SG11201510461SA - Substituted metallocene catalysts - Google Patents

Substituted metallocene catalysts

Info

Publication number
SG11201510461SA
SG11201510461SA SG11201510461SA SG11201510461SA SG11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA SG 11201510461S A SG11201510461S A SG 11201510461SA
Authority
SG
Singapore
Prior art keywords
metallocene catalysts
substituted metallocene
substituted
catalysts
metallocene
Prior art date
Application number
SG11201510461SA
Inventor
Jo Ann M Canich
Ilya S Borisov
Arkady K Golenishchev
Georgy P Goryunov
Dmitry V Uborsky
Pavel S Kulyabin
Dmitry S Kononovich
Vyatcheslav V Izmer
Alexander Z Voskoboynikov
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of SG11201510461SA publication Critical patent/SG11201510461SA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/09Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
SG11201510461SA 2013-07-17 2014-07-08 Substituted metallocene catalysts SG11201510461SA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361847442P 2013-07-17 2013-07-17
PCT/US2014/045652 WO2015009479A1 (en) 2013-07-17 2014-07-08 Substituted metallocene catalysts

Publications (1)

Publication Number Publication Date
SG11201510461SA true SG11201510461SA (en) 2016-01-28

Family

ID=52344082

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201510461SA SG11201510461SA (en) 2013-07-17 2014-07-08 Substituted metallocene catalysts

Country Status (7)

Country Link
US (1) US9458254B2 (en)
EP (1) EP3022234B1 (en)
JP (1) JP2016531978A (en)
CN (2) CN105377906A (en)
ES (1) ES2715831T3 (en)
SG (1) SG11201510461SA (en)
WO (1) WO2015009479A1 (en)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201510461SA (en) 2013-07-17 2016-01-28 Exxonmobil Chem Patents Inc Substituted metallocene catalysts
EP3848401A1 (en) * 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US20160122452A1 (en) 2013-07-17 2016-05-05 Exxonmobil Chemical Patents Inc. Ethylene-Propylene Copolymeric Compositions With Long Methylene Sequence Lengths
CN105377905B (en) 2013-07-17 2018-09-14 埃克森美孚化学专利公司 Metallocene and by its derivative carbon monoxide-olefin polymeric
CN105358589B (en) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 Metallocene and by its derivative carbon monoxide-olefin polymeric
WO2016057124A1 (en) 2014-10-06 2016-04-14 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin containing amorphous ethylene elastomer
US10253173B2 (en) 2015-01-14 2019-04-09 Exxonmobil Chemical Patents Inc. Polymer compositions and processes for their production
EP3405524B1 (en) 2016-01-19 2021-12-01 ExxonMobil Chemical Patents Inc. High molecular weight multimodal elastomer compositions with good processability
WO2017127175A1 (en) 2016-01-22 2017-07-27 Exxonmobil Chemical Patents Inc. High viscosity metallocene polymers with low volatiles content
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US10808049B2 (en) 2016-07-13 2020-10-20 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013283A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
JP6936303B2 (en) 2016-07-14 2021-09-15 エクソンモービル・ケミカル・パテンツ・インク Bimodal copolymer composition polymerized with a binary metallocene catalyst
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2018044395A1 (en) 2016-08-31 2018-03-08 Exxonmobil Chemical Patents Inc. Spiral heat exchanger as a preheater in polymer devolatilization processes
US11186753B2 (en) 2016-09-23 2021-11-30 Exxonmobil Chemical Patents Inc. Shrinkable thermoplastic vulcanizate and method and article
US10364308B2 (en) 2016-12-08 2019-07-30 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin compositions
US10822481B2 (en) 2017-01-05 2020-11-03 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin compositions with ethylene-propylene copolymers
US10513601B2 (en) 2017-01-05 2019-12-24 Exxonmobil Chemical Patents Inc. Ethylene-propylene copolymers with amorphous and semi-crystalline components
SG11201907497PA (en) * 2017-02-20 2019-09-27 Exxonmobil Chemical Patents Inc Supported catalyst systems and processes for use thereof
EP3589693B1 (en) 2017-02-28 2024-01-03 ExxonMobil Chemical Patents Inc. Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized epdm
JP6921563B2 (en) * 2017-03-07 2021-08-18 出光興産株式会社 Method for Producing Transition Metal Compounds and Olefin Polymers
WO2018190940A1 (en) 2017-04-14 2018-10-18 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising epdm and epr
CN111032772B (en) 2017-06-14 2022-07-15 埃克森美孚化学专利公司 Ethylene copolymer blends for crosslinking applications
WO2019004418A1 (en) * 2017-06-30 2019-01-03 三井化学株式会社 Propylene-based polymer, method for preparing same, propylene-based resin composition, and molded body
CN111051355A (en) 2017-08-29 2020-04-21 埃克森美孚化学专利公司 Carbon dioxide as a catalyst quencher in solution polymerization and products made therefrom
KR102452018B1 (en) * 2017-10-23 2022-10-07 엑손모빌 케미칼 패턴츠 인코포레이티드 Catalyst system and polymerization method using same
US11001657B2 (en) 2017-10-25 2021-05-11 Exxonmobil Chemical Patents Inc. Unbridged indacenyl metallocenes
EP3714025A1 (en) 2017-11-21 2020-09-30 ExxonMobil Chemical Patents Inc. Bimodal copolymer compositions useful as oil modifiers
CN111417657B (en) * 2017-11-29 2022-11-25 埃克森美孚化学专利公司 Asymmetric ansa-metallocene catalyst compounds for the preparation of polyolefins having broad molecular weight distribution
US11390734B2 (en) 2017-12-08 2022-07-19 Exxonmobil Chemical Patents Inc. Elastomeric terpolymer compositions for corner molding applications
KR20200097739A (en) 2017-12-13 2020-08-19 셰브런 오로나이트 컴퍼니 엘엘씨 Binary Copolymer Compositions Useful As Oil Conditioners And Lubricating Oils Containing These
EP3752538B1 (en) 2018-02-12 2024-07-03 ExxonMobil Chemical Patents Inc. Metallocene catalyst feed system for solution polymerization process
WO2019157169A1 (en) 2018-02-12 2019-08-15 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
US10894841B2 (en) 2018-03-19 2021-01-19 Exxonmobil Chemical Patents Inc. Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
CN112805329B (en) 2018-08-29 2024-02-02 埃克森美孚化学专利公司 Process for preparing polymer compositions with enhanced elasticity by employing VTP and HMP catalyst systems in parallel process
US11198745B2 (en) * 2018-11-29 2021-12-14 Exxonmobil Chemical Patents Inc. Poly(alpha-olefin)s and methods thereof
US20220251361A1 (en) 2019-07-17 2022-08-11 Exxonmobil Chemical Patents Inc. High Propylene Content EP Having Low Glass Transition Temperatures
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
US11325995B2 (en) * 2020-02-21 2022-05-10 Chevron Phillips Chemical Company Lp Metallocene catalysts for polyethylene
US11613593B2 (en) 2020-02-24 2023-03-28 Exxonmobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
WO2021188361A1 (en) 2020-03-20 2021-09-23 Exxonmobil Chemical Patents Inc. Linear alpha-olefin copolymers and impact copolymers thereof
US11766669B2 (en) 2020-06-26 2023-09-26 Exxonmobil Chemical Patents Inc. Hexahydrocyclopenta[e]-as-indacen-1-yl and octahydrobenzo[e]-as-indacen-1-yl based catalyst complexes and process for use thereof
CN116670146A (en) 2020-11-23 2023-08-29 埃克森美孚化学专利公司 Metallocene polypropylene prepared using aromatic solvent-free carrier
WO2022207551A1 (en) 2021-03-29 2022-10-06 Arlanxeo Netherlands B.V. Process for producing polymers
EP4313590A1 (en) * 2021-04-01 2024-02-07 Borealis AG Biaxially oriented polypropylene-based multilayer film
KR20240009451A (en) 2021-05-14 2024-01-22 엑손모빌 케미컬 패튼츠, 아이엔씨. Ethylene-propylene branched copolymers as viscosity modifiers
JP2024518829A (en) 2021-05-14 2024-05-07 エクソンモービル ケミカル パテンツ,インコーポレイティド Branched ethylene-propylene copolymers for use as viscosity modifiers
EP4396246A1 (en) 2021-09-02 2024-07-10 ExxonMobil Chemical Patents Inc. C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
WO2023217397A1 (en) 2022-05-09 2023-11-16 Arlanxeo Netherlands B.V. Process for producing polymers
CN114736099B (en) * 2022-05-18 2023-06-06 江苏南大光电材料股份有限公司 Preparation method of 1- (tertiary butyl) -3-chloronaphthalene

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5337644A (en) 1976-09-14 1978-04-06 Mitsubishi Chem Ind Ltd Transition metal complexes of 5,6-diaminocalicenes
FI59934C (en) 1978-07-05 1981-11-10 Suovaniemi Finnpipette FOERFLYTTNINGSANORDNING FOER ANALYSANLAEGGNINGAR
DE3772331D1 (en) 1986-11-13 1991-09-26 Idemitsu Kosan Co METHOD FOR OLIGOMERIZING PROPEN.
IT8919252A0 (en) 1989-01-31 1989-01-31 Ilano CATALYSTS FOR THE POLYMERIZATION OF OLEFINS.
EP0485821B1 (en) 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocenes with 2-substituted indenyl-derivates as ligands, process for their preparation and their use as catalysts
TW300901B (en) 1991-08-26 1997-03-21 Hoechst Ag
TW294669B (en) 1992-06-27 1997-01-01 Hoechst Ag
ES2114978T3 (en) 1992-08-03 1998-06-16 Targor Gmbh PROCEDURE FOR OBTAINING AN OLEPHINE POLYMER UNDER THE USE OF METALLOCES WITH SPECIAL SUBSTITUTION INDENYL LIGANDS.
CA2125246C (en) 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
US5459117A (en) 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en) 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4333128A1 (en) 1993-09-29 1995-03-30 Hoechst Ag Process for the preparation of polyolefins
DE4344688A1 (en) 1993-12-27 1995-06-29 Hoechst Ag Metallocene compound
DE4344689A1 (en) 1993-12-27 1995-06-29 Hoechst Ag Metallocene compound
DE4406963A1 (en) 1994-03-03 1995-09-07 Basf Ag Metallocene complexes with heterofunctional groups on the cyclopentadienyl system
IT1272923B (en) 1995-01-23 1997-07-01 Spherilene Srl METALLOCENIC COMPOUNDS, PROCEDURE FOR THEIR PREPARATION, AND THEIR USE IN CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
JPH08239416A (en) * 1995-03-02 1996-09-17 Mitsui Petrochem Ind Ltd New transition metal compound and olefin polymerization catalyst component comprising same
US6399533B2 (en) 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
WO1997038024A1 (en) * 1996-04-09 1997-10-16 Mitsui Chemicals, Inc. Olefin polymerization catalyst, olefin polymerization method, olefin polymer compositions, and thermoformed articles
EP0834519B1 (en) 1996-04-22 2002-03-06 Japan Polyolefins Co., Ltd. Catalyst for polyolefin production and process for producing polyolefin
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
FI971565A (en) 1997-04-14 1998-10-15 Borealis As Substituted metallocene compounds for catalyst systems intended for polymerization of olefins, intermediates and processes for their preparation
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
DE19917985A1 (en) 1999-04-21 2000-10-26 Targor Gmbh Metallocene catalyst system, useful for the production of polyolefins, comprises an organoboron or organoaluminum compound covalently bonded to a support.
RU2160276C1 (en) 1999-06-21 2000-12-10 Институт химической физики им. Н.Н. Семенова РАН Ansa-zirconocines with unsaturated cyclosilane bridge, and method of preparing thereof
DE60003936T2 (en) 1999-09-22 2004-05-13 Basell Polyolefine Gmbh CATALYST SYSTEM AND METHOD FOR THE POLYMERIZATION OF OLEFINS
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
DE19962814A1 (en) 1999-12-23 2001-06-28 Targor Gmbh Catalyst system, useful for the production of polyolefins, comprises a metallocene, a Lewis base, a support and a compound containing at least one Group 3 element
US7342078B2 (en) 1999-12-23 2008-03-11 Basell Polyolefine Gmbh Transition metal compound, ligand system, catalyst system and the use of the latter for polymerisation and copolymerisation of olefins
US6492465B1 (en) 2000-02-08 2002-12-10 Exxonmobil Chemical Patents, Inc. Propylene impact copolymers
DE60103702T2 (en) 2000-02-24 2005-06-23 Basell Polyolefine Gmbh Organometallic compounds used as cocatalyst in the polymerization of olefins
DE10025412A1 (en) 2000-05-24 2001-11-29 Basell Polypropylen Gmbh Chemical products suitable as cocatalysts, processes for their preparation and their use in catalyst systems for the production of polyolefins
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
DE60112307T8 (en) 2000-06-30 2007-02-15 Exxonmobil Chemical Patents Inc., Baytown Metallocene compounds with a bridged 4-phenylenedynyl ligand system for the polymerisation of olefins
WO2002002575A1 (en) 2000-06-30 2002-01-10 Exxonmobil Chemical Patents, Inc. Metallocenes with a bridged 4-phenyl-indenyl-ligand for olefin polymerization
US6538082B2 (en) 2000-12-05 2003-03-25 Solvay Polyolefins Europe-Belgium Asymmetric silicon-bridged metallocenes useful as catalysts in the polymerization of α-olefins, process for their preparation and use of said metallocenes for the polymerization of α-olefins
JP2005522406A (en) 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク Metallocene and catalyst composition derived from the metallocene
DE10158656A1 (en) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organo transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for making polyolefins
WO2004005360A2 (en) 2002-07-09 2004-01-15 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
US7615597B2 (en) 2002-09-06 2009-11-10 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US20040132935A1 (en) 2002-10-24 2004-07-08 Palanisamy Arjunan Branched crystalline polypropylene
AU2003294764A1 (en) 2002-12-06 2004-06-30 Basell Polyolefine Gmbh Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
DE10358082A1 (en) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organometallic transition metal compound used in catalyst system for preparation of polyolefins, uses biscyclopentadienyl ligand systems in its preparation
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US7220695B2 (en) 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7276567B2 (en) * 2004-04-16 2007-10-02 Exxonmobil Chemical Patents Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
DE102004020524A1 (en) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylene for film, e.g. stretch film, used in carrier bags, contains ethylene homopolymers and/or copolymers of ethylene with 1-alkenes
EP1799726B1 (en) 2004-10-12 2011-07-13 ExxonMobil Chemical Patents Inc. Trialkylaluminum treated supports
JP2008534705A (en) 2005-03-23 2008-08-28 バーゼル・ポリオレフィン・ゲーエムベーハー Polymerization of olefins
EP1877453A1 (en) 2005-05-03 2008-01-16 Basell Polyolefine GmbH Process for the polymerization of alpha olefins
ATE515533T1 (en) 2005-05-11 2011-07-15 Basell Poliolefine Srl POLYMERIZATION PROCESS FOR PRODUCING POLYOLEFIN BLENDS
CN101074276B (en) 2006-05-18 2011-06-22 中国石油天然气股份有限公司 Long-chain branched polypropylene and preparation method thereof
WO2009050037A1 (en) 2007-10-19 2009-04-23 Basell Polyolefine Gmbh Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands
JP5598856B2 (en) 2007-10-25 2014-10-01 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Metallocene compound, catalyst containing the same, process for producing olefin polymer using the catalyst, and olefin homopolymer and copolymer
GB0918736D0 (en) 2009-10-26 2009-12-09 Isis Innovation Catalysts
WO2012134715A2 (en) 2011-03-25 2012-10-04 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
EP2760895A4 (en) * 2011-09-30 2015-07-22 Exxonmobil Chem Patents Inc Dynamic modulation of metallocene catalysts
SG11201510461SA (en) 2013-07-17 2016-01-28 Exxonmobil Chem Patents Inc Substituted metallocene catalysts

Also Published As

Publication number Publication date
CN110845546A (en) 2020-02-28
US20150025209A1 (en) 2015-01-22
EP3022234A4 (en) 2016-06-15
EP3022234B1 (en) 2018-12-26
WO2015009479A1 (en) 2015-01-22
US9458254B2 (en) 2016-10-04
ES2715831T3 (en) 2019-06-06
JP2016531978A (en) 2016-10-13
CN105377906A (en) 2016-03-02
EP3022234A1 (en) 2016-05-25

Similar Documents

Publication Publication Date Title
SG11201510461SA (en) Substituted metallocene catalysts
DK3088517T3 (en) Humant anti-il-33-neutraliserende monoklonalt antistof
DK3354246T3 (en) Udstyrsmonteringssystem
DK3077519T3 (en) Cmv-vacciner
AU354897S (en) Hook
EP3037167A4 (en) Hybrid-supported metallocene catalyst
SG11201508750SA (en) Cyclopropyl substituted metallocene catalysts
ZA201508187B (en) Catalyst
GB201318846D0 (en) Photocatalysts
SG11201504965XA (en) Dewaxing catalysts
GB201302016D0 (en) Catalyst
DK3470074T3 (en) Probiotika
EP2960532A4 (en) Hook
AU353575S (en) Stamphousing
DK3056208T3 (en) Immunpotentiator
GB2511396B (en) Pre-turbocharger catalyst
DK2979701T3 (en) Antitumormiddel indbefattende irinotecanhydrochloridhydrat
IL228776A0 (en) Analog -to-inforamation converter via spectrum-compression
GB201321230D0 (en) Catalysts
GB201310953D0 (en) New catalysts
DK2989854T3 (en) Strømstyret opvarmningssystem
AU4899P (en) Herbie53 Iresine herbstii
AU4953P (en) Flogazora Gazania rigens
AU4977P (en) Harrosy Gaura lindheimeri
AU353327S (en) Kettlebell