SU324820A1 - Abrasive material elbor - Google Patents

Abrasive material elbor

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Publication number
SU324820A1
SU324820A1 SU1476053A SU1476053A SU324820A1 SU 324820 A1 SU324820 A1 SU 324820A1 SU 1476053 A SU1476053 A SU 1476053A SU 1476053 A SU1476053 A SU 1476053A SU 324820 A1 SU324820 A1 SU 324820A1
Authority
SU
USSR - Soviet Union
Prior art keywords
boron nitride
elbor
abrasive
nitrides
abrasive material
Prior art date
Application number
SU1476053A
Other languages
Russian (ru)
Inventor
М.А. Варзанов
В.А. Рыбаков
Н.Е. Филоненко
В.Г. Кондаков
Л.И. Фельдгун
В.А. Пономаренко
В.В. Дигонский
В.М. Давиденко
М.И. Сохор
В.С. Павлов
Ю.М. Ковальчук
В.С. Лысанов
М.Г. Эфрос
Г.О. Гомон
В.Б. Лощинин
Original Assignee
Всесоюзный Научно-Исследовательский Институт Абразивов И Шлифования
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Всесоюзный Научно-Исследовательский Институт Абразивов И Шлифования filed Critical Всесоюзный Научно-Исследовательский Институт Абразивов И Шлифования
Priority to SU1476053A priority Critical patent/SU324820A1/en
Priority to CH462771A priority patent/CH559146A5/xx
Priority to PL1971147294A priority patent/PL76371B1/pl
Priority to DE2116020A priority patent/DE2116020C3/en
Priority to ZA712251A priority patent/ZA712251B/en
Priority to HUVE650A priority patent/HU163062B/hu
Priority to BG17314A priority patent/BG17855A1/xx
Priority to CS7100002809A priority patent/CS184855B1/en
Priority to GB2625971*A priority patent/GB1335909A/en
Priority to SE7105624A priority patent/SE372495B/xx
Priority to FR7122869A priority patent/FR2098009A5/fr
Priority to DD156229A priority patent/DD98271A1/xx
Priority to DD165860A priority patent/DD99527A1/xx
Application granted granted Critical
Publication of SU324820A1 publication Critical patent/SU324820A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/58Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
    • C04B35/583Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride
    • C04B35/5831Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride based on cubic boron nitrides or Wurtzitic boron nitrides, including crystal structure transformation of powder
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/06Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron
    • C01B21/064Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with boron

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Ceramic Products (AREA)

Description

Известен абразивный материал - боразон, представл ющий собой кубический нитрид бора в сочетании с нитридами металлов - катализаторов, образурощихс  в процессе синтеза в качестве побочных фаз. Однако боразон тер ет свою прочность при выдержке на воздухе, в воде и в кислотах в результате гидролиза побочных фаз - нитридов металловкатализаторов , вследствие чего не может быть использован в абразивном инструменте.A known abrasive material is borazon, which is a cubic boron nitride in combination with metal nitrides - catalysts, which are formed during synthesis as side phases. However, borazon loses its strength when exposed to air, in water and in acids as a result of hydrolysis of side phases - metal catalysts nitrides, as a result of which it cannot be used in an abrasive tool.

Не вс кий нитрид бора алмазоподобной структуры может примен тьс  дл  изготовлени  абразивного инстру-мента. Непригоден дл  этих целей, например, вгорцитный нитрид бора, цолучаемый в результате ударного воздействи  на гексагональный нитрид бора, вследствие высокой дисперсности получаемого продукта (2-3 мк и менее). Размер зерна нитрида бора  вл етс  не единственной причиной , ограничивающей его применение в абразивиом инструменте. В процессе синтеза кубического нитрида бора нар ду с последним образуютс  и некоторые побочные вещества , располагающиес  в поликристаллическом зерне В-BN по границам срастани  его монокристаллов, прежде всего нитриды и бориды металла-катализатора.Not all boron nitride of diamond-like structure can be used to make abrasive tools. It is unsuitable for these purposes, for example, boron nitride, produced as a result of impact on hexagonal boron nitride, due to the high dispersion of the obtained product (2-3 microns or less). Boron nitride grain size is not the only reason limiting its use in abrasive tools. In the process of the synthesis of cubic boron nitride, along with the latter, some side substances are formed, which are located in the polycrystalline grain B-BN along the fusion boundaries of its single crystals, primarily nitrides and borides of the metal catalyst.

действию атмосферной влаги и компонентов св зок, примен емых дл  изготовлени  абразивного инструмента, то нитриды металловкатализаторов активно гидролизуютс  влагой воздуха уже при обычных температурах. Доступ компонентов св зок к нитриду металлакатализатора , расположенному но границам монокристаллов в поликристаллическом нитриде бора, и их химическое взаимодействие возрастают с увеличением температуры при обжиге абразивных изделий, в результате чего разрушаетс  зерно кубического нитрида бора и само абразивное изделие.to the action of atmospheric moisture and binder components used for the manufacture of an abrasive tool, the nitrides of the metal catalysts are actively hydrolyzed by the moisture of air already at normal temperatures. The access of the binder components to the metal-catalytic nitride located on the edges of single crystals in polycrystalline boron nitride and their chemical interaction increases with increasing temperature during the firing of abrasive products, as a result of which the cubic boron nitride grain and the abrasive product itself are destroyed.

Дл  обеспечени  сохранности абразивных свойств и устойчивости во влажных средах предлагаетс  новый сверхтвердый абразивный материал-эльбор. Он имеет поликристаллическое строенне и содержит 90-96% кубического нитрида бора, 0,5-0,1% гексагонального нитрнда бора и 3,5-9,0% негидролизуемых побочных фаз. Нобочиые фазы представл ют собой негидролизуемые бориды и нитриды металлов I, II групп периодической системы и переходных металлов, а также бор. Эльбор, благодар  указанному фазовому составу, не гндролизуетс  влагой воздуха ,  вл етс  устойчивым при выдержке в воде и кислотах, что обусловливает его высокую механическою прочность и абразивнуюTo ensure the safety of abrasive properties and stability in wet environments, a new superhard abrasive material elbor is proposed. It has a polycrystalline structure and contains 90-96% of cubic boron nitride, 0.5-0.1% of hexagonal boron nitride, and 3.5-9.0% of non-hydrolysable side phases. The nobium phases are non-hydrolysable borides and nitrides of metals of the I, II groups of the periodic system and transition metals, as well as boron. Elbor, due to the specified phase composition, is not hydrolyzed by air moisture, is stable when exposed to water and acids, which makes it highly mechanical and abrasive.

способность вплоть до температур 1000- 1300°С.capacity up to temperatures of 1000–1300 ° C.

Пример. Шлифпорошок эльбора зернистостью -125+100 мкм, содержащий 93,4% кубического нитрида бора, 0,8% гексагонального «итрида бора и 5,8% гексаборида магни , имеюш,ий механическую прочность на раздавливание 420 г, выдерживают во влажном воздухе в течение 30 суток. Механическа  прочность после выдержки во влажном воздухе 410 г. Боразон, испытанный в аналогичных услови х, тер ет механическую прочность на 50,%.Example. Elbor grinding powder with a grain size of -125 + 100 μm, containing 93.4% of cubic boron nitride, 0.8% hexagonal boron itridide and 5.8% magnesium hexaboride, having a mechanical crush strength of 420 g, is kept in moist air for 30 days. Mechanical strength after exposure to moist air of 410 g. Borazon, tested under similar conditions, loses mechanical strength by 50%.

Абразивный материал - эльбор широко примен етс  в точном машиностроении, приборостроении и других отрасл х науки и техники при шлифовании, доводке заточки высокотвердых легированных конструкционных сталей.Abrasive material - elbor is widely used in precision engineering, instrument making and other fields of science and technology in grinding, fine-tuning sharpening of high-hard alloyed structural steels.

Claims (3)

1.Абразивный материал - эльбор на основе кубического нитрида бора, гексагонального1. Abrasive material - elbor based on cubic boron nitride, hexagonal нитрида бора, отличаюш,ийс  тем, что, с целью обеспечени  сохранности абразивных свойств и устойчивости во влажных средах, материал содержит не менее 90% кубического нитрида бора, не более 1% гексагонального нитрида бора, не более 9% негидролизуемых боридов и нитридов, а также бора.boron nitride is different because in order to ensure the safety of abrasive properties and stability in wet environments, the material contains not less than 90% of cubic boron nitride, not more than 1% of hexagonal boron nitride, not more than 9% of non-hydrolysable borides and nitrides, and also boron. 2.Материал по п. 1, отличающийс  тем, что содержание лоликристаллических агрегатов зернистого строени  составл ет не2. The material according to claim 1, characterized in that the content of the lycrystalline aggregates of the granular structure is not мепее80%.mepe80%. 3.Материал по пп. 1 и 2, отличающийс  тем, что бориды и нитриды образованы металлами I, II групп, а также переходными металлами.3.Material on PP. 1 and 2, characterized in that the borides and nitrides are formed by metals of groups I and II, as well as transition metals.
SU1476053A 1970-10-12 1970-10-12 Abrasive material elbor SU324820A1 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
SU1476053A SU324820A1 (en) 1970-10-12 1970-10-12 Abrasive material elbor
CH462771A CH559146A5 (en) 1970-10-12 1971-03-31
PL1971147294A PL76371B1 (en) 1970-10-12 1971-04-01
DE2116020A DE2116020C3 (en) 1970-10-12 1971-04-01 Cubic Boron Nitride-Based Abrasives and Process for their Manufacture ''
ZA712251A ZA712251B (en) 1970-10-12 1971-04-07 Method of producing cubic boron nitride and abrasive material based thereon
HUVE650A HU163062B (en) 1970-10-12 1971-04-09
BG17314A BG17855A1 (en) 1970-10-12 1971-04-10
CS7100002809A CS184855B1 (en) 1970-10-12 1971-04-19 Grinding agent based on isometric boron nitride and method for making the same
GB2625971*A GB1335909A (en) 1970-10-12 1971-04-19 Method of producing cubic boron nitride and abrasive material based thereon
SE7105624A SE372495B (en) 1970-10-12 1971-04-30
FR7122869A FR2098009A5 (en) 1970-10-12 1971-06-23
DD156229A DD98271A1 (en) 1970-10-12 1971-07-02
DD165860A DD99527A1 (en) 1970-10-12 1971-07-04

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1476053A SU324820A1 (en) 1970-10-12 1970-10-12 Abrasive material elbor

Publications (1)

Publication Number Publication Date
SU324820A1 true SU324820A1 (en) 1976-07-05

Family

ID=20457382

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1476053A SU324820A1 (en) 1970-10-12 1970-10-12 Abrasive material elbor

Country Status (12)

Country Link
BG (1) BG17855A1 (en)
CH (1) CH559146A5 (en)
CS (1) CS184855B1 (en)
DD (2) DD98271A1 (en)
DE (1) DE2116020C3 (en)
FR (1) FR2098009A5 (en)
GB (1) GB1335909A (en)
HU (1) HU163062B (en)
PL (1) PL76371B1 (en)
SE (1) SE372495B (en)
SU (1) SU324820A1 (en)
ZA (1) ZA712251B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE805525A (en) * 1972-10-02 1974-04-01 Vnii Abrazivov EXTRA-HARD COMPOSITE MATERIAL BASED ON CUBIC BORON NITRIDE AND PROCESS FOR OBTAINING THIS MATERIAL
DE2702082C3 (en) * 1976-01-30 1982-02-25 Institut fizičeskoj chimii Akademii Nauk SSSR, Moskva Polycrystalline Superhard Cubic Boron Nitride Material and Process for Its Manufacture
DE3030362C2 (en) * 1980-08-11 1986-11-27 Institut sverchtverdych materialov Akademii Nauk Ukrainskoj SSR, Kiew/Kiev Process for the production of cubic boron nitride
FR2495597A1 (en) * 1980-08-26 1982-06-11 Inst Sverkhtverdykh Mat Cubic boron nitride of larger particle size - produced by addition of salt having water of crystallisation to the initial charge contg. the hexagonal form and initiator
US4349517A (en) * 1980-10-21 1982-09-14 Lysanov Vladislav S Method of producing cubic boron nitride
CN117925074B (en) * 2024-03-25 2024-05-17 南京盛凯新材料有限公司 High-wear-resistance UV matte coating and preparation process thereof

Also Published As

Publication number Publication date
CH559146A5 (en) 1975-02-28
ZA712251B (en) 1972-06-28
PL76371B1 (en) 1975-02-28
DE2116020C3 (en) 1979-02-01
SE372495B (en) 1974-12-23
DE2116020A1 (en) 1972-04-13
HU163062B (en) 1973-05-28
CS184855B1 (en) 1978-09-15
GB1335909A (en) 1973-10-31
DD99527A1 (en) 1973-08-20
DD98271A1 (en) 1973-06-12
DE2116020B2 (en) 1976-02-26
FR2098009A5 (en) 1972-03-03
BG17855A1 (en) 1974-03-05

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