TW200812525A - Toothbrush - Google Patents

Toothbrush Download PDF

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Publication number
TW200812525A
TW200812525A TW096123554A TW96123554A TW200812525A TW 200812525 A TW200812525 A TW 200812525A TW 096123554 A TW096123554 A TW 096123554A TW 96123554 A TW96123554 A TW 96123554A TW 200812525 A TW200812525 A TW 200812525A
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TW
Taiwan
Prior art keywords
oral hygiene
weight percent
thermoplastic elastomer
plasticizer
layer
Prior art date
Application number
TW096123554A
Other languages
Chinese (zh)
Other versions
TWI422342B (en
Inventor
Josef Merl
Wolf-Dieter Mueller
Original Assignee
Glaxosmithkline Consumer Healt
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Publication date
Application filed by Glaxosmithkline Consumer Healt filed Critical Glaxosmithkline Consumer Healt
Publication of TW200812525A publication Critical patent/TW200812525A/en
Application granted granted Critical
Publication of TWI422342B publication Critical patent/TWI422342B/en

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Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B5/00Brush bodies; Handles integral with brushware
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B15/00Other brushes; Brushes with additional arrangements
    • A46B15/0055Brushes combined with other articles normally separate from the brushing process, e.g. combs, razors, mirrors
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B15/00Other brushes; Brushes with additional arrangements
    • A46B15/0055Brushes combined with other articles normally separate from the brushing process, e.g. combs, razors, mirrors
    • A46B15/0081Brushes with a scraper, e.g. tongue scraper
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/04Arranged like in or for toothbrushes
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/006Antimicrobial, disinfectant bristles, handle, bristle-carrier or packaging
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1066Toothbrush for cleaning the teeth or dentures

Landscapes

  • Brushes (AREA)
  • Cosmetics (AREA)
  • Packages (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

An oral hygiene implement, typically a toothbrush, having an oral hygiene element made of a thermoplastic elastomer material having a hardness in the range ShoreA 20-50 and a composition comprising 100-200 parts of a thermoplastic elastomer base material and 10-100 parts of a plasticiser comprising a mixture of a plasticising oil and a lipophilic flavouring substance which comprises menthol and/or derivatives thereof, the lipophilic flavouring substance being 5-15 wt% of the mixture.

Description

200812525 九、發明說明: 【發明所屬之技術領域】 本發明係關於口腔衛生裝置。 【先前技術】 本發明特別係關於在與有刷毛突出之表面相反的牙刷頭 部之表面上併入彈性薄層之類型的牙刷。提供該薄層之目 • 的主要係為了舌清潔(亦即,自舌柔和地移除可能導致口 臭之沈積物)。 • 人們已知此類型之牙刷,舉例言之,參看GB-A-2 391 462,其中揭不之牙刷具有自頭部之一表面延伸之刷毛及 自相反表面延伸之熱塑性彈性薄層,且此等彈性薄層尚可 併入香味劑。目前本申請人以諸如Dr BESTTM Du〇 p⑺恍匕 之商標出售此類牙刷,但未將香味併入至其彈性薄層中。 現在仍需要提供該等牙刷之改良形式。本發明之一目標 即為提供該改良。 【發明内容】 _ 根據本發明,提供一種口腔衛生器具,其具有至少一彈 性口腔衛生元件,該彈性口腔衛生元件係由一熱塑性彈性 體材料製造,該熱塑性彈性體材料具有在Sh〇reA 2〇至200812525 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to an oral hygiene device. [Prior Art] The present invention relates in particular to a toothbrush of the type incorporating an elastic thin layer on the surface of the toothbrush head opposite to the surface on which the bristles protrude. The purpose of providing this thin layer is primarily for tongue cleaning (i.e., softly removing deposits that may cause bad breath from the tongue). • This type of toothbrush is known, for example, see GB-A-2 391 462, wherein the toothbrush has a bristles extending from one surface of the head and a thermoplastic elastic layer extending from the opposite surface, and this An equal elastic layer can also be incorporated into the fragrance. The Applicant currently sells such toothbrushes under a trademark such as Dr BESTTM Du(R) p(7)(R), but does not incorporate the fragrance into its elastic sheet. There is still a need to provide improved versions of such toothbrushes. It is an object of the invention to provide this improvement. SUMMARY OF THE INVENTION According to the present invention, there is provided an oral hygiene device having at least one elastic oral hygiene element made of a thermoplastic elastomer material having a Sh〇reA 2〇 to

ShoreA 50之範圍内的硬度,且其組成乃包含1〇〇至2〇〇份 之熱塑性彈性體基底材料及1 〇至1 〇〇份之一塑化劑。該 塑化劑包含一增塑油與親脂芳香物質之混合物,該親脂芳 香物質包含薄荷腦及/或其衍生物且為混合物之5至〗5重量 百分比。 121838.doc 200812525 由本發明提供之一項改良為由於親脂芳香物質之存在而 產生之舒適香味所提供的增強之口腔體驗。 口腔衛生器具較佳包含一塑膠材料把手部分,在該塑膠 材料把手部分上安裝一或多個口腔衛生元件。合適之塑膠 材料包括牙刷由其製造之塑膠材料,通常為聚丙烯。 口腔衛生器具較佳為一牙刷,其包含一緊握把手及一具 有自牙刷之頭部之一表面延伸之刷毛的整體或可替代頭The hardness in the range of Shore A 50, and its composition includes 1 to 2 parts of the thermoplastic elastomer base material and 1 to 1 part of a plasticizer. The plasticizer comprises a mixture of a plasticizing oil and a lipophilic aroma comprising menthol and/or a derivative thereof in an amount of from 5 to 5% by weight of the mixture. 121838.doc 200812525 An improvement provided by the present invention is an enhanced oral experience provided by a comfortable fragrance produced by the presence of a lipophilic aroma. Preferably, the oral hygiene implement comprises a handle portion of a plastic material on which one or more oral hygiene elements are mounted. Suitable plastic materials include plastic materials from which the toothbrush is made, typically polypropylene. The oral hygiene device is preferably a toothbrush comprising a gripping handle and an integral or replaceable head having a bristles extending from a surface of the head of the toothbrush.

部。較佳地,至少一彈性口腔衛生元件包含熱塑性彈性薄 層,其自頭部之相反表面延伸。該薄層可為一已知形狀。 舉例而言,該薄層可呈條帶之形式,條帶具有一垂直於牙 刷之頭部把手長度方向的長度方向、—I直於該相反表面 的寬度方向及一平行於該頭部把手方向的厚度方向。該薄 層之-典型形式為已知Dr.BESTTM Duo Pr〇tekt牙刷之薄層 形式。 曰 或者,口腔衛生器具可為一除一牙刷之外的舌清潔裝 置。該裝置之一實例係(例如)在pct/ep〇6/〇〇〇i8i&de g_ 202 005 004291.9中揭示,係關於以,,DrBESTTM,,商標出售 之"Zungen Reiniger"舌清潔裝置。 <…Λ-王Ί土丹力一万面為 彈性體之特徵的熟知之材料。已知許多類型的熱塑性彈性 體基底材料用於本發明之口腔衛生器具中,例如,苯乙烯 被段共聚物。—合適之基底材料為用作S於由本H銷 售之AQUA删H DUO CLEANTM牙刷之舌清潔^的基 底熱塑性彈性體材料之基底材料。該等材料之實例為自供 121838.doc 200812525 應商 Gummiwerk Kraiburg GmbH & Co· KG,Germany購得 之Thermolast K™系列的熱塑性彈性體材料(例如,材料TF 3 A AH)。此等材料係基於氫化苯乙烯嵌段共聚物。 熱塑性彈性體材料較佳具有在Sh〇reA 30+/-3之範圍内的 硬度。 較佳地,熱塑性彈性體材料含有20至80份之塑化劑。塑 化劑之組合物範圍(亦即,塑化劑混合物中之5至15重量百 分比的親脂芳香物質)看來似乎在最佳化由本發明之口腔 衛生器具之使用者感知的味道中係重要的。一較佳比例為 10+/-2%。舉例而言,通常發現若使用小於5%,則可體驗 較少有益之味道,且若使用15%以上,則味道可為不良 的。 本文中所使用之術語’’增塑油’’意欲涵蓋能夠增塑熱塑性 彈性體材料之所有油。如本文中所使用之術語”油”意欲涵 蓋具有一增塑功能之所有有機液體,包括石蠟、烴及酯基 油。該等油之黏度可在一流性液體與一樣之間改變。為了 用於一牙刷之頭部中,油必須為無毒的口腔可接受之類 型,且一合適之增塑油為所謂的醫用白油。醫用白油為一 用於熱塑性彈性體材料之已知增塑油,且為較佳的。通 常,一醫用白油包含一符合British及US Pharmacopoeia之 品質要求的高度精煉礦物油。通常,該等油遵守"Mineral Hydrocarbons in Food Regulations"1996、(S.I·第 1073號)及 United States F & D. A Regulations 第 178.3620(a)號及第 172.878號之品質要求。通常,該等油具有以下特性: 121838.doc 200812525 ISO 15ISO 68 相對密度@6〇°F 0.850 0.880 黏度 @20°C(cS) 25.0 235 黏度 @40°C(cS) 15.0 69.0 合適地,親脂芳香物質包含70重量百分比武 ^ -Χι / 0重量百分 比以上,較佳80重量百分比或80重量百分比 Μ上之薄荷腦unit. Preferably, the at least one elastic oral hygiene element comprises a thermoplastic elastomeric layer extending from the opposite surface of the head. The thin layer can be of a known shape. For example, the thin layer may be in the form of a strip having a length direction perpendicular to the length of the head handle of the toothbrush, - a straight direction to the opposite surface, and a direction parallel to the head handle The thickness direction. The thin layer is typically in the form of a thin layer of a known Dr. BESTTM Duo Pr〇tekt toothbrush.曰 Alternatively, the oral hygiene implement can be a tongue cleaning device other than a toothbrush. An example of such a device is disclosed, for example, in pct/ep〇6/〇〇〇i8i&de g_202 005 004291.9, relating to the "Zungen Reiniger" tongue cleaning device sold under the trademark DrBESTTM. <...Λ-王Ί土丹力 Ten thousand faces are well-known materials for the characteristics of elastomers. Many types of thermoplastic elastomer base materials are known for use in the oral hygiene implements of the present invention, for example, styrene-segmented copolymers. - A suitable substrate material is the base material of the base thermoplastic elastomer material used as the S-cleaning of the AQUA-deleted H DUO CLEANTM toothbrush sold by the present H. An example of such materials is the thermoplastic elastomeric material of the Thermolast KTM series (e.g., material TF 3 A AH) available from Gummiwerk Kraiburg GmbH & Co. KG, Germany, from 121838.doc 200812525. These materials are based on hydrogenated styrene block copolymers. The thermoplastic elastomer material preferably has a hardness in the range of 30 +/- 3 of Sh〇reA. Preferably, the thermoplastic elastomer material contains from 20 to 80 parts of a plasticizer. The range of plasticizer compositions (i.e., 5 to 15 weight percent of the lipophilic fragrance in the plasticizer mixture) appears to be important in optimizing the taste perceived by the user of the oral hygiene device of the present invention. of. A preferred ratio is 10 +/- 2%. For example, it has generally been found that less than 5% can be used to experience less beneficial taste, and if more than 15% is used, the taste can be undesirable. The term 'plasticizing oil' as used herein is intended to encompass all oils capable of plasticizing thermoplastic elastomeric materials. The term "oil" as used herein is intended to encompass all organic liquids having a plasticizing function, including paraffin, hydrocarbon and ester base oils. The viscosity of these oils can vary between first-class liquids and the same. For use in the head of a toothbrush, the oil must be of a non-toxic, orally acceptable type, and a suitable plasticizing oil is the so-called medical white oil. Medical white oil is a known plasticizing oil for thermoplastic elastomer materials and is preferred. Typically, a medical white oil contains a highly refined mineral oil that meets the quality requirements of British and US Pharmacopoeia. Typically, such oils are subject to the quality requirements of "Mineral Hydrocarbons in Food Regulations" 1996, (S.I. No. 1073) and United States F & D. A Regulations Nos. 178.3620(a) and 172.878. Typically, these oils have the following characteristics: 121838.doc 200812525 ISO 15ISO 68 Relative density @6〇°F 0.850 0.880 Viscosity @20°C(cS) 25.0 235 Viscosity @40°C(cS) 15.0 69.0 Suitably, lipophilic The fragrant substance contains 70% by weight of menthol - Χι / 0% by weight or more, preferably 80% by weight or 80% by weight of menthol

及/或其衍生物。為了用於一牙刷之頭部φ 少 τ ’诉生物必須 為-無毒的Π腔可接受之類型。已知自薄荷腦核衍生之許 多該等無毒的口腔可接受之化合物。合適之衍生物可包括 薄荷腦酯(例如,C1-5烷酸酯)、醚及酮衍生物,其中薄荷 腦核之羥基被羰基部分置換或經環化成醚(例如,/'呋唾 分。較佳地,親脂芳香物質包含較佳與20至35重量百分比 之薄荷_混合、較佳與5至8重量百分比之—或多個蓋基醋 齡言之,蓋基醋酸)混合、較佳與⑴重量百分比之薄 订夫南此α的40至60重量百分比之薄荷腦。該物質之一實 例為薄荷油。薄荷油通常包含組合物: 總薄荷腦 薄荷酮 蓋基酉旨 薄荷呋喃 通常在薄荷油中 最小值 52重量百分比 22重量百分比 5·8重量百分比 1·7重量百分比 最大值 56重量百分比 30重量百分比 7.8重量百分比 3.7重量百分比 薄荷咬喃為(RH+)_異構體。薄荷油 121838.doc 200812525 之另一組份為薄荷腦衍生物^)_(+)_蒲勒酮。 除了使人舒適之外,薄荷腦及薄荷腦衍生物之香味亦傳 遞口氣清新之感覺,且可有助於克服口臭之任何問題。 親脂芳香物質可與增塑油混合以形成塑化劑,且混合物 • 接著與熱塑性彈性體摻合。或者,親脂芳香物質及增塑油 可單獨與熱塑性彈性體摻合。 具有其口腔衛生元件之口腔衛生器具可根據用於製造該 器具之已知過程中之任一者來製造。一典型製造過程包含 由一塑膠材料及熱塑性彈性體材料共同模製器具。在該過 程中,可藉由一類似於用於習知材料之過程的模製過程來 共同模製上文中所界定之用於本發明中的熱塑性彈性體材 料。WO-A-2005/084487中揭示了該共同模製過程之一實 例。 在本發明之另一態樣中,因此提供一種用於製造一包含 塑膠材料把手部分及一口腔衛生元件之口腔衛生器具的 Φ 方法,該方法包含共同模製塑膠材料把手部分及一由一熱 塑性彈性體材料製造之口腔衛生元件,該熱塑性彈性體材 料具有在ShoreA 20至ShoreA 50之範圍内的硬度,且其組 . 成乃包含100至200份之熱塑性彈性體基底材料及1〇至100 伤之塑化劑’該塑化劑包含一增塑油與一親脂芳香物質 之此合物’該親脂芳香物質包含薄荷腦及/或其衍生物且 為混合物之5至15重量百分比。 該方法在其他方面可為大體上習知的。通常,該方法包 s首先在一第一射出模型中製造牙刷之一塑膠材料部分, 121838.doc 200812525 接著將如此製造之塑膠材料部分封閉於一具有一界定彈性 口腔衛生元件之形狀之模型空腔的第二射出模型中,接著 在塑膠材料與熱塑性彈性體之間達成接合之條件下將熱塑 性彈性體材料射出至第二模型中。牙刷製造之技術中=知 典型的塑膠材料,例如,用以製造Dr BESTTM Du。Pmtekt 牙刷之塑膠材料部分且包括聚丙烯的塑膠材料。 較佳提供以一些合適之包裝(例如,發泡包裝)來出售本 發明之口腔衛生器具。已發現一些親脂芳香物質(特定言 之,包括薄荷腦之物質)可能不利地影響用於包裝上之顏 料(尤其係藍色顏料)。本發明進一步解決此問題。 此問題係藉由一包裝來解決,該包裝包含一具有一在其 上為併入一顏料之印刷物質之表面的包裝層,且此印刷物 質係由一包含至少一層之障壁層覆蓋,該至少一層之每一 者為聚乙烯醇及聚乙烯,障壁層位於印刷物質與口腔衛生 器具之間。 另外提供一種產物,其包含一如上文所界定之口腔衛生 器具,該口腔衛生器具封閉於一包裝内,該包裝包含一包 裝層,該包裝層具有一在其上為併入一顏料之印刷物質的 表面’此印刷物質係由一包含至少一層之障壁層覆蓋,該 至少一層之每一者為聚乙烯醇及聚乙烯,且此障壁層位於 印刷材料與口腔衛生器具之間。 已發現該障壁層***在口腔衛生元件與印刷物質之間有 助於防止芳香對用於包裝上之印刷物質中之典型顏料的不 利影響。 121838.doc 11 200812525 合適地,包裝層可包含一紙板-鋁箔層壓物,其中印刷 物質印刷於鋁箔層之表面上。較佳地,障壁層包含兩個聚 乙烯層,其在此等兩個層之間夾入一在中間之聚乙烯醇 層。 【實施方式】 參看圖1,其展示一為牙刷之口腔衛生器具1,該口腔衛 生器具1包含一緊握把手2及一整體頭部3,該整體頭部3具 有自牙刷頭部3之一表面5延伸的刷毛4。把手2及頭部3係 由已知聚丙烯材料(例如,用於牙刷製造中之Moplen EP 548 TTM)製造。 在頭部3上提供彈性口腔衛生元件6,該彈性口腔衛生元 件6為自刷毛4自其延伸之頭部3之相反表面7延伸的熱塑性 彈性薄層。薄層6在構造上與已知之Dr.BEST™ Duo Protekt牙刷的薄層相同,亦即,自表面7延伸約2 mm,且 在其與表面7交叉處之基底處約1 mm寬。薄層6係與一在頭 部3上方的彈性體之覆蓋物8整體形成為一體。 薄層6及覆蓋物8係由具有ShoTeA 30之硬度的熱塑性彈 性體材料製造,該熱塑性彈性體材料包含100至200份之熱 塑性彈性體基底材料(例如,Thermolast K™ TF 3 AAH)及 10至100份之塑化劑。具體言之,使用分別包含120份之熱 塑性彈性體基底材料與20份之塑化劑,及200份之熱塑性 彈性體基底材料與100份之塑化劑的熱塑性彈性體材料。 在熱塑性彈性體材料之此等組合物之每一者中,塑化劑 包含遵守”Mineral Hydrocarbons in Food Regulations” 121838.doc -12- 200812525 1996、(S.L 第 1073號)及 United States F & D· A Regulations 第178.3620(a)號及第172.878號之品質要求的醫用白油之 混合物,其具有以下特性: ISO 15ISO 68 相對密度@6〇°F 0.850 0.880 黏度 @20°C (cS) 25.0 235 黏度 @40°C(cS) 15.0 69.0 用一組合物之薄荷油混合此油:And / or its derivatives. In order to be used on the head of a toothbrush, φ less τ ́ v. The creature must be of a type that is non-toxic and acceptable for the cavity. Many such non-toxic orally acceptable compounds derived from the menthol nucleus are known. Suitable derivatives may include menthol esters (e.g., C1-5 alkanoates), ethers, and ketone derivatives in which the hydroxy group of the menthol core is partially replaced by a carbonyl group or cyclized to an ether (e.g., /' furansene. Preferably, the lipophilic aroma comprises, preferably, 20 to 35 weight percent of the mint-mixed, preferably 5 to 8 weight percent - or a plurality of cover vinegars, capped acetic acid), preferably With 40% by weight of the menthol of this alpha of 40% by weight of the menthol. An example of this material is peppermint oil. Peppermint oil usually comprises a composition: Total menthol menthone ketone capsin Mint furan usually in peppermint oil Minimum 52 weight percent 22 weight percent 5.8 weight percent 1.7 weight percent maximum 56 weight percent 30 weight percent 7.8 The weight percentage of 3.7 weight percent of the mint bite is the (RH+) _ isomer. The other component of peppermint oil 121838.doc 200812525 is the menthol derivative ^)_(+)_Pullerone. In addition to being comfortable, the scent of menthol and menthol derivatives also conveys a refreshing sensation and helps to overcome any problems with bad breath. The lipophilic aroma can be mixed with a plasticizing oil to form a plasticizer, and the mixture is then blended with the thermoplastic elastomer. Alternatively, the lipophilic aroma and the plasticizing oil may be blended separately with the thermoplastic elastomer. An oral hygiene implement having its oral hygiene element can be manufactured in accordance with any of the known processes for making the appliance. A typical manufacturing process involves co-molding an instrument from a plastic material and a thermoplastic elastomer material. In this process, the thermoplastic elastomer material used in the present invention as defined above can be co-molded by a molding process similar to the process for conventional materials. An example of this co-molding process is disclosed in WO-A-2005/084487. In another aspect of the invention, there is therefore provided a method of making a Φ method comprising a handle portion comprising a plastic material and an oral hygiene member, the method comprising co-molding a handle portion of the plastic material and a thermoplastic An oral hygiene element made of an elastomer material having a hardness in the range of ShoreA 20 to Shore A 50, and a group comprising 100 to 200 parts of a thermoplastic elastomer base material and 1 to 100 wounds The plasticizer 'the plasticizer comprises a compound of a plasticizing oil and a lipophilic aroma. The lipophilic aroma comprises menthol and/or a derivative thereof and is 5 to 15 weight percent of the mixture. This method can be generally known in other respects. Typically, the method package s first manufactures a portion of the plastic material of the toothbrush in a first shot model, 121838.doc 200812525. The portion of the plastic material thus fabricated is then enclosed in a mold cavity having a shape defining an elastic oral hygiene element. In the second shot model, the thermoplastic elastomer material is then ejected into the second mold under conditions in which the bond between the plastic material and the thermoplastic elastomer is achieved. In the technology of toothbrush manufacturing = typical plastic materials, for example, for the manufacture of Dr BESTTM Du. Pmtekt toothbrushes are made of plastic material and include polypropylene plastic material. It is preferred to provide the oral hygiene implement of the present invention in some suitable package (e.g., a blister pack). It has been found that some lipophilic aromas (specifically, substances including menthol) may adversely affect the pigments used on the package (especially blue pigments). The present invention further addresses this problem. The problem is solved by a package comprising a packaging layer having a surface on which a pigment is incorporated, and the printing material is covered by a barrier layer comprising at least one layer, the at least Each of the layers is polyvinyl alcohol and polyethylene, and the barrier layer is between the printed material and the oral hygiene device. Further provided is a product comprising an oral hygiene device as defined above, the oral hygiene device enclosed in a package comprising a packaging layer having a printed material on which a pigment is incorporated The surface of the printed material is covered by a barrier layer comprising at least one layer, each of which is polyvinyl alcohol and polyethylene, and the barrier layer is between the printed material and the oral hygiene implement. The insertion of the barrier layer between the oral hygiene element and the printed material has been found to help prevent the adverse effects of aroma on typical pigments used in the printed materials on the package. 121838.doc 11 200812525 Suitably, the packaging layer may comprise a paperboard-aluminum foil laminate in which the printed material is printed on the surface of the aluminum foil layer. Preferably, the barrier layer comprises two polyethylene layers sandwiching an intermediate layer of polyvinyl alcohol between the two layers. [Embodiment] Referring to Figure 1, there is shown an oral hygiene implement 1 for a toothbrush, the oral hygiene implement 1 comprising a gripping handle 2 and an integral head 3 having one of the self-brush heads 3 The bristles 4 extending from the surface 5. Handle 2 and head 3 are made of a known polypropylene material (e.g., Moplen EP 548 TTM for use in the manufacture of toothbrushes). An elastic oral hygiene element 6 is provided on the head 3, the elastic oral hygiene element 6 being a thin layer of thermoplastic elastomer extending from the opposite surface 7 of the head 3 from which the bristles 4 extend. The thin layer 6 is identical in construction to the thin layer of the known Dr. BESTTM Duo Protekt toothbrush, i.e., extends about 2 mm from the surface 7, and is about 1 mm wide at the base where it intersects the surface 7. The thin layer 6 is integrally formed integrally with the cover 8 of the elastomer above the head 3. The thin layer 6 and the cover 8 are made of a thermoplastic elastomer material having a hardness of ShoTeA 30, the thermoplastic elastomer material comprising 100 to 200 parts of a thermoplastic elastomer base material (for example, Thermolast KTM TF 3 AAH) and 10 to 100 parts of plasticizer. Specifically, a thermoplastic elastomer material comprising 120 parts of a thermoplastic elastomer base material and 20 parts of a plasticizer, and 200 parts of a thermoplastic elastomer base material and 100 parts of a plasticizer, respectively, was used. In each of these compositions of thermoplastic elastomeric materials, the plasticizer comprises compliance with "Mineral Hydrocarbons in Food Regulations" 121838.doc -12-200812525 1996, (SL No. 1073) and United States F & D · A Regulations A mixture of medical white oils of quality requirements 178.3620(a) and 172.878 with the following characteristics: ISO 15ISO 68 Relative density @6〇°F 0.850 0.880 Viscosity @20°C (cS) 25.0 235 Viscosity @40°C(cS) 15.0 69.0 Mix this oil with a blend of peppermint oil:

最大值 56重量百分比 30重量百分比 7.8重量百分比 3.7重量百分比 -薄荷油混合物之 最小值 總薄荷腦 薄荷酮 堇基酯 薄荷呋喃 在混合物中,薄 1 0重量百分比。 52重量百分比 22重量百分比 5.8重量百分比 1.7重量百分比 油相當於白醫用油 牙刷之塑膠材料部分(亦即,把手2及頭部3)係藉由一習 知射出成形過程來製造。接著將此塑膠材料部分封閉於一 具有一界定薄層6之形狀之模型空腔(未圖示)的射出模型 (未圖示)中,且此組合物之熱塑性彈性體材料經射出成形 以形成薄層6。該程序與將不具有薄荷油之相同白醫用油 用作塑化劑之已知彈性體材料組合物為完全相同的方式, 亦即,以與已知Dr.BEST™ Duo Protekt牙刷之薄層相同的 方式。此在用含有上文所描述之材料的薄荷油實現對 121838.doc •13- 200812525Maximum 56 weight percent 30 weight percent 7.8 weight percent 3.7 weight percent - minimum of peppermint oil mixture Total menthol Menthone oxime ester Menthyl furan In the mixture, thin 10% by weight. 52 weight percent 22 weight percent 5.8 weight percent 1.7 weight percent Oil equivalent to white medical oil The plastic material portion of the toothbrush (i.e., handle 2 and head 3) is manufactured by a conventional injection molding process. The plastic material is then partially enclosed in an injection mold (not shown) having a mold cavity (not shown) defining the shape of the thin layer 6, and the thermoplastic elastomer material of the composition is injection molded to form Thin layer 6. This procedure is identical to the known elastomeric material composition which uses the same white medical oil without peppermint oil as the plasticizer, ie, with a thin layer of the known Dr. BESTTM Duo Protekt toothbrush. same way. This is achieved with peppermint oil containing the materials described above. 121838.doc •13- 200812525

DnBEST™ Duo Protekt牙刷之已知熱塑性彈性體材料的工·· i 替代中係有利的。發現塑化劑中之1〇重量百分比薄荷油的 比例在達成使消費者滿意之味道中為最佳的。 參看圖2及圖3,其展示一整體適於一上文之牙刷丨的包 裝10。此包裝包含一 250微米厚之聚對苯二甲酸乙二酯發 泡11 ’其界疋一適於封閉牙刷1之典型發泡空腔i 2。發泡 空腔12係由一包裝層13封閉,該包裝層13包含一紙板13A_ 鋁箱13B層壓物,其中印刷物質14印刷於鋁落層13B之表 面上。此包裝層13通常為3 00至400微米厚,例如,約35〇 微米厚。此印刷物質14係由一包含兩個聚乙烯層15八、 15B之障壁層15覆蓋,該兩個聚乙烯層i5A、156在此等兩 個層15A、15B之間夾入一在中間之聚乙烯醇層15(:。障壁 層15通常為40至60微米厚,通常約5〇微米厚。 【圖式簡單說明】 圖1展不為牙刷之本發明之口腔衛生裝置的總侧視圖。 圖2展示用於圖丨之口腔衛生裝置之包裝的總侧視圖。 圖3展示圖2之包裝之部分之構造的放大橫截面。 【主要元件符號說明】 1 口腔衛生器具/牙刷 2 緊握把手 3 頭部 4 刷毛 5 表面 6 口腔衛生元件/薄層 121838.doc 14· 200812525 7 表面 8 覆蓋物 10 包裝 11 發泡 12 發泡空腔 13 包裝層 13A 紙板 13B 鋁箔 14 印刷物質 15 障壁層 15A 聚乙稀層 15B 聚乙烯層 15C 聚乙烯醇層 121838.doc - 15-DnBESTTM Duo Protekt toothbrushes are known to be advantageous in the alternative of thermoplastic elastomer materials. It has been found that the proportion of 1% by weight of peppermint in the plasticizer is optimal in achieving a taste which is satisfactory to the consumer. Referring to Figures 2 and 3, there is shown a package 10 integrally adapted for a top toothbrush. The package comprises a 250 micron thick polyethylene terephthalate foam 11' which is a suitable foaming cavity i2 suitable for closing the toothbrush 1. The foamed cavity 12 is closed by a packaging layer 13 comprising a paperboard 13A_aluminum box 13B laminate in which the printed material 14 is printed on the surface of the aluminum falling layer 13B. This packaging layer 13 is typically from 300 to 400 microns thick, for example, about 35 inches thick. The printed material 14 is covered by a barrier layer 15 comprising two polyethylene layers 15,8, 15B, between which the two layers of layers 15A, 15B are sandwiched. The vinyl alcohol layer 15 (: the barrier layer 15 is usually 40 to 60 μm thick, usually about 5 μm thick.) Brief Description of the Drawings Fig. 1 is a general side view of the oral hygiene device of the present invention which is not a toothbrush. 2 shows a general side view of the package for the oral hygiene device of Fig. 2. Fig. 3 shows an enlarged cross section of the configuration of the portion of the package of Fig. 2. [Explanation of main components] 1 oral hygiene device/toothbrush 2 gripping handle 3 Head 4 bristles 5 Surface 6 Oral hygiene components / Thin layer 121838.doc 14· 200812525 7 Surface 8 Cover 10 Packaging 11 Foam 12 Foaming cavity 13 Packaging layer 13A Paperboard 13B Aluminum foil 14 Printing material 15 Barrier layer 15A Polyethylene B Thin layer 15B polyethylene layer 15C polyvinyl alcohol layer 121838.doc - 15-

Claims (1)

200812525 十、申請專利範圍: 1 ·種口腔衛生器具,其具有至少一彈性口腔衛生元件, 該彈性口腔衛生元件係由一熱塑性彈性體材料製造,該 熱塑性彈性體材料具有在ShoreA 20至处〇代八5〇之範圍 内的硬度,且其組成乃包含100至2〇〇份之一熱塑性彈性 , 體基底材料及10至100份之一塑化劑,該塑化劑包含一 _ 增塑油與一親脂芳香物質之混合物,該親脂芳香物質包 含薄荷腦及/或其衍生物且為該混合物之5至15重量百分 • 比。 2. 如請求項丨之口腔衛生器具,其為一牙刷,該牙刷包含 一緊握把手及一具有自該牙刷頭部之一表面延伸之刷毛 的整體或可替代頭部,且該至少一彈性口腔衛生器具包 3自忒頭部之相反表面延伸的熱塑性彈性薄層。 3. 如咕求項1或2之口腔衛生器具,其中該增塑油包含醫用 白油。200812525 X. Patent application scope: 1 - An oral hygiene device having at least one elastic oral hygiene element, which is made of a thermoplastic elastomer material having a generation at ShoreA 20 a hardness within the range of 8.5 Å, and the composition thereof comprises 100 to 2 parts of thermoplastic elastomer, a bulk substrate material and 10 to 100 parts of a plasticizer, the plasticizer comprising a plasticizer and a plasticizer A mixture of a lipophilic aroma comprising menthol and/or a derivative thereof and being 5 to 15 weight percent of the mixture. 2. The oral hygiene device of claim 1 , which is a toothbrush comprising a gripping handle and an integral or replaceable head having bristles extending from a surface of the head of the toothbrush, and the at least one elastic The oral hygiene implement package 3 is a thin layer of thermoplastic elastomer extending from the opposite surface of the head. 3. The oral hygiene device of claim 1 or 2, wherein the plasticizing oil comprises medical white oil. 4·如明求項1或2之口腔衛生器具,其中該親脂芳香物質包 含10+/-2%之該塑化劑。 5.:請求:】或2之口腔衛生器具,其中該親脂芳香物質包 3 70重置百分比或7〇重量百分比以上之薄荷腦及,或其之 一或多個衍生物。 比之 6.如明求項5之口腔衛生器具,其中該親脂芳香物質包含 與'至35重量百分比之薄荷酮、…重量百分比之一或 夕個蓋基酯(特定言之,菫基醋酸)及1至5重量百分 薄荷夫喃混合的4〇至6〇重量百分比之薄荷腦。 121838.doc 200812525 如請求項6之口腔衛生器具,其中該親脂芳香物質包含 下列組成: 最小值 最大值 總薄荷腦 52重量百分比 56重量百分比 薄荷酮 22重量百分比 3〇重量百分比 堇基酯 5.8重量百分比 7 · 8重量百分比 薄荷呋喃 1.7重量百分比 3.7重量百分比 如請求項1或2之 口腔衛生器具,其 中該親脂芳香物質包 含薄荷油。 9. 一種用於製造一 口腔衛生器具的方法,該口腔衛生器具 包含一塑膠材料把手部分及一 口腔衛生元件,該方法包 含共同模製該塑膠材料把手部分及一 口腔衛生元件,該 口腔衛生元件係由一熱塑性彈性體材料製造該材料具有 在ShoreA 20至Sh〇reA 50之範圍内的硬度且其組成乃包 含: 100至200份之一熱塑性彈性體基底材料及1〇至1〇〇份 之一塑化劑,該塑化劑包含一增塑油與一親脂芳香物質 之混合物,該親脂芳香物質包含薄荷腦及/或其衍生物且 為該混合物之5至1 5重量百分比。 10· —種包含一以包裝提供之如請求項丨至8中任一項之口腔 衛生器具的物品,該物品包含一包裝層,該包裝層具有 一在其上為併入一顏料之印刷物質的表面,且此印刷物 質係由一包含至少一層之障壁層覆蓋,該至少一層之每 一者為聚乙烯醇及聚乙稀,該障壁層位於該印刷物質與 121838.doc 200812525 該口腔衛生器具之間。 11 ·如請求項10之物品,其中該障壁層包含兩個聚乙烯層, 該兩個聚乙烯層在此等兩個聚乙烯層之間夾入一在中間 的聚乙烯醇層。 12·如請求項10或11之物品,其中該障壁層具有40至60微米 之厚度。4. The oral hygiene device of claim 1 or 2, wherein the lipophilic aroma comprises 10 +/- 2% of the plasticizer. 5. The oral hygiene device of claim 2 or 2, wherein the lipophilic aroma substance comprises a 70% replacement percentage or more than 7% by weight of menthol and, or one or more derivatives thereof. The oral hygiene device of claim 5, wherein the lipophilic aroma comprises - to 35 weight percent of menthone, ... one by weight or one of a galenyl ester (specifically, thioglycolic acid And 4 to 6 weight percent of menthol mixed with 1 to 5 weight percent of the puff. The oral hygiene device of claim 6, wherein the lipophilic aroma comprises the following composition: minimum value maximum total menthol 52 weight percent 56 weight percent menthone 22 weight percent 3 weight percent thiol ester 5.8 weight Percentage 7.8 wt% Peppermint Furan 1.7 wt% 3.7 wt% The oral hygiene implement of claim 1 or 2, wherein the lipophilic fragrance comprises peppermint oil. 9. A method for making an oral hygiene implement comprising a handle portion of a plastic material and an oral hygiene member, the method comprising co-molding the handle portion of the plastic material and an oral hygiene member, the oral hygiene member Made of a thermoplastic elastomer material having a hardness in the range of ShoreA 20 to Sh〇reA 50 and a composition comprising: 100 to 200 parts of one thermoplastic elastomer base material and 1 to 1 part A plasticizer comprising a mixture of a plasticizing oil and a lipophilic aroma comprising menthol and/or a derivative thereof and being 5 to 15 weight percent of the mixture. An article comprising an oral hygiene device according to any one of claims 1 to 8, which comprises a packaging layer having a printing substance on which a pigment is incorporated a surface, and the printed material is covered by a barrier layer comprising at least one layer, each of the at least one layer being polyvinyl alcohol and polyethylene, the barrier layer being located on the printed material and 121838.doc 200812525 the oral hygiene device between. 11. The article of claim 10, wherein the barrier layer comprises two polyethylene layers, the two polyethylene layers sandwiching an intermediate layer of polyvinyl alcohol between the two polyethylene layers. 12. The article of claim 10 or 11, wherein the barrier layer has a thickness of from 40 to 60 microns. 121838.doc 200812525 七、指定代表圖: (一) 本案指定代表圖為:第(1)圖。 (二) 本代表圖之元件符號簡單說明: 1 口腔衛生器具 2 緊握把手 ^ 3 頭部 4 剛毛 5 表面 6 口腔衛生元件/薄層 7 表面 8 覆蓋物 Φ 八、本案若有化學式時,請揭示最能顯示發明特徵的化學式 (無) 121838.doc121838.doc 200812525 VII. Designated representative map: (1) The representative representative of the case is: (1). (2) Brief description of the symbol of the representative figure: 1 Oral hygiene device 2 Grip handle ^ 3 Head 4 Bristle 5 Surface 6 Oral hygiene component / Thin layer 7 Surface 8 Cover Φ 8. If there is a chemical formula in this case, please Reveal the chemical formula that best shows the characteristics of the invention (none) 121838.doc
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