SG152125A1 - Aromatic isomerization catalyst - Google Patents
Aromatic isomerization catalystInfo
- Publication number
- SG152125A1 SG152125A1 SG200806391-9A SG2008063919A SG152125A1 SG 152125 A1 SG152125 A1 SG 152125A1 SG 2008063919 A SG2008063919 A SG 2008063919A SG 152125 A1 SG152125 A1 SG 152125A1
- Authority
- SG
- Singapore
- Prior art keywords
- catalyst
- weight
- alumina
- isomerization catalyst
- aromatic isomerization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 125000003118 aryl group Chemical group 0.000 title abstract 2
- 238000006317 isomerization reaction Methods 0.000 title abstract 2
- 239000011148 porous material Substances 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7469—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/74—Noble metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/868,844 US20090093662A1 (en) | 2007-10-08 | 2007-10-08 | Aromatic isomerization catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
SG152125A1 true SG152125A1 (en) | 2009-05-29 |
Family
ID=40229806
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG200806391-9A SG152125A1 (en) | 2007-10-08 | 2008-08-29 | Aromatic isomerization catalyst |
Country Status (11)
Country | Link |
---|---|
US (1) | US20090093662A1 (ja) |
EP (1) | EP2047906B1 (ja) |
JP (1) | JP5123810B2 (ja) |
KR (1) | KR101061961B1 (ja) |
CN (1) | CN101690897B (ja) |
BR (1) | BRPI0804106A2 (ja) |
MX (1) | MX2008011764A (ja) |
PT (1) | PT2047906E (ja) |
RU (1) | RU2406568C2 (ja) |
SG (1) | SG152125A1 (ja) |
TW (1) | TWI377983B (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090093662A1 (en) | 2007-10-08 | 2009-04-09 | Whitchurch Patrick C | Aromatic isomerization catalyst |
US9309170B2 (en) * | 2011-11-14 | 2016-04-12 | Uop Llc | Aromatics isomerization using a dual-catalyst system |
FR2984180A1 (fr) * | 2011-12-20 | 2013-06-21 | IFP Energies Nouvelles | Procede de fabrication de particules spheroidales d'alumine |
FR2999955B1 (fr) * | 2012-12-20 | 2015-11-13 | IFP Energies Nouvelles | Catalyseur modifie de type structural mtw, sa methode de preparation et son utilisation dans un procede d'isomerisation d'une coupe c8 aromatique |
US20140296601A1 (en) * | 2013-03-29 | 2014-10-02 | Uop Llc | Isomerization process with mtw catalyst |
ITMI20131704A1 (it) | 2013-10-15 | 2015-04-16 | Versalis Spa | Composizione catalitica e processo che la utilizza per l'alchilazione di idrocarburi aromatici con alcoli, o miscele di alcoli e olefine |
US9890094B2 (en) * | 2015-03-03 | 2018-02-13 | Uop Llc | High meso-surface area and high acid site density pentasil zeolite for use in xylene conversion |
CN112295592A (zh) * | 2019-07-26 | 2021-02-02 | 中国石油化工股份有限公司 | 一种烷基芳烃异构化催化剂及制备和应用 |
FR3104458B1 (fr) | 2019-12-17 | 2022-01-07 | Ifp Energies Now | Catalyseur a base de zeolithe izm-2 ayant une teneur en alcalin faible et son utilisation pour l’isomerisation de la coupe c8 aromatique |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2108863C1 (ru) * | 1996-05-20 | 1998-04-20 | Открытое акционерное общество НПП "Нефтехим" | Катализатор изомеризации парафиновых углеводородов |
US6413898B1 (en) * | 1999-12-28 | 2002-07-02 | Corning Incorporated | Zeolite/alumina catalyst support compositions and method of making the same |
WO2004087315A1 (de) * | 2003-04-01 | 2004-10-14 | Süd-Chemie AG | Synthetischer zeolith, insbesondere für die katalytische hydroisomerisierung von höheren paraffinen |
RU2005133011A (ru) * | 2005-10-26 | 2007-05-10 | ГОУ ВПО Иркутский государственный университет (RU) | Катализатор изомеризации парафиновых углеводородов |
Family Cites Families (49)
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NL76445C (ja) | 1950-03-08 | |||
US3201491A (en) | 1962-09-05 | 1965-08-17 | Universal Oil Prod Co | Continuous sorption process with emphasis on product purity |
US3832449A (en) | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
CA1139731A (en) * | 1979-01-15 | 1983-01-18 | Mae K. Rubin | Zsm-12 composition method of preparing same and catalytic conversion therewith |
US4452769A (en) | 1979-03-21 | 1984-06-05 | Mobil Oil Corporation | Method of preparing crystalline zeolite |
US4537758A (en) | 1979-03-21 | 1985-08-27 | Mobil Oil Corporation | Process for preparing highly siliceous porous ZSM-12 type crystalline material |
JPS55129232A (en) * | 1979-03-29 | 1980-10-06 | Teijin Yuka Kk | Isomerization of xylenes |
US4224141A (en) * | 1979-05-21 | 1980-09-23 | Mobil Oil Corporation | Manufacture of aromatic compounds |
US4385195A (en) * | 1980-04-14 | 1983-05-24 | Mobil Oil Corporation | Aromatics processing |
US4300011A (en) * | 1980-04-28 | 1981-11-10 | Mobil Oil Corporation | Selective production of aromatics |
US4413156A (en) * | 1982-04-26 | 1983-11-01 | Texaco Inc. | Manufacture of synthetic lubricant additives from low molecular weight olefins using boron trifluoride catalysts |
US4441990A (en) * | 1982-05-28 | 1984-04-10 | Mobil Oil Corporation | Hollow shaped catalytic extrudates |
US4557919A (en) * | 1983-04-12 | 1985-12-10 | Teijin Petrochemical Industries Ltd. | Production of crystalline zeolites |
US4694114A (en) * | 1984-01-11 | 1987-09-15 | Mobil Oil Corporation | Process for isomerizing alkyl aromatic hydrocarbons utilizing ZSM-23 zeolite and a hydrogenation/dehydrogenation metal |
US4626609A (en) * | 1984-01-23 | 1986-12-02 | Mobil Oil Corporation | Aromatic compound conversion |
US4665253A (en) * | 1984-06-13 | 1987-05-12 | Mobil Oil Corporation | Conversion of aromatics over novel catalyst composition |
JPS63156733A (ja) * | 1986-12-19 | 1988-06-29 | Teijin Yuka Kk | キシレンの異性化方法 |
US4700012A (en) * | 1986-12-30 | 1987-10-13 | Teijin Petrochemical Industries, Ltd. | Process for isomerizing xylene |
US4749819A (en) * | 1987-03-27 | 1988-06-07 | Shell Oil Company | Terminal to interior double bond isomerization process for an olefinic molecule |
US4727203A (en) * | 1987-04-13 | 1988-02-23 | Shell Oil Company | Terminal to interior double bond isomerization process for an olefinic molecule with reduced dimerization |
US4861740A (en) * | 1987-06-10 | 1989-08-29 | Uop | Magnesium-exchanged zeolitic catalyst for isomerization of alkylaromatics |
US4874731A (en) * | 1987-10-13 | 1989-10-17 | Uop | Catalyst for the isomerization of aromatics |
US5081084A (en) * | 1987-10-16 | 1992-01-14 | Uop | Catalyst for isomerizing alkylaromatics |
US4899012A (en) * | 1988-10-17 | 1990-02-06 | Uop | Catalyst for the isomerization of aromatics |
US5177287A (en) * | 1989-03-29 | 1993-01-05 | Teijin Petrochemical Industries, Ltd. | Catalyst composition, process for cracking non-aromatic hydrocarbons and process for isomerizing C8 aromatic hydrocarbons |
US5081286A (en) * | 1989-04-11 | 1992-01-14 | Shell Oil Company | Process for the preparation of an alkyl methacrylate |
US5082984A (en) * | 1990-01-29 | 1992-01-21 | Mobil Oil Corp. | Dual function catalyst and isomerization therewith |
US5235120A (en) * | 1991-11-21 | 1993-08-10 | Uop | Selective isoparaffin synthesis from naphtha |
US5198097A (en) * | 1991-11-21 | 1993-03-30 | Uop | Reformulated-gasoline production |
US5401388A (en) * | 1991-11-21 | 1995-03-28 | Uop | Selective upgrading of naphtha |
EP0762936A1 (en) * | 1994-06-03 | 1997-03-19 | Akzo Nobel N.V. | Hydrocracking catalyst comprising coated craking component particles |
US5628978A (en) * | 1994-12-23 | 1997-05-13 | Intevep, S.A. | MTW zeolite for cracking feedstock into olefins and isoparaffins |
EP0923987A1 (fr) * | 1997-12-22 | 1999-06-23 | Institut Français du Pétrole | Catalyseur contenant une zéolithe EUO et son utilisation en isomérisation des composés C8 aromatiques |
US6075175A (en) * | 1998-09-29 | 2000-06-13 | Exxon Chemical Patents, Inc. | Isomerization of olefins |
DE19845293A1 (de) * | 1998-10-01 | 2000-04-06 | Basf Ag | Herstellung eines basischen Katalysators unter Vermeidung hoher Temperaturen |
US6787023B1 (en) * | 1999-05-20 | 2004-09-07 | Exxonmobil Chemical Patents Inc. | Metal-containing macrostructures of porous inorganic oxide, preparation thereof, and use |
US7084087B2 (en) * | 1999-09-07 | 2006-08-01 | Abb Lummus Global Inc. | Zeolite composite, method for making and catalytic application thereof |
US6926882B2 (en) * | 2000-01-05 | 2005-08-09 | Exxonmobil Chemical Patents Inc. | Porous inorganic macrostructure materials and process for their preparation |
US6652832B2 (en) | 2001-02-05 | 2003-11-25 | Exxonmobil Oil Corporation | Synthesis of ZSM-12 |
US6893624B2 (en) * | 2002-11-15 | 2005-05-17 | Exxonmobil Chemical Patents Inc. | High activity small crystal ZSM-12 |
US6740788B1 (en) * | 2002-12-19 | 2004-05-25 | Uop Llc | Integrated process for aromatics production |
US6872866B1 (en) * | 2003-12-15 | 2005-03-29 | Uop Llc | Liquid phase process for C8 alkylaromatic isomerization |
US20050143614A1 (en) * | 2003-12-30 | 2005-06-30 | Leon-Escamilla E. A. | Process and catalyst for C8 alkylaromatic isomerization |
CN100512954C (zh) * | 2003-12-30 | 2009-07-15 | 环球油品公司 | 用于c8烷基芳烃异构化的方法和催化剂 |
US20050143615A1 (en) * | 2003-12-30 | 2005-06-30 | Bogdan Paula L. | Process and bimetallic catalyst for C8 alkylaromatic isomerization |
US7368620B2 (en) * | 2005-06-30 | 2008-05-06 | Uop Llc | Two-stage aromatics isomerization process |
WO2007050745A1 (en) * | 2005-10-28 | 2007-05-03 | Shell Internationale Research Maatschappij B.V. | Internal olefins process |
US20090093662A1 (en) | 2007-10-08 | 2009-04-09 | Whitchurch Patrick C | Aromatic isomerization catalyst |
US7629283B2 (en) | 2007-10-08 | 2009-12-08 | Uop Llc | Aromatic isomerization catalyst and isomerization process |
-
2007
- 2007-10-08 US US11/868,844 patent/US20090093662A1/en not_active Abandoned
-
2008
- 2008-08-29 SG SG200806391-9A patent/SG152125A1/en unknown
- 2008-09-05 TW TW097134262A patent/TWI377983B/zh not_active IP Right Cessation
- 2008-09-12 MX MX2008011764A patent/MX2008011764A/es active IP Right Grant
- 2008-09-18 BR BRPI0804106-7A patent/BRPI0804106A2/pt not_active IP Right Cessation
- 2008-09-23 EP EP08253097.3A patent/EP2047906B1/en active Active
- 2008-09-23 PT PT82530973T patent/PT2047906E/pt unknown
- 2008-10-06 KR KR1020080097831A patent/KR101061961B1/ko active IP Right Grant
- 2008-10-07 RU RU2008139864/04A patent/RU2406568C2/ru active
- 2008-10-07 CN CN2008101684351A patent/CN101690897B/zh active Active
- 2008-10-07 JP JP2008260592A patent/JP5123810B2/ja not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2108863C1 (ru) * | 1996-05-20 | 1998-04-20 | Открытое акционерное общество НПП "Нефтехим" | Катализатор изомеризации парафиновых углеводородов |
US6413898B1 (en) * | 1999-12-28 | 2002-07-02 | Corning Incorporated | Zeolite/alumina catalyst support compositions and method of making the same |
WO2004087315A1 (de) * | 2003-04-01 | 2004-10-14 | Süd-Chemie AG | Synthetischer zeolith, insbesondere für die katalytische hydroisomerisierung von höheren paraffinen |
RU2005133011A (ru) * | 2005-10-26 | 2007-05-10 | ГОУ ВПО Иркутский государственный университет (RU) | Катализатор изомеризации парафиновых углеводородов |
Also Published As
Publication number | Publication date |
---|---|
CN101690897A (zh) | 2010-04-07 |
RU2406568C2 (ru) | 2010-12-20 |
EP2047906A1 (en) | 2009-04-15 |
RU2008139864A (ru) | 2010-04-20 |
PT2047906E (pt) | 2015-11-23 |
TWI377983B (en) | 2012-12-01 |
TW200920485A (en) | 2009-05-16 |
US20090093662A1 (en) | 2009-04-09 |
CN101690897B (zh) | 2012-12-12 |
EP2047906B1 (en) | 2015-08-26 |
KR20090036076A (ko) | 2009-04-13 |
JP2009090285A (ja) | 2009-04-30 |
KR101061961B1 (ko) | 2011-09-05 |
MX2008011764A (es) | 2009-05-11 |
JP5123810B2 (ja) | 2013-01-23 |
BRPI0804106A2 (pt) | 2009-10-20 |
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