TW200906947A

TW200906947A - Compositions comprising metallocene polypropylene waxes and carbon nanotubes

Info

Publication number: TW200906947A
Application number: TW097118707A
Authority: TW
Inventors: Pirko Kolditz; Reinhold Kling
Original assignee: Clariant Internat Co Ltd
Priority date: 2007-05-25
Filing date: 2008-05-21
Publication date: 2009-02-16
Also published as: TW200904884A; TW200906948A

Abstract

The invention relates to compositions comprising metallocene polypropylene waxes with a dropping point and/or a softening point of from 70 to 130DEG C, and carbon nanotubes (CNTs), the compositions being in the form of masterbatches, compounds or conductive polymers, and their use for producing conductive polymers and articles made of conductive polymers.

Description

200906947 九、發明說明：【發明所屬之技術領域】本發明係關於包含滴點及/或軟化點為7(rc至13〇t之茂金屬聚丙烯蠟及碳奈米管（CNT)之組合物，該等組合物係呈母體混合物、化合物或導電聚合物之形式；及其用於產生導電聚合物及由導電聚合物製成之製品的用途。 » 【先前技術】在塑膠工業中通常使用呈化合物或母體混合物形式之添 ,、加劑。 \ : 出於本發明之目的，母體混合物為包含載劑聚合物及添加劑之組合物，其中添加劑係以高於最終應用中之濃度存在於母體混合物中，且該載劑聚合物通常不為最終應用之聚合物。添加劑於母體混合物中之較佳濃度介於〇 5重量％至90重量％，尤其1重量％至8〇重量％之範圍内，以母體混合物之總重量計。 > 出於本發明之目的’化合物為包含聚合物及添加劑之組 L:’ 合物，其中該添加劑係以最終應用或最終製品之所需最終濃度存在於化合物中，且該聚合物為最終應用或最終製品 - 之所需聚合物，因此該化合物僅藉助於物理成型方法製成 ' 最終應用或最終製品之所需形狀。出於本發明之目的’導電化合物及由導電化合物製成之最終產品係以1〇.6歐姆至1〇n歐姆，較佳1〇_5歐姆至歐姆，尤其0.1歐姆至1〇9歐姆之表面電阻為特徵。表面電阻係根據DIN EN WMOd]定義，且在測試樣品 130449.doc 200906947 展示至少80 mmxl20 mm之尺寸或至少110 mm之直徑的情況下根據DIN EN 6 1 340-2-3量測。在測試樣品既未展示至少80 mmxl20 mm之尺寸亦未展示至少11〇 mm之直徑的情況下’表面電阻係根據IEC 93，以尺寸為60 mmx40 mm之平樣品及該樣品表面上直接以導電銀塗料塗刷之尺寸為 a-40 mm、b = 3 mm且g=l 〇 mm之矩形電極測定。含有作為添加劑之CNT且用於產生導電聚烯烴的母體混200906947 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD The present invention relates to a composition comprising a metallocene polypropylene wax and a carbon nanotube (CNT) having a dropping point and/or a softening point of 7 (rc to 13 〇t) The compositions are in the form of a parent mixture, compound or conductive polymer; and their use for producing conductive polymers and articles made from conductive polymers. » [Prior Art] Generally used in the plastics industry Addition of the compound or matrix mixture, additive. \ : For the purposes of the present invention, the parent mixture is a composition comprising a carrier polymer and an additive, wherein the additive is present in the parent mixture at a higher concentration than in the final application. And the carrier polymer is generally not the final application polymer. The preferred concentration of the additive in the parent mixture ranges from 〇5 wt% to 90 wt%, especially from 1 wt% to 8 wt%, Based on the total weight of the parent mixture. > For the purposes of the present invention, a compound is a group of L:' compounds comprising a polymer and an additive, wherein the additive is used in the final application. Or the desired final concentration of the final product is present in the compound, and the polymer is the desired polymer for the final application or final product, so the compound is made only by physical forming methods for the final application or final product. Shape. For the purposes of the present invention, the conductive compound and the final product made of the conductive compound are from 1 〇.6 ohm to 1 〇n ohm, preferably from 1 〇5 ohm to ohm, especially from 0.1 ohm to 1 〇9. The surface resistance of ohms is characterized by the surface resistance according to DIN EN WMOd] and in the case of test specimen 130449.doc 200906947 showing a size of at least 80 mm x 20 mm or a diameter of at least 110 mm according to DIN EN 6 1 340-2- 3 Measurement. In the case where the test sample does not exhibit a size of at least 80 mm x 20 mm and does not exhibit a diameter of at least 11 mm, the surface resistance is based on IEC 93, with a flat sample of size 60 mm x 40 mm and on the surface of the sample. Measured directly by a conductive silver coating with a rectangular electrode measuring a-40 mm, b = 3 mm and g = l 〇 mm. Containing CNTs as an additive and used to produce conductive polyolefins

合物及/或化合物必須滿足嚴格要求：該等組合物應具有極低黏度以產生良好加工性，其應具有高負載量，亦即高 CNT濃度’且應可能在最終製品中獲得所需導電性。其他要求為：冑導熱性’在母體混合物的情況下與最終應用或取終製品之聚合物的良好可混性及相容性，以及CNT於母體混合物及/或化合物中之良好分散，對最終製品之機械特性及熱特性’尤其對衝擊強度、拉伸強度或熱變形抗性之極小不利作用。導電聚稀烴係用於產生用於存在高***風險之領域、區域或應用中之製品；出於本發明之㈣，此等製品將簡單概括為用於***防護之製品。此外’僅導電聚婦烴可藉助於靜電粉末塗佈著色。出於本發明之目的，該使用領域將稱為靜電粉末塗佈。此外，導電聚烯烴係座生咸子不展不靜電荷載之包裝’且用於(例如)電子組件之包裝中。導電聚稀烴亦用作燃料電池之雙極板。 130449.doc 200906947 包含聚乙烯（PE)及碳奈米管（CNT)之化合物由 "Polyethylene multiwalled carbon nanotube composites", Polymer 46 (2005)，8222 ff 已知。 EP 1 777 258 A1於請求項1中揭示以下組合物：碳奈米管（CNT)加強熱塑膠模製組合物，其包含組份 ⑷至⑺， A) 5重量％至80重量％由以下各物組成之混合物： A1) 〇.1重量％至50重量％(以A計）由以下各物組成之混合物： (31)4.75重量％至95.25重量％(以（八1)計）〇1^丁，及 (a2) 95.25重1 /〇至4.75重量％(以（A1)計）水溶性兩親媒性聚合物之鹽，及， A2) 50重量％至99.9重量％(以（A)計）接枝聚合物（A2)，其具有雙峰粒度分布，且由以下各物組成，以（A2)計： "3) 4〇重量％至90重量％彈性體微粒接枝基質（a3)，其係藉由使以下各物聚合獲得，以（a3)計： a31) 70重量％至1〇〇重量％至少一種共軛二烯，或至少一種丙稀酸C ! -C8烧酯，或其混合物， a32) 0至30重量％至少—種其他單烯系不飽和單體，及 a33) 0至10重量％至少一種多官能交聯單體； a4) 1 〇重量％至60重量〇/0由以τ 至里/〇田以下各物組成之接枝物 (a4)，以（a4)計： a4 1) 65重量％至95重量％至少_扬7比甘朴里王· v 種乙烯基芳族單體， 130449.doc 200906947 a42) 5重量％至3 5重量％丙稀猜， a43) a44) 種單歸系不飽和單體，及種多官能交聯單體； 0至30重量％至少— 〇至10重量％至少一 B) 20重量％至95重量％熱 ml/g至120 ml/g之黏度值vn，計：塑性聚合物（B)，其具有5〇且由以下各物組成，以（B) bl) b2) 64重量。/〇至81重量〇/〇至小 ^ 至夕—種乙烯基芳族單體 19重量％至36重量％丙烯腈，及 b3) 0至30重量％至少—種其他單烯系不飽和單體； C) 〇至50重量％熱塑性聚合物(c)，其具有μ·至 mrm/g之黏度值VN，且由以下各物組成以（c)計： cl) 62重量％至81會吾〇/„ 5 /卜 ^ 垔®/〇至少一種乙烯基芳族單體， c2) 19重量％至38重量％丙烯腈，及 c3) 0至30重量％至少一種其他單烯系不飽和單體，其中組份（B)及（C)之黏度值VN相差至少5個單位（mi/幻，或其丙稀腈含量相差至少5個單位（重量％)，或黏度值㈣與丙烯腈含量兩個特徵均相差至少5個單位，及 D) 〇至50重量％由以下各物組成之熱塑性聚合物⑴），以（D)計： dl) 4重量❶/〇至96重量％至少一種乙烯基芳族單體， d2) 4重量/〇至96重量％來自由甲基丙烯酸曱酯 '順丁烯二酸酐及順丁烯二醯亞胺組成之群之至少一種單體，及 d3) 〇至50重量％丙烯腈，其中若存在則（D)不同於（B) 及（C); 130449.doc 200906947 E) 〇至8〇重量％非晶形或（半）_結晶聚合物，及 F) 〇至50重量％添加劑（ρ)。Compounds and / or compounds must meet stringent requirements: these compositions should have very low viscosity to produce good processability, which should have a high loading, ie high CNT concentration 'and should be possible to obtain the desired conductivity in the final product Sex. Other requirements are: 胄 thermal conductivity 'good miscibility and compatibility with the final application or polymer of the final product in the case of the parent mixture, and good dispersion of the CNT in the parent mixture and / or compound, for the final The mechanical and thermal properties of the product are particularly detrimental to the resistance to impact strength, tensile strength or thermal deformation. Conductive polyhydrocarbons are used to produce articles for use in areas, regions or applications where there is a high risk of explosion; for the purposes of (4) of the present invention, such articles will be briefly summarized as articles for use in explosive protection. Furthermore, only conductive polytetrahydrocarbons can be colored by means of electrostatic powder coating. For the purposes of the present invention, this field of use will be referred to as electrostatic powder coating. In addition, the conductive polyolefin pedestal is not packaged in a non-static load package and is used, for example, in the packaging of electronic components. Conductive polyurenes are also used as bipolar plates for fuel cells. 130449.doc 200906947 Compounds comprising polyethylene (PE) and carbon nanotubes (CNT) are known from "Polyethylene multiwalled carbon nanotube composites", Polymer 46 (2005), 8222 ff. EP 1 777 258 A1 discloses the following composition in claim 1 : a carbon nanotube (CNT) reinforced thermoplastic elastomer molding composition comprising components (4) to (7), A) 5 to 80% by weight of each of the following Mixture of composition: A1) 11% by weight to 50% by weight (in terms of A) of a mixture consisting of: (31) 4.75 wt% to 95.25 wt% (based on (eight 1)) 〇 1^ D, and (a2) 95.25 weight 1 /〇 to 4.75重量% (by (A1)) salt of water-soluble amphiphilic polymer, and, A2) 50% by weight to 99.9% by weight (by (A) a graft polymer (A2) having a bimodal particle size distribution and consisting of (A2): "3) 4% by weight to 90% by weight of the elastomeric particulate graft matrix (a3) , which is obtained by polymerizing the following materials, in terms of (a3): a31) 70% by weight to 1% by weight of at least one conjugated diene, or at least one C-C8 ester of acrylate, or a mixture thereof, a32) 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, and a33) 0 to 10% by weight of at least one polyfunctional crosslinking monomer; a4) 1 〇% by weight to 60% by weight 〇/0 is a graft (a4) consisting of τ to 里/〇田 below, in terms of (a4): a4 1) 65 wt% to 95 wt% at least _ yang 7 than 甘朴里王·v Vinyl aromatic monomer, 130449.doc 200906947 a42) 5 wt% to 35 wt% propylene guess, a43) a44) species of mono-unsaturated monomers, and polyfunctional cross-linking monomers; 30% by weight at least - 〇 to 10% by weight at least one B) 20% by weight to 95% by weight of the heat ml/g to 120 ml/g of the viscosity value vn, calculated as: plastic polymer (B) having 5 〇 and The following composition is composed of (B) bl) b2) 64 weight. / 〇 to 81 weight 〇 / 〇 to small ^ 至 — - a vinyl aromatic monomer 19% by weight to 36% by weight of acrylonitrile, and b3) 0 to 30% by weight of at least one other monoethylenically unsaturated monomer C) 〇 to 50% by weight of thermoplastic polymer (c) having a viscosity value VN of μ·mrm/g, and consisting of the following components in (c): cl) 62% by weight to 81 〇 / „ 5 / 卜垔 ® / 〇 at least one vinyl aromatic monomer, c2) 19% by weight to 38% by weight of acrylonitrile, and c3) 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, The viscosity values VN of the components (B) and (C) differ by at least 5 units (mi/illusion, or the acrylonitrile content differs by at least 5 units (% by weight), or the viscosity value (4) and the acrylonitrile content. The characteristic difference is at least 5 units, and D) 〇 to 50% by weight of the thermoplastic polymer (1) consisting of the following: (D): dl) 4 parts ❶ / 〇 to 96% by weight of at least one vinyl aryl a monomer, d2) 4 wt / 〇 to 96 wt% from at least one monomer consisting of a group consisting of methacrylic acid methacrylate 'maleic anhydride and maleimide, D3) 〇 to 50% by weight of acrylonitrile, wherein (D) is different from (B) and (C) if present; 130449.doc 200906947 E) 〇 to 8〇% by weight of amorphous or (semi)-crystalline polymer, And F) 〇 to 50% by weight of additive (ρ).

如上所述，已知組合物不能滿足當前所有工業需要。需要滿足當前需要，且詳言之具有所需黏度及負栽量，且藉此可獲得聚烯烴之所需導電性之含CNT母體混合物Q 包含茂金屬聚丙烯蠟及CNT之母體混合物令人驚對地展示改良之特性。【發明内容】本發明提供組合物Z，其包含組份A及組份B，其中該組份A為滴點及/或軟化點為7〇°c至i3(rc之茂金屬聚丙烯蝶；且該組份B為CNT。組合物Z較佳為母體混合物mb或導電聚合物cp，其中該導電聚合物較佳為導電有機聚合物。基於本發明之目的，對由導電聚合物Cp製成之壓縮模製板量測的該導電聚合物CP之負載量·比表面電阻LSSR較佳小於或等於130 ’尤佳小於或等於12〇 ; LSSR各較佳上限之下限較佳為-15,000，尤佳為_1〇〇〇〇，尤其為_1〇〇〇，尤其為-100，極尤其為-10。此外’基於本發明之目的’對由導電聚合物Cp製成之平膜量測的該導電聚合物CPiLSSR較佳小於或等於53〇，尤佳小於或等於4〇〇，尤其小於或等於3〇〇，尤其小於或等於 250 ; LSSR各較佳上限之下限較佳為_15，⑻〇，尤佳為_1〇〇〇() ，尤其為-1,000，尤其為_100，極尤其為1()。 LSSR係藉由以下方法計算：將表面電阻（以歐姆度量）之 130449.doc -10- 200906947 絕對值以十為底之對數乘以導電聚合物Cp之cnt負載量 (以重量％計）之絕對值的二次方，其中重量°/。係以導電聚合物CP之總重量計。因此，例如，以壓製（壓縮模製）板之總重量計CNT負載量為3重量❶且表面電阻為丨丨歐姆之壓製（壓縮模製）板之LSSR為135。基於本發明之目的，茂金屬聚丙烯蠟為在作為催化劑之茂金屬存在下製備之聚丙烯蠟。茂金屬催化劑之特殊能力係用於合成具有選擇性及全新特性概況之新穎聚丙烯蠟。在不使用茂金屬催化劑的情況下，不可能精確地組合且控制聚丙烯蠟之熔點、黏度及分子量。此外’未使用茂金屬催化劑製備之習知聚丙烯蠟具有顯著高於13〇t：之滴點及/ 或軟化點。較佳茂金屬聚丙烯蠟具有在i 70〇c之溫度下量測之介於 4〇 mPa*s 至 80,000 mPa*s，較佳 45 爪以、至 35 〇㈧ mPa*s，尤佳50爪以〜至⑺⑽。mpa*s，尤其5〇至 7’000 mPa*s範圍内之黏度。黏度亦可根據蠟之性質在不同於17(rc之溫度下測定。較佳在聚丙烯躐之情況下，在均聚合蠛與共聚合蠘之情況下，黏度係在17(TC下測定；較佳在聚乙烯蠟之情況下，黏度係在140°C下測定。此外，茂金屬聚丙烯蠟之特徵在於與無茂金屬催化的情況下合成之習知蠟相比莫耳質量分布較窄。莫耳質量分布係由質量平均莫耳質量(Mw值[g/mo⑴及數量平均莫耳質量（Μη值[g/m〇i])表徵。 130449.doc 200906947 較佳地 ’ Μη 為 500 g/mol 至 50,〇〇〇 g/m〇i，更佳 ι,000 g/mol 至 35,000 g/mol，甚至更佳 uoo g/m〇1 至 25〇〇〇 g/mol ° 較佳地 ’ Mw為 1,000 g/mol至 140,000 g/m〇i，更佳 ι,9〇〇 g/mol 至 100,000 g/mol，甚至更佳 21〇〇 g/m〇1 至 7〇〇〇〇 g/mol。較佳地，Mw除以Μη，在下文中稱為Mw/Mn值，較佳為 1.0至3.0，更佳為1.5至2_9，甚至更佳為丨_7至2.8 ;尤其為 2_1至2.7’更尤其為2.2至2.5;而在習知非茂金屬催化之蠟的情況下’ Mw/Mn值為至少3.1且可高達7或8。較佳茂金屬聚丙稀堰為基於丙稀之均聚合蝶或共聚合蝶。茂金屬共聚物蝶較佳衍生自丙稀與至少一個、較佳— 個、兩個或三個’更佳一個不同於丙烯之丨_烯烴Ra_ CH=CH2，更佳衍生自丙烯與乙烯；其中以為非分支鏈或分支鏈烷基。此外’在作為催化劑之茂金屬存在下製備之茂金屬聚丙烯蠛較佳為丙烯及〇· 1重量％至5〇重量％乙稀及/或〇〗重量％至50重量％至少一種具有4至2〇個碳原子之分支鏈或非分支鏈1-烯烴之共聚物蠟，更佳為丙烯及〇」重量％至5〇重量 %乙稀之共聚物蠟；其中重量％係以原料之總量計，且該等茂金屬聚丙烯蠟具有介於7〇°C至130T：範圍内之滴點及/ 或軟化點。更佳地，乙烯係以1重量％至4〇重量％，甚至更佳3重量％至3〇重量％之量使用；其中重量0/〇係以原料之總量’亦即烯烴之總量計。 130449.doc •12· 200906947 較佳茂金屬聚丙烯蠟具有851至丨〇〇。〇之滴點。較佳茂金屬聚丙烯蠟具有85 〇c至i 〇〇。〇之軟化點。更佳地’茂金屬聚丙烯蠟具有在17(TC之溫度下量測之 "於40 !^34至1〇〇〇〇 mPa*sK圍内之黏度及7〇它至13〇它之滴點，或70°c至130°C之軟化點。茂金屬聚丙烯蠟在170〇c下之黏度決定測定滴點或軟化點：較佳地，低於約1，5〇〇1111^*8之黏度，測定滴點，且在 1’500 mPa*s或高於丨，5〇〇 mPa*s之黏度情況下，測定軟化點。在作為催化劑之茂金屬存在下製備之茂金屬聚丙烯蠟較佳报大程度上或完全為非晶形且若需要可另外經改質以使其具有極性。出於本發明之目的，很大程度上意謂超過8〇重ΐ %，較佳超過9〇重量％，尤其超過95重量％，尤其超過99重量％ ’在各種情況下重量％係以蠟之總重量計。茂金屬聚丙烯蠟係使用式（I)之茂金屬化合物製備。 i, R1 R3 Μ1 ① R2 R4 該式包涵式（Ia)之化合物， 130449.doc •13- 200906947As noted above, known compositions do not meet all current industrial needs. It is necessary to meet the current needs, and in detail the CNT-containing precursor mixture Q having the desired viscosity and load, and thereby obtaining the desired conductivity of the polyolefin, comprising a metallocene polypropylene wax and a matrix mixture of CNTs. Show the improved features to the ground. SUMMARY OF THE INVENTION The present invention provides a composition Z comprising component A and component B, wherein the component A is a dropping point and / or softening point of 7 ° ° c to i3 (rc metallocene polypropylene butterfly; And the component B is a CNT. The composition Z is preferably a precursor mixture mb or a conductive polymer cp, wherein the conductive polymer is preferably a conductive organic polymer. For the purpose of the present invention, the conductive polymer Cp is made. The load of the conductive polymer CP measured by the compression molding plate and the specific surface resistance LSSR is preferably less than or equal to 130 ', preferably less than or equal to 12 〇; the lower limit of each preferred upper limit of the LSSR is preferably -15,000. Preferably, it is _1 〇〇〇〇, especially _1 〇〇〇, especially -100, very especially -10. Further, for the purpose of the present invention, the measurement of the flat film made of the conductive polymer Cp is carried out. The conductive polymer CPiLSSR is preferably less than or equal to 53 〇, particularly preferably less than or equal to 4 〇〇, especially less than or equal to 3 〇〇, especially less than or equal to 250; the lower limit of each preferred upper limit of the LSSR is preferably _15, (8) 〇, especially good is _1〇〇〇(), especially -1,000, especially _100, especially 1 (). LSSR Calculated by multiplying the surface resistance (in ohms) 130449.doc -10- 200906947 absolute value by the base 10 logarithm of the conductive polymer Cp by the cnt loading (in % by weight) The square, wherein the weight is based on the total weight of the conductive polymer CP. Thus, for example, the CNT loading is 3 weights and the surface resistance is 丨丨 ohms based on the total weight of the pressed (compression molded) sheet. The LSSR of the pressed (compression molded) sheet is 135. For the purpose of the present invention, the metallocene polypropylene wax is a polypropylene wax prepared in the presence of a metallocene as a catalyst. The special ability of the metallocene catalyst is used for synthesis. Novel polypropylene waxes with an optional and novel character profile. Without the use of metallocene catalysts, it is not possible to accurately combine and control the melting point, viscosity and molecular weight of polypropylene waxes. In addition, conventional polypropylenes prepared without metallocene catalysts The wax has a drop point and/or softening point significantly higher than 13 〇t: The preferred metallocene polypropylene wax has a temperature between 4 〇 mPa*s and 80,000 measured at a temperature of i 70 〇c. mPa*s, preferably 45 claws, up to 35 〇 (eight) mPa*s, especially good 50 claws with ~ to (7) (10).mpa*s, especially in the range of 5 〇 to 7'000 mPa*s. Viscosity can also be The properties of the wax are determined at a temperature different from 17 (rc). Preferably, in the case of polypropylene crucible, in the case of homopolymerization of rhodium and copolymerization, the viscosity is determined at 17 (TC); preferably in polyethylene. In the case of wax, the viscosity is measured at 140 ° C. Further, the metallocene polypropylene wax is characterized in that the mass distribution of the mole is narrower than that of the conventional wax synthesized without metallocene catalysis. The molar mass distribution is characterized by mass average molar mass (Mw value [g/mo (1) and number average molar mass (Μη value [g/m〇i]). 130449.doc 200906947 Preferably 'Μη is 500 g/ Mol to 50, 〇〇〇g/m〇i, more preferably ι,000 g/mol to 35,000 g/mol, even more preferably uoo g/m 〇1 to 25 〇〇〇g/mol ° preferably ' Mw It is from 1,000 g/mol to 140,000 g/m〇i, more preferably ι, from 9〇〇g/mol to 100,000 g/mol, even more preferably from 21〇〇g/m〇1 to 7〇〇〇〇g/mol. Preferably, Mw is divided by Μη, hereinafter referred to as Mw/Mn value, preferably from 1.0 to 3.0, more preferably from 1.5 to 2-9, even more preferably from 丨7 to 2.8; especially from 2_1 to 2.7'. It is 2.2 to 2.5; and in the case of a conventional non-metallocene-catalyzed wax, the 'Mw/Mn value is at least 3.1 and can be as high as 7 or 8. The preferred metallocene polypropylene is a propylene-based homopolymer butterfly or a total of The polymeric butterfly. The metallocene copolymer butterfly is preferably derived from propylene and at least one, preferably one, two or three 'more preferably one different from propylene olefin _Ra_ CH=CH2, more preferably derived from propylene and Ethylene; which is considered to be non-branched or branched Further, the metallocene polypropylene oxime prepared in the presence of a metallocene as a catalyst is preferably propylene and 〇·1% by weight to 5% by weight of ethylene and/or 〇% by weight to 50% by weight. a copolymer wax having a branched or unbranched chain 1-olefin of 4 to 2 carbon atoms, more preferably a copolymer wax of propylene and hydrazine in an amount of 5% by weight to 5% by weight of ethylene; The total amount of the raw materials, and the metallocene polypropylene wax has a dropping point and/or a softening point in the range of from 7 ° C to 130 T: more preferably, the ethylene is from 1% by weight to 4 % by weight. , even more preferably used in an amount of 3% by weight to 3% by weight; wherein the weight 0/〇 is based on the total amount of the raw materials 'that is, the total amount of olefins. 130449.doc •12· 200906947 Preferred metallocene polypropylene wax It has a dropping point of 851 to 丨〇〇. The preferred metallocene polypropylene wax has a softening point of 85 〇c to i 〇〇. The metallocene polypropylene wax has a temperature of 17 (TC). Measure the viscosity in the range of 40 !^34 to 1〇〇〇〇mPa*sK and 7〇 to 13〇, the drop point, or 70° The softening point of c to 130 ° C. The viscosity of the metallocene polypropylene wax at 170 ° C determines the drop point or softening point: preferably, the viscosity is less than about 1,5 〇〇 1111 ^ * 8 Point and measure the softening point at a viscosity of 1'500 mPa*s or higher than 丨, 5〇〇mPa*s. The metallocene polypropylene wax prepared in the presence of a metallocene as a catalyst is more or less amorphous to the extent and may be additionally modified to impart polarity if desired. For the purposes of the present invention, it is meant to a large extent that it exceeds 8 〇 ΐ %, preferably more than 9% by weight, in particular more than 95% by weight, in particular more than 99% by weight 'in each case the weight % is waxed Total weight. Metallocene polypropylene waxes are prepared using metallocene compounds of formula (I). i, R1 R3 Μ1 1 R2 R4 This formula contains the compound of formula (Ia), 130449.doc •13- 200906947

式（lb)之化合物，a compound of formula (lb),

及式（Ic)之化合物And a compound of formula (Ic)

130449.doc • 14· 200906947 在式⑴、⑽及（Ib)中，Ml為元素週期表第IVb、Vb或倾族金屬，車交佳為欽、鍅、給、飢、銳、组、絡、翻、鎢，尤佳為鈦、锆、铪。130449.doc • 14· 200906947 In formulas (1), (10) and (Ib), Ml is the IVb, Vb or the inversion metal of the periodic table, and the car is good for Qin, 鍅, give, hunger, sharp, group, network, Turning, tungsten, especially preferably titanium, zirconium, hafnium.

R1及R2相同或不同且各自彼此獨立地為氫原子；CA。烧基，較佳Cl-c3烧基，尤其甲基；c】_Ci〇烧氧基，較佳 CVC3烷氧基；c6_Cl()芳基，較佳C6_C8芳基；芳基氧基’較佳以芳基氧基；C2_Ci。烯基，較佳C2_C4烯基； CVC4〇芳基烷基，較佳C7_Ci〇芳基烷基；院基芳基，較佳C7_c12烧基+基；c8_C4。芳基烯基，較佳芳基稀基；或齒素原子，較佳氣原子。 R及R4相同或w且各自彼此獨立地為單環或多環煙基，其與中心原子M1 一起可形成夾層結構。R3及R4較佳為環戊二烯基、節基、四氫節基、苯并節基或第基，其中基本骨架可帶有其他取代基或彼此橋接。此外，基團RW 中之一者可為經取代之氮原子，其中R24具有R1?之含義中之一者且較佳為甲基、第三丁基或環己基。 R 、R、R、R、R9及R】0相同或不同且各自彼此獨立地為氫原子；鹵素原子，較佳氟、氣或溴原子；Ci_c^烷基’較佳Cl-c4烧基；c6_Cl0芳基，較佳c6_C8芳基；Ci_“ 烧氧基’較佳 C〗-C3烷氧基；_NR162、_SRl6、_〇siRl63、 -SiR163或-PR162基團，《中Rl6為Ci_Ci〇烧基，較佳Ci_c3院基，或C6-C1()芳基，較佳cvc：8芳基，或在含Si_或p_基團之情況下亦可為函素原子’較佳為氣原？；或兩個鄰接基團 R5、R6、R7、R8、R9或Ri〇與連接其之碳原子一起形成 130449.doc -15- 200906947 環。尤佳配位基為基本骨架環戊二烯基、茚基、四氫節基、苯并茚基或雖基之經取代化合物。 R13為R1 and R2 are the same or different and each independently of each other is a hydrogen atom; CA. An alkyl group, preferably a Cl-c3 alkyl group, especially a methyl group; c] _Ci oxime alkoxy group, preferably a CVC3 alkoxy group; a c6_Cl() aryl group, preferably a C6_C8 aryl group; an aryloxy group is preferably Aryloxy; C2_Ci. Alkenyl, preferably C2_C4 alkenyl; CVC4 fluorenylalkyl, preferably C7_Ci arylalkyl; aryl, preferably C7_c12 alkyl + yl; c8_C4. An arylalkenyl group, preferably an aryl group; or a dentate atom, preferably a gas atom. R and R4 are the same or w and are each independently of each other a monocyclic or polycyclic nicotine group which together with the central atom M1 can form a sandwich structure. R3 and R4 are preferably a cyclopentadienyl group, a benzyl group, a tetrahydrobenzyl group, a benzo-p-mental group or a group, wherein the basic skeleton may have other substituents or be bridged to each other. Further, one of the groups RW may be a substituted nitrogen atom, wherein R24 has one of the meanings of R1? and is preferably a methyl group, a tert-butyl group or a cyclohexyl group. R, R, R, R, R9 and R] 0 are the same or different and are each independently a hydrogen atom; a halogen atom, preferably a fluorine, gas or bromine atom; a Ci_c^alkyl group preferably a Cl-c4 alkyl group; C6_Cl0 aryl, preferably c6_C8 aryl; Ci_"alkoxy" preferably C-C3 alkoxy; _NR162, _SRl6, _〇siRl63, -SiR163 or -PR162 group, "中Rl6 is Ci_Ci 〇 Preferably, Ci_c3, or C6-C1() aryl, preferably cvc:8 aryl, or in the case of a Si- or p--containing group, may be a functional atom, preferably a gas source? Or two adjacent groups R5, R6, R7, R8, R9 or Ri〇 together with the carbon atom to which they are attached form a ring of 130449.doc -15-200906947. The especially preferred ligand is a basic skeleton cyclopentadienyl group, Mercapto, tetrahydroindenyl, benzofluorenyl or substituted compounds of the group. R13 is

R17—M2UR17-M2U

RR

^ —τ^ 7 _ 8 1 2 1 ‘ R —MIR R1IΜ2—R1 CR1 ο 7 一 8 12 1 R—M2— R Iο^ —τ^ 7 _ 8 1 2 1 ‘ R —MIR R1IΜ2—R1 CR1 ο 7 A 8 12 1 R—M2 — R Iο

:A1R :BR17 =NR17 17 R17 | R17 | R17 0-M2,— | 1 s —~M2— I 1 ~0—M2-— R18 1 R18 1 R18 、-Ge-、-Sn- 、-O-、-s- 、=so、 =so: ，'一 a 久 m 或不同且各自彼此獨立地為氫原素原子，較佳氟氯或溴原子；（VCw烷基，較佳Ci_C4烷基，尤其甲基 CVC〗。氟烷基，較佳CF3基團；C6_Ci〇氟芳基，較佳五氣基；C6-Cl0芳基，較佳c6_c8芳基；Ci_Ci〇烧氧基，較佳< C：4燒氧基，尤其甲氧基；C2_Ci〇烯基，較佳締基 c7-c4G芳烧基’較佳C7_CiG芳院基；C8_c4G芳基烯基，車1 CVC12芳基_ ; g7_c4〇烧基芳基，較佳C7A貌基基’駐17及R】8或及R、連接其之原子一起形成= M2為矽、鍺或錫，較佳為矽或鍺。 =GeR17R1; R13較佳為=CR17R18、、=SO、=PR17 或=P(〇)r17。 130449.doc • 16 - 200906947 -耆。，其1ί7:A1R :BR17 =NR17 17 R17 | R17 | R17 0-M2, — | 1 s —~M2— I 1 ~0—M2-— R18 1 R18 1 R18 , —Ge—, —Sn- , —O—, -s-, =so, =so: , 'a a long or different and each independently of each other is a hydrogen atom, preferably a chlorofluoro or bromine atom; (VCw alkyl, preferably Ci_C4 alkyl, especially A Base CVC. Fluoroalkyl, preferably CF3 group; C6_Ci〇fluoroaryl, preferably pentylene; C6-Cl0 aryl, preferably c6_c8 aryl; Ci_Ci oxime, preferably < C: 4 alkoxy, especially methoxy; C2_Ci decenyl, preferably phenyl c7-c4G aryl ketone 'preferably C7_CiG aryl base; C8_c4G arylalkenyl, car 1 CVC12 aryl _; g7_c4 decyl An aryl group, preferably a C7A top group 'in 17 and R} 8 or a combination of R and an atom to which it is bonded = M2 is ruthenium, osmium or tin, preferably ruthenium or osmium. =GeR17R1; R13 is preferably = CR17R18, , =SO, =PR17 or =P(〇)r17. 130449.doc • 16 - 200906947 -耆., its 1ί7

Rn及R12相同或不同且獨立地具有r17之含義中之讀11相同或不同且各自為〇、1或2,較佳為〇戒1 m加上11為〇、1或2，較佳為0或1。 R及R2相同或不同且獨一者。立地具有R17及R18之含義中之較佳茂金屬為：雙（1，2,3·二f基環戊二烯基）二氯化錯 •雙(U，4-三甲基環戊二烯基)二氯化鍅 •雙(1，2-二甲基環戊二烯基)二氯化鍅 •雙（1，3-二甲基環戊二烯基）二氯化錯 •雙（1-甲基節基）二氣化錯 •雙（1-正丁基-3-甲基環戊二烯基）二氣化锆 •雙（2-曱基-4,6-二-異丙基節基）二氣化鍅 •雙（2-甲基節基）二氣化錯 •雙（4-甲基節基）二氣化鍅 •雙（5-甲基節基）二氣化锆 •雙（院基環戊二烯基）二氣化锆 •雙（烷基茚基）二氣化锆 •雙（環戊二烯基）二氯化錘 •雙（節基）二氯化錯 •雙（甲基環戊二烯基）二氯化鍅 •雙（正丁基環戊二烯基）二氯化鍅 •雙（十八基環戊二烯基）二氯化鍅 •雙（五甲基環戊二烯基）二氣化鍅 130449.doc 17· 200906947 •雙（三甲基矽烷基環戊二烯基）二氣化鍅 •雙環戊二烯基二苯甲基锆 •雙環戊二烯基二甲基鍅 •雙四氫茚基二氣化鍅 •二甲基石夕烧基-9-第基環戊二缚基二氯化錯 •二甲基矽烷基雙-l-(2,3,5-三曱基環戊二烯基）二氣化鍅 . •二甲基矽烷基雙4-(14-二甲基環戊二烯基）二氯化鍅 •二甲基矽烷基雙-1-(2-甲基-4,5-苯并節基）二氯化锆 •二甲基石夕炫•基雙-1-(2-甲基-4-乙基節基）二氯化錯 •二甲基矽烷基雙“-(2-甲基-4-異丙基節基）二氣化鍅 •二甲基矽烷基雙-1-(2-曱基-4-苯基節基）二氣化锆 •二甲基石夕烧基雙-1-(2-曱基茚基）二氣化錯 •二甲基石夕烧基雙-1-(2-甲基四氫節基）二氣化銘 •二甲基矽烷基雙-1-節基二氣化鍅 •二曱基矽烷基雙-1-茚基二曱基鍅 •二曱基矽烷基雙-1-四氫節基二氣化鍅 J ' I •二苯基亞曱基-9-第基環戊二烯基二氯化錯 •二苯基矽烷基雙-1-節基二氯化錯 •伸乙基雙-1-(2-甲基-4,5-苯并茚基）二氯化鍅 • •伸乙基雙-1-(2-甲基-4-苯基茚基）二氣化錯 •伸乙基雙-1-(2-甲基四氫茚基）二氣化錯 •伸乙基雙-l-(4,7-二甲基茚基）二氯化錯 •伸乙基雙-1-茚基二氯化鍅 •伸乙基雙-1-四氫茚基二氣化鍅 130449.doc -18· 200906947 •茚基環戊二烯基二氣化锆 •亞異丙基（1-節基）（環戊二烯基）二氣化鍅 •亞異丙基（9-萬基）（環戊二烯基）二氣化锆 •苯基甲基矽烷基雙_1_(2_甲基茚基）二氣化鍅以及該等茂金屬二氯化物之烷基或芳基衍生物。使用合適輔催化劑以活化單一活性中心催化劑系統。式 (I)之茂金屬之合適輔催化劑為有機鋁化合物，尤其鋁氧烷，或無鋁系統，諸如 R2〇xNH4 xBR214、R2〇xpH4 χΒΚ2ΐ4、 R 3CBR 4或br2、。在該等式中，χ為1至4，基團r20相同或不同，較佳相同，且各自彼此獨立地為Ci_Ci〇烷基或C6_ Cu芳基，或兩個基團R2〇與連接其之原子一起形成環，且基團R相同或不同，較佳相同，且各自彼此獨立地為玎經烷基、鹵烷基或氟取代之C6_Ci8芳基。詳言之，R2〇為乙基丙基、丁基或苯基，且R21為苯基、五氟苯基、3,5-雙三氣甲基苯基、均三甲苯基、二曱苯基或甲苯基。此外，經常需要第三組份以保持針對極性催化劑毒害之保羞It如二乙基鋁、三丁基鋁及其他者之有機鋁化合物以及該等化合物之混合物適合於此目的。視方法而定，亦可使用擔持型單一活性中心催化劑。較產物中擔持材料及輔催化劑之殘餘含量不超過1 〇〇 Ppm之濃度的催化劑系統。茂金屬聚丙烯蠟為已知物質，其可根據即切M2…或 EP 384 264 A1 製備。較隹茂金屬聚丙熵磯歸％係藉由使用茂金屬催化劑二甲基矽 130449.doc 19 200906947 烷基雙茚基二氯化锆，根據EP 384 264 A中所報導之方法，詳言之根據實例1至16之方法使丙烯與乙烯共聚合來製備。其可以精細微粒狀態使用，較佳經喷灑或碾磨，或呈顆粒形式。此外，較佳為滴點及/或軟化點為70°C至130°C之接枝茂金屬聚丙烯蠟。較佳接枝茂金屬聚丙烯蠟為以所用原料之總重量計以0.5重量％至10重量％順丁烯二酸酐改質之茂金屬聚丙烯蠟。組份A較佳包含1、2、3或4種不同茂金屬聚丙烯蠟，更佳包含1或2種茂金屬聚丙烯蝶且甚至更佳包含1種茂金屬聚丙烯躐。較佳CNT為單壁碳奈米管（SWCNT)或多壁碳奈米管 (MWCNT)，其中 MWCNT較佳。除非另外指明，否則質量-比表面積係由使用氮根據 ASTM D3037 量測之 Brunauer Emmet Teller (BET)吸附測定；該表面積將在下文中稱為BET表面積。較佳 CNT具有 50 m2/g至 1000 m2/g，尤佳 200 m2/g至600 m2/g，尤其 25 0 m2/g至 5 60 m2/g之 BET表面積。較佳為具有由2至50個碳層，尤其3至15個碳層構成之壁結構之MWCNT。較佳MWCNT具有1 nm至500 nm，尤佳2 nm至1 00 nm，尤其3 nm至60 nm，尤其3 nm至20 nm之平均外徑（定義為數量分布之中值）。 130449.doc -20- 200906947 存在多種技術及方法產生CNT，該等技術及方法因產生方法不同或催化劑粒子不同而不同。此使得（尤其）cnt中催化劑殘餘含量不同。較佳為殘餘催化劑含量為20重量％或低於2〇重量％，尤佳8重量％或低於8重量％，尤其5重量％或低於5重量％，尤其3重量％或低於3重量％之咖，其中在各種情況下重量％係以CNT之總重量計。較佳為W02006/050903 A中所揭示之CNT且其可藉由該文獻中所揭示之方法獲得。因此該文獻之揭示内容，尤其描述所揭不之產生碳奈米管之方法的技術特徵及可藉由該方法獲得之碳奈米管的請求項丨至1〇以引用的方式明確地併入本文中。因此尤佳為可藉由經非均相催化劑分解氣態烴而獲得之 CNT，該非均相催化劑包含Mn、Co及擔持材料，其中c〇及Mn係以金屬形式以活性組份之總含量計以2莫耳％至98 莫耳％之量存在，且視情況該非均相催化劑另外含有Mo ; 尤佳亦為主直徑為3 11111至15〇 nm且使用該催化劑產生之碳奈米官；其中個別或混合物形式之輕烴（諸如脂族烴及烯烴）較佳用作原料，且該方法較佳連續或分批進行，其基於催化劑之引入及所形成之碳奈米管隨廢催化劑之排出；且較佳將催化劑以主要催化活性組份以氧化物，部分還原或完全還原，或氫氧化物形式存在之形式引入反應空間中。該方法之更多細節可見於w〇2〇〇6/〇5〇9〇3 A之說明書中。尤其，以此方式產生之該等碳奈米管令人驚訝地使得 130449.doc -21 - 200906947 產生：有低黏度且同時具有高負載量之組合物z;聚烯烴中獲得所需f電性；且聚烯烴之表面電阻較低成為可能。車乂佳使用α聚烯μ《乙稀·乙酸乙烯g旨#聚物塗佈之 CNT。該塗層較佳藉由原位聚合塗覆。尤佳為以聚乙烯及聚丙烯’尤其聚乙烯塗佈之MWCNT。較佳使用藉由改質或活化表面而成易於分散之CNT。 CNT之尤佳表面處理係藉助於電漿或γ輻射，其中極佳為電漿處理之MWCNT。 CNT可較佳自 Mitsui、Arkema、Nan〇cyl、Th〇mas Swan & Co Ltd.、CNI及尤其 Bayer Material Science AG公司獲得。對於組份B，較佳使用一種類型之cnt，但亦可使用多種CNT ’較佳1、2或3種，尤其1或2種不同CNT。此外’ CNT與導電碳黑及/或石墨之組合或混合物亦可用作組份B。較佳導電碳黑具有根據ASTM D2414量測之1〇〇 mi/i00 g 至 500 ml/100 g’ 尤佳 i5〇 ml/100 g 至 400 ml/100 g，尤其 170 ml/100 g至 3 50 ml/100 g之吸油值（OAN)。較佳導電碳黑具有3〇 mVg至2,000 m2/g，尤佳50 m2/g至 1,5 00 m2/g ’ 尤其 60 m2/g至 1，250 m2/g之 BET表面積。導電碳黑可較佳自 Cabot、Phelps Dodge、Timcal、 Degussa及Akzo公司獲得。較佳石墨具有根據DIN 53601量測之30 g至300 g鄰苯二甲酸二丁酯（DBP)/l〇〇 g，尤佳40 g至 170 g DBP/100 g ’ 尤 130449.doc •22- 200906947 其50 g至 150 g DBP/100 g 的 DBp吸油值。較佳石墨具有Ο」m2/g至50 m2/g，尤佳1 m2/g至40 m /g，尤其1.5 m2/g至3〇 m2/g之BET表面積。可使用天然存在之石墨及合成產生之石墨。石墨可較佳自 Timed ' SGL Carbon 或 Nationale de Graphite公司獲得。 CNT與導電碳黑之重量比較佳為1:99至99:1 ,尤佳為 1:19至 19:1，尤其為 1:9至1:1。 CNT與石墨之重量比較佳為1:99至99:1，尤佳為丨：9〇至 90:1，尤其為 1:85至 1:1。較佳地，組合物Z含有50重量。/❶至9〇重量％，更佳6〇重量 %至85重量％，甚至更佳65重量％至8〇重量％之石墨，重量 /W糸以總组合物z之重量計。當使用CNT、碳黑及石墨時，導電碳黑與石墨之重量比較佳為1:99至99:1，尤佳為1:4〇至4〇:1，尤其為丨2〇至 1:1。組份B尤佳含有CNT與石墨二者。組份B尤佳僅含有CNT，而無石墨及/或碳黑。組合物Z中之組份A與組份B之重量比較佳為至 99:1 ’尤佳為1:90至90:1，尤其為1:85至85:1。當組份B不含有石墨及/或碳黑時，組合物乙中之組份a 與組份B之重量比較佳為1:1至1:5〇，尤佳為丨丨至丨_，尤其為1:1至1:35。當組份B除含CNT之外，亦含有石墨及/或碳黑時，^ 130449.doc •23· 200906947 物Z中之組份A與組份B之重量比較佳為1:1至ι:99，尤佳為 1:1 至 1:90，尤其為 1:1 至 1:85。組合物Z較佳含有分散劑作為其他組份c。尤佳分散劑為長鏈醇之極性酸酯，尤其為烧基績酸酯、新烷氧基鈦酸醋、新烷氧基錘酸醋、單烷氧基鈦酸醋、單烷氧基锆酸酯，且尤其為烷基磺酸鈉及此處烷基磺酸鈉。組合物Z較佳含有極性或非極性非茂金屬聚烯烴蠟或不同於滴點及/或軟化點為7(rc至13(rc之茂金屬聚丙烯蠟之茂金屬聚烯烴蠟，或兩種、三種、四種或五種極性及/或非極性非茂金屬聚烯烴蠟或不同於滴點及/或軟化點為70它至130C之茂金屬聚丙烯蠟之茂金屬聚烯烴蠟的混合物作為其他組份D。非茂金屬聚烯烴蠟為使用不為茂金屬催化劑之催化劑產生之聚稀烴蟻。幸乂佳非汶金屬聚烯垣蟻為乙烯或具有3至1〇個碳原子之高碳1-烯烴之均聚物或其彼此之間的共聚物。較佳為丨或2 種極性及/或非極性非茂金屬聚烯烴蠟或1或2種不同於滴點及/或軟化點為7(TC至13(TC之茂金屬聚丙烯蠟之茂金屬聚烯烴蠟。當非茂金屬聚烯烴蠟或不同於滴點及/或軟化點為7〇〇c 至13〇C之茂金屬聚丙烯壞的茂金屬聚烯烴躐用作組份d 蛉，尤佳使用1種滴點及/或軟化點為川它至丨㈤它之茂金屬聚丙烯蠟作為組份A，及丨種非茂金屬聚烯烴蠟或丨種不同於滴點及/或軟化點為7(TC至13(rc之茂金屬聚丙烯蠟之茂 130449.doc •24- 200906947 金屬聚烯烴蠟作為組份D。不同於滴點及/或軟化點為70。〇至13〇。(：之茂金屬聚丙烯蠟之較佳茂金屬聚烯烴蠟係選自由茂金屬聚乙烯蠟及滴點或軟化點高於13(TC，更佳為135它至170〇C，甚至更佳為 140°C至170°C之茂金屬聚丙烯蠟組成之群。該等不同於滴點及/或軟化點為7〇。〇至13(rc之茂金屬聚丙烯蠟之茂金屬聚烯烴蠟亦可為接枝茂金屬聚烯烴蠟。較佳地’接枝係以所用原料之總重量計以〇5重量。/❶至1〇重量 %順丁烯二酸酐進行；更佳地，接枝係在茂金屬聚乙烯蠟上或在滴點或軟化點高於J 3〇〇c之茂金屬聚丙烯蠟上進行。較佳地，不同於滴點及/或軟化點為7〇〇c至n(rc之茂金屬聚丙烯蠟之茂金屬聚烯烴蠟具有500 g/mol至50,000 g/m〇1，更佳 i，000 g/mol 至 35,000 g/m〇l，甚至更佳 11〇() g/mol至 25,000 g/m〇i2Mn。較佳地，不同於滴點及/或軟化點為7(rc至13〇。〇之茂金屬5^丙烯峨之戊金屬聚浠煙蠛具有1，〇〇〇 g/m〇l至1 〇〇〇 g/mol 更佳1，900 §/111〇1至 100,000 旦/111〇1，甚至更佳2，100 g/mo1 至 70,000 g/m〇i之 Mw。較佳地’在不同於滴點及/或軟化點為70。(：至130°C之茂金屬聚丙稀蠟之茂金屬聚稀烴蠟的情況下，Mw/Mn值較佳為1.0至3.0，更佳為1 5至2 9 ’甚至更佳為1 7至2.8 ;尤其為2.1至2.7;更尤其為2.2至2.5。非茂金屬聚稀烴蟻較佳具有介於丨，〇〇〇 g/m〇l至2〇,〇〇〇 130449.doc •25· 200906947 g/mol範圍内之重量平均莫耳質量Mw及/或介於500 g/mol 至15,000 g/mol範圍内之數量平均莫耳質量Mn。組份Α與組份D之重量比較佳為1〇:1至1:1〇，尤佳為4:i 至1:4，尤其為3:1至1:3。本發明另外提供除含有組份A及組份b之外亦含有有機聚合物組份P作為其他組份的組合物Z。組份P較佳選自由熱塑性縮聚物，尤佳熱塑性聚酯，尤其聚碳酸酯（PC)、聚對苯二甲酸丁二酯（PBT)及聚對苯二甲酸乙二酯（PET)組成之群。組份P較佳選自由苯乙烯聚合物，尤佳聚苯乙烯（ps)、苯乙烯-丙烯腈共聚物（SAN)、丙烯腈_聚丁二烯-苯乙烯接枝聚合物（ABS)及苯乙烯-乙烯-丁二烯-苯乙烯嵌段共聚物 (SEBS)組成之群。組份p較佳選自由聚醯胺’尤佳聚醯胺46 (PA46，聚醢胺 6/6t (PA6/6T))、聚醯胺6 (PA6)、聚醯胺 12 (PA12)及聚醯胺6.6 (PA6.6)組成之群。組伤P較佳選自由聚丙稀酸g旨（PMMA)組成之群，尤佳為聚甲基丙烯酸甲酯。組伤P較佳選自由聚縮酿組成之群，尤佳為聚曱路 (POM)。組伤P較佳選自由聚加合物組成之群，尤佳為熱塑性聚胺基甲酸酯彈性體（TPU)。組份P較佳選自由聚烯烴及聚烯烴共聚物組成之群。當組合物Z為導電聚合物CP時，組份P較佳為聚烯烴或 130449.doc -26- 200906947 聚烯烴共聚物。作為組份p之尤佳聚烯烴或聚烯烴共聚物係選自由以下各物組成之群： •聚乙烯（PE)，較佳高密度聚乙烯（HDPE)、中密度聚乙烯（MDPE)、低密度聚乙烯（LDPE)、線性低密度聚乙烯（LLDPE)、茂金屬低密度聚乙烯（mLDPE)及茂金屬線性低密度聚乙烯（mLLDPE)， •聚丙烯（PP)，較佳聚丙烯均聚物（PPH)、聚丙烯無規 ' 共聚物（PP-R)及聚丙烯嵌段共聚物（PP-嵌段-COPO)， •聚稀烴塑膝，較佳1-辛稀與乙稀之聚合物，及 • PE共聚物，較佳乙烯-乙酸乙烯酯共聚物（EVA)、乙烯與丙烯酸曱酯之共聚物（EMA)、乙烯與丙烯酸丁酯之共聚物（EBA)、乙烯與丙烯酸乙酯之共聚物（EEA)、環烯烴共聚物（COC); •尤佳選自由以下各物組成之群： • PE，較佳 HDPE、LDPE 及 LLDPE， ?· \ υ · PP，較佳 PPH、PP-R及PP-嵌段-COPO， •聚烯烴塑膠，較佳1-辛烯與乙烯之聚合物，及 • PE共聚物，較佳EVA及EMA。 - 組合物Z較佳含有熱塑性塑膠，尤其乙烯與丙烯酸甲酯之共聚物作為其他組份E。當欲產生含有選自由PC、 PBT、PET、PS、SAN、ABS、PA6 或 PA6.6 組成之群之聚合物作為組份P的組合物Z時，較佳使用組份E。Rn and R12 are the same or different and independently have the same or different read 11 in the meaning of r17 and each is 〇, 1 or 2, preferably 〇 or 1 m plus 11 is 〇, 1 or 2, preferably 0. Or 1. R and R2 are the same or different and unique. The preferred metallocenes having the meaning of R17 and R18 are: bis(1,2,3·dif-cyclopentadienyl) dichloro-d-bis(U,4-trimethylcyclopentadiene) Base) bismuth dichloride • bis(1,2-dimethylcyclopentadienyl) ruthenium dichloride • bis(1,3-dimethylcyclopentadienyl) dichloromethane • double (1) -Methyl group) Digastricization • Bis(1-n-butyl-3-methylcyclopentadienyl) disilicide zirconium • Bis(2-mercapto-4,6-di-isopropyl Dibasic) bismuth hydride • bis(2-methylnodal) digastrication • bis(4-methyl) bismuth hydride • bis(5-methyl) zirconia • Double (hospital cyclopentadienyl) disilicide zirconium • bis(alkyl fluorenyl) di-zirconium oxide • bis(cyclopentadienyl) dichloride hammer • double (nodal) dichloride Bis(methylcyclopentadienyl)iridium dichloride•bis(n-butylcyclopentadienyl)phosphonium dichloride•bis(octadecylcyclopentadienyl)phosphonium dichloride•double (five Methylcyclopentadienyl) bismuth hydride 130449.doc 17· 200906947 • bis(trimethyldecylcyclopentadienyl) di-vaporized bismuth • biscyclopentadienyl diphenyl Methyl zirconium • biscyclopentadienyl dimethyl hydrazine • bis tetrahydroindenyl bis gasified hydrazine • dimethyl sulphate-9-ylcyclopentane dimethyl dichloride • dimethyl decane Bis-l-(2,3,5-trimethylcyclopentadienyl) di-vaporized hydrazine. • Dimethyldecyl bis-4-(14-dimethylcyclopentadienyl) dichloride鍅•Dimethyldecyl bis-(2-methyl-4,5-benzo-p-)zirconium dichloride • dimethyl shi shi yun • bis-l-(2-methyl-4 -ethyl benzyl) dichloroindolyl dimethyl succinate "-(2-methyl-4-isopropyl) bismuth phthalate dimethyl dimethyl ketone Mercapto-4-phenyl nodal group) zirconium dichloride dimethyl oxalate bis-(2-mercapto fluorenyl) di-gasification error dimethyl sulphide double -1- (2-methyltetrahydrobenzyl) Digasification Ming•Dimethyldecyl bis-1-pyryldicarbonate 曱•Dimercaptoalkyl bis-diyl fluorenyl fluorene矽alkyl bis-1-tetrahydronoken 2 gasified hydrazine J ' I • diphenyl fluorenylene-9-dicyclopentadienyl dichloride • • diphenyl fluorenyl double -1- benzyl Dichloro-diethyl-di-(2-methyl-4,5-benzofluorenyl) dichloride鍅••Ethyl bis-(2-methyl-4-phenylindenyl) di-gasification-extension ethyl bis-(2-methyltetrahydroindenyl) digasification Ethyl bis-l-(4,7-dimethylindenyl) dichloride-extension ethyl bis-indenyl ruthenium dichloride • exoethyl bis-1-tetrahydroindenyl鍅130449.doc -18· 200906947 • Mercaptocyclopentadienyl di-zirconium oxide • isopropylidene (1-block) (cyclopentadienyl) di-vaporized hydrazine • isopropylidene (9 -Vanyl)(cyclopentadienyl)zirconium dihydride-phenylmethyl decyl bis-xyl-(2-methylindenyl) bismuth hydride and alkyl or aryl of the metallocene dichloride Base derivative. A suitable cocatalyst is used to activate a single active site catalyst system. Suitable cocatalysts for the metallocene of formula (I) are organoaluminum compounds, especially aluminoxanes, or aluminum-free systems such as R2〇xNH4 xBR214, R2〇xpH4 χΒΚ2ΐ4, R 3CBR 4 or br2. In the formula, χ is 1 to 4, and the groups r20 are the same or different, preferably the same, and each independently of one another is a Ci_Ci〇 alkyl group or a C6_Cu aryl group, or two groups R2〇 and a linking group thereof The atoms together form a ring, and the groups R are the same or different, preferably the same, and each independently of one another is a C6_Ci8 aryl group substituted with an alkyl group, a haloalkyl group or a fluorine. In particular, R2 is ethyl propyl, butyl or phenyl, and R21 is phenyl, pentafluorophenyl, 3,5-bistrimethylphenyl, mesitylene, diphenyl Or tolyl. In addition, a third component is often required to maintain the shame of the polar catalyst, such as diethylaluminum, tributylaluminum, and other organoaluminum compounds, as well as mixtures of such compounds, for this purpose. Depending on the method, a supported single active site catalyst can also be used. A catalyst system in which the residual content of the material and the cocatalyst in the product does not exceed a concentration of 1 〇〇 Ppm. Metallocene polypropylene waxes are known materials which can be prepared according to the instant cut M2... or EP 384 264 A1.隹金属系系藉藉藉藉藉 by using the metallocene catalyst dimethyl hydrazine 130449.doc 19 200906947 alkyl bis-indenyl zirconium dichloride, according to the method reported in EP 384 264 A, in detail The methods of Examples 1 to 16 were prepared by copolymerizing propylene with ethylene. It can be used in a fine particulate state, preferably by spraying or milling, or in the form of granules. Further, a grafted metallocene polypropylene wax having a dropping point and/or a softening point of 70 ° C to 130 ° C is preferred. Preferably, the graft metallocene polypropylene wax is a metallocene polypropylene wax modified with 0.5% by weight to 10% by weight of maleic anhydride based on the total weight of the raw materials used. Component A preferably comprises 1, 2, 3 or 4 different metallocene polypropylene waxes, more preferably 1 or 2 metallocene polypropylene butterflies and even more preferably 1 metallocene polypropylene fluorene. Preferably, the CNT is a single-walled carbon nanotube (SWCNT) or a multi-walled carbon nanotube (MWCNT), of which MWCNT is preferred. Unless otherwise indicated, the mass-specific surface area is determined by Brunauer Emmet Teller (BET) adsorption using nitrogen according to ASTM D3037; this surface area will be referred to hereinafter as the BET surface area. Preferably, the CNTs have a BET surface area of from 50 m2/g to 1000 m2/g, particularly preferably from 200 m2/g to 600 m2/g, especially from 25 0 m2/g to 5 60 m2/g. It is preferably a MWCNT having a wall structure composed of 2 to 50 carbon layers, particularly 3 to 15 carbon layers. Preferred MWCNTs have an average outer diameter (defined as the median value of the number distribution) from 1 nm to 500 nm, particularly preferably from 2 nm to 100 nm, especially from 3 nm to 60 nm, especially from 3 nm to 20 nm. 130449.doc -20- 200906947 There are a variety of techniques and methods for producing CNTs that differ by the method of production or by the different catalyst particles. This makes the (in particular) cnc residual catalyst content different. Preferably, the residual catalyst content is 20% by weight or less, more preferably 8% by weight or less, especially 5% by weight or less, especially 3% by weight or less % coffee, wherein in each case the weight % is based on the total weight of the CNT. The CNTs disclosed in WO2006/050903 A are preferred and are obtainable by the methods disclosed in the literature. Therefore, the disclosure of this document, in particular the technical features of the method for producing carbon nanotubes, and the claims of the carbon nanotubes obtainable by the method, are explicitly incorporated by reference. In this article. Therefore, it is particularly preferred that the CNT can be obtained by decomposing a gaseous hydrocarbon by a heterogeneous catalyst comprising Mn, Co and a supporting material, wherein c〇 and Mn are in a metal form based on the total content of the active component. It is present in an amount of from 2 mol% to 98 mol%, and optionally the heterogeneous catalyst further contains Mo; and particularly preferably a carbon nanomantle having a main diameter of 3 11111 to 15 〇 nm and using the catalyst; Light hydrocarbons (such as aliphatic hydrocarbons and olefins) in individual or mixtures are preferably used as starting materials, and the process is preferably carried out continuously or batchwise based on the introduction of the catalyst and the formation of the carbon nanotubes with the spent catalyst. And preferably, the catalyst is introduced into the reaction space in the form of a main catalytically active component in the form of an oxide, a partial reduction or a complete reduction, or a hydroxide. More details of this method can be found in the specification of w〇2〇〇6/〇5〇9〇3 A. In particular, the carbon nanotubes produced in this way surprisingly result in 130449.doc -21 - 200906947 producing: a composition z having a low viscosity and at the same time a high loading; obtaining the desired electrical properties in the polyolefin And the surface resistance of polyolefin is low. Che Yujia uses α-polyene μ “ethylene acetate-vinyl acetate g-polymer coated CNT. The coating is preferably applied by in situ polymerization. It is especially preferred to use MWCNT coated with polyethylene and polypropylene', especially polyethylene. It is preferred to use CNTs which are easily dispersed by modifying or activating the surface. A particularly preferred surface treatment for CNTs is by means of plasma or gamma radiation, of which MICCNTs are preferably plasma treated. CNTs are preferably obtained from Mitsui, Arkema, Nan〇cyl, Th〇mas Swan & Co Ltd., CNI and especially Bayer Material Science AG. For component B, one type of cnt is preferably used, but a plurality of CNTs can be used, preferably 1, 2 or 3, especially 1 or 2 different CNTs. Further, a combination or mixture of CNT and conductive carbon black and/or graphite can also be used as component B. Preferably, the conductive carbon black has a concentration of from 1 〇〇mi/i00 g to 500 ml/100 g' according to ASTM D2414, particularly preferably i5 〇ml/100 g to 400 ml/100 g, especially 170 ml/100 g to 3 50 Oil absorption value (OAN) of ml/100 g. Preferably, the conductive carbon black has a BET surface area of from 3 mVg to 2,000 m2/g, particularly preferably from 50 m2/g to 1,500 m2/g', especially from 60 m2/g to 1,250 m2/g. Conductive carbon black is preferably obtained from Cabot, Phelps Dodge, Timcal, Degussa and Akzo. Preferred graphite has 30 g to 300 g of dibutyl phthalate (DBP) / l〇〇g, particularly preferably 40 g to 170 g DBP/100 g ', especially 130449.doc • 22- according to DIN 53601 200906947 DBp oil absorption value from 50 g to 150 g DBP/100 g. Preferably, the graphite has a BET surface area of from m2/g to 50 m2/g, particularly preferably from 1 m2/g to 40 m/g, especially from 1.5 m2/g to 3 〇 m2/g. Naturally occurring graphite and synthetically produced graphite can be used. Graphite is preferably obtained from Timed 'SGL Carbon or Nationale de Graphite. The weight of the CNT and the conductive carbon black is preferably from 1:99 to 99:1, particularly preferably from 1:19 to 19:1, especially from 1:9 to 1:1. The weight of CNT and graphite is preferably from 1:99 to 99:1, more preferably from 9:90 to 90:1, especially from 1:85 to 1:1. Preferably, composition Z contains 50 weights. /❶ to 9 wt%, more preferably 6 wt% to 85 wt%, even more preferably 6 wt% to 8 wt% graphite, weight / W 糸 by weight of the total composition z. When CNT, carbon black and graphite are used, the weight of conductive carbon black and graphite is preferably 1:99 to 99:1, particularly preferably 1:4〇 to 4〇:1, especially 丨2〇 to 1:1. . Component B is particularly preferred to contain both CNT and graphite. Component B is particularly preferred to contain only CNTs and no graphite and/or carbon black. The weight of component A and component B in composition Z is preferably from 99:1 y, particularly preferably from 1:90 to 90:1, especially from 1:85 to 85:1. When component B does not contain graphite and/or carbon black, the weight of component a and component B in composition B is preferably from 1:1 to 1:5 〇, especially preferably from 丨丨 to 丨 _, especially It is 1:1 to 1:35. When component B contains graphite and/or carbon black in addition to CNT, ^ 130449.doc • 23· 200906947 The weight of component A and component B in Z is preferably 1:1 to ι: 99, especially preferably 1:1 to 1:90, especially 1:1 to 1:85. Composition Z preferably contains a dispersing agent as the other component c. The preferred dispersant is a polar acid ester of a long-chain alcohol, especially a calcined acid ester, a neoalkoxy titanic acid vinegar, a neoalkoxy oleic acid vinegar, a monoalkoxy titanic acid vinegar, a monoalkoxy zirconium. An acid ester, and especially sodium alkyl sulfonate and sodium alkyl sulfonate herein. Composition Z preferably contains a polar or non-polar non-metallocene polyolefin wax or a metallocene polyolefin wax having a dropping point and/or a softening point of 7 (rc to 13 (rc metallocene polypropylene wax, or both) , a mixture of three, four or five polar and/or non-polar non-metallocene polyolefin waxes or a metallocene polyolefin wax different from the metallocene polypropylene wax having a dropping point and/or a softening point of from 70 to 130C Other component D. The non-metallocene polyolefin wax is a polyolefin ant which is produced using a catalyst which is not a metallocene catalyst. Fortunately, the carbaryl olefin is ethylene or has a carbon atom of 3 to 1 〇. a homopolymer of carbon 1-olefin or a copolymer thereof. Preferably, it is or two polar and/or non-polar non-metallocene polyolefin waxes or one or two different from the dropping point and/or softening point. 7 (TC to 13 (TC metallocene polypropylene wax metallocene polyolefin wax. When non-metallocene polyolefin wax or metallocene different from dropping point and / or softening point of 7〇〇c to 13〇C) Polypropylene bad metallocene polyolefin 躐 is used as component d 蛉, especially using a drop point and / or softening point for it to 丨 (5) it Metallocene polypropylene wax as component A, and bismuth non-metallocene polyolefin wax or bismuth species different from dropping point and / or softening point is 7 (TC to 13 (rc metallocene polypropylene wax ruthenium 130449.doc • 24-200906947 Metallic polyolefin wax as component D. Different from dropping point and/or softening point of 70. 〇 to 13〇. (: The preferred metallocene polyolefin wax of metallocene polypropylene wax is selected from Metal polyethylene wax and a group of metallocene polypropylene waxes having a dropping point or softening point higher than 13 (TC, more preferably 135 to 170 ° C, even more preferably 140 ° C to 170 ° C. The dropping point and/or the softening point is 7 〇. 〇 to 13 (rc metallocene polypropylene wax metallocene polyolefin wax may also be a graft metallocene polyolefin wax. Preferably 'grafting is used for the raw materials used The total weight is carried out in an amount of 〇5 by weight/❶ to 1% by weight of maleic anhydride; more preferably, the grafting is on the metallocene polyethylene wax or at a dropping point or softening point higher than J 3〇〇 Performed on a metallocene polypropylene wax of c. Preferably, a metallocene polyolefin wax different from a metallocene polypropylene wax having a dropping point and/or a softening point of 7 〇〇c to n (rc) It is preferably from 500 g/mol to 50,000 g/m〇1, more preferably from i,000 g/mol to 35,000 g/m〇l, even more preferably from 11〇() g/mol to 25,000 g/m〇i2Mn. , different from the dropping point and / or softening point is 7 (rc to 13 〇. 〇茂茂 5 5 5 蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛蠛/mol Better 1,900 §/111〇1 to 100,000 denier/111〇1, even better Mw of 2,100 g/mo1 to 70,000 g/m〇i. Preferably, it is 70 different from the point of dropping and/or softening. (In the case of a metallocene polypropylene wax having a metallocene polypropylene wax of 130 ° C, the Mw / Mn value is preferably from 1.0 to 3.0, more preferably from 15 to 29 ' or even more preferably from 17 to 2.8; especially 2.1 to 2.7; more particularly 2.2 to 2.5. The non-metallocene polysulfide ant preferably has a 丨, 〇〇〇g/m〇l to 2〇, 〇〇〇130449.doc •25· 200906947 The weight average molar mass Mw in the range of g/mol and/or the number average molar mass Mn in the range of 500 g/mol to 15,000 g/mol. The weight of the component Α and the component D is preferably 1 〇: 1 to 1:1 Torr, particularly preferably 4: i to 1: 4, especially 3: 1 to 1: 3. The present invention additionally provides an organic polymer in addition to component A and component b. Component P is used as composition Z of the other components. Component P is preferably selected from thermoplastic polycondensates, especially thermoplastic polyesters, especially polycarbonate (PC), polybutylene terephthalate (PBT) and poly a group consisting of ethylene terephthalate (PET). Component P is preferably selected from the group consisting of styrene polymers, preferably polystyrene (ps), styrene-acrylonitrile copolymer (SAN), acrylonitrile-poly Butadiene-styrene graft polymer (A BS) and a group consisting of styrene-ethylene-butadiene-styrene block copolymer (SEBS). Component p is preferably selected from the group consisting of polyamido's polycarbamide 46 (PA46, polyamine 6/ a group consisting of 6t (PA6/6T)), polyamido 6 (PA6), polyamido 12 (PA12) and polyamine 6.6 (PA6.6). The group P is preferably selected from the group consisting of polyacrylic acid ( The composition of PMMA) is especially polymethyl methacrylate. The group injury P is preferably selected from the group consisting of polycondensation, especially the polypyrene (POM). The group injury P is preferably selected from polyaddition. The composition of the composition is particularly preferably a thermoplastic polyurethane elastomer (TPU). Component P is preferably selected from the group consisting of polyolefins and polyolefin copolymers. When composition Z is a conductive polymer CP, Component P is preferably a polyolefin or a thermoplastic copolymer of 130449.doc -26-200906947. The preferred polyolefin or polyolefin copolymer as component p is selected from the group consisting of: • Polyethylene (PE) ), preferably high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), metallocene low density polyethylene (mLDPE), and gold Linear low density polyethylene (mLLDPE), • Polypropylene (PP), preferably polypropylene homopolymer (PPH), polypropylene random 'copolymer (PP-R) and polypropylene block copolymer (PP-embedded) Segment-COPO), • Polycarbonate plastic knee, preferably 1-octane and ethylene polymer, and • PE copolymer, preferably ethylene-vinyl acetate copolymer (EVA), ethylene and decyl acrylate Copolymer (EMA), copolymer of ethylene and butyl acrylate (EBA), copolymer of ethylene and ethyl acrylate (EEA), cyclic olefin copolymer (COC); • preferably selected from the group consisting of: • PE, preferably HDPE, LDPE and LLDPE, ?· \ υ · PP, preferably PPH, PP-R and PP-block-COPO, • Polyolefin plastic, preferably 1-octene and ethylene polymer, And • PE copolymers, preferably EVA and EMA. - Composition Z preferably contains a thermoplastic plastic, especially a copolymer of ethylene and methyl acrylate as the other component E. When it is desired to produce a composition Z containing a polymer selected from the group consisting of PC, PBT, PET, PS, SAN, ABS, PA6 or PA6.6 as component P, component E is preferably used.

組合物Z較佳含有1 0重量％至1 00重量％之組份A與組份B 130449.doc -27- 200906947 之總和’其中在各種情況下重量％係以組合物z之總重量計。當組合物Z為母體混合物mb時，組合物Z較佳含有10重量％至100重量％，更佳5〇重量％至1〇〇重量％，甚至更佳7〇重至100重量％，尤其95重量。/。至！ 00重量％之組份八與組份B之總和，其中在各種情況下重量％係以組合物z之總重量计，更尤其組合物Z由組份A及組份B組成。當組合物z為母體混合物MB且組份B僅含有CNT而無石墨及/或碳黑時，組合物Z較佳含有3重量％至90重量％，尤佳5重量％至50重量％，尤其1〇重量％至4〇重量％，尤其重量。/〇至35重量％組份b，其中在各種情況下重量％係以組合物Z之總重量計。當組合物Z為母體混合物MB時，組合物2較佳含有6〇重量％至90重量％，更佳7 5重量％至9〇重量％，甚至更佳25 重量％至90重量％，尤其55重量％至90重量％組份A，其中在各種情況下重量％係以組合物Z之總重量計。組合物Z較佳包含： 5重量％至90重量％組份p， 10重量％至95重量％之組份A與組份B之總和，及視情況 0至85重量％其他組份；其中組合物Z中組份P、組份a及組份b之總量始終為15 重量％至100重量％，其中在各種情況下重量％係以組合物 Z之總重量計；較佳其中組份A、組份B及組份p之重量％及其他組份之 130449.doc -28- 200906947 重量％始終累加為100重量％。組合物Z尤佳含有10重量％至9〇重量％，尤其12 5重量％至90重罝％組份P，其中在各種情況下重量％係以組合物z 之總重量計。當組合物Z為導電聚合物且含有組份p時，組份a與組份 B之總和較佳為15重量％至9〇重量％，其中在各種情況下重量％係以組合物Z之總重量計。當組合物Z為導電聚合物CP且組份B僅含有CNT而無石墨及/或碳黑時，組合物Z較佳含有〇丨重量％至丨〇重量％，甚至更佳0.5重量％至9重量％，尤其丨重量％至8重量％，尤其2重量％至8重量％組份b，其中在各種情況下重量％係以組合物Z之總重量計。較佳地，當組合物Z為導電聚合物cp且組份B僅含有 CNT而無石墨及/或碳黑時，組合物2較佳含有6 〇重量％至 45重量％，更佳7·5重量％至45重量％，甚至更佳ι〇重量％至35重量％，尤其15重量％至35重量％組份Α，其中在各種情況下重量％係以組合物Ζ之總重量計。更佳地，當組合物Ζ為導電聚合物cp且組份Β僅含有 CNT而無石墨及/或碳黑時，組合物z 較佳含有0.1重量％至10重量％組份B及6_〇重量％至45重量％組份A ; 更佳0.5重量％至9重量％組份B及7.5重量％至45重量％組份A ; 甚至更佳1重量％至8重量％組份B及1〇重量％至35重量％ 130449.doc -29- 200906947 組份A ; 尤其1重量％至8重量％組份8及15重量％至35重量％組份 A ；其中在各種情況下重量❶/。係以組合物Z之總重量計。當組合物z為導電聚合物CP且組份B既含有CNT亦含有石墨時’組合物Z較佳含有〇· 1重量％至1 〇重量％，更佳〇 2 重量％至7.5重量％，甚至更佳0.5重量％至5重量％，尤其 0.5重量％至4.0重量％ CNT，其中在各種情況下重量％係以〜組合物Z之總重量計。較佳地’當組合物z為導電聚合物CP且組份B既含有 CNT亦含有石墨時，組合物z較佳含有2 · 5重量％至1 〇重量 % ’更佳3重量％至9重量％組份A ’其中在各種情況下重量 %係以組合物Z之總重量計。更佳地，當組合物Z為導電聚合物CP且組份B既含有 CNT亦含有石墨時，組合物z 較佳含有0.1重量％至1〇重量％ CNT及2·5重量％至1〇重量 ki %組份A; 更佳含有0.2重量％至7.5重量％ CNT及2.5重量％至1〇重 ' 量％組份A ; 甚至更佳含有0.5重量％至5重量％ CNT及3重量％至9重量％組份A ;Composition Z preferably contains from 10% to 100% by weight of component A and component B 130449.doc -27-200906947 'wherein in each case the weight % is based on the total weight of composition z. When the composition Z is the parent mixture mb, the composition Z preferably contains 10% by weight to 100% by weight, more preferably 5% by weight to 1% by weight, even more preferably 7% by weight to 100% by weight, especially 95. weight. /. to! 00% by weight of the sum of component VIII and component B, wherein in each case the weight % is based on the total weight of the composition z, more particularly the composition Z consists of component A and component B. When the composition z is the parent mixture MB and the component B contains only CNTs without graphite and/or carbon black, the composition Z preferably contains from 3% by weight to 90% by weight, particularly preferably from 5% by weight to 50% by weight, especially 1% by weight to 4% by weight, especially by weight. /〇 to 35 wt% of component b, wherein in each case the weight % is based on the total weight of the composition Z. When composition Z is the parent mixture MB, composition 2 preferably contains from 6% by weight to 90% by weight, more preferably from 7% by weight to 9% by weight, even more preferably from 25% by weight to 90% by weight, especially 55. % by weight to 90% by weight of component A, wherein in each case the weight % is based on the total weight of the composition Z. Composition Z preferably comprises: from 5% by weight to 90% by weight of component p, from 10% by weight to 95% by weight of the sum of component A and component B, and optionally from 0 to 85% by weight of other components; The total amount of component P, component a and component b in the material Z is always from 15% by weight to 100% by weight, wherein in each case the weight % is based on the total weight of the composition Z; preferably wherein the component A % by weight of component B and component p and other components of 130449.doc -28- 200906947% by weight is always added to 100% by weight. The composition Z particularly preferably contains from 10% by weight to 9% by weight, in particular from 125% by weight to 90% by weight of the component P, wherein in each case the % by weight is based on the total weight of the composition z. When composition Z is a conductive polymer and contains component p, the sum of component a and component B is preferably from 15% by weight to 9% by weight, wherein in each case the weight % is the total of the composition Z Weight meter. When the composition Z is a conductive polymer CP and the component B contains only CNTs without graphite and/or carbon black, the composition Z preferably contains 〇丨% by weight to 丨〇% by weight, even more preferably 0.5% by weight to 9 % by weight, in particular from 8% by weight to 8% by weight, in particular from 2% by weight to 8% by weight, of component b, wherein in each case the weight % is based on the total weight of the composition Z. Preferably, when composition Z is conductive polymer cp and component B contains only CNTs and no graphite and/or carbon black, composition 2 preferably contains from 6% by weight to 45% by weight, more preferably 7·5. From 5% by weight to 45% by weight, even more preferably from 3% by weight to 35% by weight, in particular from 15% by weight to 35% by weight of the component hydrazine, wherein in each case the % by weight is based on the total weight of the enthalpy of the composition. More preferably, when the composition Ζ is a conductive polymer cp and the component Β contains only CNTs and no graphite and/or carbon black, the composition z preferably contains 0.1% by weight to 10% by weight of the components B and 6_〇. % by weight to 45% by weight of component A; more preferably 0.5% by weight to 9% by weight of component B and 7.5% by weight to 45% by weight of component A; even more preferably from 1% by weight to 8% by weight of component B and 1 〇 % by weight to 35% by weight 130449.doc -29- 200906947 Component A; especially 1% by weight to 8% by weight of component 8 and 15% by weight to 35% by weight of component A; wherein in each case the weight ❶/. It is based on the total weight of the composition Z. When the composition z is a conductive polymer CP and the component B contains both CNT and graphite, the composition Z preferably contains 〇·1% by weight to 1% by weight, more preferably 〇2% by weight to 7.5% by weight, even More preferably from 0.5% by weight to 5% by weight, especially from 0.5% by weight to 4.0% by weight of CNT, wherein in each case the % by weight is based on the total weight of the composition Z. Preferably, when the composition z is a conductive polymer CP and the component B contains both CNT and graphite, the composition z preferably contains 2·5 wt% to 1 wt%, more preferably 3 wt% to 9 wt%. % component A' wherein the weight % in each case is based on the total weight of the composition Z. More preferably, when the composition Z is a conductive polymer CP and the component B contains both CNT and graphite, the composition z preferably contains 0.1% by weight to 1% by weight of CNT and 2.5% by weight to 1% by weight. Ki % component A; more preferably 0.2% by weight to 7.5% by weight of CNT and 2.5% by weight to 1% by weight of '% by weight component A; even more preferably containing 0.5% by weight to 5% by weight of CNT and 3% by weight to 9 % by weight of component A;

其中在各種情況下重量％係以組合物Z之總重量計。尤其當組合物Z為導電聚合物CP且組份B既含有CNT亦含有石墨時，組合物Z 130449.doc -30- 200906947 較佳含有0.1重量％至10重量％ CNT及2.5重量。/❶至10重量 %組份A及50重量％至9〇重量。/。石墨；更佳含有0.2重量％至7.5重量％ CNT及2.5重量❶/。至1〇重量％組份Α及60重量。/。至85重量％石墨；甚至更佳含有0.5重量％至5重量％ CNT及3重量❶/。至9重量％組份Α及65重量％至80重量％石墨；其中在各種情況下重量％係以組合物z之總重量計。組合物Z較佳含有〇.1重量％至1〇重量％，尤佳〇 1重量％至5重量◦/❶，尤其〇.5重量％至3重量％組份c，其中在各種情況下重量％係以組合物Z之總重量計。組合物z較佳含有(^丨重量^义至咒重量％，尤佳1〇重量％至 40重量。/。，尤其15重量％至35重量％組份E，其中在各種情況下重量°/。係以組合物Z之總重量計。本發明另外提供產生組合物z之方法，其特徵在於將組份A及組份B及任何其他組份彼此物理混合。組份之混合可在一個步驟或在複數個步驟中進行。對於物理混合之混合裝置，可使用災用型膠工業中慣用之混合裝置’較佳選自由以下裝置組成之群之裝置：擠壓機、捏合機、麼城、射出模製機及葉片混合機。當組合物Z 為母體混合物MB時，混合裝置較佳為擠壓機、捏合機及/ 或葉片混合機。當組合物z為導電聚合物❽時，混^裝置較佳為擠壓機、壓力機及射出模製機，尤佳為擠壓機口。混合較佳連續或分批進行，尤佳連續進行，在母體混合物MB情況下，較佳藉由擠壓或捏合進 T 尤佳藉由擠壓 130449.doc 200906947 進行，且在導電聚合物CP情況下，較佳藉由擠壓或射出模製或壓製進行，尤佳藉由擠壓進行。混合較佳在80°c至300°C之溫度下進行。在母體混合物MB情況下，混合較佳在至2〇〇°c，尤佳H)(TC至18(TC，尤其ll(TC至i5(TC之溫度下進行；在導電聚合物cp情況下，混合較佳在80。(：至3〇〇。(：，尤佳1〇〇它至280°C之溫度下進行。混合時間較佳為5 sec至10 h。在連續混合之情況下，混合時間較佳為5 3“至丨h，尤佳為 10 sec至 15 min。在分批混合之情況下，混合時間較佳為〖1^11至1〇11,尤佳為2 min至8 h ’尤其為2 min至5 h，尤其為2流至i h，尤佳為2 min至1.5 min。在導電聚合物CP之情況下，組份A及組份B較佳以母體混合物MB之形式與組份p混合。此外，母體混合物⑽與粒化組份P之預混物較佳用於物理混合中。本發明另外提供組合物Z用於產生導電聚合物cp或用作導電聚合物CP之用途。當組合物Z為母體混合物mb時，組合物2較佳用於產生導電聚合物CP’尤其用於產生導電聚烯烴。當組合物Z為導電聚合物CP時，組合物2較佳用於產生導電聚稀烴或用作導電聚烯烴。當組合物Z含有組份E時，組合物Z較佳用於產生導電非聚烯烴聚合物或用作導電非聚烯烴聚合物。 130449.doc •32- 200906947 由、’且口物Z ’尤其導電聚合物cp產生導電聚烯烴係藉由類似於上述產生組合物2，尤其導電聚合物cp之方法，以類似方法步驟及過程參數進行。出於本發明之目的，導電聚合物為表面電阻為⑺·6歐姆至1011歐姆，較佳10·5歐姆至1〇11歐姆，尤其〇」歐姆至1〇9 歐姆之聚合物。、’、&物Z較佳用於產生或用作適用於***防護之導電聚合物及/或由導電聚合物製成之製品。組合物Z較佳用於產生或用作可藉由靜電粉末塗佈著色之導電聚合物及/或由導電聚合物製成之製品。組合物Z較佳用於產生或用作可產生幾乎不展示靜電荷載率之包裝的導電聚合物。出於本發明之目的，幾乎無荷電率較佳意謂1〇-6歐姆至1〇"歐姆，較佳1〇_5歐姆至1〇11歐姆，尤其(M歐姆至1G9歐姆之表面電阻，且至初始電荷之 10%的靜電放電時間小於或等於2秒。The weight % is in each case based on the total weight of the composition Z. Particularly when the composition Z is a conductive polymer CP and the component B contains both CNT and graphite, the composition Z 130449.doc -30- 200906947 preferably contains 0.1% by weight to 10% by weight of CNT and 2.5 parts by weight. /❶ to 10% by weight of component A and 50% by weight to 9 〇 by weight. /. Graphite; more preferably from 0.2% by weight to 7.5% by weight of CNT and 2.5% by weight of CNT. Up to 1% by weight of the component and 60% by weight. /. Up to 85% by weight of graphite; even more preferably from 0.5% by weight to 5% by weight of CNT and 3 parts by weight of CNT/. To 9% by weight of the component 65 and 65% by weight to 80% by weight of graphite; wherein in each case the % by weight is based on the total weight of the composition z. The composition Z preferably contains from 0.1% by weight to 1% by weight, particularly preferably from 1% by weight to 5% by weight, more preferably from 5% by weight to 3% by weight of the component c, wherein in each case the weight % is based on the total weight of the composition Z. The composition z preferably contains (% by weight) to the weight of the curse, particularly preferably from 1% by weight to 40% by weight, especially from 15% by weight to 35% by weight of the component E, wherein in each case the weight is / The present invention further provides a method of producing composition z, characterized in that component A and component B and any other components are physically mixed with each other. The mixing of the components can be carried out in one step. Or in a plurality of steps. For the mixing device of physical mixing, a mixing device conventionally used in the disaster-type rubber industry can be used. Preferably, it is selected from the group consisting of: an extruder, a kneader, a mj, The injection molding machine and the blade mixer. When the composition Z is the parent mixture MB, the mixing device is preferably an extruder, a kneader and/or a blade mixer. When the composition z is a conductive polymer, the mixture is mixed. Preferably, the device is an extruder, a press and an injection molding machine, and more preferably an extruder port. The mixing is preferably carried out continuously or in batches, preferably continuously, in the case of the parent mixture MB, preferably by extrusion. Press or knead into T yuga by squeezing 130449 .doc 200906947, and in the case of a conductive polymer CP, preferably by extrusion or injection molding or pressing, preferably by extrusion. Mixing preferably at a temperature of 80 ° C to 300 ° C In the case of the parent mixture MB, the mixing is preferably at 2 ° ° C, especially H) (TC to 18 (TC, especially ll (TC to i5 (TC temperature; in the case of conductive polymer cp) Preferably, the mixing is carried out at 80. (: to 3 Torr. (:, especially preferably 1 Torr to 280 ° C. The mixing time is preferably 5 sec to 10 h. In the case of continuous mixing) The mixing time is preferably from 5 3" to 丨h, especially preferably from 10 sec to 15 min. In the case of batch mixing, the mixing time is preferably from 1^11 to 1〇11, particularly preferably 2 min to 8 h 'especially 2 min to 5 h, especially 2 to ih, especially 2 min to 1.5 min. In the case of a conductive polymer CP, component A and component B are preferably a parent mixture MB The form is mixed with component p. Furthermore, the premix of the parent mixture (10) and the granulated component P is preferably used in physical mixing. The invention further provides composition Z for producing a conductive polymer cp or Use as conductive polymer CP. When composition Z is the parent mixture mb, composition 2 is preferably used to produce conductive polymer CP', especially for producing conductive polyolefin. When composition Z is conductive polymer CP Composition 2 is preferably used to produce a conductive polyhydrocarbon or as a conductive polyolefin. When composition Z contains component E, composition Z is preferably used to produce a conductive non-polyolefin polymer or as a conductive non-polymer. Olefin polymer. 130449.doc • 32- 200906947 The conductive polyolefin is produced from the 'and the mouth Z', especially the conductive polymer cp, by a method similar to the above to produce the composition 2, especially the conductive polymer cp, in a similar manner. The steps and process parameters are carried out. For the purposes of the present invention, the conductive polymer is a polymer having a surface resistance of from (7) 6 ohms to 1011 ohms, preferably from 10.5 ohms to 1 〇 11 ohms, especially from ohms to 1 〇 9 ohms. , ', & Z is preferably used to produce or be used as an electrically conductive polymer suitable for explosion protection and/or an article made of a conductive polymer. Composition Z is preferably used to produce or be used as an electrically conductive polymer which can be colored by electrostatic powder coating and/or an article made of a conductive polymer. Composition Z is preferably used to produce or act as a conductive polymer that produces a package that exhibits little electrostatic loading. For the purposes of the present invention, the almost no charge rate preferably means 1 -6 ohms to 1 〇 ohms, preferably 1 〇 5 ohms to 1 〇 11 ohms, especially (surface resistance from M ohms to 1 G 9 ohms). And the electrostatic discharge time to 10% of the initial charge is less than or equal to 2 seconds.

V 荷電率係根據则EN⑴…]定義且根據細EN 61340-2-1 量測。組合物Z較佳用於產生或用作可用作燃料電池中之雙極板的導電聚合物，較佳導電聚稀烴。此外，組合物Z適用作聚合物中之添加劑或用作聚合物’尤其用於機械補強及用於增加電導率，亦用作用於氣體及能量儲存之材料，用於著色且用作阻燃劑用作電極材料或用於產生導體履帶（eGnduetGr traek)及導電結構及用作顯示器中之發射I組合物2較仙於或用作改良電導 130449.doc •33- 200906947 率或熱導率及機械特性之平八& 、竹往之a合物、陶瓷或金屬複合材料，用於產生或用作導電塗料万適人ϋ 土杆及稷合材料，用作著色劑，用於電池、冷凝器、顯示哭、[办丨丄τ ，，為（例如平面螢幕顯示器）或磷光體，用作場效電晶體，用作（合彳士 )虱或鐘之儲存媒體’用於（例 )屯化氣體之臈’用作催化劑或用作（例如）化學反應中催化活性組份之擔持材料，用於燃料電池，用於醫療領域，例如用作控制細胞έ且敏；±β β 飑、，且織生長之框架，用於診斷領域，例如用作標記，以及用於^卜風n ^ 、化干及物理分析（例如用於原子力顯微鏡）。組合物z可含有其他組份’較佳著色J其中有機及無機染料及顏料可能作為著色劑；對於有機顏料，較佳使用偶氮或重氮顏料，經塗佈之偶氮或重氮顏料或多環顏料；較佳多環顏料為二縣：°各并π比略、醜菁、啥侧、m葱靴、硫鼓藍'二芳基或啥駄酬顏料；對於無機顏料，車广使用適合於著色之金屬氧化物、混合氧化物、硫 :鋁，鉻s夂鹽、金屬粉末、珠光效果顏料(雲母)、發光顏料、氧化鈦、鎘-鉛顏料、氧化鐵、碳黑、矽酸鹽、欽酸錄、鈷類顏料或氧化鉻；填充劑，諸如石夕石，沸石，石夕酸鹽，諸如石夕酸銘，石夕酸鈉，矽酸鈣，白堊，滑石；助劑，較佳硬脂酸鹽、發泡劑、成核劑、過氧化物、抗氧化劑；抗靜電劑，較佳硬脂酸甘油酯、單硬脂酸甘油酯、烷 130449.doc •34· 200906947 基fe、乙乳基化烧基胺、烧基續酸醋、甘油自旨或其混合物（摻合物）； • uv吸收劑及受阻胺光穩定劑（HALS)化合物、滑爽劑、防霧劑、抗冷凝劑及/或懸浮穩定劑、阻燃劑；抗氧化劑或其他慣用塑膠添加劑；或上述各者之混合物。壬母體混合物MB或導電聚合物CP形式之組合物z令人驚訝地均以低黏度為特徵，該低黏度可與高CNT負載量同時獲付，詳言之，可達成母體混合物MB高達2〇重量％，甚至问達25重量％，在許多情況下甚至高達3〇重量％且有時甚至更回之CNT負載量，其中重量％係以母體混合物mb之總重量計，而黏度不會變差以至於會不再產生及加工母體混合物MB，或根本不能形成母體混合物；此外，在導電聚烯烴中可獲得所需導電性及所需低表面電阻。高固體含量以及低黏度使得將添加劑引入聚合物中可能較廉價；亦使模具上之磨損最小化，且使得快速均質化及均勻分布cnt 成為可能。在組合物Z中，CNT良好分散。藉由光學手段對壓製（壓縮模製）板或薄臈定性地測定分散品質。流動性、衝擊韌性、熱變形溫度（亦即載荷撓曲溫度）及拉伸強度亦滿足要求。黏度或流動性係根據01>| IS〇 1133測定且表示為熔體流動速率MFR，衝擊韌性係根據mN EN is〇 179測定熱變形溫度（亦即載荷撓曲溫度）係根據DIN EN IS〇乃」測疋，且拉伸強度係根據DIN EN ISO 527-1測定。 130449.doc -35- 200906947 其他測試方法：除非另外指明，否則藉由以下方法測定產品特性：The V charge rate is defined in accordance with EN(1)...] and is measured according to the fine EN 61340-2-1. Composition Z is preferably used to produce or be used as a conductive polymer useful as a bipolar plate in a fuel cell, preferably a conductive polylute hydrocarbon. In addition, the composition Z is suitable as an additive in polymers or as a polymer 'especially for mechanical reinforcement and for increasing electrical conductivity, also as a material for gas and energy storage, for coloring and as a flame retardant The composition I used as an electrode material or for producing a conductor track (eGnduetGr traek) and a conductive structure and used as a display in the display is more advantageous or used as an improved conductance 130449.doc • 33- 200906947 rate or thermal conductivity and mechanical The characteristics of the flat eight &, bamboo to a compound, ceramic or metal composite material, used to produce or be used as a conductive coating, universal soil rod and composite material, used as a coloring agent, used in batteries, condensers, Show crying, [do 丨丄τ,, (for example, flat screen display) or phosphor, used as a field effect transistor, as a storage medium for (synergy) 虱 or 钟" (for example) 屯 gas 'used as a catalyst or as a supporting material for, for example, a catalytically active component in a chemical reaction, for use in a fuel cell, for use in the medical field, for example, as a control cell, and sensitive; ±ββ飑, and Woven growth framework Diagnostics, such as labels, and a ^ ^ n-Bu wind, stem and physical analysis (for example, atomic force microscopy). Composition z may contain other components 'better coloring J where organic and inorganic dyes and pigments may be used as colorants; for organic pigments, azo or diazo pigments, coated azo or diazo pigments or Polycyclic pigments; preferred polycyclic pigments are two counties: ° π ratio, ugly, 啥 side, m onion boots, sulphur blue 'diaryl or fluorene pigment; for inorganic pigments, car use Suitable for coloring metal oxides, mixed oxides, sulfur: aluminum, chromium s strontium salts, metal powders, pearlescent effect pigments (mica), luminescent pigments, titanium oxide, cadmium-lead pigments, iron oxides, carbon black, tannic acid Salt, acid acid, cobalt pigment or chromium oxide; fillers, such as Shi Xishi, zeolite, ashes, such as Shi Xi acid, sodium sulphate, calcium citrate, chalk, talc; Preferred stearates, foaming agents, nucleating agents, peroxides, antioxidants; antistatic agents, preferably glyceryl stearate, glyceryl monostearate, alkane 130449.doc •34· 200906947 Fe, ethyl lactyl amide, succinic acid vinegar, glycerin or a mixture thereof ; uv absorbers and hindered amine light stabilizers (HALS) compounds, slip agents, antifogging agents, anti-condensing agents and / or suspension stabilizers, flame retardants; antioxidants or other conventional plastic additives; or a mixture of the above. The composition z of the parent matrix mixture MB or the conductive polymer CP form is surprisingly characterized by a low viscosity which can be paid simultaneously with the high CNT loading. In particular, the parent mixture MB can be as high as 2〇. % by weight, even up to 25% by weight, in many cases even up to 3% by weight and sometimes even more CNT loading, where % by weight is based on the total weight of the parent mixture mb and the viscosity does not deteriorate The parent mixture MB is no longer produced and processed, or the parent mixture is not formed at all; in addition, the desired conductivity and the desired low surface resistance are obtained in the conductive polyolefin. High solids content and low viscosity make it less expensive to introduce additives into the polymer; it also minimizes wear on the mold and makes it possible to quickly homogenize and evenly distribute cnt. In composition Z, the CNTs were well dispersed. The dispersion quality was qualitatively determined by pressing (press molding) sheets or sheets by optical means. Fluidity, impact toughness, heat distortion temperature (i.e., deflection temperature under load), and tensile strength also meet the requirements. The viscosity or fluidity is measured according to 01>|IS〇1133 and expressed as the melt flow rate MFR, and the impact toughness is determined according to mN EN is 179. The heat distortion temperature (ie, the deflection temperature under load) is based on DIN EN IS The enthalpy is measured and the tensile strength is determined in accordance with DIN EN ISO 527-1. 130449.doc -35- 200906947 Other Test Methods: Unless otherwise indicated, product characteristics are determined by:

藉由凝膠滲透層析法（Gpc)根據DIN 55672，但在135°C 之溫度下且在溶劑1，2-二氯苯（其中蠟完全溶解）中進行莫耳質量分布，亦即Mw及Μη值的測定；使用市售PE標準物來校準。使用Ubbelohde滴點儀根據DIN 51801/2進行滴點測定 (。。）。根據DIN EN 1427進行環/球軟化點之測定（。〇。除非另有說明’否則出於精確之目的，若在說明書或申請專利範圍中以整數形式給出軟化點，則其代表" 0°c ”，例如 "13〇°(：”代表”130.0它，，。根據DIN 530 1 8測定堪之黏度（mPa*s)。根據180 1183測定密度（§/(；11[13)。藉由凝膠層析法測定莫耳質量（GPC)。藉由DIN EN ISO 60測定容積密度（kg/m3)。藉由180 3 681測定皂化值（111&〖01^§)。藉由180 2114測定酸值（1^【011化）。藉由DIN EN ISO 527-1測定彈性模數（MPa)。測定表面電阻之方法SR-1係根據DIN EN 61340-2-3。測定表面電阻之方法SR-2係根據IEC 93。熔點量測方法：根據ISO 3 146之差示掃描熱量測定 (DSC)。擠壓機扭矩（以Nm計）及擠壓機頭之熔體壓力（以巴計）係 130449.doc -36- 200906947 在機器上讀出且為擠壓機中溶體之黏度或流動性之量度。【實施方式】實例所用物質：組份A1 :聚丙烯茂金屬聚烯烴蠟，其具有i70°c下所量測之190 mPa*s至210 mpa*s之黏度，88°C至93°C之軟化點 ’ 2,900 g/mol 之 Μη 值，6,400 g/mol 之 Mw 值，2.2 之Moir mass distribution, ie Mw and by gel permeation chromatography (Gpc) according to DIN 55672, but at a temperature of 135 ° C and in the solvent 1,2-dichlorobenzene (where the wax is completely dissolved) Determination of Μη value; calibration using commercially available PE standards. The dropping point (...) was measured according to DIN 51801/2 using a Ubbelohde dropping point meter. Determination of ring/ball softening point according to DIN EN 1427 (. 〇. Unless otherwise stated) Otherwise, for the sake of precision, if the softening point is given in integer form in the specification or patent application, it stands for " 0 °c", for example "13〇°(:" stands for "130.0",. The viscosity (mPa*s) is determined according to DIN 530 18. The density is determined according to 180 1183 (§/(;11[13). The molar mass (GPC) was determined by gel chromatography. The bulk density (kg/m3) was determined by DIN EN ISO 60. The saponification value (111 & 01^§) was determined by 180 3 681. 2114 Determination of acid value (1^[011]. Determination of the modulus of elasticity (MPa) by DIN EN ISO 527-1. Method for determining surface resistance SR-1 according to DIN EN 61340-2-3. Determination of surface resistance Method SR-2 is based on IEC 93. Melting point measurement method: Differential Scanning Calorimetry (DSC) according to ISO 3 146. Extruder torque (in Nm) and melt pressure of the extruder head (in bar) ) 130449.doc -36- 200906947 Read on the machine and measure the viscosity or fluidity of the solution in the extruder. Materials used: Component A1: Polypropylene metallocene polyolefin wax having a viscosity of 190 mPa*s to 210 mpa*s measured at i70 °c and a softening point of '88 ° C to 93 ° C ' 2,900 Μη value of g/mol, Mw value of 6,400 g/mol, 2.2

Mw/Mn值及 0.86 g/cm3至 0.89 g/cm3之密度。組份A2·聚丙稀茂金屬聚稀烴蠛，其具有170 °C下所量測之 1,700 mPa*s至 1,900 mPa*s之黏度，85°C 至 88°C 之軟化點 ’ 6,700 g/mol 之 Μη 值，15,500 g/mol 之 Mw值，2 3之Mw/Mn value and density from 0.86 g/cm3 to 0.89 g/cm3. Component A2. Polypropylene metallocene polythene hydrocarbon having a viscosity of 1,700 mPa*s to 1,900 mPa*s measured at 170 °C, and a softening point of 6,700 g/mol at 85 ° C to 88 ° C Μ η value, Mw value of 15,500 g/mol, 2 3

Mw/Mn值及 0.86 g/cm3至 0.89 g/cm3之密度。組份A3 :聚丙烯茂金屬聚烯烴蠟，其具有n(rc下所量測之6,800 mPa*s至7,200 mPa*s之黏度，87°C至90。〇之軟化點 ’ 11,200 g/mol 之 Μη 值，25,200 g/mol 之 Mw 值，2.3 之Mw/Mn value and density from 0.86 g/cm3 to 0.89 g/cm3. Component A3: a polypropylene metallocene polyolefin wax having a viscosity of from 6,800 mPa*s to 7,200 mPa*s measured at rc, 87 ° C to 90. Softening point of ' 11,200 g/mol Μη value, Mw value of 25,200 g/mol, 2.3

Mw/Mn值及 0·86 g/cm3至 0.89 g/cm3之密度。組份B 1 : MWCNT，其係藉由經非均相催化劑分解氣態產生’該非均相催化劑含有Mn、Co及擔持材料，其中 Co及Μη係以金屬形式以活性組份含量計以2莫耳％至卯莫耳％之量存在’且視情況另外含有Μ〇，且該等MWCNT具有10 nm至16 nm之平均外徑（定義為數量分布之中值），由 3至15個碳層構成之壁結構，低於6重量％之殘餘催化劑含量’ 1微米至10微米之長度及150 kg/m3至350 kg/m3之容積密度。 130449.doc -37- 200906947 組伤B2 .合成石墨，其具有根據〇ΐΝ 536〇1量測之52 g 鄰苯一曱酸二丁鹗（DBP)/l〇〇 g之DBP吸油值及3 m2/g之 BET表面積。組份B3 :導電碳黑，其具有320 ml/100 g之吸油值 (OAN)及大於700 m2/g之bet表面積。組份C1 : Cn-Cu烷基磺酸鈉，其具有以總量計至少9〇重量％之活性物質含量。組份D1 :使用齊格勒-納塔催化劑產生之非極性聚乙烯壤均聚物’其具有14〇°c下所量測之64〇 mPa*s至660 mPa*s之黏度，介於117〇c至122。〇範圍内之滴點，〇 92 g/cm3至 0.94 g/cm3之密度（在 2〇。〇下量測），〇 mg KOH/g之酸值 ’ 1，800 g/mol 之 Μη值，5,600 g/mol 之 Mw 值，3.1 之 Mw/Mn值及0 mg KOH/g之皂化值。組份D2 :使用齊格勒-納塔催化劑產生之非極性聚丙烯壤均聚物，其具有1 70 C下所量測之1，500-1，800 mPa*s之黏度’介於160°C至166°C範圍内之滴點，0.88 g/cm3至0.90 、 g/cm3之密度（在20°C下量測），〇 mg KOH/g之酸值，2,500 g/mol 之 Μη 值 ’ 18,000 g/mol 之 Mw 值，7.2 之 Mw/Mn 值及〇 mg KOH/g之皂化值。組份D3 :順丁烯二酸酐改質之聚乙烯茂金屬聚烯烴蠟，其具有140C下所量測之130 mPa*s至150 mP a * s之黏度， 122C至 125C之滴點，0.97 g/cm3 至 1.00 g/cm3 之密度， 1,200 g/mol之 Μη值，3,000 g/mol之 Mw值，2.5之 Mw/Mn值及 17 mg KOH/g至 19 mg KOH/g之酸值。 130449.doc -38- 200906947 組份D4 :聚丙烯茂金屬聚烯烴蠟，其具有170T：下所量測之 1，500 mPa*s至 2,000 mPa*s之黏度，160°C 至 166°C 之軟化點 ’ 7,100 g/mol 之 Μη 值，19,300 g/mol 之 Mw 值，2.7 之 Mw/Mn值及 0.88 g/cm3 至 0_92 g/cm3 之密度。組份E1 :乙烯與丙烯酸甲酯之共聚物，其含有24%重量 %丙稀酸甲酯且具有0.944 g/cm3之密度，2 g/10 min之熔體流動速率（在190°C下使用2.16 kg之重量量測）及91。(：之熔點。組份P1 :聚烯烴塑膠（1-辛烯與乙烯之聚合物），其具有 0.87 g/cm3 之密度 ’ 450 g/10 min 至 550 g/10 min 之熔體流動速率（在190°(：下且以2.16 1^之重量量測），及69°(：至71。〇之熔點。組份 P2 . HDPE ’ 其具有 0.945 g/cm3 之密度，6 g/10 min 之MFR(在19CTC/21.6 kg下量測）及131°C之熔點。組份 P3 : HDPE，其具有 0.956 g/cm3之密度，30.0 g/10 min之MFR(在190°C/21.6 kg下量測）及1,250 MPa之彈性模數。組份P4 : PPH，其具有 0.91 g/cm3之密度，120 g/10 min 之MFR(在23(TC/2_16 kg下量測）及l，450 MPa之彈性模數。除非另外指明，否則下文中所提及之重量％係以混合物或製品之總重置計，份數為重量份；"Comp."意謂比較實例。實例1 將8 5份組份A 3及1 5份組份B1在雙螺桿擠壓機（擠壓機溫 130449.doc -39- 200906947 度：100°c至160。〇上一起均質化。獲得母體混合物MB1。實例2 將85份組份A2及15份組份扪在雙螺桿擠壓機（擠壓機溫度_ 160C至200。〇上一起均質化。獲得母體混合物MB2。比較實例3 將85伤組份p 1及15份組份b丨在雙螺桿擠壓機（擠壓機溫度：160°C至200。〇上一起均質化。獲得母體混合物MB3。實例4 將57.5份組份A3、27.5份組份E1及15份組份B1在雙螺桿擠壓機（擠壓機溫度：16〇它至200。〇上一起均質化。獲得母體混合物]VIB4。比較實例5 將85份組份P3及1 5份組份B1在雙螺桿擠壓機（擠壓機溫度.220°C至240。〇上一起均質化。獲得母體混合物MB5。實例10 將73份組份A1、25份組份B1及2份組份C1在雙螺桿擠壓機（擠壓機溫度：100°C至130。〇上一起均質化。獲得母體混合物MB 1 0。實例11 將38份組份八2、35份組份03、25份組份則及2份組份(：1 在雙螺桿擠壓機（擠壓機溫度：l〇〇°C至160。〇上一起均質化。獲得母體混合物MB 11。比較實例12 將58份組份P2、25份組份D1、15份組份B1及2份組份C1 130449.doc -40- 200906947 在雙螺桿擠壓機（擠壓機溫度：200°C至220°C)上一起均質化。獲得母體混合物MB12。實例13 將50份組份A2、25份組份D4、2 5份組份B1在雙螺桿擠壓機（擠壓機溫度：l〇〇°C至160°C)上一起均質化。獲得母體混合物MB 1 3。比較實例20 將1 7份組份P4及83份組份B2在雙螺桿擠壓機（擠壓機溫度：23 0-260°C)上一起均質化。獲得母體混合物MB20。該母體混合物MB20極易碎且難以粒化。比較實例21 將17份組份P4、78份組份B2及5份組份B3在雙螺桿擠壓機（擠壓機溫度：23 0-260°C)上一起均質化。獲得母體混合物MB21。該母體混合物MB2 1極易碎且難以粒化。實例22 將78份組份A1、2份組份C1及20份組份B1在雙螺桿擠壓機（擠壓機溫度：100-13 0°C)上一起均質化。獲得母體混合物MB22。該母體混合物MB22不易碎且可易於粒化。實例23 將63份組份A1、15份組份D3、2份組份C1及20份組份B1 在雙螺桿擠壓機（擠壓機溫度：100-13 0°C)上一起均質化。獲得母體混合物MB23。該母體混合物MB23不易碎且可易於粒化。比較實例25 130449.doc -41 - 200906947 重複實例22，唯一不同之處在於使用組份D1替代組份 A1。由於自模頭產生不黏結之粉狀物質而非擠出物股料，故不可能產生母體混合物。比較實例26 重複實例22，唯一不同之處在於使用組份D2替代組份 A1。由於自模頭產生不黏結之粉狀物質而非擠出物股料，故不可能產生母體混合物。流動性之量測結果在表A中以熔體流動速率MFR形式報導且直接對母體混合物量測。表A 實例壓製(壓縮模製)板負載量 MFR參數 MFR結果名稱 [重量％] rc/kg] [g/10 min] 1 MB1 15 190/2.16 > 100 2 MB2 15 190/2.16 > 100 Comp. 3 MB3 15 190/2.16 <0.1 4 MB4 15 190/2.16 > 100 Comp. 5 MB5 15 190/2.16 <0.1 10 MB10 25 190/10 12.0 11 MB11 25 190/10 6.0 Comp· 12 MB12 15 190/10 <1.0 13 MB13 25 190/2,16 > 100 母體混合物MB3、5及12極硬且難以分布於聚合物中。實例51 將20份如實例1中所述產生之母體混合物MB 1與80份組份P3在輥筒研磨機上均質化且混合（使用兩個輥筒研磨機）（Labtech)且在加熱液壓印壓機上在200°C下壓製（壓縮模 130449.doc -42- 200906947 製）2分鐘且隨後冷卻至室溫。獲得壓製（壓縮模製）板 20MB 1 (該名稱意謂2〇份實例1中所述產生之母體混合物 MB 1)。實例52、比較實例53、實例54及比較實例55 如實例5 0 ’將2 0份如實例2至5中所述產生之母體混合物 MB2至MB5在各種情況下與80份組份P3在親筒研磨機上均貝化且/昆合（使用兩個輥筒研磨機）（Labtech)，且在加熱液塵印壓機上在200°C下壓製（壓縮模製）2分鐘且隨後冷卻至室溫。獲得壓製（壓縮模製）板2〇MB2、20MB3、20MB4及 20MB5(名稱類似於實例51)。比較實例61、實例62、比較實例63、實例64及比較實例65 將30份如實例1至5中所述產生之母體混合物mb 1至MB5 在各種情況下與70份組份P3在輥筒研磨機上均質化且混合 (使用兩個輥筒研磨機）（Labtech)且在加熱液壓印壓機上在 200 C下壓製（壓縮模製）2分鐘且隨後冷卻至室溫。獲得壓製（壓縮模製）板3 0MB1至3〇MB5(名稱類似於實例51)。實例71、實例72、比較實例*73、實例74及比較實例75 將40份如實例！至5中所述產生之母體混合物mb丨至MB5 與6〇份組份P3在輥筒研磨機（Labtech)上均質化且混合且在加熱液壓印壓機上在200。(3下壓製（壓縮模製）2分鐘且隨後冷卻至室溫。獲得壓製（壓縮模製）板4〇ΜΒ1至40MB5(名稱類似於實例5 1)。隨後將壓製（壓縮模製）板置於23〇C及50%相對濕度之條件下至少24小時。隨後根據SR-2量測表面電阻。 130449.doc -43 - 200906947 表B中展示量測結果。表B 實例壓製(壓縮模製)板厚度2 mm CNT負載量表面電阻 SR-2 LSSR 名稱 [重量％] [歐姆] 51 20MB1 3 > 1.0*1015 > 135 52 20MB2 3 6.0*109 88 Comp, 53 20MB3 3 > 1.0*1015 > 135 54 20MB4 3 > 1.0”0丨5 > 135 Comp. 55 20MB5 3 > 1.0*1015 > 135 Comp. 61 30MB1 4.5 5.0*1012 258 62 30MB2 4.5 1.0*104 81 Comp. 63 30MB3 4.5 3.0*10" 234 64 30MB4 4.5 3.0*104 91 Comp. 65 30MB5 4.5 > 1.0*1015 >304 71 40MB1 6 3.0*103 125 72 40MB2 6 2.0*103 119 Comp. 73 40MB3 6 1.0*104 144 74 40MB4 6 2.0*103 119 Comp. 75 40MB5 6 > 1.0*1015 >540 實例80 將3 0份如實例10中所述產生之母體混合物MB10與70份組份P2於翻轉混合機中預混合且於Brabender單螺桿擠壓機中混合及均質化，該擠壓機具有混合區（溫度：1 75°C至 190°C)。藉由經平膜模具擠出獲得0.7 mm厚度之平膜 FF10 ° 實例81 將30份如實例11中所述產生之母體混合物MB 11與70份組份P2於翻轉混合機中預混合且於Brabender單螺桿擠壓機中混合及均質化，該擠壓機具有混合區（溫度：175°C至 130449.doc -44- 200906947 190C) °藉由經平膜模具擠出獲得〇·7 mm厚度之平膜 FF11。比較實例82 將50份如實例12中所述產生之母體混合物MB12與50份組伤於翻轉混合機中預混合且於Brabender單螺桿擠麼機中混合及均質化，該擠壓機具有混合區（溫度：1 75。(：至 190°C) °藉由經平膜模具擠出獲得〇.7 mm厚度之平膜 FF 12 °隨後將平膜置於23。(：及50%相對濕度之條件下至少 24小時。隨後根據srj量測表面電阻。表^中展示量測結果。實例83 將30份如實例1 3中所述產生之母體混合物MB 1 3與70份、、且伤P2於翻轉混合機中預混合且於Braben(jer單螺桿擠壓機中混合及均質化，該擠壓機具有混合區（溫度：175。(：至 190 C) °藉由經平膜模具擠出獲得〇.7爪爪厚度之平膜 FF13。表C 〜實例〜 —~— 平膜一— 負載量表面電阻 LSSR -----1 名稱 [重量％] SR-1/[歐姆] 80 FF10 —— 7.5 1.0*104 225 81 FF11 7.5 2·0*103 186 Comp. 82 FF12 h———---- 7.5 1.0*10'° 562.5 83 1 FF13 7.5 2.0*10 186 比較實例9〇將1 〇〇知如比較實例20中所述產生之母體混合物mb2〇於 130449.doc -45- 200906947Mw/Mn value and density from 0·86 g/cm3 to 0.89 g/cm3. Component B 1 : MWCNT, which is produced by decomposing a gaseous state by a heterogeneous catalyst. The heterogeneous catalyst contains Mn, Co and a supporting material, wherein Co and Μη are in a metal form with an active component content of 2 Mo. The amount of % to 卯 mol % is present and optionally contains yttrium, and the MWCNTs have an average outer diameter of 10 nm to 16 nm (defined as the median value distribution), from 3 to 15 carbon layers The wall structure is composed of less than 6% by weight of residual catalyst content '1 micron to 10 microns length and 150 kg/m3 to 350 kg/m3 bulk density. 130449.doc -37- 200906947 Group injury B2. Synthetic graphite with a DBP oil absorption value of 52 g of diphenyl phthalate (DBP)/l〇〇g measured according to 〇ΐΝ 536〇1 and 3 m2 BET surface area of /g. Component B3: Conductive carbon black having an oil absorption value (OAN) of 320 ml/100 g and a bet surface area of more than 700 m2/g. Component C1: sodium Cn-Cu alkyl sulfonate having an active substance content of at least 9 〇 by weight based on the total amount. Component D1: a non-polar polyethylene soil homopolymer produced using a Ziegler-Natta catalyst having a viscosity of 64 〇 mPa*s to 660 mPa*s measured at 14 ° C, between 117 〇c to 122. The dropping point in the range of 〇, 密度92 g/cm3 to 0.94 g/cm3 (measured at 2〇. under the armpit), the acid value of 〇mg KOH/g, the value of Μ1 of 1,800 g/mol, 5,600 Mw value of g/mol, Mw/Mn value of 3.1 and saponification value of 0 mg KOH/g. Component D2: a non-polar polypropylene soil homopolymer produced using a Ziegler-Natta catalyst having a viscosity of 1,500-1,800 mPa*s measured at 1 70 C' between 160° Dropping point in the range of C to 166 ° C, density of 0.88 g/cm 3 to 0.90, g/cm 3 (measured at 20 ° C), acid value of 〇 mg KOH / g, Μ η value of 2,500 g / mol ' Mw value of 18,000 g/mol, Mw/Mn value of 7.2 and saponification value of 〇mg KOH/g. Component D3: maleic anhydride modified polyethylene metallocene polyolefin wax having a viscosity of 130 mPa*s to 150 mP a*s measured at 140 C, a dropping point of 122 C to 125 C, 0.97 g Density from /cm3 to 1.00 g/cm3, Μη value of 1,200 g/mol, Mw value of 3,000 g/mol, Mw/Mn value of 2.5 and acid value of 17 mg KOH/g to 19 mg KOH/g. 130449.doc -38- 200906947 Component D4: Polypropylene metallocene polyolefin wax having a viscosity of 1,500 mPa*s to 2,000 mPa*s measured at 170T: 160 ° C to 166 ° C The softening point '7,100 g/mol Μ value, 19,300 g/mol Mw value, 2.7 Mw/Mn value and 0.88 g/cm3 to 0_92 g/cm3 density. Component E1: a copolymer of ethylene and methyl acrylate containing 24% by weight of methyl acrylate and having a density of 0.944 g/cm 3 and a melt flow rate of 2 g/10 min (used at 190 ° C) 2.16 kg weight measurement) and 91. (: melting point. Component P1: polyolefin plastic (polymer of 1-octene and ethylene) having a density of 0.87 g/cm3 '450 g/10 min to 550 g/10 min ( 190 ° (: and measured by the weight of 2.16 1 ^), and 69 ° (: to 71. 〇 melting point. Component P2. HDPE ' has a density of 0.945 g / cm3, 6 g / 10 min MFR (measured at 19 CTC/21.6 kg) and melting point at 131 ° C. Component P3 : HDPE with a density of 0.956 g/cm 3 and an MFR of 30.0 g/10 min (at 190 ° C / 21.6 kg) Test) and elastic modulus of 1,250 MPa. Component P4: PPH with a density of 0.91 g/cm3, MFR of 120 g/10 min (measured at 23 (TC/2_16 kg) and 1,450 MPa) Elastomeric modulus. Unless otherwise indicated, the weight % referred to below is based on the total reset of the mixture or article, and the parts are parts by weight; "Comp." means a comparative example. Example 1 will be 8 5 Parts A 3 and 15 parts B1 were homogenized in a twin-screw extruder (extruder temperature 130449.doc -39 - 200906947 degrees: 100 ° c to 160. The precursor mixture MB1 was obtained. 2 will be 85 A2 and 15 parts of the crucible were homogenized in a twin-screw extruder (extruder temperature _160C to 200. 母. The parent mixture MB2 was obtained. Comparative Example 3 85 parts of the component p 1 and 15 parts b丨 homogenization in a twin-screw extruder (extruder temperature: 160 ° C to 200 °. The precursor mixture MB3 is obtained. Example 4 57.5 parts A3, 27.5 parts E1 and 15 parts) B1 was homogenized in a twin-screw extruder (extruder temperature: 16 Torr to 200 Torr. The precursor mixture was obtained) VIB4. Comparative Example 5 85 parts of P3 and 15 parts of component B1 were placed in a twin screw Extruder (extruder temperature. 220 ° C to 240. Homogenization together. Obtain the parent mixture MB5. Example 10 73 parts of A1, 25 parts of B1 and 2 parts of C1 in twin-screw extrusion Press (extruder temperature: 100 ° C to 130. Homogenize together. Obtain the parent mixture MB 10 0. Example 11 38 parts of the components 8, 2 parts of the components 03, 25 parts and 2 The components (:1 were homogenized in a twin-screw extruder (extruder temperature: l〇〇 ° C to 160 〇. The parent mixture MB 11 was obtained. Comparative Example 12 58 parts P2, 25 parts D1, 15 parts B1 and 2 parts C1 130449.doc -40- 200906947 In a twin-screw extruder (extruder temperature: 200 ° C to 220 ° C) Homogenize together. The parent mixture MB12 was obtained. Example 13 50 parts of component A2, 25 parts of component D4, and 25 parts of component B1 were homogenized together on a twin-screw extruder (extruder temperature: 10 ° C to 160 ° C). The parent mixture MB 1 3 was obtained. Comparative Example 20 17 parts of P4 and 83 parts of component B2 were homogenized together in a twin-screw extruder (extruder temperature: 23 0-260 ° C). The parent mixture MB20 was obtained. The parent mixture MB20 is extremely brittle and difficult to granulate. Comparative Example 21 17 parts of P4, 78 parts of component B2 and 5 parts of component B3 were homogenized together on a twin-screw extruder (extruder temperature: 23 0 to 260 ° C). The parent mixture MB21 was obtained. The parent mixture MB2 1 is extremely brittle and difficult to granulate. Example 22 78 parts of component A1, 2 parts of component C1 and 20 parts of component B1 were homogenized together on a twin-screw extruder (extruder temperature: 100-13 0 °C). The parent mixture MB22 was obtained. The parent mixture MB22 is not brittle and can be easily granulated. Example 23 63 parts of component A1, 15 parts of component D3, 2 parts of component C1 and 20 parts of component B1 were homogenized together in a twin-screw extruder (extruder temperature: 100-13 0 °C). The parent mixture MB23 was obtained. The parent mixture MB23 is not brittle and can be easily granulated. Comparative Example 25 130449.doc -41 - 200906947 Example 22 was repeated, the only difference being that component D1 was used instead of component A1. Since the non-bonded powdery material is produced from the die rather than the extrudate strand, it is impossible to produce a parent mixture. Comparative Example 26 Example 22 was repeated except that component D2 was used instead of component A1. Since the non-bonded powdery material is produced from the die rather than the extrudate strand, it is impossible to produce a parent mixture. The measurement of the fluidity is reported in Table A as the melt flow rate MFR and directly measured on the parent mixture. Table A Example Press (Compression Molding) Plate Loading MFR Parameter MFR Result Name [% by weight] rc/kg] [g/10 min] 1 MB1 15 190/2.16 > 100 2 MB2 15 190/2.16 > 100 Comp 3 MB3 15 190/2.16 <0.1 4 MB4 15 190/2.16 > 100 Comp. 5 MB5 15 190/2.16 <0.1 10 MB10 25 190/10 12.0 11 MB11 25 190/10 6.0 Comp· 12 MB12 15 190 /10 <1.0 13 MB13 25 190/2,16 > 100 The parent mixtures MB3, 5 and 12 are extremely hard and difficult to distribute in the polymer. Example 51 20 parts of the precursor mixture MB 1 produced as described in Example 1 and 80 parts of the component P3 were homogenized and mixed on a roller mill (using a two-roll mill) (Labtech) and heated at the hydraulic printing Press on a press at 200 ° C (compression molding 130449.doc -42 - 200906947) for 2 minutes and then cool to room temperature. A pressed (compression molded) sheet of 20 MB 1 was obtained (this name means 2 parts of the parent mixture MB 1 produced as described in Example 1). Example 52, Comparative Example 53, Example 54 and Comparative Example 55 As Example 5 0 '20 parts of the parent mixture MB2 to MB5 produced as described in Examples 2 to 5 were in each case with 80 parts of the component P3 in the tube Milling and/or kneading (using two roller mills) (Labtech) on a grinder and pressing (compression molding) at 200 ° C for 2 minutes on a heated liquid-press press and then cooling to the chamber temperature. Pressed (compression molded) sheets 2 〇 MB2, 20 MB3, 20 MB4, and 20 MB5 (name similar to Example 51) were obtained. Comparative Example 61, Example 62, Comparative Example 63, Example 64, and Comparative Example 65 30 parts of the precursor mixture mb 1 to MB5 produced as described in Examples 1 to 5 were in each case and 70 parts of the component P3 were ground in a roll. It was homogenized and mixed (using two roller mills) (Labtech) and pressed (compression molding) at 200 C on a heated hydraulic press for 2 minutes and then cooled to room temperature. A compression (compression molding) plate of 3 0MB1 to 3〇MB5 was obtained (the name is similar to Example 51). Example 71, Example 72, Comparative Example *73, Example 74, and Comparative Example 75 40 parts are as an example! The parent mixture mb丨 to MB5 and the 6 parts of the component P3 produced as described in 5 were homogenized and mixed on a roller mill (Labtech) and at 200 on a heated hydraulic press. (3 presses (compression molding) for 2 minutes and then cooled to room temperature. Pressed (compression molded) sheets 4 to 1 to 40 MB5 (name similar to Example 5 1) were obtained. Subsequently, press (compression molding) sheets were placed. At 23 〇C and 50% relative humidity for at least 24 hours. The surface resistance is then measured according to SR-2. 130449.doc -43 - 200906947 The measurement results are shown in Table B. Table B Example compression (compression molding) Plate thickness 2 mm CNT load surface resistance SR-2 LSSR Name [% by weight] [ohm] 51 20MB1 3 > 1.0*1015 > 135 52 20MB2 3 6.0*109 88 Comp, 53 20MB3 3 > 1.0*1015 &gt ; 135 54 20MB4 3 > 1.0”0丨5 > 135 Comp. 55 20MB5 3 > 1.0*1015 > 135 Comp. 61 30MB1 4.5 5.0*1012 258 62 30MB2 4.5 1.0*104 81 Comp. 63 30MB3 4.5 3.0 *10" 234 64 30MB4 4.5 3.0*104 91 Comp. 65 30MB5 4.5 > 1.0*1015 >304 71 40MB1 6 3.0*103 125 72 40MB2 6 2.0*103 119 Comp. 73 40MB3 6 1.0*104 144 74 40MB4 6 2.0*103 119 Comp. 75 40MB5 6 > 1.0*1015 > 540 Example 80 30 parts are produced as described in Example 10 The precursor mixture MB10 was premixed with 70 parts of the component P2 in a tumble mixer and mixed and homogenized in a Brabender single screw extruder having a mixing zone (temperature: 175 ° C to 190 ° C). A flat film FF10 ° of 0.7 mm thickness was obtained by extrusion through a flat film die. Example 81 30 parts of the precursor mixture MB 11 produced as described in Example 11 and 70 parts of the component P2 were premixed in a tumble mixer and in Brabender. Mixing and homogenizing in a single screw extruder with a mixing zone (temperature: 175 ° C to 130 449. doc - 44 - 2009 069 947 190 C) ° 〇 · 7 mm thickness obtained by extrusion through a flat film die Flat film FF11. Comparative Example 82 50 parts of the parent mixture MB12 produced as described in Example 12 were premixed with 50 parts of the wound in a tumble mixer and mixed and homogenized in a Brabender single screw extruder having a mixing zone (Temperature: 1 75. (: to 190 ° C) ° A flat film of 〇. 7 mm thickness was obtained by extrusion through a flat film die. FF 12 ° and then the flat film was placed at 23. (: and 50% relative humidity At least 24 hours under conditions. The surface resistance is then measured according to srj. The measurement results are shown in Table 2. Example 83 30 parts of the parent mixture MB 1 3 and 70 parts as described in Example 13 were obtained, and the P2 was Premixed in a tumble mixer and mixed and homogenized in a Braben (jer single screw extruder with a mixing zone (temperature: 175. (: to 190 C) ° obtained by extrusion through a flat film die 〇.7 The thickness of the claw film FF13. Table C ~ Example ~ -~ - Flat film one - Load surface resistance LSSR -----1 Name [% by weight] SR-1/[Ohm] 80 FF10 —— 7.5 1.0*104 225 81 FF11 7.5 2·0*103 186 Comp. 82 FF12 h———---- 7.5 1.0*10'° 562.5 8 3 1 FF13 7.5 2.0*10 186 Comparative Example 9〇 The parent mixture mb2 produced as described in Comparative Example 20 is immersed in 130449.doc -45- 200906947

Brabender單螺桿擠壓機中混合且均質化，該擠壓機具有混合區（溫度：260°C至275°C)。藉由經平膜模具擠出獲得1.5 mm厚度之板EP20。實例91 將95份如比較實例20中所述產生之母體混合物MB20與5 份如實例22中所述產生之母體混合物MB22於翻轉混合機中預混合且於Brabender單螺桿擠壓機中混合且均質化，該擠壓機具有混合區（溫度：260°C至275°C)。藉由經平膜模具擠出獲得1.5 mm厚度之板EP2 1。實例92 將95份如比較實例20中所述產生之母體混合物MB20與5 份如實例23中所述產生之母體混合物MB23於翻轉混合機中預混合且於Brabender單螺桿擠壓機中混合且均質化，該擠壓機具有混合區（溫度：260°C至275°C)。藉由經平膜模具擠出獲得1.5 mm厚度之板EP22。比較實例93 將1 00份如比較實例2 1中所述產生之母體混合物MB21於 Brabender單螺桿擠壓機中混合且均質化，該擠壓機具有混合區（溫度：260°C至275t)。藉由經平膜模具擠出獲得1.5 mm厚度之板EP23。實例94 將95份如比較實例21中所述產生之母體混合物MB21與5 份如實例22中所述產生之母體混合物MB22於翻轉混合機中預混合且於Brabender單螺桿擠壓機中混合且均質化，該 130449.doc •46- 200906947 擠壓機具有混合區（溫度：260°C至275°C)。藉由經平膜模具擠出獲得1.5 mm厚度之板EP24。表D 實例擠壓板扭矩熔體壓力表面電阻名稱 [Nm] [巴】 SR-2/丨歐姆] Comp· 90 EP20 47.0 149 0.80 91 EP21 31.2 114 0.53 92 EP22 37.0 125 0.66 Comp. 93 EP23 44.0 185 1.00 94 EP24 29.0 101 0.70 95 EP25 25.0 90 0.59 實例95 將90份如比較實例21中所述產生之母體混合物MB2 1與 1 0份如實例22中所述產生之母體混合物MB22於翻轉混合機中預混合且於Brabender單螺桿擠壓機中混合且均質化，該擠壓機具有混合區（溫度：260°C至275°C)。藉由經平膜模具擠出獲得1.5 mm厚度之板EP25。在所有實驗中Brabender單螺桿擠壓機之轉速為悝定值每分鐘80轉。表D中展示量測結果。 130449.doc -47-The Brabender single screw extruder is mixed and homogenized, and the extruder has a mixing zone (temperature: 260 ° C to 275 ° C). A plate EP20 having a thickness of 1.5 mm was obtained by extrusion through a flat film die. Example 91 95 parts of the parent mixture MB20 produced as described in Comparative Example 20 and 5 parts of the parent mixture MB22 produced as described in Example 22 were premixed in a tumble mixer and mixed and homogenized in a Brabender single screw extruder. The extruder has a mixing zone (temperature: 260 ° C to 275 ° C). A plate EP1 1 having a thickness of 1.5 mm was obtained by extrusion through a flat film mold. Example 92 95 parts of the parent mixture MB20 produced as described in Comparative Example 20 and 5 parts of the parent mixture MB23 produced as described in Example 23 were premixed in a tumble mixer and mixed and homogenized in a Brabender single screw extruder. The extruder has a mixing zone (temperature: 260 ° C to 275 ° C). A plate EP22 having a thickness of 1.5 mm was obtained by extrusion through a flat film mold. Comparative Example 93 100 parts of the precursor mixture MB21 produced as described in Comparative Example 21 were mixed and homogenized in a Brabender single screw extruder having a mixing zone (temperature: 260 ° C to 275 t). A plate EP23 having a thickness of 1.5 mm was obtained by extrusion through a flat film die. Example 94 95 parts of the parent mixture MB21 produced as described in Comparative Example 21 and 5 parts of the parent mixture MB22 produced as described in Example 22 were premixed in a tumble mixer and mixed and homogenized in a Brabender single screw extruder. The 130449.doc •46- 200906947 extruder has a mixing zone (temperature: 260 ° C to 275 ° C). A plate EP24 having a thickness of 1.5 mm was obtained by extrusion through a flat film mold. Table D Example Extrusion Plate Torque Melt Pressure Surface Resistance Name [Nm] [bar] SR-2/丨 ohm] Comp· 90 EP20 47.0 149 0.80 91 EP21 31.2 114 0.53 92 EP22 37.0 125 0.66 Comp. 93 EP23 44.0 185 1.00 94 EP24 29.0 101 0.70 95 EP25 25.0 90 0.59 Example 95 90 parts of the parent mixture MB2 1 produced as described in Comparative Example 21 and 10 parts of the parent mixture MB22 produced as described in Example 22 were premixed in a tumble mixer And mixing and homogenizing in a Brabender single screw extruder with a mixing zone (temperature: 260 ° C to 275 ° C). A plate EP25 of 1.5 mm thickness was obtained by extrusion through a flat film die. In all experiments, the Brabender single-screw extruder was rated at 80 rpm. The measurement results are shown in Table D. 130449.doc -47-

Claims

200906947 十、申請專利範圍： Κ 一種組合物Z ’其包含組份A及組份B，其中該組份A為滴點及/或軟化點為抓㈣代之茂金屬聚丙稀螺，該點係藉由使用UbbelGhde滴點儀根據刪5ΐ8〇ι/2測該軟化點係藉由使用環/球根據DIN en 1々η測定，·且該組份B為碳奈米管。 2. 如請求们之組合物2，其特徵在於該茂金屬聚丙稀堪之滴點為85°C至1 〇〇°C。 3. 如請求項⑷之組合物2，其特徵在於該茂金屬聚丙烯壤之軟化點為85°C至1 〇〇。(：。月求項1至3中一或多項之組合物z，其特徵在於該茂金屬聚稀烴蠛具有在17(rc之溫度下量測之介於4()mpa*s 至8〇,000 mPa*S範圍内之黏度，該黏度係根據DIN 53018 測定。 5·如请求項1至4中一或多項之組合物z，其特徵在於該碳奈米管具有50 ^仏至1，00。m2/g之BET表面積，該BET表 ’面積係使用氮根據ASTM D3037量測。 6·如叫求項1至5中一或多項之組合物z，其特徵在於該碳奈米管為MWCNT。 7·如請求項1至6中一或多項之組合物z，其特徵在於該組伤A與該組份b之重量比為丨：99至99: j。 8_如請求項1至7中一或多項之組合物Z，其特徵在於該組 s物Zg有1〇重量％至1〇〇重量％之該組份a與該組份b之總和’其中在各種情況下重量❶/〇係以該組合物Z之總重量 130449.doc 200906947 計。 9. 如請求項1至8中一或多項之組合物z，其特徵在於該組合物Z含有有機聚合物作為其他組份p。 10. 如請求項9之組合物z，其特徵在於該組份p係選自由以下各物組成之群：聚烯烴及聚烯烴共聚物。 11·如請求項9或10之組合物2，其特徵在於該組合物2包含 5重量％至90重量❶/。組份P， 10重量％至95重量％組份A與組份B之總和，及視情況 0至8 5重量％其他纽份；其中組合物Z中組份p、組份A及組份B之總量始終為15 重I %至100重量％ ’其中在各種情況下重量％係以該組合物Z之總重量計。如叫求項1至11中一或多項之組合物z，其特徵在於該組合物Z含有分散劑作為其他組份c。 13. 如明求項丨至12中一或多項之組合物z，其特徵在於該組合物z含有乙烯與丙烯酸甲醋之共聚物作為其他組份 14. 種產生如叫求項i至】3中—或多項之組合物z之方法，其其特徵在於將該組份A及該組份B及任何其他組份彼此物理）¾合。月长項14之產生組合物z之方法，其特徵在於將選自由以下裝置組成之群之m作物理混合之混合裝置：擠壓機、捏合機、壓力機、射出_模製機及葉#混合機。 16·如請求項14或15之產生組合物Z之方法，其特徵在於在 m：至骑之溫度下進行混合。 130449.doc 200906947 17. 如請求項14至16中一或多項之產生組合物z之方法，其特徵在於該混合時間為5 sec至1〇 h。 18. —種如請求項1至13中一或多項之組合物z之用途，其係用於產生導電聚合物CP或用作導電聚合物Cp。 19. 一種如請求項1至13中一或多項之組合物z之用途，其係用作聚合物中之添加劑或用作聚合物，尤其用於機械補強及用於增加電導率，亦用作用於氣體及能量儲存之材料，用於著色且用作阻燃劑，用作電極材料或用於產生導體履帶及導電結構及用作顯示器中之發射器，用於戋用作改良電導率或熱導率及機械特性之聚合物、陶瓷或金屬複合材料，用於產生或用作導電塗料及複合材料，用作著色劑，用於電池、冷凝器、顯示器（例如平面螢幕顯示器）或磷光體，用作場效電晶體，用作儲存媒體，用於膜，用作催化劑或用作擔持材料，用於燃料電池，用於醫療領域’用於診斷領域，以及用於化學及物理分析’用於產生或用作適用於***防護之導電聚合物及/或由導電聚合物製成之製品’用於產生或用作可藉由靜電粉末塗佈著色之導電聚合物及/或由導電聚合物製成之製品，用於產生或用作可產生幾乎不展示靜電荷載率之包裝的導電聚合物，用於產生或用作可用作燃料電也中之雙極板之導電聚合物，較佳導電聚烯烴。 130449.doc 200906947 七、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明：八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無） 130449.doc200906947 X. Patent application scope: Κ A composition Z' comprising component A and component B, wherein the component A is a dropping point and/or a softening point is a metallocene polypropylene snail of the scratch (four) generation, the point is The softening point was determined by using a Ubbel Ghde dropping point meter according to the deletion of 5ΐ8〇ι/2 by using a ring/ball according to DIN en 1々η, and the component B was a carbon nanotube. 2. The composition 2 of claimant, characterized in that the metallocene polypropylene has a dropping point of from 85 ° C to 1 ° C. 3. Composition 2 of claim (4), characterized in that the metallocene polypropylene has a softening point of from 85 ° C to 1 Torr. (:. Composition z of one or more of months 1 to 3, characterized in that the metallocene polythene hydrocarbon has a ratio of 4 () mpa*s to 8 量 measured at a temperature of 17 (rc) a viscosity in the range of 10,000 mPa*S, the viscosity being determined according to DIN 53018. 5. The composition z according to one or more of claims 1 to 4, characterized in that the carbon nanotube has a 50 μ仏 to 1, 00. BET surface area of m2/g, the BET table 'area is measured using nitrogen according to ASTM D3037. 6. The composition z of one or more of items 1 to 5, characterized in that the carbon nanotube is MWCNT. 7. The composition z of one or more of claims 1 to 6, characterized in that the weight ratio of the group A to the component b is 丨: 99 to 99: j. 8_ as claimed in claim 1 A composition Z of one or more of 7 characterized in that the group s Zg has from 1% by weight to 1% by weight of the sum of the component a and the component b, wherein the weight ❶ in each case The lanthanide is based on the total weight of the composition Z 130449.doc 200906947. 9. The composition z according to one or more of claims 1 to 8, characterized in that the composition Z contains an organic polymer as another group The composition z of claim 9, wherein the component p is selected from the group consisting of polyolefins and polyolefin copolymers. 11. The composition of claim 9 or 10 2, characterized in that the composition 2 comprises from 5% by weight to 90% by weight of the component P, from 10% by weight to 95% by weight of the total of the components A and B, and optionally from 0 to 85 % by weight. The total amount of component p, component A and component B in composition Z is always 15% I % to 100% by weight 'wherein in each case the weight % is based on the total weight of the composition Z The composition z of one or more of the items 1 to 11 is characterized in that the composition Z contains a dispersing agent as the other component c. 13. A composition of one or more of the following items a composition of the composition z containing a copolymer of ethylene and methyl acetonate as a further component 14. A method for producing a composition z of the formulae i to 3 or more, characterized in that Component A and component B and any other components are physically commensurate with each other. The method of producing composition z of month length item 14 In the mixing device selected from the group consisting of the following devices: physical mixing: extruder, kneader, press, injection_molding machine and leaf #mixer. 16. Combination of claims 14 or 15 The method of Z, characterized in that the mixing is carried out at a temperature of m: to ride. 130449.doc 200906947 17. The method of producing composition z according to one or more of claims 14 to 16, characterized in that the mixing time is 5 sec to 1 〇h. 18. Use of a composition z as claimed in one or more of claims 1 to 13 for producing a conductive polymer CP or as a conductive polymer Cp. 19. Use of a composition z as claimed in one or more of claims 1 to 13 for use as an additive in a polymer or as a polymer, especially for mechanical reinforcement and for increasing electrical conductivity, Materials for gas and energy storage, for coloring and use as flame retardants, as electrode materials or for generating conductor tracks and conductive structures and as emitters in displays for use as improved conductivity or heat Conductivity and mechanical properties of polymers, ceramics or metal composites used in the production or use as conductive coatings and composites, as colorants for batteries, condensers, displays (eg flat screen displays) or phosphors, Used as a field effect transistor, as a storage medium, as a film, as a catalyst or as a supporting material, for fuel cells, for medical applications 'for diagnostics, and for chemical and physical analysis' Producing or used as an electrically conductive polymer suitable for explosion protection and/or an article made of a conductive polymer' for producing or using as a conductive polymer which can be colored by electrostatic powder coating and/or An article made of a conductive polymer for the production or use as a conductive polymer that produces a package that exhibits little electrostatic loading, for the production or use as a conductive polymer for use as a bipolar plate in fuel electricity. Preferably, the conductive polyolefin. 130449.doc 200906947 VII. Designation of the representative representative: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 8. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 130449.doc