RU97122261A - COMPOSITION FOR OXIDATIVE COLORING KERATIN FIBERS, COLORING METHOD USING THIS COMPOSITION AND SET FOR COLORING - Google Patents

COMPOSITION FOR OXIDATIVE COLORING KERATIN FIBERS, COLORING METHOD USING THIS COMPOSITION AND SET FOR COLORING

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RU97122261A
RU97122261A RU97122261/14A RU97122261A RU97122261A RU 97122261 A RU97122261 A RU 97122261A RU 97122261/14 A RU97122261/14 A RU 97122261/14A RU 97122261 A RU97122261 A RU 97122261A RU 97122261 A RU97122261 A RU 97122261A
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amino
composition
para
alkyl
composition according
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RU97122261/14A
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RU2160086C2 (en
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Рондо Кристин
Коттере Жан
Де Ля Меттри Ролан
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Л'Ореаль
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1. Красящая композиция для окислительного окрашивания окислением кератиновых волокон и, в частности, кератиновых волокон человека, таких как волосы, готовая к употреблению, отличающаяся тем, что она содержит в подходящей для окрашивания среде по меньшей мере одно окислительное основание, по меньшей мере одну краскообразующую компоненту, выбираемую среди метааминофенолов следующей формулы I и их аддитивных солей с кислотой:
Figure 00000001

где R1 является атомом водорода, алкилом с C1-C4, моногидроксиалкилом с C1-C4 или полигидроксиалкилом с C2-C4;
R2 является атомом водорода, алкилом с C1-C4, алкоксилом с C1-C4 или атомом галогена, выбираемого среди хлора, брома или фтора,
R3 является алкилом с C1-C4, алкоксилом с C1-C4, моногидроксиалкилом с C1-C4, полигидроксиалкилом с C2-C4, моногидроксиалкоксилом с C1-C4 или полигидроксиалкоксилом с C2-C4,
по меньшей мере один прямой катионный краситель, выбираемый среди соединений следующей формулы II:
Figure 00000002

где D является атомом азота или группой -СН;
R4 и R5, одинаковые или различные, являются атомом водорода; алкилом с C1-C4, который может быть замещен радикалом -CN, -ОН или NH2, или образуют с атомом углерода бензольного цикла гетероцикл, возможно содержащий кислород или азот, который может быть замещен одним или несколькими алкилами с C1-C4; радикал 4'-аминофенил;
R6 является атомом водорода или галогена, выбираемого среди хлора, брома, иода или фтора, алкоксилом с C1-C4 или ацетилоксилом;
Х является анионом, предпочтительно выбираемым среди хлорида, метилсульфата и ацетата;
А является группой, выбираемой среди следующих структур:
Figure 00000003

Figure 00000004

Figure 00000005

Figure 00000006

Figure 00000007

Figure 00000008

Figure 00000009

Figure 00000010

Figure 00000011

Figure 00000012

где R7 является алкилом с C1-C4, который может быть замещен гвдроксилом, a R8 является алкоксилом с C1-C4, при условии что, когда D является -СН, А является А4 или А13 и R6 не является алкоксилом, тогда R4 и R5 не обозначают одновременно атом водорода;
и по меньшей мере один окислитель.1. Ink dyeing composition for oxidative dyeing by oxidation of keratin fibers and, in particular, human keratin fibers, such as ready-to-use hair, characterized in that it contains at least one oxidative base in an environment suitable for dyeing, at least one paint-producing component selected among metaminophenol following formula I and their additive salts with acid:
Figure 00000001

where R 1 is a hydrogen atom, alkyl with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 or polyhydroxyalkyl with C 2 -C 4 ;
R 2 is a hydrogen atom, alkyl with C 1 -C 4 , alkoxy with C 1 -C 4 or halogen atom selected among chlorine, bromine or fluorine,
R 3 is alkyl with C 1 -C 4 , alkoxy with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 , polyhydroxyalkyl with C 2 -C 4 , monohydroxyalkoxy with C 1 -C 4 or polyhydroxyalkoxy with C 2 -C 4 ,
at least one direct cationic dye selected among compounds of the following formula II:
Figure 00000002

where D is a nitrogen atom or a —CH group;
R 4 and R 5 , the same or different, are a hydrogen atom; alkyl with C 1 -C 4 , which may be substituted by a -CN, -OH or NH 2 radical, or form a heterocycle with a carbon atom of the benzene ring, possibly containing oxygen or nitrogen, which may be substituted with one or more C 1 -C alkyl; 4 ; 4'-aminophenyl radical;
R 6 is a hydrogen or halogen atom selected from chlorine, bromine, iodine or fluorine, alkoxy with C 1 -C 4 or acetyloxy;
X is an anion, preferably selected among chloride, methyl sulfate and acetate;
A is a group selected among the following structures:
Figure 00000003

Figure 00000004

Figure 00000005

Figure 00000006

Figure 00000007

Figure 00000008

Figure 00000009

Figure 00000010

Figure 00000011

Figure 00000012

where R 7 is alkyl with C 1 -C 4 that may be substituted with hydroxy, and R 8 is alkoxy with C 1 -C 4 , provided that when D is -CH, A is A 4 or A 13 and R 6 is not alkoxy, then R 4 and R 5 do not simultaneously denote a hydrogen atom;
and at least one oxidizing agent. 2. Композиция по п. 1, отличающаяся тем, что окислительное основание или основания, выбраны среди парафенилендиаминов, бифенилалкилендиаминов, парааминофенолов, ортоаминофенолов и гетероциклических окислительных оснований. 2. The composition according to claim 1, characterized in that the oxidizing base or bases selected from para-phenylenediamines, biphenylalkylenediamines, para-aminophenols, ortho-aminophenols and heterocyclic oxidative bases. 3. Композиция по п. 2, отличающаяся тем, что окислительное основание или основания выбраны среди парафенилендиаминов и парааминофенолов. 3. The composition according to p. 2, characterized in that the oxidizing base or bases selected among para-phenylenediamine and para-aminophenols. 4. Композиция по п. 2 или 3, отличающаяся тем, что парафенилендиамины выбраны среди соединений следующей формулы III и их аддитивных солей с кислотой:
Figure 00000013

где R9 является атомом водорода, алкилом с C1-C4, моногиароксиалкилом с C1-C4, полигидроксиалкилом с C2-C4, фенилом, 4'-аминофенилом или алкокси(C1-C4)алкилом с C1-C4;
R10 является атомом водорода, алкилом с C1-C4, моногидроксиалкилом с C1-C4, полигидроксиалкилом с C2-C4;
R11 является атомом водорода, атомом галогена, таким как атом хлора, брома, иода или фтора, алкилом с C1-C4, моногидроксиалкилом с C1-C4, гидроксиалкоксилом с C1-C4 ацетиламиноалкоксилом с C1-C4, мезиламиноалкоксилом с C1-C4 или карбомоиламиноалкоксилом с C1-C4;
R1 является атомом водорода или алкилом с C1-C4.4. The composition according to p. 2 or 3, characterized in that the paraphenylenediamine selected among the compounds of the following formula III and their additive salts with acid:
Figure 00000013

where R 9 is a hydrogen atom, alkyl with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 , polyhydroxyalkyl with C 2 -C 4 , phenyl, 4'-aminophenyl or alkoxy (C 1 -C 4 ) alkyl with C 1 -C 4 ;
R 10 is a hydrogen atom, alkyl with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 , polyhydroxyalkyl with C 2 -C 4 ;
R 11 is a hydrogen atom, a halogen atom such as a chlorine, bromine, iodine or fluorine atom, alkyl with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 , hydroxyalkoxy with C 1 -C 4 acetylaminoalkoxy with C 1 -C 4 , mesylaminoalkoxy with C 1 -C 4 or carbamoylaminoalkoxy with C 1 -C 4 ;
R 1 is a hydrogen atom or alkyl with C 1 -C 4 . 5. Композиция по п. 4, отличающаяся тем, что парафенилендиамины формулы III выбраны среди парафенилендиамина, паратолуилендиамина, 2-хлорпарафенилендиамина, 2,3-диметилпарафенилендиамина, 2,6-диметилпарафенилендиамина, 2,6-диэтилпарафенилендиамина, 2,5-диметилпгфафенилендиамина, N,N-димeтилпapaфeнилeндиaминa, N,N-диэтилпарафенилендиамина, N,N-дипропилпарафенилендиамина, 4-амино-N,N-диэтил-3-метиланилина, N,N-бис-β- гидроксиэтил)парафенилендиамина, 4-амино-N,N-бис(β-гидроксиэтил)-3-метиланилина, 4-aминo-3-xлop-N,N-биc(β-гидpoкcиэтил)aнилинa, 2-β-гидpoкcиэтилпapaфeнилeндиaминa, 2-фторпарафенилендиамина, 2-изопропилпарафенилендиамина, N-β- гидроксипропил)парафенилендиамина, 2-гидроксиметилпарафенилендиамина, N,N-димeтил-3- метилпарафенилендиамина, N,N-(этил,β- гидроксиэтил)парафенилендиамина, N-β,γ- дигидроксипропил)парафенилендиамина, N-(4'-аминофенил)-парафенилендиамина, N-фeнилпapaфeнилeндиaминa, 2-β- гидроксиэтилоксипарафенилендиамина, 2-β- ацетиламиноэтилоксипарафенилендиамина и их аддитивных солей с кислотой. 5. The composition according to p. 4, characterized in that the paraphenylenediamines of the formula III are selected among paraphenylene diamine, pee tafluamide diamine, 2-chloroparaphenylene diamine, 2,3-dimethyl paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl para-phenylenediamine, 2,5-dimethyl para-phenylenediamine, 2,6-diethyl para-phenylenediamine, 2,5-dimethyl para-phenylenediamine, 2,6-diethyl para-phenylenediamine, 2,5-dimethyl para-phenylenediamine, 2,6-diethyl para-phenylenediamine, 2-teh , N-Dimethyl-para-phenylenediamine, N, N-diethyl para-phenylenediamine, -bis (β-hydroxyethyl) -3-methylaniline, 4-amino-3-chlorop-N, N-bis (β-hydroxyethyl) aniline, 2-β-hydroxyethylpapaphenylenedia ina, ftorparafenilendiamina-2, 2-izopropilparafenilendiamina, N-β- hydroxypropyl) paraphenylenediamine, 2-gidroksimetilparafenilendiamina, N, N-dimethyl-3- metilparafenilendiamina, N, N- (ethyl, β- hydroxyethyl) para-phenylenediamine, N-β, γ - dihydroxypropyl) paraphenylenediamine, N- (4'-aminophenyl) para-phenylenediamine, N-phenyl para-phenylenediamine, 2-β-hydroxyethyloxy para-phenylenediamine, 2-β-acetylamino-ethyloxy paraphenylenediamine, and their additive salts, and their salts, and their salts, 2-hydroxyethyloxyphenylenediamine, 2-β-acetylaminoethyloxy paraphenylenediamine, 2-β-hydroxyethyloxyphenylenediamine, 2-β-acetylaminoethylaphenylenediamine, 2-β-hydroxyethyloxyphenylenediamine, 2-β-acetylaminoethylaphenylenediamine 6. Композиция по п. 2, отличающаяся тем, что бифенилалкилендиамины выбраны среди соединений следующей формулы IV и их аддитивных солей с кислотой. 6. The composition according to p. 2, characterized in that the biphenylalkylenediamine selected among the compounds of the following formula IV and their additive salts with acid.
Figure 00000014

где Z1 и Z2, одинаковые или различные, являются гидроксилом или NHR16, в котором R16 является атомом водорода или алкилом с C1-C4,
R13 является атомом водорода, алкилом с C1-C4, моногидроксиалкилом с C1-C4, полигидроксиалкилом с C2-C4 или аминоалкилом с C1-C4, аминный остаток которого может быть замещен,
R14 и R15, одинаковые или различные, являются атомом водорода или галогена или алкилом с C1-C4,
Y является радикалом, взятым из группы, образованной следующими радикалами:
-(СН2)n; -(СН2)m-O-(СН2)m; -(СН2)m-СНОН-(СН2)m и
Figure 00000015

где n - целое число от 0 до 8 включительно;
m - целое число от 0 до 4 включительно.
Figure 00000014

where Z 1 and Z 2 , identical or different, are hydroxyl or NHR 16 , in which R 16 is a hydrogen atom or alkyl with C 1 -C 4 ,
R 13 is a hydrogen atom, alkyl with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 , polyhydroxyalkyl with C 2 -C 4 or aminoalkyl with C 1 -C 4 , the amine residue of which may be substituted,
R 14 and R 15 , the same or different, are a hydrogen or halogen atom or alkyl with C 1 -C 4 ,
Y is a radical taken from the group formed by the following radicals:
- (CH 2 ) n ; - (CH 2 ) m —O- (CH 2 ) m ; - (CH 2 ) m -CHOH- (CH 2 ) m and
Figure 00000015

where n is an integer from 0 to 8 inclusive;
m is an integer from 0 to 4 inclusive. 7. Композиция по п. 6, отличающаяся тем, что бифенилалкилендиамины формулы IV выбраны среди N,N'-бис-β-гидроксиэтил N,N'-бис-(4'-аминофенил)-1,3-диаминопропанола, N,'N-бис-β-гидроксиэтил) N,N'-биc(4'-aминoфeнил)этилeндиaминa, N, N-бис(4-аминофенил)тетраметилендиамина, N, N'-биc-β-гидpoкcиэтил) N,N'- бис(4-аминофенил)тетраметилендиамина, N,N'-бис(4-метиламинофенил)тетраметилендиамина, N, N'-бис(этил)-N, N'-бис(4'-амино-3'-метилфенил)этилендиамина их аддитивных солей с кислотой. 7. The composition according to p. 6, characterized in that the biphenylalkylenediamines of formula IV are selected from among N, N'-bis-β-hydroxyethyl N, N'-bis- (4'-aminophenyl) -1,3-diaminopropanol, N, ' N-bis-β-hydroxyethyl) N, N'-bis (4'-aminophenyl) ethylenediamine, N, N-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis-β-hydroxyethyl) N, N'- bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (4-methylaminophenyl) tetramethylenediamine, N, N'-bis (ethyl) -N, N'-bis (4'-amino-3'-methylphenyl) ethylenediamine them acid addition salts. 8. Композиция по п. 2 или 3, отличающаяся тем, что парааминофенолы выбраны среди соединений следующей формулы V и их добавочных солей с кислотой
Figure 00000016

где R17 является атомом водорода или фтора, алкилом с C1-C4, моногидроксиалкилом с C1-C4, алкокси(C1-C4)алкил(C1-C4), аминоалкилом с C1-C4 или гидроксиалкил(C1-C4)аминоалкилом с C1-C4,
R18 является атомом водорода или фтора, алкилом с C1-C4, моногидроксиалкилом с C1-C4, полигидроксиалкилом с C2-C4, аминоалкилом с C1-C4, цианоалкилом с C1-C4 или алкокси(C1-C4)алкил (C1-C4),
при условии, что по меньшей мере один из радикалов R1 или R18 является атомом водорода.8. The composition according to p. 2 or 3, characterized in that the para-aminophenol selected among the compounds of the following formula V and their added salts with acid
Figure 00000016

where R 17 is a hydrogen or fluorine atom, alkyl with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 , alkoxy (C 1 -C 4 ) alkyl (C 1 -C 4 ), aminoalkyl with C 1 -C 4 or hydroxyalkyl (C 1 -C 4 ) aminoalkyl with C 1 -C 4 ,
R 18 is a hydrogen or fluorine atom, alkyl with C 1 -C 4 , monohydroxyalkyl with C 1 -C 4 , polyhydroxyalkyl with C 2 -C 4 , aminoalkyl with C 1 -C 4 , cyanoalkyl with C 1 -C 4 or alkoxy ( C 1 -C 4 ) alkyl (C 1 -C 4 ),
provided that at least one of the radicals R 1 or R 18 is a hydrogen atom. 9. Композиция по п. 8, отличающаяся тем, что парааминофенолы формулы V выбраны среди парааминофенола, 4-амино-3-метилфенола, 4-амино-3-фторфенола, 4-амино-3-гидроксиметилфенола, 4-амино-2-метилфенола, 4-амино-2-гидроксиметилфенола, 4-амино-2-метоксиметилфенола, 4-амино-2-аминометилфенола, 4-амино-2-β- гадроксиэтиламинометил)фенола, 4-амино-2-фторфенола и их аддитивных солей с кислотой. 9. The composition according to p. 8, characterized in that the para-aminophenols of formula V are selected among para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-2-methylphenol , 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2-β-hydroxyethylaminomethyl) phenol, 4-amino-2-fluorophenol and their addition salts with an acid . 10. Композиция по п. 2, отличающаяся тем, что ортоаминофенолы, выбраны среди 2-аминофенола, 2-амино-5-метилфенола, 2-амино-6-метилфенола, 5-ацетамидо-2-аминофенола и их аддитивных солей с кислотой. 10. The composition according to p. 2, characterized in that the orthoaminophenols are selected among 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 5-acetamido-2-aminophenol and their acid addition salts. 11. Композиция по п. 2, отличающаяся тем, что гетероциклические основания, выбраны среди пиридиновых производных, пиримидиновых производных, пиразольных производных и их аддитивных солей с кислотой. 11. The composition according to p. 2, characterized in that the heterocyclic bases selected from pyridine derivatives, pyrimidine derivatives, pyrazole derivatives and their additive salts with acid. 12. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что мегааминофенолы формулы 1 выбраны среди 5-амино-2-метоксифенола, 5-амино-2-(β-гидроксиэтилокси)фенола, 5-амино-2-метилфенола, 5-N-(β-гидpoкcиэтил)aминo-2-мeтилфeнoлa, 5-N-(β-гидрооксиэтил)амино-4-метокси-2-метилфенола, 5-амино-4-метокси-2-метилфенола, 5-амино-4-хлор-2-метилфенола, 5-амино-2,4-диметоксифенола, 5-(γ-гидроксипропиламино)-2-метилфенола и их аддитивных солей с кислотой. 12. The composition according to any one of the preceding paragraphs, characterized in that the megaaminophenols of formula 1 are selected from 5-amino-2-methoxyphenol, 5-amino-2- (β-hydroxyethoxy) phenol, 5-amino-2-methylphenol, 5 -N- (β-hydroxyethyl) amino-2-methylfenol, 5-N- (β-hydroxyethyl) amino-4-methoxy-2-methylphenol, 5-amino-4-methoxy-2-methylphenol, 5-amino-4 -chloro-2-methylphenol, 5-amino-2,4-dimethoxyphenol, 5- (γ-hydroxypropylamino) -2-methylphenol and their acid addition salts. 13. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что прямые катионные красители формулы II выбраны среди соединений, отвечающих структурам (II1) -(II43), приведенным в описании. 13. The composition according to any of the preceding paragraphs, characterized in that the direct cationic dyes of formula II are selected among the compounds corresponding to the structures (II1) - (II43) given in the description. 14. Композиция по п. 13, отличающаяся тем, что прямые катионные красители формулы (II) выбраны среди соединений, отвечающих структурам (II1), (II2), (II14) и (II31). 14. The composition according to p. 13, characterized in that the direct cationic dyes of formula (II) are selected among the compounds corresponding to the structures (II1), (II2), (II14) and (II31). 15. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что аддитивные соли с кислотой выбраны среди хлоргидратов, бромгидратов, сульфатов и тартратов. 15. The composition according to any one of the preceding paragraphs, characterized in that the acid addition salts with the acid are chosen among the chlorohydrates, hydrobromous, sulphates and tartrates. 16. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что окислитель выбран среди перекиси водорода, перекиси мочевины, броматов щелочных металлов, персолей, таких как пербораты и персульфаты. 16. The composition according to any one of the preceding paragraphs, characterized in that the oxidizing agent is selected among hydrogen peroxide, urea peroxide, alkali metal bromates, persalts, such as perborates and persulfates. 17. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что окислительное основание или основания составляет 0,0001 - 10 мас.% от общего веса готовой к применению красящей композиции. 17. The composition according to any one of the preceding paragraphs, characterized in that the oxidizing base or bases is 0.0001 - 10 wt.% Of the total weight of the coloring composition ready for use. 18. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что мегааминофенол или мегааминофенолы формулы (I) составляют 0,0001 - 5 мас.% от общего веса готовой к применению красящей композиции. 18. The composition according to any one of the preceding paragraphs, characterized in that the megaaminophenol or megaaminophenols of formula (I) comprise 0.0001 to 5% by weight of the total ready-to-use dye composition. 19. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что прямой катионный краситель или красители формулы (II) составляет 0,001 - 10 мас.% от общего веса готовой к применению красящей композиции. 19. The composition according to any one of the preceding paragraphs, characterized in that the direct cationic dye or dyes of formula (II) is 0.001 - 10 wt.% Of the total weight of the coloring composition ready for use. 20. Композиция по какому-либо из предыдущих пунктов, отличающаяся тем, что она имеет рН 5-12. 20. The composition according to any of the preceding paragraphs, characterized in that it has a pH of 5-12. 21. Композиция по какому-либо из предыдущих признаков, отличающаяся тем, что подходящая для окрашивания среда состоит из воды или из смеси воды и по меньшей мере одного органического растворителя. 21. Composition according to one of the preceding features, characterized in that the medium suitable for dyeing consists of water or a mixture of water and at least one organic solvent. 22. Способ окрашивания кератиновых волокон и, в частности, кератиновых волокон человека, таких как волосы, отличающийся тем, что наносят на эти волокна по меньшей мере одну красящую композицию, такую как определенная в каком-либо из пп. 1-21. 22. A method of dyeing keratin fibers and, in particular, human keratin fibers, such as hair, characterized in that at least one dye composition is applied to these fibers, such as that defined in any one of claims. 1-21. 23. Способ по п. 22, отличающийся тем, что он включает предварительную стадию, заключающуюся в раздельном хранении, с одной стороны, композиции (А), включающей в подходящей для окрашивания среде по меньшей мере одно окислительное основание, по меньшей мере одну краскообразующую компоненту, выбираемую среди мегааминофенолов формулы (I), таких как определены в п. 1 или 12, и по меньшей мере один прямой катионный краситель, выбираемый среди соединений формулы (II), таких как определены в п. 1, 13 или 14, а с другой стороны, композиции (Б), содержащей в подходящей для окрашивания среде по меньшей мере один окислитель, и в их смешивании в момент употребления перед нанесением этой смеси на кератиновые волокна. 23. The method according to p. 22, characterized in that it includes a preliminary stage, consisting in separate storage, on the one hand, the composition (A), comprising at least one oxidizing base in a medium suitable for dyeing, at least one paint-forming component selected among the megaaminophenols of formula (I), such as those defined in section 1 or 12, and at least one direct cationic dye chosen among compounds of formula (II), such as those defined in section 1, 13, or 14, and c on the other hand, the composition (B) containing in the approach boiling dyeing medium, at least one oxidizing agent, and in mixing them together at the time of use before applying this mixture to the keratin fibers. 24. Способ окрашивания по п. 22, отличающийся тем, что он включает предварительную стадию, заключающуюся в раздельном хранении, с одной стороны, композиции (А), включающей в подходящей для окрашивания среде, по меньшей мере, одно окислительное основание, по меньшей мере, одну краскообразующую компоненту, выбираемую среди мегааминофенолов формулы (I), таких как определены в п. 1 или 12, а с другой стороны, композиции (А'), включающей в подходящей для окрашивания среде по меньшей мере, один прямой катионный краситель, выбираемый среди соединений формулы (II), определенных в п. 1, 13 или 14, и, наконец, композиции (Б), содержащей в подходящей для окрашивания среде, по меньшей мере один окислитель, и в их смешивании в момент употребления перед нанесением этой смеси на кератиновые волокна. 24. The method of dyeing according to claim 22, characterized in that it includes a preliminary stage consisting in separate storage, on the one hand, of composition (A), comprising, in a suitable medium for dyeing, at least one oxidizing base, at least , one kraskoobrazuyuschego component selected among the megaaminophenols of formula (I), such as defined in claim 1 or 12, and on the other hand, the composition (A '), which includes at least one direct cationic dye chosen by the medium suitable for dyeing among compounds form ly (II), defined in paragraphs 1, 13 or 14, and, finally, composition (B) containing at least one oxidizing agent in a medium suitable for dyeing, and mixing them at the time of use before applying this mixture to keratin the fibers. 25. Способ по п. 24, отличающийся тем, что композиция (А') представлена в виде порошка. 25. The method according to p. 24, characterized in that the composition (A ') is presented in powder form. 26. Устройство с несколькими отделениями или "набор" для окрашивания, отличающееся тем, что в первом отделении содержится композиция (А), такая как определена в п. 23, а во втором отделении содержится окислительная композиция (Б). 26. A device with several compartments or a “dyeing kit”, characterized in that the first compartment contains the composition (A), such as defined in § 23, and the second compartment contains the oxidative composition (B). 27. Устройство с несколькими отделениями или "набор" для окрашивания, отличающееся тем, что в первом отделении содержится композиция А', такая как определена в пункте 24, во втором отделении содержится композиция А', такая как определена в п. 24 или 25, а в третьем отделении содержится окислительная композиция (Б). 27. A device with several compartments or a dyeing kit, characterized in that the first compartment contains composition A ', such as defined in paragraph 24, the second compartment contains composition A', such as defined in paragraph 24 or 25, and in the third compartment contains the oxidizing composition (B).
RU97122261/14A 1996-12-23 1997-12-22 Composition for oxidative dyeing of keratin fibers, method of dyeing using this composition, and dyeing kit RU2160086C2 (en)

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FR3067599B1 (en) 2017-06-16 2020-09-04 Oreal PROCESS FOR COLORING KERATINIC MATERIALS USING AT LEAST ONE BLUE, PURPLE OR GREEN COLOR AND AT LEAST ONE FLUORESCENT COLORANT DISULPHIDE, THIOL OR PROTECTED THIOL
FR3083100B1 (en) 2018-06-27 2021-01-15 Oreal COLORING COMPOSITION CONSISTING OF A DIRECT DYE, A PEROXYGEN SALT AND A CYCLODEXTRIN, AND PROCESS USING THIS COMPOSITION
FR3083106B1 (en) 2018-06-29 2020-10-02 Oreal PROCESS FOR COLORING KERATINIC FIBERS USING A MONOSACCHARIDE, A POLYSACCHARIDE WITH AMINO GROUPS AND A COLORING MATTER
FR3090345B1 (en) 2018-12-21 2021-06-25 Oreal Process for dyeing keratin materials using a direct dye and an aliphatic ammonium salt and composition comprising them
FR3090349B1 (en) 2018-12-21 2020-12-18 Oreal Process for dyeing keratin materials using a direct dye and a saturated heterocyclic salt and composition comprising them
FR3090358B1 (en) 2018-12-21 2020-12-18 Oreal Process for dyeing keratin materials using a direct dye and an unsaturated heterocyclic salt and composition comprising them
IT201900008040A1 (en) 2019-06-04 2020-12-04 Pool Service S R L Composition in gel for oxidation coloring hair and other keratin fibers, and related coloring method
FR3097438B1 (en) 2019-06-24 2021-12-03 Oreal Anhydrous composition comprising at least one amino silicone, at least one alkoxysilane and at least one coloring agent
FR3097752B1 (en) 2019-06-27 2023-10-13 Oreal Process for coloring keratin fibers using a particular cyclic polycarbonate, a compound comprising at least one amine group and a coloring agent, composition and device
FR3097760B1 (en) 2019-06-28 2022-04-01 Oreal Process for dyeing keratin fibers comprising the application of an extemporaneous mixture of a direct dye and a composition comprising a liquid fatty substance, a solid fatty substance and a surfactant.
FR3097755B1 (en) 2019-06-28 2021-07-16 Oreal Process for dyeing keratin fibers comprising a step of cold plasma treatment of said fibers
FR3098114B1 (en) 2019-07-05 2022-11-11 Oreal Composition comprising a natural dye, a hydrazono and/or azo cationic synthetic direct dye and an aromatic compound
FR3103090A1 (en) 2019-11-20 2021-05-21 L'oreal Coloring or lightening process using a hand-held hairdressing device and a substrate
FR3104983B1 (en) 2019-12-20 2023-11-24 Oreal Hair coloring composition comprising a direct dye, a scleroglucan gum and a nonionic associative polymer.
FR3104952B1 (en) 2019-12-20 2022-08-26 Oreal Process for the cosmetic treatment of keratin fibers using a coloring composition and a composition based on rare earths
FR3109313B1 (en) 2020-04-15 2022-11-25 Oreal METHOD FOR THE TREATMENT OF KERATIN MATERIALS USING AN ACRYLIC POLYMER OF ANHYDRIDE IN OILY DISPERSION AND A HYDROXYL AND/OR THIOLE COMPOUND
FR3111553A1 (en) 2020-06-22 2021-12-24 L'oreal Process for dyeing keratin fibers using a direct dye and a saccharinate salt and composition comprising them
FR3111557B1 (en) 2020-06-23 2022-11-25 Oreal Cosmetic composition comprising a polyhydroxyalkanoate copolymer comprising at least two different polymeric units with an (un)saturated hydrocarbon chain in a fatty medium
FR3111552B1 (en) 2020-06-23 2024-04-05 Oreal Composition for the simultaneous bleaching and coloring of keratin fibers comprising a particular heterocyclic salt and process using this composition
FR3111812B1 (en) 2020-06-24 2023-02-10 Oreal Cosmetic composition comprising a grafted polyhydroxyalkanoate copolymer in a fatty medium
FR3117806B1 (en) 2020-12-18 2024-03-01 Oreal Composition for the simultaneous bleaching and coloring of keratin fibers and process using this composition
FR3117807B1 (en) 2020-12-18 2024-03-01 Oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3117809B1 (en) 2020-12-18 2024-02-16 Oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3117805B1 (en) 2020-12-18 2024-02-16 Oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
US20240082121A1 (en) 2020-12-18 2024-03-14 L'oreal Process for lightening keratin fibres
FR3117808B1 (en) 2020-12-18 2024-03-01 Oreal Composition for the simultaneous bleaching and coloring of keratin fibers and process using this composition
FR3130569B1 (en) 2021-12-16 2024-06-28 Oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3130572A1 (en) 2021-12-16 2023-06-23 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3130571B1 (en) 2021-12-16 2024-02-16 Oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3130567B1 (en) 2021-12-16 2024-02-16 Oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3130568B1 (en) 2021-12-16 2024-02-16 Oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3130570A1 (en) 2021-12-16 2023-06-23 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3130610A1 (en) 2021-12-20 2023-06-23 L'oreal Composition comprising a polyhydroxyalkanoate copolymer with a long hydrocarbon chain containing ionic group(s), process for treating keratin materials using the composition
FR3136967A1 (en) 2022-06-22 2023-12-29 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3136975A1 (en) 2022-06-22 2023-12-29 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3136972A1 (en) 2022-06-22 2023-12-29 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3136968A1 (en) 2022-06-22 2023-12-29 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3136976A1 (en) 2022-06-22 2023-12-29 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3136966A1 (en) 2022-06-22 2023-12-29 L'oreal Composition for lightening keratin fibers and process for lightening keratin fibers using this composition
FR3144510A1 (en) 2022-12-29 2024-07-05 L'oreal Composition comprising at least N,N-dicarboxymethyl glutamic acid, at least one direct dye, at least one cationic polysaccharide, and at least one non-cationic polysaccharide
FR3144513A1 (en) 2022-12-29 2024-07-05 L'oreal Composition comprising at least N,N-dicarboxymethyl glutamic acid, at least one direct dye, and at least one associative polymer
FR3144511A1 (en) 2022-12-29 2024-07-05 L'oreal Composition comprising at least one direct dye, at least N,N-dicarboxymethyl glutamic acid, at least one cationic surfactant and at least one non-silicone fatty substance in a particular content
FR3144512A1 (en) 2022-12-29 2024-07-05 L'oreal Composition comprising at least N,N-dicarboxymethyl glutamic acid, at least one coloring agent, and at least one fatty amine

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