SG11202000742QA - A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst - Google Patents
A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalystInfo
- Publication number
- SG11202000742QA SG11202000742QA SG11202000742QA SG11202000742QA SG11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA
- Authority
- SG
- Singapore
- Prior art keywords
- production
- methyl methacrylate
- heterogeneous catalyst
- oxidative esterification
- esterification
- Prior art date
Links
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 title 1
- 239000002638 heterogeneous catalyst Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000006709 oxidative esterification reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/394—Metal dispersion value, e.g. percentage or fraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/399—Distribution of the active metal ingredient homogeneously throughout the support particle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/48—Silver or gold
- C07C2523/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Dispersion Chemistry (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762538237P | 2017-07-28 | 2017-07-28 | |
PCT/US2018/039238 WO2019022889A1 (en) | 2017-07-28 | 2018-06-25 | A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
SG11202000742QA true SG11202000742QA (en) | 2020-02-27 |
Family
ID=63042096
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG11202000742QA SG11202000742QA (en) | 2017-07-28 | 2018-06-25 | A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst |
Country Status (11)
Country | Link |
---|---|
US (1) | US10829431B2 (en) |
EP (1) | EP3658533B1 (en) |
JP (2) | JP2020528442A (en) |
KR (1) | KR102639245B1 (en) |
CN (1) | CN111051274A (en) |
BR (1) | BR112020001805A2 (en) |
CA (1) | CA3071241A1 (en) |
MX (1) | MX2020001032A (en) |
SA (1) | SA520411180B1 (en) |
SG (1) | SG11202000742QA (en) |
WO (1) | WO2019022889A1 (en) |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2848369C3 (en) | 1977-11-17 | 1981-08-06 | Asahi Kasei Kogyo K.K., Osaka | Process for the preparation of carboxylic acid esters |
DE3018071C2 (en) | 1979-05-17 | 1985-06-05 | Asahi Kasei Kogyo K.K., Osaka | Process for the preparation of carboxylic acid esters |
DE3306907A1 (en) | 1983-02-26 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | CATALYST AND ITS USE FOR PRODUCING METHYL METHACRYLATE |
US5723041A (en) * | 1994-10-10 | 1998-03-03 | Amoco Corporation | Process and apparatus for promoting annularly uniform flow |
EP1361206B1 (en) | 1995-07-18 | 2004-10-27 | Asahi Kasei Chemicals Corporation | Method for producing carboxylic esters |
US5856533A (en) * | 1995-12-28 | 1999-01-05 | Praxair Technology, Inc. | High efficiency heat and mass transfer for vapor phase heterogeneous reactions |
JPH09216850A (en) | 1996-02-09 | 1997-08-19 | Mitsubishi Rayon Co Ltd | Production of carboxylic acid ester |
TW385304B (en) | 1996-09-10 | 2000-03-21 | Asahi Chemical Ind | Process for producing methacrylic acid ester or acrylic acid ester |
TW377306B (en) * | 1996-12-16 | 1999-12-21 | Asahi Chemical Ind | Noble metal support |
JP3297342B2 (en) | 1997-03-24 | 2002-07-02 | 三菱レイヨン株式会社 | Method for producing carboxylic acid ester |
SG71815A1 (en) | 1997-07-08 | 2000-04-18 | Asahi Chemical Ind | Method of producing methyl methacrylate |
US7326806B2 (en) | 2001-06-04 | 2008-02-05 | Nippon Shokubai Co., Ltd. | Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters |
JP4860064B2 (en) | 2001-08-03 | 2012-01-25 | 旭化成ケミカルズ株式会社 | PH control method in carboxylic acid ester synthesis reactor |
JP4849387B2 (en) | 2004-07-12 | 2012-01-11 | アイシーエス株式会社 | Process for producing fatty acid ester from fats and oils |
KR100905812B1 (en) | 2004-11-17 | 2009-07-02 | 아사히 가세이 케미칼즈 가부시키가이샤 | Oxidation catalyst and oxidation method |
JP4993437B2 (en) | 2006-05-12 | 2012-08-08 | 旭化成ケミカルズ株式会社 | Gold-supporting particles containing aluminum, silica and zirconia, and method for producing carboxylic acid ester using the particles |
CN1931824A (en) | 2006-09-18 | 2007-03-21 | 鲁东大学 | Process and catalyst for preparing unsaturated carboxylate continuously from unsaturated aldehyde |
US8461373B2 (en) | 2007-08-13 | 2013-06-11 | Asahi Kasei Chemicals Corporation | Catalyst for producing carboxylic acid esters, process for producing same and process for producing carboxylic acid esters |
EP2500093B1 (en) | 2007-10-26 | 2020-06-10 | Asahi Kasei Kabushiki Kaisha | Use of a supported composite particle material, production process of said material and process for producing compounds using supported composite particle material as catalyst for chemical synthesis |
GB201102502D0 (en) | 2011-02-14 | 2011-03-30 | Johnson Matthey Plc | Catalysts for use in reforming processes |
EP2886528A1 (en) * | 2013-12-20 | 2015-06-24 | Evonik Industries AG | Method for producing unsaturated esters from aldehydes by direct oxidative esterification |
EP2886529A1 (en) * | 2013-12-20 | 2015-06-24 | Evonik Industries AG | Process for producing methyl methacrylate |
CN107074727B (en) * | 2014-10-31 | 2021-02-09 | 罗门哈斯公司 | Oxidative esterification process for the manufacture of methyl methacrylate |
CN107107034B (en) | 2015-01-16 | 2020-06-05 | 罗姆化学有限责任公司 | Gold-based catalyst for the oxidative esterification of aldehydes to obtain carboxylic esters |
EP3170558A1 (en) | 2015-11-19 | 2017-05-24 | Evonik Röhm GmbH | Catalyst for oxidative esterification of aldehydes to carboxylic acid esters |
EP3235560A1 (en) * | 2016-04-22 | 2017-10-25 | Evonik Röhm GmbH | Method for performing a heterogeneously catalysed reaction |
-
2018
- 2018-06-25 CN CN201880057093.8A patent/CN111051274A/en active Pending
- 2018-06-25 JP JP2020504216A patent/JP2020528442A/en active Pending
- 2018-06-25 US US16/632,939 patent/US10829431B2/en active Active
- 2018-06-25 EP EP18746785.7A patent/EP3658533B1/en active Active
- 2018-06-25 SG SG11202000742QA patent/SG11202000742QA/en unknown
- 2018-06-25 KR KR1020207004915A patent/KR102639245B1/en active IP Right Grant
- 2018-06-25 BR BR112020001805-8A patent/BR112020001805A2/en not_active Application Discontinuation
- 2018-06-25 CA CA3071241A patent/CA3071241A1/en active Pending
- 2018-06-25 MX MX2020001032A patent/MX2020001032A/en unknown
- 2018-06-25 WO PCT/US2018/039238 patent/WO2019022889A1/en active Application Filing
-
2020
- 2020-01-28 SA SA520411180A patent/SA520411180B1/en unknown
-
2023
- 2023-04-11 JP JP2023063866A patent/JP7457859B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
MX2020001032A (en) | 2020-07-20 |
US10829431B2 (en) | 2020-11-10 |
KR102639245B1 (en) | 2024-02-20 |
JP2020528442A (en) | 2020-09-24 |
CN111051274A (en) | 2020-04-21 |
EP3658533A1 (en) | 2020-06-03 |
EP3658533B1 (en) | 2024-03-20 |
SA520411180B1 (en) | 2023-11-19 |
JP7457859B2 (en) | 2024-03-28 |
CA3071241A1 (en) | 2019-01-31 |
BR112020001805A2 (en) | 2020-07-21 |
KR20200033293A (en) | 2020-03-27 |
WO2019022889A1 (en) | 2019-01-31 |
JP2023098982A (en) | 2023-07-11 |
US20200148620A1 (en) | 2020-05-14 |
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