TW200803729A - Active compound combinations having insecticidal and acaricidal properties - Google Patents

Abstract

The novel mixtures comprising at least one active compound of the formula (I) where Hal represents chlorine, bromine or iodine and at least one of the active compounds 1 to 4, listed in the description, from the class of the acaricides have very good insecticidal and acaricidal properties.

Description

200803729 九、發明說明： 【發明所屬之技術領域】 本發明係關於新穎活性化合物組合，其首先包含至少 一種式（I)之已知化合物，且其次為至少一種殺蟎劑群中之 5 另一已知活性化合物，此等組合頗適用於控制動物害蟲， 例如：昆蟲及不欲之蜱瞒。 【先前技術】 已知式（I)之化合物200803729 IX. INSTRUCTIONS OF THE INVENTION: FIELD OF THE INVENTION The present invention relates to novel active compound combinations which first comprise at least one known compound of formula (I), and secondly at least one of at least one acaricide group Active compounds are known, and such combinations are quite suitable for controlling animal pests such as insects and unwanted insects. [Prior Art] Compounds of formula (I) are known

10 其中10 of which

Hal代表氯、漠:或埃， *代表呈R-或S-構形之碳原子，具有殺昆蟲活性。此適用於 該化合物之消旋型式(EP-A 1 006 107)甚且適用於其（S)-構 形之鏡像異構物(WO 06/22225)。其可特指化合物(la)、（lb) 15 和（Ic) 0Hal represents chlorine, desert: or angstrom, and * represents a carbon atom in the R- or S-configuration, which has insecticidal activity. This racemic form for the compound (EP-A 1 006 107) is even applicable to the mirror image isomer of its (S)-configuration (WO 06/22225). It may specifically refer to compounds (la), (lb) 15 and (Ic) 0

(la): (S)-3-碘-NM2-甲基-4-[l，2,2,2-四氟小(三氟曱基）乙基] 苯基}-Ν2-(1-曱基-2-曱基磺醯基乙基）鄰苯二曱醯胺 5 96050-發明說明書 200803729(la): (S)-3-iodo-NM2-methyl-4-[l,2,2,2-tetrafluorosuccinyl(trifluoromethyl)ethyl]phenyl}-Ν2-(1-曱Base-2-mercaptosulfonylethyl) phthalamide 5 96050 - invention specification 200803729

(lb): (S)-3-氯甲基-4-[1，2,2,2-四氟小(三氟甲基）乙基] 苯基}-N2-(l-曱基-2-曱基磺醯基乙基）鄰苯二曱醯胺(lb): (S)-3-Chloromethyl-4-[1,2,2,2-tetrafluorosuccinyl(trifluoromethyl)ethyl]phenyl}-N2-(l-fluorenyl-2 -mercaptosulfonylethyl) phthalamide

5 (Ic): (S)-3-溴曱基-4-[l，2,2,2-四氟小(三氟甲基）乙基] 苯基卜Ν2-(1-曱基-2-曱基磺醯基乙基）鄰苯二甲醯胺 此外，咸知某些化合物具有抗蜗特性。其包括例如： 1·毆蟎多（propargite)(從 US-A3,272,854 得知）5 (Ic): (S)-3-bromoindolyl-4-[l,2,2,2-tetrafluorosuccinyl(trifluoromethyl)ethyl]phenyl bromide 2-(1-indolyl-2 - Mercaptosulfonylethyl) o-phthalamide In addition, certain compounds have anti-worm properties. It includes, for example: 1·propargite (from US-A3,272,854)

ίο 2·芬佈賜（fenbutatin oxide)(從 US-A 3,657,451 得知） 6 96050-發明說明書 200803729Οο· 芬butatin oxide (available from US-A 3,657,451) 6 96050-invention specification 200803729

3·汰芬隆（diafenthiuron)(從 DE-A 3034905 得知）3. Difenthiuron (available from DE-A 3034905)

CH3 ICH3 I

CHj- CH S / H ch3CHj- CH S / H ch3

0又七人n-CH3 \ Η H CH,0 and seven people n-CH3 \ Η H CH,

CH3—CH CH3CH3—CH CH3

4·依殺蟎（etoxazole)(從 EP-A 0 639 572 得知） 【發明内容】 令人驚訝地，根據本發明之活性化合物組合之殺昆蟲活 性頗高於個別活性化合物之活性總和。有未預期之真實相乘 10 效應存在，且其非僅為活性之加成而已。 令人驚訝地，根據本發明之活性化合物組合之殺蟎活性 頗高於個別活性化合物之活性總和。有未預期之真實相乘效 應存在，且其非僅為活性之加成而已。 除了至少一種呈純鏡像異構型式或為兩種鏡像異構物 7 96050-發明說明書 200803729 以任意比例之混合物型式之式(i)活性化合物之外，根據本發 明之活性化合物組合尚包含至少一種個別列於上文中之殺 蟎劑1至4。 較佳者，根據本發明之活性化合物組合包含活性化 5 合物（la)、（lb)或（Ic)其中之一及個別列於上文中之殺蟎劑 其中之一。 特佳者係為列於表1中之混合物。 表1 混合物包含 la 和 殿虫茜多 la 和 芬佈賜 la 和 汰芬隆 la 和 依殺蜗 lb 和 區曼瞒多 lb 和 芬佈賜 lb 和 汰芬隆 lb 和 依殺虫茜 Ic 和 殿虫高多 Ic 和 芬佈賜 Ic 和 汰芬隆 Ic 和 依殺蜗 更特佳者為列於表2中之混合物。 ίο 表2 混合物包含 8 96050-發明說明書 200803729 lb 和 歐虫禹多 lb 和 ---- 芬佈賜 lb 和 汰芬降 lb 和 依殺虫高 '1 虽根據本發明之活性化合物組合中之活性化合 些重量比例存在時，其協乘作用會特別明顯。然而二化 合物組合中之活性化合物之重量比可在相#廣之範圍 «變化。-般而言，_本發明之組合包 ，和編…其中之-以下列之較二= 合比例存在： 較佳之混合比例：125:1至1:125 特佳之混合比例：25:1至1:25 10 15 .混合比㈣為重量比。該比例被理解為表示為式 (I):殺蜗劑之活性化合物。 人本發明之活性化合物組合，結合良好之植物耐受性斑適 之毒性以及良好之環境耐受度，可適用以保護植 2=官、用以提高收穫量、用以改善收穫品之品質及 _二=:物广特別是昆蟲、蛛形綱動物，蟲、線蟲 :體=，其可見於農業、園藝業、動物飼養業、森林、 1 匕園和休閒設施、貯存產品及原料之保護及衛生管理區中遇 性。為植物保護劑使用。其對於正常之敏感及抗 =種具有抗性且可對抗所有或—些發展階段。上述害蟲包 96〇5〇-發明說明書 9 200803729 來自益目（Anoplura(Phthiraptera))者，例如：恙蟲屬 (Damalinia spp.)、血蟲屬（Haematopinus spp·)、毛兹屬 (Linognathus spp·)、虱蝨屬（Pediculus spp·)、齧毛蝨屬 (Trichodectes spp. ) 〇 5 來自蛛形綱者，例如：粗足粉蜗（Acarus siro )、桔瘤 節蜱（Aceria sheldoni)、刺皮癭蜗屬（Aculops spp·)、刺 癭蜗屬（Aculus spp·)、花蜱屬（Amblyomma spp·)、銳緣 蜱屬（Argasspp.)、牛蜱屬（Boophilusspp·)、偽葉蜗屬 (Brevipalpus spp.)、苜蓿苔蜗（Bryobia praetiosa)、足蟎 1〇 屬（Chorioptes spp·)、雞皮刺蜗（Dermanyssus gallinae)、 原葉蜗屬（Eotetranychusspp.)、棗葉錄瞒（Epitrimerus pyri)、褐葉蜗屬（Eutetranychusspp·)、癭蜗屬（Eriophyes SPP·)、半跗線蜗屬（Hemitarsonemusspp·)、璃眼蜱屬 (Hyalomma spp·)、硬蜱屬（Ixodes spp·)、黑寡婦虫知蛛 15 ( Latrodectus mactans )、紅虫知蛛屬（Metatetranychus spp* )、 小爪瞒屬（Oligonychusspp·)、鈍緣蜱屬（Ornithodoros spp·)、物蛛蜗屬（Panonychus spp.)、柑桔銹蜗（Phyllocoptruta oleivora)、側多食跗線蜗（Polyphagotarsonemus latus )、 癢瞒屬（Psoroptesspp·)、扇頭蜱屬（Rhipicephalusspp·)、 20 根瞒屬（Rhizoglyphus spp.)、齋瞒屬（Sarcoptes spp.)、 中東金蛾（Scorpio maurus)、小跗線蜗屬（Stenotarsonemus spp·)、跗線蜗屬（Tarsonemusspp·)、葉蜗屬（Tetranychus spp·)、蕃祐沙棘癭蜗（Vasateslycopersici) 〇 來自雙殼綱（Bivalva )者，例如：貝屬（Dreissena spp·)。 10 96050-發明說明書 200803729 來自唇足目（Chilopoda)者，例如：地娱虫公屬（Geophilus SPP )、虫由蜒（Scutigeraspp·)。 來自勒翅目（Coleoptera )者，例如：菜豆象 (Acanthoscelides obtectus)、金龜屬（Adoretus spp.)、 5 揚樹螢葉曱（Agelastica alni)、叩頭蟲屬（Agriotes spp·)、 馬鈴薯自思金龜（Amphimallon solstitialis )、家具竊蠹 (Anobium punctatum)、星天牛屬(Anoplophora spp.)、 鈴象屬（Anthonomusspp·)、圓皮蠹屬（Anthrenusspp.)、 總金龜屬（Apogonia spp·)、隱食甲屬（Atomaria spp·)、 10 毛皮蠢屬（Attagenus spp·)、敏豆象（Bruchidius obtectus )、 豆象屬（Bruchusspp) ·、龜象屬（Ceuthorhynchusspp·)、 方°彖象鼻蟲（Cleorms mendicus)、金針蟲屬（Conoderus SPP·)、象鼻蟲屬（Cosmopolites spp.)、新西蘭草地蜻増 (Costelytra zealandica)、象蟲屬（Curculio spp·)、揚乾 15 象（Cryptorhynchus lapathi)、皮蠢屬（Dermestes spp·)、 葉曱屬（Diabroticaspp.)、植食瓢轰屬（Epilachnaspp·)、 古巴象鼻蟲（Faustinus cubae )、裸蛛甲（Gibbium psylloides )、非洲獨角蟲（Heteronychus arator )、白虫齊增 (Hylamorpha elegans )、北美家天牛（Hylotrupes bajulus )、 20 苜蓿象鼻蟲（Hypera postica)、小蠢屬（Hypothenemus SPP·)、藍刺鹤蟲（Lachnostema consanguinea )、科羅拉多 金花蟲（Leptinotarsa decemlineata )、水稻水象鼻蟲 (Lissorhoptrus oryzophilus)、筒嗓象屬（Lixus spp·)、粉 蠹屬（Lyctus spp·)、花粉甲蟲（Meligethes aeneus )、大 11 96050-發明說明書 200803729 栗總角金龜（Melolontha melolontha )、天牛（Migdolus spp，）、墨天牛屬（Monochamus spp·)、葡萄象鼻蟲（Naupactus x a lithograph us )、黃蛛曱（Niptus hololeucus )、犀角金龜 (Oryctes rhinoceros )、鑛胸粉扁蟲（Oryzaephilus 5 surinamensis)、黑葡萄耳象（Otiorrhynchus sulcatus )、小 青花金龜（Oxycetonia jucunda)、辣根猿葉蟲（Phaedon cochleariae )、金龜子（Phyllophaga spp·)、曰本豆金龜 (Popillia japonica)、安第斯馬鈴薯象屬（Premnotrypes spp·)、油菜蘭跳甲（Psylliodes chrysocephala)、蛛甲屬 ίο ( Ptinus spp.)、黑根瓢蟲（Rhizobius ventralis )、榖蠢 (Rhizopertha dominica )、稻榖象鼻蟲屬（Sitophilus spp·)、 尖隱 σ彖象屬（Sphenophorus spp· ) 、Sternechus spp.、4. Etoxazole (known from EP-A 0 639 572) SUMMARY OF THE INVENTION Surprisingly, the insecticidal activity of the active compound combinations according to the invention is considerably higher than the sum of the activities of the individual active compounds. There is an unexpected real multiplication. 10 The effect exists, and it is not just the addition of activity. Surprisingly, the acaricidal activity of the active compound combinations according to the invention is considerably higher than the sum of the activities of the individual active compounds. There is an unexpected real multiplication effect, and it is not just an additive addition. In addition to at least one active compound of the formula (i) in a mixture of any of the image isomers or the two mirror isomers 7 96050-invention specification 200803729 in any ratio, the active compound combinations according to the invention still comprise at least one Individual acaricides 1 to 4 listed above. Preferably, the active compound combination according to the invention comprises one of the active compounds (la), (lb) or (Ic) and one of the acaricides listed above individually. The most preferred ones are the mixtures listed in Table 1. Table 1 The mixture contains la and worms 茜la and fenbufen la and fenflulon la and lysine lb and region mandarin lb and fenbufen lb and fenfen lb and insecticide Ic and worm High poly Ic and fenbufen Ic and fenflulon Ic and snails are more excellent as the mixture listed in Table 2. Οο Table 2 Mixture contains 8 96050 - invention specification 200803729 lb and worms lb and - fenbene lb and fenfen lb and insecticidal high '1 although active combination in the active compound combination according to the invention When these weight ratios exist, their synergistic effect will be particularly noticeable. However, the weight ratio of the active compound in the di-compound combination can be varied in the range of the phase. In general, the combination package of the present invention, and the composition thereof, are present in the following two ratios: preferred mixing ratio: 125:1 to 1:125. Excellent mixing ratio: 25:1 to 1 :25 10 15 . The mixing ratio (4) is the weight ratio. This ratio is understood to mean the active compound of formula (I): a smoldering agent. The combination of active compounds of the present invention, combined with good toxicity of plant-tolerant plaques and good environmental tolerance, can be applied to protect plants, to increase yield, to improve the quality of harvested products and _二=: Wuguang, especially insects, arachnids, insects, nematodes: body=, which can be found in agriculture, horticulture, animal husbandry, forests, 1 garden and leisure facilities, storage products and raw materials protection and Suffering in the health management area. Used as a plant protection agent. It is resistant to normal sensitivity and resistance and can combat all or some stages of development. The above-mentioned pest package 96〇5〇-Invention specification 9 200803729 From Anoplura (Phthiraptera), for example: Damalinia spp., Haematopinus spp., Linognathus spp· ), Pediculus spp., Trichodectes spp. 〇5 from arachnids, such as: Acarus siro, Aceria sheldoni, thorn Aculops spp., Aculus spp., Amblyomma spp., Argasspp., Boophilus spp., Pseudostellaria Brevipalpus spp.), Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychusspp., Epipirerus pyri, Eutetranychusspp·, Eriophyes SPP·, Hemitarsonemusspp·Hyalomma spp·, Ixodes spp·, black widow Latrodectus mactans, Metatetranychus spp* ), Oligonychusspp·, Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus , genus Psoroptesspp, Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Scorpio maurus (Stenotarsonemus spp.), genus Tarsonemusspp, Tetranychus spp., Vasateslycopersici 〇 from Bivalva, for example: Dreissena spp· ). 10 96050-Invention Manual 200803729 From the family of Chilopoda, for example: Geophilus SPP, Scutigeraspp. From the order of the genus Coleoptera, for example: Acanthoscelides obtectus, Adoretus spp., 5 Agelastica alni, Agriotes spp., (Amphimallon solstitialis), Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia spp., Hidden Atomaria spp., 10 Attagenus spp., Bruchidius obtectus, Bruchusspp, Ceuthorhynchus spp, and weevil Cleorms mendicus), Conoderus SPP·, Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabroticaspp., Epilachnaspp., Faustinus cubae, Gibbium psylloides, African hornworm (H) Eteronychus arator ), Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus SPP, Lachnostema consanguinea, Leptinotarsa decemlineata, Lisorhoptrus oryzophilus, Lixus spp., Lyctus spp., Meligethes aeneus, large 11 96050-invented Specification 200803729 Melolontha melolontha, Migdolus spp, Monochamus spp, Naupactus xa lithograph us, Niptus hololeucus, Rhinoceros beetle (Oryctes rhinoceros), Oryzaephilus 5 surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp. Popillia japonica, Andean potato genus (Premnotrypes spp.), Brassica rapae (Psylliodes chrysocephala), genus ίο (Ptinus spp.), Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., genus Sphenophorus spp· ), Sternechus spp.,

Symphyletes spp，、離體黃粉蟲（Tenebrio molitor)、麵包 蟲屬（Triboliumspp·)、斑皮蠢屬（Trogodermaspp·)、籽 15 象屬（Tychius spp·)、虎天牛屬（Xylotrechus spp·)、距 步甲屬（Zabrus spp·)。 來自彈尾目（Collembola )者，例如：具刺棘跳蟲 (Onychiurus armatus ) 〇 來自革翅目（Dermaptera)者，例如··地虫吳忪（Forficula 2〇 auricularia) 〇 來自倍足目（Diplopoda )者，例如：斑點千足蟲 (Blaiiiulus guttulatus ) 〇 來自雙翅目（Diptera)者，例如：斑蚊屬（Aedes spp.)、 瘧蚊屬（Anopheles spp.)、全北毛蚊（Bibio hortulanus)、 12 96050-發明說明書 200803729 紅頭麗繩（Calliphora erythrocephala )、地中海果繩（Ceratitis capitata)、金繩屬（Chrysomyiaspp.)、錐繩屬（Cochliomyia spp·)、盾波蠅（Cordylobia anthropophaga)、家蚊屬（Culex spp·)、黃蠅屬（Cuterebraspp.)、橄欖實绳（Dacusoleae)、 5 人膚繩（Dermatobia hominis)、果蠅屬（Drosophila spp·)、 廁繩屬（Fanniaspp·)、胃繩屬（Gastrophilusspp.)、黑蠅 屬（Hylemyia spp· )、Hyppobosca sp|3·、皮 it 屬（Hypoderma spp.)、斑潛繩屬（Liriomyzaspp·)、綠繩屬（Luciliaspp·)、 家蠅屬（Musca spp·)、綠蝽屬（Nezara spp·)、狂繩屬（Oestrus i〇 spp·)、瑞典杆繩（Oscinella frit)、藍簟潛葉繩（Pegomyia hyoscyami)、草種蠅屬（Phorbiaspp·)、螯繩屬（Stomoxys spp.)、虹:屬（Tabanusspp·)、Tamiiaspp♦、區欠洲大蚊（Tipula paludosa)、污蠅屬（Wohlfahrtiaspp·)。 來自腹足綱（Gastropoda)者，例如：Arion spp·、雙腾螺 15 屬（Biomphalaria spp·)、水泡螺屬（Bulinus spp·)、媧牛 屬（Deroceras spp· )、土堝屬（Galba spp·)、椎實螺屬（Lymnaea spp·)、釘螺屬（Oncomelaniaspp·)、椎實媧牛屬（Succinea spp·) 0 來自始蟲綱者，例如：十二指腸鉤蟲（Ancylostoma 2〇 duodenale )、錫蘭鉤蟲（Ancylostoma ceylanicum )、巴西鉤 蟲（Ancylostoma braziliensis )、鉤蟲屬（Ancylostoma spp.)、 似虫弓丨虫回蟲（Ascarislubricoides)、虫回蟲屬（Ascarisspp·)、馬 來布魯線蟲（Brugia malayi)、帝汶線蟲（Brugia timori)、 仰口線蟲屬（Bunostomum spp·)、夏伯特線蟲屬（Chabertia 13 96050-發明說明書 200803729 spp·)、支睪吸蟲屬（Clonorchis spp·)、古柏屬（Cooperia spp·)、雙腔吸蟲屬（Dicrocoelium spp )、絲狀網尾線蟲 (Dicytocaulus filaria )、廣節裂頭絛蟲（Diphyllobothrium latum)、麥地那龍線蟲（Dracunculus medinensis)、細粒棘 5 球絛蟲（Echinococcus granulosus )、多房性包蟲 (Echinococcus multilocularis )、蟯蟲(Enterobius vermicularis )、吸蟲屬（Faciola spp.)、血線蟲屬（Haemonchus spp·)、異刺線蟲屬（Heterakis spp.)、短小包膜絛蟲 (Hymenolepis nana)、豬圓線蟲屬（Hyostrongulus spp.)、 10 羅阿血絲蟲（Loa Loa)、細頸線蟲屬（Nematodirus spp·)、 結節蟲屬（Oesophagostomum spp.)、肝吸蟲屬（Opisthorchis spp·)、旋盤尾線蟲（Onchocerca volvulus )、奥斯特屬 (Ostertagia spp·)、並殖吸蟲（Paragonimus spp·)、 Schistosomen spp.、福氏類圓線蟲（Strongyloides 15 fuelleborni)、糞桿線蟲（Strongyloides stercoralis)、類圓線 蟲屬（Stronyloides spp·)、牛帶絛蟲（Taenia saginata)、豬 f 條轰（Taenia solium)、豬旋毛蟲（Trichinella spiralis)、 本地毛形線蟲（Trichinella nativa )、布氏旋毛蟲（Trichinella britovi )、南方旋毛蟲（Trichinella nelsoni )、旋毛蟲 20 ( Trichinella pseudopsiralis )、毛迴線蟲屬（Trichostrongulus SPP·)、鞭蟲（Trichuris trichuria)、班氏線蟲（Wuchereria bancrofti) 〇 此外，其可能控制原生動物（Protozoa)，例如：艾美 耳球蟲(Eimeria) 〇 14 96050-發明說明書 200803729 來自異翅目（Heteroptera)者，例如：菜瓜蟲（Anasa tristis)、Antestiopsis spp.、土長蝽屬（Blissus sppj、俊盲 蝽屬（Calocoris spp·)、青盲墙（Campylomma livida)、椿象 屬（Cavelerius spp·)、臭蟲屬（cimex spp·)、綠盲蝽 5 ( Creontiades dilutus )、胡椒椿象（Dasynus piperis )、Symphyletes spp, Tenebrio molitor, Triboliumspp·, Trogodermaspp·, Tychius spp., Xylotrechus spp· From the genus Zabrus spp. From the group of Collembola, for example: Onychiurus armatus 〇 from Dermaptera, for example, Forficula 2〇auricularia 〇 from Diplopoda For example, the spotted millipede (Blaiiiulus guttulatus) is from the order of the Diptera, such as Aedes spp., Anopheles spp., and Bibio hortulanus. 12 96050-Invention specification 200803729 Calliphora erythrocephala, Ceratitis capitata, Chrysomyiaspp., Cochliomyia spp., Cordylobia anthropophaga, House mosquito (Culex spp·), Cutrebraspp., Dacusoleae, Dermatobia hominis, Drosophila spp., Fanniaspp·, stomach genus (Gastrophilusspp.), Hylemyia spp., Hyppobosca sp|3, Hypoderma spp., Liriomyzaspp., Luciliaspp·, Musca domestica Musc a spp·), Nezara spp·, Oestrus i〇spp·, Oscinella frit, Pegomyia hyoscyami, Phorbiaspp· ), Stomoxys spp., Rainbow: Tabanusspp, Tamiaspp♦, Tipula paludosa, Wohlfahrtiaspp. From Gastropoda, for example: Arion spp·, Biomphalaria spp., Bulinus spp., Deroceras spp., genus Galba spp ·), Lymnaea spp., Oncomelaniaspp·, Succinea spp. 0 From the genus of the genus, for example: Ancylostoma 2〇duodenale, Ceylon Ancylostoma ceylanicum, Ancylostoma braziliensis, Ancylostoma spp., Ascarislubricoides, Ascarisspp·, Brugia malayi , Brugia timori, Bunostomum spp., Chapelia genus (Chabertia 13 96050-invention specification 200803729 spp·), genus Clonochis spp., Coopers (Cooperia spp.), Dicrocoelium spp, Dicytocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterodera (Heterakis spp.), Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Nodular ( Oesophagostomum spp.), Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosomen spp., Fu's Strongyloides 15 fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis , Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pse Udopsiralis ), Trichostrongulus SPP·, Trichuris trichuria, Wuchereria bancrofti 〇 In addition, it may control protozoa, eg Eimeria 〇 14 96050-Invention specification 200803729 From Heteroptera, for example: Anasa tristis, Antestiopsis spp., Blissus sppj, Calocoris spp·, blue blind wall ( Campylomma livida), Cavererius spp., cimex spp., Creontiades dilutus, Dasynus piperis,

Dichelops iurcatus、胡椒網峰（Diconocoris hewetti)、紅墙 屬（Dysdercus spp.)、美洲 4春屬（Euschistus spp.)、扁盾蝽 屬（Eurygaster spp·)、茶角盲椿象屬（Heliopeltis spp·)、 Horciasnobilellus、稻緣蝽屬（Leptocorisaspp·)、葉足緣椿 ίο ( Leptoglossus phyllopus )、草盲蝽屬（Lygus spp·)、凹甲巨 股長蝽（Macropes excavatus )、盲蝽科（Miridae )、綠蝽屬、 歐巴拉屬（Oebalus spp·)、竭蝽（pent〇midae)、藜擬網椿 (Piesma quadrata )、壁蝽屬（Piez〇d〇rus spp.)、棉偽斑腿盲 蝽（Psallusseriatus)、路梨網培（pseudacystapersea)、紅撒 15 蝽屬（Rhodnius spp·)、可可斑褐盲蝽（Sahlbergella singularis )、稻黑蝽屬（Scotinophora spp·)、梨冠網蝽 (Stephanitis nashi)、太巴卡屬（Tibraca spp·)、錐獵蝽屬 (Triatoma spp.) 〇 來自同翅目（Homoptera)者，例如：Acyrthosipon spp.、 2〇 稻褐飛兹屬（Aeneolamia spp· )、（ Agonoscena spp·)、 (Aleurodes spp·)、白粉益(Aleurolobus barodensis )、 (Aleurothrixus spp.)、芒果葉蟬屬（Amrasca spp·)、 (Anuraphis cardui)、蹄盾蛉屬（Aonidiella spp·)、梨瘤蚜 (Aphanostigma piri)、虫牙蟲屬（Aphis spp.)、葉蟬（Arboridia 15 96050-發明說明書 200803729 apicalis )、圓盾介殼蟲屬（Aspidiella spp·)、圓紛屬 (Aspidiotus spp·)、Atanus spp·、馬鈴薯蚜蟲（Aulacorthum solani)、白粉蟲屬（Bemisia spp·)、舌尾虫牙（Brachycaudus helichrysii )、小管财屬（Brachycolus spp· )、甘蘭财蟲 5 ( Brevicoryne brassicae )、Calligypona marginata、閃葉蟬 (Carneocephala fulgida )、甘蔬緯虫牙蟲（Ceratovacuna lanigera)、葉蟬科（Cercopidae)、纖蛉屬（Ceroplastes spp·)、 草莓毛管虫牙（Chaetosiphon fragaefolii )、印尼雪盾虫介 (Chionaspis tegalensis )、葉蟬（Chlorita onukii)、核桃黑斑 i〇 蚜（Chromaphis juglandicola)、褐圓介殼蟲（Chrysomphalus ficus)、姆比拉葉蟬（Cicadulina mbila)、Coccomytilus halii、 軟虫介屬（Coccus spp·)、棉財（Cryptomyzus rib丨s)、達巴拉 屬（Dalbulus spp·)、粉蝨屬（Dialeurodes spp·)、木蝨屬 (Diaphorina spp·)、盾虫介屬（Diaspis spp· )、Doralis spp·、 15 草履岭屬（Drosicha spp·)、圓尾蚜屬（Dysaphis spp·)、粉 蚧屬（Dysmicoccus spp·)、小葉蟬屬（Empoasca spp·)、綿 蚜屬（Eriosoma spp·)、斑葉蟬屬（Erythroneura spp·)、 (Euscelisbilobatus)、咖啡荒粉虫介（Geococcus coffeae)、玻 璃葉蟬（Homalodisca coagulata)、桃大尾蚜（Hyalopterus 2〇 arundinis)、吹綿蚧屬（Icerya spp·)、片角葉蟬屬（idiocerus spp·)、扁喙葉蟬屬（Idioscopusspp·)、斑飛蝨（Laodelphax striatellus)、球蚧屬（Lecaniumspp·)、蠣蚧屬（Lepidosaphes spp·)、蘿蔔蚜（Lipaphiserysimi)、長管蚜屬（Macrosiphum spp·)、沫蟬（Mahanarva fimbriolata)、黍蚜（Melanaphis 16 96050-發明說明書 200803729 sacchari )、角蟬（Metcalfiella spp·)、麥無網長管财 (Metopolophium dirhodum )、平翅斑蚜（Monellia costalis )、 Monelliopsis pecanis、蚜蟲屬（Myzus spp·)、萵苣蚜 (Nasonovia ribisnigri)、黑尾葉蟬屬（Nephotettix spp·)、褐 5 飛蝨（Nilaparvata lugens)、Oncometopia spp,、長吻介殼蟲 (Orthezia praelonga)、揚梅粉蝨（parabemisia myricae)、 木蝨屬（Paratriozaspp·)、片盾蚧屬（parlat〇riaspp·)、癭錦 财屬（Pemphigus spp·)、玉米飛兹（Peregrinusmaidis)、綿 粉虫介屬(Phenacoccus spp. )、Phloeomyzus passerinii、忽布 i〇 疲額财（Phorodon humuli)、根瘤虫牙屬（Phylloxera spp·)、 並盾介殼蟲（Pinnaspisaspidistrae)、紋粉蛉屬（Planococcus spp·)、厚緣原綿介殼蟲（Protopulvinariapyriformis)、桑介 殼蟲（Pseudaulacaspis pentagona)、粉介殼蟲屬（Pseudococcus spp·)、木兹屬（Psylla spp·)、金小蜂屬（Pteromalus spp·)、 15 派利亞屬（Pyrilla spp·)、齒盾紛屬（Quadraspidiotus spp·)、 克薩達盾蛉（Quesada gigas )、平刺粉紛（Rastrococcus spp·)、溢管财屬（Rhopalosiphum spp·)、硬介殼蟲屬（Saissetia spp. )、( Scaphoides titanus )、麥二叉虫牙(Schizaphis graminum)、刺圓盾虫介（Selenaspidus articulatus)、飛兹屬 20 ( Sogata spp·)、白背飛蟲（Sogatella furcifera)、稻飛蟲屬 (Sogatodes spp. )、Stictocephala festina、Tenalaphara malayensis、黑胡桃虫牙蟲（Tinocallis caryaefoliae )、Tomaspis spp.、二叉蚜屬（Toxoptera spp·)、溫室粉蝨（Trialeurodes vaporariorum )、尖翅木益屬（Trioza spp·)、小葉蟬屬 17 96050-發明說明書 200803729 (Typhlocyba spp·)、矢尖盾蚧屬（Unaspis spp·)、葡萄根瘤 虫牙（Viteus vitifolii) 〇 來自膜翅目（Hymenoptera )者，例如：松葉蜂屬（Diprion spp·)、實葉蜂屬（Hoplocampa spp·)、毛蟻屬（Lasius spp,)、 5 小黃家蟻（Monomorium pharaonis )、胡蜂屬（Vespa spp·)。 來自等足目（Isopoda)者，例如：鼠婦（Armadillidium vulgare)、壁潮蟲（Oniscusasellus)、経皮鼠婦（Porcellio scaber) 〇 來自等翅目（Isoptera )者，例如：散白蟻屬（Reticulitermes 10 spp· ) 、土 白蟻屬（Odontotermes spp·)。 來自鱗翅目（Lepidoptera )者，例如：桑劍紋夜娥 (Acronictamajor)、白斑煩夜蛾（Aedialeucomelas)、切根 蟲屬（Agrotis spp·)、木棉蟲（Alabama argillacea)、夜蛾屬 (Anticarsia spp·)、甘藍夜蛾（Barathra brassicae)、棉潛蛾 15 ( Bucculatrix thurberiella)、松尺虫蔓（Bupalus piniarius )、黃 尾捲葉蛾（Cacoecia podana )、蘋捲葉蛾（Capua reticulana )、 蘋果橐蛾（Carpocapsa pomonella)、冬尺蛾（Cheimatobia brumata )、模蟲屬（Chilo spp.)、雲杉捲葉蛾（Choristoneura fumiferana )、葡萄果蠢蛾（Clysia ambiguella )、Ciiaphalocerus 20 spp·、埃及鑽夜蛾（Earias insulana)、地中海粉模（Ephestia kuehniella )、黃毒蛾（Euproctis chrysorrhoea )、切葉蛾屬 (Euxoa spp·)、臟切葉蛾屬（Feltia spp·)、墙模（Galleria mellonella )、棉鈴蟲屬（Helicoverpa spp·)、實葉蛾屬 (Heliothis spp·)、織蛾（Hofmannophila pseudospretella)、 18 96050-發明說明書 200803729 茶捲葉蛾（Homona magnanima)、蘋果巢蛾（Hyponomeuta padella )、夜蛾屬（Laphygma spp.)、斑幕潛葉細蛾 (Lithocolletis blancardella )、觸角夜蛾（Lithophane antennata )、白緣夜蛾（Loxagrotis albicosta )、毒蛾屬 5 ( Lymantria spp·)、黃褐天幕毛蟲（Malacosoma neustria)、 甘藍夜蛾（Mamestra brassicae )、稻毛脛夜蛾（Mods repanda)、黏蟲（Mythimna separata)、Oria spp·、水稻負泥 蟲（Oulemaoryzae)、小眼夜蛾（Panolisflammea)、棉紅鈴 蟲（Pectinophora gossypiella)、掛桔葉潛哦（Phyllocnistis ίο citrella )、紋白蝶屬（Pieris spp·)、菜蛾（Plutella xylostella )、 斜紋夜蛾屬（Prodenia spp·)、黏蟲屬（Pseudaletia spp·)、大 豆尺夜蛾（Pseudoplusia includens )、玉米模（Pyrausta nubilalis )、灰翅夜蛾屬（Spodoptera spp·)、黎豆夜蛾 (Thermesiagemmatalis)、袋衣蛾（Tinea pellionella)、衣蛾 15 ( Tineola bisselliella)、櫟綠捲蛾（Tortrix viridana)、粉夜蛾 屬（Trichoplusia spp· ) 〇 來自直翅目（Orthoptera )者，例如：家虫悉蟀（Acheta domesticus )、東方斐蠊（Blatta orientalis )、德國小蠊（Blattella germanica )、螻蛄屬（Gryllotalpa spp·)、馬德拉蜚蠊 2〇 ( Leucophaea maderae )、飛虫皇屬（Locusta spp·)、黑虫皇屬 (Melanoplus spp·)、美洲大嫌（Periplaneta americana)、沙 漠虫皇（Schistocerca gregaria) 〇 來自蚤目（Siphonaptera)者，例如：鼠蚤屬（Ceratophyllus spp·)、印度客蚤（Xenopsyllacheopis)。 19 96050-發明說明書 200803729 來自綜合目（Symphyla)者，例如：無斑點麼姑 (Scutigerella immaculata) 〇 來自缪翅目（Thysanoptera)者，例如：稻薊馬（Baliothrips biformis )、黃薊馬（Enneothrips flavens )、薊馬屬（Frankliniella 5 spp·)、陽薊馬屬（Heliothrips spp·)、粟網薊馬（Hercinothrips femoralis )、卡薊馬屬（Kakothrips spp·)、腹鉤薊馬 (Rhipiphorothrips cruentatus )、硬薊馬屬（Scirtothrips spp·)、莖蔻薊馬（Taeniothrips cardamoni)、花薊馬屬（Thrips spp·)。 i〇 來自總尾目（Thysanura)者，例如：衣魚（Lepisma saccharina) 〇 植物寄生性線蟲包括例如：癭線蟲屬（Anguinaspp·)、 滑刃線蟲屬（Aphelenchoides spp·)、Belonoaimus spp·、傘滑 刃線蟲屬（Bursaphelenchus spp·)、起絨草莖線蟲（Ditylenchus 15 dipsaci)、球異皮線蟲屬（Globodera spp· )、（ Heliocotylenchus spp·)、異皮線蟲屬（Heterodera spp.)、長針線蟲屬（Longidorus spp·)、根結線蟲屬（Meloidogyne spp·)、草地墊刃線蟲屬 (Pratylenchus spp·)、相似穿孔線蟲（Radopholus similis )、 盤旋線蟲屬（Rotylenchus spp·)、毛刺線蟲屬（Trichodorus 2() spp·)、矮化線蟲屬（Tylenchorhynchus spp·)、小墊刃屬 (Tylenchulus spp·)、半穿刺線蟲（Tylenchulus semipenetrans)、劍線蟲屬（Xiphinema spp·)。 倘若合適，根據本發明之活性化合物組合亦可以某種濃 度或施用率作為除草劑、安全劑、生長調節劑或改善植物特 20 96050-發明說明書 200803729 或Ϊ作為殺微生物劑，例如：作為殺真菌劑、抗 、ad'极細_、殺病毒劑（包括抗類病毒劑）或者作為抗 =〇(類《菌生物)和RL0(類立克次體生物)之試劑。倘若 口適其亦可作為用以合成其他活性化合物之中間物或前趨 物。 所有植物及植物料均可輯本發明加以處理 。本文中之 10 15 20 植物係指所有植物及植物族群，例如··吾人想要或不想要之 野生植物或作物（包括天然發生之作物）。作物得為藉由傳統 ，物月種及最適方法或藉由生物技術及基因工程方法或者 ，由此等方法之組合，包括轉基因植物且包括經或不經育種 豕核保護者而獲得之植物。植物部件係指植物在地上或地底 :之所有部件及器官，例如：芽、葉、花和根，其實例可為： 葉針葉、柄、里、t、果貫、種子、根、塊莖和地下莖。 植物部件亦包括經收成之物質，以及具生長繁殖力之遺 傳物質，例如：插條、塊莖、地下莖、分枝和種子。 根據本發明以活性化合物組合對植物及植物部件之處 理可直接實施或藉由慣用之處理方法使該化合物作用於其 環境、棲地或貯藏處，例如：藉由浸泡、喷灑、蒸發、罩霧、 撒佈、塗佈、注射，且對於繁殖物質，特別是種子，亦可藉 由塗敷一或多層。 該活性化合物組合可轉化成慣用之調配物，例如··溶 液、乳化液、可與水混合之粉末、水基和油基懸浮液、粉末、 粉塵、糊狀物、可溶性粉末、可溶性顆粒、播撒用顆粒、懸 浮乳化液濃縮物、巍含活性化合物之天然物質、巍含活性化 96050-發明說明書 21 200803729 合物之人造物 甘承合物内之微膠嚢。 此等調配物係採已知方式力如 活性化合物與驗態溶❹η π At ^ . ]及/或固恶載劑之增量劑混合，視 成劑。該調配物可調製於適當之植物中或於施狀前或期間 加以調製。 10 15 20 h適合作為_之物質係、為適合賦予組合物本身及/或由 "衍生之製劑（例如·噴灑液體、種子敷劑）特別性質，例如： 某些專門性質及/或特別之生物性質者。典型之適當輔劑為： 增量劑、溶劑和載劑。 適合之增里劑為例如：水、極性和非極性有機化學液 體，例如來自芳香及非芳香烴之類群者（例如：石蠟類、烷 基笨類、烧基萘類、氯化苯類）、醇類和多元醇類（其若適合 亦可經取代、_化及/或酯化）、酮類（例如··丙酮、環己酮）、 5曰類（包括脂類和油類）以及（聚）醚類、非經取代及經取代之 ，類、醯胺類、内醯胺類（例如：N-烧基吡咯烷酮類）和内酯 ;:、石風類和亞石風類（例如：二甲基亞石風）。 、 询若所使用之增量劑為水，則可使用例如··有機溶劑作 ，補助溶劑。實質上，適當之溶劑為：芳香烴類，例如：二 ^ 、甲苯或烷基萘類、氯化芳香烴類和氯化脂肪烴類，例 •氯化笨類、氯乙烯類或二氯甲烷、脂肪烴類，例如··環 己境或石蠟類，例如··石油分餾物、礦物及植物油類、醇類， 例如： ' 醇或乙二醇以及其醚類和醋類、酮類，例如··丙g同、 土乙基_、甲基異丁基酮或環己酮，強極性溶劑，例如： 22 96〇5〇-發明說明書 200803729 -一甲基亞石風，以及水。 適合之固態載劑為： 例如：錢鹽和磨碎之天然礦物，例如：高嶺土、黏土、滑石、 白堊、石英、凹凸棒石（論pulgite)、蒙脫土（ m〇nt—te) 5 或矽澡土，以及磨碎之人造礦物，例如：經細分之二氧化矽、 氧化鋁、礬土和矽酸鹽類；適當之顆粒用固態載劑為例如: 經碾砰和經區分之天然岩石，例如：方解石、大理石、輕石、 海泡石和白雲$，以及無機和有機粗粉之顆粒，及有機材 料，例如：紙、鋸木屑、椰子殼、玉米穗軸和菸草莖之顆粒， 適a之乳化劑及/或泡沬生成劑為例如：非離子性及陰離子 性乳化劑，例如：聚氧乙烯脂肪酸酯類，聚氧乙烯脂肪醇醚 類，例如：烷基芳基聚乙二醇醚類，烷基磺酸鹽類、烷基硫 酸鹽類、芳基磺酸鹽類以及蛋白質解物，適當之分散劑為非 離子及/或離子性物質，例如選自下列所組成之種類者：醇 15 _P0E&/或、酸及/或POP POE酯類、烧基芳基及/ 或P0P P0E醚類、脂肪及/或POP POE加成物POE-及/或POP-夕元醇竹生物、POE-及/或p〇p_山梨醇或糖加成物、烧基或 芳基硫酸鹽類、烷基-或芳基磺酸鹽類及烷基或芳基磷酸鹽 或相為應之PO-醚加成物。此外，適當之寡體或聚合物為例 2〇 如彼等衍生自乙烯性單體、自丙烯酸、單獨自EO及/或PO或 結合例如：（聚）醇類或（聚）胺類者。亦可使用木質素及其磺 酸衍生物，未經修飾及經修飾之纖維素、芳香性及/或脂肪 族磺酸及其與甲醛之加成物。 增黏劑例如：羧甲基纖維素以及呈粉末、顆粒或乳膠狀 96〇5〇-發明說明書 200803729 之天然和人工聚合物，例如：***膠、聚乙烯醇及聚醋酸 乙稀S旨，以及天然填脂類，例如··腦鱗脂和卵礙脂，以及人 工磷脂類，可使用於調配物中。 可使用著色劑，例如：無機色素，例如：氧化鐵、气化 鈦及普魯士藍（Prussian Blue)，以及有機染料，例如^茜 素染料、偶氮染料和金屬g大菁染料，以及微|款 里言香常，例如： 鐵、鎂、硼、銅、钻、鉬和鋅之鹽類。 其他可能之添加物為：香料、礦物或蔬菜 修飾之油類、蠟類及營養素（包括微量營 而為、、二 鎂、石朋、銅、鉛、銦和鋅之鹽類。養素例如：鐵、 安定劑，例如：低溫安定劑、防腐劑 定劑或其它可改善化學及/<物 几虱化劑、光女 _酬常包含介可存在。 物，較佳為介於0·5至9〇g/q。 里比之活性化合 15 20 根據本發明之活性化合物人 物’例如：殺昆蟲劑、誘引劑、滅與其他活性化合 殺線蟲劑、殺真菌劑、生長調節物質或；、殺蜗劑、 使用於市售調配物以及自此等調配物之混合物型式 見蟲劑包括例如，酸_、胺基甲：:二使用型式中。殺 化，、苯基尿素類、由尤其是由微生類、氯 亦可能為與其他已知活性化:生產之物質。 料及生長調節劑之混合物。 如.除草劑或與肥 作為殺③麵時，減本發明之 與協乘劑之混合物型式存在 ^物組合亦可以 q调配物以及自此等調 96050-發明說明書 24 200803729 用協乘劑係為可提高活性化合物之作 自協乘劑，其本身即有活性。 市售调配物製得之使用型式中之活性化合物含量可 動。使用型式中之活性化合物濃度可 马 U.U0000001 至 95% 舌旦" 〇.〇〇〇〇!至1%重量比。里比之活性化合物，較佳為介於 【實施方式】 應用係以適用於使用型式之方式施行。 可本發明處理所有植物及其部 種。二ί - ί實施例中’野生植物品系及植物栽培品 二i 4 Γ物育種法，例如:雜交或原生質體 ^獲件者’及其部件係被處理。 例中，由基因工程法，芒、吞木 逆平乂往 篮貫她 適當可結合慣用之方法所獲得之轉 15 20 i處理。術語物因修鋅之生物)’咖 在上文中已予以說明。植物之部件」以及「植物部件」 #據=圭ΐ广種市售或使用之植物栽培品種之植物係 =力， D=:_。其可為裁培品二 /見植n或植物裁培品種、其所在 壤、氣候、營養期、羞八、 生長條件（土 使用之物質或組合物之施用用率二=如:可根據本發明 用丰降低及/或活性範圍加寬及/ 96050-發明說明書 25 200803729 或活性之提高、較佳之植物生長、對高或低溫 高、對乾旱或水或土壌之鹽含量之耐受性料、開花品= 現提尚、較易收成、加速熟成、較高之收穫率、較 口餅 及/或收成產品讀高營養價值、較佳之貯存安定^及 成產品之加工性均為可能，其會超過實際期望之效 根據本發明加以處理之較佳轉基因植物或植物栽择口 =藉由基因工程獲得者）包括所有植物，其藉由進行基^ 10 20 :有對此等值物之料優點、有用特徵之基因物 貝。此寻4寸徵之實例為較佳之植物生長、對高或低溫 :提高：對乾旱或水或土壤之鹽含量之耐受性提高、開花： 質表現提高、較易收成、加速熟成、較高之收穫率、較古: 品質及/或收成產品之較高營養價值、較佳之貯存安定^及/ 或收成產品之加工性。此特徵之其他及特別重要之實 =對動物及為小害蟲之較佳防禦性，❹:對抗昆蟲、蝨、 勿病原性真菌、細菌及/或病毒，且亦可提高植物對於某些 除草活性化合物之耐受性。可能述及之轉基因植物之實例^ 重要之作物植物，例如：穀類（小麥、稻米）、玉米、大豆、 =鈴薯、甜菜、蕃茄、婉豆及其他植物變種、棉、菸草、油 菜以及果貫植物（有蘋果、梨、柑桔類果實及葡萄者），且特 要者為玉米、大豆、馬鈐薯、棉、於草及油菜。特別重 ，之特彳政係為藉由植物内生成之毒素之作用使植物對昆 蟲二=形綱動物、線蟲和蝸牛及蛞蝓之防禦力提高，特別是 彼等藉由來自蘇力菌（Bacillus thuringiensis )之基因物質於 植物中生成者（例如：藉由基因CrylA(a)、CrylA(b)、 26 96050-發明說明書 200803729Dichelops iurcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurygaster spp., Heliopeltis spp. Horciasnobilellus, Leptocorisaspp·, Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Oysterus, Oebalus spp., pent〇midae, Piesema quadrata, Piez〇d〇rus spp., cotton pseudo-spotted scorpion (Psallusseriatus), pseudacystapersea, Rhodnius spp., Sahlbergella singularis, Scotinophora spp., Stephanitis nashi ), Tibraca spp., Triatoma spp. 〇 from the homoptera (Homoptera), for example: Acyrthosipon spp., 2 indica genus Aeneolamia spp. (Agonoscena spp·), (Aleurodes spp·), Aleurolobus barodensis, (Aleurothrixus spp.), Mango genus (Amrasca spp.), (Anuraphis cardui), Aonidiella spp., Aphanostigma piri, and genus Aphis spp.), Acacia (Arboridia 15 96050 - invention specification 200803729 apicalis), Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, white powder Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Phytophthora larvae Ceratovacuna lanigera), Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Walnut black spot Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus hali i, Coccus spp., Cryptomyzus rib丨s, Dalbulus spp., Dialeurodes spp., Diaphorina spp., shield Diaspis spp., Doralis spp., 15 Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp. Eriosoma spp., Erythroneura spp., (Euscelisbilobatus), Geococcus coffeae, Homalodisca coagulata, Hyalopterus 2〇arundinis ), Icerya spp., idiocerus spp., Idioscopusspp., Laodelphax striatellus, Lecaniumspp, 蛎Lepidosaphes spp., Lipaphiserysimi, Macrosiphum spp., Mahanarva fimbriolata, Melanaphis 16 96050-invention specification 200803729 sacchari, and Metcalfiella spp· ), Mai no network manager (Met Opolophium dirhodum), Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens Oncometopia spp, Orthezia praelonga, parabemisia myricae, Paratriozaspp·, parlat〇riaspp·, Pemphigus spp· ), Peregrinusmaidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phyloxera spp., Pinnaspisaspidistrae ), Planococcus spp., Protopulvinariapyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Jin Xiao Pteromalus spp., 15 (Pyrilla spp.), Quadraspidiotus spp., Quesada gigas, flat thorn Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus ), Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp. Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., genus 17 96050-invention specification 200803729 (Typhlocyba spp.), genus Unaspis spp·), Viteus vitifolii 〇 from Hymenoptera, for example: Diprion spp., Hoplocampa spp., Lasius spp, ), 5 Monomorium pharaonis, Vespa spp. From Isopoda, for example: Armadillidium vulgare, Oniscusasellus, Porcellio scaber, from Isoptera, for example, Reticulitermes 10 spp· ), Odontotermes spp. From Lepidoptera, for example: Acronictamajor, Aedialeucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp ·), Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella ), Cheimatobia brumata, Chilo spp., Choristoneura fumiferana, Clysia ambiguella, Ciiaphalocerus 20 spp·, Earias insulana, Mediterranean model (Ephestia kuehniella), Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Walleria mellonella, Helicoverpa spp ), Heliothis spp., Hofmannophila pseudospretella, 18 96050-Invention Manual 200803729 Tea Leaf Moth (H Omona magnanima), Hyponomeuta padella, Laphygma spp., Lithocolletis blancardella, Lithhophane antennata, Loxaltis albicosta, venomous moth Genus 5 Lymantria spp., Malacosoma neustria, Mamestra brassicae, Mods repanda, Mythimna separata, Oria spp·, rice negative worm ( Oulemaoryzae), Panolisflammea, Pectinophora gossypiella, Phyllocnistis ίο citrella, Pieris spp, Plutella xylostella, Spodoptera (Prodenia spp.), Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesiagemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Trichoplusia spp 〇 From Orthoptera, for example: Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp, Madeira蠊2〇 (Leucophaea maderae), Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria Si from Siphonaptera For example, Ceratophyllus spp., Xenopsyllacheopis. 19 96050-Invention Manual 200803729 From the group of Symphyla, for example: Scutigerella immaculata 〇 from Thysanoptera, such as Baliothrips biformis, Enneothrips flavens ), genus Frankliniella 5 spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirthothrips spp., Taeniothrips cardamoni, Thrips spp. I〇 comes from the total order (Thysanura), for example: Lepisma saccharina 〇 plant parasitic nematodes include, for example, Anguinaspp., Aphelenchoides spp., Belonoaimus spp·, umbrella slippery Nematodes (Bursaphelenchus spp.), Ditylenchus 15 dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Nematodes (Longidorus spp.), Meloidogyne spp., Pratylenchus spp., similar Radopholus similis, Rotylenchus spp., Trichoderma genus (Trichodorus 2) () spp·), Dylhenorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp. If appropriate, the active compound combinations according to the invention can also be used as herbicides, safeners, growth regulators or as a microbicide as a microbicide, for example as a fungicide, at a concentration or rate of application as a herbicide, safener, growth regulator or improved plant special 20 96050 - invention specification 200803729 Agent, anti-ad, extremely fine _, viricide (including anti-viral agents) or as an anti- 〇 (classic "bacterial organism" and RL0 (like rickettsia organisms) reagents. It can also be used as an intermediate or pre-existing agent for the synthesis of other active compounds. All plants and plant materials can be processed by the present invention. 10 15 20 Plants in this context refer to all plants and plant communities, such as wild plants or crops (including naturally occurring crops) that we want or don't want. The crop may be obtained by conventional, monthly and optimal methods or by a combination of biotechnological and genetic engineering methods, or a combination thereof, including transgenic plants and including those obtained by or without breeding of the nucleus. Plant parts refer to all parts and organs of plants on the ground or underground: for example, buds, leaves, flowers and roots, examples of which may be: leaf needles, stalks, linings, t, fruit, seeds, roots, tubers and Underground stems. Plant parts also include harvested material and genetically propagated material such as cuttings, tubers, underground stems, branches and seeds. The treatment of plants and plant parts with active compound combinations according to the invention can be carried out directly or by conventional treatments to effect the compounds in their environment, habitat or storage, for example by soaking, spraying, evaporating, hooding Fog, spreading, coating, injecting, and for propagating materials, particularly seeds, may also be applied by coating one or more layers. The active compound combination can be converted into a conventional formulation, for example, a solution, an emulsion, a powder which can be mixed with water, a water-based and oil-based suspension, a powder, a dust, a paste, a soluble powder, a soluble granule, a spread The use of granules, suspension emulsion concentrates, natural substances containing hydrazine active compounds, bismuth containing active 96050 - invention specification 21 200803729 compound of artificial gums in the manganese compound. These formulations are prepared by mixing the active compound with an inhibitor of the active compound η π At ^ . . and/or a bulk carrier. The formulation can be formulated in a suitable plant or prepared prior to or during application. 10 15 20 h is suitable as a substance system, is suitable for imparting the composition itself and/or a special property derived from a "derivative (for example, spray liquid, seed dressing), for example: certain specialized properties and / or special Biological nature. Typical suitable adjuvants are: extenders, solvents and carriers. Suitable extenders are, for example, water, polar and non-polar organic chemical liquids, such as those from aromatic and non-aromatic hydrocarbons (eg, paraffin, alkyl, naphthene, chlorinated benzene), Alcohols and polyols (which may also be substituted, _ and/or esterified if appropriate), ketones (eg acetone, cyclohexanone), 5 quinones (including lipids and oils) and Poly)ethers, unsubstituted and substituted, steroids, indoleamines (eg N-alkylpyrrolidone) and lactones;: stone-type and slate-type (eg: Dimethyl sapphire wind). If the extender used is water, you can use, for example, an organic solvent to supplement the solvent. In essence, suitable solvents are: aromatic hydrocarbons, such as: di-, toluene or alkyl naphthalenes, chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbons, such as chlorinated, vinyl chloride or methylene chloride , aliphatic hydrocarbons, such as · cyclohexane or paraffin, such as · petroleum fractions, minerals and vegetable oils, alcohols, such as: 'alcohol or ethylene glycol and its ethers and vinegars, ketones, for example · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · Suitable solid carriers are: for example: money salt and ground natural minerals such as: kaolin, clay, talc, chalk, quartz, attapulgite (on pulgite), montmorillonite (m〇nt-te) 5 or Bathing soil, and ground artificial minerals such as finely divided cerium oxide, alumina, alumina and strontium; suitable granules for solid carrier are, for example: pulverized and differentiated natural rock For example: calcite, marble, pumice, sepiolite and white clouds $, as well as inorganic and organic coarse powder particles, and organic materials such as: paper, sawdust, coconut shell, corn cob and tobacco stem granules, suitable for a The emulsifier and/or foam generating agent is, for example, a nonionic and anionic emulsifier, for example, a polyoxyethylene fatty acid ester, a polyoxyethylene fatty alcohol ether, for example, an alkyl aryl polyglycol ether. Classes, alkyl sulfonates, alkyl sulfates, aryl sulfonates, and proteinolytics, suitable dispersing agents are nonionic and/or ionic materials, for example selected from the group consisting of: Alcohol 15 _P0E&/or, acid and/or POP POE esters, alkyl aryl and/or P0P P0E ethers, fats and/or POP POE adducts POE- and/or POP-alternal bamboo organisms, POE- and/or p〇p_sorbitol Or a sugar adduct, a burnt or aryl sulfate, an alkyl- or aryl sulfonate and an alkyl or aryl phosphate or a corresponding PO-ether adduct. Further, suitable oligo or polymers are exemplified by the fact that they are derived from an ethylenic monomer, from acrylic acid, from EO and/or PO alone or in combination with, for example, (poly)alcohols or (poly)amines. Lignin and its sulfonic acid derivatives, unmodified and modified cellulose, aromatic and/or aliphatic sulfonic acids and their addition to formaldehyde can also be used. Tackifiers such as: carboxymethyl cellulose and natural and artificial polymers in the form of powders, granules or latexes, in the specification of the invention, 200803729, for example: gum arabic, polyvinyl alcohol and polyvinyl acetate, and Natural fat-filled lipids, such as cerebral squama and ocular lipids, as well as artificial phospholipids, can be used in formulations. Coloring agents such as inorganic pigments such as iron oxide, titanium carbide and Prussian Blue, and organic dyes such as halogen dyes, azo dyes and metal g macrocyanine dyes, and micro-forms can be used. It is often said, such as: iron, magnesium, boron, copper, diamond, molybdenum and zinc salts. Other possible additives are: perfumes, minerals or vegetable-modified oils, waxes and nutrients (including micro-capacity, di-magnesium, stone, copper, lead, indium and zinc salts. Iron, tranquilizers, for example: low temperature stabilizers, preservatives, or other chemicals that can improve the chemical and/or chemical agents, may be present, preferably between 0. 5 To 9 〇g/q. Libi's active compound 15 20 The active compound character according to the invention 'for example: insecticide, attractant, chlorpyrifos and other active nematicides, fungicides, growth regulating substances or; The smoldering agent, the mixture of the commercially available formulations and the formulations from which the formulations are used include, for example, the acid-, amine-based:: two-use form, bactericidal, phenylurea, especially From the micro-organisms, chlorine may also be a mixture with other known substances: a mixture of materials and growth regulators, such as herbicides or fertilizers, as a mixture of the invention and the synergistic agent. The presence of a combination of substances can also be adjusted as well as Such adjustments 96050 - invention specification 24 200803729 The synergistic agent is used as a self-coordinating agent for enhancing the active compound, which is active in itself. The content of the active compound in the use form prepared by the commercially available formulation is movable. The concentration of the active compound in the medium can be U.U0000001 to 95% of the tongue " 〇.〇〇〇〇! to 1% by weight. The active compound of the ratio is preferably between [embodiment] The invention can be used in the form of a pattern. The invention can be used to treat all plants and their parts. In the example, 'wild plant lines and plant cultivation products 2 i 4 breeding methods, for example: hybrid or protoplasts 'And its components are processed. In the example, by the genetic engineering method, the awn, the swallowing, the squad, the squad, the squad, the syllabus, the syllabus, the syllabus, the syllabus 'Caf has been explained above. "plant parts" and "plant parts" # according to the plant variety of the plant cultivars sold or used by the company, force, D =: _. It can be a cropped product 2 / see plant or plant cut varieties, its soil, climate, vegetative period, shame, growth conditions (the use of substances or compositions of soil use 2 = such as: according to this Inventive use reduced and / or broadened range of activity and / 96050 - invention specification 25 200803729 or improved activity, preferred plant growth, high or low temperature, tolerance to drought or water or soil salt content, Flowering products = ready-to-finish, easier to harvest, accelerated ripening, higher harvest rate, higher nutrient value than cakes and/or harvested products, better storage stability and processing properties of finished products are possible Preferred transgenic plants or plant-growing mouths which are treated according to the invention over the actual desired effect = by genetic engineering) include all plants by carrying out the basis 10 10 20: having the advantages of this value Genes with useful features. Examples of this 4 inch sign are better plant growth, high or low temperature: increase: tolerance to drought or water or soil salt content, flowering: improved quality, easier harvest, accelerated ripening, higher Harvest rate, more ancient: higher nutritional value of quality and / or harvested products, better storage stability and / or processing of harvested products. Other and particularly important features of this feature = better defense against animals and small pests, cockroaches: against insects, cockroaches, pathogenic fungi, bacteria and/or viruses, and may also increase the herbicidal activity of plants Tolerance of the compound. Examples of genetically modified plants that may be mentioned ^ Important crop plants, such as: cereals (wheat, rice), corn, soybeans, = bell peppers, beets, tomatoes, cowpeas and other plant varieties, cotton, tobacco, canola, and fruit Plants (with apples, pears, citrus fruits and grapes), and specialties are corn, soybeans, horses, potatoes, cotton, grass and canola. It is particularly important that the Department of Politics uses the action of toxins produced in plants to enhance the defense of plants against insects, nematodes, snails and snails, especially from the bacteria (Bacillus). The gene substance of thuringiensis is produced in plants (for example: by gene CrylA(a), CrylA(b), 26 96050-invention specification 200803729

CrylA(c)、CryllA、CrylllA、CryIIIB2、Cry9c、Cry2Ab、Cry3Bb 和CrylF以及其組合)(下文中稱之為「Bt植物」）。亦特別重 要之特徵為植物對真菌、細菌之防禦力及藉由系統誘導抗病 性（SAR)、系統素、植物抗毒素（phyt〇aiexins )、激發因子 5 (elicit〇rs)和抗性基因以及相對應之表現蛋白質及毒素之效 用之提高。進一步特別重要之特徵為植物對某些除草活性化 合物，例如：咪唑啉酮類、磺醯基尿素類、嘉磷賽（glyph〇sate ) 或膦基苜蓿素（phosphinotricin)之耐受性提高（例如：「pat」 基因）。帶有所欲特徵之基因亦可在轉基因植物内合併存 10 在。可能述及之「Bt植物」之實例為玉米變種、棉變種、大 豆變種和馬鈴薯變種，其銷售之商標名為YIELD gArd® (例如：玉米、棉、大豆），Knock〇u_ (例如：玉米）、此旧吐⑧ (例如··玉米），Bollgard⑧（棉），Nuc〇tn⑧（棉）和NewLeaf⑧（馬 鈴薯）。可能述及之抗除草劑植物之實例為玉米變種、棉變 ，彳大豆殳種，其銷售之商標名為· R〇undUp Rea(jy⑧（而于嘉 磷賽，例如··玉米、棉、大豆），Liberty Link(g)(耐 pho^hinotricin ’例如：油菜），題⑧（耐味。坐琳嗣類）和sts⑧ (=½ S&基尿素類’例如玉米）。可能述及之抗除草劑植物（以 慣用方式篩育除草劑耐性之植物）包括以Clea曲咖之商標 2〇 名例如：玉米）銷售之變種。當然，此等說明亦適用於具^ =等基因特徵或仍在研發之基因特徵之植物栽培品種，該 植物栽培品種可在未來被研發出來及/或上市販售。 、、二列出之植物可以特別有利之方式以根據本發明之 '化合物組合處理之。上述之活性化合物組合之較佳範圍亦 96050·•發明說明書 27 200803729 適用以處理鱗植物。制重要者係為以此等制於本文中 提及之活性化合物組合來處理植物。 根據本發明之活性化合物組合之作用不僅為抗植物、衛 生及經貯存產品之害蟲，其亦可於獸醫用藥之領域中對抗動 5 物可生烛（體外和體内寄生物），例如：硬蜱、軟蜱、济瞒、 葉蟎、蒼蠅（牛蠅和舔蠅）、寄生性蠅幼蟲、蝨、毛蝨、羽蝨 和跳蚤。此等寄生蟲包括： 來自蝨目（Anoplurida)者，例如：血蝨屬、毛蝨屬、 虱蝨屬、陰蝨屬（Phtirusspp·)、管蝨屬（Solenopotesspp.)。 10 來自羽蝨目（Mallophagida )以及純角亞目（Amblycerina) 和細角亞目（Isehnocerina )者，例如：（Trimenopon spp·)、 雞羽蝨屬（Menoponspp·)、巨羽蝨屬（Trinotonspp·)、牛蝨 屬（Bovicola spp·)、嚼蝨（Werneckiella spp·)、嚅蝨 (Lepikentronspp.)、住兹（Damalinaspp·)、齧毛兹屬、 15 ( Felicola spp· ) 〇 來自雙翅目和長角亞目（NematocerimO和短角亞目 (Brachycerina)者，例如：斑蚊屬、癔蚊屬、家蚊屬、蚋 屬（Simulium spp·)、真蚋屬（Eusimulium spp·)、白蛉屬 (Phlebotomus spp·)、沙蠅屬（Lutzomyia spp.)、庫礞屬 2〇 ( Culicoides spp·)、斑虻屬（Chrysops spp·)、瘤虻屬 (Hybomitra spp.)、黃 屬（Atylotus spp· )、it 屬、麻 屬 (Haematopota spp· )、（ Philipomyia spp·)、蜂虱蠅屬（Braula spp·)、家蠅屬、齒股蠅屬（Hydr〇taeasPP·)、螯蠅屬、角蠅 屬（Haematobiaspp·)、莫蠅屬（Morelliaspp·)、廁蠅屬、舌 28 96050-發明說明書 200803729 繩屬（Glossina spp·)、麗蠅屬（Calliphora spp·)、綠繩屬、 金繩屬、污繩屬、麻繩屬（Sarcophaga spp·)、狂繩屬、皮繩 屬、胃蠅屬（Gasterophilus spp·)、風繩屬（Hippobosca spp·)、 兹繩屬（L'ipoptena spp·)、蜱蠅屬（Melophagus spp·)。 5 來自蚤目（Siphonapterida)者，例如：蚤屬（Pulex spp·)、 梅首蚤屬（Ctenocephalidesspp·)、客蚤屬（Xenopsyllaspp·)、 鼠蚤屬。 來自異翅目（Heteropterida)者，例如：臭蟲屬、錐獵蝽屬、 紅獵蝽屬、錐培屬（Panstrongylus spp·)。 ίο 來自蜚簾目（Blattarida)者，例如：東方蜚蠊、美洲大蠊、 德國小蠊、夏柏拉屬（Supella spp·)。 來自蜱蜗亞綱（Acari (Acarina))以及後氣孔目 (Metastigmata)和中氣門目（Mesostigmata)者，例如：銳 緣蜱屬、軟蜱屬（Ornithodorus spp·)、扁蟲屬（Otobius spp.)、 15 硬蜱屬、花蜱屬、牛蜱屬、革蜱屬（Dermacentor spp·)、i 蜱屬（Haemophysalis spp·)、璃眼蜱屬、扇頭蜱屬、皮刺蜗 屬（Dermanyssus spp·)、耳蜗屬（Raillietia spp·)、鼻蜗屬 (Pneumonyssus spp.)、鼻刺蜗(Sternostoma spp.)、蜂蜗 属(Varroa spp. ) 〇 2〇 來自輻瞒目（Actinedida (Prostigmata))和粉蜗亞目 (Acaridida (Astigmata))者，例如：蜂盾蜗屬（Acarapis spp·)、螯蜗屬（Cheyletiellaspp·)、（Ornithocheyletiaspp·)、 恙轰屬（Myobia spp·)、癢蜗屬（Psorergates spp·)、螺形 虫茜屬（Demodexspp·)、恙蜗屬（Trombiculaspp·)、犛螨屬 29 96〇5〇-發明說明書 200803729 (Listrophorus spp.)、粉蜗屬（Acarus spp·)、腐食瞒屬 (Tyrophagus spp.)、嗜木蟎屬（Caloglyphus spp.)、 (Hypodectesspp,)、（PteroUchusspp· )、癢蜗屬、足瞒屬、 耳癢蟎屬（Otodectes spp.)、济瞒屬、背肛蜗（Notoedres spp·)、膝蜗（Knemidocoptes spp·)、羽軸蜗（Cytodites spp·)、 膜瞒屬（Laminosioptes spp.)。 10 15 20 根據本發明之活性化合物組合亦適用以控制感染農業生產 性豕畜，例如：牛、綿羊、山羊、馬、豬、驢、駱駝、水牛、 ^、滩、火難、鴨、鵝和蜜蜂、其他寵物類，例如：狗、貓、 ，中鳥:口觀！魚，以及所謂之試驗動物，例如：倉鼠、天竺 I* a f乳及豕乳之卽肢動物。藉由控制此等節肢動物，死亡 例合、读2卜低(針對··肉、奶、毛、皮革、蛋、蜂蜜等)之案 更:濟:使本發明之活性化合物組合可以 腸給：據：明组合可以已知之方式，藉由經 藥丸、饋通法和检劑之=、服f、灌藥、膠囊、貼劑、大 注射(肌内、腹膜内和同4，)猎”經腸給藥’例如：藉由 例如·浸人或μ、由經鼻灌人給藥、藉由以 粉之方式域·用，、亦^在上面及點在上面、洗滌及撒 例如：項圈、耳棹、尸^从含活性化合物之模組化物件， 者加以辅助應用：獸::域肢幹帶、韁繩、打標裝置及同類 若使用於牛、家禽、 物組合可以調配物之心^及同類者’本發明之活性化合 ^'式（例如：粉末、乳化液、自由流動 96050-發明說明書 30 200803729 之組合物），其中包含1至80%重量比之活性化合物，直接 或經100至10000倍稀釋之後加以使用，或者其可作為化學浴 劑使用。 吾人進一步發現根據本發明之活性化合物組合對於破 5 壞工業原料之昆蟲具有強烈之殺昆蟲作用。 下列昆蟲可作為實例且其為較佳者-但不受任何限定： 曱蟲類’例如：北美家天牛、Chlorophorus pilosis、家 具竊蠹、斑駁大竊蠹（Xestobium rufovillosum)、梅角竊蠹 (Ptilinus pecticornis )、Dendrobium pertinex、松竊蠹 ίο ( Ernobius mollis )、Priobium carpini、褐粉蠢（Lyctus brunneus)、非洲粉蠹（Lyctusafricanus)、南方粉蠹（Lyctus planicollis )、櫟粉蠹（Lyctus linearis )、毛粉蠢（Lyctus pubescens )、等形粉蠹（Trogoxylon aequale )、鱗毛粉蠹 (Minthes rugicollis )、木蠹蟲（Xyleborus spec·)、 15 Tryptodendron spec·、黑長蠢（Apate monachus)、Bostrychus capucins、棕異翅長橐（Heterobostrychus brunneus )、長蠹 (Sinoxylon spec·)、竹長蠹(Dinoderus minutus )； 膜翅目，例如：樹蜂（Sirexjuvencus)、大樹蜂（Urocerus gigas)、泰加大樹蜂（Urocerusgigastaignus)、小紅大樹峰 20 ( Urocerus augur); 白蟻（Termites )，例如：歐洲木白蟻（Kalotermes flavicollis)、麻頭砂白蟻（Cryptotermes brevis)、印度異 白蟻（Heterotermes indicola)、黃肢散白蟻（Reticulitermes flavipes)、桑托散白蟻（Reticulitermes santonensis)、歐 31 96050-發明說明書 200803729 洲散白蟻（Reticulitermes lucifugus )、達爾文澳白蟻 (Mastotermes darwiniensis)、内華達動白蟻（z〇〇termopsis nevadensis )、台灣乳白犧（Coptotermes formosanus ); 石虫丙科（Bristletails)，例如：衣魚。 5 本文中之工業原料係指無生命之物質，例如，較佳為：塑 膠、膠黏劑、塗料、紙類和硬紙板、皮革、木材和經加工之 木製品和塗層成分。 倘若適合，則立即可用之組合物可進一步包含殺昆蟲劑 及，倘若適合之一或多種殺真菌劑。 ίο 關於可能之額外添加物，可以上述之殺昆蟲劑和殺真菌劑 作為參考。 根據本發明之活性化合物組合同樣可用以保護與海水 或鹹水接觸之物體，特別是船殼、掩蔽物、建築物、繫船設 備和信號系統，以防止其腐壞。 15 此外，根據本發明之活性化合物組合，單獨或與其他活 性化合物組合，可作為抗腐劑。 在家庭、衛生及經貯存產品之保護上，該活性化合物組 合亦適用以控制動物害蟲，特別是昆蟲、蛛形綱動物和蜗 類’其被發現於封閉空間内，例如：住宅、廠房、運輪工 20 具之艙房和同類者。其可單獨使用或與其他活性化合物和輔 劑併用於家庭用殺昆蟲劑產品中以控制此等害蟲。其對於敏 感性化抗性物種均有效且可抗所有發展階段。此等害蟲包 括： 鸩0 來自徵目（Scorpionidea)者，例如：地中海黃缴（Buthus 32 96〇5〇-發明說明書 200803729 occitanus ) 〇 來自蛛形目（Acarina)者，例如：波斯銳緣蜱（Argas persicus)、翹緣銳緣蜱（Argasreflexus)、苔蟎屬（Bryobia spp·)、雞皮刺蟎、家食甜蟎（Glyciphagus domesticus)、軟 蜱（Omithodorus moubat )、犬壁蝨（Rhipicephalus sanguineus )、恙蜗(Trombicula alfreddugesi )、松葉蜂 (Neutrombicula autumnalis )、塵蜗(Dermatophagoides pteronissimus )、粉皮蜗（Dermatophagoides forinae) 〇 來自虫知蛛目（Araneae )者，例如··（ Aviculariidae )、金 蛛科（Araneidae)。 來自盲蛛目（Opiliones)者，例如：螯蠍 (Pseudoscorpiones chelifer)、手擬峨（Pseudoscorpiones cheiridium )、蟹盲蛛（Opili⑽es phalangium )。 來自等足目者，例如··壁潮蟲（Oniscus asellus )、球鼠 婦（Porcellioscaber) · 來自倍足目者，例如：斑點千足蟲（ Blaniulus guUulatus)、馬陸屬（Polydesmus spp.)。 來自唇足目者，例如··地虫吳虫公屬。 來自衣魚目（Zygentoma )者，例如：毛衣魚屬 (Ctenolepismaspp·)、衣魚、盜火蟲（Lepismodes inquilinus ) 〇 來自蜚簾目（Blattaria)者，例如：東方蜚蠊、德國小 蠊、亞洲蟑螂（Blattellaasahinai)、馬德拉蜚蠊、Panchl〇ra spp·、（ Parcoblatta spp·)、澳洲蜚蠊（Periplaneta 33 96050-發明說明書 200803729 australasiae)、美洲大蠊、掠色蜚蠊（Periplaneta brunnea)、 黑胸大蠊（Periplaneta fuliginosa )、棕帶蜚蠊（Supella longipalpa) 〇 來自跳躍亞目（Saltatoria)者，例如：家蟋蟀。 5 來自革翅目（Dermaptera)者，例如··地娱虫公。 來自等翅目者，例如：木白蟻屬（Kalotermes spp.)、散 白蟻屬。 來自 17齧蟲目（Psocoptera)者，例如：Lepinatus spp.、 書蟲屬（Liposcelis spp·)。 10 來自鞘翅目者，例如：圓皮蠢屬、毛皮蠢屬、皮蠹屬、 長首榖盜（Latheticus oryzae )、郭公蟲屬（Necrobia spp·)、 蛛曱屬、穀蠢、穀象（Sitophilus granarius )、米象（Sitophilus oryzae )、玉米象（Sitophilus zeamais )、藥材甲蟲（Stegobium paniceum) 〇 15 來自雙翅目者，例如：埃及玫蚊（Aedes aegypti)、白紋 伊蚊（Aedes albopictus)、帶喙伊蚊（Aedes taeniorhynchus)、 癔蚊屬、紅頭麗繩、麻it ( Chrysozona pluvialis )、致倦庫蚊 (Culex quinquefasciatus)、淡色庫蚊（Culex pipiens)、媒斑 蚊（Culextarsalis)、果蠅屬、夏蠅（Fanniacanicularis)、家 2〇 蠅（Musca domestica)、白岭屬（phlebotomus spp.)、肉繩 (Sarcophaga carnaria )、蚋屬(Simulium spp·)、螫蠅 (Stomoxys calcitrans)、區欠洲大虫文。 來自鱗翅目者’例如：小壤蛾（Achroia grisella)、大虫鼠 蛾（Galleria mellonella)、印度穀蛾（pi〇dia interpunctella)、 34 96050-發明說明書 200803729 軟木蛾（Tinea doacella)、袋衣蛾（Tinea pellionella)、衣蛾 (Tineola bisselliella) 〇 5 10 15 20 來自蚤目者，例如：狗蚤（Ctenocephalides canis)、貓 蚤（Ctenocephalides felis)、人蚤（Pulex irritans)、穿皮潛 蚤（Tunga penetrans)、印鼠客蚤（Xenopsyllacheopis)。 來自膜翅目者，例如：大黑蟻（Camponotus herculeanus)、亮毛蟻（Lasiusfuliginosus)、黑毛蟻（Lasius niger)、隱毛蟻（Lasius umbmtus )、小黃家蟻（Monomorium pharaonis)、胡蜂（Paravespula spp·)、鋪道蟻（Tetramorium caespitum ) 〇 來自益目者’例如：頭盘（Pediculus humanus capitis )、 體兹（Pediculus humanus corporis)、天瘡屬(Pemphigus spp.)、Phylloera vastatrix、陰蝨（Phthirus pubis) o 來自異翅目者，例如：熱帶臭蟲（Cimex hemipterus)、 酿 六、烛（Cimex lectularius )、錐捲(Rhodinus prolixus )、 騷擾錐椿（Triatoma infestans)。 在家用殺昆蟲劑之領域中，其可單獨使用或與其他適合 之活性化合物，例如：磷酸酯類、胺基甲酸酯類、除蟲菊精 犬員、新於驗類、生長調節劑或來自其他已知之殺③蟲劑種類 之活性化合物合併使用。 其使用型式可為：噴霧罐、無壓力喷難品，例如：幫 ft喷霧器喷濃、自動造霧系統、噴霧機、泡泳、膠體、具 ^纖^或聚合物製之蒸發器藥錠之蒸發器產品、液體蒸發 -、㈣及膜蒸發器、推進劑推動之蒸發器、無能源或主動 96050-發明說明書 35 200803729 蒸發系統、蠹紙、蠢袋和蠹膠，呈顆粒或粉塵，在撒佈用餌 劑或餌站内。 根據本發明之活性化合物組合之良好殺昆蟲及殺蟎活 性可見於下列實例中。雖然個別活性化合物顯現微弱之活 5 性，但其組合卻顯現超越其作用之簡單加總之活性。 杀又昆蟲劑和殺蟎劑之協乘作用亦呈現於活性化合物組 合之活性超越活性化合物個別施用時之活性總和上。 對於兩種特定活性化合物之組合之期望活性可根據8卫·CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb, and CrylF, and combinations thereof (hereinafter referred to as "Bt plants"). Also of particular importance are plant defenses against fungi, bacteria, and by systemic induced disease resistance (SAR), systemin, phytoxins (phyt〇aiexins), elicitors 5 and resistance genes, and Corresponding to the improvement of the utility of proteins and toxins. A further particularly important feature is the increased tolerance of plants to certain herbicidal active compounds, such as imidazolinones, sulfonyl ureas, glyph〇sate or phosphinotricin (eg : "pat" gene). Genes with the desired characteristics can also be combined in transgenic plants. Examples of "Bt plants" that may be mentioned are corn varieties, cotton varieties, soybean varieties and potato varieties sold under the trade name YIELD gArd® (eg corn, cotton, soybeans), Knock〇u_ (eg corn) This old spit 8 (for example, corn), Bollgard8 (cotton), Nuc〇tn8 (cotton) and NewLeaf8 (potato). Examples of herbicide-tolerant plants that may be mentioned are corn varieties, cotton varieties, and soybean varieties, and their trademarks are sold under the trade name R〇undUp Rea (jy8 (and in Jiajia, for example, corn, cotton, soybeans). ), Liberty Link(g) (resistant to pho^hinotricin 'eg: canola), title 8 (taste resistant. sitting on a scorpion) and sts8 (=1⁄2 S& urea-based 'for example corn). May be resistant to weed control Plants (plants that screen herbicide tolerance in a conventional manner) include those sold under the trademark Cleaf's trademark 2, for example, corn. Of course, these instructions also apply to plant cultivars having the genetic characteristics of the gene or the genetic characteristics still under development, which may be developed and/or marketed in the future. The plants listed in the two, in a particularly advantageous manner, are treated as a combination of compounds according to the invention. The preferred range of combinations of the above active compounds is also 96050. • Inventive Manual 27 200803729 Suitable for treating scale plants. The important system is to treat plants by the combination of active compounds mentioned herein. The combination of active compounds according to the invention acts not only as pests against plant, hygiene and stored products, but also in the field of veterinary medicine, which can produce candles (in vitro and in vivo parasites), for example: hard蜱, soft 蜱, 瞒, leaf 螨, flies (bovine flies and ticks), parasitic larvae, crickets, ticks, feathers and fleas. Such parasites include: From Anoplurida, for example: Blood genus, Ranunculus, genus, genus Phtirusspp, and Solenopotesspp. 10 From Mallophagida and Amblycerina and Isehnocerina, for example: (Trimenopon spp.), Menoponsp., Trinotonspp· ), Bovicola spp., Werneckiella spp., Lepikentronspp., Damalinaspp., genus, 15 (Felicola spp.) 〇 from Diptera and NematocerimO and Brachycerina, for example, Aedes, Aquilaria, Musca, Simulium spp., Eusimulium spp., White genus (Phlebotomus spp.), genus Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Axylus spp. ), it genus, Haematopota spp., (Philipomyia spp.), genus Braula spp., housefly genus, genus genus (Hydr〇taeasPP·), genus, hornfly Genus (Haematobiaspp·), Mosquito (Morelliaspp·), Drosophila, Tongue 28 96050-Invention Manual 200803729 Glossina spp., Calliphora spp., Green genus, Golden genus, genus, Sarcophaga spp., genus, genus, genus Gasterophilus spp·), Hippotosca spp., L'ipoptena spp., Melophagus spp. 5 From Siphonapterida, for example: Pulex spp ·), Ctenocephalides spp., Xenopsyllaspp·, genus genus. From Heteropterida, for example: bedbug, cone genus, red genus, cone Genus (Panstrongylus spp.) ίο From Blattarida, for example: Oriental cockroach, American cockroach, German cockroach, Supella spp. From the Acari (Acarina) and the post-Metastigmata and Mesostigmata, for example, the genus Ornithodorus spp., the genus Otobius spp. ), 15 genus, genus, burdock, genus Dermacentor spp, genus Haemophysalis spp, genus, genus, genus Dermanyssus spp ·), genus Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp. 〇2〇 from Actinedida (Prostigmata) And Acaridida (Astigmata), for example: Acarapis spp., Cheyletiellaspp., Ornithocheyletiaspp., Myobia spp., genus (Psorergates spp·), genus (Demodexspp·), genus (Trombiculaspp), genus 29 96〇5〇-invention specification 200803729 (Listrophorus spp.), genus Acarus spp. , Tyrophagus spp., Caloglyphus spp., (Hypodectesspp,) (PteroUchusspp·), genus, genus, genus Otodectes spp., genus, genus Notoedres spp., Knemidocoptes spp., Cytodites spp ·), Laminosioptes spp. 10 15 20 The active compound combination according to the invention is also suitable for controlling infection of agricultural productive scorpions, such as: cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, ^, beaches, fire, ducks, geese and bees Other pets, such as: dogs, cats, and medium birds: mouth view! Fish, as well as so-called test animals, such as hamsters, scorpio I* a f milk and scorpion milk. By controlling these arthropods, the case of death, reading 2, and low (for meat, milk, wool, leather, eggs, honey, etc.) is more: the combination of the active compounds of the present invention can be given to the intestines: According to: Ming combination can be known in the way, by the pill, feedthrough method and test agent =, service f, medicine, capsules, patches, large injections (intramuscular, intraperitoneal and the same 4,) hunting" Intestinal administration 'for example: by, for example, dip or μ, by nasal administration, by means of powder, and also by above and above, washing and spreading, for example: collar, Deafness, corpse ^ From the module containing the active compound, the auxiliary application: Beast:: domain limbs, reins, marking device and similar if used in cattle, poultry, combination of things can be formulated ^ And the same type of active compound of the present invention (for example, a powder, an emulsion, a free-flowing 96050 - a composition of the invention specification 30 200803729), which contains 1 to 80% by weight of the active compound, directly or via 100 to It is used after 10,000 times dilution, or it can be used as a chemical bath. It has further been found that the active compound combination according to the invention has a strong insecticidal action against insects which break the 5 bad industrial raw materials. The following insects can be exemplified and preferred - but not subject to any limitation: Locusts such as: North American Ceramus, Chlorophorus pilosis, furniture burglary, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus , Lycusafricanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec·, 15 Tryptodendron spec·, Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec·, Dinoderus minutus; Hymenoptera, for example: Sirexjuvencus, Urocerus gigas, and Urocer Usgigastaignus), Urocerus augur; Termites, for example: Kalofermes flavicollis, Cryptotermes brevis, Heterotermes indicola, yellow termites Reticulitermes flavipes), Reticulitermes santonensis, European 31 96050-invention specification 200803729 Reticulitermes lucifugus, Mastotermes darwiniensis, Zevada termite nevadensis, Taiwan Coptotermes formosanus; Bristletails, for example: squid. 5 Industrial raw materials herein refers to inanimate materials, for example, preferably: plastics, adhesives, coatings, paper and cardboard, leather, wood, and processed wood products and coating compositions. If appropriate, the ready-to-use compositions may further comprise an insecticide and, if appropriate, one or more fungicides. Ίο For possible additional additives, the above-mentioned insecticides and fungicides can be used as a reference. The combination of active compounds according to the invention can also be used to protect objects in contact with sea water or salt water, particularly hulls, shelters, buildings, moorings and signalling systems, from spoilage. Further, the active compound combination according to the present invention, alone or in combination with other active compounds, can be used as a preservative. In the protection of household, sanitary and stored products, the active compound combination is also suitable for controlling animal pests, especially insects, arachnids and worms, which are found in enclosed spaces, such as: residential, factory, transport 20 cabins and similar people. It can be used alone or in combination with other active compounds and adjuvants in household insecticide products to control such pests. It is effective against sensitive resistant species and is resistant to all stages of development. Such pests include: 鸩0 from Scorpionidea, for example: Mediterranean yellow (Buthus 32 96〇5〇-invention specification 200803729 occitanus) 〇 from the arachnid (Acarina), for example: Persian sharp 蜱 ( Argas persicus), Argasreflexus, Bryobia spp., chicken skin hedgehog, Glyciphagus domesticus, Omithodorus moubat, Rhipicephalus sanguineus, cockroach Worm (Trombicula alfreddugesi), Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae, from Araneae, such as Aviculariidae, Araneidae . From the Opiliones, for example: Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, and Opili (10) es phalangium. From the isopods, for example, Oniscus asellus, Porcellioscaber, from the amphibians, such as Blaniulus guUulatus, Polydesmus spp. From the lips and feet, such as · · worms and worms. From Zygentoma, for example: Ctenolepismaspp·, squid, and Lepismodes inquilinus B from Blattaria, for example: Oriental 蜚蠊, German 蠊, Asia Lat(Blattellaasahinai), Madeira, Panchl〇ra spp·, (Parcoblatta spp·), Australian 蜚蠊 (Periplaneta 33 96050-invention specification 200803729 australasiae), American cockroach, Periplaneta brunnea, Periplaneta fuliginosa and Supella longipalpa are from the Saltatoria, such as the family. 5 From the person of the genus Dermaptera, for example, the worm. From the order of the isopods, for example: Kalotermes spp., termites. From the Psocoptera, for example: Lepinatus spp., Liposcelis spp. 10 From Coleoptera, for example: scorpion, snail, genus, Latheticus oryzae, Necrobia spp., spider mites, valley stupid, valley elephant (Sitophilus) Granarius ), Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum 〇15 from the order of the Diptera, such as: Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Aphis genus, Red-headed lynx, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culextarsalis, Drosophila Genus, Summerfly (Fanniacanicularis), Musca domestica, phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, owed Chau large insects. From Lepidoptera 'for example: Achroia grisella, Galleria mellonella, pi〇dia interpunctella, 34 96050-invention specification 200803729 Cornea moth (Tinea doacella), Coat Moth ( Tinea pellionella), Tineola bisselliella 〇5 10 15 20 From the eyes, such as: Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans ), Xenopsyllacheopis. From Hymenoptera, for example: Camponotus herculeanus, Lasiusfuliginosus, Lasius niger, Lasius umbmtus, Monomorium pharaonis, wasps ( Paravespula spp·), travertine ants (Tetramorium caespitum) 〇 from the eyes of the people of the 'Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus spp., Phylloera vastatrix, haze ( Phthirus pubis) o From the Heteroptera, for example: Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans. In the field of household insecticides, they may be used alone or in combination with other suitable active compounds, for example: phosphates, urethanes, pyrethrin dogs, new tests, growth regulators or from Other active compounds known to kill the 3 insecticide species are used in combination. The type of use can be: spray can, non-pressure spray, such as: spray spray, automatic fogging system, sprayer, swimming, colloid, evaporator or polymer evaporator Ingot evaporator products, liquid evaporation -, (d) and membrane evaporators, propellant-driven evaporators, no energy or active 96050 - invention instructions 35 200803729 Evaporation systems, crepe paper, idiots and silicones, in the form of granules or dust, Use a bait or bait station in the spread. The good insecticidal and acaricidal activity of the active compound combinations according to the invention can be found in the following examples. Although individual active compounds exhibit a weak activity, their combination exhibits a simple sum of activity beyond its function. The synergistic effect of the insecticide and the acaricide is also manifested in the activity of the active compound combination over the sum of the activities of the active compound when administered individually. The expected activity for the combination of two specific active compounds can be based on 8 Wei·

Colby，Weeds (1967)，20-22 如下加以計算： 10 倘若 X係為使用活性化合物A以组g/ha之施用率或 m ppm 之濃度時之殺滅率，以其為未經處理對照組之％表示之， Y係為使用活性化合物B以ng/ha之施用率或 Uppm 之 濃度時之殺滅率，以其為未經處理對照組之％表示之，且 15 E係為使用活性化合物八和B以也和这岁“之施用率 或HL和nppm之濃度時之殺滅率，以其為未經處理對照組 之％表示之 則 倘若實際之昆轰或㈣滅率超過計算值，則該組合之作 用為超力4亦即·有協乘作用存在。此等情;兄下，實際觀 察到之殺滅率必然會超較用上式所計#出之期望殺滅率 (E)之數值。 96050_發明說明書 36Colby, Weeds (1967), 20-22 is calculated as follows: 10 If X is the kill rate of active compound A at the application rate of group g/ha or m ppm, use it as an untreated control % is expressed as Y, which is the killing rate when the active compound B is used at an application rate of ng/ha or a concentration of Uppm, which is expressed as % of the untreated control group, and 15 E is the active compound used. Bahe B is also indicated by the application rate of the age and the killing rate of the concentration of HL and nppm, which is expressed as % of the untreated control group, if the actual quenching or (four) extinction rate exceeds the calculated value, Then the effect of the combination is super force 4, that is, there is a synergistic effect. This situation; under the brother, the actual observed kill rate will inevitably exceed the expected kill rate (E) Numerical value. 96050_Invention manual 36

Claims (1)

200803729 十、申請專利範圍： 1·一種包含組份(a)和（b)之組合物，其中 組份(a)係選自式（I)之活性化合物200803729 X. Patent application scope: 1. A composition comprising components (a) and (b), wherein component (a) is selected from the active compound of formula (I) 5 其中 Hal代表氣、溴或埃， *係指R-或S-構形之碳原子 且 組份(b)係由下列組成之群中選出 1〇 殿瞒多（propargite ) 芬佈賜（fenbutatin oxide) 汰芬隆（diafenthiuron ) 依殺蜗（etoxazole)。 2·如申請專利範圍第1項之組合物，其中組份(a)為式(lb)之 15 (S)-3-氯-NM2-甲基-4-[l，2,2,2-四氟小(三氟曱基）乙基]苯 基} -N -(1 -甲基-2-甲基石黃酸基乙基)-鄰苯二胺。 37 96050-發明說明書 2008037295 wherein Hal represents gas, bromine or angstrom, * refers to the carbon atom of the R- or S-configuration and component (b) is selected from the group consisting of: 1 prop 瞒 瞒 ( (propargite) fenbutatin Oxide) diafenthiuron is called etoxazole. 2. The composition of claim 1, wherein component (a) is 15 (S)-3-chloro-NM2-methyl-4-[l,2,2,2- of formula (lb) Tetrafluorosuccinic (trifluoromethyl)ethyl]phenyl}-N-(1-methyl-2-methyl-retinylethyl)-o-phenylenediamine. 37 96050-Invention Manual 200803729 3.如申請專利範圍第1或2項之組合物係用於控制動物害蟲 之用途。 4·如申請專利範圍第1或2項之組合物係用於處理種子之用 途。 5·如申請專利範圍第1或2項之組合物係用於處理轉基因植 物之用途。 6.如申請專利範圍第1或2項之組合物係用於處理轉基因植 物之種子之用途。 1〇 7·—種經如申請專利範圍第1或2項之組合物處理之種子。 8. —種用以控制不欲之動物害蟲之方法，其特徵在於將如申 請專利範圍第1或2項之組合物施用於該不欲之動物害蟲 及/或其棲地及/或種子。 9·一種用以製備殺昆蟲和殺蟎組合物之方法，其特徵在於將 15 如申請專利範圍第1或2項之組合物與增量劑及/或界面活 性劑混合。 38 96050-發明說明書 200803729 七、指定代表圖： (一） 本案指定代表圖為：第（無）圖。 (二） 本代表圖之元件符號簡單說明： 無0 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式：3. The composition of claim 1 or 2 for use in the control of animal pests. 4. The composition of claim 1 or 2 is used for the treatment of seeds. 5. The use of the composition of claim 1 or 2 for the treatment of transgenic plants. 6. The use of a composition according to claim 1 or 2 for the treatment of seeds of a transgenic plant. 1〇 7·- Seeds treated with a composition as claimed in claim 1 or 2. 8. A method for controlling an undesired animal pest, characterized in that the composition of claim 1 or 2 is applied to the unwanted animal pest and/or its habitat and/or seed. A method for preparing an insecticidal and acaricidal composition, characterized in that a composition according to claim 1 or 2 is mixed with a bulking agent and/or an interfacial activator. 38 96050-Invention Manual 200803729 VII. Designation of Representative Representatives: (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the representative figure: No. 0. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 4 96050-發明說明書4 96050-Invention Manual