SG11202107811PA - A bimetallic nanoparticle-based catalyst, its use in selective hydrogenation, and a method of making the catalyst - Google Patents

A bimetallic nanoparticle-based catalyst, its use in selective hydrogenation, and a method of making the catalyst

Info

Publication number
SG11202107811PA
SG11202107811PA SG11202107811PA SG11202107811PA SG11202107811PA SG 11202107811P A SG11202107811P A SG 11202107811PA SG 11202107811P A SG11202107811P A SG 11202107811PA SG 11202107811P A SG11202107811P A SG 11202107811PA SG 11202107811P A SG11202107811P A SG 11202107811PA
Authority
SG
Singapore
Prior art keywords
catalyst
making
selective hydrogenation
bimetallic nanoparticle
based catalyst
Prior art date
Application number
SG11202107811PA
Inventor
Tobias Herzfeld
Andreas Klemt
Sven Scholz
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of SG11202107811PA publication Critical patent/SG11202107811PA/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/23—
    • B01J35/30—
    • B01J35/397—
    • B01J35/40—
    • B01J35/45—
    • B01J35/51—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05—Metallic powder characterised by the size or surface area of the particles
    • B22F1/054—Nanosized particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/17—Metallic particles coated with metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/02—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
    • B22F7/04—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers with one or more layers not made from powder, e.g. made from solid metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/16—Making metallic powder or suspensions thereof using chemical processes
    • B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
    • B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/04—Making non-ferrous alloys by powder metallurgy
    • C22C1/0466—Alloys based on noble metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C5/00—Alloys based on noble metals
    • C22C5/04—Alloys based on a platinum group metal
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C5/00—Alloys based on noble metals
    • C22C5/06—Alloys based on silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • B22F7/062—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools involving the connection or repairing of preformed parts
    • B22F2007/066—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools involving the connection or repairing of preformed parts using impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
SG11202107811PA 2019-01-17 2020-01-15 A bimetallic nanoparticle-based catalyst, its use in selective hydrogenation, and a method of making the catalyst SG11202107811PA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962793561P 2019-01-17 2019-01-17
PCT/US2020/013682 WO2020150354A1 (en) 2019-01-17 2020-01-15 A bimetallic nanoparticle-based catalyst, its use in selective hydrogenation, and a method of making the catalyst

Publications (1)

Publication Number Publication Date
SG11202107811PA true SG11202107811PA (en) 2021-08-30

Family

ID=69630614

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202107811PA SG11202107811PA (en) 2019-01-17 2020-01-15 A bimetallic nanoparticle-based catalyst, its use in selective hydrogenation, and a method of making the catalyst

Country Status (10)

Country Link
US (1) US11478780B2 (en)
EP (1) EP3911436A1 (en)
JP (1) JP2022517812A (en)
KR (1) KR20210116500A (en)
CN (1) CN113365729A (en)
BR (1) BR112021014097A2 (en)
CA (1) CA3126803A1 (en)
SG (1) SG11202107811PA (en)
TW (1) TW202027855A (en)
WO (1) WO2020150354A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11813594B2 (en) * 2021-01-11 2023-11-14 Purdue Research Foundation Heterogeneous catalysts for substrate-directed hydrogenation and methods of producing such catalysts
CN114471540B (en) * 2022-02-22 2023-08-08 北京化工大学 Sub-nanometer Pt selective hydrogenation catalyst, preparation method and application thereof

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA610337A (en) 1960-12-13 The Dow Chemical Company Catalyst and method of preparation thereof for selective hydrogenation of acetylene in ethylene
GB686574A (en) 1949-11-05 1953-01-28 Du Pont Improvements in production of hydrogen peroxide and catalyst therefor
US2802889A (en) 1954-06-01 1957-08-13 Dow Chemical Co Selective hydrogenation of acetylene in ethylene and catalyst therefor
US2857337A (en) 1955-05-10 1958-10-21 Du Pont Method of preparing hydrogenation catalysts
DE1171901B (en) 1958-07-15 1964-06-11 Girdler Suedchemie Katalysator Process for the removal of acetylenes and diolefins from hydrocarbon gases or their mixtures by selective hydrogenation
US3243387A (en) 1963-04-25 1966-03-29 Leuna Werke Veb Palladium-silver-iron oxide on alphaalumina catalyst composition for the selective hydrogenation of acetylene
NL129408C (en) 1965-03-18
DE2531770C3 (en) 1975-07-16 1979-04-26 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Process for applying a catalytically active coating to a catalyst carrier
JPS54157507A (en) 1978-06-02 1979-12-12 Mitsubishi Chem Ind Ltd Selective hydrogenation of acetylene compound
DE3064972D1 (en) 1979-11-20 1983-10-27 Ici Plc Hydrogenation catalyst material, a precursor thereto, method of making the latter and use of the catalyst for selective hydrogenation
US4484015A (en) 1981-05-06 1984-11-20 Phillips Petroleum Company Selective hydrogenation
JPS5817835A (en) 1981-07-23 1983-02-02 Mitsubishi Chem Ind Ltd Catalyst for selective hydrogenation
US4762956A (en) 1983-04-13 1988-08-09 Beijing Research Institute Of Chemical Industry He Ping Li Novel catalyst and process for hydrogenation of unsaturated hydrocarbons
DE3543640A1 (en) 1985-12-11 1987-06-19 Bayer Ag Process for the catalytic decomposition of dinitrogen monoxide in pure form or contained in mixtures of gases
FR2603578B1 (en) 1986-09-10 1989-02-17 Inst Francais Du Petrole PROCESS FOR SELECTIVE HYDROGENATION OF PHENYL-ACETYLENE IN A STYRENE-RICH CUT
EP0686615B2 (en) 1994-06-09 2007-06-27 Institut Francais Du Petrole Process for the catalytic hydrogenation and catalyst useable in this process
US5488024A (en) 1994-07-01 1996-01-30 Phillips Petroleum Company Selective acetylene hydrogenation
DE4443701C1 (en) * 1994-12-08 1996-08-29 Degussa Shell catalyst, process for its production and its use
US5583274A (en) 1995-01-20 1996-12-10 Phillips Petroleum Company Alkyne hydrogenation process
DE69720235T2 (en) 1996-09-11 2004-02-12 Süd-Chemie Catalysts Japan, Inc. CATALYST FOR SELECTIVE HYDROGENATION OF MULTIPLE UNSATURATED HYDROCARBON IN AN OLEFINE COMPOUND
KR100229236B1 (en) 1996-12-30 1999-11-01 이정국 A catalyst for selective hydrogenation of acetylene and its preparation method
DE19734974A1 (en) * 1997-08-13 1999-02-25 Hoechst Ag Production of supported catalyst for vinyl acetate production
FR2770520B1 (en) 1997-10-31 1999-12-10 Inst Francais Du Petrole PROCESS FOR SELECTIVE HYDROGENATION OF UNSATURATED COMPOUNDS
DE19840373A1 (en) 1998-09-04 2000-03-09 Basf Ag Catalyst and process for the selective hydrogenation of unsaturated compounds in hydrocarbon streams
KR20000059743A (en) 1999-03-08 2000-10-05 이정국 Hydrogenation catalyst for selectively converting a triple bonded, conjugated double bonded or allene-type hydrocarbon and method of preparing the same
US6417136B2 (en) 1999-09-17 2002-07-09 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
US6465391B1 (en) 2000-08-22 2002-10-15 Phillips Petroleum Company Selective hydrogenation catalyst and processes therefor and therewith
US6797669B2 (en) 2000-12-29 2004-09-28 China Petroleum & Chemical Corporation Catalyst for selective hydrogenation, its preparation process and application
CN1145687C (en) 2000-12-29 2004-04-14 中国石油化工股份有限公司 Selective hydrogenation catalyst carrier and its prepn and use
US6572673B2 (en) 2001-06-08 2003-06-03 Chang Chun Petrochemical Co., Ltd. Process for preparing noble metal nanoparticles
US20030134744A1 (en) 2001-12-19 2003-07-17 Sud-Chemie Inc. Process for production and distribution of a prereduced selective hydrogenation catalyst
MXPA05008643A (en) 2003-03-26 2005-10-18 Basf Ag Palladium-based catalyst for selective hydrogenation of acetylene.
CN1290613C (en) 2003-11-26 2006-12-20 蔡万煜 Preparation method for charcoal loading noble metal nanometer crystal hydrogenation catalyst and platinum charcoal catalyst produced by the method
US7199076B2 (en) 2003-12-19 2007-04-03 Chevron Phillips Chemical Company Lp Methods of making and using a selective hydrogenation catalyst
US7301062B2 (en) 2004-07-27 2007-11-27 Abb Lummus Global Inc. Process for the selective hydrogenation of alkynes and/or dienes in an olefin-containing hydrocarbon stream
US7521393B2 (en) 2004-07-27 2009-04-21 Süd-Chemie Inc Selective hydrogenation catalyst designed for raw gas feed streams
DE102004059282A1 (en) 2004-10-13 2006-04-27 Basf Ag selective hydrogenation catalyst
EP1710222A3 (en) 2005-04-06 2006-10-25 Saudi Basic Industries Corporation Method for selective hydrogenation of acetylene to ethylene
SG164387A1 (en) 2005-07-27 2010-09-29 Chevron Phillips Chemical Co A selective hydrogenation catalyst and methods of making and using same
FR2893262A1 (en) * 2005-11-14 2007-05-18 Inst Francais Du Petrole PROCESS FOR SYNTHESIS IN THE PRESENCE OF CATALYST REDUCER BASED ON ANISOTROPIC METAL NANOPARTICLES.
US7317154B2 (en) 2006-01-31 2008-01-08 Pioneer Hi-Bred International, Inc. Hybrid maize plant and seed 31P41
US7744675B2 (en) 2006-11-08 2010-06-29 Shell Oil Company Gas separation membrane comprising a substrate with a layer of coated inorganic oxide particles and an overlayer of a gas-selective material, and its manufacture and use
FR2914200B1 (en) * 2007-03-30 2009-11-27 Inst Francais Du Petrole PROCESS FOR THE SYNTHESIS OF CUBIC METAL NANOPARTICLES IN THE PRESENCE OF TWO REDUCERS
EP2082805A1 (en) * 2008-01-28 2009-07-29 Basf Se Process for the preparation of an aqueous colloidal precious metal suspension
WO2009140694A2 (en) * 2008-05-16 2009-11-19 Verutek Technologies, Inc. Green synthesis of nanometals using plant extracts and use thereof
EP2547443B1 (en) 2010-03-19 2022-04-06 Shell Internationale Research Maatschappij B.V. Hydrogenation catalyst
US9283545B2 (en) * 2011-02-14 2016-03-15 Rutgers, The State University Of New Jersey Efficient and recyclable heterogeneous nanocatalysts
EP2858752A1 (en) 2012-06-11 2015-04-15 Reliance Industries Limited A catalyst composition and a process for selective hydrogenation of methyl acetylene and propadiene
EP2983850A1 (en) * 2013-04-12 2016-02-17 Board of Regents, The University of Texas System Synthesis of bimetallic nanoparticle catalysts using microwave irradiation
US10543536B2 (en) * 2013-06-07 2020-01-28 Lg Chem, Ltd. Method for fabricating metal nanoparticles
FI125920B (en) 2013-09-09 2016-04-15 Beneq Oy Method of coating substrates
US20150314269A1 (en) * 2014-05-01 2015-11-05 The Research Foundation For The State University Of New York Plasmonically active nanocomposites with a bimodal nanoparticle size distribution
KR101768275B1 (en) * 2014-08-14 2017-08-14 주식회사 엘지화학 Method for fabricating metal nano particles
US10016751B2 (en) * 2014-09-15 2018-07-10 University Of South Carolina Supported, bimetallic nanoparticles for selective catalysis
US9878306B2 (en) * 2014-09-19 2018-01-30 Georgia Tech Research Corporation Silver nanowires, methods of making silver nanowires, core-shell nanostructures, methods of making core-shell nanostructures, core-frame nanostructures, methods of making core-frame nanostructures
EP3271071A1 (en) * 2015-03-20 2018-01-24 BASF Corporation Pt and/or pd egg-shell catalyst and use thereof
KR20170081299A (en) * 2015-11-11 2017-07-11 사빅 글로벌 테크놀러지스 비.브이. Multifunctional and stable nano-architectures containing nanocarbon and nano- or micro structures and a calcined hydrotalcite shell
WO2017172763A1 (en) * 2016-03-28 2017-10-05 Kansas State University Research Foundation Synthesis and application of chiral substituted polyvinylpyrrolidinones
FR3059253B1 (en) 2016-11-29 2020-01-17 IFP Energies Nouvelles SELECTIVE HYDROGENATION CATALYST OF A C3 HYDROCARBON CUT.

Also Published As

Publication number Publication date
TW202027855A (en) 2020-08-01
US11478780B2 (en) 2022-10-25
KR20210116500A (en) 2021-09-27
US20200230580A1 (en) 2020-07-23
CA3126803A1 (en) 2020-07-23
EP3911436A1 (en) 2021-11-24
WO2020150354A1 (en) 2020-07-23
BR112021014097A2 (en) 2021-09-21
JP2022517812A (en) 2022-03-10
CN113365729A (en) 2021-09-07

Similar Documents

Publication Publication Date Title
SG10201912299WA (en) Hydrogenation catalyst, its production and application thereof
SG10201609346WA (en) Hydrocracking catalyst, preparation method and use thereof, and method for hydrocracking catalytic diesel oil
GB2563128B (en) Selective catalytic reduction catalyst composition
GB2584368B (en) A chromium catalyst, its preparation and use
GB201911860D0 (en) Catalytic cracking catalyst and preparation method therefor
PT3625379T (en) Nickel electrode, method for the production thereof, and use thereof
EP3733288A4 (en) Hydrogenation reaction catalyst and preparation method therefor
EP3778021A4 (en) Hydrorefining catalyst, preparation method therefor and use thereof
GB2578208B (en) Bimetallic Cu/Mn Catalysts for selective catalytic reduction
SG11202107811PA (en) A bimetallic nanoparticle-based catalyst, its use in selective hydrogenation, and a method of making the catalyst
EP3504978A4 (en) Lactase-containing double microcapsule, preparation method therefor, and use thereof
SG11202007127QA (en) Bioink composition for dermis regeneration sheet, method for manufacturing customized dermis regeneration sheet using same, and customized dermis regeneration sheet manufactured using manufacturing method
EP3272577A4 (en) Seat core material, seat portion, and seat
EP3690075A4 (en) Ferritic stainless steel having excellent high-temperature oxidation resistance, and manufacturing method therefor
EP4079981A4 (en) Faucet-controlling device and method, and faucet
SG10201509955WA (en) Method for Preparing Noble Metal Hydrogenation Catalyst, Noble Metal Hydrogenation Catalyst and Use thereof
GB2561084B (en) Selective catalytic reduction catalyst
SG10202007253YA (en) Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method
SG11202103593VA (en) Selective hydrogenation methods and catalysts
FI20185940A (en) Catalyst for dehydrogenation, method for preparing the catalyst and use
EP3833472A4 (en) Catalysts, preparation method thereof, and selective hydrogenation processes
EP3530353A4 (en) Metal catalyst support, manufacturing method and apparatus therefor
EP4279067A4 (en) Nanocomplex, preparation method therefor, and use thereof
EP4127177A4 (en) Catalysts, preparation method thereof, and selective hydrogenation processes
EP3831817A4 (en) Epoxyalkane production method and solid oxidation catalyst