SG11201806106XA - Catalysts and methods for producing propylene from ethylene and butene - Google Patents

Catalysts and methods for producing propylene from ethylene and butene

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Publication number
SG11201806106XA
SG11201806106XA SG11201806106XA SG11201806106XA SG11201806106XA SG 11201806106X A SG11201806106X A SG 11201806106XA SG 11201806106X A SG11201806106X A SG 11201806106XA SG 11201806106X A SG11201806106X A SG 11201806106XA SG 11201806106X A SG11201806106X A SG 11201806106XA
Authority
SG
Singapore
Prior art keywords
international
houston
butene
mckinney
catalyst
Prior art date
Application number
SG11201806106XA
Inventor
Lei Zhang
Daniel White
Original Assignee
Lyondell Chemical Technology L P
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Chemical Technology L P filed Critical Lyondell Chemical Technology L P
Publication of SG11201806106XA publication Critical patent/SG11201806106XA/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/30Tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/08Alkenes with four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25Migration of carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25Migration of carbon-to-carbon double bonds
    • C07C5/2506Catalytic processes
    • C07C5/2512Catalytic processes with metal oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10Magnesium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08Silica
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10Magnesium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/30Tungsten
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

WO 17 / 13 215 0 Al (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2017/132150 Al 3 August 2017 (03.08.2017) WIPO I PCT 11111111111111011101111111111101011111011101110111010111100111111111110111111 (51) International Patent Classification: B01J 21/10 (2006.01) C07C 6/04 (2006.01) B01J 23/30 (2006.01) C07C 11/06 (2006.01) C07C 5/25 (2006.01) (21) International Application Number: PCT/US2017/014749 (22) International Filing Date: 24 January 2017 (24.01.2017) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/288,954 29 January 2016 (29.01.2016) US (71) Applicant: LYONDELL CHEMICAL TECHNO- LOGY, L.P. [US/US]; LyondellBasell Tower, 1221 McKinney, Suite 700, Houston, TX 77010 (US). (72) Inventors: ZHANG, Lei; c/o LyondellBasell IP Legal Dept., 1221 McKinney, Suite 700, Houston, TX 77010 (US). WHITE, Daniel, F.; c/o LyondellBasell IP Legal Dept., 1221 McKinney, Suite 700, Houston, TX 77010 (US). (74) Agents: KILPATRICK-LEE, Diane, L. et al.; Lyondell- Basell Industries, 1221 McKinney Street, Houston, TX 77010 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, [Continued on next page] (54) Title: CATALYSTS AND METHODS FOR PRODUCING PROPYLENE FROM ETHYLENE AND BUTENE (57) : The present disclosure relates to chemical catalysts and methods that may be used for the production and/or interconversion of olefins. In some embodi- ments, methods for producing propylene from ethylene and butene comprising, (a) obtaining a catalyst composition comprising an isomerization catalyst and a dispro- portionation catalyst, wherein the weight ratio of the isomerization catalyst to the disproportionation catalyst is from 10: 1 to 1 : 10: and (b) reacting butene with ethyl- ene at a temperature from about 500 °F (260 °C) to about 650 °F (350 °C) in the presence of the catalyst composition under conditions sufficient to produce propyl- ene are provided. Figure 3 WO 2017/132150 Al 1#11101M011111 1111 IIMMEM3011100101111100111EHOM TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, Published: TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, with international search report (Art. 21(3)) LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG).
SG11201806106XA 2016-01-29 2017-01-24 Catalysts and methods for producing propylene from ethylene and butene SG11201806106XA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662288954P 2016-01-29 2016-01-29
PCT/US2017/014749 WO2017132150A1 (en) 2016-01-29 2017-01-24 Catalysts and methods for producing propylene from ethylene and butene

Publications (1)

Publication Number Publication Date
SG11201806106XA true SG11201806106XA (en) 2018-08-30

Family

ID=57963497

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201806106XA SG11201806106XA (en) 2016-01-29 2017-01-24 Catalysts and methods for producing propylene from ethylene and butene

Country Status (11)

Country Link
US (1) US10029960B2 (en)
EP (1) EP3408022A1 (en)
KR (1) KR102029612B1 (en)
CN (2) CN114539016A (en)
BR (1) BR112018014896B1 (en)
CA (1) CA3012461C (en)
MX (1) MX2018009012A (en)
MY (1) MY185577A (en)
RU (1) RU2671207C1 (en)
SG (1) SG11201806106XA (en)
WO (1) WO2017132150A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110922291B (en) * 2019-11-22 2021-09-21 中国石油大学(北京) Method for producing propylene by using bio-based ethanol and butanol mixed solution
CN114433070B (en) * 2020-10-20 2023-08-29 中国石油化工股份有限公司 Catalyst particles for olefin disproportionation reaction, preparation method and application thereof

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3660507A (en) 1970-01-12 1972-05-02 Phillips Petroleum Co Conversion of olefins
US3996166A (en) 1971-12-06 1976-12-07 Phillips Petroleum Company Catalysts for conversion of olefins
US4575575A (en) 1984-04-05 1986-03-11 Phillips Petroleum Company Catalysts and process for olefin conversion
US4684760A (en) * 1986-02-24 1987-08-04 Phillips Petroleum Company Catalyst compositions useful for olefin isomerization and disproportionation
US5120894A (en) * 1988-09-19 1992-06-09 Lyondell Petrochemical Company Olefin conversion process
US5043520A (en) * 1989-12-21 1991-08-27 Shell Oil Company Concurrent isomerization and disproportionation of olefins
US6683019B2 (en) 2001-06-13 2004-01-27 Abb Lummus Global Inc. Catalyst for the metathesis of olefin(s)
US20050124839A1 (en) * 2001-06-13 2005-06-09 Gartside Robert J. Catalyst and process for the metathesis of ethylene and butene to produce propylene
US6872862B2 (en) * 2003-06-25 2005-03-29 Equistar Chemicals, Lp Propylene production
US7223895B2 (en) * 2003-11-18 2007-05-29 Abb Lummus Global Inc. Production of propylene from steam cracking of hydrocarbons, particularly ethane
US6977318B2 (en) * 2004-05-04 2005-12-20 Equistar Chemicals, Lp Propylene production
CN101148391B (en) * 2006-09-20 2010-10-13 中国石油化工股份有限公司 Method for producing propylene by butylene and ethylene dismutation
US8178737B2 (en) 2007-06-14 2012-05-15 Lyondell Chemical Technology, L.P. Propylene production
US20090281364A1 (en) 2008-05-12 2009-11-12 Halsey Richard B Metathesis process using a moving phase reactor
TW201016657A (en) * 2008-08-28 2010-05-01 Mitsui Chemicals Inc Olefin production process
AR078212A1 (en) * 2008-09-04 2011-10-26 Basf Catalysts Llc CATALYST FOR ISOMERIZATION AND METALSIS OF OLEFINS
KR20110128865A (en) 2009-04-01 2011-11-30 미쓰이 가가쿠 가부시키가이샤 Process for producing olefin
US8586813B2 (en) 2009-07-21 2013-11-19 Lummus Technology Inc. Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization
US8722950B2 (en) * 2010-04-26 2014-05-13 Saudi Basic Industries Corporation Process for producing propylene and aromatics from butenes by metathesis and aromatization
CN103030495B (en) * 2011-09-29 2014-10-15 中国石油化工股份有限公司 Method for manufacturing propylene by butene and ethylene disproportionation
EP2848300A1 (en) 2013-09-13 2015-03-18 Borealis AG Process for olefin production by metathesis and reactor system therefore
CN104447163B (en) * 2013-09-24 2016-08-10 中国石油化工股份有限公司 The method producing propylene
EP2891643A1 (en) 2014-01-02 2015-07-08 Borealis AG Process for obtaining olefins by metathesis

Also Published As

Publication number Publication date
KR102029612B1 (en) 2019-10-07
US10029960B2 (en) 2018-07-24
CN108495710A (en) 2018-09-04
EP3408022A1 (en) 2018-12-05
US20170217856A1 (en) 2017-08-03
KR20180099884A (en) 2018-09-05
MX2018009012A (en) 2018-09-28
CA3012461A1 (en) 2017-08-03
BR112018014896A2 (en) 2018-12-18
BR112018014896B1 (en) 2022-02-15
RU2671207C1 (en) 2018-10-30
CA3012461C (en) 2019-12-24
MY185577A (en) 2021-05-22
CN114539016A (en) 2022-05-27
WO2017132150A1 (en) 2017-08-03

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