TW200900859A

TW200900859A - Coloring resin composition, color filter, liquid-crystal display device and organic EL display

Info

Publication number: TW200900859A
Application number: TW97114141A
Authority: TW
Inventors: Toshiyuki Tanaka; Junji Mizukami; Tatsunori Tsuchiya
Original assignee: Mitsubishi Chem Corp
Priority date: 2007-04-20
Filing date: 2008-04-18
Publication date: 2009-01-01
Also published as: JP5169422B2; CN101542393A; JP2008287246A; KR101434275B1; KR20100014075A; CN101542393B; TWI421634B; WO2008129986A1

Abstract

The present invention provides a coloring resin composition, which has an excellent image forming property even in the condition of a large quantity of colorants, a color filter using said coloring resin composition, a liquid-crystal display device and an organic EL display. The coloring resin composition according to the present invention comprises at least (A) a colorant and (B) an organic binder, and is characterized in that the (B) organic binder comprises an alkali soluble unsaturated resin having an acid value of 10 mg-KOH/g or above, and the alkali soluble unsaturated resin is obtained by reacting the reactants of an epoxy compound (a) represented by the following formula (1) and a carboxylic acid (b) containing unsaturated groups, with a polyanhydride (d). [In the above formula (1), X represents a specific linking group, which comprises one or more adamantane structures in its molecular structure, and 1 represents an integer of 2 or 3. ]

Description

200900859 九、發明說明：【發明所屬之技術領域】本發明係關於一種著色樹脂組成物、彩色濾光片、液晶顯不裝置及有機EL顯示器。詳細而言，係關於一種液體穩定性、耐熱性優異’顯影時之浮渣少，與基板之密著性、像素之邊緣形狀、錐形形狀良好’且可提供適於製造彩色 ; 渡光片之感光性著色樹脂組成物的著色樹脂組成物；使用 f) 3玄感光性著色樹脂組成物之彩色濾光片；以及使用該彩色濾、光片之液晶顯示裝置及有機EL顯示器。【先前技術】習知，作為使用有顏料之彩色濾光片之製造法，已知有染色法、電鍍法、喷墨法、顏料分散法等。於利用顏料分散法製造彩色滤光片之情況，通常，將於使用分散劑等分散顏料而成之著色樹脂組成物中添加黏合劑樹脂、光聚合起始劑、光聚合性單體等而進行感光化的感光性著色樹脂組成物，塗層於玻璃基板上，使之乾燥後’使用光罩進行曝光、顯影’藉此形成著色圖案，盆後 2將其加熱而固著圖案，形成像素。對於每種顏色重複 5亥寺步驟，從而形成彩色濾光片。 ::於上述杉色濾光片之圖像形成中所使用之 ^腊組成物，要求具有充分之解析性、與基板之良好: =性 '低_殘料雜。⑼近年來 3素或光學密度高之樹脂黑色起陣。因此，對者色難組成物，要求含有大量顏料或碳黑等色材:2 97114141 200900859 上述特性優異。通常，感光性樹脂組成物被供於經由顯影之步驟之光微影㈣，故㈣步驟中， :呈：：步驟中之去除部分中不產生殘渣或浮渣；去除；刀具有充分之溶解性.媒古阁安、息矣 ^ 等圄傻m 邊銳度(sharpness) 二:=，。然而’於使用如上所述之色材含量高之感) …者色树肊組成物，形成像素或黑色矩陣（以下，昧 fi ::亥等總私為「圖案」)之情況，易於明顯出現如下問題：驟中’未曝光部分之基板上產生殘潰或浮渣；無法 =曝光部分之良好之溶解性；圖案邊緣之銳度不良· 光部分之光硬化不充分所導致之表面平滑性不良；等。 ’ 呈^其由於樹脂黑色矩陣包含黑色色材，於廣波長區域内 :光性，因此出現如下重大課題：（1)明顯難以賦予二光部分與未曝光部分之交聯密度差；（2)於經曝光之部为中亦產生沿膜厚方向之交聯密度差，即，即便於光照射面=充分硬化，於基底面側亦難以硬化；（3)因含有大量不/合於顯影液之黑色色材，故難以獲得高顯影性等。、主為了解決上述問題，提出有使用具有羧基之酚醛 :、衣氧丙烯酸酯樹脂作為黏合劑樹脂的感光性著色樹月曰=成物（參照專利文獻丨）。然而，根據本發明者等人之研九判明出現如下問題：即便使用該黏合劑樹脂之情扣’合解性與靈敏度之平衡亦不充分，故於未曝光部分之心解之同時，顯影液滲透入曝光部分，圖案邊緣部分之直 97114141 7 200900859 線性低；圖案與基板之密著性不充分；等。又，提出有使用具有叛基之丙烯酸系樹脂與含有脂環式環氧基之不飽和化合物之反應物作為黏合劑樹脂的感光性樹脂組成物（參照專利文獻2)。然而，根據本發明者等人之研究，判明即便使用該黏合劑樹脂之情況，靈敏度亦不充分，故圖案與基板之密著性不良，難以形成高精=之 > 圖案。〇提出有包含使苐型環氧樹脂與（甲基）丙烯酸之反應 =夕元羧酸或其酸酐反應而獲得之含有不飽和基之羧酉义化合物作為黏合劑樹脂的樹脂組成物（參照專利文獻 3)。然而’根據本發明者等人之研究，爿明雖然該樹脂組成物具有高靈敏度或解析力，但存在顯影後未曝光部分之二，上產生殘渣之傾向。又’報告有作為原料之㈣錄樹脂具有強烈之皮膚刺激性，故操作：等疾病。 y 〇利文獻1 :曰本專利特開平1卜84126號公報，利文獻2 :日本專利特開平卜289820號公報 , 獻3 :日本專利特開平4-355450號公報脂組i二之目的在於提供—種圖像形成性優異之著色樹顯示著色樹脂組成物之彩色滤光片、及液晶衣置以及有機EL顯示器。【發明内容】本發"明繁/ 構造之特定产扣極研九，結果發現藉由將自具有金剛烷衣乳化合物獲得之鹼可溶性不飽和樹脂用作 97114141 8 200900859 有機黏合劑，可解決上述課題。即，本發明係以以下内容為要旨。 [1]一種著色樹脂組成物，其係至少包含色材及（b) 有機黏合劑（organic binder)者，其特徵在於：（B)有機 =合劑包含酸值為1〇 mg_K〇H/g以上之鹼可溶性不飽和樹月曰，該鹼可溶性不飽和樹脂係藉由使以下述通式（丨）所表不之環氧化合物（a)與含有不飽和基之羧酸（b)之反應物，與多元酸酐（d)反應而獲得。 [化1]200900859 IX. Description of the Invention: [Technical Field] The present invention relates to a colored resin composition, a color filter, a liquid crystal display device, and an organic EL display. Specifically, it is excellent in liquid stability and heat resistance, and has less scum during development, adhesion to a substrate, edge shape of a pixel, and a tapered shape, and can be provided to be suitable for color production; A colored resin composition of the photosensitive colored resin composition; a color filter using f) 3 a photosensitive photosensitive resin composition; and a liquid crystal display device and an organic EL display using the color filter and the optical sheet. [Prior Art] Conventionally, as a method of producing a color filter using a pigment, a dyeing method, a plating method, an inkjet method, a pigment dispersion method, and the like are known. In the case of producing a color filter by a pigment dispersion method, a binder resin, a photopolymerization initiator, a photopolymerizable monomer, or the like is usually added to a colored resin composition obtained by dispersing a pigment such as a dispersant. The photosensitive photosensitive resin composition is coated on a glass substrate, dried, and then subjected to exposure and development using a photomask to form a colored pattern, which is heated and fixed to form a pixel. The 5 hai temple step is repeated for each color to form a color filter. :: The wax composition used in the image formation of the above-mentioned cedar filter is required to have sufficient resolution and goodness with the substrate: = 'low _ residual material miscellaneous. (9) In recent years, a resin having a high crystal density or a high optical density has been arrayed. Therefore, it is required to contain a large amount of coloring materials such as pigments or carbon black for the difficult composition: 2 97114141 200900859 The above characteristics are excellent. Usually, the photosensitive resin composition is supplied to the photo lithography through the step of development (4), so in the step (4), the residue in the step is: no residue or scum is generated in the removed portion; the removal; the knife has sufficient solubility .Media ancient cabinet security, interest 矣 ^, etc. 圄 silly m sharpness (sharpness) 2: =,. However, it is easy to appear clearly when the composition of the color tree is used to form a pixel or a black matrix (hereinafter, 总fi:Hai, etc. is a "pattern"). The following problems occur: In the middle of the 'unexposed portion, a residue or scum is generated on the substrate; the solubility of the exposed portion is not good; the sharpness of the edge of the pattern is poor. The surface smoothness due to insufficient light hardening of the light portion is poor. ; Wait. Since the resin black matrix contains a black color material and is in a wide wavelength region: light, the following major problems occur: (1) it is difficult to impart a difference in crosslink density between the two-light portion and the unexposed portion; (2) The difference in cross-linking density in the film thickness direction is also generated in the exposed portion, that is, even if the light-irradiated surface = sufficiently hardened, it is difficult to harden on the base surface side; (3) due to a large amount of non-cobalt solution Since it is a black color material, it is difficult to obtain high developability and the like. In order to solve the above problems, the present invention proposes a photosensitive coloring tree using a phenolic phenolic resin having a carboxyl group as a binder resin (see Patent Document 丨). However, according to the researcher of the present inventors, the following problem has been found: even if the adhesive of the adhesive resin is used, the balance between the compatibility and the sensitivity is insufficient, so that the developer is not affected by the unexposed portion. Penetration into the exposed portion, the edge of the pattern is straight 97114141 7 200900859 linear low; the adhesion of the pattern to the substrate is not sufficient; Further, a photosensitive resin composition using a reaction product of a repellent acrylic resin and an alicyclic epoxy group-containing unsaturated compound as a binder resin has been proposed (see Patent Document 2). However, according to the study by the inventors of the present invention, it has been found that even when the binder resin is used, the sensitivity is insufficient, so that the adhesion between the pattern and the substrate is poor, and it is difficult to form a high-precision > pattern. A resin composition containing a carboxyl group-containing compound containing an unsaturated group obtained by reacting a reaction of a fluorene-type epoxy resin with (meth)acrylic acid = a carboxylic acid or an anhydride thereof as a binder resin is proposed (see Patent Document 3). However, according to the study by the inventors of the present invention, although the resin composition has high sensitivity or resolving power, there is a tendency that residue is generated on the unexposed portion after development. Also reported as a raw material (4) recorded resin has a strong skin irritation, so the operation: and other diseases. Y 〇文献 1 1 1 1 专利 126 126 126 126 126 126 126 126 126 126 126 126 126 126 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 289 A color filter which is excellent in image formability, displays a color filter of a colored resin composition, a liquid crystal garment, and an organic EL display. SUMMARY OF THE INVENTION The present invention has been developed as a specific binder of the Mingfan/structure. As a result, it has been found that by using an alkali-soluble unsaturated resin obtained from an adamantane latex compound as the 97114141 8 200900859 organic binder, it can be solved. The above issues. That is, the present invention is based on the following contents. [1] A colored resin composition comprising at least a color material and (b) an organic binder, characterized in that: (B) an organic = mixture contains an acid value of 1 〇 mg_K 〇 H / g or more. The alkali-soluble unsaturated tree ruthenium, the alkali-soluble unsaturated resin is a reaction product of the epoxy compound (a) represented by the following formula (丨) and the carboxylic acid (b) containing an unsaturated group It is obtained by reacting with a polybasic acid anhydride (d). [Chemical 1]

⑴ [於上述通式（1)中，x表示以下述通式（2a)或（2b)所表示之連結基。其中，分子構造中含有一個以上之金剛烷構造。1表示2或3之整數。 [化2](1) [In the above formula (1), x represents a linking group represented by the following formula (2a) or (2b). Among them, the molecular structure contains more than one adamantane structure. 1 represents an integer of 2 or 3. [Chemical 2]

(於上述通式（2a)及（2b)中’ R1〜R4、R13〜Ri5分別獨立表示可具有取代基之金剛烷基、氫原子、可具有取代基之碳數為1〜12之烧基、或可具有取代基之苯基。於上述通式（2a)及（2b)中，*表示與通式（1)中之環氧丙氧基之鍵結部位。）] [2] —種者色樹脂組成物’其係至少包含（a)色材及（b) 97114141 9 200900859 有機黏合劑者，其特徵在於：⑻有機黏合劑包含酸值為 10 Hig-KOH/g以上之鹼可溶性不飽和樹脂，該鹼可溶性不飽和樹脂係藉由使以下述通式⑴所表示之環氧化合物⑷ 及/或以下述通式（1A)所表示之環氧化合物（a,)與含有不飽和基之羧酸（b)之反應物，與多元醇（c)混合後，與多元酸酐（d)反應而獲得。 [化3](In the above formulae (2a) and (2b), 'R1 to R4 and R13 to Ri5 each independently represent an adamantyl group which may have a substituent, a hydrogen atom, and a carbon group which may have a substituent and have a carbon number of from 1 to 12; Or a phenyl group which may have a substituent. In the above formulas (2a) and (2b), * represents a bonding site with a glycidoxy group in the formula (1).)] [2] The resin composition is a material comprising at least (a) a color material and (b) 97114141 9 200900859 organic binder, characterized in that: (8) the organic binder contains an alkali solubility of an acid value of 10 Hig-KOH/g or more. The alkali-soluble unsaturated resin is an epoxy compound (4) represented by the following general formula (1) and/or an epoxy compound (a) represented by the following general formula (1A) and an unsaturated group. The reactant of the carboxylic acid (b) is obtained by mixing with the polyol (c) and then reacting with the polybasic acid anhydride (d). [Chemical 3]

0) 一[於上述通式（1)中，X表示以下述通式（2a)或（2b)所表連、、、σ I其中，分子構造中含有一個以上之金剛烷構造。1表示2或3之整數。 [化4]0) In the above formula (1), X represents a structure represented by the following formula (2a) or (2b), and σ I wherein the molecular structure contains one or more adamantane structures. 1 represents an integer of 2 or 3. [Chemical 4]

(於上述通式（2a)及（2b)中’ f〜R4、Ru〜Rl5分別獨立 ^示可具有取代基之金剛烷基、氫原子、可具有取代基之碳數為1〜12之烷基、或可具有取代基之苯基。 ^上述通式（2a)及（2b)中，*表示與通式〇)中之環氧丙氧基之鍵結部位。）] [化5](In the above formulas (2a) and (2b), 'f to R4 and Ru to Rl5 each independently represent an adamantyl group which may have a substituent, a hydrogen atom, and an alkyl group which may have a substituent and have a carbon number of from 1 to 12 a phenyl group which may have a substituent. ^ In the above formulae (2a) and (2b), * represents a bonding site with a glycidoxy group in the formula 〇). )] [Chemical 5]

(1A) 97114141 10 200900859 [於上述通式（1A)中，χ，表示以結基。其令，分子错m… 式⑻所表示之連表示2或3之整：有以上之金剛燒構造。〗 [化6](1A) 97114141 10 200900859 [In the above formula (1A), χ represents a base group. Therefore, the molecular error m... The combination represented by the formula (8) indicates the whole of 2 or 3: The above-mentioned diamond-fired structure. 〗 [Chemistry 6]

(3) 〇有取代基之碳數為分別獨立表示氫原子、可具 12之烷基、或可具有取代基之苯基。Y表不可具有取代基且具有金剛烷構造的二價連結基。之鍵結部位。；)；] 2述通式（3)中，與通式（1A)中之 M i-k Μ ^ ν η 土 m如[2]之著色樹脂組成物，其中，多元酸酐⑷包含四兀酸酐及/或二元酸酐、三元酸酐。 ° [4]一種者色樹脂組成物，其係至少包含（A)色材及（B) 有機黏σ知】者，其特徵在於：⑻有機黏合劑包含酸值為 10 mg KOH/g以上之驗可溶性不飽和樹脂，該驗可溶性不，飽和樹脂係藉由使以下述通式⑴所表示之環氧化合物⑷ 及/或以下it通式（1A)所表示之環氧化合物⑷與含有不飽和基之賴⑻之反應物，與多元酸酐⑷反應而獲得；夕元自文酐（d)包含四元酸酐及/或二元酸酐、三元酸酐。 [化7] 97114141 11 200900859(3) The carbon number of the substituent is a phenyl group which independently represents a hydrogen atom, an alkyl group which may have 12 or a substituent. Y represents a divalent linking group which may have a substituent and has an adamantane structure. Bonding part. ;);] 2 in the general formula (3), and the coloring resin composition of M ik Μ ^ ν η in the general formula (1A), such as [2], wherein the polybasic acid anhydride (4) comprises tetraphthalic anhydride and/or Or a dibasic acid anhydride or a tribasic acid anhydride. [4] A color resin composition comprising at least (A) a color material and (B) an organic viscosity, wherein: (8) the organic binder contains an acid value of 10 mg KOH/g or more. The soluble unsaturated resin is not soluble, and the saturated resin is obtained by the epoxy compound (4) represented by the following general formula (1) and/or the epoxy compound (4) represented by the following general formula (1A). The reactant of the base (8) is obtained by reacting with the polybasic acid anhydride (4); the ionic anhydride (d) comprises a tetrabasic acid anhydride and/or a dibasic acid anhydride and a ternary acid anhydride. [化7] 97114141 11 200900859

[於上述通式（1)中，X表示以下述通式（2a)或（2b)所表示之連結基。其中，分子構造中含有一個以上之金剛烷構造。1表示2或3之整數。 [化8][In the above formula (1), X represents a linking group represented by the following formula (2a) or (2b). Among them, the molecular structure contains more than one adamantane structure. 1 represents an integer of 2 or 3. [化8]

(2b) (於上述通式（2a)及（2b)中，R1〜R4、Ri3〜Rl5分別獨立表示可具有取代基之金剛烷基、氫原子、可具有取代基之碳數為1〜12之烷基、或可具有取代基之苯基。於上述通式（2a)及（2b)中，*表示與通式（1)中之環氧丙氧基之鍵結部位。）] (j [化 9 ] (ΙΑ) T° h2 cypH2)1 示之連造〇 1 [於上述通式（1Α)中，X’表示以下述通式（3)所表結基。其中’分子構造中含有一個以上之金剛燒構表示2或3之整數。 [化 10] 97114141 12 (3) 200900859(2b) (In the above formulas (2a) and (2b), R1 to R4 and Ri3 to Rl5 each independently represent an adamantyl group which may have a substituent, a hydrogen atom, and a carbon number which may have a substituent of 1 to 12 An alkyl group or a phenyl group which may have a substituent. In the above formulas (2a) and (2b), * represents a bonding site with a glycidoxy group in the formula (1).)] (j (ΙΑ9) (T) h2 cypH2) 1 shows the hydrazine 1 [In the above formula (1 Α), X' represents a group represented by the following formula (3). Wherein the 'molecular structure contains more than one diamond, representing an integer of 2 or 3. [化 10] 97114141 12 (3) 200900859

有取代基之碳數為 ,^ ^ ^ ^ 1 之烷基、或可具有取代基之苯土 \不可具有取代基且具有金剛烷構造的二價連結基。 f：之：式Ο)中’ *表示與通式(U)中之環氧丙氧基之鍵結部位。）j [5]如[2]至[4]中述通式（3)中之γ係 [化 11] 任一項之著色樹脂組成物，其中，以下式（4)或（5)所表示之連結基。上The carbon group having a substituent is an alkyl group of ^ ^ ^ ^ 1 or a benzene having a substituent, and a divalent linking group having a substituent and having an adamantane structure. f: where: * in the formula Ο) indicates a bonding site with a glycidoxy group in the formula (U). [5] The colored resin composition of any one of the γ series [11] in the above formula (3) in [2] to [4], wherein the formula (4) or (5) is represented by the following formula (4) or (5) Linkage. on

(5) 之鍵結部位。] *表示與通式（3)中之苯環，其中，以且4個以下 [6 ]如[1 ]至[5 ]中任—項之著色樹脂組成物上述通式㈤或(2b)所表示之X具有2個以上之金剛烧構造。 [1]至[W任—項之著色樹脂上述通式⑴所表示之产…又御具中，以表衣乳化5物（a)係以下述通式（7)所 97114141 13 200900859 [化 12](5) The bonding part. ] * represents a benzene ring in the formula (3), wherein, in the above formula (5) or (2b), and 4 or less [6], such as any one of [1] to [5] The X shown has two or more diamond-fired structures. [1] to [W---------------------------------------------------------------------------------------------------------- ]

(7) p [於通式⑺巾，、r25分別獨立表示可具有取代基之金剛烷基、氫原子、可具有取代基之碳數為1〜12之烷基、或可具有取代基之苯基。通式（7)中所示之金剛烷基可具有取代基。] I ] [2 ]至[7 ]中任一項之著色樹脂組成物，其中，以述^式（1A)所表不之環氧化合物（&，）係以下述通式（6 戶斤表示。 [化 13](7) p [In the formula (7), r25 each independently represents an adamantyl group which may have a substituent, a hydrogen atom, an alkyl group which may have a substituent having 1 to 12 carbon atoms, or a benzene which may have a substituent base. The adamantyl group represented by the formula (7) may have a substituent. The coloring resin composition according to any one of the above [1], wherein the epoxy compound (&,) represented by the formula (1A) is represented by the following formula (6 kg) Said. [Chemistry 13]

取代基之H): ’ R:〜R23分別獨立表示氫原子、可具有通式（6)中1 斤為1〜12之烧基、或可具有取代基之苯基。 r所不之金剛烷基可具有取代基。] 97114141 200900859 [9]如[1]至[8]中任— 述通式⑴中之乂之八早：’者色树月曰組成物’其中，上刀子頁為200以上且1 000以下。 [10 ]如[2 ]至[91 中# — τε β 項之者色樹脂組成物，其中，上 = 之分子量為2QQ^mT。以上述、U[10]中任—項之著色樹脂組成物，其中，以上所表示之環氧化合物(a)之環氧當量為21〇以上且4 5 0以下。、[12]如[2]至[11]中任—項之著色樹脂組成物，其中，以上述通式（1A)所表示之環氧化合物（ $ 210以上且450以下〇衣乳田置為物[1ΓΓ[2:、[3]、[5]至[12]中任一項之著色樹脂組成、、中’夕兀醇(c)係自三羥甲基丙烷、二一三羥甲基丙烷、季戊四醇、二季戊四醇、三經甲基乙烷…"_ 丙三醇所組成群組中選擇之1種或2種以上之多元醇。一 Π4]如m至[13]中任—項之著色樹脂組成物，其中，二兀酸酐係偏苯三酸酐及/或六氫偏苯三酸酐。 [15]如[1]至[14]中任一項之著色樹脂組成物，其中，上述鹼可溶性不飽和樹脂之重量平均分子量為2,〇〇〇以上且20,000以下。 + [16]如[1]至[15]中任一項之著色樹脂組成物，其中，著色樹脂組成物進一步包含（C)分散劑。 [17]如[1]至[16]中任一項之著色樹脂組成物，其中，著色樹脂組成物進一步包含（E)單體。 [18 ]如[1 ]至[17 ]中任一項之著色樹脂組成物，其中， 97114141 15 200900859 著色樹脂組成物進一步包含（D)光聚合起始劑。 .[19 ]如[1 ]至[18 ]中任一項之著色樹脂組成物，其中， (A)色材之含量於著色樹脂組成物之總固形分中，占％〜 70重量％。 [20]如[1]至[19]中任一項之著色樹脂組成物，其中， (A)色材含有黑色色材。 : [21]一種彩色濾光片，其特徵在於：透明基板上，具有使用[1]至[20]中^壬-項之著色樹脂組成物而形成之像素或黑色矩陣。 [22] —種液晶顯示裝置，其係使用[21]之彩色濾光片而製作。 [23] 種有機EL顯示器，其係使用[21 ]之彩色濾光片而製作。 ’ 根據本發明，可提供一種著色樹脂組成物，其係即便以高濃度含有顏料或碳黑等色材之情況，靈敏度及溶解性之〇平衡亦優異，進而所得之圖像之邊緣形狀或錐形形狀之銳度、與基板之密著性、表面平滑性、抗浮渣性、耐熱性優異者。而且，藉由使用上述著色樹脂組成物，可提供一種H) of the substituent: R' to R23 each independently represent a hydrogen atom, and may have a phenyl group of 1 to 12 in the formula (6) or a phenyl group which may have a substituent. The adamantyl group which r does not have may have a substituent. 97114141 200900859 [9] As in [1] to [8] - eight of the above-mentioned formula (1): 'the color tree sap composition', wherein the upper knife page is 200 or more and 1,000 or less. [10] The resin composition of [2] to [91, ## τε β, wherein the molecular weight of upper = 2QQ^mT. The colored resin composition of the above-mentioned item [10], wherein the epoxy compound (a) represented by the above has an epoxy equivalent of 21 Å or more and 450% or less. [12] The colored resin composition of any one of [2] to [11], wherein the epoxy compound represented by the above formula (1A) ($210 or more and 450 or less The coloring resin composition of any one of [1ΓΓ[2:, [3], [5] to [12], and the middle oxime (c) is derived from trimethylolpropane and ditrimethylol One or more selected from the group consisting of propane, pentaerythritol, dipentaerythritol, and tri-methylethane..."_ glycerol. 1) 4] m to [13] The coloring resin composition of the above-mentioned alkali-soluble unsaturated resin, which is a coloring resin composition according to any one of [1] to [14], wherein the phthalic anhydride is a phthalic acid anhydride, or a hexahydrotrimellitic anhydride. The colored resin composition of any one of [1] to [15], wherein the colored resin composition further contains (C) a dispersing agent. [17] The colored resin composition according to any one of [1] to [16] wherein the colored resin composition further comprises (E) a monomer. [18] as in any one of [1] to [17] The coloring resin composition of the present invention, wherein the coloring resin composition further comprises (D) a photopolymerization initiator, wherein the coloring resin composition of any one of [1] to [18], wherein The coloring resin composition of any one of [1] to [19], wherein the coloring resin composition of the coloring resin composition is in the total solid content of the coloring resin composition, wherein (20) A) The color material contains a black color material. [21] A color filter characterized in that the transparent substrate has a pixel formed using the colored resin composition of [1] to [20]. Or a black matrix. [22] A liquid crystal display device produced by using the color filter of [21]. [23] An organic EL display produced by using a color filter of [21]. According to the present invention, it is possible to provide a colored resin composition which is excellent in sensitivity and solubility balance even when a color material such as a pigment or carbon black is contained in a high concentration, and the edge shape or the taper of the obtained image is further obtained. Sharpness of shape, adhesion to substrate, surface smoothness, scum resistance, heat resistance Sexually superior. Moreover, by using the above colored resin composition, a kind can be provided

1同°口夤彩色濾光片，進而高品質液晶顯示裝置或有機EL 顯示器。【實施方式】以下，具體說明本發明之實施形態，但本發明並未限定於以下實施形態，可於其要旨範圍内進行各種變更而實施。 97114141 16 200900859 再者，於本發明中，所謂r(f基）丙烯酸」意指「丙烯酸及/或甲基丙烯酸」，「（甲基）丙烯酸酯」、「（子基）丙烯醯基」亦相同。又，所謂「（多）羥基」意指「羥基及/或多羥基」。於本發明中’所謂「總固形分」意指著色樹脂組成物中或下述油墨中所含之溶劑以外之總成分。於本發明中，所謂重量平均分子量係指藉由Gpc(凝膠滲透層析法）測定之以聚苯乙烯換算之重量平均分子量又，於本發明中，所謂「胺值」，只要未特別說明，則表不有效_分換算之隸，制旨與分散狀固形分每ι g之驗量等量之K0H之重量表里里尸/r衣不之值。再者’測定方法於其後加以敍述。 [著色樹脂組成物] 0 首先就本叙明之著色樹脂組成物加以說明。機著色樹脂組成物係至少包含⑷色材及⑻有 =黏合劑者，其特徵在於含有特定樹脂作為⑻有機黏合 [調配成分] U)色材之色材，意指將 /斤謂本發明之I色樹月旨組成物中所使用著色樹脂組成物著色之成分。而作為色材，可使用染顏料， 5，較佳為顏料。作為顏料但就耐熱性、耐光性等方面，可使用藍色顏料、綠色顏 97114141 17 200900859 料、紅色顏料、黃色顏料、紫色顏料、橙色顏料、棕色顏料、黑色顏料等各種顏色的顏料。又，作為其構造，除了偶氮系、敗青系、喧吖酮（quinacr idone)系、苯并咪η坐酮系異°引α朵琳_ (isoindol inone)系、二β号啡系、陰丹士林系、Κ系等有機顏料以外，亦可利用各種無機顏料等。以下’以顏料編號表示可使用之顏料之具體例。以下舉出之 > 「C. L顏料紅2」等用語意指顏料索引（c. I.)。 0 作為紅色顏料，可舉出C.I.顏料紅1、2、3、4、5、6、 7 、 8 、 9 、 12 、 14 、 15 、 16 、 17 、 21 、 22 、 23 、 31 、 32 、 37、38、4卜 47、48、48」、48:2、48:3、48:4、49、49:1、 49:2 > 50：1 ^ 52:1 ^ 52:2 ' 53 > 53:1 > 53:2 ^ 53:3 > 57 > 57:：1、57:2、58:4、60、63、63:卜 63:2、64、64:卜 68、 69、8卜 81:卜 81:2、81:3、8卜 4、83、88、90:1、101、 101:1、104、108、108:1、109、112、113、114、122、 123 、 144 、 146 、 147 、 149 、 151 、 166 、 168 、 169 、 170 、 (J 172 、 173 、 174 、 175 、 176 、 177 、 178 、 179 、 181 、 184 、 185、187、188、190、193、194、200、202、206、207、 -208 、 209 、 210 、 214 、 216 、 220 、 221 、 224 、 230 、 231 、 • 232 、 233 、 235 、 236 、 237 、 238 、 239 、 242 、 243 、 245 、 247 、 249 、 250 、 251 、 253 、 254 、 255 、 256 、 257 、 258 、 259 、 260 、 262 、 263 、 264 、 265 、 266 、 267 、 268 、 269 、 270、271、272、273、274、275、276。其中，較佳的可舉出 C. I.顏料紅 48:1、122、168、177、202、206、207、 209、224、242、254,更佳的可舉出 c. I.顏料紅 177、209、 97114141 18 200900859 224 、 254 。作為氣色顏料’可舉出C. I.顏料藍卜1:2、9、14、15、 15:卜 15:2、15:3、15:4、15··6、16、17、19、25、27、 28、29、33、35、36、56、56]、60、61、61 :卜 62、63、 66 ' 67 ' 68、71、72、73、74、75、76、78、79。其中，較佳的可舉出C.1.顏料藍15、15:1、15:2、15:3、15:4、 :15 : 6，更佳的可舉出C. I.顏料藍15 : 6。 ^ 作為綠色顏料’可舉出c. 1.顏料綠 13、14、15、17、18、19、26、36、45、48、50、5卜 54、 55。其中，較佳的可舉出c. j.顏料綠7、36。作為黃色顏料，可舉出c. ί .顏料黃1、1: i、2、3、4、 5 、 6 、 9 、 10 、 12 、 13 、 14 、 16 、 17 、 24 、 31 、 32 、 34 、 35 、 35:1 、 36 、 36:1 、 37 、 37:1 、 40 、 41 、 42 、 43 、 48 、 53 、 55 、 61 、 62 、 62:1 、 63 、 65 、 73 、 74 、 75 、 81 、 83 、 87 、 93 、 94 、 95 、 97 、 1〇〇、 1〇1 、 104 、 105 、 108 、 109 、 (J Π0、111、116、117、119、120、126、127、127:1、128、 129、133、134、136、138、139、142、147、148、150、 ' 151、153、154、155、157、158、159、160、161、162、 • 163 、 164 、 165 、 166 、 167 、 168 、 169 、 170 、 172 、 173 、 174 、 175 、 176 、 180 、 181 、 182 、 183 、 184 、 185 、 188 、 189、190、191、191:1、192、193、194、195、196、197、 198 、 199 、 200 、 202 、 203 、 204 、 205 、 206 、 207 、 208 。其中’較佳的可舉出C. I.顏料黃83、117、129、138、139、 150、154、155、180、185，更佳的可舉出c. I.顏料黃83、 97114141 19 200900859 138、 139、 150、 18〇。 5 、 13 、 16 、 39、43、46、 Ή 、 72 、 73 、 C. I.顏料禮· 作為撥色顏料，可舉出C. I·顏料橙1、2 17、19、20、2卜 22、23、24、34、36、38、 “、49、6卜 62、64、65、67、68、69、70、 74 75、77、78、79。其中，較佳的可舉出 38 、 71 。1 same port color filter, and then high quality liquid crystal display device or organic EL display. [Embodiment] The embodiments of the present invention are specifically described below, but the present invention is not limited to the embodiments described below, and various modifications can be made without departing from the spirit and scope of the invention. 97114141 16 200900859 In the present invention, the term "r(f-)acrylic acid" means "acrylic acid and/or methacrylic acid", "(meth) acrylate", "(sub-based) acrylonitrile group" the same. Further, "(poly)hydroxyl" means "hydroxyl and/or polyhydroxy". In the present invention, the term "total solid content" means a total component other than the solvent contained in the colored resin composition or the ink described below. In the present invention, the weight average molecular weight refers to a weight average molecular weight in terms of polystyrene measured by Gpc (gel permeation chromatography), and in the present invention, the "amine value" is not particularly specified. , the table is not valid _ sub-conversion, the purpose of the system and the dispersion of the solid shape of each ι g of the same amount of K0H weight in the corpse / r clothing is not worth. Further, the measurement method will be described later. [Colored Resin Composition] 0 First, the coloring resin composition described herein will be described. The machine-colored resin composition is at least (4) a color material and (8) has a binder, and is characterized in that it contains a specific resin as (8) an organic binder [formulation component] U) a color material, which means that the invention is A component colored by the colored resin composition used in the composition of the I color tree. As the color material, a dye can be used, 5, preferably a pigment. As the pigment, in terms of heat resistance, light resistance, and the like, a pigment of various colors such as a blue pigment, a green pigment, a red pigment, a yellow pigment, a purple pigment, an orange pigment, a brown pigment, and a black pigment can be used. Further, as the structure, in addition to the azo system, the cyanidin, the quinac idone system, the benzopyran yone, the isoindol inone system, the second β-morphine system, In addition to organic pigments such as indanthrene and lanthanide, various inorganic pigments and the like can be used. Specific examples of the pigments that can be used are indicated by pigment numbers. The following terms > "C. L Pigment Red 2" and the like mean the pigment index (c. I.). 0 As the red pigment, CI Pigment Red 1, 2, 3, 4, 5, 6, 7, 8, 9, 12, 14, 15, 15, 16, 17, 21, 22, 23, 31, 32, 37 , 38, 4, 47, 48, 48", 48:2, 48:3, 48:4, 49, 49:1, 49:2 > 50:1 ^ 52:1 ^ 52:2 ' 53 > 53:1 > 53:2 ^ 53:3 > 57 > 57::1, 57:2, 58:4, 60, 63, 63: Bu 63:2, 64, 64: Bu 68, 69, 8 Bu 81: Bu 81:2, 81:3, 8 Bu 4, 83, 88, 90:1, 101, 101:1, 104, 108, 108:1, 109, 112, 113, 114, 122, 123 , 144, 146, 147, 149, 151, 166, 168, 169, 170, (J 172, 173, 174, 175, 176, 177, 178, 179, 181, 184, 185, 187, 188, 190, 193 , 194, 200, 202, 206, 207, -208, 209, 210, 214, 216, 220, 221, 224, 230, 231, • 232, 233, 235, 236, 237, 238, 239, 242, 243 , 245, 247, 249, 250, 251, 253, 254, 255, 256, 257, 258, 259, 260, 262, 263, 264, 2 65, 266, 267, 268, 269, 270, 271, 272, 273, 274, 275, 276. Among them, CI Pigment Red 48:1, 122, 168, 177, 202, 206, 207 are preferred. More preferably, 209, 224, 242, 254, c. I. Pigment Red 177, 209, 97114141 18 200900859 224, 254. As a gas color pigment, CI pigment blue b 1:2, 9, 14 , 15, 15: Bu 15:2, 15:3, 15:4, 15··6, 16, 17, 19, 25, 27, 28, 29, 33, 35, 36, 56, 56], 60, 61, 61: Bu 62, 63, 66 ' 67 ' 68, 71, 72, 73, 74, 75, 76, 78, 79. Preferred examples thereof include C.1. Pigment Blue 15, 15:1, 15:2, 15:3, 15:4, and 15:6, and more preferably C.I. Pigment Blue 15:6. ^ As a green pigment, c. 1. Pigment green 13, 14, 15, 17, 18, 19, 26, 36, 45, 48, 50, 5, 54, 55. Among them, preferred are c. j. Pigment Green 7, 36. As the yellow pigment, c. ί. Pigment Yellow 1, 1: i, 2, 3, 4, 5, 6, 9, 10, 12, 13, 14, 16, 17, 14, 24, 31, 32, 34 , 35, 35:1, 36, 36:1, 37, 37:1, 40, 41, 42 , 43 , 48 , 53 , 55 , 61 , 62 , 62:1 , 63 , 65 , 73 , 74 , 75 , 81, 83, 87, 93, 94, 95, 97, 1〇〇, 1〇1, 104, 105, 108, 109, (J Π0, 111, 116, 117, 119, 120, 126, 127, 127 : 1, 128, 129, 133, 134, 136, 138, 139, 142, 147, 148, 150, ' 151, 153, 154, 155, 157, 158, 159, 160, 161, 162, • 163, 164 , 165 , 166 , 167 , 168 , 169 , 170 , 172 , 173 , 174 , 175 , 176 , 180 , 181 , 182 , 183 , 184 , 185 , 188 , 189 , 190 , 191 , 191 : 1, 192 , 193 194, 195, 196, 197, 198, 199, 200, 202, 203, 204, 205, 206, 207, 208. Among them, preferred are CI pigment yellow 83, 117, 129, 138, 139. 150, 154, 155 180, 185, more preferably c. I. Pigment Yellow 83, 97114141 19 200900859 138, 139, 150, 18〇. 5, 13, 16, 39, 43, 46, Ή, 72, 73, CI pigment礼· As a coloring pigment, C. I·Pigment Orange 1, 2 17, 19, 20, 2 Bu 22, 23, 24, 34, 36, 38, “, 49, 6 Bu 62, 64, 65 67, 68, 69, 70, 74 75, 77, 78, 79. Among them, 38 and 71 are preferable.

作為紫色顏料，可舉出c. I.顏料紫卜J :卜2、2.2、3、 3:1、3:3、5、5:1、14、15、16、19、23、25 27、、29: 3卜 32、37、39、42、44、47、49、50。其中，較佳的可舉出c.i.顏料紫19、23,更佳的可舉出C I.顏料紫23。作為黑色色材，可單獨使用黑色色材，或者可使用混合紅、綠、藍色等之色材而成之黑色色材。該等黑色色材可自無機或有機顏料、染料中適宜選擇，可單獨使用1種或者將複數多種混合使用。作為單獨之黑色色材’可舉出碳黑、乙炔黑、燈黑、骨黑、石墨、鐵黑、苯胺黑、花青黑、鈦黑等。該等中，就遮光率、圖像特性之觀點而言，尤佳為碳黑、鈦黑。作為碳黑之市售品之例子，可舉出如下所述之品牌。三菱化學公司製造：MA7、MA8、MA11、MA100、MA220、 MA230 、 # 52 、 # 50 、 # 47 、 # 45 、 # 2700 、 # 2650 、 # 2200 、#1〇〇〇、# 990 、# 9〇〇等。 DEGUSSA 公司製造：Pr intex95、Pr intex90、Pr intex85、As the purple pigment, c. I. Pigment Violet J: Bub 2, 2.2, 3, 3:1, 3:3, 5, 5:1, 14, 15, 16, 19, 23, 25 27, 29: 3 Bu 32, 37, 39, 42, 44, 47, 49, 50. Among them, c.i. Pigment Violet 19 and 23 are preferable, and C I. Pigment Violet 23 is more preferable. As the black color material, a black color material may be used alone, or a black color material obtained by mixing color materials such as red, green, and blue may be used. These black color materials may be appropriately selected from inorganic or organic pigments and dyes, and may be used singly or in combination of plural kinds. Examples of the black color material alone include carbon black, acetylene black, lamp black, bone black, graphite, iron black, aniline black, cyanine black, and titanium black. Among these, carbon black and titanium black are particularly preferable from the viewpoint of light blocking ratio and image characteristics. As an example of a commercial item of carbon black, the brand mentioned below is mentioned. Mitsubishi Chemical Corporation manufactures: MA7, MA8, MA11, MA100, MA220, MA230, #52, #50, #47, #45, #2700, #2650, #2200, #1〇〇〇, #990, #9〇 Hey. Manufactured by DEGUSSA: Pr intex95, Pr intex90, Pr intex85,

Printex75 、 Printex55 、 Printex45 、 Printex40 、Printex75, Printex55, Printex45, Printex40,

Printex30 、 Printex3 、 PrintexA 、 PrintexG 、 Special 97114141 20 200900859Printex30, Printex3, PrintexA, PrintexG, Special 97114141 20 200900859

Black550'Special Black350'Special Black250'Special BlacklOO 等。 CABOT 公司製造：Monarch460、Monarch430、 Monarch280 、 Monarchl20 、 Monarch800 、 Monarch4630 、 REGAL99、REGAL99R、REGAL415、REGAL415R、REGAL250、 REGAL250R、REGAL330、BLACK PEARLS480、PEARLS130 等。 , COLUMBIAN CARBON 公司製造：RAVEN11、RAVEN15、 RAVEN30 ' RAVEN35 ' RAVEN40 ' RAVEN410 > RAVEN420 ' RAVEN450 > RAVEN500 ' RAVEN780 ' RAVEN850 ' RAVEN890H ' RAVEN1000 、 RAVEN1020 、 RAVEN1040 等。作為鈦黑之製造方法，存在如下方法：將二氧化鈦與金屬鈦之混合體，於還原環境中加熱，使其還原之方法（曰本專利特開昭49-5432號公報）；將四氯化鈦之高溫水解所獲得之超微細二氧化鈦，於含氫之還原環境中進行還原之方法（日本專利特開昭57-205322號公報）；將二氧化鈦 f》或氫氧化鈦，於氨存在下進行高溫還原之方法（曰本專利特開昭60-65069號公報、日本專利特開昭61-201610號 - 公報）；於二氧化鈦或氳氧化鈦上附著釩化合物，於氨存 . 在下進行高溫還原之方法（日本專利特開昭61-201610號公報）等，但並未限定於該等。作為鈦黑之市售品之例子’可舉出MITSUBISHI MATERIALS 公司製造之鈦黑 l〇S、12S、13R、13M、13M-C 等。其次，就將複數穆顏色之色材混合而成之黑色色材加以 97114141 21 200900859 說明。作為成為混合基礎之色材之具體例，可舉出維多利亞純藍（42595)、金胺 0(41000)、卡磁隆亮黃（Cathil〇nBlack550'Special Black350'Special Black250'Special BlacklOO and more. Made by CABOT: Monarch460, Monarch430, Monarch280, Monarchl20, Monarch800, Monarch4630, REGAL99, REGAL99R, REGAL415, REGAL415R, REGAL250, REGAL250R, REGAL330, BLACK PEARLS480, PEARLS130, etc. , COLUMBIAN CARBON Company: RAVEN11, RAVEN15, RAVEN30 ' RAVEN35 ' RAVEN40 ' RAVEN410 > RAVEN420 ' RAVEN450 > RAVEN500 ' RAVEN780 ' RAVEN850 ' RAVEN890H ' RAVEN1000 , RAVEN1020 , RAVEN1040 , etc . As a method for producing titanium black, there is a method in which a mixture of titanium oxide and titanium metal is heated in a reducing atmosphere to reduce it (Japanese Patent Laid-Open Publication No. SHO 49-5432); High-temperature hydrolysis of ultrafine titanium dioxide obtained by reduction in a hydrogen-containing reducing environment (Japanese Patent Laid-Open Publication No. SHO 57-205322); titanium dioxide f or titanium hydroxide in the presence of ammonia for high-temperature reduction A method of attaching a vanadium compound to titanium dioxide or ruthenium titanium oxide and depositing it in ammonia at a high temperature is carried out under the method (Japanese Patent Laid-Open No. Hei 60-65069, Japanese Patent Application Laid-Open No. Hei 61-201610-- Japanese Patent Laid-Open No. 61-201610, etc., but is not limited thereto. Examples of the commercially available product of titanium black include titanium black l〇S, 12S, 13R, 13M, 13M-C manufactured by MITSUBISHI MATERIALS. Next, a black color material obtained by mixing a plurality of color materials of a Mu color is described in the description of 97114141 21 200900859. Specific examples of the coloring material to be a mixed base include Victoria Pure Blue (42595), Auramine 0 (41000), and Caroline Bright Yellow (Cathil〇n).

Brilliant Flavin)(鹼性 13)、玫瑰紅 6GCP(45160)、玫瑰紅 B(45170)、番紅 OK70 :100(50240)、罌紅 χ(42080)、如.120/雷奥諾爾黃（1^〇11〇1丫611〇诃）（21090)、雷奥諾爾 -黃 GRO(21〇90) 、 Symuler 堅牢黃（Syrauler Fast p Yell〇w)8GF(21105)、聯笨胺黃 4T-564D(21095)、Symuler 堅牢紅（Symuler Fast Red)4015(12355)、雷奥諾爾紅 7B4401 (15850)、Fastogen 藍（Fastogen Blue)TGR-L· (74160)、雷奥諾爾藍SM(2615〇)、雷奥諾爾藍ES(顏料藍 15:6)、Li〇n〇gen紅GD(顏料紅168)、雷奥諾爾綠2YS(顏料綠36)等（再者，上述（）内之數字意指顏料索引（c. 又，進而關於其他可混合使用之顏料，若以C I.編號表示，則例如可舉出c. ί•黃色顏料20、24、86、93、1〇9、 U 110、117、125、137、138、147、148、153、154、166， C. I.橙色顏料 36、43、51、55、59、61，c· 1.紅色顏料 9、 97 、 122 、 123 、 149 、 168 、 177 、 18G 、 192 、 215 、 216 、 217、220、223、224、226、227、228、240 ’ C. I·紫色顏料 19、23、29、30、37、40、50, C. I 藍色顏料 15、15:1、 64’ C.I·綠色顏料7, C. I.棕色顏料23、 25 、 26 等。再者上述奴黑可與其他黑色或有色無機、有機顏料併用其中，因其他顏料之遮光性或圖像特性低於碳黑，故 97114141 22 200900859 於黑色矩陣用之情況，必然會限制混合比率。如上所述之色材可單獨使用丨種，亦可將2種以上併用。 /再者’於本發明之著色樹脂組成物包含黑色色材且用於 =ΤΊ^慮光片之黑色矩陣之情況’其圖像形成性明顯優異，故尤其理想。 (B)有機黏合劑， =明之著色樹脂組成物中所使用之有機黏合劑，包含 P / _1)〜（B-3)中任—項之鹼可溶性不飽和樹脂。含=?以下述通式(1)所表示之環氧化合物⑷與之羧酸⑻之反應物，與多元酸_應而獲寸之夂—值為10 mg—K0H/g以上之驗可溶性不飽和樹脂。 (B-2)措由使以下述通式⑴所表 /或以下述通式（1A)所表示夕庐各衣乳化口物U)及和A之跆舻r 衣氧化0物（a，）與含有不飽酐(土d)反靡之反應物’與多元醇（c)混合後，與多元酸酐（d)反應而獲得之酸值為 tj不餘㈣脂。上之驗可溶性 (B-3)藉由使以下述通式（ ‘ /或以下述通式（1A)所表^所表不之環氧化合物⑷及 .^ Λ )所表不之環氧化合物（a，）盥含有不# .和基之羧酸（b)之反應物，遍台人抑-缺有不飽 _ 一 - △ 、包含四凡酸酐及/或二元酸 -錢酐之多元酸酐⑷反應而獲以上之鹼可溶性不飽和樹脂。 X十0-Brilliant Flavin) (alkaline 13), rose red 6GCP (45160), rose red B (45170), red OK 70: 100 (50240), erythroid 420 (42080), such as .120 / Leonor Yellow (1^ 〇11〇1丫611〇诃)(21090), Leonor-Yellow GRO(21〇90), Symuler Fast yellow Yyr〇l 8GF(21105), phenylamine yellow 4T-564D(21095 ), Symerer Fast Red 4015 (12355), Leonor Red 7B4401 (15850), Fastogen Blue TGR-L (74160), Leonor Blue SM (2615〇), Leo Nord Blue ES (Pigment Blue 15:6), Li〇n〇gen Red GD (Pigment Red 168), Leonor Green 2YS (Pigment Green 36), etc. (again, the numbers in () above refer to the pigment index ( c. Further, as for other pigments which can be used in combination, as indicated by C I., for example, c. ί•Yellow pigments 20, 24, 86, 93, 1〇9, U 110, 117, 125 , 137, 138, 147, 148, 153, 154, 166, CI orange pigments 36, 43, 51, 55, 59, 61, c· 1. red pigments 9, 97, 122, 123, 149, 168, 177, 18G, 192, 215, 216, 217, 2 20, 223, 224, 226, 227, 228, 240 'C. I·Purple Pigments 19, 23, 29, 30, 37, 40, 50, C. I Blue Pigment 15, 15:1, 64' CI· Green pigment 7, CI brown pigment 23, 25, 26, etc. In addition, the above black can be used together with other black or colored inorganic and organic pigments, because other pigments have lower light-shielding or image characteristics than carbon black, so 97114141 22 200900859 In the case of the black matrix, the mixing ratio is inevitably limited. The color materials as described above may be used singly or in combination of two or more. Further, the coloring resin composition of the present invention contains black color materials. Moreover, it is particularly preferable because it is excellent in image formability. (B) Organic binder, organic binder used in the composition of the colored resin, including P / _1) ~ (B-3) - the alkali-soluble unsaturated resin of the formula - containing the reaction product of the epoxy compound (4) represented by the following general formula (1) and the carboxylic acid (8), and the polybasic acid It should be obtained as a solvent-soluble unsaturated resin with a value of 10 mg-K0H/g or more. (B-2) The treatment is carried out by the following formula (1) or by the following formula (1A), and the emulsification of the clothes U) and the oxidizing agent (a,) of A The acid value obtained by reacting with the polyhydric anhydride (d) after mixing with the polyol (c) containing the unsaturated anhydride (soil d) ruthenium (c) is tj not less than (iv) fat. The above-mentioned solvent (B-3) is an epoxy compound which is represented by the following formula ('or or the epoxy compound (4) and . . . which is represented by the following formula (1A)). (a,) 盥 contains not reacting with the carboxylic acid (b) of the base, and it is not enough to contain __-, including tetrabasic anhydride and/or dibasic acid-polyanhydride. The acid anhydride (4) is reacted to obtain the above alkali-soluble unsaturated resin. X ten 0-

Η -C—C一CHoH2 V (ϊ) rl 97114141 23 200900859 [於上述通式（1)中，X表杀以下述通式（2a)或（2b)所表不之連結基。其中，分子構造中具有一個以上之金剛烷構造。1表示2或3之整數。 [化 15]Η -C—C—CHoH2 V (ϊ) rl 97114141 23 200900859 [In the above formula (1), the X form is bonded to a linking group represented by the following formula (2a) or (2b). Among them, the molecular structure has more than one adamantane structure. 1 represents an integer of 2 or 3. [化15]

(於上述通式（2a)及（2b)中，R1〜R4、R13〜π分別獨立表示可具有取代基之金剛烷基、氫原子、可具有取代基之石炭數為1〜12之烧基、或可具有取代基之笨基。於上述通式（2a)及（2b)中’*表示與通式（！）中之環氧丙氧基之鍵結部位。）] [化 16](In the above formulae (2a) and (2b), R1 to R4 and R13 to π each independently represent an adamantyl group which may have a substituent, a hydrogen atom, and a calcined carbon group having a substituent having a number of from 1 to 12; Or a stupid group which may have a substituent. In the above formulas (2a) and (2b), '* indicates a bond site with a glycidoxy group in the formula (!).)] [Chem. 16]

[於上述通式（1A)中’X’表示以下述通式（3)所表示之連結基。其中’分子構造中含有一個以上之金剛烷構造。表示2或3之整數。 [化 17][In the above formula (1A), 'X' represents a linking group represented by the following formula (3). Among them, the molecular structure contains more than one adamantane structure. Represents an integer of 2 or 3. [Chem. 17]

97114141 24 200900859 (於上述通式（3)Φ 5 有取代基之碳數為/R〜R12分別獨立表示氫原子、可具基。Y表示可具有敢12之烷基、或可具有取代基之苯於上述通式（3)代基且具有金剛烷構造的二價連結基。之鍵結部位。）]’ *表示與通式（U)t之環氧丙氧基 <環氧化合物（a)、（a，）> 示之連式（3)中’ Y較佳為以下述通式⑷或（5)所表 [化 18]97114141 24 200900859 (The carbon number of the substituent of the above formula (3) Φ 5 is /R~R12 each independently represents a hydrogen atom, and may have a group. Y represents an alkyl group which may have 12 or may have a substituent. a bonding site of a divalent linking group of benzene to the above formula (3) and having an adamantane structure.)]* represents a glycidoxy group & epoxy compound of the formula (U)t a), (a,) > In the formula (3), 'Y is preferably expressed by the following formula (4) or (5) [Chem. 18]

(4)(4)

(5) 環 [式（4) (5)可具有取代基，*表示與通式⑶ 之鍵結部位。] 承又，以上述通式（2a)、（2b)所表示之χ，較佳為且個以上且4個以下之金剛烷構造。若金剛烷構造有存在耐顯影液性下降導致解析力不良之傾向。」尤其是’以上述通式（1)所表示之環氧化合物（a)，_ 為以下述通式（7)所表示，以上述通式（1A)所表示之二二化合物（a’）較佳為以下述（6 )所表示。 &氣 [化 19] 97114141 25 200900859(5) Ring [Formula (4) (5) may have a substituent, and * represents a bond site with the formula (3). Further, the oxime represented by the above formulas (2a) and (2b) is preferably one or more and four or less adamantane structures. If the adamantane structure has a tendency to deteriorate in developer resistance, the analytical force tends to be poor. In particular, the epoxy compound (a) represented by the above formula (1), _ is a compound represented by the following formula (7), and the compound (a') represented by the above formula (1A) Preferably, it is represented by the following (6). & gas [Chem. 19] 97114141 25 200900859

..............具有〇取代基之碳數為卜12之絲、或可具有取代基之苯基。 =式⑺中’m別獨立表示可具有取代基之金 ^基、氫原子、可具有取代基«數為卜12之烧基、或可具有取代基之苯基。通式（6)、（7)所示之金剛烷基可具有取代基。] 作為上述通式㈤、⑽、（3)、（6)、⑺中之r1〜r25 之碳數為卜12之烧基，較佳可舉出碳數為卜⑺之烧基。 u 、二，作為該等烷基可具有之取代基，可舉出齒素原子、 :錄：數為1〜1〇之烧氧基、碳數為2〜10之烯基、笨土羧基、硫基（sulfanyl)、膦基、胺基 '硝基等。 R =射具有之取代基，可舉㈣素原子、㈣、碳數為1〜10之烷氧基、碳數為硫基、膦基、驗、硝㈣。G之縣、祕、羧基、又，作為上述通式㈤、⑽令之r1〜r4、ri 剛烷基’通式⑶之γ中所含之金之金剛始r j夢，、s斗、广7、+ ^ ^通式（6)中之金職％ ’通式⑺中之金剛炫基，通式⑺中之之 97114141 26 200900859 金剛烧基，式⑷、⑸之金剛烧環可具有之取代基，可兴出鹵素原子、經基、碳數為卜1〇之烧氧基牛 10之稀基、苯基、羧基、硫基、膦基、胺基、硝基為等2。〜 ^上切式⑻中«尤佳輕基、齒素原子、燒氧基、婦基或笨基。元又，於上述通式⑺中，r24、r25尤烧氧基、烯基或苯基。國京原子、 Ο Ο 通式⑴中所示之乂及通式(1A)中所示之 :佳為以上且_以下。若…之分子成為低靈敏度之^1。良之傾向，若超過圈，則存在所：干η上1丄所表示之環氧化合物⑷及以通式(ία) 斤=壞氧化合物(a，)之環氧當量，較佳為2 ^圭為230以上。又’該環氧當量較佳為45〇以下，更佳 =400 U下。若環氧化合物⑷及環氧化 =，，則有時耐驗性不充分，若超過45〇: —成之有機黏合劑之靈敏度下降之傾向。 =氧化合=a)可單獨使用1種，亦可將2種以上組合以上έ ％减合物（a’）可單獨使用1種，亦可將2種及二：：用亦可將環氧化合物U)之1種或2種以上 5物(〇之1種或2種以上併用。利：甲：口物U)及環氧化合物“，)可使用市售者，亦可用眾所周知之方法’自如下所述之苯驗化合物合成而使 97114141 27 200900859 Ο [化 20].............. A phenyl group having a fluorene substituent having a carbon number of 12 or a substituent. In the formula (7), "m" independently represents a metal group which may have a substituent, a hydrogen atom, a phenyl group which may have a substituent "number", or a phenyl group which may have a substituent. The adamantyl group represented by the formulae (6) and (7) may have a substituent. As the alkyl group having the carbon number of r1 to r25 in the above formulae (5), (10), (3), (6), and (7), it is preferably a group having a carbon number of (7). u and 2, as a substituent which the alkyl group may have, a dentate atom, an alkoxy group having a number of 1 to 1 fluorene, an alkenyl group having 2 to 10 carbon atoms, a stupid carboxyl group, Sulfany, phosphino, amine 'nitro, and the like. R = a substituent having a shot, which may be a (tetra) atom, (iv), an alkoxy group having a carbon number of 1 to 10, a carbon number of a sulfur group, a phosphino group, a test, and a nitrate (tetra). The county of G, the secret, the carboxyl group, and the gold in the gamma of the above formula (5), (10), r1 to r4, ri-cycloalkyl-formula (3), and the gamma of the gold , + ^ ^% of the gold in the general formula (6) 'The ruthenium group in the formula (7), 97114141 26 in the formula (7) 200900859 The diamond ring, the ring of the diamond ring of the formula (4), (5) may have a substituent The halogen atom, the mercapto group, the carbon number of the calcined cow 10, the phenyl group, the carboxyl group, the thio group, the phosphino group, the amine group and the nitro group can be derived. ~ ^Top cut (8) «Ultra light base, dentate atom, alkoxy group, base group or stupid base. Further, in the above formula (7), r24 and r25 are an alkoxy group, an alkenyl group or a phenyl group. Guojing Atom, Ο 乂 shown in the formula (1) and in the formula (1A): preferably more than _. If the molecule of ... becomes a low sensitivity ^1. If the tendency is good, if it exceeds the circle, there is an epoxy compound (4) represented by 1 干 on the dry η and an epoxy equivalent of the general formula (ία) kg = bad oxygen compound (a,), preferably 2 ^ It is 230 or more. Further, the epoxy equivalent is preferably 45 Å or less, more preferably = 400 Å. When the epoxy compound (4) and the epoxidation =, the testability may be insufficient, and if it exceeds 45 Å: the sensitivity of the organic binder tends to decrease. = Oxidation = a) It can be used alone or in combination of two or more. The % reduction compound (a') can be used alone or in combination of two or two: One or two or more of the compounds U) (one or two or more of them) may be used commercially or by a known method. From the synthesis of benzene compounds as described below, 97114141 27 200900859 Ο [Chem. 20]

(9b)(9b)

(10) R15分別與通式 [上述通式（9a)、（9b)、（1〇)中之Rl (2a)、（2b)、（3)之意義相同。] 如下方法獲得環氧化合物⑷:於以通式 ()或⑽所表示之化合物與過剩之表氯醇、表漠醇等表 ο 合Γ，預先添加氫氧化鋼、氫氧化鉀等驗金^氧化物’或者—面添加—面於2〇〜12代之溫度下 =1〜1M、時’藉此可獲得通式⑴中之χ為以上述通式（2a)或（2b)所表示之連結基的環氧化合物⑷。又’_可藉由如下方法獲得環氧化合物（a):於以通式（10) 所表不之化合物與過剩之表氣醇、㈣醇等表鹵醇之溶解此合物中’預先添加氫氧化鈉、氫氧化鉀等鹼金屬氫氧化物，或者一面添加一面於2〇〜12〇ΐ之溫度下反應丨〜1〇小時，藉此可獲得通式（1Α)中之χ，為以上述通式（3)所表示的環氧化合物（a，）。於該獲得環氧化合物（a)及環氧化合物（a，）之反應中， 97114141 28 200900859 作為驗金屬氫氧化物，可使用其水溶液。於該情況下，可使用如下方法：將該驗金屬氳氧化物之水溶液連續添加至反應糸統内，並且於減壓下或常壓下連續㈣水及表齒醇進而進行分液，去除水分，使表齒醇連續返回反應系統内。〜ν' 〇 ϋ 又，藉由如下方；去，亦可製造以通式⑴所表示之環氧化合物⑷或以通式（1Α)所表示之環氧化合物（〇 :於以上述通式㈤、⑽或（10)所表示之化合物與表齒醇之溶 f混合物中，添加氯化四甲銨、漠化四甲銨、氯化三甲基苄基銨等四級銨鹽作為觸媒，於5〇〜15〇它下反應丨〜^ ^時’獲得以通式（9a)、（9b)或⑴）所表示之化合物之齒醇醚化物’於其中添加鹼金屬氳氧化物之固體或水溶液， :侧〜⑽之溫度下反應卜⑺小時，而使之脫齒化虱（閉環）。上述反應中之表_醇之使用量係相對於以通式（9U、 ⑽)或(1〇)所表示之化合物之羥基i當量，通常使用卜 2〇莫耳，較佳為2〜10莫耳。又，驗金屬氯氧化物之使用量係相對於以通式（9a)、（9b)或（1〇)所表示之化合物之羥基1當量，通常使用0 8〜15莫耳，較佳為〇·9〜11莫耳。、於上述反應中，為了更加_地進行反應，除了甲醇、乙醇等醇類以外，亦可添加二甲基颯、二甲基亞石風等非質 :性極性溶劑等而進行反應。於使用醇類之情況，其使用量係相對於表自醇量，為2〜2G重量％，較佳為4叫5重 97114141 29 200900859 量％。又，於使用非質子性極性溶劑之情況，並相對於表鹵醇量，為5〜:[〇〇重量％，較隹八係〈含有不飽和基之㈣⑻〉 4ΐ〇^9〇ί*%° 作為含有不飽和基之幾酸（b)，可泉 w 印具有乙稀性不偷和基之不飽和賴，作為具體例，可舉出（甲基）丙稀酸，丁烯酸乙婦基苯甲酸，間乙烯基苯甲酸，對乙甲酸，肉桂酸，α-位齒烷基、烷氧基、南素原子、硝；、或亂基取代之（甲基）丙烯酸等單羧酸；丁二酸2_^基）丙烯酿氧基乙S旨、己二酸2 — (?基）丙稀醯氧基乙醋、土醜酸2-(甲基）丙烯醯氧基乙_、六氫敵酸2_(甲基）丙_ 乳基乙酯、順丁烯二酸2_(甲基)丙烯醯氧基乙酯、丁二 $ 2-（甲基）丙烯酿氧基丙醋、己二酸2_(甲基）丙稀醯氧土丙自曰、四氫酞酸2-(甲基）丙烯醯氧基丙酯、酞酸2一（曱 $)丙烯醯氧基丙酯、順丁烯二酸2_(曱基)丙烯醯氧基丙酉曰丁一酉文2-(甲基）丙烯醯氧基丁酯、己二酸2_(曱基） 1烯酿氧基丁醋、氫敌酸2_(甲基）丙烯醯氧基丁醋、酞酉文2 (曱基）丙烯醯氧基丁酯、順丁烯二酸2 —(曱基）丙烯醯虱基丁酯等二元酸之（曱基）丙烯醯氧基烷基酯；於（曱基）丙烯酸上加成ε_己内酉旨、万—丙内酉旨、了― 丁内醋、占 -戊内®旨等内醋類而成之單體；（曱基）丙稀酸二聚物等。 ^，亦可舉出於如季戊四醇三（曱基）丙烯酸酯、二季戊四醇五（甲基）丙稀酸自旨、三Μ甲基丙院二丙烯酸醋、環氧 7基曱基丙烯酸醋（丙烯酸加成物，環氧丙基甲基丙稀酸酉旨之甲基丙稀酸加成物般之含有羥基之不飽和化合物 97114141 30 200900859 上，加成丁二酸酐、順丁嫌_ 等酸酐而成之化合物。、一次酐、四氫酞酸酐、酞酸酐尤佳為（甲基）丙婦酸。 = 用1種，亦可將2種以上混合使用。基盘含有二物⑷及/或環氧化合物(〇中之環氧二:不:：基之_反應之方法，可化十，三甲基錄、；::甲=胺，’氯使上錄建’"〜笨基膦等作為觸媒’ ⑷及/或環氧化合物(a，)與含有不飽才基之羧酉夂（b)於有機溶反應數小時〜數十小時：中，反應溫度50〜靴下酸。數十小時’猎此可於環氧化合物上可加成叛 Ο 係相對於反應原料混合物(環氧化合物 ^及^壤乳化合物（〇與含有不飽和基之竣酸⑻之合 °啟佳為〇·〇1〜10重量％，尤佳為〇.3〜5重旦y 反應：之聚合’較佳為使用阻聚劑(例：：對曱苯：：：第對；:：、甲基對苯二紛、對甲氧基苯驗、鄰本一齡帛二丁基鄰苯二酚、硫二苯胺等）相對於反應原料混合物，較佳為0 0H :為 0.03〜5重量％。里1/◦，尤佳為裱氧化合物（a)及/或環氧化合物（a，）之環含有不飽和基之致酸⑻之比例，通常為9 土口若環氧基殘存，則對保存衫性Μ不良影響，==為 97114141 31 200900859 乳口物(a )之Μ基1當量’通常為0.8〜"卷旦尤佳為U〜U當量之比例進行反應。·田里、〈多元醇（c)> 作為多元醇㈦’較佳為自三經甲基丙烧、二 :烧、季戊四醇、二季戊四醇、三經甲基乙烧、Γ;3基 :丙^醇中所選擇之1種或2種以上之多元醇。，，3〜藉由使用多元醇（(：），可*:1 涵·Α/0、·^η (1 ^ 了、加（Β)有機黏合劑之分子量， 2 可導入支鍵’可取得分子量與黏度之平衡。又子中之酸基之導入率，可獲得取得靈敏度或密著則戈果丨衡之有機黏合劑。多元醇(C)之使用量，若過少収果小，若過多則存在增黏或凝膠化之 ^ ϋ 〈多元酸酐（d)> 等作為多元酸酐，可使用二元酸酐、三元酸酐、四元酸酐，可酸軒(四賴二酐)，可使用眾所周知者，例如用二酐、聛：四甲酸酐、二苯基酮四羧酸二酐、聯苯四羧酸 -聯術幾酸二酐等四叛酸二酐等。該等作為四元酸酐，上述例示化合物中，尤佳為聯苯四緩種，亦可將2種以上組合使用文酐酸 97114141 32 200900859 =使環氧化合物⑷及/或環氧化合物基之賴⑻之反應物，與作為多元酸酐之四元酸肝 =密=由f =應增加分子量。因此，存在提高與基故較：。°周即’谷解性、提高靈敏度或耐鹼性等效果，作為一兀酸酐(二羧酸酐），例如可舉出順丁烯二酸酐，二：酸酐、伊康酸野、駄酸酐、四氫酞酸酐、六氫敌酸酐、土：亞曱基四氫酞酸酐、氯橋酸酐、f基四氫酞酸酐專。。/、中，較佳為四氫酞酸酐、丁二酸奸。該等二元酸肝可早獨使用1種，亦可將2種以上組合使用。藉由使環氧化合物（a)及/或環氧化合物（a，）與含有不飽和基之羧酸（b)之反應物，與作為多元酸酐之；;元酸酐反應，溶解性之調節變得容易，又，與基板上之密著升，故較佳。作為三元酸酐（三羧酸酐），可舉出偏苯三酸酐、六氫偏〇苯三酸酐#，尤佳為偏苯三酸針、力氯偏苯三酸野^等三元酸酐可單獨使用丨種，亦可將2種以上組合使用。 * 藉由使用三元酸酐，可增加（B)有機黏合劑之分子量， •於分子中可導入支鏈，可取得分子量與黏度之平衡。又，可增加分子中之酸基之導入量，可獲得取得靈敏度、密著性等之平衡之有機黏合劑。作為多元酸針（d)’尤佳為使用四元酸酐，於該情況下，四元酸酐之加成率係相對於環氧化合物（a)及/或環氧化合物（a，）上加成含有不飽和基之羧酸（㈧時生成之經基， 97114141 33 200900859 通常為10〜100莫耳％， 3〇〜⑽莫耳％。若四元酸^之^〜=莫耳[更佳為可溶性不飽和樹脂之溶解，則有時驗不充分。兄或者與基板之密著性再者，就調節著色樹脂組成物之黏度或溶解性之方而言’較佳為將上述四元酸軒八解〖生之方面而仇版m _ 口丨刀替換為二元酸酐。 '元酸軒.四與一凡酸肝之情況’其莫耳比較佳為二 7。二.Γ ": 1 〜2〇: S〇,更佳為，20 〜30 . Ϊ膜之膜物性下降之可能性，於二二it:得有之 %所得之樹脂溶液之黏度增大，難以操作。/有況又若於併：四元酸軒及/或二元酸酐與三元酸酐之情降之;：：吏用量過少，則效果小，存咖^ (a)及/赤卢# / 文酐之使用里係相對於環氧化合物時生成：：：匕口物(8 )上加成含有不飽和基之羧酸⑻ C) %左;^ 通常為5〜7〇莫耳％，較佳為10〜莫耳，況於=多元酸酐’使用四元酸酐及/或二元酸酐之情 ‘、兄二夕’使用四兀酸酐及/或二元酸酐與三元酸酐之情 _美，）加成3有不飽和基之羧酸（b)時生成之 1通吊為10〜100莫耳％，較佳為20〜100莫耳％，更 =30〜100莫耳％。若多元酸針⑷之加成率過少，則有寺驗可溶性不飽和樹脂之溶解性不充分，或者與 97114141 34 200900859 著性不充分。作為於上述環氧化合物（3)及/或環氧化合物（a，）上加成含有不飽和基之羧酸（1))後，或者，於上 ⑷及/或環氧化合物(a’)上加成含有不飽和基氧之^ (b) ’於其中混合多元醇（c)後，加成四元酸酐及/或二元酸酐、或者四元酸酐及/或二元酸酐與三元酸酐等多元酸酐（d )之方法，可使用眾所周知之方法。(10) R15 has the same meaning as R1 (2a), (2b), and (3) in the above formula (9a), (9b), and (1). The epoxy compound (4) is obtained by the following method: a compound represented by the formula () or (10) is combined with an excess of epichlorohydrin, epichlorohydrin, etc., and a gold hydroxide, potassium hydroxide or the like is added in advance. When the oxide 'or the surface is added to the surface at a temperature of 2 〇 to 12 =1 to 1 M, the enthalpy of the general formula (1) can be obtained by the above formula (2a) or (2b). A linking group epoxy compound (4). Further, the epoxy compound (a) can be obtained by the following method: pre-added in the dissolution of the compound represented by the formula (10) with an excess of epigas alcohol or an epihalohydrin such as an alcohol An alkali metal hydroxide such as sodium hydroxide or potassium hydroxide may be reacted for one to one hour at a temperature of from 2 Torr to 12 Torr, whereby hydrazine in the formula (1 Α) can be obtained. The epoxy compound (a,) represented by the above formula (3). In the reaction for obtaining the epoxy compound (a) and the epoxy compound (a,), 97114141 28 200900859, as a metal hydroxide, an aqueous solution thereof can be used. In this case, the following method may be used: the aqueous solution of the metal ruthenium oxide is continuously added to the reaction system, and the water is further separated by continuous (iv) water and dentate alcohol under reduced pressure or normal pressure to remove water. , the dentate alcohol is continuously returned to the reaction system. Νν' 〇ϋ Further, an epoxy compound represented by the formula (1) or an epoxy compound represented by the formula (1Α) can be produced by the following; (〇: in the above formula (5) a mixture of a compound represented by (10) or (10) and a solution of a dentate alcohol, wherein a quaternary ammonium salt such as tetramethylammonium chloride, tetramethylammonium chloride or trimethylbenzylammonium chloride is added as a catalyst. When 5 〇 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 The aqueous solution, the side ~ (10) at the temperature of the reaction b (7) hours, and make it de-toothed 虱 (closed loop). The amount of the alcohol used in the above reaction is usually equivalent to the hydroxyl group i equivalent of the compound represented by the formula (9U, (10)) or (1), and is usually 2 to 10 moles, preferably 2 to 10 moles. ear. Further, the amount of the metal oxychloride to be used is usually from 0 8 to 15 mol, preferably 〇, based on 1 equivalent of the hydroxyl group of the compound represented by the formula (9a), (9b) or (1). · 9 to 11 moles. In the above reaction, in order to carry out the reaction, a reaction may be carried out by adding an inert polar solvent such as dimethyl hydrazine or dimethyl sulphur, in addition to an alcohol such as methanol or ethanol. In the case of using an alcohol, the amount thereof is 2 to 2 G% by weight, preferably 4 to 5, 97,114,141, 2009,00,00, 859 %, based on the amount of the alcohol. Further, in the case of using an aprotic polar solvent, and relative to the amount of epihalohydrin, it is 5 to: [〇〇% by weight, compared with the octagonal system (containing (4) (8) of the unsaturated group), 4ΐ〇^9〇ί*% ° As the acid (b) containing an unsaturated group, it can be smear-free and sulphur-free, and as a specific example, (meth)acrylic acid, butyric acid a monocarboxylic acid such as benzoic acid, m-vinylbenzoic acid, p-acetic acid, cinnamic acid, α-position dentate alkyl group, alkoxy group, south atom, nitrate; or chaotically substituted (meth)acrylic acid; Succinic acid 2 _ base) propylene oxyethylene S, adipic acid 2 - (?) propylene methoxy acetate, ruthenium acid 2- (meth) propylene oxy ethoxy _, hexahydrogen 2,(methyl)propanyl-lactyl ethyl ester, 2,(meth)propenyloxyethyl maleate, butyl 2,2-(methyl)propene oxypropyl acetonate, adipic acid 2_(Methyl) propylene azide, bismuth hydride, 2-(methyl) propylene methoxy propyl tetrahydro phthalate, phthalic acid 2 曱 ) ) 醯醯 propyl propyl acrylate Acid 2_(indenyl) propylene oxy propyl butyl hydrazine 2- (A) ) propylene oxy butyl acrylate, adipic acid 2 _ (mercapto) 1 ene oxy butyl vinegar, hydrogen dihydro acid 2 - (meth) propylene oxy butyl vinegar, 酞酉 2 (fluorenyl) propylene oxime a (fluorenyl) propylene oxime alkyl ester of a dibasic acid such as butyl ketone or maleic acid 2-(fluorenyl) propylene decyl butyl acrylate; In the meantime, the purpose of the 酉------------------------------------------------------------------------------------------------------- ^, can also be cited as pentaerythritol tris(mercapto) acrylate, dipentaerythritol penta (meth) acrylic acid, zirconium methacrylate acrylate, epoxy 7 methacrylate acrylate (acrylic acid) An adduct, an epoxy group-containing methyl acrylate acid-like hydroxy-acid-containing unsaturated compound 97114141 30 200900859, added succinic anhydride, cis-butyl _ anhydride The compound, the primary anhydride, the tetrahydrophthalic anhydride, and the phthalic anhydride are preferably (meth)propanoid. = One type may be used, or two or more types may be used in combination. The base contains two substances (4) and/or rings. Oxygen compound (epoxidation in bismuth: no:: base _ reaction method, can be converted to ten, trimethyl record,;:: a = amine, 'chlorine makes the record" " ~ stupyl phosphine, etc. As the catalyst '(4) and / or epoxy compound (a,) and the carboxy oxime (b) containing the unsaturated group in the organic solvent reaction for several hours to tens of hours: in the reaction temperature 50 ~ boots under the acid. Hour 'hunting this can be added to the epoxy compound on the epoxy compound relative to the reaction raw material mixture (epoxy compound ^ and ^ lobe compound合〇〇含有含有含有含有含有含有含有含有含有〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 ::P-Phenylbenzene:::pair;::, methyl-p-phenylene, p-methoxybenzene, adjacent one-year-old dibutyl catechol, thiodiphenylamine, etc.) relative to the reaction materials The mixture is preferably 0 0H: 0.03 to 5% by weight. 1/◦, particularly preferably the ring of the anthracene compound (a) and/or the epoxy compound (a,) contains an unsaturated group (8) Proportion, usually 9 earth mouth if the epoxy group remains, it will have an adverse effect on the preservation of the shirt, == is 97114141 31 200900859 nipple (a) Μ base 1 equivalent 'usually 0.8~" The reaction is carried out in a ratio of U to U equivalents. · Tianli, <polyol (c)> as polyol (7)' is preferably from triacetin, propylene, pentaerythritol, dipentaerythritol, and tris. Ethylacetone, hydrazine; 3 group: one or more polyols selected from the group consisting of propylene alcohols, and 3~ by using a polyol ((:), *: 1 涵·Α/0, ·^η (1 ^, plus Β) The molecular weight of the organic binder, 2 can be introduced into the bond' to obtain the balance between the molecular weight and the viscosity. In addition, the introduction rate of the acid group in the sub-group can obtain the organic binder which is sensitive or dense. When the amount of the alcohol (C) is too small, the amount of the fruit is small, and if it is too small, there is a thickening or gelation. <Polyuric anhydride (d)> As a polybasic acid anhydride, a dibasic acid anhydride or a tribasic acid anhydride can be used. Tetrabasic anhydride, can be acid (four dia dianhydride), can be used well known, such as with dianhydride, hydrazine: tetracarboxylic anhydride, diphenyl ketone tetracarboxylic dianhydride, biphenyl tetracarboxylic acid - conjugated acid Four retinoic acid dianhydrides such as dianhydride. These are tetrabasic acid anhydrides, and among the above-exemplified compounds, it is particularly preferred to use a biphenyltetradecyl group, and two or more of them may be used in combination with vinonic anhydride 97114141 32 200900859 = epoxy compound (4) and/or epoxy compound-based (8) The reactant, and the quaternary acid liver as a polybasic acid anhydride = dense = by f = the molecular weight should be increased. Therefore, there is an increase compared to the base: ° Week is the effect of 'glutenability, sensitivity or alkali resistance. Examples of monoanhydride (dicarboxylic anhydride) include maleic anhydride, di-anhydride, itaconic acid, phthalic anhydride, and tetra Hydroquinone anhydride, hexahydrochamoic anhydride, soil: fluorenyltetrahydrophthalic anhydride, chloro-bridge anhydride, and f-based tetrahydrophthalic anhydride. . /, medium, preferably tetrahydrophthalic anhydride, succinic acid. These dibasic acid livers may be used alone or in combination of two or more. By reacting the epoxy compound (a) and/or the epoxy compound (a) with a carboxylic acid (b) containing an unsaturated group, and reacting with a polybasic acid anhydride; It is easy, and it is better to adhere to the substrate. Examples of the tribasic acid anhydride (tricarboxylic anhydride) include trimellitic anhydride and hexahydropyridinic anhydride #, and particularly preferably a tribasic acid anhydride such as a trimellitic acid needle or a chlorotrimellitic acid, which can be used alone. Two or more types may be used in combination. * By using a ternary anhydride, the molecular weight of (B) organic binder can be increased. • Branches can be introduced into the molecule to achieve a balance between molecular weight and viscosity. Further, the amount of introduction of the acid group in the molecule can be increased, and an organic binder which balances sensitivity and adhesion can be obtained. It is preferable to use a tetrabasic acid anhydride as the polybasic acid needle (d)'. In this case, the addition ratio of the tetrabasic acid anhydride is added to the epoxy compound (a) and/or the epoxy compound (a). The carboxylic acid containing an unsaturated group ((8) is formed by a base, 97114141 33 200900859 is usually 10~100 mol%, 3〇~(10) mol%. If quaternary acid ^^=mole [better The dissolution of the soluble unsaturated resin is sometimes insufficient. Brother or adhesion to the substrate, in terms of adjusting the viscosity or solubility of the colored resin composition, it is preferable to use the above-mentioned tetrabasic acid Eight solutions 〖Life's aspects and hate version m _ mouth knives replaced with dibasic anhydride. 'Yuanshui Xuan. Four and one of the situation of sour liver' its Moer is better for two 7. II. Γ ": 1 ~2〇: S〇, more preferably, 20~30. The possibility of the film properties of the film is reduced. In the second two: it has a % increase in the viscosity of the resin solution, which is difficult to handle. If and in: the four yuan acid Xuan and / or dibasic acid anhydride and ternary anhydride decreased; :: 吏吏 too small, the effect is small, save the coffee ^ (a) and / Chilu # / text When the anhydride is used, it is formed relative to the epoxy compound::: the garamine (8) is added with an unsaturated group-containing carboxylic acid (8) C) % left; ^ is usually 5 to 7 mole %, preferably 10 to Mo, in the case of = polybasic anhydride 'use of tetrabasic anhydride and / or dibasic anhydride ', 'brothers' using tetraphthalic anhydride and / or dibasic anhydride and tribasic anhydride _ US, When the addition of the carboxylic acid (b) having an unsaturated group of 3 is carried out, it is 10 to 100 mol%, preferably 20 to 100 mol%, more preferably 30 to 100 mol%. If the addition ratio of the polyacid needle (4) is too small, the solubility of the soluble unsaturated resin in the temple is insufficient, or the property is not sufficient with 97114141 34 200900859. The addition of the unsaturated group-containing carboxylic acid (1) to the epoxy compound (3) and/or the epoxy compound (a), or the upper (4) and/or epoxy compound (a') Addition of an unsaturated group containing oxygen (b) 'after mixing the polyol (c), adding a tetrabasic anhydride and / or a dibasic acid anhydride, or a tetrabasic acid anhydride and / or a dibasic acid anhydride and a tribasic anhydride As the method of the polybasic acid anhydride (d), a well-known method can be used.

Ο 其反應溫度，通常為80〜13(rc，較佳為9〇〜mt。若反應溫度超過13(rc，則引起一部分不飽和基之聚合，存在導致分子量急劇增加之可能性’若未$ 8(TC，則反應無法順利進行，存在多元酸酐⑷殘存之可能性。如此獲得之鹼可溶性不飽和樹脂之酸值，通常為1〇 mg ΚΟΗ/g以上，較佳為5() mg—腿/g以上。若該驗可溶料飽和樹脂之酸值未滿1G mg_KQH/g，則有時顯影性不充刀。又，右鹼可溶性不飽和樹脂之酸值過高，則耐鹼性方面存在問題（即，有時因驗性顯影液而導致圖案表面之粗面化或膜知失之產生），因此酸值較佳為⑽mg_K〇H/g 以下，更佳為15〇 mg_K〇{j/g以下。本1月之1«可办性不飽和樹脂之重量平均分子量，較佳為1’500以上’更佳為2肩以上。又，較佳為2〇，_ =下’更佳為1〇,咖以下。若重量平均分子量過小，則存在靈敏度或塗膜強度、耐鹼性方面產生問題之可能性，若過大，則有時顯影性或再溶解性方面產生問題。本發明之（B)有機勘合劑，可於不損害本發明效果之範 97114141 35 200900859 ί=::性)不飽和樹_之樹脂(《下作為其他有機黏合劑，並無特別限定，於曰本專利特開2007-271727號公報、 2007-31 6620號公報、日本專利特開2〇〇7 等之黏合劑樹脂等。該等可單獨使用〗種上組合使用。 (c)分散劑Ο The reaction temperature is usually 80 to 13 (rc, preferably 9 〇 to mt. If the reaction temperature exceeds 13 (rc, a polymerization of a part of the unsaturated group is caused, there is a possibility that the molecular weight sharply increases) if not 8 (TC, the reaction cannot proceed smoothly, and there is a possibility that the polybasic acid anhydride (4) remains. The acid value of the alkali-soluble unsaturated resin thus obtained is usually 1 〇 mg g / g or more, preferably 5 () mg - leg /g or more. If the acid value of the soluble resin saturated resin is less than 1G mg_KQH/g, the developability may not be filled. In addition, the acid value of the right alkali-soluble unsaturated resin is too high, and the alkali resistance is There is a problem (that is, sometimes the surface of the pattern is roughened or the film is lost due to the developer), so the acid value is preferably (10) mg_K 〇 H / g or less, more preferably 15 〇 mg _ K 〇 {j /g or less. The weight average molecular weight of the disposable unsaturated resin in January is preferably 1'500 or more', more preferably 2 or more shoulders. Further, preferably 2 inches, _ = lower 'better' It is 1 〇, below the coffee. If the weight average molecular weight is too small, there is sensitivity or film strength and alkali resistance. The possibility of a problem, if it is too large, sometimes causes problems in developability or resolubility. (B) The organic retort of the present invention can be used without impairing the effects of the present invention 97114141 35 200900859 ί=:: The resin of the unsaturated tree is not particularly limited as described in Japanese Patent Laid-Open Publication No. 2007-271727, No. 2007-31 6620, Japanese Patent Laid-Open No. 2-7, and the like. Resin, etc. These can be used alone or in combination. (c) Dispersant

重要的是本發明之著色樹月旨組成4勿中微細分散( 材，且穩定其分散狀態，故較佳為調配（(：）分散劑。 ⑹分散劑係對⑴色材及⑻有機黏合劑之兩者具有親和性者:例如可舉出非離子、陽離子、陰離子等之界面活性劑，高分子分散劑等。其中，較佳為高分子分散劑，尤佳為具有-級、二級或三級胺基’或來自❸定、嘴咬、吡讲等含氮雜環之基等鹼性官能基之高分子分散劑。〇圍内稱作例如可舉出揭示曰本專利特開 -334290號公報 ’亦可將2種以作為具有鹼性官能基之高分子分散劑，若具體例示較佳之化學構造，則例如可舉出使聚異氰酸酯化合物、分子内具有1個或2個羥基之化合物、及同一分子内具有活性氫與三級胺基之化合物反應而獲得之胺基甲酸乙酯系高分子分散劑。作為上述聚異氰酸g旨化合物之例子，可舉出對伸苯基二異氰酸酯、2, 4-曱苯二異氰酸酯、2, 6_曱苯二異氰酸酯、 ^4’—二苯基曱烷二異氰酸酯、萘-1，5-二異氰酸酯、聯曱苯胺二異氰酸酯等芳香族二異氰酸酯，二異氰酸己二酯、 97114141 36 200900859 離胺酸曱酯二異氰酸酯、2, 4, 4一二異氰酸三曱基己二酯、一聚酸二異氰酸酯等脂肪族二異氰酸酯，異佛爾酮二異氰酸酯、4, 4，-亞甲雙（環己基異氰酸酯）、ω，ω，-二異氰酸 =一曱基％己烷等脂環族二異氰酸酯，苯二亞曱基二異氰魷§曰、α，α，α’，四曱基苯二亞曱基二異氰酸酯等具有芳s環之知肪族二異氰酸酯，離胺酸酯三異氰酸酯、 I 6’ 1卜十一烷三異氰酸酯、1，8-二異氰酸酯-4-異氰酸酯 =基辛烷、1，3, 6-三異氰酸己二酯、二環庚烷三異氰酸知一參(>異氰酸酯苯基曱烷）、參（異氰酸酯苯基）硫磷酸酯等-異氰酸gg ’及該等之三聚物、水加成物、以及該等之多元醇加成物等。作為聚異氰酸g旨，較佳為二異氰酸g旨之三聚物，最佳為甲苯二異㈣酯之三聚物及異佛爾酮二異氰酸酯之三聚物。該專可單獨使用，亦可併用。作為異氰酸酯之三聚物之贺生 yr 一初之裏&方法，可舉出使用適當三 G t化觸媒，例如三級胺類、膦類、烷醇類、金屬氧化物、 -取# ^ 过一異氰馱酯類進行異氰酸酯基之部分 ^二水化，藉由添加觸媒毒而停止二 .取、薄膜錢而去除未反库n—Λ 制；谷劑萃 .s.,, 木夂應之一異氰酸酯，獲得目標之含有異鼠尿酸酯基之聚異氰酸酯的方法。作為同一分子内且右1袖斗、 ^ 有1個或2個羥基之化合物，可與山聚醚二元醇、聚酯二元了舉出醇等’以及該等化合物之單 =-疋基進行炫氧基化者及該等2種以上之混=為1〜25之燒 97114141 200900859 作為聚醚二元醇，等中2種以上之混合物牛出聚醚二醇、聚醚酯二醇、及該作為聚鱗二醇，可粗醇、聚氧丁二醇、聚童ρ一％來丙二醇、聚乙烯-丙二物。己—醇、聚氧辛二醇及彼等之混合作為聚醚酯二醇，可舉 k他二元醇之混合物，與二錄1、 3有醚基之二醇或與其者’藉由使聚酯二元醇與環酐反，而獲得者’或氧四亞f基）己二酸g旨等。A Μ而獲得者，例如聚（聚作為聚醚二元醇，最佳為聚乙二醇二醇或該等化合物之單末端經數-：、聚氧丁進行烷氧基化的化合物。数為1〜25之烷基作為聚酯二元醇，可舉出使二叛酸（丁己二酸、癸二酸、反丁烯二酸夂、、一酸、彼等之酸針與二元醇（乙二醇、二乙二«等）或 -醉、二丙二醇、。丙二醇、1，2-丁二醇、丙 1，4-丁二醇、2,3_ 丁二醇、3_ 甲基 _ ，丁-醇、醇、2-甲基―仏丙二醇、2〜甲基_2」丙=「醇、新戊二 2-丁基-2-乙基-1，3-丙二醇 ^ ，3''丙一醇、 2-甲基-2,4-戊二醇、2,2,4、三甲基—】3 /，6—己-酵、 *己二醇、2,5-二曱基义5二ΓΓΠ乙基 :Γ，8-辛二醇…二醇等脂肪族二’二曱基環己烧等脂環族二元醇;苯二亞甲基二醇:雙= 97114141 38 200900859 基本等芳香族二元醇；Ν_曱基二乙醇胺等烷基聚::？得者(例如’聚己二酸乙:醇::聚夂丁一_…己二酸己二醇醋、聚丙二醇醋等）’或者’將上述二醇類或碳數為卜25 一： υ起始原料而獲得之聚内酯二醇或聚如’聚己内酯二醇、聚甲美占、混合物。 W基戊㈣），及料2種以上之 Ο Ο 作為聚酯二元醇，最佳為聚己内酯二醇或 25之醇用作起始原料而獲得之聚己内酉旨。、人-〜 s作為聚碳酸g|二元醇，可舉出聚（U-伸己基）碳酸酉旨、 W3-甲基伸戊基）碳酸酯等，作為聚稀烴二元醇，可舉出聚丁二烯二醇、加氫型聚丁二烯聚戊二烯二醇等。風ϋ異同一分子内具有1個或2個經基之化合物之數量平均分子量’通常為3G()〜1G，咖，較佳為剛〜6，_ 1，000〜4, 000。两就本發明中所使用之同—分子内具有活性氣與三級胺基之化合物加以說明。作為活性H直接鍵結於氧原子、氮原子或硫原子上之氫原子，可舉出絲、胺基、硫醇基等官f基中之氫原子，其中，較佳為胺基，尤佳為一級胺基之氮原子。對於r:奴…# μ l 丁％ —級私基並無特別限定。又，作三級胺基’可舉出具有碳數為卜4之炫基之胺基、或雜環構造，更具體而言可舉出咪。坐環或三〇坐環。若例不上述同一分子内具有活性氳與三級胺基之化合 97114141 39 200900859 物，則可舉出N N- -甲其！〇珥ΙΜ’Ν 一 f基-U一丙二胺、丙二胺、N，~| 1 〇工一乙基-1,3- —丙基-1，3-丙二胺、N N__ 胺、N，N-二甲基乙二胺、N 一丁基-1，3-丙二乙二胺、N，N—二/ 一乙基乙二胺、n，N-二丙基丁基乙一二甲其1 / Ν,Ν-二乙基 — 彳/丁於丁二胺、 g 丞 1,4-丁二胺、N，N_ 二丙基二丁基-1，4-丁二胺等。，丁一胺、又作為二級胺基為含^雜環、三唾環、四唾環、物::哇；舉，環、味唾 1環、苯并三唾環、苯㈣唾環=二：唾環、苯并咪唑環等含N之雜五員環，、苯并噻二圭啉％、吖啶環、異喹啉環开衣含N之雜产,+ + 3 w之雜/、員裱。作為該等二之雜& ’較佳者為㈣環或三唾環。若具體例示具有該等咪唑 W3-脸其& #、，衣/、妝基之化合物，則可舉出 r ^ nοφ u ^ 2-胺基咪唑、1-(2-胺基乙基）未唑寻。又，若具體物E, ^ ^ 、篮例不具有***環與胺基之化合物，則可舉出3-胺基-1 2 4-二， « X q +, ^ ，，4 二唑、5-(2-胺基-5-氯苯基）-3-苯基—Η-〗』4_二 0 c —主 4~胺基-4H-1，2, 4-*** --二醇、3_胺基_5_苯基_1H—1>3士三唾、5_胺m 一：基―1’2,3 —三唾、3-胺基Ή基-胸，4-三嗤等。 _/、中，較佳為Ν，Ν-二甲基'UmN-二乙基 ’3丙一月女、1 (3-月女基丙基）σ米唑、3 一胺三唾。分散劑原料之調配比率係相對於100重量份之聚異氰酸醋化合物，同一分子内且古1 〃有1個或2個羥基之數量平均分子量為300〜1〇，_之化合物，通常為10〜200重量 97114141 200900859 份’較佳為20〜190重量份，更佳為3〇〜18〇重量份 -分子内具有活性氫與三級胺基之化合物，通常為二 25重量份，較佳為〇. 3〜24重量份。 ·〜具有驗性官能基之高分子分散劑的藉由凝膠渗透法(GPC)測定之以聚苯乙烯換算之重量平均分子量心斤通常為U00〜較佳為2，_〜1〇〇，伟 Ο ? 3, _〜50’_。若具有鹼性官能基之高分子分散劑之分子罝未滿1，000 ’則有時分散性及分散穩定性不超過200, _，則存在溶解性下降且分散性不良，同以控制反應之可能性。胺基甲酸乙酯系高分子分散劑，可依據眾所周知之聚胺基甲酸®旨樹脂之製造方法而製造。作為衣這胺基甲酸乙酯系高分子分散劑時之溶劑，通常可使用丙鋼、甲基乙基酉同、甲基異丁基酮、環戊酮、環己酮、異佛_等酮類，醋酸乙_、醋酸丁酉旨、醋酸赛路蘇。等酯類：苯、甲苯、二曱苯、己烷等烴類，二丙酮醇、異丙知、第一丁醇、第三丁醇等一部分醇類，二氯曱烷、氣 ,仿等氣化物，四氫呋喃、二***等醚類，二曱基曱醯胺' -N_甲基吡咯啶酮、二曱基亞砜等非質子性極性溶劑等。又，作為觸媒，可使用普通胺基曱酸乙酯化反應觸媒，具體而言，例如可舉出二丁基錫二月桂酸酯、二辛基錫二月桂酸酯、二丁基錫二辛酸酯、辛酸亞錫等錫系，乙醯丙酮鐵、二氣化鐵等鐵系，三乙胺、三乙二胺等三級胺系等之1種或2種以上。 97114141 41 200900859 同一分子内具有活性氫盥二 L /、—級胺基之化合物之使用量為㈣為朗料分子分㈣之職成為卜1〇〇腫g之㈣内。該胺值更佳為5〜95心_之範圍。It is important that the coloring tree of the present invention is composed of 4 finely dispersed materials, and is stable in dispersion state, so it is preferably formulated ((:) dispersing agent. (6) Dispersing agent pair (1) color material and (8) organic binder The affinity of the two may be, for example, a nonionic, cationic, anionic surfactant or the like, a polymer dispersant, etc. Among them, a polymer dispersant is preferred, and it is preferably a grade, a secondary or a tertiary amino group' or a polymer dispersing agent derived from a basic functional group such as a nitrogen-containing heterocyclic group such as a sputum, a mouth bite, or a pyridyl group, and the like is exemplified by the disclosure of Japanese Patent Laid-Open No. 334290 In the above-mentioned publication, two kinds of polymer dispersing agents having a basic functional group may be used. Specific examples of the preferred chemical structure include a polyisocyanate compound and a compound having one or two hydroxyl groups in the molecule. And an urethane-based polymer dispersing agent obtained by reacting a compound having an active hydrogen and a tertiary amino group in the same molecule. Examples of the poly-isocyanate g-based compound include a para-phenylene group. Isocyanate, 2, 4- Aromatic diisocyanate such as phenyl diisocyanate, 2,6-nonyl diisocyanate, ^4'-diphenyldecane diisocyanate, naphthalene-1,5-diisocyanate, benzidine diisocyanate, diisocyanate Diester, 97114141 36 200900859 An aliphatic diisocyanate such as decyl amide diisocyanate, 2, 4, 4 diisocyanate tridecyl hexane diester or monopoly acid diisocyanate, isophorone diisocyanate, 4 , 4,-methylene bis(cyclohexyl isocyanate), ω, ω, -diisocyanate = fluorenyl diisocyanate such as monodecyl hexane, benzodiamidylene diisocyan 鱿曰, α, An aliphatic diisocyanate having an aryl s ring such as α,α′, tetradecyl phenyldiamidylene diisocyanate, an isocyanate triisocyanate, I 6′ 1 bundane triisocyanate, 1,8-di Isocyanate-4-isocyanate=base octane, 1,3,6-triisocyanate, dicycloheptane triisocyanate (> isocyanate phenyl decane), ginseng (isocyanate phenyl) a thiophosphate, etc. - isocyanate gg 'and such terpolymers, water adducts, and polyol additions thereof The polyisocyanate g is preferably a terpolymer of diisocyanate g, and is preferably a trimer of tolylene di(tetra) ester and a terpolymer of isophorone diisocyanate. It can be used singly or in combination. As a method for the isocyanate trimer, it is possible to use a suitable tri-Gt catalyst such as a tertiary amine, a phosphine or an alkanol. , metal oxide, - take # ^ over-isocyanohydrazide to carry out part of the isocyanate group dihydrate, by adding catalyst poisoning to stop the second, take, film money and remove the anti-reservoir n - system; The granule extracts s.,, hibiscus is one of the isocyanates, and the target method of obtaining the isocyanurate-containing polyisocyanate is obtained. As the same intramolecular and right 1 sleeve, ^ has 1 or 2 hydroxyl groups. The compound may be ethoxylated with a polyether diol, a polyester, a diol, or the like, and a mono--fluorenyl group of the compounds, and a mixture of the two or more = 1 to 25烧烧97114141 200900859 As a polyether diol, a mixture of two or more kinds of a mixture of polyether diol, polyether ester diol, and Polysqualane diol, crude alcohol, polyoxybutylene glycol, poly-p- propylene glycol, polyethylene-propylene. a mixture of hexanol, polyoxyoctanediol and the like as a polyether ester diol, which may be a mixture of k diols, and a diol having an ether group of 1, 3 or the same The polyester diol is opposite to the cyclic anhydride, and the winner 'or oxytetram-f-) adipic acid g is equivalent. A is obtained by, for example, a poly(polyether diol, preferably a polyethylene glycol diol or a compound having a single terminal number of: - a polyoxybutylene alkoxylated. The alkyl group of 1 to 25 is used as the polyester diol, and the dioxic acid (butyric acid, sebacic acid, bismuth fumarate, monoacid, and the acid needle and the binary are mentioned). Alcohol (ethylene glycol, diethyl 2, etc.) or - drunk, dipropylene glycol, propylene glycol, 1,2-butanediol, propane 1,4-butanediol, 2,3-butanediol, 3_methyl_ , butyl alcohol, alcohol, 2-methyl-propane propylene glycol, 2~methyl-2" propane = "alcohol, neopentyl 2-butyl-2-ethyl-1,3-propanediol ^, 3'' Propyl alcohol, 2-methyl-2,4-pentanediol, 2,2,4, trimethyl-]3/,6-hexyl-fermentation, *hexanediol, 2,5-didecyl 5 bis-ethyl: hydrazine, 8-octanediol, diol, and the like, an aliphatic diol such as an aliphatic bis-didecylcyclohexane; benzodiamethylene glycol: double = 97114141 38 200900859 basic, etc. Aromatic diol; alkyl group such as Ν-mercaptodiethanolamine: :?? (eg 'polyhexamethylene diacetate: alcohol: polyglycolate _... adipic acid Glycol vinegar, polypropylene glycol vinegar, etc. 'or 'the above diols or carbon number is a 25: a polylactone diol obtained from a starting material or a poly-caprolactone diol, polymethyl US-based, mixture. W-based (4)), and more than 2 kinds of Ο Ο As a polyester diol, preferably polycaprolactone diol or 25 alcohol used as a starting material _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Examples thereof include polybutadiene diol and hydrogenated polybutadiene polypentadiene diol. The number average molecular weight of a compound having one or two thio groups in the same molecule is usually 3G. ()~1G, coffee, preferably just ~6, _1,000~4, 000. Both are the same as those used in the present invention, and the compound having an active gas and a tertiary amino group in the molecule is explained. H is a hydrogen atom directly bonded to an oxygen atom, a nitrogen atom or a sulfur atom, and examples thereof include a hydrogen atom in a group such as a silk group, an amine group or a thiol group. Among them, an amine group is preferred. More preferably, it is a nitrogen atom of a primary amine group. For r: slave... # μ l 丁% - grade private base is not particularly limited. Also, as a tertiary amine group, it can be exemplified as having a carbon number of 4 An amine group or a heterocyclic ring structure, more specifically, a ring of a ring or a tricyclic ring. If the compound of the above formula has an active oxime and a tertiary amine group, 97114141 39 200900859, N N- -甲甲! 〇珥ΙΜ'Ν a f-based-U-propylenediamine, propylenediamine, N,~| 1 一-ethyl-1,3-propyl-1,3- Propylenediamine, N N__amine, N,N-dimethylethylenediamine, N-butyl-1,3-propanediethylenediamine, N,N-di-ethylethyldiamine, n,N -dipropylbutylethyl dimethyl ketone 1 / Ν, Ν-diethyl- 彳 / butyl to butane diamine, g 丞 1,4-butane diamine, N, N - dipropyl dibutyl -1 , 4-butane diamine and the like. , D-monoamine, and as a secondary amine group are a heterocyclic ring, a tri-salt ring, a tetra-salt ring, a substance:: wow; lift, ring, taste saliva 1 ring, benzotris-salt ring, benzene (tetra) spit ring = Two: a five-membered ring containing N, such as a saliva ring, a benzimidazole ring, a benzothiazamide, an acridine ring, an isoquinoline ring, a N-containing miscellaneous product, + + 3 w of miscellaneous / Member. Preferred as the above two & ' is a (iv) ring or a trisal ring. Specific examples of the compound having the imidazole W3-face &#,, clothing, and makeup base include r ^ nοφ u ^ 2-aminoimidazole and 1-(2-aminoethyl) Oxazole. Further, if the specific substance E, ^ ^, or the basket does not have a compound of a triazole ring and an amine group, a 3-amino-1 2 4-di, «X q +, ^ , , 4 -diazole, 5-(2-Amino-5-chlorophenyl)-3-phenyl-indole-] 4_2 0 c - main 4~amino-4H-1,2,4-triazole-diol , 3_Amino _5_phenyl_1H-1> 3 striatum, 5 _amine m 1 : yl 1'2, 3 - tris, 3-aminoindenyl-thoracic, 4-triterpene Wait. _/, medium, preferably Ν, Ν-dimethyl 'UmN-diethyl ‘3 propyl female, 1 (3-month propyl propyl) sigmaazole, 3 monoamine trisal. The compounding ratio of the dispersant raw material is a compound having a number average molecular weight of 300 to 1 Å in the same molecule and having 1 or 2 hydroxyl groups in the same molecule with respect to 100 parts by weight of the polyisocyanate compound, usually 10 to 200 weight 97114141 200900859 parts 'preferably 20 to 190 parts by weight, more preferably 3 to 18 parts by weight - a compound having an active hydrogen and a tertiary amino group in the molecule, usually 2 to 25 parts by weight, preferably 2 It is 〇. 3~24 parts by weight. - The weight average molecular weight of the polymer dispersing agent having an intrinsic functional group measured by a gel permeation method (GPC) in terms of polystyrene is usually U00~ preferably 2, _~1〇〇, Wei Wei? 3, _~50'_. If the molecular enthalpy of the polymer functional group having a basic functional group is less than 1,000 Å, the dispersibility and dispersion stability may not exceed 200, and _, the solubility may be lowered and the dispersibility may be poor, and the reaction may be controlled. possibility. The urethane-based polymer dispersant can be produced by a known method for producing a polyurethane resin. As the solvent in the case of the ethyl urethane polymer dispersing agent, a ketone such as propylene steel, methyl ethyl fluorene, methyl isobutyl ketone, cyclopentanone, cyclohexanone or isophor may be used. Class, acetic acid B _, acetic acid butyl hydrazine, acetic acid 赛路苏. Esters such as benzene, toluene, diphenylbenzene, hexane, etc., diacetone alcohol, isopropanol, first butanol, third butanol and other alcohols, dichlorosilane, gas, imitation, etc. An ether such as tetrahydrofuran or diethyl ether; an aprotic polar solvent such as dimercaptoamine'-N-methylpyrrolidone or dimercaptosulfoxide. Further, as the catalyst, a common amino phthalic acid ethyl esterification reaction catalyst can be used, and specific examples thereof include dibutyltin dilaurate, dioctyltin dilaurate, and dibutyltin dioctanoate. And a tin-based system such as stannous octoate, an iron-based compound such as acetonitrile, iron or sulphur, or a ternary amine such as triethylamine or triethylenediamine. 97114141 41 200900859 The amount of the compound having the active hydroquinone II L /, - amine group in the same molecule is (4) is the content of the material (4) of the material of the material (4). The amine value is more preferably in the range of 5 to 95 hearts.

再者，分散劑之胺值係以盥本a八I 一去除刀放劑試料中之溶劑之固形为母1 g之驗置等量之舌旦όιί· * 里及重里所表示，藉由以下方法測定。 π Μ 於100 mL之燒杯内’準確稱量分散劑試料之"叫c g’以5〇乩之醋酸溶解。使用具備PH電極之自動滴定裝置，利用（M _/L之譲4醋酸溶液中和滴定該溶液：將滴定PH曲線之反曲點設為較終點，根據下式算出胺胺值[mg-KOH/g] = (561xV)/(WxS) (其中」曰W表示分散劑試料之秤取量[g]，V表示滴定終 ,,、占之滴疋里[mL]，S表示分散劑試料之固形分濃 %]。) 里若胺值小於上述範圍，則存在分散能力下降之傾向，又，若超過上述範圍，則著色樹脂組成物之顯影性容易下降。再者，於藉由上述反應獲得之胺基甲酸乙酯系高分子分放刈刀子中殘存有異氰酸酯基之情況，藉由使該異氰酸酯基與醇或胺基化合物反應，而使分散劑之經時穩定性而，故較佳。 (D)光聚合起始劑 97114141 42 200900859 2發Λ之著色樹脂組成物提供除上述成分以外，進而包 3 )光來合起始劑之感光性著色樹脂組成物。始劑(D)，通常作為與加速劑及視需要添加之 =色素專加成劑之混合物（光聚合起始劑系）而使用。光 “起始劑糸係藉由直接吸收光或者光增感，而引起分解 /反應或虱抽提反應（hydrGgen abstracti〇n咖…⑻，從而產生聚合活性自由基之成分。作為μ合起始劑，例如可舉出揭示於 59-152396 號公耜、η 女奎名^ m B〇珑a報日本專利特開昭61-151197號各公報之一戊鈦化合物之二茂金屬化合物；揭示於日本專利特開_ —56118號公報之六芳基聯咪唾衍生物；揭示於日本專利特開平10一39503號公報之鹵甲基化5二唾衍生物，鹵甲基—均三°井衍生物、N-苯基甘胺酸等N_芳基 =酸類、N-芳基胺基酸鹽類、N—芳基十胺^ 類等自由基活性劑、α_胺基苯燒基網系化合物；揭示於日本專利特開2〇〇〇_8〇〇68號公報、日本專利 2006-36750號公報等之肟酯系化合物等。幵八體而σ，例如作為二茂鈦衍生物類，可舉出二環戊一烯基二氯化鈦、二環戊二烯基雙苯基鈦、u二^基= (2’ 3’ 4, 5, 6-五氟苯—丨-基）鈦、二環戊二烯基雙（2, 3, 5 6-四氟苯+基）鈦、二環戊二烯基雙（2,4,6—三氟苯+基鈦、二環戊二烯基二(2,6 —二氟苯+基)鈦、二環土基二（2,4-二氣苯—卜基）鈦、二（甲基環戊二烯基）雙 (2,3,4’5,6-五氟苯_1_基）鈦、二（甲基環戊二烯基）雙 97114141 43 200900859 (2, 6-二氟苯-i-基）鈦、二環戊二烯基[2 咯-卜基）-苯小基]鈦等。 ’ —比又，作為聯咪唑衍生物類，可舉出2~(2，* 二苯基咪唾二聚物、2 —(2，_氯苯基)_…了苯，4,5-基）咪唾二聚物、2_(2，_氟苯基）_4,5 —二又甲乳基苯物：2,甲氧基苯基)_4, 5 —二苯基味唾二二唾=聚甲氧基苯基）-4, 5-二苯基咪唑二聚物等。又，作為#甲基化噚二唑衍生物類， -5-(「苯并㈣)…二心== _(2 _苯并呋喃基）乙烯基]二[万 β ( ~(6 _本并呋喃基）乙烯基）]-ι 3 4 ,一唑、2~三氯甲基-5-呋喃基-1，3, 4一噚二唑等。，，了一又，作為S甲基-均三4衍生物類，可舉出2_( 苯基）-4, 6-雙（三氯f基）_均三哜、土 Π6-雙(三氣甲基)—均三讲、2*乙氧Further, the amine value of the dispersing agent is represented by the same amount of the solid solution of the solvent in the sample of the sputum a8I-removing squeegee sample, which is represented by the same amount of the tongue, ιί·*, and zhongli, by the following Method determination. π Μ In a 100 mL beaker, accurately weigh the dispersant sample "c g' and dissolve it with 5 醋酸 acetic acid. Using an automatic titrator equipped with a pH electrode, neutralize the solution by neutralizing (M _ / L 譲 4 acetic acid solution: set the inflection point of the titration PH curve to the end point, and calculate the amine amine value according to the following formula [mg-KOH] /g] = (561xV)/(WxS) (where "W" is the amount of the dispersant sample [g], V is the end of the titration, and the [mL] is in the drip, and S is the dispersant sample. When the value of the ruthenium is less than the above range, the dispersibility is lowered, and if it exceeds the above range, the developability of the colored resin composition is liable to be lowered. In the case where an isocyanate group remains in the ethyl amide-based polymer separation boring knife, it is preferred to react the isocyanate group with an alcohol or an amine compound to stabilize the dispersant over time. (D) Photopolymerization initiator 97114141 42 200900859 The colored resin composition of the hairpin is provided with a photosensitive coloring resin composition containing, in addition to the above components, a light-based initiator. The starting agent (D) is usually used as a mixture (photopolymerization initiator) with an accelerator and optionally a pigment-additive additive. The light "initiator" is caused by direct absorption of light or light sensitization, which causes decomposition/reaction or hydrazine extraction reaction (hydrGgen abstracti〇n...(8), thereby producing a component of polymerization active radicals. For example, a metallocene compound of a penta titanium compound disclosed in Japanese Laid-Open Patent Publication No. 61-151197, the disclosure of which is incorporated herein by reference. Japanese Patent Laid-Open No. 56118, the hexaaryl hydrazine derivative; a halomethylated 5 di-salt derivative disclosed in Japanese Patent Laid-Open No. Hei 10-39503, a halogenated methyl group-average three-dimensional derivative , N-aryl group such as N-phenylglycine; free radical activators such as acid, N-arylamino acid salt, N-aryldeftaamine, etc., α-aminobenzene alkylene network An oxime ester compound, etc., which is disclosed in Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. The dicyclopenta-alkenyl titanium dichloride, dicyclopentadienyl bisphenyl titanium, u bis group = (2' 3' 4, 5, 6-pentafluorophenyl-fluorene-based titanium, dicyclopentadienyl bis(2,3,5 6-tetrafluorobenzene+yl) titanium, dicyclopentadienyl bis (2,4,6-three) Fluorobenzene+based titanium, dicyclopentadienylbis(2,6-difluorobenzene+yl)titanium, bicyclic tertyl bis(2,4-dioxabenzene-diyl)titanium, di(methylcyclo) Pentadienyl)bis(2,3,4'5,6-pentafluorophenyl-1-yl)titanium, bis(methylcyclopentadienyl)bis 97114141 43 200900859 (2,6-difluorobenzene- I-based) titanium, dicyclopentadienyl [2 fluorenyl]-phenylyl] titanium, etc. '--, as a biimidazole derivative, 2~(2,* diphenyl) Chimi saliva dimer, 2-(2,-chlorophenyl)-...benzene, 4,5-yl)imidyl dimer, 2_(2,-fluorophenyl)_4,5-di-A Milk-based benzene: 2, methoxyphenyl)_4, 5-diphenyl-salt salicyrene = polymethoxyphenyl)-4, 5-diphenylimidazole dimer, etc. #methylated oxadiazole derivatives, -5-("benzo(tetra))...dicentric == _(2 _benzofuranyl)vinyl] bis [10,000 β (~(6 _ benzofuranyl) ) vinyl)]-ι 3 4 , monoazole, 2~trichloromethyl-5-furanyl-1,3,4-oxadiazole, and the like. One, as a S-methyl-all-three derivative, 2_(phenyl)-4,6-bis(trichlorof-yl)_-tetrazine, Π6-double (three-gas) Base) - three lectures, 2 * ethoxy

L 雙基)-均三付([乙氧基幾基蔡基H，二 (二虱甲基）-均三啡等。又作為α—胺基苯烷基酮衍生物類，可舉出2_ +[4-(甲硫基）苯基]_2_味琳基丙+胴、2_m—二^ 基胺基-1-(4-咮啉基苯基）_ 丁酮_丨，2-苄基_2_二甲美胺基+ (4★林基苯基）丁+酮、4_二甲基胺基乙基^酸酯、4-二甲基胺基異戊基苯曱酸酯、4-二乙基胺基苯乙闕、4 —二甲基胺基苯丙鲷、2-乙基己基-1，4-二甲基胺基苯甲鷇g曰、2’ 5-雙（4-二乙基胺基苯亞甲基）環己酮、厂 97114141 44 200900859 二乙基胺基-3_(4_二乙基胺基苯曱酿基）香丑素、4-(二乙基胺基）查耳酮等。又，作為月亏S旨系衍生物類，例如可舉出以下化合物等。 [化 21]L-diyl)--all three ((ethoxy ethoxycalyl H, bis(dimethyl)- stilbene, etc.) Also as α-amino phenylalkyl ketone derivatives, 2_ +[4-(Methylthio)phenyl]_2_味琳基丙+胴, 2_m-diaminoamino-1-(4-carbolinylphenyl)-butanone 丨, 2-benzyl _2_Dimethylaminol+(4★林基phenyl)butanone, 4-dimethylaminoethylate, 4-dimethylaminoisoamylbenzoate, 4 -diethylaminophenylidene, 4-dimethylaminophenylpropionamidine, 2-ethylhexyl-1,4-dimethylaminobenzamide g曰, 2' 5-double (4- Diethylaminobenzylidene)cyclohexanone, plant 97114141 44 200900859 Diethylamino-3_(4-diethylaminobenzophenone) fragrant sulphate, 4-(diethylamino) (2) The following compounds are exemplified as the derivatives of the monthly loss S.

97114141 45 200900859 [化 22]97114141 45 200900859 [Chem. 22]

97114141 200900859 [化 23]97114141 200900859 [Chem. 23]

47 97114141 200900859 [化 24]47 97114141 200900859 [Chem. 24]

2'2'

97114141 200900859 [化 25]97114141 200900859 [Chem. 25]

Ο 此外，亦可舉出安息香甲醚、安息香苯醚、安息香異丁醚、安息香異丙醚等安息香烷醚類；2-曱基蒽醌、2-乙基蒽酿、2-第三丁基蒽醌、卜氯蒽醌等蒽醌衍生物類；二笨基_、米其勒酮、2-曱基二苯基酮、3-甲基二苯基酮、4-曱基二苯基酮、2-氯二苯基酮、4-溴二苯基酮、2-羧基二苯基酮等二苯基酮衍生物類；2,2_二曱氧基_2_苯基苯乙酮、2’2-二乙氧基苯乙酮、卜羥基環己基苯基酮、“ _羥基2甲基苯基丙酮、1-羥基-1-甲基乙基-(對異丙基苯基） :1經基1一（對十二燒基苯基）酮、2-甲基-(4, _曱硫基 2乙—:未琳基-卜丙鲷、u，1-三氣甲基-(對丁基苯基）、凋何生物類；9-氧硫咄嗟、2-乙基-9-氧硫咄嗟、 2 -異丙基氧石☆πΙ,σβ、。> 星、2-氣_9-氧疏卩山p星、2, 4-二甲基-9_ 氧硫卩山卩星、2 4--产苴η # ’ 一土氧硫口山嗟、2, 4-二異丙基-9-氧 97114141 49 200900859 石瓜口山Ρ星等9-氧硫咄ρ星衍生物類；對二酯、對其始甘— 〒基私基苯甲酸乙 ^曰乙基胺基苯甲酸乙s旨等苯甲酸㈣生物類.9 本基M、9-(對甲氧基苯基）十定等心定衍 ’ 二甲基苯并啡啡等啡畊衍生物類· 物頦’9, 10- 類等。 #开订生物類’本开相等‘！ _衍生物該等光聚合起始财，就靈敏度之方面酯糸衍生物類。尤隹為肪 N:乍為構f光聚合起始劑系成分之加速劑，例如可使用其炉一 9基苯甲酸乙二烧基胺基苯甲酸烧基3日’ 2-巯基苯并噻唑、美贫丑 70 唑等且右％浐夕2肩基本开。亏唑、2-巯基苯并咪广有雜㈣基化合物或脂肪族多官能疏基化合物用該等光聚合起始劑及加速劑可分別單獨使用，亦可併 Ο 作為，體，光聚合起始劑系成分，例 chemical」（1991 年、3 H ! 一 ne 16〜26頁之-产其“月1日唬、v〇l.20、No. 4)之第等以外，亦可舉出揭_日U 9_乳硫口山口星衍生物報、特公昭45-37377號八2利特開昭58—403023號公齒f基三讲系，揭示於日^ ^之六芳基聯口米0坐系、均三 4±ffajp. 4-2197^ ^ I本專利特開平4-221 958號公報、且有扩其〜么報等之二茂鈦與二苯并哌喃色素、具有胺基或胺基甲酸 + 基之可加成聚合的具有乙烯性不飽和雙鍵之化合物的組合系等。冲1 於光聚合起始劑系成分令Γ視需要可以提高感應靈敏度 97114141 50 200900859 ί 添加相應圖像曝光光源波長之增感色素。作為該背曰二、素彳舉出揭不於曰本專利特開平4~221 958 Γ = : 4娜6號公報之二苯并…素，揭示於曰本專利㈣平3—23簡號、㈣平_35號公報之 „環之香豆素色素，揭示於曰本專利特開平3_2397〇3 m平5-2瞻號公報之3-酮香豆素化合物，揭示 •於日本專利制平6 _丨9 2 4 G號公報之料亞甲基色素，此。3 =9舉出揭示於曰本專利特開昭47一2528號、特開昭 155292號、特公昭45_37377號、特開昭48_84ι83號、 =::'112681號、特開昭58 — 15503號、特開昭號、特開昭59-56403號、特開平2_69號、特開昭57-1_8號、特開平5_1〇7761號、特開平5_21_ 號、特開平4-288818號公報之具有二炫基胺基笨骨架之色素等。該等增感色素中，較佳為含有胺基之增感色素，更佳為 Q同一分子内具有胺基及苯基之化合物。尤佳為，例如4, 4，一二甲基胺基二苯基酮、4, 4，_二乙基胺基二苯基酮、2 —胺 :基二苯基酮、4_胺基二苯基酮、4,4’一二胺基二苯基酮、 —I3’—二胺基二苯基酮、3,4-二胺基二苯基酮等二苯基酮系化合物；2-(對二甲基胺基苯基）苯并嘮唑、2一（對二乙基胺基笨基）苯并$唾、2-(對二甲基胺基苯基）苯并[4,5] 苯并噚唑、2-(對二甲基胺基苯基）苯并[6,7]苯并噚唑、 2,5-雙（對二乙基胺基苯基）1，3,4—噚唑、2_(對二甲基胺基苯基）苯并噻唑、2-(對二乙基胺基苯基）苯并噻唑、 97114141 51 200900859 2-(對二曱基胺基苯基）苯并咪唑、2气對二乙基胺基苯基）苯并咪唾、2, 5-雙（對二乙基胺基苯基）1，3, 4-噻二唑、（對二曱基胺基苯基）吼啶、（對二乙基胺基苯基）π比啶、（對二甲基胺基苯基）喹啉、（對二乙基胺基苯基）喹啉、（對二曱基胺基苯基）嘧啶、（對二乙基胺基苯基）嘧啶等含有對二烧基胺基苯基之化合物等。 ; 其中最佳為4, 4,-二烷基胺基二苯基酮。 fs 又’增感色素可單獨使用1種’亦可將2種以上混合使 1」用。 (E)單體於本發明之著色樹脂組成物中，單體並非必需成分，但較佳為使用單體。作為本發明中所使用之單體，可使用具有一個以上乙烯性不飽和基之化合物（以下，稱作乙烯性化合物）。具體而言，可舉出脂肪族（多）羥基化合物與不飽和羧酸之酯；芳〇香族（多）羥基化合物與不飽和羧酸之酯；由不飽和羧酸、夕元羧S文及脂肪族多羥基化合物獲得之酯；芳香族多羥基化&物之環氧乙烷或環氧丙烷加成物與不飽和羧酸之酯 -化反應物；脂肪族多羥基化合物之環氧乙烷或環氧丙烷加成物與不飽和羧酸之酯化反應物；己内酯改質多元醇與不飽和羧酸之酯；多元醇、多元異氰酸酯與不飽和羧酸之反應物；苯乙烯基末端化合物；含鱗酸不飽和化合物；聚環氧與不飽和羧酸之加成物等。該等之中Μ乍為脂肪族⑷窥基化合物與不飽和叛酸之 97114141 52 200900859 酯’具體而言可舉出乙二醇二丙烯酸酯、三乙二醇二丙歸酸酯、新戊二醇二丙稀酸酯、己二醇二丙烯酸酯、三声甲基丙烷三丙烯酸酯、三羥曱基乙烷三丙烯酸酯、季戊四醇一丙卸酸s日、季戍四醇二丙稀酸目旨、季戍四醇四丙稀酉Λ 酯、二季戊四醇四丙烯酸酯、二季戊四醇五丙稀酸g旨、二季戊四醇六丙烯酸酯、甘油丙烯酸酯等丙烯酸酯，將該等例示化合物之丙烯酸酯替換為曱基丙烯酸酯之曱基丙缔酸酯’同樣地替換為伊康酸酯之伊康酸酯，替換為巴豆酸酯之巴豆酸酯或者替換為順丁烯二酸酯之順丁烯二酸醋等。曰作為芳香族（多）羥基化合物與不飽和羧酸之酯，可舉出對笨二酚二丙烯酸酯、對苯二酚二曱基丙烯酸酯、間苯二酚二丙烯酸酯、間苯二酚二曱基丙烯酸酯、鄰苯三酚三丙烯酸酯等。Ο In addition, benzoin ethers such as benzoin methyl ether, benzoin phenyl ether, benzoin isobutyl ether, and benzoin isopropyl ether; 2-mercaptopurine, 2-ethyl oxime, 2-t-butyl butyl Anthraquinone derivatives such as hydrazine and chloropurine; bis-phenylene, michelitone, 2-mercaptodiphenyl ketone, 3-methyldiphenyl ketone, 4-mercaptodiphenyl ketone a diphenyl ketone derivative such as 2-chlorodiphenyl ketone, 4-bromodiphenyl ketone or 2-carboxydiphenyl ketone; 2,2-dioxaoxy-2-phenylacetophenone, 2'2-diethoxyacetophenone, hydroxycyclohexyl phenyl ketone, "-hydroxy 2-methylphenylacetone, 1-hydroxy-1-methylethyl-(p-isopropylphenyl): 1 via a group of 1 (p-dodecylphenyl) ketone, 2-methyl-(4, _ thiol 2 ethane-: un-linyl-bupropion, u, 1-trimethyl-methyl-( p-Butylphenyl), withered organisms; 9-oxopurine, 2-ethyl-9-oxothione, 2-isopropyloxysulfide ☆πΙ, σβ, .gt; star, 2-gas_ 9-Oxygen sparse mountain p star, 2, 4-dimethyl-9_ oxysulfonate mountain comet, 2 4-- 苴苴 η # ' 一土氧硫口, 2, 4-diisopropyl -9-oxygen 97114141 49 200900859 stone 9-oxopurine ruthenium derivatives such as scorpion scorpion; p-diester, keto-yl benzoic acid, benzoic acid, ethyl benzoic acid, benzoic acid, benzoic acid (IV), biological class. 9 The basic group M, 9-(p-methoxyphenyl) decidine is the same as the derivation of dimethyl benzophenone and other morphological derivatives, such as 9 '9, 10-, etc. #开订生物The class 'this is equal'! _ Derivatives such photopolymerization start-ups, in terms of sensitivity, ester oxime derivatives. 隹隹 is a fat N: 乍 is an accelerator of the photo-polymerization initiator component, for example It can be used as a furnace, a 9-alkyl benzoic acid, ethanediamine benzoic acid, a 3-mercapto-2-benzothiazole, a poor ugly 70 azole, etc., and a right 浐 2 2 shoulder is basically opened. The mercaptobenzoimine heteropoly(tetra)-based compound or the aliphatic polyfunctional sulfhydryl compound may be used alone or in combination with the photopolymerization initiator and the accelerator. Example chemical" (1991, 3 H! a ne 16~26 page - the first of its "month 1st, v〇l.20, No. 4"), also can be cited as a U 9 _乳硫口山口星衍生Report, special public Zhao 45-37377 No. 8 2 Li Tekai Zhao 58-403023 No. 5, the public lecture of the syllabary, revealed in the day ^ ^ six aryl joint mouth rice 0 sitting system, all three 4 ± ffajp. 4- 2197^^I Patent Publication No. 4-221,958, and the addition of the ferrocene and dibenzopyran pigments, and the addition polymerization of an amine group or a carbamic acid + group. A combination of compounds having an ethylenically unsaturated double bond, etc. The composition of the photopolymerization initiator can increase the sensitivity of the sensation as needed. 97114141 50 200900859 ί Add the sensitizing pigment of the corresponding image exposure source wavelength. As the 曰曰、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、 (4) The coumarin pigment of the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _丨9 2 4 G. The material of the methylene pigment, 3:9 is disclosed in Japanese Patent Laid-Open No. 47-2528, Special Kai-Show 155292, Special Public Show 45_37377, Special Open 48_84ι83 No., =:: '112681, Special Open No. 58-15503, Special Open No., Special Open No. 59-56403, Special Kaiping No. 2_69, Special Open No. 57-1_8, Special Kaiping 5_1〇7761, A dye having a dihydrogenamine-based stupid skeleton, etc., which is disclosed in Japanese Laid-Open Patent Publication No. Hei No. Hei No. Hei. No. Hei 4-288818. The sensitizing dye is preferably an amine group-containing sensitizing dye, more preferably Q in the same molecule. A compound having an amine group and a phenyl group. More preferably, for example, 4, 4, monodimethylaminodiphenyl ketone, 4, 4, dimethylaminodiphenyl ketone, 2-amine: amide Phenyl ketone 4_Aminodiphenyl ketone, 4,4'-diaminodiphenyl ketone, -I3'-diaminodiphenyl ketone, 3,4-diaminodiphenyl ketone, etc. a compound; 2-(p-dimethylaminophenyl)benzoxazole, 2-(p-diethylaminophenyl)benzoxene, 2-(p-dimethylaminophenyl)benzene And [4,5] benzoxazole, 2-(p-dimethylaminophenyl)benzo[6,7]benzoxazole, 2,5-bis(p-diethylaminophenyl) 1,3,4-carbazole, 2-(p-dimethylaminophenyl)benzothiazole, 2-(p-diethylaminophenyl)benzothiazole, 97114141 51 200900859 2-(p-diyl) Aminophenyl)benzimidazole, 2-p-diethylaminophenyl)benzimid, 2,5-bis(p-diethylaminophenyl) 1,3,4-thiadiazole, (p-diodecylaminophenyl) acridine, (p-diethylaminophenyl)π-pyridinium, (p-dimethylaminophenyl)quinoline, (p-diethylaminophenyl) a compound containing a p-dialkylaminophenyl group such as quinoline, (p-didecylaminophenyl)pyrimidine or (p-diethylaminophenyl)pyrimidine, etc., wherein the most preferred is 4, 4,- Dialkyl Diphenyl ketone. FS and 'sensitizing dye may be used alone' two or more types may be mixed to make a "use. (E) Monomer In the colored resin composition of the present invention, the monomer is not an essential component, but a monomer is preferably used. As the monomer used in the present invention, a compound having one or more ethylenically unsaturated groups (hereinafter referred to as an ethylenic compound) can be used. Specifically, an ester of an aliphatic (poly)hydroxy compound and an unsaturated carboxylic acid; an ester of an aromatic sulfonate (poly) hydroxy compound and an unsaturated carboxylic acid; and an unsaturated carboxylic acid, And an ester obtained from an aliphatic polyhydroxy compound; an esterification reaction of an aromatic polyhydroxylated & ethylene oxide or propylene oxide adduct with an unsaturated carboxylic acid; an epoxy of an aliphatic polyhydroxy compound An esterification reaction of an ethane or propylene oxide adduct with an unsaturated carboxylic acid; an ester of a caprolactone-modified polyol with an unsaturated carboxylic acid; a reactant of a polyol, a polyisocyanate and an unsaturated carboxylic acid; a vinyl terminal compound; a scaly acid-containing unsaturated compound; an adduct of a polyepoxy group and an unsaturated carboxylic acid; and the like. Among these, it is an aliphatic (4) fluorescein compound and an unsaturated taurine 97114141 52 200900859 ester 'specifically, ethylene glycol diacrylate, triethylene glycol dipropionate, neopentyl Alcohol diacrylate, hexanediol diacrylate, trimethopropane triacrylate, trihydroxydecylethane triacrylate, pentaerythritol-propionic acid s day, quaternary tetral dipropylene acid An acrylate such as quaternary tetral tetrapropyl phthalate, dipentaerythritol tetraacrylate, dipentaerythritol pentapropylene acid, dipentaerythritol hexaacrylate or glycerin acrylate, and acrylates of the exemplified compounds The mercaptopropionate of the mercapto acrylate is similarly replaced with the itaconate of the iconate, replaced by the crotonate of the crotonate or the butylene of the maleate. Sour and so on. Examples of the ester of an aromatic (poly)hydroxy compound and an unsaturated carboxylic acid include p-diphenol diacrylate, hydroquinone dimercapto acrylate, resorcin diacrylate, and resorcin. Dimercapto acrylate, pyrogallol triacrylate, and the like.

作為藉由不飽和羧酸、多元羧酸及多元羥基化合物之酯化反應而獲得之醋’並非一定為單一物，作為代表性具體例，可舉出（甲基）丙烯酸、酞酸及乙二醇之縮合物，（甲基）丙烯酸、順丁烯二酸及二乙二醇之縮合物，（曱基）丙烯酸、對醜酸及季戊四醇之縮合物，（甲基）丙稀酸、己二酸、丁二醇及甘油之縮合物等。作為其他之本發明中所使用之乙烯性化合物之例子，伸龆,二？烯酉“女等丙烯醯胺類；酞酸二烯丙酯等烯丙酯類，酜酸二乙稀醋等含有乙稀基之化合物等亦有用。以上舉出之乙稀性化合物中，較佳為具有（甲基）丙烯醯 97114141 53 200900859 ί = 有丙_基者。作為尤佳之化合物，可舉季：四醇丙稀酸酯、三”基乙燒三丙烯酸酯、予从W鮮一丙烯酸酯、丙烯酸酯、二季戊醇二丙烯酸酯、季戊四醇四酯、二季戊四醇婦酸醋、二季戊四醇五丙婦酸乂以知/、丙烯酸酯等。該等（Ε)單體可單獨使 (F)溶劑蜀使用1種，亦可將2種以上併用。單合料劑'⑻ 使用。〃成为，溶解或分散至溶劑中之狀態下作為（F)溶劑，較佳為選擇组成物之m B冰解或刀月構成著色樹脂、、且成物之各成为，且沸點為1〇〇〜3 佳為具有12〇〜28〇。〇；彿點之溶劑。㉚圍内者。更作為上述溶劑，例如可舉出如下所述者。如乙二醇單甲鱗、乙二醇單乙轉、乙二醇醇單頂、丙二醇單甲H醇單乙_、己一醚、丙二醇第三丁醚、二乙二醇單甲醚、二 ^正丁 w ~^予單Λ秘、二乙二醇單正丁醚、甲氧基甲基戊醇、二 … 4 一酉子單乙麟、二丙二醇單曱醚、3-曱基-3—曱氧基丁醇、二 ^ g二醇罝审醚、三乙二醇單***、三丙二醇曱醚之二醇單烷醚類· 如乙二醇二曱醚、乙二醇二***、二乙二醇二甲醚’一乙二醇二***、二乙二醇二丙_、二乙二醇二丁_;The vinegar obtained by the esterification reaction of an unsaturated carboxylic acid, a polyvalent carboxylic acid, and a polyhydric hydroxy compound is not necessarily a single substance, and a typical example is (meth)acrylic acid, citric acid, and ethylene. a condensate of an alcohol, a condensate of (meth)acrylic acid, maleic acid and diethylene glycol, a condensate of (mercapto)acrylic acid, ruthenic acid and pentaerythritol, (meth)acrylic acid, hexan A condensate of acid, butanediol, and glycerin. As another example of the ethylenic compound used in the present invention, what is the extension? It is also useful for the olefinic group, such as propylene amides such as acrylamides; allyl esters such as diallyl phthalate, and compounds containing ethylene groups such as bismuth citrate and the like. Jiawei has (meth) propylene 醯 97114141 53 200900859 ί = has a propyl base. As a compound of Optima, it can be seasoned: tetraol acrylate, triterpene triacrylate, from W fresh Monoacrylate, acrylate, dipentaerythritol diacrylate, pentaerythritol tetraester, dipentaerythritol vinegar vinegar, dipentaerythritol pentane acetoacetate hydrazine, acrylate, and the like. One type of the (F) solvent may be used alone or two or more types may be used in combination. Single compound '(8) is used. In the state of being dissolved or dispersed in a solvent, as the solvent (F), it is preferred to select a composition of m B ice solution or a knife to form a colored resin, and each of the products is formed, and the boiling point is 1〇〇. ~3 good for having 12〇~28〇. 〇; the solvent of Buddha points. 30 inside. Further, examples of the solvent include the following. For example, ethylene glycol monomethine, ethylene glycol monoethylamine, ethylene glycol monotop, propylene glycol monomethyl alcohol, monohexyl ether, propylene glycol tert-butyl ether, diethylene glycol monomethyl ether, two ^正丁 w~^至单Λ秘, Diethylene glycol mono-n-butyl ether, methoxymethylpentanol, two... 4 一酉子单乙麟, Dipropylene glycol monoterpene ether, 3-mercapto-3 - 曱oxybutanol, dimethyl glycol oxime ether, triethylene glycol monoethyl ether, tripropylene glycol oxime ether glycol monoalkyl ethers, such as ethylene glycol dioxime ether, ethylene glycol diethyl ether, two Ethylene glycol dimethyl ether 'monoethylene glycol diethyl ether, diethylene glycol dipropyl _, diethylene glycol dibutyl _;

二醇二甲醚之二醇二烷醚類； J 97114141 54 200900859 Γ Ο 如乙二醇單曱醚乙酸酯、乙二醇單***乙酸酯、乙二醇單正丁_乙酸酯、丙二醇單甲醚乙酸酯、丙二醇單***乙酸醋、丙二醇單丙醚乙酸酯、丙二醇單丁醚乙酸酯、甲氧基丁基乙酸醋、3-甲氧基丁基乙酸酯、曱氧基戊基乙酸酉曰、一乙一醇單甲鱗乙酸酯、二乙二醇單乙鍵乙酸酯、二乙一醇單正丁醚乙酸酯、二丙二醇單甲醚乙酸酯、三乙二醇單甲醚乙酸酯、三乙二醇單***乙酸酯、3—曱基—3_曱氧基丁基乙酸酯之二醇烷醚乙酸酯類；乙二醇二乙酸酯、1，3-丁二醇二乙酸酯、丨，6—己醇二乙酸酯等二醇二乙酸酯類；環己醇乙酸酯等烷基乙酸酯類；如戊鱗、二乙域、二丙縫、二異丙鍵、二丁鱗、二戊崎、乙基異丁、二己轉之域類；如丙酮、甲基乙基酮、曱基戊基酮、甲基異丙基酮、甲 2戊基酮、二異丙基嗣、二異丁基酮、甲基異丁基綱、 =綱、乙基戊基|^、甲基丁基嗣、甲基己基闕、甲基壬基酮、甲氧基甲基戊酮之類；如乙醇、丙醇、丁酿、P龄丁二醇、二乙：/ ”壤己醇、乙二醇、丙二醇、醇、丙三醇如正戊烷烯、雙戊烯如環己烷式烴類；二：、一丙二醇、三乙二醇'甲氧基甲基戊卞醇之—元或多元醇類；正辛烷、一異丁烯、正己烷、己烯、異戊二十二烷之脂肪族烴類；、一曱基環己烧、甲其？班ρ γ Τ基％己烯、聯環己烷之脂環 97114141 55 200900859 如苯、甲苯、二曱苯、異丙苯之芳香族烴類；如曱酸戊酯、曱酸乙酯、醋酸乙酯、醋酸丁酯、醋酸丙酯、醋酸戊酯、異丁酸曱酯、乙二醇乙酸酯、丙酸乙酯、丙酸丙酯、丁酸丁酯、丁酸異丁酯、異丁酸曱醋、辛酸乙酯、硬脂酸丁酯、苯曱酸乙酯、3-乙氧基丙酸曱酯、3-乙氧基丙酸乙酯、3-曱氧基丙酸曱酯、3-曱氧基丙酸乙；酯、3 -曱氧基丙酸丙酯、3 -曱氧基丙酸丁_、γ 一丁内酯之鍵狀或環狀g旨類； f) ^ 如3-甲氧基丙酸、3-乙氧基丙酸之烧氧基缓酸類；如氣丁烷、氯戊烷之鹵化烴類；如曱氧基甲基戊酮之醚酮類；如乙腈、苯甲腈之腈類等；作為相當於上述溶劑之市售溶劑，可舉出礦油精 (mineral spirit)、Varsol # 2、Apco# 18 溶劑、Apco 稀釋劑（Apco thinner)、Socal Solvent No. 1 及 No. 2、 υ SOLVESSO#150、SHELLTS28溶劑、卡必醇、乙基卡必醇、 T基卡必噼、曱基赛珞蘇、乙基賽珞蘇、乙基赛珞蘇乙酸 .點、甲基赛珞蘇乙酸酯、Diglyme (二乙二醇二甲醚）（均為 . 商品名）等。 Λ 該等溶劑可單獨使用，亦可將2種以上併用。 (利用光Μ衫法开》成彩色滤光片之像素或黑色矩陣之情況下之溶劑）主於利用光微影法’形成彩色濾、光片之像素或黑色矩陣之情況，作為溶劑，較佳為選擇沸點為1〇〇〜2〇(rc(壓力為 97114141 56 200900859 1013. 25[hPa]之條件下。以下，關於沸點完全相同。）之範圍者。更佳為具有12〇〜17(rc之沸點者。上述溶劑中，就塗佈性、表面張力等之平衡良好且組成物中之構成成分之溶解度較高之方面而言，較佳為二醇烧醚乙酸酯類。又，二醇烷醚乙酸酯類可單獨使用，亦可併用其他溶 '州作為併用之溶劑，尤佳為二醇單烷醚類。其中，就組 p成物t之構成成分之溶解性而言，尤佳為丙二醇單甲鱗。再者一％單烷醚類之極性高，若添加量過多則存在顏料易於凝XK，隨後彳隻得之著色樹脂組成物之黏度上升等保存穩定性下降之傾向，因此溶劑中之二醇單燒峻類之比例^ 仫為5重置％〜3〇重量％,更佳為5重量％〜2〇重量％。「士 ’併用具有15(rc以上沸點之溶劑（以下，有時稱作向彿點溶劑」。）亦較佳。藉由併用上述高沸點溶劑色樹脂組成物難以乾燥，<旦具有防止組成物中之顏料之均 υ勻分散狀態由於急劇乾燥而被破壞之效果。即，具有防止嘴前端中由於色材等之析出、固化而；生異物 , 二、就上述效果高之方面而言，上述各種溶劑，gt 5佳為二乙二醇單正丁醚、二乙二醇單正丁醚乙酸西曰、一乙—醇單***乙酸酯。浴劑中之高沸點溶劑之含有比例，較佳為3重二，更佳為5重量%〜4。重量%，尤佳為5重量;：中=色^等弗^；容劑量過少，則存在例如狹缝嘴嘴前端色材4析出、固化而產生異物缺陷之可能性，又， 97114141 57 200900859 若過多，則擔心組成物之乾燥速度變慢，而引起下述彩色濾光片製造步驟中之減壓乾燥製程之生產節拍不良或預烘烤之針痕之問題。再者，沸點為150 C以上之高沸點溶劑，可為二醇烷醚乙酸酯類，又，亦可為二醇烷醚類，於該情況下，可不另行包含沸點為15(rc以上之高沸點溶劑。作為較佳之高沸點溶劑，例如上述各種溶劑中，可舉出Glycol dialkyl ethers of glycol dimethyl ether; J 97114141 54 200900859 Γ Ο such as ethylene glycol monoterpene ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol mono-n-butyl-acetate, Propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monobutyl ether acetate, methoxybutyl acetate vinegar, 3-methoxybutyl acetate, hydrazine Barium oxypentyl acetate, monomethyl sulphate monoacetate, diethylene glycol monoethyl acetate, diethylene glycol mono-n-butyl ether acetate, dipropylene glycol monomethyl ether acetate, three Glycol monomethyl ether acetate, triethylene glycol monoethyl ether acetate, diol alkyl ether acetate of 3-mercapto-3-indolyl butyl acetate; ethylene glycol diacetate a glycol diacetate such as an ester, 1,3-butanediol diacetate, hydrazine or 6-hexanol diacetate; an alkyl acetate such as cyclohexanol acetate; Domains such as acetone, methyl ethyl ketone, decyl amyl ketone, methyl ketone; Propyl ketone, methyl 2-keto ketone Diisopropyl hydrazine, diisobutyl ketone, methyl isobutyl amide, = yl, ethyl amyl |, methyl butyl hydrazine, methyl hexyl hydrazine, methyl decyl ketone, methoxy methyl pentanone Such as ethanol, propanol, butyl, P-butylene glycol, diethylene: / "l-hexyl alcohol, ethylene glycol, propylene glycol, alcohol, glycerol such as n-pentane, dipentene such as cyclohexane Hydrocarbons; 2: propylene glycol, triethylene glycol 'methoxymethylpentanol- or polyhydric alcohols; n-octane, isobutylene, n-hexane, hexene, isoprene Aliphatic hydrocarbons; 曱曱己己、、甲、、、、 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 971 Hydrocarbons; such as amyl citrate, ethyl citrate, ethyl acetate, butyl acetate, propyl acetate, amyl acetate, decyl isobutyrate, ethylene glycol acetate, ethyl propionate, C Butyl acrylate, butyl butyrate, isobutyl butyrate, bismuth acetonate, ethyl octanoate, butyl stearate, ethyl benzoate, decyl 3-ethoxypropionate, 3-B Ethyl oxypropionate 3-decyloxypropionate, 3-methoxypropionic acid B; ester, 3-methoxypropionic propionate, 3-methoxypropionic acid butyl, γ-butyrolactone linkage or a ring-shaped g-type; f) ^ such as 3-methoxypropionic acid, 3-ethoxypropionic acid, alkoxylates; halogenated hydrocarbons such as gas butane, chloropentane; An ether ketone of a pentanone; a nitrile such as acetonitrile or benzonitrile; and a commercially available solvent corresponding to the above solvent, mineral spirit, Varsol #2, Apco# 18 solvent, Apco Thinner (Apco thinner), Socal Solvent No. 1 and No. 2, υ SOLVESSO #150, SHELLTS28 solvent, carbitol, ethyl carbitol, T-carbamide, thiopyrazine, ethyl Bismuth, ethyl cyanohydrin, etc., methyl acesulfame acetate, Diglyme (diethylene glycol dimethyl ether) (both. trade name). Λ These solvents may be used singly or in combination of two or more. (The solvent used in the case of a pixel or a black matrix of a color filter by using a light-coated shirt method) is mainly used as a solvent by using a photolithography method to form a color filter or a pixel of a light film or a black matrix. Preferably, the boiling point is 1〇〇~2〇(rc (pressure is 97114141 56 200900859 1013. 25[hPa]. Below, the boiling point is exactly the same.). More preferably has 12〇~17 ( In the above solvent, in terms of a good balance between coatability and surface tension, and a high solubility of constituent components in the composition, diol ether ether acetate is preferred. The alcohol alkyl ether acetates may be used singly or as a solvent for use in combination with other solvents, and particularly preferably a glycol monoalkyl ether. Among them, the solubility of the constituents of the group p product t is particularly The propylene glycol monomethyl squama is preferred. Further, the monomethyl ether ether has a high polarity, and if the amount is too large, the pigment tends to condense XK, and then the viscosity of the colored resin composition is increased, and the storage stability is lowered. Therefore, the diol in the solvent is single-burned. The ratio ^ 仫 is 5 reset % to 3 〇 wt%, more preferably 5% by weight to 2 〇 wt%. "The s" uses a solvent having a boiling point of 15 or more (hereinafter, sometimes referred to as a solvent for the Buddha) Further, it is preferable that the above-mentioned high-boiling solvent color resin composition is difficult to dry, and has an effect of preventing the uniform dispersion state of the pigment in the composition from being destroyed by rapid drying. In the front end, the coloring material or the like is precipitated and solidified; and the foreign matter is produced. 2. In terms of the above-mentioned effects, the above various solvents, gt 5 are preferably diethylene glycol mono-n-butyl ether or diethylene glycol mono-n-butyl The content of the high boiling point solvent in the bath is preferably 3 parts by weight, more preferably 5% by weight to 4% by weight, and particularly preferably 5 parts by weight. ;: Medium = color ^ et al ^; If the dose is too small, there is a possibility that, for example, the color material 4 at the tip end of the slit nozzle is precipitated and solidified to cause foreign matter defects, and 97114141 57 200900859, if too much, the composition is dried. Slower speed, resulting in the following color filter manufacturing steps The problem of poor tempo or pre-baked needle marks in the press drying process. Further, the high boiling point solvent having a boiling point of 150 C or higher may be a glycol alkyl ether acetate or a glycol alkyl ether. In this case, a high boiling point solvent having a boiling point of 15 or more is not included. As a preferred high boiling point solvent, for example, the above various solvents may be mentioned.

二乙二醇單正丁醚乙酸醋、二乙二醇單***乙酸S旨、二丙 :醇甲鍵乙酸醋、以―丁二醇二乙酸醋、U一己醇二乙酸酉曰、甘油三乙酸酯（triacetin)等。 (利用噴墨法形成彩色濾光片之像素之情況下之溶劑）於利用喷墨法形成彩色濾光片之像素之情況，作為溶劑’適當的是沸點通常^ 13代以上且如代以下，較佳為W以上且戰以下者。若溶劑之沸點過低，則存 =得，塗膜之均勻性不良之傾向。相反，若溶劑之沸點 t回⑧如下所述，雖然著色樹脂組成物之乾燥抑制效果有時於熱锻燒後，塗針仍存在大量殘留溶劑而產良’或者由於真空乾燥等之乾燥時間延長，而產生增加生產節拍時間（tact time)等問題。而：溶劑：蒸氣壓，就所得之塗膜之均勻性之觀點 :^吏用通吊為！〇 mmHg以下’較佳為5 以下，更住為1 mmHg以下者。時，因自喷嘴喷出故存在於著落於噴再者，於利用喷墨法製造彩色濾光片之油墨為非常微細之數PL〜數十仙， 97114141 58 200900859 或:f、組内，f、，溶劑蒸發而油墨產生濃縮、乾含之詞A 1避免#情況’較佳為著色樹脂組成物+所 3 I /合别為南〉弗點，目触尤丄含彿點為⑽。c以上之卜較佳為著色樹脂組成物包沸點為2〇m尤更佳㈣色樹麵成物包含沸點為仏為沸點為22(TC以上之溶劑。又，沸”沾為180 C以上之高沸點溶劑，於濾光片用著色榭浐相忐铷λ 、，墨及/或衫色 50會曰。/ 中所含之總溶劑中，較佳為占 Ο 旦^/以上，更佳為占70重量％以上，最佳為占90重 :二二於總溶f中之沸點為18 〇〇C以上之高沸點溶劑自r、1 $ z高5〇重量％之情況’有時無法充分發揮防止溶劑自液滴蒸發之效果。作為彿點為18(rc以上之高彿點溶劑之較佳溶劑，例如亡，，溶劑中，可舉出二乙二醇單正丁趟乙酸醋、二乙一醇單***乙酸酯、二丙二醇曱醚乙酸酯、丨，3—丁二醇二乙酸酯、1，6-己醇二乙酸酯、甘油三乙酸酯等。一進而，為了調整下述油墨或著色樹脂組成物之黏度或固形分之溶解度，包含一部分沸點低於丨8〇它之溶劑亦有 -效。作為上述溶劑，較佳為低黏度且溶解性高、低表面張 r力之溶劑，較佳為醚類、酯類或酮類等。其中，尤佳為产己酉同、一丙，一醇一曱酸、環己醇乙酸|旨等。 ‘、、、另一方面，若溶劑包含醇類，則有時喷墨法中之噴出穩定性不良。由此，醇類較佳為占總溶劑中之20重量％2 下，更佳為占10重量％以下，尤佳為占5重量％以下里0以 (G)其他成分 97114141 59 200900859 本發明之著色樹脂組成物，除了包含（A)色材、⑻有黏合劑、（C)分散劑及視需要調配之（D)光聚合起始劑、單體、（F)m ’進而可視需要添加密著改善劑、塗佈性改善劑、顯影改良劑等。 $ [調配比例] 於本發明之著色樹脂組成物中，（A)色材之調配量於色樹脂組成物之總固形分中，通常占3〇〜7〇重量％，較為35〜65重量％。土 :(A)色材之調配量未滿上述範圍，則存在著色性(於⑷ =為黑色之情況為遮光性）下降之可能性。尤其於含有 :材作為⑴色材之黑色矩陣用著色樹脂組成物之情形成光學密度充分之樹脂黑色矩陣。相反地，若顯旦/㈣之㈣1超過上述範圍’則有時靈敏度、解析性、性4不充分，存在難以形成圖像之可能性。量===脂組成物中，⑻有機黏合劑之調配成物之總固形分中，通常占5〜80重量 %，較佳為10〜50重量％。有機黏合劑之調配量少於上述範圍，則存在顯影性不充刀之傾向’若多於上述傾向，或色密h充分之可紐料在祕度不良之 # ^ ( A) t 3〇(# ^ ^ #i ^ ^ ^ ^ ^ 25重量％。材^仏為0.1〜30重量％，尤佳為0.5〜則有時分散穩定若（C)分散劑之調配量少於上述範圍 97114141 200900859 性不充分，若多於上述範圍，則有時光學密度、靈敏度或顯影性不充分。 f本發明之著色樹腊組成物中，⑻光聚合起始劑之調里係相對於100重量份之（β)有機黏合劑，通常為〇·工〜^0重讀，較佳為卜45重量份。若（D)光聚合起始劑之調配，未滿上述範圍’财時靈敏度不充分，又，若超Diethylene glycol mono-n-butyl ether acetate vinegar, diethylene glycol monoethyl ether acetate S, dipropylene: alcohol methyl acetate, butyl glycol diacetate, U-hexanol diacetate, glycerol triethyl Triacetin and the like. (Solvent in the case of forming a pixel of a color filter by an inkjet method) When a pixel of a color filter is formed by an inkjet method, as a solvent, it is appropriate that the boiling point is usually 13 generations or more and below, It is preferably W or more and the following. If the boiling point of the solvent is too low, the uniformity of the coating film tends to be poor. On the other hand, if the boiling point t of the solvent is as follows, the drying inhibition effect of the colored resin composition may be such that a large amount of residual solvent is present on the needle after hot calcination, and the drying time is prolonged due to vacuum drying or the like. , resulting in increased production tact time (tact time) and other issues. And: Solvent: vapor pressure, the viewpoint of the uniformity of the obtained coating film: ^ 吏 use the hanging crane! 〇 mmHg or less is preferably 5 or less, and is more than 1 mmHg. When it is sprayed from the nozzle, it is present in the spray, and the ink for producing the color filter by the ink jet method is a very fine number PL to several tens of centimeters, 97114141 58 200900859 or: f, in the group, f The solvent is evaporated and the ink is concentrated, and the dry word A 1 is avoided. The case is preferably a colored resin composition + 3 I / the combination is a south point, and the point of contact is (10). Preferably, the coloring resin composition has a boiling point of 2 〇m or more. (4) The coloring of the tree surface comprises a boiling point of 仏, which is a solvent having a boiling point of 22 (TC or more. Further, boiling) is 180 C or more. The high-boiling solvent is preferably used in the total solvent contained in the coloring 榭浐 phase λ, the ink and/or the color of the film 50. Preferably, it is more than ^ / above, more preferably 70% by weight or more, preferably 90% by weight: 22% of the high boiling point solvent in the total solution f is 18 〇〇C or higher, and the case is higher than 5 重量% by weight of r, 1 $ z. It is effective to prevent the solvent from evaporating from the droplets. As a preferred solvent for a high-foam solvent of 18 or more, the solvent is, for example, diethylene glycol mono-n-butyl hydrazine acetate, and Ethyl alcohol monoethyl ether acetate, dipropylene glycol oxime ether acetate, hydrazine, 3-butanediol diacetate, 1,6-hexanol diacetate, triacetin, etc. Adjusting the viscosity of the following ink or colored resin composition or the solubility of the solid component, including a part of the solvent having a boiling point lower than 丨8, and also having a effect. The solvent is preferably a solvent having a low viscosity and a high solubility and a low surface tension, and is preferably an ether, an ester or a ketone, etc. Among them, it is particularly preferred to produce a propylene, a propylene, an alcohol Hydric acid, cyclohexanol acetic acid, etc. On the other hand, if the solvent contains an alcohol, the discharge stability in the inkjet method may be poor. Therefore, the alcohol preferably accounts for the total solvent. More preferably, it is 10% by weight or less, more preferably 10% by weight or less, and particularly preferably 5% by weight or less of 0 to (G) other components 97114141 59 200900859 The colored resin composition of the present invention, except for (A) color material (8) There are binders, (C) dispersants, and (D) photopolymerization initiators, monomers, and (F)m' which may be added as needed. Further, a adhesion improving agent, a coating property improving agent, and development improvement may be added as needed. Agent [Equation ratio] In the colored resin composition of the present invention, (A) the amount of the color material is generally 3 to 7 〇% by weight of the total solid content of the color resin composition, more than 35~ 65% by weight. Soil: (A) When the amount of the color material is less than the above range, coloring is present (in the case of (4) = black) The possibility of a decrease in the light-shielding property. In particular, a resin black matrix having a sufficient optical density is formed as a coloring resin composition for a black matrix of (1) color material. Conversely, if (a) 1 of the sensation/(4) exceeds the above range' In some cases, the sensitivity, the resolution, and the property 4 may be insufficient, and there is a possibility that it is difficult to form an image. The amount === in the fat composition, and (8) the total solid content of the organic binder is usually 5 to 80. The weight % is preferably 10 to 50% by weight. When the compounding amount of the organic binder is less than the above range, there is a tendency that the developability is not filled with a knife, 'if more than the above tendency, or the color density h is sufficient Poor degree # ^ ( A) t 3〇 (# ^ ^ #i ^ ^ ^ ^ ^ 25 wt%. The material is 0.1 to 30% by weight, and particularly preferably 0.5 to be dispersed stably. If the amount of the (C) dispersant is less than the above range, 97114141 200900859 is insufficient, and if it is more than the above range, the optical density may be , sensitivity or developability is not sufficient. f In the colored tree wax composition of the present invention, (8) the photopolymerization initiator is adjusted to 100 parts by weight of the (β) organic binder, usually 〇·工~^0, preferably 45 weight. Share. If the (D) photopolymerization initiator is blended, the sensitivity is not sufficient when the above range is exceeded.

L, °述範圍則存在降低著色樹脂組成物之成膜性之傾向。 ⑻單體係相對於⑽重量份之⑻有機黏合劑，通常於〇〜？0重I份，較佳為3〜18。重量份之範圍内使用。若 (E)單體之使用比例未滿上述範圍，則交聯密度不充分，有時所得圖案之耐久性、耐熱性等方面出現問題。又，若超過上述範圍，則有時顯影性下降。又，上述增感色素之調配量，係相對於100重量份之（B) =機黏合劑’通常為0.H0重量份，較佳為〇1〜1〇重量份。若增感色素之調配量超過上述範圍，則存在所得圖案形狀不良之可能性。 —再者，本發明之著色樹脂組成物，使用上述（F)溶劑進 =調液，直至其固形分濃度成為通常為5〜重量％，較佳為10〜30重量％之範圍内。 [製造方法] 八人，就本發明之著色樹脂組成物（以下，稱作「抗姓劑」。）之製造方法，加以說明。於製造本發明之I色樹脂組成物時，m常較佳為預先使 97114141 200900859In the range of L, °, there is a tendency to lower the film formability of the colored resin composition. (8) Single system relative to (10) parts by weight of (8) organic binder, usually in 〇~? 0 parts by weight, preferably 3 to 18. Used within the range of parts by weight. When the ratio of use of the (E) monomer is less than the above range, the crosslinking density is insufficient, and problems such as durability and heat resistance of the obtained pattern may occur. Moreover, when it exceeds the said range, the developability may fall. Further, the amount of the sensitizing dye is usually 0.H0 parts by weight, preferably 〇1 to 1 part by weight, based on 100 parts by weight of the (B) = machine binder. If the amount of the sensitizing dye is more than the above range, there is a possibility that the shape of the resulting pattern is poor. Further, in the colored resin composition of the present invention, the above (F) solvent is used to adjust the liquid until the solid content concentration is usually in the range of 5 to 30% by weight, preferably 10 to 30% by weight. [Manufacturing method] The manufacturing method of the colored resin composition of the present invention (hereinafter referred to as "anti-surname") will be described. When manufacturing the I color resin composition of the present invention, m is usually preferably made in advance to 97114141 200900859

用塗料調節器、砂磨機、球磨機、輥磨機、石磨機、喷磨機、均質器等，將⑴色材進行分散處理。藉由分散處理而使⑴色材微粒子化，故提高抗姓劑之塗佈^ I =使用黑色色材作為⑴色材之情況，有助於提高遮光能刀政處理’較佳為於併用(Α)色材、⑹分 :?二要尸Γ黏合劑之-部分或全部的系統内進：之組分散處歡齡物及心料理獲得為⑹二=制分子分散劑作 (分散穩定性優異)，故較佳二之f時增黏組成物中調配之绚成分 ' 於者色樹脂分散f2 體進行分散處理之情況，由於处守生之發熱，存在高反應性成分改質之可& 性。因此，較佳為於包含上诚占八夕多处刀改貝之可迠於利用砂磨线_行分散處理。 Ο 随左右吉情況’可較佳地使m 0.1〜8 直仫之玻璃珠或氧化锆珠。至於溫度通常為rc至，C，較佳為室溫至件’ ，根據液體組成及分散處理裝置之尺:等之;，有所不同’故適宜調節。分散標準為如下尺控制為使抗_之2G度鏡面光^之先澤，。之範圍内。於抗_之光澤度：)成為：密著性、解析;糙顏料(色材)粒子至m 4 可能性。又，若進行分埒声柿澤值超過上述範圍，則存在顏料破碎而產生許 97114141 62 200900859 粒子’反而損害分散穩定性之傾向。其次’混合藉由上述分散處理而獲得之油墨與抗蝕劑中所含之上述其他成分，製成㈣溶液。於錢劑之製造步驟二，微細灰塵經常混入液體中，故所得之抗姓劑，較佳為藉由過濾、器等進行過濾處理。 [彩色濾光片] ：其次’就使用本發明之著色樹脂組成物之彩色濾、光片，依據其製造方法加以說明。 Γ為了製造本發明之彩色濾、光片，首先，於透明基板上塗佈本發明之感光性著色樹脂組成物，將其乾燥後，於該試料上放置光罩，經由該光罩進行圖像曝光、顯影，視需要進行熱硬化或光硬化’從而形成圖案。藉由該製程，通常，百先製作樹脂黑色矩陣，繼而，形成紅（[〇、綠…）、藍（β) 之3色像素’藉此形成彩色濾、光片。 [透明基板] 〇對於透明基板之材質並無特別限制，例如可舉出聚駄酸乙二酯等聚酯，或聚丙烯、聚乙烯等聚烯烴等，聚碳酸酯、 :聚甲基丙烯酸甲酯、聚砜等熱可塑性塑膠片材，環氧樹 .脂、聚酯樹脂、聚（曱基）丙烯酸系樹脂等熱硬化性塑膠片材，或者各種玻璃板等。尤其就耐熱性方面而言，可較佳地使用玻璃板、耐熱性塑膠片材。於透明基板上，為了改善其表面之黏著性等物性，亦可預先進行電暈放電處理、臭氧處理、矽烷偶合劑或胺基曱酸乙ί旨聚合物等各種聚合物之薄膜處理等。 97114141 63 200900859 [著色樹脂組成物之塗佈及乾燥] 對於透明基板上塗佈著色樹脂組成物之方法並無特別限定，通常使用旋轉塗佈機、線棒塗佈機、淋塗機、模塗機、輥塗機、喷霧器等塗佈裝置進行。塗佈後之乾燥可使用加熱板、IR烘箱、對流烘箱等，較佳為乾燥條件為40〜150。(： ’乾燥時間為秒〜6〇分鐘之範圍。 Γ 塗佈、乾燥後之樹脂黑色矩陣之膜厚，通常為〇 1〜2 #m，較佳為〇.1〜1.5 ，更佳為之範圍。再者，本發明之彩色濾光片中之樹脂黑色矩陣，就遮光性之方面而言，較佳為每i以瓜膜厚之光學密度為3 〇以上。又，作為（A)色材之分散狀態之指標，較佳為里色矩陣之20度鏡面光澤度（JIS 28741 )為1〇〇〜2〇〇。 [曝光及顯影] 曝光時使用之光源，例如可舉出氣氣燈、_素燈、鎢燈、高壓水銀燈、超高壓水銀燈、金屬齒素燈、中壓水銀^、低壓水銀燈等燈光源，或氬離子雷射、YAG雷射、準^子雷射、氮氣雷射等雷射光源等。於僅使用特定之照射光波長之情況’亦可利用光學濾光片。〜 ' 顯影處理時使用之顯影液，若❹有可溶解未曝光部分之杬蝕膜之能力的液體，則無特別限制。例如，亦可丙網、二氯甲烷、三氯乙烯、環己_等有機溶劑:：有機溶劑具有環境汚染、對人體之有害性、 ^ 等，故較佳為使用不具有上述危險性之驗性顯影 97114141 200900859 作為上述鹼性顯影液， ^ ^ ^ j 了舉出包含碳酸鈉、碳酸卸石夕酸納、石夕酸鉀、氣氧化韵 ^ 或者二乙醇胺、三乙醇胺飞氧化鉀4無機驗劑’ 的水溶液。虱氧化四烷基銨鹽等有機鹼劑鹼性顯影液中，視需要機溶劑、具有經基或竣基之低物等劑尤：二有面活性劑具有對顯影性、解析性料=夕界較佳為予以添加。彳之改良效果’故The (1) color material is subjected to dispersion treatment using a paint regulator, a sand mill, a ball mill, a roll mill, a stone mill, a jet mill, a homogenizer, and the like. By dispersing the (1) color material microparticles, the coating of the anti-surname agent is improved. I = the use of the black color material as the (1) color material, which contributes to the improvement of the shading treatment. Α) color material, (6) points: two parts of the corpse adhesive - part or all of the system: the group of dispersions of the aging and heart dishes are obtained (6) two = molecular dispersing agent (excellent dispersion stability Therefore, it is preferable to adjust the composition of the bismuth component in the viscosity-increasing composition at the time of f. The disperse treatment of the dispersion of the resin in the color resin is carried out, and the high reactivity component can be modified due to the heat of the circumstance. . Therefore, it is preferable to use a sanding line _ row dispersion treatment in the case of including a plurality of knives. Ο With the case of the left and right, it is preferable to make m 0.1 to 8 straight glass beads or zirconia beads. The temperature is usually rc to, C, preferably room temperature to the part, depending on the composition of the liquid and the size of the dispersion treatment device: etc., which are different. The dispersion standard is controlled as follows to control the 2G degree mirror light of the anti-_. Within the scope. The gloss of the anti- _:: becomes: adhesion, analysis; rough pigment (color material) particles to m 4 possibility. Further, when the value of the split sound permeation exceeds the above range, the pigment is broken and the particles tend to impair the dispersion stability. Next, the ink obtained by the above dispersion treatment and the other components contained in the resist are mixed to prepare a (iv) solution. In the second production step of the money agent, fine dust is often mixed into the liquid, so that the obtained anti-surname agent is preferably subjected to filtration treatment by filtration, the like, or the like. [Color filter]: Next, a color filter or a light sheet using the colored resin composition of the present invention will be described in accordance with the production method. In order to manufacture the color filter and the light sheet of the present invention, first, the photosensitive colored resin composition of the present invention is applied onto a transparent substrate, dried, and then a mask is placed on the sample, and an image is formed through the mask. Exposure, development, thermal hardening or photohardening as needed to form a pattern. By this process, usually, a resin black matrix is formed first, and then three (color pixels of red ([〇, green...), blue (β)] are formed, thereby forming a color filter and a light sheet. [Transparent Substrate] 〇 The material of the transparent substrate is not particularly limited, and examples thereof include polyesters such as polyethylene phthalate, polyolefins such as polypropylene and polyethylene, and polycarbonates: polymethyl methacrylate Thermoplastic plastic sheets such as esters and polysulfones, thermosetting plastic sheets such as epoxy resin, polyester resin, poly(fluorenyl) acrylic resin, or various glass plates. In particular, in terms of heat resistance, a glass plate or a heat-resistant plastic sheet can be preferably used. On the transparent substrate, in order to improve the physical properties such as adhesion on the surface, a film treatment of various polymers such as a corona discharge treatment, an ozone treatment, a decane coupling agent, or an amino phthalic acid-based polymer may be performed in advance. 97114141 63 200900859 [Coating and Drying of Colored Resin Composition] The method of applying the colored resin composition on the transparent substrate is not particularly limited, and a spin coater, a bar coater, a coater, and a die coat are usually used. It is carried out by a coating device such as a machine, a roll coater or a sprayer. The drying after coating can be carried out using a hot plate, an IR oven, a convection oven or the like, preferably 40 to 150. (: 'The drying time is in the range of seconds to 6 minutes. Γ The film thickness of the resin black matrix after coating and drying is usually 〇1~2 #m, preferably 〇.1~1.5, more preferably Further, the resin black matrix in the color filter of the present invention preferably has an optical density of 3 Å or more per iv film thickness in terms of light shielding property. Further, as (A) color The index of the dispersion state of the material is preferably a 20 degree specular gloss (JIS 28741) of the neutral matrix of 1 〇〇 to 2 〇〇. [Exposure and development] A light source used for exposure, for example, a gas lamp , _ prime lamp, tungsten lamp, high pressure mercury lamp, ultra high pressure mercury lamp, metal tooth lamp, medium pressure mercury ^, low pressure mercury lamp, etc., or argon ion laser, YAG laser, quasi-son laser, nitrogen laser Such as a laser source, etc. The optical filter can also be used when only a specific wavelength of the illumination light is used. ~ ' The developer used in the development process, if it has the ability to dissolve the etched film of the unexposed portion There is no particular limitation on the liquid. For example, it can also be a network of propylene, dichloromethane or trichloroethane. Organic solvents such as olefin and cyclohexane:: Organic solvents have environmental pollution, harmfulness to human body, etc., so it is preferable to use the invisible development 97114141 200900859 which does not have the above-mentioned danger as the above alkaline developing solution, ^ ^ ^ j An aqueous solution containing sodium carbonate, sodium sulphate, potassium oxalate, gas oxidized or diethanolamine, triethanolamine, and potassium oxide 4 inorganic test agent is given. In the organic alkaline agent alkaline developing solution, if necessary, an organic solvent or a low substance having a warp group or a sulfhydryl group may be added. The two surfactants are preferably added to developability and analytical materials. Improvement effect

V :如’作為顯影液中所使用之界萘磺酸鈉基、苯磺酸鈉基 J舉出具有 ^" 丞之陰離子性界面活性劑，且右咿伸烷氧基之非離子性界面：j -有t 子性界面活性㈣。 m具有四絲銨基之陽離較處理方法並無特別限定，通常A 10〜50。。，旦/;〜45 c之顯影溫度下’藉由浸潰顯影、噴霧顯影1式顯影、超音波顯影等方法進行。贺務顯 Ο 藉由上述著色樹脂組成物驟，而製作樹曝先及顯影步色译光I主陣及RGB3色像素，藉此可獲得彩本發明之著色樹脂組成物，可用於形成 …色矩陣，亦可用於形成RGB之像素。成 =’於使用本發明之著色樹脂組成物形成彩 :像素之情況，因具有非常高之靈敏度及解析力，故可二开=聚乙稀醇等氧阻隔層之狀態下，進行曝光、顯影而开）成圖像。只办而 [液晶顯示裝置（面板）] 97114141 65 200900859 本發明之液晶顯示裝置可使用上述彩色濾光片，以如下所述方式製造。首先於Α色;慮光片上形成配向膜，於該配向膜上配置間隔件後，與對向基板貼合而形成液晶單元。繼而，於所形成之液晶單兀中注入液晶，與對向電極接線而完成。配向膜較佳為聚酿亞胺等樹脂膜。配向膜之形成通常採 =凹版印刷法或可撓性凸版印職，通常將配向膜之厚度二為10〜1〇〇 nm。藉由熱煅燒進行配向膜之硬化處理後， '"曰由|外線之照射或使用配向布（^沾丨叫ci〇th)之處理而進行表面處理’加工成可調節液晶斜率之表面狀態。、間隔件係使用相應與對向基板之間隙（卿）之大:者，通兩較佳為2〜8 者。於彩色濾光片基板上，採用光微影法形成透明樹脂膜之感光性間隔件（ps)，亦可將其代替間隔件使用。作為對向基板，通常使用陣列基板，尤佳為TFT(薄膜電晶體）基板。 Ο 與對向基板之貼合間隙，依據液晶顯示裝置之用途而 :不同’ ϋ常於2〜8 之範圍内選擇。與對向基板貼 S後’液晶注入口以外之部分由環氧樹脂等密封 ::密封材料藉由UV照射及/或加熱而硬化，從而密封液曰日旱7L周邊。將周邊密封之液晶單元切割為面板單位後，於直 A 内減壓，將上述液晶注入口浸潰於液晶後，使腔漏：從而於液晶單元内注入液晶。液晶單元内之減· 通常為 1x10 2〜lxl〇-7Pa，較佳為 1χ1〇—3〜lxl〇_6pa。=， 97114141 66 200900859 佳Γ圭:加溫液晶單元，加溫溫度通常為3〇〜loo C較佳為50〜9〇°C。減壓時之加、、Θ仅姓 100 〜6〇分鐘之範圍，1德〇保持，通常設定為液曰置-1 其後次漬於液晶中。注入有液曰之精此完成液晶顯示裝置（面板）。于液曰曰左入口，季對並無㈣限制，可為芳㈣系、脂肪族糸夕％狀化合物等習知眾所周知之液晶，矢 :;知::型液晶等之任-種。心型一種。歹1型液晶、矩列型液晶、膽固醇型液晶等之任 [有機EL顯示器] 於使用本發明之彩色濾光片製作況，例如如圖i所示，首先，製作於透持貝情形成有由著色樹脂組成物形成之 =板10上於相鄰之偾本ΟΛ 口系〈即，像素20及設置 Ο 光片，二=繼色矩陣(未圖示))的㈣膜而由有機保護層3〇及無機氧化 ⑽。再者Λ細5°〇’藉此可製作有機EL元件本發明之著^ 樹脂黑色矩陣中之至少—個係使用之積C 成物而製作者。作為有機發光體5〇。 5〇、電洞、^^出於彩线光片上依序形成透明陽極入声主入層51、電洞傳輸層52、發光層⑽、電子注 a及陰極55的方法，或將其他基板上形成之右機# 光體_貼合於無機氧化膜40上之方法等开=:，製作之有機EL元件100,藉由例如揭亍=「二使用如此 1 j如揭不於「有機EL·顯示 97114141 67 200900859 器」（Ohmsha，2004年8月2〇日發光，時任靜士、〜千波矢、村田英幸著）之方法等，製戈 ^ 衣扑虿機EL·顯示器。再者’本發明之彩色濾光片’可適用於被動驅動方式之有機:L顯示器中’亦可適用於主動驅動方式之有機乩顯不器中。 [實施例] ：以下’舉出合成例、實施例及比較例，更具體說明本發明’但本發明只要不超過其要旨，則並未限定於以下實^ ι '例之記載。 [合成例] 〈高分子分散劑溶液之製備> [合成例1 ] 將32g之曱苯二異氰酸酯之三聚物（三菱化學公司製造之「Mitec GP750A」，樹脂固形分5〇重量％，醋酸丁酯溶液），及作為觸媒之〇. 02 g之二丁基錫二月桂酸酯，以 47 g之丙二醇單曱醚乙酸酯（pGMEA)稀釋溶解。授拌下，於其中滴加14.4 g之單末端為甲氧基且數量平均分子量為1’ 〇〇〇之聚乙二醇（曰本油脂公司製造之「Uni〇x M_ 10 00」）與9. 6 g之數量平均分子量為1，〇〇〇之聚丙二醇（三洋化成工業公司製造之「SU丽IXPP-1 000」）的混合物後’於70°C下進而反應3小時。其次，添加1 g之n，N-一曱基胺基-1，3-丙二胺，於40°C下進而反應1小時。將如此獲得之包含鹼性高分子分散劑之溶液之胺值，藉由中和滴定求得為14 mg-KOH/g。又，將樹脂含量藉由乾燥法 97114141 68 200900859 ’根據重量變化 O50C下30分鐘’於加熱板上去除溶劑量算出樹脂濃度）求得為4〇重量％。〈有機勸合劑之合成> [合成例2] [化 26]V: such as 'the sodium naphthalene sulfonate group used in the developer, the sodium benzene sulfonate group J exemplifies the nonionic interface of the anionic surfactant having the oxime and the right alkoxy group. :j - has t-sub-interface activity (4). The treatment method of m having a tetra-ammonium group is not particularly limited, and usually A 10 to 50. . , at a development temperature of ~45 c, by a method such as dipping development, spray development, development by ultrasonic wave, or ultrasonic development. By the above-mentioned colored resin composition, a tree exposure and development step color light main array and RGB color pixels are prepared, whereby a colored resin composition of the color invention can be obtained, which can be used to form a color matrix. Can also be used to form RGB pixels. In the case of using the colored resin composition of the present invention to form a color: pixel, since it has a very high sensitivity and resolution, it can be exposed and developed in the state of an oxygen barrier layer such as polyethylene glycol. And open) into an image. Only the liquid crystal display device (panel) 97114141 65 200900859 The liquid crystal display device of the present invention can be manufactured in the following manner using the above-described color filter. First, an alignment film is formed on the light-sensitive sheet; a spacer is disposed on the alignment film, and then bonded to the counter substrate to form a liquid crystal cell. Then, liquid crystal is injected into the formed liquid crystal cell, and wiring is completed with the counter electrode. The alignment film is preferably a resin film such as polyacrylonitrile. The formation of the alignment film is usually carried out by gravure printing or flexographic printing, and the thickness of the alignment film is usually 10 to 1 〇〇 nm. After the hardening treatment of the alignment film by thermal calcination, the surface is treated by the irradiation of the outer line or by the treatment of the alignment cloth (^ 丨〇 ci〇th). . The spacers are larger than the gaps between the corresponding substrates and the opposite substrates, and the two are preferably 2 to 8. On the color filter substrate, a photosensitive spacer (ps) of a transparent resin film is formed by photolithography, and it may be used instead of the spacer. As the counter substrate, an array substrate is usually used, and a TFT (Thin Film Transistor) substrate is particularly preferable.贴 The bonding gap with the opposite substrate depends on the use of the liquid crystal display device: different ' ϋ is often selected within the range of 2 to 8. After the S is attached to the counter substrate, the portion other than the liquid crystal injection port is sealed with an epoxy resin or the like. The sealing material is cured by UV irradiation and/or heating, thereby sealing the liquid to a periphery of 7 L. After the liquid crystal cell sealed in the periphery is cut into panel units, the liquid crystal is injected into the liquid crystal injection port to be immersed in the liquid crystal, and the cavity is leaked: liquid crystal is injected into the liquid crystal cell. The subtraction in the liquid crystal cell is usually 1x10 2~lxl〇-7Pa, preferably 1χ1〇-3~lxl〇_6pa. =, 97114141 66 200900859 Jiayugui: heating liquid crystal unit, the heating temperature is usually 3 〇 ~ loo C is preferably 50 ~ 9 〇 ° C. When decompressing, add Θ, only the range of 100 ~ 6 〇 minutes, 1 〇保持, usually set to liquid 曰 set -1 and then the next stain in the liquid crystal. The liquid crystal display device (panel) is completed by injecting liquid helium. In the left inlet of the liquid helium, there is no (four) restriction on the season, and it can be a well-known liquid crystal such as an aromatic (four) system or an aliphatic compound, such as a liquid crystal, or a liquid crystal. Heart type.歹1 type liquid crystal, rectangular liquid crystal, cholesteric liquid crystal, etc. [Organic EL display] In the case of using the color filter of the present invention, for example, as shown in Fig. i, first, it is formed in a transparent state. The plate 10 formed by the colored resin composition is formed on the adjacent layer of the substrate (i.e., the pixel 20 and the (4) film provided with the light-emitting film, and the secondary color matrix (not shown). 3 〇 and inorganic oxidation (10). Further, an organic EL device can be produced by thinning 5° 〇', and at least one of the resin black matrix is produced by using the product C. As an organic light-emitting body 5〇. 5〇, a hole, a method for sequentially forming a transparent anode sounding main entrance layer 51, a hole transport layer 52, a light emitting layer (10), an electron injection a and a cathode 55 on a color line light sheet, or on other substrates Forming the right machine #光体_A method of bonding to the inorganic oxide film 40, etc. =:, the organic EL element 100 produced by, for example, 亍「 = "two uses such 1 j as not revealed "organic EL· It shows the method of 97114141 67 200900859" (Ohmsha, which shines on August 2, 2004, when Jing Shi, ~ Qianbo Ya, Murata Yuki), etc., and made the EL. Further, the "color filter of the present invention" can be applied to the organic type of the passive driving method: the 'L display' can also be applied to the organic driving device of the active driving mode. [Examples] Hereinafter, the present invention will be described in more detail with reference to Synthesis Examples, Examples, and Comparative Examples. However, the present invention is not limited to the following description of the examples as long as it does not exceed the gist of the invention. [Synthesis Example] <Preparation of Polymer Dispersant Solution> [Synthesis Example 1] 32 g of terpolymer of toluene diisocyanate (Mitec GP750A, manufactured by Mitsubishi Chemical Corporation, resin solid content of 5 wt%, acetic acid) Butyl ester solution), and as a catalyst, 02 g of dibutyltin dilaurate was diluted and dissolved with 47 g of propylene glycol monoterpene ether acetate (pGMEA). Under stirring, 14.4 g of polyethylene glycol having a single-end methoxy group and a number average molecular weight of 1' 曰 ("Uni〇x M_ 10 00" manufactured by Sakamoto Oil Co., Ltd.) and 9 were added dropwise thereto. 6 g of a mixture having a number average molecular weight of 1, and a mixture of polypropylene glycol ("SU IXPP-1 000" manufactured by Sanyo Chemical Industries Co., Ltd.) was further reacted at 70 ° C for 3 hours. Next, 1 g of n,N-monodecylamino-1,3-propanediamine was added, and further reacted at 40 ° C for 1 hour. The amine value of the solution containing the basic polymer dispersant thus obtained was determined by neutralization titration to be 14 mg-KOH/g. Further, the resin content was determined to be 4% by weight by drying method 97114141 68 200900859 'by 30 minutes under weight change O50C' to remove the solvent amount on the hot plate. <Synthesis of Organic Exercising Agent> [Synthesis Example 2] [Chem. 26]

〇將50 g之上述構造之環氧化合物（環氧當量為264)、 13.6^^之丙烯酸、6〇5§之3_甲氧基丁基乙酸酯、〇.936 g之三笨基膦及0 032 §之對曱氧基笨酚，放入安裝有溫度計、攪拌機、冷卻管之燒瓶内，一面攪拌，一面於9〇 °c下反應，直至酸值成為5 mg_K0H/g以下。反應需要12 ^小時’獲得環氧丙烯酸酯溶液（2—〇)。將所得之環氧丙烯酸酯溶液（2_〇)、三羥甲基丙烷 :(TMP)、聯苯四魏酸二酐（BPDA)、四氫酞酸酐（THPA)、及 -偏笨二酸酐（TMA)，以表1所示之重量比，放入安裝有溫度計、攪拌機、冷卻管之燒瓶内，一面攪拌，一面緩慢升溫至105°C ’進行反應（其中，製備黏合劑樹脂溶液（2_2) 及（2-3)時，不使用TMP。）。於樹脂溶液變為透明時，利用甲氧基丁基乙酸酯稀釋，調整至固形分成為50重量％，獲得表〗所示之固形分酸值之環氧丙烯酸酯反應液（黏合 97114141 69 200900859 劑樹脂溶液）（2-1)、（2~2)及（2-3) [合成例3 ] [化 27]50 g of the above-structured epoxy compound (epoxy equivalent: 264), 13.6^^ of acrylic acid, 6〇5§ of 3-methoxybutyl acetate, 936.936 g of tris-phenylphosphine And 0 032 § p-oxo-oxyphenol was placed in a flask equipped with a thermometer, a stirrer, and a cooling tube, and stirred while reacting at 9 ° C until the acid value became 5 mg_K0H/g or less. The reaction required 12 ^ hrs to obtain an epoxy acrylate solution (2-oxime). The obtained epoxy acrylate solution (2_〇), trimethylolpropane: (TMP), biphenyltetrahydro dianhydride (BPDA), tetrahydrophthalic anhydride (THPA), and - succinic anhydride ( TMA), placed in a flask equipped with a thermometer, a stirrer, and a cooling tube in a weight ratio shown in Table 1, while slowly stirring to a temperature of 105 ° C to carry out a reaction (wherein a binder resin solution (2_2) was prepared) And (2-3), do not use TMP.). When the resin solution became transparent, it was diluted with methoxybutyl acetate and adjusted to have a solid content of 50% by weight to obtain an epoxy acrylate reaction liquid having a solid acid value as shown in the table (adhesive 97114141 69 200900859) Resin solution) (2-1), (2~2) and (2-3) [Synthesis Example 3] [Chem. 27]

〇〇

將50 g之上述構造之瑗翁 nr 衣虱化5物（環氧當量為264)、 13. 65 g之丙烯酸、6〇. 5 ^ ^ ^ g气r乳基丁基乙酸酯、0. 936 g ^二本基膦及U32g之對甲氧基苯盼，放人安裝有溫度攪拌機、冷卻管之燒瓶内，一面攪拌，一面於下反應，直至酸值成為5mg_K〇H/g以下。反應需要12小時’獲得環氧丙稀酸酯溶液（3_〇)。將所彳于之環氧丙稀酸酯溶液（3_〇)、三經甲基丙烧 (TMP)、聯苯四羧酸二酐（BpDA)、及四氫酞酸酐（THpA)，以表1所示之重量比，以與合成例2相同之方式進行反應 (其中’製備黏合劑樹脂溶液（3_2)時，不使用TMP。），獲得表1所示之固形分酸值之環氧丙烯酸酯反應液（黏合劑樹脂溶液）（3-1)及（3-2)。 [合成例4 ] [化 28] 97114141 20090085950 g of the above-structured 瑗瑗 nr 虱虱 5 5 (epoxy equivalent of 264), 13. 65 g of acrylic acid, 6 〇 5 ^ ^ ^ g gas r-butyl butyl acetate, 0. 936 g ^di-propylphosphine and U32g of p-methoxybenzene were placed in a flask equipped with a temperature stirrer and a cooling tube, and stirred while stirring, until the acid value became 5 mg_K〇H/g or less. The reaction took 12 hours to obtain a solution of the epoxy acrylate (3 〇). The epoxy acrylate solution (3_〇), trimethoprim (TMP), biphenyltetracarboxylic dianhydride (BpDA), and tetrahydrophthalic anhydride (THpA) The weight ratio shown in 1 was reacted in the same manner as in Synthesis Example 2 (wherein TMP was not used when preparing the binder resin solution (3_2)), and the solid acid value of epoxy acrylate shown in Table 1 was obtained. Ester reaction liquid (binder resin solution) (3-1) and (3-2). [Synthesis Example 4] [Chem. 28] 97114141 200900859

σσ

將40 g之上述構造之環氧化合物（環氧當量為a〗）、 :12.7g之丙烯酸、47.8§之甲氧基丁基乙酸醋、1〇“ 之三苯基膦、及〇.〇25g之對甲氧基苯齡，放入安裝有溫度計、攪拌機、冷卻管之燒瓶内，-面攪拌，-面於90 c下反應直至酸值成為5 mg_K〇H/g以下。反應需要15 小時，獲得環氧丙烯酸酯溶液（4_〇)。將所得之環氧丙稀酸@旨溶液U-G)、三經曱基丙烧 CTMP) :四羧酸—酐（BpDA)、及四氫酜酸酐（THPA)，、表斤丁之重里比，以與合成例2相同之方式進行反應 (其甘中，製備黏合劑樹脂溶液（4一2)時，不使用τΜρ。），〇獲得表1所示之固形分酸值之環氧丙稀酸醋反應液（黏合劑樹脂溶液）（4-1)或（4-2)。， [合成例5 ] - [化 29]40 g of the epoxy compound of the above structure (epoxy equivalent is a), : 12.7 g of acrylic acid, 47.8 § methoxybutyl acetate vinegar, 1 〇 "triphenylphosphine, and 〇. 〇 25 g The p-methoxybenzene age is placed in a flask equipped with a thermometer, a stirrer, and a cooling tube, and the surface is stirred, and the surface is reacted at 90 c until the acid value becomes 5 mg_K〇H/g or less. The reaction takes 15 hours. Obtaining an epoxy acrylate solution (4_〇). The obtained epoxy acrylic acid @ solution UG), tris-propyl propyl sulfonate CTMP): tetracarboxylic acid anhydride (BpDA), and tetrahydrophthalic anhydride ( The reaction was carried out in the same manner as in Synthesis Example 2, in the same manner as in Synthesis Example 2 (in the case where the binder resin solution (4-2) was prepared, τΜρ was not used.), and 〇 was obtained as shown in Table 1. The solid acid value of the epoxy acrylate vinegar reaction solution (binder resin solution) (4-1) or (4-2). , [Synthesis Example 5] - [Chem. 29]

將40 g之上述構造之 11. 6 g之丙烯酸、46. 5 環氧化合物（環氧當量為252)、 g之甲氧基丁基乙酸酯、L 〇〇 g 97114141 71 200900859 ^ a科、及〇,〇25g之對曱氧基苯紛’放入安裝有溫。·^汁攪拌機、冷卻管之燒瓶内，一面攪拌，一面於95 C 及藤 * …，直至酸值成為5 mg-K0H/g以下。反應需要15 小時’獲得環氧丙烯酸酯溶液（5-0)。將所彳于之環氧丙烯酸酯溶液（5-0)、聯苯四羧酸二酐、及四氫酞酸酐（THPA)，以表}所示之重量比，以二口成，2相同之方式進行反應，獲得表i所示之固形分 Ο 酉欠值之環氧丙烯酸酯反應液（黏合劑樹脂溶液）（5-:^。 [表1]40 g of the above structure of 11.6 g of acrylic acid, 46.5 epoxy compound (epoxy equivalent of 252), g of methoxybutyl acetate, L 〇〇g 97114141 71 200900859 ^ a, And 〇, 〇 25g of 曱曱苯 ' 放入 ' put into the installation temperature. • The flask of the juice blender and the cooling tube is stirred at 95 C and vines until the acid value is 5 mg-K0H/g or less. The reaction took 15 hours to obtain an epoxy acrylate solution (5-0). The epoxy acrylate solution (5-0), the biphenyltetracarboxylic dianhydride, and the tetrahydrophthalic anhydride (THPA), which are contained in the weight ratio of the table, are formed in two parts, and the same is the same. The reaction was carried out to obtain an epoxy acrylate reaction solution (binder resin solution) having a solid bifurcation value as shown in Table i (5-:^. [Table 1]

〈油墨之製備> [合成例6] 將100 g之彩色用碳黑（三菱化學公司製造之「MA_8」，平均粒徑24㈣，DBP吸油量58 ml/100 g)，於雙轴捏合機内與50〇ml之超純水同時i練2G分鐘’藉由過滤去除超純水。於經過遽之碳黑中再次添加超純水進行混練，重，4次過濾。最後將過濾、之碳黑乾燥而獲得清洗後之碳 …、。j清洗之碳黑為50重量份，合成例j中製備之含有驗性高分子分散劑之溶液作為固形分 1 1 ^ 董置份之比例，且以固形分漠度成為30重量％之方式，添加碳黑、含 97114141 72 200900859 有驗性高分子分散劑之溶液及PGMEA。分散液之總重量為 50 g。將其藉由攪拌機充分攪拌，進行預混合。其次’藉由塗料振盪器，於25〜45°C之範圍内進行6 J寸刀政處理。珠粒係使用〇. 5 _ $之氧化錄珠，添加 f分散液相同之重量。分散結束後（JIS Z8741下之2〇度銳面光澤度為170)，藉由過濾器分離珠粒與分散液’製 . 備碳黑分散油墨。 [實施例1〜5及比較例1〜3] (1)抗钮劑之調合使用δ成例6中製備之碳黑分散油墨，以下述調配比例添加各成分，藉由攪拌器攪拌、溶解，製備黑色抗餘劑。〈調配比例〉 $成例6中製備之油墨：作為固形分為50 g -成2 5中製備之黏合劑樹脂溶液：作為固形分 30 g 〇匕光聚合性單體（乙烯性化合物：二季戊四醇六丙烯酸酉旨）.10 g ，合成例1中製備之含有驗性高分子分之溶 - 固形分為5 g 碍光聚合起始劑（汽巴精化CGI242 ;下诚播垆式俗一合物” 5 g 了述構-式所不之化 [化 30] 97114141 73 200900859<Preparation of Ink> [Synthesis Example 6] 100 g of color carbon black ("MA_8" manufactured by Mitsubishi Chemical Corporation, average particle size 24 (four), DBP oil absorption of 58 ml/100 g) was used in a biaxial kneader 50 〇 ml of ultrapure water at the same time i practice 2G minutes 'by removing ultrapure water by filtration. The ultrapure water was added again in the carbon black of the crucible for mixing, heavy, and 4 times of filtration. Finally, the filtered carbon black is dried to obtain the cleaned carbon. j is 50 parts by weight of carbon black, and the solution containing the organic polymer dispersing agent prepared in Synthesis Example j is used as a solid content of 1 1 ^ Dong parts, and the solid content is 30% by weight. Add carbon black, a solution containing 9714141 72 200900859 with a polymer dispersant and PGMEA. The total weight of the dispersion is 50 g. This was thoroughly stirred by a stirrer to carry out premixing. Secondly, 6 J-inch knife processing was carried out in the range of 25 to 45 ° C by means of a paint shaker. For the beads, use 〇. 5 _ $ of the oxidized bead and add the same weight of the f dispersion. After the completion of the dispersion (JIS Z8741, the 2 degree of sharpness gloss is 170), the beads and the dispersion were separated by a filter to prepare a carbon black dispersion ink. [Examples 1 to 5 and Comparative Examples 1 to 3] (1) Preparation of anti-buckling agent The carbon black-dispersed ink prepared in Example 6 was used, and each component was added in the following blending ratio, and stirred and dissolved by a stirrer. A black anti-surplus agent was prepared. <Preparation ratio> $Ink prepared in Example 6: As a solid solution, a binder resin solution prepared in 50 g to 25: as a solid component 30 g of a photopolymerizable monomer (ethylene compound: dipentaerythritol) Six acrylic acid).10 g, the solute-solid form of the test compound 1 prepared in Synthesis Example 1 is divided into 5 g light-blocking polymerization initiator (Ciba quinone CGI242; "5" has a description of the formula - the formula is not [chemical 30] 97114141 73 200900859

有機溶劑（PGMEA) : 300 g 界面活性劑（住友3M公司製造之r FC_43〇」氟系界面活性劑）：於抗姓劑中之濃度為1〇〇 ppm之量 (2)抗蝕劑之評價Organic solvent (PGMEA): 300 g of surfactant (r FC_43〇 manufactured by Sumitomo 3M Co., Ltd.) Fluoride interface active agent): The concentration in the anti-surname agent is 1 〇〇 ppm (2) Evaluation of resist

(1)將抗蝕劑之調合中獲得之黑色抗蝕劑，利用旋轉塗佈機塗佈於玻璃基板（康寧公司製造之「7〇59」）上，藉由加熱板，於80°C下乾燥1分鐘。使用觸針式膜厚計（tenc〇r 公司製造之「a-step」）測定乾燥後之抗蝕劑之膜厚之結果為1 //m。其次，使該樣本透過光罩，利用高壓水銀燈改變曝光量，進行曝光。其後，於溫度25艽下，使用濃度0·8重量％之碳酸鈉水溶液，以壓力〇· 15Μρ&進行喷霧顯影，藉此獲得抗蝕劑圖案。對於所形成之抗蝕劑圖案，根據下述標準評價靈敏度、解析力及遮光性，將結果示於表2。 1.靈敏度窃以可按2尺寸形成尺寸為2Q ^之鮮圖案的最佳曝光量（mj/cm2)表示。即，曝光量少之抗蝕劑，可以低曝光量形成圖像，故表示高靈敏度。 2.解析力將忠實再現尺寸為20 ”之光罩圖案之曝光量下之可 97114141 74 200900859 解析之最小圖案尺寸，以200倍之倍率進行顯微鏡觀察，根據下述標準評價。最小圖案尺寸為1〇以下：◎ 最小圖案尺寸超過10 //111且15以爪以下：〇最小圖案尺寸超過15 Αΐηΐχ 3. 遮光性藉由Macbeth反射密度計（K〇Um〇rgen公司製造之「TR927」），測定圖像之光學密度⑽）。再者，卯值係表示遮光能力之數值，數值越大表示遮光性越高。 4. 殘渣 m 首先，對於各個上述實施例及比較例中獲得之抗韻劑，分別算出利用下述方法規定之「未曝光部分溶解之時 m「未曝光部分溶解之時間」中，仔細觀察抗蝕 ::二:去除之部分(未曝光部分)，根據下述標準〖完全看不到膜。〇(1) The black resist obtained by blending the resist was applied onto a glass substrate ("7〇59" manufactured by Corning Incorporated) by a spin coater, and heated at 80 ° C by a heating plate. Dry for 1 minute. The film thickness of the resist after drying was measured by a stylus type film thickness meter ("a-step" manufactured by Tenc〇r Co., Ltd.) to be 1 / m. Next, the sample was passed through a reticle, and the exposure amount was changed by a high pressure mercury lamp to perform exposure. Thereafter, at a temperature of 25 Torr, a sodium carbonate aqueous solution having a concentration of 0.8% by weight was used, and spray development was carried out under a pressure of 〇·15Μρ& to obtain a resist pattern. With respect to the formed resist pattern, the sensitivity, the resolution, and the light blocking property were evaluated according to the following criteria, and the results are shown in Table 2. 1. Sensitivity The stealing is expressed by the optimum exposure amount (mj/cm2) which can form a fresh pattern of 2Q^ in size. In other words, since the resist having a small exposure amount can form an image with a low exposure amount, it indicates high sensitivity. 2. The resolution will faithfully reproduce the exposure of the reticle pattern of 20" size. 97114141 74 200900859 The minimum pattern size analyzed, microscope observation at 200 times magnification, evaluated according to the following criteria. The minimum pattern size is 1 〇The following: ◎ The minimum pattern size exceeds 10 //111 and 15 is below the claw: 〇The minimum pattern size exceeds 15 Αΐηΐχ 3. The shading is measured by Macbeth reflection densitometer ("TR927" by K〇Um〇rgen) Optical density of the image (10)). Furthermore, the devaluation indicates the value of the shading ability, and the larger the value, the higher the opacity. 4. Residue m First, in each of the above-mentioned examples and comparative examples, the anti-rhythm agent obtained in each of the above examples and the comparative examples was calculated by the following method: "When the unexposed portion is dissolved, m "time when the unexposed portion is dissolved", Eclipse:: 2: The removed portion (unexposed portion), the film was not seen at all according to the following criteria. 〇

看到些許白膜。X 〈未曝光部分溶解之時間〉以與上述「（2)抗蝕劑之評價」相同之 ^ l· A-L· +L. 万式’於玻璃基 |布、乾餘黑色抗敍劑，將所得之乾燥塗佈膜，以嚷度:重量—水溶液，於顯影‘ 顯影（正確而言，使鞋塗佈膜溶其叔〜土板者色樹脂組成物完全溶解於顯影液甲，基板路出之時間，設為今莫& 、 ‘、、、以者色树梟組成物之「未曝光部分 97114141 75 200900859 溶解之時間 [表2] 有機黏合劑 (黏合劑樹脂溶液）靈敏度 (nJ) 解析力遮光性 (0D 值）See a little white film. X <Time when the unexposed portion is dissolved> In the same manner as the above "(2) Evaluation of the resist", the same formula is used in the glass base, the cloth, and the dry black anti-synthesis agent. The dried coating film is developed in a developing temperature of the twist: weight-water solution (correctly, the shoe coating film dissolves the resin composition of the uncoated material layer completely dissolved in the developer A, and the substrate is discharged. Time, set as the "unexposed part of the composition of the current color &, ',,, and color tree 971 97114141 75 200900859 dissolution time [Table 2] organic binder (binder resin solution) sensitivity (nJ) resolution Shading (0D value)

Γ—^______30 | 〇 1 3.8 表2可知，本發明之著色樹脂組成物係使用特定之樹月曰作為（Β)有機黏合劑，藉此成為靈敏度、解析力、遮光性優異，而且不產生殘渣之優異者。、使用特定態樣詳細說明了本發明，熟悉本技藝者明白可 ;脫離本發明之意圖及範圍之狀態下，進行各種變更。再者，本申請案係基於2〇〇7年4月2〇曰申請之日本專利申請案（日本專利特願2007-111990)，其全文以引用之方式挺用於本文。 ϋ【圖式簡單說明】圖1係表示包含本發明之彩色濾光片之有機EL元件之 . 一例的剖面概略圖。 • 【主要元件符號說明】 10 透明支持基板 20 像素 30 有機保護層 40 無機氧化膜 97114141 76 200900859 50 透明陽極 51 電洞注入層 52 電洞傳輸層 53 發光層 54 電子注入層 55 陰極 100 有機EL元件 « 500 有機發光體 97114141 77Γ—^______30 | 〇1 3.8 In Table 2, it is understood that the colored resin composition of the present invention uses a specific tree ruthenium as a (Β) organic binder, thereby providing excellent sensitivity, resolving power, and light-shielding property without causing residue. Excellent. The present invention has been described in detail with reference to the specific embodiments thereof. Further, the present application is based on a Japanese patent application filed on Apr. 2, 2008 (Japanese Patent Application No. 2007-111990), the entire disclosure of which is incorporated herein by reference. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic cross-sectional view showing an example of an organic EL element including a color filter of the present invention. • [Main component symbol description] 10 Transparent support substrate 20 Pixel 30 Organic protective layer 40 Inorganic oxide film 97114141 76 200900859 50 Transparent anode 51 Hole injection layer 52 Hole transport layer 53 Light-emitting layer 54 Electron injection layer 55 Cathode 100 Organic EL element « 500 Organic Lights 97114141 77

Claims

200900859 十、申請專利範圍： 1· 一種著色樹脂組成物，其係至少包含（A)色材及（B) 有機黏合劑（organic binder)者，其特徵在於：有機 =合劑包含酸值為l〇mg_KOH/g以上之鹼可溶性不飽和樹月曰，該鹼可溶性不飽和樹脂係藉由使以下述通式（1 )所表不之環氧化合物（a)與含有不飽和基之羧酸（b)之反應物’與多元酸酐（d)反應而獲得； [化 31]200900859 X. Patent application scope: 1. A colored resin composition comprising at least (A) color material and (B) an organic binder, characterized in that: organic = mixture contains an acid value of l〇 An alkali-soluble unsaturated tree ruthenium of not more than mg_KOH/g, which is an epoxy resin (a) represented by the following formula (1) and a carboxylic acid containing an unsaturated group (b) The reactant 'is obtained by reacting with the polybasic acid anhydride (d); [Chem. 31]

x-^-oX-^-o

CD ~ίΓ^ν〇Η2 [於上述通式（1)中，X表示以下述通式（2a)或（2b)所表不之連結基；其中，分子構造中含有一個以上之金剛烷構造；1表示2或3之整數； [化 32]CD ~ίΓ^ν〇Η2 [In the above formula (1), X represents a linking group represented by the following formula (2a) or (2b); wherein the molecular structure contains one or more adamantane structures; 1 represents an integer of 2 or 3; [Chem. 32]

(於上述通式（2a)及（2b)中，R1〜R4、R13〜R15分別獨立表示可具有取代基之金剛烧基、氫原子、可具有取代基之碳數為1〜12之烷基、或可具有取代基之苯基；於上述通式（2a)及（2b)中，*表示與通式（1)中之環氧丙氧基之鍵結部位）]。 2. —種著色樹脂組成物，其係至少包含（A)色材及（b) 97114141 78 200900859 有機黏合劑者’其特徵在於：极(ii有機黏合劑包含酸值為1G mg—_/g以上之驗可溶和樹脂，該鹼可溶性不飽和樹脂係藉由使以下述通二表示之環氧化合物U)及/或以下述通式（ία)所表 ::，化5物（8 )與含有不飽和基之魏酸（b)之反應 ”夕元醇（c)混合後’與多元酸野（d)反應而獲得； [化 33](In the above formulae (2a) and (2b), R1 to R4 and R13 to R15 each independently represent an adamantyl group which may have a substituent, a hydrogen atom, and an alkyl group which may have a substituent and have a carbon number of 1 to 12 Or a phenyl group which may have a substituent; in the above formulas (2a) and (2b), * represents a bonding site with a glycidoxy group in the formula (1)). 2. A colored resin composition comprising at least (A) a color material and (b) 97114141 78 200900859 an organic binder characterized by: a pole (ii organic binder comprising an acid value of 1 G mg-_/g The above is soluble and resin, and the alkali-soluble unsaturated resin is represented by the epoxy compound U) represented by the following two and/or by the following formula (ία): It is obtained by reacting with the polybasic acid (d) after mixing with the reaction of the unsaturated acid containing the acid (b) containing the unsaturated group (b); [Chem. 33]

一[於上述通式（1)中，X表示以下述通式（2a)或（2b)所表八之連、、Ό基，其中’分子構造中含有一個以上之金剛烧構造；1表示2或3之整數； [化 34][In the above formula (1), X represents a hydrazine group of the following formula (2a) or (2b), wherein the 'molecular structure contains one or more diamond-fired structures; 1 means 2 Or an integer of 3; [34]

(於上述通式（2a)及（2b)中，R1〜R4、R13〜R15分別獨立表示可具有取代基之金剛烷基、氩原子、可具有取代基之石反數為1〜12之烧基、或可具有取代基之苯基；於上述通式（2a)及（2b)中，*表示與通式（1)中之環氧丙氧基之鍵結部位；）] [化 35](In the above formulas (2a) and (2b), R1 to R4 and R13 to R15 each independently represent an adamantyl group which may have a substituent, an argon atom, and a pyrene having a substituent of from 1 to 12; a phenyl group which may have a substituent; in the above formulas (2a) and (2b), * represents a bonding site with a glycidoxy group in the formula (1);)] [Chem. 35]

(1A) 97114141 79 200900859 紝^上^通式（1A)中，x，表示以下述通式（3)所表示之連分子構造中含有-個以上之金剛燒構造表不2或3之整數； [化 36] 七 R®人I (3) Γ FT 、甿 R..，、R1 (於上述通式（3)中，R5〜RlZ分別獨立表示氫原子、可且基之碳數為1〜12之烧基、或可具有取代基之；土#^可具有取代基且具有金剛燒構造的二價連結基；於上述通式（3)中，*表示與通式（1 之鍵結部位）]。丙乳基 —3.如申請專利範圍第2項之著色樹脂組成物，其中兀酸酐⑷包含四元酸酐及/或二元酸酐、三元酸酐。著色樹脂組成物，其係至少包含⑷色材及⑻ 有黏合劑者’其特徵在於·· (B)有機黏合劑包含酸值為1〇 mg_K〇H/g以上之鹼可溶性不飽和樹脂，該驗可溶性不飽和樹脂係藉由使以下述= 式⑴，表示之環氧化合物⑷及/或以下述通式⑽所表 :之，氧化合物(a’)與含有不飽和基之羧酸⑻之反應物’與多元酸酐（d)反應而獲得；多元酸酐（d)包含四元酸酐及/或二元酸酐、三元酸 [化 37] 97114141 200900859 Xi°^r\/CH2\ ⑴ [於上述通式（丨）中，x表糸以下述通式（2a)或（2b)所表示之連結基；其中，分子構造中含有一個以上之金剛烷構造’ 1表示2或3之整數； [化 38](1A) 97114141 79 200900859 In the formula (1A), x represents an integer of not more than 2 or 3 in the continuous molecular structure represented by the following general formula (3); [7] RR® human I (3) FT FT, 氓R.., R1 (In the above formula (3), R5 to RlZ each independently represent a hydrogen atom, and the carbon number of the radical is 1~ a base of 12 or may have a substituent; earth #^ may have a substituent and have a divalent linking group of a diamond-fired structure; in the above formula (3), * represents a bond with a formula (1) The colored resin composition of the second aspect of the invention, wherein the phthalic anhydride (4) comprises a tetrabasic acid anhydride and/or a dibasic acid anhydride or a ternary acid anhydride. The colored resin composition contains at least (4) Color material and (8) A binder is characterized in that (B) the organic binder contains an alkali-soluble unsaturated resin having an acid value of 1 〇 mg_K 〇 H/g or more, and the soluble unsaturated resin is obtained by The epoxy compound (4) represented by the following formula (1) and/or represented by the following formula (10): the oxygen compound (a') and the The reactant of the unsaturated carboxylic acid (8) is obtained by reacting with the polybasic acid anhydride (d); the polybasic acid anhydride (d) comprises a tetrabasic acid anhydride and/or a dibasic acid anhydride, a tribasic acid [Chem. 37] 97114141 200900859 Xi°^r \/CH2\ (1) [In the above formula (丨), x represents a linking group represented by the following formula (2a) or (2b); wherein the molecular structure contains more than one adamantane structure '1' An integer of 2 or 3; [38]

(於上述通式（2a)及（2b)甲，R1〜R4、Ru〜Rl5分別獨立 ^示可具有取代基之金剛烷基、氫原子、可具有取代基之碳數為1〜12之烷基、或可具有取代基之苯基；於上述通式（2a)及（2b)中，丙氧基之鍵結部位；）] *表示與通式（1)甲之環氧 [化 39](In the above formula (2a) and (2b) A, R1 to R4 and Ru to Rl5 each independently represent an adamantyl group which may have a substituent, a hydrogen atom, and an alkyl group which may have a substituent and have a carbon number of 1 to 12 a phenyl group which may have a substituent; in the above formulas (2a) and (2b), a bonding site of a propoxy group;)]* represents an epoxy group of the formula (1)

下述通式（3)所表示之連個以上之金剛烷構造；ι [於上述通式（1A)中，X，表示以結基，其中’分子構造中含有一表示2或3之整數； [化 40] 97114141 81 (3) 200900859More than one adamantane structure represented by the following formula (3); ι [in the above formula (1A), X represents a group, wherein 'the molecular structure contains an integer representing 2 or 3; [化40] 97114141 81 (3) 200900859

有取代基之碳數為丨〜 ’、 ^ 基；Y表示彳基、或可具有取代基之苯 /、有取代基且具有金剛烷構造的二價連处A. 於上述通式（3)中，*主-办= 1貝逆、，、σ暴，鍵結部位）]。表U切Α)中之環氧丙氧基物之連結基； [化 41]The carbon number of the substituent is 丨~ ', ^ group; Y represents a fluorenyl group, or a benzene group which may have a substituent, a substituted divalent linkage having an adamantane structure, A. in the above formula (3) In the middle, * main - do = 1 Beibei,, σ violent, bonding parts)]. The linking group of the epoxy propoxy group in Table U;

，[式（4)、（5)可具有取代基， • 之鍵結部位]。 *表示與通式（3)中之苯環 6·如申μ專利圍第丨至5項中任—項之著色物’其中，以上述通式（2a)或⑽所表示之&具有2個上且4個以下之金剛烷構造。如申請專利範圍第項中任—項之著色樹脂物’其中’以上述通式⑴所表示之環氡化合物u)係以$ 97114141 82 200900859 述通式（7)所表示； [化 42][Formula (4), (5) may have a substituent, • a bonding site]. * represents a coloring matter with a benzene ring in the general formula (3), such as a coloring matter of any one of the above-mentioned items, from the above-mentioned formula (2a) or (10) Up to 4 or less adamantane structures. The colored resin (wherein the above-mentioned general formula (1) is represented by the formula (7) represented by the above formula (1), as shown in the formula (7);

[於通式⑺中’ r24、r25分別獨立表示可具有取代基之金剛烧基、氫原子、可具有取代基之碳數為1〜12之烷基、或可具有取代基之苯基；通式（7)中所示之金剛烷基可具有取代基]。物8:!請專利範圍第2至7項中任一項之著色樹脂組成 ’，、，以上述通式（1A)所表示之環氧化合物（a，）係以下述通式（6)所表示； [化 43][ r24 and r25 in the formula (7) each independently represent an adamantyl group which may have a substituent, a hydrogen atom, an alkyl group which may have a substituent having 1 to 12 carbon atoms, or a phenyl group which may have a substituent; The adamantyl group shown in the formula (7) may have a substituent]. The coloring resin composition of any one of the above-mentioned general formulas (1A) is obtained by the following formula (6). Representation;

97114141 83 200900859 通式（6)中所示之金剛烷基可具有取代美]。 \如中=利範圍第項中任—項之著色樹脂組成 =下/、中通式⑴中之Χ之分子量為200以上且10〇〇 10.如申請專利範圍第2至9項中任一項之著色樹脂组成物，其中，上述通式⑽中之χ，之分子量為2G 且1 000以下。 r 1 1.如申請專利範圍第彳$ η “甘士固弟1至10項中任-項之著色樹脂組成物/中’以上述通式⑴所表示之環氧化合物⑷ 氧當量為210以上且450以下。义專利範圍第2至11項中任—項之著色樹脂組成物’其中’以上述通式（1Α)所表示之環氧化合物之環氧當量為210以上且45〇以下。 13.如申請專利範圍第2、3及5至12項中任色樹脂組成物，其中，多元醇⑷係自三經甲基丙烧、二一三羥甲基丙烷、季戊四醇、二季戊四醇、三羥甲基乙烷、及1，2, 3-丙三醇所组成群組中選擇之i種或2種以上凡多元醇。 14·如申請專利範圍第3至13項中任一項之著色樹脂电成物’其中，三元酸軒係偏苯三酸酐及"戈六氫偏苯三酸酐。 15·如申請專利範圍第！至14項中任成物’其中，上述驗可溶性不飽和樹脂之重量為2，000以上且20，〇〇Q以下。 97114141 84 200900859 、16.如申請專利範圍第ι至15項中任-項之著色樹脂組成物’其中’進—步包含（c)分散劑。 Π.如申請專利範圍第u16項中任一項之著色樹脂組成物，其中，進一步包含（E)單體。專利範圍第1至17項中任—項之著色樹脂組成物’八中’進—步包含（D)光聚合起始劑。二·如1申：專利範圍第1至18項中任一項之著色樹脂組 r Ο j Ί ’ U)色材之含量於著色樹脂組成物之總固形勿中，占30〜7〇重量％。成：如專利範圍第1至19項中任-項之著色樹脂組成物”中，（A)色材含有黑色色材。使2用1申：直必色濾光片，其特徵在於：透明基板上，具有申專利範圍第1 i 20項中任-項之著色物而形成之像素或黑色矩陣。、于曰、、、成 22. 種液晶顯示裝置，其係使用申請專利範之彩色濾光片而製作。胃寻㈣圍第21項 23. 種有機EL顯示器，其係使用申項之彩色濾光片而製作。月导利範圍第21 97114141 8597114141 83 200900859 The adamantyl group represented by the formula (6) may have a substitution ratio]. \中中=利范围范围的任任 Item colored resin composition = lower /, the molecular weight of the enthalpy in the formula (1) is 200 or more and 10 〇〇 10. As in the scope of claims 2 to 9 The colored resin composition of the above formula, wherein the molecular weight in the above formula (10) is 2 G and less than 1,000. r 1 1. The application of the patent range 彳$ η "the coloring resin composition of the 1st to 10th items of the sylvestre of the sylvestre", the epoxy compound (4) represented by the above formula (1), having an oxygen equivalent of 210 or more And the epoxy resin composition of the above-mentioned general formula (1Α) has an epoxy equivalent of 210 or more and 45 Å or less. The color resin composition of any of claims 2, 3 and 5 to 12, wherein the polyol (4) is derived from trimethyl ketone, ditrimethylolpropane, pentaerythritol, dipentaerythritol, trihydroxyl The selected one or more than one of the group consisting of methylethane and 1,2,3-propanetriol. 14. The colored resin according to any one of claims 3 to 13. Among the electroforms', among them, tribasic acid is a trimellitic anhydride and "go hexahydrotrimellitic anhydride. 15·As claimed in the patent scope! to any of the 14 items, the weight of the above-mentioned soluble unsaturated resin is 2,000. Above and 20, below 〇〇Q. 97114141 84 200900859 , 16. If applying The colored resin composition of any one of the above-mentioned items of the present invention, wherein the coloring resin composition of any one of the above-mentioned items, wherein Further comprising (E) a monomer. The colored resin composition of the above-mentioned item of the first to seventh aspects of the invention includes the (D) photopolymerization initiator. The colored resin group r Ο j Ί ' U) of any one of items 1 to 18 is contained in the total solid content of the colored resin composition, and accounts for 30 to 7 % by weight. Among the 19 items of the colored resin composition of the item, the (A) color material contains a black color material. The invention is characterized in that a transparent color filter is formed on a transparent substrate, and a pixel or a black matrix formed by the coloring matter of any one of the items 1 to 20 of the patent range is obtained. , 曰, 、, 、 22. The liquid crystal display device is produced by using the color filter of the patent application. Stomach Seeking (4) Enclosure 21 23. An organic EL display made using the color filter of the application. Monthly guidance range 21 97114141 85