SA515361037B1 - بوليولات بوليمر نشطة وعملية لإنتاجها - Google Patents

بوليولات بوليمر نشطة وعملية لإنتاجها

Info

Publication number
SA515361037B1
SA515361037B1 SA515361037A SA515361037A SA515361037B1 SA 515361037 B1 SA515361037 B1 SA 515361037B1 SA 515361037 A SA515361037 A SA 515361037A SA 515361037 A SA515361037 A SA 515361037A SA 515361037 B1 SA515361037 B1 SA 515361037B1
Authority
SA
Saudi Arabia
Prior art keywords
polymer polyols
production
optionally
ethylene oxide
active polymer
Prior art date
Application number
SA515361037A
Other languages
English (en)
Inventor
اف. بازوس جوزيه
ال. ادكنز ريك
ال. هاجر ستانلي
Original Assignee
باير ماتيريالز ساينس ال ال سي
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by باير ماتيريالز ساينس ال ال سي filed Critical باير ماتيريالز ساينس ال ال سي
Publication of SA515361037B1 publication Critical patent/SA515361037B1/ar

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Graft Or Block Polymers (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

يتعلق الاختراع الحالي بإنتاج بوليول بوليمر (polymer polyol) له محتوى مواد صلبة أكبر من 40 وزن٪، محتوى ethylene oxide كلي حتى 25 بالوزن٪، ولزوجة عند 25°مئوية أقل من 15000 سنتي ستوك عن طريق تفاعل (1) بوليول قاعدة له ذرات هيدروجين نشطة مع محتوى ethylene oxide من 15 إلى 40 وزن٪ تم تشكيله في وجود حفاز cyanide فلز مزدوج (double metal cyanide) (DMC)، (2) مونومرات غير مشبعة واحدة أو أكثر، (3) بادئ شق (radical initiator) واحد على الأقل، اختياريا (4) مثبت مسبق التشكيل (preformed stabilizer) واختياريا (5) عامل نقل سلسلة (chain transfer agent). تكون بوليولات البوليمر هذه (PMPOs) مفيدة في تحضير رغوات polyurethane والمواد المطاطية.
SA515361037A 2013-03-15 2015-09-10 بوليولات بوليمر نشطة وعملية لإنتاجها SA515361037B1 (ar)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/836,583 US8987396B2 (en) 2013-03-15 2013-03-15 Active polymer polyols and a process for their production
PCT/US2014/025499 WO2014151334A1 (en) 2013-03-15 2014-03-13 Active polymer polyols and a process for their production

Publications (1)

Publication Number Publication Date
SA515361037B1 true SA515361037B1 (ar) 2017-02-07

Family

ID=51530115

Family Applications (1)

Application Number Title Priority Date Filing Date
SA515361037A SA515361037B1 (ar) 2013-03-15 2015-09-10 بوليولات بوليمر نشطة وعملية لإنتاجها

Country Status (5)

Country Link
US (1) US8987396B2 (ar)
EP (1) EP2970559A4 (ar)
CN (1) CN105051086A (ar)
SA (1) SA515361037B1 (ar)
WO (1) WO2014151334A1 (ar)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HUE054307T2 (hu) * 2016-03-31 2021-08-30 Dow Global Technologies Llc Eljárás polimer poliol készítésére, amely monodiszperz diszpergált polimer részekkel rendelkezik
US11312811B2 (en) * 2016-04-26 2022-04-26 Covestro Llc Flexible foam using polymer polyols produced via DMC catalyzed polyols
US10040903B2 (en) * 2016-09-13 2018-08-07 Covestro Llc Polymer polyol quality
CN109266098A (zh) * 2018-08-21 2019-01-25 广东天龙油墨有限公司 一种水性预印乳液及其制备方法和在油墨中的应用
CN114479050B (zh) * 2020-10-23 2023-08-04 中国石油化工股份有限公司 一种稳定剂前体及其制备方法和应用
CN115232257B (zh) * 2021-04-22 2023-09-29 中国石油化工股份有限公司 一种低粘度聚合物多元醇的制备方法及得到的聚合物多元醇与应用
CN115232256B (zh) * 2021-04-22 2024-07-23 中国石油化工股份有限公司 一种高回弹聚合物多元醇的制备方法及得到的聚合物多元醇与应用
US11866543B2 (en) * 2021-05-06 2024-01-09 Covestro Llc Glycidyl (meth)acrylate polymer polyol stabilizers
US11952454B2 (en) 2021-10-18 2024-04-09 Covestro Llc Processes and production plants for producing polymer polyols
US12006413B2 (en) 2022-01-12 2024-06-11 Covestro Llc Polymer polyols, processes for their preparation, and the use thereof to produce foams exhibiting resistance to combustion

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3427256A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanide complex compounds
GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3427335A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an acyclic aliphatic saturated monoether,an ester and a cyclic ether and methods for making the same
US3427334A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity
DE1770548A1 (de) 1967-06-02 1972-02-10 Gen Tire & Rubber Co Polyester und ihre Herstellung
US3829505A (en) 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
AU552988B2 (en) 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
AU551979B2 (en) 1982-03-31 1986-05-15 Shell Internationale Research Maatschappij B.V. Epoxy polymerisation catalysts
US5059541A (en) 1988-04-29 1991-10-22 Neorx Corporation Minimal derivatization of proteins
US5011908A (en) 1988-07-12 1991-04-30 Arco Chemical Technology, Inc. Polymer polyol compositions and their use in the preparation of polyurethane foams
JP3097854B2 (ja) 1989-05-12 2000-10-10 旭硝子株式会社 ポリウレタン類の製造方法
US5059641A (en) 1990-01-10 1991-10-22 Arco Chemical Technology, Inc. Epoxy modified polyols as dispersants for high styrene, high solids content polymer polyols
US5196476A (en) 1990-06-12 1993-03-23 Arco Chemical Technology, L.P. Polymer/polyol and preformed stabilizer systems
WO1992012208A1 (fr) 1990-12-27 1992-07-23 Idemitsu Petrochemical Co., Ltd. Composition de resine polycarbonate
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
JP3357110B2 (ja) 1993-02-03 2002-12-16 旭硝子株式会社 ポリマー分散ポリオールの製造方法
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5545601A (en) 1995-08-22 1996-08-13 Arco Chemical Technology, L.P. Polyether-containing double metal cyanide catalysts
DE69518423T2 (de) 1995-10-10 2000-12-14 Bayer Ag Kontinuierliches Verfahren zur Herstellung von sehr stabilen, feinstteiligen, niedrig viskösen Polymerpolyolen mit niedriger durchmittlicher Teilchengrösse
ES2143080T3 (es) 1995-10-23 2000-05-01 Dow Chemical Co Poliol polimero y sistemas de estabilizador preconformado.
US6013731A (en) 1997-12-16 2000-01-11 Arco Chemical Technology L.P. Stabilizer based on high molecular weight polyols having low monol content for polymer polyol production
US6455603B1 (en) 1998-06-30 2002-09-24 Dow Global Technologies Inc. Polymer polyols and a process for the production thereof
US6172164B1 (en) * 1999-04-01 2001-01-09 Basf Corporation Process for making graft polyols using t-amyl peroxy free radical initiator
US6780932B2 (en) 2002-03-22 2004-08-24 Basf Corporation Graft polyols prepared by a continuous process
US8017664B2 (en) 2002-05-22 2011-09-13 Shell Oil Company Process for preparing polymer polyols
DE10319393A1 (de) 2003-04-30 2004-11-18 Bayer Materialscience Ag Flexible Formteile aus geschäumten Polyurethan und ihre Verwendung
HK1063576A2 (en) 2004-06-23 2004-11-26 John Mfg Ltd Multi-function optoelectronic air purifier.
US7759423B2 (en) * 2004-08-02 2010-07-20 Bayer Materialscience Llc Polymer polyols with ultra-high solids contents
US20070060690A1 (en) * 2005-09-09 2007-03-15 Bayer Materialscience Llc Low viscosity polymer polyols characterized by a high hydroxyl number
US20090281206A1 (en) 2006-07-05 2009-11-12 Dow Global Technologies Inc. Copolymer polyols and a process for the production thereof
EP2290002B1 (en) * 2008-06-16 2018-08-08 Sanyo Chemical Industries, Ltd. Polymer polyol and method for producing polyurethane
EP2408841B1 (de) * 2009-03-17 2014-11-19 Basf Se POLYURETHANFORMKÖRPER MIT VERBESSERTER WEITERREIßFESTIGKEIT UND VERBESSERTEM DAUERBIEGEVERHALTEN
JP5545364B2 (ja) 2010-04-30 2014-07-09 旭硝子株式会社 ポリオキシアルキレンポリオール、ポリマー分散ポリオール、および軟質ポリウレタンフォーム、ならびにこれらの製造方法

Also Published As

Publication number Publication date
WO2014151334A1 (en) 2014-09-25
US20140275471A1 (en) 2014-09-18
EP2970559A1 (en) 2016-01-20
EP2970559A4 (en) 2016-11-30
US8987396B2 (en) 2015-03-24
CN105051086A (zh) 2015-11-11

Similar Documents

Publication Publication Date Title
SA515361037B1 (ar) بوليولات بوليمر نشطة وعملية لإنتاجها
MX2015011761A (es) Polioles polimericos modificados con polibutadieno, espumas preparadas a partir de polioles polimericos modificados con polibutadieno, y procesos para su produccion.
MX2014012474A (es) Estabilizantes preformados utiles para la produccion de polioles polimericos y polioles polimericos producidos a partir de estos.
SA113340340B1 (ar) عملية إنتاج بوليمرات الدايين
EA033278B1 (ru) СПОСОБ ПОЛУЧЕНИЯ ТВЕРДОГО КОМПОНЕНТА КАТАЛИЗАТОРА НА ПОДЛОЖКЕ MgCl
SA114350667B1 (ar) بوادئ بلمرة جديدة ثنائية انونية واستخدامها
MXPA05002180A (es) Proceso para la produccion de polioles polimericos.
MX352477B (es) Proceso para producir materiales de bajo peso molecular a base de etileno y alfaolefina.
MX2017007092A (es) Espuma de poliuretano viscoelastica con dispersion acuosa de polimero.
MX2016008028A (es) Copolimero de propileno heterofasico.
MX360854B (es) Polímeros basados en etileno con una resistencia a la fusión mejorada, y procesos para lo mismo.
MX2014001245A (es) Metodo para producir un copolimero en bloque.
SG194760A1 (en) Stabilizer polymerization process and process for making polymer polyols
MX2016005089A (es) Fluorocopolimero curable formado a partir de tetrafluoropropeno.
IN2015DN01523A (ar)
IN2012DN02388A (ar)
MX2016002966A (es) Espuma flexible convencional a base de poliol de poliadicion de poliisocianato (pipa).
MX2015008003A (es) Un material de almacenamiento de hidrogeno.
SA518391793B1 (ar) بوليمر مشترك إيثيلين وبيوتادايين ذو بنية دقيقة متجانسة
MX2017000346A (es) Resina absorbente al agua y articulo absorbente.
MY183768A (en) Resin film and process for its production
HUE059586T2 (hu) Folyamatos eljárás nagy polimerizált etilén-oxid tartalmú poliéter-poliolok elõállítására kettõs fém-cianid katalizátor komplexum és egy magnézium-, 3-15. csoportú fém- vagy lantanoida sorozatú fémvegyület felhasználásával
MX2016016709A (es) Proceso para preparar polimeros basados en etileno que usa una distribucion de monoxido de carbono.
SA517381040B1 (ar) تركيبة مضادة للتآكل
MX362697B (es) Proceso de manufactura de poliol de poliadicion de poliisocianato y producto.