TW200814050A - Method and apparatus for manufacturing optical recording medium - Google Patents

Abstract

To provide a method for manufacturing an optical recording medium by which a stamper is excellently removed from a transfer layer during manufacture of the optical recording medium having an intermediate layer having pits and lands. A first recording medium 100 is formed in which a recording/reproducing function layer 2 and a lower intermediate layer 3 are sequentially stacked on a substrate 1. A transfer layer stacked stamper 200 having a transfer layer 6 which is formed by half-curing an ultraviolet curing resin film applied on a surface of a stamper 4 having pits and lands and thereafter further curing the film in a low oxygen concentration atmosphere, is formed. Thereafter, the first recording medium 100 is bonded to the transfer layer stacked stamper 200 with the lower intermediate layer 3 and the transfer layer 6 facing each other, and thereafter, the stamper 4 is removed.

Description

200814050 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種光&己錄媒體之製造方法等。詳細而 言，係關於一種製造設有記錄再生功能層之光記錄媒體之 方法等。 【先前技術】200814050 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD The present invention relates to a method of manufacturing a light & recorded medium. More specifically, the present invention relates to a method of manufacturing an optical recording medium having a recording and reproducing functional layer. [Prior Art]

近年來’對CD — R、CD ~ RW、D VD — R、可重寫型d VD 等光A錄媒體（以下有時稱為「光碟」）要求更高之記錄密 度化。 作為用以增大上述光碟容量之手段，有如設置2層以上 之記錄層之方法。於設置2層以上之記錄層之情況，通常 於記錄層與記錄層之間設置中間層。 另一方面，於設於基板上之反射層上、或者反射層及記 錄層上，具有厚0·1 mm之被覆層的下一代高密度光碟亦 得到實用化（藍光光碟（Blu — ray Disk)、超密度光學 _ (UDO, Ultra—Density Optical)等）。該等高密度光碟中， 藉由具有高NA(數值孔徑，例如〇·85)之物鏡使藍紫色雷 射光聚光，將该經聚光之雷射光自上述被覆層侧照射，藉 此進行資訊信號之記錄及/或再生。上述光碟被稱為膜面 入射型光碟。對於該等膜面入射型光碟，亦設置2層以上 記錄層，而嘗試更加提高光碟之記錄密度。於此情況，通 常於不同之記錄層與記錄層之間設置中間層。 作為介紹相關中間層之技術之文獻，有如專利文獻工。 於該專利文獻1中，使形成於樹脂壓模101之導向溝中 312ΧΡ/發明說明書(補件)/96-06/96111269 5 200814050 之樹脂材料AHM(硬化後之樹脂材料A，於該文獻之圖4 中表不為2〇4)硬化。繼而’將積層有樹脂材料a綱 脂壓模與第1基盤⑴，以屬於薄片狀黏著材之樹脂材料 謂5予以貼合。其後，_樹脂壓模。並且揭示有如下 要點.較佳係樹脂材料A為與壓模之接黏力弱者，考慮到 1自樹㈣料A㈣之方面’亦可龍模實 之處理。 2003-203402號公報（段落 [專利文獻1]曰本專利特開 籲[0020]〜[0027]，圖 3、圖 5) 【發明内容】 (發明所欲解決之問題） 然而，根據本發明者之研究，於專利文獻丨之方法中， 判明了將有壓模（更具體而言為樹脂壓模）與樹脂材料 A+(轉印層）無法良好地剝離之情況。特別判明了，若於應 模使用如聚碳酸醋之極性高之材料（與轉印層之接黏力變 籲大之材料），則難以進行良好剝離。 本發明係#於上述課題而成者。即，本發明之目的在於 提供一種於製造具備具有凹凸形狀之中間層之光記錄媒 體時，壓模與轉印層可良好進行剝離的光記錄媒體之製造 方法及製造裝置。 (解決問題之手段） #鑒於上述實情，本發明者進行潛心研究，結果發現，可 藉由改善形成於麼模上之紫外線硬化性樹月旨膜之硬化方 法，而改良壓模與轉印層之剝離。具體而言，首先，對形 312XP/發明說明書(補件)/96-06/96111269 6 200814050 卜於^上之紫外線硬化性樹麟照射紫外線，使其半硬 線石#降低氧漠度之環境中’照射紫外線’使紫外 pm” /月曰膜進—步硬化而形成轉印層。發玉見可藉此改 良㈣與轉印層之剝離，從而完成本發明。 即，本發明之t匕+ 具備於表面上具有:凸开種媒體之製造方S ’係 中間層者;其特徵為Γ有二 間層及轉印層的 製造步驟，係心:有L有下四個步驟··第1記錄媒體 壓模!^迭牛驟又：;、有基板之第1記錄媒體；轉印層積層 •:广步知’其係於表面具有對應中間層之凹凸形狀之 膜，卜凸绫形狀的壓模表面上設置紫外線硬化性樹脂 樹脂膜2'1=性樹脂膜照射紫外線’使紫外線硬化性 使f外線硬彳丄:於減少氧濃度之環境中，照射紫外線而 =外：硬化性樹腊膜進一步硬化，藉此形 媒體之間存在下中間= 筮1打拉m _ 丧口轉印層積層壓模盥 剝離步驟，其係自轉印層剝離屬模。、 处’父佳係於帛1記錄媒體製造步驟中，藉 ί形於成 =錄再生功能層而製造第1記錄媒體^接合㈣ ;轉印層與記錄再生功能層之間存在下 Μ 乂 下，接合轉印層積層壓模與第1記錄媒體。Β" 又’較佳係於第1記錄媒體製造步驟中， 形成複數個記錄再生功能層而製 丨 拔；土反上 步驟中，於轉印層與距離基板最位^於接合 層之間存在下中間層的狀態下，接合轉二積::模生:第能 312ΧΡ/發明說明書(補件)/96·〇6/961丨1269 200814050 1記錄媒體。 此處，較佳係紫外線硬化性樹脂膜之半硬化， 氧之環境中進行紫外線照射。 ；子 =，作為減少氧濃度之環境，較佳為氮環境。 繼而’較佳係於第1記錄 采成於Μ， 步驟中，下申間層為 I成於弟1記錄媒體上。 又 平父住係於減壓環境中進行接合步驟。 此處’較㈣於接合步射，將硬化性樹脂塗佈於第工 δ己錄媒體上後，以硬化性樹脂與轉印層相對面之方式 轉印層積層屢模載置於硬化性樹脂上 脂’藉此形成下中間層。 更化拴树 又’作為硬化性樹脂，較佳為紫外線硬純樹脂。 進而較佳係於大氣中進行接合步驟。 又，較佳係壓模為聚碳酸酯系樹脂製。 又，較佳係自轉印層剝離壓模後，於轉印層上形成上部 _記錄再生功能層。 此處’較佳係記錄再生功能層中，為自基板侧依序設置 反射層及記錄層。 進而，根據本發明將提供一種光記錄媒體之製造裝置， γ係用以製造具備於表面上具有凹凸形狀且具有下中間 層^轉印層之中間層的光記錄媒體者；其特徵為具有如下 手段·、第一硬化手段，其係於表面上具有對應中間層之凹 凸狀之轉印用凹凸形狀的壓模表面上設置紫外線硬化 陡树知膜，對紫外線硬化性樹脂膜照射紫外線，使紫外線 312XP/發明說明書(補件)/96·〇6/96111269 200814050 硬化性樹脂膜半硬化；第二硬化手段，其係於降低氧濃度 之環境中照射紫外線，使紫外線硬化性樹脂臈進一步ς 化，藉此形成轉印層。 ， 再者，紫外線硬化性樹脂膜是否半硬化，例如，可以紫 外線硬化性樹脂膜之硬化程度來判斷。具體而言，可藉由 紅=分光光度計（IR)進行測定而對殘存雙鍵之比例進行大 致定量。殘存雙鍵之比例，可於設置於壓模上之紫外線硬 化j樹脂膜之表面硬化前後進行紅外分光測定，並算出硬 化前後之雙鍵#之比率而獲得。因此，例如，作^硬化 之狀態’可列舉如：設於壓模上之紫外線硬化性樹脂膜之 表面經半硬化處理後之硬化度（硬化前後之雙鍵量之比率） 為50%以下之情況。 另一方面，作為定性判斷紫外線硬化性樹脂膜是否半硬 =之方法之一，可列舉如，於進行半硬化處理後，設於壓 模上之紫外線硬化性樹脂膜之表面具有黏性之狀態。具體 =言，可列舉，於進行半硬化處理後，用手指觸碰設於壓 模上之紫外線硬化性樹脂膜表面時，感到黏溶之狀態。 又所明降低氧濃度之環境，具體而言係指氧濃度為 5%以下之環境。 (發明效果） 根據本發明，提供一種壓模與轉印層之剝離性經改良之 生產效率高的製造方法。 【實施方式】 以下，本發明以藍光光碟等膜 面入射型媒體構成為中心 312XP/發明說明書(補件)/96-06/96111269 9 200814050 進仃詳細說明，但本發明並不侷限於以下說明，可於其主 旨範圍内加以各種變更而實施。 1 ·製造方法 具備於表面上具有凹凸形狀、且具有下中間層及轉印層 之中間層的光記錄媒體之製造方法，係具有以下步驟。 0)第1記錄媒體製造步驟，其獲得具有基板之第1 媒體。 σ _ 轉印層積層壓模製造步驟，其係於表面上具有對應中 間層之凹凸形狀之轉印用凹凸形狀之壓模表面上設置紫 外線硬化性樹脂膜，對紫外線硬化性樹脂膜照射紫外線， 使该紫外線硬化性樹脂膜半硬化後，於減少氧濃度之環境 :照射紫外線，使上述紫外線硬化性樹脂膜進一步硬化， 藉此形成轉印層而獲得轉印層積層壓模。 (3)接合步驟，以轉印層與第丨記錄媒體之間存在下中間 層之狀態，接合轉印層積層壓模與第1記錄媒體。 • (4)剝離步驟，自轉印層剝離壓模。 又本么明中，作為上述（i)之第丨記錄媒體製造步驟中 所得之第1記錄媒體，可考慮以下3種態樣。 (i )僅具有基板之態樣 (ii)基板上具有記錄再生功能層之態樣（記錄再生功能 層為1層之態樣） (m)基板上具有複數個記錄再生功能層之態樣 該等之中，於（I)態樣中，係於基板上形成具有凹凸形 狀之中間層，故無需預先於基板上設置凹凸形狀。另一方 312XP/發明說明書(補件)/96·06/96111269 10 200814050 面於（ii)及(m)態樣中，係於基板上設置i個或複數個 。己錄再生功能層，故較佳係預先於基板表面設置凹凸形 "再者，於上述(I )、（丨Ί)、（I丨丨）之任一態樣中，中間層之 处成係基本上使用同種方法。因而，首先使用上述（丨丨·）之 二樣對本發明中使用之光記錄媒體之製造方法進行具體 况明。其後，對第1記錄媒體中使用上述⑴、（i之熊 樣的情況進行說明。 . I -1.使用具有1層記錄再生功能層之第1記錄媒體之情況 本實施形態中，作為第1記錄媒體，係使用基板上形成 有n己錄再生功能層者。於使用如此之第丨記錄媒體而獲得 具備表面具有凹凸形狀、且具有下中間層及轉印層之中間 層的光記錄媒體之情況，可根據於哪個階段使下中間層存 在，而分為下述兩個製造方法。第丨製造方法為於第}記 錄媒體製造步驟中形成下中間層之情況。又，第2製造方 法為於接合步驟中形成下中間層之情況。以下分別對各個 製造方法進行詳細說明。 Α·第1製造方法 本實施形態中，於第i記錄媒體製造步驟中，係於記錄 再生功能層上形成下中間層。 圖1及圖2係用以說明應用本實施形態之光記錄媒體之 製造方法之較佳例的示意剖面圖。具體而言，圖〗及圖2 中，圖1(a)表示對應上述（1)〜（4)各步驟中之上述步驟（ι) 的一例，圖1(b)表示對應上述（1)〜（4)各步驟中之上述步 312XP/發明說明書(補件)/96-06/96111269 11 200814050 驟(2)的一例。又，繼圖卜圖2中之圖2(c)對應上述步驟 (3) ’圖2⑷對應上述步驟（4)。再者，通常光記錄媒體為 圓盤狀：且於中心處形成中孔，但圖i及圖2中則省略中 孔之揭示同樣地’通常壓模為圓盤狀，且於中心處形成 中孔’但圖1及圖2中則省略中孔之揭示。 說明各圖式之概略。 圖i(a)中，表不於表面具有凹凸形狀之基板丨上具有記 錄再生功施層2的第i記錄媒體1〇〇。並且，於第}記錄 媒體100上形成下中間層3。 、 圖1(b)中，矣+ · #上 ”“衣不·對表面上設置有紫外線硬化性樹脂膜 5之壓;照射紫外線uv，使紫外線硬化性樹脂膜$半 二：之：驟(b - 1);與作為減少氧濃度之環境之一例，於 ίΥΡ6 atm〇Sphere>T^^ u V，使紫外線硬化性谢护赠 f树知膜5進一步硬化而獲得轉印層6 之乂驟(卜2):經該等步驟而形成轉印層積層壓模綱。 體錄^接二步驟’其係以轉印層6與第1記錄媒 入隸u Γ ▲層2)之間存在下中間層3之狀態，接 :轉印f積層壓模200與第1記錄媒請。具體而言 表不4印層6與下中間層3相對面之方式，於 3上載置轉印層積層壓模2〇〇 . ^ 間層3與轉印層6之步驟(c—f驟卜1)’與接黏下中 :(:二4表示自轉印層6剝離壓模4的剝離步驟。藉 甶剝離壓杈4，而形成中間層7。 再者’對於錢式+之共職成要素，係使關-符號 312XP/發明說明書(補件)/96-06/96111269 12 200814050 邊對上述各步驟進 表示。以下’ -邊參照圖1及圖2 行更詳細的說明。 (!)獲得第1記錄媒體100之步驟 圖1(a)係用以說_货 _示，第"二= 彔 再生功能層2而择得/〇係猎由於基板1上形成記錄 步設置下中間層3 於第1記錄媒體刚上進一 [1 ·基板] 作為基板1之材粗 膠、金屬、玻璃等。有適度加工性與剛性之塑 透明性或雙二制則對於對記錄·再生用雷射光之 況，如下之方; 用作美柘夕从细 ，、體而$，係於將金屬或玻璃 硬化㈣樹脂層之:二其冓表面設置光硬化性或熱 導向溝於製=。而同時形成基板1之形狀與表面之 中所使：ί型之塑膠材料，可使用習知於cd或dvd 環氧樹脂等刪酷樹脂、聚烯烴樹脂、丙烯酸系樹脂、 上基’通常，較佳為Μ mm以 i.2 mm以下之範圍。 基板1上，通常形成循軌用之導向溝（例如，參照圖⑼ 騰/發明_書(補件)/96-_61麵 13 200814050 心圓狀導向溝通常係於基板1上設置為同 再生中= m導向溝之執距因光記錄媒體之記錄 =中所使用之雷射光之波長不同而不同。具體而言，cd 糸錄媒體中’執距通常為1.5阳以上，h6叫以下。 DVD系光記錄媒體中，執 _ 、吊為 〇·7 Mm 以上，〇·8 /im 皿色田射用光記錄媒體中，執距通常為U醉以 上，〇·6 /un以下。 +私止面4之*度亦因光記錄媒體之記錄再生中所用 體中，瀵wm: CD系光記錄媒 體中/冓冰度通常為10nm以上，3〇〇nm以下。勵系 ，錄媒體中，溝深度通常為1〇nm以上，2〇〇·以下。 監色雷射用光記錄媒體中，溝深度通常為1()咖以上，· nm以下。 =者，圖！⑷中雖未圖示，作為基板卜通常係使用中 I 環狀者狀無特別限制，可考慮圓盤 橢圓狀、多邊形等各種形狀。其中，基板i通常為圓 盤狀。於此情況，基板1之直徑通常設為肋瓜爪或i 左右。 [2·記錄再生功能層] 首先，如圖1(a)所示，於上述基板j上形成可藉由光進 行記錄或再生之記錄再生功能層2。 記錄再生功能層2係以可記錄再生或可再生資訊信號 之方式而構成的層，可為單層亦可具有多層。記錄再生2 能層2中，可根據光記錄媒體為再生專用之媒體 312XP/發明說明書(補件)/96-06/96111269 14 200814050 體）之隋况、為僅可記錄一次之一次寫入型媒體 CW媒體)之情況、可反覆進行記錄消去之可重寫』媒體 (Rewritable媒體）之情況，採用對應各個目的之層構成。 又，記錄再生功能層2係可根據記錄•再生用雷射光之入 射方向，分為基板面入射型與膜面入射型。本發明中，就 -藍色雷射之使用與高密度記錄方面而言，較佳為使用膜面 •入射型記錄再生功能層2。因此’以下說明中，作為記錄 再生功能層2之一例，係針對使用膜面入射型之構成的 響形進行說明。 (再生專用媒體之例） 再生專用媒體中，所謂記錄再生功能層2，通常係指於 具有設為同心圓或螺旋狀之預製凹坑之基板上所設置之 反射層。作為反射層之材料，通常使用入卜Ag、/u等金 屬或合金。記錄再生功能層2可藉由以濺鍍法將 Au反射層成膜於基板上形成反射層而獲得。 馨（一次寫入型媒體之例1} 一次寫人型媒體中之膜面人射型媒體t，所謂記錄再生 功能層2通常係指設於基板上之至少具有記錄層之單層 或多層構造。具體而言，通常以反射層及記錄層之順序^ 置。進而’可於記錄層上下之至少一邊設置含有無機材‘ (，例如’金屬或半導體之氧化物、氮化物、碳化物談 等=混合物；進而加與⑽之混合物等）之緩衝層。= =況，反射層、記錄層、及缓衝層將成為記料生功能 312ΧΡ/發明說明書(補件)/96·〇6/96111269 15 200814050 作為反射層之材料，通常可使用A1、Ag、Au等金屬或 合金。反射層之形成方法，可與再生專用媒體相同。又， 緩衝層通常以濺鍍法形成。 作為上述一次寫入型媒體中之記錄層材料，通常使用有 機色素。作為上述有機色素，可列舉：巨環狀氮雜輪烯 .(azaammlene)系色素（酞青色素、萘酞青色素、卟啉色素 .等）、聚次曱基系色素（花青色素、部花青色素、方酸青色 素等）、蒽醌系色素、奠鏽（azlenium)系色素、含金屬偶氮 系色素、含金屬吲哚苯胺（ind〇aniline)系色素等。特別是 含金^偶氮系色素因具有耐久性優異之傾向故而較佳。 於藉由有機色素形成記錄層之情況，通常以塗佈方法形 ΐ。作為塗佈方法，可列舉：湘將有機色素溶解於適當 中而成之/谷液所進行的旋塗法、喷塗法、浸塗法 塗法等。此時，作為溶劑，通常使用二丙闕醇、3•經基* 甲基-2-丁嗣等酮醇溶劑，甲基 蘇溶劑，四氟丙n 土脊I禾4赛路 ，、虱戊醇等王氟烷醇溶劑，乳酸甲酯、 異丁酸甲酯等羥基乙基溶劑。 記錄層之厚度，因却棘 ^ n 、，卜 α、彔方法不同，所適合之膜厚亦有所 口，亚…特別限制，為獲^ ^ ^ ^ 以上，較佳為5nm以上度’通吊為 ^ 尤佳為10 nm以上。JL中，钟 Λ , 汞θ之；度通常為1 μιη以下，較佳為 0.5/m以下，更佳為i〇〇nm以下。 車仏為 (一次寫入型媒體之例2) 一次寫入型媒體中 <馭面入射型媒體之其他具體例 3_發明說明書(補件)/9_6111269 16 200814050 中，所謂記錄再生功能層2通常係指設置於基板上之反射 層、電介質層、記錄層、及電介質層。 作為反射層之材料，通常係使用Al、Ag、Au等金屬或 合金。反射層之形成方法與再生專用媒體相同。 作為電介質層之材料，通常係使用無機材料（代表性者 、 為ZnS/Si02或GeCrN)。電介質層之膜厚通常為0.5|1111以 . 上，又，通常為50 nm以下。電介質層可視需要予以積層 複數層不同之無機材料而形成（例如，可為ZnS/Si02層及 ⑩GeCrN層之積層構造）。電介質層通常藉由濺鍍而形成。 記錄層，通常使用無機材料膜（例如，如Ge · Te、Ge · Sb · Te之硫系合金膜，Si/Ge、Al/Sb等2層膜，BiGeN、 SnNbN等（部分）氮化膜，TeOx、BiFOx等（部分)氧化膜）。 記錄層之膜厚通常為1 nm以上，較佳2 nm以上。又，記 錄層之膜厚通常為50 nm以下，較佳20 nm以下。記錄層 通常藉由濺鍍而形成。 φ (可重寫型媒體之例1) 可重寫型媒體中之膜面入射型之媒體中，所謂記錄再生 _ 功能層2通常係指設於基板上之反射層、電介質層、記錄 層、及電介質層。 作為反射層、電介質層、及記錄層，可與上述「一次寫 入型媒體之例2」相同。但，記錄層必須為可雙向進行記 錄•消去之材料。作為如此之材料，例如可列舉SbTe系、 GeTe 系、GeSbTe 系、InSbTe 系、AgSbTe 系、AglnSbTe 系、GeSb 系、GeSbSn 系、InGeSbTe 系、InGeSbSnTe 系 312XP/發明說明書(補件)/96-06/96111269 17 200814050 專材料。 (可重寫型媒體之例2) ^為可重寫型媒體之其他具體例，可列 (MO磁碟）。 [3·下中間層] 峰=愿如圖1⑷所不’於上述第1記錄媒體100(記錄再 3，係^成下中^層^本發明中，所謂下中間層 I r . ' 9 〃、 g」之形態者。例如，以液體狀或黏性體 (:=)狀樹脂材料形成下中間層3時，無論該樹脂材料 疋否乾_或硬化，若具有「層」之形態便成為「下 3 J 〇 再者，記錄再生功能層2與中 ._ 要存在其他層。 卜甲間層3之間，亦可視需 使使用之材料無特別限制。工業方面，通常 庐作兔曰涵；作為樹脂材料，更具體可列舉硬化性樹 脂。作Λ放射^料中’工業上較佳者為放射線硬化性樹 而硬=::線::性樹脂，可列 硬化性樹脂。—慮到工業生產性’較佳為使用紫外線 ::間層3通常期望具有以.下3種性質。 透光性至記錄再生功能層2之雷射光的 材料。此;t :、f可確保對上述雷射光之充分透明性的 免於適用本實施形態之光記錄媒體中，所謂厂透 312XP/發明說明書(補件)/96_〇6軸】汹 18 200814050 光性（或透明）」，係指對照射記錄再生功能層2之雷射光之 :匕八有充刀牙匕性。所謂「透光性（或透明）」，具體而言， 係^對用以§己錄·再生之光波長（例如，彻細）通常具有 来乂上較佳80〇/〇以上、更佳90%以上之穿透性。再者， ^光性之上限，理想者為100%。 第二，為了抑制光記錄媒體整體之翹曲，較佳係使用羊 ，或收縮率小之材料。如下所述，為了改良轉印性或於： _印層上形成之記錄再生功能層之記錄特性，作為轉印層中 使用之紫外線硬化性樹脂，將有使用收縮率大之材料之情 況。於此情況下，光記錄媒體整體具有易於翹曲之傾向。 因此，較佳係下中間層3中使用常溫下之彈性率小之樹脂 (具有柔軟性質之樹脂）或收縮率小之樹脂。 更具體而言，為了更加良好地抑制光記錄媒體整體翹 曲，下中間層3中所使用之樹脂，較佳為使用常溫下之彈 性率小且收縮率小之樹脂。 _ 考慮到上述觀點，下中間層3中使用之樹脂於3〇°C下 之彈性率，通常為150〇 MPa以下，較佳1300 MPa以下， 更佳700 MPa以下，再更佳080 MPa以下，尤佳650 MPa 以下。若30¾下之彈性率於上述範圍内，則可有效抑制 形成下中間層3時所產生之基板i之翹曲。 另一方面’下中間層3中所使用之樹脂於3〇。匸下之彈 性率，實際上為40 MPa以上。再者，所謂彈性率，係指 以通系之動恕黏彈性測定機所測定之動態彈性率。 又，下中間層3中使用之樹脂之收縮率，通常為4%以 312XP/發明說明書(補件)/96-06/96111269 19 200814050 下，較佳3·5〇/〇以下，更佳3%以下。若下中間層3中使用 之樹脂收縮率於上述範圍内，則可有效抑制基板丨之翹 曲。其中，收縮率理想的是為〇%。此處，所謂收縮率，In recent years, optical recording media such as CD-R, CD-RW, D VD-R, and rewritable d VD (hereinafter sometimes referred to as "disc") require higher recording density. As means for increasing the capacity of the above-mentioned optical disk, there is a method of providing two or more recording layers. In the case where two or more recording layers are provided, an intermediate layer is usually provided between the recording layer and the recording layer. On the other hand, on the reflective layer provided on the substrate, or on the reflective layer and the recording layer, the next-generation high-density optical disk having a coating layer having a thickness of 0.1 mm is also put into practical use (Blu-ray Disk). , Ultra Density Optical (UDO, Ultra-Density Optical), etc.). In the high-density optical discs, the blue-violet laser light is condensed by an objective lens having a high NA (numerical aperture, for example, 〇85), and the condensed laser light is irradiated from the side of the coating layer to perform information. Recording and/or regeneration of signals. The above-mentioned optical disc is called a film-faced type optical disc. For these film-faced optical discs, two or more recording layers are also provided, and an attempt is made to further increase the recording density of the optical disc. In this case, an intermediate layer is usually provided between different recording layers and recording layers. As a document introducing the technology of the relevant intermediate layer, it is like a patent document. In the patent document 1, the resin material AHM (hardened resin material A) formed in the guide groove of the resin stamper 101, 312 ΧΡ / invention specification (supplement) / 96-06/96111269 5 200814050, is used in the literature. The table in Figure 4 is not 2〇4) hardened. Then, the resin material a template and the first substrate (1) are laminated, and the resin material belonging to the sheet-like adhesive material is bonded to each other. Thereafter, the resin was molded. Further, it is revealed that the resin material A is preferably weak in adhesion to the stamper, and it is considered that the self-tree (four) material A (four) can be processed by the dragon mold. Japanese Patent Publication No. 2003-203402 (Paragraph [Patent Document 1] pp. Patent Application [0020] to [0027], Fig. 3, Fig. 5) [Disclosure of the Invention] However, according to the present inventors In the case of the method of the patent document, it was found that a stamper (more specifically, a resin stamper) and a resin material A+ (transfer layer) could not be peeled off favorably. In particular, it has been found that if a material having a high polarity such as polycarbonate (a material having a large adhesion to the transfer layer) is used in a mold, it is difficult to perform good peeling. The present invention is a subject of the above problems. In other words, an object of the present invention is to provide a method and a device for producing an optical recording medium in which a stamper and a transfer layer can be easily peeled off when an optical recording medium having an intermediate layer having an uneven shape is produced. (Means for Solving the Problem) # In view of the above facts, the present inventors conducted intensive studies and found that the stamper and the transfer layer can be improved by improving the hardening method of the ultraviolet curable resin film formed on the mold. Stripping. Specifically, first, the shape of the 312XP/invention specification (supplement)/96-06/96111269 6 200814050 is applied to the UV-curable cypress to irradiate the ultraviolet rays to make the semi-hardline stone reduce the environment of oxygen inversion. The 'irradiation ultraviolet ray' causes the ultraviolet pm" / ruthenium film to be hardened to form a transfer layer. This can be used to improve (4) the peeling of the transfer layer, thereby completing the present invention. + It has a manufacturing layer S'-based intermediate layer on the surface: it is characterized by the manufacturing steps of the two layers and the transfer layer, and the core: there are four steps in the next step. 1 recording medium stamper! ^ 牛 骤 又 ; ; ; ; ; ; ; ; ; ; ; ; 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第The ultraviolet curable resin resin film 2'1=the resin film is irradiated with ultraviolet rays on the surface of the stamper. The ultraviolet curability is made to make the outer line hard. In the environment where the oxygen concentration is reduced, the ultraviolet rays are irradiated and the outer: hardening tree The wax film is further hardened, whereby there is a lower middle between the shaped media = 筮1 pull m _ 丧 转印 转印 层 层压 盥 盥 盥 盥 盥 盥 盥 盥 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父 父The first recording medium is bonded to the first recording medium. The transfer layer and the recording/reproducing functional layer are provided with a lower layer, and the transfer layer laminated mold and the first recording medium are bonded to each other. Β" In the step, a plurality of recording and reproducing functional layers are formed to form a plucking; in the reverse step, in the state in which the lower intermediate layer exists between the transfer layer and the most adjacent layer of the substrate, the second product is joined: Molding: No. 312ΧΡ/Invention Manual (Supplement)/96·〇6/961丨1269 200814050 1 Recording medium. Here, it is preferable to perform semi-hardening of the ultraviolet curable resin film, and to irradiate ultraviolet rays in an oxygen atmosphere. ; sub =, as an environment to reduce the oxygen concentration, preferably a nitrogen environment. Then 'preferably in the first record is collected in the Μ, in the step, the lower inter-layer is I Cheng on the 1 recording medium. The parental residence is engaged in a decompression environment. Here, 'more (four) After the bonding step, the curable resin is applied onto the δ-recorded medium, and the laminated layer is transferred to the curable resin by the surface of the curable resin opposite to the transfer layer. The lower intermediate layer. The eucalyptus is also made of a curable resin, preferably an ultraviolet hard resin. Further, it is preferably a bonding step in the air. Further, the stamper is preferably made of a polycarbonate resin. Preferably, after the stamper is peeled off from the transfer layer, an upper recording/reproducing functional layer is formed on the transfer layer. Here, in the recording/reproducing functional layer, a reflective layer and a recording layer are sequentially provided from the substrate side. Further, according to the present invention, there is provided an apparatus for manufacturing an optical recording medium, wherein γ is used for manufacturing an optical recording medium having an intermediate layer having a concave-convex shape on a surface and having a lower intermediate layer transfer layer; And a first curing means for providing a UV-curable resin film on a surface of a stamper having a concave-convex shape for transfer which has a concave-convex shape corresponding to an intermediate layer, and irradiating the ultraviolet curable resin film External line, UV 312XP / invention manual (supplement) / 96 · 〇 6 / 9611269 200814050 semi-hardening of the curable resin film; second hardening means, which is irradiated with ultraviolet rays in an environment where the oxygen concentration is lowered, so that the ultraviolet curable resin 臈Further, the transfer layer is formed by further deuteration. Further, whether or not the ultraviolet curable resin film is semi-cured can be determined, for example, by the degree of hardening of the ultraviolet curable resin film. Specifically, the ratio of the remaining double bonds can be roughly quantified by measurement using a red = spectrophotometer (IR). The ratio of the remaining double bonds can be obtained by performing infrared spectrometry before and after hardening of the surface of the ultraviolet ray hardened resin film provided on the stamper, and calculating the ratio of the double bonds # before and after hardening. For example, the degree of hardening (the ratio of the amount of double bonds before and after hardening) of the surface of the ultraviolet curable resin film provided on the stamper after the semi-hardening treatment is 50% or less. Happening. On the other hand, as one of the methods for qualitatively determining whether or not the ultraviolet curable resin film is semi-hardened, the surface of the ultraviolet curable resin film provided on the stamper is viscous after the semi-hardening treatment. . Specifically, when the surface of the ultraviolet curable resin film provided on the stamper is touched with a finger after the semi-hardening treatment, the state of stickiness is felt. Further, the environment for reducing the oxygen concentration is specifically an environment having an oxygen concentration of 5% or less. (Effect of the Invention) According to the present invention, there is provided a production method in which the peeling property of a stamper and a transfer layer is improved and the production efficiency is high. [Embodiment] Hereinafter, the present invention is described in detail with respect to a film surface incident type medium such as a Blu-ray disc or the like. 312XP/Invention Manual (Supplement)/96-06/96111269 9 200814050, but the present invention is not limited to the following description. It can be implemented with various changes within the scope of its subject matter. 1. Manufacturing method A method of producing an optical recording medium having an uneven layer on the surface and having an intermediate layer of a lower intermediate layer and a transfer layer has the following steps. 0) A first recording medium manufacturing step of obtaining a first medium having a substrate. a σ _ transfer layer laminated mold manufacturing step in which an ultraviolet curable resin film is provided on a surface of a stamper having a concave-convex shape for transfer having a concave-convex shape corresponding to the intermediate layer, and the ultraviolet curable resin film is irradiated with ultraviolet rays. After the ultraviolet curable resin film is semi-hardened, the ultraviolet curable resin film is further cured by irradiating ultraviolet rays in an environment where the oxygen concentration is reduced, whereby a transfer layer is formed to obtain a transfer laminated laminating mold. (3) The bonding step of bonding the transfer laminated lamination mold to the first recording medium in a state where the lower intermediate layer exists between the transfer layer and the second recording medium. • (4) Peeling step, peeling the stamper from the transfer layer. Further, in the present invention, as the first recording medium obtained in the above-described (i) recording medium manufacturing step, the following three aspects can be considered. (i) a state having only a substrate (ii) a state in which a recording and reproducing functional layer is provided on the substrate (a state in which the recording and reproducing functional layer is one layer) (m) a state in which a plurality of recording and reproducing functional layers are provided on the substrate In the (I) aspect, since the intermediate layer having the uneven shape is formed on the substrate, it is not necessary to provide the uneven shape on the substrate in advance. The other side 312XP/Invention Manual (Supplement)/96·06/96111269 10 200814050 In the (ii) and (m) aspects, i or a plurality of sheets are arranged on the substrate. Since the reproduction function layer has been recorded, it is preferable to provide a concavo-convex shape on the surface of the substrate in advance. Further, in any of the above (I), (丨Ί), (I丨丨), the intermediate layer is formed. The same method is basically used. Therefore, the manufacturing method of the optical recording medium used in the present invention will first be specifically described using the above (丨丨·). In the case where the first recording medium of the above (1) and (i) is used in the first recording medium, the case where the first recording medium having the one-layer recording/reproduction functional layer is used is used as the first embodiment. (1) A recording medium in which an n-recording/reproducing functional layer is formed on a substrate, and an optical recording medium having an intermediate layer having a concave-convex shape on the surface and having a lower intermediate layer and a transfer layer is obtained by using such a second recording medium. In the case where the lower intermediate layer is present at any stage, it can be divided into the following two manufacturing methods. The second manufacturing method is a case where the lower intermediate layer is formed in the recording medium manufacturing step. Further, the second manufacturing method In order to form the lower intermediate layer in the bonding step, each of the manufacturing methods will be described in detail below. Α·First Manufacturing Method In the present embodiment, in the i-th recording medium manufacturing step, the recording layer is formed on the recording and reproducing functional layer. 1 and 2 are schematic cross-sectional views for explaining a preferred example of a method of manufacturing an optical recording medium to which the present embodiment is applied. Specifically, in Fig. 2 and Fig. 2, Fig. 1(a) shows an example of the above step (1) in the respective steps (1) to (4), and Fig. 1(b) shows the above step 312XP/ in the respective steps (1) to (4). BRIEF DESCRIPTION OF THE INVENTION (Supplement) /96-06/96111269 11 200814050 An example of the step (2). Further, FIG. 2(c) in FIG. 2 corresponds to the above step (3). FIG. 2(4) corresponds to the above step (4). Further, in general, the optical recording medium has a disk shape: a mesopores are formed at the center, but the disclosure of the mesopores is omitted in FIGS. i and 2, similarly, 'the normal stamper is disk-shaped and formed at the center. In the middle hole, the disclosure of the mesopores is omitted in Fig. 1 and Fig. 2. The outline of each figure is illustrated. In Fig. i(a), the substrate having the uneven shape on the surface has a recording and reproducing work layer 2 thereon. The i-th recording medium is 1 并且. Further, the lower intermediate layer 3 is formed on the recording medium 100. In Fig. 1(b), 矣+·#上”“衣衣· is provided with ultraviolet curable resin on the surface. The pressure of the film 5; the ultraviolet uv is irradiated to make the ultraviolet curable resin film $1/2: which is the step (b-1); and as an example of the environment for reducing the oxygen concentration, at ΥΡ6 atm〇Sphere >T^^ u V, a step of obtaining the transfer layer 6 by further curing the ultraviolet curable protective film 5 (b): a transfer layer lamination mold is formed through the steps. The second recording step is performed in a state in which the lower intermediate layer 3 exists between the transfer layer 6 and the first recording medium, and the transfer recording layer 6 and the first recording are carried out. Please. Specifically, in the manner of the opposite side of the 4th printed layer 6 and the lower intermediate layer 3, the transfer layer laminated mold 2 is placed on the layer 2, and the step of the interlayer layer 3 and the transfer layer 6 is carried out (c-f) 1) 'With the adhesive under: (: 2: 4 shows the peeling step of peeling the stamper 4 from the transfer layer 6. By peeling off the press 4, the intermediate layer 7 is formed. Further, for the money type + the joint job The elements are marked with the symbol - 312XP / invention manual (supplement) / 96-06 / 9611269 12 200814050. The following steps are described in the following paragraphs - (see below). The step of obtaining the first recording medium 100 is as follows: Figure 1 (a) is used to say that the _ _ _ _ _ _ _ 彔 彔 再生 再生 再生 再生 再生 再生 再生 再生 再生 再生 再生 再生 再生 再生3 When the first recording medium has just been inserted into a [1·substrate], it is used as the material of the substrate 1, such as rough rubber, metal, glass, etc. Plastic transparency with moderate processability and rigidity, or dual-system for laser light for recording and reproduction. In the case of the following, it is used as a fine, solid body, which is used to harden metal or glass (4) resin layer: photohardenability or thermal conductivity is set on the surface of the crucible The groove is formed. At the same time, the shape and surface of the substrate 1 are formed: a plastic material of the type: a conventional resin such as cd or dvd epoxy resin, a polyolefin resin, an acrylic resin, or the like can be used. The base 'usually, preferably Μ mm is in the range of i.2 mm or less. On the substrate 1, a guide groove for tracking is usually formed (for example, refer to the figure (9) Teng/Invention_Book (Supplement)/96-_61 face 13 200814050 The circular guide groove is usually set on the substrate 1 to be the same as the reproduction m = m guide groove, which is different depending on the wavelength of the laser light used in the recording of the optical recording medium. Specifically, cd 糸In the recording media, the distance is usually 1.5 or more, and h6 is called the following. In the DVD-based optical recording medium, the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The distance is usually U drunk, 〇·6 /un or less. +Personal stop 4 is also used in the recording and reproduction of optical recording media, 瀵wm: CD-based optical recording media / 冓 is usually 10 nm or more and 3 〇〇 nm or less. In the excitation system, the groove depth is usually 1 〇 nm or more, 2 〇〇 · or less. In the optical recording medium for color-adjusting lasers, the groove depth is usually 1 () or more, or less than nm. = =, although not shown in the figure (4), it is usually used as a substrate. The shape of the disk is usually elliptical or polygonal, and the substrate i is usually in the shape of a disk. In this case, the diameter of the substrate 1 is usually about rib claw or i. [2. Recording and reproducing functional layer] First, as shown in FIG. 1(a), a recording and reproducing functional layer 2 which can be recorded or reproduced by light is formed on the substrate j. The recording/reproducing functional layer 2 is a layer formed by recording or reproducing a reproducible information signal, and may be a single layer or a plurality of layers. In the recording/reproducing 2 energy layer 2, the optical recording medium can be used as a reproduction-only medium 312XP/invention specification (supplement)/96-06/96111269 14 200814050, which is a write-once type that can be recorded only once. In the case of media CW media, the rewritable media (Rewritable media) that can be repeatedly erased and erased is composed of layers corresponding to each purpose. Further, the recording/reproducing functional layer 2 can be classified into a substrate surface incident type and a film surface incident type in accordance with the direction in which the laser light for recording and reproducing is incident. In the present invention, it is preferable to use a film surface/incident type recording and reproducing functional layer 2 in terms of use of blue laser light and high density recording. Therefore, in the following description, as an example of the recording/reproducing functional layer 2, a shape using a film surface incident type will be described. (Example of reproduction-dedicated medium) In the reproduction-dedicated medium, the recording/reproducing functional layer 2 generally refers to a reflective layer provided on a substrate having pre-pits or concentric pits. As the material of the reflective layer, a metal or an alloy such as Ag or /u is usually used. The recording and reproducing functional layer 2 can be obtained by forming a reflective layer by sputtering a Au reflective layer on a substrate by sputtering. Xin (Example 1 of write-once type media) Writes the film-type human-type media t in a human-type medium at a time, and the recording-reproducing functional layer 2 generally refers to a single-layer or multi-layer structure having at least a recording layer provided on a substrate. Specifically, it is usually arranged in the order of the reflective layer and the recording layer. Further, 'the inorganic material can be provided on at least one side of the upper and lower sides of the recording layer (for example, 'metal or semiconductor oxide, nitride, carbide, etc. = Mixture; further add a buffer layer of (10), etc.) = = condition, the reflective layer, the recording layer, and the buffer layer will become the recording function 312 ΧΡ / invention manual (supplement) / 96 · 〇 6 / 9611269 15 200814050 As the material of the reflective layer, a metal or an alloy such as A1, Ag, Au, etc. can be used. The formation method of the reflective layer can be the same as that of the dedicated medium for reproduction. Further, the buffer layer is usually formed by sputtering. An organic dye is usually used as the recording layer material in the type of medium. Examples of the organic dye include azaammlene pigment (anthraquinone pigment, naphthoquinone pigment, porphyrin pigment, etc.). Poly-peptone-based pigments (cyanine pigment, merocyanine pigment, squaraine pigment, etc.), lanthanide pigments, azlenium pigments, metal-containing azo dyes, metal-containing anilides ( Ind〇aniline) is a dye, etc. In particular, a gold-containing azo-based dye is preferred because it has excellent durability. When a recording layer is formed of an organic dye, it is usually formed by a coating method. The method may be a spin coating method, a spray coating method, a dip coating method, or the like which is carried out by dissolving an organic pigment in an appropriate organic solvent. In this case, dipropanol is usually used as a solvent. 3• ketone alcohol solvent such as methyl * methyl-2-butanin, methyl sulfonate, tetrafluoropropane n ridge Ihe 4 race, pentyl alcohol and other fluoroalkanol solvents, methyl lactate, different A hydroxyethyl solvent such as methyl butyrate. The thickness of the recording layer, because of the different methods of the spine, n, and α, is suitable for the thickness of the film, especially for the limitation of the film, ^ ^ ^ ^ The above is preferably 5 nm or more, and the pass-through is preferably more than 10 nm. In JL, Zhong Rong, mercury θ; 1 μιη or less, preferably 0.5/m or less, more preferably i〇〇nm or less. The rut is (example 2 of write-once type media) in the write-once medium < other specific plane of the incident medium Example 3—Invention Manual (Supplement)/9_6111269 16 In 200814050, the recording/reproducing functional layer 2 generally refers to a reflective layer, a dielectric layer, a recording layer, and a dielectric layer provided on a substrate. A metal or an alloy such as Al, Ag, or Au is used. The method of forming the reflective layer is the same as that of the dedicated medium for reproduction. As the material of the dielectric layer, an inorganic material (typically, ZnS/SiO 2 or GeCrN) is usually used. The film thickness of the dielectric layer is usually 0.5|1111 or more, and is usually 50 nm or less. The dielectric layer may be formed by laminating a plurality of layers of inorganic materials (for example, a laminated structure of a ZnS/SiO 2 layer and a 10 GeCrN layer). The dielectric layer is typically formed by sputtering. As the recording layer, an inorganic material film (for example, a sulfur-based alloy film such as Ge · Te, Ge · Sb · Te, a two-layer film such as Si/Ge or Al/Sb, or a (partial) nitride film such as BiGeN or SnNbN, TeOx, BiFOx, etc. (partial) oxide film). The film thickness of the recording layer is usually 1 nm or more, preferably 2 nm or more. Further, the film thickness of the recording layer is usually 50 nm or less, preferably 20 nm or less. The recording layer is usually formed by sputtering. φ (Example 1 of rewritable medium) In the medium of the film surface incident type in the rewritable medium, the recording/reproduction layer 2 generally refers to a reflective layer, a dielectric layer, a recording layer, and a recording layer provided on the substrate. And dielectric layer. The reflective layer, the dielectric layer, and the recording layer can be the same as the above-described "Example 2 of the write-once type media". However, the recording layer must be a material that can be recorded and erased in both directions. Examples of such a material include SbTe, GeTe, GeSbTe, InSbTe, AgSbTe, AgInSbTe, GeSb, GeSbSn, InGeSbTe, InGeSbSnTe, 312XP/Invention (Supplement)/96-06/ 96111269 17 200814050 Special materials. (Example 2 of rewritable media) ^ Other specific examples of rewritable media can be listed (MO disk). [3. Lower middle layer] Peak = wishing to be in the above-mentioned first recording medium 100 as shown in Fig. 1 (4) (recording again 3, system ^ forming lower layer ^ in the present invention, the so-called lower intermediate layer I r . ' 9 〃 For example, when the lower intermediate layer 3 is formed of a liquid or a viscous (:=) resin material, whether or not the resin material is dry or hardened, if it has a "layer" form, "The next 3 J 〇 , 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Further, as the resin material, a curable resin is more specifically mentioned. In the case of radioactive materials, 'the industrially preferred one is a radiation curable tree and hard =:: a wire: a resin, a curable resin. - Industrial productivity 'preferably using ultraviolet light:: interlayer 3 is generally desired to have three properties. Light transmissive to the material of the laser light for recording and reproducing functional layer 2. This; t:, f can ensure the above-mentioned lightning In the optical recording medium of the present embodiment, which is sufficiently transparent to the light, the so-called factory 312XP/invention specification (补)) / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / Or transparently," specifically, the wavelength of light (for example, fine) used for § recording/regeneration is generally better than 80 〇 / 〇, more preferably 90% or more. Furthermore, the upper limit of the optical property is 100%. Secondly, in order to suppress the warpage of the optical recording medium as a whole, it is preferable to use a sheep or a material having a small shrinkage ratio as described below, in order to improve the transfer. Or the recording characteristics of the recording and reproducing functional layer formed on the printing layer, and the ultraviolet curable resin used in the transfer layer may be a material having a large shrinkage ratio. In this case, the entire optical recording medium is used. Therefore, it is preferable to use a resin having a small modulus of elasticity at normal temperature (a resin having a soft property) or a resin having a small shrinkage ratio in the lower intermediate layer 3. More specifically, in order to suppress more favorably The optical recording medium is warped as a whole, and is used in the lower intermediate layer 3. The resin is preferably a resin having a small modulus of elasticity at a normal temperature and a small shrinkage ratio. _ In view of the above, the modulus of elasticity of the resin used in the lower intermediate layer 3 at 3 ° C is usually 150 MPa or less. Preferably, it is 1300 MPa or less, more preferably 700 MPa or less, still more preferably 080 MPa or less, and particularly preferably 650 MPa or less. If the elastic modulus at 303⁄4 is within the above range, the formation of the lower intermediate layer 3 can be effectively suppressed. On the other hand, the resin used in the lower intermediate layer 3 is 3 〇. The elastic modulus of the underarm is actually 40 MPa or more. In addition, the elastic modulus refers to the movement of the system. The dynamic elastic modulus measured by the viscoelasticity measuring machine. Further, the shrinkage ratio of the resin used in the lower intermediate layer 3 is usually 4% to 312XP/invention specification (supplement)/96-06/96111269 19 200814050, preferably 3·5 〇/〇 or less, more preferably 3 %the following. When the resin shrinkage ratio used in the lower intermediate layer 3 is within the above range, the warpage of the substrate yoke can be effectively suppressed. Among them, the shrinkage rate is ideally 〇%. Here, the shrinkage rate,

係指藉由比重法所測定之收縮率。又，收縮率亦可 之K7H26」等進行測定。 稞JIS 第二，為了確保與轉印層6(以下詳述）之密著性，較佳 係於下中間層3中使用具有充分接黏性之材料。就確保與 轉印層6之密著性而言，可使用使轉印層6及下中間層^ 中使用之材料之種類一致（具體而言為紫外線硬化性樹 脂）、於下中間層3表面設置接黏層等方法。 又二圖1(a)中雖未圖示，本實施之形態中，下中間層3 可為早層構造’亦可為積層複數層之構造。作為積層複數 層之構造’藉由適當控制各層中所使用之樹脂種類 密控制下中間層3整體之彈性率或收縮率，將發揮容易= 步減少基板1之翹》曲之優點。 構成下中間層3之樹脂層數無特別限制。為了良好 制基板1之翹曲，樹脂層數通常設為1〇層以下， 二I':'4層以I:另一方面，樹脂層數係設為1層 ’、，就生產效率而言，構成下中間層3之樹产展 數較佳為1層以上’ 5層以下。就生產效率而言：： 下中間層3為1層構造。 土 ’、 下中間層3之膜厚無特別限制，可根據所用 體之種類，於岐範圍内予以選擇。例如，中門 厚通常為Ι5μπι以上，較佳2〇 ^馭 乃一方面，中間 312ΧΡ/發明說囑(補件)/96-06/96111269 20 200814050 層7之膜厚通常為8〇/lm以下，較佳以下。更具體 而言，於使用藍色雷射之藍光光碟（Blu—ray disk)^情 况中間層7之膜厚較佳為2〇 μηι以上，3〇辦以下。於 、 R可重舄型之情況，中間層7之膜厚，較佳 為〇 Mm以上，70 μηι以下。繼而，通常，下述之轉印層 1之膜厚大於〇 μΐΏ，且為20 μηΐ以下，故下中間層3之膜 厚為中間層7膜厚減去轉印層6膜厚之剩餘厚度。 以下、，對下中間層3中所使用樹脂材料之情況進行說 日^ =為樹月旨’例#，可列舉熱可塑性樹脂、熱硬化性樹 月曰、電子束硬化性樹脂、紫外線硬化性樹脂（包含延遲硬 化型）等。材料可自上述樹脂中適當選擇。 熱可塑性樹脂、熱硬化性樹料係通常轉於適當之溶 f中而製備成塗佈液。其後，塗佈該塗佈液，進行乾燥（加 熱），藉此可形成下中間層3。 紫外線硬化性樹脂通常可直接或者溶解於適當之溶 中而製備成塗佈液。豆德，淨欲# + 7士 ，饮，、後塗佈该塗佈液，照射紫外線而 使其硬化，藉此可形成下中間層3。 上述材料可單獨使用亦可混合使用。 、作為塗佈方法’可使用旋塗法或洗铸法等之塗佈法等方 法，其中’較佳為旋塗法。使用了高黏度樹脂之下中間層 3,亦可藉由網版印刷等而塗佈形成。 ς 脂使用赃〜4代下為液狀者，則就生產性而言= 使不使用溶劑亦易於進行塗佈’故而較佳。又，塗 黏度較佳係製備為20 MPa · s〜15〇〇 MPa · s之範圍。更 312Xp/發明說明書(補件)/96-06/96111269 21 200814050 佳係塗佈液之黏度設為1〇〇〇Mpa· S以下。 =者=1(a)t雖省略圖示，於基板】具有圓盤狀，並 在中心形成中孔時使料塗法㈣ 較佳係使用下述方法而开彡杰π士日日s ^Λ 、万/麦而形成下中間層3。即，於大於中孔 外徑之既定半徑位署由 ^ 中’將具有黏性之樹脂滴下成 (剛叫環狀而進行塗佈。繼而，較佳係於其後進行旋 塗。 作為樹脂材料’較佳係使用紫外線硬化性樹脂。紫外線 硬化性樹脂的透明度高，硬化時間短，於製造上有利故而 較佳。作為紫外線硬化性樹脂，可列舉自由基系紫外線硬 化性樹脂與陽離子系紫外線硬化性樹脂，可使用任一者。 陽離子系紫外線硬化性樹脂具有收縮率小之性質，故適 合用以減少光記錄媒體之翹曲。以下，針對自由基系紫外 線硬化性樹脂及陽離子系紫外線硬化性樹脂進行說明。 自由基系紫外線硬化性樹脂可使用含有紫外線硬化性 籲化合物與光聚合起始劑之組成物。作為紫外線硬化性化合 物，可使用單官能（甲基）丙烯酸酯及多官能（曱基）丙烯酸 酯作為聚合性單體成分。該等可分別單獨使用或並用2種 以上。此處，將丙烯酸酯與曱基丙烯酸酯一併稱為（曱基） 丙烯酸醋。 作為單官能（曱基）丙烯酸酯，例如，可具有甲基、乙基、 丙基、丁基、戊基、2-乙基己基、辛基、壬基、十二烧基、 十六烷基、十八烷基、環己基、苄基、曱氧基乙基、丁氧 基乙基、本氧基乙基、壬基苯氧基乙基、四氫糠基、縮水 312XP/發明說明書(補件)/96-06/96111269 22 200814050 甘油基、2-羥基乙基、2-羥基丙基、3-氯-2-羥基丙基、二 曱基胺乙基、二乙基胺乙基、壬基苯氧基乙基四氫糠基、 己内酯改質四氫糠基、異稻基、二環戊基、二環戍稀基、 一環戊烯氧基乙基等基作為取代基之（甲基）丙烯酸酯等。 作為多官能（曱基）丙烯酸酯，例如可列舉·· 二醇、 I4·丁二醇、i，5·戊二醇、3-甲基-1，5-戊二醇、1，6-己二醇、 新戊二醇、1，8_辛二醇、19·壬二醇、三環癸烷二甲醇、 乙二醇、聚乙二醇' 丙二醇、二丙二醇、三丙二醇、聚丙 一醇等之二（甲基）丙烯酸酯，三（2-羥基乙基）異三聚氰酸 醋之二（甲基）丙烯酸酯等。 又，可列舉··於1莫耳新戊二醇上加成4莫耳以上之環 氧乙院或環氧丙烧而獲得之二醇之二（甲基）㈣酸醋；於 1莫耳雙紛A上加成2莫耳之環氧乙烧或環氧丙燒而獲得 之二醇之二（甲基）丙烯酸酯；於！莫耳三經甲基丙燒上加 成一3莫耳以上之環氧乙烷或環氧丙烷而獲得之三醇之二 或„丙烯酸酯；於1莫耳雙酚A上加成4莫耳以： ^氧?：:戈環氧丙烷而獲得之二醇之二(甲基)丙烯酸 -曰，二羥甲基丙燒三⑽)丙烯酸酯；季戊四 季戊r醇之，丙婦酸酯；環氧乙烧： 婦酸醋等。土丙烯^醋，壤氧乙燒改質炫化磷酸（甲基）丙 ^ 合性翠體叫並肖料，作為聚合性 聚物，可列舉··聚酯 ，承口 f玍 醋、（甲a )而、二1 烯酸酯、聚醚(尹基)丙烯 312XP/發明說明書(補件)/96韻96ιι_ "、—夂核乳酯、（甲基）丙烯酸胺基f酸酯等。 23 200814050 ^而，於自由基系紫外線硬化性掛月旨中，通常可調配光 ^起始劑。作為光聚合起始齊 較佳係分子斷裂型或奪 虱型。如此之光聚合起始劑中，作為分子斷裂 列舉:安息香異頂、2,4_二乙基冬氧硫㈣、…： 二乳:其基、2,4,6_三甲基苯甲醯基二苯基氧化膦、 一 土 _ ·一甲土胺基咪啉苯基）_丁烷-1-嗣、雔Γ2 6--甲氧基苯甲酉藍基）_2,4,4-三甲基戊基氧化膦等。又， 進而’可並用！-羥基環己基苯基酮、安息香***、节美 一甲基、縮酮、2-經基_2_甲基小苯基丙燒+酉同显二 ί)笨2=基基丙炫相及2·甲基媒甲基硫苯 :可^舉笨3等。作為奪氯型光聚合起始劑，例 _ . 本暴一本基酮、間苯二甲酩贫 "rPh^ 又’可將增感劑與該等光聚合起始劑並用 二 劑，例如可列舉··三甲基胺、甲基二甲醇胺、-乙^ ^乙基胺基苯乙酉同、對二甲基胺基苯子酸乙西:^甲 =苯甲酸異戊醋、N，N•二甲基节基職： 基月女基）二苯基酮等。 ，又（一乙 作為陽離子系紫外線硬化性樹脂，例如， 離子艰合型光聚合起始劑之環氧樹脂。作气^陽 如，可列舉：雙龄A_表氯醇型、脂^ 月曰，例 =化環氧樹脂、縮水甘油醋型、縮I:油;Π 為: 312XP/發明說明書(補件)/96-06/96111269 氣之里較佳為】重量％以下，更佳0.5重 24 200814050 量％以下。 趟作：陽離子聚合型之光聚合起始劑，可列舉：銃鹽、鎭 。二鹽等：作為錤鹽，例如’可列舉··二苯基鎭鑌六 =外-夂風、二苯基錤鑌六氟銻酸鹽、二苯基鎭鑌六氣碼酸 二：，鐄鑌四(五氟苯基)硼酸鹽、雙(十二烷基苯基) 氟恤馱鹽、雙（十二烷基苯基）鎭鑌六氟銻酸鹽、雙 .(十苯基)鐫鑌六氟硼酸鹽、雙(十二烧基苯基)錤鑌 W (五氟本基）硼酸鹽等。 ，=可列舉：4_甲基苯基邻_甲基乙基）苯基鎖鐵六 Γ %，甲基苯基邻-甲基乙基)苯基鎭鑌六氣錄酸 ;二甲基苯基邻_甲基乙基）苯基鎖錯六氟刪酸鹽、4_ 笼土本基-4-(1_甲基乙基）苯基錤鑌四（五氟苯基）石朋酸 寻0 刑Γ _重量份之陽離子型紫外線硬化性樹脂的光聚合 2例，通常為0·1重量份〜20重量份，較佳的 =·里伤〜5重置份。再者，為了更有效地利用紫外 :源波長區域之近紫外區域或可見區域的波長，可並用 :所周知之光敏劑。作為此時之光敏劑，例如，可列舉： 恩、紛斜、聯苯酿縮二甲醇、二苯基酮、苯乙酮等。 又於备、外線硬化性樹脂中，亦可視需要進一步調配其 :力:：’如熱聚合抑制劑、受阻酚、受阻胺、亞磷酸酯 專為代表之抗氧化劑，可㈣、及環氧料、㈣石夕烧、 士甲基）丙烯酸我等為代表之我偶合劑等，以改良各種 4寸性。該料選用對紫外線硬化性化合物之溶解性優良 312XP/發明說明書(補件)抓〇6/96111269 25 200814050 者、不阻礙紫外線穿透性者。 (2)獲得轉印層積層壓模2〇〇之步驟 本：施形態中，係於壓模4表面上形成轉印層6而獲得 榦P層積層屋模200。具體而言，係於壓模4上設 線硬化性樹脂膜5，對紫外線硬化性樹脂膜5照射紫外線 U'，使紫外線硬化性樹脂膜5半硬化後，於減少氧濃戶 之壤境下照射紫外線UV，使紫外線硬化性樹脂膜5進一It refers to the shrinkage rate measured by the specific gravity method. Further, the shrinkage rate can also be measured by K7H26" or the like.稞JIS Second, in order to ensure adhesion to the transfer layer 6 (described in detail below), it is preferable to use a material having sufficient adhesion in the lower intermediate layer 3. In order to ensure the adhesion to the transfer layer 6, the type of the material used in the transfer layer 6 and the lower intermediate layer can be used (specifically, ultraviolet curable resin), and the surface of the lower intermediate layer 3 can be used. Set the adhesion layer and other methods. Further, although not shown in Fig. 1(a), in the embodiment of the present embodiment, the lower intermediate layer 3 may have an early layer structure' or a structure in which a plurality of layers are laminated. As a structure for laminating a plurality of layers, the flexibility or shrinkage ratio of the entire intermediate layer 3 under the control of the resin type used in each layer is appropriately controlled, and the advantage of reducing the warpage of the substrate 1 is easily achieved. The number of resin layers constituting the lower intermediate layer 3 is not particularly limited. In order to improve the warpage of the substrate 1, the number of resin layers is usually set to 1 〇 or less, and the second I': '4 layers are I: on the other hand, the number of resin layers is 1 layer', in terms of production efficiency. The number of trees exhibiting the lower intermediate layer 3 is preferably one layer or more '5 layers or less. In terms of production efficiency: The lower intermediate layer 3 has a one-layer structure. The film thickness of the soil ' and the lower intermediate layer 3 is not particularly limited, and may be selected within the range of the crucible depending on the type of the body to be used. For example, the thickness of the middle door is usually Ι5μπι or more, preferably 2〇^驭 is on the one hand, the middle 312ΧΡ/the invention says 补(supplement)/96-06/96111269 20 200814050 The film thickness of the layer 7 is usually 8〇/lm or less. Preferably, the following. More specifically, in the case of a Blu-ray disk using a blue laser, the film thickness of the intermediate layer 7 is preferably 2 〇 μηι or more, and 3 or less. In the case where the R is of a re-type, the film thickness of the intermediate layer 7 is preferably 〇Mm or more and 70 μηι or less. Then, generally, the film thickness of the transfer layer 1 described below is larger than 〇μΐΏ and is 20 μηΐ or less. Therefore, the film thickness of the lower intermediate layer 3 is the film thickness of the intermediate layer 7 minus the remaining thickness of the transfer layer 6. In the following, the case of the resin material used in the lower intermediate layer 3 is described as the example of the case, and the thermoplastic resin, the thermosetting resin, the electron beam curable resin, and the ultraviolet curability are mentioned. Resin (including delayed hardening type) and the like. The material can be appropriately selected from the above resins. The thermoplastic resin and the thermosetting tree are usually prepared by converting to a suitable solvent to prepare a coating liquid. Thereafter, the coating liquid is applied and dried (heated), whereby the lower intermediate layer 3 can be formed. The ultraviolet curable resin can be usually prepared as a coating liquid by directly or dissolving in a suitable solution. Bean De, 净欲# + 7 士, drink, and then apply the coating liquid, and irradiate it with ultraviolet rays to harden it, whereby the lower intermediate layer 3 can be formed. The above materials may be used singly or in combination. As the coating method, a coating method such as a spin coating method or a die-casting method can be used, and 'the spin coating method is preferred. The intermediate layer 3 under the high-viscosity resin is used, and it can also be formed by screen printing or the like. When the resin is used in a liquid form in the next 4th generation, it is preferable in terms of productivity = it is easy to apply without using a solvent. Further, the coating viscosity is preferably in the range of 20 MPa · s to 15 MPa MPa · s. Further 312Xp/Invention Manual (Supplement)/96-06/96111269 21 200814050 The viscosity of the best coating liquid is set to 1 〇〇〇Mpa· S or less. = = 1 (a) t Although not shown in the figure, the substrate has a disk shape, and when the mesopores are formed at the center, the coating method (4) is preferably used by the following method to open the π π 日 日 日 ^ ^ The lower middle layer 3 is formed by Λ, 10,000/mike. That is, in a predetermined radius larger than the outer diameter of the mesoporous, the resin having the viscosity is dropped into the coating (the ring is just called the coating. Then, it is preferably followed by the spin coating. As the resin material) It is preferable to use an ultraviolet curable resin. The ultraviolet curable resin has high transparency and a short curing time, and is preferable in terms of production. Examples of the ultraviolet curable resin include a radical ultraviolet curable resin and a cationic ultraviolet curable resin. Any of the cationic ultraviolet curable resins has a small shrinkage property and is suitable for reducing warpage of an optical recording medium. Hereinafter, the radical ultraviolet curable resin and cationic ultraviolet curability are used. A resin containing a UV curable compound and a photopolymerization initiator can be used as the radical ultraviolet curable resin. As the ultraviolet curable compound, a monofunctional (meth)acrylate and a polyfunctional (曱) can be used. Acrylate as a polymerizable monomer component. These may be used alone or in combination of two. Here, the acrylate and the mercapto acrylate are collectively referred to as (mercapto) acryl vinegar. As the monofunctional (fluorenyl) acrylate, for example, it may have a methyl group, an ethyl group, a propyl group, a butyl group, Pentyl, 2-ethylhexyl, octyl, decyl, dodecyl, hexadecyl, octadecyl, cyclohexyl, benzyl, decyloxyethyl, butoxyethyl, oxygen Base ethyl, nonylphenoxyethyl, tetrahydroindenyl, shrinkage 312XP/invention specification (supplement)/96-06/96111269 22 200814050 glyceryl, 2-hydroxyethyl, 2-hydroxypropyl, 3 -Chloro-2-hydroxypropyl, dimethylaminoethyl, diethylaminoethyl, nonylphenoxyethyltetrahydroindenyl, caprolactone modified tetrahydroindenyl, isobaric, di A (meth) acrylate having a substituent such as a cyclopentyl group, a bicyclononyl group or a cyclopentenyloxyethyl group as a substituent. Examples of the polyfunctional (fluorenyl) acrylate include a diol and an I4. · Butanediol, i,5·pentanediol, 3-methyl-1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, 1,8-octanediol, 19·壬Glycol, tricyclodecane dimethanol, ethylene glycol , bis(meth) acrylate such as polyethylene glycol 'propylene glycol, dipropylene glycol, tripropylene glycol, polypropanol, di(meth)acrylate of tris(2-hydroxyethyl)isocyanurate, etc. Further, a bis(methyl)(tetra) acid vinegar obtained by adding 4 moles or more of epoxy ketone or propylene propylene to 1 mole of neopentyl glycol; The bis(meth) acrylate of the diol obtained by adding 2 moles of ethylene bromide or propylene propylene to the ear, and adding 3 gram of methyl methacrylate The second alcohol or acrylate obtained by the above ethylene oxide or propylene oxide; the addition of 4 moles to 1 mole bisphenol A to obtain: ^ oxygen?:: propylene oxide to obtain the second Alcohol bis(meth)acrylic acid-hydrazine, dimethylolpropane tris(10)) acrylate; pentaerythritol pentoxide, propyl acrylate; epoxy ethene: vinegar vinegar. Soil propylene vinegar, soil oxy-oxygen bromide modified dysfunctional phosphoric acid (methyl) propylene ^ 翠 翠 翠 翠 , , , , , , , , , , , , , , , , , , , , , , , , , , , , a), bisenoic acid ester, polyether (yinyl) propylene 312XP / invention manual (supplement) / 96 rhyme 96 ιι_ ", 夂 夂 乳 lactate, (meth) acrylate amine f acid ester. 23 200814050 ^ In addition, in the free radical UV curing sclerosing moon, usually with adjustable light initiator. As a photopolymerization initiation, a molecular cleavage type or a ruthenium type is preferred. In such a photopolymerization initiator, as a molecular cleavage, benzoin, 2,4-diethyloxosulfuric acid (tetra), ...: di-milk: its base, 2,4,6-trimethylbenzhydrazide Diphenylphosphine oxide, a soil _ ·monomethane imiline phenyl)-butane-1-anthracene, 雔Γ2 6--methoxybenzamide blue base)_2,4,4-three Methyl amyl phosphine oxide and the like. Also, 'can be used together! -hydroxycyclohexyl phenyl ketone, benzoin ethyl ether, cyclamate monomethyl ketone, ketal, 2-amino-based 2-methyl phenyl propyl hydride + hydrazine succinct 2) 2. Methyl methyl thiobenzene: can be stupid 3 and so on. As a chlorine-removing photopolymerization initiator, for example, a ketone-based ketone, a meta-xylylene benzoate "rPh^ and a sensitizer can be used in combination with the photopolymerization initiator, for example, Examples thereof include trimethylamine, methyldimethanolamine, -ethylaminoethylphenidinium, p-dimethylaminobenzoic acid, acetonitrile, and ethylamine = isoamyl benzoate, N. N• dimethyl node base: base month female base) diphenyl ketone and so on. Further, (B) is a cationic ultraviolet curable resin, for example, an epoxy resin of an ion-hard photopolymerization initiator. As a gas, it can be exemplified by a double-aged A_epichlorohydrin type, a fat ^ month曰, example = epoxy resin, glycidol vinegar type, shrinking I: oil; Π is: 312XP / invention manual (supplement) / 96-06/96111269 gas is better in the weight% or less, more preferably 0.5 Weight 24 200814050% or less. 趟 : : 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子 阳离子- hurricane, diphenyl sulfonium hexafluoroantimonate, diphenyl sulfonium hexahydrate, acid: bis(pentafluorophenyl)borate, bis(dodecylphenyl) fluoride Bismuth salt, bis(dodecylphenyl)phosphonium hexafluoroantimonate, bis(decylphenyl)phosphonium hexafluoroborate, bis(dodecylphenyl) fluorene W (pentafluorocarbon) Base) borate, etc., = can be enumerated: 4-methylphenyl o-methylethyl) phenyl-locked iron hexafluorene, methylphenyl o-methylethyl) phenyl hydrazine Acid; dimethylphenyl o-methylethyl)benzene C-protected hexafluoro-decanoate, 4_ cage soil-based 4-(1-methylethyl)phenylphosphonium tetrakis(pentafluorophenyl)-penic acid 2 examples of photopolymerization of the resin, usually from 0.1 part by weight to 20 parts by weight, preferably = 5% to 5 parts by weight. Further, in order to more effectively utilize the wavelength of the near ultraviolet region or the visible region of the ultraviolet: source wavelength region, a well-known photosensitizer can be used in combination. The photosensitizer at this time may, for example, be exemplified by enthalpy, stilbene, biphenyl condensed dimethanol, diphenyl ketone or acetophenone. In addition to the external and external curable resins, it can be further formulated as needed: force:: such as thermal polymerization inhibitors, hindered phenols, hindered amines, phosphites, specifically represented by antioxidants, (4), and epoxy materials (4) Shi Xizhuo, Shi Ke) Acrylic acid, etc. I represent the coupling agent to improve various 4 inch properties. This material is excellent in solubility in ultraviolet curable compounds. 312XP/invention manual (supplement) grabs 6/96111269 25 200814050, does not hinder UV penetration. (2) Step of obtaining a transfer laminated lamination mold 2: In the embodiment, a transfer layer 6 is formed on the surface of the stamper 4 to obtain a dry P laminated house mold 200. Specifically, the line-curable resin film 5 is provided on the stamper 4, and the ultraviolet curable resin film 5 is irradiated with ultraviolet rays U' to semi-harden the ultraviolet curable resin film 5, thereby reducing the oxygen-rich environment. Irradiation of ultraviolet light UV to make the ultraviolet curable resin film 5 into one

步硬化而形成轉印層6。 針對此步驟，一邊參照圖1(b)一邊進行說明。再者，圖 ()中係將藉由|外線UV照射而硬化前之膜稱為紫外 線硬化性樹賴5 ’將藉由料線UV照射而硬化後之膜 :為轉印層6。為了使轉印層6具有對射入至記錄再生功 能層2之雷射光的透光性’較佳係使用可確保對上述雷射 光之充分透明性之材料。此處，本實施形態中，所謂「透 光性（或透明）」，係指對照射記錄再生功能層2之雷射光波 長具有充分之穿透性。所謂「透光性（或透明）」，具體而言， 係指對用以記錄•再生之光之波長（例如，405 rnn)，通常 八有70/❶以上、較佳8〇%以上、更佳⑼％以上之穿透性。 再者，透光性之理想上限為1〇〇%。 士 =先，如圖l(b)(b— 1)所示，對表面設有紫外線硬化性 i月曰膜5之壓模4照射紫外線uv，使紫外線硬化性樹脂 膜5半硬化。 [1·壓模4] 壓模4係於表面上具有對應於中間層7上形成之凹凸形 312XP/發明說明書(補件)/96-06/96111269 26 200814050 狀（凹凸形狀）的形 凸）。 ^(#印用㈣形狀）之凹凸（轉印用四 作為屢模4材料，者 使用樹脂。又，考^到7b記錄媒體之製造成本，通常 外線硬化性樹自㈣4側照射紫外線而使紫 有充分之透光性二情較佳係壓模4對光具 穿透率為_以上 ^ = \對於波長400㈣， 100%。 1 0/〇以上。牙透率之理想上限為 於壓模4為由樹脂带 列舉各種材料。例如'可亩接作為所使用之樹脂，可 碳酸®旨f 可直接使用通常用作光碟基板之聚 丙烯酸系樹脂。此外，為了確保壓模4與 可使用㈣煙系樹脂或聚苯乙稀系樹 之材料，減少壓模4之表面能量。如上所述， 产狀？：？成罝之壓模4而實際實用化者，有如非晶質 二二^稀煙樹脂（例如，ze〇nex(註冊商標）及 • (°主冊商標）(兩者均為日本ΖΕΟΝ股份有限公司 製）〇 非晶質環狀聚烯烴具有良好之剝離性，為工業性優異之 材料::然而，非晶質環狀聚烯烴為特殊材料，故高價，因 =£模4之成本將有增大之傾向。而且，樹脂製壓模4通 韦為不可回收，故事實上光記錄媒體整體中壓模4之成本 負擔灸大因此，較佳係使用盡可能廉價之樹脂。一般就 成本方面而&，較佳係使用聚碳酸酯系樹脂或丙烯酸系樹 脂，就剝離性而言，較佳係使用聚烯烴系樹脂或聚苯乙烯 312χρ/發明說明書(補件)/96-06/96111269 27 200814050 系樹脂。 匕本發明中，獲得轉印層6時，係首先使紫外線硬化性樹 月曰膜5半硬化。其後照射紫外線uv，使紫外線硬化性樹 脂膜5硬化而獲得轉印層6。根據本發明者之研究可知， 如上所述，藉由使紫外線硬化性樹脂膜5經過一次之半硬 -化狀態，可改良轉印層6與壓模4之剝離性。其理由尚未 ,明確，但推測可能起因於下述現象之產生。The transfer layer 6 is formed by step hardening. This step will be described with reference to Fig. 1(b). Further, in the figure (), the film which is cured by UV irradiation of the outer line is referred to as an ultraviolet curable tree 5'. The film which is cured by UV irradiation of the material line is the transfer layer 6. In order to make the transfer layer 6 have a light transmittance of laser light incident on the recording and reproducing functional layer 2, it is preferable to use a material which ensures sufficient transparency to the above-mentioned laser light. Here, in the present embodiment, "translucent (or transparent)" means that the laser light having the recording/reproducing functional layer 2 has sufficient penetration. The term "transparency (or transparency)" means, in particular, the wavelength of light used for recording/regeneration (for example, 405 rnn), usually eight or more, preferably more than 8%, and more Good (9)% or more penetration. Further, the ideal upper limit of the light transmittance is 1% by weight. In the first embodiment, as shown in Fig. 1(b)(b-1), the stamper 4 provided with the ultraviolet curable i moon film 5 is irradiated with ultraviolet uv to semi-harden the ultraviolet curable resin film 5. [1. Compression Mold 4] The stamper 4 has a concavo-convex shape corresponding to the concavo-convex shape formed on the intermediate layer 7/inventive specification (supplement)/96-06/96111269 26 200814050 (concave-convex shape) on the surface) . ^(#Printing (4) shape) The unevenness (transfer is used as the material of the repeating mode 4, and the resin is used. In addition, the manufacturing cost of the recording medium is 7b. Usually, the external hardening tree is irradiated with ultraviolet rays from the (four) 4 side to make the purple It is better to have sufficient light transmittance. The pressure of the stamper 4 is _ above ^ = \ for the wavelength 400 (four), 100%. 1 0 / 〇 or more. The ideal upper limit of the tooth permeability is the stamper 4 In order to stipulate various materials from the resin tape, for example, 'available as a resin to be used, a carbonated resin can be directly used as a polyacrylic resin which is usually used as a substrate of a disc. In addition, in order to ensure that the stamper 4 and the usable (four) smoke are used It is a material of resin or polystyrene tree, which reduces the surface energy of the stamper 4. As described above, the shape is as follows: the mold is used for the mold 4, and the practical use is like amorphous two-two-dilute smoke. Resin (for example, ze〇nex (registered trademark) and • (° main volume trademark) (both manufactured by Nippon Co., Ltd.) 〇 Amorphous cyclic polyolefin has good peelability and is industrially excellent. Material: However, amorphous cyclic polyolefin is a special material, so The price, because the cost of the mold 4 will increase, and the resin mold 4 is not recyclable, so in fact, the cost of the stamper 4 in the optical recording medium as a whole is burdened by moxibustion. A resin which is as inexpensive as possible is used. Generally, a polycarbonate resin or an acrylic resin is used in terms of cost, and in terms of peelability, a polyolefin resin or polystyrene 312 χ ρ / invention is preferably used. Instruction Manual (Supplement)/96-06/96111269 27 200814050 Resin. In the present invention, when the transfer layer 6 is obtained, the ultraviolet curable dendritic film 5 is first semi-hardened. Thereafter, the ultraviolet uv is irradiated to ultraviolet rays. The curable resin film 5 is cured to obtain the transfer layer 6. According to the study of the present inventors, as described above, the transfer layer 6 can be improved by subjecting the ultraviolet curable resin film 5 to a semi-hardened state once. The peeling property of the stamper 4. The reason for this is not clear, but it is presumed that it may be caused by the following phenomenon.

即，於強烈照射紫外、線uv之情況，或於無泮滅體 (q encher)(如氧分子之自由基激發淬滅（quenching)之分 子）之狀態下照射紫外、線uv之情況下，彳認為在壓模4 與紫外線硬化性樹脂膜5之界面附近，成為來自反應起始 j之自由基與未反應樹脂高濃度共存之狀態。推測若於該 況下使用;^脂製壓模4，則除了於紫外線硬化性樹脂膜 5内產生聚合以外，壓模4與紫外線硬化性樹脂膜5之間 亦生成化學鍵^產生交聯部分。繼而，認為其結果可能造 成透明壓拉與硬化樹脂之剝離性惡化。特別是若使用極性 权4之材料，則壓模4與紫外線硬化性樹脂膜^之界面上 更易產生上述化學鍵。 囚此 吁考慮於進行強烈照射紫外線uv之操 減=氧濃度之環境下照射紫外線uv等進行急速硬化:操 作月〗使紫外線硬化性樹脂膜$緩慢硬化（半硬化）@; 麵以紫外線硬化性樹賴5之反應。; ㈣4及紫外線硬化性樹脂膜5之界面，成為麼模=4果及為紫 312XP/發明說明書贿牛)/96·〇咖η汹 28 200814050 外線硬化性樹脂膜5各自之表面性較為安定之狀離 而，於該狀態下’藉由於減少氧濃度之環境中照射；後 UV’而使料線硬錄樹脂膜5進—步硬化轉= 6,推測藉此可改善轉印層6與壓模4之剝離性。和P層 如上所述，本發明中藉由經過紫外線硬化性樹脂 半硬化，而變得容易確保壓模4與轉印層6之剝離性 此’發揮壓模4中所使用之材料之自由度變大 即’如上所述，就減少壓模4表面能量而言，# 聚烯煙可較佳地用作壓模4之材料，但本發明中，不^狀 上述高功能性樹脂，可使用聚碳酸酿系樹脂、㈣ΊThat is, in the case of strongly irradiating the ultraviolet ray, the line uv, or in the case of irradiating the ultraviolet ray and the line uv in a state where no quencher (such as a molecule excited by a free radical of the oxygen molecule) is irradiated, In the vicinity of the interface between the stamper 4 and the ultraviolet curable resin film 5, it is considered that the radicals from the reaction start j and the unreacted resin coexist in a high concentration. In the case where the pressure is applied to the ultraviolet curable resin film 5, a chemical bond is generated between the stamper 4 and the ultraviolet curable resin film 5 to produce a crosslinked portion. Then, it is considered that the result may cause deterioration in peelability of the transparent pressure-drawing and hardening resin. In particular, when the material of the polar weight 4 is used, the chemical bond is more likely to occur at the interface between the stamper 4 and the ultraviolet curable resin film. In this case, it is considered to be subjected to intense irradiation of ultraviolet rays uv. In the environment of oxygen concentration, ultraviolet uv or the like is subjected to rapid hardening: the operation month is made to cure the ultraviolet curable resin film slowly (semi-hardening) @; The reaction of the tree Lai. (4) 4 and the interface of the ultraviolet curable resin film 5, which becomes a mold = 4 fruit and purple 312XP / invention manual bribe) / 96 · 〇 汹 汹 2008 28 200814050 The external surface of the curable resin film 5 is relatively stable In this state, the irradiation of the hard-wired resin film 5 by the irradiation of the environment in which the oxygen concentration is reduced; the post-UV' is further improved, and it is presumed that the transfer layer 6 and the pressure can be improved. The peelability of the mold 4. As described above, in the present invention, in the present invention, it is easy to ensure the releasability of the stamper 4 and the transfer layer 6 by semi-curing the ultraviolet curable resin, and the degree of freedom of the material used in the stamper 4 is exhibited. When it is enlarged, as described above, in terms of reducing the surface energy of the stamper 4, the polyolefin can be preferably used as the material of the stamper 4, but in the present invention, the above-mentioned highly functional resin can be used. Polycarbonate brewing resin, (4) Ί

脂等通用且低成本之樹脂。 ' ' A 就使上述優勢顯著發揮而言’作為壓模4之材料， 係使用聚碳酸i旨㈣脂、丙稀酸系樹脂。更佳係聚碳= 系樹脂。再者，壓模4之材料可單獨使用1種，亦可依曰 意組合及比例並用2種以上。 &壬 •圖1(b)中雖省略圖示，壓模4通常形成為於中央部形 有貫穿正反之中心孔的圓板狀。 ^ 再者，於製作壓模4之情況，其製作方法為任意。例如 於壓模4為樹脂製壓模之情況，可使用具有與壓模*所且 有之轉印用凹凸形狀相反之（負）之凹凸圖案的金屬製壓模 (例如，鎳製壓模），藉由射出成形等製作壓模4。 、 又’本實施形態中使用之堡模4之厚度，就形狀安定性 及操作之容易性而言，通常期望為〇3 mm以上。但厚产 通常為5 mm以下。若壓模4厚度為該範圍中，則變 3 UXP/發明說明書(補件)/96-06/96111269 29 200814050 易確保充分之透光性。因此，即使如下述般透過壓模4照 射紫外線uv，亦可使紫外線硬化性樹脂等有效硬化，易 於提高生產性。 [2·紫外線硬化性樹脂膜5] 紫外線硬化性樹脂膜5通常以下述方法形成。即，紫外 、線硬化性樹脂膜5可藉由視需要與添加劑（例如，光聚合 •起始劑、增感劑等添加劑）或溶劑一同塗佈於壓模4之具 有轉印用凹凸形狀之面而形成。塗佈方法無特別限制，就 易形成均勻膜厚方面、適合工業生產方面等理由而言，通 常使用旋塗法。 於使用旋塗法之情況，紫外線硬化性樹脂之組成物之黏 度’通常為50 MPa· s以上，35〇 Mpa·以下。藉由設 f該黏度範圍内，可易於將轉印層6之厚度控制於‘定： 範圍内X，右設為上述黏度範圍内，則容A general-purpose and low-cost resin such as grease. ' ' A makes the above advantages stand out.' As a material of the stamper 4, a polycarbonate or an acrylic resin is used. More preferred poly carbon = resin. Further, the material of the stamper 4 may be used singly or in combination of two or more kinds depending on the combination and the ratio. & 壬 • Although not shown in Fig. 1(b), the stamper 4 is generally formed in a disk shape having a center hole formed in the center portion. ^ Furthermore, in the case of producing the stamper 4, the manufacturing method is arbitrary. For example, in the case where the stamper 4 is a resin stamper, a metal stamper (for example, a nickel stamper) having a (negative) concave-convex pattern opposite to that of the stamper* can be used. The stamper 4 is produced by injection molding or the like. Further, the thickness of the bunker 4 used in the present embodiment is generally desirably 〇3 mm or more in terms of shape stability and ease of handling. However, the yield is usually less than 5 mm. If the thickness of the stamper 4 is within this range, then it is easy to ensure sufficient light transmission. UXP/Invention Manual (Supplement)/96-06/96111269 29 200814050 Therefore, even if the ultraviolet uv is irradiated through the stamper 4 as described below, the ultraviolet curable resin or the like can be effectively cured, and the productivity can be easily improved. [2. Ultraviolet curable resin film 5] The ultraviolet curable resin film 5 is usually formed by the following method. In other words, the ultraviolet curable resin film 5 can be applied to the stamper 4 with a concave-convex shape for transfer by an additive (for example, an additive such as a photopolymerization initiator or a sensitizer) or a solvent. Formed in the face. The coating method is not particularly limited, and a spin coating method is usually used for the purpose of forming a uniform film thickness and being suitable for industrial production. In the case of using the spin coating method, the viscosity of the composition of the ultraviolet curable resin is usually 50 MPa·s or more and 35 Å Mpa· or less. By setting f within the viscosity range, the thickness of the transfer layer 6 can be easily controlled within the range of θ: within the range of X, and the right is set within the above-mentioned viscosity range.

之膜厚範圍大幅變化。且㉟而丄 „^A 叫八r田文化具體而吕，易於良好地製作薄轉印 _，6(例如5/πη左右），另一方面亦易於製作膜厚較厚之轉 =者’目1(b)中雖省略圖示，於壓模為圓盤狀且中心形 =二之情況’較佳係使用以下方法形成紫外線硬化性樹 ^硬仆Π 於中孔外徑线定半錄置巾，將紫外 " 树脂滴下成（disPence)環狀而塗佈。 、、k而’較佳的係於其後進行旋塗。 作二紫：線硬化性胸5中使用之紫外線硬化性樹 曰亚热特別限制。就提高璧模4之轉印性及設於轉印層 312XP/MiS__/_/96111269 3〇 200814050 6上之上部纪錄再生功能層（下述）之記錄特性而言，較佳 係，用硬化所得之轉印層6相對地較堅固之紫外線硬化 f生树知。具體而言，較佳係紫外線硬化性樹脂於1別。〇下 =彈ί!率為300 MPa以上。其原因為，彈性率高之樹脂通 系具有硬性。再者，所謂彈性率，係指以通常之動態黏彈 性測定機所測定之動態彈性率。 …軏印層6中使用之紫外線硬化性樹脂於15〇它下之彈性 ⑩率越高越佳。150。〇下之彈性率，較佳係3⑽Mpa以上， 更佺33〇]^〇^以上，再更佳35〇]^1^以上，再更佳5〇〇]^1^ 以上，再更佳75〇 MPa以上，尤佳95〇 以上，最佳 1000 MPa 以上。 此處所。胃彈性率，係如上所述，指以通常之動態黏彈 性測定機所測定之動態彈性率。其中，就生產性而言，紫 外線硬化性樹脂於15(rc下之彈性率通常為25⑻心以 下。 • 再者，於150〇C下之彈性率為300 MPa以上之情況，一 般將有樹脂之玻璃轉移溫度變高之傾向。具體而言，i5〇t 下之彈f生率為300 MPa以上之樹脂之玻璃轉移溫度通常 為140 C以上。另一方面，玻璃轉移溫度之上限通常 200〇C 〇 又，轉印層6中使用之紫外線硬化性樹脂之收縮率，就 抑制光碟翹曲而言，較佳為收縮率小者。但，具有上述彈 性率之紫外線硬化性樹脂中，收縮率容易變成相對較大 值。又，若加大收縮率則容易發揮下述之優勢。收縮率通 312XP/發明說明書(補件)/96-06/96111269 31 200814050 常為6%以上，較佳9Q/〇以上，更佳9 5%以上，更佳ι〇% 以上其中，收縮率較佳為20°/。以下。此處，所謂收縮率 係指以比重法所測定之收縮率。又，收縮率亦可依據 K71126.1等進行測定。 藉由於轉印層6中使用收縮率為6%以上之紫外線硬化 性樹脂而使之形成，於使用樹脂製壓模4於轉印層6上形 .成記錄軌用溝時，將容易改善自壓模4之剝離性，故而較 佳。壓模4之剝離性良好之理由，認為例如係進入壓模4 溝中之樹脂於硬化時收縮，產生輕微變形或間隙所造成。 如上所述，為了確保與壓模4之剝離性，轉印層6中所 使用之樹脂，較佳為具有既定以上之收縮率。另一方面， 由收縮率較大之樹脂形成轉印層6之結果為，轉印層6之 成膜時之收縮有變大之傾向。其意味著光記錄媒體整體變 得容易趣曲。針對此點，可適當控制下中間層3之材料， 緩和光記錄媒體整體之翹曲。針對此點，於說明下中間岸 _ 3中所使用之材料時已加以說明。 曰 以下對下中間層3與轉印層6中使用之材料的較佳电人 進行說明。 、口 如上所述，本實施形態中，較佳係於轉印層6中使用「古 溫（例如wc)下之彈性率高之紫外線硬化性樹脂 I率較大之紫外線硬化性樹脂」。另—方面，較佳係於下 間層3中使用「常溫（例如3〇。〇下之彈性率小之樹脂、 「收縮率較小之樹脂」。 曰」 以下，針對用以獲得具有上述4種性質之樹脂（具體而 312XP/發明說明書(補件)/96-06/96111269 ” 200814050 言，紫外線硬化性樹脂）之具體方法 (獲得尚溫（例如i50°c)下之彈性 之方法） 评f旱阿之紫外線硬化性樹脂 為了提高紫外線硬化性樹 化而獲得之交聯構造之布朗運動二=，’= 聯密度即可。更且體而士，你你m P誕同又 八 -於使用丙烯酸系單體形成紫外 線硬化性樹脂之情況下，例如， ^ ^ -Γ ^ - 稽由進仃如下之（a)〜（C)， 將可獲侍：溫下之彈性率高之紫外線硬化性樹脂。 (a)使用父聯密度高之丙婦酸系單體。 ⑻使用交聯構造中具有剛直構造之丙烯酸系單體。 且==交聯密度高之丙婦酸系單體與交聯構” /、有Π]直構造之丙烯酸系單體。 :為”之丙稀酸系單體，可列舉每“固丙稀醯 f之刀子置小之多官能丙婦酸系單體(多官能 酸酯）。 ^ 甲醇、乙一醇、聚乙二醇、丙二醇 聚丙二醇等之二（甲基）丙烯酸酯、 氰酸酯之二（甲基）丙烯酸酯等。 产又，可列舉：於〗莫耳新戊二醇上加成4莫耳以上之产 乳乙院或環氧丙燒而獲得之二醇之二（甲基）㈣酸醋 1莫耳雙紛A上加成2莫耳之環氧乙燒或環氧丙燒而獲得 ▲作為多官能（甲基）丙烯酸酯，例如，可列舉：〗，夂丁二 醇、1，4-丁二醇、π戊二醇、3_甲基-以-戊二醇、卜 二醇、新戊二醇、M_辛二醇、〗，9·壬二醇、三環癸烷二 醇 聚 -丙二醇、三丙二 (2-羥基乙基）異 312XP/發明說明書(補件)/96·06/96111269 33 200814050 之二醇之二（曱基）丙烯酸酯、於1莫耳雙酚A上加成4莫 耳以上之環氧乙烷或環氧丙烧所獲得之二醇之二（甲基）丙 烯酸酯、環氧乙烷改質磷酸（曱基）丙烯酸酯、環氧乙烷改 質烷化磷酸（曱基）丙烯酸酯、三羥曱基丙烷三（曱基）丙烯 酸酯、於1莫耳三羥曱基丙烷上加成3莫耳以上之環氧乙 烷或環氧丙烷而獲得之三醇之二或三（曱基）丙烯酸酯、季 戊四醇三（曱基）丙烯酸酯、季戊四醇四（甲基）丙烯酸酯、 馨於1莫耳季戊四醇上加成4莫耳以上之環氧乙烷或環氧丙 烷所獲得之四醇之三或四（曱基）丙烯酸酯、二季戊四醇之 聚（曱基）丙烯酸酯（例如，二季戊四醇五（甲基）丙烯酸酯或 一季戊四醇六（甲基）丙烯酸酯）'於i莫耳二季戊四醇上加 成6莫耳以上之環氧乙烷或環氧丙烷所獲得之六醇之五 或六（曱基）丙烯酸酯等。 該等之中，就可加大高溫下之彈性率而言，較佳為如下 材料即’二备甲基丙院三（甲基）丙婦酸醋、於1莫耳三 基=上加成3莫耳以上之環氧乙炫或環氧丙㈣ ::之：ί之二(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯 :ΓΛ 四基)丙稀酸醋、於1莫耳季戊四醇上 口、耳以上之環氧乙烷或環氧丙烷而獲得之四醇之 =(甲基)丙稀酸醋、二季戊四醇五(甲基)丙婦酸：、 季戊：六(，基)丙賴、於i莫耳二季戊四醇上加 成 6莫耳以上之環蓋/ ^斗、 <衣虱乙烷或裱虱丙烷而獲 或六（甲基）丙浠酸酉旨等多官能（甲基）丙烯酸醋等r 就加大高溫下之彈性率而言，更佳為三經甲基丙燒三 312ΧΡ/發明說明書(補件)/96-06/96111269 34 200814050 (曱基）丙烯酸酯、季戊四醇三（甲基）丙烯酸酯、季戊四醇 四（曱基）丙烯酸酯、二季戊四醇五（曱基）丙烯酸酯，二季 戊四醇六（曱基）丙烯酸酯。 繼而’作為交聯構造中具有剛直構造之丙烯酸系單體， 可列舉具有剛直環狀構造之丙烯酸系單體。 作為上述丙烯酸系單體之具體例，可列舉：降稍烧二甲 醇二丙烯酸酯、降稻烷二乙醇二（甲基）丙烯酸酯、於降稻 烧二甲醇上加成2莫耳之環氧乙烷或環氧丙烷而獲得之 一酵之二（甲基）丙烯酸酯、三環癸烷二曱醇二（曱基）丙烯 曰、二環癸烧二乙醇二（甲基）丙烯酸酯、於三環癸烧二 甲醇上加成2莫耳之環氧乙烷或環氧丙烷而獲得之二醇 之二（曱基）丙烯酸酯、五環十五烷二曱醇二（曱基）丙烯酸 酉曰、五環十五烧二乙醇二（甲基）丙烯酸酯、於五環十五烧 一曱醇上加成2莫耳之環氧乙烧或環氧丙烧而獲得之二 醇之二（甲基）丙烯酸酯、於五環十五烷二乙醇上加成2莫 _耳之環氧乙烷或環氧丙烷而獲得之二醇之二（甲基）丙烯酸 酯等。 口亥專之中，就可提咼咼溫下之彈性率而言，較佳係：三 裱癸烷二甲醇二（甲基）丙烯酸酯、三環癸烷二乙醇二（甲基） 丙烯酸酯、五環十五烷二甲醇二(甲基）丙烯酸酯。 此外，亦可列舉··雙（2_丙烯醯氧基乙基）羥基乙基異三 聚氰酸酯、雙（2-丙稀醯氧基丙基）羥基丙基異三聚氰酸 酯、雙（2-丙烯醯氧基丁基）羥基丁基異三聚氰酸酯、 甲基丙烯醯氧基乙基）羥基乙基異三聚氰酸酯、雙甲基 312ΧΡ/發明說明書(補件)/96-06/96111269 35 200814050 丙烯醯氧基丙基）羥基丙基異三聚氰酸酯、雙（2_甲基丙烯 醯氧基丁基）羥基丁基異三聚氰酸酯、三（2_丙烯醯氧基乙 基）異三聚氰酸酯、三（2·丙烯醯氧基丙基）異三聚氰酸酯、 二（2-丙烯醯氧基丁基）異三聚氰酸酯、三（2_曱基丙烯醯氧 基乙基）異三聚氰酸酯、三（2•甲基丙烯醯氧基丙基）異三聚 •氰酸酯、三（2-曱基丙烯醯氧基丁基）異三聚氰酸醋等。 -&就可提高高溫下之彈性率而言，尤佳係：三環癸烷二甲 _醇一（甲基）丙烯酸酯、三環癸烷二乙醇二（曱基）丙烯酸酯。 於組合使用交聯密度高之丙烯酸系單體與交聯構造中 具有剛直構造之丙烯酸系單體之情況，可使用如下者。 即，選擇1個以上上述說明之交聯密度高之丙烯酸系單體 之具體化合物。進而，選擇i個以上上述說明之交聯構造 中具有剛直構造之丙烯酸系單體之具體化合物。繼而，根 據广期望之彈性率將該等化合物以任意比例組合使用。 (獲得收縮率較兩之紫外線硬化性樹脂之方法） • 一於紫外線硬化性樹脂之情況下，所謂收縮率係指硬化收 縮率。硬化收縮率為相對於硬化前密度之硬化時之密度變 化的比例。因此為了加大收縮率，可加大硬化時之密度 變化。具體而言，於使用丙烯酸系單體形成紫外線硬化性 樹脂之情況，可提高丙烯醯基之密度。換言之，可使用交 耳外禮、度南之丙細酸系單體。 作為交f密度高之丙烯酸系單體，可列舉每丨個丙烯醯 基之分子1小之多官能丙烯酸系單體（多官能（甲基）丙烯 酸酯）。作為如此之多官能丙烯酸系單體（多官能（甲基）丙 312XP/發明說明書(補件)/96-06/96111269 % 200814050 烯酸醋）之具體例，可使用與 下之彈性率高之樹脂之方丰击彳又件同/皿（例如150。〇 稀酸酯相同者。 /」所說明之多官能(甲基)丙 高，如15〇。。)下之彈性率且使收縮率變 于又 对月曰之十月況，例如，如上述「獲得高溫（例如15〇。) 下之彈性率高之樹脂之方法」中之 / ^ 15〇C) 巾且右_ | m 了亚用父聯構造 中具有剛直構造之丙烯酸系單體。交聯構造中具有剛直構 二糸早體之含量為可獲得所期望之彈性率及收 細年之含量即可。 (獲得常溫（例如3〇。〇下之彈性率小之樹脂之方法） 以下况明使用紫外線硬化性樹脂（更具體而言，自由基 系紫外線硬化性樹脂）形成樹脂層之情況之具體方法。土 為了減小紫外線硬化性樹脂於3〇t下之彈性率，可減 =化時之密度變化。具體而言，可歹㈣，於使用丙稀酸 系單體而形成紫外線硬化性樹脂之情況，組合每〗個丙烯 _醯基之分子量較大且具有柔軟構造之丙烯酸系寡聚物與 單官能丙烯酸系單體的方法。具有柔軟構造之丙烯酸系寡 聚物及單官能丙烯酸系單體之含有比率，可以獲得所期望 之彈性率為目的予以適當控制。 作為具有柔軟構造之丙烯酸系寡聚物之具體例，可列 舉··含有聚醚或聚酯二醇之（甲基）丙烯酸胺基甲酸酯、聚 烷二醇二丙烯酸酯等丙烯酸系寡聚物等。 作為單官能丙稀酸系單體之具體例，可列舉··（甲基）丙 烯酸乙酯、（甲基）丙婦酸丁醋、（甲基）丙浠酸2-乙基己g旨、 312XP/發明說明書(補件)/96-06/96111269 37 200814050 (甲基）丙烯酸壬酯、（甲基）丙烯酸十三烷基酯、（甲基）丙烯 酸十六烷基酯、（曱基）丙烯酸十八烷基酯、（甲基)丙烯酸 異戊酯、（甲基）丙烯酸異癸酯、（曱基）丙烯酸異硬脂酸酯、 (甲基）丙烯酸2-羥基乙酯、（甲基）丙烯酸3_氯_2_羥基丙 酯、（甲基）丙烯酸甲氧基乙酯、（曱基）丙烯酸丁氧基乙酯、 (甲基）丙烯酸壬基苯氧基乙酯、（曱基）丙烯酸2_羥基_3_苯 氧基丙酯等。The film thickness range is greatly changed. And 35 and 丄 „ ^ A is called the eight r Tian culture specific and Lu, easy to make a thin transfer _, 6 (for example, 5 / πη or so), on the other hand is also easy to make a thick film thickness of the person 1(b), although not shown in the figure, in the case where the stamper is disc-shaped and the center shape=two, it is preferable to form the ultraviolet curable tree by the following method. The towel is coated with a UV resin dispersion into a (disPence) ring shape, and k is preferably used for spin coating. The second ultraviolet: ultraviolet curable tree used in the line hardening chest 5 The heat transfer is particularly limited. In terms of improving the transferability of the mold 4 and the recording characteristics of the upper recording and reproducing functional layer (described below) provided on the transfer layer 312XP/MiS__/_/96111269 3〇200814050 6 Preferably, the transfer layer 6 obtained by hardening is relatively strong in ultraviolet curing, and specifically, it is preferably an ultraviolet curable resin. The underarm=elasticity ratio is 300 MPa or more. The reason is that the resin having a high modulus of elasticity is rigid. Further, the elastic modulus refers to the usual dynamic viscoelasticity. The dynamic elastic modulus measured by the measuring machine. The higher the elastic 10 ratio of the ultraviolet curable resin used in the printing layer 6 is. 150. The elastic modulus of the underarm is preferably 3 (10) Mpa or more.佺33〇]^〇^ or more, and then better 35〇]^1^ or more, and even better 5〇〇]^1^ or more, and more preferably 75〇MPa or more, especially better than 95〇, the best 1000 MPa The above-mentioned gastric elastic modulus is a dynamic elastic modulus measured by a usual dynamic viscoelasticity measuring machine as described above, wherein, in terms of productivity, the elastic modulus of the ultraviolet curable resin at 15 (rc) Usually, it is 25 (8) or less. • In addition, when the modulus of elasticity at 150 ° C is 300 MPa or more, there is a tendency that the glass transition temperature of the resin becomes higher. Specifically, the bomb under i5〇t The glass transition temperature of the resin having a rate of 300 MPa or more is usually 140 C or more. On the other hand, the upper limit of the glass transition temperature is usually 200 〇C, and the shrinkage ratio of the ultraviolet curable resin used in the transfer layer 6 is suppressed. In terms of disc warpage, it is preferable that the shrinkage rate is small. In the ultraviolet curable resin having an elastic modulus, the shrinkage ratio tends to be relatively large. Further, if the shrinkage ratio is increased, the following advantages are easily exhibited. Shrinkage rate 312XP/invention specification (supplement)/96-06/96111269 31 200814050 is usually 6% or more, preferably 9Q/〇 or more, more preferably 95% or more, and more preferably ι〇% or more. The shrinkage ratio is preferably 20°/. or less. Here, the shrinkage ratio means The shrinkage ratio measured by the specific gravity method. The shrinkage ratio can also be measured in accordance with K71126.1, etc. The transfer layer 6 is formed by using an ultraviolet curable resin having a shrinkage ratio of 6% or more. When the stamper 4 is formed on the transfer layer 6, it is preferable to improve the peelability of the self-pressing die 4 when it is formed into a groove for recording tracks. The reason why the peelability of the stamper 4 is good is considered to be, for example, that the resin which has entered the groove of the stamper 4 shrinks during hardening, resulting in slight deformation or gap. As described above, in order to ensure the releasability with the stamper 4, it is preferred that the resin used in the transfer layer 6 has a predetermined shrinkage ratio or more. On the other hand, as a result of forming the transfer layer 6 from a resin having a large shrinkage ratio, shrinkage at the time of film formation of the transfer layer 6 tends to become large. It means that the optical recording medium as a whole becomes easiest. In view of this, the material of the lower intermediate layer 3 can be appropriately controlled to alleviate the warpage of the entire optical recording medium. In this regard, the material used in the middle bank _ 3 has been described.曰 A preferred electric person for the materials used in the lower intermediate layer 3 and the transfer layer 6 will be described below. In the present embodiment, it is preferable to use an ultraviolet curable resin having a high modulus of ultraviolet curable resin I having a high modulus of elasticity (for example, wc) in the transfer layer 6. On the other hand, it is preferable to use "normal temperature (for example, 3 〇. resin having a small elastic modulus under the armpit, and a resin having a small shrinkage ratio) in the lower layer 3. 曰" A specific method of resin (specifically 312XP/invention specification (supplement)/96-06/96111269" 200814050, ultraviolet curable resin) (method of obtaining the elasticity under temperature (for example, i50 °c)) f The dry UV curable resin is a Brownian motion of the crosslinked structure obtained to improve the ultraviolet curability of the tree. 2 =, '= The density can be combined. More and more, you are the same as the other. In the case where an ultraviolet curable resin is formed using an acrylic monomer, for example, ^^ -Γ ^ - is obtained as follows (a) to (C), and an ultraviolet curable resin having a high modulus of elasticity at a temperature can be obtained. (a) Using a high-density propylene-glycolic acid monomer. (8) Using an acrylic monomer having a rigid structure in a crosslinked structure. And == a high-crosslinking density of a propylene-glycolic acid monomer and a cross-linking structure "/, Π] Straight-structured acrylic monomer. Examples of the acid-based monomer include a polyfunctional polyglycolic acid monomer (polyfunctional acid ester) which is small per turpentine 。f. ^Methanol, ethyl alcohol, polyethylene glycol, propylene glycol polypropylene glycol, etc. Di(meth) acrylate, cyanate di(meth) acrylate, etc. Production, for example, the addition of 4 mol or more of the milk to the ethene neopentyl glycol The diol of the propylene (M) (tetra) vinegar obtained by the propylation of the propylene vinegar 1 Mo Er Shuang A is added to the 2 Mo Er Ethylene Ethylene or Ethylene Acetate to obtain ▲ as a polyfunctional (meth) acrylate For example, 1,3-butanediol, 1,4-butanediol, π-pentanediol, 3-methyl-pentanediol, diol, neopentyl glycol, M_xin Alcohol, 〗 9, 9-decanediol, tricyclodecanediol poly-propylene glycol, tripropylene bis(2-hydroxyethyl)iso 312XP / invention specification (supplement) / 96·06/96111269 33 200814050 diol Di((meth)acrylate, bis(meth)acrylate, epoxy B obtained by adding 4 moles of ethylene oxide or propylene oxide to 1 mole of bisphenol A Alkyl modified phosphoric acid Acrylate, ethylene oxide modified alkylated phosphoric acid (mercapto) acrylate, trishydroxypropyl propane tris(fluorenyl) acrylate, added to 3 moles of 1 mole of trihydroxy hydrazinopropane Di- or tri(indenyl) acrylate of triol obtained by ethylene oxide or propylene oxide, pentaerythritol tri(indenyl) acrylate, pentaerythritol tetra(meth) acrylate, and scented on 1 mole of pentaerythritol Addition of tetra- or tetra(indenyl) acrylate of tetraol obtained by adding ethylene oxide or propylene oxide of 4 moles or more, poly(indenyl) acrylate of dipentaerythritol (for example, dipentaerythritol penta (methyl) Acrylate or pentaerythritol hexa(meth) acrylate) 5 or 6 (fluorenyl) hexaol obtained by adding 6 moles of ethylene oxide or propylene oxide to i mole dipentaerythritol Acrylate and the like. Among these, in order to increase the modulus of elasticity at high temperatures, it is preferred that the following materials are 'di-prepared methyl propyl tris(methyl) propyl acetoacetate, 1 liter tribasic = upper addition 3 Moore or more Epoxy Ethylene or Ethylene Glycol (4) ::Zhe: bis (meth) acrylate, pentaerythritol tris(meth) propylene: ΓΛ tetrayl acrylate vinegar, 1 mol of pentaerythritol The tetraol obtained by the upper mouth, the ethylene oxide or the propylene oxide above the ear = (meth) acrylic acid vinegar, dipentaerythritol penta (methyl) propylene benzoic acid: pentane: six (, base)丙 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , For the increase of the modulus of elasticity at high temperatures, it is more preferred to be trimethyl methacrylate 312 ΧΡ / invention specification (supplement) / 96-06/96111269 34 200814050 (mercapto) acrylate Pentaerythritol tri(meth) acrylate, pentaerythritol tetrakis(meth) acrylate, dipentaerythritol penta(indenyl) acrylate, dipentaerythritol hexakisyl acrylate. Then, as the acrylic monomer having a rigid structure in the crosslinked structure, an acrylic monomer having a rigid ring structure can be cited. Specific examples of the acrylic monomer include a slightly burnt dimethanol diacrylate, a nordane diethanol di(meth)acrylate, and a 2 mol epoxy on a rice-fired dimethanol. Ethane or propylene oxide to obtain one of the di(meth) acrylate, tricyclodecane dimercapto bis(indenyl) propylene oxime, bicyclo fluorenyl diethanol di(meth) acrylate, Di(indenyl) acrylate of diol obtained by adding 2 moles of ethylene oxide or propylene oxide to tricycloanthracene dimethanol, pentacyclopentadecanedonol di(indenyl)acrylic acid二醇, pentane pentacene diethanol di(meth) acrylate, diol 2 obtained by adding 2 moles of ethylene oxide or propylene propylene to five rings of fibrin Methyl) acrylate, a di(meth) acrylate of a diol obtained by adding 2 moles of ethylene oxide or propylene oxide to pentacyclopentadecane diethanol. In the case of the mouth, it is preferable to use trioxane dimethanol di(meth)acrylate or tricyclodecane diethanol di(meth)acrylate. Pentapentadecane dimethanol di(meth)acrylate. Further, bis(2-propenyloxyethyl)hydroxyethyl isomeric cyanurate or bis(2-propoxymethoxypropyl)hydroxypropyl isocyanurate may be mentioned. Bis(2-propenyloxybutyl)hydroxybutylisocyanate, methacryloxyethyl)hydroxyethylisocyanate, bismethyl 312ΧΡ/invention specification (supplement )/96-06/96111269 35 200814050 propylene methoxypropyl) hydroxypropyl isocyanate, bis(2-methylpropoxy butyl) hydroxybutyl isocyanurate, three (2_Propyleneoxyethyl)isocyanate, tris(2·acryloxypropyl)isocyanate, bis(2-propenyloxybutyl)isocyanide Acid ester, tris(2-mercaptopropenyloxyethyl)isocyanate, tris(2·methacryloxypropyl)isotrimeric acid; cyanate, tris(2-fluorenyl) Acryloxybutyl) iso-cyanuric acid vinegar or the like. In addition, it is preferable to increase the modulus of elasticity at a high temperature: tricyclodecane dimethyl-alcohol mono(meth) acrylate or tricyclodecane diethanol bis(indenyl) acrylate. In the case where an acrylic monomer having a high crosslinking density and an acrylic monomer having a rigid structure in a crosslinked structure are used in combination, the following may be used. Namely, one or more specific compounds of the acrylic monomer having a high crosslinking density as described above are selected. Further, specific compounds having an acrylic monomer having a rigid structure among the above-described crosslinked structures described above are selected. Then, the compounds are used in combination at any ratio according to a wide desired elastic modulus. (Method of obtaining an ultraviolet curable resin having a shrinkage ratio of two) • In the case of an ultraviolet curable resin, the shrinkage ratio means a hardening shrinkage ratio. The rate of hardening shrinkage is a ratio of density change upon hardening of the density before hardening. Therefore, in order to increase the shrinkage ratio, the density change at the time of hardening can be increased. Specifically, when an ultraviolet curable resin is formed using an acrylic monomer, the density of the acrylonitrile group can be increased. In other words, it is possible to use an aromatic acid monomer which is a foreigner. Examples of the acrylic monomer having a high density of f are a polyfunctional acrylic monomer (polyfunctional (meth) acrylate) having a small molecular weight per propylene group. As a specific example of such a polyfunctional acrylic monomer (polyfunctional (methyl) propylene 312XP / invention specification (supplement) / 96-06 / 9611269 % 200814050 oleic acid vinegar), the elastic modulus of the following can be used. The resin is also the same as the dish (for example, 150. The same as the bismuth ester. /" The polyfunctional (methyl) propyl high, such as 15 〇. It is changed to the tenth month of the moon, for example, as in the above "method of obtaining a resin having a high modulus of elasticity under high temperature (for example, 15 〇.)" / ^ 15〇C) towel and right _ | m An acrylic monomer having a rigid structure in the parent structure is used. The content of the rigid-structured diterpenoid in the crosslinked structure may be such that the desired elastic modulus and the content of the fine years can be obtained. (Method of obtaining a resin having a small modulus of elasticity at room temperature (for example, 3 Å.) A specific method of forming a resin layer using an ultraviolet curable resin (more specifically, a radical ultraviolet curable resin) will be described below. In order to reduce the elastic modulus of the ultraviolet curable resin at 3 〇t, the density of the ultraviolet curable resin can be reduced. Specifically, it can be used to form an ultraviolet curable resin by using an acrylic monomer. A method of combining an acrylic oligomer having a large molecular weight and having a soft structure and a monofunctional acrylic monomer, each having a soft structure and a monofunctional acrylic monomer. The content ratio can be appropriately controlled for the purpose of obtaining a desired elastic modulus. Specific examples of the acrylic oligomer having a soft structure include a (meth)acrylic acid amine group containing a polyether or a polyester diol. An acrylic oligomer such as a formate or a polyalkylene glycol diacrylate. Examples of the monofunctional acrylic monomer include ethyl (meth)acrylate. , (methyl) acetobutyl vinegar, (methyl) propionate 2-ethylhexyl, 312XP / invention instructions (supplement) / 96-06/96111269 37 200814050 (meth) acrylate, Tridecyl (meth)acrylate, cetyl (meth)acrylate, octadecyl (decyl)acrylate, isoamyl (meth)acrylate, isodecyl (meth)acrylate , (fluorenyl) acrylate isostearate, 2-hydroxyethyl (meth)acrylate, 3-chloro-2-hydroxypropyl (meth)acrylate, methoxyethyl (meth)acrylate, ( Mercapto)butyloxyethyl acrylate, nonylphenoxyethyl (meth)acrylate, 2-hydroxy-3-phenylphenoxypropyl (meth)acrylate, and the like.

(獲得收縮率小之樹脂之方法） 於紫外線硬化性樹脂之情況下，所謂收縮率係指硬化收 縮率。硬化收縮率為相對於硬化前密度之硬化時之密度變 化的比例。因此，為了減小收縮率，可減小硬化時之密度 、交化。具體而言，於使用丙烯酸系單體而形成紫外線硬化 性樹脂之情況，可組合每1個丙烯醯基之分子量較大且分 子中丙烯醯基少之丙烯酸系寡聚物及丙烯酸系單體。丙烯 酸系募聚物及丙烯酸系單體之含有比率，可以獲得所期望 之彈性率為目的而進行適當控制。 作為丙烯酸系寡聚物之具體例，可使用與上述「 溫（例如301)下之彈性率小之樹脂之方法」中之㈣相同 者。作為丙烯酸系單體之具體例，可使用與上述「獲得常 溫（例如30T：)下之彈性率小之樹脂之方法」中說明:單官 能丙烯酸系單體相同者。 [3 ·紫外線硬化性樹脂膜5之半硬化] 如圖l(b)(b—1)所示，對設置於壓模4表面上之紫外喰 硬化性樹賴5照射紫外線UV，使紫外線硬化性樹脂膜 312XP/發明說明書(補件)/96-06/96111269 38 200814050 5半硬化。 作為用以使紫外線硬化性樹脂膜5硬化之且 法，可列舉： /、體方 U)減少紫外線照射量。 (b)於存在氧之環境下照射紫外線UV。 • (c)組合使用（a)與（b)。 - 根據所用之紫外線硬化性樹脂之種類之性質，適當使用 ⑩士述方法（a)〜（c)。圖l(b)(b-l)為上述（c)之例。即，於大 氣環境下減少紫外線照射量，使紫外線硬化性樹脂膜5 化。 以下’對各個方法進行具體說明。 於減少紫外線照射量之情況，可考慮使用減弱光量本身 之情況及減少照射時間之情況之任一者或兩者。 作為’、外線UV之光量，通常為50 mW/cm2以下，較佳 40 mW/cm2以下，更佳30 mW/cm2以下。 9 另一方面’為了更確實地進行紫外線硬化性樹脂膜5之 半硬化，作為紫外線UV之光量，通常為lmW/cm2以上， 較佳5 mW/cm2以上，更佳7 mW/cm2以上。 若於上述數值範圍内，則可發揮剝離性限度變大、易於 進行工業生產之優勢。 為了使紫外線硬化性樹脂膜5之硬化停留於適當階 段，紫外線UV之照射時間通常為1〇秒以下，較佳5秒 以下’更佳3秒以下。 另一方面，就確實進行半硬化而言，紫外線UV之照射 312χΡ/發明說明書(補件)/96-06/96111269 39 200814050 時間，通常為0.1秒以上 上0 較佳0.5 秒以上，更佳1秒以 若於上述數值範圍内，則可 易進行工案4$揮可剝離性限度變大、容 ί二==!。於減少氧之環境(例如，氮環境) 下#、?、射兔外線UV之情況，於7土及 h况奴佳係縮短照射時間。於此情 況下，照射時間通常為（U秒以上， =]於此b -方面’照射時間較佳為3秒以下。又土 . &以上。另 紫外線硬化性樹脂多數為具有難以於存在氧之環境中 進行硬化之性«的_。㈣料制自由 線硬化性樹脂之情況，將有空氣中之氧與自由基反應而阻 破硬化之傾向。因此於在方@ 、伟在乳之壌1兄下照射紫外線UV亦 為使紫外線硬化性樹脂膜5半硬化之有效方法之一。 於存在氧之環境下進行紫外4tuv照射之情況下之氧濃 度，以〇高比表示通常為〇1以上，較佳〇2以上，更 仫0.25(約大氣中之氧濃度）以上。若於該範圍内，則可良 好地控制由氧引起之聚合阻礙。 另一方面，氧濃度之上限係大氣全部為氧（1〇〇%氧）。 再者，圖l(b)(b-l)中，係自紫外線硬化性樹脂膜5侧照 射紫外線UV，但當然亦可自壓模4側照射紫外線uv。但， 於自壓模4側照射紫外線uv之情況下，較佳係極力減少 壓模4中存在之妨礙紫外線照射之缺陷。 [4.於減少氧濃度之環境下藉由紫外線照射之硬化] 本實施形態中，如圖1(b)(b—2)所示，係使紫外線硬化 性樹脂膜5半硬化後，於減少氧濃度之環境下照射紫外線 3 nXP/發明說明書(補件)/96-06/96111269 40 200814050 UV，使紫外線硬化性樹脂膜5進一步硬化而獲得轉印層 6。於該圖内，表示了作為減少氧濃度之環境之一例，於 氮環境下照射紫外線UV，使紫外線硬化性樹脂膜5進一 步硬化而獲得轉印層6之步驟。 該步驟+之硬化進行至紫外線硬化性樹脂膜5表面（圖 l(b)(b—2)令紫外線照射側之表面）無黏性（黏著性）。再 者，所謂無黏性（tack function)，具體而言，係指紫外線硬 化性樹脂膜5具有用手指觸碰上述表面無黏疼感程度之 表面性。 該步驟中，紫外線硬化性樹脂膜5硬化而形成轉印層 6 ’稭此亦發揮以下優勢。@，於下述下中間層3斑轉印 黏時，轉印層6之表面成為無黏性之狀態，故變得 ====轉印層6中。其結果，無需以抑制氣泡 二中：目的而使下，間層3與轉印層6之接黏 …、二中進仃。換言之，下中間層3 得容易於大氣中進行。 層之接黏交 本實施形態中，係於氮環境 化之方彳丁—. 衣兄下進仃。然而，即使如氮淨 式不遮斷氧而於含既定濃产气夕 可藉由例如πν 展境下進行，亦 昭射時严 |外線uv<照射量（提高照射光量，延長 …、射4間），而形成轉印層6。 佳，氧濃度通常設為5%以下，較佳1%以下，更 硬化之㈣T。1此將有良好地使紫外線硬化性樹脂膜5 方面’ I辰度越小越佳，於玉業方面考慮，下限值 312XP/發明說明書(補件)/96-06/96111269 4] 200814050 為100 ppm左右。 再者，藉由於氮環境下進行硬化， 相同表面性之轉印層6所需要之照射紫外具: 蚯進仃先里调即，即可使硬化變得容 ^ _ 淨化之情況下，為了獲得且有 丁 ；不進行氮 〇又付具有既定表面性 有需要非常強之UV光之情況（ At J*曰’亦 況）。 月凡（而要同旎力紫外線燈之情 紫外線照射量，可以獲得具有既定表面 的而適當控制。具體而言，作為 τ ρ θ為目 馬系外線uv之光量，诵奮 為200 mW/cm以下，較佳 wW/ 2 各 w/cm以下，更佳100 卩下。若於上述數值範圍内，則即使於使用極性 而之壓模4(例如’聚碳酸醋樹脂製之壓模)之情況，亦可 :損害轉印層6與壓模4之剝離性，而容易使轉印層6硬 化0 另-方面，為了獲得具有既定表面之轉印層6，作為紫 外線UV之光量’通常為30 mW/cm2以上，較佳5〇 mw/cm2 以上’更佳70 mww以上。若於上述數值範圍内，則紫 外線硬化性樹脂膜5之表面硬化可充分進行，而容易形成 具有既定表面之轉印層6。 紫外線UV之照射時間可以獲得具有㈣表面之轉印層 6為目的適當控制。具體而言，照射時間，通常為2〇秒 以下，較佳15秒以下，更佳1〇秒以下，再更佳$秒以下， 尤佳3秒以下’最佳2秒以下。 3 UXP/發明說明書(補件)/96-06/96111269 200814050 另-方面，為了獲得具有既定表面之轉印層6，紫外線 UV之照射時間，通常為0.2秒以上，較佳〇 5秒以上，更 佳0 · 7秒以上。 [5·轉印層之膜厚] 經上述步驟，轉印層6形成於壓模4上。轉印層6之膜 厚，就確保轉印之凹凸形狀之硬度、及轉印層6^壓模4 之剝離性而言，通常大於〇Mm，較佳1μιη以上，更佳 以上。 ♦另-方面，轉印層6之膜厚，通常為2()牌以下，較佳 15 以下，更佳10 μιη以下，再更佳5 以下。若轉 印層6之膜厚於上述範圍内，則可發揮容易確保轉印之凹 凸形狀之硬度，及轉印層6與壓模4之剝離性，且容易控 制碟之魅曲的優勢。 斗寸別係若將轉印層6之膜厚設為1 〇 以下，則容易發 揮如下優勢。第一，具有即使省略一邊藉由旋塗法延伸紫 _外線硬化性樹脂、一邊照射紫外線UV等之操作，亦可容 易地使轉印層6之膜厚分佈成為良好的優勢。 第二，因薄化轉印層6之膜厚，故亦具有容易獲得紫外 線硬化性樹脂膜5之半硬化狀態之優勢。 第三，具有考慮到轉印性或剝離性而於轉印層6中使用 堅固之紫外線硬化性樹脂或收縮率大之紫外線硬化性樹 脂之情況，於此情況下若可薄化轉印層6之膜厚，則容易 減少光記錄媒體整體之翹曲。 (3)轉印層積層壓模200與第1記錄媒體1〇〇之接合 312XP/發明說明書(補件)/96-〇6/%111269 43 200814050 (adhesion)步驟 之==圖2(e)所示，以轉印層6與下中間層3相對面 ^方，將轉印層積層壓模2〇〇載置於下中間層3 )’、/、後，接黏下中間層3與轉印層6(c_2)。 相：圖Me—”所以轉印層6與下中間層3 轉印層積層壓模_載置於下中間層3 中間層1 層6與記錄再生功能層2之間存在下 之Ϊ置方法無特別限制。又’轉印層積層壓模200 太於大氣中或真空中之任一環境下進行。其中， 辦只施开八％中’較佳係於減壓環境下進行接合步驟。更且 體:言，較佳係於減壓環境下進行上操減 壓環境，具體而言可列舉真空狀離。 作為減 =係於減壓環境下進行載置之理由為如下所示。即， ⑪Pa及下中間層3之各自表面並非完全平坦，具有細 微之凹凸。因此，若於大氣 ^ 、 中間層3之界面可能進入置，則轉印層6及下 而存在於中間声7中夕^乳。如此之空氣進入’將成泡 门S …、、而，就光學性而言較佳係減少上 為、了抑制上述空氣之進入(換言之，泡之 )較t為於減愿環境_進行載置。 :處:：為減壓環境之具體愿力’可列舉通常為動 以下，較UGPa以下，更佳5Qpa以下。 另-方面，減麼環境可列舉通常為心以 5(Method of obtaining a resin having a small shrinkage ratio) In the case of an ultraviolet curable resin, the shrinkage ratio means a hardening shrinkage ratio. The rate of hardening shrinkage is a ratio of density change upon hardening of the density before hardening. Therefore, in order to reduce the shrinkage ratio, the density and cross-linking at the time of hardening can be reduced. Specifically, when an ultraviolet curable resin is formed by using an acrylic monomer, an acrylic oligomer and an acrylic monomer having a large molecular weight per propylene group and a small amount of propylene groups in the molecule can be combined. The content ratio of the acrylic acid-based polymer and the acrylic monomer can be appropriately controlled for the purpose of obtaining a desired elastic modulus. As a specific example of the acrylic oligomer, the same as (4) of the above-mentioned "method of resin having a small modulus of elasticity (for example, 301)" can be used. As a specific example of the acrylic monomer, the above-mentioned "method of obtaining a resin having a small modulus at room temperature (for example, 30T:)" can be used. [3. Semi-hardening of the ultraviolet curable resin film 5] As shown in Fig. 1 (b) (b-1), the ultraviolet ray curable tree 5 provided on the surface of the stamper 4 is irradiated with ultraviolet rays UV to harden the ultraviolet rays. Resin film 312XP / invention manual (supplement) / 96-06/96111269 38 200814050 5 semi-hardening. The method for curing the ultraviolet curable resin film 5 is as follows: /, the body U) The amount of ultraviolet irradiation is reduced. (b) Irradiation of ultraviolet UV in the presence of oxygen. • (c) Use (a) and (b) in combination. - The methods (a) to (c) of 10 are used as appropriate depending on the nature of the type of ultraviolet curable resin used. Fig. 1(b)(b-1) is an example of the above (c). In other words, the amount of ultraviolet irradiation is reduced in an atmospheric environment, and the ultraviolet curable resin film is made into a film. The following describes each method in detail. In the case of reducing the amount of ultraviolet radiation, either or both of the case of reducing the amount of light itself and the case of reducing the irradiation time can be considered. The amount of light of the external light UV is usually 50 mW/cm2 or less, preferably 40 mW/cm2 or less, more preferably 30 mW/cm2 or less. On the other hand, in order to more reliably perform the semi-curing of the ultraviolet curable resin film 5, the amount of ultraviolet light UV is usually lmW/cm2 or more, preferably 5 mW/cm2 or more, more preferably 7 mW/cm2 or more. When it is within the above numerical range, the peeling limit is increased and the industrial production is easy. In order to keep the curing of the ultraviolet curable resin film 5 at an appropriate stage, the irradiation time of the ultraviolet ray UV is usually 1 sec or less, preferably 5 sec or less, more preferably 3 seconds or less. On the other hand, in the case of semi-hardening, ultraviolet UV irradiation 312 χΡ / invention manual (supplement) / 96-06/96111269 39 200814050 time, usually 0.1 second or more, above 0, preferably 0.5 second or more, more preferably 1 If the second is within the above numerical range, the workable 4$ detachable limit can be easily increased, and the thickness can be increased. In the environment of reducing oxygen (for example, nitrogen environment), #,?, shooting the external UV of the rabbit, in 7 soil and h condition slaves to shorten the irradiation time. In this case, the irradiation time is usually (U seconds or more, =] in this b-direction, the irradiation time is preferably 3 seconds or less. In addition, the soil is more than the above. The ultraviolet curable resin is mostly difficult to exist in the presence of oxygen. The hardening property in the environment «. (4) In the case of a free-line curable resin, there is a tendency for oxygen in the air to react with free radicals to prevent hardening. Therefore, it is in the side @, Wei in the milk Irradiation of UV light under the 1st brother is also one of the effective methods for semi-hardening the ultraviolet curable resin film 5. The oxygen concentration in the case of ultraviolet 4tuv irradiation in the presence of oxygen is usually expressed as 〇1 or more in the height ratio. Preferably, it is 2 or more, more preferably 0.25 (about the oxygen concentration in the atmosphere) or more. If it is within this range, the polymerization inhibition by oxygen can be favorably controlled. On the other hand, the upper limit of the oxygen concentration is all of the atmosphere. In the case of the ultraviolet curable resin film 5 side, the ultraviolet ray UV is irradiated to the ultraviolet curable resin film 5 side, but it is of course possible to irradiate the ultraviolet uv from the side of the stamper 4, however, in the case of (b) (b). In the case of irradiating ultraviolet uv from the side of the stamper 4, The best system is to reduce the defects that hinder the ultraviolet irradiation in the stamper 4. [4. Hardening by ultraviolet irradiation in an environment where the oxygen concentration is reduced] In the present embodiment, as shown in Fig. 1 (b) (b-2) In the case where the ultraviolet curable resin film 5 is semi-hardened, the ultraviolet curable resin film 5 is further irradiated with ultraviolet rays 3 nXP/invention specification (supplement)/96-06/96111269 40 200814050 UV in an environment where the oxygen concentration is reduced. In the figure, the transfer layer 6 is obtained as an example of an environment in which the oxygen concentration is reduced, and the ultraviolet curable resin film 5 is further cured by irradiation with ultraviolet rays UV in a nitrogen atmosphere to obtain a transfer layer 6. The hardening of this step + is carried out until the surface of the ultraviolet curable resin film 5 (the surface of the ultraviolet irradiation side in Fig. 1(b) (b-2) is not sticky (adhesiveness). Further, the so-called tack function Specifically, the ultraviolet curable resin film 5 has a surface property in which the surface is not sticky with a finger. In this step, the ultraviolet curable resin film 5 is cured to form a transfer layer 6' Also take advantage of the following advantages. @ When the intermediate layer 3 is transferred to the lower layer, the surface of the transfer layer 6 becomes in a non-adhesive state, so that it becomes ==== in the transfer layer 6. As a result, it is not necessary to suppress the bubble two: The purpose is to make the interlayer 3 and the transfer layer 6 adhere to each other. The second intermediate layer 3 is easily formed in the atmosphere. The adhesion of the layers is in the nitrogen environment. The fangs of the 彳 — . . . . . 然而 然而 然而 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃 仃The amount of irradiation (increasing the amount of light to be irradiated, extending, and spraying 4) forms the transfer layer 6. Preferably, the oxygen concentration is usually 5% or less, preferably 1% or less, and more hardened (IV) T. 1 This will have a good effect on the UV curable resin film 5, the smaller the I, the better, in terms of jade industry, the lower limit 312XP / invention manual (supplement) / 96-06/96111269 4] 200814050 About 100 ppm. Furthermore, by curing under a nitrogen atmosphere, the irradiation of the same surface of the transfer layer 6 is required to be irradiated with ultraviolet light: 蚯 仃 仃 里 调 , , , , 硬化 硬化 硬化 硬化 硬化 硬化 硬化 硬化 硬化 硬化 净化 净化And there is a case where there is a need for a very strong UV light with a predetermined surface property (At J*曰').                                                       In the following, wW/2 is preferably w/cm or less, more preferably 100 Torr. If it is within the above numerical range, even if a mold 4 of a polarity (for example, a stamper made of polycarbonate resin) is used. Alternatively, the peeling property of the transfer layer 6 and the stamper 4 may be impaired, and the transfer layer 6 may be easily hardened. In addition, in order to obtain the transfer layer 6 having a predetermined surface, the amount of light as ultraviolet UV 'is usually 30. mW/cm2 or more, preferably 5 〇mw/cm2 or more, more preferably 70 mww or more. If it is within the above numerical range, the surface hardening of the ultraviolet curable resin film 5 can be sufficiently performed, and transfer having a predetermined surface can be easily formed. Layer 6. The irradiation time of the ultraviolet ray UV can be appropriately controlled for the purpose of obtaining the transfer layer 6 having the surface of (4). Specifically, the irradiation time is usually 2 sec or less, preferably 15 sec or less, more preferably 1 sec or less. Better than $ seconds, especially better than 3 seconds' Preferably, it is less than 2 seconds. 3 UXP/Invention Manual (Supplement)/96-06/96111269 200814050 In another aspect, in order to obtain the transfer layer 6 having a predetermined surface, the irradiation time of ultraviolet UV is usually 0.2 second or more, preferably 〇 5 seconds or more, more preferably 0 · 7 seconds or more. [5. Film thickness of the transfer layer] Through the above steps, the transfer layer 6 is formed on the stamper 4. The thickness of the transfer layer 6 ensures transfer The hardness of the uneven shape and the peeling property of the transfer layer 6 and the stamper 4 are usually larger than 〇Mm, preferably 1 μm or more, more preferably ♦ otherwise, the film thickness of the transfer layer 6 is usually 2 or less, preferably 15 or less, more preferably 10 μm or less, still more preferably 5 or less. When the film thickness of the transfer layer 6 is within the above range, the hardness of the uneven shape of the transfer can be easily ensured, and The peeling property of the transfer layer 6 and the stamper 4 is easy to control the advantage of the embossing of the disc. When the film thickness of the transfer layer 6 is set to 1 〇 or less, the following advantages are easily exhibited. An operation of irradiating ultraviolet ray UV or the like by stretching a violet-external curable resin by spin coating even if omitted It is easy to make the film thickness distribution of the transfer layer 6 a good advantage. Second, since the film thickness of the transfer layer 6 is thinned, it is also advantageous in that the semi-hardened state of the ultraviolet curable resin film 5 is easily obtained. A case where a strong ultraviolet curable resin or an ultraviolet curable resin having a large shrinkage ratio is used in the transfer layer 6 in consideration of transferability or releasability, and in this case, the film of the transfer layer 6 can be thinned. When it is thick, it is easy to reduce the warpage of the entire optical recording medium. (3) Bonding of the transfer laminated laminate mold 200 to the first recording medium 1 312XP / invention manual (supplement) / 96 - 〇 6 / % 111269 43 200814050 (adhesion) step == as shown in Fig. 2(e), with the transfer layer 6 and the lower intermediate layer 3 facing each other, the transfer laminated laminate mold 2 is placed on the lower intermediate layer 3)' After the /, and then, the intermediate layer 3 and the transfer layer 6 (c_2) are bonded. Phase: Fig. Me—“So the transfer layer 6 and the lower intermediate layer 3 are transferred and laminated laminating molds _ placed under the lower intermediate layer 3, the intermediate layer 1 layer 6 and the recording and reproducing functional layer 2 In particular, the 'transfer laminated laminating mold 200 is carried out in any environment in the atmosphere or in a vacuum. Among them, only 8% of the application is carried out, preferably in a decompression environment. In other words, it is preferable to carry out a pressure-reduced environment in a reduced-pressure environment, and specifically, it is a vacuum-like separation. The reason why the reduction is performed in a reduced-pressure environment is as follows. That is, 11 Pa The respective surfaces of the lower intermediate layer 3 are not completely flat and have fine irregularities. Therefore, if the interface between the atmosphere and the intermediate layer 3 may enter, the transfer layer 6 and the lower layer are present in the intermediate sound 7 Such air enters 'will become the bubble door S ..., and, in terms of optical properties, it is better to reduce the above, and to prevent the entry of the above air (in other words, the bubble) than to reduce the wish environment _ carry : : : :: The specific willingness of the decompression environment can be listed as usually below. UGPa less, further more preferably less 5Qpa - aspects include reducing environment it is usually 5 to heart

Pa以上’更佳20 pa以上。若於上述範圍内，則可於確實 312XP/發明說明書(補件y9W)6/961丨1269 44 200814050 地，持樹脂中之揮發成分的狀態下容易地接合。 為繼:二圖rc)(c-2)所示，使下中間層3與轉印層6接 黏可错由如下方法來實現。例如，於下+問展3矣 面或轉印層6表面塗佈接黏劑，或者 ^曰' 式馘1¾ s 士 、丨τ间層3表面 ㈣“ 6:::感難接黏片。又’例如於下中間層 = 照射紫外線UV*接黏下中間層3與轉 :工業上’較佳係下中間層3及轉印層6均由 硬 uv，成中，载置轉印層積層麼模2〇〇後，照射紫外線 接黏下中間層3與轉印層6的方法。再者，於使用 以方法之情況，較佳係下中間層 、 於未硬化或半硬化之狀態。其；因性編 於進行下中間層3與轉印層 黏i 下’ === 生(用手指觸碰時之黏著感)，故可藉由使下 翔5曰接a面具有黏者性’而變得容易良好地進行接 =射=紫外線照射方向無特別限制，於自壓模4侧進行 較佳係壓模4具有對紫外線υν之透光性。 (4)自軺印層6剝離壓模4之步驟 間層3與轉印層6後，自轉印層6剝離壓模 反、；：剝離方法亦無特別限制。通常，將刀口自 二板外徑侧插人至壓模4與轉印層6之間，切入 Γ且？氣而自轉印層6剝離壓模4(圖2⑷中未圖示)。 更“而言，於光記錄媒體為圓盤狀之情況，以下述方 312XP/發明說明書(補件)/96-06/96111269 45 200814050 :進：：=吸附内周’於光記錄媒體内周切入刀 攻；/、吹入空氣一邊分離轉印層ό與壓模4。葬 d =二而於第1記錄媒體1〇。上’形成具有下中 間層3及轉印層6之中間層7。 B·第2製造方法 下= 中，係於接合步驟中形成下中間層。除了 下中間層之形成與上述第1製造方法不同以外，i他摔作 =第1製物，相同，故以下僅對不同部分進;=作 ，、體而吕，第2製造方法中，係於第 中不m由心 甲係於弟1把錄媒體製造步驟 成下中間層’而於進行接合步驟時形成下中間声。 圖3係用以說明第2像』t、、土 & & /v、 曰 的亍音a丨面R 。，接& v驟之—實施形態 係對應用以說明第1製造方法之圖 ()圖。再者，W 3中，對與圖i或圖2共 素，使用相同符號表示。又，通當， 構成要 於中心又通吊，心己錄媒體為圓盤狀， 、 形成中孔，但圖3中省略對中孔之記载。 | 以下說明各圖之概略。 圖3⑷表示將硬化性樹脂8〇塗佈於記錄再 上之狀態。進而，表示為了載置於硬化性樹 ：： 將轉印層積層壓模200配置於上方之樣子。 上而 圖3(b)表示以硬化性樹脂8〇與轉印層 式，於硬化性樹脂80上載置轉印層積層壓模 始延伸硬化性樹脂8〇之樣子。 、 歼 圖3⑷表示硬化性樹脂8〇延伸至第 轉印層積層壓模200兩端部之狀態。 t嫖版1〇〇及 312XP/發明說明書(補件)/96-〇6/96 i丨i 269 46 200814050 圖3⑷表示照射紫外線uv，形成下中間層3 層7之樣子。 τ间 邊對本實施形態中之接合步驟 以下，——邊參照圖3， 進行說明。 首先，如圖3(a)所示，將硬化性樹脂8〇塗佈於 錄媒體100(記錄再味#台bμ ^ ° 球冉生功此層2)上。作為硬化性樹脂80之 材料，可使用與第丨製造方法中 ^ ^ L π τ %卜中間層3中使用硬化 性樹脂之情況相同者。 使：：：：：作為硬化性樹· 80,於本實施形態下，係 '、、、化性樹脂，當然亦可使用熱硬化性樹脂等其 他之硬化性樹脂。 其中’考慮到下中間層3之膜厚控制、工業生產等，較 佺係硬化性樹脂8〇為紫外纟 、 夕μ +一 身、卜、，泉硬化性樹脂。硬化性樹脂80 之塗佈方法亦可使用先前公知之方法。 此處，本實施之形能φ ^ 心中可於記錄再生功能層2上直接 主佈硬化性樹脂8 〇，當缺亦 、方了視需要於記錄再生功能層2 上形成其他層後塗佈硬化性樹脂8〇。 再者，圖3(a)中雖劣欢罔— 形， 略圖不，於基板1為圓盤狀，中心 t成中孔之情況下形成 涂德、s # 土 卜肀間層3時，硬化性樹脂80之 主佈通带較佳係以下述方 ^ ^ 乃式進行。即，於大於中孔外徑之 既疋+徑位置，將硬化 進行涂佈。 对月曰80滴下成（dispence)環狀而 再者’如圖3(a)所示，箓 L 弟1 C錄媒體100係由基板1及 5己錄再生功能層2播# 。、嶺而，於基板1表面設置凹凸， 312XP/發明瞧書(補件)/96-06/96111269 άΊ 200814050 ^ L上形成記錄再生功能層2。另一方面，轉印層積 二系由壓模4及轉印層6構成。於壓模4表面， ‘开間層7之凹凸形狀之轉印用凹凸形狀。繼而， 1憾=印用凹凸形狀之表面上形成轉印層6。對於第 方Vi 00或轉印層積層壓模200等，因與第1製造 方法相同，故而此處省略說明。 對：！古如圖3(b)所示，以硬化性樹脂80與轉印層6相 200 + ±式，於硬化性樹脂80上载置轉印層積層壓模 m，較佳係以盡可能不介人空氣或不進入氣泡地 表面卿印屌6 # j即’ f先使記錄再生功能層2之 声而p/ 表面幾乎平行地靠近而對置。繼而，於各 ^ :之空隙處滴下（dispenee)硬化性樹脂8〇 下t立即使硬化性樹脂8〇與上述各表面接黏。 ^而思開始延伸硬化性樹脂8〇。於本實施形態中 馨由^ 印層積層壓旦 精 _及轉印層積層壓模之：二擠 脂80。藉由上、十、^ ^之方式’延伸硬化性樹 膜之膜將容易使硬純㈣⑼所形成之 延伸於所期望之範圍。當然，硬化性樹脂80之 延伸亦可错由旋塗法等進行。 又 據j而如圖3⑷所不’於硬化性樹脂80到達第卜己钎 及轉印層積層壓模2。。之兩端後，高 月&匕〇甩Γ及轉印層積層壓模200 ’將多餘之硬化性樹 月曰80甩出至外部。藉此，容易更精密地控制硬化性樹= 312XP/發明說明書(補件)/96-_61„269 48 200814050 80所形成之臈的膜厚。 7 成下中間層3。 乂上述方法’由硬化性樹脂80形 鼷而如圖3(d)所述’自壓模4側照射紫外線而使 硬化性樹脂80(紫外μ & & ，卜線硬化性樹脂）硬化。其結果為，以轉 印層6與弟1 §己錄媒辦1 n rn ’、00(5己錄再生功能層2)之間存在下 中間層3之狀態，接合韓^展 ~印層積層壓模200與第1記錄媒 體 100。 第2製造方法之優勢之一 另之 為可於大氣中進行接合步 驟。具體而言，圖3所示夕夂ρ ^/ 厅下之各刼作（至少圖3(a)至圖3(c) 之操作）’可於大氣中進扞0盆么士 選仃其結果為可發揮簡化製造裝 置構成之優勢。 可於大氣中進行接合步驟之理由係如下所示。即，於 轉印層積層壓模_載置於硬倾樹脂8g上後延伸硬化 性樹脂8G時’將存在於難4與記錄再生功能層2之間 之空氣’由硬化性樹脂80排出至第i記錄媒體i · 印層積層壓模200外側。其結果為，空氣變得難以進入‘ 模4與硬化性樹脂80(進而下中間層3)之間，從而 壓模4及下中間層3之界面上所產生之泡。其結果為，接 合步驟可不於真空中進行。 如上所达’形成中間層7 ’進行壓模4之剝離步驟。 於該點，可與第丨製造方法（參照圖2(d))相同。對於= 步驟，已經說明，故此處省略說明。 雕 C.其後之步驟 本實施形態中，如上所述，製造具備表面上具有凹凸形 312XP/發明說明書(補件)/96-06/96111269 49 200814050 狀且具有下中間層3及 體。以下，對1後之牛明社 中間層7的光記錄媒 耵八傻之步驟進行說明。 (1) 上部圮錄再生功能層等之形成 圖4係用以說明應用本發明實 1000之較佳-例的示咅^ R "-之光。己錄媒體 表示於藉由圖i、圖2::二具體广言，圖4係用以 q ϋ 圖3所付之中間層7上依序積層 上部§己錄再生功能層8、接釉恳Q ;西 ^ ^ ^ 接黏層9、及被覆層1〇，藉此獲 之示意剖面圖。再者，對於與圖^ 圖二圖3共同之構成要素係使用同一符號表示。 圖4所示，於形成有溝哎凹炕來## 7)上，形成上部記！… 之轉印層6(中間層 8之其太之μ接:' 生功能層8。上部記錄再生功能層 欽二'冓成與記錄再生功能層2大致相同。1中， 車父佳係上部記錄再味六〜 、 穿透。因此，上部記錄=:使記錄再生用之雷射光[ 整。 " 生功能層8之各層膜厚需適宜調 (2) 被覆層等之形成 於設置所需層數之記錄再生功 部記錄再生功能層8後），如同4餅_口 r σ又置上 再生功能層(圖4中為U丄所不，於最上層之記錄 接黏声卜晉姑Λ 錄再生功能層8)上面，介隔 接置被覆層10。接黏層9及被覆層10之 形成順序然特別限制。 :為接黏層9 ’通常可使用接黏劑、 外線硬化性樹脂等。又，作為被覆層 聚恤樹脂或環婦煙聚合物等低吸脂吏= 312ΧΡ/發明說明書(補件)/96·〇6/96111269 50 200814050 等。較佳係以確保光碟翹曲等特性 板相同之材料，㈣〜、H、光碟基 性樹脂等使接黏層9與被覆μ 1() ^ ” 、、在更化 t A 復層10 一體化。此時所佶用夕 土外線硬化性樹脂嗵常係1000姆"以上 藉此可以旋塗法形成厚50_〜2〇〇_之膜。门士又， 係藉由旋塗法等方法或直接貼附而形成。 接黏層9之厚度無特別限制，通常為 以下。藉由於該範圍内，容易 -30帅 料之優勢。 ^輝衣仏均勻厚度之黏著材 另一方面，被覆層10之厚度，通常為 r:v藉由於此範圍内’容易形成可對應讀取物：Above Pa is better than 20 pa. If it is within the above range, it can be easily joined in a state in which the volatile component in the resin is held in the 312XP/Invention Manual (Supplement y9W) 6/961丨1269 44 200814050. For the following, as shown in the second figure rc) (c-2), the adhesion of the lower intermediate layer 3 to the transfer layer 6 can be achieved by the following method. For example, the adhesive is applied to the surface of the lower surface of the lower surface or the surface of the transfer layer 6, or the surface of the interlayer layer 3 of the 馘 ⁄ 丨 丨 丨 丨 四 四 四 四 四 四 四 四 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 Also 'for example, in the lower middle layer = UV-irradiated UV* adhesive under the intermediate layer 3 and the transfer: industrially, the lower intermediate layer 3 and the transfer layer 6 are all made of hard uv, in the middle, and the transfer layer is placed. After the mold is used, the method of irradiating the intermediate layer 3 and the transfer layer 6 by ultraviolet rays is irradiated. Further, in the case of using the method, the intermediate layer is preferably in an unhardened or semi-hardened state. Because the sex is programmed in the lower middle layer 3 and the transfer layer is sticky i ' === raw (adhesive feeling when touched with a finger), so it can be made sticky by making the lower side 5 曰 a face Further, it is easy to carry out the connection = the direction of the ultraviolet irradiation is not particularly limited, and the preferred mold 4 has a light transmissive property against the ultraviolet ray ν on the side of the stamper 4 (4) peeling pressure from the squeegee layer 6 After the step 3 between the layer 4 and the transfer layer 6, the stamper is peeled off from the transfer layer 6. The peeling method is also not particularly limited. Usually, the knife edge is inserted from the outer diameter side of the second plate to the stamper 4 and Between the printing layers 6, the stamper 4 is peeled off from the transfer layer 6 (not shown in Fig. 2 (4)). Further, in the case where the optical recording medium is in the form of a disk, the following side 312XP/ Inventive specification (supplement)/96-06/96111269 45 200814050: In::=Adsorption inner circumference' is cut into the inner circumference of the optical recording medium; /, the transfer layer 分离 and the stamper 4 are separated while blowing air. The burial d = two and the first recording medium 1 〇. The upper layer 7 having the lower intermediate layer 3 and the transfer layer 6 is formed. B. Second Manufacturing Method Next = Medium, the lower intermediate layer is formed in the bonding step. Except that the formation of the lower intermediate layer is different from that of the first manufacturing method described above, i is the same as the first manufacturing method, and the same is true. Therefore, the following is only for the different parts; =,, and the body is the same, in the second manufacturing method, In the middle of the second, the heart is made by the heart of the brother 1 and the recording medium is made into the lower intermediate layer', and the lower intermediate sound is formed when the bonding step is performed. Fig. 3 is a diagram for explaining the second side of the second image 』t, earth && /v, 曰. And the embodiment of the first manufacturing method is shown in the figure. Further, in W 3, the same symbols as those in Fig. 1 or Fig. 2 are denoted by the same reference numerals. Moreover, the composition is required to be hoisted at the center, and the media has been recorded as a disc, forming a middle hole, but the description of the center hole is omitted in FIG. | The outline of each figure is explained below. Fig. 3 (4) shows a state in which the curable resin 8 is applied to the recording. Further, it is shown that the transfer laminated laminate mold 200 is placed on the upper side in order to be placed on the curable tree. 3(b) shows a state in which a curable resin 8 〇 and a transfer layer are placed on the curable resin 80, and a transfer lamination mold is used to stretch the curable resin 8 。. ( Fig. 3(4) shows a state in which the curable resin 8〇 is extended to both end portions of the first transfer laminate lamination mold 200. T嫖版1〇〇 and 312XP/Invention Manual (Supplement)/96-〇6/96 i丨i 269 46 200814050 Figure 3(4) shows how the ultraviolet uv is irradiated to form the lower intermediate layer 3 layer 7. The joining step in the present embodiment between the τ and the following will be described with reference to Fig. 3 . First, as shown in Fig. 3 (a), a curable resin 8 is applied onto a recording medium 100 (recording re-flavor #台bμ^球冉生功层2). As the material of the curable resin 80, the same as the case where the curable resin is used in the intermediate layer 3 of the second manufacturing method in the second manufacturing method can be used. In the present embodiment, other types of curable resin such as a thermosetting resin may be used as the curable tree. Among them, considering the film thickness control of the lower intermediate layer 3, industrial production, etc., the lanthanum-curable resin 8 〇 is an ultraviolet ray, a μ μ + body, a body, and a spring-curable resin. The method of applying the curable resin 80 can also be carried out by a previously known method. Here, in the shape energy φ ^ of the present embodiment, the curable resin 8 主 can be directly applied to the recording/reproducing functional layer 2, and when it is missing, it is necessary to form another layer on the recording and reproducing functional layer 2, and then harden the coating. Resin resin 8 〇. In addition, in Fig. 3(a), although the shape is inferior, the shape is not shown, when the substrate 1 is in the shape of a disk, and the center t is formed into the mesopores, the formation of the Tude, s# soil interdiction layer 3 is hardened. The main distribution band of the resin 80 is preferably carried out in the following manner. That is, it is hardened and applied at a position larger than the outer diameter of the mesoporous body. The 曰 曰 滴 滴 滴 滴 滴 滴 滴 disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp disp In addition, the surface of the substrate 1 is provided with irregularities, and the recording and reproducing functional layer 2 is formed on the 312XP/invention book (supplement)/96-06/96111269 άΊ 200814050. On the other hand, the transfer layer is composed of a stamper 4 and a transfer layer 6. On the surface of the stamper 4, the uneven shape of the uneven shape of the opening layer 7 is transferred. Then, the transfer layer 6 is formed on the surface of the uneven shape. The first Vi 00, the transfer laminated lamination mold 200, and the like are the same as those of the first manufacturing method, and thus the description thereof is omitted here. Correct:! As shown in Fig. 3(b), the transfer lamination mold m is placed on the curable resin 80 in a 200 + ± form of the curable resin 80 and the transfer layer 6, preferably as much as possible. The air or the surface that does not enter the bubble is 6# j, which is the first to make the recording and reproducing function layer 2 sound and the p/ surface is almost parallel to the opposite side. Then, the curable resin 8 was dispensed in the gap of each of the following: immediately, the curable resin 8〇 was adhered to the respective surfaces. ^ And think began to extend the hardening resin 8〇. In the present embodiment, the eucalyptus is laminated and the laminate is laminated: Extending the film of the curable tree film by means of the above, ten, and ^ ^ will easily extend the formation of hard pure (4) (9) to the desired range. Of course, the extension of the curable resin 80 can also be carried out by a spin coating method or the like. Further, according to j, as shown in Fig. 3 (4), the curable resin 80 is reached and the transfer laminated laminate mold 2 is reached. . After both ends, the high month & transfer and transfer laminate mold 200' removes the excess hardenable tree moon 80 to the outside. Thereby, it is easy to more precisely control the film thickness of the crucible formed by the hardenable tree = 312XP / invention specification (supplement) / 96-_61 „ „ „ s s s s s s s s s s s s s s s s s s s s s s s s s The resin 80 is shaped like a crucible, and as shown in Fig. 3 (d), the ultraviolet curable resin 80 is cured by ultraviolet rays from the side of the stamper 4, and the curable resin 80 (ultraviolet μ &&& curable resin) is cured. There is a state of the lower intermediate layer 3 between the printing layer 6 and the brother 1 § recording media 1 n rn ', 00 (5 recorded reproduction function layer 2), and the bonding embossing die 200 and the first Recording medium 100. One of the advantages of the second manufacturing method is that the bonding step can be performed in the atmosphere. Specifically, the various operations under the 夂 ρ ^ / hall shown in Fig. 3 (at least Figure 3 (a) to The operation of Fig. 3(c)) can be carried out in the atmosphere. The result is that the composition of the device can be simplified. The reason for the bonding step in the atmosphere is as follows. The transfer layer lamination mold _ is placed between the hard resin 8g and the hard curable resin 8G, and will exist between the hard 4 and the recording and reproducing functional layer 2 The air 'is discharged from the curable resin 80 to the outside of the i-th recording medium i · the laminate lamination mold 200. As a result, it becomes difficult for air to enter between the mold 4 and the curable resin 80 (and thus the lower intermediate layer 3). Thereby, the bubbles generated at the interface between the stamper 4 and the lower intermediate layer 3. As a result, the joining step may not be performed in a vacuum. As described above, the forming of the intermediate layer 7' performs the peeling step of the stamper 4. At this point, It can be the same as the second manufacturing method (refer to Fig. 2(d)). The description of the = step has been omitted, and the description is omitted here. The carving C. The subsequent steps In the present embodiment, as described above, the manufacturing has the surface unevenness. Shape 312XP / invention manual (supplement) / 96-06 / 9611269 49 200814050 shape and has a lower intermediate layer 3 and body. Hereinafter, the steps of the optical recording medium of the Niu Mingshe intermediate layer 7 after 1 will be explained. (1) Formation of upper recording reproduction function layer and the like Fig. 4 is a diagram for explaining the light of the preferred embodiment of the present invention. The recorded medium is represented by the figure i, Figure 2: Two specific terms, Figure 4 is used for q ϋ Figure 3 is applied to the middle layer 7 The upper part of the sequential layer § has recorded the regenerative function layer 8, the glaze 恳 Q; the west ^ ^ ^ adhesion layer 9, and the coating layer 1 〇, thereby obtaining a schematic cross-sectional view. Furthermore, for the figure and Figure 2 Figure 3 The common constituent elements are denoted by the same reference numerals. As shown in Fig. 4, on the formation of the grooved depressions ## 7), the transfer layer 6 of the upper layer is formed (the intermediate layer 8 is too much connected: The raw functional layer 8. The upper recording and reproducing functional layer Qin 2' is substantially the same as the recording and reproducing functional layer 2. In 1st, the upper part of the car father's department recorded the taste of six ~, and penetrated. Therefore, the upper record =: the laser light for recording and reproduction is used. " The film thickness of each layer of the raw functional layer 8 needs to be adjusted appropriately (2) The coating layer or the like is formed after the recording and reproducing work portion of the recording and reproducing function layer 8 having the required number of layers is set), and the same as the 4 cake _ mouth r σ The regenerating functional layer (not shown in Fig. 4, the recording recording on the uppermost layer, and the recording and reproducing functional layer 8) is placed on the upper surface of the coating layer 10. The order in which the adhesive layer 9 and the coating layer 10 are formed is particularly limited. : For the adhesive layer 9 ', an adhesive, an external curable resin, or the like can be usually used. Further, as a coating layer, a low-wicking 等 = 312 ΧΡ / invention manual (supplement) / 96 · 〇 6/96111269 50 200814050, etc., such as a terry resin or a ring-female polymer. Preferably, the material is the same as that of the characteristic plate such as the warpage of the optical disk, and the bonding layer 9 is coated with the μ 1 () ^ ′ and the integrated layer 10 is integrated. At this time, the smectite resin used in the outer earth is usually 1000 mils. The above film can be formed by spin coating to form a film having a thickness of 50 〜 2 〇〇 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The thickness of the adhesive layer 9 is not particularly limited, and is usually the following. By virtue of the range, it is easy to advantage. 辉 仏 仏 仏 uniform thickness of the adhesive material, on the other hand, the coating layer 10 The thickness, usually r:v, is easily formed into a corresponding reading by this range:

—P1二P:S)之局ΝΑ化之均句膜厚的被覆層！〇。於DVD 一 K寺中，可介隔接黏層人 成被覆層等。 θ貼口、·、勺0.6咖之基板而代替形 I -2.僅使用基板作為第i記錄媒體之情況 果中’僅使用基板作為第1記錄媒體。其結 = =狀、且具有下"_印層 士己錚禅二；土 本貝轭之形態，係除了使用之第1 有、;態不同以外’其他可與上述已說明之使用具 實施二^ 能層之第1記錄媒體製造光記錄媒體之 妒能=相同地進行實施。根據所使用之第！記錄媒體之 面；Γ言，存在如下差異。第-點，本實施形 心〒 表面具有凹1¾形狀、b b , 間層並不介隔記錄再生功以㈣印層的中 力犯層而直接形成於基板上。因 312XP/發明說明書(補件)/96·06/96111269 51 200814050 =’無需預先於基板上設置凹凸形狀。第二點，本實施形 態中’於基板上最初設置之記錄再生功能層將成為上部記 錄再生功能層。 如上所述，除了所使用之第1記錄媒體之形態不同以 外’可以與上述已說明之具有i層記錄再生功能層之第i 記錄媒體相同之方法，製造具備表面具有凹凸形狀、且且 有下中間層及轉印層之中間層的光記錄媒體。必需之說明 丨已加以說明，故此處省略說明。 1广使用具有複數個記錄再生功能層之$ 1記錄媒體之 情況 本實施形態’除了所使用之第“己錄媒體之形態不同以 外，其他與上述已說明之使用具有1層記錄再生功能層之 弟"己錄媒體製造光記錄媒體之實施形態同樣 根據所使用，第1記錄媒體之形態不同，具體而言： 子如下差異。第一點，第1記錄媒體製造㈣中，藉由 :基？上形成複數個記錄再生功能層而製造第媒 二㈡位本/施形態中，接合步驟中’以轉印層與距 基板取讀置之記錄再生功能層之时在下中間層的 狀恶’接合轉印層積層壓模與上述第、記錄媒體。θ 如上所述，除了所使用之第！記錄媒體之形態不同以 可以與上述已說明之具有1層記錄再生功能層之第！ 具有下中間層及轉印層之;間凸形狀、且 下對作為差異之第丨記錄媒體 =;錄媒趙。繼而 312XP/發明說明書(補件)/96-06/96111269 52 200814050 通常以如下方法進 本貫施形態中使用繁 行製造。 用之弟1記錄媒體 ⑷於基板上形成記錄再生功能層。 ⑻於上述記錄再生功能層上形心間声。 (C)於上述中間層上形成第2記錄二 ⑷於第2記錄再生功能層 ⑷根據所需之記錄再生功能層之；二中 步驟。 嘴數而重複上述（c)、（d) 積層之記錄再生功能層數益 錄再生功能層之積層數以10層=制。但’現實中，記 再生功能層之積層數，通常 芦 '"另一方面’記錄 更佳5層以上。考慮到工業生產=較佳3層以上， 最佳係記錄再生功能層之積層數敦為2、=性4各種要素， 再者，作為上述第2記錄再生 θ 能層之層構成·材料，可使用盘‘二後之記錄再生功 2中之記錄再生功能# 2)相以^再生功能層（圖1、圖 士从 )相同之層構成•材料。又，於# 成弟2中間層以後之中間層之情 又於形 層之材料或製作順序、壓模之構造、藉由：：：：及轉印 化之順序等詳情亦可與上述說明者相同。、，“、、射之硬 工-4·其他 二t明==複數個實施 y亚非偈限於上述貫施形態者，於不超出本發明主 曰之乾圍内，可適當加以變更進行實施。 例如，光記錄媒體之層構成並非揭限於上述實施形態之 312XP/發明說鴨(補件)/96-06/96111269 53 200814050 構成。於不超出本發 序、可追加其他層、 11 ·製造裝置 明主旨之範圍内，可有不同之積層順 可將二層以上之層一體化。 狀：：，明’亦提供-種用以製造具備表面具有凹凸形 ^:有下中間層及轉印層之中間層之光記錄媒體的製 =。具體而言，為了製造轉印層積層屋模， 造 t置中增加如下功能。 _ Ρ杧加第一硬化手段：於表面具有對應中間層之凹凸 形狀之轉印用凹凸形狀之壓模的該表面上設置紫外線硬 化性樹脂膜’對紫外線硬化性樹脂膜照射紫外線而使該紫 外線硬化性樹脂膜半硬化。進而，增加第二硬化手段：於 =1氧/辰度之環&下知射紫外線’使上述紫外線硬化性樹 脂膜進一步硬化而形成轉印層。 對於上述第一硬化手段及第二硬化手段之具體操作，與 士述製造方法中所說明者相同，此處省略說明。又，用以 馨實現上述第一硬化手段及第二硬化手段之具體裝置構 成，可適當改良先前公知之製造裝置而進行使用。 (實施例） 以下，根據實施例，對本發明進行更詳細的說明。再者， 本發明若不超出其主旨，則不限於如下之實施例。 (實施例1) (第1記錄媒體製造步驟） 準備轉印有溝深約20nm、間距約〇·32 μηι之溝的厚j j mm之聚碳酸酯製基板。以濺鍍法於上述基板之形成有溝 312XP/發明說明書(補件)/96·06/96111269 54 200814050 狀之表面上、形成可重寫型記錄再生功能層（可重寫型媒 體之例1，膜面入射構成）。 、 如此製造第1記錄媒體。 (轉印層積層壓模製造步驟） 藉由射出成型而製造轉印有溝深約20 nm、間距約〇·32 Mm之溝的厚〇·6 mm、外徑i2〇 之聚碳酸酯製透明壓 1模^以旋塗法於該壓模之形成有溝狀之表面上塗佈自由基 _ 1外線硬化性樹脂（自由基聚合型紫外線硬化性樹 月曰）A(丙稀酸系樹脂，黏度約3〇〇Mpa· s)。繼而，將上述 自由基系紫外線硬化性樹脂A製成厚約4 之薄膜狀 後彳τ止回速甩出旋轉。如上所述，於壓模上形成紫外線 硬化性樹脂膜。 /、後，於大氣環境中，對上述紫外線硬化性樹脂膜之整 面…、射22 mW/cm2之具有大致平均之強度分佈的υν光 (光源· Hari_ Toshiba 製之 TOSCURE 751)3 秒鐘。照射 _後^觸碰紫外線硬化性樹脂膜之表面，為黏著狀態。繼而， 於氮環丨兄中，對上述紫外線硬化性樹脂膜整面，照射8〇 mW/cm之具有大致平均之強度分佈之光源發出的uv光 1移釦。如此獲得轉印層。轉印層之表面狀態為即使以銳 利金屬摩擦亦難以劃傷之狀態。 如上所述而製造轉印層積層壓模。 (接合步驟） 於第1纪錄媒體之記錄再生功能層上之表面，於半徑约 35 mm之位置，將自由基系紫外線硬化性樹脂（自由基聚 312XP/發明說明書(補件)/96·〇6/96111269 200814050 合型紫外線硬化性樹脂）B(丙烯酸李 A/fn 、、人 w文系封脂，黏度約500 MPa · s)塗佈為一周之環狀。繼而， ...^ t M自由基系紫外線硬 化性树月曰B與轉印層相對面之方式 t 、 万式於自由基系紫外線硬 化性树知B上載置上述轉印層積> f曰嶺盾塋杈。將自由基系紫外 線硬化性樹脂B延伸至第】記錄婵於 你μ 蜾版及轉印層積層壓模之 鈿邛後，使弟1記錄媒體以5000 ^ . . ^ . ^ , Ρ進仃旋轉，將多餘 之自由基糸系外線硬化性樹脂Β甩出至第】記 印層積層壓模之外部。立彳纟自 ^ ^、 八後，自壓杈側對整面照射來自相 同光源之80 mW/cm2之且右夫$々巫仏七Α ^ ^ ^ 有大致千均之強度分佈的UV光 6秒釦，而使下申間層硬化。 (剝離步驟） 其後，若自轉印層剝離透明壓模，則可於透明壓模盘轉 印層界面，以整面無不均之良好狀態進行剝離。、 (上部記錄再生功能層之形成） 進而以濺鍍法於轉印層上形成可重寫型上部記錄再生 功能層（可重寫型媒體之例卜膜面入射構成），進而以樹 脂旋塗法形成厚度為75 夕址癸昆崔丨 運而以樹 光光碟。’又為75 _之被覆層’製作雙層轉印型藍 ，（評價） 號評價以上述製造方法製作之雙層轉印型藍 光光碟中溝向轉印層轉印之轉印性。其結果可知可择 好之溝信號，整面均可良好地進行轉印。 X于又 (比較例1) 於實施例1之「轉印層積層壓模製造步驟」中，除了僅 312XP/發明說明書(補件)/96-06/96111269 56 200814050 SI:初之大氣環境下之22 mW/Cm、UV照射(不進 二丁 + =之操作），及不進行「上部記錄再生功能層之形 =之Γ驟以外’以與實施例1同樣方式嘗試製造光 ，故難以剝離。實際上，若強行進行剝離 =鄉月壓模上，而記錄再生功能層上之記= 剝離。繼而’麵而成之記錄層之膜的整面均破 (貫施例2) 除了將實施例1之「轉印層積層屢模製造步驟」中之 肋mw/cm2之uv光照射設為1〇秒鐘及不進行「第2 =再生功能層之形成」以後之步驟料，以與實施例1 同‘方式嘗試製造光記錄媒體。其結果為，剝離步驟中， 僅有部分濺鍍而成之記錄層之膜剝離，轉印層與透明壓模 之剝離基本上可良好進行。 、 (:施例3 :變更轉印層及下中間層之樹脂材料之實驗 (第1記錄媒體製造步驟） 、x 準備轉印有溝深約2〇nm、間距約0.32jUm之溝的厚J i mm之聚碳酸酯製基板。以濺鍍法於上述基板上之形^成有 溝狀之表面上形成可重寫型記錄再生功能層（可重寫型媒 體之例1，膜面入射構成）。如此製造第i記錄媒體。’、 (轉印層積層壓模製造步驟） 藉由射出成型製作轉印有溝深約2〇 nm、間距約〇 32从讯 之溝的厚0.6 mm、外徑120mm之聚碳酸酯製透明壓模。 以旋塗法於該壓模之形成有溝狀之表面上塗佈自由基系 M2XP/發明說明書(補件 57 200814050 紫外線硬化性樹脂（自由基聚合型紫外線硬化性樹脂）c(丙 烯酸系樹脂，黏度約300 MPa · s)。繼而，將上述自由基 糸I、外線硬化性樹脂C製成厚約4 μιη之薄膜狀後，停止 高速甩出旋轉。如上所述，而於壓模上形成紫外線硬化性 樹脂膜。 其後’於大氣環境中，對上述紫外線硬化性樹脂膜之整 面’照射22 mW/cm2之具有大致均勻之強度分佈的υν光 (光源：Harison Toshiba 製之 TOSCURE 751)3 秒鐘。照射 後，觸碰紫外線硬化性樹脂膜之表面，為黏著狀態。繼而， 於氮環境中，對上述紫外線硬化性樹脂膜整面，照射8〇 mW/cm2之具有大致均勻之強度分佈之光源發出之uv光 1秒鐘。如上所述獲得轉印層。轉印層之表面狀態為即使 以銳利金屬摩擦亦難以劃傷之狀態。 如上所述而製造轉印層積層壓模。 (接合步驟） 於第 圮錄媒體之記錄再生功能層上之表面，於半徑約 35 mm之位置，將自由基系紫外線硬化性樹脂（自由基聚 合型紫外線硬化性樹脂）D(丙烯酸系樹脂，黏 〇〇〇 MPa · S)塗佈為—周之環狀。繼而，卩自由基系紫外線硬 化性樹脂D與轉印層相對面之方式，於自由基系紫外線硬 化性樹脂D上載置上述轉印層積層屢模。將自由基系紫外 線硬化性樹脂D延伸至第】記錄媒體及轉印層積模之 端部後’使第1記錄媒體以5_啊進行旋轉，曰將多餘 之自由基系紫外線硬化性樹脂D甩出至第】記錄媒體及轉 312XP/發明說明書(補件)/96·〇6/961丨丨汹 58 200814050 印層積層_之外部。其後，自_側對整面照射來自相 同光源之8〇mW/cm2之具有大致均勾之強度分佈之1；乂光 6秒鐘，而使下中間層硬化。 (剝離步驟） 其後，若自轉印層剝離透明壓模，則可於透明壓模與轉 印層界面，以整面無不均之良好狀態進行剝離。 才 (實施例4 :於氮氣下進行半硬化之實驗） 馨（第1記錄媒體製造步驟） 準備轉印有溝深約2〇nm、間距約〇.32μηι之溝的厚 _之聚碳酸醋製基才反。以㈣法於上述基板之形成有溝 狀之表面上形成可重寫型記錄再生功能層（可重寫型媒體 之例1，膜面入射構成）。如此製造第i記錄媒體。 (轉印層積層壓模製造步驟） 藉由射出成型而製造轉印有溝深約20 nm、間距約0 32 Mm之溝的厚0.6 mm、外徑12〇腿之聚碳酸醋製透明壓 馨模。以旋塗法於該壓模之形成有溝狀之表面上塗佈自由基 系紫外線硬化性樹脂（自由基聚合型紫外線硬化性樹 脂）A(丙烯酸系樹脂，黏度約3〇〇Mpa· s)。繼而，將上述 自由基系紫外線硬化性樹脂A製成厚約4 之薄膜狀 後仔止同速甩出旋轉。如上所述，於壓模上形成紫外線 硬化性樹脂膜。 其後，於大氣環境中，對上述紫外線硬化性樹脂膜之整 面 > 射10 mW/cm之具有大致均勻之強度分佈之UV光 (光源· Hanson Toshiba 製之 TOSCURE 751)0.2 秒鐘。照 312XP/發明說明書(補件)/96-06/96111269 200814050 射後，觸碰紫外線硬化性樹脂膜之表面，為黏著狀態。繼 而，於氮環境中，對上述紫外線硬化性樹脂膜整面，照射 80 mW/cm2之具有大致均勻之強度分佈之光源發出之uv 光1秒鐘。如上所述獲得轉印層。轉印層之表面狀態為即 使以銳利金屬摩擦亦難以劃傷之狀態。 如上所述而製造轉印層積層壓模。 (接合步驟） 於第1記錄媒體之記錄再生功能層上之表面，於半徑約 35 mm之位置，將自由基系紫外線硬化性樹脂（自由基聚 σ垔糸外線硬化性樹脂丙烯酸系樹脂，黏度約1 〇〇〇 r^s)塗佈為—周之環狀。繼而’以自由基系紫外線硬 轉印層相對面之方式，於自由基系紫外線硬 树月曰D上載置上述轉印層積層屋模。將自 線硬化性樹脂D延伸至第1¾锊據雕尔糸Γ 甲主弟K己錄媒體及轉印層積層壓模之 =後’使弟"己錄媒體以5_ rpm進行旋轉，將多餘 ❿之自由基系紫外線硬化性樹脂D 、 :=。模之棒其後，自_= 冋先源之80mW/cm2之具有大致均勻 6秒鐘，而使下中間層硬化。 X π之UV光 (剝離步驟） 其後’若自轉印層剝離透明壓模，、 印層界面，以整面盔；^ β i 、、可於透明壓模與轉 (實施例5)無不均之良好狀態進行制離。 除了僅將實施例4中，製作轉印芦 π 9 $ ’表初照射之υν 312ΧΡ/發明說明書(補件)/96-06/961 11269 60 200814050 照射時間（用以半硬化之uv照射時間）由〇2秒改為 秒以外，以與實施例4同樣方式嘗試製造光記錄媒體。其 、、’口果為剝離步驟中，僅有部分濺鍍而成之記錄膜剝離， 基本上可良好地進行轉印層與透明壓模之剝離。 λ轭例4、5中之轉印層之形成方法為具有對轉印層照 射2 -人UV光時，無需由大氣環境轉為氮環境的優勢。然 而，於轉印層積層壓模製造步驟中，進行半硬化時所使用、 籲之uv光之照射強度與進行進一步硬化時（第2次硬化）所 使用之UV光之照射強度的差較大。因此，若欲使用相同 之UV照射裝置（υν光源）進行半硬化及其後之硬化，則有 可用於工業中之υν照射裝置（υν光源）之機種有其限制 的傾向。又，將有半硬化時之紫外線照射強度及照射時間 之適宜範圍變窄，光記錄媒體之製造限度變小之傾向。考 慮到上述觀點，認為半硬化最好為於存在氧之環境中進 行。 •(參考例） 除了實施例1之「轉印層積層壓模製造步驟」中，最初 .於大氣下照射200爪界/〇„12之11¥光2秒鐘，其後不進行 氮環境中之UV光照射，及不進行「第2記錄再生功能層 t形成」以後之步驟以外，以與實施例丨同樣方式嘗試製 造光記錄媒體。此處，為了於接合步驟前確認紫外線硬化 性樹脂膜之表面狀態，以手指觸碰紫外線硬化性樹脂膜表 面為稍Μ黏著之狀態（半硬化狀態）。即，本實驗中，不 形成轉印層，而使用半硬化狀態之紫外線硬化性樹脂膜進 312ΧΡ/發明說明書(補件)/96-06/96111269 61 200814050 行接合步驟。 声」腔^狀怨下進行剝離步驟，僅有部分機鑛而成之記錄 缺"離基本上可良好地進行轉印層與透明>1模之剝 欠“、、、而:除了使用1〇〇 mW/cm2之uv光以外，以相同 ^件進行剝離步驟後，誠而成之記錄層之膜整體剝 -離。 —由本貫驗結果’可知#由經過半硬化狀態，可良好地進 籲Hr I層與透明壓模之剝離。然而，於本實驗之方法中， :以紫外線硬化性樹脂膜之表面具有黏性之狀態進行接 一 v驟口此，接合步驟時，將有於轉印層與下中間層之 間進入氣泡之情況。又，若uv光之照射量降低則可能引 2剝離不良。因此，為了確保生產性，需要UV光之照射 畺大之衣置，於成本方面變得不利。故而，半硬化後於減 少氧濃度之環境下進行進一步硬化，對實現工業生產時之 低成本化、提高生產安定性或良率方面較有效。 _ (產業上之可利用性） 本發明之光記錄媒體之製造方法可較佳地適用於CD、 DVD、BD等各種光記錄媒體領域。 再者，本申請案係根據於2006年3月31曰提出申請之 曰本專利申請案（曰本專利特願2⑽6-1〇〇145)，其全體以 引用之方式而援用於此。 【圖式簡單說明】 圖1(a)、（b)、（b-1)、（b-2)係用以說明應用本實施形態 之光記錄媒體之製造方法之較佳一例的示意剖面圖。 312XP/發明說明書(補件)/96-06/96111269 62 200814050 圖2(c)、（ol)、（c_2)、（句係用以說明應用本實施形態之 光記錄媒體之製造方法之較佳一例的示意剖面圖。 圖3(a)至⑷係用以說明帛2製造方法中之接合 一實施形態的示意剖面圖。 夕知之 丄圖4係Ί兄明應用本發明實施形態之光記錄 較佳一例的示意剖面圖。 ’、體之 【主要元件符號說明】- P1 two P: S) The smashing of the film thickness of the sentence! Hey. In the DVD-K Temple, it is possible to isolate the adhesive layer into a coating layer. θ 贴 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , The knot == shape, and has the lower "_print layer 士 铮 铮 ;; the shape of the soil yoke, in addition to the use of the first, and the state is different, the other can be implemented with the above described use The first recording medium of the second energy layer is manufactured in the same manner as the optical recording medium. According to the number used! Record the media; rumors, there are the following differences. At the first point, the surface of the present embodiment has a concave shape and b b , and the interlayer is formed on the substrate without intervening the recording regenerative work with the intermediate layer of the (4) printing layer. 312XP/Invention Manual (Repair)/96·06/96111269 51 200814050 =' It is not necessary to provide a concave-convex shape on the substrate in advance. Secondly, in the present embodiment, the recording and reproducing functional layer initially disposed on the substrate will become the upper recording and reproducing functional layer. As described above, in addition to the difference in the form of the first recording medium to be used, the method can be manufactured in the same manner as the above-described i-th recording medium having the i-layer recording and reproducing functional layer, and has a surface having a concave-convex shape and having a lower surface. An optical recording medium of an intermediate layer between the intermediate layer and the transfer layer. The necessary explanations have been explained, so the description is omitted here. In the case where a recording medium having a plurality of recording and reproducing functional layers is widely used, the present embodiment "is different from the above-described "recorded and reproduced functional layer". The embodiment of the "recorded media" for producing optical recording media is also different depending on the format of the first recording medium. Specifically, the difference is as follows: First, in the manufacture of the first recording medium (4), by: Forming a plurality of recording and reproducing functional layers to form a dielectric second (two) position/application form, and in the bonding step, 'in the lower middle layer when the transfer layer and the recording and reproducing functional layer are read from the substrate Bonding the transfer laminated lamination mold to the above-mentioned first recording medium. θ As described above, in addition to the form of the recording medium to be used, it is possible to have the first layer of the recording and reproducing functional layer described above! Layer and transfer layer; convex shape, and the second recording medium as the difference =; recording medium Zhao. Then 312XP / invention manual (supplement) / 96-06/96111269 52 200814050 usually The following method is used in the conventional embodiment. The recording medium (4) is used to form a recording and reproducing functional layer on the substrate. (8) The inter-center sound is formed on the recording and reproducing functional layer. (C) Formed on the intermediate layer. The second record 2 (4) is used in the second recording/reproducing functional layer (4) to reproduce the functional layer according to the required recording; the second step is to repeat the above-mentioned (c), (d) layered recording and reproducing function layer number recording and reproducing function. The number of layers in the layer is 10 layers = 1. However, in reality, the number of layers of the regenerative functional layer is usually more than 5 layers. In view of industrial production = preferably 3 layers or more, The number of layers of the optimum recording and reproducing function layer is 2, and the number of layers is 2, and the layer structure and material of the second recording and reproducing θ energy layer can be used. The recording and reproducing function # 2) The phase consists of the same layer of the regenerative function layer (Fig. 1, the figure). In addition, the middle layer after the middle layer of Chengdi 2 is also the material of the layer or Production order, structure of the stamper, by ::: The details of the order of the transfer and the like may be the same as those described above., ",, the hard work of the shoot - 4, the other two t = the == a plurality of implementations y Yafei is limited to the above-mentioned forms, Excessively within the dry circumference of the main body of the present invention, it can be appropriately changed and implemented. For example, the layer configuration of the optical recording medium is not limited to the configuration of 312XP/Invention Duck (Supplement)/96-06/96111269 53 200814050 of the above embodiment. In the range beyond the scope of this report, the addition of other layers, and the purpose of the manufacturing device, there may be different layers to integrate two or more layers. The shape::, also provides a kind of optical recording medium having a surface having a concavo-convex shape: an intermediate layer having a lower intermediate layer and a transfer layer. Specifically, in order to manufacture a transfer layer laminate mold, the following functions are added to the build-up. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The curable resin film is semi-hardened. Further, a second hardening means is added: the ultraviolet curable resin film is further cured by a ring of ultraviolet rays / ampere of <RTIgt; The specific operations of the first hardening means and the second hardening means are the same as those described in the manufacturing method of the above description, and the description thereof is omitted here. Further, the specific device configuration for realizing the first curing means and the second curing means can be suitably used to improve the conventionally known manufacturing apparatus. (Embodiment) Hereinafter, the present invention will be described in more detail based on examples. Furthermore, the present invention is not limited to the following embodiments without departing from the gist thereof. (Example 1) (First recording medium manufacturing step) A polycarbonate substrate having a thickness of j j mm having a groove depth of about 20 nm and a pitch of about 〇·32 μηι was transferred. Forming a rewritable recording and reproducing functional layer on the surface of the substrate formed by the sputtering method 312XP/invention specification (supplement)/96·06/96111269 54 200814050 by sputtering (example 1 of the rewritable medium) , film surface incidence constitutes). The first recording medium is manufactured in this manner. (Transfer Laminated Molding Process Manufacturing Step) A polycarbonate transparent to a groove having a groove depth of about 20 nm and a pitch of about 〇32 Mm is transferred by injection molding, and the outer diameter i2 is transparent. Pressing a die to apply a radical _ 1 external curable resin (radical polymerization type ultraviolet curable resin) A (acrylic resin) to the surface on which the stamper is formed by spin coating The viscosity is about 3〇〇Mpa·s). Then, the above-mentioned radical-based ultraviolet curable resin A is formed into a film shape having a thickness of about 4, and the 彳τ check speed is rotated. As described above, an ultraviolet curable resin film is formed on the stamper. After that, in the atmosphere, the entire surface of the ultraviolet curable resin film was irradiated with φν light having a substantially average intensity distribution of 22 mW/cm 2 (light source, TOSCURE 751 by Hari_Toshiba) for 3 seconds. After the irradiation, the surface of the ultraviolet curable resin film is touched to be in an adhesive state. Then, the uv light 1 which is emitted from a light source having a substantially average intensity distribution of 8 〇 mW/cm is applied to the entire surface of the ultraviolet curable resin film. The transfer layer was thus obtained. The surface state of the transfer layer is a state in which it is difficult to scratch even if it is rubbed with a sharp metal. The transfer laminated laminate was produced as described above. (Joining step) On the surface of the recording and reproducing functional layer of the first recording medium, a radical-based ultraviolet curable resin is placed at a position of a radius of about 35 mm (radical poly 312XP/invention specification (supplement)/96·〇 6/96111269 200814050 Combined UV curable resin) B (Li-acrylic acid A/fn, human w-system sealant, viscosity about 500 MPa · s) is coated in a one-week ring shape. Then, the surface of the ultraviolet ray-curable tree 曰B is opposite to the transfer layer, t, and the type of the free radical ultraviolet ray-curable tree B is placed on the transfer layer > f曰岭盾茔杈. Extending the radical-based ultraviolet curable resin B to the 】 婵 你 你 你 你 你 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟 弟The excess free radical lanthanide external curable resin is extracted to the outside of the first recording laminate mold. From the ^ ^, after eight, the entire surface of the self-compressed side is irradiated from the same source of light 80 mW / cm 2 and right husband $ 々 仏 仏 Α ^ ^ ^ There are roughly a thousand average intensity distribution of UV light 6 The second button is used to harden the lower layer. (Peeling step) Thereafter, when the transparent stamper is peeled off from the transfer layer, peeling can be performed in a good state in which the entire surface is not uneven at the interface of the transparent stamper transfer layer. (Formation of the upper recording and reproducing functional layer) Further, a rewritable upper recording and reproducing functional layer is formed on the transfer layer by sputtering (the rewritable medium is exemplified as a film surface incident), and further spin-coated with a resin The law forms a thickness of 75 eves, and the Kun Cui 丨 is shipped with a tree light disc. Further, a double-transfer type blue was produced for the coating layer of 75 Å. (Evaluation) No. The transfer property of the transfer to the transfer layer in the double-transfer type blue-light-disc manufactured by the above-described production method was evaluated. As a result, it was found that the groove signal can be selected, and the entire surface can be transferred well. X (also, Comparative Example 1) In the "transfer layering lamination mold manufacturing step" of the first embodiment, except for only the 312XP/invention specification (supplement)/96-06/96111269 56 200814050 SI: under the initial atmosphere In the same manner as in the first embodiment, 22 mW/cm, UV irradiation (operation without the operation of the double-butting +=), and the case where the shape of the upper recording and reproducing functional layer is not performed is attempted to produce light in the same manner as in the first embodiment, so that it is difficult to peel off. In fact, if the peeling is forcibly carried out = the township monthly stamper, and the mark on the recording and reproducing functional layer = peeling. Then the entire surface of the film of the recording layer formed by the surface is broken (Example 2) except that it will be implemented. In the "transfer layered multilayer mold manufacturing step" of Example 1, the uv light irradiation of the rib mw/cm2 is set to 1 second, and the step material after the "second = regeneration functional layer formation" is not performed, and is implemented. Example 1 The same method was used to make an optical recording medium. As a result, in the peeling step, only the film of the partially deposited recording layer was peeled off, and the peeling of the transfer layer and the transparent stamper was basically performed well. (Example 3: Experiment of changing the resin material of the transfer layer and the lower intermediate layer (first recording medium manufacturing step), x Preparation for transfer of a groove J having a groove depth of about 2 〇 nm and a pitch of about 0.32 jUm a substrate made of polycarbonate of i mm. A rewritable recording and reproducing functional layer is formed on the surface of the substrate having a groove shape by sputtering (Example 1 of the rewritable medium, film surface incident composition) The i-th recording medium is thus manufactured. ', (transfer layering lamination mold manufacturing step) by transfer molding to produce a groove having a groove depth of about 2 〇 nm, a pitch of about 32, and a thickness of 0.6 mm from the groove of the signal. A transparent stamper made of polycarbonate having a diameter of 120 mm. The surface of the stamper formed on the grooved surface is coated with a radical type M2XP/invention specification (Supplement 57 200814050 UV curable resin (radical polymerization type) The ultraviolet curable resin c (acrylic resin, viscosity: about 300 MPa · s). Then, the above-mentioned radical 糸I and the external curable resin C are formed into a film having a thickness of about 4 μm, and then the high-speed ejection rotation is stopped. As described above, an ultraviolet curable resin film is formed on the stamper. Then, in the atmosphere, the entire surface of the ultraviolet curable resin film was irradiated with υν light (light source: TOSCURE 751 manufactured by Harison Toshiba) having a substantially uniform intensity distribution of 22 mW/cm 2 for 3 seconds. Touching the surface of the ultraviolet curable resin film to be in a state of adhesion. Then, in the nitrogen atmosphere, the entire surface of the ultraviolet curable resin film is irradiated with a light source having a substantially uniform intensity distribution of 8 〇mW/cm 2 . Light is passed for 1 second. The transfer layer is obtained as described above. The surface state of the transfer layer is a state in which it is difficult to scratch even if rubbed with a sharp metal. The transfer laminated lamination mold is manufactured as described above (joining step) On the surface of the recording and reproducing functional layer of the recording medium, a radical-based ultraviolet curable resin (radical polymerization type ultraviolet curable resin) D (acrylic resin, adhesive MPa) is placed at a radius of about 35 mm. S) is applied to the ring-shaped ring. Then, the ruthenium radical-based ultraviolet curable resin D is placed on the surface opposite to the transfer layer, and the above-mentioned radical-based ultraviolet curable resin D is placed thereon. The layer of the printed layer is multi-layered. After the radical ultraviolet curable resin D is extended to the end of the recording medium and the transfer layer mold, the first recording medium is rotated by 5_, and the excess radical is removed. The ultraviolet curable resin D is discharged to the first recording medium and the 312XP/invention manual (supplement)/96·〇6/961丨丨汹58 200814050 the outer layer of the printed layer _. The surface is irradiated with an intensity distribution of 8 〇mW/cm 2 from the same light source and having a substantially uniform hook; the light is rubbed for 6 seconds to harden the lower intermediate layer. (Peeling step) Thereafter, if the transparent stamper is peeled off from the transfer layer Then, the interface between the transparent stamper and the transfer layer can be peeled off in a good state without unevenness on the entire surface. (Example 4: Experiment of semi-hardening under nitrogen) Xin (first recording medium manufacturing step) Preparation of a polycarbonate having a groove depth of about 2 〇 nm and a pitch of about 32.32 μηι The base is reversed. A rewritable recording and reproducing functional layer (Example 1 of a rewritable medium, incident on a film surface) was formed on the surface of the substrate formed with a groove by the method (4). The ith recording medium is thus manufactured. (Transfer layer lamination mold manufacturing step) By injection molding, a polycarbonate transparent transparent press having a groove width of about 20 nm, a groove having a pitch of about 0 32 Mm, a thickness of 0.6 mm, and an outer diameter of 12 legs is manufactured. mold. A radical-based ultraviolet curable resin (radical polymerization type ultraviolet curable resin) A (acrylic resin, viscosity of about 3 〇〇Mpa·s) is applied onto the surface of the stamper having a groove shape by spin coating. . Then, the above-mentioned radical ultraviolet curable resin A was formed into a film shape having a thickness of about 4, and then rotated at the same speed. As described above, an ultraviolet curable resin film is formed on the stamper. Then, UV light having a substantially uniform intensity distribution (light source, TOSCURE 751 manufactured by Hanson Toshiba) of 10 mW/cm was irradiated to the entire surface of the ultraviolet curable resin film in the air atmosphere for 0.2 seconds. Photograph 312XP/Invention Manual (Supplement)/96-06/96111269 200814050 After the shot, touch the surface of the ultraviolet curable resin film to make it adhere. Then, in the nitrogen atmosphere, the entire surface of the ultraviolet curable resin film was irradiated with uv light of a light source having a substantially uniform intensity distribution of 80 mW/cm 2 for one second. The transfer layer was obtained as described above. The surface state of the transfer layer is a state in which it is difficult to scratch even if it is rubbed with a sharp metal. The transfer laminated laminate was produced as described above. (Joining step) On the surface of the recording/reproducing functional layer of the first recording medium, a radical-based ultraviolet curable resin (radical poly-σ垔糸 external curable resin acrylic resin, viscosity) at a position of a radius of about 35 mm About 1 〇〇〇r^s) is coated as a ring of weeks. Then, the transfer layer laminate was placed on the radical-based ultraviolet hardened tree layer D so as to face the opposite surface of the radical ultraviolet light transfer layer. Extending the self-curable resin D to the 13th 锊 锊 糸Γ 主 主 主 主 主 K K K K K 媒体 媒体 媒体 = = = = = = = = = = = = = = = = = 使 使 使 使 使 使 使 使 使 使 使 使 使The radicals of hydrazine are ultraviolet curable resins D and :=. After the mold stick, the 80 mW/cm2 from the _= 冋 source has a substantially uniformity of 6 seconds, and the lower intermediate layer is hardened. X π UV light (peeling step) Thereafter, if the transparent stamper is peeled off from the transfer layer, the interface of the stamp is used to face the entire helmet; ^ β i , can be transparent stamped and transferred (Example 5) All are in good condition for separation. In addition to only Example 4, the transfer of the reed π 9 $ 'the initial illumination of the υ ν 312 ΧΡ / invention instructions (supplement) / 96-06/961 11269 60 200814050 irradiation time (for semi-hardened uv irradiation time) An optical recording medium was attempted in the same manner as in Example 4 except that 2 seconds was changed to seconds. In the peeling step, only the partially deposited recording film is peeled off, and the transfer layer and the transparent stamper are substantially peeled off. The method of forming the transfer layer in the λ yoke examples 4 and 5 has the advantage of not having to change from the atmospheric environment to the nitrogen atmosphere when the transfer layer is irradiated with 2-human UV light. However, in the transfer lamination mold manufacturing step, the difference between the irradiation intensity of the uv light used for the semi-hardening and the irradiation intensity of the UV light used for the further curing (second hardening) is large. . Therefore, if semi-hardening and subsequent hardening are to be carried out using the same UV irradiation device (υν source), there is a tendency that the type of the υν irradiation device (υν source) which can be used in the industry is limited. Further, the range of the ultraviolet irradiation intensity and the irradiation time in the case of the semi-hardening is narrowed, and the manufacturing limit of the optical recording medium tends to be small. In view of the above, it is considered that semi-hardening is preferably carried out in an environment in which oxygen is present. (Reference Example) In addition to the "transfer laminated laminate mold manufacturing step" of the first embodiment, the first step is to irradiate the ink of 200 claws/〇12 to 2 hours in the atmosphere for 2 seconds, and thereafter, it is not carried out in a nitrogen atmosphere. The optical recording medium was attempted in the same manner as in the Example except that the steps of the "second recording and reproducing functional layer t formation" were not performed. Here, in order to confirm the surface state of the ultraviolet curable resin film before the bonding step, the surface of the ultraviolet curable resin film that is touched by the finger is slightly adhered (semi-hardened state). That is, in this experiment, the transfer layer was not formed, but the ultraviolet curable resin film in a semi-hardened state was used. The bonding step was carried out in accordance with the specification (supplement)/96-06/96111269 61 200814050. The sound is “small” and the stripping step is carried out, and only a part of the machine is made into a record missing. “The transfer layer and the transparent layer are basically peeled off.”, and: In addition to the uv light of 1 〇〇mW/cm2, after the peeling step is carried out with the same member, the film of the recording layer of Chengcheng is peeled off as a whole. - From the results of the test, it is known that the film is semi-hardened. The peeling of the Hr I layer and the transparent stamper. However, in the method of the present experiment, the surface of the ultraviolet curable resin film is viscous, and the bonding step is performed. In the case where bubbles are introduced between the transfer layer and the lower intermediate layer, if the amount of irradiation of the uv light is lowered, the peeling of the uv light may be poor. Therefore, in order to ensure productivity, it is necessary to illuminate the clothes with UV light at a cost. Further, it is disadvantageous in that the semi-hardening is further hardened in an environment in which the oxygen concentration is reduced, which is effective in achieving cost reduction in industrial production and improving production stability or yield. _ (Industrial availability) ) Optical recording medium of the present invention The manufacturing method can be preferably applied to various optical recording media such as CD, DVD, BD, etc. Further, the present application is based on the patent application filed on March 31, 2006 (the patent application 2 (10) 6 -1〇〇145), the whole of which is hereby incorporated by reference. [Simplified Schematic] Figure 1 (a), (b), (b-1), (b-2) is used to illustrate the application A schematic cross-sectional view showing a preferred example of the method for producing an optical recording medium according to the present embodiment. 312XP/Invention Manual (Supplement)/96-06/96111269 62 200814050 Fig. 2(c), (ol), (c_2), ( The sentence is a schematic cross-sectional view for explaining a preferred example of a method of manufacturing the optical recording medium of the present embodiment. Fig. 3 (a) to (4) are schematic sectional views for explaining an embodiment of the bonding in the manufacturing method of the crucible 2; Fig. 4 is a schematic cross-sectional view showing a preferred example of optical recording according to an embodiment of the present invention. ', [Main component symbol description]

1 基板 2 記錄再生功能層 3 下中間層 4 壓模 5 紫外線硬化性樹脂膜 6 轉印層 7 中間層 8 上部3己錄再生功能層 9 接黏層 10 被覆層 80 硬化性樹脂 100 第1記錄媒體 200 轉印層積層壓模 1000 光記錄媒體 312XP/發明說明書(補件)/96-06/96111269 631 Substrate 2 Recording and reproducing functional layer 3 Lower intermediate layer 4 Stamper 5 UV curable resin film 6 Transfer layer 7 Intermediate layer 8 Upper 3 Recording and reproducing functional layer 9 Adhesive layer 10 Coating layer 80 Curable resin 100 First record Media 200 Transfer Lamination Laminate 1000 Optical Recording Media 312XP/Invention Manual (Repair)/96-06/96111269 63

Claims (1)

200814050 十、申請專利範圍： 1 · 一種光記錄媒體之製造方法，該光記錄媒體係具備於 表面具有凹凸形狀、且具有下中間層及轉印層的中間層， 其特徵為，具有如下步驟： 第1記錄媒體製造步驟，其獲得具有基板之第1記錄媒 、、轉印層積層壓模製造步驟，其係在於表面上具有對應上 _述:間層之凹凸形狀之轉印用凹凸形狀之壓模表面上，設 置糸外線硬化性樹脂膜，對該紫外線硬化性樹脂膜照射紫 外=而使該紫外線硬化性樹脂膜半硬化後，於降低氧濃度 之％t中照射紫外線，使該紫外線硬化性樹脂膜進一步硬 藉此形成上述轉印層而獲得轉印層積層壓模； 接°步驟’其係於上述轉印層與上述第1記錄媒體之間 ,Ιί上述下中間層之狀態下，接合上述轉印層積層壓模盘 该弟1記錄媒體；與 /、 釗離步驟’其係自上述轉印層剝離上述壓模。 2·如申明專利範圍第！項之光記錄媒體之製造方法，並 1記錄媒體製造步驟中，藉由於上述基板^ /、/己二再生功能層而製造上述第1記錄媒體； 層乂間疒/ I ^驟中，於上述轉印層與上述記錄再生功能 壓模盘lit第^層之狀態下’接合上述轉印層積層 I衩興上述弟1記錄媒體。 中=申請！利範圍第1項之光記錄媒體之製造方法，其 ;上述第1記錄媒體製造步驟中，藉由於上述基板上 312xp/發明翻書(翻〇/96挪96山269 200814050 於、复數们σ己錄再生功能層而製造上述第工記錄媒體； ^述接合步驟中，於上述轉印層與距離上述基板最遠 能下之上^記錄再生功能層之間存在上述下中間層之狀 “下接σ上述轉印層積層壓模與上述第丨記錄媒體。 制4::申請專利範圍第1至3項中任-項之光記錄媒體之 、、 /、τ精由於存在氧之環境中照射紫外線，而 仃上述紫外線硬化性樹脂膜之半硬化。 •制5二申：專利範圍第1至3項中任-項之光記錄媒體之 衣、/ ，其中，上述降低氧濃度之環境為氮環境。 制!^申5月專利範圍第1至3項中任一項之光記錄媒體之 ，其中’上述下中間層係於上述第1記錄媒體製 k步“中，形成於上述第1記錄媒體上。 制St請專利範圍第1 Μ項中任-項之光記錄媒體之 衣k / ，其中，上述接合步驟係於減壓環境中進行。 •製=21範圍第：至3項中任-項之光記錄媒體之 _ 、、二中，於上述接合步驟中，將硬化性樹脂塗佈 ;上述第1 5己錄媒體上後，以該硬化性樹脂與上述轉印層 目對面之方式’於該硬化性樹脂上载置上述轉印層積層壓 輭，亚延伸該硬化性樹脂，藉此形成上述下中間層。 9.如中請專利範圍第8項之光記錄媒體之製造方法，立 中，上述硬化性樹脂為紫外線硬化性樹脂。 八 1〇.如申請專利帛8項之光記錄媒體之製造方法，其中， 上达接合步驟係於大氣中進行。 11.如申請專利範圍第…項中任一項之光記錄媒體 312XP/發明說明書(補件)/96-06舰11269 65 200814050 之製造方法，其中，上述壓模為聚碳酸s旨系樹脂製。 H如申請專利範圍第1至3項中任—項之光記錄媒體 :衣：方法，其中’自上述轉印層剝離上糊後，於該 各卩層上形成上部記錄再生功能層。 u盆如申請專利範圍第2或3項之光記錄媒體之製造方 /晉；^1’上述記錄再生功能層，係自上述基板側依序設 置反射層及記錄層。 H一種光記錄媒體之掣生_ 之衣k衣置，其係用以製造具備於 ，有凹凸形狀、且具有下中間層及轉印 光記錄媒體者； 1曰的 其特徵為具有如下手段： 第-硬化手段，係在於表面上具有對應上述中間 凸形狀之轉印用凹凸形狀之_表面上，設置紫外ς 2脂膜，對該紫外線硬化性樹脂膜照射紫 外線硬化性樹脂膜半硬化；與 從 ?二硬化手段，係於減少氧濃度之環境中照射 =述紫外線硬化性樹脂膜進一步硬化，藉此形成上述轉 312ΧΡ/發明說明書(補件)/96-06/96111269200814050 X. Patent Application Range: 1 . A method of manufacturing an optical recording medium comprising an intermediate layer having a concave-convex shape on a surface and having a lower intermediate layer and a transfer layer, wherein the optical recording medium has the following steps: A first recording medium manufacturing step of obtaining a first recording medium having a substrate and a transfer lamination mold manufacturing step, wherein the surface has a concave-convex shape for transfer corresponding to the uneven shape of the interlayer An ultraviolet curable resin film is provided on the surface of the stamper, and the ultraviolet curable resin film is irradiated with ultraviolet light to semi-harden the ultraviolet curable resin film, and then ultraviolet rays are irradiated at %t of the oxygen concentration to harden the ultraviolet light. The resin film is further hardened to form the transfer layer to obtain a transfer laminated laminating mold; and the step of attaching between the transfer layer and the first recording medium, in the state of the lower intermediate layer, Bonding the above-described transfer layer laminated die to the recording medium; and/or removing the step of peeling the stamper from the transfer layer. 2. If the scope of the patent is declared! In the method of manufacturing the optical recording medium of the item, in the recording medium manufacturing step, the first recording medium is manufactured by the substrate/reproduction function layer, and the layer 乂/I is in the above The transfer layer is bonded to the above-described transfer layer 11 in a state in which the transfer layer is in the state of the above-mentioned recording and reproducing function. Medium = application! The method for manufacturing an optical recording medium according to Item 1, wherein the first recording medium manufacturing step is performed by the 312xp/invention on the substrate (reversing/96/96 269 200814050, plural σ己The recording medium is produced by recording the reproduction function layer; in the bonding step, the lower intermediate layer is present between the transfer layer and the recording function of the recording and reproducing layer at a distance from the substrate. σ The above-mentioned transfer layer laminated mold and the above-mentioned third recording medium. System 4: The optical recording medium of any of the items 1 to 3 of the patent application scope, /, τ fine is irradiated with ultraviolet rays in the presence of oxygen And the semi-hardening of the above-mentioned ultraviolet curable resin film. The system of the optical recording medium of any one of the first to third aspects of the patent range, /, wherein the environment for reducing the oxygen concentration is a nitrogen environment The optical recording medium according to any one of the first to third aspect of the invention, wherein the lower intermediate layer is formed in the first recording medium, and is formed in the first recording medium. Above. Please ask for the scope of patents. The medium-item optical recording medium garment k / , wherein the above-mentioned joining step is carried out in a decompression environment. • System = 21 range: to any of the 3 items of the optical recording medium _, 2, In the bonding step, the curable resin is applied; after the first recording medium is applied, the transfer layer is placed on the curable resin so that the curable resin is opposite to the transfer layer. In the method of producing an optical recording medium according to the eighth aspect of the invention, the curable resin is an ultraviolet curable resin. </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; The manufacturing method of the above-mentioned stamper is a polycarbonate resin, which is made of a resin, and is an optical recording medium of any one of the items 1 to 3 of the patent application: Clothing: method, where 'from the above After the transfer layer is peeled off, the upper recording and reproducing functional layer is formed on each of the enamel layers. The u-pot is manufactured by the optical recording medium of the second or third patent application scope. The reflective layer and the recording layer are sequentially disposed from the substrate side. H is a kind of optical recording medium, which is used for manufacturing, has a concave-convex shape, has a lower intermediate layer, and is transferred. The optical recording medium is characterized in that: the first-hardening means is provided with a UV ς 2 lipid film on the surface having a concave-convex shape for transfer corresponding to the intermediate convex shape on the surface, and The ultraviolet curable resin film is irradiated with the ultraviolet curable resin film to be semi-cured; and the ultraviolet curable resin film is further cured by the second curing means in an environment in which the oxygen concentration is reduced, thereby forming the above-mentioned transfer 312 ΧΡ / invention specification ( Supplement) /96-06/96111269