SA112340020B1 - تركيب حفاز لنزع الهيدروجين من الهيدروكربونات وطريقة لتحضيره - Google Patents

تركيب حفاز لنزع الهيدروجين من الهيدروكربونات وطريقة لتحضيره

Info

Publication number
SA112340020B1
SA112340020B1 SA112340020A SA112340020A SA112340020B1 SA 112340020 B1 SA112340020 B1 SA 112340020B1 SA 112340020 A SA112340020 A SA 112340020A SA 112340020 A SA112340020 A SA 112340020A SA 112340020 B1 SA112340020 B1 SA 112340020B1
Authority
SA
Saudi Arabia
Prior art keywords
component
hydrocarbons
dehydrogenation
catalyst composite
preparation
Prior art date
Application number
SA112340020A
Other languages
English (en)
Inventor
دونجارا راجيشوير
كوندا كريشنامورثي راماسوامي
يونيكريشنان سريدهاران
فاسوديراو لاندي شاراد
فايديا شاشانك
ساتيا بهاسكارا سيتا راما مورثي كاترافولابالي فينكاتا
شارما ناجيش
Original Assignee
ريليانس اندستريز ليمتد
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ريليانس اندستريز ليمتد filed Critical ريليانس اندستريز ليمتد
Publication of SA112340020B1 publication Critical patent/SA112340020B1/ar

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C07C5/325—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

يتعلق الاختراع الراهن بتركيب حفاز لنزع الهيدروجين dehydrogenation catalyst composite حيث يكون قادر على تزويد منتج هيدروكربوني منزوع الهيدروجين dehydrogenated hydrocarbon يتميز برقم برومينيّ bromine number يبلغ 19 على الأقل للهيدروكربونات hydrocarbons. ويشتمل حفاز نزع الهيدروجين hydrogen وفقاً للاختراع الراهن على معقد دقيق الحجم nano-sized complexيحتوي على مكون ينتمي إلى المجموعة VIII؛ مكون ينتمي إلى المجموعة IVA وعامل تغليف capping agent يحتوي على كبريت sulfur؛ مكون قلوي alkali؛ مكون هالوجيني halogen؛ ومادة داعمة support مع جزء لبّي داخلي inner core من ألفا ألومينا alpha alumina وطبقة خارجية outer layer مشتملة على خليط من غاما ألومينا gamma alumina ودلتا ألومينا delta alumina. [الشكل 2]
SA112340020A 2011-11-21 2012-11-21 تركيب حفاز لنزع الهيدروجين من الهيدروكربونات وطريقة لتحضيره SA112340020B1 (ar)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IN3190MU2011 2011-11-21

Publications (1)

Publication Number Publication Date
SA112340020B1 true SA112340020B1 (ar) 2015-10-07

Family

ID=48050877

Family Applications (1)

Application Number Title Priority Date Filing Date
SA112340020A SA112340020B1 (ar) 2011-11-21 2012-11-21 تركيب حفاز لنزع الهيدروجين من الهيدروكربونات وطريقة لتحضيره

Country Status (12)

Country Link
US (1) US20140323785A1 (ar)
EP (1) EP2782671A1 (ar)
KR (1) KR20140123929A (ar)
CN (1) CN104105546B (ar)
AR (1) AR088923A1 (ar)
AU (1) AU2012365439B2 (ar)
CA (1) CA2856323A1 (ar)
MX (1) MX2014006135A (ar)
RU (1) RU2612498C2 (ar)
SA (1) SA112340020B1 (ar)
TW (1) TWI577444B (ar)
WO (1) WO2013105112A1 (ar)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101535388B1 (ko) 2013-07-19 2015-07-08 주식회사 엘지화학 담지촉매, 이의 제조방법 및 이를 이용하여 제조된 탄소나노구조체의 2차구조물
WO2016005896A2 (en) * 2014-07-08 2016-01-14 Reliance Industries Limited Dehydrogenation catalyst composite and a process for the preparation thereof
CN104289219B (zh) * 2014-09-04 2017-01-25 辽宁石油化工大学 一种低碳烷烃脱氢催化剂的制备方法
CN104289220A (zh) * 2014-09-18 2015-01-21 南京沃来德能源科技有限公司 一种高热稳定性低碳烷烃脱氢催化剂的制法和用途
KR101716170B1 (ko) 2015-11-10 2017-03-14 희성촉매 주식회사 안정화 활성금속 복합체를 이용한 직쇄형 경질탄화수소류 탈수소화 촉매 제조방법
KR101814451B1 (ko) * 2015-11-10 2018-01-04 희성촉매 주식회사 안정화 활성금속 착체를 이용한 직쇄형 탄화수소류 탈수소화 촉매 제조방법
KR101981886B1 (ko) 2018-02-01 2019-05-23 효성화학 주식회사 탈수소화 촉매
EP3932544A4 (en) * 2019-02-28 2022-11-23 Cataler Corporation SUPPORTED CATALYST PARTICLES
US20210053034A1 (en) * 2019-08-23 2021-02-25 Uop Llc Dehydrogenation catalyst composition
CN112892612B (zh) * 2019-12-03 2023-01-17 中国石化集团金陵石油化工有限责任公司 一种用于烃类转化反应的催化剂
US11000832B1 (en) * 2020-03-13 2021-05-11 Uop Llc Dehydrogenation catalyst with minimized aromatic production
JP7235417B2 (ja) * 2020-08-28 2023-03-08 トヨタ自動車株式会社 排ガス浄化装置

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3562147A (en) 1968-04-24 1971-02-09 Universal Oil Prod Co Catalytic reforming of hydrocarbons
US3558477A (en) 1968-05-14 1971-01-26 Chevron Res Reforming with a platinum-rhenium catalyst
US3755481A (en) 1969-09-10 1973-08-28 Universal Oil Prod Co Dehydrogenation method and multicomponent catalytic composite for usetherein
US3632503A (en) 1969-09-10 1972-01-04 Universal Oil Prod Co Catalytic composite of platinum tin and germanium with carrier material and reforming therewith
US3584060A (en) 1970-06-08 1971-06-08 Universal Oil Prod Co Dehydrogenation with a catalytic composite containing platinum,rhenium and tin
US3682838A (en) 1970-06-26 1972-08-08 Universal Oil Prod Co Multicomponent dehydrogenation catalyst
US3761531A (en) 1970-06-26 1973-09-25 Universal Oil Prod Co Dehydrogenation with a multicomponent catalyst
US3878131A (en) 1971-09-29 1975-04-15 Universal Oil Prod Co Multicomponent dehydrogenation catalyst
US4077912A (en) 1972-10-12 1978-03-07 Standard Oil Company Catalysts useful for exothermic reactions
CA1002508A (en) 1972-11-30 1976-12-28 Takashi Ohara Method for the production of noble metal catalysts
US4104317A (en) 1976-05-10 1978-08-01 Uop Inc. Dehydrogenation method
US4430517A (en) 1981-12-02 1984-02-07 Uop Inc. Dehydrogenation process using a catalytic composition
US4495308A (en) 1983-03-04 1985-01-22 Chevron Research Company Two-region spherical catalysts
US4465789A (en) 1983-04-04 1984-08-14 American Cyanamid Company Hydrotreating catalyst support having dual pore structure
US4595673A (en) 1984-11-29 1986-06-17 Uop Inc. Dehydrogenation catalyst compositions and method of their preparation
US4672146A (en) 1985-07-02 1987-06-09 Uop Inc. Dehydrogenation catalyst compositions and its use in dehydrogenation
US4716143A (en) 1986-06-06 1987-12-29 Uop Inc. Dehydrogenation catalyst composition
US4827072A (en) 1986-06-06 1989-05-02 Uop Inc. Dehydrogenation catalyst composition and hydrocarbon dehydrogenation process
US5012027A (en) * 1986-06-06 1991-04-30 Uop Dual profile surface-impregnated dehydrogenation catalyst and process
US4762960A (en) 1987-02-25 1988-08-09 Uop Inc. Dehydrogenation catalyst composition and paraffin dehydrogenation
CN1013361B (zh) * 1987-03-13 1991-07-31 中国科学院大连化学物理研究所 饱和烃类脱氢用铂、锡、锂、硫催化剂
ATE78718T1 (de) * 1987-12-17 1992-08-15 Uop Inc Dehydrierungskatalysatorteilchen mit schichtstruktur.
CA2055929A1 (en) * 1990-12-14 1992-06-15 William C. Baird, Jr. Process for reforming at low severities with high activity, high yield tin modified platinum-iridium catalysts
US5200382A (en) 1991-11-15 1993-04-06 Exxon Research And Engineering Company Catalyst comprising thin shell of catalytically active material bonded onto an inert core
CN1032678C (zh) * 1992-12-21 1996-09-04 中国石油化工总公司 饱和烃类脱氢用催化剂
FR2704773B1 (fr) * 1993-05-06 1995-07-21 Inst Francais Du Petrole Procédé de préparation de catalyseurs utilisables en déshydrogénation.
US5681658A (en) * 1995-05-30 1997-10-28 Aluminum Company Of America Gelation-resistant alumina
US5677260A (en) 1995-06-23 1997-10-14 Indian Petrochemicals Corporation Limited Catalyst composite for dehydrogenation of paraffins to mono-olefins and method for the preparation thereof
US5935889A (en) * 1996-10-04 1999-08-10 Abb Lummus Global Inc. Catalyst and method of preparation
US6177381B1 (en) 1998-11-03 2001-01-23 Uop Llc Layered catalyst composition and processes for preparing and using the composition
FR2792550B1 (fr) * 1999-04-26 2001-06-01 Inst Francais Du Petrole Catalyseur comprenant un element des groupes 8,9 et 10 presentant une bonne accessibilite et son utilisation dans un procede de deshydrogenation des paraffines
US6417135B1 (en) 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
US6756515B2 (en) 2001-06-22 2004-06-29 Uop Llc Dehydrogenation process using layered catalyst composition
US6486370B1 (en) * 2001-06-22 2002-11-26 Uop Llc Dehydrogenation process using layered catalyst composition
US20050265920A1 (en) * 2002-11-11 2005-12-01 Conocophillips Company Supports and catalysts comprising rare earth aluminates, and their use in partial oxidation
US7408089B2 (en) * 2004-03-19 2008-08-05 Catalytic Distillation Technologies Ni catalyst, process for making catalysts and selective hydrogenation process
GB0410408D0 (en) * 2004-05-11 2004-06-16 Johnson Matthey Plc Catalysts
US7687676B1 (en) * 2005-02-18 2010-03-30 Uop Llc Dehydrogenation process with water and temperature control
US8524971B2 (en) * 2009-03-18 2013-09-03 Uop Llc Catalyst for higher production rates in hydrocarbon dehydrogenation
CN101992085B (zh) * 2009-08-31 2013-04-03 中国石油化工股份有限公司 用于氢气选择性燃烧反应的催化剂及其制备方法
CA2881920A1 (en) * 2012-08-13 2014-03-06 Reliance Industries Limited A dehydrogenation catalyst for hydrocarbons and method of preparation thereof

Also Published As

Publication number Publication date
CA2856323A1 (en) 2013-07-18
MX2014006135A (es) 2015-09-07
AU2012365439A1 (en) 2015-08-06
CN104105546A (zh) 2014-10-15
TW201334864A (zh) 2013-09-01
CN104105546B (zh) 2016-10-19
AR088923A1 (es) 2014-07-16
RU2612498C2 (ru) 2017-03-09
TWI577444B (zh) 2017-04-11
WO2013105112A1 (en) 2013-07-18
KR20140123929A (ko) 2014-10-23
RU2014125147A (ru) 2015-12-27
EP2782671A1 (en) 2014-10-01
WO2013105112A8 (en) 2014-01-03
US20140323785A1 (en) 2014-10-30
AU2012365439B2 (en) 2017-04-13

Similar Documents

Publication Publication Date Title
SA112340020B1 (ar) تركيب حفاز لنزع الهيدروجين من الهيدروكربونات وطريقة لتحضيره
HK1199223A1 (en) Catalytic composition and process for the dehydrogenation of butenes or mixtures of butanes and butenes to give 1,3-butadiene 13-
WO2009119975A3 (ko) 연속 흐름식 2중 촉매 반응 장치를 이용하여 노르말-부텐으로부터 1,3-부타디엔을 제조하는 방법
WO2016005896A3 (en) Dehydrogenation catalyst composite and a process for the preparation thereof
EP3967783A4 (en) ORGANIC HYDROGEN STORAGE RAW MATERIALS DEHYDROGENATION CATALYST, CATALYST SUPPORT, HYDROGEN STORAGE ALLOY AND HIGH PURITY HYDROGEN SUPPLY METHOD
WO2011150217A3 (en) Conversion of liquid heavy hydrocarbon feedstocks to gaseous products
MX2013006308A (es) Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados.
EP2873458A4 (en) BY THE OXYDATION AND DEHYDRATION OF BUTYLENE PRODUCED BUTADIA CATALYST FOR SWIVEL LAYER REACTOR AND MANUFACTURING PROCESS AND USE
EP2300157A4 (en) CATALYST FOR DEHYDROGENATION OF HYDROCARBONS
MX354839B (es) Deshidrogenación de alcanoles para incrementar la producción de compuestos aromáticos.
MX2015001915A (es) Un catalizador de deshidrogenacion para hidrocarburos y un metodo para la preparacion del mismo.
EA033166B1 (ru) Способ конверсии углеводородов в олефины
WO2012078435A3 (en) Process and apparatus for oligomerizing one or more hydrocarbons
EP2604590A4 (en) METHOD FOR PRODUCING UNSATURATED HYDROCARBONS AND DEHYDRATION CATALYST USED IN THIS PROCESS
SG2014007173A (en) Premixer, radially fixed bed reactor, and reaction system for oxidative dehydrogenation of butene
MY166947A (en) Process for the alkylation of aromatic hydrocarbons with olefins
MY159792A (en) Methods for co-production od alkylbenzene and biofuel from natural oils using hydrocracking
BR112014012128A8 (pt) veículo para catalisadores de óxido de etileno
MY160581A (en) Method for the selective hydrogenation of polyunsaturated hydrocarbons in olefin-containing hydrocarbon mixtures
MY161864A (en) Methods for co-production of alkylbenzene and biofuel from natural oils
EP3892373A4 (en) CATALYST STRUCTURE AND METHOD OF PRODUCTION THEREOF AND METHOD OF PRODUCTION OF HYDROCARBON USING A CATALYST STRUCTURE
ES1088956U (es) Neumático macizo provisto de medios de indicación visual del estado de desgaste excesivo
WO2014083426A8 (en) Method for demethylating or demethoxylating aromatic compound having methoxy group and catalyst used in the method
WO2012112380A3 (en) Alkylation process and catalysts for use therein
MX2014015731A (es) Proceso para la conversión de oxigenatos en olefinas.