SG11202009693XA - Hydrofining catalyst, its preparation and application thereof - Google Patents

Hydrofining catalyst, its preparation and application thereof

Info

Publication number
SG11202009693XA
SG11202009693XA SG11202009693XA SG11202009693XA SG11202009693XA SG 11202009693X A SG11202009693X A SG 11202009693XA SG 11202009693X A SG11202009693X A SG 11202009693XA SG 11202009693X A SG11202009693X A SG 11202009693XA SG 11202009693X A SG11202009693X A SG 11202009693XA
Authority
SG
Singapore
Prior art keywords
preparation
application
hydrofining catalyst
hydrofining
catalyst
Prior art date
Application number
SG11202009693XA
Inventor
Wenbin Chen
Le Zhang
Xiangyun Long
Hong Nie
Mingfeng Li
Dadong Li
Qinghe Liu
Xueyan Ju
Original Assignee
China Petroleum & Chem Corp
Research Institute Of Petroleum Processing Sinopec
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum & Chem Corp, Research Institute Of Petroleum Processing Sinopec filed Critical China Petroleum & Chem Corp
Publication of SG11202009693XA publication Critical patent/SG11202009693XA/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1074—Vacuum distillates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
SG11202009693XA 2018-04-10 2019-04-09 Hydrofining catalyst, its preparation and application thereof SG11202009693XA (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN201810317848 2018-04-10
CN201810316695 2018-04-10
CN201810317849 2018-04-10
CN201810317845 2018-04-10
PCT/CN2019/081915 WO2019196836A1 (en) 2018-04-10 2019-04-09 Hydrorefining catalyst, preparation method therefor and use thereof

Publications (1)

Publication Number Publication Date
SG11202009693XA true SG11202009693XA (en) 2020-10-29

Family

ID=68162800

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202009693XA SG11202009693XA (en) 2018-04-10 2019-04-09 Hydrofining catalyst, its preparation and application thereof

Country Status (5)

Country Link
US (1) US11439989B2 (en)
EP (1) EP3778021A4 (en)
SG (1) SG11202009693XA (en)
TW (1) TWI802675B (en)
WO (1) WO2019196836A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114433058B (en) * 2020-10-31 2023-11-07 中国石油化工股份有限公司 Liquid phase hydrogenation catalyst composition
CN113042057B (en) * 2021-02-10 2023-06-23 中国海洋石油集团有限公司 Catalyst for hydrogenation of carbon four-superimposed product and preparation method thereof
CN115368213A (en) * 2021-05-18 2022-11-22 中国石油化工股份有限公司 Crude glycol hydrofining agent and preparation method and application thereof
CN115501873B (en) * 2021-06-23 2024-01-05 中国石油化工股份有限公司 Catalyst, preparation method and application thereof, and method for selectively hydrogenating and removing olefin from mixed aromatic hydrocarbon
CN115501741B (en) * 2022-08-30 2023-11-03 四川轻化工大学 High-activity ferric oxide desulfurizing agent based on modified carrier, and preparation method and application thereof

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2848376A (en) 1953-08-17 1958-08-19 Basf Ag Two-stage hydrogenation process for the production of gasoline from hydrocarbon oils
FR1287439A (en) 1961-01-30 1962-03-16 Exxon Research Engineering Co Improvement of hydrorefining catalysts
GB2101005B (en) 1981-06-02 1984-09-05 Asia Oil Co Ltd Hydrogenation catalyst
CN1039477C (en) 1992-11-24 1998-08-12 中国石油化工总公司 Method for preparing macropore alumina supporter
CN1055877C (en) 1996-03-26 2000-08-30 中国石油化工总公司抚顺石油化工研究院 Large-pore alumina carrier and its preparation process
CN1101455C (en) 2000-05-26 2003-02-12 中国石油化工集团公司 Hydrorefining catalyst for hydrocarbons and its preparing process
CN1188216C (en) 2002-10-10 2005-02-09 中国石油化工股份有限公司 Method for preparing alumina supporter
JP5060044B2 (en) 2005-12-08 2012-10-31 日本ケッチェン株式会社 Hydrocarbon hydrotreating catalyst, process for producing the same, and hydrotreating process for hydrocarbon oil
CN101092573B (en) 2006-06-22 2011-08-10 中国石油化工股份有限公司 A hydrogenation method for producing diesel oil in low sulphur
CN101450327B (en) 2007-11-29 2010-08-25 南化集团研究院 Process for preparing alumina carrier
CN101591566B (en) 2008-05-29 2012-12-12 中国石油化工股份有限公司 Grading method of catalyst of deep hydrodesulfurization of diesel oil
CN102311759B (en) 2010-07-07 2015-02-18 中国石油化工股份有限公司 Method for hydrodesulfurization of diesel
CN102876374B (en) 2011-07-11 2015-04-01 中国石油化工股份有限公司 Inferior diesel oil hydrodesulfurization method
US20130178670A1 (en) * 2012-01-06 2013-07-11 Celanese International Corporation Hydrogenation catalysts with bulk multiple oxidated supports
PH12013000353A1 (en) * 2012-12-05 2015-06-01 Cosmo Oil Co Ltd Hydrodesufurization catalyst for hydrocarbon oil
CN104338538B (en) * 2013-08-02 2017-03-22 中国石油化工股份有限公司 A hydrogenation demetalization catalyst for heavy oil, and preparation and applications thereof
CN104437517B (en) * 2013-09-22 2016-10-05 中国石油化工股份有限公司 A kind of heavy oil hydrogenating treatment catalyst and preparation and application thereof
CN104437518B (en) 2013-09-22 2017-03-29 中国石油化工股份有限公司 A kind of catalyst for selectively hydrodesulfurizing and its preparation and application
FR3013720B1 (en) 2013-11-28 2015-11-13 IFP Energies Nouvelles METHOD FOR HYDROPROCESSING VACUUM DISTILLATES USING A CATALYST SURFACE
JP6284403B2 (en) * 2014-03-27 2018-02-28 Ｊｘｔｇエネルギー株式会社 Hydrocarbon oil hydrodesulfurization catalyst
US10376873B2 (en) 2014-04-24 2019-08-13 Advanced Refining Technologies Llc Method of preparing high activity hydrotreating catalysts
CN105985799B (en) * 2015-02-12 2017-11-03 中国石油化工股份有限公司 The hydrodesulfurizationprocess process of Hydrobon catalyst system and sulphided state Hydrobon catalyst system and diesel oil
US10286386B2 (en) * 2015-05-27 2019-05-14 Jgc Catalysts And Chemicals Ltd. Hydrotreating catalyst for hydrocarbon oil, process for producing same, and hydrotreating method
CN109718867B (en) * 2017-10-27 2020-07-28 中国石油化工股份有限公司 Hydrofining catalyst system and application thereof, preparation method of hydrofining catalyst and hydrofining method of distillate oil
CN109718866B (en) * 2017-10-27 2020-07-28 中国石油化工股份有限公司 Hydrofining catalyst system and application thereof, preparation method of hydrofining catalyst and hydrofining method of distillate oil

Also Published As

Publication number Publication date
EP3778021A1 (en) 2021-02-17
US11439989B2 (en) 2022-09-13
WO2019196836A1 (en) 2019-10-17
EP3778021A4 (en) 2021-11-17
TWI802675B (en) 2023-05-21
US20210094023A1 (en) 2021-04-01
TW201943457A (en) 2019-11-16

Similar Documents

Publication Publication Date Title
IL268588A (en) Anti-gprc5d antibodies, compositions comprising same and uses thereof
IL288816A (en) Aminobenzazepine compounds, immunoconjugates, and uses thereof
EP4042881A4 (en) Microcapsule, preparation method and application thereof
SG11202009693XA (en) Hydrofining catalyst, its preparation and application thereof
EP3452520A4 (en) Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
IL291299A (en) Anti-tnfr2 antibodies, composotions comprising same and uses thereof
IL283754A (en) Anti-claudin antibodies, compositions comprising same and uses thereof
EP3638415A4 (en) Lanthanide-supported transition metal catalysts and uses thereof
GB2573252B (en) Catalytic cracking catalyst and preparation thereof
EP3617287A4 (en) Thickening agent, composition, and sheet
GB201705241D0 (en) Catalyst composition
EP3833476A4 (en) Metal-organic framework catalysts, and uses thereof
EP3590595A4 (en) Ni-coated al203@si02 catalyst, preparation method thereof and application thereof
EP3689458A4 (en) Honeycomb catalyst
EP3452521A4 (en) Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
EP3689454A4 (en) Honeycomb catalyst
EP3689453A4 (en) Honeycomb catalyst
PL3579971T3 (en) Catalyst composition
EP3569833A4 (en) Catalyst heating device and heating device
IL276753A (en) Afibrotic compounds, devices, and uses thereof
EP3689455A4 (en) Honeycomb catalyst
SG11202004945TA (en) Molecular sieve catalyst, preparation method therefor and application thereof
EP3689460A4 (en) Honeycomb catalyst
EP3689459A4 (en) Honeycomb catalyst
GB201904104D0 (en) Composition, method and use