RU95112455A - Инденильные соединения, компонент катализатора для полимеризации олефинов, способ полимеризации олефинов, полиолефин - Google Patents
Инденильные соединения, компонент катализатора для полимеризации олефинов, способ полимеризации олефинов, полиолефинInfo
- Publication number
- RU95112455A RU95112455A RU95112455/04A RU95112455A RU95112455A RU 95112455 A RU95112455 A RU 95112455A RU 95112455/04 A RU95112455/04 A RU 95112455/04A RU 95112455 A RU95112455 A RU 95112455A RU 95112455 A RU95112455 A RU 95112455A
- Authority
- RU
- Russia
- Prior art keywords
- ind
- polymerization
- indenyl
- group
- olefins
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Изобретение относится к инденильному соединению общей формулы R'Ind-M-(Cp)Q, в которой символы имеют следующие значения: Ind - инденильная группа, R' - заместитель группы Ind, отличный от водорода, Ср-циклопентадиенильная группа, М - переходный металл из 3, 4, 5 или 6 группы периодической системы элементов, Q- лиганд для М, k - целое число, связанное с валентностью М. Изобретение характеризуется тем, что заместитель R' присоединен к Ind группе во 2-м положении. Инденильные соединения являются компонентом катализатора для полимеризации олефинов. Изобретение также относится к полимерам, получаемым с помощью таких инденильных соединений.
Claims (1)
- Изобретение относится к инденильному соединению общей формулы R'Ind-M-(Cp)Qk, в которой символы имеют следующие значения: Ind - инденильная группа, R' - заместитель группы Ind, отличный от водорода, Ср-циклопентадиенильная группа, М - переходный металл из 3, 4, 5 или 6 группы периодической системы элементов, Qk - лиганд для М, k - целое число, связанное с валентностью М. Изобретение характеризуется тем, что заместитель R' присоединен к Ind группе во 2-м положении. Инденильные соединения являются компонентом катализатора для полимеризации олефинов. Изобретение также относится к полимерам, получаемым с помощью таких инденильных соединений.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL9201970 | 1992-11-11 | ||
NL9201970A NL9201970A (nl) | 1992-11-11 | 1992-11-11 | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
PCT/NL1993/000229 WO1994011406A1 (en) | 1992-11-11 | 1993-11-03 | Indenyl compounds and catalyst components for the polymerization of olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
RU95112455A true RU95112455A (ru) | 1997-03-20 |
RU2128183C1 RU2128183C1 (ru) | 1999-03-27 |
Family
ID=19861509
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU95112455A RU2128183C1 (ru) | 1992-11-11 | 1993-11-03 | Инденильные соединения, способ полимеризации олефина, полиолефин |
Country Status (15)
Country | Link |
---|---|
US (2) | US5646322A (ru) |
EP (1) | EP0668865B1 (ru) |
JP (1) | JP3419456B2 (ru) |
CN (1) | CN1088212A (ru) |
AU (1) | AU677026B2 (ru) |
BR (1) | BR9307420A (ru) |
CA (1) | CA2149026A1 (ru) |
DE (1) | DE69333114T2 (ru) |
ES (1) | ES2203621T3 (ru) |
FI (1) | FI114798B (ru) |
MY (1) | MY130143A (ru) |
NL (1) | NL9201970A (ru) |
NO (1) | NO306782B1 (ru) |
RU (1) | RU2128183C1 (ru) |
WO (1) | WO1994011406A1 (ru) |
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KR940009020B1 (ko) * | 1990-07-24 | 1994-09-29 | 미쓰이 도오아쓰 가가쿠 가부시키가이샤 | α-올레핀의 중합촉매 및 그것을 이용한 폴리 α-올레핀의 제조방법 |
EP0485823B1 (de) * | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
DE4039451A1 (de) * | 1990-12-11 | 1992-06-17 | Hoechst Ag | Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren |
ATE199911T1 (de) * | 1991-05-27 | 2001-04-15 | Targor Gmbh | Verfahren zur herstellung von polyolefinen mit breiter molmassenverteilung |
US5391789A (en) * | 1991-08-08 | 1995-02-21 | Hoechst Aktiengesellschaft | Bridged, chiral metallocenes, processes for their preparation and their use as catalysts |
DE4139261A1 (de) * | 1991-11-29 | 1993-06-03 | Basf Ag | Ethylen-copolymerisate niederer dichte |
ES2100388T3 (es) * | 1992-05-26 | 1997-06-16 | Hoechst Ag | Procedimiento para preparar ceras de poliolefina. |
ES2114978T3 (es) * | 1992-08-03 | 1998-06-16 | Targor Gmbh | Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos con ligandos indenilo de substitucion especial. |
NL9201970A (nl) * | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
US5372980A (en) * | 1993-06-03 | 1994-12-13 | Polysar | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers |
DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
DE4344688A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
-
1992
- 1992-11-11 NL NL9201970A patent/NL9201970A/nl not_active Application Discontinuation
-
1993
- 1993-11-03 AU AU55774/94A patent/AU677026B2/en not_active Expired - Fee Related
- 1993-11-03 BR BR9307420-4A patent/BR9307420A/pt not_active Application Discontinuation
- 1993-11-03 CA CA002149026A patent/CA2149026A1/en not_active Abandoned
- 1993-11-03 JP JP51194394A patent/JP3419456B2/ja not_active Expired - Fee Related
- 1993-11-03 DE DE69333114T patent/DE69333114T2/de not_active Expired - Lifetime
- 1993-11-03 ES ES94901064T patent/ES2203621T3/es not_active Expired - Lifetime
- 1993-11-03 WO PCT/NL1993/000229 patent/WO1994011406A1/en active IP Right Grant
- 1993-11-03 RU RU95112455A patent/RU2128183C1/ru active
- 1993-11-03 EP EP94901064A patent/EP0668865B1/en not_active Expired - Lifetime
- 1993-11-10 CN CN93112942A patent/CN1088212A/zh active Pending
- 1993-11-10 MY MYPI93002351A patent/MY130143A/en unknown
-
1995
- 1995-05-10 FI FI952266A patent/FI114798B/fi not_active IP Right Cessation
- 1995-05-10 NO NO951848A patent/NO306782B1/no not_active IP Right Cessation
- 1995-05-11 US US08/439,449 patent/US5646322A/en not_active Expired - Lifetime
-
1997
- 1997-03-10 US US08/812,675 patent/US5990253A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
FI952266A0 (fi) | 1995-05-10 |
CN1088212A (zh) | 1994-06-22 |
FI952266A (fi) | 1995-05-10 |
NO306782B1 (no) | 1999-12-20 |
DE69333114T2 (de) | 2004-06-24 |
WO1994011406A1 (en) | 1994-05-26 |
EP0668865A1 (en) | 1995-08-30 |
RU2128183C1 (ru) | 1999-03-27 |
US5990253A (en) | 1999-11-23 |
US5646322A (en) | 1997-07-08 |
NO951848D0 (no) | 1995-05-10 |
DE69333114D1 (de) | 2003-08-28 |
JP3419456B2 (ja) | 2003-06-23 |
NO951848L (no) | 1995-07-11 |
CA2149026A1 (en) | 1994-05-26 |
EP0668865B1 (en) | 2003-07-23 |
BR9307420A (pt) | 1999-08-31 |
MY130143A (en) | 2007-06-29 |
FI114798B (fi) | 2004-12-31 |
AU677026B2 (en) | 1997-04-10 |
NL9201970A (nl) | 1994-06-01 |
JPH08503457A (ja) | 1996-04-16 |
AU5577494A (en) | 1994-06-08 |
ES2203621T3 (es) | 2004-04-16 |
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