RU2018119291A - COMPOSITION OF ALPHA- INSOLUBLE IN WATER- (1,3 → Glucan) - Google Patents

COMPOSITION OF ALPHA- INSOLUBLE IN WATER- (1,3 → Glucan) Download PDF

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RU2018119291A
RU2018119291A RU2018119291A RU2018119291A RU2018119291A RU 2018119291 A RU2018119291 A RU 2018119291A RU 2018119291 A RU2018119291 A RU 2018119291A RU 2018119291 A RU2018119291 A RU 2018119291A RU 2018119291 A RU2018119291 A RU 2018119291A
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coating composition
agent
aqueous coating
aqueous
base
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RU2018119291A
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RU2018119291A3 (en
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Натнаэль БЕХАБТУ
Сяоцин ЛИ
Майкл Стефен ВУЛФ
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Е.И.Дюпон Де Немур Энд Компани
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Publication of RU2018119291A3 publication Critical patent/RU2018119291A3/ru

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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/52—Cellulose; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/72—Coated paper characterised by the paper substrate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/08—Ingredients of unknown constitution and ingredients covered by the main groups C08K3/00 - C08K9/00

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paper (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Laminated Bodies (AREA)
  • Seasonings (AREA)

Claims (26)

1. Основа, где на по меньшей мере часть основы нанесен слой композиции покрытия, причем композиция покрытия содержит:1. A base, wherein at least a portion of the base is coated with a coating composition layer, the coating composition comprising: i) нерастворимый в воде полимер α-(1,3→глюкан), содержащий 90% или более α-1,3-гликозидных связей, массовую долю менее чем 1% α-1,3,6-гликозидных точек ветвления, и его среднечисловая степень полимеризации находится в пределах от 55 до 10000; иi) a water-insoluble α- (1,3 → glucan) polymer containing 90% or more α-1,3-glycosidic bonds, a mass fraction of less than 1% of α-1,3,6-glycosidic branch points, and the number average polymerization is in the range from 55 to 10,000; and ii) по меньшей мере один пигмент, по меньшей мере одно связующее или их комбинацию.ii) at least one pigment, at least one binder, or a combination thereof. 2. Основа по п. 1, где основа представляет собой целлюлозную основу, полимер, бумагу, текстиль, картонную бумагу, картон или гофрированный картон.2. The base according to claim 1, where the base is a cellulosic base, polymer, paper, textiles, cardboard paper, cardboard or corrugated cardboard. 3. Основа по п. 1, где средний размер объема пор слоя композиции покрытия составляет от 0,1 до 0,50 миллилитра/грамм.3. The basis of claim 1, wherein the average pore volume size of the coating composition layer is from 0.1 to 0.50 milliliters / gram. 4. Основа по п. 1, где связующее представляет собой поливиниловый спирт, поливинилацетат, частично омыленный поливинилацетат, модифицированный силанолом поливиниловый спирт, полиуретан, крахмал, кукурузный декстрин, карбоксиметилцеллюлозу, простые эфиры целлюлозы, гидроксиэтилцеллюлозу, гидроксипропилцеллюлозу, этилгидроксиэтилцеллюлозу, метилцеллюлозу, альгинаты, альгинат натрия, ксантан, каррагинан, казеин, соевый белок, гуаровые камеди, синтетические полимеры, бутадиен-стирольный латекс, стиролакрилатный латекс или их комбинации.4. The base according to claim 1, wherein the binder is polyvinyl alcohol, polyvinyl acetate, partially saponified polyvinyl acetate, silanol-modified polyvinyl alcohol, polyurethane, starch, corn dextrin, carboxymethyl cellulose ethers, cellulose ethers, hydroxyethyl cellulose, hydroxycyl cellulose cellulose cellulose acetate. sodium, xanthan, carrageenan, casein, soy protein, guar gums, synthetic polymers, styrene butadiene latex, styrene acrylate latex, or combinations thereof. 5. Основа по п. 1, где композиция покрытия содержит массовую долю в пределах от 0,1 до 50% нерастворимого в воде полимера α-(1,3→глюкана) от общей массы композиции покрытия.5. The base according to claim 1, where the coating composition contains a mass fraction in the range from 0.1 to 50% of a water-insoluble polymer α- (1,3 → glucan) of the total weight of the coating composition. 6. Основа по п. 1, где композиция покрытия дополнительно содержит одну или несколько: iv) добавок.6. The basis of claim 1, wherein the coating composition further comprises one or more: iv) additives. 7. Основа по п. 1, где нерастворимый в воде полимер α-(1,3→глюкан) является линейным полимером, имеющим 99% или более α-1,3-гликозидных связей и менее 1% α-1,3,6-гликозидных точек ветвления.7. The base according to claim 1, where the water-insoluble polymer α- (1,3 → glucan) is a linear polymer having 99% or more α-1,3-glycosidic bonds and less than 1% α-1,3,6 -glycoside branch points. 8. Основа по п. 1, где композиция покрытия не содержит или в основном не содержит крахмал или гидроксиалкилкрахмал.8. The basis of claim 1, wherein the coating composition does not or substantially does not contain starch or hydroxyalkyl starch. 9. Основа по п. 6, где добавка представляет собой одно или несколько из диспергента, солей четвертичного аммония, хлорида кальция, ПАВ, отвердителя, вещества, улучшающего растекаемость, смазки, антивспенивателя, высвобождающего агента, вспенивателя, вещества, способствующего просачиванию, оптического отбеливателя, консерванта, биоцида, ингибитора пожелтения, поглотителя ультрафиолетового излучения, антиоксиданта, вещества, препятствующего солюбилизации, антистатика, регулятора pH, водостойкого агента, упрочняющего во влажном и/или сухом состоянии средства, сшивающего агента, впитывающего вещества для глянцевой краски, добавки для жиро- и маслостойкости, выравнивающего вспомогательного вещества или их комбинации.9. The basis of claim 6, wherein the additive is one or more of a dispersant, quaternary ammonium salts, calcium chloride, a surfactant, a hardener, a spreading agent, a lubricant, an anti-foaming agent, a releasing agent, a blowing agent, an penetration promoting agent, an optical brightener , preservative, biocide, yellowing inhibitor, ultraviolet absorber, antioxidant, anti-solubilization agent, antistatic agent, pH adjuster, waterproof agent, hardening in wet and / or dry TATUS agent, a crosslinking agent, an absorbent material for gloss paint, additives for grease and oil resistance, leveling auxiliary substances or combinations thereof. 10. Водная композиция покрытия, включающая в себя композицию покрытия по п. 1 и iii) водный носитель.10. An aqueous coating composition comprising a coating composition according to claim 1 and iii) an aqueous carrier. 11. Водная композиция покрытия по п. 10, где водная композиция покрытия не содержит водорастворимые полисахариды.11. The aqueous coating composition of claim 10, wherein the aqueous coating composition does not contain water soluble polysaccharides. 12. Водная композиция покрытия по п. 10, где содержание водного носителя составляет (в массовых долях) 60% или менее от общей массы водной композиции покрытия.12. The aqueous coating composition of claim 10, wherein the content of the aqueous carrier is (in mass fractions) 60% or less of the total weight of the aqueous coating composition. 13. Водная композиция покрытия по п. 10, где композиция покрытия дополнительно содержит одну или несколько iv) добавок.13. The aqueous coating composition of claim 10, wherein the coating composition further comprises one or more iv) additives. 14. Водная композиция покрытия по п. 10, где композиция в основном не содержит крахмал или гидроксиалкилкрахмал.14. The aqueous coating composition of claim 10, wherein the composition is substantially free of starch or hydroxyalkyl starch. 15. Водная композиция покрытия по п. 10, где полимер α-(1,3→глюкан) является линейным полимером, имеющим 99% или более α-1,3-гликозидных связей и менее 1% α-1,3,6-точек ветвления.15. The aqueous coating composition of claim 10, wherein the α- (1,3 → glucan) polymer is a linear polymer having 99% or more α-1,3-glycosidic bonds and less than 1% α-1,3,6- branch points. 16. Водная композиция покрытия по п. 10, где связующее представляет собой поливиниловый спирт, поливинилацетат, частично омыленный поливинилацетат, модифицированный силанолом поливиниловый спирт, полиуретан, крахмал, кукурузный декстрин, простые эфиры целлюлозы, гидроксиэтилцеллюлозу, гидроксипропилцеллюлозу, этилгидроксиэтилцеллюлозу, метилцеллюлозу, альгинаты, альгинат натрия, ксантан, каррагинан, гуаровые камеди, синтетические полимеры, бутадиен-стирольный латекс или их комбинацию.16. The aqueous coating composition of claim 10, wherein the binder is polyvinyl alcohol, polyvinyl acetate, partially saponified polyvinyl acetate, silanol-modified polyvinyl alcohol, polyurethane, starch, corn dextrin, cellulose ethers, hydroxyethyl cellulose, hydroxypropyl cellulose, ethyl gum, hydroxyethyl cellulose, ethyl sulfate. sodium, xanthan, carrageenan, guar gums, synthetic polymers, styrene butadiene latex, or a combination thereof. 17. Водная композиция покрытия по п. 13, где добавка представляет собой одно или несколько из диспергента, солей четвертичного аммония, хлорида кальция, ПАВ, отвердителя, вещества, улучшающего растекаемость, смазки, антивспенивателя, высвобождающего агента, вспенивателя, вещества, способствующего просачиванию, оптического отбеливателя, консерванта, биоцида, ингибитора пожелтения, поглотителя ультрафиолетового излучения, антиоксиданта, вещества, препятствующего солюбилизации, антистатика, регулятора pH, водостойкого агента, упрочняющего во влажном и/или сухом состоянии средства, сшивающего агента, впитывающего вещества для глянцевой краски, добавки для жиро- и маслостойкости, выравнивающего вспомогательного вещества или их комбинации.17. The aqueous coating composition of claim 13, wherein the additive is one or more of a dispersant, quaternary ammonium salts, calcium chloride, a surfactant, a hardener, a spreading agent, a lubricant, an anti-foaming agent, a releasing agent, a blowing agent, an infiltrating agent, optical brightener, preservative, biocide, yellowing inhibitor, ultraviolet absorber, antioxidant, anti-solubilization agent, antistatic agent, pH regulator, waterproof agent that strengthens on the wet and / or dry state of the product, a crosslinking agent, an absorbent for glossy paint, additives for grease and oil resistance, leveling excipients, or combinations thereof. 18. Способ формирования на основе слоя композиции покрытия, включающий в себя18. A method of forming a coating composition based on a layer, including 1) нанесение водной композиции покрытия на по меньшей мере часть основы, где водная композиция покрытия содержит:1) applying an aqueous coating composition to at least a portion of the base, wherein the aqueous coating composition comprises: i) нерастворимый в воде полимер α-(1,3→глюкан), содержащий 90% или более α-1,3-гликозидных связей, менее чем 1% α-1,3,6-гликозидных точек ветвления, и его среднечисловая степень полимеризации находится в пределах от 55 до 10000;i) a water-insoluble α- (1,3 → glucan) polymer containing 90% or more of α-1,3-glycosidic bonds, less than 1% of α-1,3,6-glycosidic branch points, and its number average polymerization is in the range from 55 to 10,000; ii) пигмент, связующее или их комбинацию;ii) a pigment, a binder or a combination thereof; iii) водный носитель; иiii) an aqueous carrier; and 2) удаление по меньшей мере части водного носителя из нанесенного слоя водной композиции покрытия с целью формирования слоя композиции покрытия.2) removing at least a portion of the aqueous carrier from the applied layer of the aqueous coating composition in order to form a layer of the coating composition. 19. Способ по п. 18, где основа представляет собой бумагу или полимер.19. The method of claim 18, wherein the base is paper or polymer.
RU2018119291A 2015-10-26 2016-10-24 COMPOSITION OF ALPHA- INSOLUBLE IN WATER- (1,3 → Glucan) RU2018119291A (en)

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US201562246308P 2015-10-26 2015-10-26
US62/246,308 2015-10-26
PCT/US2016/058453 WO2017074862A1 (en) 2015-10-26 2016-10-24 Water-insoluble alpha-(1,3->glucan) composition

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JP7420561B2 (en) * 2017-06-30 2024-01-23 ニュートリション・アンド・バイオサイエンシーズ・ユーエスエー・フォー，インコーポレイテッド Polysaccharide-elastomer masterbatch composition
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