SG10201809230YA - Method for producing isobutylene from isobutanol - Google Patents

Method for producing isobutylene from isobutanol

Info

Publication number
SG10201809230YA
SG10201809230YA SG10201809230YA SG10201809230YA SG10201809230YA SG 10201809230Y A SG10201809230Y A SG 10201809230YA SG 10201809230Y A SG10201809230Y A SG 10201809230YA SG 10201809230Y A SG10201809230Y A SG 10201809230YA SG 10201809230Y A SG10201809230Y A SG 10201809230YA
Authority
SG
Singapore
Prior art keywords
isobutanol
reaction
isobutylene
catalyst
present
Prior art date
Application number
SG10201809230YA
Inventor
Toshiya Yasukawa
Tatsuya Suzuki
Akio Takeda
Wataru Ninomiya
Kenichi Miyaki
Ken Ooyachi
Shuji Akihara
Original Assignee
Mitsubishi Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chem Corp filed Critical Mitsubishi Chem Corp
Publication of SG10201809230YA publication Critical patent/SG10201809230YA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

METHOD FOR PRODUCING ISOBUTYLENE FROM ISOBUTANOL : The purpose of the present invention is to provide a method that can produce, with high yield or high selectivity isobutylene by means of isobutanol dehydration-reaction. An isobutylene production method of a first embodiment of the present invention is a method for producing isobutylene by means of isobutanol dehydration-reaction, wherein isobutanol is reacted using a catalyst for which the BET specific surface area is within the range of 60m 2/g-175m 2/g, and the reaction is carried out under a reaction pressure of 50kPa-750kPa as the absolute pressure. An isobutylene production method of a second embodiment of the present invention includes: using a catalyst which is filled into a reaction chamber and for which the particle diameters of at least 90 mass% of the catalyst are within the range of 700 µm - 1000 µm; setting the isobutanol concentration within a supplied reaction gas to 30vol% -85vol%; setting the weight hourly velocity (WHSV) of the isobutanol to 0.175h -1~20h -1; and reacting isobutanol under a reaction pressure of 50kPa-750kPa as the absolute pressure. [No Figure.]
SG10201809230YA 2014-05-07 2015-05-01 Method for producing isobutylene from isobutanol SG10201809230YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2014095675 2014-05-07
JP2014167032 2014-08-20

Publications (1)

Publication Number Publication Date
SG10201809230YA true SG10201809230YA (en) 2018-11-29

Family

ID=54392536

Family Applications (2)

Application Number Title Priority Date Filing Date
SG11201607927WA SG11201607927WA (en) 2014-05-07 2015-05-01 Method for producing isobutylene from isobutanol
SG10201809230YA SG10201809230YA (en) 2014-05-07 2015-05-01 Method for producing isobutylene from isobutanol

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SG11201607927WA SG11201607927WA (en) 2014-05-07 2015-05-01 Method for producing isobutylene from isobutanol

Country Status (6)

Country Link
US (1) US10464860B2 (en)
JP (1) JP6485351B2 (en)
KR (1) KR101960146B1 (en)
CN (1) CN106458786B (en)
SG (2) SG11201607927WA (en)
WO (1) WO2015170686A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018047773A1 (en) * 2016-09-06 2018-03-15 三菱ケミカル株式会社 Method for separating and purifying isobutylene and method for producing isobutylene
EP3526183A4 (en) 2016-10-14 2020-06-17 GEVO, Inc. Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols
CN108358740A (en) * 2018-02-09 2018-08-03 安徽海德化工科技有限公司 A kind of auxiliary agent preparing isobutene for isobutyl dehydration of alcohols
CA3145216A1 (en) 2019-06-27 2020-12-30 Gevo, Inc. Bio-based olefin oligomerization via chabazite zeolite catalyst
CN115135625A (en) 2020-03-31 2022-09-30 三菱化学株式会社 Catalyst, method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
CN115135624A (en) * 2020-03-31 2022-09-30 三菱化学株式会社 Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
KR102584441B1 (en) 2020-06-19 2023-10-05 주식회사 엘지화학 Method for preparing alumina catalyst, alumina catalyst prepared therefrom, and method for preparing propylene using the same
EP3967394A4 (en) 2020-06-19 2022-04-20 Lg Chem, Ltd. Dehydration catalyst, method for preparing same and method for preparing alkene using same

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69212854T2 (en) * 1991-02-04 1997-01-16 Mitsui Petrochemical Ind Process for the production of propylene
JP2976396B2 (en) * 1991-02-04 1999-11-10 三井化学株式会社 Gamma-alumina catalyst for dehydration reaction and method for producing olefins using this catalyst
EP2266939B1 (en) * 2005-11-01 2016-09-28 Asahi Kasei Kabushiki Kaisha Processes for production of tertiary butanol
BR112012009385A2 (en) 2009-10-06 2017-09-26 Gevo Inc integrated process to selectively convert renewable isobutanol to p-xylene
JP2013516487A (en) * 2010-01-08 2013-05-13 ジーヴォ，インコーポレイテッド An integrated method for preparing renewable chemicals
ES2603029T3 (en) 2010-03-15 2017-02-23 Total Research & Technology Feluy Simultaneous dehydration and isomerization of the isobutanol skeleton on acid catalysts
EP2583957A1 (en) * 2011-10-18 2013-04-24 LANXESS Deutschland GmbH Linear butene from isobutanol
KR101337301B1 (en) * 2012-03-28 2013-12-05 서울대학교산학협력단 Aluminosilicate Nano-spheres having 3-Dimensional Open Pores, Method for Preparing the Same and Method for Producing Acrylic Acid from Glycerol Using the Same
FR2988718B1 (en) * 2012-03-29 2014-04-11 Ifp Energies Now METHOD FOR DEHYDRATION AND ISOMERIZATION OF ALCOHOLS USING A NON-ZEOLITHIC ALUMINOSILICATE SOLID
FR2988717B1 (en) * 2012-03-29 2014-04-11 IFP Energies Nouvelles METHOD FOR DEHYDRATION AND ISOMERIZATION OF ALCOHOLS USING A CATALYST BASED ON MESOSTRUCTURE MATERIAL COMPRISING SILICON
FR3001728B1 (en) 2013-02-04 2015-11-13 Adisseo France Sas PROCESS FOR PREPARING OLEFIN BY CATALYTIC CONVERSION OF AT LEAST ONE ALCOHOL

Also Published As

Publication number Publication date
US10464860B2 (en) 2019-11-05
US20170050896A1 (en) 2017-02-23
JPWO2015170686A1 (en) 2017-04-20
KR101960146B1 (en) 2019-03-19
SG11201607927WA (en) 2016-11-29
KR20160130279A (en) 2016-11-10
CN106458786B (en) 2020-05-08
WO2015170686A1 (en) 2015-11-12
CN106458786A (en) 2017-02-22
JP6485351B2 (en) 2019-03-20

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