TW200534B - - Google Patents

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200534 A 6 B6 經濟部屮央標準局员工消費合作社印製 五、發明説明（1) 發明背景 本發明有關改良之連績缕絲耐綸服裝纱且特別有闊製 造耐綸平纱之穿經法及由彼所製之改良纱品。 耐綸平纱用於各種使用前染色之機織或經编針織物。 當此類織物使用小分子染料時，通常可得均勻染色而無多 大困難。但是，就某些嚴格染料應用諸如泳裝或自動傢倶 用之織物而言，其需優越之耐洗及/或耐光牢度，故期望 使用大分子酸染料。以大分子酸染料染色此種織物時，即 使在平纱染料攝取有少量不均，仍可在織物染色造成高度 可見不均度及由是所致之差織物外觀。 耐编平纱通常具少於6 0%之斷裂伸長度且因此可稱 為a完金拉伸"紗。一般，已知平纱之高度定向藉在總體 纺拉成形法（由紡絲板退繞之速度在約1400及 2000米每分鐘（mpm)間且捲取速在約2500及 3500mpm間）或裂膜成布法（其中在一般少於 1〇00mpm退繞速度紡絲之纱包在個別法中使用單纱 拉伸絡絲機拉伸）之纱産製間拉伸賦予。但是，常發現所 製纱常不能適於嚴格染色應用諸如泳裝或自動傢倶，因為 必需在此纱製備中及形成織物之製備及染色中特別小心以 得可接受之染色均度。 已有市售可在熱水浴中拉伸耐綸經纱之設備。但是， 雖使用此設備之方法可增加染色均度，但設備確實具有數 値固有優點。使用此設備之方法麻煩且因在拉伸時纱整理 劑移入水中而産生污染水之廢流。而且，纱用於針織時， (請先閲讀背面之注意事項再填寫本頁) 裝. 訂 線· 太银κ疳iA m Φ因因宅拽rn f CNS) Ψ 4极格ί 210 y 297公分） -3 - 經濟部中央標準局员工消費合作社印製 200534 A6 _B_6 五、發明説明（2 ) 必需在拉伸後再施加整理劑。市售濕式拉伸設備的另一嚴 重缺點為流程速一般限於約300—350mpm,因設 備在捲取前將纱乾燥的有限能力。 發明坡给 依發明提出，扁平連缠纖絲耐綸服裝用纱（待.別遒於 駸格染色應用）及此纱之製法。纱製法包括： 將具約35及約80間之相對粘度（RV)之耐綸聚 合物紡絲，纺絲以足以形成剩餘拉伸比（R D R ) s少於 約2. 75之紡纱之退繞速度（Vs )進行； 安定化，交織，並施加整理劑於紡纱以形成剩餘拉伸 比（RDR) ^•在約1. 55及約2. 25之餵入纱，餵 入纱具動態長度變化（^L)及縮率（ΔΙ^/ΔΤ)，其 在401C及1 351C間皆少於0 ; ί 乾燥拉伸並實施乾燥放鬆餵入經纱以形成拉伸經纱， 乾燥拉伸在約1. 05及約（RDR) F/l. 25間之 經纱拉伸比（WRD)及約20¾及約該聚醯胺聚合物之 溫度T /間之纱拉伸溫度（D )進行，拉伸之餵入經 纱之乾燥放鬆在約2 0它及比聚醯胺聚合物之熔點（T« )少於約4 0 1C之溫度間之纱放鬆溫度（Τ «)進行，放 鬆溫度另藉下式定義： T«(°C [ 1000/(Ki-K2 (RDR)fl) ]-273 (請先閱讀背面之注意事項再填寫本頁) 裝. 訂- 線. 太《.後 Κ iA m Ψ Η Η «:摁雄（CNS) Ψ4姐格（210x297公货） 200534 A 6 B6 經濟部中央楳準局员工消f合作社印製 五、發明説明（3 ) 溫度如以下更詳盡說明之固定張力下測 董對溫度之長度改變％而決定。乾燥拉伸及乾燥放鬆是使 拉伸經纱之沸溶收縮（BOS)在約3%及約1 0%且剩 餘拉伸比（R D R ) />在約1 . 2 5及約1 . 8間般進行 Ο 就耐綸66聚合物之餵入纱而言，既定拉伸纱_之剩餘 拉伸比（RDR) d之較佳溫度範圍可在上式中指定K; 值為4. 95且為1. 75而得。就耐綸6聚合物而 言，Κι 5. 35且仄2 1. 95為得到較佳溫度範圍之 適當值。 依一較佳法，纺絲中之退繞速率高至使纺纱之剩餘拉 伸比少於約2. 5。發明之另一較佳形式中，初生纱之紡 絲速率使剩餘拉伸比少於2 . 2 5。通常，具此剩餘拉伸 比之纺纱具有在40^及1 351C間皆少於0之動態長度 ί 變化（AL)及縮率（AL/ΔΤ)。因此，高速紡絲藉 以安定纺纱而不添加安定化處理，然後初生纱可用為餵入 纱。 依發明之另一較佳法，可進行紡絲及安定化使餵入纱 之剩餘拉伸比在約2 . 0及約1 . 5 5間。較好，程序提 供具有少於約1. 4g/d,更好少於約1. 2g/d, 尤其是少於約1g/d之拉伸張力（DT33%)之餵入 發明法中，使用餵入經纱之乾燥拉伸及乾燥放鬆。較 好乾燥拉伸及乾燥放鬆是在惰性氣氛，例如，空氣，約 (請先閲讀背面之注意事項再填寫本頁) 火认伐κ /ί 1Λ m中因a玄摁ift(CNS) Ψ4助^210x297公.糾 -5 - 經濟部中央標準局貝工消t合作社印製 200534 A6 ___B_6 五、發明説明（4) 50¾至約90%相對濕度（RH),更好，約60%至 約8 0%R Η中完成。乾燥放鬆中，使用少於約T//,** ，尤其是少於Τ 〃〃之溫度。放鬆中之較佳條件導致在約 3 %及約8 %之拉伸經纱沸溶收縮（BOS)及約 1 . 2 5及約1 . 5 5間之拉伸經纱剩餘拉伸比 (R D R ) ζ» 〇 _ 發明方法可用於大部分耐綸聚合物。較佳耐綸聚合物 含有耐綸66聚合物及耐綸6聚合物。較佳耐编66聚合 物含有少量雙官能聚醯胺共聚單體或可與耐綸6 6聚合物 氫鍵結之非反應性添加物。 發明方法提供可用於多種必需可以大分子染料均匀染 色之經编或機織織物中之高度均勻耐编纱。發明較佳法所 製之纱尤適於此用途且具至少約6之大分子染料均度级數 (L M D R )。 附圖簡沭 圖1為可依本發明方法製造餵入纱之裝置的圖示； 圖2為可用於本發明方法之一般市售穿經設備圖示； 圖3為拉伸張力（DT)之一般圖（Α線）及沿端拉 伸張力變動（DTV)在室溫對拉伸比（DR),百分比 伸長度（Ε)及剩餘拉伸比（RDR) ^之對應圖（Β線 )〇 圖4為耐綸餵入纱之長度變化百分比（△長度％)對 溫度之不圖，其使用 Dupont Thermal Mechanical Analy- (請先閱讀背面之注意事項再填寫本頁) 太《.张κ疳ii m Ψ团η艾鸩诅（CNS) V 4组格m 0 X 297公炝） -6 - 200534 A6 B6 經濟部屮央榣準局员工消费合作社印製 五、發明説明（5) ser在毎分鐘5 0 1C之固定加熱速率並將初預張力由 3mg/旦尼爾變至500mg/旦尼爾得到；其中，纱 在大於約50mg/d之張力下延伸（圖4A —上半部） 且在少於約5〇mg/d之張力下收縮（圖4B—下半部 )〇 圖5為耐綸餵入纱在50至500mg/d預張力下 動態延伸率，（AL/AT),對溫度之示圖，其使用 D u ρ ο n t T h e r m a 1 M e c h a n i c a 1 A n a 1 y s e r 在毎分鐘 5 0 之 加熱速率下得到；其中，最大動態延伸率； (△L/ΛΤ) ，在此，取為主要結晶之始點並在 Τ/h*溫度發生（即，對大部分耐綸纱而言約1 10 — 1 4 0 Ό ) 〇 圔6為動態延伸率（△ L/△ T ) 對預張力應力 (σ)之示圖（如圖5所述）；其中，斜率，在 300mg/d之d (AL/ΔΤ) ,用為對變動應 力標準下（即，變動超餵％)放鬆步驟中拉伸之餵入經纱 的蚕敏度測量。 圖7為耐编餵入纱之長度變化百分比（△長度，％) 對溫度之一般圖（A線），其使用Du Pont Thermal Mechanical Analyser在 3 0 ◦ m g / d 之預張力 得到； 及對 應之動態延伸率圖（B線），其定義為A線之毎攝氏度數 的瞬時長度變化（△長度％) (△溫度，*C)。 圖8為相對結晶率，dx/dt,對處理溫度之示圖 ;其中，dx/dt值增加，在Tc逹最大值。 (請先閲讀背面之注意事項再填寫本頁) 裝- ,?τ. 線. 太Κ 泞 iA Ψ H ra «：^miCNSVH4M；tM2U)y297公;«·) -7 - 200534 A 6 B6 經濟部中央標準局员工消費合作社印製 五、發明説明（6 ) 圖9為放鬆溫度（Τ«，Ί0)之倒數，以1〇〇〇/ (丁《+ 2 7 3 )表示，對拉伸纱之剩餘拉伸比（ RDR)〇之圖示。粗線所框之I (ABDE)及II ( AEHI)區表示相對於方法之拉生步驟可用以産生具優 越大分子染料均度级數（LMDR)之放鬆步驟溫度條件 (T « ) 〇 圖10為動態收縮張力（ST),在3〇1〇/min 加熱速率定長條件下，對溫度之圖，其在高於T*之溫度 突然增加並在T 逹最大值。 圖1 1為使用Lawson-Hemphill TYT由7 0t：逐步增 溫至150P所測之乾熱收縮的一般圖。 圖12為動態損耗係數（E 對數值對溫度（A線 )及對應之Tan Delta對數值對溫度（B線）之一般圖 Ο } 圖1 3為差示掃描熱量器所測之熱流變化對溫度之一 般圖。在601C至200/C溫度範圍之介入增大顯示各因 T / /,i, T / 及T / /,**所致之三値熱轉移。 圖1 4及1 5為拉伸經纱TMA動態延伸率對溫度之 一般圖；其中圖14具有小於6之LMDR且圖15者具 大於6之LMDR。 圖1 6為初生耐编6 6纱（R D R ) s之剩餘拉伸比 ,以其倒數表示，1/ (RDR) s , (A線）及密度（ B線）對纺絲速率之圖示。 圖1 7為新初生纱沸溶後長度改變（A線）及雙折射 (請先閲讀背面之注意事項再填寫本頁) 裝- 訂· 線· 太ii m Ψ 团 S3 它 1¾堆（CHS 1 Ψ4姐格ί210乂297公 -8 - 200534 A6 B6 經濟部屮央標準局员工消費合作社印製 五、發明説明（7) (B線）對紡絲速度之圖。 圖1 8為實施例中用為穿經之各種紡絲定向及部分拉 伸纱在3 0 Om g/g張力下之動態延伸速率 (△L/ΔΤ)對溫度之TMA圖示。 圖19為各種不同纱型在5mg/d張力下收縮（△ 長度％)對溫度之Τ Μ A圖示。 圖20為拉伸應力（σΰ )，以每拉伸旦尼爾之克數 表示，對拉伸比在751012 5 =，及 175*0之圖示；其中，斜率稱為拉伸模數（M〇 )且定 義為（△az^/ADR)。 圖2 1比較在7 5Ό下各種餵入纱之拉伸應力（σ〇 )對拉伸比（D R )。 圔22為圖21之餵入纱之拉伸模數對數值， In (MD)，對〔1000/(T〇，t： + 273)〕 ί 之圖示；其中取斜率為拉伸能量（Ε。）測量。 圔2 3 — 3 2為可用以決定本案之實施例中産製之纱 的LMDR標準的織物條電腦模擬。 諾沭 本案所用之耐綸聚合物為任何可熔紡成具有適於織物 應用性質之各種一般直鏈，脂族聚醛胺均聚物及共聚物。 較佳耐綸聚合物為聚（己二醯己二胺）（耐綸66)及聚 (ε —己内醯胺）（耐綸6)。耐綸聚合物在纺絲時具約 3 5及約8 0間之相對粘度（R V )。 (請先閱讀背面之注意事項再填寫本頁) 裝. 線. 太紙张β泞iAffl Φ因03¾:摁m(CNS) 姐格〖210乂297公货） -9 一 經濟部屮央標準局员工消費合作社印製 200534 A6 _B6 五、發明説明（8) 當使用耐綸66聚合物時，聚合物之RV大於約46 為佳，如美國再申請專利33, 059 (美國專利 4, 583, 357)所教示，其掲示在此作為參考。但 是，RV通常應少於約6 5.,因為依再申請專利 33, 059所得之優點在RV高於65時不能明顯增加 。而且當紡纱耐綸66時，較好使用包括少量共聚物單元 諸如ε_己内醯胺或己二醯2 —甲基一伸戊二胺（Me 5 -6)或可與耐綸66氫鍵結之反應性添加物。就餵入纱 紡絲用之既定紡絲條件而言，此使斷裂伸長度增加，就既 定斷裂伸長度而言，減少在程序穿經步驟中利於拉伸之拉 伸張力。因為以具低RT之聚合物得到相同餵入纱性質之 能力，尤其在高紡絲速度下，使用2-甲基-伸戊二胺提 供在耐编6 6聚合物中之己二醯2_甲基一伸戊二胺單元 尤佳。使用Me5—6, 66共聚物餵入纱於穿經法中, 拉伸張力在相同拉伸比下減少，且拉伸纱之機械性應改善 。隨Me 5 — 6量增加，染料深度增加。此示上染率隨 Me 5 — 6量增加而增加或結構更開放，其一般為改善之 染色勻度表示。拉伸纱之收縮隨Me 5 - 6量增加而增加 ，在20% Me5_6達>1〇%B〇S之程度。此程 度難以在産生良好機械性之拉伸比下以耐编66得到。或 者，若需要可用美國專利4, 72 1, 65 ◦所掲示之雜 支化劑。如技藝界已知，遮光劑諸如二氧化鈦，色劑，抗 氯劑及其他可用添加劑可摻入聚合物中。 具有可與耐綸6 6聚合物氫鍵結之雙官能共聚醯胺共 (請先閲讀背面之注意事項再填寫本頁) 裝· *lr· 10 ™ 200534 A 6 B6 經濟部中央標準局負工消費合作社印製 五、發明説明（9) 聚單體之耐綸6 6可藉含適當比例之單體的、、鹽"水溶液 中縮聚製得。可用於均聚耐编66産製之方法可應用於 N6， 66産製，添加e—己内醛胺於鹽液。為製Me5 一6， 66,産製具期望重量比之己二醯2—甲基一伸戊 二胺之共聚物所需之荚耳比下之己二酸與伸己二胺（ HMD)及2-甲基-伸戊二胺（HPMD)用於製造鹽 液。但是，就Me5_6， 66而言，通常需改變一般耐 綸66之方法以確定MPMP,其較具揮發性，停留於溶 液中之時間足以反應。2 —甲基一伸戊二胺市售自E. I. du Pont de Nemours & Co·， Wilmington， Delaware， 商標為DYTEK AR 0 參考圖1,其說明包括製造餵入纱之代用者之方法， 纱γ使用高速熔纺法由纺絲板1纺出。纖絲在a驟冷〃道 中使用，例如，2 01C之交流風冷卻，並在整理劑施加器 ί 諸如棍或量測整理劑施加器匯集。 依本發明方法，退繞速度（Vs ),即，用以將纱拉 離纺絲板1之第一锟，足以形成'"剩餘拉伸比" (RDR) s少於約2. 75之紡纱。如下文所釋，第一 棍依所用之特定設備而定可為多種不同棍之任一種。本專 利申請案所用之a剩餘拉伸比"意指在纱斷裂前可藉拉伸 使纱長增加數倍且可藉下式由斷裂伸長度$計算： RDD-1+(Eb /100) (請先閲讀背面之注意事項再填寫本頁) 裝. 訂· 太址张R疳iA ffl Ψ因囷玄找迆（CNS) Ψ4码格（210X297公对) 11 — 200534 A 6 B6 經濟部屮央標準局员工消費合作社印製 五、發明説明（1() 已發現剩餘拉伸比（R D R) S在紡纱中必需小於 2· 75且與方法之其他程序步驟合併以得到拉伸經纱中 改良之大分子染料勻度。較好，紡纱中之剩餘拉伸比小於 約2 . 5，最好小於約2 . 2 5。 賦予小於2 . 7 5之剩餘拉伸比於纺纱之退繞速度依 纺絲法中多種因素而定包括所纺纱之細度（旦尼爾每纖絲 ),聚合物之相對粘度，紡絲溫度，紡絲板毛細尺寸，及 以驟冷風流動方式，流速，及驟冷風溫度決定之驟冷效率 。一般使剩餘拉伸比（R D R ) s小於2 · 7 5之最小退 繞速度對一般織纱而言為約2000mpm之大小。通常 ，較好以高於約3000mpm之退繞速率纺成餵入纱， 其不需小心控制程序條件。 發明法中，將紡纱安定化以提供剩餘拉伸比為 1. 55及約2. 25間且動態長度變化（AL)及縮率 ) (△ L / △ T )在4 ◦ °C及1 3 5 C間皆小於◦。較好， 餵入纱具有在約1 . 5 5及約2 . 0間之剩餘拉伸比（ R D R ) ^ 〇 如圖1虛線所示，安定化可藉多種不同代用法完成。 安定化可如代用法A所示藉將紡纱曝於U . S .專利 3, 9 9 4, 1 2 1所示之蒸汽室之蒸汽中或將纱通經 U. S. 4, 181, 697所示之無蒸汽，加熱管而完 成。然後纱經拉出器及放長棍，5及6,個別，雖其實質 上無任何拉伸。代用法B顯示一組引出器及放長锟5及6 ，其以實質用於捲曲之速度驅動，因此在此類棍及捲取間 (請先閲讀背面之注意事項再塡寫本頁) -裝麗 太蚯铬K汶iA Ιίΐ Ψ团团玄尥m i CNS) Ψ 4斑格m 0 X 297公货） -12 - 經濟部中央標準局员工消費合作社印製 200534 A6 _B6 五、發明説明（I》 無實質拉伸。安定化由是藉如代用法C所示之高纺速賦予 ，例如，大於約40〇〇mpm。辊5及6可加熱（若需 要）以安定化纱收縮，若在低於約40〇〇mpm之速率 紡絲。代用法C為a無導錕，"法，其中纱不與紡絲板及捲 取棍間之棍接觸。捲取速度足使在紡絲時賦予纱之紡絲定 向提供穩定之餵入纱而不需其他個別安定化步驟。一般完 成此之速度高於約4000mpm。代用法B及C所製之 纱稱為纺絲定向或a S Ο Y 〃纱。代用法D說明a部分拉 伸"於安定纱之用途。在放長棍6前，餵入棍7及拉伸棍 8充分拉伸纱以安定化。完成此者所需之拉伸量依來自纺 絲速度及條件之纱定向而定在約1. 05及約1. 8間。 代用法D所製纱常稱為部分拉伸〃或w P D Y 〃纱。所 述之安定化代用法之變化在本發明方法中是可能的。 纱在交織噴嘴9交織使餵入纱具充分交鑣度以能在捲 取1 0有效捲取餵入纱並由穿經筒移除餵入纱。此者之適 當交織度，藉快速針數法（RPC)測量，為不多於約 14之RPC交織。雖然可諸如在穿經後採用''缠結〃增 加以如所期望般進一步加工或用以織物形成，餵入纱中高 度交織為消除此種額外交織所需。因此，某些較佳餵入纱 中之交織度應高至足以在穿經後得到延伸於交織结間期望 量之交織。此者所需之精確交織量通常依纖絲數及d g f ,纱整理劑種類，及纱所施加之拉伸比及拉伸張力，及含 拉伸纱之最終織物所期望性質，尤其美觀而定。就許多餵 入纱而言，採用約6及約10間之RPC交織為佳。 太 >k 因國宏找徂（CNSPfM 捋格（210x297 公货） _ 13 - (請先閲讀背面之注意事項再填寫本頁) 裝· 訂 線. 200534 A 6 B6 經濟部屮央標準局貝工消费合作社印製 五、發明説明（ 依發明，頷入纱在紡絲後組成經纱。為有完成此者， 較好將餵入纱包括成數個大體均勻長度之包裝，其可由集 中架提供以形成經纱。 發明法，餵入經纱進行乾拉及乾放以提供拉伸經纱。 本案所用A乾燥〃拉伸及> 乾燥"放鬆意指拉伸及放鬆在 氣體環境中完成而不施加液體水於纱。依發明乾拉_及乾放 之較佳氣氛為惰性氣氛諸如相對濕度50及90%間，較 好6◦及80%間之空間。乾拉及乾放可在其他惰性氣體 諸如蒸汽，其可提供熱源及惰氣氣氛，存在下完成。 經纱在約1. 05及約（RDR) f/1. 25間之 經纱拉伸比（W D R )下拉伸。本案之 > 經纱拉伸比〃可 由a總拉伸比〃計算，其定義為餵入纱之剩餘拉伸比（ R D R ) ^•對此法所製之拉伸纱之剩餘拉伸比 (R D R ) ΰ之比例，即，在其進行放鬆後： TWDR-(RDR)f/(RDR)〇 總經纱拉伸比與下式所示之經纱拉伸比有關： TWDR-WDR(1-%0F/100) (%〇F意指詳述於下文之超餵。）經纱拉伸比（WDR )亦可由纱之長度變化計算，例如，拉伸棍對餵入棍之速 率比。相同地，總經纱拉伸比（T W D R )可由放鬆後之 (請先閲讀背面之注意事項再填寫本頁) 裝· 200534 A 6 B6 經濟部屮央標準局貝工消費合作社印製 五、發明説明（1岑 棍對餵入棍速度計算。 拉伸時之纱溫（τβ )在約2〇υ及約聚合物之 間。如圖7及以下所附者，及試驗法所示， 丁 為定定張力下測量纱長度對溫定變化而定義之耐 綸聚合物溫度。乾拉伸之加熱有利減少發明程序中之拉伸 張力。較好，拉伸中纱溫最好少於約Τζ/,ι。就耐綸6 6 及具少量氫鍵組成之耐綸66而言，纱拉伸溫度可達約 175¾。較好，溫度在約20°及約135Ί0,最好， 在約20t：及約90Ό間。就耐綸6而言，經拉伸溫度應 通常約比耐綸66對應溫度少20 - 40C。非接觭或接 觸加熱裝置諸如烤爐，輻射加熱器，板熱器，熱棍，等適 於在拉伸中加熱纱。 纱進行熱放鬆步驟以控制熱溶收縮且放鬆亦使拉伸纱 之剩餘拉伸比（R D R /> )明顯增加。選擇乾拉伸中之經 纱拉伸比（WDR)及乾放鬆中之條件使拉伸經纱具有約 3%及約1 0%間之沸溶收縮（BOS)及約1. 25及 約1 . 8間之剩餘拉伸比（R D R ) D。較好，沸溶收縮 在約3及約8 %間且拉伸纱之剩餘拉伸比（R D R ) β在 約1 . 2 5及約1 . 5 5間。此外，本發明之經纱拉伸及 放鬆中，可調整其他最终用途期望之纱性質。發明可提供 斷裂伸長度範圍及其他期望性質而保持纱中勻度，其可産 生具良好纱勻度之染色織物。較好，拉伸經纱之靱度高於 約2g/d且可高約6g/d或更高。較佳模數標準高於 約1 5g/d且可達約40g/d或更高。 太泞a m Ψ 因 a 宏找規格（210x297公货） -15 - (請先閲讀背面之注意事項再填寫本頁) 裝. 訂 -線· 經濟部屮央橾準局負工消費合作社印製 200534 A 6 __B_6 五、發明説明（1今 此法放鬆步驟中之超餵％，即，經收縮産生之長度變 化量，必需選擇以得到期望性質。超餵％可藉在放鬆前後 調整與纱接觸之棍速而設定且收縮通常隨增加之超餵而減 少。依其達收縮步驟及期望，之拉伸纱性質時之纱定向而定 ,超餵可極少且可逹約10%。較好，超餵％在約2及約 8%間。雖然超餵％可在此範圍變化，但就特定餓.入紗而 言超餵％應不太高，且放鬆步驟中纱之放鬆溫度或纱張力 降至零且程序不能進行。若使用缠結以賦予額外交鐵於纱 則適當控制超餵亦重要，因較低之放鬆張力産生較緊密之 纏結。使用缠結時，應調整超餵以産生0. 25至 ◦ · 50克/拉伸旦尼爾（g/dd)或較好0. 30至 0. 375g/dd之放鬆區張力。放鬆區張力低於 〜〇.25g/dd時，纏結操作性差。 發明法中，放鬆時之纱溫（T« )必需在約2〇"0早 低於耐綸聚合物熔點（Τ« .)約401C之溫度間。如程序 之拉伸步驟，非接觸性或接觸性加熱裝置諸如烤瀘，輻射 加熱器，板熱器，熱棍適於在放鬆時加熱纱。 已發現將拉伸纱溫（Τ« )控制在對拉伸纱 (RDRz> )之剩餘拉伸比特定關係中所對應者可提供高 度大分子染料分子染色勻度级數。依發明，依以下關係選 擇放鬆溫度（T « ): [ 1000/(Ki-K2 (RDR) 〇) )-273 (請先閱讀背面之注意事項再填寫本頁) 太址帒R /iifi m Ψ因因玄鸪摧（CNS) Ψ4报柊（210>：297公贷） -16 - 200534 A 6 B6 經濟部中央標準局员工消費合作社印製 五、發明説明（13 式中 Κι :100(^(1^/,1 + 273) + 1.251(2 且 K2 = [ 1000/( T7/ , ζ. + 273)-1000(Τ// , ** + 273) )/0.3, 較好，纱放鬆溫度少於,最好少於Τ« ,Τ7/,μ及Tw,*在耐綸聚合物餵入抄.上決定 ,其用以説明圖7及伴隨文字及以下試驗法。 就耐编66聚合物餵入纱而言，既定之拉伸纱剩餘拉 伸比（RDR) σ之較佳放鬆溫度範圍可在上式中指定 Ki為4. 95且Κ2為1. 75而得。較佳放鬆溫度為 少於約175¾且，最好，少於約135*0,就耐编66 或具擻量氫鍵結組份之耐綸6 6而言。就耐綸6而言，較 佳溫度圍範各指定K2為5. 35且K2為1. 95而定 義。通常，耐綸6纱之較佳溫度比對應耐綸66溫度少 ； 2 0 - 4 Ο Ό 〇 發現市售設備適於依發明穿經適當之餵入纱。型式 D S S Τ 5 0 其製自1(31'1肘3_761'了6乂111111350^11611£31)-rik GmbH，D-6053 Obertshausen，Germany.及型式 S Τ FI,其製自 Barmag Akt iengesel lshaft » 5630 Remsch-eid, Germany為適且二者之用途說明於下例中。此設備之 一般捲取速度在達約600mpm之範圍。因設備相近， 故僅將Barmag STF1圖示於圖2。 參考圖2，餵入纱之經纱片（以符號W表示）藉餵入 提1 1_1 3由左側集中架（未示）拉出。餵入棍可加熱 (請先閱讀背面之注意事項再填窝本頁) 裝· 訂_ 太紙帒尺泞1¾ m屮因因灾找iMCNS) Ψ4姐格（210乂297公货） -17 - 經濟部屮央標準局员工消費合作社印製 200534 A 6 _B_6 五、發明説明（19 且一般加熱至約5 0及約9 OC間之溫度。此單元具斜板 加熱器且若需要可進一步將纱加熱。然後經纱W送至未熱 拉伸锟14— 17。拉伸棍14及15 — 17以大於餵入 棍之速度驅動以賦予經纱期望之拉伸量。 通過拉伸棍17後，纱在通經與具有熱至約2 0 〇1〇 之能力之板熱器f觸之經纱時進行放鬆。放鬆量以引出辊 18—20控制，其在約比拉伸锟14一17少之速度驅 動以提供所需超餵。形成之纱成束同時捲取於成束絡絲機 (未示）。 就圔2所示之設備而言，餵入纱之經纱片在棍13及 14間拉伸，拉伸溫度（Td )定義為為錕13及14表 面速度比之經纱拉伸比（WDR)(即，WDR = V14 /V13 ;放鬆溫度（Ts )棍17及18間之熱放鬆， 超餵百分比，％〇F= (1—V18/V17)100, t 其中VI8/V17為锟17及18之表面速度比；只要 總經纱拉伸比TWDR*S:TWDR=WDRX(1_ %0F/100) = (V14/V13) X (V18/ V17) =V18/V13,因為一般V14=V17。 依發明所製之纱具有使其極適為駸格染色應用之性質 。多種纱物性反應均匀染色性且其中任一或多種對染色勻 度極重。相信為發明方法或發明法所製纱之性質的待性為 館入及拉伸纱二者之旦尼爾變化分析（DVA)的沿端 %CV少於約0. 7且當餵入纱拉伸 1. 33X (DT33%)時，拉伸張力之沿端％CV少 (請先閲讀背面之注意事項再填寫本頁) 装. 訂 太K 飧 iA 用 Ψ 团 K 媪格（210x297公;«·) -18 - Ϊ00534 A 6 B6 經濟部中央標準局员工消费合作社印製 五、發明説明（ 於約1 . 0。 發明之較佳法提供具至少6之A大分子染料勻度级數 "(LMDR)之纱。''大分子染料〃一詞意指八1^111^(1- uinone Milling Blue BL(C.I. Acid Blue 122) SSando-1 i η M i 1 1 i ng B 1 ue BL_N ( C . I . Ac i d B 1 ue 80 )中任一*者〇 此二染料皆為大分子，耐洗，速率敏感酸染料。雖_未用於 本案LMDR之測量，但其他大分子染料可能更薛格或更 不嚴格。本案所用之''大分子酸染料勻度级數"意指將纱 織成經平織物再以上述任一種大分子染料染色所得之纱染 色勻度評估。在評估法中染色後，織物藉藉專門板片如以 下試驗法中詳述者使用圖2 3 — 3 2所示之織物條為導線 之電腦模擬分成1至10级。認為評估為5或以下者不可 接受且評估5至6者為某些非駸格之經编織物所接受。6 或以上之级數認為傜大部分經编織物可接受。6. 5或更 ί 高之级數為嚴格經编織物諸如泳裝所用者所接受且本發明 之纱更利於産生髙於約5之勻度级數。認為7或更高 级數為佳且可産生高於7之级數之纱最佳。高至8. ◦或 更高之级數在本發明中亦可能。 圖3為拉伸張力，DT (Α線），在室溫測量（以每 初旦尼爾之克數表示），就具有80%斷裂伸張度之耐编 餓入纱而言（即，(RDR) f =1+80/100 = 1 . 8 0 )對伸長度百分比（Ε ),拉伸比.（D R = 1 + Ε / 1 0 ◦),及拉伸纱之剩餘拉伸比〔（R D R ) 〇 = (RDR) / /DR〕所繪之圖；其中，DT先隨拉伸比 (請先閲讀背面之注意事項再填寫本頁) 裝. 線< -19 - f200534 A 6 B 6 經濟部屮央標準局员工消費合作社印製 五、發明説明（ 迅速增至屈服點（Ey, i )，在約5%E (即，約 1. 05XDR)，並較缓和地隨拉伸比增至在ΕΛ之斷 裂點（即，RDR=1. 0);及對應之沿端拉伸張力變 化（DTV)之圖（B線）U%CV表示，其迅速減至初 屈服點（Ey, i)並在Ey,丨至£：7, f之曲服區中實 質保持固定，然後一般增加至纱斷裂。最佳拉伸區.定義為 E y, i至Ey, f ;即，在此例中為5%至55%之E-值，相當於1. 05之（WDR) 至1. 44之 (WDR) ,對應於 1. 71 之（RDR) 至 1. 25 之（RDR) 。 圖4為耐编餵入纱之長度變化百分比（△長度％)對 溫度之圔，其使用〇11?011111161：111&1^^0匕311丨0&141^1丫26-r (TMA)在每分鐘50°C (±0. ιυ)之加速率下並將 預張力（本文亦稱為應力，a,以毎初旦尼爾分之微克數 } 表示）由3mg/旦尼爾變至500mg/旦尼爾而得； 其中，纱在大於約50mg/d預張力下延伸（圖4A— 上半部）且在少於約50mg/d預張力下收縮（圖4B 一下半部）。 在既定張力下相對於溫度之即時長度變化反應，〔（ △長度，％ ) / ( △溫度，t： )〕=〔 △ L / △ T〕，在 收縮條件下稱為\'動態收縮率〃且在延伸狀態下稱a動態 延伸率〃。本發明所用之較佳纱在401C及1 35Ό間於 5mg/d之初張力下收縮，約對應於玻璃化溫度（Tg )及生結晶始點（T〃，d ;且在某些條件下具有小於零 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂_ 太蚯格βm Φ因因犮鸪迆（CMSVP4姐格（210乂297公修） -20 - 200534 A 6 B 6 經濟部屮央標準局员工消费合作社印製 五、發明説明（19 之動態收縮率（即，收縮隨溫度增加且在約40TC及 135t：間初收縮後不具任何直發延伸）。 圖5為耐綸餵入纱TMA動態延伸率，（AL/AT ),對溫度在50至50 0 τη g/d張力下之示圖（詳細 情況參考圖4)。最大動態延伸率，（△L/^T) mu ，在此，取為主結晶之始點且在溫度T/i,*發生。較佳拉 伸溫度少於約T / / ,，。 圖6為最大TMA動態延伸率，（AL/AT) m«x ，對初應力，以毎初旦尼爾分之毫克數表示，之示圖；其 中，（△L/AT)^：^隨漸增應力（σ)增加，其特色 為正斜率，d (△ L / △ T ) mu / d σ。 d (△L/^T) 通常隨漸增之聚合物RV, 及漸增轉速（即，漸減之（RDR) s )而減少。本發明 所用之較佳餵入纱特色為（△L/^T) „»«^值少於約 I 0. 20,較好在約0.15及約0. 05%/υ間，且 d (△ L/△ T ) d σ 值在 3 0 0 m g / d 應力（ σ)下在約3X1 0_4及約7X1 0_4間，其選為發明較 佳纱之特色，因為其為放鬆區（圖2中之锟17及18間 )之般通稱張力。 圖7 (A線）為耐綸餵入纱之長度變化百分比（△長 度％)對溫度（ΐ；)之一般圖，其使用Du Pont Thermal Mechanical Analyser在毎分鐘5 0 ^之固定加熱速率（ + /_0. 1°C)及每初旦尼爾300毫克之定張力下得 到。延伸始點（即，ALSO)在約玻璃化溫度（Tg) (請先閱讀背面之注意事項再填窝本頁) 裝· -5 · 太紙帒尺泞Ιίΐ Ψ @3囷玄摁迆（CNSVP4排.格（210x297公势） -21 - 經濟部屮央標準局员工消费合作杜印製 200534 A 6 ____ B6_ 五、發明説明（2Q 發生且在溫度迅速增加，其相信與氫鍵開始斷裂使 聚合物鏈延伸且晶片移動之溫度有關。 圖7 (B線）為對應於A線之TMA動態延伸率圖， 在此定義為每攝氏度數之瞬間長度變化，（△長度，％) / (△溫度，t：) = (Δί/ΔΤ)，動態延伸率， (△L/ΛΤ),在Tg及Τ//“間相當固定，然後在 溫度增至初最大值，其相信伴有主結晶始點。動態 延伸率在丁 至T / 溫度範圍之較高溫實質保持定值 ,然後在劇增，其伴有結晶熔融及纱軟化始點，至 纱在張力及一般少於熔點（Tm )溫度下斷裂為止；其中 ,T / /,£/少於 T m 4 0 1C。 大部分脂族聚醯胺具有B線之動態延伸率對溫度行為 ，其中，在T//,*之初最大值達之最小值後，動態 延伸率稍減，其就耐綸66聚醯胺而言常稱為Brill溫度 } 且伴有較熱不安定之/3 —結晶構形成為較熱安定之2 —結 晶構形之轉變；就耐綸6聚醯胺而言，T//,〃溫度相信 伴有7 —結晶構形僅經由旋定向而成更安定之2 —結晶形 成之轉換，其為拉伸及/或熱處理纱之典型。 簌格酸染性之較佳經纱拉伸條件發現與拉伸程度（示 為WDR),拉伸溫度（Τβ),放鬆溫度（T«),及 允許放鬆之程度（示為％超餵，％〇F,或為放鬆度，1 一 ％ Ο F / 1 0 0 )之小心平衡有關。此中，較佳範圍為 :WDR在約1. 05X及（RDR) f/1. 25間； 丁 D在2 0 t至少於約T / / , ,較好少於約T / / ,尤 (請先閱讀背面之注意事項再塡寫本頁) 裝- .νφ _ 太Κ ffi Ψ Η 6Η它鸪谁ίCNS)平4規格f 210乂297公婊） -22 - 經濟部屮央標準局負工消費合作社印製 200534 A 6 ___B_6_ 五、發明説明（M 其是少於約T ; T *少於約T (即，τ « - 40t!),較好少於約Τ^, 〃，尤其是少於約Τ^,*。 隨著降低（RDR) 而降低ΤΛ之需求（即，增加 W D R並減少％◦ F )伴隨著結晶間孔隙大小分佈成為較 小值之轉移，其降低染料擴散速率並增加孔隙主要遷移始 點之溫度（在此有關染料轉移溫度，，及最.大動.態 模數溫度（Tnu)。相信存有定義嚴格酸染性之孔隙 大小分佈及孔隙遷移率之組合物。相信此組合物藉適當選 擇餵入纱及發明之經纱拉伸法達成。 圔8為相對結晶率，d x/d t ,對處理溫度之代表 圖。dx/dt值增加，在Tc達最大值，其就耐编66 而言約1 5〇t且就耐綸6而言約146t：。溫度Ti及 T2示相對結晶度x= 1/2之處理溫度。就耐綸66而 言，T2及丁；約丁。+ /— 20Ό。在溫度T/·及 > Tc間，結晶經核化進行且經發現存晶髏在Tc及丁2間 之生長持缠。比較圖8及7,顯示T//, ^及丁^,〃可能對 應於Τ:及Τ2 ;且Τη,*及可能各對應於Τ/" 及Τ 2 •。雖本發現未限於任何特定理論，但相信經纱拉伸 中之較佳放鬆溫度少於約Tc ,即，在就晶體生長為均勻 核化之條件下，尤其是在拉伸纱之（RDR)。減少時。 圖9為放鬆溫度（Τ«, Ό)之倒數，示為10〇〇 / (Τ«+273),對拉伸纱之剩餘拉伸（RDR) D 之圖示。粗線所包括之I (ABDE)及II (AEHI )區表示可用以産生具優越大分子染料勻度级數 (請先閲讀背面之注意事項再填寫本頁) 太蚯帒κ泞消rn Ψ @3囚«:鸩谁Ψ4姐格（210x297公娘） -23 - 經濟部中央標準局貝工消費合作社印製 200534 A6 ___B_6 五、發明説明（23 (LMDR)之纱的方法中拉伸步驟（RDRfl )有關之 拉伸步驟溫度條件（T« )。BCD線對應於室溫（RT ),ΑΜΕ線代表（約9〇1〇) , KLF線對應於 T//,* (約 135t：) , JG線對應於 T//,^ (約 1 75它）且I Η線對應於(耐綸66聚醛胺約 225¾或其他聚醯胺約Τ-4〇·Ό。AKJ I線示下式 :〔1000 / (T«+273)〕& Ki-K2(RDR) β其可再排列産生下式：T*(t：) S〔1 000 / (K, -Κ 2 ( R D R ) c) 〕一273 式中，Kz=1000/ (T/yf273) +1. 25KdK2=〔1 000/ T//,1+273) - 1 0 0 0 / (Ί 11 Z 7 3 )] 〇.3。就大部分耐綸而言，K:及1<：2值各約4. 95 及1. 75。就具較低熔點（T« )之耐编而言，諸如具 有低於耐编6 6均聚物者約4 ◦ C之熔點的耐綸6 , 丁^,1及丁/，，〇值一般低於1^及仄2之不同值（參見 圖18比較高速纺絲耐綸6及耐綸66均聚物之ΤΜΑ曲 線）〇 圖1 0至1 3為顯示如圖6之類似熱轉移之耐綸餵入 纱的代表性熱反應。圖10為動態收縮張力（ST),在 定長條件及3〇1〇/m i η之加熱速率下，對溫度之圖， 其劇增至高於Tg並在達最大值，然後劇減至溫 度，此稱為Τ ίί,Ζ並較缓和地連缠減至Τ / /,Λ及不為 之溫度間，之後更快地減少。TsTma:»:常伴有主要 聚合物鏈遷移始點及後續核化。特佳拉伸溫度（τ〃）一 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂 線. 太《.帒Κ ϋί用Ψ因Η犮找维（CNS) Ψ4規格（210x297公货） -24 - 200534 A 6 B6 經濟部屮央標準局员工消费合作社印製 五、發明説明（23 般在丁8及丁^^間。例中大部分纱在接近丁〃》〃處拉 伸。 圖1 1為藉由701C逐步將溫度增至150t：使用 Lawson-Hemphill TYT測量之典型收縮圖。收縮在約 9 ΟΌ劇增，其類似於使用Du Pont TMA觀察者（參見圖 4)。收縮劇增之溫度伴有溫度Tni。 圖12為動態損失模數（E 〃）之對數，A線，及對 應之Loss Tan Delta對數，B線，對溫度之圖；其中，二 者皆在5 t：/分之加熱速率下使用rheovibron測量。標出 特性熱轉移並與在圖6及10中察得者比較。 圖1 3為以差示掃描熱量計（D S C )測量之熱流變 化對溫度之圖。6 0Ό至2 0 01C之仲介溫度範圍擴大顯 不各為T / /,i，Τ / /，^及丁 / 之熱轉移。此耐编6 6 纱在約2 2 5 1C之熔融吸熱始點發生於T //, ί；且比熔點 i T » 約少 4 0 °C。 圖14及圖1 5為在300mg/d預張力下TMA 動態延伸率對溫度之圖，其各為例IV-3及IV—10 之拉伸經纱；其中例I V — 1 0之纱LMDR>6且例 IV — 3纱之LMDR少於6,其對應於（ΔΙ^/ΛΤ) 對溫度Α及D間溫度之較大變化，尤其是Α及C間（比較 圖1 4與圖1 5 )。 圖1 6及1 7為重要初纺耐綸66纱性質對紡速 (Vs )之圖，但亦發現耐綸6之一般行為。圖16 ( A 線）為初紡耐綸66纱之剩餘拉伸比（RDR) s，示為 太紙後尺冷试Jii中因03定:嫂格（210x297公贷） 一 25 - (請先閲讀背面之注意事項再填寫本頁) 裝- * 200534 A 6 B6 經濟部屮央標準局貝工消費合作社印製 五、發明説明（24 倒數，1/ (RDR) s (其約與分子鐽延伸度成比例且 常稱為纺纱拉伸比）對纺速（Vs )之代表圖，且察得隨 在1 OOOmpiri至約4000nipm範圍增加之纺速 (Vs )線性增加，然後在約4000至約800〇mp m範圍之紡速以降低之速率線性增加。（RDR) s之絶 對值已知随聚合物RV及dp f變化，例如，但圖.1 6 A 線之重點為在約4000mprri之（RDR) s行為變化 。高於約400〇mPm,通常不需熱/機械安定化以提 供安定纱包裝。低於約40〇0mpm，初纺纱必需再安 定化以提供可用於經纱拉伸之纱包（見圖1之討論）。 圖16 (B線）中，密度（p)隨漸增之纺速增加且 高於約4000mpm增加更快。發現紡纱之 (RDR) s少於約2. 75之餓入纱，對應 1/ (RDR) s值大於約0. 364,利於經纱拉伸。 .1 圖16非單獨顯示少於約2. 75之（RDR) S值之需 求的原因。 圖17 (A線）為未老化超過24小時之紡纱沸溶後 長度變化對紡速之代表圔。紡纱在沸水中伸長達約 2〇〇0mpm (I區）。紡纱在沸水中伸長約2000 及約4000mpm間，但對纺速具較少程度（I I區） 。初紡纱在沸水中收縮，高約4000mpm (I I I區 )〇 圖17 (B線）中，此種纱之對應雙折射值對纺速晝 圖。察得在約20〇0mpm紡速之雙折射增加速率之減 (請先閱讀背面之注意事項再填寫本頁} 裝- 線· 太址得K泞Ψ因Η定媿摧（CNS) 頫栘（210x297公 -26 - 200534 A 6 B6 經濟部屮央標準局貝工消t合作社印製 五、發明説明（2$ 低，相信伴有I區及II區行為間之轉變且歸因於纺線上 應力誘致核化之始點。I及II區之轉變約對應於少於約 2. 75之初纺纱（RDR) s。具I區所示之初纺纱性 之餵入纱不能 ''乾燥〃拉伸産生大於6之LMDR。用於 本發明之纱為II及III區且較好為III區者，因察 得I I I區之纱在整理劑施用時染料程度（MB BJ對纱 上濕度具極撤靈敏度且‘其纱性在儲存時對時間更安定。 圖18為各種餵入纱型在30〇mg/d張力下動態 延伸率（AL/AT)對溫度之TMA圖：A=通稱 50RV耐编66纱，其在530〇mpm纺絲且含5% Me5_6 ; B=耐綸66均聚物纱，其在 5300mpm纺絲（例I之纱J) ;C=耐綸共聚物纱 ，其在530〇mprri纺絲（例I之K纱）；D =耐綸部 分拉伸纱（表示例I之D — F纱）；E=通稱47RV耐 编6均聚物纱，其在53〇〇mpm紡絲。耐綸6餵入纱 對耐编66餵入纱移動約20 — 30 °C至較低溫，其相對 於耐綸6 6均聚物者將耐綸6之最大放鬆溫度（Ts) 降低約20 — 3〇1〇。 圖19為不同纱型在5mg/d張力下收縮（△長度 ,%)對溫度之TMA圖。大部分餵入纱隨漸增溫度尤其 是401C及135Ί0間而收縮；但是，A纱先伸長且僅在 高於約150¾之溫度收縮。A纱非較佳纱，因其不收縮 ，但在40及135t：間延伸（即，ALSO);亦因其 特色為正長度變化率，此稱為、、正動態收縮率〃（即， (請先閲讀背面之注意事項再填寫本頁) 裝· 訂- >線· -27 - 經濟部屮央標準局貝工消费合作社印製 200534 A 6 _B6_ 五、發明説明（2Θ △ L/ AT>0) ，C)。經纱拉伸用之較佳餵入纱在 40¾及1 35t：溫度範圍具免動態長度變化及負動態收 縮率。 圔20為拉伸應力（σ/β )，以每拉伸旦尼爾分之克 數表示，在20Ό, 751C, 125t：及175*0對拉伸 比之代表圖。拉伸應力（σ。）高於屈服點時隨拉伸比線 性增加且斜率在此稱為拉伸模數（Μβ )且定義為（ △ σ /ADR)。拉伸應力（σ« )及拉伸模數（Μ〇 )之值隨漸增之拉伸溫度（Τβ )減少。 圖2 1在751C就各種餵入纱比較對拉伸比（DR) 之拉伸應力（σβ) (Α =在5300mpm纺絲之通稱 65RV耐綸66均聚物；B=在53〇0mpm纺絲之 通稱68RV耐綸6, 66共聚物；C=在約 3300mpm纺絲之通稱40RV耐綸66均聚物）。 期望之拉伸應力（σβ )及拉伸模數（Μΰ )程度可藉選 擇餵入纱種類及拉伸溫度（TD )控制。較佳拉伸經纱餵 入纱具有約1. ◦及約2. Og/d之拉伸應力（σζ^) ，及約3及約7 g / d間之拉伸模數（M )，在7 5 °C 及1 · 3 5拉伸比（D R)測置，取自拉伸應力（σ ) 對拉伸比之圖。 圖22為圖2 1中之種纱拉伸模數對數；1 η (Μβ )，對〔1000 / (Tfl , C + 273)〕之代表圖。 圖2 2中線性關像之斜率取為表觀拉伸能量（ΕζΟ λ,假 設Md對溫度為Arrhenins型依存性（即，Mr> = Aexp ( (請先閲讀背面之注意事項再填寫本頁) 太汴R /ί ίί Ιίΐ Ψ因Η宅拽雄iCNS)甲4組格ί 210 X 297公对) -28 - A 6 B 6 200534 五、發明説明（ E zp /RT)，其中T為Kelvin度數之溫度，R為普通 氣體常數，且'' A "為材料常數）。較佳拉伸經纱餓入纱 之表觀拉伸能量（EzO 4〔=E〇/R=^(lnMD ) /△ (1 〇00/Τζ> ),其中 Τΰ gKelvin 度數〕在約 ◦ · 2 及 0 . 6 ( g / d ) / ° k 間。 以下實施例進一步說明本發明但不構成限制。_纱性質. 及方法變數依以下試驗法測量。份數及百分比為重量，除 非另有陳述。 試驗法 聚醯胺之相對粘彦（RV)測量述於c〇l. 2,1. 42-51，在 Jennings U.S. Patent No . 4.702.875〇 妙之日尼爾依 ASTM Designat ion D-1907-80測畺。 旦尼爾可藉自動裁稱裝置測量，諸如Goodrich等人述於 U. S. P4, 084, 434 者。 張力性質(韌度，模數及斷裂伸長度）測量述於L i 之U. S. P.4, 521,484之第2橱1. 61至 第3稱1 . 6。模數（M).常稱為初樽數〃，得自負 荷伸長度曲線之第一合理直線部分，張力繪於y軸相對地 伸張度繪出X _軸〇在59^钲伸夕正割椹教（M5)穿義 為（韌度/. 05) X100之比例，其中靱度在5%延 伸處測量。 藉非接觸法使用紅外線顯微鏡及Zieminski and Spruiell， J· Αρρ1. Polymer Science， (請先閲讀背面之注意事項再填窝本頁) 裝- -V* _ 經濟部屮央橾準局貝工消费合作社印製 太认张 R/Ϋίί Ιίΐ Ψ 因 H 甲4扭格（210x297公帑） _ 29 - 經濟部屮央標準局貝工消費合作社印製 200534 A6 _B_6__ 五、發明説明（2β 35, 2223，2245 (1988)及 Bheda and Spruiellt J. Appl. Polymer Science 39» 447 一 463 (1 990)所述之方法測量。此述之設備溫度 ，例如，锟，等，使用標準熱偶測量。 沸溶收縮(B ◦ S )。以下放鬆絞纱法用於本案所述 之餵入纱並測量浸於沸水時以絞纱原長百分比表示之長度 變化。絞纱製於周邊為1一1/8公尺之標準旦尼爾軸上 。軸轉速由用以測量絞纱長之重量決定。重應如下： <30旦尼爾——100g ; 30— 1 00 旦尼爾--25〇g ; >100旦尼爾——500g。 轉速為産生5 5m s/旦尼爾之負荷所需且由下式計 算： R=1000W/2LD 式中R=最接近之整數之轉數； W =重量克數； D =旦尼爾； L=負荷=5 5mg/旦尼爾。 絞纱藉掛於鈎上並加上砝碼拉直。絞纱長度測至最近 之1mm並記為L 1。絞纱捲於乾酪包布巾並置於98 士 (請先閱讀背面之注意事項再填寫本頁) 裝- 訂 -線. 太従從Ηm Ψ因S3亥鸪迆（CNSW4覘柊（210乂297公处） -30 - A6 B6 200534 五、發明説明（29200534 A 6 B6 Printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs V. Description of the invention (1) Background of the invention The present invention relates to an improved continuous silk yarn nylon apparel yarn, and in particular, it has a broad warp method for manufacturing nylon flat yarn And improved yarn made by him. Nylon flat yarn is used in various woven or warp knitted fabrics dyed before use. When using small molecule dyes for such fabrics, they can usually be dyed uniformly without much difficulty. However, for certain strict dye applications such as swimwear or automatic home textiles, which require superior washing and / or light fastness, it is desirable to use macromolecular acid dyes. When dyeing such fabrics with macromolecular acid dyes, even if there is a small amount of unevenness in the dye intake of the plain yarn, the dyeing of the fabrics can cause highly visible unevenness and poor fabric appearance due to it. Knit-resistant flat yarns usually have an elongation at break of less than 60% and can therefore be referred to as a finished yarn. In general, it is known that the high orientation of flat yarns is caused by the overall spinning and drawing method (the speed of unwinding from the spinning board is between about 1400 and 2000 meters per minute (mpm) and the winding speed is between about 2500 and 3500mpm) or split The film-to-cloth method (in which the yarn package spun at an unwinding speed of generally less than 100 mpm is drawn by a single yarn drawing winder in a separate method) is applied during yarn production. However, it is often found that the yarns produced are often not suitable for strict dyeing applications such as swimwear or automatic home furniture, because special care must be taken in the preparation of the yarn and in the preparation and dyeing of the formed fabric to obtain acceptable dyeing uniformity. There are already commercially available equipments for stretching nylon warp yarns in a hot water bath. However, although the method of using this equipment can increase the dyeing uniformity, the equipment does have several inherent advantages. The method of using this equipment is cumbersome and a waste stream of contaminated water is generated because the yarn finishing agent moves into the water during drawing. Moreover, when the yarn is used for knitting, (please read the precautions on the back before filling in this page). Threading · Taiyin κ 疳 iA m ΦDue to house drag rn f CNS) Ψ 4 极 格 ί 210 y 297 cm ) -3-200534 A6 _B_6 printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Description of the invention (2) The finishing agent must be applied after stretching. Another serious disadvantage of commercially available wet drawing equipment is that the process speed is generally limited to about 300-350 mpm, due to the limited ability of the equipment to dry the yarn before winding. According to the invention, the invention puts forward the yarn for flat and entangled filament nylon clothing (to be applied in the dyeing process) and the preparation method of this yarn. The yarn preparation method includes: spinning a nylon polymer having a relative viscosity (RV) of between about 35 and about 80, spinning to form a sufficient drawdown ratio (RDR) s less than about 2.75 for spinning back Winding speed (Vs); Stabilize, interweave, and apply finishing agent to the spinning to form a residual draw ratio (RDR) ^ • Feed yarn at about 1.55 and about 2.25, feed yarn dynamics Length change (^ L) and shrinkage rate (ΔΙ ^ / ΔT), which are less than 0 between 401C and 1 351C; ί dry stretching and implement drying to relax the warp yarn to form a stretched warp yarn, dry stretching At a warp yarn draw ratio (WRD) of about 1.05 and about (RDR) F / l.25 and a temperature T of about 20¾ and about the polyamide polymer / yarn draw temperature (D) between , The stretching and feeding of the warp yarns are dried and relaxed at about 20 ° C and the melting temperature (T «) of the melting point (T«) of the polyamide polymer is less than about 40.1C, the relaxation temperature Another definition is by the following formula: T «(° C [1000 / (Ki-K2 (RDR) fl)] -273 (please read the precautions on the back before filling in this page). Binding. Thread. Too". 后 Κ iA m Ψ Η Η «: 揁 雄 （CNS) Ψ4 姐 格 （210x2 97 public goods) 200534 A 6 B6 Printed by the Employees ’Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs V. Description of the invention (3) The temperature is determined by measuring the change in the length of the temperature under a fixed tension as described in more detail below. Dry drawing Stretching and drying relaxation is to make the boil-off shrinkage (BOS) of the drawn warp yarns between about 3% and about 10% and the remaining draw ratio (RDR) /> between about 1.2 5 and about 1.8 Carrying out Ο As for the feeding yarn of nylon 66 polymer, the preferred temperature range of the residual draw ratio (RDR) d of the given drawn yarn can be specified in the above formula K; the value is 4.95 and is 1. 75. In terms of nylon 6 polymer, K 5.35 and 2 1.95 are appropriate values for obtaining a better temperature range. According to a better method, the unwinding rate in spinning is so high that The residual draw ratio of the spinning yarn is less than about 2.5. In another preferred form of the invention, the spinning rate of the as-spun yarn is such that the residual draw ratio is less than 2.2. 5. Generally, with this residual draw ratio The spinning has a dynamic length change (AL) and shrinkage (AL / ΔT) of less than 0 between 40 ^ and 1 351C. Therefore, high-speed spinning is used to stabilize the spinning without adding a stabilizer, but The nascent yarn can be used as the feed yarn. According to another preferred method of the invention, spinning and stabilization can be performed so that the remaining draw ratio of the feed yarn is between about 2.0 and about 1.55. Preferably, the procedure To provide a feeding invention method having a tensile tension (DT33%) of less than about 1.4 g / d, more preferably less than about 1.2 g / d, especially less than about 1 g / d, using feeding warp yarns Dry stretch and dry relaxation. It is better to dry and stretch and relax in an inert atmosphere, for example, air, about (please read the precautions on the back before filling out this page) fire recognition cut κ / ί 1Λ m 中 because a mysterious ift (CNS) Ψ4 助^ 210x297 Gong. Correction-5-Printed by the Beigongxiaot Cooperative of the Central Bureau of Standards of the Ministry of Economy 200534 A6 ___B_6 V. Description of the invention (4) 50¾ to about 90% relative humidity (RH), better, about 60% to about 8 Completed in 0% R Η. When drying and relaxing, use a temperature less than about T //, **, especially less than T 〃〃. The better conditions during relaxation result in a boil-off shrinkage (BOS) of about 3% and about 8% of the drawn warp yarns and a residual draw ratio (RDR) of the drawn warp yarns between about 1.2 5 and about 1.55 ) ζ »〇_ The inventive method can be used for most nylon polymers. Preferred nylon polymer contains nylon 66 polymer and nylon 6 polymer. The preferred knit-resistant 66 polymer contains a small amount of a bifunctional polyamide comonomer or a non-reactive additive that can hydrogen bond with the nylon 66 polymer. The inventive method provides highly uniform knitting resistant yarns that can be used in a variety of warp-knitted or woven fabrics that must be dyed uniformly by macromolecular dyes. The yarn made by the preferred method of the invention is particularly suitable for this purpose and has a macromolecular dye average degree (L M D R) of at least about 6. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a diagram of an apparatus that can be used to manufacture a yarn feeder according to the method of the present invention; FIG. 2 is a diagram of a general commercially available drawing-in equipment that can be used in the method of the present invention; FIG. 3 is a drawing tension (DT) The general graph (Line A) and the corresponding graph of the tensile tension variation along the end (DTV) at room temperature to the stretching ratio (DR), percentage elongation (E) and residual stretching ratio (RDR) ^ (Line B). Figure 4 is a graph of the percentage change in length (△ length%) of nylon feed yarn versus temperature. It uses Dupont Thermal Mechanical Analy- (please read the precautions on the back and then fill out this page) too ". 张 κ 疳 ii m Ψ 团 η Ai Chou (CNS) V 4 group m 0 X 297 gong) -6-200534 A6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economy V. Description of invention (5) ser in every minute 5 0 1C fixed heating rate and change the initial pre-tension from 3mg / denier to 500mg / denier; wherein, the yarn extends under a tension greater than about 50mg / d (Figure 4A-upper half) and Shrink under tension of less than about 50mg / d (Figure 4B-lower half). Figure 5 shows the dynamic elongation of nylon feed yarn under a pretension of 50 to 500mg / d, (AL / AT), a graph of temperature, which is obtained at a heating rate of 50 minutes per minute using D u ρ ο nt T herma 1 M echanica 1 A na 1 yser; where, the maximum dynamic elongation; (△ L / ΛΤ ), Here, taken as the starting point of the main crystallization and occurs at Τ / h * temperature (ie, for most nylon yarns about 1 10-1 4 0 Ό) 圔 6 is the dynamic elongation (△ L / △ T) plot of pre-tension stress (σ) (as shown in Figure 5); where the slope, at 300mg / d of d (AL / ΔΤ), is used to change the stress standard (ie, change over Feed%) The silkworm sensitivity of the warp yarn drawn during the relaxation step is measured. Fig. 7 is a general graph of the change in length of the knitted yarn (△ length,%) versus temperature (line A), which is obtained using a pre-tension of Du Pont Thermal Mechanical Analyser at 30 ◦ mg / d; and corresponding Dynamic elongation graph (line B), which is defined as the instantaneous length change (△ length%) of each degree Celsius of line A (△ length%) (△ temperature, * C). Figure 8 is a graph of relative crystallization ratio, dx / dt, to the treatment temperature; where the dx / dt value increases and reaches the maximum value at Tc. (Please read the precautions on the back before filling in this page) Install-,? τ. Line. Too Κ 泞 iA Ψ H ra «: ^ miCNSVH4M; tM2U) y297 公;« ·) -7-200534 A 6 B6 Ministry of Economic Affairs Printed by the Central Bureau of Standards' Staff Consumer Cooperative V. Description of the invention (6) Figure 9 is the reciprocal of the relaxation temperature (T «, Ί0), expressed as 100 / (丁 《+ 2 7 3）. Graphical representation of residual draw ratio (RDR). The areas I (ABDE) and II (AEHI) framed by the thick line indicate the temperature conditions (T «) that can be used to generate relaxation steps with superior macromolecular dye average degree (LMDR) relative to the drawing step of the method. Figure 10 For dynamic shrinkage tension (ST), under a fixed length of heating rate of 3010 / min, the temperature graph suddenly increases at a temperature higher than T * and reaches a maximum value at T. Figure 11 is a general graph of the dry heat shrinkage measured by Lawson-Hemphill TYT from 70 °: gradually increased to 150P. Figure 12 is a general diagram of the dynamic loss coefficient (E logarithmic value vs. temperature (line A) and the corresponding Tan Delta logarithm vs. temperature (line B)).} Figure 13 is the heat flux change measured by the differential scanning calorimeter vs. temperature General diagram. The increase of the intervention in the temperature range of 601C to 200 / C shows the three-value heat transfer caused by T / /, i, T / and T / /, **. Figure 1 4 and 15 are the pull A general plot of the dynamic elongation of the warp yarn TMA versus temperature; where Figure 14 has an LMDR of less than 6 and Figure 15 has an LMDR of greater than 6. Figure 16 shows the residual draw ratio of the nascent knitting resistant yarn 6 (RDR) s , Represented by its reciprocal, 1 / (RDR) s, (A line) and density (B line) vs. spinning rate. Figure 17 is the change in length (A line) and birefringence of new primary yarn after boiling (Please read the precautions on the back before filling out this page) Packing-booking · thread · too ii m Ψ 團 S3 It's 1¾ piles (CHS 1 Ψ4 姐 格 ί210 乂 297 Gong-8-200534 A6 B6 Ministry of Economics, Central Standards Bureau Printed by the employee consumer cooperative 5. Description of the invention (7) (line B) vs. spinning speed. Figure 18 shows the various spinning orientations and partially stretched yarns used in the example for threading at 30 Om g / g Dynamic elongation rate (△ L / ΔΤ) vs. temperature TMA graph under force. Figure 19 is a graph of the shrinkage (△ length%) of various yarn types under 5mg / d tension versus temperature ΤΜΑ. Figure 20 is Tensile stress (σΰ), expressed in grams per denier, for a drawing with a draw ratio of 751012 5 =, and 175 * 0; where the slope is called the tensile modulus (M〇) and It is defined as (△ az ^ / ADR). Figure 2 1 compares the tensile stress (σ〇) to the draw ratio (DR) of various feed yarns under 7 5Ό. 圔 22 is the stretch of the feed yarn in FIG. 21 Modulus logarithm value, In (MD), the graph of [1000 / (T〇, t: + 273)] ί; which takes the slope to measure the tensile energy (Ε.). 圔 2 3 — 3 2 is available The computer simulation of the LMDR standard fabric strip that determines the yarn produced in the examples of this case. The nylon polymer used in Nuoshu in this case is any general straight-chain, aliphatic polymer that can be melt-spun into suitable properties for fabric applications. Aldehyde homopolymers and copolymers. Preferred nylon polymers are poly (hexamethylene diamine) (Nylon 66) and poly (ε-caprolactam) (Nylon 6). Nylon polymer When spinning Relative viscosity (RV) between about 3 5 and about 80. (Please read the precautions on the back before filling in this page) Pack. Line. Too paper β 泞 iAffl Φ due to 03¾: 摁 m (CNS) sister grid〗 210 to 297 public goods) -9 Printed by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 200534 A6 _B6 V. Description of the invention (8) When using nylon 66 polymer, the RV of the polymer is preferably greater than about 46, such as U.S. Patent Application No. 33, 059 (U.S. Patent No. 4,583,357) is taught, and the disclosure is hereby incorporated by reference. However, the RV should usually be less than about 65, because the advantages obtained by re-applying for patent 33, 059 cannot be significantly increased when the RV is higher than 65. Moreover, when spinning nylon 66, it is preferred to use a small amount of copolymer units such as ε_caprolactam or hexamethylene diamyl 2-methyl-pentamethylene diamine (Me 5 -6) or hydrogen bond with nylon 66 Knot of reactive additives. For the given spinning conditions for yarn feeding and spinning, this increases the elongation at break, and for the predetermined elongation at break, reduces the tensile tension that facilitates drawing during the program drawing-in step. Because of the ability to obtain the same feed yarn properties with polymers with low RT, especially at high spinning speeds, the use of 2-methyl-pentanediamine provides hexamethylene diamide 2_ in the knitting resistant polymer 6_ Methyl-pentylenediamine units are particularly preferred. Using Me5-6, 66 copolymer to feed the yarn in the warp-through method, the tensile tension is reduced at the same draw ratio, and the mechanical properties of the drawn yarn should be improved. As the amount of Me 5-6 increases, the dye depth increases. This shows that the dyeing rate increases with the increase in the amount of Me 5-6 or the structure is more open, which is generally indicated by the improved dyeing uniformity. The shrinkage of the stretched yarn increases with the increase of the amount of Me 5-6, to the extent of 20% Me5_6> 10% B〇S. This degree is difficult to obtain with knitting resistance 66 at a draw ratio that produces good mechanical properties. Or, if necessary, the heterobranched agent shown in US Patent 4, 72 1, 65 may be used. As known in the art, opacifiers such as titanium dioxide, colorants, anti-chlorine agents and other useful additives can be incorporated into the polymer. Bifunctional copolymer polyamide with hydrogen bond with nylon 6 6 polymer (please read the precautions on the back before filling in this page) Pack · * lr · 10 ™ 200534 A 6 B6 Negative work of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the consumer cooperative V. Description of the invention (9) Polyester nylon 6 6 can be prepared by polycondensation in an aqueous solution containing appropriate proportions of monomers and salts. The method that can be used for the production of homopolymerized knitting 66 can be applied to the production of N6, 66, adding e-caprolactam to the salt solution. In order to produce Me5-6, 66, the copolymer with a desired weight ratio of adipic acid 2-methyl-pentylenediamine, adipic acid and hexamethylenediamine (HMD) and 2 at the required pod ratio -Methyl-pentanediamine (HPMD) is used to make salt solution. However, as far as Me5_6, 66 is concerned, it is usually necessary to change the method of general nylon 66 to determine MPMP, which is more volatile and stays in the solution for a sufficient time to react. 2—Methyl-pentylenediamine is commercially available from EI du Pont de Nemours & Co., Wilmington, Delaware, with the trademark DYTEK AR 0. Refer to FIG. 1, whose description includes the method of manufacturing a substitute for feeding yarn, and the use of yarn γ The high-speed melt spinning method is spun from the spinneret 1. The filaments are used in a quenching process, for example, AC wind cooling at 201C, and are collected in a finishing agent applicator such as a stick or measuring finishing applicator. According to the method of the present invention, the unwinding speed (Vs), that is, the first roller used to pull the yarn away from the spinneret 1, is sufficient to form a " residual draw ratio " (RDR) s less than about 2.75 Of spinning. As explained below, the first stick can be any of a variety of different sticks depending on the specific equipment used. The "a residual draw ratio" used in this patent application means that the length of the yarn can be increased several times by stretching before the yarn breaks and can be calculated from the elongation at break by the following formula: RDD-1 + (Eb / 100) (Please read the precautions on the back before filling in this page) Packing. Ordering · Taiji Zhang R 疳 iA ffl Ψ 焷 囷 玄 覤 (CNS) Ψ4 code grid (210X297 public pairs) 11 — 200534 A 6 B6 Ministry of Economic Affairs Printed by the Central Standards Bureau employee consumer cooperative. V. Invention description (1 () It has been found that the remaining draw ratio (RDR) S must be less than 2.75 in spinning and combined with other procedural steps of the method to obtain a drawn warp yarn Improved macromolecular dye uniformity. Preferably, the remaining draw ratio in spinning is less than about 2.5, and most preferably less than about 2. 25. The remaining draw ratio of less than 2.7 5 is given to the spinning back The winding speed depends on various factors in the spinning method including the fineness of the spun yarn (denier per filament), the relative viscosity of the polymer, the spinning temperature, the capillary size of the spinneret, and the method of quenching air flow, The flow rate, and the quenching efficiency determined by the temperature of the quenching air. Generally, the minimum unwinding of the residual draw ratio (RDR) s is less than 2 · 7 5. For normal weaving yarns, the degree is about 2000 mpm. Generally, it is better to spin the feed yarn at an unwinding rate higher than about 3000 mpm, and it is not necessary to carefully control the program conditions. In the invention method, the spinning yarn is stabilized to Provide residual stretch ratio of 1.55 and about 2.25 and dynamic length change (AL) and shrinkage) (△ L / △ T) between 4 ° C and 1 3 5 C are less than ◦. Preferably, the feed yarn has a residual draw ratio (RDR) between about 1.55 and about 2.0. As shown by the dotted line in FIG. 1, stabilization can be accomplished by a variety of different usages. Stabilization can be done by exposing the spinning yarn to U.S. as shown in the alternative method A. Patent 3, 9 9 4, 1 2 1 steam in the steam chamber or passing the yarn through US 4, 181, 697 It is completed without steam, heating the tube. Then the yarn warp puller and long sticks are placed, 5 and 6, individually, although they are not substantially stretched. Alternative usage B shows a set of extractors and long rollers 5 and 6, which are driven at the speed that is actually used for curling, so between these sticks and winding up (please read the precautions on the back before writing this page)- Installed Litai earth chrome K Wen iA Ιίΐ Ψ 团团 尥 尥 mi CNS) Ψ 4 spot grid m 0 X 297 public goods) -12-Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 200534 A6 _B6 V. Description of invention (I》 No substantial stretching. Stabilization is given by high spinning speed as shown in Alternative C. For example, greater than about 40,000mpm. Rolls 5 and 6 can be heated (if necessary) to stabilize the yarn shrinkage, if low Spin at a rate of about 40,000mpm. Alternative method C is a non-guide roller, " method, in which the yarn does not contact the stick between the spinning plate and the take-up stick. The take-up speed is sufficient for spinning The spinning orientation of the yarn provides stable feeding without the need for other individual stabilization steps. The speed at which this is generally completed is higher than about 4000 mpm. The yarns made by alternative methods B and C are called spinning orientation or a S Ο Y 〃 Yarn. Alternative usage D explains the use of a part of the stretching " to stabilize the yarn. Before putting the long stick 6, feed the stick 7 and the stretching stick 8 fully Yarn drawing is stabilized. The amount of drawing required to accomplish this depends on the yarn orientation from the spinning speed and conditions between about 1.05 and about 1.8. The yarn produced by the alternative method D is often called partial drawing Stretch 〃 or w PDY 〃 yarn. The described changes in the stability of the alternative method are possible in the method of the present invention. The yarn is interwoven in the interweaving nozzle 9 so that the feeding yarn is sufficiently interwoven to be able to take 10 effective reels Take the feed yarn and remove the feed yarn from the draw-through tube. The appropriate interlace degree of this is measured by the rapid stitch number method (RPC), which is an RPC interlace of not more than about 14. Although it can be used such as after warping '' Entanglement 〃 is increased for further processing as desired or used for fabric formation. High interweaving in the feed yarn is required to eliminate this extra interweaving. Therefore, the interweave degree in some preferred feed yarns should be as high as It is enough to get the desired amount of interweaving extending between the interweaving knots after threading. The precise interweaving amount required by this person usually depends on the number of filaments and dgf, the type of yarn finishing agent, and the stretching ratio and tensile tension applied by the yarn And the desired properties of the final fabric containing stretched yarns, which are particularly aesthetically pleasing. For many feed yarns It is better to use RPC interlaced between about 6 and about 10. Tai > k Yin Guohong finds a good (CNSPfM 揋 格 (210x297 public goods) _ 13-(please read the precautions on the back before filling out this page) . 200534 A 6 B6 Printed by the Beigong Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs. 5. Description of the invention A package of substantially uniform length, which can be provided by a centralized rack to form warp yarns. Inventive method, feeding warp yarns for dry drawing and dry laying to provide stretched warp yarns. In this case, A dry 〃stretch and > drying " Relaxation means that stretching and relaxation are done in a gas environment without applying liquid water to the yarn. According to the invention, the preferred atmosphere for dry pulling and dry placing is an inert atmosphere such as a relative humidity between 50 and 90%, preferably a space between 6◦ and 80%. Dry drawing and dry discharging can be accomplished in the presence of other inert gases such as steam, which can provide a heat source and an inert gas atmosphere. The warp yarn is stretched at a warp yarn draw ratio (W D R) between about 1.05 and about (RDR) f / 1.25. In this case > the warp yarn draw ratio 〃 can be calculated from a total draw ratio 〃, which is defined as the remaining draw ratio of the fed yarn (RDR) ^ • the remaining draw ratio of the drawn yarn made by this method ( RDR) ΰ ratio, that is, after it is relaxed: TWDR- (RDR) f / (RDR). The total warp yarn draw ratio is related to the warp yarn draw ratio shown in the following formula: TWDR-WDR (1- % 0F / 100) (% 〇F means overfeed as detailed below.) The warp draw ratio (WDR) can also be calculated from the change in the length of the yarn, for example, the ratio of the rate of stretching rod to feeding rod. Similarly, the total warp draw ratio (TWDR) can be relaxed (please read the precautions on the back and then fill out this page). Installation · 200534 A 6 B6 Printed by Beigong Consumer Cooperative, Bureau of Standards, Ministry of Economic Affairs Explanation (1 calculation of the speed of the feeding stick to the stick. The yarn temperature (τβ) during stretching is between about 20 and about the polymer. As shown in Figure 7 and the following appendix, and the test method, Ding Wei The temperature of the nylon polymer defined by measuring the length of the yarn at a fixed tension to the temperature change. The heating of dry stretching is beneficial to reduce the tensile tension in the inventive process. Preferably, the temperature of the yarn during stretching is preferably less than about Τζ / , ι. For nylon 66 and nylon 66 with a small amount of hydrogen bonding, the yarn drawing temperature can reach about 175¾. Preferably, the temperature is about 20 ° and about 135Ί0, the best, at about 20t: and About 90Ό. For nylon 6, the stretching temperature should usually be about 20-40C lower than the corresponding temperature of nylon 66. Non-contact or contact heating devices such as ovens, radiant heaters, plate heaters, hot sticks , Etc. are suitable for heating the yarn during drawing. The yarn undergoes a heat relaxation step to control the heat-soluble shrinkage and relaxation also causes the yarn to be drawn The residual draw ratio (RDR />) is significantly increased. Select the draw ratio of the warp yarn in dry drawing (WDR) and the conditions during dry relaxation to make the drawn warp yarn have a boiling point between about 3% and about 10% Solution shrinkage (BOS) and residual draw ratio (RDR) D between about 1.25 and about 1.8. Preferably, the boiling solution shrinkage is between about 3 and about 8% and the remaining draw ratio of the drawn yarn ( RDR) β is between about 1.2 5 and about 1.5 5. In addition, the warp yarn stretching and relaxation of the present invention can adjust the yarn properties desired for other end uses. The invention can provide a range of elongation at break and other expectations Properties while maintaining uniformity in the yarn, which can produce dyed fabrics with good yarn uniformity. Preferably, the tensile warp yarns have a degree of higher than about 2g / d and can be about 6g / d or higher. The number standard is higher than about 15 g / d and can reach about 40g / d or higher. Tailuam Ψ Because a macro find specifications (210x297 public goods) -15-(Please read the precautions on the back before filling this page) Packing. Thread-line · Printed by the Consumer Labor Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs 200534 A 6 __B_6 V. Description of the invention (1% of overfeed in the relaxation step of this method, that is, the length of the contraction The amount of change must be selected to obtain the desired properties. The overfeed% can be set by adjusting the speed of the stick in contact with the yarn before and after relaxation and the shrinkage usually decreases with increasing overfeed. According to the contraction step and desired, the stretched yarn Depending on the nature of the yarn orientation, the overfeed can be very small and can be about 10%. Preferably, the overfeed% is between about 2 and about 8%. Although the overfeed% can vary in this range, it is specifically hungry. For yarn, the overfeed percentage should not be too high, and the relaxation temperature or yarn tension of the yarn in the relaxation step drops to zero and the procedure cannot be carried out. If entanglement is used to give extra cross iron to the yarn, it is also important to properly control the overfeed, because Lower relaxation tension produces tighter tangles. When using tangles, the overfeed should be adjusted to produce 0.25 to ◦ · 50 grams / stretch denier (g / dd) or preferably 0.30 to 0.375g / dd relaxation zone tension. When the tension in the relaxation zone is lower than ~ 0.25g / dd, the entanglement operability is poor. In the invention method, the yarn temperature (T «) during relaxation must be between about 20 ° C and 401 ° C lower than the melting point (T«.) Of the nylon polymer. As in the stretching step of the procedure, non-contact or contact heating devices such as roasting lumens, radiant heaters, plate heaters, hot sticks are suitable for heating the yarn when relaxed. It has been found that controlling the temperature of the drawn yarn (T «) in a specific relationship to the remaining draw ratio of the drawn yarn (RDRz >) can provide a high degree of dyeing uniformity of the macromolecular dye molecules. According to the invention, choose the relaxation temperature (T «) according to the following relationship: [1000 / (Ki-K2 (RDR) 〇)) -273 (please read the precautions on the back before filling in this page) Taiji R / iifi m Ψ Due to the mysterious bust (CNS) Ψ4 report (210 >: 297 public loan) -16-200534 A 6 B6 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Invention description (13 Type Κι: 100 (^ ( 1 ^ /, 1 + 273) + 1.251 (2 and K2 = [1000 / (T7 /, ζ. + 273) -1000 (Τ //, ** + 273)) /0.3, better, less yarn relaxation temperature Because, it is better to be less than Τ «, Τ7 /, μ and Tw, * determined on the nylon polymer feeding. It is used to illustrate Figure 7 and accompanying text and the following test method. In terms of yarn entry, the preferred relaxation temperature range of the remaining draw ratio (RDR) σ of the given drawn yarn can be obtained by specifying Ki as 4.95 and Κ2 as 1.75 in the above formula. The preferred relaxation temperature is less At about 175¾ and, preferably, less than about 135 * 0, for nylon 66 with resistance to braid 66 or with a hydrogen bonding component, for nylon 6, the preferred temperature range is specified separately K2 is defined as 5.35 and K2 as 1.95. In general, the better temperature of nylon 6 yarn corresponds to nylon 66 low temperature; 2 0-4 Ο Ό 〇 found that the commercially available equipment is suitable for feeding through the appropriate feed yarn according to the invention. Type DSS Τ 5 0 It is made from 1 (31 '1 elbow 3_761' 6 6 111111350 ^ 11611 £ 31) -rik GmbH, D-6053 Obertshausen, Germany. And type S TF FI, manufactured by Barmag Akt iengesel lshaft »5630 Remsch-eid, Germany are suitable and the use of both is described in the following example. The winding speed is in the range of about 600mpm. Because the equipment is similar, only Barmag STF1 is shown in Figure 2. Referring to Figure 2, the warp piece (indicated by the symbol W) of the feeding yarn is fed by feeding 1 1_1 3 by The left-side concentration rack (not shown) is pulled out. The feeding stick can be heated (please read the precautions on the back before filling the nest page). Packing and ordering _ 太 纸 帒 渞 1¾ m 屮 IMCNS due to disaster) (210 to 297 public goods) -17-Printed by the Staff Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs 200534 A 6 _B_6 V. Description of the invention (19 and generally heated to a temperature between about 50 and about 9 OC. This unit has a slope Plate heater and further heat the yarn if necessary. Then the warp yarn W is sent to the unheated drawing roller 14-17. Stretching sticks 14 and 15-17 are driven at a speed greater than the feeding stick to give the warp yarn the desired amount of stretching. After passing through the stretching rod 17, the yarn relaxes when passing through the warp yarn which is contacted with the plate heater f having the ability to heat up to about 20,000. The amount of relaxation is controlled by the lead-out rollers 18-20, which is driven at a speed less than the draw rollers 14-17 to provide the required overfeed. The formed yarn is bundled and taken up at the bundle winder (not shown). As far as the equipment shown in Figure 2 is concerned, the warp yarn piece fed into the yarn is stretched between the rollers 13 and 14. The stretching temperature (Td) is defined as the warp yarn draw ratio (WDR) of the surface speed ratio of the rollers 13 and 14 (WDR ) (Ie, WDR = V14 / V13; relaxation temperature (Ts), heat relaxation between sticks 17 and 18, overfeed percentage,% 〇F = (1—V18 / V17) 100, t where VI8 / V17 is Kun 17 and The surface speed ratio of 18; as long as the total warp draw ratio TWDR * S: TWDR = WDRX (1_% 0F / 100) = (V14 / V13) X (V18 / V17) = V18 / V13, because generally V14 = V17. Yarns produced according to the invention have properties that make them extremely suitable for application in the dyeing process of the lattice. A variety of yarns have uniform dyeing properties and any one or more of them are extremely important for dyeing uniformity. It is believed that the yarns produced by the invention method or method The nature of the property is that the denier change analysis (DVA) along the end of the denier change analysis (DVA) is less than about 0.7 CV and when the feed yarn is stretched 1. 33X (DT33%), pull There is less% CV at the edge of the extension tension (please read the notes on the back before filling in this page). Packing. Order too K 飧 iA with Ψ 團 K 媪 格 (210x297 g; «·) -18-Ϊ00534 A 6 B6 Ministry of Economic Affairs Printed by the Central Standards Bureau Employee Consumer Cooperative Description of the invention (in about 1.0. The preferred method of the invention provides yarn with a macromolecular dye uniformity order of at least 6 " (LMDR). '' The term macromolecular dye 〃 means eight 1 ^ 111 ^ (1- uinone Milling Blue BL (CI Acid Blue 122) SSando-1 i η M i 1 1 i ng B 1 ue BL_N (C. I. Ac id B 1 ue 80) It is a macromolecular, washable, rate sensitive acid dye. Although _ is not used in the measurement of LMDR in this case, other macromolecular dyes may be more Scherge or less strict. The `` macromolecule acid dye uniformity grade & quot '' used in this case ; Means weaving the yarn into a warp flat fabric and then dyeing it with any of the above macromolecular dyes to evaluate the dyeing uniformity of the yarn. After dyeing in the evaluation method, the fabric is borrowed from a special plate as detailed in the following test method. 2 3-3 The computer simulation of the fabric strips shown as wires 2 is divided into 1 to 10. It is considered that the evaluation of 5 or less is unacceptable and the evaluation of 5 to 6 is accepted by some non-collapsible warp knitted fabrics. 6 Levels above or above are considered acceptable for most of the warp knitting fabrics of 傜. 6.5 or higher levels are strictly warp knitting fabrics such as swimwear. The yarns accepted by the present invention and the present invention are more conducive to the generation of uniformity grades higher than about 5. It is considered that 7 or higher grades are better and yarns that can produce grades higher than 7 are the best. Up to 8. ◦ or Higher orders are also possible in the present invention. Figure 3 is the tensile tension, DT (line A), measured at room temperature (expressed in grams per denier), as far as the knitting resistant yarn with 80% elongation at break (ie, (RDR ) f = 1 + 80/100 = 1. 8 0) for the percentage of elongation (Ε), the draw ratio. (DR = 1 + Ε / 1 0 ◦), and the remaining draw ratio of the drawn yarn ((RDR ) 〇 = (RDR) / / DR] The picture drawn; Among them, DT is first installed with the draw ratio (please read the precautions on the back before filling this page). < -19-f200534 A 6 B 6 Printed by the Consumers ’Cooperative of the Bureau of Standards of the Ministry of Economic Affairs V. Invention Instructions (Rapidly increased to yield point (Ey, i), at about 5% E (ie, about 1.05XDR) , And gradually increase to the breaking point at ΕΛ (ie, RDR = 1. 0) with the stretching ratio; and the corresponding drawing of the change in tensile tension along the end (DTV) (line B) U% CV, which It is quickly reduced to the initial yield point (Ey, i) and remains substantially fixed in the yam zone of Ey, 丨 to £: 7, f, and then generally increases to the yarn break. The optimal stretch zone is defined as E y, i To Ey, f; that is, in this example, an E-value of 5% to 55%, which is equivalent to 1.05 (WDR) to 1.44 (WDR), corresponding to 1.71 (RDR) to 1. 25 of (RDR). Figure 4 shows the percentage change in length (△ Length%) of the yarn with resistance to knitting to the temperature. It uses 〇11? 011111161: 111 & 1 ^^ 0agger 311 丨 0 & 141 ^ 1Ya 26-r (TMA) at 50 ° C per minute (± 0. Ιυ) and the pre-tension (herein also referred to as stress, a, expressed in micrograms per denier)} From 3mg / denier to 500mg / denier; where the yarn is under a pretension of greater than about 50mg / d Stretch (figure 4A—upper half) and shrink under a pretension of less than about 50 mg / d (figure 4B lower half). The immediate length change response to temperature at a given tension, [(△ length,%) / (△ Temperature, t:)] = [△ L / △ T], which is called dynamic shrinkage under shrinkage conditions and a dynamic stretch ratio in the stretched state. The preferred yarn used in the present invention is 401C And 1 35Ό shrinks at an initial tension of 5mg / d, which approximately corresponds to the glass transition temperature (Tg) and the starting point of crystallization (T〃, d; and under certain conditions has less than zero (please read the note on the back Please fill in this page for details) 装 · Order_ Taizhao βm ΦYinyingluo (CMSVP4 sister grid (210 to 297 public repair) -20-200534 A 6 B 6 Printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs 5. Description of the invention (Dynamic shrinkage rate of 19 (ie, shrinkage increases with temperature and at about 40TC and 135t: does not have any straight hair extension after initial shrinkage). Figure 5 is the dynamic extension rate of nylon feed yarn TMA, (AL / AT), for the temperature under the tension of 50 to 50 0 τη g / d (see Figure 4 for details). Maximum dynamic extension , (△ L / ^ T) mu, here, taken as the starting point of the main crystallization and occurs at the temperature T / i, *. The preferred stretching temperature is less than about T / /,. Figure 6 shows the maximum TMA dynamics Elongation, (AL / AT) m «x, for the initial stress, expressed in milligrams of the first denier, the graph; where, (△ L / AT) ^: ^ With increasing stress (σ) The increase is characterized by a positive slope, d (△ L / △ T) mu / d σ. d (△ L / ^ T) usually decreases with increasing polymer RV, and increasing speed (ie, decreasing (RDR) s). The preferred feed yarn used in the present invention is characterized by (△ L / ^ T) „» «^ value less than about I 0.20, preferably between about 0.15 and about 0.05% / υ, and d (△ L / △ T) d σ value is about 3X1 0_4 and about 7X1 0_4 under 3 0 0 0 mg / d stress (σ), which is selected as the characteristic of the better yarn of the invention because it is a relaxation zone (Figure 2) (Kun 17 and 18) is generally known as tension. Figure 7 (line A) is a general graph of the percentage change in length of nylon feed yarn (△ length%) versus temperature (1;), which uses Du Pont Thermal Mechanical Analyser in It is obtained at a fixed heating rate (+ / _ 0.1 ° C) and a fixed tension of 300 mg per initial denier every 50 ^ every minute. The starting point of extension (ie, ALSO) is about the glass transition temperature (Tg) (please Read the precautions on the back before filling the nest page) Install · -5 · Too paper and ruler Ιίΐ Ψ @ 3 囷 玄 摁 迤 (CNSVP4 row. Grid (210x297 public power) -21-Employees of the Central Standards Bureau of the Ministry of Economic Affairs Consumer Cooperation Du Printed 200534 A 6 ____ B6_ V. Description of the invention (2Q occurs and the temperature increases rapidly, which is believed to be related to the temperature at which hydrogen bonds begin to break to extend the polymer chain and the wafer moves. Figure 7 (B ) Is the TMA dynamic elongation diagram corresponding to line A, defined here as the instantaneous length change per degree Celsius, (△ length,%) / (△ temperature, t :) = (Δί / ΔΤ), dynamic elongation, (△ L / ΛΤ), which is quite fixed between Tg and Τ // ", and then increases to the initial maximum value at the temperature, which is believed to be accompanied by the starting point of the main crystallization. The dynamic elongation is in the higher temperature range from D to T / temperature range. Maintain a fixed value, and then increase rapidly, which is accompanied by crystal melting and yarn softening starting point, until the yarn breaks under tension and generally less than the melting point (Tm) temperature; where, T / /, £ / is less than T m 4 0 1C. Most of the aliphatic polyamides have dynamic elongation versus temperature behavior of B-line. Among them, after the initial maximum value of T //, * reaches the minimum value, the dynamic elongation decreases slightly, which is nylon 66 Polyamide is often referred to as the Brill temperature} and is accompanied by a thermally unstable / 3-crystal structure forming a relatively thermally stable 2-crystalline configuration transition; for nylon 6 polyamide, T / /, 〃The temperature is believed to be accompanied by 7—the crystal configuration is only stabilized by spin orientation 2—the conversion of crystal formation, which is a stretched and / or heat-treated yarn Typical. The better warp yarn drawing conditions of the acid dyeing property are found and the degree of stretching (shown as WDR), stretching temperature (Τβ), relaxation temperature (T «), and the degree of allowable relaxation (shown as% super Hello,% 〇F, or relaxation, 1 %% Ο F / 1 0 0) careful balance. Here, the preferred range is: WDR is about 1. 05X and (RDR) f / 1. 25 room ; D at 2 0 t is less than about T / /, preferably less than about T / /, especially (please read the notes on the back before writing this page) Install-.νφ _ 太 Κ ffi Ψ Η 6Η Who is it? CNS) Ping 4 specifications f 210 to 297 public bitch) -22-Printed by the Ministry of Economic Affairs, Bureau of Standards, Consumer Labor Cooperatives 200534 A 6 ___B_6_ V. Description of invention (M is less than about T; T * less At about T (ie, τ «-40t!), Preferably less than about T ^, 〃, especially less than about T ^, *. With the decrease (RDR), the demand for lowering TΛ (ie, increasing WDR and decreasing% F) is accompanied by the transfer of the pore size distribution between crystals to a smaller value, which reduces the dye diffusion rate and increases the temperature of the main migration starting point of the pores (This is about the dye transfer temperature, and the maximum dynamic mode temperature (Tnu). It is believed that there is a composition that defines the pore size distribution and pore mobility of strictly acid dyeability. It is believed that this composition is properly selected It is achieved by feeding the yarn and the invented warp yarn drawing method. 圔 8 is the relative crystallization ratio, dx / dt, a representative graph of the processing temperature. The dx / dt value increases, reaching the maximum value at Tc, which is in terms of knitting resistance 66 About 150t and about 146t for nylon 6: Temperature Ti and T2 show the processing temperature of relative crystallinity x = 1/2. For nylon 66, T2 and Ding; about Ding. + /- 20Ό. Between the temperatures T / · and> Tc, the crystallization proceeds through nucleation and the growth of the existing crystal skeleton between Tc and D2 is found. Comparing Figures 8 and 7, showing T //, ^ and D ^ , 〃 may correspond to Τ: and Τ2; and Τη, * and may correspond to Τ / " and Τ2 • Although this discovery is not limited to any specific theory However, it is believed that the preferred relaxation temperature in warp yarn drawing is less than about Tc, that is, under the condition that the crystal growth is uniformly nucleated, especially when the drawn yarn (RDR) is reduced. Figure 9 is The reciprocal of the relaxation temperature (Τ «, Ό) is shown as 100 / (Τ« +273), which is a graph of the residual stretch (RDR) D of the drawn yarn. I (ABDE) and The area II (AEHI) indicates that it can be used to produce a series with superior macromolecular dye uniformity (please read the precautions on the back before filling in this page) 太 訯 帒 κ 泞 消 rnrn Ψ @ 3 犯 «: 鸩 谁 Ψ4 姐 格 （ 210x297 Gongniang) -23-200534 A6 ___B_6 printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economy V. Invention description (23 (LMDR) Yarn method of drawing step (RDRfl) temperature conditions related to drawing step (T «). The BCD line corresponds to room temperature (RT), the AME line represents (about 9〇10), the KLF line corresponds to T //, * (about 135t :), and the JG line corresponds to T //, ^ (about 1 75 It) and the I Η line corresponds to (Nylon 66 polyaldamine about 225¾ or other polyamide about T-4〇. Ό. AKJ I line shows the following formula: [1000 / (T «+273)] & Ki-K2 (RDR) β can be rearranged to produce the following formula T * (t :) S [1 000 / (K, -Κ 2 (RDR) c)] 273, where Kz = 1000 / (T / yf273) +1. 25KdK2 = [1 000 / T //, 1 + 273)-1 0 0 0 / (Ί 11 Z 7 3)] 0.3. For most nylons, K: and 1 <: 2 values are about 4.95 and 1.75 respectively. In the case of knitting fabrics with a lower melting point (T «), such as nylon 6, which has a melting point of about 4 ° C lower than that of knitting 6 6 homopolymers, Ding ^, 1 and Ding /, the value is generally Different values below 1 ^ and 2 (see Figure 18 for comparison of TMA curves of high-speed spinning nylon 6 and nylon 66 homopolymer). Figures 10 to 13 show resistance to similar heat transfer as shown in Figure 6 The representative thermal response of nylon feed yarn. Figure 10 is the dynamic shrinkage tension (ST), under fixed length conditions and a heating rate of 3〇10 / mi η, the graph of temperature, which sharply increases above Tg and reaches the maximum value, then sharply decreases to temperature, This is called Τίί, ZO and is more slowly entangled to Τ //, Λ and the temperature of inactivity, and then decreases more quickly. TsTma: »: often accompanied by the starting point of the main polymer chain migration and subsequent nucleation. Extraordinary stretching temperature (τ〃) 1 (please read the precautions on the back before filling in this page) Binding · Threading. Too ". 帒 Κ ϋί Use Ψ because Η 犮 find dimension (CNS) Ψ4 specifications (210x297 public goods ) -24-200534 A 6 B6 Printed by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention description (23 generally between Ding 8 and Ding ^^. In the example, most yarns are stretched near Ding〃》 〃. Figure 11 is a typical contraction graph measured by Lawson-Hemphill TYT by gradually increasing the temperature to 150t by 701C. The contraction increases sharply at about 9 ΟΌ, which is similar to the observer using Du Pont TMA (see Figure 4). The increased temperature is accompanied by the temperature Tni. Figure 12 shows the logarithm of the dynamic loss modulus (E 〃), line A, and the corresponding Loss Tan Delta logarithm, line B, and temperature; where both are at 5 t: Measured using rheovibron at a heating rate of 1 / min. Mark the characteristic heat transfer and compare it with those observed in Figures 6 and 10. Figure 13 is a graph of the change in heat flow measured with a differential scanning calorimeter (DSC) versus temperature. 6 0Ό to 2 0 01C, the temperature range of the intermediary is expanded to T / /, i, Τ / /, ^ and Ding / heat transfer The starting point of the endothermic 6 6 yarn melt melting endotherm at about 2 2 5 1C occurs at T //, ί; and is about 4 0 ° C less than the melting point i T ». Figures 14 and 15 are at 300 mg / d The graph of TMA dynamic elongation versus temperature under pretension, each of which is the drawn warp yarns of Examples IV-3 and IV-10; of which the yarn LMDR of Example IV-10 is 6 and the LMDR of the yarn of Example IV-3 is less than 6, which corresponds to the (ΔΙ ^ / ΛΤ) large change in temperature between temperature A and D, especially between A and C (compare Figure 14 and Figure 15). Figures 16 and 17 are important primary spinning A plot of the properties of nylon 66 yarn versus spinning speed (Vs), but also found the general behavior of nylon 6. Figure 16 (line A) is the residual draw ratio (RDR) s of the as-spun nylon 66 yarn, shown as too Paper back ruler cold test Jii due to the 03 rule: Sister grid (210x297 public loan) 1 25-(please read the notes on the back and then fill out this page) installed-* 200534 A 6 B6 Printed by the cooperative. Fifth, the description of the invention (24 reciprocal, 1 / (RDR) s (which is approximately proportional to the molecular elongation and is often referred to as the spinning draw ratio) vs. the spinning speed (Vs). The spinning speed increases with the range of 1 OOOmpiri to about 4000 nipm (Vs ) Linear increase, and then the spinning speed in the range of about 4000 to about 800〇mp m linearly increases at a decreasing rate. (RDR) The absolute value of s is known to vary with the polymer RV and dp f, for example, but Fig. 1 6 The focus of line A is the change in behavior (RDR) s at approximately 4000 mprri. Above about 400 mPm, thermal / mechanical stabilization is usually not required to provide stable yarn packaging. Below about 40,000 mpm, the as-spun yarn must be stabilized to provide a package that can be used for warp drawing (see discussion in Figure 1). In Figure 16 (line B), the density (p) increases with increasing spinning speed and increases faster than about 4000 mpm. It is found that the (RDR) s of the spinning is less than about 2.75, and the corresponding 1 / (RDR) s value is greater than about 0.364, which is conducive to warp stretching. .1 Figure 16 does not separately show the reason for the requirement of less than about 2.75 (RDR) S value. Figure 17 (Line A) is the representative of the change in the length of the spun yarn that has not been aged for more than 24 hours after boiling. The spun yarn is elongated in boiling water up to about 2000mpm (zone I). The spinning yarn is stretched between about 2000 and about 4000 mpm in boiling water, but it has a lower degree of spinning speed (I I zone). The as-spun yarn shrinks in boiling water at a height of about 4000 mpm (I I I area). In Figure 17 (line B), the corresponding birefringence value of this yarn versus the spinning speed is shown in the day chart. Observe the decrease of the birefringence increase rate at a spinning speed of about 20,000mpm (please read the precautions on the back and then fill out this page) 装-线 · 太 位 得 K 泞 Ψ because of Η 定 殺 destroyed (CNS) 210x297 公 -26-200534 A 6 B6 Printed by Beigongxiaot Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention description (2 $ low, I believe it is accompanied by a change between the behavior of Zone I and Zone II and is attributed to the spinning line stress The starting point for inducing nucleation. The transitions in zones I and II correspond approximately to an initial spinning (RDR) s of less than approximately 2.75. Feeding yarns with initial spinning shown in zone I cannot be `` dried '' Stretching produces LMDR greater than 6. Yarns used in the present invention are in zones II and III, and preferably zone III, because the dye level of the yarn in zone III when the finishing agent is applied is detected (MB BJ has a very high degree of moisture on the yarn The sensitivity is removed and the yarn properties are more stable with time during storage. Figure 18 is a TMA diagram of the dynamic elongation rate (AL / AT) versus temperature of various feed yarn types at 30 mg / d tension: A = Generally known as 50RV resistance Braided 66 yarn, which was spun at 5300mpm and contained 5% Me5_6; B = nylon 66 homopolymer yarn, which was spun at 5300mpm (Yarn J of Example I); C = nylon copolymer yarn, which was 530〇mprri spinning Silk (K yarn of Example I); D = nylon partially stretched yarn (D-F yarn of Example I); E = generically known as 47RV knitting 6 homopolymer yarn, which is spun at 5300 mpm. The nylon 6 feed yarn moves about 20-30 ° C to a lower temperature to the knitting 66 feed yarn, which reduces the maximum relaxation temperature (Ts) of nylon 6 relative to nylon 6 6 homopolymer by about 20-3 〇10. Figure 19 is a TMA diagram of different yarn types shrinking (delta length,%) under 5mg / d tension vs. temperature. Most of the feed yarn shrinks with increasing temperature, especially between 401C and 135Ί0; however, A The yarn stretches first and shrinks only at a temperature higher than about 150¾. A yarn is not a preferred yarn because it does not shrink, but it stretches between 40 and 135t: (ie, ALSO); also because of its positive length change rate, This is called, positive dynamic shrinkage 〃 (that is, (please read the precautions on the back before filling out this page) Binding · Order-> Line · -27-Printed by Beigong Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs 200534 A 6 _B6_ V. Description of the invention (2Θ △ L / AT> 0), C). The best feed for warp yarn drawing is 40¾ and 1 35t: temperature range with dynamic length-free change and negative dynamic shrinkage圔 20 is the tensile stress (σ / β), expressed in grams per denier of tension, at 20Ό, 751C, 125t: and 175 * 0 on behalf of the drawing ratio. Tensile stress (σ .) Above the yield point, it increases linearly with the draw ratio and the slope is referred to here as the tensile modulus (Μβ) and is defined as (△ σ / ADR). The values of tensile stress (σ «) and tensile modulus (Μ〇) decrease with increasing tensile temperature (Τβ). Fig. 21: Comparison of the tensile stress (σβ) to draw ratio (DR) at 751C for various feed yarns (A = generic name for 65RV nylon 66 homopolymer spinning at 5300mpm; B = spinning at 53〇mpm The general name is 68RV nylon 6,66 copolymer; C = 40RV nylon 66 homopolymer spinning at about 3300mpm. The desired degree of tensile stress (σβ) and tensile modulus (Μΰ) can be controlled by selecting the type of feed yarn and the drawing temperature (TD). The preferred tensile warp yarn feed yarn has a tensile stress (σζ ^) of about 1. ◦ and about 2. Og / d, and a tensile modulus (M) between about 3 and about 7 g / d, in 7 5 ° C and 1 · 3 5 stretch ratio (DR) measurement, taken from the drawing of tensile stress (σ) vs. stretch ratio. Fig. 22 is the logarithm of the tensile modulus of the seed yarn in Fig. 21; 1 η (Μβ), a representative graph of [1000 / (Tfl, C + 273)]. The slope of the linear off-image in Figure 22 is taken as the apparent stretching energy (ΕζΟ λ, assuming that Md is Arrhenins-type dependent on temperature (ie, Mr > = Aexp ((Please read the precautions on the back before filling this page) Tai Bian R / ί ί Ιίΐ Ψ due to Η house drag male iCNS) A 4 group grid 210 X 297 male pairs) -28-A 6 B 6 200534 5. Description of invention (E zp / RT), where T is Kelvin degree The temperature, R is the ordinary gas constant, and "A " is the material constant). It is better to draw the apparent tensile energy of the warp yarn into the yarn (EzO 4 [= E〇 / R = ^ (lnMD) / △ (1 〇00 / Τζ>), where Τΰ gKelvin degree] is about 2 And 0.6 (g / d) / ° k. The following examples further illustrate the invention but do not constitute a limitation. _Yarn properties. And method variables are measured according to the following test method. Parts and percentages are by weight unless otherwise stated The test method Relative Viscosity (RV) measurement of polyamide is described in col. 2, 1.42-51, in Jennings US Patent No. 4.702.875. According to ASTM Designat ion D-1907 -80 measurement. Denier can be measured by an automatic weighing device, such as those described by Goodrich et al. In US P4, 084, 434. Tensile properties (toughness, modulus and elongation at break) are measured in USP of Li 4, 521,484 of the second cabinet 1. 61 to the third scale 1.6. The modulus (M). Often called the initial number of bottles 〃, obtained from the first reasonable straight line part of the load elongation curve, the tension is plotted on the y-axis Relatively the elongation is plotted on the X _ axis. At 59 ^ Chen Shen Xi Sect (M5), the ratio is (tenacity /. 05) X100, where the degree is measured at the 5% extension. Method using infrared microscope and Zieminski and Spruiell, J · Αρρ1. Polymer Science, (please read the precautions on the back before filling the nest page) Pack- -V * _ Printed by the Ministry of Economic Affairs Recognize R / Ϋίί Ιίΐ Ψ Due to H A 4 twisted grid (210x297 public money) _ 29-Printed by the Beigong Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs 200534 A6 _B_6__ V. Description of invention (2β 35, 2223, 2245 (1988) and Bheda and Spruiellt J. Appl. Polymer Science 39 »447-463 (1 990). The equipment temperature described here, for example, Kun, etc., is measured using a standard thermocouple. Boiling solution shrinkage (B ◦ S) The following loose skein method is used for feeding the yarn as described in this case and measuring the change in length expressed as a percentage of the original length of the skein when immersed in boiling water. The skein is made around the standard denier of 1 to 1/8 meters On the shaft. The shaft speed is determined by the weight used to measure the length of the skein. The weight should be as follows: < 30 denier-100g; 30-100 denier-25〇g; > 100 denier-500g. The rotation speed is required to generate a load of 5 5m s / denier and is calculated by the following formula: R = 1000W / 2LD where R = the nearest integer number of revolutions; W = weight in grams; D = denier; L = Load = 55mg / denier. The skein is hung on the hook and straightened with a weight. The length of the skein is measured to the nearest 1mm and recorded as L1. The skein is wrapped in cheese-cloth cloth and placed at 98 taxis (please read the precautions on the back before filling in this page). Set-up-thread. Too much from Ηm Ψ due to S3 鹸 鸪 瓤 (CNSW4 觇 柊 （210 侂 297 公 处) -30-A6 B6 200534 V. Description of the invention (29

It下之沸溶鍋中2〇±lmi n。由浴中移出絞纱並風 乾。以同於L 1之方法測量沸溶後絞纱長度L 2。沸溶收 縮計算為： %BOS = (Ll — L2) xiOO/Ll 沸溶收縮(Β Ο S )。以下璟形法用以測量拉伸經纱 之沸溶收縮。纱縛於長約50cni之環中且環長在 0. 05g/d負荷下使用米尺測量。移除負荷並將環置 於約0. 6S負荷之沸水中以防止漂浮而在水中缠結。將 環風乾並在0.05g/d負荷下再測長度。沸溶收縮計 算如下： 沸騰前長度一沸騰後長度 B 〇 S = -X 1 0 0 沸騰前長度 沸溶後乏埶因时縮(H S S /A B 0 )測量是將試驗 絞纱浸入沸水中，然後將其置於熱燫中並測量收縮。尤其 ，由3000旦尼爾試驗絞纱（6000旦尼爾璟）懸掛 5 0 ◦克砝碼使纱上力為8 3m g/旦尼爾，並測量絞纱 長度（L1)。然後以30gm砝碼取代500gm砝碼 並將掛重後之絞纱浸於沸水中2 0分鐘，移出並風乾 2 ◦分鐘。然後絞纱懸於175T：之燫中4分鐘，移出， (請先閲讀背面之注意事項再填寫本頁) -* -·** 經濟部屮央標準局员工消费合作社印製 太啟花 K 泞 ίΛ ffl 中因 ® 格dO V297公分） -31 200534 A 6 B6 五、發明説明（3Q 以5〇0gm砝碼取代30gm砝碼，測量絞纱長（L2 )。"沸溶後之熱固收縮"以下式計算： .L 1 - L 2 沸溶後之熱固收缩（％) =-X 1 0 0 經濟部屮央標準局员工消費合作社印製 沸溶後之熱固收縮（HSS/ABO) —般大於 BOS,即，纱在17510ABO之DHS上持缠收縮， 其利於達均自染色及整理。 靜熊乾執#縮(DHS90及DHS135)使用ϋ. S. Patent No.4 , 134, 882, Col. 11, 11. 42—45所述之方法測量，除了爐溫各為90度C, 135度C及175度C,而非160度C外。 » 大分孑酴染料勻度(LMDR)纱使用32規經平编 織機编成經平織物，並藉下法使用C.I. Acid BUe 122或 C.I. Acid Blue 80任一者染色： 此法用以染色少量（〜1 一 3碼）織物。稱重量之織 物添加於煮洗器中11〇卞之30升水中。此浴中添加 3 g MerpoI HCS (E.I. du Pont de Nemours and Com- pany所售之液體非離子性清潔劑）及3g 1 0%氫氧化銨 。浴溫以3°F/m i η之速率升至1 60T且煮洗器開動 1 5分鐘。然後放空此浴並充分洗淨並添加3 ◦升水。溫 度設於80Τ並添加〇.5%織物重之Merpoi DA (Ε.Ι. 太蜣帒尺泞ifi m巾因囚定找站（CNW4姆格（210x297公处） -32 - (請先閱讀背面之注意事項再填寫本頁) 200534 Α6 Β6 經濟部中央標準局貝工消费合作社印製 五、發明説明（3ί du Pont de Nemours and Company所售之非離子性表面活 性劑）。開動此浴5分鐘以混合，並添加2%織物重之 MSP (磷酸單鈉）。浴之pH以乙酸諝至6. 0。然後 添加6 %織物重之硫酸銨且此浴在添加1. 織物重之 Du Pont Anthraquinone Milling Blue BL (C.I· Acid Blue 122)或 Sandolin milling blue N-BL(C.I ' Ac.i. d Blue 80)前開動5分鐘。將此浴開動5分鐘，然後浴溫以 3°F/m i η升至2 1 2T。開動此浴60分鐘後，測量 pH。若ρΗ>5. 7，則調至5. 5並再開動30分鐘 。然後此浴冷卻至170Τ,放空，並以淨水洗淨。由浴 中移出織物並乾燥。 織物之纱就LMDR評估如下： 織物試樣（金寬，即，約60英寸寬及約20 — 60 英吋長）在具有漫射螢光照明之室中置於覆有暗黑塑膠之 > 大檯上。織物以專家板評估（5至7專家評估之级數平均 )記為1至1◦级，如下述圖23—32所示使用織物條 纱電腦模擬。 評估级數所選擇之評估為： 1 0=未見缺陷，絶對均勻； 8=稍見不勻，但難以察覺，幾乎所有最终用途皆可 接受； 7 =優； 6. 5=可為極嚴格之經编織物諸如泳裝所用者所接 受； (請先閱讀背面之注意事項再填寫本頁) 裝- 太κ ΖΫΙΑ ffl Ψ Η闽宅找维（(：旧）甲«&格（210父297公贷） -33 - 200534 A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明（33 6=可察得不勻度，可用於大部分服裝； 5=除第二级服裝外不能接受； 4=可察得極高不勻度，對任何服裝而言皆太不勻； 及 2=極不勻，極駸重缺陷； Μ B R染色袢 為ΜΒΒ染色試驗製備一組重1克之42纱試樣，較 好將纱噴於小盤上。9試樣為對照組，餘者為試驗用。 然後所有試驗浸於54升包含140m5標準缓衝液 及 8 Q ΤΏ 又 1 . 2 2 96 Anthraqu i none Milling Blu- e BL (間稱 MB B) (C.I. Acid Blue 122)之染料水溶 液中而染色。最終浴pH為5.1。液溫以3〜 10/111111由室溫增加至7^〃 （染料轉變溫度，其為 I 染料攝取率迅速增加之溫度）並保持彼溫度3 — 5分鐘。 染色試樣淋洗，乾燥，並以反射比色計測量染色深度。 染色值由反射讀數計算K/S值而決定。其式為： K / S試樣 Μ B B染色性=-X 1 8 0 且 K/ S對照組 (請先閱讀背面之注意事項再填寫本頁) 太址後 Κ ίΛ m 中因 H «JSm(CNS) Ψ4斑格（210X297公； -34 經濟部屮央標準局貝工消t合作杜印製 200534 五、發明説明（33 (1 - R ) 2 κ / S =-20 ± lmin in the boiling pot under It. Remove the skein from the bath and air dry. The length L 2 of the skein after boiling is measured in the same way as L 1. The boiling shrinkage is calculated as:% BOS = (Ll-L2) xiOO / Ll boiling shrinkage (Β Ο S). The following Jing method is used to measure the boiling shrinkage of the drawn warp. The yarn was bound in a ring with a length of about 50 cni and the ring length was measured using a meter ruler under a load of 0.05 g / d. Remove the load and place the ring in boiling water with a load of about 0.6 S to prevent floating and tangling in the water. The ring was air-dried and the length was measured again under a load of 0.05 g / d. The boiling shrinkage is calculated as follows: the length before boiling-the length after boiling B 〇S = -X 1 0 0 The length before boiling is measured due to time shrinkage (HSS / AB 0) after boiling. The test skein is immersed in boiling water, and then It was placed in a heat pan and the shrinkage was measured. In particular, a 3000 denier test skein (6000 denier jing) was hung by 50 ° gram weight to make the upper force of the yarn 83 mg / denier, and the skein length (L1) was measured. Then replace the 500gm weight with a 30gm weight, and immerse the skein after hanging the weight in boiling water for 20 minutes, remove and air dry for 2 ◦ minutes. Then the skein is hung in 175T: for 4 minutes, and removed, (please read the precautions on the back before filling out this page)-*-· ** Printed by the Ministry of Economic Affairs Employee Consumer Cooperative of Taiqihua K 択ίΛ ffl Zhongyin® grid dO V297 cm) -31 200534 A 6 B6 V. Description of the invention (3Q replaces the 30gm weight with a 50gm weight, and measures the length of the skein (L2). "Quotation after boiling dissolution " Calculated by the following formula: .L 1-L 2 Thermoset shrinkage after boiling (%) = -X 1 0 0 The thermoset shrinkage after boiling printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs (HSS / ABO) ) Generally larger than BOS, that is, the yarn holds shrinkage on the DHS of 17510ABO, which is conducive to self-dyeing and finishing. 静 熊 干 执 #shrinkage (DHS90 and DHS135) uses ϋ. S. Patent No. 4, 134, 882, Col. 11, 11. 42-45, except that the furnace temperature is 90 degrees C, 135 degrees C, and 175 degrees C, instead of 160 degrees C. »Oita Dye Dye Uniformity (LMDR ) The yarn is knitted into a warp and flat fabric using a 32 gauge warp and flat knitting machine, and dyed with either CI Acid BUe 122 or CI Acid Blue 80 by the following method: This method is used to dye a small amount (~ 1 to 3 yards) of weaving The weight of the fabric is added to 30 litres of water at 110 ° C in the boiler. 3 g of MerpoI HCS (liquid non-ionic detergent sold by EI du Pont de Nemours and Company) and 3 g are added to this bath 10% ammonium hydroxide. The bath temperature was raised to 160T at a rate of 3 ° F / mi η and the boiler was started for 15 minutes. Then the bath was emptied and thoroughly washed and 3 liters of water was added. The temperature was set at 80T and Add 〇.5% of the fabric weight Merpoi DA (Ε.Ι. Too 蜣 帒 渞 泞 ifi m towel to find a station due to captivity (CNW4 Muge (210x297 public office) -32-(please read the precautions on the back before filling This page) 200534 Α6 Β6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (nonionic surfactant sold by 3ί du Pont de Nemours and Company). Start the bath for 5 minutes to mix and add 2% fabric weight MSP (monosodium phosphate). The pH of the bath is acetic acid to 6.0. Then add 6% fabric weight ammonium sulfate and this bath is adding 1. fabric weight Du Pont Anthraquinone Milling Blue BL (CI 5 minutes before Acid Blue 122) or Sandolin milling blue N-BL (CI 'Ac.i. d Blue 80). The bath was started for 5 minutes, and then the bath temperature was increased to 2 1 2T at 3 ° F / m i η. After starting the bath for 60 minutes, the pH was measured. If pH> 5.7, adjust to 5.5 and start for another 30 minutes. Then the bath was cooled to 170T, vented, and washed with clean water. Remove the fabric from the bath and dry. The yarn of the fabric is evaluated with respect to the LMDR as follows: The fabric sample (gold width, ie, about 60 inches wide and about 20-60 inches long) is placed in a dark plastic-covered room in a room with diffuse fluorescent lighting. On stage. The fabric is recorded as 1 to 1◦ by expert board evaluation (average of 5 to 7 expert evaluation stages), as shown in Figure 23-32 below using computer simulation of fabric sliver. The evaluation selected by the evaluation series is: 1 0 = no defects are seen, absolutely uniform; 8 = slight unevenness, but difficult to detect, almost all end uses are acceptable; 7 = excellent; 6. 5 = can be extremely strict The warp knit fabrics such as swimwear are accepted by; (please read the precautions on the back before filling in this page) Outfit-Tai κ ZOΫΙΑ ffl Ψ Η Minzhai looking for dimension ((: old) A «& grid (210 father 297 Public loan) -33-200534 A 6 B6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention description (33 6 = detectable unevenness, can be used for most garments; 5 = except for second-level garments Unacceptable; 4 = highly detectable unevenness, which is too uneven for any garment; and 2 = very uneven, extremely short-weight defects; Μ BR dyeing loops prepare a set of 1 gram of weight for the ΜΒΒ dyeing test 42 yarn samples, it is better to spray the yarn on the small plate. 9 samples are the control group, the rest are for the test. Then all the tests are immersed in 54 liters containing 140m5 standard buffer and 8 Q ΤΏ and 1. 2 2 96 Anthraqu i none Milling Blu-e BL (Between MB B) (CI Acid Blue 122) dyed in an aqueous dye solution. Final bath The pH is 5.1. The liquid temperature is increased from room temperature to 7 ^ 〃 from 3 to 10/111111 (dye transition temperature, which is the temperature at which the dye uptake rate increases rapidly) and maintained at that temperature for 3-5 minutes. The stained sample is rinsed , Dry, and measure the depth of staining with a reflectance colorimeter. The staining value is determined by calculating the K / S value from the reflection reading. The formula is: K / S sample Μ BB stainability = -X 1 8 0 and K / S control Group (please read the precautions on the back and then fill out this page) after the address Κ ίΛ m in the H «JSm (CNS) Ψ4 patch (210X297 g; -34 Beigongxiao Bureau of the Ministry of Economic Affairs Bei Gongxiaot cooperation Du Yin System 200534 V. Description of the invention (33 (1-R) 2 κ / S =-

2 R 當R=反射值時。180值用以將對照試樣染色性調整並 正規化成已知基底。 A B B染色袢 以同於MBB染色性之方式製備一組試樣。然後所有 試樣浸入54升包含140τηί檫準缓衝液；lOOmi? 1 0 % Merpol LFH (來自 E.I· d u Pont de Nemours a-nd Co.之液體，非離子性清潔劑），及80-500mi2 R When R = reflection value. A value of 180 is used to adjust and normalize the dyeability of the control sample to a known substrate. A B B dyeing loop Prepare a set of samples in the same way as MBB dyeing. Then all the samples were immersed in 54 liters of 140 τηί quasi-buffer solution; lOOmi? 10% Merpol LFH (liquid from E.I · d u Pont de Nemours a-nd Co., non-ionic detergent), and 80-500mi

0.56% ALIZARINE CYANINE BLUE SAP (間稱 A B B \ )(C.I. Acid Blue 45)之染色水溶液中而染色。最終浴 pH為5. 9。液溫以3〜10 /min由室溫增至 120 C,並保持彼溫度3 — 5分鐘。淋洗染色試樣， 乾燥，並以反射比色計測量染色深度。 染色值藉由反射讀數計算K/S值決定。式為： K / S試樣 A B B染色性=-X 1 8 0 且 K / S對照組 (請先閱讀背面之注意事項再填寫本頁) 裝· 線- 太K泞用中03 Η玄枕迆（¥4規格（210乂297公妤） -35 - 200534 經濟部屮央標準局貝工消費合作社印製 五、發明説明（34 (1 - R ) 2K / s =-- 2 R 當R=反射值時。180值用以將對照試樣染色性諝整並 正規化成己知基底。 雄料鶬戀溫麼為在染色中纖維結構充分開放使染料吸 取率劇增之溫度。其與聚合物玻璃化溫度，纖維熱機械性 ，及染料分子及構形有關。因此可視為特定染料用之纖雒 *孔隙〃大小的間接量測。 染料轉變溫度可就c.l. Acid blue 122染料如下決定 :纱在毎g纱試樣含800g浴之浴中預洗。添加 0. 5g/i?焦磷酸四納（TSPP)及◦. 5g/i Merp〇l(R)HCS。以3t：/m i η之速率升高浴溫至浴溫為 ί 60C。在60t：保持1 5分鐘，然後淋洗。注意先質溫 度必需不超過纖雒之染料轉變溫度。若染料轉變溫度接近 洗滌溫度，則預洗應在較低洗滌溫度重覆。浴溫設於 3〇Ό並添加1%織物重之C.l. acid blue 122及5 g / 又磷酸單鈉。使用M. S. P.及乙酸將pH調至5. 0 。添加纱試樣並以3t：/m i η之速率將浴溫升至9 5t： 〇 浴溫每升高5 °C則由染浴取出〜2 5m 5染液試樣。 試樣冷卻至室溫並在分光光度計上使用水參考在約 633nm最大吸光度測量各試樣之吸光度。計算％上色 (請先閱讀背面之注意事項再填寫本頁) 裝. 線- 太蚯铒只泞诂W Ψ困捃格（210乂297公艰） -36 - 經濟部屮央標準局貝工消费合作社印製 200534 A6 ___B_6 五、發明説明（3$ 率並對染浴溫度繪出％上色率。沿曲線之兩直線部分各繪 出一交叉線且此交點為染料轉變溫度。為改善測量之再現 性，較好在1 5%上色率測量染料轉變溫度。染料轉變溫 度（Tdu )為纖維結構開啓之測量且拉伸經纱之丁〇1^ 較佳值少於約6 51C,尤其是少於約6 0¾。 曰.尼爾戀化分析雜（D V A )為電容式裝置，使用同 於lister之原理，測量沿端旦尼爾變化。DV A在2 4 0 米試樣長度上每1 / 2米測量旦尼爾變化並記錄此測量之 %CV。亦記錄％互尼爾分佈，其為八値3 0米試樣高低 讀數差值之平均值。表中使用DVA之測量記為變化係數 (D V A96 C V )。 動態機械分析試驗依下法淮行n使用裝有'' Autovib-ron"電腦套裝物（來自 Imass，Inc., Hingham ΜΑ)及 IMC — 1 爐（亦來自 Imass，Inc.)之、'Rheovibron" DDV_ I I c。使用標準，不銹鋼試樣承桿及纖維夾， 亦來自Imass，Inc·。Autovibron所提供之電腦程式亦改 良至可在一30至220度C之溫度保持試樣上固定，可 選擇，加熱速率及靜態張力。亦改良使不論取數據點之時 間為何靜態張力，時間及現存試樣長度皆可確認張力常數 及加熱速率且可在定應力下對溫度測量收縮。此電腦程式 不含夾量及負荷元件柔量之校正，且所有操作及計算，除 上述者外，皆由Imass之Autovibron提供。 本發明試樣之試驗使用對應於每旦尼爾0. 1克（基 (請先閱讀背面之注意事項再填寫本頁) 装< 線. 太K ϋί ffl Ψ因K «:捣诅i CNS) Ψ 4姐格m 0 X： 297公资） -37 - 經濟部屮央標準局员工消货合作社印製 200534 A6 ___B6_ 五、發明説明（3弓 於預試驗旦尼爾）之靜態張力。使用1. 4 土 Ο. 1度C /分鐘之加熱速率且試驗頻率為1 1 OHz。電腦設備約 每1. 5分鐘取一讀數，但此不固定，因為電腦藉調整試 樣長度保持靜態張力常數所需時間不同。試樣初長2 . 0 ±0. 1cm。試樣在一3 ◦至23 ◦度C溫度範圍進行 。試樣旦尼爾藉堆叠或分開纱而調整以確定動態及，態力 在負荷元件範圍中。 tan delta及* E 〃峰之位置（即，溫度）以下法決 定。先由適當之變數對溫度圖預估峰之約略位置。峰之最 終位置是認定溫度為無關變數地在此估計位置之±10— 15度最小平方湊合二次多項式而決定。峰溫取為此多項 式最大值之溫度。轉變溫度，即，回折點溫度同樣決定。 约略回折點由圖預估。然後認定溫度為不相干變數將足以 包含由一表觀高原期至另一者之數據點湊合成三次多項式 I 。轉變溫度取為形成多項式之回折點。約1 001C之E 〃 峰溫度（參見圖1 2 )取為2轉變溫度（ Τ λ )且對均勻染色性重要的是使此值變低（即，少於 1〇〇1〇,較好少於95t,尤其是少於90°C)。 溶融行為，包括初熔速，藉差示掃描熱量計（DSC )或差示熱分析計（D T A)測量。各種儀器皆適於此測 量。其 ~"為Du Pont Thermal Analyzer製自 Ε· I· Du Po-nt de Nemours and Company of Wilmington，DE 〇 將 3· 0土0. 2mg之試樣置於有蓋之鋁囊中，其夾於儀 器製造商所提供之夾具中。試樣以每分鐘2 Ot之速率加 (請先閱讀背面之注意事項再填寫本頁) -裝· 線· 太认?& K沧ίΛ用Ψ困a犮控雄（CNS) Ψ 4姐格（210 乂 297公贷） -38 - 經濟部屮央標準局员工消费合作社印製 200534 A 6 ___ 五、發明説明（3? 熱以測量熔點（T «)而毎分鐘5 0 t：之速率用以偵測低 溫轉變，其在纱加熱中因為快速再結晶，故一般無法得見 。加熱在氮氣氛下（入流i η)使用儀器廠 提供之玻璃鐘罩進行。試樣熔融後，在氮氣氛下以每分鐘 1 0*0冷卻試樣決定冷卻放熱曲線。耐綸6 6均聚物之熔 點一般為26 ◦ — 26 2 Ό且諸如藉添加Ν6及M e - 5 ,6降低約1°C/1%重共聚己二醛二胺。耐綸均聚物熔 點一般為222t：(卽，約比耐綸66低4〇t：)且可添 加高熔點共聚己二醯二胺，諸如添加N66升高。 聚醯胺纱之交織度藉插針技術測量，基本上，其包括 將針***移動纱並測量纱上插針點及纱上達針上預定力之 點間之纱長（cm)。就>39旦尼爾之纱而言，預定力 為1 5克；就各39旦尼爾之纱而言預定力為9克。取2 ◦個讀數。就點間之各長度而言，保留整數，去掉小數， ,1 去掉0數據，取彼整數之基底為10之對數並乘以1〇。 2 0個讀數之結果各平均並記為交織度。 6 — 6耐綸中e — P.醅胺蜇餺畺(在此表中為N6% )如下決定：將稱重之試樣水解（藉在6N HCi中回 流），然後添加4 —胺丁酸作為内標準物。乾燥試樣並將 羧酸端甲基化（以無水甲醇3N HC5)且胺端以三氟 乙酸酐/CH2Ci^2以1/1體積比三氟乙醯化。溶劑及 過量試劑蒸發後，殘留物取於MeOH中並使用氣體層析 ,諸如Hewlett Packard 57 1 0 A，售白 H e w 1 e t t Packard Co ·， Palo Alto， CA，具Flame Ionization Detector，使 (請先閲讀背面之注意事項再填寫本頁) 裝- 線. 太《.ί&Κ 泞 IS Ψ @3 铒格m〇x297公货） -39 - 2005340.56% ALIZARINE CYANINE BLUE SAP (sometimes called A B B \) (C.I. Acid Blue 45) is dyed in an aqueous solution. The final bath pH was 5.9. The liquid temperature is increased from room temperature to 120 C at 3 ~ 10 / min, and the temperature is maintained for 3-5 minutes. The stained sample was rinsed, dried, and the depth of staining was measured with a reflectance colorimeter. The staining value is determined by calculating the K / S value from the reflection reading. The formula is: K / S sample ABB dyeing = -X 1 8 0 and K / S control group (please read the precautions on the back side and then fill out this page) Pack · Line-too K 泞 用 中 03 Η 玄 枕 迤(¥ 4 specifications (210 to 297 gongs) -35-200534 Printed by the Beigong Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs V. Invention description (34 (1-R) 2K / s =-2 R when R = reflection The value is 180. It is used to normalize and normalize the dyeability of the control sample to a known base. The male material is the temperature at which the fiber structure is fully opened during dyeing and the dye absorption rate increases dramatically. The chemical temperature, fiber thermomechanics, and dye molecule and configuration are related. Therefore, it can be regarded as an indirect measurement of the size of the fiber * pores for a specific dye. The dye transition temperature can be determined as follows for the cl Acid blue 122 dye: the yarn is in each The g yarn sample is pre-washed in a bath containing 800g bath. Add 0.5g / i? tetra sodium pyrophosphate (TSPP) and ◦. 5g / i Merp〇l (R) HCS. Increase at a rate of 3t: / mi η High bath temperature to bath temperature is 60C. At 60t: hold for 15 minutes, then rinse. Note that the precursor temperature must not exceed the dye transition temperature of the fiber. If the transition temperature is close to the washing temperature, the pre-washing should be repeated at a lower washing temperature. The bath temperature is set at 30 ° C and 1% fabric weight Cl acid blue 122 and 5 g / monosodium phosphate are added. Use MSP and acetic acid The pH is adjusted to 5.0. Add the yarn sample and raise the bath temperature to 9 5t at a rate of 3t: / mi η: 〇When the bath temperature increases by 5 ° C, the dye bath sample is taken out of ~ 2 5m 5 The sample is cooled to room temperature and the absorbance of each sample is measured using a water reference on a spectrophotometer at a maximum absorbance of about 633 nm. Calculate the% coloration (please read the precautions on the back before filling this page).鄒 只 撞 寂 W Ψ Trapped (210 to 297 metric difficult) -36-Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 200534 A6 ___B_6 V. Description of the invention (3% rate and the temperature of the dye bath Color rendering rate. A cross line is drawn along the two straight line parts of the curve and this intersection is the dye transition temperature. To improve the reproducibility of the measurement, it is better to measure the dye transition temperature at 1 5% color rendering rate. The dye transition temperature (Tdu ) Is a measurement of the opening of the fiber structure and the preferred value of the tensile warp yarn is less than about 6 51C, In particular, it is less than about 6 0¾. Said. Neil love analysis analysis (DVA) is a capacitive device, using the same principle as the lister, measuring the change in denier along the end. DV A is on the length of the sample of 2 400 meters Measure the denier change every 1/2 meter and record the% CV of this measurement. Also record the% mutier distribution, which is the average value of the difference between the readings of the high and low readings of the 30-meter sample. The measurement using DVA in the table is recorded as the coefficient of variation (D V A96 C V). The dynamic mechanical analysis test is carried out according to the following method: "Rheovibron" equipped with "Autovib-ron" computer kit (from Imass, Inc., Hingham MA) and IMC-1 furnace (also from Imass, Inc.) DDV_ II c. Use standard, stainless steel sample rods and fiber clips, also from Imass, Inc .. The computer program provided by Autovibron has also been improved to keep the sample fixed at a temperature of 30 to 220 degrees C, optional, heating rate and static tension. It has also been improved so that regardless of the time at which the data points are taken for static tension, the time and the length of the existing sample can confirm the tension constant and the heating rate and can measure the shrinkage of the temperature under a constant stress. This computer program does not include the correction of the amount of clamping and compliance of the load component, and all operations and calculations, except for the above, are provided by Autovibron of Imass. The test use of the sample of the present invention corresponds to 0.1 g per denier (base (please read the precautions on the back before filling in this page). Install & Thread. Too K ϋί ffl Ψ because K «: revil i CNS ) Ψ 4 sister grid m 0 X: 297 public funds) -37-200534 A6 ___B6_ printed by the Employee Consumers ’Cooperative of the Bureau of Standards, Ministry of Economic Affairs. 5. Static description of invention description (3 bows in pre-test denier). A heating rate of 1.4 ℃ 0.1 ° C / min was used and the test frequency was 1 1 OHz. The computer equipment takes a reading about every 1.5 minutes, but this is not fixed because the time required for the computer to adjust the length of the sample to maintain the static tension constant is different. The initial length of the sample is 2.0 ± 0.1 cm. The samples were conducted in a temperature range of 3 ° C to 23 ° C. The sample denier is adjusted by stacking or separating yarns to determine the dynamic and state forces in the load cell range. The positions of tan delta and * E 〃 peaks (ie, temperature) are determined by the following method. The approximate position of the peak is estimated from the temperature map with appropriate variables. The final position of the peak is determined by deciding that the temperature is an independent variable within ± 10-15 degrees of the estimated position and the least squares fit the quadratic polynomial. The peak temperature is taken as the maximum temperature of this polynomial. The transition temperature, that is, the turning point temperature is also determined. The approximate turning point is estimated by the graph. It is then determined that the temperature is an incoherent variable that will be sufficient to contain the data points from one apparent plateau period to another to form a cubic polynomial I. The transition temperature is taken as the turning point for forming a polynomial. The E 〃 peak temperature of about 1 001C (see FIG. 12) is taken as the 2 transition temperature (Tλ) and it is important for uniform dyeability to make this value lower (ie, less than 100, preferably less At 95t, especially less than 90 ° C). The melting behavior, including the initial melting rate, is measured by differential scanning calorimeter (DSC) or differential thermal analysis (DT A). Various instruments are suitable for this measurement. Its ~ " made for Du Pont Thermal Analyzer from E · I · Du Po-nt de Nemours and Company of Wilmington, DE 〇 Place a sample of 3.0 mg 0.2 mg in a covered aluminum bladder, which is clamped in In the fixture provided by the instrument manufacturer. The sample is added at a rate of 2 Ot per minute (please read the precautions on the back before filling out this page) -install · line · too recognized? & Kang ίΛ use Ψ Trapped a 犮 控 雄 (CNS) Ψ 4 姐 格(210 to 297 public loans) -38-Printed by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 200534 A 6 ___ V. Description of the invention (3? Heat is used to measure the melting point (T «) and every minute 5 0 t: the rate is used In order to detect the low temperature transition, it is generally not visible because of rapid recrystallization during yarn heating. Heating is performed under a nitrogen atmosphere (inflow i η) using the glass bell jar provided by the instrument factory. After the sample is melted, the nitrogen atmosphere Next, the cooling exotherm curve is determined by cooling the sample at 10 * 0 per minute. The melting point of nylon 6 6 homopolymer is generally 26 ◦ — 26 2 Ό and such as by adding Ν6 and M e-5, 6 is reduced by about 1 ° C / 1% heavy copolymerization of hexamethylenediamine diamine. Nylon homopolymer melting point is generally 222t: (卽, about 4〇t lower than nylon 66 :) and high melting point copolymerization hexamethylenediamide diamine, such as adding N66 The interweaving degree of polyamide yarn is measured by the pin insertion technique. Basically, it includes inserting the needle into the moving yarn and measuring the needle insertion point and the yarn up to The yarn length (cm) between the points where the predetermined force is applied. For > 39 denier yarn, the predetermined force is 15 grams; for each 39 denier yarn, the predetermined force is 9 grams. Take 2 ◦ Readings. For each length between the points, keep the integer, remove the decimal, and 1 remove the 0 data, take the base of the other integer as the logarithm of 10 and multiply by 10. The results of the 20 readings are averaged and remembered It is the degree of interweaving. 6 — 6 e-P in Nylon. Pixamine dihydrochloride (N6% in this table) is determined as follows: hydrolyze the weighed sample (by refluxing in 6N HCi), then add 4 -Glycobutanoic acid as an internal standard. Dry the sample and methylate the carboxylic acid end (with anhydrous methanol 3N HC5) and the amine end with trifluoroacetic anhydride / CH2Ci ^ 2 in a 1/1 volume ratio trifluoroethylene acetylation After the solvent and excess reagents are evaporated, the residue is taken in MeOH and gas chromatography is used, such as Hewlett Packard 57 1 0 A, White Hewlett Packard Co., Palo Alto, CA, with Flame Ionization Detector, ( Please read the precautions on the back before filling out this page) Pack-line. Too ".ί & Κ 泞 IS Ψ @ 3 铒 格 m〇x297 (public goods) -39-200534

66 AB 經濟部中央標準局貝工消费合作社印製 五、發明説明（3β 用Supelco 6-foot X 4mm ID玻璃管柱，其填有1 〇% SP2 1 00 於 80 / 1 00 Supe 1 copo r t 上， 售自3叩-elco Co.，Bellefonte，PA。許多氣體層析儀，管柱，及 載髏皆適於此測量。衍生6 _胺己酸峰對衍生6 -胺丁酸 峰之面積比藉校正曲線轉換成mg 6耐綸，然後計算 w t . % 6耐编。 M e 5 - 6量(重量百分比）（在表中記為MPMD %)藉在1〇〇υ在含20mi?濃鹽酸及5mi2水之溶液 中加熱片狀，膜狀，纖狀，或其他形式之兩克聚合物而決 物。然後將溶液冷至室溫，己二酸澱出並可移出。（若存 有任何T i 0 2，則應藉過濾或離心移除）。1 m j?此液 以在水中之33%氫氣化鈉中和。lmj?乙睛添加 於中和液中並搖盪混合物。形成兩相。二胺（MPMD及 HMD)在上相。此上相以氣體層析分析諸如使用 具30米DB — 5管柱（95%二甲聚矽氣烷/5%二苯 基聚矽氧烷）之毛細氣體層析，雖有其他管柱及載體適於 本測量。適當溫度程序為1 00104分鐘，然後以8Ϊ：/ m i η之速率熱至25〇·〇。二胺在約5分鐘内由管柱提 出，MPMD先提出。重量百分比MPMD由在MPMD 及HMD峰下積分面積比計算且Me 5 — 6之重量百分比 由MPMD之重量百分比計算。 拉伸嗎力(DT33%),以每初旦尼爾之克數表示 ，在加熱下拉伸試驗纖維下測量。此簡便地藉將纱通經一 組軋锟，其以約180米/分鐘表面速度旋轉，經圓筒熱 太皈R 疳 ifi Ιίΐ Ψ Η 囷亥姐格（2〗0乂297公;W·) - 40 ~ (請先閱讀背面之注意事項再填寫本頁) 裝· -3 . 200534 五、發明説明（3¾ 管，在1 8 5 土 2 υ (在高速合纖變形中出口增益溫度之 特性），具1. 3cm直徑，1米長纱通道，然後至第二 組軋辊，其比第一組旋轉更快使纱以1. 33X拉伸比在 軋棍組間拉伸。置於熱管及第一組軋錕間之習用張力計測 量纱張力。變化傺數令人滿意地由重覆謓數決定。新纺纱 在此測量完成前老化2 4小時。拉伸嗎力@ 1 . Ο 5拉伸 bb (Ό Ύ 5%)以相同方式測量，除拉伸比為1 . 0 5 X 而非1. 33X且熱管溫度為13510而非185Ϊ：外。 使用此設定，以下式計算平均Tf割椹數（Μ .,) (〔Μ 5〕/〔旦尼爾〕） (請先閲讀背面之注意事項再填寫本頁) 裝- 經濟部中央標準局兵工消費合作社印製 (中括弧所示為平均值） Μ5變化僳數％亦以此方式得到。 泣使張力@ 1 . 〇 〇拉伸比(此稱為々沿端收縮張力 ")以同於D Τ 5 %之方式測量，除拉伸比為i . 〇 〇 X 且熱溫度為7 51外。 拉伸張力@1. 20剩餘拉伸卜卜，（πτ RDR = 1 ♦ -2-)以同於D T 5之方式得到，除拉伸比是基於 1 . 2 Ο X之剩餘拉伸比外；即， -41 200534 A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明（40 1 ◦ 0 + E s (百分比） 拉伸比--- 1 2〇 變化傜數％亦使用此數據計算。 _ . 動熊牧縮嘏力(S T )使用Kanebo Stress Tester， model KE_2L，Kanebo Engineering. LTD.，Osaka . J a-n a n 所製，且在 U . S .為 T 〇 y 〇 m e n k a A m e r i c a，I n c . o f C h a-rlotte，North Carolina經銷测量。克數張力在缠成環並 置於兩環間之七公分纱試樣上於毎旦尼爾5毫克之初預負 荷下並以每分鐘3 0攝氏度數由室溫熱至2 6 0攝氏度數 而對溫度測量。記錄最大收縮張力（g/d) (STm〃） 及在STmax之溫度，示為Τ 可偵測其他熱轉變 ! (參見圖1 ◦之詳細討論）。 纱在預伸張負荷下對漸增溫度（ΛΤ)之動態長度變 化(△ L )使用 Du Pont Thermomechan i ca 1 Ana 1 yzer ( T M A ) , m o d e 1 2 9 4 0，市售自 E . I . D u P ο n t <J e N e m o u r s and Co.，Inc.，of Wilmington，Delaware測量。紗長度 對溫度（攝氏度數）之變化（AL，％)在12. 5毫米 長之纱測量，其1 )小心置於兩壓定鋁球間，每一纖絲皆 個別保持伸直且使用徹熔裝置使切段纖絲端熔於球固定器 之外而未拉伸；2 )預拉伸至初負荷5 m g /旦尼爾以測 量收縮且300mg/旦尼爾以測量延伸；及3)以每分 (請先閱讀背面之注意事項再填寫本頁) 裝- 訂- 線- 太蚯张R疳ΙΛ Ψ因K宅熄m(CNS)平4採格（210乂297公 -42 - 200534 Λ 6 Β6 經濟部屮央標準局貝工消費合作社印製 五、發明説明（41) 鐘50度由室溫熱至300攝氏度數，在35攝氏度數之 纱長度定義為初長。長度變化（AL, %)每兩秒鐘測量 一次（即，每1. 7度）並數位記錄，然後對試樣溫度繪 圖。平均關係至少由***圖定義。較佳經纱拉伸餵入 纱在5mg/d張力下4〇t：至1 35C之溫度具有負長 度變化（即，纱收縮）。 長度對溫度之瞬時變化（AL, %) / (ΛΤ, Ό) ,此在收縮條件（5mg/d)下稱動熊时縮銮曰在延伸 條件（300mg/d)下稱動態延伸率，藉浮動平均計 算衍生自原數據且再對試樣溫度繪圖。較佳經纱拉伸餵入 纱在40*0至1351C之溫度範圍具負動態收縮率（即， 纱在初收縮後不伸長）。在延伸條件下（300ms/d 預張力負荷），發現（AL/AT)之值隨漸增溫度增加 ，在約1 10 — 14〇Ί〇達仲介最大值，在約160 — > 2 0 01C此值稍減，然後此值速降而纱於熔解前開始軟化 (參見圖7)。 （AL/ΔΤ)之仲介最大值，在約 1 10Ό-140Ϊ：間發生，此稱為（△L/^T) 且取為在應力及高溫下聚合物網移動性之測量。較佳拉伸 經纱餵入纱之（△L/AT) 在300mg/d測 量時，少於約0. 2 (%/C),較好少於約0. 15 ( %/Ό)且大於約0. 5%/°C。 聚合物網之另一重要特性為其（AL/^T) ^«^對 漸增應力之敏感性，其定義為在3〇0mg/d之ere值 之（AL/AT) 圖之正切函數（示為 (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 太祕.帒R坨W Φ因困定找rn iCNS1Ψ 4姐格（2〗0 y 297公贽） 一 43 - 200534 A6 B6 經濟部中央桴準局员工消费合作社印製 五、發明説明（42) d (AL/^T) 並在由 3mg/d 至 500mg/d預拉伸下在各試樣決定（參見圖5及6) 。選擇300mg/d應力值以定性，因其接近拉伸經紗 放鬆區中之通稱應力值（即，在圖2中棍1 7及1 8間） 0 熱拉應力(σ D )對拉伸比曲線用以模擬拉伸餓入纱 對漸增之經纱拉伸比（WDR)及拉伸溫度（Tfl )之反 應。拉伸應力（σΰ )同於DT33%般測量，除纱速減至 毎分鐘50米外，在100米長取得測量，並如本文所述 般使用不同溫度及拉伸比。拉伸應力（σ〇 )示為每拉伸 旦尼爾之克數，•即，= DT (g/d) XDR,且對 拉伸比（DR)在75°C, 125°C,及1751C繪圖（ 參見圖20)。在DR大於約1. 05 (即，高於屈服點 )至應變硬化始點（即，剩餘拉伸比（R D R ) σ約 ί 1. 25)時拉伸應力（σ〇 ),隨拉伸比線性增加，且 拉伸應力對拉伸比之最佳湊和線性圖在此稱為拉伸模數（ Μ〇 = /ADR)。拉伸應力（σ〇 )及拉伸楔數 (Me )之值隨漸增之拉伸溫度（TD )減少。期望之拉 伸應力（σΰ )及拉伸模數（Μΰ )可藉選擇餵入纱種類 及拉伸溫度（T d )控制。較佳拉伸餵入纱之拉伸應力（ σ〇 )在約1. 0及約2. 〇g/d間，且拉伸模數（ )在約3至約7g/d間，在75Ό及1. 35拉伸 bb (DR)(取自拉伸應力（σβ)對拉伸比之最佳湊和 線性圖（參見圖20及2 1)下測量。選擇75 °C之溫度 (請先閲讀背面之注意事項再塡寫本頁) 裝· 訂_ 線< 大紙铬 R Φ 因 S3 姐格（210x297公册） -44 - 200534 A 6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明（43) ,因發現大部分耐綸纺絲定向餵入纱達其最大收縮張力且 尚未開始明顯再結晶（即，此更顯示在熱再結晶改質網絡 前高於其玻璃化溫度，T g，之''初纺〃聚合物鍵網絡之 機械性）。 表觀拉伸能量(ED) α ,為拉伸模數隨漸增溫度之 減少速率（75t：, 125t：, 175*C)且定義為拉伸 模數對數，In (MD),對〔1000/(TD,t： + 2 7 3)〕之圖的斜率，呈Arrhenins型溫度依存性（即 ,Md = Aexp(Ez>/RT),其中 T 為 Kelvin 度數， R為普通氣體常數，且v A "為材料常數）。較佳拉伸餵 入纱之表觀拉伸能量（E〇) a〔 = Efl/R = △ (lnMd /△ (1000/T〇),其中 vin 度數〕約 Ο. 2 至約◦. 6 (g/d) ° K。 差示染料變化為拉伸經纱之沿端染料勻度測量且定義 ,1 為各在軸向及放射向測量之K/S變化差，其在依此述之 ΜΒΒ染料法染色之勞森（lawson)針織襪上進行。發現經 编織物之LMDR與拉伸經纱之差示染料變化（軸向K/ S變化一放射向K/S變化）成反變。發明之經纱拉伸法 平衡拉伸溫度，拉伸度，放鬆溫度，及放鬆度使拉伸經纱 成品之差示染料變化（D D V )最小。 以克數表不之張力可利用Rothschild Electronic T-ensiometer測量。Model R-1192A操作條件為：〇至1〇 0克頭；範圍=25 (顯示上為0至40克刻度）；以《- ith Lawson*Hemphi11 Tensiometer Calibration Devic— (請先閱讀背面之注意事項再填寫本頁) 太紙後Η泞试用Ψ因团宅找迆（CNS) Ψ4規格（210乂297公分） _ 45 - 200534 A 6 B6 經濟部中央標準局员工消費合作社印製 五、發明説明（44) β 售自:Lawson-Hemphill Sales > Inc.» PL Drawer 638 8, Spartansburg . SC校正 0 纱之沿端败J|_可藉Uwson-Hemph i 1 1變形纱試樣条統 (T Y T )如下測量：適當試驗器為Model 30售自Laws- on-Hemph i 1 1 Sales， Inc** Ρ· 0 - Drawer 6388， Spar t- ansburg, SC。四種纱長測量依以下順序完成：（L2 ) ；(2)在恰足以拉直纱之張力下的長度（L2) ； (3 )在極低張力下加熱以進一步發展收縮之長度（L3); (4)在恰足以拉直線之張力下之最終纱長（L< )。收 縮以下式計算： L 2 — L· 4 收縮（％ ) = -X 1 0 0 L 2 I 奮施例1 A_E部分說明在以低捲速下紡纱之餵入纱拉伸並放 鬆所製之耐编平纱所織之織物染色後的不良織物外觀。此 種纱，其不能令人滿意地用於駸格染色應用，相信因為沿 端之染料攝取變化，其比習用纺拉法所製之完全拉伸纱更 糟，而致不良織物外觀。F — K部分說明發明方法及可使 用發明所製之纱得到之優越L M D R值。 Α部分一 bh較 太/ii? HI Ψ 因 格（21(1x297公帑） -46 ~ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局员工消费合作社印製 200534 Λ 6 --________Β_6_五、發明説明（45) 耐綸6 (RV〜46)在270<1〇熔體溫度纺經具 傾長〇. 〇22 〃且直徑〇. 〇15 〃之毛細管的纺 *絲板。驟冷絲道具有平均速度為每分鐘〜6 7英尺（ fPm)横流之201C驟冷風。其使用590mprri之極 低捲取速率紡絲且在紡絲過程中不機械拉伸。此纱可稱為 *低定向纱〃（L Ο Y)。在纖絲會聚後施加整理劑，但 不交織。形成之134旦尼爾纱具極低定向，使其不適於 針織或機織，如約320%之高伸長度所示。 將6 7 0筒餵入纱置於裝有拉伸裝置之集中架上以製 造2 1 〃寬經平組織用之纱。集中架及拉伸裝置同於一般 用以製造纱束者。纱端經銷筘及導子，其設計使纱平行形 成經纱，然後經Barmag STF1拉伸單元，其經纱拉伸比為 3. 00,拉伸棍溫為60¾.超餵為2. 5%,放鬆溫 度為22Ϊ：,並以32〇mpm之速度捲於經軸上。形成 ί 之纱具44. 2旦尼爾且伸長度為52. 8%。 拉伸經纱束编成3 2號之經平織物並依LMD R法以 C.I. Acid Blue 80染料染色。評估染色織物之勻度並得 不可接受之LMDR4。程序細節及纱性質示於表I。 B部分一比較 具〜40 RV之耐綸6 6在2 9 〇°C熔體溫度下纺經 含有14個長◦. 022 "且直徑0. 015 〃之毛細管 之纺絲板。將纖絲驟冷並如A部分般會聚産生具表I所示 性質之1 2 5旦尼爾之餵入纱。6 7 ◦捲餵入纱如表I所 太址ifrK泞闽它找进姐格rn〇x297公..仔） -47 - (請先閲讀背面之注意事項再填寫本頁) 2〇〇53^ A 6 B6 經濟部屮央標準局貝工消費合作社印製 五、發明説明（46) 示使用Karl Mayer DSST 50機以5〇〇mpm拉伸産生具 有表I所示性質之44旦尼爾纱。當如A部分所示染以C. I. Acid Blue 80染料時，LM DR為不可接受之3. 5 Ο 、 Γ邱分一 fch較 R V〜4 2之耐编6 , 6在2 9 0 之熔體溫度纺經 具有13値長0. 022 "且直徑〇. 015 〃之毛細管 的纺絲板。驟冷絲室具有平均速率每分鐘〜68英尺 (f pm)之2 0¾横流驟冷風。纖絲在恰位於驟冷絲室 下之整理劑锟式施加器上會聚成纱。然後纱經底板間管通 至餵入棍，其提供1 500mpm之退繞速度，接著至 1. 6倍餵入锟者之速度或24OOmpm之拉伸棍。後 續棍速可稍偏離2400mpm以調整張力。以足以在稍 後有效由捲筒移除纱之程度施加交織。纱以〜◦. 2g/ d之張力捲取於管上。此纱，僅機械拉伸1. 6X,此時 僅部分定向且尚未具有能理想用於經编或機織之張力性質 且用為前述經纱拉伸操作之餵入纱。其旦尼爾為55且伸 長度為〜8 0%且可稱為部分拉伸纱（PDY)。 餵入纱在Barmag model STF1拉伸單元以1 . 3 9 X 拉伸比，60Ϊ：拉伸溫度，5%超餵，120*0放鬆溫度 下經纱拉伸並以500mpm捲成束。形成之纱具42之 旦尼爾及3之伸長度。 拉伸經纱编成經平織物，以C.I. Acid Blue 122染料 太/« iA Ψ K @3玄找迆（CNSVP4ffi^(210x297公货） _ 48 ~ (請先閲讀背面之注意事項再填寫本頁) 裝· 訂. -線- 200534 A 6 B 6 經濟部屮央標準局员工消贤合作社印製 五、發明説明（47) 染色，並評估LMDR。LMDR為不可接受之4, 4。 程序細節及纱性質示於表I。 D部分一比較 餵入纱如C部分所述般製備，除RV為44外，餵入 锟（退繞）速率為1849mpin,捲速為 3217mpm,拉伸比為1. 74X。此例中餵入纱為 53旦尼爾/13纖絲，具74%之伸長度及58之拉伸 張力。 餵入纱在Karl Mayer DSST 50單元上以1 . 3 5 X拉 伸比經纱拉伸，拉伸锟溫為7 Ot：。拉伸纱5%超餵於引 出棍，在129t：拉伸棍及引出锟間放鬆，並於 500mpm捲束。形成之PDY纱具4 1旦尼爾及 〜4 0 %伸長度。 拉伸經纱束在32號經平编織機上编成經编織物。織 物使用C.I. Acid Blue 80染料染色並評估L M DR勻度 。得到不可接受之LMDR3。程序細節及纱性質示於表 I 〇 Ε部分一 fch較 餵入纱如C部分所述般製備，除RV為45外，餵入 棍（退繞）速率為1 937mpm,捲速為 3245mpm,拉伸比為1. 68X。此例中餵入纱為 95旦尼爾/34纖絲，具67%之伸長度且其他性質示 太蚯?&R 泞 1AIT, Ψ因因格（210x297公处） —49 一 (請先閲讀背面之注意事項再填寫本頁) 200534 經濟部屮央標準局员工消#合作社印製 五、發明説明（48) 於表I。 餵入纱在Barmag型STF1單元上以1. 43X拉伸 比經纱拉伸，拉伸锟溫為6 0C。拉伸纱5%超餺於引出 棍，在22它拉伸棍及引出棍間放鬆，並於 5〇0mpm捲束。形成之PDY纱具72. 7旦尼爾及 〜3 4 . 2 %伸長度。 拉伸經纱束在32號經平编織機上编成經编織物。織 物使用C.I. Acid Blue 80染料染色並評估LMDR勻度 。得到不可接受之LMDR3。程序細節及纱性質示於表 I 〇 F部分—[：h較 RV〜42之耐綸6, 6在290 °C之熔體溫度纺經 具有17長0. 022 〃且直徑0. 015 "之毛細管的 纺絲板。驟冷絲室具有平均速率〜67f pm之20t：橫 流驟冷風。纖絲在恰位於驟冷絲室下之整理劑輥式施加器 上會聚成纱。然後纱經底板間管通至餵入锟，其提供28 18m pm之退繞速度，接著至1. 26倍餵入棍者之速 度或355 lmpm之拉伸棍。後鑕锟速可稍偏離 3 5 5 1 m p m以調整張力。並施加交織。纱以約 355 1及〜0. 2g/d之張力捲取於管上。結果旦尼 爾為5 5且伸長度為〜6 0%且拉伸張力為5 9 g。 紗在Barmag model STF1拉伸單兀以1 . 2 9 X拉伸 比，60t：拉伸溫度，6%超餵，221C放鬆溫度下經纱 (請先閲讀背面之注意事項再場寫本頁) 裝< 訂· 線. 太蚯帒尺泞1Λ用Ψ因因宅 -50 - 200534 經濟部屮央標準局負工消费合作社印製 A 6 B6 五、發明説明（49) 拉伸並以550mpm捲成束。形成之纱具45. 5之旦 尼爾及28. 5%之伸長度。 拉伸經纱编成經平織物，以C.I. Acid Blue 122染料 依LMDR法染色，並評估勻度。勻度级數為優越之7. 8 〇 G部分一發明 具〜50RV之耐綸6, 6在290t熔融溫度紡經 具17個腳長0. 015 〃且腳寬0. 004 "之三葉形 毛細管之紡絲板。驟冷道具有平均速度〜1 27 f pm之 200驟冷横冷風。纖絲在恰位於驟冷單元下之整理锟施 加器上會集成纱。然後纱經底板間之管至速度3 9 0 9m Pm (退繞速度）之未驅動氣承分離锟並施以交織。纱以 3909mpm及〜◦. 2gpd張力捲於管上。因此， 無機械拉伸。結果為5 5旦尼爾三葉形交叉餺入纱，其未 適當拉伸但，因高速紡絲産生之張力，纱在驟冷區中充分 定向産生85%伸長度及40g拉伸張力。因此，可稱為 ''紡絲定向纱"（S O Y )。 餵入纱在Barmag STF1拉伸單元上以1. 316X拉 伸比，60*C拉伸溫度，5%超餵經拉，在室溫放鬆，並 以550mpni之速度捲束。形成之拉伸纱具43. 8旦 尼爾及53.1%伸長度。 拉伸纱编成經平織物，依LMDR法以C.I. Acid B-1 ue 80染料染色，並評估勻度。LMDR為優越之7. 1 。方法及纱性質之細節示於表1。 (請先閲讀背面之注意事項再填寫本頁) 裝- 訂 太Ψ囷因宅找迆（CNSVP4组格（210x297公分） _ 51 - 200534 A 6 B6 經濟部屮央標準局员工消#合作社印製 五、發明説明（50) Η部分一發明 具〜50RV之耐綸6, 6在29〇t：熔融溫度纺經 具17個長〇. 022 〃且直徑0. 015 〃之毛細管之 纺絲板。驟冷道具有平均速度〜6 7 f pm之2 Ot：驟冷 橫冷風。纖絲在恰位於驟冷單元下之整理棍施加器上會集 成纱。然後纱經底板間之管至速度3954mpm (退繞 速度）之未驅動氣承分離锟並施以交織。纱以3989m pm及〜〇. 2gpd張力捲於管上。因此，機械拉伸在 1. 009X不明顯。結果為52旦尼爾餵入纱，其未適 當拉伸但，因高速紡絲産生之張力，纱在驟冷區中充分定 向産生7 8%伸長度及40 g拉伸張力。因此，可稱為'' 纺絲定向纱〃（SOY)。 餌入纱在Barmag STF1拉伸單元上以1 . 4 5 X拉伸 I 比，60t：拉伸溫度，6%超餵經拉，在221放鬆，並 以55〇mpm之速度捲束。形成之拉伸纱具39. 6旦 尼爾及30. 6%伸長度。 拉伸纱编成經平織物，依LMDR法以C.I. Acid B-lue 80染料染色，並評估勻度。LMDR為優越之7. 4 。方法及纱性質之細節示於表1。 I部分一發明 具46RV之耐编6在275¾熔融溫度紡經具1〇 値長0. 010 〃且直徑◦. 020 〃之毛細管之纺絲板 (請先閲讀背面之注意事項再填寫本頁) 裝. 太蚯帒r iA ffl屮团S3 :找谁i CNS W7 4组格（210 y 297公焙） -52 - 200534 A 6 B6 經濟部中央標準局员工消费合作社印製 五、發明説明（51) 。驟冷道具有平均速度〜67f pm之20¾驟冷樓冷風 。纖絲在恰位於驟冷單元下之整理锟施加器上會集成纱， 然後纱經底板間之管其速度4200mpm (退繞速度） 且張力〜0. 2gpd而捲於管上。SOY纱無機槭拉伸 ，其在捲取前未經任何棍，因高速纺絲産生之張力，纱在 驟冷區中充分定向産生〜67. 5%%伸長度及42. 8 拉伸張力。纱旦尼爾為4 6。 餵入纱在Karl Mayer DSST 50拉伸單元上以1 . 2 3 X拉伸比，801C拉伸溫度，6. 7%超餵經拉，在12 0Ό放鬆，並以50〇mpm之速度捲束。形成之拉伸纱 具40旦尼爾及42%伸長度。 拉伸纱编成經平織物，依LMDR法以C.I. Acid B-lue 122染料染色，並評估勻度。LMDR為優越之 7 . 4 〇 J部分一發明 RV為65耐綸6， 6如F部分所述般製備，除捲取 (退繞）速率為5300mpm外。形成之13纖絲 SOY餵入纱為50. 5旦尼爾，具73. 5%之伸長度 及6 3之拉伸張力。 餵入纱在Bar mag STF1拉伸單元上以1 . 1 5 X拉伸 比，拉伸锟溫為60¾。 5%超餵經拉，在22¾放鬆， ◦ 〇mpni捲束。形成之拉伸纱具46. 5尼爾及47% 伸長度。 太紙汴尺泞用Φ因K宅熄课（CNS)屮4组格（210乂297公讣） -53 - (請先閲讀背面之注意事項再填寫本頁) 裝· 線· 200534 A 6 B 6 五、發明説明（52) 拉伸經纱编成經平織物。織物使用C.I. Acid Blue 80染料依LMDP法染色並評估勻度。匀度级數為優越之 7 . 6 〇 K部分一發明 耐綸66共聚物，95moJ2% (聚（己二醯己二胺 )及5%重ε —己醯胺單元，RV為65，如例J般製備 。形成之經拉用13纖絲SOY餵入纱為50.◦旦尼爾 ,76. 1%伸長度，及63g拉伸張力。 餵入纱在BarmagSTFl拉伸單元上以1. 3 0X拉伸 比，60Ό拉伸溫度，5%超餵拉伸，在1181C放鬆並 在550mpm捲速。形成之拉伸紗旦尼爾為39. 5且 伸長度為4 1 . 7 %。 拉伸纱編成經平織物，依LMDR法以C.I. Acid B-lue 80染料染巴，並評估勻度。勻度级數為優越之7. 6 (請先閲讀背面之注意事項再填寫本頁) 裝· 線· 經濟部屮央標準局员工消費合作社印製 太紙花κ玢iA ill Φ团团玄捃進f CNS1 Ψ 4姐格（210 X 297公货） 一 54* - 200534 A 6 B6 經濟部中央標準局员工消#合作社印製 五、發明説明（53) 實施例I-部分 A 表I 比較 B C 纺速，mpm 590 889 1500 紡拉比 1.00 1.00 1.60 餵入纱 耐綸聚合物種類 6 6,6 6*6 旦尼爾 134 125 55 纖絲 13 14 13 RV 46 40 42 伸長度，％ 320 250 80 (RDR)?· 4.2 3.5 3.5 1.80 (RDR)5 4.2 2.88 韌度，s/d 1.1 N/A 2.99 模數，g/d N/A N/A 8.2 DT 3 3 * g N/A 49 36.5 DT33,%CV N/A 1.0 1.3 DT33.g/d N/A 0.52 0.66 DVA,%CV N/A N/A .40 USTER,% N/A N/A N/A 經纱拉伸條件 WD單元 BARMAG MAYER BARMAG WD速度，mpm 320 500 500 WD比 3.00 3.00 1.39 WD溫度1C 60 85 60 超餵，％ 2.5 9 5 加熱器溫度，°C 無 180 130 放鬆溫度，t 22 161 120 拉伸纱性質 旦尼爾 44.2 44 42 伸長度，％ 52.8 48 30 (RDR)z) 1.528 1.48 1.30 度，s/d 3.70 4.1 N/A 模數，g/d 19.4 20 N/A DVA %CV 1.42 N/A N/A USTER，％ N/A N/A N/A 沸溶收縮4 10.8 3.5 3.5 N/A 级數 4 4.4 5 3 1 5 · 4 3 1 32 D 1849 1.736,6 53 13 44 74 1.74 3.01 4.14 16.6 58 .87 1.09 N/A N/A MAYER 500 1.35 70 5 140 129 A A 4 ο / / · · E 1937 1.686,6 95 34 45 67 1.67 2.81 3.9 N/A 114 1.31.20 N/A N/A BARMA 550 1.43 60 5無 /\\\ 22 72.7 34.2 1.342 5.19 24.2 .47 N/A 7.6 3.0 (請先閱讀背面之注意事項再塡寫本頁) 裝- -5 * 線· -55 - 200534 A 6 B 6 五、發明説明fe4) 經濟部中央標準局员工消f合作社印製 實施例I-部分 F 通 G H I J 纺速，mpm 2818 3909 3954 4200 5300 纺拉比1 1.26 1.00 1.009 1.00 1.00 餵入纱 耐綸聚合物種類 6 6,6 6.6 6 6,6 旦尼爾 55 55 52 46 50.5 纖絲 17 17 17 10 13 RV 42 50 50 46 65 伸長度3 60 85 78 67.5 73.5 (RDR)?· 1.60 1.85 1.78 1.675 1.735 (RDR)s 2.02 1.85 1.80 1.675 1.735 韌度，s/d 3.6 2.97 2.88 4.3 4.23 模數，g/d 18.5 12.8 12.7 N/A 14.3 DT3 3 *g 63 41.9 43.4 42.8 63.5 dt33，％cv .63 .36 .30 〜1.0 .39 DT33 »g/d 1.15 0.76 0.83 0.93 1.26 DVA,%CV .38 .27 .41 N/A .46 USTER,% .82 .68 • 63 .91 .62 經纱拉伸條件 WD單元 BARMAG BARMAG BARMAG MAYER BARMA WD速度，mpm 550 550 550 500 550 WDfcb 1.29 1.316 1.45 1.23 1.15 WD溫度°C 60 60 60 80 60 超餓，％ 6 5 6 6.7 5 加熱器溫度，°C frrr 雛 130 -fnf M 130 無 放鬆溫度*°c 22 118 22 120 22 拉伸纱性質 旦尼爾 45.5 43.8 39.6 40 46.5 伸長度3 28.5 53.1 30.6 42 47 (RDR)〇 1.285 1.531 1.306 1.42 1.47 ϋ 度，g/d 4.3 3.87 4.16 4.89 4.51 模數，g/d 25.6 15.2 N/A N/A 20.9 DVA %CV .37 .35 .35 N/A .40 USTER，％ .74 N/A N/A N/A .73 沸溶收縮，％ 5.1 6.5 7.1 8.3 7.0 5.9 级數 7.8 7.4 7.4 7.6 (請先閱讀背面之注意事項再填寫本頁) 裝- -線- -56 - 200534 A 6 B 6 五、發明説明（55) 表I (續) 發明 經濟部中央標準局貞工消費合作社印製 實施例I-部分 K 紡速，mpm 5300 紡拉比1 1.00 餵入纱 耐编聚合物種類 95%/5% 66/6 旦尼爾 50.5 纖絲 13 RV 65 伸長度 76.1 (RDR)f 1.761 (RDR)s 1.761 韌度，g/d 4.24 模數，g/d 13.7 DT33 >8 58.8 DT33，%CV .41 DT33.g/d 1.18 DVA,%CV .46 USTER,% .70 經纱拉伸比 WD單元 BARMAG WD速度，mpm 550 WD比 1.30 WD溫度1C 60 超餵，％ 5 加熱器溫度，°C 130 放鬆溫度，°C 118 拉伸纱性質 旦尼爾 39.5 伸長度，％ 41.7 (RDR)0 1.417 韌度，s/d 5.27 模數，g/d 21.8 DVA %CV .45 USTER，％ .73 沸溶收縮，％ 7.5 级數 7.6 (請先閲讀背面之注意事項再填寫本頁) -裝· J5 ' 線- -57 - 200534 A6 _ B6 五、發明説明（56)66 AB Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (3β Supelco 6-foot X 4mm ID glass column filled with 10% SP2 1 00 on 80/1 00 Supe 1 copo rt , Sold from 3 knock-elco Co., Bellefonte, PA. Many gas chromatographs, columns, and crossbones are suitable for this measurement. The ratio of the area of the derived 6-aminocaproic acid peak to the derived 6-aminobutyric acid peak The calibration curve is converted into mg 6 nylon, and then calculate the wt.% 6 resistant knitting. The amount of M e 5-6 (weight percentage) (marked as MPMD% in the table) is borrowed at 100 ℃ with 20ml of concentrated hydrochloric acid and Heat two grams of polymer in the form of 5mi2 water, flake, film, fibrous, or other forms. Then cool the solution to room temperature, adipic acid is deposited and can be removed. i 0 2 should be removed by filtration or centrifugation). 1 mj? This solution is neutralized with 33% sodium hydroxide in water. lmj? Acetonitrile is added to the neutralization solution and the mixture is shaken. Two phases are formed. Two Amine (MPMD and HMD) is in the upper phase. This upper phase is analyzed by gas chromatography such as using a 30 m DB-5 column (95% dimethiconane / 5% diphenylpolysiloxane) ) Capillary gas chromatography, although there are other columns and carriers suitable for this measurement. The appropriate temperature program is 100104 minutes, and then heated to 25〇 · 〇 at a rate of 8Ϊ: / mi η. Diamine in about 5 minutes It is proposed by the column and MPMD first. The weight percentage MPMD is calculated by the integral area ratio under the peaks of MPMD and HMD and the weight percentage of Me 5-6 is calculated by the weight percentage of MPMD. The tensile strength (DT33%) is calculated every time Denier grams is measured under the tensile test fiber under heating. This is simply by passing the yarn through a set of rollers, which rotates at a surface speed of about 180 meters / minute and passes through the cylinder. ifi Ιίΐ Ψ Η 囷 海 姐 格 （2〗 0 侂 297 Gong; W ·)-40 ~ (please read the precautions on the back and then fill out this page) 装 · -3. 200534 V. Description of the invention (3¾ tube, in 1 8 5 soil 2 υ (characteristic of outlet gain temperature in high-speed synthetic fiber deformation), with 1.3 cm diameter, 1 meter long yarn channel, and then to the second group of rollers, which rotates faster than the first group to make the yarn 1. The 33X draw ratio is stretched between the roller groups. A conventional tensiometer placed between the heat pipe and the first group of rollers to measure the yarn The change in the number of yes is satisfactorily determined by the number of repeats. The new spun yarn is aged 24 hours before this measurement is completed. Stretching force @ 1. Ο 5 Stretching bb (Ό Ύ 5%) in the same way Measured, except that the draw ratio was 1.05X instead of 1.33X and the heat pipe temperature was 13510 instead of 185Ϊ :. Using this setting, calculate the average number of Tf cuts (Μ.,) (〔Μ 5〕 / [DENIER]) (Please read the precautions on the back before filling in this page) Printed by industrial and consumer cooperatives (the average value shown in parentheses) The 5% change rate of M5 is also obtained in this way. Weeping tension @ 1. 〇〇 Stretching ratio (referred to as 々 shrinkage tension along the end ") is measured in the same manner as D Τ 5%, except that the stretching ratio is i. 〇〇X and the thermal temperature is 7 51 outer. Tensile tension @ 1. 20 Remaining stretch, (πτ RDR = 1 ♦ -2-) is obtained in the same way as DT 5, except that the stretch ratio is based on the remaining stretch ratio of 1.2 Ο X; That is, -41 200534 A 6 B6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (40 1 ◦ 0 + E s (percentage) Stretching ratio --- 1 2〇% of the change is also used here Data calculation. _. The dynamic bear animal husbandry contraction force (ST) is made by Kanebo Stress Tester, model KE_2L, Kanebo Engineering. LTD., Osaka. J an an, and in U. S. Is T 〇y 〇menka A merica , I nc. Of C ha-rlotte, North Carolina dealership measurement. The gram tension is on a seven-centimeter yarn sample wound into a loop and placed between the two loops under an initial preload of 5 mg per denier The number of 30 degrees Celsius in minutes is from room temperature to 260 degrees Celsius and the temperature is measured. Record the maximum contraction tension (g / d) (STm〃) and the temperature at STmax, shown as T can detect other thermal transitions! ( (See Figure 1 for a detailed discussion). Under the pre-stretch load, the yarn uses Du P for the dynamic length change (ΔL) of the increasing temperature (ΛT) Ont Thermomechanics ca 1 Ana 1 yzer (TMA), mode 1 2 9 4 0, commercially available from E.I. D u P ο nt < J e N emours and Co., Inc., of Wilmington, Delaware. The change in yarn length to temperature (degrees Celsius) (AL,%) is measured at a yarn length of 12.5 mm. 1) Carefully placed between two pressed aluminum balls. Each filament is kept straight and used thoroughly. The melting device melts the cut filament ends outside the ball holder without stretching; 2) pre-stretching to an initial load of 5 mg / denier to measure shrinkage and 300 mg / denier to measure extension; and 3) Per minute (please read the precautions on the back before filling out this page) Packing-Ordering-Line-Taizhang Zhang R 疳 ΙΛ Ψ Because K House Extinguishing m (CNS) Flat 4 Caige (210 297297-42-200534 Λ 6 Β6 Printed by Beigong Consumer Cooperatives, Bureau of Standards, Ministry of Economic Affairs V. Invention description (41) 50 degrees from room temperature to 300 degrees Celsius, the yarn length at 35 degrees Celsius is defined as the initial length. The change in length (AL ,%) Is measured every two seconds (ie, every 1.7 degrees) and recorded digitally, and then the sample temperature is plotted. The average relationship is defined by at least three representative graphs. It is preferable that the warp yarn is drawn and fed. The yarn has a negative length change (i.e., yarn shrinkage) at a temperature of 135 ° C at a tension of 5 mg / d: to a temperature of 135 ° C. The instantaneous change of length to temperature (AL,%) / (ΛΤ, Ό), this is called dynamic elongation under contraction condition (5mg / d) and dynamic extension rate under extension condition (300mg / d). The floating average calculation is derived from the original data and the temperature of the sample is plotted again. Preferably, the warp yarn is drawn and fed. The yarn has a negative dynamic shrinkage rate in the temperature range of 40 * 0 to 1351C (that is, the yarn does not stretch after the initial shrinkage). Under extended conditions (300ms / d pre-tension load), it is found that the value of (AL / AT) increases with increasing temperature, reaching the maximum value of the medium at about 1 10 -14 Ί〇, at about 160 — > 2 0 01C This value decreases slightly, then this value drops rapidly and the yarn begins to soften before melting (see Figure 7). The maximum value of the medium of (AL / ΔΤ) occurs between about 1 10Ό-140Ϊ: this is called (△ L / ^ T) and is taken as a measure of the mobility of the polymer network under stress and high temperature. The preferred tensile warp yarn feed (△ L / AT) is less than about 0.2 (% / C) when measured at 300 mg / d, preferably less than about 0.15 (% / Ό) and greater than About 0.5% / ° C. Another important characteristic of the polymer network is its (AL / ^ T) ^ «^ sensitivity to increasing stress, which is defined as the tangent function of the (AL / AT) graph at the ere value of 300 mg / d ( Shown as (please read the precautions on the back before filling in this page). Packing and ordering are too secret. 帒 R 坨 W ΦFind it because of difficulties iCNS1Ψ 4 sister grid (2〗 0 y 297 Gongzhi) I 43-200534 A6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economy V. Description of invention (42) d (AL / ^ T) and determined on each sample under pre-stretching from 3 mg / d to 500 mg / d (see Figures 5 and 6 ). Choose a stress value of 300mg / d for qualitative, because it is close to the general stress value in the relaxation zone of the stretched warp (ie, between rods 1 and 8 in Figure 2). 0 Thermal tensile stress (σ D) for stretching The ratio curve is used to simulate the response of the drawn yarn to the increasing warp yarn draw ratio (WDR) and drawing temperature (Tfl). The tensile stress (σΰ) is measured as the same as DT33%, except the yarn speed is reduced to Measurements are taken at a length of 100 meters, 50 meters away every minute, and using different temperatures and draw ratios as described in this article. The tensile stress (σ〇) is shown as grams per denier of stretch, ie, = DT (g / d) XDR, and pull The ratio (DR) is plotted at 75 ° C, 125 ° C, and 1751C (see Figure 20). At DR greater than about 1.05 (ie, above the yield point) to the beginning of strain hardening (ie, the remaining stretch ratio ( RDR) σ about ί 1. 25), the tensile stress (σ〇) increases linearly with the tensile ratio, and the best sum of the linear relationship between the tensile stress and the tensile ratio is called the tensile modulus (Μ 〇 = / ADR). The values of tensile stress (σ〇) and tensile wedge number (Me) decrease with increasing tensile temperature (TD). Desired tensile stress (σΰ) and tensile modulus (Μΰ) ) It can be controlled by selecting the type of feeding yarn and the drawing temperature (T d). The tensile stress (σ〇) of the preferably drawn feeding yarn is between about 1.0 and about 2. 〇g / d, and The tensile modulus () is between about 3 and about 7 g / d, and the bb (DR) (derived from the tensile stress (σβ) vs. the draw ratio is the best linear graph (refer to the figure 20 and 2 1) Measure below. Select a temperature of 75 ° C (please read the precautions on the back before writing this page) Binding · Order _ Line & Large Paper Chromium R Φ Due to S3 Sister (210x297 booklet)- 44-200534 A 6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Inventions Explanation (43), because it is found that most of the nylon spinning feed yarn reaches its maximum shrinkage tension and has not begun to recrystallize significantly (ie, this shows that it is higher than its glass transition temperature before the thermal recrystallization modification network, T g, the "mechanical nature of the initial spinning" polymer bond network). The apparent tensile energy (ED) α is the rate of decrease of the tensile modulus with increasing temperature (75t :, 125t :, 175 * C) and is defined as the logarithm of the tensile modulus, In (MD), for [1000 / (TD, t: + 2 7 3)] The slope of the graph is Arrhenins-type temperature dependence (ie, Md = Aexp (Ez> / RT), where T is the Kelvin degree, R is the ordinary gas constant, and v A " is the material constant). The apparent stretching energy (E〇) a [= Efl / R = △ (lnMd / △ (1000 / T〇), where vin degrees] is about 〇. 2 to about ◦. 6 ( g / d) ° K. Differential dye change is the measurement and definition of the dye uniformity along the end of the stretched warp yarn, 1 is the difference between the K / S changes in each axial and radial measurement, which is described in the MBB It was carried out on the Lawson knitted socks dyed by the dye method. It was found that the difference in the dye between the LMDR of the warp knit and the drawn warp yarn (the axial K / S change-the radial direction K / S change) was reversed. The warp yarn drawing method balances the drawing temperature, the degree of stretching, the relaxation temperature, and the degree of relaxation to minimize the differential dye change (DDV) of the finished warp yarn. The tension expressed in grams can be used by Rothschild Electronic T- ensiometer measurement. The operating conditions of Model R-1192A are: 0 to 100 grams head; range = 25 (the display is 0 to 40 grams scale); with "-ith Lawson * Hemphi11 Tensiometer Calibration Devic— (please read the back Please fill out this page again after you have noticed.) Too paper after Η 択 trial Ψ because the group home finds (CNS) Ψ 4 specifications (210 to 297 cm) _ 45-200534 A 6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of Invention (44) β Sold by: Lawson-Hemphill Sales &Inc; »PL Drawer 638 8, Spartansburg. SC correction 0 Yarn's edge failure J | _available The Uwson-Hemph i 1 1 textured yarn sample line (TYT) is measured as follows: the appropriate tester is Model 30 sold from Laws-on-Hemph i 1 1 Sales, Inc ** Ρ · 0-Drawer 6388, Spare t-ansburg , SC. The four yarn length measurements are completed in the following order: (L2); (2) The length under the tension just enough to straighten the yarn (L2); (3) Heating under extremely low tension to further develop the length of shrinkage (L3); (4) Final yarn length (L <) under tension just enough to draw a straight line. Shrinkage is calculated by the following formula: L 2 — L · 4 Shrinkage (%) = -X 1 0 0 L 2 I Example 1 Section A_E illustrates the poor fabric appearance after dyeing of the fabric woven with the knitted flat yarn that is spun at a low winding speed and relaxes the appearance of the fabric. This kind of yarn cannot be used satisfactorily It is believed that in the application of Singe dyeing, it is worse than the fully drawn yarn made by conventional spinning and drawing because of the change of dye uptake along the end, which is undesirable The appearance of the fabric. Sections F-K illustrate the inventive method and the superior LM D R value that can be obtained by using the yarn made by the invention. Part Ⅰbh is too much / ii? HI Ψ Inge (21 (1x297 public money) -46 ~ (please read the notes on the back before filling this page) Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 200534 Λ 6- ________ Β_6_ V. Description of the invention (45) Nylon 6 (RV ~ 46) is spun at a melt temperature of 270 < 10 with a capillary spinning tube with a length of 0.022 〃 and a diameter of 0.015 〃. The quenched yarn path has 201C quench air with an average speed of ~ 67 feet per minute (fPm). It uses a very low winding rate of 590mprri and is not mechanically stretched during the spinning process. This yarn can be called * Low-oriented yarn〃 (L Ο Y). Finishing agent is applied after the filaments converge, but they are not interwoven. The formed 134 denier yarn has very low orientation, making it unsuitable for knitting or weaving, such as about 320% high The elongation is shown. Place 6 70 bobbin feeding yarn on a concentrating rack equipped with a stretching device to produce 2 1 〃 wide warp and weave yarn. The concentrating rack and stretching device are generally used to make yarn Beamer. The yarn end is distributed by the reed and the guide, which are designed to make the yarn parallel to form the warp, and then through the Barmag STF1 stretching unit, the warp is drawn The stretch ratio is 3. 00, the stretching stick temperature is 60¾. The overfeed is 2.5%, the relaxation temperature is 22Ϊ :, and it is wound on the warp beam at a speed of 32〇mpm. The yarn is formed 44.2 denier Neil with an elongation of 52.8%. Stretched warp yarns are knitted into No. 32 warp plain fabric and dyed with CI Acid Blue 80 dye according to the LMD R method. The uniformity of the dyed fabric is evaluated and unacceptable LMDR4 is obtained ．Procedure details and yarn properties are shown in Table I. Part B compares a nylon 6 with a RV of 40 to 6 spinning at a melt temperature of 290 ° C. It contains 14 long warps. 022 " and a diameter of 0.015 〃 Spinning plate of capillary tube. The filaments are quenched and condensed as part A to produce a 1 25 denier feed yarn with the properties shown in Table I. 6 7 ◦The roll feed yarn is as shown in Table I Address ifrK 択 MinIt finds the elder sister rn〇x297 public ..)) -47-(please read the notes on the back before filling out this page) 2〇53 ^ A 6 B6 Ministry of Economic Affairs, Bureau of Standards, Peking consumption Printed by the cooperative. Fifth, the invention description (46) shows that a Karl Mayer DSST 50 machine was used to draw at 500 mpm to produce 44 denier yarns with the properties shown in Table I. When dyed with CI Acid Blue 80 dye as shown in Part A, LM DR is unacceptable 3.5 Ο, Γ Qiufenyi fch is more resistant to RV ~ 4 2 than 6, 6 at 2 9 0 melt temperature A spinning plate having a capillary tube with a 13-length length of 0.022 " and a diameter of 0.015 〃. The quench wire chamber has an average rate of ~ 68 feet per minute (2 pm) cross flow quench air. The filaments converge into a yarn on the finisher roller applicator located just below the quench filament chamber. The yarn then passes through the tube between the base plates to the feeding rod, which provides an unwinding speed of 1 500 mpm, and then to 1.6 times the speed of the feed roller or the stretching rod of 2400 mpm. The follow-up stick speed can deviate slightly from 2400mpm to adjust the tension. The interweave is applied to an extent sufficient to effectively remove the yarn from the package at a later time. The yarn is wound on the tube with a tension of ~. 2g / d. This yarn is only mechanically stretched at 1.6X, at this time it is only partially oriented and does not yet have the tensile properties that are ideal for warp knitting or weaving, and is used as the feed yarn for the aforementioned warp yarn stretching operation. It has a denier of 55 and a stretch length of ~ 80% and can be called a partially drawn yarn (PDY). The feed yarn was drawn in a Barmag model STF1 drawing unit at a stretch ratio of 1.39 X, 60Ϊ: drawing temperature, 5% overfeed, warp drawing at 120 * 0 relaxation temperature and winding into bundles at 500 mpm. The resulting yarn 42 has a denier of 3 and an elongation of 3. Stretch the warp yarn into a warp flat fabric, using CI Acid Blue 122 dyestuff / «iA Ψ K @ 3 玄 找 翤 (CNSVP4ffi ^ (210x297 public goods) _ 48 ~ (please read the precautions on the back before filling this page ) Installation and ordering. -Line- 200534 A 6 B 6 Printed by the Xiaoxian Cooperative of the Staff of the Central Standards Bureau of the Ministry of Economic Affairs 5. Invention description (47) Dyeing and evaluation of LMDR. LMDR is unacceptable 4, 4. Procedure details and Yarn properties are shown in Table I. Part D is a comparison. The feed yarn is prepared as described in Part C, except that the RV is 44, the feed roller (unwinding) rate is 1849mpin, the winding speed is 3217mpm, and the draw ratio is 1. 74X. In this example, the feed yarn is 53 denier / 13 filaments, with 74% elongation and 58 tensile tension. The feed yarn is on a Karl Mayer DSST 50 unit with a stretch ratio of 1. 3 5 X The warp is stretched, and the temperature of the drawn roller is 7 Ot :. 5% of the drawn yarn is over-fed to the draw-out roller, and at 129 t: the drawn roller and the drawn-back roller are relaxed, and bundled at 500 mpm. The formed PDY yarn 4 Denier and ~ 40% elongation. Stretched warp yarn bundles are knitted into warp knitting on No. 32 warp knitting machine. The fabric is dyed with CI Acid Blue 80 dye and evaluated for LM DR uniformity. To the unacceptable LMDR3. The details of the procedure and the yarn properties are shown in Table I. Part F. The fch is prepared as described in Part C compared to the feeding yarn. Except for the RV of 45, the feeding stick (unwinding) rate is 1 937 mpm, The winding speed is 3245mpm and the draw ratio is 1.68X. In this case, the feed yarn is 95 denier / 34 filaments, with 67% elongation and other properties show too earthworm? &Amp; R 泞 1AIT, Ψ causes Inge (210x297 public office) — 49 1 (please read the notes on the back before filling in this page) 200534 Printed by the Ministry of Economic Affairs, Bureau of Standards, Employee Consumers #Cooperative V. Description of invention (48) on table I. Feed the yarn On the Barmag STF1 unit, the warp yarn is stretched at a stretch ratio of 1.43X, and the stretching temperature is 60 ° C. The stretched yarn is 5% super-branched in the draw-out stick, and relaxes between the draw-out stick and the draw-out stick at 22 The bundle is wound at 500mpm. The formed PDY yarn is 72.7 denier and ~ 34.2% elongation. The stretched warp bundle is knitted into a warp knitted fabric on the No. 32 warp knitting machine. The fabric uses CI Acid Blue 80 dyeing and evaluation of LMDR uniformity. Unacceptable LMDR3 was obtained. The details of the procedure and yarn properties are shown in Table I 〇F part-[: h is more than RV ~ 42 nylon 6, 6 in 290 The spinning temperature at the melt temperature of ° C is a spinning plate with a capillary of 17 length 0.022 〃 and a diameter of 0.015 ". The quench wire chamber has an average rate of ~ 67f pm to 20t: cross-flow quench air. The filaments converge into yarn on the finishing roll applicator located just below the quenching filament chamber. The yarn is then passed through the tube between the base plates to the feed roller, which provides a rewinding speed of 28 18m pm, and then to 1. 26 times the speed of the feeder or the stretching rod of 355 lmpm. The rear roller speed can deviate slightly from 3 5 5 1 m p m to adjust the tension. And apply interweaving. The yarn is wound on the tube with a tension of about 355 1 and ~ 0.2 g / d. As a result, the denier was 55 and the elongation was ~ 60% and the tensile tension was 59 g. The yarn is stretched in Barmag model STF1 with a stretch ratio of 1.29 X, 60t: stretching temperature, 6% overfeed, warp yarn at 221C relaxation temperature (please read the notes on the back before writing this page) Pack < Order · Line. Taizuo Chichi 1ΛYinzhai-50-200534 Printed by the Consumer Labor Cooperative of the Bureau of Standards, Ministry of Economic Affairs A 6 B6 V. Description of the invention (49) Stretched and rolled at 550mpm Bunched up. The yarn formed was 45.5 denier and 28.5% elongation. The warp yarns were drawn into warp and flat fabrics, dyed with C.I. Acid Blue 122 dye according to the LMDR method, and evaluated for uniformity. The degree of uniformity is superior to 7.8 〇G part of the invention with a ~ 50RV nylon 6, 6 spinning at 290t melting temperature with 17 feet long 0. 015 〃 and foot width 0. 004 " three leaves -Shaped capillary spinning plate. The quench channel has an average speed of ~ 1 27 f pm of 200 quenching horizontal cold wind. The filament is integrated on the finishing applicator just below the quench unit. Then the yarn passes through the tube between the bottom plates to the undriven air bearing separation roller with speed 3 9 0 9m Pm (unwinding speed) and interweave. The yarn is wound on the tube with 3909mpm and ~. 2gpd tension. Therefore, there is no mechanical stretching. The result was a 55-denier trilobal cross-entangled yarn, which was not stretched properly. However, due to the tension produced by high-speed spinning, the yarn was sufficiently oriented in the quench zone to produce 85% elongation and 40g of tensile tension. Therefore, it can be called "spinning oriented yarn" (S O Y). The feed yarn was drawn on the Barmag STF1 drawing unit with a 1.316X draw ratio, 60 * C drawing temperature, 5% overfeed warp drawing, relaxed at room temperature, and wound at a speed of 550 mpni. The resulting drawn yarn was 43.8 denier and 53.1% elongation. The drawn yarn was knitted into a warp plain fabric, dyed with C.I. Acid B-1 ue 80 dye according to the LMDR method, and the uniformity was evaluated. LMDR is superior to 7.1. Details of the method and yarn properties are shown in Table 1. (Please read the precautions on the back and then fill out this page) Outfit-Book a Taiyue for the house (CNSVP4 group grid (210x297 cm) _ 51-200534 A 6 B6 Printed by the Ministry of Economic Affairs, Bureau of Standards, Employee Consumers # Cooperatives V. Description of the invention (50) Part H. Invented a nylon 6,6 with ~ 50 RV at 29 〇t: a spinning temperature of 17 capillary tubes with a length of 0.022 〃 and a diameter of 0.015 〃 at a melting temperature of 29〇t. The quenching channel has an average speed of 2 Ot of ~ 6 7 f pm: quenching transverse cooling air. The filaments are integrated on the finishing stick applicator located just below the quenching unit. The yarn is then passed through the tube between the bottom plates to a speed of 3954mpm ( Unwinding speed) of the undriven air bearing separation roller and interweaving. The yarn is wound on the tube at 3989m pm and ~ 0.2gpd tension. Therefore, the mechanical stretching is not obvious at 1.009X. The result is 52 denier feed The yarn is not drawn properly. However, due to the tension generated by high-speed spinning, the yarn is fully oriented in the quench zone to produce 78% elongation and 40 g of tensile tension. Therefore, it can be called `` spun oriented yarn '' 〃 (SOY). The bait yarn is drawn on the Barmag STF1 drawing unit with 1. 4 5 X drawing I ratio, 60t: drawing temperature, 6% overfeed Pull, relax at 221, and wind the bundle at a speed of 55〇mpm. The resulting drawn yarn is 39.6 denier and 30.6% elongation. The drawn yarn is knitted into a warp and flat fabric, which is CI by LMDR Acid B-lue 80 dyeing and evaluation of uniformity. LMDR is superior to 7.4. The details of the method and yarn properties are shown in Table 1. Part I-Invented a knitting fabric with 46RV 6 spinning warp at 275¾ melting temperature 1 〇 値 long 0. 010 〃 and diameter ◦. 020 〃 capillary spinning plate (please read the precautions on the back before filling in this page) installed. Taizhao r iA ffl 屮 团 S3: Who to find i CNS W7 4 Group grid (210 y 297 public baking) -52-200534 A 6 B6 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention description (51). The quenching channel has an average speed of 20¾ quenching building cold air at 67f pm. The filament is integrated on the finishing roller applicator located just below the quenching unit, and then the yarn is wound on the tube at a speed of 4200mpm (unwinding speed) and a tension of ~ 0.2gpd between the tubes between the bottom plates. The SOY yarn is inorganic maple 5% Stretching without any sticks before winding, due to the tension produced by high-speed spinning, the yarn is fully oriented in the quench zone ~ 67.5% % Elongation and 42.8 tensile tension. The yarn denier is 4 6. The yarn is fed on a Karl Mayer DSST 50 drawing unit with a 1.2 3 X draw ratio, 801C drawing temperature, 6.7% Over-feeding, pulling, relaxing at 120 °, and winding at a speed of 50mpm. The resulting drawn yarn has 40 denier and 42% elongation. The drawn yarn was knitted into a warp flat fabric, dyed with C.I. Acid B-lue 122 dye according to the LMDR method, and the uniformity was evaluated. LMDR is a superior 7.4. Part J-Invention RV is 65 nylon 6, 6 prepared as described in Part F, except the take-up (unwinding) rate is 5300mpm. The formed 13 filament SOY feed yarn is 50.5 denier, with an elongation of 73.5% and a tensile tension of 63. The feed yarn is drawn on the Bar mag STF1 drawing unit at a draw ratio of 1. 15 X, and the drawing temperature is 60¾. 5% over-feeding pulls, relaxes at 22¾, ◦mpni rolls. The drawn yarn formed was 46.5 Neal and 47% elongation. Taizhi Bianchi's use of Φ due to K House Extinguishing Class (CNS), 4 groups (210 to 297) -53-(please read the precautions on the back before filling out this page). Installation · Line · 200534 A 6 B 6 5. Description of the invention (52) Stretching the warp yarn into a warp flat fabric. The fabric was dyed with C.I. Acid Blue 80 dye according to the LMDP method and the uniformity was evaluated. The degree of uniformity is superior to 7.6 〇K part of an invention nylon 66 copolymer, 95moJ2% (poly (hexamethylene hexamethylene diamine) and 5% heavy ε-hexamethylene amine unit, RV is 65, as in the example Prepared in J. Formed by drawing 13 filaments SOY feed yarn is 50. Denier, 76.1% elongation, and 63g tensile tension. The feed yarn in the BarmagSTFl stretching unit to 1.3 0X draw ratio, 60Ό drawing temperature, 5% overfeed stretch, relax at 1181C and winding speed at 550mpm. The resulting drawn yarn has a denier of 39.5 and an elongation of 41.7%. Stretching The yarn is knitted into a warp and flat fabric, dyed with CI Acid B-lue 80 dye according to the LMDR method, and the evenness is evaluated. The degree of uniformity is superior to 7.6 (please read the precautions on the back before filling this page) Line · Employee's consumer cooperative of the Ministry of Economic Affairs printed the paper paper κ 玢 iA ill Φ 團 圃 圃 进 f f CNS1 Ψ 4 sister grid (210 X 297 public goods) One 54 *-200534 A 6 B6 Central Standard of the Ministry of Economic Affairs局 员 消 # Printed by the cooperative V. Description of the invention (53) Example I-Part A Table I Comparison of BC spinning speed, mpm 590 889 1500 Spinning ratio 1.00 1.00 1.60 Feed yarn nylon polymer types 6 6,6 6 * 6 Denier 134 125 55 Fibre 13 14 13 RV 46 40 42 Elongation,% 320 250 80 (RDR)? 4.2 3.5 3.5 1.80 (RDR) 5 4.2 2.88 Toughness, s / d 1.1 N / A 2.99 modulus, g / d N / AN / A 8.2 DT 3 3 * g N / A 49 36.5 DT33,% CV N / A 1.0 1.3 DT33.g / d N / A 0.52 0.66 DVA,% CV N / AN / A .40 USTER,% N / AN / AN / A Warp yarn drawing conditions WD unit BARMAG MAYER BARMAG WD speed, mpm 320 500 500 WD ratio 3.00 3.00 1.39 WD temperature 1C 60 85 60 overfeed,% 2.5 9 5 Heater temperature, ° C None 180 130 Relaxation temperature, t 22 161 120 Tensile yarn properties Denier 44.2 44 42 Elongation,% 52.8 48 30 (RDR) z) 1.528 1.48 1.30 degrees, s / d 3.70 4.1 N / A modulus, g / d 19.4 20 N / A DVA% CV 1.42 N / AN / A USTER,% N / AN / AN / A Boiling shrinkage 4 10.8 3.5 3.5 N / A grade 4 4.4 5 3 1 5 · 4 3 1 32 D 1849 1.736, 6 53 13 44 74 1.74 3.01 4.14 16.6 58 .87 1.09 N / AN / A MAYER 500 1.35 70 5 140 129 AA 4 ο / / · E 1937 1.686, 6 95 34 45 67 1.67 2.81 3.9 N / A 114 1.31.20 N / AN / A BARMA 550 1.43 60 5 None / \\\ 22 72.7 34.2 1.342 5.19 24.2 .47 N / A 7.6 3.0 (Please read the precautions on the back before writing this page) Installed--5 * Line · -55-200534 A 6 B 6 V. Description of invention fe4) Printed by employees of the Central Standards Bureau of the Ministry of Economic Affairs Production Example I-Part F GHIJ Spinning speed, mpm 2818 3909 3954 4200 5300 Spinning ratio 1 1.26 1.00 1.009 1.00 1.00 Feed yarn nylon polymer type 6 6,6 6.6 6 6,6 Denier 55 55 52 46 50.5 Fibre 17 17 17 10 13 RV 42 50 50 46 65 Elongation 3 60 85 78 67.5 73.5 (RDR)? 1.60 1.85 1.78 1.675 1.735 (RDR) s 2.02 1.85 1.80 1.675 1.735 Toughness, s / d 3.6 2.97 2.88 4.3 4.23 Modulus, g / d 18.5 12.8 12.7 N / A 14.3 DT3 3 * g 63 41.9 43.4 42.8 63.5 dt33,% cv .63 .36 .30 ~ 1.0 .39 DT33 »g / d 1.15 0.76 0.83 0.93 1.26 DVA ,% CV .38 .27 .41 N / A .46 USTER,% .82 .68 • 63 .91 .62 Warp draw condition WD unit BARMAG BARMAG BARMAG MAYER BARMA WD speed, mpm 550 550 550 500 550 WDfcb 1.29 1.316 1.45 1.23 1.15 WD temperature ° C 60 60 60 80 60 Super hungry,% 6 5 6 6.7 5 Heater temperature, ° C frrr young 130 -fnf M 130 No relaxation temperature * ° C 22 118 22 120 22 Tensile yarn denier 45.5 43.8 39.6 40 46.5 Elongation 3 28.5 53.1 30.6 42 47 (RDR) 〇1.285 1.531 1.306 1.42 1.47 ϋ degree, g / d 4.3 3.87 4.16 4.89 4.51 modulus, g / d 25.6 15.2 N / AN / A 20.9 DVA% CV .37 .35 .35 N / A .40 USTER,% .74 N / AN / AN / A .73 Boiling shrinkage,% 5.1 6.5 7.1 8.3 7.0 5.9 Level 7.8 7.4 7.4 7.6 (Please read the precautions on the back before filling in this page) Installation--Line--56-200534 A 6 B 6 V. Description of Invention (55) Table I (Continued) The Central Bureau of Standards of the Ministry of Invention Zhen Gong Consumer Cooperative Printed Example I-Part K Spinning speed, mpm 5300 Spinning ratio 1 1.00 Feed yarn Yarn-resistant polymer type 95% / 5% 66/6 Denier 50.5 Fibre 13 RV 65 Elongation 76.1 (RDR) f 1.761 (RDR) s 1.761 tenacity, g / d 4.24 modulus, g / d 13.7 DT33 > 8 58.8 DT33,% CV .41 DT33.g / d 1.18 DVA,% CV .46 USTER,% .70 warp draw ratio WD unit BARMAG WD speed, mpm 550 WD ratio 1.30 WD temperature 1C 60 overfeed, 5% heater temperature, ° C 130 relaxation temperature, ° C 118 stretch yarn properties Denier 39.5 Elongation,% 41.7 (RDR) 0 1.417 Toughness, s / d 5.27 modulus, g / d 21.8 DVA% CV .45 USTER,% .73 Boiling shrinkage,% 7.5 grade 7.6 (please read the note on the back first Please fill in this page again) -Install · J5 'Line- -57-200534 A6 _ B6 V. Description of the invention (56)

啻施例T T 例I I說明經纱拉伸條件對LMDR之影響。以上例 I — F "部分所述之PD 丫餵入纱在Bormag STF1單元 上以各種經纱拉伸比及放鬆溫度拉伸，如表I I 1 _ 13項所示。形成之纱束經编成32號之經平織物，以 L D M R法以C.I. Acid Blue 80染料染色，並評传勻莩 ，結果示於表II。 (請先閲讀背面之注意事項再填寫本頁) 裝- 經濟部中央標準局貝工消费合作社印製 太板张R麿诎m Ψ团03它鸪準报格（210x297公资） -58 - 200534 A 6 B6 五、發明説明（57)Example T T Example I I illustrate the effect of warp drawing conditions on LMDR. The PD yarn feed yarn described in the above Example I — F " section is stretched on the Bormag STF1 unit at various warp yarn draw ratios and relaxation temperatures, as shown in Table I I 1 _13. The resulting yarn bundles were warp knitted into No. 32 warp plain fabric, dyed with C.I. Acid Blue 80 dye by LD M R method, and evaluated for uniformity. The results are shown in Table II. (Please read the precautions on the back and then fill out this page) Outfit-Printed Taiban Zhang by the Central Standards Bureau of the Ministry of Economic Affairs Beigong Consumer Cooperative Society R 娎 m Ψ 团 03 It is a standard report (210x297 public funds) A 6 B6 V. Description of the invention (57)

表I I 例I I 餵入纱 I-F I-F I-F I-F I-F 拉伸項编號 經纱拉伸條件 II-1 II-2 11-3 11-4 II-5 WD速度，mpm 500 500 500 550 550 WD比 1.25 1.25 1.38 1.48 1.48 WD張力，g 82 68 >100 80 .84 WD 張力，g/dd* 1.78 1.48 >2.41 2.05 2.13 WD溫度，Ό 60 60 60 60 60 超餵，％ 5 6 5 5 5 加熱器溫度，ΐ： 140 OFF 140 160 OFF 放鬆溫度，它 拉伸纱性質 130 22 130 143 22 旦尼爾 46 46 41.5 39 39.5 伸長度，％ 32 33 21 15.5 16.5 (RDR)/, 1.32 1.33 1.21 1.155 1.165 韌度，g/d 4.2 4.1 4.9 5.9 5.5 模數，g/d 27.6 25.0 34.4 39.6 34.4 DVA %CV .44 .44 .44 .34 .37 USTER,% .82 .78 .73 .82 .82 沸溶收縮，$ 级數 7.0 6.0 7.2 6.2 7.8 5.8 8.0 5.4 7.4 6.1 1 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局员工消費合作社印製 -57 - 200534 A 6 B 6 五、發明説明68 ) 餵入纱 I-F 表I I-F I (缜） I-F I-F I-F 拉伸項编號 11-6 11-7 II-8 11-9 11-10 經纱拉伸條件 WD速度，mpm 550 550 550 550 550 WD比 1.05 1.05 1,29 1.29 1.29 WD張力,g 24 26 58 58 -56 WD 張力，g/dd* .46 .49 1.27 1.30 1.26 WD溫度，t： 60 60 60 60 60 超餵，％ 1 1 6 6 5 加熱器溫度，t： 160 Anr 规 無 100 130 放鬆溫度，1C 143 22 22 94 118 拉伸纱性質 旦尼爾 52 53.5 45.5 44.5 44.5 伸長度A 52.5 56.5 28.5 29 29 (RDR)d 1.525 1.565 1.285 1.29 1.29 韌度，g/d 3.7 3.5 4.3 4.4 4.3 模數，g/d 18.4 19.5 25.6 27.0 28.6 DVA %CV .31 .34 .37 .30 • 36 USTER,% .83 .73 .74 .73 .78 沸溶收縮，％ 3.4 4.8 5.1 5.7 N/A 级數 6.3 7.8 7.8 7.1 6.4 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂_ 經濟部中央標準局员工消费合作社印製 太紙袼尺汶m Ψ因S3 姐柊 —60 ~ 200534 A 6 B 6 五、發明説明 表I I (續) 餵入纱 I-F I-F I-F 拉伸項编號 11-11 11-12 11-13 經纱拉伸條件 WD速度,mpm 550 550 550 WD比 1.29 1.29 1.48 WD張力，g 60 53 80 WD 張力，g/dd， 1.35 1.20 2.05 WD溫度，t： 60 60 60 超餵A 5 5 5 加熱器溫度，°C 160 190 130 放鬆溫度，C 143 169 118 拉伸纱性質 旦尼爾 44.5 44 39 伸長度3 30 30.5 15.5 (RDR)fl 1.30 1.305 1.155 靱度，s/d 4.7 4.9 5.7 模數，g/d 30.1 32.2 29.9 DVA %CV .28 .31 .29 USTER,% .81 .89 .83 沸溶收縮，％ 6.2 5.2 8.3 级數 5.3 4.8 5.2 *g/dd=拉伸張力（g)/拉伸旦尼爾 (請先閱讀背面之注意事項再塡寫本頁) 裝· 線- 經濟部中央標準局员工消f合作社印姐 -61 200534 Α6 Β6 五、發明説明（60) 啻旆例I T T 例I I I亦說明經纱拉伸條件對LMDR之影饗。以 上例I-、' G 〃部分所述之SOY餵人纱在B〇rmag STF1 單元上以各種經纱拉伸比及放鬆溫度拉伸，如表I I I 1一6項所示。形成之纱束經编成32號之經平織物，以 L DM R法以C.I. Acid Blue 80染料染色，並評碎勻享 ，結果示於表II。 (請先閲讀背面之注意事項再填寫本頁) 裝. 線. 經濟部中央標準局员工消費合作社印製 200534 A 6 B 6 五、發明説明（έ| )Table II Example II Feeding yarn IF IF IF IF IF Drawing item number Warp yarn drawing conditions II-1 II-2 11-3 11-4 II-5 WD speed, mpm 500 500 500 550 550 WD ratio 1.25 1.25 1.38 1.48 1.48 WD tension, g 82 68 > 100 80 .84 WD tension, g / dd * 1.78 1.48 > 2.41 2.05 2.13 WD temperature, Ό 60 60 60 60 60 overfeed,% 5 6 5 5 5 heater temperature , L: 140 OFF 140 160 OFF Relax temperature, it stretches yarn properties 130 22 130 143 22 Denier 46 46 41.5 39 39.5 Elongation,% 32 33 21 15.5 16.5 (RDR) /, 1.32 1.33 1.21 1.155 1.165 Toughness , G / d 4.2 4.1 4.9 5.9 5.5 modulus, g / d 27.6 25.0 34.4 39.6 34.4 DVA% CV .44 .44 .44 .34 .37 USTER,% .82 .78 .73 .82 .82 $ Level 7.0 6.0 7.2 6.2 7.8 5.8 8.0 5.4 7.4 6.1 1 (please read the notes on the back before filling this page) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs -57-200534 A 6 B 6 V. Description of invention 68 ) Feeding yarn IF table I IF I (缜) IF IF IF Drawing item number 11-6 11-7 II-8 11-9 11-10 Warp drawing condition WD speed, mpm 550 550 550 550 550 WD ratio 1.05 1.05 1,29 1.29 1.29 WD tension, g 24 26 58 58 -56 WD tension, g / dd * .46 .49 1.27 1.30 1.26 WD temperature, t: 60 60 60 60 60 overfeed,% 1 1 6 6 5 Heater temperature, t: 160 Anr gauge without 100 130 Relaxation temperature, 1C 143 22 22 94 118 Tensile yarn denier 52 53.5 45.5 44.5 44.5 elongation A 52.5 56.5 28.5 29 29 (RDR) d 1.525 1.565 1.285 1.29 1.29 Toughness, g / d 3.7 3.5 4.3 4.4 4.3 Modulus, g / d 18.4 19.5 25.6 27.0 28.6 DVA% CV .31 .34 .37 .30 • 36 USTER,% .83 .73 .74 .73 .78 Boiling solution shrinkage,% 3.4 4.8 5.1 5.7 N / A grade 6.3 7.8 7.8 7.1 6.4 (please read the notes on the back before filling this page) Wen m Ψ because S3 sister 柊 —60 ~ 200534 A 6 B 6 V. Invention description table II (continued) Feeding yarn IF IF IF Drawing item number 11-11 11-12 11-13 Warp drawing condition WD Speed, mpm 550 550 550 WD ratio 1.29 1.29 1.48 WD tension, g 60 53 80 WD tension, g / dd, 1.35 1.20 2.05 WD temperature, t: 60 60 60 overfeed A 5 5 5 heating Temperature, ° C 160 190 130 Relaxation temperature, C 143 169 118 Tensile yarn properties Denier 44.5 44 39 Elongation 3 30 30.5 15.5 (RDR) fl 1.30 1.305 1.155 Degree, s / d 4.7 4.9 5.7 Modulus, g / d 30.1 32.2 29.9 DVA% CV .28 .31 .29 USTER,% .81 .89 .83 Boiling shrinkage,% 6.2 5.2 8.3 series 5.3 4.8 5.2 * g / dd = tensile tension (g) / stretch Denier (please read the precautions on the back before writing this page) Installation · Thread-The Ministry of Economic Affairs, Central Standards Bureau, Employee Consumers, Cooperatives, Sister-in-Jin-61 200534 Α6 Β6 V. Description of Invention (60) ITT Example III It also shows the effect of warp drawing conditions on LMDR. The SOY feed yarn described in the above example I-, 'G 〃 is drawn on the Bormag STF1 unit with various warp yarn draw ratios and relaxation temperatures, as shown in Table I I 1 1-6. The resulting yarn bundles were warp knitted into No. 32 warp plain fabric, dyed with the C.I. Acid Blue 80 dye by the L DM R method, and crushed and evenly enjoyed. The results are shown in Table II. (Please read the precautions on the back before filling out this page) Pack. Line. Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 200534 A 6 B 6 5. Description of invention (έ |)

表I I I 例I I I 餵入纱 I-G I-G I-G I-G I-G 拉伸項目编號 經纱拉伸條件 III-1 II1-2 III-3 II1-4 111-5 WD速度，mpm 550 550 550 550 550 WD比 1.316 1.316 1.447 1.447 .1.608 TO張力，g 60 58 77 60 96 WD 張力，g/dd* 1.37 1.33 1.92 1.49 2.66 WD溫度，t： 60 60 60 60 60 超餓，％ 5 5 5 5 5 加熱器溫度，°C 130 160 130 hrr Μ 無 放鬆溫度，C 拉伸纱性質 118 143 118 22 22 旦尼爾 43.8 43.7 40.0 40.2 36.1 伸長度4 53.1 51.9 39.8 43.6 30.5 (RDR)〇 1.531 1.519 1.398 1.436 1.305 韌度，g/d 3.87 3.97 4.31 4.33 5.03 模數，g/d 15.2 16.2 17.9 29.2 23.9 DVA %CV .35 .36 • 38 .40 .37 USTER,% N/A N/A N/A N/A N/A 沸溶收縮，％ 6.5 7.1 6.2 7.4 6.6 7.3 ' 6.3 级數 6.9 6.8 6.8 (請先閱讀背面之注意事項再填寫本頁) 裝- 線. 經濟部中央標準局Μ工消費合作社印製 一 63 - 200534 A 6 B 6 五、發明説明（^2) 砉Τ Τ (績） 餵入纱 I-G 拉伸項目编號 經纱拉伸條件 III-6 WD速度，mpm 550 WD比 1.608 WD張力，g 96 WD 張力，g/dcT 2.68 WD溫度，t： 60 超餵，$ 5 加熱器溫度，°C 130 放鬆溫度，ΐ： 拉伸纱性質 118 旦尼爾 35.8 伸長度，$ 22.8 (RDR)〇 1.228 靱度，s/d 5.18 模數，g/d 47.0 DVA %CV .40 USTER,% N/A 沸溶收縮，％ 级數 7.6 5.3 *g/d-拉伸張力(g)/拉伸旦尼爾 (請先閱讀背面之注意事項再填寫本頁) 裝· 訂- 經濟部屮央標準局员工消费合作社印製 -64 - 200534 A6 _B6_ 五、發明説明（63) 奮旆例V T 例VI亦說明經纱拉伸條件對LMDR之影響。以上 例I — Η "部分所述之S Ο Y餵入纱在Bormag STFi單 元上以各種經纱拉伸比及放鬆溫度拉伸，如表I I I 1 —14項所示。形成之纱束經编成32號之經平織物，以 L D M R法C.I· Acid Blue 80染料染色，並評估勺度，. 結果示於表I V。 (請先閲讀背面之注意事項再填寫本頁) 裝· 線· 經濟部中央橾準局员工消Φχ合作社印製 太姑.袼只丨11屮因因它熄课（CNS)甲4頫格（210Χ297公贷） 2〇〇534 A 6 B 6 五、發明説明44) 表I V 餵入纱 I-H I-H I-H I-H I-H 拉伸項目编號 經纱拉伸條件 IV-1 IV-2 IV-3 IV-4 IV-5 WD速度，mpm 550 550 550 550 550 WD比 1.30 1.30 1.45 1.45 1.60 WD張力，g 24.5 19 50 49 61 WD 張力，g/dd* .56 .43 1.25 1.22 1.72 WD溫度，1C 60 60 60 60 60 超餵，$ 5 6 5 6 5 加熱器溫度，°C 160 4τττ Μ 160 -frrr m 160 放鬆溫度，t： 拉伸纱性質 143 22 143 22 143 旦尼爾 44 44.5 40 40 35.5 伸長度，％ 39 45 27 30 23 (RDR)〇 1.39 1.45 1.27 1.30 1.23 韌度，s/d 3.4 3.6 4.1 4.1 5.2 模數，g/d N/A N/A N/A N/A N/A DVA %CV .32 .34 .40 .35 .34 USTER,% N/A N/A N/A N/A N/A 沸溶收縮3 级數 6.6 4.8 7.0 6.6 7.3 5.8 8.3 7.4 6.9 5.0 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印级 -66 - 200^34 A 6 B6 五、發明説明 表I V (續） 餵入纱 I-H I-H I-H I-H I-H 拉伸項目编號 經纱拉伸條件 IV-6 IV-7 、 IV-8 IV-9 IV-10 WD速度，mpm 550 550 550 550 550 WD比 1.60 1.15 1.15 1.45 1.45 WD張力，g 61 59.5 57.5 50 49 WD 張力，g/dcT 1.72 1.21 1.62 1.27 1.24 WD溫度，t： 60 60 60 60 60 超餵，％ 6 5 6 6 6 加熱器溫度，°C 無 160 -^γγΓ m m. 100 放鬆溫度，t： 拉伸纱性質 22 143 22 22 94 旦尼爾 35.5 49 49.5 39.5 39.5 伸長度，％ 22 64 71 39 38.5 (RDR)fl 1.22 1.64 1.71 1.39 1.385 韌度，g/d 5.1 3.3 3.3 4.1 4.1 模數，g/d N/A N/A N/A N/A N/A DVA %CV .35 .32 .35 .35 • 37 USTER,% N/A N/A N/A N/A N/A 沸溶收縮，％ 级數 6.6 4.8 4.0 6.5 N/A 7.0 6.1 7.1 6.7 6.9 ' (請先閱讀背面之注意事項再塡寫本頁) 裝. 線· 經濟部中央標準局员工消費合作社印製 一 67 - 200534 A 6 B6 五、發明説明) 表I V (續） 餵入纱 I-H I-H I-H I-H 拉伸項目编號 經纱拉伸條件 IV-11 IV-12 IV-13 IV-14 WD速度，mpm 550 550 550 550 WDbb 1.45 1.45 1.45 1.30 WD張力，g 49 49 46 39.5 WD 張力，g/dd* 1.26 1.26 1.18 .91 WD溫度，t： 60 60 60 60 超餵，％ 5 5 5 5 加熱器溫度，°C 130 160 190 130 放鬆溫度，°C 拉伸纱性質 118 143 169 118 旦尼爾 39 39 39 43.5 伸長度，％ 34 32.5 32 44 (RDRU 1.34 1.325 1.32 1.44 韌度，s/d 4.3 4.4 4.5 3.8 模數，g/d N/A N/A N/A N/A DVA %α .31 .40 • 33 .39 USTER,% N/A N/A N/A N/A 沸溶收縮，％ 级數 6.2 5.4 6.1 5.2 5.7 4.8 5.9 7.2 *g/d=*拉伸張力（g)/拉伸旦尼爾 (請先閲讀背面之注意事項再填寫本頁) 經濟部屮央標準局员工消费合作社印？如 -68 - 2〇〇534 A 6 B6 五、發明説明妇7) 啻施例V 例V亦說明經纱拉伸條件對LMDR之影響。以上例 I-N' J 〃部分所述之SO Y餵入纱在Bormag STF1單元 上以各種經纱拉伸比及放鬆溫度拉伸，如表V 1 — 8項 所示。形成之纱束經編成32號之經平織物，以 L DM R法C.I. Acid Blue 80染料染色，並評估勻度， 結果示於表V。 (請先閲讀背面之注意事項再填寫本頁) 裝- 線‘ 經濟部屮央標準局员工消費合作社印製 太紙诀R3 m屮闽K :鸪m(CNS) 規格（210x297公货） -69 - 五、發明説明 A 6 B 6 餵入纱 I-J 表v I-J I-J I-J I-J 拉伸項目编號 V-1 V-2 V-3 V-4 V-5 經纱拉伸條件 WD速度，mpm 550 550 550 550 550 WDbb 1.15 1.15 1.30 1.30 1.45 WD張力，g 80 53 92 90 120 WD 張力，g/dcT 1.72 1.15 2.24 2.15 3.23 WD溫度，t： 60 60 60 60 60 超餵，％ 5 5 5 5 5 加熱器溫度，°c m 160 160 無 4πτ M 放鬆溫度，π 22 143 143 22 22 拉伸纱性質 旦尼爾 46.5 46.0 41.1 41.9 37.2 伸長度，％ 47.0 58.9 39.1 41.6 29.5 (RDR)fl 1.47 1.589 1.391 1.416 1.295 韌度，g/d 4.51 4.51 5.06 4.96 5.81 模數，g/d 20.9 19.0 25.3 22.8 30.7 DVA %CV .52 .62 .62 .64 .60 USTER,% .73 .80 .82 .77 .88 沸溶收縮，％ 5.9 4.9 6.7 5.9 6.9 级數 7.6 6.6 6.7 6.7 5.1 ‘ (請先閲讀背面之注意事項再塡窝本頁) 裝. 訂 線. 經濟部中央標準局员工消f合作社印製 -70 - 200534 A 6 B 6 五、發明説明（69) 查V：(續) 餵入纱 I-J I-J I-J 拉伸項目编號 V-6 V-7 V-8 經纱拉伸條件 WD速度，mpm 550 550 550 WD比 1.45 1.35 1.35 WD張力，g 135 109 80 WD張力，g/dcT 3.67 2.71 2.00 WD溫度，Ί〇 60 60 60 超餵，％ 5 5 5 加熱器溫度，°C 160 無 130 放鬆溫度，°C 143 22 118 拉伸纱性質 旦尼爾 36.8 40.2 40.0 伸長度，％ 28.3 41.2 36.0 (ROR)d 1.283 1.412 1.36 韌度，g/d 6.06 5.31 5.27 模數，g/d 28.6 23.4 26.0 DVA %CV .63 .59 .61 USTER,% .96 .85 .82 沸溶收縮，％ 7.2 6.4 6.9 级數 4.5 6.5 5.2 *g/d=拉伸張力（g)/拉伸旦尼爾 (請先閲讀背面之注意事項再塡寫本頁) 裝· 線. 經濟部屮央標準局货工消費合作社印製 -71 - 200534 A6 _B 6 五、發明説明（70)Table III Example III Feeding yarn IG IG IG IG IG Drawing item number Warp yarn drawing conditions III-1 II1-2 III-3 II1-4 111-5 WD speed, mpm 550 550 550 550 550 WD ratio 1.316 1.316 1.447 1.447 .1.608 TO tension, g 60 58 77 60 96 WD tension, g / dd * 1.37 1.33 1.92 1.49 2.66 WD temperature, t: 60 60 60 60 60 Super hungry,% 5 5 5 5 5 Heater temperature, ° C 130 160 130 hrr Μ No relaxation temperature, C Tensile yarn properties 118 143 118 22 22 Denier 43.8 43.7 40.0 40.2 36.1 Elongation 4 53.1 51.9 39.8 43.6 30.5 (RDR) 〇1.531 1.519 1.398 1.436 1.305 Toughness, g / d 3.87 3.97 4.31 4.33 5.03 Modulus, g / d 15.2 16.2 17.9 29.2 23.9 DVA% CV .35 .36 • 38 .40 .37 USTER,% N / AN / AN / AN / AN / A Boiling shrinkage,% 6.5 7.1 6.2 7.4 6.6 7.3 '6.3 grades 6.9 6.8 6.8 (please read the precautions on the back before filling in this page) Pack-line. Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Mgong Consumer Cooperative 63-200534 A 6 B 6 5. Inventions Description (^ 2) 砉 Τ Τ (絲) Feeding yarn IG drawing item number warp drawing condition III-6 WD speed, mpm 550 W D ratio 1.608 WD tension, g 96 WD tension, g / dcT 2.68 WD temperature, t: 60 overfeed, $ 5 heater temperature, ° C 130 relaxation temperature, l: tensile yarn properties 118 denier 35.8 elongation, $ 22.8 (RDR) 〇1.228 degree, s / d 5.18 modulus, g / d 47.0 DVA% CV .40 USTER,% N / A Boiling shrinkage,% grade 7.6 5.3 * g / d-tensile tension ( g) / Stretch Denier (please read the precautions on the back and then fill out this page) Binding · Order-Printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs -64-200534 A6 _B6_ V. Description of Invention (63) Fen Example VT Example VI also illustrates the effect of warp drawing conditions on LMDR. The S Ο Y feed yarn described in the above Example I — Η " section is stretched on Bormag STFi units at various warp yarn draw ratios and relaxation temperatures, as shown in Table I I I 1-14. The formed yarn bundles were warp knitted into No. 32 warp plain fabric, dyed with LD M R method C.I. Acid Blue 80 dye, and evaluated for scoop. The results are shown in Table IV. (Please read the precautions on the back and then fill out this page) Installation · Line · The Ministry of Economic Affairs Central Bureau of quasi-bureau employees print Φχ Cooperative printed aunt. 袼 only 丨 11 屮 Because it is out of class (CNS) A 4 down grid ( 210Χ297 public loan) 200534 A 6 B 6 V. Description of invention 44) Table IV Feeding yarn IH IH IH IH IH Drawing item number Warp yarn drawing conditions IV-1 IV-2 IV-3 IV-4 IV-5 WD speed, mpm 550 550 550 550 550 550 WD ratio 1.30 1.30 1.45 1.45 1.60 WD tension, g 24.5 19 50 49 61 WD tension, g / dd * .56 .43 1.25 1.22 1.72 WD temperature, 1C 60 60 60 60 60 overfeed, $ 5 6 5 6 5 heater temperature, ° C 160 4τττ Μ 160 -frrr m 160 relaxation temperature, t: tensile yarn properties 143 22 143 22 143 denier 44 44.5 40 40 35.5 elongation,% 39 45 27 30 23 (RDR) 〇1.39 1.45 1.27 1.30 1.23 Toughness, s / d 3.4 3.6 4.1 4.1 5.2 Modulus, g / d N / AN / AN / AN / AN / A DVA% CV .32 .34. 40 .35 .34 USTER,% N / AN / AN / AN / AN / A Boiling melt shrinkage 3 series 6.6 4.8 7.0 6.6 7.3 5.8 8.3 7.4 6.9 5.0 (Please read the notes on the back before filling this page) Ministry of Economic Affairs Central Bureau of Standards Consumer Cooperative Printing Class-66-200 ^ 34 A 6 B6 V. Invention Description Table IV (Continued) Feeding Yarn IH IH IH IH IH Drawing Item Number Warp Yarn Drawing Conditions IV-6 IV-7, IV-8 IV-9 IV-10 WD speed, mpm 550 550 550 550 550 WD ratio 1.60 1.15 1.15 1.45 1.45 WD tension, g 61 59.5 57.5 50 49 WD tension, g / dcT 1.72 1.21 1.62 1.27 1.24 WD temperature, t: 60 60 60 60 60 Overfeed,% 6 5 6 6 6 Heater temperature, ° C None 160-^ γγΓ m m. 100 Relaxation temperature, t: Tensile yarn properties 22 143 22 22 94 Denier 35.5 49 49.5 39.5 39.5 Elongation ,% 22 64 71 39 38.5 (RDR) fl 1.22 1.64 1.71 1.39 1.385 Toughness, g / d 5.1 3.3 3.3 4.1 4.1 Modulus, g / d N / AN / AN / AN / AN / A DVA% CV .35. 32 .35 .35 • 37 USTER,% N / AN / AN / AN / AN / A Boiling shrinkage,% series 6.6 4.8 4.0 6.5 N / A 7.0 6.1 7.1 6.7 6.9 '(Please read the notes on the back first (Write this page) Packing. Thread · Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 67-200534 A 6 B6 V. Description of invention) Table IV (continued) Feeding yarn IH IH IH IH Stretching project No. warp drawing conditions IV-11 IV-12 IV-13 IV-14 WD speed, mpm 550 550 550 550 WDbb 1.45 1.45 1.45 1.30 WD tension, g 49 49 46 39.5 WD tension, g / dd * 1.26 1.26 1.18. 91 WD temperature, t: 60 60 60 60 overfeed,% 5 5 5 5 heater temperature, ° C 130 160 190 130 relaxation temperature, ° C tensile yarn properties 118 143 169 118 denier 39 39 39 43.5 elongation ,% 34 32.5 32 44 (RDRU 1.34 1.325 1.32 1.44 toughness, s / d 4.3 4.4 4.5 3.8 modulus, g / d N / AN / AN / AN / A DVA% α .31 .40 • 33 .39 USTER, % N / AN / AN / AN / A Boiling shrinkage,% series 6.2 5.4 6.1 5.2 5.7 4.8 5.9 7.2 * g / d = * tensile tension (g) / tensile denier (please read the notes on the back first Please fill in this page again) Printed by Employee Consumer Cooperative of the Bureau of Standards of the Ministry of Economic Affairs? Such as -68-2〇〇534 A 6 B6 5. Description of the woman 7) Example V Example V also illustrates the effect of warp drawing conditions on LMDR. The SO Y feed yarn described in the above example I-N 'J 〃 is drawn on the Bormag STF1 unit at various warp draw ratios and relaxation temperatures, as shown in Table V 1-8. The resulting yarn bundle was warp-knitted into No. 32 warp plain fabric, dyed with the L DM R method C.I. Acid Blue 80 dye, and the uniformity was evaluated. The results are shown in Table V. (Please read the precautions on the back before filling in this page) 装-线 'Taijiju R3 m printed by the Employee Consumer Cooperative of the Bureau of Standards of the Ministry of Economic Affairs R3 m 屮 Min K: 鸪 m (CNS) Specification (210x297 public goods) -69 -V. Description of invention A 6 B 6 Feeding yarn IJ table v IJ IJ IJ IJ Drawing item number V-1 V-2 V-3 V-4 V-5 Warp drawing condition WD speed, mpm 550 550 550 550 550 WDbb 1.15 1.15 1.30 1.30 1.45 WD tension, g 80 53 92 90 120 WD tension, g / dcT 1.72 1.15 2.24 2.15 3.23 WD temperature, t: 60 60 60 60 60 overfeed,% 5 5 5 5 5 heater Temperature, ° cm 160 160 without 4πτ M relaxation temperature, π 22 143 143 22 22 Tensile yarn denier 46.5 46.0 41.1 41.9 37.2 elongation,% 47.0 58.9 39.1 41.6 29.5 (RDR) fl 1.47 1.589 1.391 1.416 1.295 Toughness , G / d 4.51 4.51 5.06 4.96 5.81 modulus, g / d 20.9 19.0 25.3 22.8 30.7 DVA% CV .52 .62 .62 .64 .60 USTER,% .73 .80 .82 .77 .88 % 5.9 4.9 6.7 5.9 6.9 grade 7.6 6.6 6.7 6.7 5.1 '(please read the precautions on the back before reading this page). Binding. Line. Central Ministry of Economic Affairs Printed by the Standards Bureau ’s employee cooperatives -70-200534 A 6 B 6 V. Description of invention (69) Check V: (continued) Feeding yarn IJ IJ IJ Stretching project number V-6 V-7 V-8 warp Yarn drawing conditions WD speed, mpm 550 550 550 WD ratio 1.45 1.35 1.35 WD tension, g 135 109 80 WD tension, g / dcT 3.67 2.71 2.00 WD temperature, Ί〇60 60 60 overfeed,% 5 5 5 heater temperature , ° C 160 without 130 relaxation temperature, ° C 143 22 118 Tensile yarn properties denier 36.8 40.2 40.0 elongation,% 28.3 41.2 36.0 (ROR) d 1.283 1.412 1.36 tenacity, g / d 6.06 5.31 5.27 modulus, g / d 28.6 23.4 26.0 DVA% CV .63 .59 .61 USTER,% .96 .85 .82 Boiling shrinkage,% 7.2 6.4 6.9 grade 4.5 6.5 5.2 * g / d = tensile tension (g) / pull Denier (please read the precautions on the back before writing this page). Installation and line. Printed by the Cargo Consumption Cooperative of the Bureau of Standards, Ministry of Economic Affairs -71-200534 A6 _B 6 V. Description of Invention (70)

曹施例V I 例VI亦說明經纱拉伸條件對LMDR之影饗。以上 例I-'' K 〃部分所述之SOY餵入纱在B〇rmag STF1單 元上以各種經拉拉伸比及放鬆溫度拉伸，如表V I 1 -7項所示。形成之纱束經编成32號之經平織物，以 LDMR法C.I. Acid Blue 80染料染色，並評估勾度， 結果示於表VI。 (請先閲讀背面之注意事項再填寫本頁) 裝- -•°_ 線. 經濟部屮央標準局貝工消费合作社印製 太紙接尺泞试用Φ因因宅找迆（CNS)甲4頫格（21〇y 297公分） -72 - 200534 A 6 B6 五、發明説明（71) 餵入纱 I-K 表V I I-K I-K I-K 拉伸項目編號 VI-1 VI-2 VI-3 VI-4 經纱拉伸條件 TO速度，mpm • 550 550 550 550 WD比 1.15 1.30 1.30 1.30 WD張力，g 50 85 80 80 WD 張力，g/dcT 1.12 2.14 2.03 2.15 WD溫度，1〇 60 60 60 60 超餵，％ 5 5 5 5 加熱器溫度，°C 160 160 130 無 放鬆溫度，°C 143 143 118 22 拉伸纱性質 旦尼爾 44.7 39.8 39.5 40.5 伸長度3 60.3 43.2 41.7 49.8 (RDR)fl 1.603 1.432 1.417 1.498 韌度，g/d 4.69 5.29 5.27 5.15 模數，g/d 18.4 23.5 21.8 21.8 DVA %CV .46 .48 .45 .42 USTER，％ .75 .76 .73 .71 沸溶收縮，％ 5.9 7.6 7.5 6-9 级數 7.7 5.7 7.6 5-8 (請先閲讀背面之注意事項再塡寫本頁) 裝. *1T' 線* 經濟部屮央標準局眞工消費合作社印製 太R泞ifi用屮Η Β3宅找m(CNS)屮4姐格（210x297公贤） -73 - 200534 A 6 B 6 五、發明説明（72 ) 餵入纱 I-K 丟V T I-K (續） I-K 拉伸項目編號 VI-5 VI-6 VI-7 經纱拉伸條件 WD速度，mpm 550 550 550 WD比 1.45 1.45 1.45 WD張力，g 105 115 110 WD 張力，g/dcT 2.88 3.23 2.87 WD溫度，°C 60 60 60 超餵.¾ 5 5 5 加熱器溫度，°C 無 130 160 放鬆溫度，t： 22 118 143 拉伸纱性質 旦尼爾 36.5 35.6 35.4 伸長度，％ 36.4 33.2 30.5 (RDR)z, 1.364 1.332 1.305 韌度，g/d 5.86 6.13 6.17 模數，g/d 21.3 29.2 26.6 DVA %CV .51 .49 .41 USTER,% .73 .72 .72 沸溶收縮，％ 8.1 8.6 8.3 级數 6.5 3.6 5.6 *g/d=拉伸張力（g)/拉伸旦尼爾 (請先閲讀背面之注意事項再填寫本頁) 裝- 訂_ 線. 經濟部中央標準局员工消费合作社印製 太紙语Η玢徜ill Φ因因玄熄S(CNS)申4姐格（210x297公浓） -74 - 200534 A6 B6 _ 五、發明説明（73) 奮施例V I I 例VI I說明拉伸溫度對LMDR之影轡。以上例I 一、、J "部分所述之PDY餵入纱在Bormas STF1單元上 以各種經纱伸溫度拉伸，如表V I I 1 — 8項所示。形 成之纱束經编成3 2號之經平織物，以 L DM R法C.I. Acid Blue 80染料染色，並評估勻度， 結果示於表V I I。在1 56及1 7810間之纱拉伸溫度 産生勻度之急劇破壞。 (請先閲讀背面之注意事項再填窝本頁) 裝- .1T_ - 經濟部屮央橾準局员工消费合作社印製 _ 75 - 200534 A 6 B6 五、發明説明（74 ) 表V I I 餵入纱 I-J I-J I-J I-J I-J 拉伸項目编號 經纱拉伸條件 VII-1 VII-2 VII-3 VII-4 VII-5 WD速度，mpm 550 550 550 550 550 WD比 1.33 1.33 1.33 1.33 1.33 WD張力，g 88 86 82 74 75 WD 張力，g/dcT 2.18 2.16 2.06 1.88 1.92 加熱器溫度，°C 80 95 100 125 150 纱溫，t 80 90 94 113 135 超餵3 50 5 5 5 2.5 放鬆加熱器溫度，°COFF 4rrr /nr M fnr m 無 放鬆溫度，°C 拉伸纱性質 22 22 22 22 22 旦尼爾 40.4 39.8 39.9 39.4 39.0 伸長度，％ 42.1 42.5 40.6 38.6 36.9 (RDR)zj 1.421 1.425 1.406 1.386 1.369 靱度，s/d 5.23 5.44 5.40 5.51 5.65 模數，g/d 21.6 19.3 23.0 24.3 28.2 DVA %CV .42 .53 .43 .39 .41 USTER,% N/A N/A N/A N/A N/A 沸溶牧縮，％ 级數 6.5 8.3 7.0 8.3 6.7 6.4 6.9 7.0 6.9 8.2 (請先閲讀背面之注意事項再填寫本頁) 裝- .νφ _ 線. 經濟部中央標準局员工消費合作社印製 太紙铬ΗΨ因团定itrn(CNS)甲4姐格（210x297公帒） -76 - 200534 A 6 B6 五、發明説明（75) 餵入纱 I-J 表V I I-J I I-J 拉伸項目编號 VII-6 VII-7 VII-8 經纱拉伸條件 WD速度，瓜pm 550 > 550 550 WDbb 1.33 1.33 1.33 WD張力，g 75 60 65 WD 張力，g/dcT 1.94 1.58 1.70 加熱器溫度，°C 175 200 225 纱溫，t： 156 178 199 超餵4 2.0 1.7 0.2 放鬆加熱器溫度，°0無 無 無 放鬆溫度，C 22 22 22 拉伸纱性質 旦尼爾 38.6 37.9 38.2 伸長度.¾ 35.0 33.3 32.2 (RDR)fl 1.35 1.333 1.322 韌度，g/d 5.73 6.01 5.94 模數，g/d 32.5 41.7 39.4 DVA %CV .41 • 48 .45 USTER，％ N/A N/A N/A 沸溶收縮，％ 6.6 7.7 6.0 5.1 级數 3.6 3.6 *g/d-拉伸張力（g)/拉伸旦尼爾 (請先閱讀背面之注意事項再塡寫本頁) 裝* 線- 經濟部中央標準局員工消費合作社印製 77 - 200534 A 6 B6 五、發明説明（76) 啻施例V I T T 例VI I I說明含M PMD之拉伸經纱的可能性。使 用三種S Ο Υ餵入纱。J項同於例1 一 a J 〃部分所述之 纱。L項如例I 一J 〃部分所述般纺絲，除其含5 % Μ e 5 — 6外，Μ項亦如例I 一 a J 〃部分所述般纺絲，除 其含20%MPMD外。此類項目在Barmag STF1單元上 以相同拉伸比，但不同之放鬆溫度拉伸，且捲於單纱捲器 。形成之纱捲編成Lawson Tubing且所有經拉伸項目皆在 相同染浴中以C.I. Acid Blue 122使用LMDR染色法染 色，除僅評估相對色度外。 (請先閲讀背面之注意事項再填窝本頁) 裝· 線- 經濟部中央標準局员工消費合作社印製 太ίΛ ffi Ψ ® 描.格〖210乂297公贤） -78 - 200534 A 6 B 6 五、發明説明（77) 經濟部中央標準局员工消费合作社印製 表V I I I 餵入纱 L L L Μ Μ 拉伸項编號 VIII-1 VIII-2 VIII-3 VIII-4 VIII- 紡速，mpm 5300 5300 5300 5300 5300 紡拉比 1.00 1,00 1.00 1.00 1.00 餵入纱 % MPMD 5 5 5 20 20 旦尼爾 50.7 50.7 50.7 50.5 50.5 纖絲 13 13 13 13 13 RV 66.4 66.4 66.4 66.8 66.8 伸長度.¾ 80.3 80.3 80.3 74.5 74.5 (RDR)；· 1.803 1.803 1.803 1.745 1.745 (RDR)s 1.803 1.803 1.803 1.745 1.745 韌度，g/d 3.84 3.84 3.84 3.58 3.58 模數，g/d 11.6 11.6 11.6 10.9 10.9 DT^3 *g 55.8 55.8 55.8 52.6 52.6 DTj3,%CV .79 .79 .79 .46 • 46 DTj 3 *s/d 1.10 1.01 1.10 1.04 1.04 DVA,%CV .86 .86 .86 Ν/Α Ν/Α 經拉條件 WD單元 BARMAG BARMAG BARMAG BARMAG BARMA WD 速，mpm 550 550 550 550 550 WD比 1.316 1.316 1.316 1.316 1.316 WD溫度t： 60 65 60 60 60 超餵4 5 5 5 5 5 加熱器溫度，°C 無 105 130 無 95 放鬆溫度，°C 22 98 118 22 90 WD張力，gms 90 88 82 80 78 WD 張力，g/dd 2.12 2.04 1.90 1.88 1.84 拉伸纱性質 旦尼爾 42.3 43.1 43 42.5 42.4 伸長度，％ 46.3 45.2 44.8 37.5 39.3 (RDR)；, 1.463 1.452 1.448 1.375 1.393 韌度，g/d 4.55 4.51 4.54 4.28 4.34 模數，g/d 27.0 29.6 35.6 30.2 25.6 DVA %CV .67 .86 .76 .57 .58 沸溶收縮，％ 8.3 8.3 7.6 10.7 10.7 相關染色深度 中 中 中 深 深 (請先閱讀背面之注意事項再填寫本頁) 裝- -5 線. 太κ/5· iS ffi Ψ 囷 ® 玄摁纸（CNS'pPd描.格（210x297公货） _ 79 - 200534 A 6 B 6 五、發明説明（78 ) 表V I I I (續) 經濟部中央標準局员工消費合作社印製 餵入纱 Μ I-J I-J I-J 拉1申項编號 VIII-6 VIII-7 VIII-8 VIII-9 纺速，mpm 5300 5300 5300 5300 紡拉比 1.00 1.00 1.00 1.00 餵入纱 '% MPMD 20 0 0 0 旦尼爾 50.7 50.5 50.5 50.5 纖絲 13 13 13 13 RV 66.8 65 65 65 伸長度，$ 74.5 73.5 73.5 73.5 (RDR)；· 1.745 1.735 1.735 1.735 (RDR)s 1.745 1.735 1.735 1.735 靱度，s/d 3.58 4.23 4.23 4.23 模數，g/d 10.9 14.3 14.3 14.3 DTjJ »g 52.6 63.5 63.5 63.5 DT33f%CV .46 .39 .39 .39 ΌΊ33*g/d 1.04 1.26 1.26 1.26 DVA，％CV Ν/Α .46 .46 .46 經拉條件 WD單元 BARMAG BARMAG BARMAG BARMAG WD 速，mpm 550 550 550 550 WDtb 1.316 1.316 1.316 1.316 WD溫度1C 60 60 60 60 超餵，％ 5 5 5 5 加熱器溫度，°C 120 無 95 120 放鬆溫度，°C 109 22 90 109 WD張力，gms 80 96 96 98 WD^^，g/dd 1.90 2.28 2.32 2.38 拉伸纱性質 旦尼爾 42.2 42.1 41.4 41.1 伸長度，％ 42.1 36.5 35.8 34.1 (RDR)〇 1.421 1.365 1.358 1.341 韌度，g/d 4.46 5.05 5.08 5.04 f莫數，g/d 28.0 42.1 37.5 38.8 DVA %CV .56 .51 .44 .41 沸溶收縮，％ 10.6 7.3 7.3 7.3 相關染色深度 深 淡 淡 淡 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂 線- 太K /5· iA ffl Ψ囷Η玄熄雄（CNS VP 4姐格（210 X 297公货） -80 -Cao Shi Example VI I Example VI also illustrates the effect of warp stretching conditions on LMDR. The SOY feed yarn described in the above example I-'' K 〃 is drawn on the Bormag STF1 unit at various draw-stretch ratios and relaxation temperatures, as shown in Table V I 1 -7. The resulting yarn bundles were warp knitted into No. 32 warp plain fabric, dyed with LDMR method C.I. Acid Blue 80 dye, and evaluated for hook degree. The results are shown in Table VI. (Please read the precautions on the back before filling out this page) Install--• ° _ Line. Printed paper size ruler printed by Beigong Consumer Cooperative, Bureau of Standards, Ministry of Economic Affairs. Trial ΦInner House Search (CNS) A 4 Folding grid (21〇y 297 cm) -72-200534 A 6 B6 V. Description of invention (71) Feeding yarn IK table VI IK IK IK Drawing item number VI-1 VI-2 VI-3 VI-4 Warp Tensile condition TO speed, mpm • 550 550 550 550 WD ratio 1.15 1.30 1.30 1.30 WD tension, g 50 85 80 80 WD tension, g / dcT 1.12 2.14 2.03 2.15 WD temperature, 1060 60 60 60 overfeed,% 5 5 5 5 Heater temperature, ° C 160 160 130 No relaxation temperature, ° C 143 143 118 22 Tensile yarn denier 44.7 39.8 39.5 40.5 Elongation 3 60.3 43.2 41.7 49.8 (RDR) fl 1.603 1.432 1.417 1.498 Toughness , G / d 4.69 5.29 5.27 5.15 modulus, g / d 18.4 23.5 21.8 21.8 DVA% CV .46 .48 .45 .42 USTER,% .75 .76 .73 .71 Boiling shrinkage,% 5.9 7.6 7.5 6- 9 levels 7.7 5.7 7.6 5-8 (please read the precautions on the back before writing this page). * 1T 'line * Printed by Suigong Consumer Cooperative, Ministry of Economic Affairs太 R 泞 ifi using 屮 Η B3 house to find m (CNS) 屮 4 sister grid (210x297 male sage) -73-200534 A 6 B 6 V. Description of invention (72) Feeding yarn IK Throw VT IK (continued) IK pull Project No. VI-5 VI-6 VI-7 Warp drawing condition WD speed, mpm 550 550 550 WD ratio 1.45 1.45 1.45 WD tension, g 105 115 110 WD tension, g / dcT 2.88 3.23 2.87 WD temperature, ° C 60 60 60 Overfeed. ¾ 5 5 5 Heater temperature, ° C None 130 160 Relaxation temperature, t: 22 118 143 Tensile properties Denier 36.5 35.6 35.4 Elongation,% 36.4 33.2 30.5 (RDR) z, 1.364 1.332 1.305 Toughness, g / d 5.86 6.13 6.17 Modulus, g / d 21.3 29.2 26.6 DVA% CV .51 .49 .41 USTER,% .73 .72 .72 Boiling melt shrinkage,% 8.1 8.6 8.3 grade 6.5 3.6 5.6 * g / d = tensile tension (g) / tensile denier (please read the precautions on the back before filling in this page) Binding-Order _ Line. Printed in Taichi by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs Η 玢 徜 ill ΦYin Yinxuan S (CNS) Shen 4 sister grid (210x297 gong) -74-200534 A6 B6 _ Fifth, the invention description (73) Fen Shi Example VII Example VI I illustrates the stretching temperature to LMDR Shadow bridle. The PDY feed yarn described in Example I above, J " is stretched on Bormas STF1 unit at various warp elongation temperatures, as shown in Table VI I 1-8. The formed yarn bundles were warp knitted into No. 32 warp plain fabric, dyed with L.DM R method C.I. Acid Blue 80 dye, and evaluated for uniformity. The results are shown in Table VI. The yarn drawing temperature between 1 56 and 1 7810 produces a sharp destruction of uniformity. (Please read the precautions on the back before filling in the nest page) Packing-.1T_-Printed by the Employee Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs _ 75-200534 A 6 B6 V. Description of the invention (74) Table VII Feed yarn IJ IJ IJ IJ IJ Drawing item number Warp yarn drawing condition VII-1 VII-2 VII-3 VII-4 VII-5 WD speed, mpm 550 550 550 550 550 550 WD ratio 1.33 1.33 1.33 1.33 1.33 WD tension, g 88 86 82 74 75 WD tension, g / dcT 2.18 2.16 2.06 1.88 1.92 Heater temperature, ° C 80 95 100 125 150 Yarn temperature, t 80 90 94 113 135 Overfeed 3 50 5 5 5 2.5 Relax heater temperature, ° COFF 4rrr / nr M fnr m No relaxation temperature, ° C Tensile yarn properties 22 22 22 22 22 Denier 40.4 39.8 39.9 39.4 39.0 Elongation,% 42.1 42.5 40.6 38.6 36.9 (RDR) zj 1.421 1.425 1.406 1.386 1.369 , S / d 5.23 5.44 5.40 5.51 5.65 modulus, g / d 21.6 19.3 23.0 24.3 28.2 DVA% CV .42 .53 .43 .39 .41 USTER,% N / AN / AN / AN / AN / A Shrink,% series 6.5 8.3 7.0 8.3 6.7 6.4 6.9 7.0 6.9 8.2 (please read the precautions on the back before filling this page) Install-.νφ _ line. The Ministry of Economy, Central Standards Bureau, Employee Consumer Cooperative printed Taiga chromium ΗΨ in order to set itrn (CNS) A 4 sister grid (210x297 public) -76-200534 A 6 B6 V. Description of invention (75) Feeding yarn IJ form VI IJ I IJ Drawing item number VII-6 VII-7 VII-8 Warp drawing conditions WD speed, melon pm 550 > 550 550 WDbb 1.33 1.33 1.33 WD tension, g 75 60 65 WD tension, g / dcT 1.94 1.58 1.70 Heater temperature, ° C 175 200 225 Yarn temperature, t: 156 178 199 Overfeed 4 2.0 1.7 0.2 Relax heater temperature, ° 0 None None Relax temperature, C 22 22 22 Tensile yarn denier 38.6 37.9 38.2 Elongation. ¾ 35.0 33.3 32.2 (RDR) fl 1.35 1.333 1.322 Toughness, g / d 5.73 6.01 5.94 Modulus, g / d 32.5 41.7 39.4 DVA% CV .41 • 48 .45 USTER,% N / AN / AN / A Boiling shrinkage,% 6.6 7.7 6.0 5.1 Grade 3.6 3.6 * g / d- Tensile Tension (g) / Tension Density (Please read the notes on the back before writing this page) Pack * Line -Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 77-200534 A 6 B6 V. Description of invention (76) Example VITT Example VI II Example contains M PMD The possibility of stretching the warp. Three types of S Ο Υ are used to feed the yarn. Item J is the same as that described in Example 1 a J 〃. Item L is spun as described in Example I-J 〃, except that it contains 5% Μ e 5-6, item M is also spun as described in Example I-a J 〃, except that it contains 20% MPMD outer. Such items are stretched at the same draw ratio on the Barmag STF1 unit, but at different relaxation temperatures, and wound on a single yarn winder. The resulting yarn rolls were knitted into Lawson Tubing and all stretched items were dyed with C.I. Acid Blue 122 using the LMDR dyeing method in the same dyeing bath, except that only the relative chromaticity was evaluated. (Please read the precautions on the back before filling in the nest page) Installation · Line-Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. 6 V. Description of invention (77) Printed form VIII Employee Cooperative of Central Bureau of Standards, Ministry of Economic Affairs VIII Feeding yarn LLL Μ Μ Stretching item number VIII-1 VIII-2 VIII-3 VIII-4 VIII- Spinning speed, mpm 5300 5300 5300 5300 5300 Spinning ratio 1.00 1,00 1.00 1.00 1.00 Feed yarn% MPMD 5 5 5 20 20 Denier 50.7 50.7 50.7 50.5 50.5 Fibre 13 13 13 13 13 RV 66.4 66.4 66.4 66.8 66.8 Elongation. ¾ 80.3 80.3 80.3 74.5 74.5 (RDR); 1.803 1.803 1.803 1.745 1.745 (RDR) s 1.803 1.803 1.803 1.745 1.745 Toughness, g / d 3.84 3.84 3.84 3.58 3.58 Modulus, g / d 11.6 11.6 11.6 10.9 10.9 DT ^ 3 * g 55.8 55.8 55.8 52.6 52.6 DTj3,% CV .79 .79 .79 .46 • 46 DTj 3 * s / d 1.10 1.01 1.10 1.04 1.04 DVA,% CV .86 .86 .86 Ν / Α Ν / Α Unit BARMAG BARMAG BARMAG BARMAG BARMA WD speed, mpm 550 550 550 550 550 WD WD ratio 1.316 1.316 1.316 1.316 1.31 6 WD temperature t: 60 65 60 60 60 Overfeed 4 5 5 5 5 5 Heater temperature, ° C None 105 130 No 95 Relaxation temperature, ° C 22 98 118 22 90 WD tension, gms 90 88 82 80 78 WD tension , G / dd 2.12 2.04 1.90 1.88 1.84 Tensile yarn denier 42.3 43.1 43 42.5 42.4 elongation,% 46.3 45.2 44.8 37.5 39.3 (RDR) ;, 1.463 1.452 1.448 1.375 1.393 tenacity, g / d 4.55 4.51 4.54 4.28 4.34 Modulus, g / d 27.0 29.6 35.6 30.2 25.6 DVA% CV .67 .86 .76 .57 .58 Boiling shrinkage,% 8.3 8.3 7.6 10.7 10.7 Relevant dyeing depth medium to medium deep (please read the note on the back first Please fill out this page again)--5 line. Too κ / 5 · iS ffi Ψ 囷 ® paper (CNS'pPd description. Grid (210x297 public goods) _ 79-200534 A 6 B 6 V. Description of invention ( 78) Table VIII (continued) Printed feed yarn printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Μ IJ IJ IJ La 1 Application Number VIII-6 VIII-7 VIII-8 VIII-9 Spinning speed, mpm 5300 5300 5300 5300 Spinning ratio 1.00 1.00 1.00 1.00 Feed yarn '% MPMD 20 0 0 0 Denier 50.7 50.5 50.5 50.5 Fibre 13 13 13 13 RV 6 6.8 65 65 65 elongation, $ 74.5 73.5 73.5 73.5 (RDR); 1.745 1.735 1.735 1.735 (RDR) s 1.745 1.735 1.735 1.735 dimple, s / d 3.58 4.23 4.23 4.23 modulus, g / d 10.9 14.3 14.3 14.3 DTjJ »G 52.6 63.5 63.5 63.5 DT33f% CV .46 .39 .39 .39 ΌΊ33 * g / d 1.04 1.26 1.26 1.26 DVA,% CV Ν / Α .46 .46 .46 Drawbar condition WD unit BARMAG BARMAG BARMAG BARMAG WD speed , Mpm 550 550 550 550 WDtb 1.316 1.316 1.316 1.316 WD temperature 1C 60 60 60 60 overfeed,% 5 5 5 5 heater temperature, ° C 120 no 95 120 relaxation temperature, ° C 109 22 90 109 WD tension, gms 80 96 96 98 WD ^^, g / dd 1.90 2.28 2.32 2.38 Tensile yarn denier 42.2 42.1 41.4 41.1 elongation,% 42.1 36.5 35.8 34.1 (RDR) 〇1.421 1.365 1.358 1.341 tenacity, g / d 4.46 5.05 5.08 5.04 f Mohs, g / d 28.0 42.1 37.5 38.8 DVA% CV .56 .51 .44 .41 Boiling shrinkage,% 10.6 7.3 7.3 7.3 Related staining depth is faint (please read the notes on the back before filling this page ) Packing · Threading-Tai K / 5 · iA ffl Ψ 囷 Η Xuan Xiong (CNS VP 4 sister grid (2 10 X 297 public goods) -80-

Claims (1)

Α ί Β7 C7 D7 ♦ )；；· 200Ι5Ϊ9Γ : 公告本 六、申锖專利範園 附件一（A ): (請先閱讀背面之注意事項再琪寫本頁) 第80104796號專利申請案 中文申請專利範圍修正本 民國81年10月修正 1 ·—種供製備服裝用連绩多絲耐綸平纱之方法，該 纱尤其適於嚴格染色之最终用途，其包括： 將相對粘度（RV)在35至80之間的耐綸聚合物 纺絲，該纺絲操作以足以形成剩餘拉伸比（R D R ) s少 於2. 75之纺纱之退繞速度（Vs )進行； 安定化，交織，並施加整理劑於纺纱以形成剩餘拉伸 比（RDR)尸在1. 5至52. 25之間的餵入纱，餵 入纱之動態長度變化（AL)及縮率（AL/AT),在 4 0 °C至1 3 5 °C之間皆小於〇； •訂· 經濟部屮央樣準工消费合作社印製 乾燥拉伸並實施乾燥放鬆餵入經纱以形成拉伸經纱， 乾燥拉伸在1 . 0 5至（R D R ) f / 1 . 2 5之間的經 纱拉伸比（W R D )及2 0 °C至該聚醯胺聚合物之溫度 Τ //Λ#間之纱拉伸溫度（D )進行，拉伸之餵入經纱 之乾燥放鬆在2 0 °C至比聚醯胺聚合物之熔點（T ~ )少 於4 0 °C之溫度間之纱放鬆溫度（T «)進行，放鬆溫度 另藉下式定義： T«(°C [ 1000/Ki-K2 (RDR)o) )-273 溫度T / / , ^及T 〃，如以下更詳盡說明之固定張力下測 本纸張尺度逋用中Β Η家揉準(CNS) Τ4規格(210x297公釐) 200534 A7 B7 C7 D7 六、申货專利範面 (請先聞請背面之注素事項再填寫本頁) 量對溫度之長度改變％而決定，乾燥拉伸及乾燥放鬆的進 行使拉伸經纱之沸溶收縮（B 0 S )在3 %至1 〇 %之間 且剩餘拉伸比（R D R ) 在1 . 2 5至1 . 8間進行。 2.如申請專利範圍第1項之方法，其中該乾燥拉伸 及該乾燥放鬆在相對濕度（RH)在5 0%至9 0%之間 的惰性氣氛中進行且其中該乾燥放鬆使用少於約1之 超餵（〇 F )百分比進行。 3 ·如申請專利範圍第1項之方法，其中該纺絲中之 該退繞速度是使該纺纱之剩餘拉伸比（R D R s )少於 2 . 5 〇 4 .如申請專利範圍第1項之方法，其中該纺絲中之 該退繞速度是使該紡纱之剩餘拉伸比（R D R s )少於 2 . 2 5 〇 5 .如申請專利範圍第1項之方法，其中該紡絲中之 該退繞速度是使該紡紗之剩餘拉伸比（R D R s ) 少於 2 . 0 〇 6 .如申請專利範圍第1項之方法，其中該紡絲中之 經濟部十央標準历貝工消费合作社印製 該退繞速度是使該紡纱之剩餘拉伸比（R D R s ) 少於 2 . 5 ,其中該乾燥拉伸及該乾燥放鬆在相對濕度（R η )在5 0 %至9 ◦ %之間的惰性氣氛中進行，且其中該乾 燥放鬆使用少於1 ◦ %之超餵（◦ F )百分比進行。 7 .如申請專利範圍第1項之方法，其中該紡絲中之 該退繞速度是使該纺纱之剩餘拉伸bb ( R D R s )少於 2 . 2 5，其中該乾燥拉伸及該乾燥放鬆在相對濕度（ 本纸張尺度適用中B國家株準（CNS) T4規格（210x297公釐） -2 - 經濟部屮央標準局员工消费合作社印製 200534 B7 C7 _____D7 _ 六、申請專利範園 RH)在50%至90%之間的惰性氣氛中進行，且其中 該乾燥放鬆使用少於10%之超餵（OF)百分比進行。 8 ·如申請專利範圍第1項之方法，其中該紡絲中之 該退繞速度是使該纺纱之剩餘拉伸比（R D R s) 少於 2. 0,其中該乾燥拉伸及該乾燥放鬆在相對濕度（RH )在5 0%至9 0%之間的惰性氣氛中進行，且其中該乾 燥放鬆使用少於1 〇%之超餵（OF)百分比進行。 9 .如申請專利範圍第1項之方法，其中該乾燥拉伸 在2 0 °C至T ^ *間的拉伸溫度（T 〇 )下進行。 1 0 .如申請專利範圍第1項之方法，其中該乾燥拉 伸在2 ◦ 1C至Τ 間之拉伸溫度（T D )下進行。 1 1 .如申請專利範圍第1項之方法，其中該乾燥拉 伸是在2 ◦ °C至1 3 5 °C之間之拉伸溫度（Τ σ )下進行 〇 1 2 .如申請專利範圍第1項之方法，其中該乾燥拉 伸是在2 0 °C至9 ◦ °C之間之拉伸溫度（Τ σ )下進行。 1 3 ·如申請專利範圍第1項之方法，其中該乾燥放 鬆是在少於Τ /, , ^之放鬆溫度（Τ « )下進行。 1 4 .如申請專利範圍第1項之方法，其中該乾燥放 鬆是在少於之放鬆溫度（Τ« )下進行。 1 5 .如申請專利範圍第1項之方法，其中該乾燥放 鬆是在少於T w , ι之放鬆溫度（Τ « )下進行。 1 6 ·如申請專利範圍第1項之方法，其中該耐编聚 合物包括耐綸6 6聚合物。 冬紙張又度適用中B國家標準（CNS)甲4規格(210x297公釐） (請先聞磧背面之注意事項#'蜞窝本頁) { •綠· -3 * Α7 Β7 C7 D7 200534 六、申請專利範圊 (請先Μ讀背面之注會事項^:填宵本頁) 17.如申請專利範圍第i項之方法其中該耐编聚 合物包括耐綸66聚合物，其含有少量可與66聚合物氬 鍵結之雙官能聚醯胺共聚單體單元或非反應性添加物。 1 8 .如申請專利範圍第丨項之方法，其中該耐綸聚 « 合物包括耐論6 6聚合物，其含有少量ε _己醯胺共聚單 體單元。 1 9 .如申請專利範圍第χ項之方法，其中該耐綸聚 合物包括耐論6 6聚合物，其含有少量2 —甲基_戊二酷 己二胺共聚單髏單元。 20.如申請專利範圍第1項之方法，其中該耐綸聚 合物包括耐编66聚合物，其含2%至8%重之ε—己酿 胺共聚單體單元。 •訂· 2 1 .如申請專利範圍第1項之方法，其中該耐编聚 合物包括耐綸66聚合物，其含2%至20%重之2—甲 基一戊二醯己二胺共聚單體單元。 經濟部屮央標準局貝工消费合作社印製 •線· 2 2 .如申請專利範圍第丨項之方法，其中該耐编聚 合物包括耐编6 6聚合物，其含有20%至40%重之2 一甲基一戊二醯己二胺共聚單體單元。 2 3 .如申請專利範圍第1項之方法，其中該耐綸聚 合物包括耐綸6 6聚合物，其含有ε —己醯胺共聚單體單 元及2—甲基一戊二醒己二胺共聚單體。 2 4 .如申請專利範圍第1項之方法，其中該耐编聚 合物包括6 -己醯胺單元。 2 5 ♦如申請專利範圍第1項之方法，其中該耐綸聚 衣纸張尺度逋用中國Β家捃準(CNS)甲4規格(210x297公釐) -4 一 200534 A7 B7 C7 D7 經 濟 部 屮 央 標 準 局 员 X 消 费 合 社 印 製 六、申請專利苑園 合物包括耐綸66聚合物且其中K:為4. 9 1 . 7 5 〇 26. 如申請專利範圍第1項之方法其 合物包括耐綸6 6聚合物，其含有2%至 共聚單體單元且其中K/為4. 95且K2為 27. 如申請專利範圍第i項之方法其 合物包括耐綸66聚合物，其含有2%至10 甲基一戊二醯己二胺共聚單體單元且其中K, 且 K2 為 1. 75。 2 8 .如申請專利範圍第1項之方法，其 合物包括ε —己醯胺單元且其中K:為5. 3 1.95。 2 9 .如申請專利範圍第1項之方法，其 該安定化之進行使該餵入纱具少於1 . 2 g / 力（D T 3 3 % ) 0 3〇.如申請專利範圍第1項之方法，其 該安定化之進行使該餵入纱之拉伸張力（D T 1 . 0 g / d 0 3 1 .如申請專利範圍第5或8項之方法 絲及該安定化之進行使該餵入纱之Τ Μ A最大 (△L/ΛΤ) ，在 〇. 〇5 至 0. 15 且（△ L /△ T ) 隨應力（σ )之變化〔 /△T) / d σ〕在 3x 1 〇_4 至 7x 1 °C ) / ( m g / d )之間，如前述般測量。 中該耐编聚 己醯胺 1 . 7 5 〇 中該耐编聚 %重之2 — 為 4 . 9 5 中該耐綸聚 5且K 2為 中該纺絲及 d之拉伸張 中該紡絲及 3 3 % )少於 ，其中該纺 動態延伸率 % / 〇之間 =d ( △ L 0 -4 {% / (請先閱讀背面之注意事項νφΑ寫本頁) •綵· 本紙張尺度適用中Η國家搮竿(CNS) T4規格(210X297公釐） -5 A7 B7 C7 D7 200534 六、申鲭專利範園 32. 如申請專利範圍第5或8項之方法，其中該纺 (猜先«1請背面之注t事項再滇鸾本百) 絲及該安定化之進行使該餵入纱之拉伸應力（σβ )在 1. 0至2. Og/d之間，拉伸模數)在3至7 g/d之間，且表觀拉伸能量（Ep )在〇. 2至〇. 6 (g / d ) ° K之間，如前述般測量。 33. 如申請專利範圍第1項之方法，其中該纺絲安 定化及該乾燥拉伸與乾燥放鬆之進行使該拉伸纱之沸溶收 縮（BOS)在3%至8%之間。 34. 如申請專利範圍第1項之方法，其中該紡絲安 定化及該乾燥拉伸與乾燥放鬆之進行使該拉伸纱之沸溶收 縮（B 0 S )大於8 %。 Λ" 3 5 .如申請專利範圍第1項之方法，其中該纺絲安 定化及該乾燥拉伸與乾燥放鬆之進行使至少部分該拉伸纱 之沸溶收縮（B ◦ S )少於8 %且其他該拉伸經纱之沸溶 收縮（B ◦ S )大於8 % ,而該拉伸經纱之沸溶收縮（ B0S)百分比之差至少為4%。 經濟部屮央標準局貝工消贽合作社印製 .綠· 3 6 .如申請專利範圍第1項之方法，其中該紡絲與 安定化及該乾燥拉伸與乾燥放鬆進行使該拉伸經紗之剩餘 拉伸比在1 . 2 5至1 . 5 5之間。 3 7 .如申請專利範圍第1項，其中該纺絲安定化與 及該乾燥拉伸與乾燥放鬆之進行使該拉伸經纱之T d〃少 於 6 5 0C 〇 3 8 .如申請專利範圍第1項，其中該紡絲與安定化 及該乾燥拉伸之進行使該拉伸經纱之T 少於1 0 ◦ 表紙張尺度適用中國國家掸準（CNS)肀4規格(210x297公釐） 200534 Α7 Β7 C7 D7 經濟部屮央標準局貝工消费合作社印製 六、申請專利苑園 〇C 〇 39·如申請專利範圍笫1項之方法，其中該纺絲與 安定化及該乾燥拉伸與乾燥放鬆之進行使形成之拉伸經纱 具至少6之大分子染料勻度级數（LMDR)。 4 0 .如申請專利範圍第丨項之方法，其中該纺絲與 安定化及該乾燥拉伸與乾燥放鬆之進行使形成之拉伸經纱 具至少6. 5之大分子染料勻度级數（LMDR)。 4 1 ·如申請專利範圍第1項之方法，其中該纺絲與 安定化及該乾燥拉伸與乾燥放鬆之進行使形成之拉伸經紗 具至少約7. ◦之大分子染料勻度级數（LMDR)。 42.如申請專利範圍第1項之方法，其中該餵入纱 經纱包括不同耐綸聚合物及/或餵入纱種類之餵入纱。 4 3 .如申請專利範圍第1項之方法， 其中該紡絲與安定化及該乾燥拉伸與乾燥放鬆之進行 使該拉伸經纱之沸溶收縮（B 0 S )在3 %至8 %之間。 4 4 . 一種服裝用多絲聚醯胺耐綸平纱，其剩餘拉伸 比（R D R β )在1 . 2 5至1 . 5 5之間，沸溶收縮（ BOS)在3%至8%之間或大於8%, Tdye小於 6 5 t：且 Τ 小於 1 0 ◦ 。 ί沆先閱讀背面之注會事項I填寫本頁) •綠. 本紙張尺度逋用中國國家標準（CNS)肀4規格(210x297公釐）Α ί Β7 C7 D7 ♦) ;; · 200Ι5Ϊ9Γ: Bulletin 6. Attachment 1 (A) of Shenfan Patent Park: (Please read the notes on the back before writing this page) No. 80104796 Patent application Chinese patent application Amendment of the scope of the Republic of China in October 81 Amendment 1-a method for preparing continuous multifilament nylon flat yarn for apparel, which is particularly suitable for the end use of strict dyeing, which includes: the relative viscosity (RV) is Spinning of nylon polymer between 80 and 80, the spinning operation is carried out at an unwinding speed (Vs) sufficient to form a spinning ratio (RDR) s less than 2.75; stabilization, interweaving, and Apply a finishing agent to the spinning to form a feed yarn with a residual draw ratio (RDR) between 1.5 and 52. 25, the dynamic length change (AL) and shrinkage rate (AL / AT) of the feed yarn, Between 4 0 ° C and 1 3 5 ° C, it is less than 0; • Order · The Ministry of Economic Affairs, Pyongyang quasi-industrial consumer cooperatives print dry stretch and implement drying and relax feeding warp yarn to form stretch warp yarn, dry Stretching the warp yarn draw ratio (WRD) between 1.05 to (RDR) f / 1.25 and 20 ° C to the polyamide The temperature of the polymer Τ // Λ # is between the yarn drawing temperature (D), the drawing is fed into the warp, the drying is relaxed at 20 ° C to less than the melting point of the polyamide polymer (T ~) The relaxation temperature (T «) of the yarn between 4 0 ° C is carried out. The relaxation temperature is defined by the following formula: T« (° C [1000 / Ki-K2 (RDR) o)) -273 Temperature T / /, ^ And T 〃, as described in more detail below, the paper size is measured under the fixed tension. The paper is used in the middle of the home standard (CNS) Τ4 specifications (210x297 mm) 200534 A7 B7 C7 D7 VI. Application patent scope (please Please read the note item on the back first and then fill in this page.) The amount is determined by the change of the length of the temperature in%. Drying and drying and relaxation are carried out to make the boiling warp of the drawn warp (B 0 S) between 3% and 1 〇% and the residual stretch ratio (RDR) between 1.2 5 to 1.8. 2. The method as claimed in item 1 of the patent scope, wherein the drying stretching and the drying relaxation are performed in an inert atmosphere with a relative humidity (RH) of 50% to 90% and wherein the drying relaxation is used less than About 1 percent of overfeeding (〇F) is performed. 3. The method as claimed in item 1 of the patent scope, wherein the unwinding speed in the spinning is such that the remaining draw ratio (RDR s) of the spinning is less than 2.5 〇4. As claimed in the patent scope of the first Item of the method, wherein the unwinding speed in the spinning is such that the residual draw ratio (RDR s) of the spinning is less than 2.2 5 〇5. As in the method of claim 1 of the patent application, wherein the spinning The unwinding speed in the silk is such that the remaining draw ratio (RDR s) of the spinning is less than 2.06. As in the method of claim 1 of the patent application scope, in which the spinning is under the Ten Central Standard The unwinding speed printed by the Libei Consumer Cooperative Society is such that the remaining draw ratio (RDR s) of the spinning is less than 2.5, where the dry draw and the dry relaxation are at a relative humidity (R η) of 50 It is carried out in an inert atmosphere between% and 9 ◦%, and the drying and relaxation is carried out using an overfeed (◦ F) percentage of less than 1 ◦%. 7. The method as claimed in item 1 of the patent scope, wherein the unwinding speed in the spinning is such that the residual drawing bb (RDR s) of the spinning is less than 2. 25, wherein the dry drawing and the Dry and relax at relative humidity (This paper scale applies to the National B Standard (CNS) T4 specification (210x297 mm) -2-Printed by the Staff Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs 200534 B7 C7 _____D7 _ VI. RH) is carried out in an inert atmosphere between 50% and 90%, and where the drying is relaxed using an overfeed (OF) percentage of less than 10%. 8. The method as claimed in item 1 of the patent scope, wherein the unwinding speed in the spinning is such that the remaining draw ratio (RDR s) of the spinning is less than 2.0, wherein the dry drawing and the drying Relaxation is performed in an inert atmosphere with a relative humidity (RH) between 50% and 90%, and wherein the drying relaxation is performed using an overfeed (OF) percentage of less than 10%. 9. The method as claimed in item 1 of the patent application, wherein the dry stretching is performed at a stretching temperature (T 〇) between 20 ° C and T ^ *. 1 0. The method as claimed in item 1 of the patent application, wherein the dry stretching is performed at a stretching temperature (T D) between 2 ◦ 1C and Τ. 1 1. The method as claimed in item 1 of the patent application scope, wherein the dry stretching is performed at a stretching temperature (T σ) between 2 ◦ ° C and 1 3 5 ° C. 1 2. As the patent application scope The method of item 1, wherein the dry stretching is performed at a stretching temperature (T σ) between 20 ° C and 9 ° C. 1 3 · The method as claimed in item 1 of the patent scope, wherein the drying and loosening is performed at a relaxation temperature (T «) less than Τ /, ^. 14. The method as claimed in item 1 of the patent application, wherein the drying and loosening is performed at a temperature lower than the relaxation temperature (T «). 15. The method as claimed in item 1 of the patent application, wherein the drying and loosening is performed at a relaxation temperature (T «) less than T w, ι. 1 6. The method as claimed in item 1 of the patent application, wherein the knit-resistant polymer includes nylon 66 polymer. Winter paper is again applicable to the National B Standard (CNS) A 4 specifications (210x297 mm) (please read the notes on the back of the moraine # '蜞 窝 this page) {• Green · -3 * Α7 Β7 C7 D7 200534 Apply for a patent fan (please read the notes on the back ^: fill in this page) 17. For the method of applying for patent scope item i, the braided polymer includes nylon 66 polymer, which contains a small amount of 66 Polymer argon-bonded bifunctional polyamide comonomer unit or non-reactive additive. 18. The method as claimed in item 丨 of the patent application, wherein the nylon polymer comprises a polymer 66, which contains a small amount of ε _ hexamethylene amide copolymer monomer unit. 19. The method as described in item χ of the patent application scope, wherein the nylon polymer includes a nylon 6 6 polymer, which contains a small amount of 2-methyl-pentanediamine copolymerized mono-skeletal unit. 20. The method as claimed in item 1 of the patent application, wherein the nylon polymer comprises a knitting resistant 66 polymer, which contains 2% to 8% by weight of ε-hexylamine comonomer units. • Order 2 1. The method as claimed in item 1 of the patent scope, in which the braided polymer includes nylon 66 polymer, which contains 2% to 20% by weight of 2-methyl-pentanediamide copolymerization Monomer unit. Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs • Line 2 2. As in the method of patent application item No. 1, wherein the knitting resistant polymer includes a knitting resistant 6 6 polymer, which contains 20% to 40% by weight Part 2 Monomethyl-pentanediamine hexamethylene diamine comonomer unit. 2 3. The method as claimed in item 1 of the patent application, wherein the nylon polymer includes nylon 66 polymer, which contains ε-hexylamide comonomer unit and 2-methyl-pentanediamine hexamethylenediamine Comonomer. 2 4. The method as claimed in item 1 of the patent application, wherein the knit-resistant polymer includes 6-hexamide units. 2 5 ♦ If the method of claim 1 is applied, the size of the nylon coat is in accordance with China ’s CNA standard 4 (210x297 mm) -4 1 200534 A7 B7 C7 D7 Ministry of Economic Affairs Printed by the member of the Bureau of Standards X Consumer Council. 6. The patent application garden compound includes nylon 66 polymer and the K: is 4. 9 1. 7 5 〇26. If the method of applying for the first item of the patent scope is The compound includes a nylon 66 polymer, which contains 2% to comonomer units and wherein K / is 4.95 and K2 is 27. As in the method of claim i, the compound includes a nylon 66 polymer It contains 2% to 10 methyl pentanediamine hexamethylene diamine comonomer units and wherein K, and K2 is 1.75. 28. The method as claimed in item 1 of the scope of patent application, the compound of which includes ε-hexamide unit and where K: is 5.3 1.95. 2 9. If the method of applying for the first item of the patent scope, the stabilization is carried out so that the feeding yarn is less than 1.2 g / force (DT 3 3%) 0 3〇. If applying for the first item of the patent scope Method, the stabilization is carried out to make the tensile tension of the feed yarn (DT 1.0 g / d 0 3 1. If the method of patent application scope item 5 or 8 and the stabilization is carried out to make the The maximum TMA of the fed yarn (△ L / ΛΤ) is between 0.05 and 0.15 and (△ L / △ T) changes with stress (σ) [/ △ T) / d σ] at 3x 1 〇_4 to 7x 1 ° C) / (mg / d), measured as described above. In the braided polyhexamethylene amide 1. 7 5 〇 In the weight of the braided polymer 2-4 to 4.9 5 in the nylon poly 5 and K 2 is in the spinning and d in the tensile sheet Spinning and 3 3%) Less than, where the dynamic elongation of the spinning% / 〇 = d (△ L 0 -4 {% / (please read the precautions on the back νφΑ to write this page) • Color · This paper The standard is applicable to China National Rod (CNS) T4 specification (210X297 mm) -5 A7 B7 C7 D7 200534 VI. Patent application for the mackerel patent garden 32. If the method of applying for patent scope item 5 or 8, the spinning (guess First «1 please note the item on the back side, then the Yunnan Luan Hundred) The silk and the stabilization are carried out so that the tensile stress (σβ) of the fed yarn is between 1.0 and 2. Og / d, the tensile die Number) is between 3 and 7 g / d, and the apparent stretching energy (Ep) is between 0.2 and 0.6 (g / d) ° K, measured as described above. 33. The method as claimed in item 1 of the patent application, wherein the spinning stabilization and the drying stretching and drying relaxation are carried out so that the drawn yarn has a boiling shrinkage (BOS) of between 3% and 8%. 34. The method as claimed in item 1 of the patent application, wherein the spinning stabilization and the drying stretching and drying relaxation are carried out so that the boil-off shrinkage (B 0 S) of the drawn yarn is greater than 8%. Λ " 3 5. The method as claimed in item 1 of the patent application, wherein the spinning stabilization and the drying stretching and drying relaxation are performed so that at least part of the drawn yarn has a boiling shrinkage (B ◦ S) of less than 8 % And the boiling shrinkage (B ◦ S) of the other drawn warp yarns is greater than 8%, and the difference in the boiling shrinkage (BOS) percentage of the drawn warp yarns is at least 4%. Printed by the Beigong Xiaozhi Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Green · 3 6. The method as claimed in item 1 of the patent scope, in which the spinning and stabilization and the drying stretching and drying relaxation are carried out to make the stretching warp The remaining stretch ratio is between 1.2 5 and 1.5 5. 3 7. As claimed in item 1 of the patent scope, wherein the spinning is stabilized and the dry stretching and drying are carried out so that the T d of the drawn warp yarn is less than 6 5 0C 〇3 8. If a patent is applied Item 1 of the scope, wherein the spinning and stabilization and the dry stretching are carried out so that the T of the drawn warp yarn is less than 10 ◦ The table paper scale is applicable to the Chinese National Shan Standard (CNS) 4 (210x297 mm) ) 200534 Α7 Β7 C7 D7 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 6. Applying for a patent garden 〇C 〇39. The method as described in item 1 of the patent application, in which the spinning and stabilization and the dry drawing Stretching and drying are carried out so that the resulting drawn warp yarn has a macromolecular dye uniformity level (LMDR) of at least 6. 5 0. The method as claimed in item 丨 of the patent application, wherein the spinning and stabilization and the drying stretching and drying relaxation are carried out so that the drawn warp yarn is formed with a macromolecular dye uniformity grade of at least 6.5 (LMDR). 4 1 · The method as claimed in item 1 of the patent application, in which the spinning and stabilization and the drying stretching and drying relaxation are carried out so that the drawn warp yarn is formed with a macromolecular dye uniformity level of at least about 7. ◦ (LMDR). 42. The method as claimed in item 1 of the patent application, wherein the feed yarn warp yarns include feed yarns of different nylon polymer and / or feed yarn types. 4 3. The method as claimed in item 1 of the patent scope, wherein the spinning and stabilization and the drying stretching and drying relaxation are carried out so that the drawn warp yarn has a boiling shrinkage (B 0 S) of 3% to 8 %between. 4 4. A multifilament polyamide nylon flat yarn for apparel, the residual draw ratio (RDR β) is between 1.2 5 and 1.5 5 and the boiling shrinkage (BOS) is between 3% and 8% Between or greater than 8%, Tdye is less than 6 5 t: and T is less than 1 0 ◦. ί 沆 First read the notes on the back of the meeting I fill in this page) • Green. This paper uses the Chinese National Standard (CNS) 4 specifications (210x297 mm)