TW200424399A - Paper wiping products treated with a polysiloxane composition - Google Patents

Abstract

A tissue web and/or tissue product comprises a polysiloxane composition. The tissue web and/or tissue product has a post-aged AGAT value of about 60% or more of a pre-aged AGAT value after aging the tissue web and/or tissue product at about 25 DEG C for about 28 days.

Description

424399 玖、發明說明： 【發明所屬之技術領域】 消費者將賴用品(比如面紙、衛钱及紙巾)使用於各種廣泛用 途。面紙不做用於鼻賴料，但除了其他使用外，也可使用作為一般擦 拭用品。因此，目前商業上可買到許多不同類型的薄紙用品。 在些用途中，薄紙用品以洗劑與/或者各種不同其他添加物處 以製作許多理想益._來說，含有聚魏_配方—般已運用於 薄、氏用w此乃為了々加薄紙用品的紐度。尤其，將補合成物加入面 紙可添加改善面紙的絲度，同時維持面紙強度。 【先前技術】 二化子添加物(比如各種不同軟化劑，包括聚矽氧垸)可具有傾 向万、4r疏水性添加至處理的薄紙織物，之後轉變成各種不同薄紙用品。增 加薄紙用叩的疏水性可提供各種不同好處及優點。舉例來說，以疏水性添 加物^理薄紙用品表面有益於以薄紙用品内部空間之薄紙用品吸收堵住 的流體’因此經由薄紙用品緩慢或阻止流體流動 。因此，在使用期間被薄 、，、座吸收的於尚需捕獲於薄紙用品内，而不是轉移至使用者手 中〇 隹；疏水性在一些用途中為理想的，增加疏水性也對薄紙用品或 本身力叱有反作用。例如，增加薄紙用品(比如面紙)的疏水性對薄紙用品 在使用d間吸收體况能力（比如擦拭博反效果。疏水劑也可防止薄紙用品 在使職㈣足夠數量巾魏，並防止使用後於便器或馬桶時 77 政衛生紙。因此’由於疏水性添加物的特質，經由使用疏水性 、、” '毛現處理薄紙織物之理想特性之間的適當平衡，且當轉變成 薄氏用Ρα時’維持薄紙織物的可接受吸收力及可濕性特徵。 另外’聚碎氧燒(比如聚二烷基聚矽氧烷)的親水性益處為與熟化424399 发明 Description of the invention: [Technical field to which the invention belongs] Consumers rely on supplies (such as facial tissue, toilet paper, and paper towels) for a wide variety of uses. Tissue paper is not used for nasal materials, but it can also be used as a general wipe, among other uses. Therefore, many different types of tissue paper supplies are currently commercially available. In some applications, tissue products are made with lotions and / or various other additives to make many ideal benefits. New degree. In particular, adding a supplement to the tissue paper can improve the silkiness of the tissue paper while maintaining the strength of the tissue paper. [Previous Technology] Dimer additives (such as various softeners, including polysiloxane) can be added to the treated tissue paper with a hydrophobicity of 4r, and then converted into various tissue products. Increasing the hydrophobicity of rhenium for tissue paper can provide various benefits and advantages. For example, the use of hydrophobic additives to organize the surface of tissue paper products is beneficial for absorbing blocked fluid with tissue paper products in the interior space of tissue paper products, and thus slowing or preventing fluid flow through the tissue paper products. Therefore, those that are absorbed by tissues during use need to be captured in tissue products, rather than being transferred to users. The hydrophobicity is ideal in some applications. Increasing the hydrophobicity is also useful for tissue products or It is counterproductive. For example, increasing the hydrophobicity of tissue products (such as facial tissues) can absorb the body condition of tissue products (such as wiping the effect of anti-bodies). Hydrophobic agents can also prevent tissue products from using a sufficient number of towels and prevent the use of tissue products. 77 toilet paper after toilet or toilet. Therefore, 'due to the nature of hydrophobic additives, through the use of hydrophobicity, the appropriate balance between the ideal characteristics of the thin tissue fabrics, and when converted into P? The 'acceptable absorbency and wettability characteristics of tissue paper fabrics are maintained at the same time. In addition, the hydrophilicity benefits of polyoxysilanes (such as polydialkyl polysiloxanes) are related to curing.

Mavis-D:\專称 PkOOl .08-Λ0890\ΡΚ-001 -〇890‘doc2004/6/30 5 奴作具有低程度取代的聚二·魏罐例來說，聚二甲基砂 氧燒)提供柔軟性及疏水性好處，此聚魏垸有益於感應熱引發與/或麵 間引11水性變化。在薄紙織物與/或者薄紙用品的最初準備後，具有良好 吸入及滲__薄紙用品不適合在—期間後使用，甚至在四周溫度下使 用具有低程度取代的聚二烷基矽氧烷。 高度變化的聚魏燒可使用於減輕與疏水性增加有關的限制。达 錢化可代替具有聚醚或她麻基㈣魏垸主鏈上的喊基。儘管此 度又化的4魏可減輕若干排出物，這些高度變更的聚魏燒一般以 可觀價位蜂給具有高程度聚二絲魏_聚魏燒，再者，此高度變 更的永魏^上的低程度聚二絲魏·產生高度變化，此在軟化薄紙 ，、哉物上較不有效，且因此甚至在高額外程度的高變化聚魏垸，結果軟化 通常比含料度變化聚二絲魏燒基的高。也知道使用高親水性聚魏 燒與聚二縣魏雜合的混合物，以減輕由聚二絲魏生的若干 疏水性排出物。無論如何，此—般可依照簡單以減少聚二魏燒程度 來取代d在而程度的聚二燒基魏財，薄輯物—般再次變成疏水 性。此外，此混合物有益於具有提高熟化的不穩定性。 、疏水性添加物可局部運用於薄紙織物上的個別位置，此與薄紙織 物的較大未處理顧連接’使得低於·簡_物表面涵蓋疏水性添加 物。此與其在雜織物上個職制疏水性添加物提供疏水性及親水性區 域。無論如何，此侧放置需大多數薄輯物表面，以不含有疏水性添加 物。依照此應用結果，減少用品好處(比如柔軟性)可了解關於具有高程度 表面所及範圍的薄紙織物。此薄紙織物的另一缺點為發生一般迅速雄 (牆through) ’因此’在犧牲薄紙織物與/或者薄紙用品能力獲得的疏水性 可防止流觀速娜至薄輯_/或稍_4其他侧。 -層薄紙用PP可具有大體無聚石夕氧燒的内層，此與親水性聚石夕氧Mavis-D: \ Specially named PkOOl .08-Λ0890 \ ΡΚ-001 -〇890'doc2004 / 6/30 5 Slaves have polydi · wei tanks with a low degree of substitution (for example, polydimethyl sintering) Providing softness and hydrophobicity benefits, this polyweed is beneficial for inducing thermally induced and / or interfacial water changes. After the initial preparation of tissue and / or tissue supplies, tissues with good inhalation and permeability are not suitable for post-period use, even with polydialkylsiloxanes with a low degree of substitution at ambient temperatures. The highly variable polypyridine can be used to alleviate the limitations associated with increased hydrophobicity. Daqianhua can be used as a substitute for polyether or succinyl on the main chain. Although this time, the Weiwei can reduce a number of discharges, these highly altered polyweiyao generally give a high degree of polydiweiwei_polyweiyao at a considerable price, and furthermore, this highly changed Yongwei ^ 上The low degree of polysilicone yields a high degree of change, which is less effective in softening tissues, papers, and therefore even at a high additional degree of high polysilicone. As a result, softening is usually more variable than the content of polysilicone. Wei Shaoji's high. It is also known to use a mixture of a highly hydrophilic poly-Wei-Yan and a poly-Wei-Xian Wei to reduce several hydrophobic effluents produced by Poly-Wei-Wei. In any case, this can generally be replaced by reducing the degree of polydicarbonate instead of polydicarbonate-based Weicai, and the thinner is generally hydrophobic again. In addition, this mixture is beneficial to have instability that increases aging. 2. The hydrophobic additives can be applied locally to individual locations on tissue paper fabrics. This is connected to the larger untreated substrates of tissue paper fabrics, so that the surface of the sub-material covers the hydrophobic additives. This provides a hydrophobic and hydrophilic area with a custom-made hydrophobic additive on the hybrid fabric. In any case, this side is placed on the surface of most albums so as not to contain hydrophobic additives. Based on the results of this application, the benefits of reduced supplies (such as softness) can be learned about tissues with a high degree of surface coverage. Another disadvantage of this tissue fabric is that the general rapid male (wall through) occurs 'hence' the hydrophobicity obtained at the expense of the tissue fabric and / or tissue supplies can prevent the flow rate from being viewed to the thinner_ / or slightly_4 other side . -PP for tissue paper may have an inner layer substantially free of polyoxygen sintering, which is in contrast to hydrophilic polyoxygen sintering

MaV1S-D:\ 專称 PkOOl ·08〜\0890\ΡΚ-001 -0890.doc2004/6/30 200424399 燒連接運用於薄紙用品的二外層，以製造具有結合吸收容量及流體渗勝特 性的溥紙用品。儘管此-結構可提出在吸收用品(比如薄紙用品)中改善渗 膠特性的絲，此不提《具有結合迅速流體吸人咖及滲膠特性的薄紙 織物與/或者薄關品。此外，此—結構不提出祕流體吸人_及渗膠特 性的熱穩定性。 口此目W而要有可運用於薄紙用品的聚石夕氧燒合成物，在超過 理想範圍’此無須增加薄紙織物及薄紙用品的疏水性而供薄紙織物愈/或者 雜用品好處。《具有高程度聚二綠魏_薄_物輿/或者薄紙用 、/、疋木-甲基魏;^ ’以使薄紙織物與/或者薄紙用品添加高程度的 ，性’並提供迅速流體吸人，同時具有長渗糊。再者，需此薄紙織 _/或者薄紙用品來改善熱及時間穩定性，使得薄紙織物的流體吸入速率 與/或者薄紙用品在熟化後仍很高。 【發明内容】 Λ右卞文。的聚二烷矽氧烷(比如IXM149)乳劑商業上 ^=wC_ng ’此位於密西根州的中部地區，此可運用於薄紙織物與/ ^/紙用品’以提供具有高度柔軟性、迅速水吸入(此由AGAT測量來 ^的薄紙織物與/或者薄紙用品，並依照增加騰測量而改善渗膠抗 甲細至 氏織物與域者薄紙用品含有高度聚二燒魏細娜^ :乳=此外，以這些聚石夕氧燒合成物處理的薄紙織物與/或者薄紙 顯㈣傳雜二縣魏錢相當敎的熟化作業。 。林明為針對已㈣魏燒合成物處理的薄紙織物與 及柔 二以改善薄紙織物與/或者薄紙用品的特性，比如跳抗力 同日維持可接受的可濕特性。例如，在-實施例中，本發明為 織物與/二=;及且=卜_ 、、勺2 乂方公分/克(cm3/g)或更大的蓬鬆密度，MaV1S-D: \ Specially known as PkOOl · 08 ~ \ 0890 \ ΡΚ-001 -0890.doc2004 / 6/30 200424399 The two outer layers used for tissue paper products are fired to make a paper with combined absorption capacity and fluid penetration characteristics. Supplies. Although this structure can be proposed to improve the permeability characteristics of silk in absorbent articles (such as tissue products), it does not mention "thin tissue fabrics and / or tissues with a combination of rapid fluid absorption and permeability characteristics. In addition, this structure does not propose the thermal stability of the secret fluid absorption and oozing properties. In order to achieve this goal, there is a need for polyoxygenated sintered composites that can be used in tissue paper products. Above the ideal range, there is no need to increase the hydrophobicity of tissue paper fabrics and tissue paper products for the benefit of tissue paper fabrics and / or miscellaneous goods. "Has a high degree of poly-di-green Wei_Thin_Things and / or tissue paper, /, Tochigi-methyl Wei; ^ 'In order to add a high degree of sexuality to tissue paper and / or tissue supplies' and provide rapid fluid absorption People, while having long ooze. Furthermore, the tissue paper weaving _ / or tissue paper products are required to improve thermal and time stability, so that the fluid suction rate of tissue paper fabrics and / or tissue paper products are still high after curing. [Summary of the Invention] Λ right scripture. Polydioxane Siloxane (such as IXM149) emulsion is commercially available ^ = wC_ng 'This is located in the middle of Michigan, this can be applied to tissue paper and / / / paper supplies' to provide highly flexible, rapid water inhalation (This is tissue paper and / or tissue products measured by AGAT, and the penetration resistance is improved according to the increased measurement. The anti-jam fabric and domain tissue paper products contain highly polydioxane Weissner ^: In addition, to these The tissue paper fabric treated with the polyoxygen sintered composite and / or the tissue paper is quite mature in Weiqian County, Weiqian. Lin Ming is aiming at the improvement of the tissue and fabrics treated with the Weiwei composite. The characteristics of tissues and / or tissue products, such as jumping resistance, maintain acceptable wettability characteristics on the same day. For example, in the embodiment, the present invention is a fabric with / 二 =; and and = 卜 _ ,, spoon 2 square Cm / g (cm3 / g) or greater bulk density,

Mavis-D:\^^IJ\Pk001 08~\0890\PK-001 -0890.doc2004/6/30 200424399 比如約3 cm3/g或更大，並 r基一 _為~百分一= 【實施方式】 目前將詳細參照發明實施例，τ面發表 ==r繼例傭崎限他，輸= 又產生各種不问變更及變動，此無須達反本發明的範圍及精 的-亦r照本發明’聚魏燒合成物可運用於薄紙織物與/或者薄紙用品 =或—側’使縣體狀迅速，流體轉延遲，财完成财高柔軟性 了與/或者薄紙用品。在本發明的特定實施例中，聚魏 物與/或者薄紙用品的二側。聚魏燒合成物可運用於薄紙 I軍=用品，以便充分涵蓋整個薄紙織物與/或者薄紙用品，或 rtr舒。糊來說，砂魏合麟可朝相蓋任何約篇 二二:的薄紙織物與/或者薄紙用品之表面面積。在本發明的—特定實施 歹’’永彻見合成物可涵蓋约50%至職的薄紙織物與/或者薄紙用品 =面，。在本發明的另一實施例中，聚石夕氧燒合成物可涵蓋約砂/0或 的賴織物與/或者薄紙用品之表面面積。在本發明的又另一實施例 氧^成物可涵盖約75%或更多的薄紙織物與/或者薄紙用品之表 =4。在本發明的另—實施例中，可在一致間隔點的圖案中運謝氧 =物’撕點的密度約大於觸點/射，其中聚魏垸合成物可涵 盖、杉0%或更多的薄紙織物與/或者薄紙用品之表面面積。 齡轉•咖〇8〜_PK-001 0890.doc2004/6/30 了解處理薄紙織物與/哎者蘧 a 之探討同樣適用於其«面，如第與/或者第二外侧表面 面。 及弟一外層的内貼邊表面及内層表 用擦拭用品、衛二=口二於與薄紙用品連接，比如紙巾用品 '工業 者多層薄紙用品。等等。薄紙用品可為單層薄紙用品或 使用於此的薄紙及㈣t Γ 薄紙用品為三層的面紙用品。 的用品蓬鬆計算成直„^他 =類用品的差異為本身的蓬鬆。此發明 義）。最後«以立方2=)除以基飾平方公尺)的商數(之後定 直徑的薄紙用品比較基姆’與易於具有較高 挺产及密户m 其他此紙類具有較高強度、硬 明彻21!Γ=Γ的薄紙用品具有約w/g或更大的綠^ 基重範園可約為5 cm3/g 3二更了確约為3 或更大。薄紙用品的Mavis-D: \ ^^ IJ \ Pk001 08 ~ \ 0890 \ PK-001 -0890.doc2004 / 6/30 200424399 For example, about 3 cm3 / g or more, and r-based one _ is ~ one hundredth = [implementation Mode] At present, referring to the embodiment of the invention in detail, the τ surface is published == r following the example to limit him, and the loser = there are various changes and changes, which do not need to reach the scope and precision of the present invention. The invention of "Polymer burning composition can be applied to tissue paper fabrics and / or tissue paper products = or-side" makes the county shape quickly, the fluid transfer is delayed, and the property is soft and / or tissue paper products. In a particular embodiment of the present invention, both sides of the polymeric and / or tissue products are provided. Poly-Wei-Yan composites can be used in tissue papers to provide sufficient coverage for the entire tissue and / or tissue supplies, or rtrshu. To put it bluntly, Sha Wei Helin can cover any of the relevant articles 22: The surface area of tissue paper fabrics and / or tissue supplies. In the specific implementation of the present invention, 歹 ’’ sees that the composition can cover about 50% of the tissue paper fabric and / or tissue paper products. In another embodiment of the present invention, the polysilicon oxy-fired composition may cover a surface area of about 3,000 g / g of rayon fabric and / or tissue paper products. In yet another embodiment of the present invention, the oxygen product may cover about 75% or more of the tissue paper fabric and / or tissue paper table = 4. In another embodiment of the present invention, the density of oxygen tearing points can be transported in a pattern of uniformly spaced dots. The density of the tearing points is greater than that of the contact / radiation, wherein the poly-Weiying composition can cover 0% or more. Surface area of thin tissues and / or tissue supplies. Age transfer • Ca〇08 ~ _PK-001 0890.doc2004 / 6/30 The discussion about understanding the treatment of tissue paper and / 蘧 者 蘧 a also applies to its «faces, such as the first and / or second outer surface faces. The outer surface of the inner layer and the inner surface of the first layer are connected with tissue products such as wipes, sanji = mouth two, such as tissue products' industrial multi-layer tissue products. and many more. Tissue paper supplies can be single-layer tissue paper supplies or tissue paper and ㈣t Γ tissue paper supplies are three-layer facial tissue supplies. The fluffy of the supplies is calculated as straight ^ he = the difference between the types of supplies is its own fluffy. This invention meaning). Finally «divided by cube 2 =) divided by the square meters of the base decoration (comparison of tissue products with a fixed diameter afterwards) Kim 'and easy to have high yield and dense household m. Other this paper has high strength, hard and clear 21! Γ = Γ thin tissue supplies have a w / g or greater of green. For 5 cm3 / g 3 2 more is indeed about 3 or more.

g 土 〇〇 Cm /g，更明確約為 7 cm3/g 至 150 cm3/ 且甚土更加明確约為lW/g至100cmV 聚魏境合成物可運用於單側，或可運用於薄紙織物與/或者薄紙 用印的一側。進十當薄紙織物與/或者薄紙用品為多層用品，聚魏烷 口成4 :為運用於外層與/或者内層的添加物。在本發明的另一特定多層薄 紙用口P實施例中’聚魏燒合成物可運薄紙用品二外層的—或二個内 面表面。在本發明的另一實施例中，薄紙用品為具有第一外貼邊例及第二 外贴邊側的單層薄紙用品，其令聚魏垸合成物可運用於薄紙用品的第一 及第卜、^邊#ί縣發明的另一特定實施例中，薄紙用品為具有第一外 贴邊侧及第二外貼迻侧的二層薄紙用品，其中聚魏燒合成物運用於第一 及第二外貼邊側。在本發明的又另—實施例中，薄紙用品為包含三或更多 層的多層薄紙用品’並包含第—外層、第二外層及—或更多内層。聚魏 燒合成物可個別運用於第—及第二外層的至少其中—第—與/或者第二外 他祕專獅0丨织晴Κ-0請〇.doc屬/30 9 側表面。薄紙用品的⑽大體上沒有聚魏虎合成物，此造成薄紙用品能 快速吸收流體，同時具有改善滲膠特性。此處所使用“大體上沒有，， (substantially free)—詞意謂薄紙織物與/或者薄紙用品的層(pHes)、層(layers) 或區域’其中在薄紙織物與/或者象紙用品於此層⑽es)、層㈣㈣或區域 中約3〇%或更少的聚魏規合成物總重量，更明確的是，其巾在薄紙織物 與/或者薄紙用品於此層(plies)、層(layers)或區域中約Μ%或更少的聚石夕氧 燒合成物總重量，更明麵是，其巾在薄紙織物與/或者薄紙用品於此層 (plies)、層(layers)或區域中約20%或更少的聚矽氧烷合成物總重量，更明 確的是，射在薄紙織物與/或者薄紙用品於此層⑽吻、層物㈣或區域 中約15%或更少的聚魏燒合成物總重量，更明確狀，其中在薄紙織物 與/或者薄紙用品於此層⑽es)、層(layers)或區域中約1〇%或更少的聚石夕氧 合成物總重量，更加明麵是，其巾在薄紙織物與/或者薄紙用品於此層 (plies)、層(layers)或區域中約5%或更少的聚矽氧烷合成物總重量。 本發明的料氧、絲成物可依水分散、制(包括微關)以適當 表面活化劑系統(此可將一電荷給予微乳劑乳胞)穩定傳送。 可使用非軒、陽軒及鋒子_。聚魏燒也可依純流體傳 送0 聚砂氧燒合成物運用於薄賴物與/或者薄紙用品的方法對本發 明並非非f重要。本發_聚魏燒合成物雜輯物與域者薄紙用品之 應用可由任何已知技藝方法完成，但不限定於： •接觸印刷方法，比如照相凹版、偏移照相凹版、橡膠版轉輪 印刷等等。 在薄'、、氏、、哉物與/或者薄紙用品中噴〉麗。舉例來說，噴霧頭可安 ^於移動薄紙織物上方，以將理想少量溶液運用於薄紙織物 H/或者薄紙用品。喷霧器也可使用於將光霧運用於薄紙織物 與/或者薄紙用品的表面。 非接觸式印刷方法，比如喷墨印刷、任何種類的數位印刷等 等。 塗佈薄紙織物與/或者薄紙用品的一或二個表面，比如刮刀塗 佈(Wade coating)、空氣刮漿刀塗佈(air knife coating)、短滯留 時間塗佈(short dwell咖㈣）、熱輥塗佈(cast c〇ating)等等。 薄紙織物可(或不可)為潮濕。 從模頭（比如UFD噴灑尖端，比如獲自位於田納西州 Henderson的ITW-Dynatec)將聚矽氧烷合成物擠壓形成溶 液、分散或乳劑或黏性混合物。 濕薄紙織物注入溶液或淤漿，其中聚矽氧烷合成物穿過薄紙 織物厚度相當距離，比如約20%或更多的薄紙織物厚度，更 明確約為30%或更大的薄紙織物厚度，且更加明確約為 或更大的薄紙織物厚度，此包括完全穿過薄紙織物經過整個 厚度範圍。濕薄紙織物的有用注入方法為Hydra-Sizer®系 統’此由紐約Watertown的Black Clawson Corp·製造，描述 運用漿及其他添加物的新科技（New Technology to Applyg soil 〇〇 Cm / g, more specifically about 7 cm3 / g to 150 cm3 / and even more clearly about lW / g to 100 cmV Poly-Weijing composition can be used on one side, or can be applied to tissue paper and / Or the printed side of the tissue paper. When the tissue paper and / or tissue supplies are multi-layer products, the polyweirane port is 4: it is an additive applied to the outer layer and / or the inner layer. In another specific embodiment of the mouth P of the multi-layer tissue paper of the present invention, the ' Poly-fired Composite can transport two outer layers of tissue products--or two inner surfaces. In another embodiment of the present invention, the tissue paper product is a single-layer tissue paper product having a first outer edge edge and a second outer edge edge side, which allows the poly-Weizhi composite to be used for the first and second edges of the tissue paper edge. 、 ^ 边 # In another specific embodiment of the county invention, the tissue paper product is a two-layer tissue paper product having a first outer edge side and a second outer edge side, in which the polyweier burning composition is applied to the first and the second side. Two outside side edges. In yet another embodiment of the present invention, the tissue paper article is a multilayer tissue paper article ' comprising three or more layers and includes a first outer layer, a second outer layer, and / or more inner layers. The poly-Wei-yin composition can be applied individually to at least one of the first and second outer layers and the second and / or second outer layers. Tissue paper products are generally free of poly-Weihu composites, which results in tissue paper products being able to absorb fluids quickly and at the same time have improved adhesive properties. As used herein, "substantially free" —the word means tissues and / or tissue layers, layers, or areas' wherein tissue and / or paper furnishings are on this layer About 30% or less of the total weight of the polygauge composition in the layer, or layer, or region, and more specifically, the towel is on tissue paper and / or tissue supplies in the plies, layers Or the area of about 5% or less of the total weight of the polyoxygenated sintered composite, more clearly, the tissue is in tissues and / or tissue supplies in this layer, layer or area. 20% or less of the total weight of the polysiloxane composition, and more specifically, about 15% or less of the polyimide shot on the tissue, fabric, or area of the tissue and / or tissue product The total weight of the burned composition is more specific, wherein about 10% or less of the total weight of the polyoxygenated composite in tissues and / or tissue supplies is used in this layer, layer, or area. On the bright side, the towel is about 5% in tissues and / or tissues in this plies, layers or areas Less total weight of the polysiloxane composition. The feed oxygen and silk products of the present invention can be dispersed in water and made (including micro-off) with a suitable surfactant system (this can give a charge to the microemulsion cells) Stable delivery. Non-xuan, Yangxuan and Fengzi can be used. Poly-Wei-Yan can also be delivered as a pure fluid. The method of applying poly-sand oxygen-burning compound to thin lye and / or tissue paper is not important to the present invention. Hair_Polyurethane Composites and Domain Tissue Paper Supplies can be applied by any known technique, but are not limited to: • Contact printing methods, such as photogravure, offset gravure, rubber roll printing, etc. Etc. Spraying in thin, thin, thick, thin, and / or thin paper supplies> Li. For example, the spray head can be installed over the moving thin paper fabric to apply the ideal small amount of solution to the thin paper fabric H / or thin paper Sprayers can also be used to apply mist to the surface of tissue and / or tissue supplies. Non-contact printing methods such as inkjet printing, any kind of digital printing, etc. Coating tissue and / or tissue One or two surfaces of the product, such as Wade coating, air knife coating, short dwell coffee, and hot roll coating ) Etc. Tissue fabrics may (or may not) be moist. Extrusion of a polysiloxane composition from a die (such as a UFD spray tip, such as ITW-Dynatec from Henderson, Tennessee) into a solution, dispersion, or emulsion Or a viscous mixture. A wet tissue paper fabric is filled with a solution or slurry, in which the polysiloxane composition passes through the tissue fabric at a considerable distance, such as about 20% or more, and more specifically about 30% or more. The thickness of the tissue paper fabric, and more specifically about or more tissue paper thickness, this includes passing through the tissue paper completely through the entire thickness range. A useful method for injecting wet tissues is the Hydra-Sizer® system, which is manufactured by Black Clawson Corp., Watertown, New York, and describes a new technology using pulp and other additives (New Technology to Apply

Starch and Other Additives)中，紙漿及紙 Canada，100(2): T42-T44(1999年2月）。此系統由沖模、可調整支撐結構、 擋盤及附加供應系統。下降液體或淤漿的薄幕接觸下面的移 度薄紙織物。系統也可運用於遮蔽塗佈較乾的薄紙織物，比 如恰巧在起縐之前或之後的薄紙織物。 聚矽氧燒合成物至薄紙織物的泡沐給液(例如泡泳整理），不 是局部應用就是將聚矽氧烷合成物在壓力不同影響下注入 薄紙織物(例如以真空幫助泡沫注入）。添加物(比如黏合劑及Starch and Other Additives), Pulp and Paper Canada, 100 (2): T42-T44 (February 1999). This system consists of a die, an adjustable support structure, a baffle and an additional supply system. The curtain of falling liquid or slurry touches the mobile tissue paper underneath. The system can also be used to mask dry tissue paper coatings, such as tissue paper that happens to be before or after creping. The infusion solution of the polysiloxane composite to tissue paper (such as bubble finishing) is not a local application, but the polysiloxane composite is injected into the tissue paper under the influence of different pressures (for example, vacuum is used to help foam injection). Additives (such as adhesives and

Mavis-D:\專利\Pk00 丨 _08〜\0890\ΡΚ-001 -0890. doc2004/6/30 || 200424399 聚矽氧烷)的泡沫給液原理描述於由Paciflci等人頒布於198l 年11月3日的美國專利編號第4,297,86〇號，以及G. j. Hopkins頒布於1兆8年9月27日的美國專利編號第4,773，ιι〇 號，二者無對立而完全合併於此作為參考。 *聚魏垸合成物藉噴灑或其他裝置運用於軸扣帶或織 品，此依序接觸薄紙織物與/或者薄紙用品，以將聚矽氧烷合 成物運用於薄紙織物與/或者薄紙用品，比如在名稱s· Eichhom下描述於WO 01/49937，此公佈於2〇〇1年6月12 曰。 使用於本發明聚魏燒合成物的聚魏燒之特殊結構可提供理 想用品特性給薄紙織物與/或者薄紙用品。聚魏燒含有非常廣泛種類的化 合物。了解使祕此的此項“聚魏燒合成物” _於_聚魏燒或聚 石夕氧坑齡物及與其他成分結合的聚主鏈結構的特徵為：Mavis-D: \ Patents \ Pk00 丨 _08 ~ \ 0890 \ ΡΚ-001-0890. Doc2004 / 6/30 || 200424399 (Polysiloxane) The principle of foam feeding is described in Paciflci et al. U.S. Patent No. 4,297,86 on March 3, and U.S. Patent No. 4,773, ιιο, issued by G. j. Hopkins on September 27, 2018. The two are incorporated here without any opposition. Reference. * Polyurethane composites are applied to shaft buckles or fabrics by spraying or other devices. This sequentially contacts tissue paper fabrics and / or tissue paper supplies to apply polysiloxane composites to tissue paper fabrics and / or tissue paper supplies, such as It is described under the name s · Eichhom in WO 01/49937, which was published on June 12, 2001. The special structure of the polyweier fired used in the polyweier fired composition of the present invention can provide desirable characteristics for tissues and / or tissues. Polywean contains a very wide variety of compounds. Learn about the "poly-weiyao composition" that ___ __weiwei-yao or poly-shixiu pit age and the main characteristics of the poly-chain structure combined with other ingredients are:

II

RR

I --Si--〇 I ·I --Si--〇 I

R 此處R'及R'、可為廣範圍的有機及無機群，包括此群的混合物， 且η為大於2的錄。這錄魏燒可為直線、分支或環狀4們包括各 種廣之的聚魏燒共聚物，此共聚物含有官能基的各種不同合成物，因 此’汉'及R''魏上可表示_聚合物分刊好不嗎型的群。有機或 無機群可载漿纖維處理，錢聚魏燒共價、離子或氫鍵結至纖維素。 這些官能基也可本身反應，以戰與崎_蚊鍵基質。R Here R 'and R' can be a wide range of organic and inorganic groups, including mixtures of these groups, and η is greater than 2. This record can be straight, branched, or cyclic. They include a wide range of poly-Wei-Yan copolymers. This copolymer contains a variety of different functional groups. Therefore, 'Han' and R 'Wei can be represented by _ The polymer sub-group is not a good type of group. Organic or inorganic groups can be treated with pulp fibers, and copolycarbonate is covalently, ionically, or hydrogen bonded to cellulose. These functional groups can also react by themselves to fight the mosquito-keyboard matrix.

Mavis-_W_.08、\_\pK〇〇i_ 如2_/3〇 12 200424399 •树明謂戰不纽树殊料絲轉，只要聚石夕 mrt述賴用品的好處雜__與/或者最後薄_品，柔軟 用薄^=或者薄紙用品可含有若干程度的聚二乾基魏垸。此處所使 Ζΐ'ΓΓR''4 CrC3〇^W ° 1. 41。含絲4_氧__官能歧矽氧垸可使用於 ^的。各種耳能基可存於除了有聚二甲垸石夕氧規個體外的聚合物 ㈣化合物也可使麟產生理想產物。舉例來說，氨基官能聚 I魏可氧基甘醇-共聚晴氧燒。此材料的範例為DC-謂及 -_〇讀’此商業上獲自密西根州中部地區的Dow C⑽㈣。 、發月的$實犯例中，聚碎氧垸部分可選自稱為“氣基官 月匕的耳能聚矽氧烷基，此一般式為：Mavis-_W_.08, \ _ \ pK〇〇i_ Such as 2_ / 3〇12 200424399 • Tree Ming said that war will not last forever, as long as the benefits of jushi mrt relies on miscellaneous supplies __ and / or in the end Thin products, thin ^ = soft or thin paper supplies may contain some degree of polydimeric Wei Wei. Here, Znΐ'ΓΓR''4 CrC3〇 ^ W ° 1. 41. Silk-containing 4_oxy__functional bissiloxane can be used for ^. A variety of ear energy groups can be stored in addition to the polymer with polydimethylene sulphate, and rhenium compounds can also produce ideal products. By way of example, amino-functional poly (oxyco) glycol-co-polymers are available. Examples of this material are DC-predicated and -_〇 读 ', which is commercially available from Dow C⑽㈣ in central Michigan. In the actual case of Fa Yue, the polyoxo moiety can be selected from the ear-energy polysiloxy group called "air-based official moon dagger", this general formula is:

•Ο· R7 ’ 1 R9 I 1 一 Si-〇 一 1 "*Si·-〇— R8 R10 y 一- R4 I _Si—R5 X R1 r2_• 〇 · R7 ’1 R9 I 1-Si-〇-1 " * Si · -〇— R8 R10 y--R4 I _Si—R5 X R1 r2_

I •Si- /、及3"為大於〇的整數。X與(x+y)的莫爾比率約為0.005% 至30%。R #部分可獨立為任何單價有機群，此包括q或較高的燒基、 謎、聚敲、麵、胺、亞胺、雜或其他t能基(包括此基、絲或燒氧基 的綠及輸目似物）。R7、r8及r9可獨立為Crc3G脂賊烴基。Ri〇部分 可為氨基官能烴部分，此包括(但不受限)第—胺、第二胺、第三胺、第四 胺、雜環族化合胺、相咖航魏合物。祕R1^_成分含有 一胺基’或每取代有二或更舰，此由cl或更大的直線或分支燒鍵分I • Si−, and 3 " are integers greater than 0. The Mohr ratio of X to (x + y) is about 0.005% to 30%. The R # part can be any monovalent organic group independently. This includes q or higher alkynyl, mystery, polyknolide, surface, amine, imine, hetero, or other t-energy groups (including this group, silk or alkoxy group). Green and losers). R7, r8, and r9 may independently be Crc3G aliphatic octadecyl groups. The Rio moiety may be an amino-functional hydrocarbon moiety, which includes (but is not limited to) a first amine, a second amine, a third amine, a fourth amine, a heterocyclic compound amine, and a phase compound. The component R1 ^ _ contains one amino group or two or more per substitution, which is divided by a straight line or branched bond of cl or larger.

Mavis-m 專孙Pk001 〇8〜\〇8ί 90XPK-001 -0890.doc2004/6/30 13 200424399 離。r1g基可含有雜環族環、兩性基或其他官能度還有氮官能度。 可適當使用於本發明的其他種類官能聚矽氧烷為聚醚聚矽氧 烷。它們可單獨使用或與其他聚矽氧烷(比如上述的氨基官能聚矽氧烷)一 起使用。此聚矽氧烷一般可具有下面結構··Mavis-m special grandson Pk001 〇8 ～ \ 〇8ί 90XPK-001 -0890.doc2004 / 6/30 13 200424399. The r1g group may contain a heterocyclic ring, an amphoteric group, or other functionality, as well as a nitrogen functionality. Another type of functional polysiloxane that can be suitably used in the present invention is polyether polysiloxane. They can be used alone or in combination with other polysiloxanes such as the amino-functional polysiloxanes described above. This polysiloxane can generally have the following structure ...

R1 I R7 I 一 — R9 I _ 麵 R° I R4 I R2-Si—_ 〇— 1 1 "Si—-〇- 一 1 -Si--π- ΐ 一 I rSi-〇* I -Si--R5 R8 R10 * R11 * R6 — X 曝 麵 y _ _ Z 其中’ X及Z為大於〇的整數。y為-〇的整數。χ與仏+#2)的莫 爾比率可約為0.05%至95%。y與㈣㈣的比率可約為〇%至25%。R〇-R9 部分可獨jl為·ΟΗ、燒氧基或任何有齡縣，此包括&或較高絲、酸、 聚酸、聚醋、胺、亞胺、雜或其他官能基(包括此基的燒基及婦基相似物）。 R7及R8可為Q-C%脂肪族烷基，此包括這些基的混合物。RlG部分可為氨 基官能部分，此包括(但不姐)第—胺、第二胺、第三胺、第哺、未取 代驗胺及其混合物。示範rig部分每倾分含有—絲，絲取代有二或 更多胺基，此由C1或更大的直線或分支燒鏈分離。Rll可為具有一般式的 -R12-(R13-〇)a.(R14〇VRi5, R12 ^ Ci^ fe基、直線或分支;R15可為H或Ci 3〇燒基;且“a，，及“b，，約為整數！至 100 ’更明確約為5至3G。R1。也可為使用於與聚_能基結合的環氧官能 基或聚氫氧官縣。可控姆_、職基、聚魏基及絲的比率，以使 本發明有特定產物益處。 。-如上所述’在薄紙織物與/或者薄紙用品中的聚二燒基石夕氧燒數量 可、=聚二絲魏域分轉換成具有三氟化硼的n基魏燒。二氣 、疋基魏U後”使喊體層析法測量，以測定薄紙織物與域者薄紙R1 I R7 I one — R9 I _ plane R ° I R4 I R2-Si—_ 〇— 1 1 " Si --- 〇- one 1 -Si--π- ΐ one I rSi-〇 * I -Si- -R5 R8 R10 * R11 * R6 — X exposure surface y _ _ Z where 'X and Z are integers greater than 0. y is an integer of -0. The mole ratio of χ to 仏 + # 2) may be about 0.05% to 95%. The ratio of y to ㈣㈣ may be about 0% to 25%. The part of R〇-R9 can be ΗΗ, oxo, or any aged county, this includes & or higher silk, acid, polyacid, polyacetate, amine, imine, hetero or other functional groups (including this Burning base and analogues of feminine base). R7 and R8 may be Q-C% aliphatic alkyl, which includes a mixture of these groups. The RlG moiety may be an amino functional moiety, which includes (but is not limited to) the first amine, the second amine, the third amine, the first amine, the unsubstituted test amine, and mixtures thereof. The demonstrative rig part contains-silk, which is substituted with two or more amine groups, which are separated by straight or branched chains of C1 or larger. R11 may be -R12- (R13-〇) a. (R14〇VRi5, R12 ^ Ci ^ fe group, straight line or branch; R15 may be H or Ci 30 group; and "a, and "B, is about an integer! To 100 'more specifically about 5 to 3G. R1. It can also be an epoxy functional group or a polyoxygen group used in combination with a polyenergetic group. Ratio of base, poly-Wei-ki, and silk, so that the present invention has a specific product benefit.-As described above, the amount of poly-di-fired cornerstone in tissue and / or tissue supplies can be oxidized, = The domains are converted into n-based Weiyan with boron trifluoride. After the two gas, fluorene-based Wei U ", the method of bulk chromatography was used to determine tissue paper and domain tissue paper.

Ma.s-D:Wm〇〇,〇8^pK.〇〇1^ i4 200424399 :W Μ永—&基_完之總數量。薄紙織物與/或者薄紙用品中的聚二燒 ^她讀量在本發明__中可_·55%或更大。在本發明的: 〇 Txl 1，+ ^ 〇·6/〇或更大。在本發明的 ^ ^ ^ 议另种，在薄紙織物與/或者薄紙用品中 的4二燒麵魏數量可約為q/7%或更大。 $ / &不希麵理論綑綁，好處為聚魏紐具魏燒合成物傳送 有薄紙__/或者觀心的㈣齡雜部分與聚魏垸的分子 量有關。黏度常常使用作為聚魏_分子量標示，此測定正確 數目或重量平均分子量。在本發明的各種不同實施例中，此目的為經由使 用氷碎滤與/或者聚魏齡成物來傳送隸性好處，聚魏㈣黏度約 為5 cP(百刀之一泊)或更大，在本發明的另一實施例中約為％ π或更 大，且又本發明的另一實施例中約為1〇〇 cP或更大。此處所使用“黏度” (viscosity)-咐謂純聚石夕氧燒本身的黏度，且假使傳送的化並非乳劑與/ 或者合成物的黏度。也須了解本發明的聚魏餅隨含有稀釋劑的溶液來 傳U此稀釋劑可降低溶液黏度，使低於上面限制設定，無論如何，聚碎 氧k的有效#刀與上面給的黏度範圍一致。此稀釋劑的範例包括(但不受限） 齊聚物或壤齊聚物聚魏燒，比如八甲基環1魏垸、八甲基三碎氧燒、 十甲基環五石夕氧燒、十甲基4_矽氧烷及包括這些化合物之混合物的相似 物 額外添加物可併入聚矽氧烷合成物，此無須達背本發明精神。舉 例來說，可能額外的化學添加物可併入聚矽氧烷合成物，依照本發明，此 可運用於薄紙織物與/或者薄紙用品，包括(但無受限)鬆解劑、抗瘡作用、 抗菌作用、抗黴菌作用、殺菌作用、抗氧化劑、化妝用收斂劑、藥品收斂 劑、生物添加物、防臭劑、軟化劑、外用止痛藥、黏合劑、薄膜成形器' 香氣及已知技藝的其他肌膚保濕原料、不透明劑、肌膚調理劑、肌膚剥落Ma.s-D: Wm〇〇, 〇8 ^ pK.〇〇1 ^ i4 200424399: The total number of WM Yong- & base-end. Polydiamine in tissues and / or tissue supplies ^ She reads __ in the present invention _ 55% or greater. In the present invention: 〇 Txl 1, + ^ 0.6 / 0 or greater. In another aspect of the present invention, the number of noodles in tissue paper fabrics and / or tissue supplies may be about q / 7% or more. $ / & Does not wish to be bound by theory, the advantage is that the poly-Wei-Niu-Wei-Wei-Synthetic compound is transported with thin paper __ / or the concentric part of the mind that is related to the molecular weight of Poly-Wei-Pu. Viscosity is often used as a molecular weight indicator, which determines the correct number or weight average molecular weight. In various embodiments of the present invention, the purpose is to convey the benefits of slavery by using ice crushing and / or poly-Wei-Ling products, the poly-Wei-Ping viscosity is about 5 cP (one hundred poises) or more, It is about% π or more in another embodiment of the present invention, and about 100 cP or more in another embodiment of the present invention. As used herein, "viscosity"-refers to the viscosity of the pure polyoxygen oxidizer itself, and if the transferred chemical is not the viscosity of the emulsion and / or the composition. It is also necessary to understand that the polywei cake of the present invention is passed along with the solution containing the diluent. This diluent can reduce the viscosity of the solution and make it lower than the upper limit setting. In any case, the effective #knife and the viscosity range given above Consistent. Examples of such diluents include, but are not limited to, oligomers or soil oligomers, such as octamethylcyclopentane, octamethyltrioxane, and decamethylcyclopentane. Decamethyl 4-siloxane and analogues including mixtures of these compounds can be incorporated into the polysiloxane composition without the addition of the spirit of the present invention. For example, it is possible that additional chemical additives may be incorporated into the polysiloxane composition. According to the present invention, this may be applied to tissue paper and / or tissue supplies, including (but not limited to) a release agent, an anti-ulcer effect , Antibacterial effect, antifungal effect, bactericidal effect, antioxidant, cosmetic astringent, pharmaceutical astringent, biological additives, deodorant, softener, topical analgesics, adhesives, film shaper's aroma and known techniques Other skin moisturizing ingredients, opacity agents, skin conditioners, skin peeling

Mavis-D:\^i IJ\Pk001,08-\0890\PK-001 -0890. doc2004/6/30 200424399 劑、肌膚保護劑、防曬乳等等。 面祕/紙用品可為任何適#軌用品，㈣紙巾、擦拭物、衛生紙、 彻於製造本發明薄紙用品的賴織物越或未起續以及 二或料。薄紙用品可為單層或多層薄紙用品。本發明的薄紙用品可為 此口、分層或其任何組合。另外，薄紙用品可為起續、未起續或其组合。 在本發明的其_酬巾，薄紙織财藉水_作用、氣流成網作用或已 知技藝的其他方法製造。 ，單層或夕層的薄紙織物與/或者薄紙用品可藉已知技藝的任何方 法製造。舉例來說，薄紙片可藉濕法成網作賴造，其帽釋水性紙漿纖 、隹於隸t祕網上’以將崎纖維過濾出，並形成胚胎薄紙織物，此之 後以裝置組合(包括狀箱、濕壓器、乾聽裝置等等)脫水。已知脫水及 其他操作來自Farrmgton，k等人頒布於簡年8 $ u日的美國專利編號 第5,656，132號。毛細管脫水也可運用於除去薄紙織物的水分，如1997年 2月4日頒布所揭發的美國專利編號第5,598,643號，以及”幻年以月3 日頒布所揭發的美國專利編號第切6,4%號，二者皆為s· c· Chuang等 人，其在非對JL的範圍内合併於此作為參考。 對本發明的薄紙織物與/或者薄紙用品而言，可使用起縐及未起縐 的製造方法。未起縐製造由Farrington，Jr.等人於1998年6月30日頒布所 揭發的美國專利編號第5,772,845號，二者無對立而完全合併於此作為參 考。起縐薄紙製造由Ampulski等人於1997年6月10日所頒布揭發的美國 專利編號第5,637，194號;Trokhan於1985年7月16日所頒布的美國專利編 號第4,529,480號;Oriaran等人於2000年8月15日所頒布的美國專利編號 第6，103,063號;Wells等人於1984年4月3曰所頒布的美國專利編號第 4,440,597號，二者無對立而完全合併於此作為參考。同樣適合上面提到的 聚矽氧烷與/或者聚矽氧烷合成物之應用為壓實或蓋印圖案的薄紙織物與/Mavis-D: \ ^ i IJ \ Pk001,08- \ 0890 \ PK-001 -0890. Doc2004 / 6/30 200424399, skin protection agent, sunscreen lotion, etc. The facial / paper supplies can be any suitable rail products, such as paper towels, wipes, toilet paper, fabrics, etc., which are completely different from the fabrics used to make the tissue products of the present invention. Tissue paper supplies can be single-layer or multi-layer tissue supplies. The tissue product of the present invention may be a spout, a layer, or any combination thereof. In addition, tissue paper supplies may be continuous, non-continuous, or a combination thereof. In the present invention, it is made of a towel, a tissue weaving, a water-repellent effect, an air-laid effect, or other methods known in the art. Tissue fabrics and / or tissue products in single or evening layers can be made by any method known in the art. For example, the tissue paper sheet can be made by wet-laid web. The cap releases the water-based pulp fibers and smashes them on the secret net to filter out the saki fibers and form an embryo tissue paper fabric. Including case, wet press, dry listening device, etc.) Dehydration. Dehydration and other operations are known from U.S. Patent No. 5,656,132 issued by Farrmgton, K. et al. Capillary dehydration can also be used to remove moisture from tissue paper fabrics, such as US Patent No. 5,598,643, issued on February 4, 1997, and US Patent No. 6,4, published on February 3, 1997. %, Both of which are s · c · Chuang et al., Which are incorporated herein by reference within the scope of non-parallel JL. For the tissue paper fabric and / or tissue products of the present invention, creped and uncreped can be used Uncreped Manufacturing US Patent No. 5,772,845 issued by Farrington, Jr. et al. On June 30, 1998, the two are incorporated herein by reference without any opposition. The creped tissue paper is manufactured by U.S. Patent No. 5,637,194 issued by Ampulski et al. On June 10, 1997; U.S. Patent No. 4,529,480 issued by Trokhan on July 16, 1985; Oriaran et al. On August 15, 2000 U.S. Patent No. 6,103,063 issued on the same day; U.S. Patent No. 4,440,597 issued by Wells et al. On April 3, 1984, the two are incorporated herein by reference without any opposition. The same applies to the above Polysiloxane And / or polysiloxane composition for compacted or stamped tissue paper fabrics and /

Mavis-D:\專横 k001.08 〜、0890\PK-〇01 -0890_d〇c2004/6/30 200424399 或者薄紙用品，比如下面任一揭發的織物·· Johnson等人於1985年4月3〇 日頒布的美國專利編號第4,514,345氮由T]Okhan於1985年7月9日頒 布的美國專利編號第4,528，；239號;I"2年3月24日頒布的美國專利編號 第5,〇98,522號;由Smurkoski等人於1993年11月9日頒布的美國專利編 號第5,260，171號;由Trokhan於1994年i月4日頒布的美國專利編號第 5,275,700號;由Rasch等人於1994年7月12日頒布的美國專利編號第 5,328,565氮由Trokhan等人於1994年8月2日頒布的美國專利編號第 5,334,289號;由Rasch等人於1995年7月u日頒布的美國專利編號第 5,431，786號;由Steltjes，Jr.等人於1996年3月5日頒布的美國專利編號第 5,496,624號;由Trokhan等人於觸年3月19日頒布的美國專利編號第 5,500,277號;由Trokhan等人於簡年5月7曰頒布的美國專利編號第 5,514,523號;由Trokhan等人於1996年9月1〇日頒布的美國專利編號第 5,554,467號;由Trokhan等人於1996年10月22日頒布的美國專利編號第 W，724號;由Trokhan等人於1997年4月29日頒布的美國專利編號第 5,624，’號;以及由Ayers等人於聰年5月13日頒布的美國專利編號第 5,628,876號，二者鱗立而完全合餅此作為參考。此蓋印的薄紙織物與 /或者薄紙用品可具有網狀組織的壓實區域，此已由蓋印織品蓋印緊靠一滾 筒乾燥器’此區域較不壓實(例如在薄紙片中的“棋頂”），此與蓋印織品 中偏離導f-致’其巾放於偏料管的薄紙彳藉不赌跨偏離導管的氣 壓而偏離，以在賴織物與/或者薄_品中軸低密度似枕區域或棋頂。 各種不同乾燥操作可用於本發明薄_物與/或者薄紙用品的製 造。此乾燥方法的範例包括(但不受限)滾筒乾燥、完全乾燥、蒸氣乾燥(比 如過熱蒸氣乾燥）、取代脫水、楊琪乾燥、紅外線乾燥、微波乾燥、一般射 頻乾燥及脈衝乾燥，如由_於簡年頒掏_錢專利編號第 5,353,521號以及由〇齡等人於1997年2月*日頒布的美國專利編號第Mavis-D: \ bossy k001.08 ~, 0890 \ PK-〇01 -0890_d〇c2004 / 6/30 200424399 or tissue paper supplies, such as any of the following fabrics disclosed · Johnson et al. April 3, 1985 U.S. Patent No. 4,514,345 issued on July 30, 2015; U.S. Patent No. 4,528, issued by T] Okhan on July 9, 1985; No. 239; I " U.S. Patent No. 5,098,522 issued on March 24, 2 U.S. Patent No. 5,260,171 issued by Smurkoski et al. On November 9, 1993; U.S. Patent No. 5,275,700 issued by Trokhan on January 4, 1994; Rasch et al. On July 7, 1994 U.S. Patent No. 5,328,565 issued on December 12, Nitrogen No. 5,334,289 issued by Trokhan et al. On August 2, 1994; U.S. Patent No. 5,431 issued by Rasch et al. On July u, 1995, No. 786; U.S. Patent No. 5,496,624 issued by Steltjes, Jr. et al. On March 5, 1996; U.S. Patent No. 5,500,277 issued by Trokhan et al. On March 19, 1996; by Trokhan et al. U.S. Patent No. 5,514,523 issued on May 7, 2007; issued by Trokhan et al. U.S. Patent No. 5,554,467 issued on September 10, 1996; U.S. Patent No. W, 724 issued by Trokhan et al. On October 22, 1996; issued by Trokhan et al. On April 29, 1997 U.S. Patent No. 5,624, '; and U.S. Patent No. 5,628,876 issued by Ayers et al. This stamped tissue and / or tissue product may have a compacted area of the mesh structure, which has been stamped against the tumble dryer by the stamped fabric. 'This area is less compacted (for example, in the " Chess top "), which is inconsistent with the deviation in the stamped fabric, which causes the tissue paper placed on the bias tube to deviate by not betting across the pressure of the deflection duct to lower the center axis of the fabric and / or thin product. The density resembles a pillow area or chess top. A variety of different drying operations can be used in the manufacture of tissue and / or tissue supplies of the present invention. Examples of this drying method include (but not limited to) drum drying, complete drying, steam drying (such as superheated steam drying), replacement of dehydration, Yang Qi drying, infrared drying, microwave drying, general radio frequency drying and pulse drying, such as by _ Issued in the short year _ Qian Patent No. 5,353,521 and U.S. Patent No.

Mavis-DA^f IJ\Pk〇〇 ι ,〇8~\0890\PK-001 -0890. doc2004/6/3〇 17 200424399 5,598,642號，—者無對立而完全合併於此作為參考。可使用其他乾燥技 術，比如使用不同氣壓的方法，此包括使用氣壓，如A Hermans等人於2〇〇〇 年8月1日頒布所揭發的美國專利編號第6,〇96，169號，以及由Hada等人 於2_年11月7日頒布的美國專利編號第6，143，135號，二者無對立而 完全合併於此作為參考。同樣相關為紙機械，此由ι α·越咖。η等人於 1993年7月27日頒布所揭發的翻專利編號第5,23()，776號。 各種廣泛的天然或合成紙漿纖維適合使用於本發明的薄紙織物 與/或者薄紙用品。紙漿纖維可包括由各種漿化作用（比如牛皮紙槳、亞硫 H域械式紙漿等等)形成。另外，紙漿纖維可由任何高平均纖維 長度紙漿、低平均纖維長度紙漿或相同混合物所組成。 一、適田回平均長度紙衆纖維的一範例包括軟木纖維。♦大木紙裝纖維 饤生万、針葉樹，並包括紙漿纖維，比如(但不受限)北方軟木、南方軟木、 人，」、工柏木、母胡蘿萄、松木(例如南方松木）、雲杉(例如黑雲杉)及其組 合轉。北方軟木牛皮紙漿纖維可使用於本發明中。商業上可適當使用於 =月中所利用的北万軟木牛皮紙漿纖維的範例包括獲自金百利克拉克 «Longlac.19^ τ〇 太^(二低平均長度紙聚纖維的另一範例為所謂的硬木紙漿纖維。硬 樺科洛葉树’並包括紙漿纖維，比如(但不受限)桉樹、槭樹、 胁地㈣等S右干實财，彳梅緣麟尤其理想可增加薄紙片的 姆。桉樹紙漿纖維也可提高亮度、增加不透明度，並改變薄紙片的細 材=以=本身的芯吸能力。再者，假使理想的話，可使賴自再生 物的紙衆纖維。 沫説出自白報紙、再生硬紙板及辦公室廢Mavis-DA ^ f IJ \ Pk〇〇ι, 〇8 ~ \ 0890 \ PK-001-0890. Doc2004 / 6 / 3〇 17 200424399 5,598,642, which is hereby incorporated by reference without any opposition. Other drying techniques may be used, such as methods using different air pressures, including the use of air pressure, such as US Patent No. 6,096,169, issued by A Hermans et al. On August 1, 2000, and U.S. Patent No. 6,143,135 issued by Hada et al. On November 7, 2_, which is hereby incorporated by reference without any opposition. It is also related to paper machinery, which is made by ια · 越 咖啡. η et al., issued on July 27, 1993, issued a patent reference No. 5,23 (), 776. A wide variety of natural or synthetic pulp fibers are suitable for use in the tissue and / or tissue products of the present invention. Pulp fibers can include a variety of pulping processes (such as kraft paddles, sulfite H-domain mechanical pulp, etc.). Alternatively, the pulp fibers may be composed of any high average fiber length pulp, low average fiber length pulp, or the same mixture. 1. An example of Shida Hui average length paper fibers includes softwood fibers. ♦ Big wood paper fibers produce 10,000, coniferous trees, and include pulp fibers, such as (but not limited to) northern softwood, southern softwood, humans, ", cypress, mahogany, pine (such as southern pine), spruce (Such as black spruce) and combinations thereof. Northern softwood kraft pulp fibers can be used in the present invention. Examples of commercially available Beiwan softwood kraft pulp fibers that can be suitably used in the middle of the month include those obtained from Kimberly-Clark «Longlac.19 ^ τ〇 太 ^ (Another example of two low average length paper polyfibers is the so-called Hardwood pulp fibers. Hard birch kolo leaves' and include pulp fibers, such as (but not limited to) eucalyptus, maple, oxford, etc. S. serrata are especially good for cultivating plum trees. E. Eucalyptus pulp fibers can also increase brightness, increase opacity, and change the wicking ability of the thin material of the thin paper sheet. In addition, if ideal, it can make paper fibers that rely on regeneration. From white paper, recycled cardboard and office waste

Mavis-D:\^f IJ\Pk001 -〇8~-\0890\PK-001 -0890.doc2004/6/30 18 200424399 明確約為9· 1至1: 4，且更加明確約為9: 1至1:：[。在本發明的一實 犯例中，在形成薄紙織物與/或者薄紙用品之前，可將硬木紙漿纖維及軟木 紙聚纖維混合’藉以在z方向的薄紙織物與/或者薄紙用品中製造硬木紙聚 纖維及軟木紙漿纖維的同種分類。在本發明的另—實施例中，硬木紙裝纖 維及軟木綠_可分層，以便在z柏的薄紙織物與/或者薄紙用品中得 到硬木紙漿纖維及軟械___分類。在另—f施射，硬木紙裝 纖維可位於薄紙織物與/或者薄紙用品的至少其中一外層，其中至少其中一 内層可包含軟木紙漿纖維。 另外，合成纖維也可利用於本發明的薄紙織物與/或者薄紙用品 中。此處關於紙漿纖維的討論了解乃包括合成纖維。可使用於形成合成纖 維的-些適當聚合物包括(但不受限课烴(比如聚乙婦、聚丙婦：聚丁婦等 等)、聚醋(比如聚乙婦對苯二甲酸酯、聚乙醇酸(PGA)、聚乳酸(PLA)、聚(点 -蘋果酸XPMLA)、聚己内酯XPCL)、聚(…二魏XPDS)、聚絲丁醋 (poly LhydroxybutyrateXPHB)等等)以及聚醯胺(比如尼龍等等）。包括(但^ 受限)醋纖維素、醚纖維素、硝酸鹽纖維素、醋酸鹽纖維素、路醋酸纖維素、 乙基纖維素、再生纖維素(比如纖維黏液、人造絲等等）、棉花、亞麻、大 麻及其混合物的合成或天然纖維素聚合物可使用於本發明中。合成纖維可 位於任一或全部的薄紙織物與/或者薄紙用品中，以及任一或全部層的特定 薄紙層中。 在本發明的-實施例中，依照本發明處理的薄紙織物與/或者薄紙 用品可具有層化紙漿纖_漿。舉例來說，在本發明的―實施例中，薄紙 織物與/或者薄紙用品可在硬木紙漿外層之間有軟木紙_維的中間層。假 使理想的話，每層也可含有碎紙。在本發明的—特別實施例中，成層紙嚷 纖漿可包括-外層的硬木紙漿纖維、—中間層的敕木紙漿纖敎碎= 以及第二外層的硬木紙漿纖維與軟木紙漿纖維混合物。在本發明的又另Mavis-D: \ ^ f IJ \ Pk001 -〇8 ~-\ 0890 \ PK-001 -0890.doc2004 / 6/30 18 200424399 Explicitly about 9.1 to 1: 4, and more explicitly about 9: 1 To 1 :: [. In an actual case of the present invention, before forming the tissue paper fabric and / or tissue paper product, the hardwood pulp fiber and the cork paper polyfiber can be mixed to thereby manufacture the hardwood paper polymer in the tissue paper fabric and / or tissue paper product in the z direction. The same classification of fiber and softwood pulp fiber. In another embodiment of the present invention, the hardwood paper fiber and softwood green_ can be layered so as to obtain the hardwood pulp fiber and soft machine____ classification in the tissue paper fabric and / or tissue products of the cypress. In another example, the hardwood paper fibers may be located in at least one of the outer layers of tissue paper fabric and / or tissue supplies, and at least one of the inner layers may include softwood pulp fibers. Synthetic fibers can also be used in tissue paper fabrics and / or tissue products according to the present invention. The discussion of pulp fibers herein includes synthetic fibers. Some suitable polymers that can be used to form synthetic fibers include (but are not limited to hydrocarbons (such as polyethylene, polypropylene: polybutylene, etc.), polyacetate (such as polyethylene terephthalate, Polyglycolic acid (PGA), polylactic acid (PLA), poly (point-malate XPMLA), polycaprolactone XPCL), poly (... diweis XPDS), poly Lhydroxybutyrate XPHB, etc.) and poly Amidine (such as nylon, etc.). Including (but limited to) cellulose acetate, ether cellulose, nitrate cellulose, cellulose acetate, cellulose acetate, ethyl cellulose, regenerated cellulose (such as fiber slime, rayon, etc.), cotton Synthetic or natural cellulose polymers of linseed, flax, hemp, and mixtures thereof can be used in the present invention. Synthetic fibers can be located in any or all tissue tissues and / or tissue supplies, as well as in specific tissue layers in any or all of the layers. In embodiments of the present invention, tissue paper fabrics and / or tissue supplies treated in accordance with the present invention may have a layered pulp fiber pulp. For example, in an embodiment of the present invention, tissue paper fabrics and / or tissue supplies may have a cork paper-dimensional intermediate layer between the outer layers of hardwood pulp. If desired, each layer may also contain shredded paper. In a particular embodiment of the present invention, the layered paper pulp fiber pulp may include-an outer layer of hardwood pulp fibers,-an intermediate layer of hardwood pulp fibers, and a second outer layer of hardwood pulp fibers and a softwood pulp fiber mixture. In another aspect of the invention

Mavis-D:\ 專称Pk〇〇i. 8 \〇89〇\ρκ-〇〇 1-0890. doC2〇〇4/6,3〇 19 200424399 實施例中’成層紙親維㈣可包括二外層的硬木㈣、_與碎紙混合 物。紙雜維於將可進-步包括外層之間的中間層軟木紙浆纖維。 此處所使用“直徑”（caliper)一詞意謂單張薄紙織物與/或者單層 薄紙用品的厚度，且不是依單張薄紙織物與/或者薄紙用品的厚度測量，就 是依10張薄紙織物與/或者薄紙用品的厚度測量，並將1〇張厚度除以1〇， 此處堆疊_每輯紙織物與/或者薄紙用品面朝上。餘以微米表 示。此依照mm試驗方法T402 “紙類、厚紙板、紙聚、手巾及相關用 品的標準調整及試驗氣壓，，（standard conditi〇ning — Te_Mavis-D: \ Specially named Pk〇〇i. 8 \ 〇89〇 \ ρκ-〇〇1-0890. DoC2〇〇4 / 6, 3〇19 200424399 In the embodiment, the "layered paper pro-dimensional" may include two outer layers Hardwood ㈣, _ and shredded paper mixture. Paper miscellaneous will be further-including an intermediate layer of cork pulp fibers between the outer layers. As used herein, the term "caliper" means the thickness of a single tissue and / or single-layer tissue product and is measured either by the thickness of the single tissue and / or tissue product or by the 10 tissues and Measure the thickness of tissue paper supplies and divide the thickness of 10 sheets by 10. Here, stack each paper fabric and / or tissue paper face up. The rest is expressed in microns. This is in accordance with mm test method T402 "Standard adjustment and test pressure of paper, cardboard, paper, hand towels and related products," (standard conditi〇ning — Te_

For Paper，Board，Pulp Handsheets and Related Products)以及 Τ411 〇m-89 “紙類、紙板及組合板的厚度（直徑），，（Thickness㈣㈣〇fFor Paper, Board, Pulp Handsheets and Related Products) and Τ411 〇m-89 "Thickness (diameter) of paper, paperboard and composite board, (Thickness㈣㈣〇f

Pa__andCombinedB〇ard) ’此任意有聽3的堆疊^ T411 〇m-89的測微计為蓬鬆測微計(BuikMi咖加㈣(tmi型號49 72⑻， 紐約的Amltyvme)或具有4又1/16英叶⑽2毫米摩徑(娜η如齡 及22〇克/平方英忖(3·3千巴斯卡)的站壓(anvil pre贿e)。 在本發明的-實施例中，聚石夕氧規合成物一律運用於薄紙織物與 /或者薄紙用品，使得涵蓋約6〇%或更大的薄紙織物與/或者薄紙用品的至 少-處理表面之表面面積。在本發明的另—實施财，聚魏燒合成物一 律運用於薄紙織物與/或者薄紙用品，使得涵蓋約7〇%或更大的薄紙織物與 /鱗薄紙用品的至少—處理表面之表面面積。此處使用相同分離沉殿的聚 氧k 口成物此在娜及CD方向中的沉殿頻率一般約為1〇〇制或更 大。在本發_-實施例中，在MD與/或者cd方向中的沉殿頻率可約 為勘dp或更大。在本發明的其他實施例中，在婦辦或者⑶方向中 的沉澱頻率可約為300 dpi或更大。 在本發明的-些實施例中，薄紙織物與/或者薄紙用品一般可用聚 傾垸合成物處理，比如含有聚二絲矽魏的_燒合成物。舉例來Pa__andCombinedB〇ard) 'This is a stack of 3 ^ T411 〇m-89 micrometer is a fluffy micrometer (BuikMi Kajia ㈣ (tmi model 49 72⑻, New York Amltyvme) or has 4 and 1/16 inches The leaf diameter of 2 mm is 2 mm, and the standing pressure is 22 g / square inch (3.3 kBska). In the embodiment of the present invention, The gauge composition is always applied to tissue paper fabrics and / or tissue paper products so as to cover at least 60% or more of the surface area of the tissue paper fabric and / or tissue paper products in at least the treated surface. In another embodiment of the present invention, The Wei burning composition is always applied to tissue paper fabric and / or tissue paper products, so that it covers at least 70% or more of the surface area of the tissue paper and / or tissue paper products. At least the surface area of the treated surface is used here. The oxygen sinking frequency of the products in the Na and CD directions is generally about 100 times or more. In the embodiment of the present invention, the Shen frequency in the MD and / or cd directions may be about Is dp or greater. In other embodiments of the present invention, the precipitation frequency in the direction of women's office or ⑶ may be Is 300 dpi or greater in the present invention - such embodiments, the fabric and the tissue / tissue or articles are typically available polyethylene composition was poured embankment processing, such as polydimethylsiloxane containing silicon wire burning composition Wei _ way of example.

MaviS-D:\l：Wk001,08^\〇890\PK.〇〇l.〇89〇.d〇c2〇〇4/6/3〇 20 200424399 說:在-實施例中，聚魏垸合成物可包含—聚二綠魏燒。聚二燒基 魏燒的總數量至少為a6 wt%的乾燥薄紙，更明確約大於a7 wt%的乾燥 薄紙。聚二錄魏燒的數量由gc_BF3方法測定。假使聚二垸基魏燒 除了使用聚：甲基魏垸外，GC.BF3方法適合測量整個聚二絲魏燒而 不是只有聚二甲基矽氧烷。 如上面所說明，由於本身的疏水性，聚秒氧垸合成物及其他化學 添加物-般節省使聽-些職中，如，由於在衛生_品的可濕性之 反效果’在聚魏細_運用於衛錢用品中遭遇—些問题。根據本發 明’藉運《魏燒合成物，已發現聚魏燒合成物可運麟薄紙織物^ /或者溥紙用品中，以改善薄紙織物與/或者職用品的特性，同時維持可 此處所使用“流體滲膠”（制d strikethrough) 一詞意謂流體吸收 能從薄紙織物與/或者薄紙用品—側通過薄紙織物與/或者薄紙用品另一 側。儘轉紙織物與/或者薄紙用品預期為吸收物，理想的是此薄紙織物盘 /或者薄紙用品防止流體通過而接觸使用者手中。薄紙織物與/或者薄紙用 品快速吸錄_能力可由浸_間(概财)啦。可使用H_iesSize Test ^ 〇 ^ ^在本發實施财，薄紙織物與/或者軌用品可具有約3秒或更 大的HST值，且更明確約為4秒或更大。 、同樣細本發明，本發___績/鱗_用品可里有料 此與流體吸人時間有i使用具有高聚二垸基魏垸之聚_ 二 =有以此聚彻處理的疏水性薄 向’ =«舰(甚至在觸溫度刀增加不被' =屬性’且發現疏水性效果隨溫度崎增加。與具有她程二 基魏______，本發日___者MaviS-D: \ l: Wk001,08 ^ \ 〇890 \ PK.〇〇Ι.〇89〇.d〇c2〇〇 / 6 / 6〇20 200424399 Said: In the example, polywei The material may include-poly di green Weiwei. The total quantity of polydioxane-based sintered at least a6 wt% dry tissue paper, more specifically about a7 wt% dry tissue paper. The quantity of Ju Er Lu Wei Wei was determined by gc_BF3 method. Assuming polydioxane, in addition to the use of poly: methylwei, the GC.BF3 method is suitable for measuring the entire polydioxane, not just polydimethylsiloxane. As explained above, due to its hydrophobic nature, polysecond oxygen compounds and other chemical additives-as economical as possible-in some jobs, such as, due to the adverse effect of hygienic product's wettability in Juwei Fine_Applied to some problems encountered in health supplies. According to the present invention, the "Wei burning composition" was borrowed, and it has been found that the poly Wei burning composition can be used in tissue paper fabrics and / or paper products to improve the characteristics of tissue paper fabrics and / or office supplies, while maintaining usability for use herein. The term "d strikethrough" means that the fluid absorbs energy from tissue paper and / or tissue supplies-one side through tissue paper and / or tissue supplies. While the tissue and / or tissue product is expected to be an absorbent, it is desirable that the tissue fabric tray and / or tissue product prevent fluid from passing through and contacting the user's hands. Tissue paper fabrics and / or tissue paper products can quickly absorb _ ability can be dip _ (fortune). The H_iesSize Test may be used. In the present implementation, tissue paper and / or rail supplies may have an HST value of about 3 seconds or more, and more specifically about 4 seconds or more. The same details of the invention, the present ___ performance / scale _ supplies can be expected in this and fluid intake time i use a polymer with a high polymer difluorenyl radical Wei _ two = there is a thin hydrophobic treatment '= «Jiang (even when the temperature is increased, the knife is not changed by' = attribute ') and the hydrophobic effect is found to increase with temperature. With those who have her Cheng Erji Wei ______, this date ___

Mavis-D：^WkooJ.〇M〇89^ 21 200424399 薄紙用品可具有改善穩定性。 ， 本發曰⑽薄紙織物與/或者薄紙用品約於歡下約2星編化之 ^可具有約w克/克/秒W或更大的AGAT值，更明確約為〇·55克_、 1/2或更大，且更加明確約為〇·6克/克/秒1/2或更大。薄紙織物與/或者薄紙 用品於4〇〇c下約2星期熟化之後可具有約4或更大的腺值，且更明確 約為5或更大。於挪下約4星期或更長熟化之後，薄紙織物與/或者薄 =用品的AGAT值可約為0.6克广或更大，更明確約為〇 7克/克/秒 2或更大’且更明確約為0.8克/克/秒,"或更大。於25〇c下約4星期或更 長热化《後，薄紙織物與/或者薄紙用品的咖值可約為3秒或更大，更 月崔勺為4秒或更大。換句話說，本發明的薄紙織物與域者薄紙用品於 25〇C下約28天之後保有至少約6〇%的預熟化A·值，更明確保有至少 約65%的預熟化AGAT值，且更明確至少约有7〇%的預熟化A·值。 在4〇%c，本發明的薄紙織物與/或者薄紙用品在2星期後保有至少約鳩 的預熟化AGAT值，且更明輕少約35%的職化A·值。 如上所述’倾本發明製造㈣輯物與/或者賴用品顯示結合 有利特性。尤其’薄輯物與/或者薄紙用品不僅擁有—般運薄紙織物 與/或者薄紙用品的化學添加物好處，薄紙織物與/或者薄紙用品也維持可 接受可濕性特徵及滲膠特徵。 额外化學添加抽 在开4薄紙織物或胚胎薄紙織物前，也可任意將化學添加物加入 水性製紙中’以使薄紙織物鐵錄_品及作縣加婦好處，且 不，、本=_ _盈互相牴觸。下面材料包括可運用於薄紙織物與/或者 薄紙用品_外化學添加物勤⑽及本發_聚魏垸合成射。化與六 加物包括範例’且無意圖限制本發日_。可在製紙作用中的任—點(2Mavis-D: ^ WkooJ.〇M〇89 ^ 21 200424399 Tissue products can have improved stability. The hair tissue and / or tissue products of this hairdress are about 2 stars, and can have an AGAT value of about w g / g / sec W or more, more specifically about 0.55 g. 1/2 or more, and more specifically about 0.6 g / g / sec. 1/2 or more. Tissue fabrics and / or tissue supplies may have a gland value of about 4 or greater after curing at 400c for about 2 weeks, and more specifically about 5 or greater. After being aged for about 4 weeks or longer, the AGAT value of tissue paper fabrics and / or thinner articles can be about 0.6 grams or more, more specifically about 0.7 grams / gram / second 2 or more 'and More specifically about 0.8 g / g / s, " or greater. After heating at 25 ° C for about 4 weeks or longer, the coffee value of tissue paper and / or tissue supplies can be about 3 seconds or more, and 4 seconds or more. In other words, the tissue and fabric of the present invention retain at least about 60% of the pre-aged A · value after about 28 days at 25 ° C, and more clearly ensure that there is at least about 65% of the pre-aged AGAT value, and More specifically, at least about 70% of the pre-aged A · value. At 40% c, the tissues and / or tissue products of the present invention retain a pre-aged AGAT value of at least about 2 weeks after the two weeks, and more clearly about 35% of the professional A · value. As described above, the present invention exhibits advantageous characteristics in combination with making an edited material and / or a product. In particular, the tissue paper and / or tissue products not only possess the advantages of chemical additives for tissue paper fabrics and / or tissue paper products, but also maintain acceptable wettability and bleed characteristics of tissue paper fabrics and / or tissue paper products. Additional chemical additions can be drawn before opening 4 tissue paper or embryo tissue paper, and chemical additives can be added to the water-based paper arbitrarily to make the tissue paper iron products and the benefits of the county, and no, this = _ _ Ying touched each other. The following materials include tissue paper fabrics and / or tissue supplies.化 和 六 加 物 includes examples ’and is not intended to limit this date. Can be used in the papermaking role-point (2

Ma祕專獅00丨綱崎κ補鐵 22 200424399 聚矽氧烷合成物)加入此化學添加物。化學添加物可與本發明的聚矽氧烷合 成物混合，或作為分離化學添加物。 重荷控制劑 電荷促進劑及控制劑一般使用於製紙作用中，以在作用濕部控制 製紙淤漿的界面電位。這些種類可為陰離子或陽離子，大部分通常為陽離 子’且不是自然發生材料(比如明礬)就是一般分子量約為5〇〇,〇〇〇或更少的 低分子量咼電荷密度合成聚合物。可將排水及保留力扶助加入淤漿 ，以改 善構造、排水及優良保留力。所包括的保留力及排水扶助為含有高表面地 區、鬲陰離子電荷密度材料的微粒子系統。 心、G、㈢涟劑也可運用於薄紙織物與/或者薄紙用品中。此處所 使用濕增強齊Hwet strength agents)-詞意謂在濕狀態中使用於固定鍵 結紙漿纖維之間的材料。一般方法為紙漿纖維固定於 日用品中，此峨鍵結，且檐合氫鍵及共働/或者峨 月中’可有i於提供可允許以此—方式連結紙漿纖維的增強劑，以固定 維間_、_ ’邮紐態中統漿齡抗***。在此賴中，渴狀 ^^當賴織物與/或輕賴品大量财或其财溶赫者 薄紙用。二?=而言'當將任何增強劑材料加八薄紙織物與/或者 率的： 強劑就是“卿，、.π # ^些材料不是稱為持久濕增 時辦強劑。為了區別持久濕增強劑與暫時濕增強劑，持 _專獅飢0一 23 200424399 久增強劑漿定義為樹脂，當併人薄紙織物與/或者薄紙用品時，在暴露逾水 中至少5分鐘期間後，將提供保留超過5〇%最初濕強度的薄紙織物與域者 薄紙用品。暫_增_在浸泡5分鐘細示約观或更少的最初濕強 度。本發明巾發現應用二麵增關。根據紙漿纖維的乾重，濕增強劑加 入紙漿纖維的數量至少約為(U乾重％，更明確約為〇·2乾重％或更大，且 更加明確約為〇·1至3乾重％。 持久濕增強劑-般將提供薄紙織物與/或者薄紙用品結構有更多 或更少長期濕彈力。對照下，暫時濕增強劑—般將提供具有低蚊及高彈 力的薄紙織物與/或者雜用品結構，但不提供财長她絲露於水或體 液中的結構。 m到及暫時濕增蓥劊 暫時濕增強劑可為陽離子、分離子或陰離子。此化合物包括 PAREZ M631 NC及PAREZ®725暫時濕增強劑樹脂，此為獲自cytecMa Secret Lion 00 丨 Tsuzaki Kappa Iron 22 200424399 Polysiloxane compound) Add this chemical additive. The chemical additive may be mixed with the polysiloxane compound of the present invention or used as a separation chemical additive. Heavy load control agents Charge promoters and control agents are generally used in papermaking to control the interface potential of the papermaking slurry at the wet end. These species may be anionic or cationic, most of which are usually cations ' and are either naturally occurring materials (such as alum) or low molecular weight europium charge density synthetic polymers with a molecular weight of generally about 50,000 or less. Drainage and retention can be added to the slurry to improve structure, drainage and excellent retention. Included retention and drainage aids are particulate subsystems containing high surface area, tritium anion charge density materials. Cardiac, G, and ripple agents can also be used in tissue and / or tissue products. As used herein, the term Hwet strength agents)-means a material used in a wet state between fixedly bonded pulp fibers. The general method is that the pulp fiber is fixed in the daily necessities, and this E bond is bonded, and the eaves are hydrogen bonded and coexisting, and / or E Yuezhong can provide a reinforcing agent that allows the pulp fiber to be connected in this way to fix the fiber. Between the _, _ 'postal state, the anti-splitting of the median age. In this case, thirsty ^ ^ when relying on fabrics and / or relying on a large amount of wealth or their wealth-soluble tissue paper. Two? = In terms of 'when adding any enhancer material to eight tissue paper fabrics and / or ratios: the strong agent is "Qing ,. π # ^ These materials are not called strong wet agents when they are used. In order to distinguish between durable wet Reinforcing agent and temporary wet strengthening agent, holding_Special Lion 0-21 23 200424399 Long-reinforcing agent pulp is defined as resin. When combined with tissue and / or tissue supplies, it will provide retention after being exposed to water for at least 5 minutes. More than 50% of the initial wet strength of tissue paper fabrics and domain tissue products. Temporarily _ increase _ 5 minutes of soaking to show about or less initial wet strength. The towel of the present invention is found to apply two-sided increase. According to the pulp fiber's Dry weight, the amount of wet reinforcing agent added to the pulp fiber is at least about (U dry weight%, more specifically about 0.2 dry weight% or more, and more specifically about 0.1 to 3 dry weight%. Persistent wet Reinforcing agent-will generally provide tissue fabric and / or tissue structure with more or less long-term wet elasticity. In contrast, temporary wet reinforcement-generally will provide tissue and / or miscellaneous structures with low mosquito and high elasticity. But did not provide the Treasurer The structure in the liquid. M to and temporarily wet increase 蓥 刽 temporary wet enhancer can be cation, separator or anion. This compound includes PAREZ M631 NC and PAREZ®725 temporary wet enhancer resin, which is obtained from cytec

Industries(新澤西州West Paterson)的陽離子二羥醋酸鹽聚丙稀醯胺。此及 相似禎f脂由Cosda等人於1971年1月19日頒布描述於美國專利編號第 3,556,932號，以及Willimis等人於1971年1月19日頒布描述於美國專利 編號第3,556,933號。Hercobond 1366(由Hercules有限公司製造，公司位 於德拉威州的維明頓)為另一商業上可利用的陽離子二羥醋酸鹽聚丙婦醯 胺，此可依照本發明使用。暫時濕增強劑的額外範例包括二乙醛淤漿(比如 出自National Starch及化學公司的Cobond®1000)及含有聚合物的其他乙醛 (比如Schroeder等人於2001年5月1日頒布描述的美國專利編號第 6,224,714號;Shannon等人於2001年8月14日頒布描述的美國專利編號第 6,274,667號;Schroeder等人於2001年9月11日頒布描述的美國專利編號 第6,287,418號;以及Shannon等人於2002年4月2曰頒布的美國專利編號Industries (West Paterson, NJ), a cationic diglycolate polyacrylamide. This and similar lipids were issued by Cosda et al. On January 19, 1971 and described in U.S. Patent No. 3,556,932, and Willimis et al. On January 19, 1971 and described in U.S. Patent No. 3,556,933. Hercobond 1366 (manufactured by Hercules Co., Ltd., Wilmington, Delaware) is another commercially available cationic diglycolate polypropylamidine, which can be used in accordance with the present invention. Additional examples of temporary wet enhancers include diacetaldehyde slurry (such as Cobond® 1000 from National Starch and Chemical Company) and other acetaldehyde containing polymers (such as those described by Schroeder et al., Issued on May 1, 2001 in the United States Patent No. 6,224,714; U.S. Patent No. 6,274,667, described by Shannon et al. On August 14, 2001; U.S. Patent No. 6,287,418, described by Schroeder et al. On September 11, 2001; and Shannon et al. U.S. Patent Number Issued April 2, 2002

Mavis-D:\專利 \Pk〇〇 1 ·08~\0890\ΡΚ-001 -〇890.doc2004/6/30 24 200424399 第6,365,667號，二者無對立而完全合併於此作為參考。） 本發明可使用包含陽離子齊聚物或聚合樹脂的持久濕增強劑。聚 酉&胺a -¾氧-鼠-丙類型樹脂(比如KYMENE 557H ’此售於位於德拉威州 維明頓的Hercules有限公司）大部分使用持久性濕增強劑，並可適合使用於 本發明中。此材料已描述於下面美國專利編號中：Keim於1972年10月 24日頒布的USP 3,700,623;Keim於1973年11月13日頒布的USP 3,772,076;Petr〇ViCh 等人於 1974 年 12 月 17 日頒布的 USP 3,855，158;Petrovich等人於 1975 年8 月 12 日頒布的USP3,899,388;Petrovich 等人於I978年12月I2曰頒布的USO 4，129,528; Petrovich等人於1979年 4月3日頒布的1^4，147,586;以及¥&11£61^111於1980年9月16日頒布的 USP4,222,921。其他陽離子樹脂包括聚次乙亞胺及氨基塑料樹脂，此獲自 甲醛與三聚氰醯胺或尿素反應。常常有助於在薄紙用品製造中使用持久及 暫時濕增強掏·月旨，此屬於本發明範圍内。 乾增強渐 乾增強劑也可運用於薄紙織物與/或者薄紙用品中，此不影響執行 本發明所紐的聚魏絲摘。使_域增_爾料為眾所週知的 技並包括(但不限足)改質㈣及其他多醣類(比如陽離予、兩性及陰離 ^ jc及古村义膠及角且膠）、改質聚丙婦齡、幾甲基、纖維素、糖、聚乙 ΓΓ纖铸。此乾增鋪—般在薄賴物軸或部分㈣包裝之前 。無論如何’有_於__本 成物混合，並將二個化學藥品同時運用於薄紙織物與/或者薄紙用品中Γ 有時有助赠财轉織魏化學藥·人軸織物與/或者 -001 -0890. doc2004/6/30Mavis-D: \ Patent \ Pk〇〇 1 · 08 ~ \ 0890 \ ΡΚ-001 -〇890.doc2004 / 6/30 24 200424399 No. 6,365,667, the two are completely incorporated herein by reference. ) The present invention makes it possible to use long-lasting wet reinforcements comprising cationic oligomers or polymeric resins. Polyammonium & amine a-¾-oxo-rat-C type resins (such as KYMENE 557H 'sold by Hercules Ltd. in Wilmington, Delaware) mostly use persistent wet enhancers and are suitable for use in this Invented. This material has been described in the following U.S. patent numbers: USP 3,700,623 issued by Keim on October 24, 1972; USP 3,772,076 issued by Keim on November 13, 1973; PetrOViCh et al. Issued on December 17, 1974 USP 3,855,158 issued by Petrovich et al. On August 12, 1975; USP 3,899,388 issued by August 12, 1975; USO 4,129,528 issued by Petrovich et al. On December 2 of I978; Petrovich et al. Issued April 3, 1979 1 ^ 4,147,586; and US $ 4,222,921 issued on September 16, 1980, and ¥ & 11 £ 61 ^ 111. Other cationic resins include polyethylenimine and aminoplast resins, which are obtained from the reaction of formaldehyde with melamine or urea. It is often helpful to use long-term and temporary wet-reinforcement in the manufacture of tissue products, which is within the scope of the present invention. Dry-reinforced and gradually-reinforced enhancers can also be used in tissue paper fabrics and / or tissue products, which does not affect the performance of the polysilicone extracts of the invention. Make _ domain increase_ Seoul materials are well-known techniques and include (but not limited to) modified pupae and other polysaccharides (such as Yang Liyu, bisexual and Yin Li ^ jc and Gucun Yijiao and Jiaojiejiao), modified Polypropylene age, polymethyl, cellulose, sugar, and polyethylene. This dry-addition shop-generally before the thin reel shaft or part of the package. Anyway, '有 _ 于 __ This product is mixed, and the two chemicals are used in tissue paper fabrics and / or tissue products at the same time. Γ Sometimes it helps to transfer money to weaving chemical medicines, woven fabrics, and / or- 001 -0890. Doc2004 / 6/30

Mavis-D:\^ljU»kOO 1,08->\0890\ρΚ. 25 200424399 薄紙用品中。此鬆解劑及軟化化學藥品的範例廣布於技藝中指示。示範化 合物包括具有一般式的簡單四級銨鹽，其中R1、(^6烷 基，R1為CM-C22烷基，b為1〜3整數，且χ_為任何適當抗衡離子。其他 相似化合物包括簡單四級銨鹽的單酯、二酯、單醯胺及二醯胺衍生物。已 知在四級鞍化合物上的一些變動，且屬於本發明的範圍内。額外軟化合成 物包括陽離子十八烯咪唑啉材料，比如曱基4·十八烯氨基乙基十八晞咪 唑啉硯酸甲酯，此商業上獲自Mackemium D(M83(出自McIntyre Ltd.， 位於UmversityPark，奶及朽⑽ftTQ]〇〇3(獲自H_les有限公司）。此軟 化劑也可結合稀_或可雜加鋪(比如低分子量的聚次乙基乙二醇，分 子里，、々4,000道爾頓或更少)或聚羥化合物(比如甘油或丙二醇）。儘管這些 軟化劑可續物形成之前運用於纖維，本發明的聚魏燒合成物-般顧 充分軟化及絲性改善’时不級賴外的賴軟化劑。 。^想+可用餐化學添加物細處理賴織物與/或者薄紙用 :。=匕學添加物包括(但不限定)吸收劑(通常繁助陽離子、陰離子或非離 的，活化劑形成)、稀釋劑及可塑性加強劑(比如低分子量的聚次乙基 乙二轉及聚經化合物(比如甘油及丙二醇)）。 不盎太 而"私明的聚魏㉖合成物可使用於與任何已知材料及 括时政f對立姆添加物連結。此材料及化學添加物的範例包 氧化劑等| ^ ^石、辅或其他氣味修·、環糊精化合物、 子染料、光學H鄭峨擇包括陽離 可包括熟知製紙及薄紙製进技: 又日的械織物與/或者薄紙用品 “技相各種其他廣泛材料及化學添加物，此可Mavis-D: \ ^ ljU »kOO 1,08- > \ 0890 \ ρΚ. 25 200424399 Tissue paper supplies. Examples of this releasing agent and softening chemicals are widely indicated in the art. Exemplary compounds include simple quaternary ammonium salts of the general formula, where R1, (^ 6 alkyl, R1 is CM-C22 alkyl, b is an integer from 1 to 3, and χ_ is any suitable counterion. Other similar compounds include Mono-, di-, mono-, and di-amidine derivatives of simple quaternary ammonium salts. Some variations on quaternary saddle compounds are known and fall within the scope of this invention. Additional softening compositions include cationic octadecyl Imidazoline materials, such as fluorenyl 4. octadecylaminoethyl stearyl imidazoline methyl acetate, are commercially available from Mackemium D (M83 (from McIntyre Ltd., located in Umversity Park, Milk and FTTQ). 〇3 (obtained from H_les Co., Ltd.). This softener can also be combined with dilute or heterogeneous (such as low molecular weight polyethylene glycol, molecular weight, 々 4,000 Daltons or less) or Polyhydroxy compounds (such as glycerol or propylene glycol). Although these softeners can be applied to fibers before the continuum is formed, the polyweier burning composition of the present invention-generally softens and improves silkiness-is not a common softener. ...... ^ Thinking + edible chemical additives For materials and / or tissues: == Additives include (but are not limited to) absorbents (usually cationic, anionic or non-ionic, activator formation), diluents, and plasticity enhancers (such as low molecular weight polymer Ethylene glycol and polyethylene compounds (such as glycerol and propylene glycol). The non-toxic " private polypyridine compound can be used to link with any known materials and additives such as current politics and anti-lime additives. Examples of this material and chemical additives include oxidants, etc. ^ ^ stone, auxiliary or other odor modifiers, cyclodextrin compounds, sub-dye, optical H Zheng E-selection including Yang Li may include well-known paper and tissue technology: Japan ’s textiles and / or tissue supplies “technical various other wide range of materials and chemical additives, this can be

Mavis-Dmm〇〇i 〇8，戰顧侧 d〇c2_3〇 26 200424399 包括提供肌膚健康益處的洗劑及其他材料。 此材料及辦添祕的應轉質《與本發明無關 ，且此材料及 化學製品在賴製造作财可運祕何特f。此包括作職財的紙製、 共同應關預先處理、在錄後於軌機_後處理以及局雜處理。 分析試轮方法 基重: 使用變更的TAPPI T410程序測定薄紙片樣本的基重及極乾燥基 重。基重樣本可限制於2yC±：rC及5〇±2%相對·下最少4小時。在 Ρ艮制後，將一堆3” X 3”樣本使用沖模壓製及結合沖模切割。此表示144平 万英吋的薄紙片樣本面積。適當沖模壓製的樣本為由紐約Islandia的 Testing Machines，lnc.製造之TMI DGD沖模壓製或麻薩諸塞州維明頓的 USM有限公司製造之Swing Beam試驗機械。沖模尺寸公差在二方向為土 0.008英吋。然後將樣品堆在分析天平上秤重至最接近〇 〇〇1克。然後使用 下面方程式計算基重(碎/2880平方英呎)： 基重=堆疊重量(克)/454*2880 從樣本罐秤重可獲得極乾燥的基重，且樣本罐蓋極接近〇·〇(η克 (此重量為Α)。樣本堆置放於樣本罐中，且剩下無蓋。對秤重低於1〇克的 樣本堆而言，無蓋樣本罐及堆疊連同樣本罐蓋置於105°C±2°C烘箱中1 小時±5分鐘，且對秤重10克或更高的樣本堆而言至少為8小時。在偏離 詳述烘箱時間後，可將樣本罐蓋置於樣本罐上，且將樣本罐從烘箱除去。 樣本罐允許冷卻至大約周圍溫度，但不超過10分鐘。然後將樣本罐、樣Mavis-Dmm〇〇i 〇8, War Gu side 〇doc2_3〇 26 200424399 Including lotions and other materials to provide skin health benefits. This material and its application should be converted to "Unrelated to the present invention, and this material and chemical products can be transported by making money." This includes paperwork for work, pre-processing of common applications, post-recording on track machines, post-processing, and miscellaneous processing. Analytical test wheel method Basis weight: The basis weight and extremely dry basis weight of tissue paper samples were determined using the modified TAPPI T410 program. Basis weight samples can be limited to 2yC ±: rC and 50 ± 2% relative · down for at least 4 hours. After being manufactured, a pile of 3 "X 3" samples were pressed with a die and cut in combination with a die. This represents a sample area of 144 square inches of thin paper. Samples of suitable die pressing are TMI DGD die pressing manufactured by Testing Machines, Inc. of Islandia, New York or Swing Beam test machinery manufactured by USM Co., Ltd. of Wilmington, Mass. The die size tolerance is 0.008 inches in both directions. The sample stack was then weighed on an analytical balance to the nearest 0.001 g. Then use the following equation to calculate the basis weight (fragment / 2880 square feet): Basis weight = stacked weight (g) / 454 * 2880 Weighing from the sample tank can get a very dry basis weight, and the sample tank lid is very close to 〇 · 〇 (ηg (this weight is A). The sample stack is placed in the sample tank with no cover left. For sample stacks weighing less than 10 grams, the coverless sample tank and stack with the sample tank cover are placed in 105 ° C ± 2 ° C in an oven for 1 hour ± 5 minutes, and at least 8 hours for a sample stack weighing 10 grams or more. After deviating from the detailed oven time, the sample can lid can be placed in the sample can And remove the sample container from the oven. The sample container is allowed to cool to about ambient temperature, but not more than 10 minutes. Then the sample container, sample

MaviS-D:\專f咖〇1 Ό8〜\_\ρκ韻嶋也義彻。27 200424399 本罐蓋及樣本堆秤重至最接近〇·〇〇1克(此重量為c)。使用下面方程式計算 及乾燥的基重(镑/2880平方英呎)： 極乾燥基重=(C-A)/454*2880 直徑： 此處所使用“直徑’’（caliper)—詞意謂單薄紙織物的厚度，並不 是可依單薄紙織物厚度測量就是依10張薄紙織物堆的厚度並將1〇張薄紙 織物厚度除以10來測量，此處堆疊内的每張薄紙織物製放相同面朝上。 直徑以微絲示。直雛照TAPPI試驗方法T4()2 “罐、厚紙板、紙裝 手巾及相關用品的標準調節及試驗環境，，（standard conditiQning and Testing Atmosphere For Paper, Board, Pulp Handsheets and Related Products) 及TWl·89 “紙張、紙板及結合板的厚度(直徑)，，卿如挪㈣㈣ Paper，Paperboard，and combined Board)任意測量紀錄3的堆疊薄紙片。使 用於元成T411 om-89的測微計為Bulk Micrometer (TMI型號49-72-00，紐 約的Amityville)或具有4又1/16英吋(1〇3·2毫米)的砧徑及22〇克/平方英 吋(3.3克千巴斯卡)的砧壓。 教燥張力（薄蚯)·· 幾何平均張力(GMT)強度試驗結果以克-力/3英吋樣本寬度表 PGMT由MD(機械方向)及CD(交又機械方向)張力曲線的最高載荷值估 计此在23.0 C±l.〇°C、50·0±2·0%相對溼度的實驗用狀況下獲得，且在 薄紙織物平衡至試驗狀況不超過4小時期間後。在維持一定延伸速率的張 力4驗機械上處理試驗，且每個試驗樣品的寬度為3英吋。鉗口之間的‘‘鉗 口全長（jaw span)或距離(有時稱為間距長度)為2 〇英吋(5〇·8毫米)。聯桿MaviS-D: \ 专 f 咖啡 〇1 Ό8 ~ \ _ \ ρκ 韵 嶋 is also righteous. 27 200424399 This tank lid and sample stack weighed to the nearest 0.001 g (this weight is c). Calculate and dry the basis weight (pounds / 2880 square feet) using the following equation: Extremely dry basis weight = (CA) / 454 * 2880 Diameter: As used herein, "caliper" —the word means a single tissue The thickness can be measured either by the thickness of a single tissue, or by the thickness of a stack of 10 tissues and dividing the thickness of 10 tissues by 10. Here, each tissue in the stack is placed with the same side facing up. Diameters are shown in microwires. Straight chick photos TAPPI test method T4 () 2 "Standard conditiQning and Testing Atmosphere For Paper, Board, Pulp Handsheets and Related Products) and TWl · 89 "Thickness (diameter) of paper, paperboard, and bonded boards, such as paper, paperboard, and combined board). Randomly measure the stack of thin paper sheets of record 3. Used in Yuancheng T411 om-89 The micrometer is a Bulk Micrometer (TMI model 49-72-00, Amityville, New York) or has an anvil diameter of 4 1/16 inches (10.3.2 mm) and 22 g / square inch (3.3克 千 巴卡卡) anvil pressure. Tension (thickness). The geometric mean tension (GMT) strength test results are based on the gram-force / 3 inch sample width table. PGMT is estimated from the highest load values of the MD (mechanical direction) and CD (crossing and mechanical direction) tension curves. Obtained under the experimental conditions of 23.0 C ± 1.0 ° C and 50 · 0 ± 2 · 0% relative humidity, and after the tissue is equilibrated to the test condition for a period of not more than 4 hours. The tension is maintained at a certain elongation rate 4 The test is mechanically processed and the width of each test sample is 3 inches. The "jaw span" or distance (sometimes called the pitch length) between the jaws is 20 inches (50 inches). 8 mm). Link

Mavis-D:\WJ\Pk001.08~\0890\PK-001-0890.doc2004/6/30 28 200424399 器速度為10英付/分鐘(254亳米/分鐘）。挑選負荷感應器(l0ad cell)或滿負 荷(foll-scaleload)，因此所有最高載荷結果在1〇及9〇%的滿負荷之間。尤 其，在Instron II22張力機連接至Sintech數據獲得而產生描述於此的結 果，且控制系統利用MAP軟體在“概型，，個人電腦上執行。此數據系統 紀錄至少每秒有2G鋪荷及延雜。以使用作為紀錄張力制樣本平均 值試驗每個樣本的全部10個樣品。由下面方程式計算幾何平均張力： GMT=(MD 張力 *CD 張力)1/2 為了說明基重的小變動，然後使用下面方程式將GMT值校正成ΐ8·5磅 /2880平方英叹的指標基重。 校正GMT==測量的GMT*(18.5/極乾燥的基重） 、 、“浸濕時間”㈣⑽time)為關於吸收力，且為將給予樣本置放 I水中而元全浸濕的時間。更明確的是，浸濕時間由將如片薄紙織物與/ 或者薄紙用品域2·5射正方形來測定。使祕試驗的片數不依每片薄 輯_/或者薄紙用品的層數而定。將2〇張正方形片堆疊在一起，並在 母角裝訂，以形成-她。鱗可固定緊#_定溫度蒸麻浴(23土 p面，此為適當大小及深度，以確保_樣品不同時接觸容器底部及水 1面上端1後襯麵平滴至水表面，主要點向下。鱗變得完全浸濕的 、、門(以L)為薄紙織物與/或者薄紙用品樣本的浸濕時間，並表示薄紙 滅物與/或者薄_品的吸收速率。增加麵時間表示減少吸收速率。 吣也轉_0108，着K__9〇d〇娜靡 29Mavis-D: \ WJ \ Pk001.08 ~ \ 0890 \ PK-001-0890.doc2004 / 6/30 28 200424399 The speed of the machine is 10 pay / minute (254 亳 m / minute). Select a load cell (10ad cell) or a full-scale load (foll-scaleload), so all maximum load results are between 10 and 90% of full load. In particular, the results described here were obtained when the Instron II22 tensioner was connected to Sintech data, and the control system was executed on a "profile, personal computer using MAP software. This data system records at least 2G load and delay per second. Test all 10 samples of each sample using the average value of the sample as the record tension system. Calculate the geometric average tension from the following equation: GMT = (MD tension * CD tension) 1/2 To illustrate small changes in basis weight, then Use the following equation to correct the GMT value to an index basis weight of ΐ8.5 lbs / 2880 square sighs. Corrected GMT == Measured GMT * (18.5 / Extremely dry basis weight),, “wet time” ㈣⑽time) are about Absorptive power, and the time of total soaking for placing a given sample in I water. More specifically, the soaking time is measured by shooting a square of tissue paper and / or tissue paper supplies 2.5 squares. The number of pieces to be tested does not depend on the number of sheets of thin paper and / or tissue paper supplies. 20 square pieces are stacked together and bound at the female corner to form -her. Hemp bath (23 soil p surface, this Appropriate size and depth to ensure that the sample does not contact the bottom of the container and the surface of the water at the same time. The backing surface drips flatly to the surface of the water, the main point is downwards. The door (with L) is completely wetted with scales. Wetting time of fabric and / or tissue paper samples, and indicates the absorption rate of tissue paper and / or tissue. Increasing the surface time indicates decreasing the absorption rate. 吣 also turn to _0108, writing K__90 〇 was over 29

Hercu丨es尺兮辞放 “Hercules ·尺寸試驗”（HST)為一般測量花費多久使液體移經薄 紙片的試驗。Hercules尺寸試驗-般依照ΤΑρρι方法τ 53〇 pM_89(具有油 墨抵抗力的紙張尺寸试驗)元成。Hercuies尺寸試驗使用製造者提供的白色 及綠色杈準拼塊地毯及黑盤集中於M〇del HST^<驗器上。以蒸餾水將2% 的Napthol Green N染料稀釋成1%使用作為染料。所有材料獲自德拉威州 維明頓的 Hercules，Inc.。 在試驗之前，將所有樣品至少在23土1Τ及5〇±2%相對溼度中 調節4小時。試驗對染料溶液溫度敏感，因此染料溶液在試驗之前也平衡 至控制調節溫度最少4小時。 為試驗挑選6張博紙片(對三層薄紙用品為ls層）。將樣品切成 2.5 X2·5英忖的適g尺寸。儀器為符合每位製造商方向的白色及綠色校準 拼塊地毯。樣品(對二層薄紙用品為u層)置放於層的外侧表面朝外之樣本 支持器中。然後樣品固定至樣本支持器。然後樣品支持器置於光學罩上端 上的扣環。使用黑盤測定儀器。除去黑盤，並將1G±a5公撮的染料溶液 分运至扣壤，且將黑盤置於樣品上方時，馬錶開始。自儀器紀錄試驗時間 (秒）。 _|_動重量分析的吸收詖腌ί APAT> 自動重量分析吸收試驗器，，（Aut_tic Gravi_rie Tester，AGAT)-般為測量薄紙片的最初吸收力。裝置及試驗為眾所週知的 技藝，並描述於美國專利編號第4,357,827號，其合併於此作為參考。在 下面範例中，六個薄紙片(每片為三層，共有18層)一起試驗。在試驗期間， 將樣本置放於試驗室，此與水槽容器聯繫。然後將_開，因此液體自由 自容器流賴驗t。漸縣吸收水槽㈣驗體。測以嫌樣品吸收"Hercules Dimensional Test" (HST) is a test for how long it takes a general measurement to move a liquid through a thin piece of paper. Hercules size test-generally in accordance with TAFA method τ 53 pM_89 (paper size test with ink resistance). The Hercuies size test uses white and green quasi-block carpets and black plates provided by the manufacturer to focus on the Model HST ^ < tester. 2% of Napthol Green N dye was diluted to 1% with distilled water and used as dye. All materials were obtained from Hercules, Inc., Wilmington, Delaware. Prior to testing, all samples were conditioned for at least 4 hours at 23 ° 1T and 50 ± 2% relative humidity. The test is sensitive to the temperature of the dye solution, so the dye solution is also equilibrated to a controlled conditioning temperature for a minimum of 4 hours before the test. Select 6 pieces of Bo paper for the test (1s layer for three-layer tissue paper supplies). The sample was cut into a suitable size of 2.5 x 2.5 inches. The instrument is calibrated in white and green to match the direction of each manufacturer. The sample (u-layer for two-layer tissue paper supplies) was placed in a sample holder with the outside surface of the layer facing outward. The sample is then fixed to the sample holder. The sample holder is then placed on the retaining ring on the upper end of the optical cover. Use a black plate measuring instrument. The black disk was removed, and a 1 G ± a5 meter of dye solution was dispensed to the buckle soil, and when the black disk was placed over the sample, the horse watch began. Record the test time (seconds) from the instrument. _ | _ Absorption 动 picking by dynamic gravimetric analysis APAT > Automatic Gravimetric Absorption Tester, (Aut_tic Gravi_rie Tester, AGAT)-generally measures the initial absorption of tissue paper. The device and test are well known techniques and are described in U.S. Patent No. 4,357,827, which is incorporated herein by reference. In the example below, six pieces of tissue paper (three layers each with 18 layers in total) were tested together. During the test, the samples are placed in the test chamber, which is connected to the sink container. Then _ will be opened, so the liquid will flow freely from the container. Jianxian County absorbs sinks for examination. Suspected sample absorption

Mavis DAltfIJ\Pk〇〇 ι .〇8->\〇89〇\ΡΚ-〇〇ι -0890.doc2004/6/30 3 Q 2004243 99 的液體數ι 一段時間。一般AGAT機械從2 ·25秒至如理想長般產生一吸收 曲線。由測量2.25與6·25秒之間的平均坡度得知AGAT結果。每個樣本 上有ίο個複製，且10個複製的平均值使用樣本AGAT值。 聚二烷基矽氡 使用下面程序測定纖維素纖維基質上的聚二燒基咬氧燒含量。將 含有聚二燒基石夕氧烷的樣本置於頂層空間取樣瓶中，加入三氟化硼試劑， 並將取樣瓶密封。在約10〇Τ中約反應15分鐘後，在頂層空間取樣瓶中 的二氟二甲基矽氧烷以具有FID偵查器的氣體層析法測量。 3Me2Si0+2BF30(C2H5)2 — 3Me2SiF2+B203+2(C2H5)20 使用具有FID的Hewlett-Packard型號5890氣體層析計及 hewlett-Packard7964自動注射器來發展描述於此的方法。可用相等氣體層 析法系統替代。 儀咨可由Perkin-Elmer Nelson Turbochrom軟體(第4.1版)控制及 收集數據。可用相等軟體程式替代。使用具有薄膜厚度〇·25 # m(目錄編號 115-3432)的J&W科學GSQ(30公尺X0.53毫米i.d·)圓柱。可替換相等圓 柱。 氣體層析計裝備有Hewlett-Packard頂樣空間取樣自動注射器 (headspace autosampler)、HP-7964，並設置下面狀況：Mavis DAltfIJ \ Pk〇〇ι .〇8- > \ 〇89〇 \ ΡΚ-〇〇-0890.doc2004 / 6/30 3 Q 2004243 99 for a period of time. Generally, the AGAT machine produces an absorption curve from 2.25 seconds to as long as desired. The AGAT results were obtained by measuring the average slope between 2.25 and 6.25 seconds. There are 复制 copies on each sample, and the average of 10 copies uses the sample AGAT value. Polydialkylsilicones Use the following procedure to determine the polydialkylene content on the cellulose fiber matrix. Place the sample containing polydioxanyloxane in a headspace sampling bottle, add boron trifluoride reagent, and seal the sampling bottle. After about 15 minutes of reaction in about 100T, the difluorodimethylsiloxane in the headspace sampling bottle was measured by gas chromatography with a FID detector. 3Me2Si0 + 2BF30 (C2H5) 2 — 3Me2SiF2 + B203 + 2 (C2H5) 20 The Hewlett-Packard Model 5890 gas chromatograph with FID and the hewlett-Packard7964 autoinjector were used to develop the method described here. Can be replaced by an equivalent gas chromatography system. The instrument can be controlled and collected by Perkin-Elmer Nelson Turbochrom software (version 4.1). Can be replaced by equivalent software programs. A J & W Scientific GSQ (30 m X 0.53 mm i.d.) cylinder having a film thickness of 0.25 #m (catalog number 115-3432) was used. Replaces equal cylinders. The gas chromatograph was equipped with a Hewlett-Packard headspace autosampler, HP-7964, and set the following conditions:

浴溫(Bath Temperature): 100T 環溫(Loop Temperature): 100〇C 轉移線溫度·· 120°C GC循環時間：25分鐘 破璃瓶平衡時間：15分鐘 壓力時間：0.2分鐘 -001-0890.doc2004/6/30Bath Temperature: 100T Loop Temperature: 100 ° C Transfer line temperature · 120 ° C GC cycle time: 25 minutes Glass bottle equilibrium time: 15 minutes Pressure time: 0.2 minutes-001-0890. doc2004 / 6/30

Mavis-D:\專称 pk001 ·〇8〜\〇890\ΡΚ- 31 200424399 環裝填時間·· 〇·2分鐘 環平衡時間：0.05分鐘 注入時間：L0分鐘 破璃衡1(低） 氣體層析計設定下面儀器狀況： 载氣：氦Mavis-D: \ Specially named pk001 · 〇8 ~ \ 〇890 \ ΡΚ- 31 200424399 Ring filling time ·· 2 minutes Ring equilibration time: 0.05 minutes Injection time: L0 minutes Breaking glass scale 1 (low) Gas chromatography Set the following instrument conditions: Carrier gas: Helium

>見速：16.0公撮經過圓柱，且在偵查器中有14公撮補充 注射器溫度：150°C 偵查器溫度：220°C 層析法狀況·> Seeing speed: 16.0mm passing through the cylinder, and 14mm replenishment in the detector Syringe temperature: 150 ° C Detector temperature: 220 ° C Status of chromatography ·

50°C以10°C/分鐘而在4分鐘衝到i5〇°C 維持於末溫5分鐘 維持時間：對DFDMS為7.0分鐘 備用液的製備 方法為使用DC-200流體(獲自密西根州中部地區的D〇w c〇ming) 杈準成純PDMS。以下面核準備含有約125()〃g/公撮％•勘流體的備 用液。將約0.3125克的DC_200流體秤重至最接近〇1毫克放入25〇公撮 私貝的Ί瓶、、、己錄賁際重量(以X表示）。力口入適當溶劑(比如曱醇、服 或氯仿）’並織赠轉，以分解/分散流體。當分麟，溶液稀釋成具有 溶劑的容量，並齡。聚1基魏_解(以γ表示)由下面方程辆 算··50 ° C at 10 ° C / min and 4 minutes to i50 ° C. Maintained at the final temperature for 5 minutes. Maintenance time: 7.0 minutes for DFDMS. The preparation method of the backup solution was to use DC-200 fluid (obtained from Michigan). Dowcoming) in the central region becomes a pure PDMS. Prepare a stock solution containing approximately 125 (g) / g% of the test fluid below the core. Approximately 0.3125 grams of DC-200 fluid was weighed to the nearest 0.001 mg and placed in a 250-milliliter bottle, and the weight of the recorded medium (expressed as X). Inject a suitable solvent (such as methanol, clothing or chloroform) ’and weave it to dissolve / disperse the fluid. When divided, the solution was diluted to have a solvent capacity and aged. The poly 1 solution (represented by γ) is calculated by the following equation ...

Mavis-D:\專早IJ\Pk001.08〜\0890\PK-001-0890.(i〇c2004/6/30 32 200424399 聚二甲基矽氧烷的ΡΡΜ(Υ)=Χ/0·250 刻度標準的製備 刻度標準為將0(空白）、50、100、250及500//L的備用液(容積 以// L· Vc紀錄)加入連續20公撮頂層空間取樣瓶(含有〇· 1 ±〇·〇〇1克的未處 理控制薄紙織物或薄紙用品)而產生括號的指標濃度。溶劑藉由將頂層空間 取樣瓶置放於溫度範圍約為60°C〜70°C之間15分鐘的烘箱中來蒸發。每 個刻度標準的聚二甲基矽氧垸(以Z表示)之//g由下面方程式計算： Z=VC*Y/1000 分析程序 然後根據下面程序分析刻度標準：將O.lOOiO.OOi克的薄紙樣本 秤重至最接近0.1毫克放入20公撮的頂層空間取樣瓶。以亳克紀綠樣本重 量(以ws表示）。標椁及樣本之薄紙織物與/或者薄紙用品的數量必須相同。 100/zL的BF3試劑加入每個樣本及刻度標準。加入Β]ρ3試劑後立 即密封每個取樣瓶。 密封取樣瓶置放於頂層空間取樣自動注射器，並使用事先描述的 狀況分析，從每個薄紙樣本級標準注射丨公撮的頂層空間氣體。 準備//g聚二曱基矽氧烷vs.分析最高點面積的刻度曲線。 然後將薄紙樣本的分析最高點面積與刻度曲線比較，並測定在薄 、氏、哉物與/或者薄紙用品上的聚二甲基石夕氧燒(以⑷表示)數量(“ g)。 使用下面核纽計聚二？切|^數量(以(c)表示)在薄紙樣Mavis-D: \ Special Morning IJ \ Pk001.08 ~ \ 0890 \ PK-001-0890. (Iocc2004 / 6/30 32 200424399 PPDM (Υ) of polydimethylsiloxane = X / 0 · 250 Preparation of the calibration standard The calibration standard is to add 0 (blank), 50, 100, 250, and 500 / L of stock solution (the volume is recorded as // L · Vc) to a continuous 20-millimeter top-space sampling bottle (containing 0.1 ± 〇〇〇〇1 grams of untreated control tissue paper or tissue products) to produce the index concentration of brackets. Solvent by placing the top space sampling bottle between the temperature range of about 60 ° C ~ 70 ° C for 15 minutes Evaporate in the oven. The polydimethylsiloxane (represented by Z) at each calibration standard // g is calculated by the following equation: Z = VC * Y / 1000 The analysis program then analyzes the calibration standard according to the following program: O.lOOiO.OOi grams of tissue paper samples are weighed to the nearest 0.1 mg and placed in a 20-millimeter top-space sampling bottle. Sample weight in grams of green (expressed as ws). Tissue and / or tissue paper on the label and sample The quantity of supplies must be the same. 100 / zL BF3 reagent is added to each sample and calibration standard. Each sampling bottle is sealed immediately after adding B] ρ3 reagent. The sampling bottle is placed in the top space sampling autoinjector, and the pre-determined condition analysis is used to inject a standard amount of top space gas from each tissue sample level. Prepare // g polydioxosiloxane vs. highest analysis The scale curve of the spot area. Then compare the analysis of the highest spot area of the tissue paper sample with the scale curve, and determine the amount of polydimethyl sulfide burned (expressed as thorium) on the tissue of thin, thick, thin, and / or thin paper. ("G). Use the following cores to calculate the dichotomous? Cut | ^ Quantity (indicated by (c)) on a thin paper pattern

Mavis-D:\專称Pk001 ·08〜\0890\ΡΚ-001 -0890.doc2004/6/30 33 本上的重量百分比: (cHa)/(ws1i〇4) 本上的重咖抑二彻氧_(以(D)絲)在薄紙樣 (D)气 C)/100 當存铜於聚二甲基的聚二垸基嫩時 基魏垸產生刻度標準，每個聚二燒基繼的數量= ===喊。軸账絲物_嫩使用於= 織物與/或者雜用品巾細氧垸之紐量。 氏 知覺柔教度 以便提供評做娜__。麵度 == =量’且假使薄紙織物與/或者薄_的差別為人射自行察知，則 以下為小組參與者利用的特定柔軟度程序，同時估計衛生紙 紙及紙巾與/或者用品的知警、° ^上置放_# 1 _w贼姉嶋以代碼面 向上置就跨非^。然後主要手㈣拇指、食指及巾指 料行中移動。許料紙__«制柯Π 柔滑、、、糸狀及起毛觸感。相 才门万式汗估樣本二側。然後每個附加樣本重Mavis-D: \ Specially named Pk001 08 ~ \ 0890 \ ΡΚ-001 -0890.doc2004 / 6/30 33 Percent by weight of the book: (cHa) / (ws1i〇4) Diceoxy _ (With (D) silk) in tissue paper pattern (D) gas C) / 100 When copper is stored in polydimethylpolydimethyene, the time base Weizhi produces a scale standard, and the number of each polydimer = === shout. Axle wire material _ tender use = the amount of fabric and / or miscellaneous goods towels. Degree of perceptual softness in order to provide a review to do __. Face === amount 'and if the difference between tissue paper and / or thin is self-detected, the following is the specific softness procedure used by the group participants, and the police of toilet paper and tissues and / or supplies are also estimated. 、 ° ^ 上 放 放 _ # 1 _wThe thief slaps the non- ^ with the code facing up. Then move the thumb, forefinger and towel finger in the main hand. Xu material paper __ «Manufacture Ke Π Silky, silky, silky, and fluffy feel. The two sides of the sample Caimen Wanshi sweat estimation sample. Then each additional sample weighs

Mavis-DA專利仰〇〇丨〇8〜v 34 1 〇890\PK-001 -0890. doc2004/6/30 200424399 複程序。然後化驗者將樣本從最少至最大柔軟排列。 使用 Ranks 的 Freidman Two-Way Analysis 〇f Variance (an〇va) 分析知覺柔軟度數據結果。此分析為使用於排列數據的非母數統計檢定方 法(iion-parametric test)。目的為測定不同實驗用處理方式之間是否有差異。 假使不Μ實驗用處理方式之間無順序差異，_—處理方式的中央感應統 計上並不與其他處理方式的巾央感應有差異，或可由齡引起任何差異。 知覺柔軟度坪疋由10至12位小組參與者運用無複製的次序統計 方法範例。對每個個別特性而言，產生大約24至72個數據點。曾經制 六個數據的最高點。假使在多數研究中比較代碼，可由錄研討使用控制 代碼評定更多代碼，以提供共同參考文。 當理想獲得柔軟度的整合性評估或測定樣本差異為人可察覺 時，可運用知覺紐度。此翼片逐_練，以提供更接近消#者所提供的 冲估知克柔权度有益於獲得作為不論樣本改變為人可發覺與/還是影響柔 軟度感受。數據可以順序格式存在。因此，隨樣本順序依照樣本順序而定， 數據可使用於研究範圍内的相對比較。 範例 對範例1及範例2而言，使用具有完成基重23.0碎/〇平方英 ㈣4起、__品及由65%硬木與35%軟木紙漿纖輯組成的給裝。 每層(薄紙織物)由包括二外層及一中間層的成層紙聚纖維給漿製造。藉同 日輪移輪轉凹版照像印刷術印刷作用，將聚魏垸合成物印在三層薄紙用 口口的一外侧上。二’氧垸合成物處财式傳送作為含有大約黑補固 把的Jcf生U ’知、相凹版輥為電子雕刻絡合金在銅輥上方，此由位於肯塔 土 9丨各易，、斤、准爾的S〇uthem Graphics供應。照相凹版輥具有36〇室/英付的 線條網及每她細版财u十億立方财(職v平方射體積的表Mavis-DA patents 〇〇 丨 〇8 ～ v 34 1 〇890 \ PK-001 -0890. Doc2004 / 6/30 200424399. The analyst then arranges the samples from minimal to maximum softness. Freidman Two-Way Analysis 〇f Variance (an〇va) of Ranks was used to analyze the results of perceptual softness data. This analysis is a non-maternal statistical test method (iion-parametric test) used to rank data. The purpose is to determine whether there are differences between different experimental treatments. Assuming that there is no order difference between the treatment methods used in the experiment, the central induction of the treatment method is not statistically different from the central induction of other treatment methods, or any difference can be caused by age. The perceptual softness scale consists of 10 to 12 group participants using a copy-free sequence statistics method example. For each individual characteristic, approximately 24 to 72 data points are generated. The highest point of the six data was made. If the code is compared in most studies, more code can be assessed by the controlled study using the control code to provide a common reference. Perceived softness can be used when it is desirable to obtain an integrated assessment of softness or to measure differences in the sample. This wing is practiced one by one to provide a closer estimation of the flexibility provided by the consumer. It is beneficial to obtain the flexibility as a sample regardless of the sample change and / or affect the softness feeling. Data can exist in a sequential format. Therefore, as the sample order follows the sample order, the data can be used for relative comparisons within the scope of the study. Example For Example 1 and Example 2, use a package with a finished basis weight of 23.0 pieces per square inch, __products, and 65% hardwood and 35% softwood pulp fibers. Each layer (tissue paper fabric) is made of layered paper polyfiber pulp including two outer layers and an intermediate layer. By the same day-to-day revolving gravure photo printing method, the poly-Weiying composite was printed on one outer side of the mouth of the three-layer thin paper. The second type of oxygen-containing compound is conveyed as a Jcf product, which contains approximately black patches. The gravure roll is an electronic engraving alloy on a copper roll, which is located in Kentatu 9 丨Supplied by Southem Graphics. The gravure roll has a line of 36 / room and a British pay line net and one billion cubic meters of fine-grained assets

Mavis-D:\WWk001.08^\0890\PK-00I-0890.doc2004/6/30 35 200424399 面。一般照相凹版輥的室大小為35微米長、110微米寬及13微米深。橡 膠精偏移給液輥為75Sh⑽A硬度測定闕型聚胺基甲酸酯，此由位於 威斯康辛州Union grove的American Roller Company供應。作用設定於在 '、、、相凹版滾及橡膠逆行偏移給液輥之間具有約Μ?5彡叶干擾的狀況及貼 (卞橡膠逆仃偏移給液輥之間約有議3英对的距離。同時偏移/偏移照相凹 版印刷契約在2000英呎/分鐘速度下運轉。 一範例1 範例1為&制樣本，並說明傳統科技。依照如上所探討的製造 作用。DC2議2(商業上可利用的氨基官能聚石夕氧燒，此獲自密西根州中 部地區的DGW 運祕薄_物(《據上面賴製造作用製 k)、DC-81Sm為氨基貫能聚石夕氧燒及聚乙酸聚石夕氧燒的混合物。在塗 佈尤用後H躺轉受成_%成的3層面紙用品。改變的薄紙用品具有 約 780 g/3”的 GMT。 範例2 薄紙織物«上騎探討隨造作賴造，聽使祕範例ι有 相同的薄紙織物。薄紙織物依照如上所探討的照相凹版印刷作用而塗有 DC2-U49，此為„上可_聚錢_彳(_西根州巾部地區的 D〇W Co—。薄紙織轉變成—完成的3層面紙，如範例！。轉變的薄 紙用品具有約813克/3”的GMT。 然後範例1及範例2的改變薄紙用品分析聚二垸基石夕氧燒含量、 吸收力特徵及知覺驗度性能。結果如表ι所示。 表1Mavis-D: \ WWk001.08 ^ \ 0890 \ PK-00I-0890.doc2004 / 6/30 35 200424399. Typical gravure roll chambers are 35 microns long, 110 microns wide, and 13 microns deep. The offset rubber feed roller was a 75Sh ⑽A hardness test 阙 type polyurethane, which was supplied by the American Roller Company in Union grove, Wisconsin. The action is set in the condition of the interference between the gravure roll and the rubber retrograde offset feeding roller with about 5 to 5 blades and the sticking (about 3 inches between the rubber retrograde offset feeding roller). The right distance. Simultaneous offset / offset gravure printing contract runs at a speed of 2000 feet per minute. Example 1 Example 1 is a sample of & making and explaining traditional technology. According to the manufacturing effect as discussed above. DC2 Negotiation 2 (Commercially available amino-functional polysilicon oxy-combustion, this is obtained from DGW Transportation Materials in Central Michigan ("according to the above manufacturing process"), DC-81Sm is an amino perforated polymer A mixture of oxo-fired and polyacetic acid-polyester oxo-fired. After being applied, the H-lay is converted into a 3-layer paper product. The changed tissue paper product has a GMT of about 780 g / 3 ". Example 2 Tissue paper fabric «Study on the ride and make it depend on the making, listen to the secret example I have the same tissue paper fabric. The tissue paper fabric is coated with DC2-U49 according to the gravure printing effect discussed above. This is" 上 可 _ 聚 钱 _ 彳 " (_DoW Co—of Nishiken region. Tissue weave is transformed into—a finished 3-layer paper, such as Example ... The converted tissue product has a GMT of about 813 g / 3 ". Then the tissue products of Example 1 and Example 2 were analyzed to analyze the content of polydioxonite, oxygen absorption, and perceptual test performance. The results are shown in Table ι Shown in Table 1.

Mavis-D:\專獅001蘭89幫糊咖—ο。· 36 200424399 範例 聚二烷基 矽氧烷含 量(如聚二 甲基矽氧 燒)的全部 乾燥片之 重量百分 比 最初 HST(秒) 最初 AGAT( 克/克/ 秒， 4星期熟 化的 HST@25 0C(秒） 4星期熟 化的 HST@25 〇c(克/克/ 秒 1/2) 2星期熟 化的 HST@40 °C(秒） 2星期熟 化的 HST@40° C(克/克/ 秒 1/2) 1控制 0.65 4 1.5 11 0.2 17 0.1 2發明 0.71 3 1.7 4 1.2 8 0.7 數據清楚顯示關於AGAT流體吸入的穩定性之發明用品優點。最 初HST健高，此顯示良好兼具流體吸人、滲膠及熱穩定。知覺柔軟度結 果顯示二代碼為相等柔軟度。在25〇c下熟化9星期之後，發明薄紙用品 的浸濕時間為19·3秒，_控制薄紙用品具有遍秒的浸濕時間。 _ &明的&些及其他變更與變動可由-般精通技絲實施，此無須 現反本發⑽^神及關’而尤其發表於附加中請專利範圍中。另外，需 ==種硕實施㈣H树全料冑分缝。骑，這些一般精通 技藝將明白前文敘述僅經由範例完成，且無«蚊發明，以進-步描 述於此附加申請專利範圍中。Mavis-D: \ Special lion 001 orchid 89 gang dung coffee — ο. · 36 200424399 Exemplary polydialkylsiloxane content (such as polydimethylsiloxane) Weight percentage of all dry tablets Initial HST (seconds) Initial AGAT (g / g / second, HST aged 4 weeks @ 25 0C (second) HST matured in 4 weeks @ 25 〇c (g / g / second 1/2) HST matured in 2 weeks @ 40 ° C (seconds) HST matured in 2 weeks @ 40 ° C (g / g / seconds) 1/2) 1 Control 0.65 4 1.5 11 0.2 17 0.1 2 Invention 0.71 3 1.7 4 1.2 8 0.7 The data clearly shows the advantages of the invention article regarding the stability of AGAT fluid inhalation. Initially, HST is high, which shows that it has good fluid absorption. , Glue penetration and thermal stability. Perceptual softness results show that the two codes are equal in softness. After 9 weeks of aging at 25 ° C, the wetting time of the tissue paper products was 19.3 seconds. Soaking time. _ &Amp; Ming & some and other changes and changes can be implemented by the general mastery of technology, this need not be reflected in the present invention ^ Shen and Guan 'and especially published in the scope of patents attached. In addition, Need == Seed Master to implement ㈣H tree full material 胄 seam. Riding, these general proficient skills will understand the foregoing Via said sample only completed, and no «mosquito invention to progress - further described herein additional patent scope.

Mavis-D_\專利\Pk001.08~\0890\PK-001-0890.d〇c2004/6/30 37Mavis-D_ \ Patents \ Pk001.08 ~ \ 0890 \ PK-001-0890.d〇c2004 / 6/30 37

Claims (1)

200424399 拾、申請專利範圍： —種以聚魏燒合成物處獨薄紙用品，在薄纟㈣品於2沉下熟化 Μ天之後，薄紙用品具有至少〇射/〇的乾燥薄紙之聚二燒基^燒 含量及具有0.8克/躺严錢大的AGAT值，且在沉下熟化μ 天或更多天之後，具有3秒或更大的j^ST。 2. 如申請專利範圍第丨項的薄紙用品，其中在薄_品於卿下熟化 14天或更多天之後，薄紙用品具有〇·5克/克/秒1/2或更大的A·， 以及4或更大的HST值。 3. 如申請專利範圍第i項的薄紙用品，其具有15秒或更少的浸濕時間。 4. 如申請專利範圍第i項的薄紙用品，其中聚魏燒合成物—律分送橫 跨薄紙用品的至少其中一第一及第二外表面。 5·如申請專利範圍第i項的薄紙用品，其中聚石夕氧燒合成物涵蓋观至 100%的薄紙用品之至少其中—第—及第二外表面的表面面積二 6·如申請專利範圍帛i項的薄紙用品，其中聚石夕氧燒合成物涵蓋75%至 100%的薄紙用品之至少其中-第—及第二外表面的表面面積。 7·如申請專利範圍第1項的薄紙用品，其中50%或更多的聚二烷基矽氧 烷含量包含聚二甲基矽氧烷。 8·如申請專利範圍第1項的薄紙用品，其中80%或更多的聚二烷基矽氧 烷含量包含聚二甲基矽氧烷。 9.如申請專利範圍第1項的薄紙用品，其中5%或更多的聚矽氧烷合成物 包含氨基官能聚矽氧燒。 10·如申請專利範圍第1項的薄紙用品，其中聚矽氧烷為氨基官能聚矽氧 烷及環氧基共同聚醚聚矽氧烷的混合物。 11.如申請專利範圍第1項的薄紙用品，其中薄紙用品包含多層。 12·如申凊專利範圍第11項的薄紙用品，其中薄紙用品為二層用品，此包 Mavis-D:\«Wk001.08~\0890\PK-001.0890.d〇c2004/6/30 38 含第-外層及第二外層，此形成並具有第—外表面及第二外表面，其 中二層薄紙用品的至少其t-第—及第二外表面含有聚魏燒合成 物0 以如中請專利範圍第U項的薄紙用品，其中二層用品的第一及第二外表 面二者含有聚碎氧燒合成物。 14.如申請專利範圍第Π項的薄紙用品，其中薄紙用品包含第—外層、第 二外層及至少-内層，其中第—外層的—外表面形成薄紙用品的曰第一 外表面’第二外層的—外表面形成薄紙用品的第二外表面。 A如申請專利綱第14項的薄紙用品，其中_姐合成物運用於薄紙 用叩的第及第一外表面’且薄紙用品的至少一内層本質上無聚石夕氧 队利範圍第Μ項的薄紙用品，其中聚魏燒合成物含於薄紙用 口口的第及第—外層中，且薄紙用品的至少—内層本質上無聚魏燒 合成物。 17. 18. 19. 如申請補請第1 ，其帽_品具有^克或更大 的蓬鬆’及5克坪方公尺至勘克坪方公尺的基重。 如申請專利第丨項的薄_品，其帽紙用品具有—克或更大 的逄餐’及5克/平方公尺至克/平方公尺的基重。如申請專觀Μ丨項的薄紙用品，其中聚二、絲魏齡量為〇.7 Wt%或更大的乾燥薄紙。 20.如申請專利範圍第！項的薄紙用品，其中薄紙用品在沉下熟化9 星期之後的反濕時間為2〇秒或更少。 几-種以聚石夕氧乾合成物處理的薄紙用品，在薄紙用品於沉下熟化 2=讀’薄紙用品具有至少〇,減的乾燥薄紙之聚二絲石夕氧燒 含里及具有G.8克，脚1/2錢大的麵化AGAT值，且具有60%或 Mavis-DA^IJ\Pk〇〇i ·〇8-\〇890\ΡΚ-〇〇ΐ -0890.doc2004/6/30 39 200424399 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 更大的預熟化AGAT值。 如申請專利範圍第21項的薄紙用品，其中薄紙用品在熟化至少〇·8克 /克/秒1/2之前具有一預熟化AGAT值，且薄紙用品在4〇π熟化14天 之後具有35%或更大預熟化AGAT值的後熟化AGAT值。 如申請專利範圍第^項的薄紙用品，其中薄紙用品具有3秒或更大的 預熟化HST值，以及3秒或更大的後熟化值。 如申請專利範圍第21項的薄紙用品，其中聚魏垸合成物—律分送橫 跨薄紙用品的至少其中一第一外表面及第二外表面。 如申請專利範圍第21項的薄紙用品，其中聚魏貌合成物涵蓋6〇% 至1〇〇%的薄紙用品之至少其中-第—及第二外表面的表面面積。 如申請專利範目第21項的薄紙用品，其中聚魏燒合成物涵蓋75% 至100%的薄紙用品之至少其中-第—及第二外表面的表面面積。 如申請專利範圍第21項的薄紙用品，其中50%或更大的聚二烷基矽氧 烷含量包含聚二甲基矽氧烷。 如申請專利範圍第21項的薄紙用品，其中8〇%或更大的薄紙用品之聚 二垸基矽氧烷含量包含聚二甲基矽氧烷。 如申請專利範圍第21項的薄紙用品，其中5%或更多的聚矽氧烷合成 物包含氨基官能聚矽氧烷。 如申請專利範圍第21項的薄紙用品’其中薄紙用品包含多層。 如申請專利範圍第30項的薄紙用品，其中薄紙用品為包含第一外層及 第二外層並具有第一外表面及第二外表面的二層用品，其中二層薄紙 用品的至少其中一第一及第二外表面含有聚矽氧烷合成物。 如申請專利範圍第31項的薄紙用品，其中二層用品的第一及第二外表 面含有聚矽氡烷合成物。 如申請專利範圍第30項的薄紙用品，其中薄紙用品包含第一外層、第 Mavis-D:\^flJ\Pk001.08~\0890\PK-001-0890.doc2004/6/30 40 200424399 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. '及土二⑽，其中弟—外層的—外表面形成薄紙用品的第-面且第—外層的一外表面形成薄紙用品的第二外表面。 __ _魏齡成物運用於薄紙 高面，蝴f ^㈣上無聚魏 =糊卿33侧咖，_嫩合搞含於薄紙用 二二心―外層中’且薄紙用品的至少—内層本質上無聚 合成物。 如申請專利範園第21項的薄紙用品，其中_品具有2 w克或更 大的紐，及5克坪方公尺至細克/平方公尺的基重。 如申請專利範圍第21項的薄紙用品，其中薄紙用品具有5 cc/克或更 大的蓬鬆，及5克/平方公尺至克/平方公尺喊重。 如申請專利範圍第21項的薄紙用品，其中薄紙用品在挪下孰化％ 天之後，薄紙用品具有7〇%或更大預熟化AGAT值的後熟化A·值。 如申請專難縣21項的薄紙用品，其中聚二燒基魏齡量為^ wt%或更大的乾燥薄紙。 如申請專利範圍第21項的薄紙用品，其中薄紙用品在2沉下熟化9 星期之後具有20秒或更少的浸濕時間。 -種以聚魏境合成物處理贿紙用品，在薄紙織物於μ下熟化 28天之後，薄紙織物具有至少G.55wt%的乾、燥薄紙之聚二絲石夕氧燒 含量及具有0.8克/克/秒、更大的AGAT值，且在25χ下熟化28 天或更多天之後，具有3秒或更大的HST。 如申請專利範圍第41項的薄紙織物，其中薄紙織物轉變觸紙用品。 如申請專利範®第41項祕紙織物，其中薄紙用品具有含聚魏燒合 成物的第一外表面及第二外表面，在薄紙織物於25〇c下熟化28天之 Ma^D：^i，JXPk0010^08WK-001-0890.doc2004/6/30 41 200424399 後，薄紙用品具有至少〇.55_乾燥薄紙的聚二燒基砂·人曰 具有α8克娜m或更大的AGAT值，並在25qc下熟二=或更 多天之後，具有3秒或更大的HST。 44. -種以聚魏綠成物處理簡賴物，在賴軸於沉下熟化 28天之後’薄紙織物具有至少㈣讀咐乾燥薄 二 含量及具有Μ克咖严或更大的職化A(}AT1: 更大的預熟化AGAT值。 45. 如申請專利範圍第44項的薄紙織物，其中薄紙織物轉變成 46. 如申請專利範圍第μ項的薄紙織物，其中薄紙用品具有含聚魏/人 成物的第-外表面及第二外表面，在薄紙用砂25τ下熟化Μ天: 後，薄紙用品具有至少G.55wt%乾燥薄_聚二絲魏燒含量，並 具有60%或更大預熟化AGAT值的Q 8克/克/秒1/2或更大之預熟化 AGAT值及後熟化AGAT值。 钎y種包含聚钱垸合成物的薄紙用品，薄紙用品在2沈下熟化Μ天 又後’薄紙用品具有6〇%或更大預熟化AGAT值的後熟化MAT值。 .=請專· 15第47項的薄_品，其中薄紙齡具有至少α55感 乾燥薄紙的聚二烷基矽氧烷含量。 49.如申請專利範圍第47項的薄紙用品，其中薄紙用品在沉下熟化％ 沁天或更多天之後，薄紙用品具有〇·8克/克/秒1/2或更大的A·值。 •如申請專利範圍第47項的薄紙用品，其中薄紙用品在2沉下熟化Μ 天或更夕天之後具有3秒或更大的hst。 種永妙氧：^合成物的薄紙織物，薄紙織物在下熟化Μ天之後， 52薄紙織物具有6〇%或更多預熟化AGAH直的後熟化AGAT值。 2.=請專·Μ 51項_峨物，其中薄紙織物具有至少Q 55感 乾燥薄紙的聚二烷基矽氧烷含量。 Mavis-D:\專称PkOO 1 ·08〜\0890\ΡΚ-001 -0890.doc2004/6/30 42 200424399 53. 54. 55. 如申請專利範圍第51項的潷祕斜 以ρ η/ 4㈣物，其中薄紙用品在2沉熟化28 ^ 〇, ^/# .AGAT ^ 〇 如申__第51項的薄紙織物，其中在咖熟化28天或更多天 之後，薄紙織物具有3秒或更大的hst。 如申請專利範圍第51項的薄紙織物，其中薄紙織物轉變成薄紙用品。 Mavis-D:\專利J\Pk001. 〇8〜\0890\ΡΚ-001 -0890.doc2004/6/30 2004243 99 柒、指定代表圖： (一） 本案指定代表圖為：第（ ）圖。 (二） 本代表圖之元件代表符號簡單說明： 捌、本案若有化學式時，請揭示最能顯示發明特徵的化 學式：200424399 Scope of patent application: — A kind of tissue paper products treated with polyweier burning compound. After the tissue products are matured for 2 days, the tissue products have at least 0 shot / 〇 It has a burn content and an AGAT value of 0.8 g / cm2, and has a jST of 3 seconds or more after being matured for a period of μ days or more. 2. For example, the tissue product of the scope of the application for patent, wherein the tissue product has 0.5 · g / g / sec 1/2 or more A · after the thin product is aged for 14 or more days. , And HST values of 4 or greater. 3. The tissue paper article of item i in the patent application scope has a soaking time of 15 seconds or less. 4. The tissue paper product of item i in the scope of the patent application, wherein the poly-Weiyin composite-law is distributed across at least one of the first and second outer surfaces of the tissue paper product. 5. If the tissue application of item i in the scope of patent application, the polyoxygen oxy-fired composition covers at least 100% of the tissue product, the surface area of the first and second outer surfaces. Item (i) of the tissue paper product, wherein the poly-stone oxy-fired composite covers 75% to 100% of the surface area of at least one of the first and second outer surfaces of the tissue paper product. 7. The tissue product according to item 1 of the patent application, wherein 50% or more of the polydialkylsiloxane content includes polydimethylsiloxane. 8. The tissue product according to item 1 of the patent application, wherein 80% or more of the polydialkylsiloxane content includes polydimethylsiloxane. 9. The tissue product according to item 1 of the patent application scope, wherein 5% or more of the polysiloxane composition contains amino-functional polysiloxane. 10. The tissue product as described in the first item of the patent application, wherein the polysiloxane is a mixture of an amino-functional polysiloxane and an epoxy-based polyether polysiloxane. 11. The tissue paper article as claimed in item 1 of the patent application scope, wherein the tissue paper article includes multiple layers. 12 · If you apply for tissue paper item No. 11 in the scope of patent application, in which tissue paper products are two-layer products, this bag Mavis-D: \ «Wk001.08 ~ \ 0890 \ PK-001.0890.d〇c2004 / 6/30 38 Including A first-outer layer and a second outer-layer, which are formed and have a first-outer surface and a second outer-surface, wherein at least its t-th and second outer surface of the two-layer tissue paper product contains a polyweier fired compound 0 as requested The U-thin tissue product of the patent scope, wherein the first and second outer surfaces of the two-layer product both contain polyoxygenated compounds. 14. The tissue paper products as claimed in item Π of the patent application scope, wherein the tissue paper products include a first outer layer, a second outer layer, and at least an inner layer, wherein the outer surface of the first-outer layer forms the first outer surface of the tissue paper product and the second outer layer. -The outer surface forms the second outer surface of the tissue product. AThe tissue paper supplies such as the item 14 of the patent application, in which the _ sister compound is applied to the first and first outer surfaces of the tissue paper 且 and at least one inner layer of the tissue paper supplies is substantially free of polysilicon. In the tissue paper product, the polyweier burning composition is contained in the first and the first-outer layers of the tissue, and at least-the inner layer of the tissue product is essentially free of the polyweier burning composition. 17. 18. 19. If you apply for replenishment No. 1, the cap product has a fluffy weight of ^ grams or more 'and a basis weight of 5 grams per square meter to Kan Keping square meters. For example, in the thin product of the patent application, the cap paper product has a gram meal or more and a basis weight of 5 g / m2 to g / m2. For example, if you apply for the tissue paper products of the special M1 item, the dry tissue paper with poly- and silk-wein content is 0.7 Wt% or more. 20. As for the scope of patent application! Item of tissue paper items, wherein the tissue paper has a dehumidification time of 20 seconds or less after 9 weeks of maturation. A few-a kind of tissue paper treated with a polysilicone oxygen dry compound, aged in a tissue paper product under the sink 2 = read 'thin paper supplies with at least 0, less dry tissue of polysilicone polyoxymethylene and containing G .8g, facet AGAT value of 1/2 foot, and has 60% or Mavis-DA ^ IJ \ Pk〇〇i -〇8- \ 〇890 \ ΡΚ-〇〇ΐ-0890.doc2004 / 6 / 30 39 200424399 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. Larger pre-aged AGAT value. For example, a tissue paper article with a scope of application of item 21, wherein the tissue paper article has a pre-aged AGAT value before being aged at least 0.8 g / g / sec 1/2, and the tissue paper article has 35% after 14 days of 40? Or greater pre-aged AGAT value. For example, the tissue application of the patent application No. ^, wherein the tissue application has a pre-cure HST value of 3 seconds or more, and a post-cure value of 3 seconds or more. For example, the tissue paper products of the scope of application for the patent No. 21, wherein the poly-Weiyi composite-law distribution distributes at least one of the first outer surface and the second outer surface of the tissue paper products. For example, the tissue paper supplies of the scope of application for the patent No. 21, wherein the poly-wei appearance composition covers 60% to 100% of the surface area of at least one of the first and second outer surfaces of the tissue paper supplies. For example, the tissue paper products of item 21 of the patent application, wherein the polyweier burning composition covers 75% to 100% of the surface area of at least one of the first and second outer surfaces of the tissue paper products. For example, a tissue paper article with a scope of application of item 21, wherein the polydialkylsiloxane content of 50% or more includes polydimethylsiloxane. For example, the thin paper products of the scope of application for patent No. 21, wherein the polydimethysiloxane content of 80% or more of the thin paper products includes polydimethylsiloxane. For example, a tissue paper article under the scope of patent application No. 21, wherein 5% or more of the polysiloxane composition contains amino-functional polysiloxane. For example, a tissue paper article of item 21 of the application scope, wherein the tissue paper article includes multiple layers. For example, a tissue paper article with a scope of application of item 30, wherein the tissue paper article is a two-layer article including a first outer layer and a second outer layer and having a first outer surface and a second outer surface, and at least one of the two-layer tissue paper articles is first And the second outer surface contains a polysiloxane compound. For example, a tissue paper article with a scope of application of item 31, wherein the first and second outer surfaces of the two-layer article contain a polysilazane compound. For example, the tissue paper supplies under the scope of patent application No. 30, where the tissue paper supplies include the first outer layer, No. Mavis-D: \ ^ flJ \ Pk001.08 ~ \ 0890 \ PK-001-0890.doc2004 / 6/30 40 200424399 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 'and Tu Erji, where the outer surface of the younger-outer layer-forms the first side of tissue paper products and an outer surface of the first-outer layer forms tissue paper products Second outer surface. __ _Wei Lingcheng applies to the high side of tissue paper, butterfly f ^ 聚 无 聚 魏 = 蝴 卿 33 lateral coffee, _ tenderly mixes the two and two hearts contained in tissue paper-in the outer layer and at least the inner nature of the tissue products There is no polymer product on it. For example, the thin paper supplies of Item 21 of the patent application park, where the products have a weight of 2 wg or more, and a basis weight of 5 grams per square meter to fine grams per square meter. For example, a tissue paper article with a scope of application for patent No. 21, wherein the tissue paper article has a fluff of 5 cc / g or more, and a weight of 5 g / m2 to g / m2. For example, the tissue paper article of the scope of application for the patent No. 21, in which the tissue paper article has a post-ageing A · value of 70% or more of the pre-aged AGAT value after it has been removed for a few days. For example, apply for tissue paper supplies in 21 counties in Zhuanxian County, where the amount of polydioxane-based Weiling is ^ wt% or more dry tissue paper. For example, a tissue paper article with a scope of patent application No. 21, wherein the tissue paper article has a soaking time of 20 seconds or less after 2 weeks of maturation and 9 weeks of maturation. -A kind of poly-Wei-Jing composition is used to treat bribe paper products. After the tissue paper fabric is aged at μ for 28 days, the tissue paper fabric has at least G.55wt% of dry and dry tissue, and the content of polysiliconite is 0.8 g Per gram / second, greater AGAT value, and HST of 3 seconds or more after 28 days or more of curing at 25x. For example, the tissue paper fabric of the scope of application for item No. 41, wherein the tissue paper fabric is transformed into a touch paper article. For example, if you apply for patent No. 41, the secret paper fabric, in which tissue paper supplies have a first outer surface and a second outer surface containing a polyweier burning compound, and the tissue is cured at 25 ° C for 28 days. Ma ^ D: ^ i, JXPk0010 ^ 08WK-001-0890.doc2004 / 6/30 41 200424399 After that, tissue products have at least 0.55_ polydisulfite-based sand of dry tissue. People have an AGAT value of α8 kna m or greater, And after ripening at 25qc = or more days, it has an HST of 3 seconds or more. 44.-Treating simple Lai products with green polyweeds, after the Lai axis has been aged for 28 days in the sun, the tissue paper has at least the content of dry thin film and has the professionalism of gram gram or more. A () AT1: Greater pre-aged AGAT value. 45. For example, the tissue paper fabric of the 44th patent application scope, where the tissue paper fabric is transformed into 46. For example, the tissue paper fabric of the μ scope of the patent application application, where the tissue paper products have polywei / person The first-outer surface and second outer surface of the product were aged at 25τ for tissue paper for 25 days: After that, the tissue products had a dry thin_poly-Eisen content of at least G.55wt%, and had 60% or more Pre-cure AGAT value of Q 8 g / g / sec 1/2 or greater of pre-cure AGAT value and post-cure AGAT value. Brazing y kinds of tissue paper products containing poly-copper tincture compound, the tissue paper products are matured under 2 sinking days Also, the tissue product has a post-cure MAT value of 60% or more of the pre-cure AGAT value.. = Please special · 15 Thin product of item 47, wherein the tissue age is at least α55 polydialkyl of dry tissue Siloxane content 49. The tissue paper supplies as claimed in item 47 of the patent application, wherein the tissue paper supplies are in After maturity% Qintian or more days, tissue paper supplies have an A · value of 0.8 g / g / sec 1/2 or greater. • For example, the tissue paper supplies in the 47th area of the patent application, where the tissue paper supplies are at 2 Hst of 3 seconds or more after sinking and ripening for M days or more. Perpetual Oxygen: ^ Synthetic tissue paper fabric, Tissue fabrics have 60% or more Straight post-aged AGAT value for aged AGAH. 2. = Please special · Item 51_ Ewu, where tissue paper fabric has a polydialkylsiloxane content of at least Q 55 dry tissue. Mavis-D: \ Specially named PkOO 1 · 08 ～ \ 0890 \ ΡΚ-001 -0890.doc2004 / 6/30 42 200424399 53. 54. 55. For example, the application of the scope of the patent application No. 51 is oblique with ρ η / 4 materials, in which tissue paper supplies Ageing 28 ^ 〇, ^ / # .AGAT ^ 〇 As mentioned in the tissue paper fabric of item 51, wherein the tissue paper fabric has a hst of 3 seconds or more after 28 days or more. The tissue paper fabric of item 51, wherein the tissue paper fabric is converted into tissue paper supplies. Mavis-D: \ patent J \ Pk001. 〇8 ~ \ 0890 \ ΡΚ-001 -0890.doc2004 / 6/30 2004243 99 柒. Designated representative map: (1) The designated representative map in this case is: () Figure. (2) Brief description of the component representative symbols in this representative map: 捌 If there is a chemical formula in this case, please reveal the features that can best show the invention Chemical formula: Mavis-D:\專和J\Pk001.08〜\0890\PK-0(H -0890.doc2004/6/30Mavis-D: \ Junhe J \ Pk001.08 ~ \ 0890 \ PK-0 (H -0890.doc2004 / 6/30