TW200529749A - Aggrobeatin that lures the cockroaches to struggle for food - Google Patents
Aggrobeatin that lures the cockroaches to struggle for food Download PDFInfo
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- TW200529749A TW200529749A TW93106049A TW93106049A TW200529749A TW 200529749 A TW200529749 A TW 200529749A TW 93106049 A TW93106049 A TW 93106049A TW 93106049 A TW93106049 A TW 93106049A TW 200529749 A TW200529749 A TW 200529749A
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- 241001674044 Blattodea Species 0.000 title claims abstract description 44
- 235000013305 food Nutrition 0.000 title claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 42
- 239000000203 mixture Substances 0.000 claims description 30
- -1 3-amino-4-hydroxyphenyl Chemical group 0.000 claims description 7
- ZZEQNXPBKOFTBG-UHFFFAOYSA-N 2,6,10,15-tetramethylheptadecane Chemical compound CCC(C)CCCCC(C)CCCC(C)CCCC(C)C ZZEQNXPBKOFTBG-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
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- 102000002322 Egg Proteins Human genes 0.000 abstract 1
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- 238000004817 gas chromatography Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000877 Sex Attractant Substances 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
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- 239000007789 gas Substances 0.000 description 3
- 241000238657 Blattella germanica Species 0.000 description 2
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- QPUQNFRDMXWYKM-UHFFFAOYSA-N CCCCCCCCC=CCCCCCCCC(N)=O.CCCCCCCCC=CCCCCCCCC(N)=O Chemical compound CCCCCCCCC=CCCCCCCCC(N)=O.CCCCCCCCC=CCCCCCCCC(N)=O QPUQNFRDMXWYKM-UHFFFAOYSA-N 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
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- 230000007774 longterm Effects 0.000 description 1
- 235000020912 omnivore Nutrition 0.000 description 1
- 244000054334 omnivore Species 0.000 description 1
- 210000003250 oocyst Anatomy 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
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Abstract
Description
200529749 五、發明說明u) 【發明所屬之技術領域】 本發明係關於一種誘引蟑螂類聚爭食之活化組成物， 尤指一種可吸引蟑螂前來群聚並刺激其攝食慾望而達到誘 . 殺目的之活性化合物（A g g r〇b e a t i η )。 【先前技術】 - 蟑螂自遠古三億五千年前即存活地球至今，其於環境 衛生或散播病菌，始終使人極端厭惡與排斥，但人類無論 使用化學藥劑或各種方法，均仍感束手無策。 申請人於長期研究蟑螂的生理與行為特性發現，蟑螂 生存的必備要件為：食物、水及棲息藏匿處，蟑螂的主要 習性包括有：趨暗、趨觸（喜愛鑽隙縫求生）、群聚、食鲁 糞、雜食（偏愛澱粉、醣類食物），食物不足時並有互殘 習性，又性喜潮濕高溫，能耐飢達3 0日，但耐水則不逾七 曰。 實際上，欲有效誘捕蟑螂須應從其生態、行為、生理 -等研究著手，並仔細觀察分析其攝食、求偶、繁殖、求生 等各種行為特徵，始能找出可有效誘引蟑螂取食慾望的刺 ’ 激成份，以便能誘引蟑螂前來群聚並爭食殺蟑餌料，或是 將此一刺激蟑螂食慾的活性物質成份直接攙入食物，一舉 完成誘殺目的；市售有少數的殺蟑餌料，其係以「性費洛 蒙」作為誘引，但因「性費洛蒙」價格極昂貴且具有專一 φ 性，例如德國蟑螂雌性費洛蒙僅對德國蟑螂雄性成蟲有效 ，針對美洲蟑螂即完全無效，且「性費洛蒙」只在一定限 度距離才能發揮效果，故無法普遍推廣。200529749 V. Description of the invention u) [Technical field to which the invention belongs] The present invention relates to an activating composition that induces cockroaches to gather for food, especially an attractant that can attract cockroaches to gather and stimulate their desire to feed. Active compound (Aggrobeati η). [Previous Technology]-Cockroaches have survived the earth since 350 million years ago. They have always caused extreme disgust and rejection in environmental sanitation or spreading germs, but humans still feel helpless regardless of the use of chemical agents or various methods. The applicant's long-term research on the physiological and behavioral characteristics of cockroaches found that the essential requirements for survival of cockroaches are: food, water, and habitat hiding places. The main habits of cockroaches include: darkening, touching (like to survive in the gap), clustering, Shi Lu feces and omnivores (preferred starch and sugar foods), when there is insufficient food, there is a mutual disability, and it is humid and hot, and can withstand hunger for 30 days, but water resistance is not more than seven days. In fact, to effectively trap cockroaches, we must start with their ecological, behavioral, physiological, and other studies, and carefully observe and analyze their behavioral characteristics such as feeding, courtship, reproduction, and survival. Only then can we find thorns that can effectively induce cockroaches to eat. 'Stimulate ingredients, so as to induce cockroaches to come together and compete for food to kill cockroaches, or to inject this active ingredient that stimulates cockroaches' appetite directly into the food to complete the purpose of lure; It is induced by "sex pheromone", but because "sex pheromone" is extremely expensive and specific, for example, German cockroach female pheromone is only effective for German cockroach male adults, and it is completely invalid for American cockroaches. And "sex pheromone" can only exert its effect within a certain limited distance, so it cannot be universally promoted.
第6頁 200529749 五、發明說明（2) 【發明内容】 本發明之主要目的，乃在於提供一種誘引蟑螂類聚爭 食之活化組成物，尤指一種能吸引各種蟑螂前來群聚並刺 激其攝食慾望而達到誘殺目的之活性化合物，此項活性物 質係收集各種蟑螂成蟲、卵鞘、若蟲及其***物，依其不 同齡期及雄雌淬取其體液或***物，經氣相色層分析質譜 儀（GC MASS)、核磁共振光譜儀（NMR)定性，再經氣相色層 分析儀（G C )定量，進而施以分層蒸餾、純化、作誘引試驗 、攝食比較試驗而找到如下三種化合物： I " 4-(3-amin〇-4-hydroxyphenyl) cyclohexanecarboxylic acid 4-(3 -胺基-4羥苯基）環己酸Page 6 200529749 V. Description of the invention (2) [Summary of the invention] The main purpose of the present invention is to provide an activated composition that induces cockroaches to gather for food, in particular to attract various cockroaches to come together and stimulate their feeding. Desirable active compound for trapping purposes. This active substance collects various cockroaches, oocysts, nymphs and their excreta, quenches their body fluids or excreta according to their age and male and female, and analyzes them by gas chromatography. Mass spectrometer (GC MASS), nuclear magnetic resonance spectrometer (NMR) qualitative, and then quantified by gas chromatography (GC), followed by stratified distillation, purification, induction test, feeding comparison test to find the following three compounds: I " 4- (3-amin〇-4-hydroxyphenyl) cyclohexanecarboxylic acid 4- (3-amino-4hydroxyphenyl) cyclohexanoic acid
Π 、9 -〇 c t ade c en am i d e 9 -十八烯驢胺 〇Π, 9-〇 c t ade c en am i d e 9-octadecyl donutylamine 〇
HyWwww\HyWwww \
Iff 、2，6，10，15-tetramethyl-Heptadecane 2, 6, 10, 15-四甲基十七烷Iff, 2, 6, 10, 15-tetramethyl-Heptadecane 2, 6, 10, 15-tetramethylheptadecane
;再以第I種化合物或將I 、Π、ΠΙ三種化合物依不同濃 度測試誘引蟑螂類聚爭食的效果，進而得到最佳之組合配; Then use the first compound or the three compounds I, Π, ΠΙ to test the effect of attracting cockroaches to compete for food at different concentrations, and then get the best combination.
第7頁 200529749 五、發明說明（3) 方，以適合提供作為一誘引蟑螂的活性物（A g g r 〇 b e a t i η ) ，此種活性物會促使雄性、雌性、成蟲及若蟲聚集在一起 且相互接觸，令其誤以為回到熟悉的安定環境中而猶如置 . 身蟑螂族群，以產生聚集安全感，同時促進其攝食慾望， 挑起類聚爭食的本能。 · 本發明之次要目的，乃在於提供一種誘引蟑螂類聚爭 食之活化組成物，所述三種化合物之組成比例如下：第I 種化合物之含量為10%〜90%，第Π種化合物之含量為 5%〜45% ，第Π種化合物之含量為5%〜45%。 本發明之次要目的，乃在於提供一種誘引蟑螂類聚爭 食之活化組成物，所述單獨第I種化合物或I 、Π、HI三春 種調配後之化合物，除可供單獨使用外，亦可與殺蟑餌料 (食物）或水混合使用。 【實施方式】 茲依附圖實施例將本發明之組成及其他作用、目的詳 ‘ 細說明如下： ^ 本發明所為「誘引蟑螂類聚爭食之活化組成物」，其 主要係收集各種蟑螂之成蟲、卵鞘、若蟲及***物，依不 同齡期及雄雌淬取其體液或***物，並經氣相色層分析質 譜儀（G C M A S S )、核磁共振光譜儀（N M R )定性，再經氣相色 層分析儀（G C)定量，進而施以分層蒸德、純化、作誘引試 · 驗、攝食比較試驗而找到以下三種化合物，其中： I " 4-(3-amino-4-hydroxyphenyl) eye 1ohexanecarboxy 1ic acid .Page 7 200529749 V. Description of the invention (3) The formula is suitable to provide an active substance (Aggr 〇beati η) as a cockroach attractant, which will cause males, females, adults and nymphs to come together and come into contact with each other. It made him mistakenly think that he would return to a familiar and stable environment. Being in a cockroach group would create a sense of gathering security, and at the same time promote his appetite for food, provoking the instinct of gathering for food. The secondary object of the present invention is to provide an activated composition that induces cockroaches to fight for food. The composition ratio of the three compounds is as follows: the content of the first compound is 10% to 90%, and the content of the first compound It is 5% to 45%, and the content of the first compound is 5% to 45%. A secondary object of the present invention is to provide an activating composition that induces cockroaches to fight for food. The first compound alone or the compound prepared by the three spring species I, Π, and HI can be used alone or in addition. Mix with cockroach bait (food) or water. [Embodiment] The composition and other functions and purposes of the present invention will be described in detail according to the embodiments of the accompanying drawings. ^ The "active composition for attracting cockroaches to gather and eat" is mainly described in the present invention. Egg sheath, nymphs and feces are quenched according to different ages and male and female body fluids or feces, and characterized by gas chromatography-mass spectrometry (GCMASS), nuclear magnetic resonance spectrometer (NMR), and then by gas chromatography The analyzer (GC) was used for quantification, and the following three compounds were found: layered steaming, purification, induction test, comparison test, and feeding comparison test. Among them, I " 4- (3-amino-4-hydroxyphenyl) eye 1ohexanecarboxyl 1ic acid.
第8頁 200529749 五、發明說明（4) 4 — ( 3 —胺基一4羥笨基）環己酸Page 8 200529749 V. Description of the invention (4) 4- (3-Amino-4hydroxybenzyl) cyclohexanoic acid
Π 9-octadecenamide 9 -十八烯醯胺Π 9-octadecenamide 9 -octadecenamide
2, 6, 10, 15-tetramethyl-Heptadecane 2, 6, 10, 15 -四甲基十七烷2, 6, 10, 15-tetramethyl-Heptadecane 2, 6, 10, 15 -tetramethylheptadecane
上述第 聚爭食之活 :或 I 、Π 類聚爭食的 引蟑螂的活 、雌性、成 回到熟悉的 安全感，同 本發明 第I種 第Π種 第m種 如上第 I種化合物 化組成物」 、Π三種化 效果，進而 性物（A g g r 〇 蟲及若蟲聚 安定環境中 時促進其攝 所述三種化 化合物之含 化合物之含 化合物之含 I種單獨化 係可單獨構成本發明「誘引蟑螂類 ，該化合物之含量為0 . 1 %〜9 5 % 合物亦可依不同濃度測試誘引蟑螂 得到最佳組合配方，以適合作為誘 be a t i η )，此種活性物會促使雄性 集在一起且相互接觸，令其誤以為 而猶如置身蟑螂族群，以產生聚集 食慾望，挑起類聚爭食的本能。 合物之組成比例如下： 量為10 %〜90 % ; 量為5 %〜45 % ; 量為5 %〜4 5 %。 合物或I 、Π 、ΠΙ三種調配之化合The above-mentioned activity of gathering for food: or the cockroaches of category I or Π, the female, and the return to a familiar sense of security are the same as those of the first, the ii, and the m-th compounds of the present invention. "Three kinds of effects", and further the sex (Aggr worms and nymphs gather in a stable environment to promote their taking of the three kinds of compounds, compound-containing compounds, compound-containing I-type singulation systems can constitute the present invention " Attract cockroaches, the content of this compound is 0.1% ~ 95%. The compound can also be tested at different concentrations to induce cockroaches to obtain the best combination formula, suitable for attracting cockroaches. This kind of active substance will promote male collection. Being together and in contact with each other makes them mistakenly think that they are like being in a cockroach group, so as to generate the desire to gather food and stir up the instinct of competing for food. The composition ratio of the compound is as follows: the amount is 10% ~ 90%; the amount is 5% ~ 45%; the amount is 5% ~ 45%. Compound or the combination of I, Π, ΠΙ
第9頁 200529749 五、發明說明（5) 物，係包含一種或一種以上的殺蟲劑並攙入食物I耳料中， 以構成一種殺蟑館料。 如上述第I種單獨化合物或I 、π 、m三種調配之化 . 合物，亦可包含：一種或一種以上的殺蟑|耳料、一種或一 種以上的助溶劑/或界面活性劑/或其它添加劑，以及可 · 促進攝食殺蟑餌料的添加物。 構成本發明「誘引蟑螂類聚爭食之活化組成物」，其 係包含以下二種化合物： (1 )、水； (2)、甲基纖維素 Methyl Cellulose /或乙基纖維 素Hydroxy ethyl Cellulose / 或洋菜膠A gar _ /或三仙膠Xanthan gum /或愛玉膠 上述（1 )的含量係佔整個組成物9 0 %〜9 9 % ，而（2 ) 的含量係佔整個組成物1 %〜1 0 % ，且整個組成物係供單 獨置放，不另混合使用。 ' 上述氣相色層分析質譜儀（GC-MASS):其作用在於針 。 對一種未知成分的化合物，欲探討其組成物之化學構造式 ，分子量、分子式及含量多寡時，可將此未知成分的化合 物以各種方法淬取（蒸餾、熬煮濃縮、溶劑抽出……），再 將淬取液注入氣相色層分析質譜儀GC-MASS ，此氣相色層 分析質譜儀會將淬取液組成物的結構打斷重組，依偵測時φ 間不同顯示在不同的位置，再依各種成分的含量多募以尖 鋒面積大小計算得知。由時間位置來判斷化學物質的種類 ，尖鋒面積即是化學物質含量多募，再比對各種可能化學 .Page 9 200529749 V. Description of the invention (5) The product contains one or more pesticides and is incorporated into the ear material of food I to constitute a cockroach-killing material. Such as the above-mentioned first type of single compound or I, π, and m. The compound may also include: one or more cockroach killer | earings, one or more cosolvents / or surfactants / or Other additives, and additives that can promote the consumption of cockroach bait. The "active composition for attracting cockroaches to fight for food" according to the present invention comprises the following two compounds: (1), water; (2), methyl cellulose Methyl Cellulose / or ethyl cellulose Hydroxy ethyl Cellulose / or Agar gar _ / or Xanthan gum / or Ai Yu Gum The content of (1) above accounts for 90% ~ 99% of the entire composition, and the content of (2) accounts for 1% of the entire composition ~ 10%, and the entire composition is for separate placement, and is not mixed. '' GC-MASS: Its role lies in the needle. For a compound of unknown composition, if you want to explore the chemical structure formula, molecular weight, molecular formula and content of the composition, you can quench the compound of unknown composition by various methods (distillation, boiling concentration, solvent extraction ...), The quenched solution is injected into the GC-MASS gas chromatographic mass spectrometer. This gas chromatography-mass spectrometer interrupts and restructures the composition of the quenched liquid composition, and displays it in different positions depending on the detection time φ. , And then based on the content of various ingredients to calculate the size of the sharp area. Judging the types of chemical substances by time and position, the area of the sharp edge is that the content of chemical substances is more recruited, and then the various possible chemistries are compared.
第10頁 200529749 五、發明說明C6) 物質之標準品 由GC-MASS 電 協助判定列出 上述之氣 有MASS的功能 為主，以定量 種類，再比對 學物質含量多 上述核磁 Spectrometer 而得光譜，對 確的鑑定。主 位置。 再言，本 於實際應用時 、不織布、棉 化學名稱。（ 的貢料庫’故 )° :其作用同上 用來分析化合 由偵測時間判 由尖鋒面積即 計算）。 ear Magmetic 分子中的氫核 構物之結構， 測出其立體結 此工作已可 電腦會自動 ，只是不具 物含量多寡 定化合物之 可計算出化 Resonance 受磁能激發 可作更為精 構式，Η 的 作確認即可找出其 腦中儲存非常豐富 可能的化合物名稱 相色層分析儀（G C ) (定性），G C主要 分析為主要目的’ 標準品即可確認， 募。（電腦會自動 共振光譜儀（N u c 1 ):其作用係利用 於化合物之同分異 要作定性分析。可 發明「誘引蟑螂類聚爭食之活化組成物」， ，其吸附載體係可選用：過濾紙板、棉紙板 花或海棉等材質。Page 10 200529749 V. Description of the invention C6) The standard substance of the substance is determined by GC-MASS electricity. The above-mentioned gas has the function of MASS. It is based on the quantitative species and the content of the substance is compared with the above-mentioned nuclear magnetic spectrometer. , Identification of the true. Home position. Besides, the chemical names of non-woven and cotton are used in practical applications. (The tribute storehouse ’s) °: Its function is the same as above. It is used to analyze the compound. It is determined by the detection time and calculated by the sharp area. The structure of the hydrogen nucleus structure in the ear Magmetic molecule can be determined automatically by measuring the three-dimensional structure of the structure. However, it can be calculated without the chemical content of the compound. Resonance can be excited by magnetic energy for a more detailed structure. Confirmation can be found in its brain, which has a very rich and possible compound name. The colorimetric analyzer (GC) (qualitative), the main analysis of GC is the main purpose. Standards can be confirmed and recruited. (Computerized automatic resonance spectrometer (N uc 1): its role is to use qualitative analysis of the differences between compounds. It can be invented as an "activating composition that induces cockroaches to gather for food". Its adsorption carrier is optional: filtration Cardboard, cotton cardboard flowers or sponges.
第11頁 200529749 圖式簡單說明 第12頁Page 11 200529749 Schematic description Page 12
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| TW93106049A TWI257290B (en) | 2004-03-08 | 2004-03-08 | Activated composition attracting cockroaches to aggregate and bite |
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| Application Number | Priority Date | Filing Date | Title |
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| TW93106049A TWI257290B (en) | 2004-03-08 | 2004-03-08 | Activated composition attracting cockroaches to aggregate and bite |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112358710A (en) * | 2020-11-16 | 2021-02-12 | 深圳市正旺环保新材料有限公司 | Biodegradable plastic bag and preparation method thereof |
| CN113519557A (en) * | 2021-07-15 | 2021-10-22 | 云南京新生物科技有限公司 | Preparation method and application of cockroach and insect sand extract |
| CN113519566A (en) * | 2021-07-15 | 2021-10-22 | 云南京新生物科技有限公司 | Method for preparing cockroach aggregation pheromone extract from cockroach sand and application thereof |
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2004
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112358710A (en) * | 2020-11-16 | 2021-02-12 | 深圳市正旺环保新材料有限公司 | Biodegradable plastic bag and preparation method thereof |
| CN113519557A (en) * | 2021-07-15 | 2021-10-22 | 云南京新生物科技有限公司 | Preparation method and application of cockroach and insect sand extract |
| CN113519566A (en) * | 2021-07-15 | 2021-10-22 | 云南京新生物科技有限公司 | Method for preparing cockroach aggregation pheromone extract from cockroach sand and application thereof |
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