RU2018101886A - Способ получения содержащей углеродные нанотрубки композиции - Google Patents
Способ получения содержащей углеродные нанотрубки композиции Download PDFInfo
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- RU2018101886A RU2018101886A RU2018101886A RU2018101886A RU2018101886A RU 2018101886 A RU2018101886 A RU 2018101886A RU 2018101886 A RU2018101886 A RU 2018101886A RU 2018101886 A RU2018101886 A RU 2018101886A RU 2018101886 A RU2018101886 A RU 2018101886A
- Authority
- RU
- Russia
- Prior art keywords
- producing
- carbon nanotube
- composition according
- carbon
- containing composition
- Prior art date
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims 12
- 239000002041 carbon nanotube Substances 0.000 title claims 10
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims 10
- 239000000203 mixture Substances 0.000 title claims 7
- 238000004519 manufacturing process Methods 0.000 title claims 6
- 239000012159 carrier gas Substances 0.000 claims 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical class [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 150000003464 sulfur compounds Chemical class 0.000 claims 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000001307 helium Substances 0.000 claims 1
- 229910052734 helium Inorganic materials 0.000 claims 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 125000004434 sulfur atom Chemical group 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 229930192474 thiophene Natural products 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/14—Production of inert gas mixtures; Use of inert gases in general
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
- B82B3/0042—Assembling discrete nanostructures into nanostructural devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/04—Nanotubes with a specific amount of walls
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/30—Purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/45—Aggregated particles or particles with an intergrown morphology
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/742—Carbon nanotubes, CNTs
- Y10S977/752—Multi-walled
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/843—Gas phase catalytic growth, i.e. chemical vapor deposition
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Thermal Sciences (AREA)
- Carbon And Carbon Compounds (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Claims (10)
1. Способ получения содержащей углеродные нанотрубки композиции для синтеза агрегатов углеродных нанотрубок, включающий:
введение ферроценового производного, соединения серы, источника углерода и газа-носителя в газовую фазу, протекающую в нагревательной печи, в пределах диапазона температур от выше 1200°C до 1800°C, причем
источник углерода по существу состоит из бензола или толуола,
газ-носитель содержит водород в диапазоне от 10% по объему до 85% по объему, и
газ-носитель имеет линейную скорость в диапазоне от 500 см/мин до 2200 см/мин.
2. Способ получения содержащей углеродные нанотрубки композиции по п.1, причем газ-носитель содержит по меньшей мере один газ, выбранный из азота, аргона и гелия, в диапазоне от более чем 15% по объему до менее чем 90% по объему.
3. Способ получения содержащей углеродные нанотрубки композиции по п.1, причем атомы серы, содержащиеся в соединении серы, содержатся в диапазоне от 0,15 моль до 0,20 моль на 1 моль атомов железа, содержащихся в ферроценовом производном.
4. Способ получения содержащей углеродные нанотрубки композиции по п.1, причем ферроценовое производное представляет собой ферроцен.
5. Способ получения содержащей углеродные нанотрубки композиции по п.1, причем соединение серы представляет собой тиофен.
6. Способ получения содержащей углеродные нанотрубки композиции по п.1, причем полученные агрегаты углеродных нанотрубок содержат двухслойные углеродные нанотрубки.
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-142018 | 2015-07-16 | ||
| JP2015142018 | 2015-07-16 | ||
| JP2016013932 | 2016-01-28 | ||
| JP2016-037380 | 2016-02-29 | ||
| JP2016037380 | 2016-02-29 | ||
| JP2016-013932 | 2016-06-30 | ||
| PCT/JP2016/070715 WO2017010523A1 (ja) | 2015-07-16 | 2016-07-13 | カーボンナノチューブ含有組成物の製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2018101886A true RU2018101886A (ru) | 2019-08-16 |
Family
ID=57757961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018101886A RU2018101886A (ru) | 2015-07-16 | 2016-07-13 | Способ получения содержащей углеродные нанотрубки композиции |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10266411B2 (ru) |
| EP (1) | EP3305723B1 (ru) |
| JP (1) | JP6094723B1 (ru) |
| KR (1) | KR20180029968A (ru) |
| CN (1) | CN107614426B (ru) |
| RU (1) | RU2018101886A (ru) |
| WO (1) | WO2017010523A1 (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7062365B2 (ja) * | 2017-02-28 | 2022-05-06 | 株式会社名城ナノカーボン | 電界放出装置 |
| US10994990B1 (en) * | 2018-11-13 | 2021-05-04 | United States Of America As Represented By The Secretary Of The Air Force | Inline spectroscopy for monitoring chemical vapor deposition processes |
| JP7158646B2 (ja) * | 2019-08-09 | 2022-10-24 | 学校法人早稲田大学 | カーボンナノチューブの製造装置および製造方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4405650B2 (ja) | 1999-07-13 | 2010-01-27 | 日機装株式会社 | 炭素質ナノチューブ、繊維集合体及び炭素質ナノチューブの製造方法 |
| US6790426B1 (en) * | 1999-07-13 | 2004-09-14 | Nikkiso Co., Ltd. | Carbonaceous nanotube, nanotube aggregate, method for manufacturing a carbonaceous nanotube |
| JP2002088591A (ja) | 2000-09-14 | 2002-03-27 | National Institute Of Advanced Industrial & Technology | 微細炭素繊維の製造方法 |
| JP3754417B2 (ja) | 2000-10-06 | 2006-03-15 | フラーレン インターナショナル コーポレイション | 二重壁炭素ナノチューブ並びにその製造および使用方法 |
| CN1237001C (zh) * | 2002-12-13 | 2006-01-18 | 中国科学院金属研究所 | 一种膜状和定向绳状双壁纳米碳管的制备方法 |
| JP4968643B2 (ja) | 2004-12-13 | 2012-07-04 | 日機装株式会社 | 単層カーボンナノチューブの製造方法 |
| EP2025643B1 (en) | 2006-04-24 | 2018-03-07 | National Institute of Advanced Industrial Science and Technology | Method for producing single-walled carbon nanotubes |
| CN101585525B (zh) * | 2008-05-21 | 2011-03-23 | 中国科学院金属研究所 | 一种直径可调的单壁纳米碳管的制备方法 |
| CN101585526B (zh) * | 2008-05-21 | 2011-05-11 | 中国科学院金属研究所 | 一种叠杯状纳米碳管的制备方法 |
| CN101830455B (zh) * | 2010-04-30 | 2012-07-04 | 北京航空航天大学 | 一种合成连续碳纳米管薄膜的方法 |
| JP5735234B2 (ja) | 2010-08-26 | 2015-06-17 | 帝人株式会社 | カーボンナノチューブ連続繊維の製造方法およびその製造装置 |
| CN103204492A (zh) * | 2013-05-03 | 2013-07-17 | 苏州汉纳材料科技有限公司 | 一种提高单壁碳纳米管产率的新方法 |
| JP2015048263A (ja) * | 2013-08-30 | 2015-03-16 | 帝人株式会社 | 単層カーボンナノチューブ及び二層カーボンナノチューブを含有しているカーボンナノチューブ集合体、並びにその合成方法 |
-
2016
- 2016-07-13 WO PCT/JP2016/070715 patent/WO2017010523A1/ja active Application Filing
- 2016-07-13 EP EP16824503.3A patent/EP3305723B1/en active Active
- 2016-07-13 CN CN201680031380.2A patent/CN107614426B/zh not_active Expired - Fee Related
- 2016-07-13 US US15/736,495 patent/US10266411B2/en not_active Expired - Fee Related
- 2016-07-13 KR KR1020177035907A patent/KR20180029968A/ko unknown
- 2016-07-13 JP JP2016564654A patent/JP6094723B1/ja not_active Expired - Fee Related
- 2016-07-13 RU RU2018101886A patent/RU2018101886A/ru not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017010523A1 (ja) | 2017-01-19 |
| CN107614426A (zh) | 2018-01-19 |
| EP3305723B1 (en) | 2021-03-31 |
| EP3305723A1 (en) | 2018-04-11 |
| JPWO2017010523A1 (ja) | 2017-07-13 |
| KR20180029968A (ko) | 2018-03-21 |
| CN107614426B (zh) | 2020-09-25 |
| US10266411B2 (en) | 2019-04-23 |
| EP3305723A4 (en) | 2018-06-27 |
| US20180170758A1 (en) | 2018-06-21 |
| JP6094723B1 (ja) | 2017-03-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA93 | Acknowledgement of application withdrawn (no request for examination) |
Effective date: 20210119 |