SK12562000A3 - SILNO REDUKOVANí OXIDA¬Ní KATALYZµTOR A JEHO POU¦ITIE NA KATALíZU REAKCIÖ V KVAPALNEJ FµZE - Google Patents

SILNO REDUKOVANí OXIDA¬Ní KATALYZµTOR A JEHO POU¦ITIE NA KATALíZU REAKCIÖ V KVAPALNEJ FµZE Download PDF

Info

Publication number: SK12562000A3
Authority: SK; Slovakia
Prior art keywords: catalyst; carbon; noble metal; promoter; oxygen
Prior art date: 1998-02-25

Application number

SK1256-2000A

Other languages

English (en)

Slovak (sk)

Inventor

Jerry R. Ebner

Mark A. Leiber

Kam-To Wan

Anthony Woods

Peter E. Rogers

Original Assignee

Monsanto Company

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-02-25

Filing date

1999-02-17

Publication date

2001-09-11

1999-02-17 Application filed by Monsanto Company filed Critical Monsanto Company

2001-09-11 Publication of SK12562000A3 publication Critical patent/SK12562000A3/sk

Links

239000003054 catalyst Substances 0.000 title claims abstract description 584
238000007254 oxidation reaction Methods 0.000 title claims abstract description 275
230000003647 oxidation Effects 0.000 title claims abstract description 247
230000002829 reductive effect Effects 0.000 title claims description 48
239000007791 liquid phase Substances 0.000 title abstract description 20
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 524
229910052799 carbon Inorganic materials 0.000 claims abstract description 418
238000000034 method Methods 0.000 claims abstract description 361
229910000510 noble metal Inorganic materials 0.000 claims abstract description 315
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 137
230000008569 process Effects 0.000 claims abstract description 118
230000001590 oxidative effect Effects 0.000 claims abstract description 86
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims abstract description 77
150000003839 salts Chemical class 0.000 claims abstract description 48
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 46
239000000376 reactant Substances 0.000 claims abstract description 28
235000019253 formic acid Nutrition 0.000 claims abstract description 23
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 22
FDQQNNZKEJIHMS-UHFFFAOYSA-N 3,4,5-trimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1C FDQQNNZKEJIHMS-UHFFFAOYSA-N 0.000 claims abstract description 13
238000002360 preparation method Methods 0.000 claims abstract description 10
230000002378 acidificating effect Effects 0.000 claims abstract description 5
229910052760 oxygen Inorganic materials 0.000 claims description 183
239000001301 oxygen Substances 0.000 claims description 175
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 174
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 173
125000004429 atom Chemical group 0.000 claims description 104
125000004430 oxygen atom Chemical group O* 0.000 claims description 90
229910052742 iron Inorganic materials 0.000 claims description 83
238000010438 heat treatment Methods 0.000 claims description 82
229910052739 hydrogen Inorganic materials 0.000 claims description 79
238000000151 deposition Methods 0.000 claims description 75
239000000243 solution Substances 0.000 claims description 73
239000012298 atmosphere Substances 0.000 claims description 64
229910052718 tin Inorganic materials 0.000 claims description 64
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 62
239000000725 suspension Substances 0.000 claims description 61
238000004833 X-ray photoelectron spectroscopy Methods 0.000 claims description 54
239000001257 hydrogen Substances 0.000 claims description 51
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 49
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 49
229910002091 carbon monoxide Inorganic materials 0.000 claims description 49
239000007789 gas Substances 0.000 claims description 48
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 47
125000004432 carbon atom Chemical group C* 0.000 claims description 42
239000000203 mixture Substances 0.000 claims description 41
229910052751 metal Inorganic materials 0.000 claims description 40
239000002184 metal Substances 0.000 claims description 40
239000010970 precious metal Substances 0.000 claims description 40
239000010936 titanium Substances 0.000 claims description 36
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 34
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 33
239000007800 oxidant agent Substances 0.000 claims description 33
229910052719 titanium Inorganic materials 0.000 claims description 33
239000010439 graphite Substances 0.000 claims description 32
229910002804 graphite Inorganic materials 0.000 claims description 32
239000002344 surface layer Substances 0.000 claims description 28
229910052797 bismuth Inorganic materials 0.000 claims description 22
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 22
229910052734 helium Inorganic materials 0.000 claims description 22
239000001307 helium Substances 0.000 claims description 22
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 22
238000004519 manufacturing process Methods 0.000 claims description 22
229910021529 ammonia Inorganic materials 0.000 claims description 21
229910052757 nitrogen Inorganic materials 0.000 claims description 20
239000000969 carrier Substances 0.000 claims description 19
239000003638 chemical reducing agent Substances 0.000 claims description 19
230000008021 deposition Effects 0.000 claims description 19
239000011777 magnesium Substances 0.000 claims description 18
229910052759 nickel Inorganic materials 0.000 claims description 17
239000011669 selenium Substances 0.000 claims description 17
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 16
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 16
229910052782 aluminium Inorganic materials 0.000 claims description 16
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
229910052787 antimony Inorganic materials 0.000 claims description 16
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 16
229910052793 cadmium Inorganic materials 0.000 claims description 16
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 16
229910017052 cobalt Inorganic materials 0.000 claims description 16
239000010941 cobalt Substances 0.000 claims description 16
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 16
229910052749 magnesium Inorganic materials 0.000 claims description 16
229910052702 rhenium Inorganic materials 0.000 claims description 16
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 16
229910052711 selenium Inorganic materials 0.000 claims description 16
229910052684 Cerium Inorganic materials 0.000 claims description 15
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 15
-1 ammonium ions Chemical class 0.000 claims description 13
239000003153 chemical reaction reagent Substances 0.000 claims description 9
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 7
229910052756 noble gas Inorganic materials 0.000 claims description 6
239000002243 precursor Substances 0.000 claims description 5
238000001465 metallisation Methods 0.000 claims description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 15
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 15
229910052726 zirconium Inorganic materials 0.000 claims 15
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 14
229910052725 zinc Inorganic materials 0.000 claims 14
239000011701 zinc Substances 0.000 claims 14
UFNRFBFHJJPDNF-UHFFFAOYSA-N [Zn].[Ce] Chemical compound [Zn].[Ce] UFNRFBFHJJPDNF-UHFFFAOYSA-N 0.000 claims 1
238000001420 photoelectron spectroscopy Methods 0.000 claims 1
AZIHIQIVLANVKD-UHFFFAOYSA-N N-(phosphonomethyl)iminodiacetic acid Chemical compound OC(=O)CN(CC(O)=O)CP(O)(O)=O AZIHIQIVLANVKD-UHFFFAOYSA-N 0.000 abstract description 86
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 55
239000000047 product Substances 0.000 abstract description 43
238000002386 leaching Methods 0.000 abstract description 32
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 28
239000005562 Glyphosate Substances 0.000 abstract description 17
229940097068 glyphosate Drugs 0.000 abstract description 17
239000006227 byproduct Substances 0.000 abstract description 14
239000001569 carbon dioxide Substances 0.000 abstract description 14
229910002092 carbon dioxide Inorganic materials 0.000 abstract description 14
239000002904 solvent Substances 0.000 abstract description 11
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 abstract description 10
239000000543 intermediate Substances 0.000 abstract description 8
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 187
229910052697 platinum Inorganic materials 0.000 description 72
238000006243 chemical reaction Methods 0.000 description 50
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 46
230000000694 effects Effects 0.000 description 45
238000006722 reduction reaction Methods 0.000 description 42
230000009467 reduction Effects 0.000 description 41
239000002245 particle Substances 0.000 description 35
239000002923 metal particle Substances 0.000 description 32
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 29
229910052786 argon Inorganic materials 0.000 description 28
239000011135 tin Substances 0.000 description 27
229910045601 alloy Inorganic materials 0.000 description 26
239000000956 alloy Substances 0.000 description 26
125000000524 functional group Chemical group 0.000 description 23
239000000523 sample Substances 0.000 description 21
238000011282 treatment Methods 0.000 description 21
238000006392 deoxygenation reaction Methods 0.000 description 20
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 16
238000002474 experimental method Methods 0.000 description 16
239000012071 phase Substances 0.000 description 15
239000011148 porous material Substances 0.000 description 13
238000003756 stirring Methods 0.000 description 13
150000001875 compounds Chemical class 0.000 description 11
230000007423 decrease Effects 0.000 description 11
MGRVRXRGTBOSHW-UHFFFAOYSA-N (aminomethyl)phosphonic acid Chemical compound NCP(O)(O)=O MGRVRXRGTBOSHW-UHFFFAOYSA-N 0.000 description 9
230000009849 deactivation Effects 0.000 description 9
239000011541 reaction mixture Substances 0.000 description 9
239000000706 filtrate Substances 0.000 description 8
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
230000008901 benefit Effects 0.000 description 7
238000003795 desorption Methods 0.000 description 7
238000000197 pyrolysis Methods 0.000 description 7
230000035484 reaction time Effects 0.000 description 7
238000005406 washing Methods 0.000 description 7
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 6
238000004458 analytical method Methods 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
238000006555 catalytic reaction Methods 0.000 description 6
150000004985 diamines Chemical group 0.000 description 6
229910001882 dioxygen Inorganic materials 0.000 description 6
238000001493 electron microscopy Methods 0.000 description 6
238000007248 oxidative elimination reaction Methods 0.000 description 6
229910052763 palladium Inorganic materials 0.000 description 6
238000010926 purge Methods 0.000 description 6
238000005245 sintering Methods 0.000 description 6
238000001179 sorption measurement Methods 0.000 description 6
238000001035 drying Methods 0.000 description 5
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239000012808 vapor phase Substances 0.000 description 5
241000196324 Embryophyta Species 0.000 description 4
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
150000001299 aldehydes Chemical class 0.000 description 4
239000011248 coating agent Substances 0.000 description 4
238000000576 coating method Methods 0.000 description 4
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238000006460 hydrolysis reaction Methods 0.000 description 4
238000005470 impregnation Methods 0.000 description 4
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229910017604 nitric acid Inorganic materials 0.000 description 4
239000007787 solid Substances 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
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NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 3
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MYWUZJCMWCOHBA-UHFFFAOYSA-N n-methyl-1-phenylpropan-2-amine Chemical compound CNC(C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-UHFFFAOYSA-N 0.000 description 3
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LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
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VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
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HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
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125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
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DFYULHRIYLAUJM-UHFFFAOYSA-N 3,4-diiodobenzoic acid Chemical compound OC(=O)C1=CC=C(I)C(I)=C1 DFYULHRIYLAUJM-UHFFFAOYSA-N 0.000 description 1
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229910002703 Al K Inorganic materials 0.000 description 1
238000004438 BET method Methods 0.000 description 1
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RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
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AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
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230000010718 Oxidation Activity Effects 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
101150003085 Pdcl gene Proteins 0.000 description 1
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239000004280 Sodium formate Substances 0.000 description 1
238000003917 TEM image Methods 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
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238000005411 Van der Waals force Methods 0.000 description 1
DSVGQVZAZSZEEX-UHFFFAOYSA-N [C].[Pt] Chemical compound [C].[Pt] DSVGQVZAZSZEEX-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000009471 action Effects 0.000 description 1
239000002156 adsorbate Substances 0.000 description 1
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150000001408 amides Chemical class 0.000 description 1
BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 1
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238000004873 anchoring Methods 0.000 description 1
238000013459 approach Methods 0.000 description 1
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238000012512 characterization method Methods 0.000 description 1
238000005234 chemical deposition Methods 0.000 description 1
150000005829 chemical entities Chemical class 0.000 description 1
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239000003795 chemical substances by application Substances 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
239000003245 coal Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000013068 control sample Substances 0.000 description 1
125000000058 cyclopentadienyl group Chemical class C1(=CC=CC1)* 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000002950 deficient Effects 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical class ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
229940120503 dihydroxyacetone Drugs 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000004070 electrodeposition Methods 0.000 description 1
238000007772 electroless plating Methods 0.000 description 1
238000009713 electroplating Methods 0.000 description 1
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000004880 explosion Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
239000008098 formaldehyde solution Substances 0.000 description 1
ZGFPIGGZMWGPPW-UHFFFAOYSA-N formaldehyde;formic acid Chemical compound O=C.OC=O ZGFPIGGZMWGPPW-UHFFFAOYSA-N 0.000 description 1
239000003574 free electron Substances 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000008187 granular material Substances 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
230000001678 irradiating effect Effects 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000003077 lignite Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
229910001092 metal group alloy Inorganic materials 0.000 description 1
229910052987 metal hydride Inorganic materials 0.000 description 1
150000004681 metal hydrides Chemical class 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000001000 micrograph Methods 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
239000001272 nitrous oxide Substances 0.000 description 1
239000005519 non-carbonaceous material Substances 0.000 description 1
229910052755 nonmetal Inorganic materials 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
239000003415 peat Substances 0.000 description 1
230000035515 penetration Effects 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
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150000003057 platinum Chemical class 0.000 description 1
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229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
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230000003389 potentiating effect Effects 0.000 description 1
239000012694 precious metal precursor Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
238000004393 prognosis Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000003223 protective agent Substances 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000007420 reactivation Effects 0.000 description 1
238000002407 reforming Methods 0.000 description 1
230000004044 response Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000010454 slate Substances 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
235000019254 sodium formate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000000758 substrate Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
238000005211 surface analysis Methods 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 1
238000001771 vacuum deposition Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1
238000004876 x-ray fluorescence Methods 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

SK1256-2000A 1998-02-25 1999-02-17 SILNO REDUKOVANí OXIDA¬Ní KATALYZµTOR A JEHO POU¦ITIE NA KATALíZU REAKCIÖ V KVAPALNEJ FµZE SK12562000A3 (sk)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US7598898P	1998-02-25	1998-02-25
US09/248,655 US6417133B1 (en)	1998-02-25	1999-02-11	Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
PCT/US1999/003402 WO1999043430A1 (fr)	1998-02-25	1999-02-17	Catalyseur d'oxydation fortement reduit et son utilisation pour catalyser des reactions d'oxydation en phase liquide

Publications (1)

Publication Number	Publication Date
SK12562000A3 true SK12562000A3 (sk)	2001-09-11

Family

ID=26757505

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1256-2000A SK12562000A3 (sk)	1998-02-25	1999-02-17	SILNO REDUKOVANí OXIDA¬Ní KATALYZµTOR A JEHO POU¦ITIE NA KATALíZU REAKCIÖ V KVAPALNEJ FµZE

Country Status (20)

Country	Link
US (4)	US6417133B1 (fr)
EP (1)	EP1060017A1 (fr)
JP (1)	JP2002504427A (fr)
KR (1)	KR20010041349A (fr)
CN (2)	CN1962673B (fr)
AR (3)	AR013023A1 (fr)
AU (1)	AU761345B2 (fr)
BR (2)	BR9917783B1 (fr)
CA (2)	CA2321923C (fr)
CZ (1)	CZ20003020A3 (fr)
EA (1)	EA200000869A1 (fr)
HU (1)	HUP0101891A3 (fr)
ID (1)	ID26942A (fr)
IL (1)	IL138081A0 (fr)
MX (2)	MX264644B (fr)
PL (1)	PL342499A1 (fr)
SK (1)	SK12562000A3 (fr)
TR (1)	TR200002459T2 (fr)
WO (1)	WO1999043430A1 (fr)
ZA (1)	ZA991496B (fr)

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US7312174B2 (en) *	2002-09-09	2007-12-25	The Board Of Trustees Of The University Of Illinois	Method for preparing highly loaded, highly dispersed platinum metal on a carbon substrate
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US20040192546A1 (en) *	2003-03-27	2004-09-30	Zhongyuan Dang	Catalyst for the low temperature oxidation of methane
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CN101583425A (zh) *	2005-02-17	2009-11-18	孟山都技术公司	含过渡金属的催化剂、包含含过渡金属的催化剂的催化剂组合物、它们的制备方法和作为氧化催化剂的用途
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- 1999-02-17 BR BRPI9908252-7A patent/BRPI9908252B1/pt active IP Right Grant
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Also Published As

Publication number	Publication date
CN1298322A (zh)	2001-06-06
WO1999043430A1 (fr)	1999-09-02
ID26942A (id)	2001-02-22
WO1999043430A9 (fr)	2000-01-27
PL342499A1 (en)	2001-06-04
AU761345B2 (en)	2003-06-05
US8143441B2 (en)	2012-03-27
CA2321923C (fr)	2008-05-06
US20070100161A1 (en)	2007-05-03
CA2610653A1 (fr)	1999-09-02
KR20010041349A (ko)	2001-05-15
EA200000869A1 (ru)	2001-04-23
CN1279048C (zh)	2006-10-11
BRPI9908252B1 (pt)	2018-11-21
AR043018A2 (es)	2005-07-13
AR013023A1 (es)	2000-11-22
EP1060017A1 (fr)	2000-12-20
JP2002504427A (ja)	2002-02-12
HUP0101891A2 (hu)	2001-09-28
IL138081A0 (en)	2001-10-31
US6603039B1 (en)	2003-08-05
CA2321923A1 (fr)	1999-09-02
BR9917783B1 (pt)	2011-05-31
WO1999043430B1 (fr)	1999-11-04
TR200002459T2 (tr)	2001-09-21
HUP0101891A3 (en)	2002-03-28
MX264644B (es)	2009-02-18
AR069820A2 (es)	2010-02-24
ZA991496B (en)	2000-11-24
CN1962673B (zh)	2012-05-02
CN1962673A (zh)	2007-05-16
WO1999043430A8 (fr)	1999-12-02
CA2610653C (fr)	2012-05-29
AU2770799A (en)	1999-09-15
BR9908252A (pt)	2000-10-24
US7067693B1 (en)	2006-06-27
CZ20003020A3 (cs)	2001-07-11
US6417133B1 (en)	2002-07-09
MX270262B (es)	2009-09-22

Publication	Publication Date	Title
SK12562000A3 (sk)	2001-09-11	SILNO REDUKOVANí OXIDA¬Ní KATALYZµTOR A JEHO POU¦ITIE NA KATALíZU REAKCIÖ V KVAPALNEJ FµZE
EP1242433B1 (fr)	2004-06-02	Utilisation d'un promoteur supplementaire conjointement a un catalyseur contenant un metal noble sur support de carbone dans des reactions d'oxydation en phase liquide
US8703639B2 (en)	2014-04-22	Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
MXPA00008441A (en)	2001-07-09	Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
CA2476255C (fr)	2012-07-31	Catalyseur d'oxydation, son procede de preparation et procede d'oxydation l'utilisant
AU2003203448B2 (en)	2006-05-18	Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions