TR201811584A2 - INNOVATION IN 3D PRINTINGS USED IN TEXTILE - Google Patents

INNOVATION IN 3D PRINTINGS USED IN TEXTILE Download PDF

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Publication number
TR201811584A2
TR201811584A2 TR2018/11584A TR201811584A TR201811584A2 TR 201811584 A2 TR201811584 A2 TR 201811584A2 TR 2018/11584 A TR2018/11584 A TR 2018/11584A TR 201811584 A TR201811584 A TR 201811584A TR 201811584 A2 TR201811584 A2 TR 201811584A2
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Turkey
Prior art keywords
formulation
effect
water
feature
paste
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TR2018/11584A
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Turkish (tr)
Inventor
Türk Huri̇ye
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Oez Anadolu Kimya Sanayi Ve Ticaret Anonim Sirketi
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Priority to TR2018/11584A priority Critical patent/TR201811584A2/en
Publication of TR201811584A2 publication Critical patent/TR201811584A2/en
Priority to PCT/TR2019/050111 priority patent/WO2020032882A2/en

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06QDECORATING TEXTILES
    • D06Q1/00Decorating textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257(Meth)acrylic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5285Polyurethanes; Polyurea; Polyguanides

Abstract

Buluş, tekstil emprime baskılarda yapılan 3D baskı (Üç boyutlu baskı efekti) tekniğinde; ekolojik olmayan PVC esaslı baskı pastaları ile PVC ve ftalat içermeyen akrilik reçine esaslı ekolojik plastisol baskı pastalarının yerine, su bazlı ve tamamen ekolojik olan, tek kalıp uygulamasıyla 3D efekti alınabilen baskı pastalarıyla ilgilidir.The invention is based on 3D printing (three-dimensional printing effect) technique for textile screen printing; It is related to non-ecological PVC based printing pastes and PVC and phthalate free acrylic resin based ecological plastisol printing pastes.

Description

TEKNIK ALAN Bulus, tekstil emprime baskilarda yapilan 3D baski (Üç boyutlu baski efekti) tekniginde; ekolojik olmayan PVC esasli baski pastalari ile PVC ve ftalat içermeyen akrilik reçine esasli ekolojik plastisol baski pastalarinin yerine, su bazli ve tamamen ekolojik olan, tek kalip uygulamasiyla 3D efekti alinabilen baski pastalariyla ilgilidir. TECHNICAL FIELD Invention, 3D printing (Three-dimensional printing effect) made on textile screen prints in technique; non-ecological PVC-based printing pastes and PVC and phthalate-free instead of acrylic resin-based ecological plastisol printing pastes, water-based and completely ecological, it is about printing pastes that can have 3D effect with a single mold application.

TEKNIGIN BILINEN DURUMU Piyasada hem yerli hem de yabanci üreticiler olsun bulus tarihi itibariyle bilindik benzer yönteme rastlanilmamistir. Sadece su bazli yüksek uygulamalari çok katli ve çok ara kurutmali olarak üst üste baski katmanlari olusturarak 3D efekti elde etmeye yönelik çalismalar yapilmakta olup, bu da isletmeye ek maliyet getirmektedir. KNOWN STATE OF THE TECHNIQUE Whether there are both domestic and foreign manufacturers in the market, it is known as of the date of invention. No similar method has been found. Only water-based high applications multi-layer and achieve a 3D effect by creating superimposed print layers with very intermediate drying. Efforts are being made to provide additional costs to the business. brings.

Tekstil Emprime Baski (Parça baski) teknigi; tekstil yüzeyinin belli bir bölgesinin renklendirilmesi veya bu bölgedeki boyarmaddenin asindirilmasi teknigidir. Dar anlamiyla bölgesel bir boyama olarak ta tanimlanabilir. Textile Screen Printing (Part printing) technique; a certain area of the textile surface It is the technique of coloring or etching the dyestuff in this region. Narrow it can also be defined as a regional dyeing.

Kumaslar üzerinde bir veya çok renkli desenler elde etmek için uygulanan birçok baski teknigi mevcuttur. Bu teknik uygulamalar arasinda 3D efektli baski yöntemleri genis yer tutmaktadir. Genel anlamda Tekstil Emprime Baski çesitlerini asagidaki gibi gruplandirirsak 3D baski teknigini özel efekt baskilar arasinda degerlendirebiliriz. Many applied to obtain one- or multi-colored patterns on fabrics. printing technique is available. 3D effect printing methods are among these technical applications. occupies a large space. In general, the following types of Textile Screen Printing If we group them like we can evaluate.

Baski Çesitleri 1-Direkt baski 2-Asindirma baski 3-Rezerv baski 4-Transfer baski -Ink-jet baski 6-Özel efekt baskilar - Metalik-Shimmer-Reflektiv baskilar - Simli baskilar . Kabaran baskilar ° Suet baskilar ° Jel baskilar - Karanlikta - özel isikta parlayan baskilar - Isi ve isikta renk degistiren baskilar . Devore baski uygulamasi - Çatlayan efektli baski uygulamalari - Metalik Yüksek kalip baski uygulamalari 3D efektli baskilar, tekstil materyalinin yüzeyinde üç boyutlu görünümdedir. Print Types 1-Direct printing 2-Analysis printing 3-Reserve printing 4-Transfer print -Ink-jet printing 6-Special effect prints - Metallic-Shimmer-Reflective prints - Glitter prints . surging prints ° Suet prints ° Gel prints - In the dark - glow-in-the-dark prints - Prints that change color in heat and light . Devore printing app - Printing apps with cracking effect - Metallic High plate printing applications 3D effect prints have a three-dimensional appearance on the surface of the textile material.

Günümüzde bu efektin alinabilecegi baski pastalari, su bazli olmayan kimyasal kompozisyonlardan olusmus pastalardir. Bu pastalari iki gruba ayirirsak; birinci olarak piyasada ilk bilinen ürünler olan PVC (polivinil klorür) reçine esasli olan pastalardir. Ekolojik olmayan ve giderek kullanimi azalan bu pastalarda PVC reçinesini plastiklestiren ve pasta haline getiren plastifiyanlar kullanilmaktadir. Bu plastifiyanlar; Dibutyl Phthalate (DBP), Benzylbutyl Phthalate (BBP), Bis-(2- ethylhexyl) Phthalate (DEHP), Diisononyl Phthalate (DINP), Di-n-octyl Phthalate (DNOP), Diisodecyl Phthalate (DIDP) , Diisobutyl phthalate (DIBP) gibi ekolojik olmayan alkil plastifiyanlar olup, insan sagligi ve çevre ekolojisi açisindan zarar teskil etmektedir. Bu sebeple tekstil uygulamalari açisindan istenmeyen hale gelmis bulunmaktadirlar. Uluslararasi kabul gören ekolojik standartlarda PVC reçinesi ve plastifiyanlarin kullanimi konusunda zaman içerisinde kisitlama ve yasaklamalarin oldugu tüzükler yayinlanmistir. Today, printing pastes where this effect can be obtained are non-water-based chemicals. They are cakes made of compositions. If we divide these cakes into two groups; first PVC (polyvinyl chloride) resin-based products, which are the first products known in the market as are cakes. PVC is used in these non-ecological pastes, which are gradually decreasing in use. Plasticizers that plasticize the resin and turn it into paste are used. This plasticizers; Dibutyl Phthalate (DBP), Benzylbutyl Phthalate (BBP), Bis-(2- ethylhexyl) Phthalate (DEHP), Diisononyl Phthalate (DINP), Di-n-octyl Phthalate (DNOP), Diisodecyl Phthalate (DIDP), Diisobutyl phthalate (DIBP) are alkyl plasticizers that are not harmful to human health and environmental ecology. constitutes. For this reason, it has become undesirable in terms of textile applications. they exist. PVC resin in internationally accepted ecological standards and restrictions and prohibitions on the use of plasticizers over time. bylaws have been published.

REACH TÜZÜGÜ XVII (BELIRLI TEHLIKELI MADDE, KARISIM VE ESYALARIN IMALATI, PIYASAYA SÜRÜLMESI VE KULLANIMIYLA ILGILI KISITLAMALAR) 51. ve 52. maddesi yukarida bahsi geçen plastifiyanlar konusundaki kisitlamalardan bahsetmektedir. REACH REGULATION XVII (CERTAIN HAZARDOUS SUBSTANCES, MIXTURES AND GOODS RESTRICTIONS ON MANUFACTURING, MARKETING AND USE) 51. and Article 52 is exempt from the above-mentioned restrictions on plasticizers. is talking about.

Oeko-Tex® Standard 100 threshold level for treated textiles(product class Il) standardi ise islenmis tekstil ürünlerinde yine yukarida bahsi geçen plastifiyanlar için max. 1000 mg/kg a kadar izin vermektedir. Oeko-Tex® Standard 100 threshold level for treated textiles(product class Il) The standard is the plasticizers mentioned above in processed textile products. for max. It allows up to 1000 mg/kg.

Bununla beraber günümüzde sektörün öncüsü olan bazi büyük tekstil firmalari, tüm sinirlandirilan alanlari daha da daraltip kendi kistaslarini belirledikleri standartlar olusturma yoluna gittiler. Örnek vermek gerekirse, bir firma yayinladigi CHEMICAL RESTRICTIONS 2018 - MANUFACTURING RESTRICTED SUBSTANCES LIST (MRSL) deklarasyonunda ftalatlari 50 ppm olarak sinirlamis. Ayni sekilde bir baska firma da MRSL deklarasyonunda PVC istememekte ve toplam ftalat içeriginin ise 1000 ppm den asagi olmasini istiyor. Bir baska firma ise MRSL'sinde ftalati tamamen yasaklamistir. Özetle bu birinci grupta anlatilan 3D efekti veren PVC esasli ürünlerin, hem üretimi asamasinda hem de baski pastasinin uygulamasi asamasinda, insan sagligini ve çevre ekolojisini ciddi sikintiya sokan durumlar söz konusudun Diger 3D efekti veren ürün grubu ise akrilik reçine esasli ekolojik ürün gruplaridir. However, some large textile companies, which are the pioneers of the sector today, standards by which they further narrow the restricted areas and set their own benchmarks they went to create. For example, a company published CHEMICAL RESTRICTIONS 2018 - MANUFACTURING RESTRICTED SUBSTANCES LIST In the (MRSL) declaration, phthalates are limited to 50 ppm. In the same way, another The company also does not want PVC in its MRSL declaration and if the total phthalate content is It wants it to be below 1000 ppm. Another company has phthalates in its MRSL. completely banned. In summary, the PVC that gives the 3D effect described in this first group based products, both in the production phase and in the application of the printing paste At this stage, there are situations that put human health and environmental ecology in serious trouble. you were about The other product group that gives a 3D effect is acrylic resin-based ecological product groups.

Bu ikinci ürün grubu sektörün ekolojik beklentisini karsilamaktadir. Ancak kullanim kosullarinda bazi fiziksel zorluklari da bünyesinde barindirmaktadir. Piyasada bu tip ürünlerfarkli fiziksel özelliklere sahip olabilmektedir. Örnegin, sert tutumlu efekte sahip olandan yumusak tutumlu 3D efektli olana kadar çesitlilik arz eder. Bir kisminin tusesinde bariz yapiskanlik hissi vardir ve bu istenmeyen bir durumdur. This second product group meets the ecological expectation of the sector. However, use It also includes some physical difficulties in its conditions. This is on the market Types of products may have different physical properties. For example, the hard-handed effect It ranges from those with soft handles to those with 3D effects. A There is an obvious sticky feeling in the tuse of the part, which is undesirable.

Bazisinin baski hatlarinda olusan düzensizlik (sektörün sakal olusturmasi diye tabir ettikleri sorun) yine olumsuz bir durumdur. Bir diger sorun ise basilan kumasin zamanla yag kusmasi diye tabir edilen zamanla baski hatlarinda islanmis görünümü veren yagin yayilmasi ve baski yüzeyinde yaglanma yapmasi. Tüm bu sorunlar ekolojik olan bu ürün grubunun fiziksel dezavantajlaridir. Irregularity in the pressure lines of some of them (the so-called beard formation of the sector) problem) is again a negative situation. Another problem is the printed fabric. soaked in pressure lines over time, which is called oil vomit over time spreading of the oil giving the appearance and lubrication on the printing surface. all this The problems are the physical disadvantages of this ecological product group.

Bu tip pastalarda reçine olarak, akrilik türevli toz reçineler kullanilmakta olup, farkli TG degerine sahip çesitleri mevcuttur. Seçilen plastiklestirici ile beraber, ürünün yumusaklik-sertlik, parlaklik-matlik, yapiskanlik gibi fiziksel özellikleri belirlenir. Bu tip ürünlerde kullanilan baslica plastiklestiricileri, Tri-cresyl phosphate, Acetyl tributyl citrate, Alkyl phenylsulfonate, Isopropylphenyl phosphate seklinde sayabiliriz. Acrylic-derived powdered resins are used as resin in this type of pastes. There are varieties with TG value. Together with the chosen plasticizer, the product Physical properties such as softness-hardness, gloss-mattness, stickiness are determined. This The main plasticizers used in such products are Tri-cresyl phosphate, Acetyl as tributyl citrate, Alkyl phenylsulfonate, Isopropylphenyl phosphate we can count.

EP 1506263A1 patentinde bu tip ürün grubunun kimyasal içeriginin fiziksel ve kimyasal olarak mekanizmasi anlatilmaktadir. Söyle ki; patente konu edilen plastisol tekstil pastasinin kimyasal kompozisyonunda esas olarak PVC ve ftalat içermediginden bahseder. Bu pastanin ana malzemesi olarak 90-125 ° C'Iik Tg'ye sahip bir akrilik polimer çekirdegi ile daha düsük Tg'ye sahip bir akrilik polimer kabuga sahip, çekirdek-kabuk akrilik polimeri içerigi vurgulanir. Ikinci malzeme olarak 60-120 mm2 / s'lik bir viskoziteye sahip bir organik fosfat plastiklestirici ve üçüncü olarak renklendirici kombinasyon için pigment bilesiminden bahseder. In the EP 1506263A1 patent, the chemical content of this type of product group is physical and The chemical mechanism is described. Namely; patented The chemical composition of plastisol textile paste is mainly PVC and phthalate. mentions that it is not included. Tg of 90-125°C as the main ingredient of this cake. an acrylic polymer core with a lower Tg The content of a core-shell acrylic polymer with a shell is highlighted. second material as an organic phosphate plasticizer with a viscosity of 60-120 mm2 / s, and thirdly, it mentions the pigment composition for the colorant combination.

Pasta bilesenlerinin fiziksel özelliklerini detaylandirir. It details the physical properties of cake ingredients.

Yukarida detaylandirilan Mevcut 3D efekt pastalarinda ortak dezavantaj olarak bir diger bahsedilmesi gereken konu ise, her iki tip baski pastalarinin uygulamasinda, baski sonrasinda sablonlar ve diger kullanilan ekipmanlarin White sprit ve ya selülozik tiner yardimiyla temizlenme zorunlulugunun olmasidir. Bu da yine hem çevre, hem is sagligi ve güvenligi açisindan uygun koruyucu donanim ve ekipmanlar gereksinimi dogurur. Bunun da firmaya ek maliyetler getirdigi ortadadir. A common disadvantage with existing 3D effect pastes detailed above is a The other issue that needs to be mentioned is that in the application of both types of printing pastes, After printing, the templates and other used equipment must be made with White sprit or the necessity of cleaning with the help of cellulosic thinner. This is again appropriate protective equipment and equipment in terms of environment, occupational health and safety. equipment is required. It is obvious that this brings additional costs to the company.

Oysaki bulus konusu ürün için baski sonrasi ekipman temizligi için sadece suya ihtiyaç duyulmasi ürünün avantajlarindan birini teskil eder. However, for the product which is the subject of the invention, only water is required for cleaning the equipment after printing. the need for it constitutes one of the advantages of the product.

Sektörün üreticileri ve de kullanicilari, 3D efektli baski pastasinin su bazli olanini yaklasik 25 yildir talep etmektedir. Sektörde bazi kullanicilar özellikle de uzak dogu emprimecileri, 3D efektinin su bazli uygulamasini, mevcut su bazli elastik pastalarin defalarca üst üste kalip uygulamasi ile gerçeklestirdikleri bilinmektedir. Bununda zamandan, isçilikten ve maliyetten dezavantaj olusturacagi ortadadir. Manufacturers and users of the industry prefer the water-based 3D effect printing paste. has been demanding for about 25 years. Some users in the industry, especially the far east printmakers, water-based application of the 3D effect, existing water-based elastic pastes It is known that they have done it with mold application over and over again. In this it is obvious that it will create a disadvantage in terms of time, labor and cost.

BULUSUN TANIMI Mevcut bulus yukarida bahsedilen dezavantajlari ortadan kaldirmak ve ilgili teknik alana yeni avantajlar getirmek üzere gelistirilmis 3 boyutlu baski teknigiyle ilgilidir. DESCRIPTION OF THE INVENTION The present invention is designed to eliminate the above mentioned disadvantages and It is about the 3D printing technique developed to bring new advantages to the field.

Bulusun bir amaci; kullanici kolayligi saglamak, mevcut ihtiyaçlari karsilamak, kullanim çesitliligi sunmak, Know-How bilgi ve beceri üretmek, kullanicinin üretim sürecini iyilestirmektir. Ayrica bulus metraj baski uygulamalarinda ve ev tekstili ürünlerinde de kullanim alani bulabilir. An aim of the invention is; to provide user convenience, to meet current needs, to offer a variety of uses, to produce know-how knowledge and skills, to produce to improve the process. In addition, the invention is used in printing applications and home textiles. It can also find use in its products.

Bulus konusu ürün teknigin bilinen durumunda bahsedilen mevcut ürünlerin dezavantajlarinin bertarafi ve sektörün yogun talebi üzerine gelistirilmistir. Bulus konusu ürünün kullanimi sonucunda sagliga zararli olan PVC ve palstifiyan gibi kimyasallardan ve baskinin fikselenmesi sonucu olusan fikse buharlarindaki zararli kontamine ürünlerden uzak kalinmis olunacaktir. Digertaraftan yine 3D efekti veren ekolojik akrilik pastalarin isletme sartlarindaki kullanim zorluklari ortadan kaldirilmis olacak ve basilmis tekstil materyalindeki zamanla olusan deforme sikintisi da ortadan kalkmis olacaktir. The product subject to the invention is known in the state of the art. It has been developed to eliminate its disadvantages and upon the intense demand of the industry. Meet As a result of the use of the product in question, such as PVC and plasticizer, which are harmful to health harmful effects in the fixing vapors formed as a result of the chemicals and the fixation of the print. Contaminated products will be avoided. On the other hand, giving the 3D effect again The difficulties of using ecological acrylic pastes in operating conditions have been eliminated. and the problem of deformation in the printed textile material over time will have disappeared.

Bulus konusu ürün, mevcut su bazli olmayan yöntemlere önemli alternatif saglamaktadir. Teknigin bilinen durumunda belirtildigi üzere iki fakli tipte olan mevcut ürünlerden PVC esasli olan ürün kullanildiginda, en basta insan sagligini olumsuz yönde etkileyen PVC ve ftalat kimyasallarindan uzak kalinmis olacaktir. The product of the invention is an important alternative to existing non-water-based methods. it provides. As stated in the state of the art, two different types of When using PVC-based products from existing products, it primarily affects human health. It will be kept away from PVC and phthalate chemicals that adversely affect it.

Gerek bu ürünlerin üretimi esnasinda ftalat ve pvc ile olan kisisel maruziyetin giderilmesi bulus konusu ürün için basli basina avantaj saglamaktadir. Üretimden sonra boyanin elleçlenmesi ile alakali olan olumsuz durumlari da ortadan kaldiracagi için avantaj saglamaktadir. Boyanin uygulama esnasinda kullanilan teçhizatlarin temizliginde kullanilan petrol naftanin da kullanimina son vereceginden bulus avantajlidir. Naftanin kullanimi konusunda kisisel koruyucu ekipmanlar isletme açisindan da maliyetli oldugundan isletme maliyetlerinde de ekonomik olacagindan avantaj saglayacaktir. Personal exposure to phthalates and pvc during the production of these products elimination provides an advantage in itself for the product subject to the invention. from production Then, the negative situations related to the handling of the paint are eliminated. It provides an advantage to remove it. Used during the application of the paint The use of petroleum naphtha, which is used in the cleaning of equipment, is also terminated. Invention is advantageous because it will give. Personal protection for the use of naphtha Since the equipment is costly in terms of operation, it is also costly in operating costs. It will be advantageous as it will be economical.

Ayni sekilde diger yöntem olan ekolojik yag bazli ürünün de kullanim sonunda teçhizat temizliginde petrol nafta kullanilmasi nedeniyle basvuru konusu ürün buna karsi yine avantaj saglamaktadir. 3D baski pastalarinin hazir konfeksiyon asamasindaki durumlarindan bahsedersek, plastik baski yapilmis mamulde, basili bölgeye dokunuldugunda plastige dokunmus hissini verir. Plastik baskinin yikama ve sürtünme hasligi iyi olmasina ragmen kuru temizleme hasligi düsüktür. Dolayisiyla kuru temizlemeye uygun bir baski degildir. Ancak bulus konusu ürün ile baski yapilmis tekstil ürününe dokunuldugunda, plastik ürün dokunusundan oldukça uzak, hos ve daha cazip bir tutum sergilemektedir. Bu da kullanici açisindan tercih nedenidir. Likewise, at the end of use of the ecological oil-based product, which is the other method. Due to the use of petroleum naphtha in cleaning equipment, the product subject to application Again, it provides an advantage. 3D printing pastes from the ready-to-wear stage. speaking, in plastic printed product, when the printed area is touched gives the feeling of touching plastic. Washing and rubbing fastness of plastic printing is good Although dry cleaning fastness is low. So dry cleaning is not a suitable one. However, the textile product printed with the subject of the invention When touched, it is pleasant and more attractive, quite far from the plastic product touch. exhibits an attitude. This is preferred by the user.

Bulus konusu ürünün kullanim alani ile alakali olarak, mevcut emprime sektörünün disinda; metraj baski, ev tekstili ürünleri ve ya dekoratif faaliyetlerde bulunan sektörlerde de zamanla kullanim alani bulabilecektir. Pazarlama stratejileri ve is gelistirme departmanlarinin faaliyetleri, bu amaç için zemin olusturabilir. Regarding the usage area of the product subject of the invention, the current printing industry outside; engaged in printing, home textile products or decorative activities It will also be able to find use in the sectors over time. Marketing strategies and business The activities of the development departments can lay the groundwork for this purpose.

Belirtilmesi gereken bir diger husus ise, bulus konusu ürünün zaman içerisinde bazi özelliklerinin daha da gelisime açik olmasidir. Bunlardan biri baski uygulamasi yapilan kumasin fikseleme süresindeki iyilestirme olabilir. Mevcut durumda fikseleme islemi iki sefer ve toplamda 4-6 dk. arasi degismektedir. Bu süreyi basilacak figürün yüksekligi ve desenin yüzey alanin büyüklügü belirler. Düsük seviyeli ve düsük yüzey alanli desenlerde fikse süresi 4-5 dk. iken yüksek seviyeli ve yüksek yüzey alanli desenlerde 5-6 dk. olabilmektedir. Iste bu fikse sürelerinde, gelisen yeni uygulamalar ve edinilecek yeni tecrübeler sonucu, zaman içerisinde fikseleme süreleri kisalabilir. Bunun yaninda pastanin sektörde kullaniminin yayginlasmasi ile beraber kullanicilarin beklentilerindeki degiskenlige göre pastanin revize edilebilme olasiligi mevcuttur. Çizimler Yukarida kisaca özetlenen ve asagida daha detayli ele alinan mevcut bulusun uygulamalari, bulusun ekteki çizimlerde betimlenen örnek uygulamalarina basvurarak anlasilabilir. Ancak ekteki çizimlerin yalnizca bu bulusun tipik uygulamalarini betimledigini ve bulus, bu nedenle, diger esit derecece etkili uygulamalara izin verebilecegi için, kapsamini sinirladiginin varsayilmayacagini belirtmek gerekir. Another point to be noted is that the product subject to the invention may have some changes over time. its features are open to further development. One of them is the printing application. There may be an improvement in the fixation time of the fabric made. In the present case The fixation process takes two times and a total of 4-6 minutes. varies between This time The height of the figure to be printed and the size of the surface area of the pattern determines. Low The fixation time is 4-5 minutes for high-level and low surface area patterns. while high level and 5-6 min in patterns with high surface area. can happen. In these fixation times, As a result of developing new applications and new experiences to be gained, fixation times can be shortened. In addition, the use of cake in the sector according to the variability in the expectations of the users with the spread of There is a possibility that the cake can be revised. drawings The present invention, which is briefly summarized above and discussed in more detail below, embodiments of the invention correspond to exemplary embodiments of the invention depicted in the accompanying drawings. can be understood by pressing. However, the accompanying drawings are only typical of this invention. and the invention therefore describes other equally effective applications. not be deemed to limit its scope, as it may allow applications must be specified.

Sekil 1, bulus yöntemin asamalaridir. Figure 1 is the stages of the invention method.

Anlasilmayi kolaylastirmak adina, sekillerde ortak olan özdes elemanlari belirtmek için, mümkün hallerde özdes referans numaralari kullanilmistir. Sekiller ölçekli çizilmemistir ve açiklik için basitlestirilebilir. Bir uygulamanin elemanlari ve özelliklerinin daha fazla açiklama lüzum olmaksizin diger uygulamalara faydali bir biçimde dâhil edilebilecegi düsünülmektedir. Çizimlerdeki Detaylarin Açiklanmasi Sekillerde gösterilen referans numaralarinin karsiliklari asagida verilmistir. 1-Alim, 2- Mikserde karisim, 3- Dispersiyon, 4- Köpük kesici-hava giderici ilavesi, - Kivamlastirici ilavesi BULUSUN DETAYLI AÇIKLANMASI Bu detayli açiklamada bulus konusu üç boyutlu baski teknigi yapilanmasinin tercih edilen alternatifleri, sadece konunun daha iyi anlasilmasina yönelik olarak ve hiç bir sinirlayici etki olusturmayacak sekilde açiklanmaktadir. baski efekti yönteminde kullanilmakta olan PVC esasli ve ekolojik akrilik pastalarin yerine bulus konusu ürün alternatif teskil eder. Bulus konusu pasta kombininin kati madde içeriginin yogun olusu, 3D efektin alinmasinda önemli etkendir. Iyi bir 3D efekti alabilmek için bulus konusu ürün, ana polimer malzemelerden su bazli polieterik poliüretan dispersiyonunun %60 kati maddeli olanini gerekli kilar. Yine kumas üzerinde etkili 3D efekti alabilmek için bulus konusu ürün ana polimer malzemelerden 1500 molekül agirlikli Polietilen Glikolü gerekli kilar. Bulus konusu ürün, kati maddesini desteklemek için akrilik kopolimer yapili isi ile genlesebilen mikro kürecikleri gerekli kilar. Ayrica bulus konusu ürün tüm bu ana malzemenin çalisma kosullarini iyilestirmek için, yüzey aktif madde, köpük kesici ve kivamlastirici malzeme kullanimini zorunlu kilar. Bu durumda asagidaki kimyasallari içermektedir. To make the figures easier to understand, specify identical elements common to the figures. Identical reference numbers are used where possible. Figures to scale is not drawn and can be simplified for clarity. Elements of an application and a useful application to other applications without the need for further explanation. is considered to be included. Explanation of Details in Drawings The equivalents of the reference numbers shown in the figures are given below. 1-Alim, 2- Mixing in the mixer, 3- Dispersion, 4- Addition of defoamer-air remover, - Addition of thickener DETAILED DESCRIPTION OF THE INVENTION In this detailed explanation, the subject of the invention is the choice of three-dimensional printing technique. alternatives, only for a better understanding of the subject and without any It is explained in a way that does not have a restrictive effect. PVC-based and ecological acrylic used in the printing effect method Instead of cakes, the subject of the invention constitutes an alternative. Invention cake The density of the solid matter content of the combi boiler is important in obtaining the 3D effect. factor. In order to obtain a good 3D effect, the inventive product must be of water-based polyetheric polyurethane dispersion with 60% solid substance makes it necessary. Again, the subject of the invention is to get an effective 3D effect on the fabric. The product requires 1500 molecular weight Polyethylene Glycol from the main polymer materials. storeroom The product of the invention is made of acrylic copolymer to support the solid material. necessitates expandable microspheres. In addition, the subject of the invention is the product of all these main to improve the working conditions of the material, surfactant, defoamer and requires the use of thickening materials. In this case the following contains chemicals.

- Polieterik bazli poliüretan dispersiyon o 1500 m.a. li Polietilen Glikol . Akrilik kopolimer yapili mikro kürecikler. - Polyetheric based polyurethane dispersion o 1500 m.a. li Polyethylene Glycol . Microspheres made of acrylic copolymer.

° Yüzey aktif madde ° Köpük kesici-hava giderici madde - Poliakrilik Ester yapili kivamlastirici Bulus konusu pasta, kumas üzerinde beyaz renkli desende 3D efekt elde etmek için dolgu tozu olarak titanyum dioksit kullanimini zorunlu kilar. Bu durumda bulus; - Polieterik bazli poliüretan dispersiyon o 1500 m.a. li Polietilen Glikol . Akrilik kopolimer yapili mikro kürecikler. ° Surfactant ° Defoamer-deaerating agent - Thickener with Polyacrylic Ester The subject of the invention is to obtain a 3D effect in a white color pattern on the cake, fabric. Requires the use of titanium dioxide as filler powder for In this case, the invention; - Polyetheric based polyurethane dispersion o 1500 m.a. li Polyethylene Glycol . Microspheres made of acrylic copolymer.

° Yüzey aktif madde - Köpük kesici-hava giderici madde 0 Titanyum dioksit dolgu tozu - Poliakrilik Ester yapili kivamlastici Kimyasallarini içerir. ° Surfactant - Defoamer-deaerating agent 0 Titanium dioxide filler powder - Thickener made of Polyacrylic Ester Contains chemicals.

Bulus konusu ürün mevcut pastalarin aksine su bazli olup, yogun kati maddesi nedeniyle kumas üzerinde 3D efekti veren pastadir. The product of the invention is water-based, unlike existing pastes, and has a dense solid material. It is a cake that gives a 3D effect on the fabric.

Bulus konusu su bazli 3D efekti veren pasta, polieterik bazli poliüretan dispersiyon, 1500 molekül agirlikli polietilen glikol, akrilik kopolimer yapili mikro kürecikler, yüzey aktif madde, köpük kesici - hava giderici madde, beyaz uygulama yapilacaksa titanyum dioksit ve kivam verici olarak poliakrilik ester yapili malzemelerden olusur. The subject of the invention is a water-based 3D effect paste, polyetheric-based polyurethane dispersion, 1500 molecular weight polyethylene glycol, acrylic copolymer made microspheres, surface active substance, defoamer - deaerator, if white is to be applied It consists of materials made of titanium dioxide and polyacrylic ester as a thickener.

Poliüretan dispersiyonun yüksek kati maddeli olan türü ile formülasyondaki diger polimerik maddelerle sinerji yaparak, belli isida kürlesip polimerize olur. Böylece kumas yüzeyinde film tabakasi katmanlari olusturarak 3D efektin olusumuna imkan saglar. Poileterik bazli poliüretan dispersiyonun bulus konusu formülasyon Içinde % 75-80 oranindadir. The high solids type of the polyurethane dispersion and the other By synergizing with polymeric substances, it cures and polymerizes at a certain temperature. Like this It allows the formation of a 3D effect by creating film layer layers on the fabric surface. it provides. % in the formulation subject to the invention of the polyetheric-based polyurethane dispersion It is 75-80 percent.

Bulus konusu su bazli 3D efekti veren pasta içinde kullanilan 1500 molekül agirlikli polietilen glikol formülasyon içinde kati maddeyi destekleyen ve uzun polimer zinciri sayesinde 3D efekte destek veren malzeme olup, bulus konusu formülasyon içinde Bulus konusu su bazli 3D efekti veren pasta içinde kullanilan Poliakrilik yapili mikro kürecikler formülasyon içinde kati maddeyi destekler ve baski fiksesi esnasinda genleserek, uçucu bilesenin kaybiyla olusacak olan 3D seviyesindeki düsmenin önüne geçer. Bulus konusu formülasyon içinde % 2-3 arasinda kullanilir. The subject of the invention is a water-based 3D effect cake with a molecular weight of 1500 used in Polyethylene glycol in the formulation supporting the solid and long polymer chain It is the material that supports the 3D effect thanks to its Polyacrylic microstructure used in the water-based 3D effect paste, which is the subject of the invention. The beads support the solid in the formulation and during pressure fixing by expanding, the reduction in the 3D level that will occur with the loss of the volatile component gets ahead of it. It is used between 2-3% in the formulation of the invention.

Bulus konusu su bazli 3D efekti veren pasta içinde kullanilan yüzey aktif madde, formülasyonda kullanilan diger bütün hammaddelerin homojen dagilimini saglar ve boyanin çalisma ortaminda kullanimini kolaylastirir. Bulus konusu formülasyon içinde % 3-5 arasinda kullanilir. The surfactant used in the water-based 3D effect paste, which is the subject of the invention, It provides homogeneous distribution of all other raw materials used in the formulation and It facilitates the use of the paint in the working environment. Formulation of the subject of the invention It is used between 3-5%.

Bulus konusu su bazli 3D efekti veren pasta içinde kullanilan köpük kesici -hava giderici, pasta üretim asamasinda ve kullanim asamasinda olusan hava kabarciklarinin bertarafini saglar. Bulus konusu formülasyon içinde %O.5-1 arasinda kullanilir. The defoamer used in the water-based 3D effect cake, which is the subject of the invention, is air. remover, the air formed during the cake production and usage phase It ensures the removal of bubbles. 0.5-1% in the formulation subject to the invention used between

Bulus konusu su bazli 3D efekti veren pasta içinde kullanilan titanyum dioksit, beyaz renkli 3D efekti baskilar elde etmek için pasta üretim asamasinda kullanilir ve bulus konusu formülasyon içinde % 5-10 arasindadir. Titanium dioxide used in the water-based 3D effect paste, which is the subject of the invention, It is used in the cake production phase to obtain white colored 3D effect prints. and 5-10% in the formulation of the invention.

Bulus konusu su bazli 3D efekti veren pasta içinde kullanilan poliakrilik ester yapili kivamlastirici, pastanin uygun kivamda kalmasini saglar ve bulus konusu formülasyon içinde orani %2 dir. 3D efekt pastasinin hazirlanmasi asagidaki islem adimlarindan olusur. ° Öncelikle poliüretan disperiyon miksere alinir. Akabinde diger malzemeler ilave edilir. Böylelikle alim (1) adimi tamamlanmis olur. The subject of the invention is made of polyacrylic ester, which is used in the paste that gives a water-based 3D effect. The thickener ensures that the paste remains in the appropriate consistency and the subject of the invention Its rate in the formulation is 2%. Preparation of the 3D effect cake consists of the following process steps. ° First, the polyurethane dispersion is taken into the mixer. Then other materials is added. Thus, the scholar (1) step is completed.

- Homojen bir görünüm elde edilinceye kadar mikserde karisim (2) devam . Sayet beyaz pasta üretimi yapilacaksa, ilk etapta poliüretan dispersiyon içinde Titanyum dioksit belirtilen oranda dispersiyon (3) edilir, sonrasinda diger malzemeler ilave edilir. - Continue mixing (2) in the mixer until a homogeneous appearance is obtained. . If white paste is to be produced, in the first place, polyurethane dispersion will be used. Titanium dioxide is dispersed in the specified ratio (3), then the other materials are added.

- Köpük kesici - hava giderici malzemenin belirtilen oranda ilave edilerek köpük kesici-hava giderici ilavesi (4) asamasi gerçeklestirilir. - Defoamer - by adding the deaerator material at the specified rate Addition of defoamer-air remover (4) is performed.

- Uygun kivama gelinceye kadar kivamlastirici ilavesi (5) yapilir. - Add thickener (5) until it reaches the appropriate consistency.

Belirtilmesi gereken bir diger husus ise, bulus konusu ürünün zaman içerisinde bazi özelliklerinin daha da gelisime açik olmasidir. Bunlardan biri baski uygulamasi yapilan kumasin fikseleme süresindeki iyilestirme olabilir. Mevcut durumda fikseleme islemi iki sefer ve toplamda 4-6 dk.arasi degismektedir. Bu süreyi basilacak figürün yüksekligi ve desenin yüzey alanin büyüklügü belirler. Düsük seviyeli ve düsük yüzey alanli desenlerde fikse süresi 4-5 dk. iken yüksek seviyeli ve yüksek yüzey alanli desenlerde 5-6 dk. olabilmektedirlste bu fikse sürelerinde, gelisen yeni uygulamalar ve edinilecek yeni tecrübeler sonucu ,zaman içerisinde fikseleme süreleri kisalabilir. Bunun yaninda pastanin sektörde kullaniminin yayginlasmasi ile beraber kullanicilarin beklentilerindeki degiskenlige göre pastanin revize edilebilme olasiligi mevcuttur. Another point to be noted is that the product subject to the invention may have some changes over time. its features are open to further development. One of them is the printing application. There may be an improvement in the fixation time of the fabric made. In the present case The fixation process takes two times and a total of 4-6 minutes. This time The height of the figure to be printed and the size of the surface area of the pattern determines. Low The fixation time is 4-5 minutes for high-level and low surface area patterns. while high level and 5-6 min in patterns with high surface area. during these fixation periods, As a result of developing new applications and new experiences to be gained, over time fixation times can be shortened. In addition, the use of cake in the sector according to the variability in the expectations of the users with the spread of There is a possibility that the cake can be revised.

Claims (11)

ISTEMLERREQUESTS 1- Bulus, tekstil ürünlerinde 3 boyutlu baski teknigi olup, özelligi; o Mikserde karisim (2), o Dispersiyon (3), o Köpük kesici-hava giderici ilavesi (4), o Kivamlastirici ilavesi (5) islem adimlarini içermesidir.1- The invention is a 3D printing technique in textile products, and its feature is; o Mixing in the mixer (2), o Dispersion (3), o Addition of defoamer-air remover (4), o Addition of thickener (5) process steps. 2- Istem 1'e göre tekstil ürünlerinde 3 boyutlu baski teknigi olup, özelligi; - Öncelikle poliüretan disperiyon miksere alinmasi (1) ve akabinde diger malzemelerin ilave edilmesi, . Homojen bir görünüm elde edilinceye kadar mikserde karisimin (2) devam ettirilmesi, - Sayet beyaz pasta üretimi yapilacaksa, ilk etapta poliüretan dispersiyon içinde Titanyum dioksit belirtilen oranda dispersiyon (3) edilmesi ve sonrasinda diger malzemelerin ilavesi, ° Köpük kesici- hava giderici malzemenin belirtilen oranda ilave edilmesi,2- It is a 3D printing technique in textile products according to claim 1, and its feature is; - Firstly, taking the polyurethane dispersion into the mixer (1) and then adding other materials, . Continuing the mixture (2) in the mixer until a homogeneous appearance is obtained, - If white paste is to be produced, dispersing the Titanium dioxide in the polyurethane dispersion at the specified rate at the first stage and then adding the other materials, ° Defoamer- deaerator material at the specified rate adding, 3- Istem 1 ve 2'ye göre tekstil ürünlerinde 3 boyutlu baski teknigi olup, özelligi; . Polieterik bazli poliüretan dispersiyon ° 1500 m.a. li Polietilen Glikol o Akrilik kopolimer yapili mikro kürecikler - Yüzey aktif madde - Köpük kesici-hava giderici madde . Eger desen beyaz renkliyse Titanyum dioksit dolgu tozu - Poliakrilik Ester yapili kivamlastici kimyasallarini içermesidir.3- It is a 3D printing technique in textile products according to claims 1 and 2, and its feature is; . Polyetheric based polyurethane dispersion ° 1500 m.a. li Polyethylene Glycol o Microspheres made of acrylic copolymer - Surfactant - Defoamer-deaerating agent. If the pattern is white, it means that it contains Titanium dioxide filling powder - Polyacrylic Ester made thickener chemicals. 4- Yukaridaki Istemlerden herhangi birine göre bir baski teknigi olup, özelligi; mevcut pastalarin aksine su bazli olmasidir.4- It is a printing technique according to any of the above claims, and its feature is; Unlike existing pastes, it is water-based. 5- Yukaridaki Istemlerden herhangi birine göre polieterik bazli poliüretan dispersiyonun olup, kumas yüzeyinde film tabakasi katmanlari olusturarak 3D efektin olusumuna imkan saglar özelligi; poliüretan dispersiyonun yüksek kati maddeli olan türü ile formülasyondaki diger polimerik maddelerle sinerji yaparak, belli isida kürlesip polimerize olmasi ve formülasyon içinde % 75-80 oraninda olmasidir.5- It is a polyetheric-based polyurethane dispersion according to any of the above claims, and it allows the formation of 3D effect by forming film layer layers on the fabric surface; The high solids type of the polyurethane dispersion makes synergy with other polymeric substances in the formulation, cures at a certain temperature and polymerizes and is 75-80% in the formulation. 6- Yukaridaki Istemlerden herhangi birine göre su bazli 3D efekti veren pasta içinde kullanilan 1500 molekül agirlikli polietilen glikol formülasyon içinde kati maddeyi destekleyen ve uzun polimer zinciri sayesinde 3D efekte destek veren malzeme olup, özelligi; formülasyon içinde % 5-10 gr arasinda olmasidir.6- It is the material that supports the solid substance in the 1500 molecular weight polyethylene glycol formulation used in the water-based 3D effect paste according to any of the above claims and supports the 3D effect thanks to its long polymer chain. It is between 5-10 g in the formulation. 7- Yukaridaki Istemlerden herhangi birine göre su bazli 3D efekti veren pasta içinde kullanilan Poliakrilik yapili mikro kürecikler olup, özelligi; formülasyon içinde kati maddeyi destekler ve baski fiksesi esnasinda genleserek, uçucu bilesenin kaybiyla olusacak olan 3D seviyesindeki düsmenin önüne geçmesi ve bulus konusu formülasyon içinde % 2-3 arasinda kullanilmasidir.7- They are polyacrylic microspheres used in a water-based 3D effect paste according to any of the above claims. It supports the solid matter in the formulation and expands during the pressure fixation, preventing the decrease in the 3D level that will occur with the loss of the volatile component and using it between 2-3% in the formulation of the invention. 8- Yukaridaki Istemlerden herhangi birine göre su bazli 3D efekti veren pasta içinde kullanilan yüzey aktif madde olup, özelligi; formülasyonda kullanilan diger bütün hammaddelerin homojen dagilimini saglamasi, boyanin çalisma ortaminda kullanimini kolaylastirmasi ve bulus konusu formülasyon içinde % 3-5 arasinda kullanilmasidir.8- It is a surfactant used in a water-based 3D effect paste according to any of the above claims, and its feature is; It provides homogeneous distribution of all other raw materials used in the formulation, facilitates the use of the paint in the working environment and is used between 3-5% in the formulation of the invention. 9- Yukaridaki Istemlerden herhangi birine göre su bazli 3D efekti veren pasta içinde kullanilan köpük kesici-hava giderici olup, özelligi; pasta üretim asamasinda ve kullanim asamasinda olusan hava kabarciklarinin bertarafini saglamasi ve bulus konusu formülasyon içinde %0.5-1 arasinda kullanilmasidir.9- It is a defoamer-air remover used in a water-based 3D effect cake according to any of the above claims, and its feature is; It ensures the removal of air bubbles formed during the cake production and usage phase and is used between 0.5-1% in the formulation subject to the invention. 10- Yukaridaki Istemlerden herhangi birine göre su bazli 3D efekti veren pasta içinde kullanilan titanyum dioksit olup, özelligi; beyaz renkli 3D efekti baskilar elde etmek için pasta üretim asamasinda kullanilmasi ve bulus konusu formülasyon içinde % 5-10 arasinda olmasidir.10- It is the titanium dioxide used in the paste that gives the water-based 3D effect according to any of the above claims, and its feature is; It is used in the cake production phase to obtain white colored 3D effect prints and it is between 5-10% in the formulation of the invention. 11- Yukaridaki Istemlerden herhangi birine göre su bazli 3D efekti veren pasta içinde kullanilan poliakrilik ester yapili kivamlastirici olup, özelligi; pastanin uygun kivamda kalmasini saglamasi ve formülasyon içinde %2 oraninda olmasidir.11- It is a polyacrylic ester made thickener used in a water-based 3D effect paste according to any of the above claims, and its feature is; It ensures that the paste remains in the appropriate consistency and is 2% in the formulation.
TR2018/11584A 2018-08-09 2018-08-09 INNOVATION IN 3D PRINTINGS USED IN TEXTILE TR201811584A2 (en)

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CN107057028A (en) * 2017-02-20 2017-08-18 深圳凯奇化工有限公司 A kind of water nano height covers 3D printing coating and preparation method thereof
CN107868441A (en) * 2017-11-24 2018-04-03 湖南新力华纳米科技有限公司 A kind of 3D printing modified aqueous polyurethane and preparation method thereof

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