SU730272A3 - Нематоцид - Google Patents
Нематоцид Download PDFInfo
- Publication number
- SU730272A3 SU730272A3 SU731957434A SU1957434A SU730272A3 SU 730272 A3 SU730272 A3 SU 730272A3 SU 731957434 A SU731957434 A SU 731957434A SU 1957434 A SU1957434 A SU 1957434A SU 730272 A3 SU730272 A3 SU 730272A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- formula
- reacting
- thionophosphorodichloridate
- bromine
- aug
- Prior art date
Links
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 230000001069 nematicidal effect Effects 0.000 abstract description 5
- 239000004480 active ingredient Substances 0.000 abstract description 3
- 125000000217 alkyl group Chemical group 0.000 abstract description 3
- 230000000361 pesticidal effect Effects 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract description 2
- 230000000749 insecticidal effect Effects 0.000 abstract description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 230000000855 fungicidal effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 1
- 241000244206 Nematoda Species 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000013543 active substance Substances 0.000 description 3
- 239000005645 nematicide Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000208822 Lactuca Species 0.000 description 2
- 235000003228 Lactuca sativa Nutrition 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 125000004969 haloethyl group Chemical group 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000243786 Meloidogyne incognita Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- -1 haloethyl phosphoric acid derivatives Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003902 lesion Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Description
(54) НЕМАТОЦИД Изобретение относитс к xtiMHMec ким средствам борьбы с нематодами, а именно, к применению галоидэтилпроизводных фосфорных кислот в качестве нематоцида. Известны галоидэтилпроизводные фосфорных кислот общей формулы ( КО). РХ СН-ССе, , II I 1 X Вг Вг где X и X - кислород или сера R - алкил, про вл ющие инсектицидную активность 1 . Известен сложный эфир 0,0-диэти -0-(1,2-дихлорэтил)-фосфорной кисл ты, обладак ций пестицидной активностью 2 , Однако при низких дозах использ вани он обладает недостаточной не матоцидной активностью. Цель изобретени - изыскание но вых нематоцидов, обладающих усилен ным нематоцидным действием. Это достигаетс применением известных галоидэтилпроизводных фосф ных кислот общей формулы S Вг Вг I I ( КО). РО СН-ССб, R - алкил С -Cj, нормального строени , в качестве нематоцида. Формы применени препаратов обыч . Соединение форму.пы Т получают бромированием соединени формулы ( RO) р-о-снгссе,(II) R имеет указанное значение, лучае необходимости в присутствии ализатора или взаимодействием соединени формуS Вг Вг || I I P-O-CH-CCCj спиртом формулы R имеет указанное значение. Были получены следующие соедине1 . (CHjO) -Р-0-СН-ССв Вг Вг К Ь5440)
S
И
(Cj,HgO)g -p-o-CH-ccej
I
Br Br
(n 1,5290)
S II (H-CflH-O) -P-O-CH-CC i
372II
Br Br
.40 I,5l2l)
S H
4,
( -P-O-CH-CCtj
Br Br
1,5089)
(
Пример , Определение предельной концентрации.
Подопытный нематод: Meloidogyne incognita растворитель: 3 вес. ч. ацетона; эмульгатор: 1 вес.ч. алкиларилполигликолевого эфира.
С целью получени 1 вес.ч. действующего вещества- его смешивают с указанным количеством растворител , добавл ют указанное количество эмульгатора и разбавл ют концентрат водой до концентрации действующего вещества , указанной в таблице.
Приготовленные действугоадне ввцества тщательно смешивают с почвой, сильно зараженной подопытными нематодами . Концентраци действующего вещества при этом не имеет значени , решающим вл етс только количество его на объемную единицу почвы, которую укаэьтают в част х на миллион. Горшки заполн ют почвой, эасеивгиот ее семенами салата и оставл ют их сто ть при температуре теплицы , По истечении 4 недель корни салата исследуют в отношении поражени их нематодами и определ ют степень эффективности действующего вещества: 100% означает, что поражение полностью исключено, 0% - поражение такое же, как при контрольных растени х в необработанной, но таким же образом зараженной почве.
В таблице приведены действующие вещества, их количества и результаты испытаний.
сГ
п
(C2H50)gP-0-CH-Cn
се се
Claims (1)
- Формула изобретенияПрименение галоидэтилпроизводных фосфорных кислот общей формулыS Вг Вг11 I I (RO)g р-о-сн-ссе^’Составите
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2241625A DE2241625A1 (de) | 1972-08-24 | 1972-08-24 | Halogenalkylthionophosphorsaeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und nematizide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU730272A3 true SU730272A3 (ru) | 1980-04-25 |
Family
ID=5854414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU731957434A SU730272A3 (ru) | 1972-08-24 | 1973-08-22 | Нематоцид |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US3845174A (ru) |
| JP (2) | JPS4955843A (ru) |
| AT (1) | AT326951B (ru) |
| AU (1) | AU474984B2 (ru) |
| BE (1) | BE803878A (ru) |
| BR (1) | BR7306508D0 (ru) |
| CA (1) | CA1014569A (ru) |
| CH (1) | CH583514A5 (ru) |
| CS (1) | CS183708B2 (ru) |
| DD (1) | DD108993A5 (ru) |
| DE (1) | DE2241625A1 (ru) |
| DK (1) | DK133006C (ru) |
| ES (2) | ES418130A1 (ru) |
| FR (1) | FR2197015B1 (ru) |
| GB (1) | GB1380385A (ru) |
| HU (1) | HU166812B (ru) |
| IE (1) | IE38127B1 (ru) |
| IL (1) | IL43038A (ru) |
| LU (1) | LU68285A1 (ru) |
| NL (1) | NL7311513A (ru) |
| PL (2) | PL90624B1 (ru) |
| RO (2) | RO64171A (ru) |
| SU (1) | SU730272A3 (ru) |
| TR (1) | TR17846A (ru) |
| ZA (1) | ZA735792B (ru) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4866045A (en) * | 1984-04-30 | 1989-09-12 | E. I. Du Pont Nemours And Company | Tetrachloroethyl phosphorothioate soil insecticide |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2140270A1 (en) * | 1971-06-07 | 1973-01-19 | Aries Robert | Organophosphorus insecticides - stabilized by styrenes |
-
1972
- 1972-08-24 DE DE2241625A patent/DE2241625A1/de active Pending
-
1973
- 1973-08-15 US US00388686A patent/US3845174A/en not_active Expired - Lifetime
- 1973-08-20 RO RO7300075845A patent/RO64171A/ro unknown
- 1973-08-20 RO RO7383640A patent/RO66312A/ro unknown
- 1973-08-20 AU AU59387/73A patent/AU474984B2/en not_active Expired
- 1973-08-21 NL NL7311513A patent/NL7311513A/xx not_active Application Discontinuation
- 1973-08-21 CH CH1202373A patent/CH583514A5/xx not_active IP Right Cessation
- 1973-08-21 TR TR17846A patent/TR17846A/xx unknown
- 1973-08-21 IL IL7343038A patent/IL43038A/en unknown
- 1973-08-22 LU LU68285A patent/LU68285A1/xx unknown
- 1973-08-22 PL PL1973175463A patent/PL90624B1/pl unknown
- 1973-08-22 JP JP48093397A patent/JPS4955843A/ja active Pending
- 1973-08-22 BE BE134808A patent/BE803878A/xx unknown
- 1973-08-22 SU SU731957434A patent/SU730272A3/ru active
- 1973-08-22 PL PL1973164790A patent/PL89381B1/pl unknown
- 1973-08-22 JP JP48093396A patent/JPS4956928A/ja active Pending
- 1973-08-23 CA CA179,538A patent/CA1014569A/en not_active Expired
- 1973-08-23 DK DK465573A patent/DK133006C/da active
- 1973-08-23 BR BR6508/73A patent/BR7306508D0/pt unknown
- 1973-08-23 HU HUBA2970A patent/HU166812B/hu unknown
- 1973-08-23 ZA ZA735792A patent/ZA735792B/xx unknown
- 1973-08-23 DD DD173057A patent/DD108993A5/xx unknown
- 1973-08-23 IE IE1476/73A patent/IE38127B1/xx unknown
- 1973-08-23 ES ES418130A patent/ES418130A1/es not_active Expired
- 1973-08-24 AT AT738373A patent/AT326951B/de not_active IP Right Cessation
- 1973-08-24 FR FR7330748A patent/FR2197015B1/fr not_active Expired
- 1973-08-24 GB GB4021073A patent/GB1380385A/en not_active Expired
- 1973-08-24 CS CS7300005936A patent/CS183708B2/cs unknown
-
1975
- 1975-12-16 ES ES443513A patent/ES443513A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| PL89381B1 (ru) | 1976-11-30 |
| JPS4955843A (ru) | 1974-05-30 |
| LU68285A1 (ru) | 1973-10-24 |
| AU5938773A (en) | 1975-02-20 |
| DE2241625A1 (de) | 1974-03-14 |
| HU166812B (ru) | 1975-06-28 |
| IL43038A0 (en) | 1973-11-28 |
| RO66312A (ro) | 1980-04-15 |
| ZA735792B (en) | 1974-07-31 |
| AT326951B (de) | 1976-01-12 |
| IE38127B1 (en) | 1978-01-04 |
| IL43038A (en) | 1976-03-31 |
| ATA738373A (de) | 1975-03-15 |
| DD108993A5 (ru) | 1974-10-12 |
| US3845174A (en) | 1974-10-29 |
| DK133006C (da) | 1976-08-30 |
| FR2197015B1 (ru) | 1977-02-25 |
| ES443513A1 (es) | 1977-05-16 |
| ES418130A1 (es) | 1976-08-01 |
| BE803878A (fr) | 1974-02-22 |
| FR2197015A1 (ru) | 1974-03-22 |
| BR7306508D0 (pt) | 1974-06-27 |
| RO64171A (fr) | 1978-09-15 |
| NL7311513A (ru) | 1974-02-26 |
| JPS4956928A (ru) | 1974-06-03 |
| DK133006B (da) | 1976-03-08 |
| CA1014569A (en) | 1977-07-26 |
| CS183708B2 (en) | 1978-07-31 |
| AU474984B2 (en) | 1976-08-05 |
| GB1380385A (en) | 1975-01-15 |
| PL90624B1 (ru) | 1977-01-31 |
| IE38127L (en) | 1974-02-24 |
| TR17846A (tr) | 1976-04-13 |
| CH583514A5 (ru) | 1977-01-14 |
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