SE7908072L - PROCEDURE FOR THE PREPARATION OF TERPHALIC ACID - Google Patents

PROCEDURE FOR THE PREPARATION OF TERPHALIC ACID

Info

Publication number
SE7908072L
SE7908072L SE7908072A SE7908072A SE7908072L SE 7908072 L SE7908072 L SE 7908072L SE 7908072 A SE7908072 A SE 7908072A SE 7908072 A SE7908072 A SE 7908072A SE 7908072 L SE7908072 L SE 7908072L
Authority
SE
Sweden
Prior art keywords
equals
reaction mixture
manganese
acid
catalytically
Prior art date
Application number
SE7908072A
Other languages
Swedish (sv)
Inventor
J D V Hanotier
Original Assignee
Labofina Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Labofina Sa filed Critical Labofina Sa
Publication of SE7908072L publication Critical patent/SE7908072L/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Terephthalic acid is prepared by oxidizing a substantially homogeneous liquid reaction mixture, comprising p-toluic acid, optionally in admixture with p-xylene and partially oxidized p-xylene derivatives, 5% to 80% by weight of water, and a catalytically-active metal compound selected from manganese compounds, cobalt compounds and mixtures thereof, with a molecular oxygen-containing gas. At least a minimum amount of M millimoles of the catalytically-active metal compound per kg of the liquid reaction mixture is used, wherein M is defined by the following equation: <IMAGE> wherein Y represents the molar ratio of water/p-toluic acid in the reaction mixture, x represents the molar ratio of manganese/total manganese + cobalt in the catalyst composition <IMAGE> A equals about 0.200, B equals about 10.9, C equals about 4.35; and D equals about 0.0724.t
SE7908072A 1978-10-02 1979-09-28 PROCEDURE FOR THE PREPARATION OF TERPHALIC ACID SE7908072L (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US94764178A 1978-10-02 1978-10-02

Publications (1)

Publication Number Publication Date
SE7908072L true SE7908072L (en) 1980-04-03

Family

ID=25486474

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7908072A SE7908072L (en) 1978-10-02 1979-09-28 PROCEDURE FOR THE PREPARATION OF TERPHALIC ACID

Country Status (23)

Country Link
JP (1) JPS5549337A (en)
AR (1) AR218771A1 (en)
AT (1) ATA638179A (en)
AU (1) AU5135679A (en)
BE (1) BE879091A (en)
BR (1) BR7906172A (en)
CA (1) CA1145357A (en)
CH (1) CH642343A5 (en)
CS (1) CS212247B2 (en)
DE (1) DE2939510C2 (en)
ES (1) ES484555A1 (en)
FI (1) FI793003A (en)
FR (1) FR2438027A1 (en)
GB (1) GB2032432B (en)
IN (1) IN152155B (en)
IT (1) IT1123749B (en)
NL (1) NL7907252A (en)
NO (1) NO150679C (en)
PH (1) PH15083A (en)
PL (1) PL118757B1 (en)
PT (1) PT70249A (en)
SE (1) SE7908072L (en)
ZA (1) ZA795037B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4334086A (en) * 1981-03-16 1982-06-08 Labofina S.A. Production of terephthalic acid
GB9210832D0 (en) * 1992-05-21 1992-07-08 Ici Plc Bromine catalysed oxidation process

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE548214A (en) *
BE562102A (en) * 1956-11-05
FR1367025A (en) * 1963-06-25 1964-07-17 Du Pont P-xylene oxidation process
US3406196A (en) * 1964-09-30 1968-10-15 Du Pont Oxidation of polyalkyl aromatics to polycarboxylic acids
US3883584A (en) * 1971-11-25 1975-05-13 Teijin Ltd Process for the preparation of terephthalic acid
CH622766A5 (en) * 1976-10-26 1981-04-30 Labofina Sa Process for the preparation of terephthalic acid
GB1542320A (en) * 1976-10-26 1979-03-14 Labofina Sa Process for the preparation of aromatic dicarboxylic acids
GB2019395B (en) * 1978-04-24 1982-07-28 Labofina Sa Production of terephthalic acid from p-xylene

Also Published As

Publication number Publication date
FR2438027B1 (en) 1984-08-24
IN152155B (en) 1983-11-05
PH15083A (en) 1982-07-02
ATA638179A (en) 1982-01-15
ZA795037B (en) 1980-09-24
BR7906172A (en) 1980-05-27
IT1123749B (en) 1986-04-30
NO150679B (en) 1984-08-20
IT7926037A0 (en) 1979-09-26
JPH0222057B2 (en) 1990-05-17
DE2939510C2 (en) 1985-08-01
PL118757B1 (en) 1981-10-31
AU5135679A (en) 1980-04-17
GB2032432A (en) 1980-05-08
DE2939510A1 (en) 1980-04-03
NO150679C (en) 1984-11-28
AR218771A1 (en) 1980-06-30
ES484555A0 (en) 1980-05-16
PL218597A1 (en) 1980-05-05
FR2438027A1 (en) 1980-04-30
NO793116L (en) 1980-04-08
BE879091A (en) 1980-03-28
FI793003A (en) 1980-04-03
JPS5549337A (en) 1980-04-09
NL7907252A (en) 1980-04-08
CA1145357A (en) 1983-04-26
CH642343A5 (en) 1984-04-13
CS212247B2 (en) 1982-03-26
ES484555A1 (en) 1980-05-16
GB2032432B (en) 1983-02-09
PT70249A (en) 1979-10-01

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