SU1167498A1 - Stationary phase for gas chromatography - Google Patents

Stationary phase for gas chromatography Download PDF

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Publication number
SU1167498A1
SU1167498A1 SU823377845A SU3377845A SU1167498A1 SU 1167498 A1 SU1167498 A1 SU 1167498A1 SU 823377845 A SU823377845 A SU 823377845A SU 3377845 A SU3377845 A SU 3377845A SU 1167498 A1 SU1167498 A1 SU 1167498A1
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USSR - Soviet Union
Prior art keywords
stationary phase
gas chromatography
phase
separation
butylamine
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SU823377845A
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Russian (ru)
Inventor
Анатолий Викторович Ардатов
Алла Марковна Вигдергауз
Вячеслав Федорович Новиков
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Казанский Ордена Трудового Красного Знамени Химико-Технологический Институт Им.С.М.Кирова
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Abstract

Применение окиси фенилUse of phenyl oxide

Description

ч.h

Изобретение относитс  к неподвижным фазам, используемым в газовор хроматографии дл  разделени  смесей органических веществ, и может быть использовано в различных област х техники, где примен етс  газохроматографический анализ.The invention relates to stationary phases used in a gas chromatography chromatography for the separation of mixtures of organic substances, and can be used in various fields of technology where gas chromatography analysis is used.

Целью изобретени   вл етс  нова  неподвижна  фаза, обладающа  высокой селективностью разделени  органических смесей, состо щих из нитропарафинов и аминов.The aim of the invention is a new stationary phase with a high selectivity of the separation of organic mixtures consisting of nitroparaffins and amines.

Существо изобретени  состоит в использовании в качестве неподвижной фазы дл  газовой хроматографии окиси фенил(2-цианэтил-2-диэтиламино)фосфина формулыThe essence of the invention consists in using as the stationary phase for gas chromatography oxides of phenyl (2-cyanoethyl-2-diethylamino) phosphine of the formula

ОABOUT

dgHs-P-clHz-clHH-clNdgHs-P-clHz-clHH-clN

К(СгНб).K (CrNb).

Ранее указанное вещество использовали как полупродукт дл  синтеза негорючих полимерных материалов,The previously mentioned substance was used as an intermediate for the synthesis of non-combustible polymeric materials.

Дл  предлагаемой неподвижной фазы разность факторов пол рности, равна  4,15 между нитрометаном (6,02) и пиридином (1,87), значительно выше, чем у паиболе селективной к указан4982For the proposed stationary phase, the difference in polarity factors, equal to 4.15 between nitromethane (6.02) and pyridine (1.87), is significantly higher than that of the paibole selective to indicated

ной задаче разделени  известной фазы 1,2,3-трис-( -1и1анэтокси)пропана (2,13). Такое различие в разности факторов пол рности позвол ет раздел ть на предлагаемой фазе смеси, которые не раздел ютс  на известных фазах. Кроме того, при высокой селективности предлагаемой фазы на ней меньше врем  удерживани  компонентов , что уменьшает врем  анализа.Noah the problem of separation of the known phase 1,2,3-tris- (-1i1etoxy) propane (2,13). Such a difference in the difference in polarity factors allows the mixture to be divided in the proposed phase, which are not separated in the known phases. In addition, with a high selectivity of the proposed phase, the retention time of the components on it is less, which reduces the analysis time.

Пример. Разделению подвергалась смесь трет-бутиламина, втор-бутиламина , нитрометана и бутиламина на колонке длиной 2 м,заполненной 10% 1, 2,3-трис(/з-цианэтокси)пропана , и колонке с 10% предлагаемой фазы на Хроматоне фракции 0,25 0 ,31 мм при скорости газа-носител  Example. Separation was subjected to a mixture of tert-butylamine, sec-butylamine, nitromethane and butylamine on a 2 m column filled with 10% 1, 2,3-tris (/ 3-cyanethoxy) propane, and a column with 10% of the proposed phase on Chromatone fraction 0 25 0, 31 mm at speed of carrier gas

35 ют/мин и температуре колонок 120С.35 sp / min and column temperature 120C.

Как видно из приведенных на чертеже хроматограмм, на предлагаемой фазе (б) достигнуто полное разделение всех компонентов, в то врем As can be seen from the chromatograms in the drawing, in the proposed phase (b), a complete separation of all components is achieved, while

как на известной (а) втор.бутиламин (2) и нитрометан (3) разделены неполностью . Пики (1) и (4) на хроматограммах - соответственно трет.бутштамин и бутиламин.as on known (a) sec. butylamine (2) and nitromethane (3) are not completely separated. Peaks (1) and (4) on the chromatograms are tert.butstamine and butylamine respectively.

Claims (2)

Применение окиси фенил(2-цианэтил-2-диэтилами.но)фосфина формулыThe use of phenyl oxide (2-cyanoethyl-2-diethylamino. But) phosphine of the formula оabout с5н5-р-сн2-ен2-скwith 5 N 5 -p-CH2-en2-ck Й(СгН5)2 Y (C g N 5 ) 2 в качестве неподвижной фазы для гаэохроматографическоТо разделения нитропарафинов от аминов.as a stationary phase for gaeochromatographic separation of nitroparaffins from amines. □_I_I 1 „1_□ _I_I 1 „1_ 0 5 10 15 200 5 10 15 20 бремя(мин)burden (min) мm сх>cx мm 4*four* СОWITH 0000 >> 1one 11674981167498 22
SU823377845A 1982-01-07 1982-01-07 Stationary phase for gas chromatography SU1167498A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU823377845A SU1167498A1 (en) 1982-01-07 1982-01-07 Stationary phase for gas chromatography

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU823377845A SU1167498A1 (en) 1982-01-07 1982-01-07 Stationary phase for gas chromatography

Publications (1)

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SU1167498A1 true SU1167498A1 (en) 1985-07-15

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SU823377845A SU1167498A1 (en) 1982-01-07 1982-01-07 Stationary phase for gas chromatography

Country Status (1)

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SU (1) SU1167498A1 (en)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
1. Авторское свидетельство СССР № 332738, кл. С 07 F 9/53, 1970. 2. Коцев Н. Справочник по газовой хроматографии. М.: Мир, 1976, с.190, *

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