200900499 九、發明說明： 【發明所屬之技術領域】 本發明有關在常溫下為半固態狀的潤滑劑組成物，特 另!有關具有咼度的耐極壓性（extreine pressure pr〇perty)及 穩疋的摩擦特性之潤滑劑組成物。再者，本發明有關將該 耐潤滑劑組成物採用於傳動元件機構（transmissi〇n element mechanism)之潤滑系統。 【先前技術】 近年來，環保關連、省能源等已成為重要的關鍵技術。 特別是環保課題而言，可例舉：二氧化碳排出量的削減、 省電、省能源、資源有效利用等多種。可作為對象之領域， 亦有各種生產事業活動、輸送系統等種種。 各種產業機械，例如，壓延機（calender)、可塑性加工 機械、工作機械、注射模塑機（injecti〇n咖仙邮 machme)、加壓（press)機、鍛壓機等當然需要精確度高的 力工鬲可罪性之外，尚強烈要求省能源化。又，屢縮機 (compressor)、真空泵（vacuum pump；)方面，亦要求省能源 之運轉。又，汽車、建設機械、農業機械、火車、飛機、 船舶等所代表之運輸系統方面亦除舒適而穩定的行車、航 行之外，尚需要省燃料費、省能源化。再者，家電製品、 〇Aj辦公室自動化）設備、精密機械等的機械系統亦在開發 考量進一步節約能源所對應之製品。 傳動 此等機械系統中，按照用途組裝有多數個軸承、齒輪 螺桿（motive screw)、直接驅動台（direct_ddve 319937 5 200900499 凸輪（cam)、皮帶、鏈條、鋼索等傳動元件機構。亦在應用 經適當組裝此等元件之系統。轴承而言，有：各種滾動轴 承、滑動軸承等。齒輪亦可例舉：正齒輪（spur gear)或斜 齒輪（helical gear)等的平行軸齒輪、平面齒輪（face gear)等 的交叉軸齒輪、螺旋齒輪（screw gear)或準雙曲面齒輪 (hypoid gear)等的不對稱軸齒輪（skew wheel)、媧輪（worm gear)、行星# 輪（epicyclic gear)、差動齒輪（differential gear) 等種種型式。傳動螺桿（motive screw)之代表性者可例舉： ( 滑動螺桿（slide screw)或滑動螺桿（rolling screw)。具體性 的傳動元件機構可例舉：有為煉鐵工場以及金屬加工領域 中所使用之壓延機（calender)或可塑性加工機（plasticity processing machine)等之軸承、輥道（table roller)、鏈條驅 動（chain driving)、齒輪聯韩器（gear coupling)等，又為機 床、注射模塑機、壓機、鍛壓機、研磨機等則有轴承、傳 動螺桿（motive screw)、齒輪、皮帶、鏈條等之精密驅動機 ， 構部位。汽車的動力系（power train)、方面有等速接頭、萬 K : 向接頭、軸承，在引擎部周邊方面則在使用致動器 (actuator)、起動器、齒輪、交流發電機（alternator)、軸承， 又操舵（steering)周邊方面則在使用電動動力轉向裝置 (power steering)、超速的齒條（rac幻和小齒輪（pini〇n)、傾 斜式望遠裝置（tilt telescope)、懸掛（suspension)球接頭（ball joint)機構、制動裝置或汽車底盤（chassis)的潤滑，電氣裝 置零件.電氣裝置機構而言，在使用車門的門把部、自動 關門裝置（door check)、門鉸鏈（door hinge)、門鎖致動器 6 319937 200900499 (door lock actuator)、門棘輪（door ratchet)的各處、鎖芯 &巧 cylinder)、電動反射鏡、座椅安全帶（seat beh)、座椅、窗Υ .門調整器（d〇〇r regulator)、各種開關（switch)的各種傳動元 ( 件機構。X ’自動兩輪車、腳踏車等方面，有鏈條驅動部 位、軸承。在挖土機（excavat〇r)、輪式裝料車 loader)、推土機（bull dGzer)、起重機（⑽狀）等的建設機械 方面’有導套（guide bush)、齒輪、軸承，而在農業機械、 割草機、電鑛⑽ain saw)等中有軸承、齒輪、鍵條驅動部。 又，在鐵路系統中，有變速啬輪、鋼軌的執道切換機構， 而在飛機或船舶上，亦設置有各種軸承及命輪。再者，以 CD(光碟）、DVD(多樣化數位光碟）、錄音磁冑、數位 作為記憶媒體之各種影像音響資訊設備、以及此等的許帶 ，設備、印表機、傳真機、複印機等的〇A設備。又^ 氣機、冰箱、吸塵機、電磁爐 ^ 家電製品中之軸承uLir 摩機等的 腦内的硬碟驅動部、，卷昭相：連：螺桿、鏈條驅動、電 機構部、透鏡驅動部、鐘錶的 機决門 機構的-例示。 、輪機構亦可作為傳動元件 於此等傳動元件機構中，適 油、潤滑劑、們诉另牧…、用途之各種潤滑 望、目、、/ ’月月日grease)、固態潤滑劑、以及經組合此 右：：滑方法。特別是潤滑腊係不容易漏油，已開發；具 有知妝各用途之要求性能之製品 —^ 揭示有一種含有碟物、击备n 並已仏為貧用。又，亦 從s有石廣物油糸及/人 (Ii_ 】Ubdcating base 〇ii)、餹戈/ U的液狀满滑基油 雙駄鞍及/或單醯胺、以及含 319937 7 200900499 :擦:周整劑之具有熱可逆性凝膠狀的潤滑性之組成物(專 利文獻ί)。 ^而近年來，由於對上述機械系統強烈要求高功能 2、小型化、耐用化，因而對潤滑劑要求更進一步之高性 能化、特別是即使極少㈣油量仍能有順利潤滑之功能。 [專利文獻l]W〇(世界專利;)2〇〇6/〇51671 【發明内容】 ί [發明所欲解決之課題] ^發明係為解決上述課弱開發者，本發明之目的在 、^叙Γ㈣滑劑組成物，係將極少量的油劑塗佈於潤滑 月。卩則即使在薄膜狀態下仍能顯示高的耐極壓性盥牙空 定的摩擦特性等優異的潤滑性，且在f溫下為半固能狀^ 種將此潤滑劑組成物使用於傳導元件機構之潤 /月糸統0 [用以解決課題之手段] ^發明人等，為解決前述課題，就潤滑油基油 添加劑等，以及此等組合而專心致： 九之、力果’終於達成本發明。 亦即’本發明係如下述之潤滑劑組成物及潤滑系統。 );。種潤賴組成物，其特徵為：含有液狀基油Μ至㈣ 買里/〇、酸胺化合物〇 J至9〇質詈。/ 至20併苗〇/+ Λ 主㈧貝里/〇、以及固態潤滑劑L0 貝1錢_5至5質量％之有機姻化合物作為鋼 (〇)里，且在常溫下為半固態狀者。 ⑺如上述⑴所記載之潤滑劑組成物，其中液狀基油，係選 319937 200900499 自聚-α -稀烴低聚合物及脂肪酸酯之至少丨種者。 (3)如上述（1)或（2)所記載之潤滑劑組成物，其中醢胺化合 物，係以下述一般式（1)至（3)表示之至少丨種化合物。 R1 — CO — NH — RZ m (2) (3) R 3 一 CO — Ν Η — A 1 — N H 一 CO — r * R —N H一CO — A2_CO·—NH — Re (式（1)至（3)中，R1、R2、R3、R4、r5以及“各自獨立，係 ,奴數5至25的飽和或不飽和鏈狀烴基，而R2可為氳，… '及A係選自碳數1至1〇的伸烷基、伸苯基或碳數7至10 的烷伸苯基之碳數丨至1〇的2價烴基。） (4) 如上述⑴至（3)中任—項所記載之潤滑劑組成物，其 中，固態潤滑劑係選自二硫化鉬、石墨、氮化侧以及含氣 樹脂中之1種以上者。 (5) 如上述⑴至（3)中任一項所記載之潤滑劑組成物，其 中有機銷化合物係二硫代胺基f酸翻及二 至少1種者。 ⑹-種潤滑系統，其特徵為：將丄地⑴主⑺节 記載之潤滑劑組成物使用於傳動元件機構中。 :上統動r傳動_ 以及鋼索之至少βΓ 凸輪、皮帶、鏈條、 [發明之效果] 動部 採用本發明之潤滑劑組成物， 則可發揮在滑動時能形成穩定 而少量塗佈於潤滑滑 的薄膜並長期間顯示 319937 9 200900499 高的耐特壓性與低的摩擦特 者。又，由於在常、、w下生* A <異的潤滑性之特別效果 固然可替代一2 ”、、+固態狀的潤滑劑組成物之故， ' J a八力又用的潤滑脂，火 螺桿、直接連動桌、凸輪、古I。作為軸承、齒輪、傳動 件機構，特別是作A、A " V、鏈條、鋼索等的傳動元 用者。 乍〜車的動力轉向裝置的潤滑劑有效使 【實施方式】 [用以實施本發明的最佳形態] 本發明係-種潤滑劑組成物 油10至99 9皙1。/ ^ 一特徵為·含有液狀基 1 ^貝U'Si胺化合物〇 固態潤滑劑1.0至20f量 90質里/〇、以及 里/。次0.0005至5皙詈％夕古德 化合物作為鉬（Mo)量，且力)貝罝/之有機鉬 :需構，則當成為;要= 會發之潤滑性能，是在擔心 上、需要耐柽芦 g trouble)之低速、高負荷之作業 ί示作業上則為有用’由於可在薄膜下 s, _ ^ ^ 同％油保持性亦優異而難以發生斷油， 叙一w 4發生燒結。又’本發明之潤滑組成物，當傳 動元件機構的滑動部問私_± 、， 月動邠開始運行時因該滑動部的溫度上升， 而從半固態狀變成液體妝能 , A 心、並進入狹乍的滑動部後作為潤 滑劑組成物發揮作用，枪+ 用准由於返離滑動部而不傳播摩擦熱 之部分則仍保持半固離的壯能& < + 干口心的狀悲，故不需要擔心所謂漏油而 可經常保持周圍之清潔。 又，在此「堂、主-^ ㊉度」表不室内的普通溫度，具體而言， 319937 10 200900499 為5 0°C以下，更一般而言，係指_1〇至3〇°c左右的溫度環 境。 [液狀基油（liquid base oil)] 用於本發明之液狀基油’可採用礦物油（minerai 〇丨1)、 s成油或此專的混合油。液狀基油的特性，並不特別限定， 惟較佳為40。(：下之動黏度（kinematic visc〇sity)在5至 5000mm2/s者，更佳為10至1〇〇〇mm2/s，再佳為2〇至 700mm/s。再者，黏度指數（visc〇sity ίη&χ)在9〇以上， 車乂佳為95至250，流動點（p0ur p〇int)在· 1〇。匸以下，較佳200900499 IX. Description of the Invention: [Technical Field] The present invention relates to a lubricant composition which is semi-solid at normal temperature, and in particular, relates to extreme pressure pr〇perty and stability A lubricant composition of the rubbing characteristics of niobium. Further, the present invention relates to a lubricating system in which the lubricant resistant composition is applied to a transmissi〇n element mechanism. [Prior Art] In recent years, environmental protection and energy conservation have become important key technologies. In particular, environmental protection projects include, for example, reduction in carbon dioxide emissions, power saving, energy saving, and efficient use of resources. It can be used as a target area, and there are various production activities and transportation systems. Various industrial machines, for example, calenders, plastic processing machines, working machines, injection molding machines (injecti〇n, machme), presses, forging presses, etc., of course require high precision In addition to the sinful nature of work, there is a strong demand for energy conservation. In addition, in terms of compressors and vacuum pumps, energy-saving operation is also required. In addition, transportation systems represented by automobiles, construction machinery, agricultural machinery, trains, airplanes, ships, etc., in addition to comfortable and stable driving and navigation, need to save fuel and energy. In addition, mechanical systems such as home appliances, 〇Aj office automation equipment, and precision machinery are also being developed to consider products that further save energy. In the transmission of these mechanical systems, a plurality of bearings, gear screws, direct drive tables (direct_ddve 319937 5 200900499 cams, belts, chains, cables, etc.) are assembled according to the application. A system for assembling these components. For the bearing, there are various rolling bearings, sliding bearings, etc. The gears are also exemplified by parallel shaft gears such as a spur gear or a helical gear, and a face gear (face). Asymmetrical shaft gear, worm gear, epicyclic gear, and the like of a cross shaft gear such as a gear, a screw gear, or a hypoid gear. Various types of differential gears, etc. The representative of the motive screw can be exemplified by: (slide screw or rolling screw. Specific transmission element mechanism can be exemplified: Bearings and roller tables for calenders or plasticity processing machines used in iron and steel workshops and metal processing Table roller), chain driving, gear coupling, etc., and for machine tools, injection molding machines, presses, forging presses, grinders, etc., have bearings, motive screws, Precision drive machine for gears, belts, chains, etc., part of the car. Power trains, constant speed joints, 10,000 K: joints, bearings, actuators in the periphery of the engine (actuator) ), starters, gears, alternators, bearings, and steering around are using electric steering, overspeed racks (rac magic and pinion (pini〇n) , tilt telescope, suspension ball joint mechanism, brake device or chassis lubrication, electrical device parts, electrical device mechanism, in the door handle of the door , door check, door hinge, door lock actuator 6 319937 200900499 (door lock actuator), door ratchet, lock &Amp; Qiao Cylinder), electric mirrors, the seat belt (seat beh), seats, door window regulator Υ (d〇〇r Regulator), various switches (switch) of various transmission element (element means. X ’ automatic two-wheelers, bicycles, etc., have chain drive parts and bearings. In the construction machinery such as excavator (excavat〇r), wheel loader (loader), bulldozer (bull dGzer), crane ((10)), there are guide bushes, gears, bearings, and in agriculture. There are bearings, gears, and key bar drive units in machinery, lawn mowers, and electric mines (10) ain saw. In addition, in the railway system, there are shifting mechanisms for shifting wheels and rails, and various bearings and life wheels are also provided on airplanes or ships. In addition, CD (disc), DVD (diversified digital optical disc), recording magnetic cymbal, digital as a memory media, various video and audio information equipment, and such belts, equipment, printers, fax machines, copiers, etc. 〇A device. In the air compressor, the refrigerator, the vacuum cleaner, the induction cooker, the hard disk drive unit in the brain of the uLir motor, etc. The example of the door-to-door mechanism of the clock. The wheel mechanism can also be used as a transmission component in such transmission component mechanisms, suitable for oil, lubricants, and other smuggling..., various lubrication purposes, purposes, / 'greases, solid lubricants, and Combine this right::slide method. In particular, the lubricating wax system is not easy to leak oil, and has been developed; the product having the required performance for each purpose of the makeup-- reveals that there is a dish containing the object, and it has been deprecated. Also, from s, there are Shiguangyuan oil 糸 and / people (Ii_ 】 Ubdcating base 〇 ii), 餹 Ge / U liquid full-slip base oil double saddle and / or monoamine, and containing 319937 7 200900499: rub A composition having a thermoreversible gel-like lubricity of a finishing agent (Patent Document ί). In recent years, due to the strong demand for high-function 2, miniaturization and durability of the above-mentioned mechanical systems, the lubricant has been required to be further improved in performance, especially even if the amount of oil is extremely small (4). [Patent Document 1] W〇 (World Patent;) 2〇〇6/〇51671 [Summary of the Invention] ί [Problems to be Solved by the Invention] ^Inventives To solve the above-mentioned weak developers, the object of the present invention is to Syrian (4) slip agent composition, a very small amount of oil agent is applied to the lubrication month.卩Excellent lubricity, such as high extreme resistance to extreme pressure, and frictional properties, even in the film state, and semi-solid state at f temperature. This lubricant composition is used for conduction. In the case of the inventors, in order to solve the above problems, the lubricant base oil additive and the like, and these combinations are dedicated: Nine, and the fruit 'finally The invention has been achieved. That is, the present invention is a lubricant composition and a lubricating system as described below. );. The composition of the genus is characterized by containing a liquid base oil Μ to (4) 里里/〇, an acid amine compound 〇 J to 9 〇 詈. / to 20 and nursery / + Λ main (eight) Berry / 〇, and solid lubricant L0 shell 1 money _ 5 to 5 mass% of organic compound as steel (〇), and semi-solid at room temperature . (7) The lubricant composition according to the above (1), wherein the liquid base oil is selected from the group consisting of at least 319937 200900499 self-poly-α-dilute hydrocarbon low polymer and fatty acid ester. (3) The lubricant composition according to the above (1) or (2), wherein the guanamine compound is at least a compound represented by the following general formulas (1) to (3). R1 — CO — NH — RZ m (2) (3) R 3 — CO — Ν Η — A 1 — NH — CO — r * R — NH — CO — A2_CO· — NH — Re (Formula (1) to ( 3), R1, R2, R3, R4, r5 and "single, independent, saturated or unsaturated chain hydrocarbon groups of 5 to 25, and R2 may be 氲, ... ' and A is selected from carbon number 1 a divalent hydrocarbon group having an alkyl group, a phenyl group or an alkyl group having a carbon number of 7 to 10 and having a carbon number of from 丨 to 1 。 to 1 。.) (4) as in the above items (1) to (3) In the above-described (1) to (3), the solid lubricant is one or more selected from the group consisting of molybdenum disulfide, graphite, a nitrided side, and a gas-containing resin. The lubricant composition described above, wherein the organic pin compound is a dithioamino group f acid and at least one of them. (6) A lubricating system characterized by: a lubricant composition described in the main (7) section of the earthworm (1) It is used in the transmission element mechanism. : Upper drive r drive _ and at least β Γ of the cable 皮带 Cam, belt, chain, [Effect of the invention] The moving part of the lubricant composition of the present invention can be used to form a shape when sliding Stable and small amount applied to the lubricious film and displayed for a long period of time 319937 9 200900499 High resistance to extreme pressure and low friction. Also, due to the usual, w generation * A < special lubricity special The effect can be replaced by a 2", + solid lubricant composition, 'J a eight-force grease, fire screw, direct linkage table, cam, ancient I. As a bearing, gear, transmission mechanism, especially for A, A &V; V, chain, steel cable and other transmission elements. The lubricant of the power steering device of the vehicle is effective. [Embodiment] [Best Mode for Carrying Out the Invention] The present invention is a lubricant composition oil of 10 to 99 9皙1. / ^ A characteristic is · Contains a liquid base 1 ^ Bei U'Si amine compound 固态 Solid lubricant 1.0 to 20f amount 90 〇 / 〇, and 里 /. The next 0.0005 to 5皙詈% of the sigma compound as the amount of molybdenum (Mo), and the force of the shellfish / the organic molybdenum: need to be constructed, then become; to = the lubricity of the hair, is worried, need resistance The low-speed, high-load operation of the gourd g trouble) is useful in the operation. Because it can be s under the film, _ ^ ^ is also excellent in % oil retention, and it is difficult to break the oil. Further, in the lubricating composition of the present invention, when the sliding portion of the transmission element mechanism is _±, the temperature of the sliding portion rises as the temperature of the sliding portion rises, and the liquid is formed from a semi-solid state, A heart, and After entering the narrow sliding part, it acts as a lubricant composition, and the gun + uses the part that does not propagate the frictional heat because it returns to the sliding part, and still maintains the semi-solidification strength &< + dry mouth shape Sad, so you don't need to worry about the so-called oil spill and you can always keep it clean. In addition, the "class, main - ^ ten degrees" table does not indicate the normal temperature in the room, specifically, 319937 10 200900499 is below 50 ° C, and more generally, it is about _1 〇 to 3 〇 ° ° The temperature environment. [Liquid base oil] The liquid base oil used in the present invention can be a mineral oil (minerai®), s oil or a special mixed oil. The characteristics of the liquid base oil are not particularly limited, but are preferably 40. (: The kinematic visc〇sity is 5 to 5000 mm2/s, more preferably 10 to 1 mm2/s, and preferably 2 to 700 mm/s. Furthermore, the viscosity index (visc) 〇sity ίη&χ) Above 9〇, the rut is preferably 95 to 250, and the pour point (p0ur p〇int) is at 1〇.
方式使用。 又，合成油而言，可例舉：Way to use. Further, in the case of synthetic oil, it is exemplified:
可例舉：聚-α -烯烴（PAO)、乙烯_ 低聚合物、燒基石油環 b (silicone oil)、氟化油 從黏度特性、氧化穩定性、材料適 -_烯烴、脂肪酸酯較優而很適合 319937 11 200900499 使用。此等合成油，祇要是能符合上述物性，則可單獨使 用，亦可組合2種以上使用。再者，可將上述鑛物油鱼入 成油按任意混合比例混合使用。此時 :厂 可分別使用複數種。 、物油及5成油’ 性優Γ且:二係化學惰性者，可在市面上蹲得黏度特 憂以、具有廣乾圍之黏度者而成本上亦較低廉。聚 _，較佳為使用將i癸稀或in、或者^ f 的烯烴低聚合物聚合後，在聚合度2至10的範圍内，哩將 此等聚合物為黏度之調整而適當調配者。 、、 脂肪酸酯亦可在市面上講得種種分子構造的化合物， 分別具有特有的黏度特性（高黏度指數、低流動點），如盘 同-黏度之烴系基油比較時’為具有閃點高的特徵之基 油。脂肪酸酉旨，可由醇與脂肪酸之脫水縮合反應而势得: t料中，在化學穩定性方面，可例舉：二醋、多醇醋、 或複δ酯卜〇1111)1以以恍〇為合適的液狀基油成分。 一酉旨而言，碳數4至；14 66 -；；ff；*； ^ . 4的—兀酸與碳數5至18的醇 2 1為適用。在此，二元酸而言，可具體例舉：己二 二，"~§夂' 癸一酸 '十H、十二烧二酸等’而較 佳為己二酸、壬二酸、癸二酸。醇而言，碳數6至12的一 兀醇’特佳為於8至10的烴基上具有分枝之-元醇。且體 ^言，可例舉：2-乙基己醇、3,5,5_三甲基己醇、:月 桂醇、油醇等。 月 ^多醇醋而言，較佳為新戊二醇、三經甲基乙院、 —尹工甲基丙燒、三經甲基丁燒、二（三經甲基丙烧）、三（三 319937 12 200900499 羥甲基丙垸）、異戊四醇、二（異戊四醇）、三（異戊四醇）等 的受阻醇（hindered alcohol)與碳數！至24 #脂肪酸所成之 酯。脂肪酸中，其碳數並不特別限制，在碳數】至24的脂 肪酸之中，從潤滑性來看，較佳為碳數3以上者，更佳為 碳數4以上者，再佳為碳數5以上者’特佳為碳數7以上 者。可具體例舉：戊酸、己酸、庚酸、辛酸、壬酸、癸酸、 十烷敲、十二烷酸、十三烷酸、十四烷酸、十五烷酸、 /十六烷酸、十七烷酸、十八烷酸、十九烷酸、二十烷酸 ' (eicosanic acid)等，而此等脂肪酸可為直鏈狀脂肪酸、分 枝狀脂肪酸中之任一者，再者亦可為α碳原子為四級碳原 子之脂肪酸（新酸）。此中，纈草酸（正戊酸）、己酸…邛⑺沁 aCldK正己酸）、庚酸（enanth acid)(正庚酸）、辛酸（caprylic acid)(正辛酸）、壬酸（pelarg〇nic add)(正壬酸）、癸酸 acid)(正癸@欠）、油酸（順式十八稀酸）、異戊酸（3·甲基丁 酸）、2-甲基己酸、2_乙基戊酸、2_乙基己酸以及3,5,5_三 4甲基己酸為適用。 V， 又，從二元酸與多元醇與一元羧酸或一元醇所合成之 複合醋亦適用。礦物油係更廣泛使用之基油，且在成本面、 黏度特性、氧化穩定性等的平衡良好者。此等基油之中， 聚-α -烯烴可作為在性能面、成本面最優異的基油使用。 [醯胺化合物] 用於本發明之醯胺化合物，為1個以上具有醯胺基 (-NH-C0-)之脂肪醯胺化合物，而具有】個下式（丨）表示之 酉I胺以及具有2個式（2)及（3)表示之雙醯胺為適用。 319937 13 200900499 R1 —CO —NH —R2 ⑴ 式中，R1及R2各自獨立，係碳數5至25的飽合或不 飽和鏈狀烴基，又，R2可為氫。 R3·— C Ο — N Η—A 1_NH — CO—R** (2) R5 —NH —CO —A2—CO —NH —R® (3) 式（2)及（3)中’ R3、r4、汉5及尺6各自獨立，係碳數5 至25的飽和或不飽和鏈狀烴基，^及A2為選自碳數i至 ^ 10的伸烷基、伸苯基或碳數7至1〇的烷伸苯基中之碳數工 '至1〇的2如'烴基。又，如係烷伸苯基時，可為伸苯基與烷 基及/或伸烷基的2個以上結合之形態的2價烴基。 2單酿胺化合物，係以上述式⑴表示者，惟構成以及 R2之氫的一部分，可經羥基所取代。此種單醯胺化合物而 。T具體例舉.月桂醯胺、棕櫚酿胺、硬脂酿胺、山茶 醯胺（behen amide)、羥基硬脂醯胺等的飽和脂肪醯胺、油 酸胺、芥子醯胺(陳amide)等的不飽和脂肪酿胺，以及硬 脂基硬脂醯胺、油基油醯胺、油基硬脂醯胺、硬脂基油醯 胺等的飽和或不飽和長鏈脂肪酸與長鏈胺之取代醯胺類 等。 此等單醯胺化合物之中，較佳為式⑴的Ri及R2係各 自獨立之碳數12至20飽和鏈狀烴基的酸胺化合物及/或 R1及R2的至少任-者係碳數12至2〇的不飽和鍵狀煙基 的酸胺化合物’更佳為兩醯胺化合物的混合物。再者，較 ，為不飽和鏈狀煙基係碳數18之具有不飽和鍵之油基之 單醯胺化合物。具體而言，較佳為油酿胺、油基油酸胺， 319937 14 200900499 η. ^ 而在滑動部形成薄膜並保持， 效的薄膜㈣性。 叫保為解除燒結困擾上有 雙酿胺化合物而言，伟以呈古_ _ • ^ ^ ^ 乂具有二兀胺的酸醯胺或二亓 酸的酸驢胺的形態之上述式⑺或⑺分別表示之化合物: 式⑺及（3)中以R3、R4、R5以及r6，再者以a、2 表示之烴基中，-部分的氫可經經基（姻)所取代。 以式（2)表示之醯胺化合物而言，可具體例舉：伸乙美 雙硬脂酿胺、伸乙某鏤里;^ ^ r, 甲卷又異硬脂酸胺、伸乙基雙油醯胺、亞 '甲基雙月桂醯胺、六亞甲其雔、、山挤p T暴雙油醯胺、六亞甲基雙羥基硬 =胺、間苯二甲基雙硬㈣胺等。以式（3)表示之龜胺化 “勿而言，可具體例舉：Ν，Ν，·二硬脂基癸二酿胺等。 Λ Κ 此等雙酿胺化合物之中，按與單酿胺化合物的情形同 樣方式，較佳為式（2)的Rl R4以及式⑶的^及r6係分 別獨立之碳數12至20飽和鏈狀烴基的醯胺化合物及/或 R3與R4以及以與…的至少任一者係碳數12至2〇不飽和 鍵狀經基的酿胺化合物’更佳為兩酿胺化合物的混合物。 f者，從確保薄膜保持性來看，較佳為不飽和鏈狀烴基係 炭數18之具有不飽和鍵之油基之雙醯胺。此種化合物而 3，可例舉：伸乙基雙油醯胺、六亞甲基雙油醯胺等。 醯胺化合物，如與液狀基油均勻混合時，則形成常溫 下為凝膠狀之具有潤滑性之組成物。將此組成物與後述的 固恕潤滑劑或有機鉬化合物均勻調配，以調製本發明之常 下為半固恶狀（凝膠狀）的潤滑劑組成物。因而，酿胺化 δ物，除了發揮使液狀基油半固化（凝膠化）之半固化化合 319937 15 200900499 物之功能，同睹Λ 況下，則因摩捧執‘熔：：劑組成物本來的潤滑特性之狀 功能。如考慮到:常溫下=體:潤:劑:一 態應用之情形時，則適用 二入在&皿下為液體的狀 5〇至200。。、更佳 ：物而言，溶點較佳為 至则，更佳為⑽至_ 者’分子量較佳為1〇0 又’在因機械系統的設計上之限 的油劑之滑動部下，為 而僅此使用極少量 燒結等情形嚴可的潤滑環境下亦不產生 保持油膜。/固地吸附.附著於滑動表面以 4 ，f要具有附著性的油劑，而在本發明中 ㈣狀時身^半固化化合物之酸胺化合物的烴基係不飽 切著性之事實。如附著性增大時，列 ψ 4表面’而即使在嚴苛的潤滑環 :仍不谷易發生油膜斷裂而提升潤滑性能。不飽和鍵狀 二較佳為碳數12至20之具有不飽和鍵之鏈稀基、 3 土’’、、於妷數18之具有不飽和鍵之油基之雙醯胺化合 物。 、、醯胺化合物係調配為完成後之常溫下為半固態狀之潤 /月=]、、且成物中所含的01至90質量％。如醯胺化合物的調 曰在〇·1貝里/〇以下呀，則在常溫下係無法形成凝膠的 組成物’另一方面，即使調配9〇質量％以上，仍因過硬而 難以操作處理，故不宜。更佳的調配量為i至8〇質量％。 [固態潤滑劑及有機鉬化合物] 本發明之潤滑劑組成物中，為實現高度潤滑性起見， 319937 16 200900499 則調配固態潤滑劑1.0至20質量％或調配M〇量為〇 〇〇〇5 至5質量％之有機鉬化合物。特佳為兩者均調配。 可於本發明之潤滑劑組成物中使用之固態潤滑劑而 言，可例舉：屬於層狀構造化合物之二硫化鉬、石墨或氮 化蝴、更進一步之聚醯亞胺、聚四氟乙稀（PTFE)等的含氟 樹脂。 固態潤滑劑，係調配為本發明之潤滑劑組成物中所含 的1至20質量％、較佳2至10質量％。如含量低於】質 量％時，則與固態潤滑劑並無調配之意義，又即使調配超 過20質量％時未能獲得相當於增量分之潤滑性的效果且 不能穩定分散於基油中。 此等固態潤滑劑，祇要是能以微粒狀均勻分散於基油 中，則可在粒徑等方面並無特別限制下使用，惟為使不致 於沉殿之下而穩定分散起見，較佳為0.01至i00/am、更 佳為0.1 i 1G//m的粒徑。又預先經將此等固態潤滑劑均 勻分散於稀釋油、稀釋溶劑中者亦可適當使用。此等固能 =劑，1由於層狀構造化合物m二硫化鋼储 ’月動4所形成之满滑被膜能在嚴厲的潤滑區域中高效率 方式對低摩擦特性有助益，故更佳。 物而士有文使用於本發明之滿滑劑組成物令之有機錮化合 ° 可例舉.二硫代胺基甲酸鉬（modt 、_ _(m°dtp)等。此等化合物可以單獨使用，亦 使：。特別是如將無機鉬化合物與有機鉬化合物組 ° 可獲得更大的潤滑性的提升效果。因而，較佳 319937 17 200900499 為將二硫化鉬、與MoDTC及/或MoDTP組合使用。此時 無機钥化合物與有機鉬化合物的混合比例係以鉬原子作為 基準時較佳為〇.5 : 1至150 : 1，更佳為1 : 1至20 : 1。 無機鉬化合物及有機鉬化合物，係以鉬原子作為基準 時’於經完成後之常溫下為半固態狀之潤滑劑組成物中， 按能含有較佳為〇.〇2至20質量％、特佳為〇.；[至10質量 %之方式調配。如調配比例低於〇.〇2質量％時，則不能獲 ^得潤滑性的提升效果，又另一方面，即使調配超過20質量 ' /°日守，不僅不能獲得調配量所相當之潤滑性之提升效果， 且可旎因添加量過多而無法穩定地溶解於基油中因而有不 良影響。 [潤滑劑組成物之調製] 本發明之常溫下為半固態狀之潤滑劑組成物，雖並不 知·別限定，惟如將液狀基油、醯胺化合物、固態潤滑劑以 及有機鉬化合物按上述比例均勻混合，即可調製。例如， I刀別按既疋i取液狀基油、酿胺化合物、固態潤滑劑以及 有枝鉬化合物，將液狀基油與醯胺化合物（半固化化合物） 加熱至熔點以上後，在液體狀態下添加固態潤滑劑及有機 铜化合物並均勻授拌，冷卻後作成半固態狀即可製得。由 於二硫化鉬係粉末固體而難以均勻混合於液體的油中’特 別是由於二硫化銷係對油為不溶性之惰性無機化合物而難 於均勻分散在液體中。於是，亦可於將液狀基油或有機銷 ，σ物與加熱至溶點以上之賴化合物均句混合後冷卻所 侍之半固態狀的組成物中混練二硫化鉬，以調製經均勻混 319937 200900499 « 。各成分之常溫下為半固態狀之濶滑劑組成物。 本發明之組成物中，可再適當調配公知之極屢劑、抗 ，肉1劑、抗摩損劑、防鱗劑、抗氧化劑、以及消泡劑等的 ，：劑。極屢劑、抗摩損劑而言，可例舉：二烧 =辞、硫系化合物、碟系化合物等，抗腐㈣而言，可 嗟二唾⑽adiaz〇le)衍生物、苯并三唾（benz〇thiaz〇 及其衍生物，防鏽劑而士，7伽 磺酸鹽、碟系化合物等'一 J牛：腊肪酸部分酉旨、金屬 / A/ 荨，抗氧化劑而言，可例舉：酚孚、 化合物等，以及消泡劑而言，可例舉：有機= =1 而言’可例舉:PMA聚合物等。又，前述各種 、、片’、可以預先經混合數種添加劑之所謂添加劑套穿 (package)的形態使用。 ^ 本發明之常溫下為主m At ^ 卜4丰固怨狀之潤滑劑組成物，如適用 =二=腎作用之機械機構(滑動部)時， .熱而改變為液體狀態而滲透於滑動部中，並於金屬或：： 二：t滑動部之固體表面形成薄膜以潤滑滑動部。如“ SI復= 而原為液體狀態之潤滑劑組成二 歲為德狀(凝膠狀)。又，本發明之潤滑 ’係由於特別是具有如高燒結荷重、低摩捧係數等優盈 的摩捧特性，盅处且& # 士 于w你数4優異 此在用途方面適：於；:'只=此種優異的摩擦特性，因 、低速、尚荷重的極壓作業者，5 4ΐα 土於補給潤滑劑之滑動部或—度經組 不之構 造的裝置的滑動部亦很適合使用。再者，本發 319937 19 200900499 組成物’係由於即使反覆經過因使用、不使用所引起之升 溫、冷卻應力（stress)，仍然能再構建凝膠（半固態狀）構造， 故可避免因漏油所引起之污染。 因而，除了能替代以往的潤滑脂而充分使用之外，尚 可適合使用於例如，軸承、齒輪、傳動螺桿、直接驅動台、 凸輪、皮帶、鏈條、鋼索等的傳動元件機構，尤其是高負 何的傳導元件機構上。特佳的用途而言，可例舉：由螞輪 ,或行星齒輪等所構成之變速齒輪等，其用途而言，可例舉： ^各種輸送機械系統、以及汽車的動力轉向裝置等。 [實施例] 以下，藉由實施例而詳細說明本發明内容，惟本發明 並不因實施例而有所限定。 [液狀基油] 為調製實施例及比較例用的潤滑劑組成物而使用下列 3種液狀基油。 基油A :市售之聚_α _烯烴（PA〇 : M〇biI社製 SHF-400 :黏度級數 VG400) 基油B: VG100的礦物油（日本能源（Japan Energy)社 製 500 中性（neutral)油） 基油C:脂肪酸酯（優尼肯馬（Unikema)社製 2087複合酯） 將此3種液狀基油的物性，表示於表丨甲。再者，此 等液狀潤滑基油中，預先調配有既定量之抗氧化劑、抗摩 損劑等添加劑’而具有作為潤滑油之基本性能（抗氧化、抗 319937 20 200900499 摩損等）。 [表1] 基油A 基油Β 墓油C 油種 PAO 礦物油 脂肪酸酉旨 #度級數 VG400 VG100 VG320 密度（15 C )，g/cm3 0.85 0.88 0.95 動黏度 f4(TC) ，/ π--- 4〇〇T〇 ^96Λ 320.0 mm /s (100 C ) 40.0 11.0 35.0 黏度指數 152 99 150 流動點，°C -40.0 -10.0 -40.0 [醯胺化合物] 调配於液狀基油，並為使其半固化而使用下述酿胺化 合物。 酿胺A :乙烯雙油醯胺（日本化成製，斯力帕克士（音For example, poly-α-olefin (PAO), ethylene_low polymer, silicone oil, fluorinated oil, viscosity, oxidative stability, material--olefin, fatty acid ester Excellent and very suitable for use in 319937 11 200900499. These synthetic oils may be used singly or in combination of two or more kinds as long as they can satisfy the above physical properties. Further, the above-mentioned mineral oil fish may be mixed and used in an arbitrary mixing ratio. At this time: the factory can use a plurality of types separately. , oil and 50% oil's excellent characteristics: the second series of chemical inertness, can be found in the market, the viscosity is particularly worrying, has the viscosity of the wide dry circumference and the cost is also lower. Preferably, the poly-polymer is polymerized by oligomerization of an olefin having a rare or in or a f, and is suitably blended in such a manner that the polymer has a viscosity of 2 to 10 in the polymerization degree. , fatty acid esters can also be said on the market of a variety of molecular structure of compounds, respectively, have unique viscosity characteristics (high viscosity index, low flow point), such as the same as the hydrocarbon-based base oil of the same viscosity A base oil with a high point. The fatty acid can be obtained by dehydration condensation reaction of an alcohol with a fatty acid: In the material, in terms of chemical stability, it may be exemplified by diacetate, polyol vinegar, or complex δ ester dip 1111) 1 to 恍〇 It is a suitable liquid base oil component. For one purpose, carbon number 4 to; 14 66 -;; ff; *; ^. 4 - decanoic acid and carbon number 5 to 18 alcohol 2 1 are suitable. Here, as the dibasic acid, specifically, it may be exemplified by the following: "2", "10", decocted diacid, etc., and preferably adipic acid, sebacic acid, Azelaic acid. In the case of an alcohol, a monoterpene alcohol having a carbon number of 6 to 12 is particularly preferably a branched-alcohol having a hydrocarbon group of 8 to 10. And, in other words, 2-ethylhexanol, 3,5,5-trimethylhexanol, lauryl alcohol, oleyl alcohol, and the like can be exemplified. For the month ^ polyol vinegar, it is preferably neopentyl glycol, Sanjing methyl keie, - Yingong methyl propylene, three methyl butyl, two (three methyl propylene), three (three 319937) 12 200900499 Hindered alcohol and carbon number such as hydroxymethyl propyl hydrazine, isopenic tetraol, bis (isopentyl alcohol), and tris (isopentaerythritol)! To 24 # fatty acid ester. In the fatty acid, the carbon number is not particularly limited, and among the fatty acids having a carbon number of 24 to 24, from the viewpoint of lubricity, it is preferably a carbon number of 3 or more, more preferably a carbon number of 4 or more, and more preferably carbon. Those with a number of 5 or more are particularly good for those with a carbon number of 7 or higher. Specific examples thereof include: valeric acid, caproic acid, heptanoic acid, caprylic acid, capric acid, capric acid, decane pentane, dodecanoic acid, tridecanoic acid, myristic acid, pentadecanoic acid, /hexadecane Acid, heptadecanoic acid, octadecanoic acid, nonadecanic acid, eicosanic acid, etc., and these fatty acids may be any of a linear fatty acid or a branched fatty acid, and then It may also be a fatty acid (new acid) in which the α carbon atom is a quaternary carbon atom. Among them, shikimic acid (n-valeric acid), hexanoic acid ... 邛 (7) 沁 aCldK n-hexanoic acid), enanth acid (n-heptanoic acid), caprylic acid (n-octanoic acid), decanoic acid (pelarg〇nic) Add)(n-decanoic acid), citric acid acid (positive 欠@欠), oleic acid (cis octadecanoic acid), isovaleric acid (3·methylbutyric acid), 2-methylhexanoic acid, 2 _ Ethyl valeric acid, 2-ethylhexanoic acid and 3,5,5-trimethylolhexanoic acid are suitable. V, in addition, a composite vinegar synthesized from a dibasic acid and a polyhydric alcohol with a monocarboxylic acid or a monohydric alcohol is also suitable. Mineral oil is a base oil that is more widely used, and has a good balance between cost surface, viscosity characteristics, and oxidation stability. Among these base oils, poly-α-olefins can be used as the base oil which is most excellent in the performance surface and the cost surface. [Indoleamine compound] The guanamine compound used in the present invention is one or more fatty guanamine compounds having a guanamine group (-NH-C0-), and has a quinone I amine represented by the following formula (丨) Bisylamine having two formulas (2) and (3) is suitable. 319937 13 200900499 R1 —CO —NH —R2 (1) wherein R1 and R2 are each independently a saturated or unsaturated chain hydrocarbon group having 5 to 25 carbon atoms, and R 2 may be hydrogen. R3·— C Ο — N Η—A 1_NH — CO—R** (2) R5 —NH —CO —A2—CO —NH —R® (3) 'R3, r4 in equations (2) and (3) , Han 5 and 6 are each independent, a saturated or unsaturated chain hydrocarbon group having 5 to 25 carbon atoms, and A 2 is an alkyl group selected from carbon number i to 10, a phenyl group or a carbon number of 7 to 1. The carbon number in the alkylene group of the oxime is from '1 to 1' such as 'hydrocarbyl group. Further, when the phenyl group is a phenyl group, it may be a divalent hydrocarbon group in a form in which two or more of a phenyl group and an alkyl group and/or an alkyl group are bonded. The mono-monoamine compound is represented by the above formula (1), and a part of the hydrogen of R2 and R2 may be substituted by a hydroxyl group. Such a monoamine compound. Specific examples of T include a saturated fatty guanamine such as laurylamine, palmitol amine, stearylamine, behen amide, and hydroxystearate, oleic acid amine, and amide amide. Unsaturated fatty amines, as well as substitutions of saturated or unsaturated long-chain fatty acids and long-chain amines such as stearyl stearamine, oleyl oleylamine, oleyl stearylamine, stearyl decylamine Amidoxis and the like. Among these monoamine compounds, it is preferred that the Ri and R2 groups of the formula (1) are independently an acid amine compound having 12 to 20 saturated chain hydrocarbon groups and/or at least one carbon number of R1 and R2 is 12 The acid amine compound of the unsaturated carboxylic acid group of 2 Å is more preferably a mixture of the two amide compounds. Further, it is an oil group-based monoamine compound having an unsaturated chain bond of 18 carbon atoms in an unsaturated chain. Specifically, it is preferably an oil-burning amine or an oil-based oleic acid amine, 319937 14 200900499 η. ^ and a thin film is formed on the sliding portion to maintain an effective film (tetra) property. The above formula (7) or (7) in the form of the acid amine or the acid amide of diterpenic acid, which is a bis-amine compound, is a bismuth amine compound. The compounds respectively represented by R3, R4, R5 and r6 in the formulae (7) and (3), and the hydrocarbyl group represented by a and 2, the hydrogen of the - moiety may be substituted by a base group. In the case of the guanamine compound represented by the formula (2), specifically, it can be exemplified by exo-ethyl bis-stearyl amide, exo-ethyl sulphate; ^ ^ r, acetaminois, isostearic acid, and ethyl bis Oleoylamine, sub-methylbislauroylamine, hexamethylene phthalocyanine, squeezing p T acesulfame, hexamethylene bishydroxyl=amine, m-xylylenebis(tetra)amine, etc. . The alkalization represented by the formula (3) "may not be specifically exemplified by hydrazine, hydrazine, bis-diaryl hydrazine, etc. Λ Κ among these bis-amine compounds, In the same manner as the amine compound, R1 R4 of the formula (2) and the oxime compound of the formula (3) and the r6 are independently 12 to 20 saturated chain hydrocarbon groups and/or R3 and R4, respectively. At least one of the carbon-based 12 to 2 fluorene-unsaturated carboxylic acid-based amine compound is more preferably a mixture of the two-caloric amine compound. In other respects, from the viewpoint of ensuring film retention, it is preferably unsaturated. The chain hydrocarbon group is an oleylamine having an oil group having an unsaturated bond of 18. Such a compound and 3 may, for example, be an ethyl acenaamine or a hexamethylene bis decylamine. When the compound is uniformly mixed with the liquid base oil, it forms a gel-like lubricity composition at normal temperature. This composition is uniformly formulated with a fumigant lubricant or an organic molybdenum compound described later to prepare the present invention. It is usually a semi-solid (gel-like) lubricant composition. Sub-cured semi-cured (gelled) semi-cured compound 319937 15 200900499 The function of the material, in the same condition, the function of the original lubrication characteristics of the composition: : Under normal temperature = body: Run: Agent: In the case of one-state application, it is suitable for the liquid form of 5〇 to 200 in the & dish. More preferably: the melting point is preferably More preferably, the molecular weight of (10) to _ is preferably 1 〇 0 and 'under the sliding portion of the oil agent which is limited by the design of the mechanical system, and only a very small amount of sintering is used. The oil film is not produced under the film. / Solid adsorption. The oil agent adhered to the sliding surface to have an adhesion to 4, f, and in the present invention, the hydrocarbon group of the acid amine compound of the semi-cured compound is not sufficient. The fact that the nature of the cut. If the adhesion is increased, the surface of the tantalum 4' and even in the harsh lubrication ring: the oil film breaks easily and the lubricating property is improved. The unsaturated bond shape is preferably 12 carbon atoms. Up to 20 chains with unsaturated bonds, 3 soils, and 18 And the bismuthamine compound of the oleyl group of the bond, and the guanamine compound are formulated to be semi-solid at room temperature after completion, and 01 to 90% by mass contained in the product. When the guanamine compound is less than or equal to 1 berry/〇, it is a composition which cannot form a gel at normal temperature. On the other hand, even if it is blended at a mass of 9 〇 or more, it is too hard to handle. It is not suitable. A better blending amount is i to 8 〇 mass%. [Solid Lubricant and Organic Molybdenum Compound] In the lubricant composition of the present invention, for the purpose of achieving high lubricity, 319937 16 200900499 is formulated with a solid lubricant. 1.0 to 20% by mass or an organic molybdenum compound having a M amount of 〇〇〇〇5 to 5% by mass. It is especially suitable for both. The solid lubricant which can be used in the lubricant composition of the present invention may, for example, be a molybdenum disulfide, a graphite or a nitriding butterfly which is a layered structural compound, a further polyimine, a polytetrafluoroethylene. Fluorine resin such as dilute (PTFE). The solid lubricant is formulated to be 1 to 20% by mass, preferably 2 to 10% by mass, based on the lubricant composition of the present invention. If the content is less than the % by mass, it is not compatible with the solid lubricant, and even if it is blended in excess of 20% by mass, the effect equivalent to the incremental lubricity is not obtained and it is not stably dispersed in the base oil. These solid lubricants can be used without any particular limitation in terms of particle size, etc., as long as they can be uniformly dispersed in the base oil in the form of fine particles, but it is preferred that they are not dispersed stably under the temple. It is a particle diameter of 0.01 to i00/am, more preferably 0.1 i 1 G//m. Further, those solid lubricants may be uniformly dispersed in a diluent oil or a diluent solvent in advance, and may be suitably used. These solid energy agents, 1 because of the layered structural compound m disulfide steel storage, the full-slip film formed by the Moonlight 4 can be used in a high-lubrication area in a high-efficiency manner, which is beneficial to low-friction characteristics, and is therefore more preferable. The organic hydrazine compound used in the composition of the present invention can be exemplified by molybdenum dithiocarbamate (modt, _ _(m°dtp), etc. These compounds can be used alone. Also, for example, if the inorganic molybdenum compound and the organic molybdenum compound group are used, a greater lubricity can be obtained. Therefore, it is preferable to use 319937 17 200900499 for the combination of molybdenum disulfide and MoDTC and/or MoDTP. In this case, the mixing ratio of the inorganic key compound to the organic molybdenum compound is preferably 〇.5:1 to 150:1, more preferably 1:1 to 20:1, based on the molybdenum atom. Inorganic molybdenum compound and organic molybdenum The compound, which is a semi-solid lubricant composition at a normal temperature after completion, is preferably contained in an amount of from 2 to 20% by mass, particularly preferably 〇. It can be blended to 10% by mass. If the blending ratio is lower than 〇.〇2 mass%, the lubricity improvement effect cannot be obtained, and on the other hand, even if the blending exceeds 20 mass ' / ° day guard, not only can not Achieving an increase in the lubricity of the blending amount, and When the amount of addition is too large, it cannot be stably dissolved in the base oil and thus has an adverse effect. [Preparation of Lubricant Composition] The lubricant composition of the present invention which is semi-solid at normal temperature is not limited, but is not limited. The liquid base oil, the guanamine compound, the solid lubricant, and the organic molybdenum compound are uniformly mixed in the above ratio, and can be prepared, for example, by taking a liquid base oil, a brewing amine compound, a solid lubricant, and the like. A molybdenum compound is obtained. After heating the liquid base oil and the guanamine compound (semi-cured compound) to a temperature above the melting point, a solid lubricant and an organic copper compound are added in a liquid state and uniformly mixed, and then cooled to form a semi-solid state. It is difficult to uniformly disperse in the liquid due to the fact that the molybdenum disulfide powder solid is difficult to be uniformly mixed in the liquid oil. In particular, since the disulfide pin is an inert inorganic compound which is insoluble to oil, it is difficult to uniformly disperse in the liquid. a base oil or an organic pin, and the σ substance is mixed with a compound which is heated to a melting point or higher and then cooled to dissolve the semi-solid composition to serve the molybdenum disulfide to Evenly mixed 319937 200900499 « The composition of each component is a semi-solid lubricant at room temperature. In the composition of the present invention, a well-known extreme agent, anti-antibody, meat 1 agent, anti-wear agent can be appropriately formulated. , anti-scaling agents, antioxidants, defoamers, etc.: agents, extreme agents, anti-wear agents, for example, two burning = words, sulfur compounds, dish compounds, etc., anti-corrosion (four)言, 嗟 嗟 (10)adiaz〇le) derivatives, benzotrisole (benz〇thiaz〇 and its derivatives, rust inhibitors, 7 gamma sulfonate, dish compound, etc. 'J cattle: wax fat The acid moiety, the metal/A/ hydrazine, and the antioxidant may, for example, be a phenolic compound, a compound or the like, and an antifoaming agent, and may be exemplified by organic = =1. Things and so on. Further, the above various sheets and sheets may be used in the form of a so-called additive package in which a plurality of additives are mixed in advance. ^ At the normal temperature of the present invention, the lubricant composition of the main m At ^ Bu 4 rich grievances, if applicable = two = mechanical mechanism (sliding portion) of the kidney action, the heat changes to the liquid state and penetrates the sliding In the part, a film is formed on the solid surface of the metal or ::2:t sliding portion to lubricate the sliding portion. For example, "SI complex = the original lubricant composition of the liquid state is two years old (gel-like). In addition, the lubrication of the present invention is due to, in particular, high sintering load, low friction coefficient, etc.捧 且 & & & & & & & & & & & & & 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异 优异The sliding portion of the replenishing lubricant or the sliding portion of the device which is not constructed by the group is also suitable for use. Furthermore, the composition of the present invention is 319937 19 200900499 because it is caused by repeated use or non-use. The temperature rise and the cooling stress can still rebuild the gel (semi-solid structure), so that the contamination caused by oil leakage can be avoided. Therefore, it can be used in addition to being able to be used in place of the conventional grease. It is used, for example, for transmission components such as bearings, gears, drive screws, direct drive tables, cams, belts, chains, steel cables, etc., especially for high-conductivity conductive element mechanisms. For particularly good applications, it can be exemplified: By the wheel The transmission gears and the like formed by planetary gears and the like may be exemplified by various transportation machinery systems, power steering devices for automobiles, and the like. [Embodiment] Hereinafter, the present invention will be described in detail by way of examples. The present invention is not limited by the examples. [Liquid base oil] The following three liquid base oils were used to prepare the lubricant compositions for the examples and the comparative examples. Base oil A: Commercially available Poly-α-olefin (PA〇: SHF-400 manufactured by M〇biI Co., Ltd.: viscosity grade VG400) Base oil B: Mineral oil of VG100 (500 Neutral oil made by Japan Energy) Oil C: Fatty acid ester (2087 complex ester manufactured by Unikema Co., Ltd.) The physical properties of the three liquid base oils are shown in Table A. Further, in these liquid lubricating base oils, It is formulated with a certain amount of additives such as antioxidants and anti-wear agents, and has the basic properties as a lubricating oil (antioxidation, anti-319937 20 200900499 abrasion, etc.) [Table 1] Base oil A base oil 墓 Tomb oil C oil type PAO Mineral oil fatty acid 酉# degree series VG400 VG100 VG320 density (15 C), g/cm3 0.85 0.88 0.95 Dynamic viscosity f4(TC) , / π--- 4〇〇T〇^96Λ 320.0 mm /s (100 C ) 40.0 11.0 35.0 Viscosity index 152 99 150 Flow point, °C -40.0 -10.0 -40.0 [Valeramine compound] It is formulated in a liquid base oil and used to make it semi-cured, and the following aramid compound is used. Amine A: ethylene bisamine (made by Nippon Chemical Co., Ltd., Slip Park)
譯）0)，熔點119°CTranslation) 0), melting point 119 ° C
酿胺B : N-硬脂基硬脂醯胺（日本化成製，日化醯胺 S)，熔點 95°CAmine B: N-stearyl stearylamine (manufactured by Nippon Chemical Co., Ltd., ruthenium amide), melting point 95 ° C
[固態潤滑劑] 作為固態潤滑劑，使用下列2種化合物。[Solid Lubricant] As the solid lubricant, the following two compounds were used.
MoS2 .二硫化鉬，粒徑1 # m，Mo量60質量％， PTFE :聚四氟乙烯微粒KD-300AS(喜多村製），粒徑 〇·3 # m，礦物油稀釋，pTFE濃度4〇% [有機翻化合物] M〇DTC :阿替卡沙克拉路布（Adeka Sakura Lube)515 (ADEKA 製），Mo 量 10 質量％，動黏度（4〇〇c)7〇〇mm2/s。 21 319937 200900499 t [潤滑劑組成物之調製] 作為上述液狀基油而使用基油Α(ΡΑ〇)及基油Β(礦物 油），作為醯胺化合物而使用醯胺Α(乙烯雙油醯胺）及醯胺 Β(Ν-硬脂基硬脂醯胺），並作為*目化合物而使用(二硫 化鉬）及MoDTC(二硫代胺基甲酸錮），按下述步驟調製實 細例1至10及比較例i、2的供試油（调滑劑組成物）。 不鏽鋼製的燒杯中，將液狀基油、酸胺化合物以及翻 ，合物依對表2的上部所示之完成後之供試油之比例（質 :%)’按分別能獲得、約1〇〇ml的供試油之方式量取既定 罝，使用桌上電磁加熱器，在加溫至醯胺化合物的熔點以 上（溶點WC)之溫度下-邊授拌。以外觀的觀察判斷已均 句洛解後’將均勾溶解液約1〇〇ml移至耐熱玻璃容徑 60mmx高度9〇mm)並放冷，制每 ;π周製貫施例1至10及比較例 吊溫下為半固態狀的潤滑劑組成物。 .、將乂往作為半固悲狀潤滑劑組成物使用之市售的鋰 (:1:;=為比較對象(比較例2)加以評價。該潤滑脂含 有Mo糸添加·XM〇計為7%)，而潤滑脂的稠度 (consistency)分類，係相當 265至295)。 田於稠度號碼2唬（混合稠度範圍 [評價方法] 組成^述之方法實施實施例及比較例的各潤滑劑 定）。將價試驗(燒結荷重及摩擦係數之測 ’ T果呈不於表2下部。 (l)FALEX燒結試驗 319937 22 200900499 使用ASTM D3233所記載之FALEX試驗機，進行依 塊料（block)/銷子（pin)的組合之燒結荷重之測定。V字塊料 及銷子的材質，係AISI(美國鋼鐵學會）鋼。按回轉數 300rpm、連續荷重、室溫之條件開始測定。一般性評價， 係在塊料/銷子全部浸潰於供試油中之狀態下測定，惟在本 評價中，則僅於2個V字塊料的V字部分（三角柱）塗佈供 試油，並記錄在少量供試油時之燒結荷重。在此，試驗中 的供試油的補給，則並未實施。 f : (2)HFRR 試驗 使用JPI-5S-50-98(石油學會規格，輕油-潤滑性試驗方 法）中所規定之HFRR試驗機（PCS Instruments社製HFRR D-826)測定摩擦係數。材質為SUJ(高碳含鉻軸承鋼）-2。圓 盤（disk)為直徑9mm、厚度5mm，而材質為SUJ-2。供試 油係於圓盤表面按作為塗布量能成為_ 0.0003g/cm2之方式 加以極薄之塗佈。試驗係依荷重300gf，振幅數50Hz，振 幅（amplitude) 1.0mm，溫度25 °C下，實施10分鐘往返摩 I... 擦0 23 319937 200900499 [表2] I I 1 1 1 (含有Mo) 1 Ο ο ο V-· 燒結 比較例 1 餘量 1 1 csi CO 1 ! I 1 ο 00 燒結 實施例 10 I 1 餘量 CM CO to ir> 1 1 1800 0.12 實施例 9 餘量 1 1 Οί CO 1 LD m 1 1600 0.12 實施例 8 餘量 1 1 ο o LO IA 1 1 ο 卜 τ— 0. 12 實施例 7 餘量 1 1 ο 1 m LT> 1 ! 1800 丨 0.14 實施例 6 餘量 1 1 1 o in in 1 1 1500 0.12 實施例 5 餘量 1 1 CM 00 O 1 1 1 ί 1600 I 0.14 實施例 4 餘量 1 1 CM CO 1 o I 1 1900 0.12 實施例 3 餘量 J 1 CNJ CO 1 m 1 1 1800 0.12 實施例 2 餘量 1 1 CM CO m ia 1 1 2100 0.12 實施例 1 I_ I 餘量 1 CM 00 LO 1 1 2000 0.13 基油A:PAO 基油B :礦物油 基油C :酯 醯胺A 醯胺B Μ 〇 S 2 Mo DT C 固態潤滑劑 pt f ε L ί潤滑脂 F A L EX 燒結荷重、LBF H F RR 摩擦係數 24 319937 200900499MoS2. Molybdenum disulfide, particle size 1 # m, Mo amount 60% by mass, PTFE: Polytetrafluoroethylene particles KD-300AS (made by Kitamura), particle size 〇·3 # m, mineral oil diluted, pTFE concentration 4〇% [Organic compound] M〇DTC: Adeka Sakura Lube 515 (made by Adeka), Mo amount 10% by mass, dynamic viscosity (4〇〇c) 7〇〇mm2/s. 21 319937 200900499 t [Preparation of Lubricant Composition] As the liquid base oil, base oil ΡΑ〇 (ΡΑ〇) and base oil 矿物 (mineral oil) are used, and amidoxime (ethylene bismuth) is used as the guanamine compound. Amine) and amidoxime (hydrazine-stearyl stearylamine), and used as a *mesh compound (molybdenum disulfide) and MoDTC (bismuth dithiocarbamate), prepared according to the following procedure Test oils (slip agent compositions) of 1 to 10 and Comparative Examples i and 2. In a beaker made of stainless steel, the liquid base oil, the acid amine compound, and the compound of the test mixture according to the upper part of Table 2 (quality: %) can be obtained, respectively. 〇〇ml of the test oil is measured in the manner of the predetermined enthalpy, using a table electromagnetic heater, heating to the temperature above the melting point of the guanamine compound (melting point WC) - while mixing. According to the observation of the appearance, after the average sentence is solved, 'the solution of the solution is about 1〇〇ml to the heat-resistant glass volume 60mmx height 9〇mm) and let it cool, make each; π week system examples 1 to 10 and compare The lubricant composition is semi-solid in the case of hanging temperature. . Commercially available lithium (:1:;= is a comparative object (Comparative Example 2) used as a semi-solid lubricant composition. The grease contains Mo糸 added·XM〇 is 7 %), and the consistency of the consistency of the grease is equivalent to 265 to 295). The field consistency number is 2 唬 (mixing consistency range [Evaluation method] The method of composition is described in each of the lubricants of the examples and the comparative examples). The price test (measurement of sintering load and friction coefficient) T is not shown in the lower part of Table 2. (l) FALEX sintering test 319937 22 200900499 Using the FALEX test machine described in ASTM D3233, the block/pin is used. The measurement of the sintering load of the combination of (pin). The material of the V block and the pin is AISI (American Iron and Steel Institute) steel. The measurement is started under the conditions of 300 rpm, continuous load and room temperature. General evaluation, The block/pin is all immersed in the test oil, but in this evaluation, only the V-shaped part (triangular column) of the two V-blocks is coated with the test oil, and recorded in a small amount. The sintering load at the time of test oil. Here, the supply of the test oil in the test is not implemented. f : (2) The HFRR test uses JPI-5S-50-98 (Petroleum Society Specification, Light Oil - Lubricity The friction coefficient was measured by the HFRR tester (HFRR D-826 manufactured by PCS Instruments Co., Ltd.) specified in Test Method. The material was SUJ (high carbon chromium bearing steel)-2. The disk was 9 mm in diameter and 5 mm in thickness. The material is SUJ-2. The test oil is applied to the surface of the disc as the coating amount can become _ 0.0 003g/cm2 is applied in a very thin coating. The test is based on a load of 300gf, an amplitude of 50Hz, an amplitude of 1.0mm, and a temperature of 25 °C for 10 minutes. Table 2] II 1 1 1 (containing Mo) 1 Ο ο ο V-· Sintering Comparative Example 1 Balance 1 1 csi CO 1 ! I 1 ο 00 Sintering Example 10 I 1 Residual CM CO to ir> 1 1 1800 0.12 Example 9 Balance 1 1 Οί CO 1 LD m 1 1600 0.12 Example 8 Balance 1 1 ο o LO IA 1 1 ο 卜 — 0. 12 Example 7 Balance 1 1 ο 1 m LT> 1 ! 1800 丨 0.14 Example 6 Balance 1 1 1 o in in 1 1 1500 0.12 Example 5 Balance 1 1 CM 00 O 1 1 1 ί 1600 I 0.14 Example 4 Balance 1 1 CM CO 1 o I 1 1900 0.12 Example 3 Balance J 1 CNJ CO 1 m 1 1 1800 0.12 Example 2 Balance 1 1 CM CO m ia 1 1 2100 0.12 Example 1 I_ I Balance 1 CM 00 LO 1 1 2000 0.13 Base Oil A: PAO Base oil B: mineral oil base oil C: ester decylamine A guanamine B Μ 〇S 2 Mo DT C solid lubricant pt f ε L ί grease FAL EX sintering load, LBF HF RR friction coefficient 24 319937 200900499
I 只施例1至10’係在FALEX時的燒結荷重為至 2100LBF(外而顯示有高度的耐㈣性能。相對地，比較 例1、2中之燒結荷重係較實施例為低的值。又，在舰r 忒驗中3〜例1至10的摩擦係數顯示有如m至〇 定：值’惟比較例中，則摩擦時間不及1〇分鐘即發生 、、Ό。攸以上的結果可知承 / ,、 ^ 貝細例中，即使極少量的油劑 仍然能顯示高度的耐極壓性， -,^ ΑΑ ^, 且即使塗佈為溥膜狀仍然能 f t成堅固的摩擦係數之情形。 [產業上之可利用性] 物^可知’本發明之常溫下為半固態狀的潤滑劑租成 物，係較通用潤滑脂為能以極 ^丄且成 態，並顯千古命Α ί ν里的使用量形成薄膜狀 並颁不阿度的耐極壓性及穩 的摩擦牿/ Α 心曰7厚擦特性。特別穩定 如適用於播知-, 原有助盃者。因而， 坶用於傳動π件機構，例如， 凸輪、虔册 車承、食輪、傳動螺桿、 皮Τ、鏈條、鋼索等機構所成 用時，則可每u 战之機械系統並加以利 二iT貫現省能源’且由於耐特堡 為了貝獻於機械系統的对用化。 d月待 【圖式簡單說明】 無 主要 無 元件符號說明 319937 25I Only the examples 1 to 10' had a sintering load of 2100 LBF at FALEX (externally showing a high resistance (4) performance. In contrast, the sintering load in Comparative Examples 1 and 2 was lower than that of the examples. In addition, in the ship's test, the friction coefficient of 3 to 1 to 10 shows that there is a value of m to :: value 'only in the comparative example, the friction time is less than 1 minute, and Ό. / , , ^ In the case of the shell, even a very small amount of oil can still show a high degree of extreme pressure resistance, -, ^ ΑΑ ^, and even if it is coated in a enamel film, it can still be a solid friction coefficient. [Industrial Applicability] The product can be known as a semi-solid lubricant renter at normal temperature in the present invention, which is more versatile and more versatile than the general-purpose grease, and has a history of 古 ν The amount of the film is formed into a film shape and is infinitely resistant to extreme pressure and stable friction 牿 / Α Α 7 thick rubbing characteristics. Particularly stable, such as suitable for broadcast - the original helper. Therefore, use In the transmission of π-piece mechanism, for example, cam, book carrier, food wheel, drive screw, leather belt, chain, steel cable, etc. When it is used, it can be used for every mechanical system of the war and it can be used to save energy. And because of the use of Natto Fort for the mechanical system, it is suitable for the use of the mechanical system. No component symbol description 319937 25