SU433691A3 - METHOD KRA1M1SH and PRESS TZHSTYLNYL iViATEPHAJiOB - Google Patents
METHOD KRA1M1SH and PRESS TZHSTYLNYL iViATEPHAJiOBInfo
- Publication number
- SU433691A3 SU433691A3 SU1334340A SU1334340A SU433691A3 SU 433691 A3 SU433691 A3 SU 433691A3 SU 1334340 A SU1334340 A SU 1334340A SU 1334340 A SU1334340 A SU 1334340A SU 433691 A3 SU433691 A3 SU 433691A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- residue
- tzhstylnyl
- kra1m1sh
- iviatephajiob
- press
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
- C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
- C09B29/3617—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom
- C09B29/3621—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring
- C09B29/3626—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring from a pyridine ring containing one or more hydroxyl groups (or = O)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
- C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
- C09B29/3617—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom
- C09B29/3621—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring
- C09B29/3626—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring from a pyridine ring containing one or more hydroxyl groups (or = O)
- C09B29/363—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring from a pyridine ring containing one or more hydroxyl groups (or = O) from diazotized amino carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B31/00—Disazo and polyazo dyes of the type A->B->C, A->B->C->D, or the like, prepared by diazotising and coupling
- C09B31/02—Disazo dyes
- C09B31/12—Disazo dyes from other coupling components "C"
- C09B31/14—Heterocyclic components
- C09B31/153—Heterocyclic components containing a six-membered ring with one nitrogen atom as the only ring hetero-atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/40—Preparation of azo dyes from other azo compounds by substituting hetero atoms by radicals containing other hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/02—Azo dyes containing onium groups containing ammonium groups not directly attached to an azo group
- C09B44/08—Azo dyes containing onium groups containing ammonium groups not directly attached to an azo group from coupling components containing heterocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/10—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
- C09B44/103—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system characterised by the coupling component being a heterocyclic compound
- C09B44/105—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system characterised by the coupling component being a heterocyclic compound derived from pyridine, pyridone
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Pyridine Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Description
1one
Известен способ крашени и печати текстильных материалов из синтетических волокон обработкой их в красильной ванне, содержащей основной азокраситель, свободный от кислых придающих растворимость в воде групп.There is a method of dyeing and printing textile materials from synthetic fibers by treating them in a dye bath containing a basic azo dye, free from acidic and water-soluble groups.
С целью получени прочных и ровных окрасок дл крашени и печати предложено использовать основной азокраситель общей форщлыFor the purpose of obtaining durable and even stains for dyeing and printing, it was proposed to use the main azo dye of common forscilla
|тической диазосостав;1;1ющей р да бензола, нафталина, котора имеет| tic diazo composition; 1; 1 tier of benzene, naphthalene, which has
.четырехзамещеиные амине-, гидразино- или этерифицированЕше гидроксиламиногруппы , причем в качестве заместителей содержит, например , атом галогена, н.5тросульфонамид- , фенил-, фенокси-, фенилазогруппы , алкил-, галогеналкил-, алКОКСИ- , ажилоульфонплт N -алкилированкый сульфонашед или сложный алкиловый эфир карооновой кислоты .4-substituted amino, hydrazino or esterified with hydroxylamino, and substituents include, for example, a halogen atom, n. carboxylic acid alkyl ester.
1де А - остаток бензола 2 - пр iviaH св зь или мостиковыи член, например - О NR. - -СО-OGO- , -NROO- или - N ,1de A - benzene residue 2 - pr iviaH bond or bridge member, for example - O NR. - -CO-OGO-, -NROO- or - N,
где -водород или низкомолекул рный алкилостаток; У - углеродный мостик, содержащий не более 6 атомов углерода, прерванный гетероатомами или образующий частьwhere is hydrogen or a low molecular weight alkyl residue; U - carbon bridge containing not more than 6 carbon atoms, interrupted by heteroatoms or forming part
из у , Nof y, n
/г и/или /2, кольца; Ri -водород, алкил-, аралкил- или циклоалкилостаток;/ g and / or / 2 rings; Ri is hydrogen, alkyl-, aralkyl- or cycloalkyl residue;
- водород или алкил-, аралкилт циклоалкил-, алкоксиостаток или аминогруппа, в которой N с К и/или К) и/или или NC и/или могут образовывать часть гетероциклического кольца; х-анион; п, равно i или 2, или красители общей фор1« улы - hydrogen or alkyl-, aralkyl cycloalkyl-, alkoxy residue or amino group, in which N with K and / or K) and / or or NC and / or can form part of a heterocyclic ring; x-anion; n is equal to i or 2, or dyes of the general form1 "uly
| 1СНз| 1СНз
Rj-N ,аи -C(7-A-N N-,A-CMRj-N, au-C (7-A-N N-, A-CM
tfe;-.H „0tfe; -. H „0
ОНHE
где X, /г , у2 , /е , /where X, / g, y2, / e, /
а1 ют указанные значени ; киленовый мостик и А бенз дро общей форь/оглыa1 given values; kilo bridge and A benz draw for general / ogly
СНз CNCNS CN
W-y-N -RWY-N -R
--х --x
J/t-1 .,J / t-1.,
22
где у -нитро-, алкилсульфонилили замещенна в соответствующем случае сульфонамидна группа; U двухвалентный остаток, -О- или - л5 - мостик или пр ма св зь и /е , /е , / , X, у и /г.where y is a nitro, alkylsulfonyl or substituted, if appropriate, sulfonamide group; U is a divalent residue, -O- or -l5 is a bridge or a direct link and / e, / e, /, X, y and / g.
имеют указанные значени ; красители формулыhave the indicated meanings; dyes of the formula
Nr- VNr-V
«1 г "1 g
-М-у.ш-MWW
;;--1,;;--one,
(У)(Y)
в которой Wf обозначает пр 1 ю св зь или двухвалентный органический остаток, --SOg, -in which Wf stands for Pr 1y bond or a bivalent organic residue, --SOg, -
- -,-СО N - или- -, - CO N - or
СОО-мостик и X 2 3 COO-bridge and X 2 3
/1- имеют упом нутое значение, а . представл ет собой водород/ 1- have the aforementioned meaning, a. is hydrogen
или низкомолекул рный алкилостаток; красители форцулыor a low molecular weight alkyl residue; dyes fortsyly
YIYi
г-4 r-4
(1У)(IV)
(П)(P)
;;
обознав данном случаеdesignating this case
ил- или карбамилашсилгруппы; У j И Z j представл ют собой атомы водорода или галогена, алКИЛ- , алкокси-, три торметил-, нитро-, ажил-, сульфоу, арилсульфо- , ари -, арилокси-, ациламино- , ацил-, циангруппы. группы сложного карбонового эфира или замещенные в соответствующем случае остатками а;жила или арил группы амида карбоновой или суль фоновой кислоты; X обозначает ан он, а /г представл ет собой i или 2. Предложенные красители форщли I могут содер:йать в качеств гетероциклического диазосоставл ю щего гетероциклическое 5 членноё кольцо с 2 или 3 гетероатомаш, преаде всего о 1 атомом азота и 1 или 2 атоь1аш1 серы, кислорода или азота, например гетероциклическое диазосоставл ющее из р да пиридина, пиразола, иш дазола, триазола, тетразола, окоазола, тиазола, селеназола, оксдиазола, тиадиазола, пириглидина, триазина хинолина, индазола, бензимидазола , нафтшлидазола, бензоксазола, нафтодиазола или бензоселеназола, или из р да тиазола, тиадиазола или бензатиазола, которые, кроме имеющейс в соответствующем случае св занной через член мостика трет- или втор-аминогруппы, могут иметь в качестве заместител еще низкомолекул рные алкилгруппы Предложенные красители форг лы I в качестве диазосоставл ющей могут содержать остаток амина общей формулы R3-N -y-W-/,-NH2 -rt I J n-1 где fl л-. указанное значение и Aj обозначает в соответствующем случае приконденсированное ароматическое кольцо, гетероциюшческое 5- или 6-членное кольцо с 1-3 гетероатомами , из которых по меньшей мере один атом вл етс атомом азота. Причем в остатке диазосоставл ющей самое большое три отрицательных заместител . В качестве диазосоставл ющей они содер;хат остаток ам1ша, св заньшй через алкиленовый мостик ашшо-, гидразино- или этерифицированную гидроксилаглиногруппу, причег.5 в а;шиленовом мостике атом азота по меньщей мере содержит I атом водорода. Алкиленовый мостик в красителе может вл тьс разветвленным и самое большое содержать 6 атомов углерода и в соответствующем случае гетероатомы, как кислород, сера или азот. В красител х соответственно а может обозначать метилен- или этилен-мостик и Д г и И, 9 - метил-, этил- или фенилостатки или предпочтительно водород . Красители могут содержать остаток arviEHa, гидразина или этерифицированного гидроксиламина который имеет содерхсащие у атома азота атог;Ш водорода, в данном случае эфирные мостики или гидроксильные группы, имеющие самое большее 4 атог.а углерода, алифатические остатки или циклогексил-, бензил- или сренилостатки, или в которых атом азота вл етс кольцевым атомом 5- или 6-членного насыщенного или ненасыщенного кольца , которое как дальнейщии гетероатом мо ет содер;кать в данном случае атом азота, кислорода или серы и у которого моиет быть приконденсировано apo eтлчecкoe кольцо. Как анион, .они содержат остаток сильной неорганической кислоты или остаток полуэфира серной или карбоновой кислоты или -Сб, . -Вт , - У, 04. - 50з- ,Il or carbamyl groups; Y j and Z j represent hydrogen or halogen atoms, alkyl, alkoxy, three tormethyl, nitro, azhyl, sulph, arylsulfo, ari, aryloxy, acylamino, acyl, cyan groups. carboxylic ester groups or substituted as appropriate with residues a; a vein or aryl group of a carboxylic or sulfonic acid amide; X is an he, a / g is i or 2. The proposed dyes for forschli I can contain: a heterocyclic diazo compound heterocyclic 5 membered ring with 2 or 3 heteroatoms, a total of 1 nitrogen atom and 1 or 2 atoms 1 sulfur, oxygen or nitrogen, e.g. zeoselenazole, or from the range of thiazole, thiadiazole, or benzathiazole, which, in addition to the tertiary or sec-amino group linked through the bridge member, may also have low molecular weight alkyl groups as a substituent. contain an amine residue of general formula R3-N -yW - /, - NH2 -rt IJ n-1 where fl is l-. the indicated value, and Aj denotes, when appropriate, a fused aromatic ring, a heterocyclic 5 or 6 membered ring with 1 to 3 heteroatoms, of which at least one atom is a nitrogen atom. Moreover, the residue of the diazocompound is at most three negative substituents. As a diazo component, they contain an ammonium residue, connected through an alkalone, hydrazino- or esterified hydroxylagroup group through an alkylene bridge, in the case of 5 a, and a nitrogen atom contains at least one hydrogen atom. The alkylene bridge in the dye may be branched and at most contain 6 carbon atoms and in the appropriate case heteroatoms like oxygen, sulfur or nitrogen. In dyes, respectively, a may represent a methylene or ethylene bridge and D g and I, 9 - methyl, ethyl or phenyl residues or preferably hydrogen. The dyes may contain an arviEHa residue, hydrazine or an esterified hydroxylamine which has atomic nitrogen atoms; hydrogen, in this case ether bridges or hydroxyl groups having at most 4 carbon atoms, aliphatic residues or cyclohexyl, benzyl or crenyl residue; or in which the nitrogen atom is a ring atom of a 5- or 6-membered saturated or unsaturated ring which, as a further heteroatom, may contain in this case a nitrogen, oxygen or sulfur atom and which has ikondensirovano apo etlcheckoe ring. As an anion, they contain a residue of a strong inorganic acid or a residue of a half-ester of sulfuric or carboxylic acid or -Sb,. -W, - Y, 04. - 50z-,
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH811368A CH557857A (en) | 1968-05-31 | 1968-05-31 | PROCESS FOR THE PREPARATION OF BASIC AZO DYES. |
Publications (1)
Publication Number | Publication Date |
---|---|
SU433691A3 true SU433691A3 (en) | 1974-06-25 |
Family
ID=4335369
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU1334340A SU433691A3 (en) | 1968-05-31 | 1969-05-28 | METHOD KRA1M1SH and PRESS TZHSTYLNYL iViATEPHAJiOB |
Country Status (8)
Country | Link |
---|---|
BE (1) | BE733834A (en) |
BR (1) | BR6909385D0 (en) |
CH (2) | CH557857A (en) |
DE (1) | DE1927213A1 (en) |
FR (1) | FR2014146A1 (en) |
GB (1) | GB1277090A (en) |
NL (1) | NL6908284A (en) |
SU (1) | SU433691A3 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2085505B1 (en) * | 1970-04-28 | 1973-07-13 | Ugine Kuhlmann | |
US3966706A (en) * | 1971-01-27 | 1976-06-29 | Ciba-Geigy Ag | 2,6-Dihydroxy-3-cyano-4-methylpyridine containing azo dyes which contain a functional amino group |
DE2222099A1 (en) * | 1972-05-05 | 1973-11-22 | Hoechst Ag | BASIC AZO DYES, THEIR PRODUCTION AND USE |
DE2721955A1 (en) * | 1977-05-14 | 1978-11-23 | Basf Ag | AZO DYES |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1489492A (en) * | 1965-08-13 | 1967-07-21 | Cassella Farbwerke Mainkur Ag | New Water Insoluble Azo Dyes and Their Preparation |
-
1968
- 1968-05-31 CH CH811368A patent/CH557857A/en not_active IP Right Cessation
-
1969
- 1969-05-22 FR FR6916780A patent/FR2014146A1/fr not_active Withdrawn
- 1969-05-28 SU SU1334340A patent/SU433691A3/en active
- 1969-05-29 DE DE19691927213 patent/DE1927213A1/en active Pending
- 1969-05-30 NL NL6908284A patent/NL6908284A/xx unknown
- 1969-05-30 BR BR20938569A patent/BR6909385D0/en unknown
- 1969-05-30 BE BE733834D patent/BE733834A/xx unknown
- 1969-05-30 GB GB2744469A patent/GB1277090A/en not_active Expired
-
1973
- 1973-10-23 CH CH1093173A patent/CH594030A5/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CH557857A (en) | 1975-01-15 |
DE1927213A1 (en) | 1969-12-04 |
NL6908284A (en) | 1969-12-02 |
BE733834A (en) | 1969-12-01 |
BR6909385D0 (en) | 1973-04-17 |
GB1277090A (en) | 1972-06-07 |
FR2014146A1 (en) | 1970-04-17 |
CH594030A5 (en) | 1977-12-30 |
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