 等諸多生活條件的急速變化，使得廿一世紀的現代人對環 境保護更加迫切，於是各式具環保概念之商品不斷的推陳 出新’而以最新的環保概念裡’除強調不破壞環境為前提 外’更強調資源回收再利用的觀念’如此使資源或原物料 可不斷的循環再生利用，直接減少對能源或物料的損粍與 浪費，如此將可適當提供大地或地球的休養生機’以期達 到對地球的保護’以商品的製造、銷售及使用後的處理等 200917985 一系列的管控而言，如能將大部份物料回收再利用或再生 設計，即便是一種具環保之商品；以鞋子而言，其使用的 材料由鞋底、鞋面及繫繩等等商品分類極多，所需搭配的 材料或成型要件分別不同，加上對鞋具使用物性需求之差 異’自然需結合到極多的材料取用，尤其在強調以舒適使 用前提下，設計使用上，通常都是採用各式生、人造膠等 新料的/昆合使用，尤以一般鞋底材而言，其因為不同鞋具 使用物性需求不同，分由不同的材料調配混合，其主要兼 具耐用、舒適緩衝性的使用需要，基於此一使用限制，一 般之鞋底材料製作，大多仍是以大自然的原始材料為主體 ，未見以用過後廢棄的鞋材料回收做為使用材料的，自然 難稱符合回收或再利用的環保需要，而基於環保意識抬頭 的消費導向，各式具環保特性的鞋底結構便應運而生，常 見的環保鞋底材開發，多述求以紙製或充填軟木塞之屑料 或以回收之植物稻殼等天然材料材質，透過參雜各種參雜 劑或膠者物等混合’達到硬化及对水性的使用需要，再配 合各種疊組或授碎、攪拌壓擠定型、裁切等技術製程的製 作，完成鞋底的成型製作；所需製程及疊製過程極多，更 需添加極多成分的原始天然踢或人工合成膠料，方能完成 所谓環保鞋底的製作，整體製作成本明顯較高昂，然對使 用後鞋具的管理或回收，根本不見有效的處理改善，而以 傳統用後破損的鞋具，又不符一般廢棄物回收的價值，故 在垃圾減量的控制上，一直很難以克服，尤其以一般人通 常有兩雙鞋具以上’所造成的環境污染及處理上的困擾， 應是現代人極需思考改善的，尤其以廢棄的鞋具若能回收 200917985 做成鞋底材料，將兼具買新回收同步的環保概念，更且真 正達到具環保之輯，以鞋底的材料開發使用而言，就環 保鏈觀點如何回收再利用廢棄的鞋具，使其轉換成鞋材的 原始使用材料，就其所產生的環保效應，容有探討研究的 空間，而相信藉由鞋材的回收再利用，將可使鞋具產製鏈 構成真正環保低成本、循環製作，符合長效使用價值的環 保鞋底材開發，確有其積極研究開發的價值。 【發明内容】 C 本發明者有鑑於現行環保鞋底材料開發生產及使用上 所仿生尚成本及加工技術繁複等製造使用上之盲點，乃依 多年來投入鞋具環保研發製作的經驗，經悉心地試驗與研 究改良後，終開發出本發明之一種以回收鞋製作之環保鞋 底材，以回收廢棄鞋具為主材料，將其金屬配件撿除後， 加以壓粉碎處理成適當大小細顆粒狀，再經攪拌處理，經 高溫脫臭、乾燥處理後形成一回收原材料，再依不同鞋具 使用物性需要，添加適量的母膠、添加劑加以攪拌均勻後 ( ’再依鞋底製程，與添加劑及熟化促進劑等材料充分擾摔 混合’再置入到成型模具内，經高壓高溫熟化成型、修邊 ’便可形成具適當使用物性的回收環保鞋底材，整個製程 簡易又可連續成型，大幅降低產製成本，確實改善現行環 保鞋底材高成本製作的諸多不合實用情形。 本發明的目的在於：提供一種以回收廢棄鞋具為主要 材料’透過撿除金屬配件後，加以壓粉碎成適當大小，通 過加熱脫臭、乾燥處理後’依成型使用物性需要添加相當 比例的母膠’攪拌混合均勻成鞋底成型材料製作，配合^ 200917985 材料成本，達到鞋材回收循 襄疋型，大幅節省製造工時、 環使用的環保經濟實用目的。 【實施方式】 為方便貴審查委員能進一步瞭解本發明之產製特性 及其產贿值’謹以―餘實施例配合詳細說明如后·· 本發明-種以暖鞋製作之環絲底材，整個環保鞋 底材的製作封，如第一圖所示產製流程簡圖敘述如下： 整氣、循環回收特性的環保鞋底使用原材料（1 〇 )製作 ，主要以用過廢、丢棄的回收鞋具（11)為回收主體， 諸如-般料的雜、錄、工雜、休_等任意破損 丢棄的鞋具，不分如或室外使㈣均可时使用，無需 另外的77類或特殊處理，僅需將回收鞋具（1 1 )上所組 裝的金屬叫先通職除處理（i 2 )，特金屬質元件 另i回收’將隨鞋具（11)財置人麟碎的機具中 進行壓卷碎處理（1 3 )’使其碎化到顆粒在5麵0的約 略大小以下細小難或粉狀，其外觀形狀不限，再置入到 二，狀_道式輸送裝置内’以近工2的以上的高 ’讀汽進行高溫脫臭處理（丄4 )，使回收的粉碎鞋材達 到相對淨化無味的處理，再經熱風缝處理（i 5 )，使 其形成粉碎均自的混合式魏时鞋底雜料（丄〇 )。 將由回收鞋具（11)製成的鞋底原材料（1〇)， 以適當的重4_調配，通常在5〜9 ◦ ，依欲製作 之鞋底材所需符合使用的物性f要，添加由天餅、人造 膠添加劑、填充劑等相混合成的母膠（2 〇 )，佔5〜9 _比例’置入到-貯槽中由機具做攪拌混合（2 1) 200917985 ’使達到混合的的需要，其混合比舰依產製鞋底材所 需物性做相對的調整，適時添加佔總量5〜i 〇%的添加 劑，包含如架橋劑、促進劑、活性劑、防老化劑、加工助 劑等添加，方便由平面輪機做壓片處理（2 2)，製作成 鞋底成咖的材則狀，通過適量添加劑_助，使^^ 製成整捆狀的原材料片，方便後續製程的裁製與收合貯置 使用，一般片體的厚度可在1〜5 〇 ，視實際使用 需要做變換調整。 ( /而鞋底製作時’將混合壓片後的材料片裁切適當大小 後，直接置入到成型模具中，做入模壓製處理（2 3)， 經過油壓機加溫加壓熟化定型（2 4 )，即可製作成完整 的鞋底形狀；按以本發明中所檢附測試之鞋底材，如附件 所*之鞋底測試冑料’其混合組成之環彳細收原材料 (10)約佔成品之鞋底成型材料比在5 〇%以上，餘所 加入之母膠（2〇)在45%間，再適量添加方便橡膠熟 成之硫磺等之添加劑及橡膠熟化促進劑等，其計量約在5、 % ’域當_和比嫩，直接與原材料做辦混合（2 1)均勻後，做則處理（2 2 )，使其呈方便疊組收捲 成捆狀的片材，以便利後續加工成型或裁切的操作使用， 再將適當大小的原材料（1〇)片，依定量置入到成型用 模f内，進行入模壓製處理（2 3)之程序，將上、下模 組蓋合，、即可進行加溫、加壓熟化㈣（2 4 )操作，而 依原材料（1〇)内部混合之添加劑硫績的熟成辅助及熟 化促進劑的$化辅助，使整個原料的流動率可大幅的提升 ，有效充滿模穴内部，達到完整鞋底的成型製作，一絲 200917985 底材成型加溫的溫度通常在1〇 〇〜16 〇它間，而其時 間通常在4〜1 5分鐘’整储料的調合比例，依實際使 用鞋底的實用物性需求不同’將原材料混合比例調整，而 有所差異，將模製完成的半成品予以出模取出後，再經修 邊程序，使成型之鞋材邊面修除整齊後，即是具一體成型 製作之完整環保鞋底之成品（2 5)結構製作二 而以本發明的壤保鞋底材的使用，其主要以回收鞋且 為主材料，不論是室Μ、外用鞋具均可簡易回收循環再生 利用’依不同鞋底使用需要，除可由其材料比的混合調整 外’配合填細的添加織，亦可·對闕強化處理， 即在原材料（10)混合中加入5〜1〇%適量填充劑， 如白土（即俗稱高嶺土）、碳酸鈣、玻璃粉（即俗稱白煙 )等物料其比例依硬實度需要做添加量的調整變換，即 可達到耐磨及較硬實的使用物性補強功效，使整支鞋底更 符實用效益；其與現行鞋底材的製作相當，故縣發明之 特性，不予多述；而以本發明的特色，即以回收的廢棄鞋 具為回收環保原材料（i 〇 )組合之主要，僅 鞋具上的金屬材質元件檢除’便可全部丢入機具中做^ 碎處理（1 3 )，可收到省工更且簡化製程的操作，更可 確實達到鞋具回收再利用犍環共生的環保理念，整個處理 製作無需增加太多成本及製程，製作上可方便生產線的連 續製作’不僅可收到環保㈣簡化、實用經濟的功效，尤 其無需如傳統鞋相收，僅能就誠部赌料分類回收所 產生之不便，就鞋底的製作上，不僅具省工、結構實用經 濟的功效’更且真j£符合環保喊永續魏使㈣完全再 200917985 生實用功效。 而以上述環保鞋底之製作設計令，整個原材料（工〇 ^主要由廢棄回收之任意鞋具，配合適量的母膠（2 0 ) ^合補，義撕朗雛絲，更且廢棄後仍可 重f 2收再粉碎使用，為-循環再生不斷的環保素材料 斜，fff的^料，幾村狱完麵縣無汗染材 你^口犯合適置的成型熟化添加劑及流動促進劑等添加 物’由於其含量低且均屬可熟化揮發之物料，完全不 整個鞋底職廢棄_收或處理上的困擾，整個加工/ 程可連續姻，完全無需特殊的技術製程，可以自動化 產線，劃控制’使產㈣動連續化，無需分段製作連結 ’、可說是-極具創新的環絲底材料組合設計，·整體產製 成本保守估計較現行環絲材的製作，可料i 5%以上 ，而在廢棄鞋具回收利用之環保理念及效益上，則是一空 :且具商業經濟效極佳的新式環保鞋底製作設計，所具的 實用效益’實非現行任—環保鞋底材料開發所可比擬，所 具的^用及產_用倾，誠屬空前之解設計。 -綜上所述，本發明一種以回收鞋製作之環保鞋底材， ，由廢棄鞋具完整簡易回收，經壓粉碎再生混合利用，配 :適量的母黟調配、定型處理，使鞋底材料可無限次循環 使用’令材料損耗減到最少，真正符合環保材料使用特 性’就其材糊發設計而言，不僅部達碰製成本降低 ，產製技_財益的提升，所具鬆_價值及創 益的提升特性，實已符合發明專利要件，爰依法 200917985 【圖式簡單說明】 (一）·圖式部份： 第一圖：係本發明之環保鞋底材製程方塊示意簡圖 【主要元件符號說明】 (二）·圖號部份： (1 0 )原材料 (12)檢除處理 (14)脫臭處理 (2 0)母膠 (2 2)壓片處堙 (2 4)熟化定型 (11)鞋具 (13)壓粉碎處理 (15)烘乾處理 (21)攪拌混合 (2 3)入模壓製處理 (2 5)成品 11200917985 Nine, invention description: [Technical field of invention] The invention is a county-made material of ugly shoes, which is an old shoe that will be discarded or damaged directly, and can be recycled with new shoes. The granule raw materials of appropriate size are deodorized and dried by high temperature, and transferred to the appropriate age or money. The private cooking additive is mixed with the activation accelerator and other materials, and the mixture is mixed into a suitable physical coarse raw material. 'After, the tablet is processed into a raw material sheet, which facilitates the production of the sole.' Then, by persuading the heating and pressing, the finished sole material can be made into a complete shoe sole material to ensure the acquisition and production of the sole material to achieve pollution-free The use of Wei, according to the sole of the sole to make the appropriate proportion of the material composition of the transformation of the transformation of the material can achieve the practical effect and purpose of reducing the cost of production. [Prior Art] Due to the extremely serious situation of industrial resource consumption and waste, and the fact that the regeneration of natural resources on the earth is not easy and limited, the situation of various products is becoming more and more obvious due to the shortage of natural resources required for various industrial production. The relatively high cost of the system, coupled with the destruction of the environment, has led to rapid changes in the living conditions such as the entire ecology and the atmosphere, making modern people in the 21st century more urgent about environmental protection, so various products with environmental protection concepts are constantly being introduced. 'With the latest environmental protection concept, 'except for the premise of not damaging the environment, 'more emphasis on the concept of resource recycling and reuse' so that resources or raw materials can be recycled continuously, directly reducing the damage to energy or materials. Waste, so that the earth or the earth's rehabilitative machine can be properly provided to achieve the protection of the earth. The manufacturing, sales and post-use treatment of the goods, etc. 200917985 For a series of control, if most of the materials can be recycled Use or regenerate the design, even if it is an environmentally friendly product; in terms of shoes, The materials used are classified by the soles, uppers and tethers, etc. The materials or molding requirements to be used are different, and the difference in the physical properties of the footwear is naturally required to be combined with a large amount of materials. In particular, under the premise of comfortable use, the design is usually used in various types of raw materials such as raw and artificial rubber, especially in the case of general shoe materials, which have different physical properties due to different footwear. It is divided into different materials to mix and mix. It mainly has the needs of durability and comfortable cushioning. Based on this limitation of use, the general sole material is mostly made of natural raw materials, but it is not used. After recycling the discarded shoe materials as materials for use, it is naturally difficult to meet the environmental protection needs of recycling or reuse. Based on the environmentally-conscious consumer-oriented consumption orientation, various environmentally-friendly sole structures have emerged, and common environmentally-friendly soles have emerged. Development of materials, more information on paper or filled with cork material or recycled natural material such as plant rice husk, through the mixed variety Mixing agent or glue, etc. 'to achieve hardening and water use needs, and then with various stacking or crushing, stirring and pressing, cutting and other technical processes to complete the molding of the sole; the required process and stack There are a lot of processes, and it is necessary to add a lot of original natural kick or synthetic rubber to complete the so-called environmentally-friendly sole production. The overall production cost is obviously high. However, the management or recycling of the shoes after use is not seen at all. Effective treatment improvement, and the traditionally worn shoes are not in line with the value of general waste recycling, so it has been difficult to overcome the control of garbage reduction, especially in the case of ordinary people usually have two pairs of shoes above The environmental pollution and handling problems should be considered by modern people. In particular, if the discarded shoes can be recycled 200917985, the sole material will be purchased, and the environmental protection concept of buying new recycling will be realized. In the environmental protection series, in terms of the development and use of the materials of the soles, how to recycle and reuse the discarded shoes and convert them into the original materials of the shoes The use of materials, the environmental impact of its production, has room for discussion and research, and believe that through the recycling of shoe materials, the footwear manufacturing chain will constitute a truly environmentally friendly low-cost, recycling production, in line with long-term use The development of environmentally-friendly shoe soles has the value of active research and development. SUMMARY OF THE INVENTION C The present inventors have in view of the blind spots in the manufacture and use of the current environmentally-friendly sole materials, such as the cost of bionics and the complexity of processing techniques, and have been carefully tested based on years of experience in environmentally-friendly research and development of footwear. After research and improvement, the invention has developed an environmentally-friendly shoe substrate made of recycled shoes, which is mainly used for recycling discarded shoes, and after being removed from the metal parts, it is crushed and processed into fine particles of appropriate size, and then After stirring, high temperature deodorization and drying treatment will form a recycled raw material, and then according to the physical properties of different shoes, add appropriate amount of masterbatch, additives and stir evenly ('receive the sole process, with additives and curing accelerator When the material is fully disturbed and mixed, it is re-inserted into the forming mold, and the high-pressure high-temperature curing and trimming can form a recycled environmentally-friendly shoe substrate with appropriate physical properties. The whole process is simple and continuous molding, which greatly reduces the cost of production. It does improve many unrealistic situations in the current high cost of environmentally friendly shoe soles. It is to provide a kind of recycled scrap shoe as the main material. After removing the metal fittings, it is crushed into appropriate size. After deodorization and drying by heating, it is necessary to add a certain proportion of the masterbatch according to the physical properties of the molding. It is made into a sole molding material and matched with the material cost of 200917985 to achieve the recycling of shoe materials, which greatly saves the environmental, economic and practical purposes of manufacturing man-hours and ring use. [Embodiment] To facilitate the review committee, you can learn more about this. The production characteristics of the invention and the bribe value of the invention are described in detail with the following examples. The invention is a ring-shaped substrate made of warm shoes, and the whole environmentally-friendly shoe substrate is produced as shown in the first figure. The schematic diagram of the production process is described as follows: The environmentally-friendly sole of the gas-recycling and recycling characteristics is made of raw materials (1 〇), mainly used for recycling and discarded recycled shoes (11) as the main body of recycling, such as - Any miscellaneous items such as miscellaneous, recorded, miscellaneous, and escaping, etc., can be used regardless of whether it is used outdoors or outdoors (4), without additional 77 types or special treatment. The metal assembled on the recycled shoe (1 1 ) needs to be treated first (i 2 ), the special metal component is recycled, and the metal will be pressed with the equipment of the shoe (11). The crushing treatment (1 3 )' is shredded to a small or difficult or powdery shape of the particles below about 5 faces, and the shape of the particles is not limited, and then placed in the second, in the shape of the conveyor. 2 of the above high 'reading steam is subjected to high temperature deodorization treatment (丄4), so that the recovered crushed shoe material can be treated with relatively clean and odorless, and then subjected to hot air seam treatment (i 5 ) to form a pulverized self-mixing type. Wei Shi soles (丄〇). The sole material (1〇) made of recycled shoes (11), with appropriate weight 4_, usually 5~9 ◦, required for the soles to be made In accordance with the physical properties of the use, add a masterbatch (2 〇) mixed with a day cake, an artificial rubber additive, a filler, etc., occupying a ratio of 5 to 9 _ into the sump and mixing and stirring by the machine (2 1) 200917985 'To achieve the need for mixing, the mixing is relatively adjusted compared to the required physical properties of the ship's shoe sole Adding additives containing 5~i 〇% in total, including additions such as bridging agent, accelerator, active agent, anti-aging agent, processing aid, etc., convenient for tableting by plane turbine (2 2), making sole The material of Chengcai is shaped into a whole bundle of raw material sheets by appropriate amount of additives, which facilitates the subsequent process of cutting and folding storage. Generally, the thickness of the sheet can be 1~5 〇. Transform adjustments are required depending on actual use. (When the sole is made], the material piece after the mixed tableting is cut to an appropriate size, and then directly placed into a molding die, and subjected to a mold pressing treatment (2 3), and subjected to a hydraulic press to pressurize and mature the mold (2 4 ), can be made into a complete sole shape; according to the shoe substrate tested in the invention, such as the sole test material of the accessory*, the mixed composition of the raw materials (10) is about the finished product. The ratio of the sole molding material is more than 5%, and the remaining masterbatch (2 〇) is between 45%, and an appropriate amount of additives such as sulphur which is convenient for rubber and rubber curing accelerator are added, and the amount is about 5, %. 'Domain _ and Bi Nen, directly mixed with the raw materials (2 1), then treated (2 2), so that it is conveniently stacked into a bundle of sheets to facilitate subsequent processing or For the cutting operation, the appropriate size raw material (1 inch) piece is placed into the molding die f according to the amount, and the mold pressing process (2 3) is performed to cover the upper and lower modules. , can be heated, pressurized and matured (four) (2 4) operation, and based on raw materials (1〇 The internal mixing of the additives and the aging of the aging agent and the aging accelerator can greatly increase the flow rate of the whole raw material, effectively fill the inside of the cavity, and achieve the complete production of the sole, a piece of 200917985 substrate molding heating The temperature is usually between 1 〇〇 and 16 〇, and its time is usually 4 to 15 minutes. The blending ratio of the whole storage material is different depending on the actual physical property requirements of the actual sole. Difference, after the molded semi-finished product is taken out of the mold, and then subjected to the trimming procedure, the finished side of the formed shoe material is neatly tidy, that is, the finished product of the complete environmentally-friendly sole with integrated molding (2 5) structure production Secondly, the use of the loaf shoe substrate of the present invention mainly utilizes recycled shoes as the main material, and can be easily recycled and recycled for both indoor and outdoor use shoes, as required by different soles, except for the material ratio thereof. The blending adjustment is external to the addition of the weaving, or the intensive treatment of the crucible, that is, adding 5 to 1% of the appropriate amount of filler, such as clay, in the mixing of the raw material (10). Commonly known as kaolin), calcium carbonate, glass powder (commonly known as white smoke) and other materials, the proportion of the material needs to be adjusted according to the degree of hardness, which can achieve the wear-resistant and harder physical properties of the reinforcing effect, so that the whole sole is more in line Practical benefits; it is equivalent to the current production of shoe soles, so the characteristics of the inventions of the county are not mentioned; but the characteristics of the invention, that is, the recycled discarded shoes are the mainstay of recycling environmentally friendly raw materials (i 〇), only The metal material on the shoe is removed, and all can be thrown into the machine to do the crushing process (1 3 ). It can receive the labor-saving and simplify the process of the process, and can actually achieve the recycling of the shoe and reuse the ring symbiosis. The concept of environmental protection, the entire processing production does not need to increase too much cost and process, the production can be convenient for the production line continuous production 'not only can receive environmental protection (four) simplified, practical and economical effects, especially without the traditional shoes, only Chengs The inconvenience caused by the recycling of gambling materials, on the production of the soles, not only has the effect of labor saving, structural and practical economy. 'More and true, it is in line with environmental protection, shouting forever Wei (4) completely again 200917 985 has a practical effect. With the design of the above-mentioned environmentally-friendly soles, the entire raw materials (manufacturing 主要^ is mainly used for scrapping any shoe, with a suitable amount of masterbatch (20) ^, and it can be used for recycling. Heavy f 2 collection and re-pulverization use, for the - cycle regeneration of environmentally friendly materials oblique, fff ^ material, several villages in the prison area no sweat dyes you ^ mouth committed to the appropriate set of molding additives and flow promoters added Because of its low content and all the materials that can be matured and volatilized, the whole process is not plagued by the disposal of the soles. The whole process/process can be continuous, no special technical process is required, and the production line can be automated. Control 'Make production (four) dynamic continuous, no need to make a joint connection', can be said to be - an innovative ring wire bottom material combination design, · overall production cost is conservatively estimated than the current ring wire production, can be expected i 5 More than %, and in the environmental protection concept and benefits of recycling and recycling of used shoes, it is empty: and has a commercial and economical effect of the new environmentally friendly sole design, the practical benefits of 'not the current--environmental sole material development Comparable, the use of the use and production _ use tilt, is an unprecedented solution design. - In summary, the present invention is an environmentally-friendly shoe substrate made of recycled shoes, which is completely and easily recycled from discarded shoes. Pressure pulverization, regenerative mixing and utilization, with: appropriate amount of mother-in-law compounding and shaping treatment, so that the sole material can be recycled indefinitely, so that the material loss can be minimized, and it is truly in line with the environmentally-friendly material use characteristics. The ministry has reduced the cost of production, the improvement of production technology _ _ benefits, the characteristics of the loose _ value and the benefits of the benefits, has been in line with the invention patent requirements, 爰 law 200917985 [simple description of the map] (a) · schema Part: The first picture is a schematic diagram of the process of the environmentally-friendly shoe substrate of the present invention. [Main component symbol description] (2) Part number: (1 0) Raw material (12) Inspection and treatment (14) Deodorization Treatment (20) Masterbatch (2 2) Tableting 堙 (2 4) Maturing styling (11) Shoe (13) Pressure pulverization treatment (15) Drying treatment (21) Stirring mixing (2 3) Compression molding Processing (2 5) finished product 11