SG11201803097XA - Trim dewaxing of distillate fuel - Google Patents

Trim dewaxing of distillate fuel

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Publication number
SG11201803097XA
SG11201803097XA SG11201803097XA SG11201803097XA SG11201803097XA SG 11201803097X A SG11201803097X A SG 11201803097XA SG 11201803097X A SG11201803097X A SG 11201803097XA SG 11201803097X A SG11201803097X A SG 11201803097XA SG 11201803097X A SG11201803097X A SG 11201803097XA
Authority
SG
Singapore
Prior art keywords
dewaxing
international
drive
applicant
trim
Prior art date
Application number
SG11201803097XA
Inventor
Stephen Mccarthy
Paul Podsiadlo
Chuansheng Bai
Richard Dougherty
Wenyih Lai
William Lonergan
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201803097XA publication Critical patent/SG11201803097XA/en

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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/703—MRE-type, e.g. ZSM-48
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J29/80—Mixtures of different zeolites
    • B01J35/30—
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/10—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
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    • C10G2400/10—Lubricating oil

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 29 June 2017 (29.06.2017) WIPOIPCT (10) International Publication Number WO 2017/112558 A1 (51) International Patent Classification: (30) (71) (72) B01J29/44 B01J29/46 B01J29/48 B01J29/70 B01J 37/00 B01J 37/02 (2006 (2006 (2006 (2006 (2006 (2006 01) 01) 01) 01) 01) 01) C10G C10G 45/10 C10G 45/12 C10G 45/62 C10G 45/64 C10G 45/08 65/04 (2006 (2006 (2006 (2006 (2006 (2006 01) 01) 01) 01) 01) 01) (21) International Application Number: PCT/US2016/067423 (22) International Filing Date: (25) Filing Language: (26) Publication Language 19 December 2016 (19.12.2016) English English Priority Data: 62/270,234 21 December 2015 (21.12.2015) US Applicant: EXXONMOBIL RESEARCH AND ENGIN­ EERING COMPANY [US/US]; 1545 Route 22 East, P.O. Box 900, Annandale, NJ 08801-0900 (US). Inventors: MCCARTHY, Stephen, J.; 4440 Devonshire Drive, Center Valley, PA 18034 (US). PODSIADLO, Paul; 15 Cobblestone Drive, Easton, PA 18045 (US). BAI, Chuansheng; 4 Grant Way, Philipsburg, NJ 08865 (US). DOUGHERTY, Richard, C.; 428 Paul Drive, Moorestown, NJ 08057 (US). LAI, Wenyih, Frank; 656 Bellerive Court, Bridewater, NJ 08807 (US). LONER- GAN, William, W.; 17410 Mount Riga Drive, Humble, TX 77346 (US). (74) Agents: BARRETT, Glenn, T. et al.; Exxonmobil Re­ search And Engineering Co., 1545 Route 22 East, P.o. Box 900, Annandale, NJ 08801-0900 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, [Continued on next page] (54) Title: TRIM DEWAXING OF DISTILLATE FUEL 00 SCO so A Vs. .•N »v 8.10 Xs •N A> V X / su s v. •X X BB £. « s % A V, ..V '\"S. .«*• '••v.. ..v Ns., m x \" V ^s S V * S3 6 X N, ' V w.» * v V \ • <^7 S4? vxxvvxxvxxvvx / /• \ V \ m *•- HG. s (57) : Methods and catalysts are provided for performing dewaxing of diesel boiling range frac­ tions, such as trim dewaxing, that allow for produc­ tion of diesel boiling range fuels with improved cold flow properties at desirable yields. In some aspects, the methods can include use of dewaxing catalysts based on an MEL framework structure (ZSM-11) to provide improved dewaxing activity. This can provide sufficient dewaxing activity to achieve a de­ sired level of improvement in cold flow properties at the lower hydrotreating temperatures that are gener­ ally desired near the start of operation of a hydro - treating reactor. In other aspects, the methods can in­ clude use of MEL dewaxing catalysts with reduced ratios of molecular sieve to binder so that trim dewaxing can be provided while maintaining a desir­ able yield under end-of-run hydrotreating conditions. n o WO 2017/112558 A1 LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: — as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(H)) as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii)) Published: with international search report (Art. 21(3))
SG11201803097XA 2015-12-21 2016-12-19 Trim dewaxing of distillate fuel SG11201803097XA (en)

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Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108431179A (en) 2015-12-21 2018-08-21 埃克森美孚研究工程公司 base metal dewaxing catalyst
SG11201906409QA (en) 2017-03-03 2019-09-27 Exxonmobil Res & Eng Co Trimetallic base metal hdn+hds+dewaxing catalysts, their preparation and use
WO2018204155A1 (en) * 2017-05-05 2018-11-08 Exxonmobil Research And Engineering Company Noble metal and base metal dewaxing catalyst
WO2019143495A1 (en) 2018-01-22 2019-07-25 Exxonmobil Chemical Patents Inc. Production and use of 3,4' and 4,4'-dimethylbiphenyl isomers
WO2019194975A1 (en) * 2018-04-06 2019-10-10 Exxonmobil Research And Engineering Company Catalysts and methods for distillate end point reduction
WO2020205354A1 (en) * 2019-03-29 2020-10-08 Exxonmobil Chemical Patents Inc. Mel-type zeolite for converting aromatic hydrocarbons, process for making and catalytic composition comprising said zeolite
EP3947325A1 (en) * 2019-03-29 2022-02-09 ExxonMobil Chemical Patents Inc. Novel zeolite, process for making same, and use thereof in converting aromatic hydrocarbons
US11098256B2 (en) 2020-01-08 2021-08-24 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for improving cold flow properties of distillates
US20220152599A1 (en) * 2020-11-16 2022-05-19 Sabic Global Technologies B.V. Catalyst for converting ethane to monoaromatic hydrocarbons
US11484869B2 (en) 2020-12-09 2022-11-01 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for dealkylation of aromatics
WO2022162680A1 (en) * 2021-02-01 2022-08-04 Hindustan Petroleum Corporation Limited A multifunctional catalyst and its composition for single step conversion of triglycerides to transportation fuels

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
AU578930B2 (en) * 1984-03-19 1988-11-10 Mobil Oil Corporation Catalytic dewaxing process using ZSM-11
US4894212A (en) * 1987-07-20 1990-01-16 Mobil Oil Corp. Synthesis of crystalline silicate ZSM-11
US4872968A (en) * 1987-08-20 1989-10-10 Mobil Oil Corporation Catalytic dewaxing process using binder-free catalyst
US7084087B2 (en) * 1999-09-07 2006-08-01 Abb Lummus Global Inc. Zeolite composite, method for making and catalytic application thereof
CN100388977C (en) * 2005-04-21 2008-05-21 中国石油化工股份有限公司 Fluorinated and phosphor-contained hydrogenation catalyst with silicon oxide-alumina as carrier and its production
US8697598B2 (en) * 2005-04-21 2014-04-15 China Petroleum & Chemical Corporation Hydrogenation catalyst and use thereof
US8252709B2 (en) * 2006-09-14 2012-08-28 Cosmo Oil Co., Ltd. Catalyst for hydrodesulfurization/dewaxing of hydrocarbon oil, process for producing the same, and method of hydrotreating hydrocarbon oil with the catalyst
US8394255B2 (en) * 2008-12-31 2013-03-12 Exxonmobil Research And Engineering Company Integrated hydrocracking and dewaxing of hydrocarbons
US8377286B2 (en) * 2008-12-31 2013-02-19 Exxonmobil Research And Engineering Company Sour service hydroprocessing for diesel fuel production
US20110056869A1 (en) * 2009-09-08 2011-03-10 Exxonmobil Research And Engineering Company Fuel production from feedstock containing lipidic material
US8142757B2 (en) * 2009-11-05 2012-03-27 Chevron U.S.A. Inc. Method for making borosilicate ZSM-48 molecular sieves
US8617383B2 (en) * 2010-06-29 2013-12-31 Exxonmobil Research And Engineering Company Integrated hydrocracking and dewaxing of hydrocarbons
JP6084798B2 (en) * 2012-10-02 2017-02-22 Ｊｘエネルギー株式会社 Manufacturing method of base oil for lubricating oil

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