RU95112455A - Инденильные соединения, компонент катализатора для полимеризации олефинов, способ полимеризации олефинов, полиолефин - Google Patents

Инденильные соединения, компонент катализатора для полимеризации олефинов, способ полимеризации олефинов, полиолефин

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Publication number
RU95112455A
RU95112455A RU95112455/04A RU95112455A RU95112455A RU 95112455 A RU95112455 A RU 95112455A RU 95112455/04 A RU95112455/04 A RU 95112455/04A RU 95112455 A RU95112455 A RU 95112455A RU 95112455 A RU95112455 A RU 95112455A
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Russia
Prior art keywords
ind
polymerization
indenyl
group
olefins
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RU95112455/04A
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English (en)
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RU2128183C1 (ru
Inventor
Антониус Мария Ван Бек Йоханнус
Nl]
Герардус Де Врис Йоханнес
Йоханнес Артс Хенрикус
Персад Радьиндракумар
Хенрикус Йозефус Ван Доремале Герардус
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Дсм Н.В. (Nl)
Дсм Н.В.
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Application filed by Дсм Н.В. (Nl), Дсм Н.В. filed Critical Дсм Н.В. (Nl)
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Изобретение относится к инденильному соединению общей формулы R'Ind-M-(Cp)Q, в которой символы имеют следующие значения: Ind - инденильная группа, R' - заместитель группы Ind, отличный от водорода, Ср-циклопентадиенильная группа, М - переходный металл из 3, 4, 5 или 6 группы периодической системы элементов, Q- лиганд для М, k - целое число, связанное с валентностью М. Изобретение характеризуется тем, что заместитель R' присоединен к Ind группе во 2-м положении. Инденильные соединения являются компонентом катализатора для полимеризации олефинов. Изобретение также относится к полимерам, получаемым с помощью таких инденильных соединений.

Claims (1)

  1. Изобретение относится к инденильному соединению общей формулы R'Ind-M-(Cp)Qk, в которой символы имеют следующие значения: Ind - инденильная группа, R' - заместитель группы Ind, отличный от водорода, Ср-циклопентадиенильная группа, М - переходный металл из 3, 4, 5 или 6 группы периодической системы элементов, Qk - лиганд для М, k - целое число, связанное с валентностью М. Изобретение характеризуется тем, что заместитель R' присоединен к Ind группе во 2-м положении. Инденильные соединения являются компонентом катализатора для полимеризации олефинов. Изобретение также относится к полимерам, получаемым с помощью таких инденильных соединений.
RU95112455A 1992-11-11 1993-11-03 Инденильные соединения, способ полимеризации олефина, полиолефин RU2128183C1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL9201970 1992-11-11
NL9201970A NL9201970A (nl) 1992-11-11 1992-11-11 Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
PCT/NL1993/000229 WO1994011406A1 (en) 1992-11-11 1993-11-03 Indenyl compounds and catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
RU95112455A true RU95112455A (ru) 1997-03-20
RU2128183C1 RU2128183C1 (ru) 1999-03-27

Family

ID=19861509

Family Applications (1)

Application Number Title Priority Date Filing Date
RU95112455A RU2128183C1 (ru) 1992-11-11 1993-11-03 Инденильные соединения, способ полимеризации олефина, полиолефин

Country Status (15)

Country Link
US (2) US5646322A (ru)
EP (1) EP0668865B1 (ru)
JP (1) JP3419456B2 (ru)
CN (1) CN1088212A (ru)
AU (1) AU677026B2 (ru)
BR (1) BR9307420A (ru)
CA (1) CA2149026A1 (ru)
DE (1) DE69333114T2 (ru)
ES (1) ES2203621T3 (ru)
FI (1) FI114798B (ru)
MY (1) MY130143A (ru)
NL (1) NL9201970A (ru)
NO (1) NO306782B1 (ru)
RU (1) RU2128183C1 (ru)
WO (1) WO1994011406A1 (ru)

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FI952266A0 (fi) 1995-05-10
CN1088212A (zh) 1994-06-22
FI952266A (fi) 1995-05-10
NO306782B1 (no) 1999-12-20
DE69333114T2 (de) 2004-06-24
WO1994011406A1 (en) 1994-05-26
EP0668865A1 (en) 1995-08-30
RU2128183C1 (ru) 1999-03-27
US5990253A (en) 1999-11-23
US5646322A (en) 1997-07-08
NO951848D0 (no) 1995-05-10
DE69333114D1 (de) 2003-08-28
JP3419456B2 (ja) 2003-06-23
NO951848L (no) 1995-07-11
CA2149026A1 (en) 1994-05-26
EP0668865B1 (en) 2003-07-23
BR9307420A (pt) 1999-08-31
MY130143A (en) 2007-06-29
FI114798B (fi) 2004-12-31
AU677026B2 (en) 1997-04-10
NL9201970A (nl) 1994-06-01
JPH08503457A (ja) 1996-04-16
AU5577494A (en) 1994-06-08
ES2203621T3 (es) 2004-04-16

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